THE SCIENTIFIC PAPERS OF THE HONOURABLE HENRY CAVENDISH, F.R.S. CAMBRIDGE UNIVERSITY PRESS C. F. CLAY, MANAGER LONDON : FETTER LANE, E.G. 4 NEW YORK : THE MACMILLAN CO. BOMBAY \ CALCUTTA [ MACMILLAN AND CO., LTD. MADRAS I TORONTO : THE MACMILLAN CO. OK CANADA, LTD. TOKYO : MARUZEN-KABUSHIKI-KAISHA ALL RIGHTS RESERVED THE SCIENTIFIC PAPERS OF THE HONOURABLE HENRY CAVENDISH, F.R.S. VOLUME I THE ELECTRICAL RESEARCHES Edited from the Published Papers, and the Cavendish Manuscripts in the possession of His GRACE THE DUKE OF DEVONSHIRE, K.G., F.R.S. by JAMES CLERK MAXWELL, F.R.S. CAVENDISH PROFESSOR OF EXPERIMENTAL PHYSICS IN THE UNIVERSITY OF CAMBRIDGE Revised by SIR JOSEPH LARMOR, F.R.S., M.P. LUCAS1AN PROFESSOR OF MATHEMATICS CAMBRIDGE AT THE UNIVERSITY PRESS 1921 The Electrical Researches First Edition 1879 Reprinted as Volume I of The Scientific Papers 1921 6? 1/3 CIS i/, I PREFACE TO VOLUME I THE University of Cambridge has a deep interest both in the Author and in the Editor of the electrical investigations now presented in final form in this volume. Henry Cavendish matriculated in the University on 18 Dec. 1749, from Hackney School. According to records preserved at Peterhouse he commenced residence there on 24 Nov. 1749, and resided very regularly and constantly as a Fellow-Commoner until 23 Feb. 1753, when he left without proceeding to a degree. Two others of the Cavendish family were at Peterhouse at the same time; Henry's younger brother Frederick who was entered 10 April, 1751, and also left without taking his degree; and his cousin Lord John Cavendish, fourth son of the Duke of Devonshire, afterwards Chancellor of the Exchequer, who was entered 21 Feb. 1750 and became M.A. in 1753. Among his contemporaries at Peterhouse, then as now a small society, were the Earl of Euston, afterwards as Duke of Grafton prominent in the writings of Junius, Gray the poet and also Mason*, and the Greek critic Markland, who was Senior Fellow of the College at the time and always in residence. These details are taken from a statement contributed in 1851 to Dr G. Wilson's Life of Cavendish^ by Prof. F. Fuller, then Fellow and Tutor of Peterhouse. James Clerk Maxwell graduated at Cambridge in Jan. 1854. After two years' resident activity at Cambridge, including election to a Fellowship at Trinity College, he was appointed in April, 1856 to the Chair of Natural Philosophy in Marischal College, Aberdeen. There he worked until 1860, when on the fusion of the two Aberdeen Universities he became Professor of Natural Philosophy in King's College, London. He resigned that Chair at Easter, 1865, left London the following year and settled down at his inherited home at Glenlair near Dalbeattie in Galloway. To quote his own words of Feb. 1866 (Life, 1882, by L. Campbell and W. Garnett, p. 344) : " I have now my time fully occupied with experiments and speculations of a physical kind, which I could not undertake so long as I had public duties." The result has contributed, more than any other cause, to the modern revolution in the ideas and methods of physical science. In October, 1870 William Cavendish, Duke of Devonshire, who had graduated as second wrangler and first Smith's Prizeman in Mathematics and a first class in Classics in 1829, and was elected in 1861 Chancellor of * Mason was tutor to Lord John Cavendish, but was of Pembroke College, having previously been of St John's. t Cf. also The Cavendish Family by F. Bickley (1911), pp. 197-208. vi Preface the University, signified his desire to build and furnish a Physical Laboratory for Cambridge: and in prospect of that gift the Cavendish Professorship of Experimental Physics was founded by Grace of the Senate in Feb. 1871. In response to appeals from the prominent Cambridge men of the time, including Stokes, W. Thomson, and Rayleigh, Clerk Maxwell was persuaded to offer himself for the Chair. He was formally elected the following month, after six years of retired study and investigation which doubtless had matured and consolidated the intellectual interests of his life, including the preparation of the Electricity and Magnetism (Feb. 1873) and the Theory of Heat (1870). The Laboratory was planned and furnished under Maxwell's direction, and formally handed over to the University in the spring of 1874. It was not however until 1877 that the Chancellor had completed his gift "by furnishing the Cavendish Laboratory with apparatus suitable to the present state of science"; an equipment to which Maxwell afterwards contributed many additions. Later, Lord Rayleigh, when Chancellor of the University, devoted the proceeds of the award of a Nobel Prize to provide for an urgent expansion of the Laboratory of which he had himself been Director. The Electricity and Magnetism shows many marks of hurried final consolidation with a view to immediate publication. It was said that the pressing need of a textbook in the University was a paramount considera- tion : there was no treatise of comparable depth and grasp at that time in any language. And certainly under Maxwell's influence Cambridge was the focus in which the new electrical ideas, inherited in outline from Faraday, were developed and propagated, years before they were taken up in other countries and thus became everywhere the mainspring of pro- gress in physical science. Maxwell's own personal investigations during the Cambridge period, in addition to a series of brilliant articles, now classical, written for the Encyclopaedia Britannica, were concerned mainly with the development of the other equally fundamental, but analytically much more complex, subjects centring round the molecular theory of gases; in this domain also he had previously (1860) been the originator of the modern exact analysis, based on application of the mathematical principles of statistics to the fortuitous dance of the innumerable molecules. According to Maxwell's biographers his chief continuous literary occupation, for the five years from 1874 to his death in October, 1879, was the editing of the Electrical Researches of Henry Cavendish. It had been well known that Cavendish's papers, preserved in the possession of his kinsman the Duke of Devonshire, contained a very remarkable and even mysterious record of progress in electrical as well as chemical science, effected a hundred years previously by a solitary investigator, of which only fragments had been revealed by various men of science who had seen the manuscripts. The publication of an adequate account of the researches of Cavendish was a task obviously incumbent on British science, for its Preface vii own sake ; but the difficulty and labour of the undertaking, and the learning and historical research that it involved, had hitherto warned off the men most competent to discharge it. The zeal of Maxwell for his new Cavendish foundation was not thus to be deterred. Already in July, 1874, we find him writing from Glenlair to Mr Garnett (Life, p. 389) : In the MS. he appears to be familiar with the theory of divided currents and also of conductors in series, but some reference to his printed paper [on the Torpedo] is required to throw light on what he says. He made a most extensive series of experiments on the conductivity of saline solutions in tubes, compared with wires of different metals, and it seems as if more marks were wanted for him if he cut out G. S. Ohm long before constant currents were invented. His measures of capacity will give us some work at the Cavendish Laboratory, before we work up to the point where he left it. His only defect is not having Thomson's electrometer. He found out inductive capacity of glass, resin, wax, etc. According to Mr Garnett (Life, p. 555) who was in a position to be intimately acquainted with the facts: The amount of labour which Professor Maxwell bestowed on this work during the last five years of his life can only be known to those who were constantly in his company. Nearly all the MSS. he transcribed with his own hand, the greater part being copied after midnight.... Every obscure passage or altera- tion was the subject of a long and searching investigation: and many were the letters written to the Librarian of the Royal Society and to scientific and literary friends in different parts of the country, to gain information respecting the meaning of obsolete words and symbols, or the history of individuals. And besides this, and a comparison of Cavendish's results with those obtained by subsequent investigators, Maxwell repeated many of Cavendish's experiments almost in their original form, only employing modern instruments for the purposes of measurement. The result of five years of continual application to the subject was the volume published in October, 1879 by the Cambridge University Press, a few weeks before the death of its Editor, and now reprinted in different form. The introductory sketch prepared by Maxwell, probably at the end of his task, gives a clear and most interesting summary of the electrical work of Cavendish: the postscript dated 14 June, 1879, describing some manuscripts on magnetism that had just come to hand, coincides with the beginning of his final illness. There is perhaps no instance in the history of science in which the unpublished records left by an investigator have been arranged and elucidated with such minute fidelity. Careless though Cavendish was of scientific reputation, intent on pressing on to new solitary achievement, to the neglect of publication, due as it would seem as much to the habit of continual postponement of final preparations for the press as to the fascination of exercising his powers of discovery — and even, as it has Vlll Preface proved, as a consequence of his recluse and self-centred life— there are perhaps few investigators of the first rank of whose work and aims and procedure we have now more complete knowledge than of his. The additions appended by Maxwell, in the form of thirty-five notes of elucidation and commentary, on modern lines, relating to Cavendish's results and methods, constitute an example of powerful and elegant relevant original investigation such as could hardly have been carried through by anyone else. Advantage has been taken of the present reprint of the Electrical Researches, as constituting Volume I of a definitive edition of the Scientific Writings of Henry Cavendish, to add a few brief annotations and references such as were needed to bring Clerk Maxwell's commentary up to date. These notes, where appended to Cavendish's text, are enclosed in curved brackets to distinguish them from Maxwell's own. As examples, reference may be made to pp. 374, 413, 422. The printing of the original edition had probably proceeded at intervals, and the final consolidation must have gone on during Prof. Maxwell's last illness in the summer of 1879. Thus it has now been possible to improve the headings of the chapters and sections, and the headlines of the pages, so as to convey a clearer and more rapid view of the nature and content of the text. The index and table of contents have been improved. Apart from his permanent contributions to experimental laws, it is possible to maintain that the theoretical views of Cavendish should now command on historical grounds even more interest than they could excite in 1878, when the Electrical Researches were made public in complete form by Clerk Maxwell. At that time attention was largely concentrated on the elucidation of the electric field, and the mode of transmission of electrical influence from one body to another. The formal settlement of that range of problems on the lines of the Faraday-Maxwell theory has now transferred investigation to the sources of electric influence; and problems of the distribution of electrons in conducting and insulating bodies, their relation to the electrically polarisable molecules of matter, their function in conduction and in radiation, even the exploration of crystals in atomic detail by radiations of molecular wave-length, are now opening out. These problems all involve interaction in a binary medium, electrons and molecules controlling activities in an aether; it is now an affair of relations of the field of transmission with electrically polar or polarisable molecules which are its sources; and though this is very different from Cavendish's idea of a uniform electric fluid pervading and inter- acting with material substances by mere attraction, yet the degree of success that had been attained by the earliei and simpler mode of repre- sentation can become again by contrast a subject of historical scientific interest. The title of one of Lord Kelvin's best-known memoirs, "^ atomized," is evidence for this view. Preface ix Numerous biographies of Cavendish have been published. He was one of the select circle of foreign associates of the Institute of France; and French interest in his work, stimulated by its close relations with that of Lavoisier, was reflected in memoirs by Cuvier in the £loges Historiques de I' Academic, vt>l. i and by Biot in the Biographic Universelle, vol. vn. These and other biographies are drawn upon by Dr George Wilson in the very thorough Life of Cavendish (pp. 478), including an analysis of his chemical work, which was undertaken under the auspices of the Cavendish Society, founded in 1846, and appeared in 1851 as one of the early volumes of their publications. The biographical sketch contributed by Dr Thomas Young to the sup- plement of the Encyclopaedia Britannica about 1820 has been reprinted here as an Appendix. Young must have been personally well acquainted with Cavendish, and no one was better qualified to form a contemporary judgment on his career. The portrait prefixed to the present volume is said to have been con- structed from surreptitious sketches made by the artist W. Alexander at a dinner of the Royal Society Club. The original is in the print room of the British Museum, where it was re-discovered by Charles Tomlinson, F.R.S. who had an engraving made from it. This engraving has been reproduced as a frontispiece to Wilson's Life, and many times since. The present photo- graphic impression has been taken from the original picture, by permission of the authorities of the British Museum. It has been the custom, even among Cavendish's admirers, to brand him as misanthropic. But there is surely another side to this judgment. The cultivation of the highest domains of physical science is rarely consistent with dispersal of interest in other directions. The tracking out of great discoveries which will be a possession to the human race for all time has indeed to be its own supreme intellectual satisfaction; and once an in- vestigator has realized, in however modest a way, his capacity for such achievement, he can feel that he is serving humanity in the most perfect manner open to him by concentrating upon that work. Yet the temptation to continual postponement of ordinary social intercourse inevitably involves increasing isolation, and growing habits of solitude. As already noted, there is no evidence that Cavendish's researches aimed at his personal gratification alone : if they had not been adequately recorded by him they could not have been recovered so completely: and it is easy to understand how the driving force of his curiosity and conscious power would impel him to the exploration of new fields, in temporary preference to the final polishing of work already achieved. If he spent his life in compelling the phenomena of physical nature to submit to exact measure and weight, it was not from a special passion for such work, for its own sake, but as the one means of assuring an adequate foundation for sciences then being born : in all directions he was opening up and securing brilliant x Preface vistas into the philosophical explication of nature. Though standing so far beyond most of his contemporaries in intellect and vision, there is abundant evidence in these volumes that in the cooperative tasks which united the scientific men of the time, largely conducted under the auspices of the Royal Society, he was always ready to take unsparing pains, 'and to devote himself without limit to the assistance of his colleagues. The operations and discussions preparatory to the gravity survey of Schehallion, sum- marised in Vol. II, are an example. The two volumes now published may be regarded as the final garnering of the work of one of the greatest of scientific discoverers. The acknowledg- ments of the intellectual world will doubtless be accorded to the Cambridge University Press for their courage in facing the great expense involved in a complete edition of the writings of Cavendish, in a form adequate to the subject, which was projected in the less exacting times before the Great War. The Editors desire to record their thanks to the staff of the Press for very efficient cooperation on the technical side of the undertaking. J.L. CAMBRIDGE, February 1921. CONTENTS INTRODUCTION BY THE EDITOR CAVENDISH AND HIS RESEARCHES PAGE Biographical data 1 Lord Charles Cavendish's experiments 1 Henry Cavendish lived with his father during his electrical researches ... 2 His laboratory in Great Maryborough Street ........ 2 His apparatus .............. 3 His attendant 5 Committee of the Royal Society on lightning conductors 5 Cavendish's researches on the electric current ........ 6 Papers on the Torpedo by Walsh, Hunter, &c. ........ 7 Experiment on the formation of nitric acid before the Royal Society .... 9 Cavendish's artificial Torpedo 9 CAVENDISH'S WRITINGS ON ELECTRICITY The two papers in the Philosophical Transactions . . . . . . .10 The manuscripts — Sir W. Snow Harris' account of them . . . . . .10 List of the manuscripts ............ 1 2 Order of the manuscripts determined 13 Why Cavendish did not publish them 15 State of electrical science. Lord Mahon's experiments. Estimate of Cavendish by Dr Thomas Young ............15 Coulomb's researches 18 Cavendish's method 18 Comparison of charges ............ 18 Proof of the law of force ............ 19 Experiments on coated plates — spreading of electricity 20 Specific inductive capacity ........... 21 Plates of air 21 " Whether the charge of a coated plate bears the same proportion to that of a simple conductor, whether the electrification is strong or weak" 21 Effect of temperature 22 Effect of floor, walls, and ceiling of room ......... 23 Experiments on resistance 23 Reference to these experiments in the paper on the Torpedo ..... 23 Method of the experiments 24 Determination of the ''power of the velocity to which the resistance is -proportional " 25 Resistance of salt solution at different temperatures 26 Resistance of pure water 26 Resistance of solutions of different salts ......... 27 Chemical equivalents of different substances as given by Cavendish .... 28 Postscript relating to papers on magnetism ........ 29 xii Contents FIRST PUBLISHED PAPER ON ELECTRICITY P. 33 AN ATTEMPT TO EXPLAIN SOME OF THE PRINCIPAL PHENOMENA OF ELECTRICITY, BY MEANS OF AN ELASTIC FLUID From the Philosophical Transactions for 1771 (pp. 584-667) Part I ARTICLES Hypothesis 1-6 Repulsion of a cone on a particle at the vertex 7-1 1 Force between two bodies over or under charged 13-15 Equilibrium of the electric fluid 16.1? Repulsion of a spherical shell . . . . • . • • . . 18,19 Equilibrium of electricity in a globe 20-27 Two plane parallel plates 28-38 Canals of incompressible fluid 39"53 Pressure of electric fluid against a surface 54 Circular disk 55~66 Charges of similar bodies as the n - i power of their corresponding diameters, and independent of the material of which they are made 67-72 Charge of a thin flat plate independent of its thickness 73 Two parallel circular plates 74-83 Equilibrium of electricity in bodies communicating by a canal is independent of the form of the canal 84-93 Whether the conditions of equilibrium are the same for two bodies communicating by a conducting wire as if they communicated by a canal of incompressible fluid 94-96 Molecular constitution of air 97 Part II p. 66 CONTAINING A COMPARISON OF THE FOREGOING THEORY WITH EXPERIMENT § i . Conductors and non-conductors 98 Electric properties of air and vacuum 99. >oo Positive and negative electrification 101-105 § 2. Attraction and repulsion 106-117 Electrometer in electrified air n? § 3. On the cases in which bodies receive electricity from or part with it to the air 1 18-122 §4. Effect of points on discharge 123-126 § 5. Canton's and Franklin's experiments 127 §6. On the Leyden vial 128-133 § 7. Wilcke and /Epinus's experiment of electrifying a plate of air (Mem. Berl. 1756, p. 119) 134 § 8. Electric spark i3S-'39 PRELIMINARY PROPOSITIONS . . p. 82 From the MS. in the possession of the Duke of Devonshire, No. 4 Prop, xxix (Fig. i). If the fluid uniformly spread on a circular plate is to that collected in the circumference as p to i the capacity of the plate is to that of the globe as p + i to 2p + 1 '4° Prop. xxx. Capacity of two disks at a finite distance 141 Cor. i. Capacity in terms of p H2 Cor. 2. Capacity when the density is supposed uniform 143 Cor. 3. The place in which the canal meets the disk is indifferent only when the fluid is in equilibrium .........•••• '44 Lemma xn (Fig. 2). Repulsion of a particle on a column 145 Contents xiii ARTICLES Lemma xiii. Repulsion of two columns !^6 Lemma xiv r^7 Lemma xv (Fig. 3). Action of a uniform cylinder on an external point . . . 148 Cor. Potential of middle and end .......... 149 Prop, xxxi (Fig. 3). Charge of cylinder compared with that of globe .... 150 Cor. Upper and lower limits of charge . . . . . . . . .151 Prop, xxxn (Fig. 4). Charge of two equal cylinders at a finite distance . . . 152 Prop, xxxin. Ratio of charges of B and b may be deduced from the ratios of Band b to C 153 Lemma xv (Fig. 5). Repulsion on a short column close to an electrified plate . . 154 Lemma xvi (Fig. 6). Two equidistant concave plates 155 Cor. i. Definition of corresponding points, &c. ....... 156 Cor. 2. Density increasing towards the circumference . . . . . .157 Lemma xvn (Fig. 7). Concave plate compared with flat one 158 Cor 159 Prop, xxxiv (Fig. 8). Theory of a coated plate 160 Cor. i. Flat coated plate of any form 161 Cor. 2. Flat circular plate . . . . . . ... . . . 162 Cor. 3. Plate not flat but of uniform thickness . . . . . . . .163 Cor. 4. Density increasing towards the circumference . . . . . .164 Cor. 5. General conclusion . . . . . . , . . . .165 Cor. 6. Comparison with globe 166 Cor. 7. Form of plate indifferent 167 Cor. 8. Charge directly as surface and inversely as thickness 168 Prop, xxxv (Fig. 9). Theory of conducting strata in the glass plate .... 169 Prop, xxxvi (Fig. 10). Penetration of glass by fluid 170 Cor. i. Equivalent thickness of plate if there were no penetration .... 171 Cor. 2. Thickness of coatings indifferent ......... 172 Prop, xxxvii. Density more nearly uniform than if there had been no penetration . 173 Cor. Distribution probably nearly the same as in plate of air of equivalent thickness 174 APPENDIX p. 102 From MS. No. 5 Prop. i. Charge of a condenser little affected by the presence of an overcharged body 175 Cor 176 Prop. II 177 Part i. A stricter demonstration, applicable to case of penetration . . . .178 Part II 179 Cor. i 180 Cor. 2 181 Cor. 3 182 Cor. 4. Effect of an overcharged body 183 Cor. 5 184 Cor. 6 (Fig. 1 1). Two coated plates in communication little affected by an overcharged body 185 Cor. 7. Canals may be curved as well as straight . . . . . . .186 Lemma. Potential of two equal particles compared with that of their sum at their centre of mass .............. 1 87 Applied to case of two parallel disks 188 Mutual action of large circle and trial plate in Experiment v ..... 189 Mutual action of small circles and trial plate in Experiment v 190 [General negative conclusion] . . . . . . . . . . .192 Effect of floor and walls of the room .......... 193 Effect of earth connexion the same as if it were infinitely long ..... 194 b xiv Contents THOUGHTS CONCERNING ELECTRICITY P. 110 From MS. No. 18. (Probably an early draft of the theory) ARTICLES Hypothesis of an electric fluid . . 195 The fluid acts at a distance but does not itself extend to any perceptible distance from electrified bodies 196 Proof of this, and objections to the hypothesis of electric atmospheres . . . 197 On the hypothesis of electric atmospheres .198 Condition of electric equilibrium between conductors in electric communication . 199 Illustration from the equilibrium of air ......... 200 Definitions of positive and negative electrification, and of over and under charge . 201 Four hypotheses 202 Cor. I, 2. Effect of two overcharged bodies approaching each other . . . . 203 Cor. 3, 4. Equally electrified bodies repel 204 Cor. 5. Electrification by induction . . . . . . . . . . 205 Cor. 6. Theory of condensers 206 Shock of the Leyden vial 207 Fifth hypothesis, on the communication of electricity between conductor and the surrounding air 208 Effect of an overcharged body 209 Attraction and repulsion of electrified bodies 210 Electrification by induction . . . . . . . . . . .211 The electric spark 212 Vacuum formed by the spark 213 Statement of the theory of one electric fluid ....... 214-216 ACCOUNT OF THE EXPERIMENTS . . P. 118 (i) INVESTIGATION OF THE LAW OF FORCE From MS. No. 7 (apparently prepared for publication) The electricity of glass is here taken to be positive 217 First experiment. A globe within a hollow globe and in communication with it does not become over or undercharged when the whole is electrified (Fig. 12) . . 218 General description of the apparatus . . . . . . . . . .219 General plan of the experiment ........... 220 The apparatus actually used 221 Mechanism for performing the required operations 222 The charging jar 223 The gauge electrometer ............ 224 Reason for using the jar 225 Theory of the experiment ............ 226 Result of the experiment ............ 227 Second method of trying the experiment 228 Advantages of the second method 229 Estimation of the degree of accuracy of the result 230 The charge of the inner globe is less than Js °f tnat °f tne outer globe . . . 23 1 Hence the electric force is inversely as the square of the distance . . . .232 Demonstration of this by Lemma 4 (Fig. 13) . 233 Limits between which the law of force must lie, n = 2 ± ^5 . . . . . 234 Second experiment. A piece of wood within a vessel formed of two wooden drawers 235 Contents xv (2) EXPERIMENTS ON THE COMPARISON OF CHARGES From MS. No. 9 (apparently prepared for publication) ARTICLES Intention of the experiments ........... 236 Definition of the ratio of the charges of two bodies, illustrated by the comparison of a disk with a sphere ............ 237 Method of the experiment ........... 238 The [adjustable] trial plate. (Fig. 13) 239 Arrangement of the apparatus 240 Method of operation. (Fig. 14) 241 Theory of the experiment 242 Interpretation of the result ........... 243 The testing electrometer ............ 244 Method of testing ............. 245 Advantages of the method 246 Capacity of the trial plate 247 The gauge electrometer ............ 248 Form of electrometer used in the later experiments. (Fig. 30) 249 Estimation of error arising from unequal electrification in the two trials . . . 250 Comparison of the capacities of two bodies . . . . . . . .251 Demonstration 252 Why the electrification is tested by the gauge electrometer 253 The bodies to be tested were chosen of nearly equal capacity 254 Measurements of the apparatus 255 The insulating supports of waxed glass. (Fig. 16) ....... 255 Electrification of air ............. 256 Effects of the electrification of the air 257 The earth-connexions 258 The electrometer threads salted .......... 259 Leakage of the Leyden vials 260 Estimate of the accuracy of the experiments 261 Probable cause of error ............ 262 Weak charges always used 263 Reason for this .............. 264 Third experiment. On the effect of variations in the arrangement of the apparatus in testing capacities. (Fig. 17) ........... 265 Six different arrangements ........... 266 Result of the six arrangements ........... 267 Conclusion .............. 268 Fourth experiment. Capacities of bodies of different substances, but of the same shape and size .............. 269 Glass coated with various substances ......... 270 Method of the experiment 271 Effect of the thickness of a plate on its capacity ....... 272 Fifth experiment. Charge of two small circles compared with that of a large one. (Fig. 18) 273 Results of the experiment 274 The experiment repeated in a different manner . . . ^ 275 Comparison with theory 276 Remarks on the calculation 277 Bearing on the theory ............ 278 Sixth experiment. Charge of two short wires compared with that of one long one . 279 Comparison with theory 280 Seventh experiment. Comparison of the capacities of several bodies .... 281 Comparison of disk with sphere . 282 bi xvi Contents ARTICLES Comparison of square plate with disk Oblong plate ... 284 Cylinder ... 285 Comparison of different cylinders Disturbing cause 2^7 Eighth experiment. Comparison of the charge of the middle plate of three parallel plates with that of the outer ones. (Fig. 19) Comparison with theory 2^9 Distribution on the middle plate ........-•• 29° GENERAL CONCLUSIONS First experiment 29' Second experiment .......-••••• 292 Fourth experiment ........••••• 293 Remaining experiments • 294 (3) COMPARISON OF THE CHARGES OF COATED PLATES From MS. No. 10 (apparently prepared for publication) New apparatus for the comparison of capacities (Fig. 20) 295 Method of making the experiment • • • • 29& The trial plate 297 Second method 29§ Advantage of the second method 299 Spreading of electricity on the surface of the glass. (Fig. 21) 3°° Difference between different kinds of glass in this respect . . . . • • 3°' Determination of the velocity of spreading ..... 3°2 Attempt to check the spreading of electricity by means of cement. (Fig. 22) . . 303 Results with cement and varnish 3°4 These methods abandoned 3°S Earth-connexion 3°° Instantaneous spreading of electricity on the surface ; electric light around the edge . 307 Fringe of dirt 3°8 Extent of this spreading 3°9 Spreading greatest at first time of charging • .310 Recapitulation of the theory of coated plates 311 Correction of the area for spreading of electricity ... 3 > 2 Computed charge of cylindric vials 3 '3 Experiments on 10 pieces of glass from the same piece . . . . • 3'4 Table of their dimensions 3'5 Adjustment of size of coatings 3'6 Comparison of D +E + F when close together and when six inches apart . . . 3 '7 Comparison of the plates with each other . . . . . • • • • 3 ' 8 Discrepancy probably due to spreading . . . . . • • • • 3'9 Experimental investigation of spreading 32° Slit coatings. (Fig. 23, Fig. 24) 32' Effect of thickness of glass 322 Spreading = 0-07 on thick plates and 0-09 on thin plates 323 Table of plates with circular coatings .......•• 324 Table of the same plates with other coatings . . . . . . • • 325 Verification of the theory of spreading 32° Effect of thickness of glass 327 Spreading not uniform throughout its extent . . . . . . • 32& Effect of different strengths of electrification . . . . . . • • 329 Comparison of crown glass with Nairne's plates 33° Effect of accumulation near the edge insensible . . . . . . . -33' Contents xvii ARTICLES Charge of glass plates is many times greater than it ought to be by the theory . . 332 Comparison with the globe ........... 333 Consideration of the effects of external bodies on the globe and the plates . . . 334 Effect of the floor and walls of the room on the charge of the globe .... 335 Experimental investigation of this effect ......... 336 Comparison of the charges of four rosin plates with those of circles 9^3, 18-5, and 36 inches diameter ............ 337 Hypothesis about the relative effect of surrounding bodies on the capacities of different bodies ............... 338 Application of this hypothesis to the three circles and the globe ..... 339 Charge of a plate of air ............ 340 Plate of air between glass plates with tinfoil coatings 341 Experiments with plates of air ........... 342 Table of Results with plates of air . . . . . . . . . . 343 Experiment to determine whether the air between the plates is charged . . . 344 The air is not charged ............ 345 Comparison with computed charge .......... 346 The table agrees with the theory nearly but not quite ...... 347 Suggested explanation ............ 348 Three hypotheses to explain why the charge of glass plates is rather more than eight times what it ought to be by the theory ........ 349 First hypothesis. Electricity penetrates into the glass to a certain depth . . . 349 Second hypothesis. A conducting stratum within the glass. (Fig. 25) . . . 350 Third hypothesis. A great number of strata alternately conducting and non-conducting. (Fig. 26) 351 Conduction only normal to the surface of the plate ....... 352 Reasons for preferring the third hypothesis ........ 353 Another reason — analogy of Newton's fits ......... 354 Effect of different degrees of electrification on the charge of a plate .... 355 Comparison of the plate D with the circle of 36 inches diameter with two different degrees of electrification. No apparent alteration in capacity .... 356 Correction for greater amount of spreading with the stronger degree of electrification 357 Comparison with a very weak degree of electrification. Large cylinder and wire. (Fig. 27) 358 Method of the experiment ........... 359 Result with weak electrification 360 Comparison with the usual strength of electrification 361 Comparison of the results ............ 362 Discussion of the results . . . . . . . . . . . -363 Comparison with positive and negative electrification . . . . . .364 Accumulation at the edge is greater in plates of air than in glass plates of the same thickness .............. 365 Charge of coated glass at different temperatures. (Fig. 28) 366 The edges of the coatings kept at constant temperature 367 Table of results at different temperatures ......... 368 Glass conducts electricity better as the temperature rises ...... 369 Table of the charges of glass plates .......... 370 Table of the charges of plates of other substances . . . . . . 371 Explanation of the tables 372 Method of making plates of wax, &c. ......... 373 Difficulty of making a plate of shellac ......... 374 Dephlegmated bees wax 375 The charge of a coated plate depends on the substance of which it is made . 376 Difference between thick plates and thin ones ........ 377 The thick plate of crown glass ........... 378 xviii Contents ARTICLES Theory of compound plates 379 Experiments with compound plates of glass ........ 380 Experiments with glass and rosin .......... 381 Charge of hollow cylinders of glass 382 Table of results with cylindric vials .......... 383 Discussion of the results • 3^4 Appearance of the three green cylinders 385 (4) REPULSION AS SQUARE OF REDUNDANT FLUID From MS. No. 8 The repulsion between two bodies electrified to the same degree ought, by the theory, to be proportional to the square of the quantity of redundant fluid . . . 386 Experiment to test the theory. (Fig. 31) 38? Comparison of the force required to produce an equal divergence of the two electro- meters ............... 388 The Leyden jars 389 Method of the experiment 39° Discussion of the experiment ........... 391 Method of preventing the vibration of the straws .... . 392 No sensible error due to leakage 393 Effect of want of conductivity of the straws 394 SECOND PUBLISHED PAPER ON ELECTRICITY P. 194 AN ACCOUNT OF SOME ATTEMPTS TO IMITATE THE EFFECTS OF THE TORPEDO BY ELECTRICITY From the Phil. Trans, for 1776 (pp. 196-225) Walsh's experiments on the Torpedo 395, 396 Shock given by the Torpedo under water 397 Electric resistance of salt and fresh water, and of iron wire .... 398 Lines of flow of the discharge of the Torpedo ...... 399> 400 Conditions requisite for a spark and for attraction and repulsion . . . 401-408 Artificial Torpedo 409, 410 The battery and its charge 411-413 Mode of charging the battery 414 Shocks in air and under salt water. Law of divided currents .... 415-420 Torpedo in a basket ; in sand ; shock through wet shoes and through net . . 42 1 -424 Why the Torpedo gives no spark 425-435 Structure of the electric organ .......... 436 Shock through a chain without any light 437 EXPERIMENTS IN 1771 ... P. 211 From MS. No. 12 ist Night 438 2nd Night 439 3rd Night ............... 440 Two pairs of large corks made, one four times as heavy as the other. Measurement of capacity of vial by touching eight or nine times with coated plate and wire . . 441 Thickness. C -0601 1 Three coated plates .... 442 D -05908 F -05914 Contents xix ARTICLES C, D, F close together and far asunder 443 Three coated plates, 1-8 diam., 'i8 thick ......... 444 Globe and circle, 19-4 of pasteboard. Sliding plates 19 x 13 Circle of 1-8 x -18 20-2 _ 10 globe ~ 12-4" 6 Double plate, 1-75 x -285, tried with small sliding trial plate; Double plate 1 1 globe ~ 18 Thick plate, 1-45 x -168 _ 14 "globe -13 "6 Trials of wires. Single wire, 96 x -19. Two wires, 48 x -i at 36 and 18 . . . 447 Two wires, •! x 24, at 18, 36 ........... 448 Results of wires ............. 449 Large circle on waxed glass and on silk ......... 450 Coated glass compared with non-electric body with strong and weak electricity . . 45 1 Two tin circles of 9-3, compared with one of 18-5 . 452 Brass wire, 72 x -19 453 Results. Best formula for cylinder .......... 454 Coated trial plate of two plates of glass with rosin between . . . . 455 Trial plate, Double plate A, Double plate B, Large circle (18-5?), I7i- 18-4. 18-3. 18-5. Globe, Globe ,8-8. circle = '^ «6 Double plates A and B, and plate air, -39 x7'95 ....... 457 Real power of plate air = computed x '243 [computed is 8 times too great] . . . 458 N, O, P,Q 459 B [2-79], D [2-73], white [2-85]. B, D, N, W tried 460 A [2-16], ist rosin 2-51, trial plates, Art. 457 461 Results for D, W, B, P, N, O, Q 462 Coated plate compared with non-electric body with strong and weak + and - electricity 463 Rosin, 3'4i x -345, compared with double B, by sliding coated plate .... 464 Side of square equivalent to trial plates ......... 465 EXPERIMENTS IN 1772 P. 224 From MS. No. 13 Plan of usual disposition of vials and bodies to be tried ...... 4°° Exp. in 46? Do. Dec. 14, 1771 4°8 Dec. 16, 1771. Conductivity of stone squares 4^9 Dec. 17, 1771. Exp. in 47° Dec. 18. Exp. IV 47' „ Exp. v, circles 9-3 and 18-5 472 Dec. 30. Exp. v, observations 473 „ Exp. v, 2nd arrangement 474 Dec. 31. Observations 475 Two wires, 36 x -i, and i of 72 x -185, Exp. VI 47^ Jan. 3, 1772. Observations ......••••• 477 Exp. vn : Large tin circle. Double plate B, Tin cylinder, 35-9, 2-53 \ Globe, Tin plate square, 15-5 „ 54'2» '73 i • • 4?8 Double plate A. „ oblong, 17-9 x 13-4 wire, 72, -i8sJ xx Contents ART1CI.KS Results: comparison with Art. 455 • • 479 Exp. IV 48° Table omitted 48 ' Twelve plates from Nairne, A to M . 48^ D, E, F, G compared with double A and B • 483 Trial plates of Nuremberg glass, H, I, K, L. Art. 303. H, I, K, L cased with cement. E, F, G and I, K, L of Nairne cased in cement. Plate of cement . . . 484 Spreading of electricity on cemented plates. Art. 302 . . 485 Rate of spreading 4^6 Trial of spreading by machine. (Fig. 20) . 4**7 Three sliding coated plates with brass slides. Six trial plates . 488 Feb. 4, 1772, D, E, F, G. Two double plates . . 489 E + F + G, with I, K, L, M .490 Closing of balls 4Qi Feb. 5, 1772, I + K + L, with A + B + C + H, crown glass trial plates . . 492 A + B + C.withH 493 EXPERIMENTS IN 1773 ... P 240 From MS. No. 14 [Cavendish's Index] PAGE The pages refer to the MS., the numbers of the Articles to the present edition OF MS. i-io. Spreading of electricity on the surface of glass ...... 494 n. List of thickness and coatings of some plates, see p. 27 500 12. Quantity of electricity in thick rosin compared with double plate B, and in 2nd rosin with D, E and G of Nairne 501 13. Q and P compared with M and K of Nairne, also green cylinder 4, and white cylinder compared with plates of Nairne by means of sliding trial plates . . 502 14. ist and 2nd green and white cylinders and white jar compared with H of Nairne in usual manner ............ 503 15. The same in the same way, except with addition of plate M on the negative side in some experiments 504 16. Quantity of electricity in the two coated globes, and in the two jars used in the machine for trying plain plates 505 17. Quantity of electricity in the 4 jars, and in the 5th and 6th sliding trial plates . 506 18. Thick rosin compared with double plates A and B, and thick white and 2nd rosin with D, E, F and G of Nairne 507 19. Thick white, 2nd rosin, D and F of Nairne and the two double plates together, compared together; also thin white with D and E, and D and F . . . 508 20. Whitish plate, P, Q, O, old G and thin rosin compared with M . . . 509 21. Crown A and C compared with A, B and C of Nairne 510 23. Whether the shock from the plate [of] air was diminished by changing the air between them* by moving them horizontally . . . . . . .511 25. Whether globe included within hollow globe is overcharged by electrifying outer globe 512 26. The same thing tried by a better machine . . . . . . .513 27. Note to list of plates in p. 11 . . . . . . . . . . 514 28. ist and 2nd sliding plates compared with double plate B; also Q, P, O and thin rosin; old G and whitish plate compared with D, E, F and M . . . . 515 30. Whether the charge of plate air is diminished by changing the air between them by lifting up the upper plate . . . . . . . . . .516 31. Trials of plate air i, 2, 3 and 4 517 35. Lac plate and 4th rosin compared with D + E + F, also thin wax with E + F, also thick wax and plate air 5 with D. . . . . . . . .518 * The two flat conductors between which the plate of air lies, or, in modern language, the electrodes. Contents xxi PAGE OF MS. ARTICLES 36. Lac and 4th rosin with D + E + F, also thin wax with D t E, also thick wax, 2nd rosin and first made rosin and plate air 5 with F 519 38. Breaking of electricity through thin plates of lac, experimental rosin, and dephlegmated bees wax . . . . . . . . . . .520 39. The quantity of electricity in a Florence flask tried with and without a magazine 521 41. Computed power of above flask 522 42. As it appeared by the foregoing experiment that the Florence flask contained more electricity when it continued charged a good while than when charged and discharged immediately, it was tried whether the case was the same with the coated globes ............. 523 43. Diminution of shock by passing through different liquors ..... 524 47. Whether force with which bodies repel is as square of redundant fluid tried by pith balls hung by threads .......... 525 5 1 . Whether the charge of plate E bears the same proportion to that of another body, whether the electrification is strong or weak, tried by machine for Leyden vials 526 53. Plain wax and 3rd dephlegmated wax with E + F, and 5th rosin with double plate A and B. Also small ground crown with D +E + F, and large do. with C 527 54. K, L and M, compared with D + E + F at distance and close together ; also large ground crown with C and small one with D + E + F; also 3rd dephlegmated wax and plain wax with E + F; also 5th rosin with double B . . . . . 528 55. K + L + M compared with A, B and C ; also A + B + C with H .... 529 56. K +L + M compared with B, with electrification of different strengths . . 530 57. K + L + M with A, B and C ; also D + E + F with K, L and M ; also small ground crown with K, L and M, and D + E + F, and large ground crown with A, B and C, andK + L + M 531 58. On the light visible round the edges of coated plates on charging them . . 532 59. Crown A and C and large ground crown with C ; also 3rd dephlegmated wax, plain wax and sliding plate 3 with E + F; also 2 double plates with E, F and D 533 60. Charge of the triple plate, the three plates A, B and C placed over each other with bits of lead between coatings 534 61. Whether the charge of plate D bears the same proportion to that of another body whether the charge is strong or weak, tried with machine for Leyden vials . 535 62. H with slits and a crown glass with oblong coating, compared with white cylinder, also A and C with slits compared with B . . . . . . . . 536 65. Crown with slits and H with do. compared with white cylinder, and A and C with oblongs compared with B .......... 537 67. Experiment of p. 61, tried with small ball blown to the end of a thermometer tube ; also fringed rings on plate of crown glass, &c. . . . . . . 538 69. Whether charge of Leyden vial bears the same proportion to that of another body when the electrification is very weak as when it is strong ; tried by communicating the electricity of small pieces of wire to tin cylinder and to D and E . . . 539 70. Lane's electrometer compared with straw and paper electrometers . . . 540 71. Crown and H with slits compared with white cylinder; also on the excitation of electricity by separating a brass plate from a glass one 541 73. Whether the middle of three parallel plates communicating together is much overcharged on electrifying the plates ........ 542 74. Charge of A, B and C laid on each other without any coatings between ; also charge of ist thermometer tube 543 75. Lane's electrometer compared with straw and paper electrometers ; also charge of plate rosin with brass coating made to prevent spreading of electricity . . 544 76. Second thermometer tube ; also comparison of charge of cylinder used in p. 69 with D + E 545 77. Charge of second thermometer tube; also that of rosin plate with brass coating; also that of A, B and C laid on each other without coatings between . . . 546 78. Quantity of electricity in plate D compared with that of tin circle of 36" and one of 30", by machine for trying simple plates ...... 547 79. Charge of plate of experimental rosin designed for compound plate of glass and rosin, tried both when warm and when cold ....... 548 xxii Contents PAGE OF MS. ARTICLES 80. Whether charge of glass plate is the same when warm as when cold . . . 549 81. Crown with slit coatings and H with oblong compared with white cylinder; also second thermometer tube with D + E + F 55° 82. Quantity of electricity in plate D, and rosin with brass coatings, compared with that of tin circle of 36", and one of 30", by machine for trying simple plates with different degrees of electrification SS1 83. Charge of compound plate of glass and rosin ....... 552 85. Circle of i8J" compared with double plates; also plate D, plate air, and the two double plates compared with circles of 36" and 30" 553 86. yo&yi. The same with addit. four small rosin plates ..... 554 87. Whether the four rosin plates contain same quantity of electricity when close together as when at a distance, tried by machine for Leyden vials . . . 555 8y. Whether charge of white glass thermometer tube is the same when hot as when cold 556 92. Allowance for connecting wires in p. 86, &c 557 93. Whether charge of the four rosin plates is the same when close together as when at a distance. Also on excitation of electricity by separating brass plate from glass one 558 94. Comparison of Henly's, Lane's, and straw electrometer 559 95. Excess of redundant fluid on the positive side above the deficiency on the negative side in glass plate and plate air, and compound plate of p. 83, compared with charge of simple plate . . . . . • • • • • 5°° 99. Whether parallelepiped box included in a hollow box of the same shape is over- charged on electrifying the outer box 5O1 100. Globe within hollow globe tried again 562 105. Whether the force with which two bodies repel is as the square of the redundant fluid, tried by straw electrometers 563-? 113. Separation of Henly's electrometer by different strengths of electrification . 568 115. Separation of Henly's electrometer when fixed in the usual way and on upright rod 569 116. Result of the comparison of different electrometers in pp. 70, 75, and 95 . . 570 118. Comparison of Lane's electrometer with light straw electrometer in different weather 571 121. Comparison of strength of shocks by points and blunt bodies . . . 572 122. Whether shock of one jar is greater or less than that of twice that quantity of fluid spread on four jars 573 123. Comparison of the diminution which the shock receives by passing through water in tubes of different bores, and whether it is as much diminished in passing through nine small tubes as through the same length of one large tube, the area of whose bore is equal to that of the nine small ones 574 125. Comparison of the diminution of the shock by passing through iron wire or through salt water 575 126. Measures of glass tubes used in pp. 123 and 124 more accurate, with the com- putations of those pages over again ......... 57° 127. Comparison of conducting powers of sat. sol. S.S.* and rain water . . . 577 128. Whether the electricity is resisted in passing out of one medium into another in perfect contact with it 57$, 579 1 29-1 3 1 . Comparison made at Nairne's of his Henly on conductor, and on upright rod 580 Here ends Cavendish's Index * Sea salt. Contents xxiii M. [MEASURES] .... P. 289 From MS. No. 20 ARTICLES Comparison of charges of jars and battery, method of repeated communication . . 581 Theory pf this method 582 Results 583 Charge of ist battery of Nairne .......... 584 Whether shock is diminished by imperfect conduction of the salt water in the jars . 585 Specific gravity of solutions of salt 586 Rule for finding the quantity of salt in water from its specific gravity . . . 586 Measurement of Lane's second and third electrometers 587 Conductivity of salted wood ........... 588 Dimensions of coatings of glass plates ......... 589 Rules for making trial plates ........... 589 Specifications for coating of plates .......... 589 Measures of thickness of 2nd rosin plate ......... 590 Measures of thickness of crown glass . . . . . . . . .591 From MS. No. 13 List of plates of glass . . . . . . . . . . . 592 Twelve plates from Nairne ........... 593 Green glass cylinders ............ 594 Coatings of jars and cylinders 595 EXPERIMENTS WITH THE ARTIFICIAL TORPEDO P. 301 From MS. No. 20 Shocks from ist Torpedo 596 Theory of divided circuits ............ 597 Shock under water 598 First leather Torpedo ............ 599 Second leather Torpedo, Tuesday, April 4 [1775] 600 Second leather Torpedo, Saturday, May 27 [1775] 601 Mr Ronayne, Mr Hunter, Dr Priestley, Mr Lane, Mr N[airne?]. Same day old Torpedo through bright and dirty links ...... 602 Tried with Lane's electrometer ........... 603 Tuesday, May 30 [1775]. Distance of discharge of Lane the same for great or small number of jars ............. 604 Charge required to force electricity through chain ....... 605 Wednesday, May 3 1 [1775]. Comparison of rows of battery 606 Results of experiments, May 30 607 Tuesday, June 6 [1775]. Torpedos in wet sand ....... 608 Shock through salted wood 609 Monday, June 12 [1775]. Relation between quantity of electricity and number of jars that the intensity of the shock may be the same 610 Second leather Torpedo under water 611 Tuesday, July 4 [1775]. Second leather Torpedo touched in various ways . . 612 Experiments without any Torpedo .......... 613 Anatomy of electric organs of Torpedo 614 Second leather Torpedo new covered . . . . . . . . .615 xx iv Contents RESISTANCE TO ELECTRICITY . . P. 311 From MS. No. 19 ARTICLES Comparison of conducting power of salt and fresh water, in the latter end of March and beginning of April, 1776. Method of experiment . . . . . . . . . . ...616 The experiments . . . . . . . . . . . . .617 Six jars compared with one row. Experiments 618 Examination whether salt in 69 conducts better when warm or when cold . . . 619 Examination whether the proportion which conducting power of sat. sol. and salt in 999 bear to each other is altered by heat ........ 620 Resistance of distilled water ........... 621 Salt in 2999 and salt in 150,000 622 Resistance of salt solutions ........... 623 Comparison of water purged of air and plain water ....... 624 Comparison of water impregnated with fixed air and plain water .... 625 Resistance of solutions of other salts .......... 626 Oil of vitriol, spirit of salt and f. alk. 627 Experiments in January, 1781 ........... 628 To find what power of the velocity the resistance is proportional to . . . . 629 Salt solutions .............. 630 Water and spirits of wine 631 CALIBRATION OF TUBES Jan. 1781. From MS. No. 19 Tube 14 632 Tubes 14, 15, 22, 23, 5, 17 633 Tubes 12, 20 634 Result 635 RESISTANCE OF COPPER WIRE From MS. No. 19 Copper wire on glass reel 636 Failure of former method ............ 637 Barometer tubes as Leyden jars ........... 638 Shock through wire plainly greater than shock received direct 639 The same with jars i , 2 or 4 640 Copper wire stretched by silk; sensation, sound and light of shock .... 641 Wire wound round a slip of glass 642 Wire from reel stretched 14 times round the garden ....... 643 Copper wire silvered put on reel 644 Comparison by sound 645 Results 646 RESULTS [OF COMPARISONS OF CHARGES] . P. 335 From MS. No. 16 Allowance for connecting wire ........... 647 Square : globe : circle :: 1-125 : J'S4 : J 648 Compared results ............. 649 Ditto. 650 Circles 36, 18-5, 9-5 651 Contents xxv ARTICLES Increase of charge by induction ........... 652 Double A and double B 653 Globe and circle i8| 654 D, E, F, G 655 D, E, F, M, K, L 656 A, B, C. K, L, M 657 H . . 658 Instantaneous spreading of electricity 659 Trials 660 Results 661 Tables of results ............ 662, 663 Whether charge of coated glass bears the same proportion to that of another body whether electricity is strong or weak ......... 664 Correction for spreading with electricity strong and weak ...... 665 Experiment with tin cylinder 666 Charge corrected for spreading 667 On plate air 668 Table of plates of air 669 Table 670 Table of Nairne's plates . . . . . . . . . . . . • 671 Computations of other flat plates of glass, &c 672 Table of glass plates 673 Table of other substances ............ 674 On the glass cylinders ............ 675 Table of glass cylinders ............ 676 On the compound plates ............ 677 Experimental rosin 678 Rosin placed between glass plates .......... 679 White glass ball at various temperatures ......... 680 Two circles 681 Globe, circle, square, oblong, cylinder 682 Wires 683 RESULTS [ON RESISTANCE] . . .' P. 349 From MS. No. 19 Pump water, rain water, salt in 1000, sea water 684 Nine tubes compared with one ........... 685 Resistance as i -03rd power of velocity 686 Resistance of iron wire 687 Sat. sol. in 99=39 sat. sol. ........... 688 Experiments in 1776 and 1777 on salt solutions 689 Distilled water .............. 690 Effect of temperature . . . . . . . . . . . .691 Air in water 692 Fixed air in water 693 Other saline solutions ............ 694 Experiments in January, 1781 ........... 695 Water with different quantities of salt in it 696 xxvi Contents NOTES BY THE EDITOR ... P. 352 [JAMES CLERK MAXWELL, 1879] NOTE PAGE 1 . On the theory of the electric fluid 352 2. Distribution of hypothetical fluids in spheres, &c 358 3. Canals of incompressible fluid .......... 365 4. Charges of two parallel disks close together 368 5. Zero of potential ............ 369 6. Molecular constitution of air 370 7. Idea of potential 372 8. Cases of Attraction and Repulsion 373 9. Escape of electricity into the air .......... 374 10. Electromotive force required to produce a spark . 375 n. Two circular disks far apart on the same axis .... . 377 12. Capacity of a long narrow cylinder ......... 382 13. Two influencing cylinders 388 14. Condensers with curved plates 389 15. Glass as a dielectric ............ 3^9 16. Mutual influence of condensers 392 17. General theory of the experiment with trial plates 394 18. On the "Thoughts concerning Electricity" 397 Early form of Cavendish's Theory of Electricity 398 19. Experiment on the charge of a globe between two hemispheres .... 404 20. Capacity of a disk of sensible thickness 409 21. Capacity of two circles on same axis 411 22. Capacity of a square . . . . . . . . . . . • 412 23. Charge of the middle one of three parallel plates 413 24. Capacity as affected by walls of the room .415 25. Tin cylinder and wires, compared with theory 416 26. Influence of different temperatures on glass 416 27. Comparison of measurements of dielectric capacity . . . . . .418 28. Computed charge of cylindrical condenser 4'8 29. On Electrical Fishes 4»9 30. Excess of redundant fluid on positive side above deficient fluid on negative side . 423 31. Intensity of shocks 423 32. Iron wire and salt water compared as regards conductance 429 33. Salt and fresh water 429 34. Other saline solutions 43° 35. Globe and disk compared as regards capacity 433 LIFE OF CAVENDISH, BY THOMAS YOUNG . P. 435 INDEX TO CAVENDISH MANUSCRIPTS . P. 449 Contents xxvii ILLUSTRATIONS Henry Cavendish, from the picture by W. Alexander .... Frontispiece FACSIMILES OF CAVENDISH'S FIGURES FIG. PAGE 12. Globe and Hemispheres ng 15. [Adjustable] Trial Plate . I2^ 14. Machine for trying simple conductors 128 30. Electrometer ............. 132 16. Insulators of waxed glass ........... 134 20. Machine for trying Leyden vials 151 23. [Perforated] coatings 163 24. [Slit coatings] 164 28. Effect of heat on glass ........... 182 Facsimile of MS. containing the words "shock melter" ..... 317 Do. containing Calc. S.S.A., &c. 320 In the late Dr George Wilson's collection of Cavendish MSS. -there is a drawing of which the following page is a reduced copy. The words " buried at Derby" are written in pencil on the margin. Henry Cavendish was buried in the Devonshire Vault, All Saints' Church, Derby, but Mr J. Cooling, Jun., Churchwarden of All Saints, inforrns me that there is no slab or monu- ment of any kind erected in memory of him there. [See introduction to Vol. II of this edition.] HENRY CAVENDISH Eldest Son of the Right Honorable LORD CHARLES CAVENDISH, Third Son of William^ 2ND ; for, as the fluid is disposed similarly in both bodies, A r aj the quantity of fluid in any small part of B, is to the quantity in the corresponding part of b, as AF"-1 to a/""1; and consequently the repulsion of that small part of B, on D, is to the repulsion of the corresponding 1 i i part of b, on d, as . F , or --}-=. , to -, . But the quantity of fluid in the AF" AF af small part DE of the canal, is to that in de, as DE to de, or as AF to af; therefore the repulsion of B on the fluid in DE, is equal to that of b on the fluid in de: therefore, taking ag to Aa, as af to AF, the repulsion of b on the fluid in ag, is equal to that of B on the fluid in Aa ; but the repulsion of b on ag may be considered as the same as its repulsion on A a; for, by the supposition, the repulsion of B on A a may be considered as the same as if it was continued infinitely; and therefore, the repulsion of b on ag may be considered as the same as if it was continued infinitely. 56 First published Paper on Electricity N.B. If n was not greater than i, it would be impossible for the length of Aa to be so great, that the repulsion of B on it might be considered as the same as if it was continued infinitely; which was my reason for re- quiring « to be greater than i. 72] COR. By just the same method of reasoning it appears, that if the bodies are undercharged, the quantity of deficient fluid in 6 will be to that in B, as afn~l to AFn~*. 73] PROP. XXI. Let a thin flat plate be connected to any other body, as in the preceding proposition, by a canal of incompressible fluid, per- pendicular to the plane of the plate; and let that body be overcharged, the quantity of redundant fluid in the plate will bear very nearly the same proportion to that in the other body, whatever the thickness of the plate may be, provided its thickness is very small in proportion to its breadth, or smallest diameter. For there can be no doubt, but what, under that restriction, the fluid will be disposed very nearly in the same manner in the plate, whatever its thickness may be ; and therefore its repulsion on the fluid in the canal will be very nearly the same, whatever its thickness may be. [See Exp. IV, Art. 272.] 74] PROP. XXII. Let AB and DF (Fig. 14) represent two equal and parallel circular plates, whose centers are C and E ; let the plates be placed so, that a right line joining their centers shall be perpendicular to the plates; let the thickness of the plates be very small in respect of their distance CE; let the plate AB communicate with the body H, and the plate DF with the body L, by the canals CG and EM of incompressible fluid, such as are described in Prop. XIX; let these canals meet their A D T N- s- fi B F Fig. 14. respective plates in their centers C and E, and be perpendicular to the plane of the plates; and let their length be so great, that the repulsion of the plates on the fluid in them may be considered as the same as if they were continued infinitely; let the body H be overcharged, and let L be saturated. It is plain, from Prop. XII, that DFwill be undercharged, and AB will be more overcharged than it would otherwise be. Suppose, now, that the redundant fluid in AB is disposed in the same manner as the Bodies connected to two parallel disks 57 deficient fluid is in DF; let P be to one as the force with which the plate AB would repel the fluid in CE, if the canal ME was continued to C, is to the force with which it would repel the fluid in CM ; and let the force with which AB repels the fluid in CG, be to the force with which it would repel it, if the redundant fluid in it was spread uniformly, as TT to i; and let the force with which the body H repels the fluid in CG, be the same with which a quantity of redundant fluid, which we will call B, spread uniformly over AB, would repel it in the contrary direction. Then will the redundant D fluid in A B be equal to ^-- pa , and therefore, if P is very small, will T> be very nearly equal to — =- ; and the deficient fluid in DF will be to the redundant fluid in AB, as i — P to i, and therefore, if P is very small, will be very nearly equal to the redundant fluid in AB. For it is plain, that the force with which AB repels the fluid in EM, must be equal to that with which DF attracts it; for otherwise, some fluid would run out of DF into L, or out of L into DF: for the same reason, the excess of the -repulsion of AB on the fluid in CG, above the attraction of FD thereon, must be equal to the force with which a quantity of redundant fluid equal to B, spread uniformly over AB, would repel it, T) or it must be equal to that with which a quantity equal to - , spread in the manner in which the redundant fluid is actually spread in AB, would repel it. By the supposition, the force with which AB repels the fluid in EM, is to the force with which it would repel the fluid in CM, supposing EM to be continued to C, as i — P to i ; but the force with which any quantity of fluid in AB would repel the fluid in CM, is the same with which an equal quantity similarly disposed in DF, would repel the fluid in EM; therefore the force with which the redundant fluid in AB repels the fluid in EM, is to that with which an equal quantity similarly disposed in DF, would repel it, as i — P to i: therefore, if the redundant fluid in A B be called A , the deficient fluid in DF must be A x i — P : for the same reason, the force with which DF attracts the fluid in CG, is to that with which AB repels it, as A x i - P x i — P, or A x (i — P)2, to A ; there- fore, the excess of the force with which AB repels CG above that with which DF attracts it, is equal to that with which a quantity of redundant fluid equal to A — A x (i — P)2, or A x (zP - P2), spread over AB, in the manner in which the redundant fluid therein is actually spread, would repel it : therefore A x (zP — P2) must be equal to - , or A must be equal 7T B to 9.P7T 75] COR. I. If the density of the redundant fluid near the middle of the plate AB, is less than the mean density, or the density which it would 58 First published Paper on E/ectricity everywhere be of, if it was spread uniformly, in the ratio of 8 to i ; and if the distance of the two plates is so small, that EC"*1 is very small in respect of AC"-1, and that ECs~n is very small in respect of AC3-", the B AC quantity of redundant fluid in AB will be greater than - x -^^. 2 3-n , and B AC3~" less than -* x -,^ 28 EC than the former. For, in this case, PIT is, by Lemma X, Corol. IV, less , but will approach much nearer to the latter value EC 3-" EC 3-n , and greater than -^-' x S, but approaches much nearer to A C( the latter value than the former; and if EC3'" is very small in respect of AC3~n, P is very small. 76] REMARKS. If DF was not undercharged, it is certain that AB would be considerably more overcharged near the circumference of the circle than near the center ; for if the fluid was spread uniformly, a particle placed anywhere at a distance from the center, as at N, would be repelled with considerably more force towards the circumference than it would towards the center. If the plates are very near together, and, consequently, DF nearly as much undercharged as A B is overcharged, AB will still be more overcharged near the circumference than near the center, but the difference will not be near so great as in the former case: for, let NR be many times greater than CE, and NS less than CE ; and take Er and Es equal to CR and CS; there can be no doubt, I think, but that the deficient fluid in DF will be lodged nearly in the same manner as the redundant fluid in AB; and therefore, the repulsion of the redundant fluid at R, on a particle at N, will be very nearly balanced by the attraction of the redundant matter at r, for R is not much nearer to N than r is; but the repulsion of S will not be near balanced by that of s ; for the distance of S from N is much less than that of s. Let now a small circle, whose diameter is ST, be drawn round the center N, on the plane of the plate; as the density of the fluid is greater at T than at S, the repulsion of the redundant fluid within the small circle tends to impel the point N towards C ; but as there is a much greater quantity of fluid between N and B, than between N and A , the repulsion of the fluid without the small circle tends to balance that; but the effect of the fluid within the small circle is not much less than it would be, if DF was not undercharged ; whereas much the greater part of the effect of that part of the plate on the outside of the circle, is taken off by the effect of the corresponding part of DF: consequently, the difference of density between T and S will not be near so great as if DF was not undercharged. Hence I should imagine, that if the two plates are very near together, the density of the redundant fluid near the center will not be much less than the mean density, or 8 will not be much less than i ; moreover, the less the distance of the plates, the nearer will 8 approach to i. Condensation by two parallel disks 59 77] COR. II. Let now the body H consist of a circular plate, of the same size as AB, placed so, that the canal CG shall pass through its center, and be perpendicular to its plane; by the supposition, the force with which H repels the fluid in the canal CG, is the same with which a quantity of fluid, equal to B, spread uniformly over AB, would repel it in the contrary direction : therefore, if the fluid in the plate H was spread uniformly, the quantity of redundant fluid therein would be B, and if it was all collected 2B in the circumference, would be - — ; and therefore the real quantity will 3-» zB be greater than B, and less than 3-« 78] COR. III. Therefore, if we suppose 8 to be equal to i, the quantity of redundant fluid in AB will exceed that in the plate H, in a greater ratio / _ than that of „ J — to i. and less than that of AC i -to i; j-* j-i \j -i-j din_i i^xoa 1110.11 una,L \ji /^jr and from the preceding remarks it appears that the real quantity of re- dundant fluid in AB can hardly be much greater than it would if 8 was equal to i. 79] COR. IV. Hence, if the electric attraction and repulsion is in- versely as the square of the distance, the redundant fluid in AB, supposing 8 to be equal to i, will exceed that in the plate H, in a greater ratio than that of A C to ^CE, and less than that of AC to 2CE. 80] COR. V. Let now the body H consist of a globe, whose diameter equals AB; the globe being situated in such a manner, that the canal CG, if continued, would pass through its center; and let the electric attraction and repulsion be inversely as the square of the distance, the quantity of redundant fluid in the globe will be zB: for the fluid will be spread uni- formly over the surface of the globe, and its repulsion on the canal will be the same as if it was all collected in the center of the sphere, and will therefore be the same with which an equal quantity, disposed in the circumference of AB, would repel it in the contrary direction, or with which half that quantity, or B, would repel it, if spread uniformly over the plate. [See Art. 140.] 81] COR. VI. Therefore, if 8 was equal to i, the redundant fluid in AB would exceed that in the globe, in the ratio of A C to ^CE; and there- fore, it will in reality exceed that in the globe, in a rather greater ratio than that of AC to ^CE; but if the plates are very near together, it will approach very near thereto, and the nearer the plates are, the nearer it will approach thereto. 82] COR. VII. Whether the electric repulsion is inversely as the square of the distance or not, if the body H is as much undercharged, as it was 6o First published Paper on Electricity Fig. 15- before overcharged, AB will be as much undercharged as it was before overcharged, and DF as much overcharged as it was before undercharged. 83] COR. VIII. If the size and distance of the plates be altered, the quantity of redundant or deficient fluid in the body H remaining the same, it appears, by comparing this proposition with the 2Oth and 2ist propositions, that the quantity of redundant and deficient fluid in AB AC\3~n AC2 will be as AC"-1 x "=J , or as ECs-n - supposing the value of 8 to remain the same*. 84] PROP. XXIII. Let AE (Fig. 15) be a cylindric canal, infinitely continued beyond E ; and let A F be a bent canal, meeting the other at A, and infinitely continued beyond F: let the section of this canal, in all parts of it, be equal to I that of the cylindric canal, and let both canals be filled with uniform fluid of the same density: the force with which a particle of fluid P, placed anywhere at pleasure, repels the whole quantity of fluid in AF, in the direction of the canal, is the same with which it repels the fluid in the canal AE, in the direction AE. On the center P, draw two circular arches BD and bd, infinitely near to each other, cutting AE in B and £, and AF in D and 8, and draw the radii Pb and Pd. As PB = PD, the force with which P repels a particle at B, in the direction Bp, is to that with which it repels an equal particle at D, in the direction Z)8, as ^ to ^ , or as ^ to ^~ ; and therefore, the force with which it repels the whole fluid in Bf$, in the direction Eft, is the same with which it repels the whole fluid in DS, in the direction D8, that is in the direction of the canal; and therefore, the force with which it repels the whole fluid in AE, in the direction AE, is the same with which it repels the whole fluid in AF, in the direction of the canal. 85] COR. If the bent canal A DF, instead of being infinitely continued, meets the cylindric canal in E, as in Fig. 16, the repulsion of P on the fluid in the bent canal ADE, in the direction of the canal, will still be equal to its repulsion on that in the cylindric canal AE, in the direction AE. 86] PROP. XXIV. If two bodies, for instance the plate AB, and the body H, of Prop. XXII, communicate with each other, by a canal filled with incompressible fluid, and are either over or undercharged, the quantity of redundant fluid in them will bear the same proportion to each other, whether the canal by which they communicate is straight or crooked, or [» Note 4, p. 368.] Theory of bent connecting canal 61 into whatever part of the bodies the canal is inserted, or in whatever manner the two bodies are situated in respect of each other; provided that their distance is infinite, or so great that the repulsion of each body on the fluid in the canal shall not be sensibly less than if it was infinite. Let the parallelograms AB and DF (Fig. 17) represent the two plates, and H and L the bodies communicating with them: let now H be re- moved to h; and let it communicate with AB by the bent canal gc; the quantity of fluid in the plates and bodies remaining the same as before ; and let us, for the sake of ease in the demonstration, suppose the canal gc to be everywhere of the same thickness as the canal GC; though the proposition will evidently hold good equally, whether it is or not : the fluid will still be in equilibrio. For let us first suppose the canal gc to be Fig. 17 continued through the substance of the plate AB, to C. along the line crC; the part crC being of the same thickness as the rest of the canal, and the fluid in it of the same density: by the preceding proposition, the repulsion' or attraction of each particle of fluid or matter in the plates AB and DF, on the fluid in the whole canal Crcg, in the direction of that canal, is equal to its repulsion or attraction on the fluid in the canal CG, in the direction CG; and therefore the whole repulsion or attraction of the two plates on the canal Crcg, is equal to their repulsion or attraction on CG: but as the fluid in the plate A B is in equilibrio, each particle of fluid in the part Crc of the canal is impelled by the plates with as much force in one direction as the other; and consequently the plates impel the fluid in the canal eg with as much force as they do that in the whole canal Crcg, that is, with the same force that they impel the fluid in CG. In like 6 2 First published Paper on Electricity manner the body h impels the fluid in eg with the same force that H does the fluid in CG ; and consequently h impels the fluid in eg one way in the direction of the canal, with the same force that the two plates impel it the contrary way; and therefore the fluid in eg has no tendency to flow from one body to the other. 87] COR. By the same method of reasoning, with the help of the corollary to the 23rd proposition, it appears, that if AB and H each, communicate with a third body by canals of incompressible fluid, and a communication is made between AB and H by another canal of incom- pressible fluid, the fluid will have no tendency to flow from one to the other through this canal; supposing that the fluid was in equilibrio before this communication was made. In like manner if AB and H communicate with each other, or each communicate with a third body, by canals of real fluid, instead of the imaginary canals of incompressible fluid used in these propositions, and a communication is also made between them by a canal of incompressible fluid, the fluid can have no tendency to flow from one to the other. The truth of the latter part of this corollary will appear by supposing an imaginary canal of incompressible fluid to be continued through the whole length of the real one. 88] PROP. XXV. Let now a communication be made between the two plates AB and DF, by the canal NRS of incompressible fluid, of any length; and let the body H and the plate AB be overcharged. It is plain that the fluid will flow through that canal from AB to DF. Now the whole force with which the fluid in the canal is impelled along it by the joint action of the two plates is the same with which the whole quantity of fluid in the canal CG or eg is impelled by them ; supposing the canal NRS to be everywhere of the same breadth and thickness as CG or eg. For suppose that the canal NRS, instead of communicating with the plate DF, is bent back just before it touches it, and continued infinitely along the line Ss; the force with which the two plates impel the fluid in Ss, is the same with which they impel that in EL, supposing Ss to be of the same breadth and thickness as EL ; and is therefore nothing; there- fore the force with which they impel the fluid in NRS, is the same with which they impel that in A^RSs ; which is the same with which they impel that in CG. 89] PROP. XXVI. Let now xyz [Fig. 17] be a body of an infinite size, containing just fluid enough to saturate it; and let a communication be made between h and xyz, by the canal hy of incompressible fluid, of the same breadth and thickness as gc or GC; the fluid will flow through it from h to xyz; and the force with which the fluid in that canal is impelled along it, is equal to that with which the fluid in NRS is impelled by the two plates. If the canal hy is of so great a length, that the repulsion of h thereon Canals of fluid compared with conducting wires 63 is the same as if it was continued infinitely, then the thing is evident: but if it is not, let the canal hy, instead of communicating with xyz, so that the fluid can flow out of the canal into xyz, be continued infinitely through its substance, along the line yv : now it must be observed that a small part of the body xyz, namely, that which is turned towards h, will by the action of h upon it, be rendered undercharged; but all the rest of the body will be saturated; for the fluid driven out of the undercharged part will not make the remainder, which is supposed to be of an infinite size, sensibly overcharged: now the force with which the fluid in the infinite canal hyv is impelled by the body h and the undercharged part of xyz, is the same with which the fluid in gc is impelled by them ; but as the fluid in all parts of xyz is in equilibrio, a particle in any part of yv cannot be impelled in any direction; and therefore the fluid in hy is im- pelled with as much force as that in hyv; and therefore the fluid in hy is impelled with as much force as that in gc ; and is therefore impelled with as much force as the fluid in NRS is impelled by the two plates. 90] It perhaps may be asked, whether this method of demonstration would not equally tend to prove that the fluid in hy was impelled with the same force as that in NRS, though xyz did not contain just fluid enough to saturate it. I answer not; for this demonstration depends on the canal yv being continued, within the body xyz, to an infinite distance beyond any over or undercharged part ; which could not be if xyz contained either more or less fluid than that*. 91] PROP. XXVII. Let two bodies B and b (Fig. 13) be joined by a cylindric or prismatic canal Aa, filled with real fluid; and not by any imaginary canal of incompressible fluid as in the 20th proposition; and let the fluid therein be in equilibrio: the force with which the whole or any given part of the fluid in the canal is impelled in the direction of its axis by the united repulsions and attractions of the redundant fluid or matter in the two bodies and the canal, must be nothing; or the force with which it is impelled one way in the direction of the axis of the canal, must be equal to that with which it is impelled the other way. For as the canal is supposed cylindric or prismatic, no particle of fluid therein can be prevented from moving in the direction of the axis of it, by the sides of the canal ; and therefore the force with which each particle is impelled either way in the direction of the axis, by the united attractions and repulsions of the two bodies and the canal, must be nothing, otherwise it could not be at rest; and therefore the force with which the whole, or any given part of the fluid in the canal, is impelled in the direction of the axis, must be nothing. 92] COR. I. If the fluid in the canal is disposed in such manner, that the repulsion or attraction of the redundant fluid or matter in it, on the [* Note 5, p. 369.] 64 First published Paper on Electricity whole or any given part of the fluid in the canal, has no tendency to impel it cither way in the direction of the axis; then the force with which that whole or given part is impelled by the two bodies must be nothing; or the force with which it is impelled one way in the direction of the axis, by the body B, must be equal to that with which it is impelled in the contrary direction by the other body; but not if the fluid in the canal is disposed in a different manner. 93] COR. II. If the bodies, and consequently the canal, is overcharged; then, in whatever manner the fluid in the canal is disposed, the force with which the whole quantity of redundant fluid in the canal is repelled by the body B in the direction Aa, must be equal to that with which it is repelled by b in the contrary direction. For the force with which the redundant fluid is impelled in the direction A a by its own repulsion, is nothing; for the repulsions of the particles of any body on each other have no tendency to make the whole body move in any direction. 94] REMARKS. When I first thought of the aoth and 22nd proposi- tions, I imagined that when two bodies were connected by a cylindric canal of real fluid, the repulsion of one body on the whole quantity of fluid in the canal, in one direction, would be equal to that of the other body on it in the contrary direction, in whatever manner the fluid was disposed in the canal; and that therefore those propositions would have held good very nearly, though the bodies were joined by cylindric canals of real fluid ; provided the bodies were so little over or undercharged, that the quantity of redundant or deficient fluid in the canal should be very small in respect of the quantity required to saturate it ; and consequently that the fluid therein should be very nearly of the same density in all parts. But from the foregoing proposition it appears that I was mistaken, and that the repulsion of one body on the fluid in the canal is not equal to that of the other body on it, unless the fluid in the canal is disposed in a particular manner: besides that, when two bodies are both joined by a real canal, the attraction or repulsion of the redundant matter or fluid in the canal has some tendency to alter the disposition of the fluid in the two bodies; and in the 22nd proposition, the canal CG exerts also some attraction or repulsion on the canal EM: on all which accounts the demonstration of those propositions is defective, when the bodies are joined by real canals. I have good reason however to think, that those proposi- tions actually hold good very nearly when the bodies are joined by real canals ; and that, whether the canals are straight or crooked, or in whatever direction the bodies are situated in respect of each other : though I am by no means able to prove that they do : I therefore chose still to retain those propositions, but to demonstrate them on this ideal supposition, in which they are certainly true, in hopes that some more skilful mathematician may be able to shew whether they really hold good or not. [See Note 3.] Molecular constitution of air 65 95] What principally makes me think that this is the case, is that as far as I can judge from some experiments I have made*, the quantity of fluid in different bodies agrees very well with those propositions, on a supposition that the electric repulsion is inversely as the square of the distance. It should also seem from those experiments, that the quantity of redundant or deficient fluid in two bodies bore very nearly the same proportion to each other, whatever is the shape of the canal by which they are joined, or in whatever direction they are situated in respect of each other. 96] Though the above propositions should be found not to hold good when the bodies are joined by real canals, still it is evident, that in the 22nd proposition, if the plates AB and DF are very near together, the quantity of redundant fluid in the plate AB will be many times greater than that in the body H, supposing H to consist of a circular plate of the same size as AB, and DF will be near as much undercharged as AB is overcharged. 97] Sir Isaac Newton supposes that air consists of particles which repel each other with a force inversely as the distance: but it appears plainly from the foregoing pages, that if the repulsion of the particles was in this ratio, and extended indefinitely to all distances, they would compose a fluid extremely different from common air. If the repulsion of the particles was inversely as the distance, but extended only to a given very small distance from their centers, they would compose a fluid of the same kind as air, in respect of elasticity, except that its density would not be in pro- portion to its compression : if the distance to which the repulsion extends, though very small, is yet many times greater than the distance of the particles from each other, it might be shewn, that the density of the fluid would be nearly as the square root of the compression. If the repulsion of the particles extended indefinitely, and was inversely as some higher power of the distance than the cube, the density of the fluid would be as some power of the compression less than f . The only law of repulsion, I can think of, which will agree with experiment, is one which seems not very likely; namely, that the particles repel each other with a force in- versely as the distance ; but that, whether the density of the fluid is great or small, the repulsion extends only to the nearest particles: or, what comes to the same thing, that the distance to which the repulsion extends, is very small, and also is not fixed, but varies in proportion to the distance of the particles f. [* Exp. Ill, Art. 265.] [f Note 6, p. 370.] c.p, i. 66 First published Paper on Electricity An attempt to explain some of the Principal Phenomena of Electricity, by means of an Elastic Fluid — Part II Containing a Comparison of the Foregoing Theory with Experiment. 98] § I. It appears from experiment, that some bodies suffer the electric fluid to pass with great readiness between their pores; while others will not suffer it to do so without great difficulty ; and some hardly suffer it to do so at all. The first sort of bodies are called conductors, the others non-conductors. What this difference in bodies is owing to I do not pretend to explain. It is evident that the electric fluid in conductors may be considered as moveable, or answers to the definition given of that term in page 6. As to the fluid contained in non-conducting substances, though it does not absolutely answer to the definition of immoveable, as it is not abso- lutely confined from moving, but only does so with great difficulty; yet it may in most cases be looked upon as such without sensible error. 99] Air does in some measure permit the electric fluid to pass through it; though, if it is dry, it lets it pass but very slowly, and not without difficulty; it is therefore to be called a non-conductor. It appears that conductors would readily suffer the fluid to run in and out of them, were it not for the air which surrounds them: for if the end of a conductor is inserted into a vacuum, the fluid runs in and out of it with perfect readiness ; but when it is surrounded on all sides by the air, as no fluid can run out of it without running into the air, the fluid will not do so without difficulty. 100] If any body is surrounded on all sides by the air, or other non- conducting substances, it is said to be insulated: if on the other hand it anywhere communicates with any conducting body, it is said to be not insulated. When I say that a body communicates with the ground, or any other body, I would be understood to mean that it does so by some conducting substance. 101] Though the terms positively and negatively electrified are much used, yet the precise sense in which they are to be understood seems not well ascertained; namely, whether they are to be understood in the same sense in which I have used the words over or undercharged, or whether, when any number of bodies, insulated and communicating with each other by conducting substances, are electrified by means of excited glass, they are all to be called positively electrified (supposing, according to the usual Positive and negative electrification 67 opinion, that excited glass contains more than its natural quantity of electricity) ; even though some of them, by the approach of a stronger electrified body, are made undercharged. I shall use the words in the latter sense; but as it will be proper to ascertain the sense in which I shall use them more accurately, I shall give the following definition. 102] In order to judge whether any body, as A, is positively or nega- tively electrified: suppose another body B, of a given shape and size, to be placed at an infinite distance from it, and from any other over or under- charged body; and let B contain the same quantity of electric fluid as if it communicated with A by a canal of incompressible fluid : then, if B is overcharged, I call A positively electrified; and if it is undercharged, I call A negatively electrified; and the greater the degree in which B is over or undercharged, the greater is the degree in which A is positively or negatively electrified. 103] It appears from the corollary to the 24th proposition, that if several bodies are insulated, and connected together by conducting sub- stances, and one of these bodies is positively or negatively electrified, all the other bodies must be electrified in the same degree: for supposing a given body B to be placed at an infinite distance from any over or under- charged body, and to contain the same quantity of fluid as if it com- municated with one of those bodies by a canal of incompressible fluid, all the rest of those bodies must by that corollary contain the same quantity of fluid as if they communicated with B by canals of incompressible fluid : but yet it is possible that some of those bodies may be overcharged, and others undercharged: for suppose the bodies to be positively electrified, and let an overcharged body D be brought near one of them, that body will become undercharged, provided D is sufficiently overcharged; and yet by the definition it will still be positively electrified in the same degree as before. Moreover, if several bodies are insulated and connected together by conducting substances, and one of these bodies is electrified by excited glass, there can be no doubt, I think, but what they will all be positively electrified ; for if there is no other over or undercharged body placed near any of these bodies, the thing is evident ; and though some of these bodies may, by the approach of a sufficiently overcharged body, be rendered undercharged ; yet I do not see how it is possible to prevent a body placed at an infinite distance, and communicating with them by a canal of in- compressible fluid, from being overcharged. In like manner if one of these bodies is electrified by excited sealing wax, they will all be negatively electrified*. 104] It is impossible for any body communicating with the ground to be either positively or negatively electrified: for the earth, taking the [* Note 7, p. 372.] 5—2 68 First published Paper on Electricity whole together, contains just fluid enough to saturate it, and consists in general of conducting substances; and consequently though it is possible for small parts of the surface of the earth to be rendered over or under- charged, by the approach of electrified clouds or other causes; yet the bulk of the earth, and especially the interior parts, must be saturated with electricity. Therefore assume any part of the earth which is itself saturated, and is at a great distance from any over or undercharged part ; any body communicating with the ground, contains as much electricity as if it communicated with this part by a canal of incompressible fluid, and therefore is not at all electrified. 105] If any body A , insulated and saturated with electricity, is placed at a great distance from any over or undercharged body, it is plain that it cannot be electrified; but if an overcharged body is brought near it, it will be positively electrified; for supposing A to communicate with any body B, at an infinite distance, by a canal of incompressible fluid, it is plain that unless B is overcharged, the fluid in the canal could not be in equilibrio, but would run from A to B. For the same reason a body insulated and saturated with fluid, will be negatively electrified if placed near an undercharged body. 106] § 2. The phenomena of the attraction and repulsion of electrified bodies seem to agree exactly with the theory; as will appear by con- sidering the following cases. 107] CASE I. Let two bodies, A and B, both conductors of electricity, and both placed at a great distance from any other electrified bodies, be brought near each other. Let A be insulated, and contain just fluid enough to saturate it; and let B be positively electrified. They will attract each other ; for as B is positively electrified, and at a great distance from any overcharged body, it will be overcharged; therefore, on approaching A and B to each other, some fluid will be driven from that part of A which is nearest to B to the further part: but when the fluid in A was spread uniformly, the repulsion of B on the fluid in A was equal to its attraction on the matter therein; therefore, when some fluid is removed from those parts where the repulsion of B is strongest to those where it is weaker, B will repel the fluid in A with less force than it attracts the matter; and consequently the bodies will attract each other. 108] CASE II. If we now suppose that the fluid is at liberty to escape from out of A, if it has any disposition to do so, the quantity of fluid in it before the approach of B being still sufficient to saturate it; that is, if A is not insulated and not electrified, B being still positively electrified, they will attract with more force than before: for in this case, not only some fluid will be driven from that part of A which is nearest to B to the opposite part, but also some fluid will be driven out of A. Various cases of electric distribution 69 It must be observed, that if the repulsion of B on a particle at E, (Fig. 19) the farthest part of A, is very small in respect of its repulsion on an equal particle placed at D, the nearest part of A, the two bodies will attract with very nearly the same force, whether A is insulated or not ; but if the repulsion of B, on a particle at E, is very near as great as on one at D, Fig Ig they will attract with very little force if A is insulated. For instance, let a small overcharged ball be brought near one end of a long conductor not electrified; they will attract with very near the same force, whether the conductor be insulated or not; but if the conductor be overcharged, and brought near a small unelectrified ball, they will not attract with near so much force, if the ball is insulated, as if it is not. 109] CASE III. If we now suppose that A is negatively electrified, and not insulated, it is plain that they will attract with more force than in the last case ; as A will be still more undercharged in this case, than in the last. no] N.B. In these three cases, we have not as yet taken notice of the effect which the body A will have in altering the quantity and dis- position of the fluid in B ; but in reality this will make the bodies attract each other with more force than they would otherwise do ; for in each of these cases the body A attracts the fluid in B; which will cause some fluid to flow from the farther parts of B to the nearer, and will also cause some fluid to flow into it, if it is not insulated, and will consequently cause B to act upon A with more force than it would otherwise do. in] CASES IV, V, VI. Let us now suppose that B is negatively electrified ; and let A be insulated, and contain just fluid enough to saturate it ; they will attract each other; for B will be undercharged ; it will therefore attract the fluid in A , and will cause some fluid to flow from the farthest part of A, where it is attracted with less force, to the nearer part, where it is attracted with more force ; so that B will attract the fluid in A with more force than it repels the matter. If A is now supposed to be not insulated and not electrified, B being still negatively electrified, it is plain that they will attract with more force than in the last case: and if A is positively electrified, they will attract with still more force. In these three last cases also, the effect which A has in altering the quantity and disposition of the fluid in B, tends to increase the force with which the two bodies attract. 112] CASE VII. It is plain that a non-conducting body saturated with fluid, is not at all attracted or repelled by an over or undercharged body, jo First published Paper on Electricity until, by the action of the electrified body on it, it has either acquired some additional fluid from the air, or had some driven out of it, or till some fluid is driven from one part of the body to the other. 113] CASE VIII. Let us now suppose that the two bodies A and B are both positively electrified in the same degree. It is plain, that were it not for the action of one body on the other, they would both be over- charged, and would repel each other. But it may perhaps be said, that one of them as A may, by the action of the other on it, be either rendered undercharged on the whole, or at least may be rendered undercharged in that part nearest to B ; and that the attraction of this undercharged part on a particle of the fluid in B, may be greater than the repulsion of the more distant overcharged part; so that on the whole the body A may attract a particle of fluid in B. If so, it must be affirmed that the body B repels the fluid in A ; for otherwise, that part of A which is nearest to B could not be rendered undercharged. Therefore, to obviate this objection, let the bodies by joined by the straight canal DC of incompressible fluid (Fig. 19) . The body B will repel the fluid in all parts of this canal ; for as A is supposed to attract the fluid in B, B will not only be more overcharged than it would otherwise be, but it will also be more overcharged in that part nearest to A than in the opposite part. Moreover, as the near under- charged part of A is supposed to attract a particle of fluid in B with more force than the more distant overcharged part repels it; it must, a fortiori, attract a particle in the canal with more force than the other repels it; therefore the body A must attract the fluid in the canal ; and consequently some fluid must flow from B to A , which is impossible ; for as A and B are both electrified in the same degree, they contain the same quantity of fluid as if they both communicated with a third body at an infinite distance, by canals of incompressible fluid ; and therefore, by the corollary to Prop. 24, if a communication is made between them by a canal of incompressible fluid, the fluid would have no disposition to flow from one to the other. 114] CASE IX. But if one of the bodies as A is positively electrified in a less degree than B, then it is possible for the bodies to attract each other ; for in this case the force with which B repels the fluid in A may be so great, as to make the body A either intirely undercharged, or at least to make the nearest part of it so much undercharged, that A shall on the whole attract a particle of fluid in B. It may be worth remarking with regard to this case, that when two bodies, both electrified positively but unequally, attract each other, you may by removing them to a greater distance from each other, cause them to repel ; for as the stronger electrified body repels the fluid in the weaker with less force when removed to a greater distance, it will not be able to drive so much fluid out of it, or from the nearer to the further part, as when placed at a less distance. Exchange of electricity with the air 71 115] CASES X and XI. By the same reasoning it appears, that if the two bodies are both negatively electrified in the same degree, they must repel each other: but if they are both negatively electrified in different degrees, it is possible for them to attract each other. . All these cases are exactly conformable to experiment. 116] CASE XII. Let two cork balls be suspended by conducting threads from the same positively electrified body, in such manner that if they did not repel, they would hang close together: they will both be equally electrified, and will repel each other : let now an overcharged body, more strongly electrified than them, be brought under them; they will become less overcharged, and will separate less than before: on bringing the body still nearer, they will become not at all overcharged, and will not separate at all : and on bringing the body still nearer, they will become undercharged, and will separate again. 117] CASE XIII. Let all the air of a room be overcharged, and let two cork balls be suspended close to each other by conducting threads communicating with the wall. By Prop. 15, it is highly probable that the balls will be undercharged; and therefore they should repel each other. These two last cases are experiments of Mr Canton's, and are described in Philosophical Transactions 1753, p. 350, where are other experiments of the same kind, all readily explicable by the foregoing theory. I have now considered all the principal or fundamental cases of electric attractions and repulsions which I can think of ; all of which appear to agree perfectly with the theory*. 118] § 3. On the cases in which bodies receive electricity from or part with it to the air. LEMMA I. Let the body A (Fig. 6) either stand near some over or undercharged body, or at a distance from any. It seems highly probable, that if any part of its surface, as MN, is overcharged, the fluid will endeavour to run out through that part, provided the air adjacent thereto is not over- charged. For let G be any point in that surface, and P a point within the body, extremely near to it ; it is plain that a particle of fluid at P must be repelled with as much force in one direction as another (otherwise it could not be at rest) unless all the fluid between P and G is pressed close together, in which case it may be repelled with more force towards G than it is in the contrary direction : now a particle at G is repelled in the direction PG, i.e. from P to G, by all the redundant fluid between P and G ; and a particle at P is repelled by the [* Note 8, p. 373.] 72 First published Paper on Electricity same fluid in the contrary direction ; so that as the particle at P is repelled with not less force in the direction PG than in the contrary, I do not see how a particle at G can help being repelled with more force in that direction than the contrary, unless the air on the outside of the surface MN was more overcharged than the space between P and G. In like manner, if any part of the surface is undercharged, the fluid will have a tendency to run in at that part from the air. The truth of this is somewhat confirmed by the third problem ; as in all the cases of that problem, the fluid was shewn to have a tendency to run out of the spaces AD and EH, at any surface which was overcharged, and to run in at any which was undercharged. 119] COR. I. If any body at a distance from other over or under- charged bodies be positively electrified, the fluid will gradually run out of it from all parts of its surface into the adjoining air; as it is plain that all parts of the surface of that body will be overcharged : and if the body is negatively electrified, the fluid will gradually run into it at all parts of its surface from the adjoining air. 120] COR. II. Let the body A (Fig. 6) insulated and containing just fluid enough to saturate it, be brought near the overcharged body B; that part of the surface of A which is turned towards B will by Prop. II be rendered undercharged, and will therefore imbibe electricity from the air ; and at the opposite surface RS, the fluid will run out of the body into the air. 121] COR. III. If we now suppose that A is not insulated, but com- municates with the ground, and consequently that it contained just fluid enough to saturate it before the approach of B, it is plain that the surface MN will be more undercharged than before; and therefore the fluid will run in there with more force than before; but it can hardly have any disposition to run out at the opposite surface RS ; for if the canal by which A communicates with the ground is placed opposite to B, as in figure 5, then the fluid will run out through that canal till it has no longer any tendency to run out at RS; and by the remarks at the end of Prop. 27, it seems probable, that the fluid in A will be nearly in the same quantity, and disposed nearly in the same manner, into whatever part of A the canal is inserted by which it communicates with the ground. 122] COR. IV. If B is undercharged the case will be reversed; that is, it will run out where it before run in, and will run in where it before run out. As far as I can judge, these corollaries seem conformable to experi- ment : thus far is certain, that bodies at a distance from other electrified bodies receive electricity from the air, if negatively electrified, and part with some to it if positively electrified : and a body not electrified and not Discharge by points 73 insulated receives electricity from the air if brought near an overcharged body, and loses some when brought near an undercharged body: and a body insulated and containing its natural quantity of fluid, in some cases, receives, and in others loses electricity, when brought near an over or undercharged body. 123] § 4. The well-known effects of points in causing a quick dis- charge of electricity seem to agree very well with this theory. It appears from the 20th proposition, that if two similar bodies of different sizes are placed at a very great distance from each other, and connected by a slender canal, and overcharged, the force with which a particle of fluid placed close to corresponding parts of their surface is repelled from them, is inversely as the corresponding diameters of the bodies. If the distance of the two bodies is small, there is not so much difference in the force with which the particle is repelled by the two bodies ; but still, if the diameters of the two bodies are very different, the particle will be repelled with much more force from the smaller body than from the larger. It is true indeed that a particle placed at a certain distance from the smaller body, will be repelled with less force than if it be placed at the same distance from the greater body; but this distance is, I believe, in most cases pretty considerable; if the bodies are spherical, and the repulsion inversely as the square of the distance, a particle placed at any distance from the surface of the smaller body less than a mean proportional between the radii of the two bodies, will be repelled from it with more force than if it be placed at the same distance from the larger body. I think therefore that we may be well assured that if two similar bodies are connected together by a slender canal, and are overcharged, the fluid must escape faster from the smaller body than from an equal surface of the larger; but as the surface of the larger body is greatest, I do not know which body ought to lose most electricity in the same time; and indeed it seems impossible to determine positively from this theory which should, as it depends in great measure on the manner in which the air opposes the entrance of the electric fluid into it. Perhaps in some degrees of electrification the smaller body may lose most, and in others the larger. 124] Let now ACB (Fig. 18) be a conical point standing on any body DAB, C being the vertex of the cone; and let DAB be overcharged: I imagine that a particle of fluid placed close to the surface of the cone anywhere between b and C, must be repelled with at least as much, if not more, force than it would, if the part AabB of the cone was taken away, and the part aCb Fig. 18. connected to DAB by a slender canal; and conse- quently, from what has been said before, it seems reasonable to suppose that the waste of electricity from the end of the cone must be very great 74 First published Paper on Electricity in proportion to its surface ; though it does not appear from this reasoning whether the waste of electricity from the whole cone should be greater or less than from a cylinder of the same base and altitude*. All which has been here said relating to the flowing out of electricity from overcharged bodies, holds equally true with regard to the flowing in of electricity into undercharged bodies. 125] But a circumstance which I believe contributes as much as any thing to the quick discharge of electricity from points, is the swift current of air caused by them, and taken notice of by Mr Wilson and Dr Priestly (vide Priestly, pp. 117 and 591) ; and which is produced in this manner. If a globular body ABD is overcharged, the air close to it, all round its surface, is rendered overcharged by the electric fluid which flows into it from the body ; it will therefore be repelled by the body ; but as the air all round the body is repelled with the same force, it is in equilibrio, and has no tendency to fly off from it. If now the conical point ACB be made to stand out from the globe, as the fluid will escape much faster in pro- portion to the surface from the end of the point than from the rest of the body, the air close to it will be much more overcharged than that close to the rest of the body ; it will therefore be repelled with much more force ; and consequently a current of air will flow along the sides of the cone, from B towards C; by which means there is a continual supply of fresh air, not much overcharged, brought in contact with the point; whereas other- wise the air adjoining to it would be so much overcharged, that the electricity would have but little disposition to flow from the point into it. The same current of air is produced in a less degree, without the help of the point, if the body, instead of being globular, is oblong or flat, or has knobs on it, or is otherwise formed in such manner as to make the electricity escape faster from some parts of it than the rest. In like manner, if the body ABD be undercharged, the air adjoining to it will also be undercharged, and will therefore be repelled by it; but as the air close to the end of the point will be more undercharged than that close to the rest of the body, it will be repelled with much more force ; which will cause exactly the same current of air, flowing the same way, as if the body was overcharged ; and consequently the velocity with which the electric fluid flows into the body, will be very much increased. I believe indeed that it may be laid down as a constant rule, that the faster the electric fluid escapes from any body when overcharged, the faster will it run into that body when undercharged. Points are not the only bodies which cause a quick discharge of electricity ; in particular, it. escapes very fast from the ends of long slender cylinders; and a swift current of air is caused to flow from the middle of the cylinder towards the end: this will easily appear by considering that [* Note 9, p. 374.] Electric 'wind 75 the redundant fluid is collected in much greater quantity near the ends of the cylinders than near the middle. The same thing may be said, but I believe in a less degree, of the edges of thin plates. What has been just said concerning the current of air, serves to explain the reason of the revolving motion of Dr Hamilton's and Mr Kinnersley's bent pointed wires, vide Philosophical Trans. Vol. LI., p. 905, and Vol. LIII., p. 86; also Priestly, p. 429: for the same repulsion which impels the air from the thick part of the wire towards the point, tends to impel the wire in the contrary direction. 126] It is well known, that if a body B is positively electrified, and another body A, communicating with the ground, be then brought near it, the electric fluid will escape faster from B, at that part of it which is turned towards A, than before. This is plainly conformable to theory; for as A is thereby rendered undercharged, B will in its turn be made more overcharged, in that part of it which is turned towards A, than it was before. But it is also well known that the fluid will escape faster from B, if A be pointed, than if it be blunt; though B will be less over- charged in this case than in the other ; for the broader the surface of A , which is turned towards B, the more effect will it have in increasing the overcharge of B. The cause of this phenomenon is as follows : If A is pointed, and the pointed end turned towards B, the air close to the point will be very much undercharged, and therefore will be strongly repelled by A, and attracted by B, which will cause a swift current of air to flow from it towards B ; by which means a constant supply of under- charged air will be brought in contact with B, which will accelerate the discharge of electricity from it in a very great degree : and moreover, the more pointed A is, the swifter will be this current. If, on the other hand, that end of A which is turned towards B is so blunt, that the electricity is not disposed to run into A faster than it is to run out of B, the air adjoining to B may be as much overcharged as that adjoining to A is undercharged; and therefore may by the joint repulsion of B and attrac- tion of A , be impelled from B to A , with as much or more force than the air adjoining to A is impelled in the contrary direction ; so that what little current of air there is may flow in the contrary direction. It is easy applying" what has been here said to the case in which B is negatively electrified. I27] § 5- In the paper of Mr Canton's, quoted in the second section, and in a paper of Dr Franklin's Philosophical Transactions 1755, p. 300, and Franklin's letters, p. 155, are some remarkable experiments, shewing that when an overcharged body is brought near another body, some fluid is driven to the further end of this body, and also some driven out of it, if it is not insulated. The experiments are all strictly conformable to the j6 First published Paper on Electricity nth, I2th, and I3th propositions: but it is needless to point out the agreement, as the explanation given by the authors does it sufficiently. 128] § 6. On the Leyden vial. The shock produced by the Leyden vial seems owing only to the great quantity of redundant fluid collected on its positive side, and the great deficiency on its negative side ; so that if a conductor was prepared of so great a size, as to be able to receive as much additional fluid by the same degree of electrification as the positive side of a Leyden vial, and was positively electrified in the same degree as the vial, I do not doubt but what as great a shock would be produced by making a communication between this conductor and the ground, as between the two surfaces of the Leyden vial, supposing both communications to be made by canals of the same length and same kind. It appears plainly from the experiments which have been made on this subject, that the electric fluid is not able to pass through the glass; but yet it seems as if it was able to penetrate without much difficulty to a certain depth, perhaps I might say an imperceptible depth, within the glass ; as Dr Franklin's analysis of the Leyden vial shews that its electricity is contained chiefly in the glass itself, and that the coating is not greatly over or undercharged. It is well known that glass is not the only substance which can be charged in the manner of the Leyden vial ; but that the same effect may be produced by any other body, which will not suffer the electricity to pass through it. 129] *Hence the phenomena of the vial seem easily explicable by means of the 22nd proposition. For let ACGM , Fig. 20, represent a flat plate of glass or any other substance which will not suffer the electric fluid to pass through it, seen edgeways ; and let BbdD, and EefF, or Bd and Ef, as I shall call them for shortness, be two plates of conducting matter of the same size, placed in contact with the glass opposite to each other; and let Bd be positively electrified; and let Ef communicate with the ground; and let the fluid be supposed either able to enter a little way into the glass, but not to pass through it, or unable to enter it at all; and if it is able to enter a little way into it, let b/38d, or bS, as I shall call it, represent that part of the glass into which the fluid can enter from the plate Bd, and e, that * The following explication is strictly applicable only to that sort of Leyden vial, which consists of a flat plate of glass or other matter. It is evident, however, that the result must be nearly of the same kind, though the glass is made into the shape of a bottle as usual, or into any other form; but I propose to consider those sort of Leyden vials more particularly in a future paper. The Ley den vial 77 which the fluid from Ef can enter. By the above-mentioned proposition, if be, the thickness of the glass, is very small in respect of bd, the diameter of the plates, the quantity of redundant fluid forced into the space Bd, or B8, (that is, into the plate Bd, if the fluid is unable to penetrate at all into the glass, or into the plate Bd, and the space b8 together, if the fluid is able to penetrate into the glass,) will be many times greater than what would be forced into it by the same degree of electrification if it had been placed by itself; and the quantity of fluid driven out of E will be nearly equal to the redundant fluid in B8. If a communication be now made between B8 and E, by the canal NRS, the redundant fluid will run from 58 to E$; and if in its way it passes through the body of any animal, it will by the rapidity of its motion produce in it that sensation called a shock. 130] It appears from the 26th proposition, that if a body of any size was electrified in the same degree as the plate Bd, and a communication was made between that body and the ground, by a canal of the same length, breadth and thickness as NRS; that then the fluid in that canal would be impelled with the same force as that in NRS, supposing the fluid in both canals to be incompressible ; and consequently, as the quantity of fluid to be moved, and the resistance to its motion is the same in both canals, the fluid should move with the same rapidity in both: and I see no reason to think that the case will be different, if the communication is made by canals of real fluid. Therefore what was said in the beginning of this section, namely, that as great a shock would be produced by making a communication between the conductor and the ground, as between the two sides of the Leyden vial, by canals of the same length and same kind, seems a necessary con- sequence of this theory ; as the quantity of fluid which passes through the canal is, by the supposition, the same in both; and there is the greatest reason to think, that the rapidity with which it passes will be nearly if not quite the same in both. I hope soon to be able to say whether this agrees with experiment as well as theory. 131] It may be worth observing, that the longer the canal NRS is, by which the communication is made, the less will be the rapidity with which the fluid moves along it ; for the longer the canal is, the greater is the resistance to the motion of the fluid in it; whereas the force with which the whole quantity of fluid in it is impelled, is the same whatever be the length of the canal. Accordingly, it is found in melting small wires, by directing a shock through them, that the longer the wire the greater charge it requires to melt it. 132] As the fluid in B8 is attracted with great force by the redundant matter in £$, it is plain that if the fluid is able to penetrate at all into 78 First published Paper on Electricity the glass, great part of the redundant fluid will be lodged in 68, and in like manner there will be a great deficience of fluid in e. But in order to form some estimate of the proportion of the redundant fluid which will be lodged in 68, let the communication between Ef and the ground be taken away, as well as that by which Bd is electrified ; and let so much fluid be taken from BS, as to make the redundant fluid therein equal to the deficient fluid in E(j>. If we suppose that all the redundant fluid is collected in 68, and all the deficient in e, so as to leave Bd and Ef satu- rated; then, if the electric repulsion is inversely as the square of the distance, a particle of fluid placed anywhere in the plane bd, except near the extremities b and d, will be attracted with very near as much force by the redundant matter in etf>, as it is repelled by the redundant fluid in 68 ; but if the repulsion is inversely as some higher power than the square, it will be repelled with much more force by 68, than it is attracted by e, provided the depth 68 is very small in respect of the thickness of the glass; and if the repulsion is inversely as some lower power than the square, it will be attracted with much more force by e, than it is repelled by 68. Hence it follows, that if the depth to which the fluid can penetrate is very small in respect of the thickness of the glass, but yet is such that the quantity of fluid naturally contained in 68, or e, is considerably more than the redundant fluid in B&; then, if the repulsion is inversely as the square of the distance, almost all the redundant fluid will be collected in 68, leaving the plate Bd not very much overcharged; and in like manner Ef will be not very much undercharged : if the repulsion is inversely as some higher power than the square, Bd will be very much overcharged, and Ef very much undercharged : and if the repulsion is inversely as some lower power than the square, Bd will be very much undercharged, and Ef very much overcharged. 133] Suppose, now, the plate Bd to be separated from the plate of glass, still keeping it parallel thereto, and opposite to the same part of it that it before was applied to; and let the repulsion of the particles be inversely as some higher power of the distance than the square. When the plate is in contact with the glass, the repulsion of the redundant fluid in that plate, on a particle in the plane bd, id est, the inner surface of the plate, must be equal to the excess of the repulsion of the redundant fluid in 68 on it, above the attraction of E; for the repulsion of 68 will be much more diminished by the removal, than the attraction of E: consequently, some fluid will fly from the plate to the glass, in the form of sparks: so that the plate will not be so much overcharged when removed from the glass, as it was Penetration into glass 79 when in contact with it. I should imagine, however, that it would still be considerably overcharged. If one part of the plate is separated from the glass before the rest, as must necessarily be the case, if it consists of bending materials, I should guess it would be at least as much, if not more, overcharged, when sepa- rated, as if it is separated all at once. In like manner, it should seem that the plate Ef will be considerably undercharged, when separated from the glass, but not so much so as when in contact with it. From the same kind of reasoning I conclude, that if the repulsion is inversely as some lower power of the distance than the square, the plate Bd will be considerably undercharged, and Ef considerably overcharged, when separated from the glass, but not in so great a degree as when they are in contact with it. X34] § 7- There is an experiment of Mr Wilcke and ^Epinus, related by Dr Priestly, p. 258, called by them, electrifying a plate of air: it consisted in placing two large boards of wood, covered with tin plates', parallel to each other, and at some inches asunder. If a communication was made between one of these and the ground, and the other was positively electrified, the former was undercharged; the boards strongly attracted each other; and, on making a communication between them, a shock was felt like that of the Leyden vial. I am uncertain whether in this experiment the air contained between the two boards is very much overcharged on one side, and very much undercharged on the other, as is the case with the plate of glass in the Leyden vial ; or whether the case is, that the redundant or deficient fluid is lodged only in the two boards, and that the air between them serves only to prevent the electricity from running from one board to the other : but whichever of these is the case, the experiment is equally conformable to the theory*. It must be observed, that a particle of fluid placed between the two plates is drawn towards the undercharged plate, with a force exceeding that with which it would be repelled from the overcharged plate, if it was electrified with the same force, the other plate being taken away, nearly in the ratio of twice the quantity of redundant fluid actually contained in the plate, to that which it would contain, if electrified with the same force by itself ; so that, unless the plate is very weakly electrified, or their distance is very considerable, the fluid will be apt to fly from one to the other, in the form of sparks. J35] § 8. Whenever any conducting body as A, communicating with the ground, is brought sufficiently near an overcharged body B, the electric [* See Articles 344, 345, 511, 516.] 80 First published Paper on Electricity fluid is apt to fly through the air from B to A, in the form of a spark: the way by which this is brought about seems to be this. The fluid placed anywhere between the two bodies, is repelled from B towards A , and will consequently move slowly through the air from one to the other: how it seems as if this motion increased the elasticity of the air, and made it rarer: this will enable Ihe fluid to flow in a swifter current, which will still further increase the elasticity of the air, till at last it is so much ratified, as to form very little opposition to the motion of the electric fluid, upon which it flies in an uninterrupted mass from one body to the other. In the same manner may the electric fluid pass from one body to another, in the form of a spark, if the first body communicates with the ground, and the other body is negatively electrified, or in any other case in which one body is strongly disposed to part with its electricity to the air, and the other is strongly disposed to receive it. 136] In like manner, when the electric fluid is made to pass through water, in the form of a spark, as in Signor Beccaria's* and Mr Lane's f experiments, I imagine that the water, by the rapid motion of the electric fluid through it, is turned into an elastic fluid, and so much ratified as to make very little opposition to its motion: and when stones are burst or thrown out from buildings struck by lightning, in all probability that effect is caused by the moisture in the stone, or some of the stone itself, being turned into an elastic fluid. 137] It appears plainly, from the sudden rising of the water in Mr Kinnersley's electrical air thermometer J, that when the electric fluid passes through the air, in the form of a spark, the air in its passage is either very much rarified, or intirely displaced: and the bursting of the glass vessels, in Beccaria's and Lane's experiments, shews that the same thing happens with regard to the water, when the electric fluid passes through it in the form of a spark. Now, I see no means by which the displacing of the air or water can be brought about, but by supposing its elasticity to be increased, by the motion of the electric fluid through it, unless you suppose it to be actually pushed aside, by the force with which the electric fluid endeavours to issue from the overcharged body: but I can by no means think, that the force with which the fluid endeavours to issue, in the ordinary cases in which electric sparks are produced, is sufficient to overcome the pressure of the atmosphere, much less that it is sufficient to burst the glass vessels in Beccaria's and Lane's experiments. 138] The truth of this is confirmed by Prop. XVI. For, let an under- charged body be brought near to, and opposite to the end of a long cylindrical body communicating with the ground, by that proposition the * Elettricismo artificial e naturale, p. no. Priestly, p. 209. f Phil. Trans. 1767, p. 451. { Phil. Trans. 1763, p. 84. Priestly, p. 216. The electric spark 8 1 pressure of the electric fluid against the base of the cylinder is scarcely greater than the force with which the two bodies attract each other, provided that no part of the cylinder is undercharged; which is very unlikely to be the case, if the electric repulsion is inversely as the square of the distance, as I have great reason to believe it is ; and, consequently, if the spark was produced by the air being pushed aside by the force with which the fluid endeavours to issue from the cylinder, no sparks should be produced, unless the electricity was so strong, that the force with which the bodies attracted each other was as great as the pressure of the atmosphere against the base of the cylinder: whereas it is well known, that a spark may be produced, when the force, with which the bodies attract, is very trifling in respect of that*. 139] One may frequently observe, in discharging a Leyden vial, that if the two knobs are approached together very slowly, a hissing noise will be perceived before the spark; which shews, that the fluid begins to flow from one knob to the other, before it passes in the form of a spark; and therefore serves to confirm the truth of the opinion, that the spark is brought about in the gradual manner here described. [* Note 10, p. 375.] C P. I. PRELIMINARY PROPOSITIONS [From the MS. in the possession of the Duke of Devonshire, N°. 4 ; hitherto unpublished.] {See Table of Contents at the beginning of this volume.} In this and all the following propositions and lemmata the electric attraction and repulsion is supposed to be inversely as the square of the distance. 140] PROP. XXIX. Let a thin circular plate be connected to a globe [of the same diameter] placed at an infinite distance from it by a straight canal of incompressible fluid such as is described in Pr. XIX, perpendicular to the plane of the plate and meeting it in its center, and let them be overcharged. If we suppose that part of the redundant fluid in the plate is spread uni- formly, and that the remainder is disposed in its circumference, and that the part which is spread uniformly is to that which is disposed in the circumference as p to one, the quantity of redundant fluid in the plate will be to that in the globe as p + i to 2p + i. For by Prop. XXII, Cor. V, the force with which that part of the redundant fluid in the plate which is disposed in the circumference repels the fluid in the canal is the same with which an equal quantity placed in the globe repels it in the contrary direction, and the repulsion of that part which is spread uniformly is the same as that of twice that quantity placed in the globe, and therefore the repulsion of a quantity of fluid equal to p + i disposed in the plate as expressed in the proposition is equal to that of the quantity 2p + i placed in the globe. 141] PROP. XXX. Fig. i. Let two equal thin circular plates AB and ab communicate with each other, and also with a third circular plate EF of the same size and shape and placed at an infinite distance from them, by the straight canal CD of incompressible fluid. Let the three plates be all parallel to each T) Fig. i. other and be placed so that CD shall pass through their centers and be per- pendicular to their planes, and let the plates be overcharged. The quantity of redundant fluid in each of the plates AB and ab will be to that in EF as the repulsion of the plate ab on the canal cD to the sum of the repulsions on cD Ratios of capacities 83 and fD (cf being taken equal to cC), supposing that the redundant fluid in all three plates is disposed in the same manner. For first, as the plates AB and ab are at an infinite distance from any other over or undercharged body, the repulsion of A B on the canal Cc in one direction must be equal to that of ab on it in the contrary, and therefore the redundant fluid in AB must be equal to that in ab. Secondly, the sum of the repulsions of AB and ab on the canal cD must be equal to that of EF on it in the contrary direction, as otherwise some fluid must flow from ab to EF or from EF to ab. But as all three plates are of the same size, and the fluid in them is disposed in the same manner, the repulsions of EF and ab on cD will be to each other as the quantity of redundant fluid in them, and therefore the quantity of redundant fluid in ab will be to that in EF as the repulsion of ab on CD to the sum of the repulsions of AB and ab on it, that is, as the repulsion of ab on cD to the sum of its repulsions on fD and cD, for the repulsion of AB on cD is equal to the repulsion of ab on/D*. 142] COR. I. If the fluid in these plates is disposed in the same manner as in Prop. XXIX the quantity of redundant fluid in each of the plates AB and ab will be to that in EF as AC(p+\) to ACQ + V+p (Ac - Cc) + For by Lemma X the repulsion of a given quantity of fluid spread uniformly over ab on the column cD; the repulsion of the same fluid on cf; the repulsion of the same quantity of fluid collected in the circumference of the plate ab on the column cD ; and the repulsion of the same fluid on cf are to each other as , ac , ac ac2 ac; ac + cf — af; — and >, 2 2 2af and therefore the whole repulsion of the plate ab on cD is to its repulsion on cf as ac ... ac ac2 pxac+ 2 : p x (ac + cf- «/) + -_ —^ and therefore the repulsion of ab on cD is to the sum of its repulsions on cD and/Z) as acx(p + l):ac(2p+i)-p (ac + cf- af) - ™ + ?L, acz or as ac(p + $:ac(p + \}+p(af-cf) + —j. 143] COR. II. Therefore if all the redundant fluid in the plates is spread uniformly, the redundant fluid in each of the plates AB and ab will be to that in EF as AC : AC + Ac — Cc, and if it is all collected in the circumference, as AC* AC :AC + A~~. Ac 144] COR. III. By Prop. XXIV it appears that the redundant fluid in the plate AB or ab will bear the same proportion to that in EF though they com- [* Note ii, p. 377.] 6—2 84 Preliminary Propositions municate with EF by separate canals, and whether the canals by which they communicate with it are straight or crooked, or in whatever direction EF is placed in respect of them, provided the situation of AB and ab in respect of each other remains the same. Only it must be observed that if the fluid in the plates is not disposed so as to be in equilibrio, as will most likely be the case if it is disposed as in the two preceding corollaries, it is necessary that the canals should meet them in their centers, for if the fluid in a plate is not in equilibrio, its repulsion on a canal of infinite length will not be the same in whatever part the canal meets it, as it will if the fluid in the plate is in equilibrio. 145] LEMMA XII. Fig. 2. Let BA be an infinitely slender cylindric column of uniform matter infinitely continued beyond A : the repulsion of a particle of C Fig. 2. matter K on this column in the direction BA is proportional to or may be represented by -^ • supposing the size of the particle and [the] base of the column to be given. For draw KC perpendicular to AB continued, and let the point B flow towards C, the fluxion of the repulsion of K on the column equals -OT CB _ - KB' KB* X KB ~ KB* ' the fluent of which, ^5 , is nothing when KB is infinite. ti.ts 146] LEMMA XIII. Suppose now KC to represent an infinitely slender cylindric column of uniform matter: the repulsion of KC on the infinite column BA is to the repulsion of the same quantity of matter collected in the point C tKC + KB^ KC on the same column as the nat. log. of ^r^ — to -^ . For the repulsion of all the matter therein, when collected at C, on BA is KC proportional to prp , and supposing the column CK to flow, the fluxion of its O.D CK' KC -L Kfl repulsion on BA is equal to T*W, the fluent of which is the nat. log. of - — ^= , and is nothing when CK is nothing. 147] LEMMA XIV. The repulsion of CK on a particle at B, in the direction CK CB, is proportional to -—& ^ , supposing the base of CK and the size of f\LJ X ' / ' the particle B to be given. Repulsion by columns 85 For supposing CK to flow, the fluxion of its repulsion on B in the direction CB is proportional to ^rg-2 x VR> ^e fluent °f which is ,^p rr> . and is nothing when CK is nothing. 148] LEMMA XV. Fig. 3. Let GEFHMN be a cylinder whose bases are GEF and HMN and whose axis is CK. Let the convex surface of this cylinder be uniformly coated with matter, and let GC be small in respect of CK. Let Fig. 3- GA be a diameter of the base produced, and D any point therein. The repulsion of the convex surface of the cylinder on the point D in the direction CD is very nearly the same as if all the matter therein was collected in the axis CK and spread uniformly therein. For let MED and meD be two planes infinitely near to each other, parallel to CK and passing through D, and cutting the convex surface in ME and NF and in me and nf, which will consequently be right lines equal to each other and perpendicular to ED; and draw CP perpendicular to ED. The repulsion of NnfF on D in the direction CD is proportional to Ff x FN PD Ee x EM PD pD ;un x rff • ancl tliat °* MmeE ls proportional to ^ ^^ x - Ff Ee But Ff is to Ee as FD to ED, therefore ^^ and v^. are each equal to ^=- = nf: — , therefore the sum of the repulsions of MmeE and NnfF ru + L.L) 2rL) is proportional to (Ff+Ee)CKxPD / i _i_\ _ (Ff + Ee)CK /_i_ _i_\ 2.PD x CD \ND + MD) 2CD \ND """ MDj ' But the repulsion of the same quantity of matter collected in CK is proportional (Ff+ Ee) x CK - — ~ — - to 2 , „„ I x -~~. , and, as CG is small in respect of CK, + 86 Preliminary Propositions 2 * differs very little from -&-=: , therefore the sum of the repulsions of MmeE and NnfF is very nearly the same as if all the matter in them was collected in CK, and consequently the repulsion of the whole convex surface of the cylinder will be very nearly the same as if all the matter in it was collected in CK. 149] COR. Therefore if BA represents an infinitely thin cylindric column of uniform matter infinitely extended beyond A, the repulsion of the convex surface of the cylinder thereon in the direction BA is very nearly the same as if all the matter therein was collected in CK, and therefore is to the repulsion of the same quantity of matter collected in the point C thereon very nearly as CK + KB . CK zCK A CK " nat. log. — ^rs -- to -^D> that is very nearly as nat. log. -^- to ^ • In like manner the repulsion on the infinite column DA is to the repulsion of the 4- KD CK same quantity of matter collected in C very nearly as nat. log. — ^== — to ^ . 150] PROP. XXXI. Fig. 3. Let the cylinder GEFHMN be connected to the globe W, whose diameter is equal to GB and whose distance from it is infinite, by a canal TR of incompressible fluid of any shape, and meeting the cylinder in any part, and let them be overcharged: the quantity of redundant fluid in the cylinder will be to that in the globe in a less ratio than that of CK to nat. log. -^=- , and in a greater ratio than that of -= to nat. log. -~5 • provided CB is small in respect of CK. By Prop. XXIV the quantity of redundant fluid in the cylinder will bear * As neither MD nor ND differ from KD by so much as CB, it is plain that II 2 j-fri + TFVJ cannot differ from -=^j= in so great a proportion as that of BC to KD, but in reality it does not differ from it in so great a ratio as that of CB2 to KD1, but as it is not material being so exact, I shall omit the demonstration. See A. I. [From MS. " A. i "] Demonstration of note at bottom of page 8, CB = r, CP = b, PF = d, PD = a, CR* + CD* = ea, b* - d* = /», e2 - /2 = g*. *-*+£ g e "*" e3 ' ND* = CR* + a* - 2ad + d* = e°- - b* - 2ad + d* = e* - f* - 2ad - g2 - 2ad, g2 + 2nd, I ad g + g3 + 3 2g& _ 2 I ad a*d* ~g g g3 2 /» aW _2 b* a*d* _ d* which is less than 2 b* d* _ 2 ~~ e e3 e* ~~ e e3 Comparison of charges 87 the same proportion to that in the globe in whatever part the canal meets the cylinder, therefore first I say the redundant fluid in the cylinder will bear a C ' K greater proportion to that in the globe than that of - _„ to nat. log. For let the canal TR be straight and perpendicular to BL, and let it meet the cylinder in R, the middle point of the line BL, and let it, if produced, meet the axis in S, which will consequently be the middle point of CK; then, if the redundant fluid in the cylinder was spread uniformly on its convex surface, the quantity of redundant fluid therein would be to that in the globe very nearly CK . . . CK as to nat. log. . For in that case the repulsion of the cylinder on the canal RT would be to the repulsion of the same quantity of redundant fluid collected in C very nearly 2SK . SK CK . CK as nat. log. -=^- to •=„• or as nat. log. -^ to —^ , and the force with which o/v jJK Co 20/3 the globe repels the canal in the direction TR is the same with which a quantity of redundant fluid equal to that in the globe placed at S would repel it in the contrary direction. But there can be no doubt but that almost all the redundant fluid in the cylinder will be collected on its surface, and also will be collected in greater quantity near the ends than near the middle, consequently the repulsion of the cylinder on RT will be less than if the redundant fluid was spread uniformly on its convex surface, and therefore the quantity of redundant fluid in it will bear a greater proportion to that in the globe than it would on that supposition. Secondly, the quantity of fluid in the cylinder will bear a less proportion to that in the globe than that of -^-^ to nat. log. _ For suppose the canal to meet the cylinder in B and to coincide with BA . Then, if the redundant fluid was spread uniformly on the convex surface, the C 'K quantity therein would be to that in the globe very nearly as -^-= to nat. log. O/5 -7^-5- , and the real quantity of redundant fluid in it will bear a less proportion CD to that in the globe than if it was spread uniformly on the convex surface. 151] COR. Therefore the quantity of redundant fluid in the cylinder is to that in a globe whose diameter equals CK in a ratio between that of 2 to nat. 2CK CK* log. -^o- and that of i to nat. log. -^ . 152] PROP. XXXII. Fig. 4. Let ADFB and adfb be two equal cylinders whose axes are EC and ec, let them be parallel to each other and placed so that Cc, the line joining the ends of the axes, shall be perpendicular to the axes, and let the lines EC and fb be bisected in G and g, and let them be connected by canals of incompressible fluid of any shape to a third cylinder of the same size and shape placed at an infinite distance from them, and let them be over- [* Note 12, p. 382.] 88 Preliminary Propositions charged : the quantity of redundant fluid in each of them will be to that in the third cylinder in a ratio between that of log ^ to log ^ + log — T^T- and 2EC . 2EC EC + Eb that of log -_„- to log y,R + log — ^r — , provided the redundant fluid in the third cylinder is disposed in the same manner as in the other two. C JS JO Fig. 4. For let us suppose that ADFB and adfb are connected to the third cylinder by the canal GM, then, if the redundant fluid in each cylinder is disposed uniformly on its convex surface, the sum of the repulsions of ADFB and adfb on the canal gM will be to the repulsion of the third cylinder thereon (supposing the quantity of redundant fluid in it to be equal to that in each of the two others) 2EG . , EG + Eg ,_ ,__.2EG as log 7^- + log - to log "Gg b CB • Let us now suppose the fluid in the first two cylinders to be disposed so as to be in equilibrio, and consequently to be disposed in greater quantity near their extremities than near their middles, and let the fluid in the third cylinder be disposed in the same manner, and be the same in quantity as before. The repulsion of ADFB on Gg will be diminished in a greater ratio, and consequently its repulsion on gM will be diminished in a less ratio than that of adfb on gM, consequently the sum of the repulsions of ADFB and adfb on gM will be diminished in a less ratio than that of the third cylinder thereon, and therefore the sum of the repulsions of ADFB and adfb on gM will be to that of the third cylinder thereon in a greater ratio than that of 2.EG EG log - + log — Eg ^ 2EG to log - . Therefore the real quantity of redundant fluid in each of the first two cylinders will be to that in the third cylinder in a less ratio than that of 2EG 2EG EG + Eg In like manner, by supposing them to be connected to the third cylinder by the canal bD, it may be shewn that the quantity of redundant fluid in either of the first two cylinders is to that in the third in a greater ratio than that of 2EC . 2EC EC + Eb* log -rrr to log -j^- + log CB CB Cb [* Note 13, p. 388.] Equidistant concave plates 89 153] PROP. XXXIII. If two bodies B and b are successively connected by canals of incompressible fluid to a third body C placed at an infinite distance from them, and are overcharged, that is, if one of them, as B, is first con- nected to G and afterwards B is removed and b put in its room, the quantity of redundant fluid in C being the same in both cases, it is plain that the quantity of redundant fluid in B will bear the same proportion to that in b that it would if B and b were placed at an infinite distance from each other, and connected by canals of incompressible fluid. 154] LEMMA XV. Fig. 5. Let AB be a thin flat plate of any shape what- soever, of uniform thickness and composed of uniform matter. Let CG be an infinitely slender cylindric column of uniform matter perpendicular to the plane of AB and meeting it in C and extended infinitely beyond G. Let ab be a thin circular plate perpendicular to cG whose center is c. Let the area of ab be equal to that of AB, and let the quantity of matter in it be the same, and let it be disposed uniformly. Fig. 5- Let B be that point of the circumference of AB which is nearest to C. If EC is small in respect of CB, the repulsion of the plate AB on the short column EC is to the repulsion of ab on the infinite column cG nearly as EC to cb. For let BD be a circle drawn through B with center C, as EC is very small in respect of CB, the repulsion of the circle BD on EC is to its repulsion on CG very nearly as EC to CB, and therefore is to the repulsion of ab on cG very nearly as EC to cb. But the repulsion of AB on EC is very little greater than that of DB, for the repulsion of DB is very near as great as it would be if its size was infinite. 155] LEMMA XVI. {Fig. 6.} Let ACB and DEF be two thin plates, not flat but concave on one side, let their distance be everywhere the same, and let it be very small in respect of the radius of curvature of all parts of their surface. Let C be any point of the surface of AB, and let CE be perpendicular to the surface in that point. Let Tt be a flat plate perpendicular to CE. Let R be any point in AB and S the corresponding point in DF, and let T 9o Preliminary Propositions be the corresponding point in Tt*: the sum of the repulsions of R on the column CE in the direction CE and of S on the same column in the opposite direction EC is very nearly equal to the force with which they would repel the same column in the direction CE if they were both transferred to T, provided CR* Fig. 6. • is very small in respect of the square of the least radius of curvature of the surface of AB. Let RS be continued till it meets CE continued in V, draw EM and SN perpendicular to CR. Let CM = C,RE-RM = E, SC - NC = S, and SE - NM = D. As CE is very small in respect of the least radius of curvature of AB, and CV is not less than the least radius of curvature, CM and NR are each very small in respect of CR, and therefore CN, MR, and ES differ from CR in a very small ratio. Moreover as CR2 is very small in respect of CF2, CM2 and RN2 are very small in respect of CE2, and therefore ME and NS differ in a very CE2 small ratio from CE ; and, moreover, 2 x (TE — TC) is greater than ==- . Now the repulsion of the point R on the column CE in the direction CE is _ A jffr f?r* r = ^7; ™ , and the repulsion of the point 5 on the same column RC RE RC x RE SC — SE in the opposite direction is ^^r — ~p-, and the sum of the repulsions of R oO X o jC- and S is RE-RC SC -SE E-C RC x RE SC x SE E RC x RE S S + C-D SC x SE' D C C ~ RC x RE ^ SC x SE ^ SC x SE RC x RE ^ SC x SE' * If RS is drawn perpendicular to the surface of A B at the point R cutting DF in S, I call S the corresponding point of the plate DF, and if CT is taken in the intersection of the plane RCE with that of the plate Tt equal to the right line CR, I call 2" the corresponding point of Tt. f Lemma XII [Art. 145]. Corresponding points 9 1 and the repulsion of the two particles when transferred to T on the column CE, TE — TC or the repulsion of T, as I shall call it for shortness, is 2 ~rr — ^ . But as ME differs in a very small ratio from CE, and RM differs in a very small ratio from RC, RE - RM or E differs in a very small ratio from TE — TC. In like manner SC — NC or S differs in a very small ratio from TE — TC, and ER and CS both differ in a very small ratio from TE, and SE differs in a small ratio from TC. Therefore =7; ^p + c-^~r-cr differs very little from 2 x == — =^ , that RC x RE SC + SE 7 E x TC is, from the repulsion of T. Moreover, as EM and SN differ very little from each other, D is very small in respect of TE — TC, and ^ ^= is very small in respect of the repulsion of T. .. RC - SE . CM + RN CE , RE - SC . Moreover, — ^^ — is less than =^ or than -^=-7 , and jj^ is KL KL L V Kt. RM - CN , RC -SE hardly greater than - , and is therefore still less than ^^ ; Kc, A.C RC RE therefore =-=- and ^ each differ from one in a less ratio than that of CE to o/i oO RC x RE CV, and therefore ^= — - differs from one in a less ratio than that of 2CE SE x SC toCV. r C C -C f RC x ~ Consequently, - ^-^ + ^-^ or ^^^ x (i - g ^= ^ SE x SC is less than ^^ =-= x -^^ , which is less than KL x Kh Lv -^ CE x RC zCE 2CE* x CV x RC x RE CV CV2 x RE ' zCE2 which is very small in respect of ~=. ™ 5^ , that is, of the repulsion of T. / / , X ./ O X i \ i '. Therefore the sum of the repulsions of R and S differs very little from the repulsion of T. N.B. Though the distance CR is ever so great, it may be shewn that the sum of the repulsions of R and 5 cannot be more than double that of T*. 156] COR. I. Let the edges of the plates ACB and DBF correspond, that is, let them be such that if a line is erected on any part of the circumference of one plate perpendicular to the [tangent] plane of the plate in that part, that line shall meet the other plate in its circumference. Let the two plates be of an uniform thickness, and let the thickness of DF bear such a proportion to that of AB that the quantity of matter shall be the same in both. Consequently the quantity of matter in each part of DF will be very nearly equal to that in the corresponding part of AB. Also let the size of the plates be such that CE [* Note 14, p. 389.] 92 Preliminary Propositions shall be very small in respect of the distance of C from the nearest part of the circumference of AB, and let the least radius of curvature of the surface of AB be so great in respect of CE that a point R may be taken such that CR shall be small in respect of that radius of curvature, and yet very great in respect of CE. Let Pp be a flat circular plate whose center is G and whose plane is per- pendicular to GZ, and let its area be equal to that of AB, and let the quantity of matter in it be also equal to that in AB, and let it be disposed uniformly: the sum of the repulsions of AB and DF on CE in the opposite directions CE and EC will be to the repulsion of Pp on the infinite column GZ very nearly as 2CE to GP. For suppose each particle of matter in all that part of AB whose distance from C is not greater than CR and in the corresponding part of DF to be transferred to its corresponding point in Tt, so as to form a circular plate whose radius is CR. If we suppose thJt the thickness of the plates Tt and Pp are both equal to that of AB, the matter in all parts of Tt will be very nearly twice as dense as that in AB or as that in Pp. Therefore the repulsion of Tt on CE will be very nearly twice the repulsion of Pp on Gg, supposing Gg to be equal to CE. But from the foregoing lemma it appears that the sum of the repulsions which the above-mentioned part of AB and DF exerted on CE before the matter was transferred is very nearly equal to that which Tt exerts thereon after the matter is transferred, and the sum of the repulsions of the remaining part of AB and DF, or that whose distance from C is greater than CR, is very small in respect of that part whose distance is less, therefore the sum of the repulsions of the whole plates AB and DF on CE is to the repulsion of Pp on GZ very nearly as 2.CE to GP. It may perhaps be supposed from this demonstration that it would be necessary that CE should be excessively small in respect of CV, in order that the sum of the repulsions of the plates on CE should be very nearly equal to the repulsion of Pp on Gg, but in reality this seems not to be the case, for if the plates are segments of concentric spheres whose center is V, the sum of their repulsions will exceed twice the repulsion of Pp on Gg in a not much CE greater ratio than that of i + ^. to i, and if the radius of curvature of their surfaces is in some places greater than CV, and nowhere less, I should think that the sum of their repulsion could hardly exceed twice the repulsion of Pp in so great a ratio as that. 157] COR. II. If we now suppose that the matter of the plate AB is denser near the circumference than near the point C, and that the density at and near C is to the mean density (or the density which it would everywhere be of if the matter was spread uniformly) as S to one, and that the quantity of matter in each part of DF is equal to that in the corresponding part of AB as before, the sum of the repulsions of the plates on CE will be less than if the matter Concave plate compared with flat one 93 was spread uniformly in a ratio approaching much nearer to that Of 8 to one than to that of equality. For if any particle of matter is removed from that part of AB which is near C to that point which is at a distance from it, and an equal alteration is made in the plate DF, the sum of the repulsions of these particles will be much less after their removal than before. 158] LEMMA XVII. Fig. 7. Let ACB be a thin plate, not flat but concave on one side, let the radius of curvature of its surface be nowhere less than CV, and let M V be perpendicular to its surface at C; let MC be very small in respect of CV, and let Tt be a plane perpendicular to MC: the difference of the repulsion of any particle of matter as R in the plate ACB on the point M in the direction CM, and of its repulsion on the point C in the same direction, is very nearly the same as if the particle was transferred to T (CT being equal to the right line CR), provided CR is small in respect of CV. Draw RN perpendicular to MC, the difference of the repulsions of R on the . _ MN CN MC CN CN ,._ points M and C = 3 - = 3 + - -3 , and the difference of the MC but + repulsions of the same particle placed at T on the same points = MR* = (MC + CAT)2 + RN2 = MC2 + CR2 + 2MC x CN = MT2 + 2MC x CN, CR2 and CN is not greater than —~~ , and therefore zMC x CN is not greater than MC x CR2 — -^= -- , and therefore is very small in respect of CR2 or MT2. O Y Therefore MR2 differs very little from MT2, and TT™ from This being premised there are two cases to be considered. 94 Preliminary Propositions First, if CR is considerably greater than MC, as CR> - MR* - MC- - 2MC x CN = MR* x {i - *ejJg+_2OV) J , i i I 3MC(MC + 2CN)\ £^3 differs not much from ^-3 x |i - - - MRi CN CN . CN - iMC (MC + zCN) , and MR* ~ CR* MC - 3CN (MC + zCN) , MC or from x - — V™ — • wnicn is very small in respect of ^p , provided CR is small in respect of CV. CR* For as CN is less than -?=-. , 20 r 3CN (MC + 2CN) . 3CR* x MC 2M#2 2 "CF" 4CF2' Therefore as j™ - =™ is very small in respect of ^^ , and as x C7 4Mfl2 x CF2 ' 3MC 3C#2 "" differs very little from , 3 + 3-3. or the difference of the AfC repulsions of R on the points M and C differs very little from JTTJ^ , the difference of the repulsions of T on the same points. Secondly, if CR is not considerably greater than MC, CN must be very small in respect of CR, and consequently must be very small in respect of MC. Therefore p™ - T™ is very small in respect of , and therefore the MC difference of the repulsions of R on C and M differs very little from 159] COR. Therefore by the same method of reasoning as was used in Cor. to Lemma XVI, the difference of the repulsions of the whole plate ACB on the points M and C is very nearly the same as if each particle of matter in it was transferred to the plane Tt and placed at the same distance from C as before, and therefore its repulsion on M is very nearly equal to its repulsion on C, provided MC is very small in respect of the least distance of the circum- ference of the plate from C, and that the thickness of the plate is everywhere very nearly the same, except at such a distance from C as is very great in respect of MC. 160] PROP. XXXIV*. Fig. 8. Let NnvV be a plate of glass or any other substance which does not conduct electricity, of uniform thickness, either flat, or concave on one side and convex on the other, and let the electric fluid be unable to penetrate at all into the glass or to move within it. Let ACB and DEF be thin coatings of metal, or any substance which conducts electricity, applied to the glass. * This proposition is nearly the same as Prop. XXII, only made more general. Theory of a coated plate 95 Let these coatings be of any shape whatsoever, and let their edges correspond as in Lemma XVI, Cor. I. Let AB communicate with the body H, and DF with the body L, by the straight canals CG and EM of incompressible fluid. Let the points C and E be so placed that the two canals shall form one right line perpendicular to A B at the point C, and let the lengths of these canals be so w 71 Fig. 8. great that the repulsion of the coatings on the fluid in them shall be not sensibly less than if they were infinite, and let H be overcharged and let L be saturated. It is plain from Prop. XII that DF will be undercharged, and that AB will be more overcharged than it would otherwise be. Let Ww be a thin flat circular plate whose center is C, perpendicular to CE, and whose area is equal to that of AB, let the force with which the redundant fluid in AB would repel the short column CE (if ME was continued to C) be called m, and let the force with which it would repel CM, or with which it repels CG (for they are both alike), be called M. Let the force with which the same quantity of redundant fluid disposed in DF, in the same manner in which the deficient fluid therein is actually disposed, would repel \pr\ be called * , let the force with which the same quantity of redundant fluid uniformly disposed on Ww would repel CG be called W, and let the force with which H repels CG be the same with which a quantity of fluid, which we will call B, uniformly distributed on Ww would repel it in the contrary direction: then will the GW quantity of redundant fluid in AB be B x ,-j ~ — , which, if M and G Mg + Gm — mg are very nearly alike, and m and g are very small in respect of G, differs very BW little from - , and the deficient fluid in DF will be to the redundant fluid g+ m in AB as M — m to G, and therefore on the same supposition will be very nearly equal to it. For the force with which AB repels the fluid in EM must be equal to that with which DF attracts it, for otherwise some fluid would run out of DF into L, or out of L into DF. For the same reason the excess of the repulsion of AB on CG above the attraction of DF thereon must be equal to the force with which a quantity of redundant fluid equal to B spread uniformly on Ww would repel it. g 6 Preliminary Propositions By the supposition the force with which AB repels the canal EM is M — m, and the force with which the same quantity of redundant fluid, spread on DF in the same manner in which the deficient fluid therein is actually disposed, repels it is G, therefore if the redundant fluid in A B is called A, the deficient fluid in DF will be A x — ~ - ; therefore the force with which DF attracts Cr CG is (G — g) — T*—~ • and the excess of the force with which AB repels CG above that with which DF attracts it is (G-g) (M-m) _ Mg+Gm-mg G G which must be equal to the force with which a quantity of fluid equal to B T> spread uniformly over Ww would repel it, that is, it must be equal to W j ; BGW therefore A equals Mg+Gm_mg- 161] COR. I. If the plate of glass is flat, and its thickness is very small in respect of the least distance of the point C from the circumference of AB, and the fluid in AB and DF is spread uniformly, the quantity of redundant fluid B x CW in DF will differ very little from — ^g— , and the deficient fluid in DF will be very nearly equal to the redundant fluid in AB. For as the plate of glass is flat, the two coatings will be equal to each other, and therefore M and G are equal to each other, and so are m and g, and CE* s.. differs very little from prp- , and moreover g is very small in respect of G. 162] COR. II. If the plate is flat and the two coatings are circular, their centers being in C and E, the quantity of redundant fluid in AB will be more B x CW CW accurately equal to - g^— x cw _ cj~ , CV being in this case equal to the semi-diameter of the coatings, and the deficient fluid in DF will be to the redundant in AB nearly as CW - CE to CW. For in this case ^ is accurately equal to CW-VCE*+CW* CW and therefore _ 2m _ m? 2CEVCW*+CE*-2CE* W Wz~ CW* which, if CE is small in respect of CW, differs very little from 2CE (CW - CE) CW> * Lemma XV [Art. 148.] Coated plate compared with globe 97 163] COR. III. If the plate of glass is not flat, and its thickness is very small in respect of the radius of curvature of its surface at and near C, every- thing else being as in Cor. I, the quantity of redundant fluid in AB will still B x CW be very nearly equal to For as CE is very small in respect of the radius of curvature, the two coatings will be very nearly of the same size, and therefore G differs very little from M , and m + g is to W very nearly as CE to CW*, and moreover m and g are both very small in respect of M and G f. 164] COR. IV. If we now suppose that the density of the redundant fluid in AB is greater at its circumference than it is near the point C, and that its density at and near C is less than the mean density, or the density which it would everywhere be of if it was spread uniformly, in the ratio of 8 to one, and that the deficient fluid in DF is spread nearly in the same manner as the redundant in AB, the quantity of redundant fluid in AB will be greater than before in a ratio approaching much nearer that of one to 8 than to that of equality, and that whether the glass is flat or otherwise. For by Lemma [XVI, Cor. II], m and g will each be less than before in the above-mentioned ratio. 165] COR. V. Whether the plate of glass is flat or concave, or whatever shape the coatings are of, or whatever shape the canals CG and EM are of, or in whatever part they meet the coatings, provided the thickness of the plate is very small in respect of the smallest diameter of the coatings, and is also sufficiently small in respect of the radius of curvature of its surface in case it is concave, the quantity of redundant fluid in AB will differ very little from B x CW 2.CE ' For suppose that the canal GC meets the coating AB in the middle of its shortest diameter, and that the point in which ME meets DF is opposite to L, as in Prop. [XXII, Art. 74], the thickness of the glass will then be very small in respect of the distance of the point C from the nearest part of the circum- ference of AB, and moreover, by just the same reasoning as was used in the Remarks to Prop. XXII, it may be shewn that 8 will in all probability differ very little from one, and consequently by Cors. I and III the redundant fluid in AB will be as above assigned. But by Prop. XXIV the quantity of fluid in the coatings will be just the same in whatever part the canals meet them, or whatever shape the canals are of. 166] COR. VI. On the same supposition, if the body H is a globe whose diameter equals Ww, id est the diameter of a circle whose area equals that of * Lemma XVI. Cor. t As the demonstration of the sixteenth Lemma and its corollary is rather intricate, I chose to consider the case of the flat plate of glass separately in Cor. I, and to demonstrate it by means of Lemma XV. c. p. i. 7 98 Preliminary Propositions the coating AB, the redundant fluid in AB will be to that in H very nearly as CW to For the quantity of redundant fluid in H will be 28. 167] COR. VII. On the same supposition the redundant fluid in AB will be very nearly the same whether the glass is flat or otherwise, or whatever shape the coatings are of. 168] COR. VIII. On the same supposition, if the size and shape of the coatings and also the thickness of the glass is varied, the size and quantity of redundant fluid in H remaining the same, the quantity of redundant fluid in AB will be very nearly directly as its surface, and inversely as the thickness of the glass. 169] PROP. XXXV (Fig. 9). Let Pp, Rr, Ss, Tt represent any number of surfaces whose distance from Nn, and consequently from each other, is the same in all parts, and let everything be as in the preceding proposition, except that the fluid in the spaces PprR, SstT, &c., that is, in the spaces comprehended between the surfaces Pp and Rr, and between 5s and Tt, &c. is moveable*, in such manner, however, that though the fluid in any of these spaces as PprR is able to move freely from Pp to Rr or from Rr to Pp, in a direction perpen- dicular to the surface Pp or Rr, yet it is not able to move sideways, or in a Fig. 9. direction parallel to those surf aces f, and let the fluid in the remaining spaces NnpP, RrsS, TtvV, &c. be immoveable: the quantity of redundant fluid in AB and the deficient fluid in DF will be very nearly the same that they would be if the whole fluid within the glass was immoveable, and its thickness was only equal to NP + RS + TV, &c., that is, to the sum of the thicknesses of those spaces in which the fluid is immoveable, provided that NV, the thickness of the glass, is very small in respect of the smallest diameter of AB, and also in respect of the radius of curvature of the surface of the glass. * To avoid confusion I have drawn in the figure only two spaces in which the fluid is supposed to be moveable, but the case would be just the same if there were ever so many. t [Note 15.] Theory of conducting strata in glass plate 99 Let the canals GC and EM be perpendicular to the plate of glass and opposite to each other, so as to form one right line, and let them meet AB and DF in the middle of their shortest diameters. The coating AB will be very much overcharged, and DF almost as much undercharged, in consequence of which some fluid will be driven from the surface Pp to Rr and from 5s to Tt. Moreover the quantity of fluid driven from any portion of the surface Pp near the line CE will be very nearly equal to the quantity of redundant fluid lodged in the corresponding part of AB, or more properly will be very nearly equal to a mean between that and the quantity of deficient fluid in the corresponding part of DF. For a particle of fluid placed anywhere in the space PprR near the line CE is impelled from Pp to Rr by the repulsion of AB and the attraction of DF, and it is not sensibly impelled either way by the spaces SstT, &c., as the attraction of the redundant matter in Ss is very nearly equal to the repulsion of the re- dundant fluid in Tt; and moreover the repulsion of AB on the particle and the attraction of DT are very nearly as great as if their distance from it was no greater than that of Pp and Rr, and therefore the particle could not be in equilibrio unless the quantity of fluid driven from Pp to Rr was such as we have assigned. As to the quantity of fluid driven from Pp to Rr at a great distance from CE, it is hardly worth considering. It is plain, too, that the quantity of fluid driven from Ss to Tt will be very nearly the same as that driven from Pp to Rr. Let now G, g, M, m and W signify the same things as in the preceding proposition, and let the quantity of redundant fluid in AB be called A as before, and let NP + RS + TV + &c., id est, the sum of the thicknesses of those spaces in which the fluid is immoveable, be to NV, or the whole thickness of the glass, as S to i, and let PR + ST + &c., or the sum of the thicknesses of those spaces in which the fluid is moveable, be to NV as D to one. Take £11 equal to PR, the repulsion of the space PprR on the infinite column EM is equal to the repulsion of the redundant fluid in Rr on EH, and therefore is to the repulsion of AB on CE very nearly as £11 or PR to CE. Therefore the repulsion of all the spaces PprR, SstT, &c. on EM is to the repulsion of A B on CE very nearly as D to one, or is equal to mD, and therefore the sum of the repulsions of AB and those spaces together on EM is very nearly equal to M — m + mD or to M — mS. But the attraction of DF on EM must be equal to the above-mentioned sum of the repulsions, and therefore the deficient fluid in DF must be very nearly , . A(M-mS) equal to — — ^ — - . By the same way of reasoning it appears that the force with which CG is repelled by AB, DF, and the spaces PprR and SstT, &c. together is very nearly equal to (M - mS) (G -g) Mg P mgS M - — -! - gD, or to 6 + mS -- - - gD, which, as M differs very little from G, and - is very small in respect of 7—2 IOO Preliminary Propositions mS or gS, is very nearly equal to g + mS — gD or to (g + m) S, therefore the BW quantity of redundant fluid in AB will be very nearly equal to , ~ , and will therefore be greater than if the fluid within the glass was immoveable very nearly in the ratio of one to S, or will be very nearly the same as if the thickness of the glass was equal to CE x S, and the fluid within it was im- moveable. 170] PROP. XXXVI. Fig. 10. Let every thing be as in the preceding pro- position, except that the electric fluid is able to penetrate into the glass on the side Nn as far as to the surface Kk, and on the side Vv as far as to Yy ; in such manner, however, that though the fluid can move freely from A B to aft or from Fig. 10. a/3 to AB, and also from DF to & or from 8 to DF, in a direction perpen- dicular to those surfaces, yet it is unable to move sideways, or in a direction parallel to those surfaces: the quantity of redundant fluid on one side of the glass, and of deficient fluid on the other, will be very nearly the same as if the spaces NnkK and VvyY were taken away and the coatings AB and DF were applied to the surfaces Kk and Yy. For by [Art. 132] of former Part, almost all the redundant and deficient fluid will be lodged on the surfaces a/3 and S, and the coatings AB and DF will be not much over or undercharged. Now if the whole of the redundant and deficient fluid was lodged in a/3 and S(f>, it is evident that the quantity of redundant and deficient fluid would be exactly the same as if the spaces NnkK and VvyY were taken away, and therefore it will in reality be very nearly the same. 171] COR. I. Therefore the quantity of redundant fluid on the positive side of the glass, that is, in the coating AB, and the space AaftB together, as well as the quantity of deficient fluid on the negative side of the glass, will be very nearly the same that they would be if the fluid was unable to penetrate into Penetration of glass by charge 101 the glass or move within it, and that the thickness of the glass was equal only to the sum of the thicknesses of those spaces in which the fluid is immoveable. 172] COR. II. Whether the electric fluid penetrates into the glass or not, it is evident that the quantity of redundant fluid on one side the glass, and of deficient fluid on the other, will be very nearly the same, whether the coatings are thick or thin. 173] PROP. XXXVII. It was shewn in the remarks on Prop. XXII in the first Part, that when the plate of glass is flat, and the fluid within it is im- moveable, the attraction of the deficient fluid in DF makes the redundant fluid in A B to be disposed more uniformly than it would otherwise be. Now if we suppose the fluid within the glass to be moveable as in the preceding proposition, and that the deficient fluid in the planes Pp, Ss, &c. and the redundant fluid in the planes Rr, Tt, &c. is equal to, and disposed similarly to that in DF, the redundant fluid in AB will be disposed more uniformly than it would be if the fluid within the glass was immoveable, and its thickness no greater than the sum of the thicknesses of those spaces in which the fluid is immoveable. For let the intermediate spaces be moved so that Tt shall coincide with Vv and Rr with Ss, &c., but let the distance between Tt and Ss and between Rr and Pp, &c. remain the same as before, that is, let the thickness of the spaces in which the fluid is moveable remain unaltered. The distance of Pp from Nn will now be equal to the sum of the thicknesses of the spaces TtVv, RrSs, NnPp, &c. in which the fluid is immoveable. Now, after this removal, the effect of the planes Tt and DF and of Rr and Ss, &c. will destroy each other, so that the intermediate spaces and DF together will have just the same effect in rendering the redundant fluid in AB more uniform than the plane Pp alone will have, that is, the fluid in AB will be disposed in just the same manner as if the thickness of the glass was no greater than the sum of the thicknesses of the spaces in which the fluid is immoveable, and the whole fluid within the glass was immoveable. But the effect of the intermediate spaces in making the fluid in AB more uniform was greater before their removal than after, for the effect of the two planes Pp and Rr together, and also that of Ss and Tt together, &c. is the greater the nearer they are to AB. 174] COR. The redundant and deficient fluid in the intermediate spaces will in reality be not exactly equal and similarly disposed to that in DF, and in all probability the quantity of deficient fluid disposed near the extremity of DF will be greater than that in the corresponding parts of Pp, Ss, &c., or than the redundant fluid in the corresponding parts of Rr, Tt, &c., so that the redundant fluid in AB will perhaps be disposed rather less uniformly than it would be if the deficient and redundant fluid in those spaces was equal to and similarly disposed to that in DF; but on the whole there seems no reason to think that it will be much less, if at all less, uniformly disposed than it would be if the thick- ness of the glass was equal to the sum of the thicknesses of the spaces in which the fluid is immoveable, and the whole fluid within the glass was immoveable. IO2 Appendix to Preliminary Propositions APPENDIX: FROM MS. NO. 5. 175] As the following propositions are not so necessary towards under- standing the experiment as the former, I chose to place them here by way of appendix. PROP. I. Let everything be as in Prop. XXXIV, except that the bodies H and L are not required to be at an infinite distance from the plates of glass; let now an overcharged body N be placed near the glass in such manner that the force with which it repels the column CG towards G shall be to that with which it repels the column EM towards M as the force with which the deficient fluid in DF attracts the column CG is to that with which it attracts EM: it will make no alteration in the quantity of redundant fluid in AB, provided thu repulsion of N makes no alteration in the manner in which the fluid is disposed in each plate. For increase the deficience of fluid in DF so much as that that coating and N together shall exert the same attraction on EM as DF alone did before, they will also exert the same attraction on CG as DF alone did before, and conse- quently the fluid in the two canals will be in equilibrio. 176] COR. In like manner, if the forces with which the body N repels the columns CG and EM bear the same proportion to each other as those with which the plate AB repels those columns, and therefore bear very nearly the same proportion to each other as those with which EM repels those columns, the quantity of deficient fluid in DF will be just the same as before N was brought near, and the redundant fluid in AB will be diminished by a quantity whose repulsion on CG is the same as that of N thereon. Therefore, if the repulsion of N on CG is not greater than that of H thereon, the diminution of the quantity of redundant fluid in AB will bear but a very small proportion to the whole. For the quantity of redundant fluid in AB is many times greater than that which would be contained in it if DF was away, id est, than that whose repulsion on CG is equal to the repulsion of H thereon in the contrary direction. 177] PROP. II. From the preceding proposition and corollary we may con- clude that if the force with which N repels the columns CG and EM bears very nearly the same proportion to each other as the force with which DF attracts those columns, the quantity of redundant fluid in AB will be altered by a quantity which will bear but a very small proportion to the whole, unless the repulsion of N on CG is much greater than that of H thereon. If the reader wishes to see a stricter demonstration of this proposition, as well as to see it applied to the case in which the fluid is supposed moveable in the intermediate spaces, as in Prop. XXXV, he may read the following: 178] PART i. Take Ee = £ thickness of those spaces in which the fluid is moveable, draw def equal and similar to DEF, and let the deficient fluid therein be equal to that in DF: the repulsion of the intermediate spaces on EM is to the Charge of condenser little affected by surroundings 103 difference of the attractions of DF on eAf and ep. (supposing Ee and M/j. to be equal to CE) very nearly as twice EC to CE, and is therefore very nearly equal to twice the difference of the attraction of df and DF on EM. Fig. ioa. In like manner the attraction of the intermediate spaces on CG is very nearly equal to twice the difference of the attraction of DF and df thereon. Suppose now the quantity of deficient fluid in DF to be increased in the ratio of i + / to i, the redundant fluid in AB remaining the same as before, a new attraction is produced on EM, very nearly equal to / x (attraction of DF on EM) - '- x 2 (diff. attr. of df and DF on EM), that is, very nearly equal to/ x (attraction of df on EM). In like manner a new attraction is produced on CG, very nearly equal to / x (attraction of df on CG), therefore, the new attraction produced on EM is to that produced on CG very nearly as the attraction of df on EM is to its attraction on CG, and therefore in order that the quantity of redundant fluid in AB shall not be altered by the approach of N, the repulsion of N on EM must be to its repulsion on CG very nearly as the attraction of df on EM to its attraction on CG. 179] PART 2. Lp t the fluid within the glass be either moveable, as in Prop. [XXXV, Art. 169], or let it be immoveable, and let the distance of H and L from the glass be either great or not. fCC (ff Let the repulsion of H on | ,,,.. in direction GC be | „ , and let the sum of these repulsions = S. (GC in direction CG = A Let the repulsion of ,/V on •[_.,,. ,. .. ,,,,, D, and let the repulsion [EM in direction EM = B which N should exert on CG in order that the redundant fluid in AB should remain unaltered be to that which it should exert on EM : : i : P. The quantity of redundant fluid in AB will be increased in the ratio of B - PA i + p S ~ P + p from that of B- PA to i, which, if P differs very little from i, differs very little i 4- to i. 104 Appendix to Preliminary Propositions For the force •! „ may be divided into two parts, namely PA- B pA+ B P+p " P+p PpA + pB PpA + PB P+p P+p (pA + B PpA + PB \ f • I P + p , has no tendency to alter the redundant fluid in AB, but the first part, or the force PA -B P + P (CG in direction CG - PpA + pB a' 1 (EM in direction EM ' or - P + p { -PA + B P + P (CG in direction GC - PpA + pB a ;1 (EM in direction EM to i. P + p (GC -PA + B as they are to the repulsion of H on j ^ as — „ -- to H, or as (- PA + B) J^-^ to S, increases the redundant fluid in the ratio of B- PA i + p S P + p 180] COR. I. If the lengths of the columns CG and EM are such that the repulsion and attraction of AB and DF on them are not sensibly less than if they were of an infinite length, the attraction of DF on CG will be very nearly equal to its attraction on EM, and therefore, if the forces with which N repels the columns CG and EM are very nearly equal to each other, the quantity of redundant fluid in AB will be very little altered thereby. N.B. If the size of H is much greater than that of AB, it is possible that its distance from the glass may be such as to exert a very considerable repulsion on EM, and yet that the action of AB and DF on CG shall be not sensibly less than if it was of an [infinite length], 181] COR. II. Let the bodies H and L be of the same size and shape and at an infinite distance from the glass, and let the fluid be in equilibrio. Let now an equal quantity of fluid be taken from H and L, the quantity of redundant fluid in AB will be very little altered thereby. For the repulsion of the whole quantity of fluid in L on the canal EM will be as much diminished as that of H on CG, so that it comes to the same thing as placing an overcharged body N in such manner that its repulsion on CG Coated plates in communication little affected 105 shall be equal to that on EM; which by the preceding proposition will make very little alteration in the quantity of redundant fluid in AB. 182] COR. III. Let the bodies H and L be at an infinite distance, and either of the same or different size, and let the fluid be in equilibrio. Let now the body H be brought so near to AB that its repulsion on GC shall be sensibly less than before. The quantity of redundant fluid in A B will be very little altered thereby, provided the repulsion of the two plates on the column CG is not sensibly diminished. For whereas when H was at an infinite distance from AB it exerted no repulsion on EM, now it is brought nearer it does exert some, and its repulsion on EM is very nearly equal to the diminution of its repulsion on CG, so that it comes to the same thing as placing a body N in such manner as to repel EM with very nearly the same force that it does CG in the contrary direction. 183] COR. IV. Let the body H be brought near A B as in the preceding corollary, and let the fluid be in equilibrio; let now an overcharged body R be placed near H, the quantity of redundant fluid in H must be so much diminished, in order that the fluid may remain in equilibrio, supposing the- fluid in AB to remain unaltered, as that the diminution of its repulsion on the two columns GC and EM shall be equal to the repulsion of R on the same columns. Consequently, if the repulsion of R on them is to the repulsion which H exerted on them before the approach of R as n to i, the quantity of re- dundant fluid in H will be diminished in the ratio of i — n to i. For supposing the quantity of fluid in H to be thus diminished, I say, the quantity of fluid in A will remain very nearly the same as before. For the repulsion of H and R on the two columns will be the same as that of H was before, but it is possible that their repulsion on GC may be a little less, and their repulsion on EM as much greater than that of H was before, but this, by the preceding corollaries, will make very little alteration in the quantity of fluid inAB. 184] COR. V. It appears from Prop. XXIII that the repulsion of the body R on the two columns GC and EM will be the same in whatever direction it is placed in respect of H and the canal, provided its distance from the point G is given, and consequently the diminution of the quantity of fluid in the body H will be very nearly the same in whatever direction R is situated, provided its distance from G is given. 185] COR. VI. Fig. n. Suppose now that instead of the body H there is placed a plate of glass Kkil, coated as in Props. XXXIV and XXXV, with the plates Tt and Ss, whereof Tt communicates with AB by the canal GC, and the other 5s communicates by the canal gP with the body P, placed at an infinite distance and saturated with electricity, and let AB and consequently Tt be overcharged, and let the fluid be in equilibrio. Suppose now that an overcharged body R is brought near the glass Kkil, I say that the proportion which the redundant fluid in Tt bears to that in AB will be very little altered thereby, supposing the length of the canal CG to be io6 Appendix to Preliminary Proposition.1: such that the repulsion of the coatings AB and DF thereon shall be not sensibly less than if it was infinite, and that the thickness of the glass Gg is very small in respect of the distance of R from it, and that the repulsion of R does not sensibly alter the disposition of the fluid in Tt and Ss, and also that the re- pulsion of R on GC and EM together is not much less than if GM was infinite, and also not much greater than the repulsion of the glass NnvV on CG. For let the quantity of fluid in Tt and Ss be so much altered that the united repulsion of R and tihpse two coatings on the two canals GC and EM together, and also their repulsion" *pn gP, shall be the same as that of the two coatings alone before the approach oi 'i& By Prop. II, Cor. i the quantity '.of fluid in Tt will be very little altered thereby, for the repulsion of R on the c^anal gP is very nearly the same as its repulsion on gC and EM together. As the repulsion of Tt, Ss and R together von the two canals GC and EM together is the same as before the approach of R, it follows that if their re- pulsion on gC is less than before, their repulsion onh\M will be as much increased. Let now the quantity of fluid in AB and DF be s-o much altered that their repulsion on gC shall be as much diminished as that i of Kkil and R on the same column is diminished, and that their repulsion on > EM shall be as much diminished as that of Kkil and R on the same is increased-1, it is plain that the fluid in ah1 three canals will be exactly in equilibrio, and' by the preceding corollary the quantity of fluid in AB will be very little altered, and therefore the proportion of the redundant fluid in AB and Tt to each ot her will be very little altered*. V 186] COR. VII. By Prop. [XXIV, Art. 86] all which is saicfc in this pro- position and corollaries holds good equally whether the canals Q7C, EM and GP are straight or crooked. LEMMA. * [Note 16, p. 392.] Testing large ami small circles by trial plate 1 07 187] Let DE be an uniform canal of incompressible fluid infinitely con- tinued towards E, and let A and B be given points in a right line with D, and let AB be bisected in C; the force with which any particle of fluid repels this canal (supposing the repulsion to be inversely as the square of the distance) is inversely as its distance from the point D, and therefore the sum of the forces with which two equal particles of fluid placed in A and B repel this canal is to the sum of the forces with which they would repel it if both collected in the point C, I I . _2_ * AD + BD : CD ' or as C£>2 : CZ>2 - CB*, CB* or as i : i - =-^ . 188] Let us now examine how far the proportion of the quantity of fluid in the large circle and the two small ones in Experiment V [Art. 273] Fig. 18, bear to each other will be affected by the circumstances mentioned in [Art. 276], supposing the plates to be connected by canals of incompressible fluid. First it appears from Cor. [VII, Art. 186], that the quantity of redundant fluid in the large circle, and also in the two small ones, will bear very nearly the same proportion to that in the jar A as it would if it had been placed at an infinite distance from A, for the distance of the plate from the jar was in neither Fig. 18. experiment less than 63 inches, and neither the length nor the diameter of the coated part of the jar exceeded four inches, so that the repulsion of the jar on the canal connecting it to the plate could not differ by more than ^ part from what it would be if the canal was infinitely continued, and would most probably differ from it by not more than J or ^ part of that quantity*; for the same * The repulsion of a globe 4 inches diameter on a straight uniform canal of incompressible fluid extending 63 inches from it differs by only ^ part from what it would be if the canal was infinitely continued, but the repulsion of a Leyden vial of that size on the same column differs probably not more than J or J of that quantity from what it would be if infinitely continued. io8 Appendix to Preliminary Propositions reason the deficience of fluid in the trial plate will bear very nearly the same proportion to that in the jar, &c. as it would if it had been placed at an infinite distance from it. • It is plain that if the plates had been placed at such a distance from the jar that the quantity of fluid in them had been considerably less than if they had been placed at an infinite distance, still the quantity in the large circle would bear very nearly the same proportion to that in the two small ones as it would if they had been placed at an infinite distance. 189] Secondly, it is plain that in trying the large circle, the repulsion of that circle increases the deficience of fluid in the trial plate, and the attraction of the trial plate increases the redundance in the circle. Now the repulsion of the plate Ee on the canal mMNa, and the attraction of the trial plate T on rRSA (supposing mMNa and rRSA to be infinitely continued beyond a and A) are by [Cor. IV, Art. 183] very nearly the same as if the redundant fluid in Ee and the deficient fluid in T were both collected in the centers of their respective plates, and the quantity of redundant fluid in Ee may be considered as equal to the deficient in T, and consequently the repulsion of Ee on mMNa is very nearly equal to the attraction of T on rRSA. Moreover, the repulsion of Ee on its own canal rRSA must be equal to the attraction of T on mMNa, as the jars with which they communicate are both equally electrified, and therefore, by Cor. [IV], the quantity of redundant fluid in Ee will be increased in very nearly the same ratio as the deficient in T. 190] In like manner, in trying the two small circles, the quantity of re- dundant fluid in them is increased in very nearly the same ratio as the deficient in T, for as half the distance of the two circles never bore a greater proportion to em than that of 18 to 72, the repulsion of the two circles on the canal mMNa will be very nearly the same, and the deficience of fluid in T will be increased in very nearly the same ratio as if all the redundant fluid in them were collected in e, the middle point between them. The quantity of redundant fluid in Bb indeed will be increased in a rather greater ratio, and that in Cc in a rather less ratio than if it was placed at e, but the ratio in which the quantity of fluid in Bb is increased must very nearly as much exceed that in which it would be increased if it was placed at e as that in which Cc is increased falls short of it, as the attraction of T on the canal fRSA exceeds that on rRSA by nearly the same quantity as its attraction gRSA falls short of it, and therefore the quantity of redundant fluid in both circles together is increased in very nearly the same proportion as that in a circle placed in e would be, and consequently the redundance in the two circles is increased in very nearly the same ratio as the deficience in the trial plate. 191]* The attraction of the trial plate on the canals fRSA and gRSA and the repulsion of the circles Bb and Cc on the canal mMNu is very nearly the same as if the deficient or redundant fluid in the plates was collected in the center of their respective plates, and therefore the repulsion of the circles Bb and Cc on the canal * Memorandum relating to the second article. Affect of floor and walls of the room 109 tnMNn is inversely as the distances of their centers from m, and the increase of the quantity of redundant fluid in the circles Bb and Cc by the attraction of T is in the same proportion. Therefore take the point a so that the repulsion of a particle at a on that canal shall be a mean between the repulsions of the same particle thereon when placed at B and C, the charge of T will be increased in the same proportion as it would be by the repulsion of a plate containing as much redundant fluid as the two plates together whose center was a, and the charge of the two circles together will also be increased in the same proportion as that of the circle whose center is a would be thereby. 192] Consequently, in trying either the large circle or the two small ones, the trial plate must be opened to very nearly the same surface to contain the same charge as them as it must be if they were placed at an infinite distance from the trial plate, and consequently no sensible alteration can be produced in the phsenomena of the experiment by the repulsion and attraction of the circles and trial plate on each other. 193] Thirdly, for the same reason it appears that as the circles and the trial plate are both at much the same distance from the ground and walls of the room, no sensible alteration can be produced in the experiment by the ground near the circles being rendered undercharged and that near the trial plate over- charged. It must be observed, indeed, that the distance of the circles and trial plate from the ground is much less than their distance from each other, and conse- quently the alteration of the charge of the two circles and trial plate produced by this cause will not be so nearly alike as that caused by their attraction and repulsion on each other; but as, on the other hand, the whole alteration of their charge produced by this cause is, I imagine, much less than that produced by the other, I imagine that this cause can hardly have a more sensible effect in the experiment than the preceding. 194] Fourthly, we have not as yet taken notice that the canals by which the jars A, a communicate with the ground are but short, and meet the ground at no great distance from the jars. But it may be shewn by the same kind of reasoning used in Prop. [II, Art. 178], with the help of the second corollary to the preceding proposition, that the quantity of redundant fluid in the circles will bear very nearly the same proportion to that in the positive side of the jar A, whether the canal by which A communicates with the ground is long or short. Besides that, if it was possible for this circumstance to make much alteration in the proportion which the redundant fluid in the circles bears to that in A , it would in all probability have very nearly the same effect in trying the two small circles as in trying the large one, so that no sensible alteration can be produced in the experiment from this circumstance. It appears, therefore, that none of the above-mentioned circumstances can cause any sensible alteration in this experiment*. * [Note 17, p. 394.] THOUGHTS CONCERNING ELECTRICITY [From MS. N° 10: probably an early draft of the theory.] {See Table of Contends at the beginning of this volume. J 195] Electricity seems to be owing to a certain elastic fluid inter- spersed between the particles of bodies, and perhaps also surrounding the bodies themselves in the form of an atmosphere. 196] This fluid, if it surrounds bodies in the form of an atmosphere, seems to extend only to an imperceptible distance from them*, but the attractive and repulsive power of this fluid extends to very considerable distances. 197] That the attraction and repulsion of electricity extend to con- siderable distances is evident, as corks are made to repel by an excited tube held out at a great distance from them. That the electric atmospheres themselves cannot extend to any perceptible distance, I think, appears from hence, that if two electric conductors be placed ever so near together so as not to touch, the electric fluid will not pass rapidly from one to the other except by jumping in the form of sparks, whereas if their electric atmospheres extended to such a distance as to be mixed with one another, it should seem as if the electricity might flow quietly from one to the other in like manner as it does through the pores of any conducting matter. But the following seems a stronger reason for supposing that these atmospheres cannot extend to any perceptible distance from the body they surround, for if they did it should seem that two flat bodies whenever they were laid upon one another should always become electric thereby, for in that case there is no room for the electric atmosphere to extend to any sensible distance from those surfaces of the bodies which touch one another, so that the electric fluid which before surrounded those surfaces would be forced round to the opposite sides, which would thereby become overcharged with electricity, and consequently appear electrical, which is contrary to experience. 198] Many Electricians seem to have thought that electrified bodies were surrounded with atmospheres of electric matter extending to great distances from them. The reasons which may have induced them to think so may be first, that an electrified body affects other bodies at a con- siderable distance. But this may, with much more probability, be supposed * There are several circumstances which shew that two bodies, however smooth and strongly pressed together, do not actually touch each other. I imagine that the distance to which the electric atmospheres, if there are any, extend must be less than the smallest distance within which two bodies can be made to approach. Conductors in communication ill owing to the attraction and repulsion of the electric matter within the body or close to its surface. And, secondly, because a body placed near a positively electrified body receives electricity itself, whence it is supposed to receive that electricity from the electrified body itself, and therefore to be within its atmosphere. But, in all probability, the body in this case receives its electricity from the contiguous air, and not immediately from the electrified body, as will be further explained in its place. 199] Let any number of bodies which conduct electricity with perfect freedom be connected together by substances which also conduct elec- tricity. It is plain that the electric fluid must be equally compressed * in all these bodies, for if it was not, the electric fluid would move from those bodies in which it was more compressed to those in which it was less compressed till the compression became equal in all. But yet it is possible that some of these bodies may be made to contain more than their natural quantity of electricity, and others less. For instance, let some power be applied to some of these bodies which shall cause the electric fluid within their pores to expand and grow rarer f, those bodies will thereby be made to contain less electric matter than they would otherwise do, but yet the electric matter within them will be just as much compressed as it would be if this power were not applied. On the other hand, if some power were applied which shall diminish the elasticity of the electric fluid within them and thereby make it grow more dense, those bodies will be made to contain more electricity, but yet the compression will remain still the same. 200] To make what is here said more intelligible, let us suppose a long tube to be filled with air, and let part of this tube, and consequently the air within, be heated, the air will thereby expand, and consequently that part of the tube will contain less air than it did before, but yet the air in that part will be just as much compressed as in the rest of the tube. In like manner, if you suppose the electric fluid to be not only confined within the pores of bodies, but also to surround them in the form of an atmosphere, let some power be applied to some of those bodies which shall prevent this atmosphere from extending to so great a distance from * Note by Editor. [That is, must sustain an equal pressure. In modern scientific language the words compression, extension, distortion, are used to express strain, or change of form, while pressure, tension, torsion, are reserved to indicate the stress or internal force which accompanies this change of form. Cavendish uses the word compression to indicate stress. The idea is precisely that of potential.] •f [No such power has been discovered. There is nothing among electrical phenomena analogous to the expansion of air by heat. — ED.] {Nowadays the free electrons in a metal, or on a large scale in an incandescent star, are often treated theoretically as constituting the molecules of a gaseous medium, responding to change of temperature. It is interesting to compare the text with electron theories of conductance and equilibrium. j 1 1 2 "Thoughts concerning Electricity them, those bodies will thereby be made to contain less electricity than they would otherwise do, but yet the electric fluid that surrounds them will be just as much compressed as it would [be] if that power was not applied. It will surely be needless to warn the reader here not to confound compression and condensation. 201] I now proceed to my hypothesis. DEF. i. When the electric fluid within any body is more compressed than in its natural state, I call that body positively electrified: when it is less compressed, I call the body negatively electrified. It is plain from what has been here said that if any number of con- ducting bodies be joined by conductors, and one of the bodies be positively electrified, that all the others must be so too. DEF. 2. When any body contains more of the electric fluid than it does in its natural state, I call it overcharged. When it contains less, I call it undercharged. 202] HYP. ist. Every body overcharged with electricity repels an overcharged body, and attracts an undercharged one. HYP. 2nd. Every undercharged body attracts an overcharged body, and repels an undercharged one. HYP. 3rd. Whenever any body overcharged with electricity is brought near any other body, it makes it less able to contain electricity than before. HYP. 4th. Whenever an undercharged body is brought near another it makes it more able to contain electricity. 203] COR. I. Whenever any body at a distance from any other electrified body is positively electrified it will be overcharged, and if negatively electrified it will be undercharged. COR. II. If two bodies, both perfectly insulated, so that no electricity can escape from them, be positively electrified and then brought near to each other, as they are both overcharged they will each, by the action of the other upon it, be rendered less capable of containing electricity, there- fore, as no electricity can escape from them, the fluid within them will be rendered more compressed, just as air included within a bottle will become more compressed either by heating the air or by squeezing the bottle into less compass; but it is evident that the bodies will remain just as much overcharged as before. 204] COR. III. If two bodies be placed near together, and then equally positively electrified, they will each be overcharged, but less so than they would [be] if they had not been placed near together. It may perhaps be said that this is owing to the electric atmosphere not having so much room to spread itself when the two bodies are brought Hypotheses regarding the electric fluid 1 1 3 near together as when they are at a distance; but I think it has already been sufficiently proved that these atmospheres cannot extend to any sensible distance from their respective bodies. COR. IV. If two bodies are placed near together and then equally negatively electrified, they will each be undercharged, but less so (id est, they will contain more electricity) than if placed at a distance. This phenomenon cannot be accounted for on the foregoing sup- position. 205] COR. V. If a body overcharged with electricity be brought near a body not electrified and not insulated, part of the electric fluid will be driven out of this body, and it will become undercharged. But if the body be insulated, as in that case the electric fluid cannot escape from it, it will not become undercharged, but the electric fluid within it will be more compressed than in its natural state, id est, the body will become positively electrified, and will remain so as long as the overcharged body remains near it, but will be restored to its natural state as soon as the overcharged body is taken away, provided no electricity has escaped during the meantime. This is in effect the same case as that described in the 5th experiment of Mr Canton's paper in the 48th vol. of [the Philosophical] Transactions, p. 353, and is explained by him much in the same manner as is done here. 206] COR. VI. If a body positively electrified in such a manner that if it is by any means made more or less capable of containing electricity, the electric fluid shall run into it from without or shall run out of it, so as to keep it always equally electrified, be brought near another body not electrified and not insulated, the second body will thereby be rendered undercharged, whereby the first body will become more capable of con- taining electricity, and consequently will become more overcharged than it would otherwise be with the same degree of electrification. This again will make the second body more undercharged, which again will make the first body more overcharged, and so on. It must be observed here, that if the two bodies are brought so near together that their action on one another shall be considerable, the electricity will jump from one to the other; otherwise if the two bodies were brought so near together that their distance should not be greater than the thickness of the glass in the Leyden bottle, it seems likely that the first body might receive many times as much additional electricity as it would otherwise receive by the same degree of electrification ; and that the second body would lose many times as much electricity as it would by the same degree of negative electrification. If the second body be negatively electrified, the same effect will be produced in a greater degree. c. P?I. 8 1 1 4 Thoughts concerning Electricity It may also happen that the second body shall be made undercharged though it is positively electrified, provided it be much less electrified than the first body, and that the two bodies be placed near enough to each other. 207] The shock produced by making a communication between the two surfaces of the Leyden vial seems owing only to the glass prepared in that manner containing vastly more electricity on its positive side than an equal surface of metal equally electrified, and vastly less on its negative side than the same surface of metal negatively electrified to the same degree, so that if two magazines of electricity were prepared, each able to receive as much additional electricity by the same degree of electrifi- cation as one of the surfaces of a Leyden vial, and one of the magazines was to be positively electrified and the other negatively, there is no doubt but what as great a shock would be produced by making a communication between the two magazines as between the two surfaces of the Leyden vial. I think, therefore, that the phenomena of the Leyden vial may very well be accounted for on the principle of the 6th Corollary, for in the Leyden vial the two surfaces of the glass are so near together, that the electric matter on one surface may act with great force on that on the other, and yet the electricity cannot jump from one surface to the other, by which means perhaps the positive side may be made many times more overcharged, and the negative side many times more undercharged, than it would otherwise be. 208] HYP. 5th. It seems reasonable to suppose that when the electric fluid within any body is more compressed than it is in the air surrounding it, it will run out of that body, and when it is less compressed it will run into the body. COR. I. Let the body A , not electrified, be perfectly insulated, and let an overcharged body be brought near it. The body A will thereby be rendered less capable of containing electricity, and therefore the electric fluid within it, as it cannot escape, will be rendered more compressed. But the electricity in the adjoining air will, for the same reason, be also compressed, and in all probability equally so, therefore the electricity will have no disposition either to run in or out of the body. COR. II. It is evidently the same thing whether A be insulated, or whether it be not insulated, but electrified in such manner that the fluid within it be as much compressed as it was before by virtue of the insula- tion. Therefore if the body A be now not insulated, but positively electrified, and an overcharged body be brought to such a distance from it that the electric fluid in the adjacent air be equally compressed with that in A, such a quantity of electricity will thereby be driven out of A that it will retain only its natural quantity. So that A will be neither Communication of electricity 1 1 5 overcharged nor undercharged, nor will the electricity have any disposition to run either in or out of it. 209] If the overcharged body be now brought nearer, A will become undercharged, and the electricity will run into it from the surrounding air. If the overcharged body be not brought so near A will be overcharged, and the electricity will run out of it. If an undercharged body be brought near A it will become more overcharged than before, and the electricity will run out stronger than before. COR. III. If the body A be negatively electrified, and an undercharged body be brought near it till the electric fluid in the adjoining air is as much compressed as that in the body A, the electricity will have no dis- position to run either in or out of A , nor will it be either overcharged or undercharged, as will appear from the same way of reasoning as was used with regard to the 2nd Corollary. If the undercharged body be now brought nearer, A will become over- charged, and the electricity will also run out of it. If the undercharged body be removed farther off, A will become undercharged, and the elec- tricity will also run into it. If an overcharged body be brought near to A, it will become more undercharged than before, and the electricity will also run in faster than before. On the whole, therefore, it appears that whenever a body is under- charged the electricity will run into it, and whenever it is overcharged it will run out. 210] It has usually been supposed that two bodies, whenever the electricity either runs into or out of both of them, repel each other ; but that when it runs into one and out of the other, they attract. In the beginning of this paper I laid down a different rule for the electric attraction and repulsion, namely, that when the two bodies are both overcharged or both undercharged they repel, but attract when one is overcharged and the other undercharged. But by what has been just said it appears that these two rules agree together, or at least if they do differ, they differ so little that there is no reason to think my rule will agree less with experiment than the other. The reasoning here used would have been more satisfactory if the bodies were capable of containing electricity only on one side, namely, on that which is turned towards the other body. But I do not imagine, however, that this will make much difference in the effect. 211] What has been here said holds good only in cases where the size of the body A is small in respect of the distance of the electrified body from it, so that the influence of the electrified body may be nearly the same on all parts of the body A as is the case in bits of cork held near an excited tube; but when the size of the body A is such that the influence 8—2 1 1 6 Thoughts concerning Electricity of the electrified body may be much greater on that part of A which is directly under it than on that which is farther removed from it, as is the case in electrifying a prime conductor by an excited tube, then the case is very different, for then on approaching the electrified tube, part of the electric fluid will be driven away from that part of the prime conductor which is nearest the excited tube to the remoter parts where its influence is weaker, whereby that part of the conductor nearest the tube will be undercharged, and consequently the compression of the electric fluid in that part will be less than in the contiguous air, consequently some electric matter will flow into it from the adjoining air, whereby the conductor will be overcharged, and therefore on taking away the tube will be posi- tively electrified. Thus if the excited tube or other electrified body is not brought within a certain distance, the conductor receives its electricity only from the contiguous air, as was before said, and not immediately from the electrified body; but if the body be brought near enough, the electric matter jumps from the electrified body to the conductor in form of a spark. 212] The means by which this is brought about seems thus — When the part of the conductor nearest the excited tube has received any electricity from the contiguous air, that air will be undercharged, and will receive electricity from the adjacent air between it and the tube, by which means the electric matter will flow in gentle current between the particles of air from the excited tube to the conductor. It seems now as if the particles of air were by this means made to repel each other with more force, and thereby to become rarer; this will suffer the electric fluid to flow in a swifter current, which again will increase the repulsion of the particles of air, till at last a vacuum is made, upon which the electric fluid jumps in a continued body to the conductor. 213] That a vacuum is formed by the electric fluid when it passes in the form of a spark through air or water appears, I think, from the violent rising of the water in Mr Kinnersley's electrical air-thermometer (Priestley, p. 216), and still more strongly from the bursting the vial of water, in Mr Lane's experiment, by making the electrical fluid pass through the water in the form of a spark. If I am not much mistaken I have frequently observed, in discharging a Leyden vial, that if the two knobs are approached together very gently, a hissing noise may be perceived before the spark, which shews that the electricity does begin to flow from one knob to the other before it moves in the form of the spark, and may therefore induce one to think that the spark is brought about in the gradual manner here described. 214] The attraction and repulsion of electrified bodies, according to the law I have laid down, may perhaps be accounted for in the following Attraction and repulsion 1 1 7 manner. Let a fluid consisting of particles mutually repelling each other, and whose repulsion extends to considerable distances, be spread uni- formly all over the globe, except in the space A , which we will suppose to contain more than its proper quantity of the fluid. The fluid placed in any space B within reach of the repulsion of A will be repelled from A with more force than it will [be] in any other direction. But as it cannot recede from A without an equal quantity of the fluid coming into its room which will be equally repelled from A, it is plain that it will have no tendency to recede from A , any more than a body of the same specific gravity as water has any tendency to sink in water. Let now the space B be made to contain more than its natural quantity of this fluid, it will then really have a tendency to recede from A , or will appear to be repelled by it, just as a body heavier than water tends to descend in it, and, on the contrary, if B is made to contain less than its natural quantity of the fluid, it will have a tendency towards A, or will appear to be attracted by it. 215] Let now the space A be made to contain less than its natural quantity of the fluid (as the fluid in B is now repelled from A with less force than it is in any other direction, id est, apparently attracted towards it), if B also contain less than its natural quantity of the fluid it will tend to recede from A , id est, appear to be repelled by it ; but if B contain more than its natural quantity, it will then tend to approach towards A , id est, appear to be attracted by it. 216] If the electric fluid is diffused uniformly through all bodies not appearing electrical and the repulsion of its particles extends to con- siderable distances, it is plain that the consequences are such as are here described ; but how far that supposition will agree with experiment I am in doubt*. * [Note 18, p. 397.] [ "8 1 EXPERIMENTS ON ELECTRICITY {See the reasoned summary of methods and results in the latter part of Prof. Clerk Maxwell's 'Introduction.'} {I.} EXPERIMENTAL DETERMINATION OF THE LAW OF ELECTRIC FORCE. [From MS. N°. 7: apparently prepared for publication. See Table of Contents at the beginning of this volume.] 217] I now proceed to give an account of the experiments, in all of which I shall suppose, according to the received opinion, that the elec- tricity of glass is positive, but it is not at all material to the purpose of this paper whether it is so or not, for if it was negative, all the experi- ments would agree equally well with the theory. 218] EXPERIMENT I. The intention of the following experiment was to find out whether, when a hollow globe is electrified, a smaller globe inclosed within it and communicating with the outer one by some con- ducting substance is rendered at all over or undercharged; and thereby to discover the law of the electric attraction and repulsion. Apparatus for experiment 'with globes \ 1 9 219] I took a globe 12-1 inches in diameter, and suspended it by a solid stick of glass run through the middle of it as an axis, and covered with sealing-wax to make it a more perfect non-conductor of electricity. I then inclosed this globe between two hollow pasteboard hemispheres, 13-3 inches in diameter, and about -fa of an inch thick, in such manner that there could hardly be less than •& of an inch distance between the globe and the inner surface of the hemispheres in any part, the two hemispheres being applied to each other so as to form a complete sphere, and the edges made to fit as close as possible, notches being cut in each of them so as to form holes for the stick of glass to pass through. By this means I had an inner globe included within an hollow globe in such manner that there was no communication by which the electricity could pass from one to the other. I then made a communication between them by a piece of wire run through one of the hemispheres and touching the inner globe, a piece of silk string being fastened to the end of the wire, by which I could draw it out at pleasure. 220] Having done this I electrified the hemispheres by means of a wire communicating with the positive side of a Leyden vial, and then, having withdrawn this wire, immediately drew out the wire which made a communication between the inner globe and the outer one, which, as it was drawn away by a silk string, could not discharge the electricity either of the globe or hemispheres. I then instantly separated the two hemispheres, taking care in doing it that they should not touch the inner globe, and applied a pair of small pith balls, suspended by fine linen threads, to the inner globe, to see whether it was at all over or undercharged. 221] For the more convenient performing this operation, I made use of the following apparatus. It is more complicated, indeed, than was necessary, but as the experiment was of great importance to my purpose, I was willing to try it in the most accurate manner. ABCDEF and AbcDef (Fig. 12) are two frames of wood of the same size and shape, supported by hinges at A and D in such manner that each frame is moveable on the horizontal line AD as an axis. H is one of the hemispheres, fastened to the frame ABCD by the four sticks of glass Mm, Nn, Pp, and Rr, covered with sealing-wax, h is the other hemisphere fastened in the same manner to the frame AbcD. G is the inner globe, suspended by the horizontal stick of glass 5s, the frame of wood by which Ss and the hinges at A and D are supported being not represented in the figure to avoid confusion. Tt is a stick of glass with a slip of tinfoil bound round it at x, the place where it is intended to touch the globe, and the pith balls are suspended from the tinfoil. I 20 Determination of the law of electric force The hemispheres were fixed within their frames in such manner that when the frames were brought near together the edges of the hemispheres touched each other all round as near as might be, so as to form a complete c Fig. 12. sphere, and so that the inner globe was inclosed within them without anywhere touching them, but on the contrary being at nearly the same distance from them in all parts. 222] It was also so contrived, by means of different strings, that the same motion of the hand which drew away the wire by which the hemi- spheres were electrified, immediately after that was done, drew out the wire which made the communication between the hemispheres and the inner globe, and immediately after that was drawn out, separated the hemispheres from each other and approached the stick of glass Tt to the inner globe. It was also contrived so that the electricity of the hemi- spheres and of the wire by which they were electrified was discharged as soon as they were separated from each other, as otherwise their repulsion might have made the pith balls to separate, though the inner globe was not at all overcharged. The inner globe and hemispheres were also both coated with tinfoil to make them the more perfect conductors of electricity. 223] In trying the experiments a coated glass jar was connected to the wire by which the hemispheres were electrified, and this wire was withdrawn so as not to touch the hemispheres till the jar was sufficiently charged. It was then suffered to rest on them for two or three seconds and then withdrawn, and the hemispheres separated as above described. 224] An electrometer also was fastened to the prime conductor by Results of experiment 'with globes 121 • which the coated jar was electrified, by which means the jar and conse- quently the hemispheres were always electrified in the same degree. This electrometer as well as the pith balls will be described in [Arts. 244 and 248] ; the strength of the electricity was the same as was commonly used in the following experiments, and is described in [Arts. 263, 329, 359, 520]. 225] My reason for using the glass jar was that without it it would have been difficult either to have known to what degree the hemispheres were electrified or to have kept the electricity of the same strength for a second or two together, and if the wire had been suffered to have rested on the hemispheres while the jar was charging, I was afraid that the electricity might have spread itself gradually on the sticks of glass which supported the globe and hemispheres, which might have made some error in the experiment. 226] From this manner of trying the experiment it appears: First, that at the time the hemispheres are electrified, there is a perfect communication by metal between them and the inner globe, so that the electricity has free liberty to enter the inner globe if it has any disposition to do so, and moreover that this communication is not taken away till after the wire by which the hemispheres are electrified is removed. Secondly, before the hemispheres begin to be separated from each other, the wire which makes the communication between them and the globe is taken away, so that there is no longer any communication between them by any conducting substance. Thirdly, from the manner in which the operation is performed, it is impossible for the hemispheres to touch the inner globe while they are removing, or even to come within T%ths of an inch of it. And Fourthly, the whole time of performing the operation is so short, that no sensible quantity of electricity can escape from the inner globe, between the time of taking away the communication between that and the hemispheres, and the approaching the pith balls to it, so that the quantity of electricity in the globe when the pith balls are approached to it cannot be sensibly different from what it is when it is inclosed within the hemispheres and communicating with them. 227] The result was, that though the experiment was repeated several times*, I could never perceive the pith balls to separate or shew any signs of electricity. 228] That I might perceive a more minute degree of electricity in the inner globe, I tried the experiment in a different manner, namely, before the hemispheres were electrified, I electrified the pith balls positively, making them separate about one inch. When the hemispheres were then separated, and the tinfoil, x, brought in contact with the globe, and [* Dec. 18-24, 1772, Arts. 512, 513, and April 4, 1773, Art. 562.] I 2 2 Delicacy of the experiment consequently the electricity of the pith balls communicated to the globe, they still continued to separate, though but just sensibly. I then repeated the experiment in the same manner, except that the pith balls were negatively electrified in the same degree that they before were positively. They still separated negatively after being brought in contact with the globe, and in the same degree that they before did positively. 229] It must be observed that if the globe was at all overcharged the pith balls should separate further when they were previously positively electrified than when negatively, as in the first case the pith balls must evidently separate further than they would do if the globe was not over- charged, and in the latter case less. Moreover, a much smaller degree of electricity may be perceived in the globe by this manner of trying the experiment than the former, for when the pith balls have already got a sufficient quantity of electricity in them to make them separate, a sensible difference will be produced in their degree of divergence by the addition of a quantity of fluid several times less than what was necessary to make them separate at first. It is plain that this method of trying the experiment is not just, unless the hemispheres are electrified in nearly the same degree when the pith balls are previously electrified positively as when negatively, which was pro- vided for by the electrometer. 230] In order to find how small a quantity of electricity in the inner globe might have been discovered by this experiment, I took away the hemispheres with their frames, leaving the globe and the pith balls as before. I then took a piece of glass, coated as a Leyden vial, which I knew by experiment contained not more than Jyth of the quantity of redundant fluid on its positive side that the jar by which the hemispheres were electrified did, when both were charged from the same conductor. I then electrified this coated plate to the same degree, as shewn by the electrometer, that the jar was in the former experiment, and then separated it from the prime conductor, and communicated its electricity to the jar, which was not at all electrified. Consequently the jar contained only ^th part of the redundant fluid in this experiment that it did in the former, for the coated plate and jar together contained only 5Vth. and therefore the jar alone contained only g^th. By means of this jar, thus electrified, I electrified the globe in the same manner that the hemispheres were in the former experiment, and im- mediately after the electrifying wire was withdrawn, approached the pith balls. The result was that by previously electrifying the balls, as in the second way of trying the experiment, the electricity of the globe was very manifest, as the balls separated very sensibly more when they were previously electrified positively than when negatively, but the electricity Discussion of the results as to law of force 123 of the globe was not sufficient to make the balls separate, unless they were previously electrified. It is plain that the quantity of redundant fluid communicated to the globe in this experiment was less than ^th part of that communicated to the hemispheres in the former experiment, for if the hemispheres themselves had been electrified they would have received only ^th of the redundant fluid they did before, and the globe, as being less, received still less electricity. 231] It appears, therefore, that if a globe 12-1 inches in diameter is inclosed within a hollow globe 13-3 inches in diameter, and communicates with it by some conducting substance, and the whole is positively elec- trified, the quantity of redundant fluid lodged in the inner globe is certainly less than g'^th of that lodged in the outer globe, and that there is no reason to think from any circumstance of the experiment that the inner globe is at all overcharged. 232] Hence it follows that the electric attraction and repulsion must be inversely as the square of the distance, and that when a globe is posi- tively electrified, the redundant fluid in it is lodged intirely on its surface. For by Prop. V [Art. 20], if it is according to this law, the whole redundant fluid ought to be lodged on the outer surface of the hemispheres, and the inner globe ought not to be at all over or undercharged, whereas, if it is inversely as some higher power of the distance than the square, the inner globe ought to be in some degree overcharged. 233] For let ADB (Fig. 13) be the hemispheres and adb the inner globe, and Aa the wire by which a com- munication is made between them. By Lemma IV [Art. 18], if the elec- tric attraction and repulsion is in- versely as some higher power of the distance than the square, the re- dundant fluid in ABD repels a particle of fluid placed anywhere in the wire A a towards the center, and consequently, unless the inner globe was sufficiently overcharged to pre- vent it, some fluid would flow from the hemispheres to the globe. But if the electric attraction and repulsion is inversely as some lower power of the distance than the square, the redundant fluid in ABD impels the particle in the contrary direction, that is, from the center, and therefore the inner globe must be undercharged. 234] In order to form some estimate how much the law of the electric attraction and repulsion may differ from that of the inverse duplicate Fig. 13- 124 Experiment with conductor of any form ratio of the distances without its having been perceived in this experiment, let AT be a diameter of the two concentric spheres ABD and abd, and let A a be bisected in e. Ae in this experiment was about -35 of an inch and Te 13-1 inches, therefore if the electric attraction and repulsion is inversely as the 2 + ^'jjth power of the distance, it may be shewn that the force with which the redundant fluid in ABD repels a particle at e towards the center is to that with which the same quantity of fluid collected in the center would repel it in the contrary direction as I to 57. But as the law of repulsion differs so little from the inverse duplicate ratio, the redundant fluid in the inner globe will repel the point e with very nearly the same force as if it was all collected in the center, and therefore if the redundant fluid in the inner globe is J7th part of that in ABD the particle at e will be in equilibrio, and as e is placed in the middle between A and a, there is the utmost reason to think that the fluid in the whole wire A a will be so too. We may therefore conclude that the electric attraction and repulsion must be inversely as some power of the distance between that of the 2 + ^th and that of the 2 — ^th, and there is no reason to think that it differs at all from the inverse duplicate ratio*. 235] EXPERIMENT II. A similar experiment was tried with a piece of wood 12 inches square and 2 inches thick, inclosed between two wooden drawers each 14 inches square and 2 inches deep on the outside, so as to form together a hollow box 14 inches square and 4 thick, the wood of which it was composed being -5 to -3 of an inch thick. The experiment was tried in just the same manner as the former. I could not perceive the inner box to be at all over or undercharged, which is a confirmation of what was supposed at the end of Prop. IX [Art. 41]— that when a body of any shape is overcharged, the redundant fluid is lodged entirely on the surface, supposing the electric attraction and re- pulsion to be inversely as the square of the distance f. DEMONSTRATION OF COMPUTATIONS IN [ART. 234]. Let aef be a sphere, c its center, b any point within it, af a diameter, plane perpendicular to af. Let cb = a, ba = d, bf = s and ad = #, and let the repulsion be inversely as the n power of the distance. The convex surface of the segment Eae is to that of the whole globe as ad : af, and therefore if the point d is supposed to flow towards/, the fluxion of the surface Eae is proportional to x, and the fluxion of its re- pulsion on b in the direction dc is proportional to Ee any * [Note 19, p. 404.] t [Art. 561.] Mathematical computation for law of force 125 or may be represented thereby, but be* = (d - x)2 + x (2a + 2d - x) = d* + 2ax, therefore the fluxion of the repulsion is *(*-*) n+l' (d* + 2ax) 2 the variable part of the fluent of which is - 2ad - d2 d* zax) but when x is nothing, d2 + 2ax, or be2 = d2, and when x = af, or s + d, it = s2, therefore the whole fluent generated while b moves from a to f is 2ad + d2 / i i \ d3~n — s3~" 2a* (n - i) W"-1 s"-1/ 2«2 (3 - «) ' but the repulsion of all the fluid collected in the center on b _s + d a" ' and a = — 2 and 2«rf + d2 = ds, therefore the repulsion of the surface of the globe is to that of the same quantity of fluid collected in the center as ds s"-1 - d"-1 d3-" — s3-" 2 (s + d) x - sn-l_ that the charge of the circle of i8£ inches was to that of two of the rosin plates together as 20-19 to 21-96, and that the charge of the circle of 36 inches was to that of all four plates as 43-75 to 42-06. But the charge of the four plates together will not be exactly four times the charge of one plate singly, as some allowance must be made for the charge of the wire connecting their upper surfaces, and, besides that, the charge of the plates when placed close together will not be quite so great as if placed at a distance fron each other §. in the inner globe, and the attraction of the outer globe on the canal BE is to the repulsion of the inner one thereon as i i CD '' I3C' and therefore the quantity of redun. fluid in the inner globe is to that which it would contain if the outer globe were away as If room was spherical, 16 feet in diameter, globe in middle of it, its charge should be increased in ratio of 1 6 to 15 by reason of undercharged floor, &c. * [This is the only indication of the Height of the room. The circles were sus- pended by silk strings from a horizontal bar (Art. 466) 87-5 inches from the floor. By Art. 474 the platform 14 inches high diminished the height of the bodies in the ratio of 2 to 3. Hence the height of the center of the bodies from the floor was 42 inches, and the height of the room 4 x 42 inches, or 14 feet. This would agree with the height of the top of the circle of 18 inches being 51 inches from the floor (Art. 472).] f These plates are non-conductors of electricity, and may be charged as Leyden vials. The manner in which I made them will be described in the following pages [Arts. 373, 514]. My reason for making them of these materials is that the charge of such a plate is much less than that of a plate of glass of the same dimensions. J It must be observed that, in the two last mentioned comparisons, the rosin plates were placed close together and their upper surfaces connected by a piece of wire. § [Art. 5570 Capacity as ajfected by floor and walls of the room 1 7 1 By trying the charge of all four rosin plates together by the machine, Fig. 20, both when placed close together and at as great a distance from each other as I could, I found their charge when close together to be to their charge when placed at a distance nearly as 41 to 41^, and, from some other experiments I made, I am inclined to think that the charge of each of the wires which connected the upper coatings of the plates was to that of one plate alone as 28 to 930*. From these circumstances, I am inclined to think that the charge of two plates together is to that of one plate alone as 21-96 to 10-34, and that the charge of the four plates together is to that of one alone as 42-06 to 10-34, an(i consequently that the charges of the tin circles of 9-3 inches, i8£ inches and 36 inches are to each other as 9-3, 20-19 and 4375 1- 338] Though I do not know how to calculate how much the charge of the circles ought to be increased by the attraction of the undercharged ground, yet I think there can be little doubt but that if the charge of the plate of i8J inches is increased in any ratio whatever as that of xto x — i8|, the charge of the plate of 36 inches will be increased in the ratio of x to x — 36, and that of the plate of 9-3 inches in the ratio of x to x — 9-3 ; therefore if we suppose that the charge of the i8J inch plate is increased in the ratio of 9 to 8, or of i66£ to i66J — i8i, the charges of the three plates should be to each other as 36 x i66| i8£ x i66J , 9-3 x i66£ — , - and ' 130^ 148 I57'2 that is, as 43-37, 19-65 and 9-3, which agrees very nearly with experiment, and nearer so than it would have done if we had supposed the charge of the i8£ inch plate to have been increased in any other proportion which can be expressed in small numbers J. 339] I think we may conclude therefore that the charge of the 12-1 inch globe was increased by the attraction of the undercharged ground nearly in the proportion of 9 to 8, for I think there can be little doubt but that the charge of the globe must be increased thereby in nearly the same ratio as that of the i8£ inch plate, and therefore we may conclude that the charge of the plate D is to the charge which the 12-1 inch globe would receive, if it was placed at a great distance from any over or undercharged matter, nearly in the proportion of 26-3 to 12-1, or, in other words, the charge of the plate D is 26-3, which is rather more than eight times greater than it ought to be if the electric fluid did not penetrate into the glass. I shall speak further as to the cause of this in [Art. 349]. * [Arts. 555, 558, also 443.] t [Art. 649.] J [Art. 652, and Note 24.] 172 Experiments on Coated Plates 340] In order to try the charge of what Jipinus* calls a plate of air, I took two flat circular plates of brass, 8 inches in diameter and J thick, and placed them on the bars Nn and Pp of the machine (Fig. 20), the two plates being placed one over the other, and kept at a proper distance from each other by three small supports of sealing-wax placed between them, the supports being all of the same height, so that the plates were exactly parallel to each other. Care was also taken to place the plates perpendicu- larly over each other, or so that the line joining their centers should be perpendicular to their planes. The lowermost plate communicated with the ground by the wire RS, and the uppermost communicated with Mm by the wire V, just as was done in trying the Leyden vials. I then found its charge, or the quantity of redundant fluid in the uppermost plate, in the usual manner, by comparing it with the plate D, and found it to be to that of D asf.... 341] As I was desirous of trying larger plates than these, and was unwilling to be at the trouble of getting brass plates made, I took two pieces of plate-glass J n£ inches square, and coated each of them on one side with a circular plate of tinfoil 11-5 inches in diameter, and placed them on the machine as I did the brass plates in the former experiment, with the tinfoil coatings turned towards each other, and kept at the proper distance by supports of sealing-wax as before, care being taken that the tinfoil coatings should be perpendicularly over each other. For the more easy making a communication between the circular coating of the lower plate and the ground, and between that of the upper plate and the wire Mm, I stuck a piece of tinfoil on the back of each plate, communicating by a narrow slip of the same metal with the circular coatings on the other side. I then tried the charge as before, the lower plate communicating with the ground and the upper with the wire Mm. As glass does not conduct electricity, it is plain that the quantity of electric fluid in the pieces of tinfoil will be just the same that it would be if the glass was taken away, and the pieces of tinfoil kept at the same distance as before. The distance of the two circular coatings of tinfoil was measured by the same instrument with which I measured the thickness of the plates of glass, and may be depended on to the loooth or at least to the 5ooth part of an inch§. * \Mirn. Berl. 1756, p. 119.] •f The memoranda I took of that experiment are lost, but to the best of my remembrance the result agreed very well with the following experiment. J [Art. 517.] § [See Art. 459, "Bird's instrument," and "dividing machine," Art. 517. Also 594. 595-] Results for plates of air 173 342] In this manner I made the experiment with the plates at four different distances, namely -910, -420, -288 and -256, and when I had made a sufficient number of trials with the plates at each distance, I took off these circular coatings and put on smaller, namely of 6-35 inches diameter, and tried the experiment as before with the plates at -259 inches distance. The result of the experiments is given in the following table : 343*] No. of Experi- ment Distance of the tinfoil coatings Diameter of the coatings corrected for the spreading of electricity Computed charge Observed charge Observed charge by computed charge Diameter of coatings by distance of ditto I 2 •910 •4.2O n-5 18-2 3Q'4 27 «2 1-49 1*^2 12-6 27-4 •3 •288 S7'4 72-1 1-26 4O A •26, and Note 25, p. 416.] 12—2 180 Discussion of results on spreading of charge was prevented from spreading on the surfaces as it should seem by these experiments, or whether it was not rather owing partly to the error of the experiment, and partly to there not being so much difference in the distance to which the electricity spreads on the surface of the glass ac- cording to the different degree in which it is electrified, as I imagined. If the first of these suppositions is true, I do not know how to reconcile it with the theory, except by supposing that the greater the force with which the plate is electrified the less is the depth to which the electricity penetrates into the glass, or the less is the thickness of the spaces in which we supposed the fluid to be moveable. Though it seemed natural to expect that the electric fluid should penetrate further into the glass, or that the fluid within the glass should move through a greater space when the glass was strongly electrified than when weakly, that is, when the force with which the fluid was impelled was great than when it was small, yet it is not strange that it should be otherwise, as it is very possible that the electric fluid may penetrate with great freedom to a certain depth within the glass, and that no ordinary force shall be able to impel it sensibly further, and in like manner it is very possible that the fluid may be able to move with perfect ease in the space ae (Fig. 25) and yet that no ordinary force shall be able to move the fluid at all beyond that space. But it would be very strange that the fluid should penetrate to a less depth within the glass, or that the fluid within the glass should move through a less space when the glass is strongly electrified than when weakly. 363] The reader perhaps may be tempted from this circumstance to think that the reason of the actual charge of the glass plates so much exceeding their computed charge is not owing to the electric fluid pene- trating into the glass, or to any motion of the fluid within the glass, but to some error in the theory. But I think the experiments on the plate of air [Art. 344] form a strong argument in favour of its being owing to the penetration of the electric fluid into, or its motion within the glass, for it appears plainly from these experiments that the electric fluid does not penetrate into the air, and on account of the fluidity of the air it seems very improbable that the electric fluid within the air should be able to move in the manner we supposed it to do within the glass ; whereas it appears plainly from Dr Franklin's analysis of the Leyden vial, that the electric fluid does actually penetrate into the glass. Therefore as this excess of the observed charge above the computed does not take place in the plate of air, where it could not do it consistently with the theory, but does in the glass plate, where it may do so consistently with the theory, I think there seems great reason to think that it is not owing to any defect in the theory, but to some such motion of the electricity as we have supposed. Dielectric influence of temperature \ 8 1 364] I could not find that there was any difference in the proportion which the charge of a glass plate bore to that of another body whether they were electrified positively or negatively*. 365] It was said in Art. [331], that there seemed no reason to think that the charge of the plate D, or of any other of those glass plates was sensibly greater than it would be if the electricity was spread uniformly on their surfaces, whereas the charge of most of the plates of air was found very considerably greater than it would be on that supposition. But this is by no means inconsistent, for according to the first way of accounting for the great excess of the real charge of those plates above the computed, namely supposing that the electricity penetrates into the glass to the depth of T7jj of its thickness, the increase of its charge on account of the electricity being not spread uniformly, should be not greater than it would be if the glass was only \ of its real thickness, and the electricity was unable to penetrate into it at all, and therefore should not be greater than it is in a plate of air in which the thickness is ^ of the diameter, and should therefore in all probability be quite imperceptible. And by Prop. XXXVI [Art. 170], the increase of charge should hardly be much, if at all, greater according to the second or third way of ac- counting for this phenomenon. 366] In order to tryf whether the charge of coated glass is the same when hot as when cold, I made use of the apparatus in Fig. 28, where ABCba represents a short thermometer tube with a ball BCb blown at the end and another smaller ball near the top. This is filled with mercury as high as the bottom of the upper ball, and placed in an iron vessel FGMN filled with mercury as high as FN. Consequently the ball BCb was coated as a Leyden vial, the mercury within it forming the inside coating, and that in the vessel FGMN the outer one. In trying it, I set the vessel FGMN on the wooden bars of the machine represented in Fig. 20, near the end NP, and dipt a small iron wire bound round the wire Mm into the mercury within the tube, so as to make a com- munication between the wire Mm and the inside coating, the outside coating, or the mercury in FGMN, being made to communicate with the ground. It was heated by a lamp placed under FGMN, and its charge was frequently tried while heating by comparing with a sliding coated plate placed on the other end of the wooden bars. When it was sufficiently heated, the lamp was taken away, and the charge frequently tried in the same manner while cooling, a thermometer being dipt every now and then into the mercury in FGMN to find its heat. 367] As it was apprehended that the electricity might spread further on the surface of the glass while hot than while cold, a paper coating * [Art. 463.] f [Art. 556, March 21, 1773. See also Arts. 548, 549, 680.] 182 Experiments on Coated Plates Glass becomes conducting as temperature rises 1 8 3 DBbd was fastened on the tube, so that as the outside coating was made to extend as far as Dd, that is three or four inches above the mercury in FGMN, where the tube was very little heated, and as the inside coating reached still higher, that is to the bottom of the upper ball, no sensible error could proceed from thence. The use of the upper ball was to prevent the mercury within the tube from overflowing when hot. 368] By a mean between the experiments made while the ball was heating and while cooling, its charge answering to the different degrees of heat was as follows. Heat Charge Difference of heat Difference of charge 55 IOO IO2 4 157 222 295 104 116 136 65 73 10 12 20 5 305 141 369] At 295° the electricity passed through the glass pretty freely, but at 305° much faster. It appears, therefore, that the charge of glass is considerably greater when heated to such a degree as to suffer the electricity to pass through than when cold, but that its charge does not begin to be sensibly increased till it is heated to a considerable degree*. 370] On the charges of plates of several different sorts of glass, and also of plates of some other substances which do not conduct electricity, charged in the manner of Leyden vials. The result of the experiments I made on this subject is contained in the two following tables: — TABLE OF GLASS PLATES f. ! Observed Thickness Diameter Ditto corrected Computed charge Observed charge charge by com- puted Specific gravity charge Flint glass ground flat •2115 2-23 2-37 3-32 26-3 7-93 3-279 Ditto a thinner piece •104 2-215 2-385 6-84 52-3 7-65 3-284 Plate glass P •127 2-85 3-02 8-98 71-9 8-01 2-752 W •I72 3-435 3-585 9-34 74-8 8-01 2-787 G •1848 3-575 3-725 9-38 75-5 8-05 2-973 N •106 2-12 2-29 6-18 5'-4 8-31 2-682 0 •106 2-505 2-675 8-44 75 8-89 2-5M Q •076 2-065 2-245 8-29 76-5 9-23 2-504 Crown glass •0682 3-495 3-675 24-76 211-3 8-54 2-537 Ditto another piece •0659 3'43 3-61 2472 208-7 8-44 2-532 Crown glass ground Part of same piece •07 •0693 2-035 3-54 2-215 3-72 8-76 24-96 76-5 215-1 8-73 8-62 } 2-535 Mean of the 10 pieces used in former experiments 8-22 2-678 [Note 26.] t [See Art. 673.] 1 84 Dielectric effects on various substances 371] Plates of other substances*. Thickness Diameter ^.g^ Observed ^charge Obscrvi-.l charge by computed Gum Lac •I25 4-23 17-89 80 4-47 f1 •4845 3'75 3-63 13-5 Mixture of rosin and bees wax. Plate 4 •192 •103 •103 3-355 7-22 4-247 21-89 4-525 24-85 25-2 69 78-9 3'49 3-15 3-18 ^5 •103 1-79 3-89 13 3-34 I1 •303 3-78 5'90 24-5 4-16 Dephlegmated beeswax. Plate -{2 •I2O 12-95 46-1 3-56 (3 •063 2-74 14-90 50-5 3-39 Plain bees wax •119 3-475 12-69 51-3 4-04 372] The coatings of all these plates were circular. In computing the charge of the glass plates, the diameter of the coating was corrected on account of the spreading of the electricity as in the fourth column, the electricity being supposed to spread -07 of an inch if the thickness is -21 and -09 if the thickness is -08, and so on in proportion in other thicknesses. But no correction is made in computing the charges of the other plates, as I was uncertain how much to allow. 373] The method I used in making all the plates of the second table was this. I first cast a round plate of the substance, three or four times as thick as I intended it should be, and rather thinner near the edges than in the middle, taking care to cast it as free from air bubbles as I could. I then heated it between two thick flat plates of brass, till it was become soft, and then pressed it out to the proper thickness by squeezing the plates together with screws f. In order to prevent its sticking to the brass plates, I put a piece of thin tinfoil between it and each plate, and I found the tinfoil did not stick to it so fast but what I could get it off without any danger of damaging them. 374] The heat necessary to melt shell lac is so great as to make it froth and boil; which makes it impossible to cast a plate of it free from air bubbles. The plate mentioned in the preceding table was as free from them as I could make it. It contained, however, a great quantity of minute bubbles, but no large ones. 375] Bees wax melts with a heat of about 145°. If it is then heated to a degree rather greater than that of boiling water, it froths very much, and seems to lose a good deal of watery matter, and if it is kept at this heat till it has ceased frothing, it will then bear being heated to a much higher degree without frothing or boiling. Bees wax thus prepared I call dephlegmated. In order that the plates of dephlegmated bees wax should all be equally so, I dephlegmated some bees wax with a pretty considerable heat, and * [See Art. 674.] f [Art. 514.] Apparent influence of thickness of the plate 1 8 5 suffered it to cool and harden, and out of this lump I made all three plates, taking care in casting them not to heat them more than necessary. I used the same precautions also in casting the plates of a mixture of rosin and bees wax, the proportion of the rosin to the bees wax was forgot to be set down. What are called in the table the 4th and 5th plate of rosin and bees wax are in reality the same plate as the 3rd, only with a smaller coating. 376] It appears from these experiments, first, that there is a very sensible difference in the charge of plates of the same dimensions according to the different sort of glass they consist of, the charge of the plates 0 and Q, which consisted of the greenish foreign plate glass mentioned in [Art. 301], being the greatest in proportion to their computed charge of any, next to them the crown glass, and the flint glass being the least of all. Secondly. The charge of the Lac plate is much less in proportion to its computed charge than that of any glass plate, and that of a plate of bees wax, or of the mixture of rosin and bees wax, still less. But it must be observed that there is a very considerable difference between the three different plates of dephlegmated bees wax in that respect. The same thing, too, obtains in the mixture of rosin and bees wax*. 377] As the proportion of the real charge to the computed is greater in the thick plates than the thin ones, one might be inclined to think that this was owing to the electricity being not spread uniformly. But as the difference seems to be greater than could well proceed from that cause, I am inclined to think that it must have been partly owing to some difference in the nature of the plates. Perhaps it may have been owing to some of the plates having been less heated, and consequently having suffered a greater degree of compression in pressing out than the others. 378] The piece of ground crown glass mentioned in the first of the foregoing tables was made out of a piece of crown glass about Jf of an inch thick, and ground down to the thickness mentioned in the table, care being taken by the workman to take away as much from one side as the other, so that the plate consisted only of the middle part of the glass. My reason for making it was that as there appears to be a considerable difference in the charge of different sorts of glass, it was suspected that there might possibly be a difference between the inside of the piece and the outside, and if there had, it would have affected the justness of the experiments with the ten pieces of glass ground out of the same piece. * 'Note 27, p. 418.] + There are pieces of that thickness sometimes blown for the use of the Opticians. i 86 Theory of multiple dielectric plates But by comparing the charges of the plates of crown glass with those of the two other pieces of crown glass in the table, there does not seem to be any difference which can be depended on with certainty. The experiment indeed would have been more satisfactory if the piece of ground glass and the pieces with which it was compared had been all made out of the same pot. But as it would have been difficult procuring such pieces, and as I have found very little difference in the specific gravity of different pieces of crown glass, and as I am informed it is all made at the same glass house, I did not take that precaution. 379] Let two or more flat plates of different non-conducting substances, as AabB, BbcC and CcdD, (Fig. 29) be placed close together and coated in the manner of a single plate with the coatings Ee and Ff. Let the charge of the plate AabB, supposing it placed by itself and coated in the usual manner, be equal to that of a plate of glass whose thickness is A and whose coatings are of the same size as those of AabB. In like manner let the charge of BbcC be equal to that of a plate of the same glass whose thickness is equal to B, and let that of CcdD equal that of one whose thickness is C. Then whichever of the three ways of accounting for the excess of the real charge of glass plates above the computed we prefer, it is a necessary consequence of our theory that the charge of this compound plate AadD should be equal to that of a single plate of glass whose thickness equals A + B + C, and whose coatings are of the same size as Ee and Ff. 380] In like manner if two or more plates of the same kind of glass are placed together and coated as above, the charge of this compound plate should be equal to that of a single plate of the same glass whose thickness is equal to that of all the plates together. This appears from the following experiments to be the case, for 1st. I took the three plates of glass A, B and C*, and laid them on one another, having first taken off their old coatings and coated the outside surfaces as in Fig. 29 with circles of tinfoil 6-6 inches in diameter. The charge of this compound plate was found to be to that of the three plates D, E and F together as -944 to i. The sum of the thicknesses of A, B and C together is -6309, and the computed charge of a plate of that thickness with coatings 6-6 in. diameter is to that of D, E and F together, allowing in the same manner as in [Art. 328] for the instantaneous spreading of the electricity, as -94 to one. So that the charge of this compound plate is exactly the same that it ought to be according to the foregoing rule. * [Arts. 534, 544, 546, 677.] JE F C f a 6 c d Fig. 29. verified by experiment 187 381] 2ndly, I made a plate of a mixture of rosin and bees wax *, about 8 inches square and somewhat more than -12 thick, and coated it with circles 6-61 in. diameter. Its charge was found to be to that of the plates K, D and E together as 56 to 55, and therefore should be equal to that of a plate of glass of the same kind as K whose thickness is -345 and the diameter of whose coatings is the same as those of the rosin plate, namely 6-61 inches. This plate was then inclosed between the glass plates B and //f, the coatings being first taken off, and the outside surfaces of B and H coated with circles 6-6 inches in diameter. Its charge was found to be to that of K as 7-56 to 8. According to the foregoing rule, its charge should be the same as that of a plate of glass of the same kind as B -634 of an inch thick with coatings 6-6 inches in diameter, and should therefore be to that of K as 7-34 to 8, which is very nearly the same that it was actually found to be. 382] On the charges of such Leyden vials as do not consist of flat plates of glass. These experiments were made with hollow cylindrical pieces of glass, open at both ends, and coated both within and without with pieces of tinfoil surrounding the cylinder in the form of a ring, the breadth of the ring being everywhere the same, and the inside and outside coatings being of the same breadth, and placed exactly opposite to each other. Only as the inside diameter of the two thermometer tubes was too small to admit of being coated in this manner, they were filled with mercury by way of inside coating. The thickness of the glass was found by suspending the cylinder by one end from a pair of scales with its axis in a vertical position, and the lower part immersed in a vessel of water, and finding the alteration of the weight of the cylinder according as a greater or less portion of it was under water J. 383] The result of the experiments is contained in the following table §. Mean thick- ness Mean outside semi-dia- meter Length of coating Com- puted charge Observed charge Observed charge by com- puted Specific gravity Outside diameter by thick- ness Part of a jar of flintl glass ' / •084 1-62 4'4 85-9 717 8-35 3-254 19-3 A cylinder of ditto •0704 •645 9-86 87-I 650 7-46 3-281 9-2 Thermometer tube I. •094 •14 ii I I'D 80-2 7-31 3-098 I'5 „ II. •130 •16 1.5-5 II-I 80-7 7-26 3-243 1-24 Cylinders of green 1 2 bottle glass |j •045 •060 •078 •50 •53 •48 7-16 8-55 7 77-2 76-6 40-8 754 690 353 9'77 9 8-65 2-665 2-664 2-665 n-3 8-8 6-2 [Arts. 548, 678.J [Art. 594.] t [Arts. 552, 679.] § [See Art. 676, and Note 28.] i 88 Curved dielectric plates not different from flat The lengths of the coating here set down are the real lengths. But in computing the charges of the white jar and cylinder and the three green cylinders, these lengths were increased on account of the spreading of the electricity according to the same supposition as was used in computing the charges of the flat plates. But in computing the charges of the thermometer tubes no correction was made, as I was uncertain how much to allow, but as the length of their coatings is so great, this can hardly make any sensible error. 384] It should seem from these experiments as if the proportion of the real to the computed charge was rather less in a cylinder in which the thickness of the glass is \ of the semidiameter than in one in which it is only ^, and most likely rather less in that than in a flat plate, but then it seems to be not much less in a cylinder in which the inside diameter is many times less than the outside, that is, in which the thickness of the glass is almost equal to the outside semidiameter, than it is in the first mentioned cylinder. Nothing certain, however, can be inferred as to this point, as in all probability the four pieces of flint glass used in these experiments and the two flat pieces used in [Art. 370] did not consist exactly of the same kind of glass, as indeed appears from their specific gravities. 385] The three green cylinders, indeed, were all made at the same time and out of the same pot, so that it seems difficult to suppose that there should be any difference of that kind between them*. But then I had no flat plates to compare them with. On the whole, I think we may with tolerable certainty infer that the ratio of the real to the computed charge is not very different from what it is in flat plates, whatever is the proportion which the thickness of the glass bears to the diameter of the cylinder, though it seems to be not exactly the same. * Though it seems not likely that there should be any difference in the nature of the glass of which the three green cylinders consisted, yet I am not sure that there was not, for the inside of the glass, that is, that part which was nearest to the inside surface, was manifestly more opaque and of a different colour from the outside, and the separation between these two sorts of glass appeared well defined, so that the cylinder seemed to consist of two different coats of glass lying one over the other. The distinction was the most visible in those cylinders which consisted of the thickest glass and in the thickest part of those cylinders. The specific gravities, however, do not indicate any difference in the nature of the glass. What was the reason of the above-mentioned appearance I cannot tell. {IV.} WHETHER THE FORCE WITH WHICH TWO BODIES REPEL IS AS THE SQUARE OF THE REDUNDANT FLUID, TRIED BY STRAW ELECTROMETERS*. [From MS. N°. 8: hitherto unpublished. See Table of Contents at the beginning of this volume.] 386] If two bodies, A and B, placed near to each other, are both connected to the same overcharged Leyden jar, and the force with which this jar is electrified is varied, everything else remaining unaltered, the force with which A and B repel each other ought by the theory to be as the square of the quantity of redundant fluid in the jar, supposing the distance of the bodies A and B to remain unaltered. For the quantity of redundant fluid in A is directly as the quantity of redundant fluid in the jar, and therefore the force with which each particle of redundant fluid in B is repelled by A is also directly as the quantity of redundant fluid in the jar, and therefore as the number of particles of redundant fluid in B is also as the quantity of redundant fluid in the jar, the force with which B is repelled by A is as the square of the quantity of redundant fluid in the jar. 387] In order to try whether this was the case, I made use of the following apparatus f . CD (Fig. 31) is a wooden rod 43 inches long, covered with tinfoil and supported horizontally by non-conductors. At the end C is suspended, as Fig. 31. in the figure, the electrometer described in Art. 249, and at the other end D is suspended a similar electrometer, only the straws reached to the bottom of the cork balls A and B, but not beyond them, and were left open so as to put in pieces of wire, and thereby increase their weight and the force with which they endeavoured to close. The lower ends of these * [Title supplied from Cavendish's Index to {the results ofj his experiments. Art. 563.] f [Arts. 563, 567, also Art. 525.] 190 Repulsion with Different Degrees wires when used were just even with the bottom of the cork balls, and were kept in that situation by wax, the wax being cut off even with the bottom of the corks, so as to leave no roughnesses to carry off the electricity. In like manner, when the wires were not used, the ends of the straws were closed up with wax. 388] The proportion which the force with which the balls of this electrometer endeavoured to close when the wires were inserted bore to that with which they endeavoured to close without the wires was thus (A found. The weight of the straw \r> with its ball and centre pin but (7-6 without its wire was found to be V, , grains, and the distance of its center of gravity from the center of suspension was I „ inches, as was found by balancing it on the edge of a knife. Consequently the force with which this straw, when put in its place, endeavours to descend towards the perpendicular, supposing it to be removed to a given distance from (7-6 x 5-36 • WaS as 0.65 x 5-285 ' The weight of the wire inserted was \ grains, and half its length was \ Z 2^ inches, so that as the distance of the bottom of the cork balls (i-oo from the center of suspension was n-i inches, the distance of its center of gravity from the center of suspension was j . inches, and therefore the excess of the force with which the ball endeavours to descend towards the perpendicular when the wire is inserted above that with which it endeavours to descend without [the wire] is to the force with which it (12-05 x 0-87 , [7-6 x 5-36 endeavours to descend without the wire as 4 y lfi.fi -ft-' 2*Q2 or as \ 0 to one. Therefore the force with which the electrometer en- (2'Oo deavours to close when the wires are inserted is to that with which it endeavours to close without the wires as 3-9 to i. 389] E and F are two coated Leyden vials, nearly of the same size. The outside coatings of both communicate with the ground, and the inside coating of E communicates with CD, but not that of F. 390] The way in which I tried the experiment was as follows. I first compared the electrometer C with the electrometer D without the wires, and found that when the jar E was electrified to such a degree as to make D separate \ divisions, C separated \ \ divisions, so that the same of Electrification 1 9 1 (jo degree of electrification which made C separate \ divisions made D separate j f divisions. I then put the wires into the electrometer D, and put the larger of the two vials in the place of E, and electrified E and consequently the rod CD (jo and the two electrometers till D separated \ divisions. (12 The wire by which E was electrified was then immediately taken away and a communication made between E and F, so that the redundant fluid in E and CD and the electrometers was communicated to F. It was found that the electrometer C then separated \ ~ * divisions. (X4 The experiment was then repeated in the same manner, except that the smaller vial was placed at E. It was found that if E was electrified till D separated j divisions, then on making a communication between (jql E and F, C separated < * divisions. (I25 391] From hence we may conclude that if the vials had been exactly equal and E had been electrified till D separated ] ^ divisions, then on (12 making a communication between E and F, C would have separated t divisions. 13* But it appears from the first mentioned part of the experiment, that the same degree of electrification which makes C separate \ ' f divisions (X3s j JO is sufficient to make D without the wires separate \ „ divisions. From I"! whence it appears that if the jars are exactly equal, and one of them is electrified till the electrometer D with the wires separates j divisions, and its electricity is then communicated to the other vial, the electricity will be of that degree of strength which is necessary to make the same electrometer without the wires separate ] . divisions, that is, very (IJs nearly the same as before, or as it did with the wire before the com- munication of the electricity. But if the vials are equal, the quantity of redundant fluid in the first vial, after its electricity is communicated to the second, will be very little more than half of what it was before the communication, for the quantity of redundant fluid in the rod DC and the electrometers is trifling in com- 192 Repulsion with Different Degrees parison of that in the vial*, and consequently it appears that the distance to which the electrometer with the wires in it separates with a given quantity of redundant fluid in the vial is very nearly the same as that to which it separates without the wires when there is only half that quantity of redundant fluid in the vial. Therefore as the force with which the electrometer endeavours to close by its weight when the wires are in is to that with which it endeavours to close without the wires as 3-9 to i, it appears that the force with which the balls of the electrometer are repelled with a given quantity of re- dundant fluid in the vial, is to that with which they are repelled when there is only half that quantity of redundant fluid in the vial as 3-9 to i (supposing the distance of the balls to be the same in both cases), that is, very nearly as the square of the quantity of redundant fluid in the vial, the difference being not more than what might very easily be owing to the error of the experiment. So that the experiment agrees very well with the theory. 392] It was found that if the communication was made between the two vials by a piece of metal, the electricity was diminished so suddenly as to set the straws a vibrating, and it was some time before they stopt, for which reason the communication was made by a piece of moist wood, which, though it communicates the electricity of one vial to the other very quickly, did not do it so instantaneously as to make the straws vibrate much. 393] The electricity of the vial was found to waste very slowly, so that it could not be sensibly diminished during the small time spent in communicating the electricity from one vial to the other and reading off the divisions, so that no sensible error could proceed from that cause. 394] I tried the experiment before in the same manner, and with the same electrometers, except that the straws were not gilt, but only moist- ened with salt. It then seemed as if the force with which the balls of the electrometer were repelled with a given quantity of redundant fluid in the vial was to that with which they were repelled with only half that quantity in the vial as 4 to §. As I suspected that this small difference from the theory was owing to the straws not conducting sufficiently readily, I gilt the straws, when, as was before shewn, the experiment agreed very well with theory. It must be observed that if the straws do not conduct sufficiently readily, the balls of the electrometer will not be so strongly electrified * [In a sentence which Cavendish has scored out in his MS. we read — ] The charge of the two vials together was found to be 2168 inches. The diameter of the rod CD was at a medium about J of an inch. [This would make the com- puted charge of the rod 9-7 inches. — En.] of 'Electrification 1 9 3 and will not separate so much as they ought to do, and in all probability the difference will be greater in the stronger degree of electricity, in which the electricity wastes much faster, than it is in the weaker, and will there- fore diminish the degree of separation more in the stronger degree of electricity than in the weaker, and will therefore make the force with which the balls repel with the stronger degree of electricity appear to be less in proportion to that with which they repel with the weaker degree than it ought to be. C.P.I. 13 PHILOSOPHICAL TRANSACTIONS. VOL. 66, 1776, PART I, pp. 196-225 account of some attempts to imitate the effects of the Torpedo by Electricity Read Jan. 18, 1775. {See Table of Contents at the beginning of this volume.] 395] Although the proofs brought by Mr Walsh *, that the phenomena of the torpedo are produced by electricity, are such as leave little room for doubt; yet it must be confessed, that there are some circumstances, which at first sight seem scarcely to be reconciled with this supposition. 1 propose, therefore, to examine whether these circumstances are really incompatible with such an opinion; and to give an account of some attempts to imitate the effects of this animal by electricity. 396] It appears from Mr Walsh's experiments, that the torpedo is not constantly electrical, but hath a power of throwing at pleasure a great quantity of electric fluid from one surface of those parts which he calls the electrical organs to the other; that is, from the upper surface to the lower, or from the lower to the upper, the experiments do not determine which ; by which means a shock is produced in the body of a person who makes any part of the circuit which the fluid takes in its motion to restore the equilibrium. 397] One of the principal difficulties attending the supposition, that these phenomena are produced by electricity, is, that a shock may be perceived when the fish is held under water; and in other circumstances, where the electric fluid hath a much readier passage than through the person's body. To explain this, it must be considered, that when a jar is electrified, and any number of different circuits are made between its positive and negative side, some electricity will necessarily pass along each; but a greater quantity will pass through those in which it meets with less resistance, than those in which it meets with more. For instance, let a person take some yards of very fine wire, holding the end in each hand, and let him discharge the jar by touching the outside with one end of the wire, and the inside with the other; he will feel a shock, provided the jar is charged high enough; but less than if he had discharged it without * [Philosophical Transactions, 1773, pp. 461-477. Of the Electric Property of the Torpedo. In a letter from John Walsh, Esq., F.R.S., to Benjamin Franklin, Esq., LL.D., F.K.S., &c. Read July i, 1773. Electric resistance of iron wire compared with water 195 holding the wire in his hands; which shews, that part of the electricity passes through his body, and part through the wire. Some electricians indeed seem to have supposed that the electric fluid passes only along the shortest and readiest circuit; but besides that such a supposition would be quite contrary to what is observed in all other fluids, it does not agree with experience. What seems to have led to this mistake is, that in dis- charging a jar by a wire held in both hands, as in the above-mentioned experiment, the person will feel no shock, unless either the wire is very long and slender, or the jar is very large and highly charged. The reason of which is, that metals conduct surprisingly better than the human body, or any other substance I am acquainted with; and consequently, unless the wire is very long and slender, the quantity of electricity which will pass through the person's body will bear so small a proportion to the whole, as not to give any sensible shock, unless the jar is very large and highly charged. 398] It appears from some experiments*, of which I propose shortly to lay an account before this Society, that iron wire conducts about 400 million times better than rain or distilled water; that is, the electricity meets with no more resistance in passing through a piece of iron wire 400,000,000 inches long, than through a column of water of the same diameter only one inch long. Sea water, or a solution of one part of salt in 30 of water, conducts 100 times, and a saturated solution of sea salt about 720 times, better than rain water. 399] To apply what hath been here said to the torpedo; suppose the fish by any means to convey in an instant a quantity of electricity through its electric organs, from the lower surface to the upper, so as to make the upper surface contain more than its natural quantity, and the lower less ; this fluid will immediately flow back in all directions, part over the moist surface, and part through the substance of its body, supposing it to conduct electricity, as in all probability it does, till the equilibrium is restored: and if any person hath at the time one hand on the lower surface of the electric organs, and the other on the upper, part of the fluid will pass through his body. Moreover, if he hath one hand on one surface of an electric organ, and another on any other part of its body, for instance the tail, still some part of the fluid will pass through him, though much less than in the former case ; for as part of the fluid, in its way from the upper surface of the organ to the lower, will go through the tail, some of. that part will pass through the person's body. Some fluid also will pass through him, even though he does not touch either electric organ, but hath his hands on any two parts of the fishes body whatever, provided one of those parts is nearer to the upper surface of the electric organs than the other. 400] On the same principle, if the torpedo is immersed in water, the fluid will pass through the water in all directions, and that even to great distances from its body, as is represented in Fig. i, where the full lines * [Arts. 576, 577, 084, (.87.! 13-2 196 Memoir on the Torpedo as imitated by electricity represent the section of its body, and the dotted lines the direction of the electric fluid; but it must be observed, that the nearer any part of the water is to the fishes body, the greater quantity of fluid will pass through it. Moreover, if any person touches the fish in this situation, either with one hand on the upper surface of an electric organ, and the other on the lower, or in any other of those manners in which I supposed it to be touched when out of the water, some fluid will pass through his body ; but evidently Fig. i. less than when the animal is held in the air, as a great proportion of the fluid will pass through the water: and even some fluid will pass through him, though he does not touch the fish at all; but only holds his hands in the water, provided one hand is nearer to the upper surface of the electric organs than the other. 401] The second difficulty is, that no one hath ever perceived the shock to be accompanied with any spark or light, or with the least degree of attraction or repulsion. With regard to this, it must be observed, that when a person receives a shock from the torpedo, he must have formed the circuit between its upper and lower surface before it begins to throw the electricity from one side to the other; for otherwise the fluid would be discharged over the surface of the fishes body before the circuit was completed, and consequently the person would receive no shock. The only way, therefore, by which any light or spark could be perceived, must be by making some interruption in the circuit. Now Mr Walsh found, that the shock would never pass through the least sensible space of air, or even through a small brass chain. This circumstance, therefore, does not seem inconsistent with the supposition that the phenomena of the torpedo are owing to electricity; for a large battery will give a considerable shock, though so weakly charged that the electricity will hardly pass through any sensible space of air; and the larger the battery is, the less will this space be. The principle on which this depends will appear from the following experiments. 402] I took several jars of different sizes, and connected them to the same prime conductor, and electrified them in a given degree, as shewn by a very exact electrometer; and then found how near the knobs of an instrument in the nature of Mr Lane's electrometer must be approached, Experiments elucidating absence of any sparking 197 before the jars would discharge themselves. I then electrified the same jars again in the same degree as before, and separated all of them from the conductor except one. It was found, that the distance to which the knobs must be approached to discharge this single jar was not sensibly less than the former. It was also found, that the divergence of the electro- meter was the same after the removal of the jars as before, provided it was placed at a considerable distance from them : from which last circumstance, I think we may conclude, that the force with which the fluid endeavours to escape from the single jar is the same as from all the jars together*. 403] It appears, therefore, that the distance to which the spark will fly is not sensibly affected by the number or size of the jars, but depends only on the force with which they are electrified; that is, on the force with which the fluid endeavours to escape from them: consequently, a large jar, or a great number of jars, will give a greater shock than a small one, or a small number, electrified to such a degree, that the spark shall fly to the same distance; for it is well known, that a large jar, or a great number of jars, will give a greater shock than a small one, or a small number, electrified with the same force. 404] In trying this experiment, the jars were charged very weakly, insomuch that the distance to which the spark would fly was not more than the 2Oth of an inch. The electrometer f I used consisted of two straws, 10 inches long, hanging parallel to each other, and turning at one end on steel pins as centers, with cork balls about J of an inch in diameter fixed on the other end. The way by which I estimated the divergence of these balls, was by seeing whether they appeared to coincide with parallel lines placed behind them at about 10 inches distance; taking care to hold my eye always at the same distance from the balls, and not less than thirty inches off. To make the straws conduct the better, they were gilded, which causes them to be much more regular in their effect. This electrometer is very accurate ; but can be used only when the electricity is very weak. It would be easy, however, to make one on the same principle, which should be fit for measuring pretty strong electricity. 405] The instrument by which I found to what distance the spark would fly is represented in Fig. 2 ; it differs from Mr Lane's electrometer } [Art. 604.] Fig. 2. t LArt. 249.] [Art. 329.] 198 Memoir on the Torpedo as imitated by electricity no otherwise than in not being fixed to a jar, but made so as to be held in the hand. The part ABCDEFGKLM is of baked wood, the rest of brass; the part GKL being covered with tinfoil communicating with the brass work at FG; and the part ABM being also covered with a piece of tinfoil, communicating with the brass work at CD. 406] I next took four jars, all of the same size; electrified one of them to a given degree, as shewn by the electrometer; and tried the strength of the shock which it gave; and found also to what distance the spark would fly. I then took two of the jars, electrified them in the same degree as before, and communicated their electricity to the two remaining. The shock of these four jars united, was rather greater than that of the single jar; but the distance to which the spark would fly was only half as great*. 407] Hence it appears, that the spark from four jars, all of the same size, will not dart to quite half so great a distance as that from one of those jars electrified in such a degree as to give a shock of equal violence; and consequently the distance to which the spark will fly is inversely in a rather greater proportion than the square root of the number of jars, supposing them to be electrified in such a degree that the shock shall be of a given strength. It must be observed, that in the last mentioned experiment, the quantity of electric fluid which passed through my body was twice as great in taking the shock of the four jars, as in taking that of the single one; but the force with which it was impelled was evidently less, and I think we may conclude, was only half as great. If so, it appears that a given quantity of electricity, impelled through our body with a given force, produces a rather less shock than twice that quantity, im- pelled with half that force; and consequently, the strength of the shock depends rather more on the quantity of fluid which passes through our body, than on the force with which it is impelled. 408] That no one could ever perceive the shock to be accompanied with any attraction or repulsion, does not seem extraordinary ; for as the electricity of the torpedo is dissipated by escaping through or over the surface of its body, the instant it is produced, a pair of pith balls sus- pended from any thing in contact with the animal will not have time to separate, nor will a fine thread hung near its body have time to move towards it, before the electricity is dissipated. Accordingly I have been informed by Dr Priestley, that in discharging a battery he never could find a pair of pith balls suspended from the discharging rod to separate. But, besides, there are scarce any pith balls so fine, as to separate when suspended from a battery so weakly electrified that its shock will not pass through a chain, as is the case with that of the torpedo. 409] In order to examine more accurately, how far the phenomena of the torpedo would agree with electricity, 1 endeavoured to imitate them * [Arts. 573, bio, 613.] Artificial electric torpedo 199 by means of the following apparatus. ABCFGDE, Fig. 3, is a piece of wood, the part ABCDE of which is cut into the shape of the torpedo, and is i6f inches long from A to D, and lof broad from B to E; the part CFGD is 40 inches long, and serves by way of handle. MNmn is a glass tube let into a groove cut in the wood. Ww is a piece of wire passing through the glass tube, and soldered at W to a thin piece of pewter Rr \ Fig- 3- lying flat on the wood, and intended to represent the upper surface of the electric organs. On the other side of the wood there is placed such another glass tube, not represented in the figure, with a wire passing through it, and soldered to another piece of pewter of the same size and shape as Rr, intended to represent the lower surface of those organs. The whole part A BCDE is covered with a piece of sheep's skin leather. 410] In making experiments with this instrument, or artificial torpedo as I shall call it, after having kept it in water of about the same saltness as that of the sea, till thoroughly soaked, I fastened the end of one of the wires, that not represented in the drawing for example, to the negative side of a large battery, and when it was sufficiently charged, touched the positive side with the end of the wire Ww; by which means the battery was discharged through the torpedo: for as the wires were inclosed in Fig. 4. glass tubes, which extended about an inch beyond the end of the wood FG, no electricity could pass from the positive side of the battery to the nega- tive, except by flowing along the wire Ww to the pewter Rr, and thence either through the substance of the wood, or along the wet leather, to the opposite piece of pewter, and thence along the other wire to the negative side. When I would receive a shock myself, I employed an assistant to charge the battery, and when my hands were in the proper position, aoo Memoir on the Torpedo as imitated by electricity to discharge it in the above mentioned manner by means of the wire Ww. In experiments with this torpedo under water, I made use of a wooden trough ; and as the strength of the shock may, perhaps, depend in some measure on the size of the trough, and on the manner in which the torpedo lies in it, I have, in Fig. 4, given a vertical section of it ; the torpedo being placed in the same situation as in the figure. ABCDE is the trough; the length BC is 19 inches; the depth A B is 14; and the breadth is 13; conse- quently, as the torpedo is two inches thick in the thickest part, there is about 5^ inches distance between its sides and those of the trough. 411] The battery was composed of 49 jars, of extremely thin glass, disposed in 7 rows, and so contrived that I could use any number of rows I chose. The outsides of the jars were coated with tinfoil; but as it would have been very difficult to have coated the insides in that manner, they were filled with salt water. In a battery to answer the purpose for which this was intended, it is evidently necessary that the metals serving to make the communications between the different jars should be joined quite close : accordingly care was taken that the contacts should be made as perfect as possible. I find, by trial, that each row of the battery contains about 15! times as much electricity, when both are connected to the same prime conductor, as a plate of crown glass, the area of whose coating is 100 square inches, and whose thickness is T^,j of an inch ; that is, such that one square foot of it shall weigh 10 oz. 12 dwts. ; and consequently, the whole battery contains about no times as much electricity as this plate*. 412] The way by which this was determined, and which, I think, is one of the easiest methods of comparing the quantity of electricity which different batteries will receive with the same degree of electrification, was this: First of all, supposing a jar or battery to be electrified till the balls of the above-mentioned electrometer separated to a given distance, I found how much they would separate when the quantity of electricity in that jar or battery was reduced to one-half. To do this, I took two jars, as nearly equal as possible, and electrified one of them till the balls sepa- rated to a given degree, and then communicated its electricity to the other; and observed to what distance the balls separated after this communi- cation. It is plain, that if the jars were exactly equal, this would be the distance sought for; as in that case the quantity of electricity in the first jar would be just half as much after the communication as before; but as I could not be sure that they were exactly equal, I repeated the experi- * I find, by experiment, that the quantity of electricity which coated glass of different shapes and sizes will receive with the same degree of electrification, is directly as the area of the coating, and inversely as the thickness of the glass; whence the proportion which the quantity of electricity in this battery bears to that in a glass or jar of any other size, may easily be computed. [See Art. 584. The charge of the first row of jars was 64,538, and that of the whole battery about 481,000 inches of electricity.] Measurement of charge of artificial torpedo 201 ment by electrifying the second jar, communicating its electricity to the first, and observing how far the balls separated; the mean between these two distances will evidently be the degree of separation sought, though the jars were not of the same size. Having found this, I electrified one row of the battery till the balls separated to the first distance, and repeatedly communicated its electricity to the plate of coated crown glass, taking care to discharge the plate each time before the communication was made, till it appeared by the electrometer, that the quantity of electricity in that row was reduced to one-half. I found it necessary to do this between ii or 12 times, or n£ times as I estimate it. Whence the quantity of electric fluid in the row may be thus determined. 413] Let the quantity in the plate be to that in the row as x to i ; it is plain, that the electricity in the row will be diminished each time it is communicated to the plate, in the proportion of i to i + x, and conse- quently after being communicated iij times will be reduced in the _ _i proportion of i to (i + #)"*; therefore, (i + x)"* = 2; and i + x = 2)"*. Whence the value of x may easily be found by logarithms. But the readiest way of computing it, and which is exact enough for the purpose, is this: multiply the number of times which you communicated the electricity of the row to the plate, by 1,444 '> and from the product subtract the fraction £ ; the remainder is equal to - , or the number of times by which the elec- X tricity in the row exceeds that in the plate*. 414] The way by which I estimated the strength of the charge given to the battery, was taking a certain number of jars, and electrifying them till the balls of the electrometer separated to a given distance, and then communicating their electricity to the battery. This method proved very convenient; for by using always the same jars, I was sure to give always the same charge with great exactness; and by varying the number and size of the jars, I could vary the charge at pleasure, and besides could estimate pretty nearly the proportion of the different charges to each other. It was also the only convenient method which occurred to me ; for I could not have done it conveniently by charging the whole battery till an electrometer suspended from it separated to a given distance ; because in most of the experiments the electricity was so weak, that a pair of fine pith balls suspended from the battery would separate only to a very small distance ; and counting the number of revolutions of the electrical machine is a very fallacious method. 415] I found, upon trial f, that though a shock might be procured from this artificial torpedo, while held under water, yet there was too great a disproportion between its strength, when received this way, and * [Arts. 441, 582.] t [Art. 596.] 2O2 Memoir on the Torpedo as imitated by electricity in air; for if I placed one hand on the upper, and the other on the lower surface of the electric organs, and gave such a charge to the battery, that the shock, when received in air, was as strong as, I believe, that of the real torpedo commonly is; it was but just perceptible when received under water. By increasing the charge, indeed, it became considerable; but then this charge would have given a much greater shock out of water than the torpedo commonly does. The water used in this experiment was of about the same degree of saltness as that of the sea; that being the natural element of the torpedo, and what Mr Walsh made his experiments with. It was composed of one part of common salt dissolved in 30 of water, which is the proportion of salt usually said to be contained in sea water. It appeared also, on examination, to conduct electricity not sensibly better or worse than some sea water procured from a mineral water warehouse. It is remarkable, that if I used fresh water instead of salt, the shock seemed very little weaker, when received under water than out; which not only confirms what was before said, that salt water conducts much better than fresh; but, I think, shews, that the human body is also a much better conductor than fresh water : for otherwise the shock must have been much weaker when received under fresh water than in air. 416] As there appeared to be too great a disproportion between the strength of the shock in water and in air, I made another torpedo*, exactly like the former, except that the part ABCDE instead of wood was made of several pieces of thick leather, such as is used for the soles of shoes, fastened one over the other, and cut into the proper shape; the pieces of pewter being fixed on the surface of this, as they were on the wood, and the whole covered with sheep skin like the other. As the leather, when thoroughly soaked with salt water, would suffer the electricity to pass through it very freely, I was in hopes that I should find less difference between the strength of the shock in water and out of it, with this than with the other. 417] For suppose that in receiving the shock of the former torpedo under water, the quantity of electricity which passed through the wood and leather of the torpedo, through my body, and through the water, were to each other as T, B, and Wf; the quantity of electricity which would pass through my body, when the shock was received under water, would be to that which would pass through it, when the shock was received r> J3 out of water, as r> , T , w to ;g~T~T' as m tne nrst case> ^e quantity D which would pass through my body would be the g — -= — ,„ part of the D whole; and in the latter the „ „ part. Suppose now, that the latter torpedo conducts N times better than the former; and consequently, that * [Arts. 599, 600.] f [Arts. 597, 598.] Law of dhnded discharges 203 in receiving its shock under water, the quantity of electricity which passes through the torpedo, through my body, and through the water, are to each other as NT, B, and W; the quantity of electricity which will now pass through my body, when the shock is received under water, and D D out of water, will be to each other as •,=,— ^r,r to 5 JT™; which two D + £\ 1 + W D + 1\ 1 T) quantities differ from each other in a less proportion than -„ — T±W T> and p — j,: consequently, the readier the body of the torpedo conducts, the greater charge will it require to give the same shock, either in water or out of it ; but the less will be the difference between the strength of the two shocks. It should be observed, that this alteration, so far from making it less resembling the real torpedo, in all probability makes it more so; for I see no reason to think, that the real torpedo is a worse conductor of electricity than other animal bodies; and the human body is at least as good, if not a much better conductor than this new torpedo. 418] The event answered my expectation ; for it required about three times as great a charge of the battery, to give the same shock in air, with this new torpedo as with the former ; and the difference between its strength when received under water and out of it, was much less than before, and perhaps not greater than in the real torpedo. There is, however, a con- siderable difference between the feel of it under water and in air. In air it is felt chiefly in the elbows; whereas, under water, it is felt chiefly in the hands, and the sensation is sharper and more disagreeable. The same kind of shock, only weaker, was felt if, instead of touching the sides, I held my hands under water at two or three inches distance from it. 419] It is remarkable, that I felt a shock of the same kind, and nearly of the same strength, if I touched the torpedo under water with only one hand, as with both. Some gentlemen * who repeated the experiment with me thought it was rather stronger. This shews, that the shock under water is produced chiefly by the electricity running through one's hand from one part to the other; and that but a small part passes through one's body from one hand to the other. The truth of this will appear with more certainty from the following circumstance ; namely, that if I held a piece of metal, a large spoon for instance, in each hand, and touched the torpedo with them instead of my hands, it gave me not the least shock when immersed in water; though when held in air, it affected me as strongly if I touched it with the spoons as with my hands. On increasing the charge, indeed, its effect became sensible: and as well as I could judge, the battery required to be charged about twelve times as high to give the same shock when the torpedo was touched with the spoons under water as out of it. * [See Art. 601, 27 May, 1775. Mr Ronayne, Mr Hunter, Dr Priestley, Mr Lane, Mr N[airne].] 204 Memoir on the Torpedo as imitated by electricity It must be observed, that in trying this experiment, as my hands were out of water, I could be affected only by that part of the fluid which passed through my body from one hand to the other. 420] The following experiments were made with the torpedo in air. If I stood on an electric stool, and touched either surface of the electric organs with one hand only, I felt a shock in that hand; but scarcely so strong as when touching it in the same manner under water. If I laid a hand on one surface of the electric organs, and with the other touched the tail, I felt a shock; but much weaker than when touching it in the usual manner; that is, with one hand on the upper surface of those organs, and the other on the lower. If I laid a thumb on either surface of an electric organ, and a finger of the same hand on any part of the body, except on or very near the same surface of the organs, I felt a small shock. In all the foregoing experiments, the battery was charged to the same degree, except where the contrary is expressed: they all seem to agree very well with Mr Walsh's experiments. 421] Mr Walsh found, that if he inclosed a torpedo in a flat basket, open at the top, and immersed it in water to the depth of three inches, and while the animal was in that situation, touched its upper surface with an iron bolt held in one hand, while the other hand was dipped into the water at some distance, he felt a shock in both of them. I accordingly tried the same experiment with the artificial torpedo ; and if the battery was charged about six times as high as usual, received a small shock in each hand*. No sensible difference could be perceived in the strength, whether the torpedo was inclosed in the basket or not. The trough in which this experiment was tried was 36 inches long, 14^ broad, and 1 6 deep ; and the distance of that hand which was immersed in the water from the electric organs of the torpedo, was about 14 inches. As it was found necessary to charge the battery so much higher than usual, in order to receive a shock, it follows, that unless the fish with which Mr Walsh tried this experiment were remarkably vigorous, there is still too great a disproportion between the strength of the shock of the artificial torpedo when received under water and out of it. If this is the case, the fault might evidently be remedied by making it of some substance which con- ducts electricity better than leather. 422] When the torpedo happens to be left on shore by the retreat of the tide, it loosens the sands by flapping its fins, till its whole body, except the spiracles, is buried; and it is said to happen sometimes, that a person accidentally treading on it in that situation, with naked feet, is thrown down by it. I therefore filled a box, 32 inches long and 22 broad, with * As well as I could judge, the battery required to be charged about 1 6 or 20 times as high, to give a shock of the same strength when received this way as when received in the usual manner with the torpedo out of water. [Art. 615.] Shock from Torpedo under various conditions 205 sand, thoroughly soaked with salt water, to the depth of four inches, and placed the torpedo in it, intirely covered with the sand, except the upper part of its convex surface, and laid one hand on its electrical organs, and the other on the wet sand about 16 inches from it. I felt a shock, but rather weak; and as well as I could judge, as strong as if the battery had been charged half as high, and the shock received in the usual way*. 423] I next took two thick pieces of that sort of leather which is used for the soles of shoes, about the size of the palm of my hand; and having previously prepared them by steeping in salt water for a week, and then pressing out as much of the water as would drain off easily, repeated the experiment with these leathers placed under my hands. The shock was weaker than before, and about as strong as if received in the usual way with the battery charged one-third part as high. As it would have been troublesome to have trod on the torpedo and sand, I chose this way of trying the experiment. The pieces of leather were intended to represent shoes, and in all probability the shoes of persons who walk much on the wet sand will conduct electricity as well as these leathers. I think it likely, therefore, that a person treading in this manner on a torpedo, even with shoes on, but more so without, may be thrown down, without any extraordinary exertion of the animal's force, considering how much the effect of the shock would be aided by the surprise. 424] One of the fishermen that Mr Walsh employed assured him, that he always knew when he had a torpedo in his net, by the shocks he re- ceived while the fish was at several feet distance; in particular, he said, that in drawing in his nets with one of the largest in them, he received a shock when the fish was at twelve feet distance, and two or three more before he got it into his boat. His boat was afloat in -the water, and he drew in the nets with both hands. It is likely, that the fisherman might magnify the distance; but, I think, he may so far be believed, as that he felt the shock before the torpedo was drawn out of water. This is the most extraordinary instance I know of the power of the torpedo; but I think seems not incompatible with the supposition of its being owing to electricity; for there can be little doubt, but that some electricity would pass through the net to the man's hands, and from thence through his body and the bottom of the boat, which in all probability was thoroughly soaked with water, and perhaps leaky, to the water under the boat: the quantity of electric fluid, however, taking this circuit, would most likely bear so small a proportion to the whole, that this effect cannot be ac- counted for, without supposing the fish to exert at that time a surprizingly greater force than what it usually does. 425] Hitherto, I think, the effects of this artificial torpedo agree very well with those of the natural one. I now proceed to consider the circum- * [Art. 608.] 2o6 Memoir on the Torpedo as imitated by electricity stance of the shock's not being able to pass through any sensible space of air. In all my experiments on this head, I used the first torpedo, or that made of wood ; for as it is not necessary to charge the battery more than one-third part as high to give the same shock with this as with the other, the experiments were more likely to succeed, and the conclusions to be drawn from them would be scarcely less convincing: for I find, that five or six rows of my battery will give as great a shock with the leathern torpedo, as one row electrified to the same degree will with the wooden one ; consequently, if with the wooden torpedo and my whole battery, I can give a shock of a sufficient strength, which yet will not pass through a chain of a given number of links, there can be no doubt, but that, if my battery was five or six times as large, I should be able to do the same thing with the leathern torpedo. 426] I covered a piece of sealing wax on one side with a slip of tinfoil, and holding it in one hand, touched an electrical organ of the torpedo with the end of it, while my other hand was applied to the opposite surface of the same organ. The shock passed freely, being conducted by the tinfoil; but if I made, with a penknife, as small a separation in the tinfoil as possible, so as to be sure that it was actually separated, the shock would not pass, conformably to what Mr Walsh observed of the torpedo. 427] I tried the experiment in the same manner with the Lane's electrometer described in Art. 405, and found that the shock would not pass, unless the knobs were brought so near together as to require the assistance of a magnifying glass to be sure that they did not touch. 428] I took a chain of small brass wire, and holding it in one hand, let the lowest link lie on the upper surface of an electric organ, while my other hand was applied to the opposite surface. The event was, that if the link, held in my hand, was the fifth or sixth from the bottom, and consequently, that the electricity had only four or five links to pass through besides that in my hand, I received a shock; so that the electricity was able to force its way through four or five intervals of the links, but not more. One gentleman, indeed, found it not to pass through a single interval; but in all probability the link which lay on the torpedo happened to bear more loosely than usual against that in his hand. If instead of this chain I used one composed of thicker wire, the shock would pass through a great number of links; but I did not count how many. It must be observed, that the principal resistance to the passage of the electrical fluid is formed by the intervals of the lower links of the chain; for as the upper are stretched by a greater weight, and therefore pressed closer together, they make less resistance. Consequently the force required to make the shock pass through any number of intervals, is not twice as great as would be necessary to make it pass through half the number. For the same reason it passes easier through a chain consisting of heavy links than of light ones. Transmission of the shock 207 429] Whenever the electricity passed through the chain, a small light was visible, provided the room was quite dark. This, however, affords no argument for supposing that the phenomena of the torpedo are not owing to electricity; for its shock has never been known to pass through a chain or any other interruption in the circuit; and consequently, it is impossible that any light should have been seen. 430] In all these experiments, the battery was charged to the same degree; namely, such that the shock was nearly of the same strength as that of the leathern torpedo, and which I am inclined to think, from my conversation with Mr Walsh, may be considered as about the medium strength of those of a real one of the same size as this. It was nearly equal to that of the plate of crown glass in Art. 411, electrified to such a degree as to discharge itself when the knobs of a Lane's electrometer were at ,0115 inches distance; whence a person, used to electrical experi- ments, may ascertain its strength*. The way I tried it was by holding the Lane's electrometer in one hand, with the end resting on the upper surface of the plate, and touching the lower surface with the other hand, while an assistant charged the plate by its upper side till it discharged itself through the electrometer and my body. There is, however, a very sensible difference between the sensation excited by a small jar or plate of glass like this, and by a large battery electrified so weakly that the shock shall be of the same strength; the former being sharper and more disagreeable. Mr Walsh took notice of this difference; and said, that the artificial torpedo produced just the same sensation as the real one. 431] As it appeared, that a shock of this strength would pass through a few intervals of the links of the chain, I tried what a smaller would do. If the battery was charged only to a fourth or fifth part of its usual height, the shock would not pass through a single interval ; but then it was very weak, even when received through a piece of brass wire, without any link in it. This chain was quite clean and very little tarnished; the lowest link was larger than the rest, and weighed about eight grains. If I used a chain of the same kind, the wire of which, though pretty clean, was grown brown by being exposed to the air, the shock would not pass through a single interval, with the battery charged to about one-third or one-half its usual strength. 432] It appears, that in this respect the artificial torpedo does not completely imitate the effects of the real one, though it approaches near to it; for the shock of the former, when not stronger than that of the latter frequently is, will pass through four or five intervals of the links of a chain; whereas the real torpedo was never known to force his through a single interval. But, I think, this by no means shews, that the phenomena * [Charge of plate = 4100 inches of electricity = 5207 centimetres capacity. Electromotive force = 5-5. See Note 10.] 208 Memoir on the Torpedo as imitated by electricity of the torpedo are not produced by electricity; but only that the battery I used is not large enough. For we may safely conclude, from the experi- ments mentioned in Arts. 402, 406, 407, that the greater the battery is, the less space of air, or the fewer links of a chain, will a shock of a given strength pass across. For greater certainty, however, I tried, whether if the whole battery and a single row of it were successively charged to such a degree, that the shock of each should be of the same strength when received through the torpedo in the usual manner, that of the whole battery would be unable to pass through so many links of a chain as that of a single row*. In order to which I made the following machine f. 433] GM, Fig. 5, is a piece of dry wood; Ff, Ee, Dd, Cc, Bb, and Aa, are pieces of brass wire fastened to it, and turned up at bottom into the Fig. 5- form of a hook, on which is hung a small brass chain, as in the figure, so as to form five loops, each loop consisting of five links; the part G is covered with tinfoil, which is made to communicate with the wire Aa. If I held this piece of wood in one hand, with my thumb on either of the wires Ff, Ee, &c. and applied the part G to one surface of an electric organ, while with a spoon, held in the other hand, I touched the opposite surface, I received a shock, provided the battery was charged high enough, the electricity passing through all that part of the chain between Aa, and my thumb; so that I could make the shock pass through more or fewer loops, according to which wire my thumb was placed on; but if the charge was too weak to force a passage through the chain, I felt no shock, as the wood was too dry to convey any sensible quantity of elec- tricity. The event of the experiment was, that if I charged the whole battery to such a degree that the shock would but just pass through two loops of the machine, and then charged a single row to such a degree as appeared, on trial, just sufficient to give a shock of the same strength as the former, it passed through all five loops ; whether it would have passed through more I cannot tell. If, on the other hand, I gave such a charge to the whole battery, and also to the single row, as was just sufficient to force a passage through two loops of the chain, the shock with the whole battery was much stronger than that with the single row. 434] It must be observed, that in the foregoing machine, each loop consisted of the same number of links, and the links of each loop were stretched by the same weight ; so that it required no more force to impel * The battery, as was before said, was divided into seven rows, each of which could be used separately. j [Arts. 605, 607.] Structure of the electric organ 209 the electricity through one loop than another, which was my reason for using this machine rather than a plain chain. Considerable irregularities occurred in trying the above experiments, and indeed all those with a chain; for it frequently happened, that the shock would not pass with the battery charged to a certain degree, when perhaps a minute after, it would pass with not more than three-fourths of the charge. The irregu- larity, however, was not so great but that, I think, I may be certain of the truth of the foregoing facts; especially as the experiments were re- peated several times. The uncertainty was at least as great in the experi- ments with Lane's electrometer, when the knobs were brought so close together, as is necessary in experiments of this kind. 435] It appears therefore, that if the whole battery, and a single row of it, are both charged in such a degree as to give a shock of the same strength, the shock with the whole battery will pass through fewer loops of the chain than that with the single row; so that, I think, there can be no doubt, but that if the battery had been large enough, I should have been able to give a shock of the usual strength, which yet would not have passed through a single interval of the links of a chain. 436] On the whole, I think, there seems nothing in the phenomena of the torpedo at all incompatible with electricity; but to make a compleat imitation of them, would require a battery much larger than mine. It may be asked, where can such a battery be placed within the torpedo? I answer, perhaps it is not necessary that there should be anything analogous to a battery within it. The case is this; it appears, that the quantity of electric fluid, transferred from one side of the torpedo to the other, must be extremely great; for otherwise it could not give a shock, considering that the force with which it is impelled is so small as not to make it pass through any sensible space of air. Now if such a quantity of fluid was to be transferred at once from one side to the other, the force with which it would endeavour to escape would be extremely great, and sufficient to make it dart through the air to a great distance, unless there was something within it analogous to a very large battery. But if we suppose, that the fluid is gradually transferred through the electrical organs, from one side to the other, at the same time that it is returning back over the surface, and through the substance, of the rest of the body; so that the quantity of fluid on either side is during the whole time very little greater or less than what is naturally contained in it; then it is possible, that a very great quantity of fluid may be transferred from one side to the other, and yet the force with which it is impelled be not sufficient to force it through a single interval of the links of a chain. There seems, however, to be room in the fish for a battery of a sufficient size; for Mr Hunter* has shewn, that each of the prismatical columns of which * "Anatomical observations on the Torpedo." By John Hunter, F.R.S. Phil. Trans. LXIII (1773), p. 485. See Art. 614. c. p. i. 14 2 1 o Memoir on the Torpedo as imitated by electricity the electrical organ is composed, is divided into a 'great number of parti- tions by fine membranes, the thickness of each partition being about the I5oth part of an inch; but the thickness of the membranes which form them is, as he informs me, much less. The bulk of the two organs together in a fish 10^ inches broad, that is, of the same size as the artificial torpedos, seems to be about 24^ cubic inches ; and therefore the sum of the areas of all the partitions is about 3700 square inches. Now 3700 square inches of coated glass T^ of an inch thick will receive as much electricity as 30,500 square inches ,055 of an inch thick * ; that is, 305 times as much as the plate of crown glass mentioned in Art. 411, or about 2f times as much as my battery, supposing both to be electrified by the same conductor; and if the glass is five times as thin, which perhaps is not thinner than the mem- branes which form the partitions, it will contain five times as much electricity, or near fourteen times as [much as] my battery. 437] It was found, both by Dr Williamson f and by a committee appointed by the Philosophical Society of Pennsylvania, that the shock of the Gymnoius would sometimes pass through a chain, though they never perceived any light. I therefore took the same chain which I used in the foregoing experiments, consisting of 25 links, and suspended it by its extremities from the extreme hooks of the machine described in Art. 433, and applying the end of the machine to the negative side of the battery, touched the positive side with a piece of metal held in the other hand, so as to receive the shock through the chain without its passing through the torpedo; the battery being charged to such a degree that the shock was considerably stronger than what I usually felt in the foregoing experi- ments. I found that if the chain was not stretched by an additional weight, the shock did not pass at all: If it was stretched by hanging a weight of seven pennyweights to the middle link, it passed, and a light was visible between some of the links ; but if fourteen pennyweights were hung on, the shock passed without my being able to perceive the least light, though the room was quite dark; the experiment being tried at night, and the candle removed before the battery was discharged J. It appears, therefore, that if in the experiments made by these gentlemen the shock never passed, except when the chain was somewhat tense, which in all probability was the case, the circumstance of their not having per- ceived any light is by no means repugnant to the supposition that the shock is produced by electricity §. * Vide note in p. 200. f " Experiments and Observations on the Gymnotus Electricus, or Electrical Eel." By Hugh Williamson, M.D. Communicated by John Walsh, Esq., F.R.S. Phil. Trans. LXV (1775), p. 94. f [Art. 613.] § [See Note 29, p. 419 and Introduction.] EXPERIMENTS, 1771 { The Journal of Experiments, of which a formal description is contained ante in Art. 217 onward. From MS. N°. 12. See Table of Contents at the beginning of this volume. The footnotes refer back to the formal account of results.} IST NIGHT*. 438] East plate neg[ative] standing east and west. West plate positive] north and south. East plate touched perpendicularly] by wire near midd[le]. West wire bearing against north side of west plate. East 10* 12 12 West 12 a small matter positive. loj nearly same perhaps rather less negative. 10 a good deal more. East plate touched flat near west side. 12 io£ separated] very little, scarce enough to say whether positive or negative, xoj 12 I thought rather more pos. Position of east and west plates reversed. Plates touched by wires as last time. io£ 12 Seemed to separate rather more than before positive. 12 io£ did but just separate. ' 439] 2ND NIGHT. vee EnegaSvee Both plates east and west, wires straight, oj Tin, pasteboard, and tinfoil, each 12 inches; separated a little and equally negative. With paper of 12 inches, in one or two first trials it seemed to separate much the same. Afterwards it did not separate at all, owing, as was supposed, to its being too dry to conduct well, but after being moistened it seemed to separate like the rest. 3j The same things being tried, the corks separated more than before and were positive, and I believe pretty equally. * [Probably the first trials of the apparatus described in Art. 240.] 14—2 2 1 2 "Journal of Experiments, 1 77 1 440] 3RD NIGHT. West East pos. neg. ioj 12 Separated visibly, I guess about i diameter. — Ilf Seemed to separate rather less. — n£ Scarcely separated. paper of 12 Separated much the same as tin of 12. 12 i°i j Nearly the same as in first experiment but of [the] ZIi = I 2 separated rather more. *3i I2 Nearly the same as in first experiment. nf Seemed as if it was rather more. ni Sensibly more than with 12. From the two other nights' experiments it seemed as if the positive bottle electrified the plates sensibly stronger than the negative one: why there was not the same difference this night I cannot tell. Plates east and west. Wires straight. 441] Two pair of large corks were made, each of which was found to separate with the same force. The weight of one pair of them was then made four times as great by the addition of lead to them. The quantity of electricity in 3rd made vial was then compared by means of these corks with that of a glass plate with circular coating 2-4 inches in diameter and about -06 thick, by touching the glass 8 or 9 times the electricity was reduced from strength requisite to make heavy corks separate to that requisite to make light corks separate, or was reduced to J, therefore the vial should contain 12 times as much electricity as the glass plate and wire by which communication was made, which was about 12 inches long*. 442] Three coated plates were made CDF Thickness -06031 -05908 -05914 inches. Diameter of coating 1-82 1-79 i'?85 Therefore square of diameter of \ coating by thickness, or com- 1 54-92 54'23 53'88 puted power of plate J Mean 54-34. (D is cased with cement.) A circular coating 5-39 inches diameter was made to thick plate in place where its thickness seemed -178, therefore its computed power is equal to the sum of foregoing three plates. The proportion of thickness to diameter is nearly the same. Two sliding coated plates were made for trying the foregoing, the trial plates being electrified negatively, the others positively. *• [See Arts. 413, 582.] Trials of charges on coated plates 213 Breadth of trial plate C 12 D — D 13 F 12 C 17 C 16 C 15 D 16 D 17 F 17 separated pos. rather more, scarce at all. same as C. separate neg. do. not at all. scarce sensibly, about as much as C at 16. about as much as C. Therefore F seems to contain about as much electricity as C, and D to contain about TV more. 443] The three foregoing plates Large plate placed close together placed as far asunder as possible The above mentioned large plate [Art. 442] 23 23 23 21 20 30 separated pos. a trifle more rather less than No. i same as No. I. same as No. 2. separated a very little neg. No. i 2 3 All 3 plates together 444] Three coated plates were made on thick plate each 1-8 inches diameter, the mean thickness of glass being supposed -18, therefore the computed power of all three together = 54. 4 separated pos. 5 did not separate, ii 10 12 ii 4 3 WithC sep. neg. did not separate, sep. neg. did not. sep. neg. did not. N.B. The breadth of the sliding plate is not known. 445] Small sliding plate not drawn out 14 x 9-4. Large 19 x 13. Globe hung on silk strings negative. Sliding plates on waxed glass positive. Globe — plate 19 x 13 14 15 16 Globe — plate 14 x 10-4 n-4 12-4 did not separate doubtful separated pos. seemed rather more separated neg. doubtful did not separate [Equivalent*] 157 16-3 16-9 17-4 12 12-6 13-2 * [This column gives the side of a square equivalent to the trial plate. See Art. 465.] 214 'Journal of Experiments ; 1771 Pasteboard circle 19-4 inches diameter hung on silk strings. [Equivalent] Circle — plate 19 x 14 did not separate 16-3 15 did rather doubtful 16-9 16 did very little 17-4 17 did more 18- Circle — plate 14 x 12-7 did 13-2 13-4 did rather doubtful 13-7 14-4 did not 14-2* With circle 1-8 inches diameter on glass -18 thick it separated a little nega- tively with plate 19 x 19, and would most likely not separate at 19 x 21 or 19 x 22 = 20 or 2o£. Therefore quantity of electricity therein most likely is to that of globe as 20-2 to 12-4 or as 10 : 6. 446] Thickness of double plate of glass at centre of circle = -285. Diameter of coating = 1-75. Being tried against small plate not drawn out, separated considerably positive, therefore quantity of electricity therein might perhaps be to that in globe as ii to 18, and therefore its actual power would be to that of thick plate as 6-6 to 18. The computed power is to that of thick plate as 10-8 to 18. A coating 1-45 inches diameter was made on thick plate where the thickness is supposed = -168, therefore computed power = 12-5. This being tried against sliding plates was as follows: Small Large sliding sliding plate 3 4 5 therefore quantity of electricity therein seems to be to that of globe as 13-7 to 12-6, or 17-4 to 16-3, id est as 14 to 13, therefore actual power = n-6 diam. plate In thick plate 1-8 diam.. ^.^ = do. 1-45 8-1 double plate 6-14 TRIALS OF WIRES. 447] The wires placed horizontally and parallel to each other, one end supported by silk, the other by waxed glass. The trial wire consisted of iron wires -14 thick sliding on each other, sup- ported in [the] same manner. * [The charges of the globe and the circle of 19-4 inches appear from these numbers to be as 28-9 : 30-7. The diameter of the tin circle, 18-5, was probably calculated from these experiments so that its charge might be equal to that of the globe. The correct diameter would have been 19 inches.] Equivalent plate Equivalent 13-2 separated negative 2 did not sep. 16-9 137 separated 3 doubtful 17-4 14-2 did not 4 separ. pos. 18 Trials of charges on wires 2 1 5 Single wire -19 inch thick, 96 inches long. Trial wire drawn out 8 inches separated neg. loi did not. 32 did not. 34 separated very little pos. Two wires -r inch thick, 48 inches long, placed 36 inches asunder. Trial wire drawn out 24 inches separated pos. 22 did not. o sep. very little neg. 2 did not. The same wires at 18 inches distance. 174 sep. pos. rather doubtful. 18 did. 16 did. I3J did not. By these it should [seem] as if trial wire required to be drawn out 9 less with the wires at 36 inches distance than with single wire, and 17 less with two wires at 18 inches, whence I should suppose that [the quantity of] elfectricity] in these three cases was as 96, 87 and 79. The trial wire not drawn out was 70 inches, but the straight part of it was only 54. 448] Wires of half that length tried in the same manner with a shorter trial wire. Two wires -i thick, 24 long, at 18 inches distance. Trial wire drawn out r inch sep. neg. 3 very little. 5 rather doubtful. 7 did not. 12 did not. 14 sep. pos. very little. The same at 36 inches distance. [trial wire] at 20 sep. pos. 18 doubtful. 16 did not. ii did not. 9 did not. 7 did a good deal. Wire 48 inches long, touched by end of touching wire, [trial wire] at 9 did not. 7 sep. neg. 20 did. 18 did not. 2 1 6 "Journal of Experiments, \ 77 1 Same wire touched by middle of touching wire. 18 doubtful. 20 did. 9 did not. 7 doubtful. 5 did. 449] From these experiments the quantity of electricity in long wire touched at end -j should / 96 middle I seem | 94 short wires 36 dist. (to | 96 do. 18 - J be as I 87 450] Experiments to determine whether the quant, el. in the large circle was the same whether it was supported on waxed glass* or on silk strings, the trial plates, which were of wood covered with tinfoil, being supported on waxed glass, the large trial plate drawn out to n inches being expressed by L — n, the small ditto by S — n. Large circle supported on silk strings. L — 5 sep. pos. very sensibly if I staid some time before letting down the wires, but scarce sensibly if I did not. L — 4 seemed to separate, but rather doubtful if I staid, but not if I did not. 8 — 5 sep. neg. if I did not stay, but not if I did. L — 5 tried again, sep. very little whether I staid or not. The circle supported on waxed glass. L - 5 sep. very little whether I staid or not. S - 5 sep. very little whether I staid or not. From these experiments there seems no reason to think that there is any sensible difference in the quantity of electricity whether the circle is supported on silk or on waxed glass. I believe the air was moderately but not very dry when these experiments were tried. The next experiment was made the same night. 451] Experiment to determine whether quantity of electricity in coated glass bears the same proportion to that in a non-electric body whether electrifi- cation is strong or weakf. Two pair of corks were made; each separated with rather a less degree of electrification than those used in former experiments. Some lead was then added to those of one pair, so as to double their weight and consequently to make them require 2ce the force to make them separate. The plate of glass used was the double plate called A in the following ex- periments, but with coating 1-78 inches diameter. Tried with light corks. L - 3 sep. a little pos. S — 4 as much neg. * [See Art. 255.] t [See Art. 355.] Trials of charges on disks 2 1 7 Tried with heavy corks. L - 2 separated pos. S - 5f as much neg. If these experiments could be depended on as perfectly exact the coated plate should contain TTgth part more electricity in proportion when electrified with heavy corks than with light, but this difference is much too small to be depended on. 452] Comparison of two tin circles* 9-3 inches diameter with one of 18-5, the tin plates supported on waxed glass and touched in the same manner as wires, the trial plates supported on silk strings. The two circles at 36 in. distance. Side of square equivalent to trial plate. S — i sep. very little neg. S — 2 did not L — i sep. very little L - doubtful 11-26 I5-03 Large circle touched by middle of touching wire. L — 2 sep. very little pos. S - i£ sep. very little neg. 15-57 11-83 Do. circle touched by extremity of touching wire. S — 3^ very little neg. L - 4 very little pos. 12-62 16-64 Small plates at 36 inches distance tried again, sep. very little with L - i, which is the same as before. Small plates at 24 inches. S — 7 very little pos. equivalent to 14-26. Do. at 18 inches S - 5^ very little pos i3'55- 453] A brass wiref, 72 inches long and -19 thick, was then tried, touched by middle of touching wire. L - 2 sep. pos. 15-57 S - 2| very little neg. 12-07 454] From these experiments it should seem as if electricity] in Large circle touched at extremity at middle Two small circles at 36 inches do. at 24 do. at 18 were as 14-63 13-55 I3-I5 12-26 "•55 If the two circles were placed at the same distance from each other in the [Art. 273 and Notes n and 21.] f [Art. 279.] 2 1 8 "Journal of Experiments, 1 77 1 same manner as in coated plates, and were electrified by wires touching their centers perpendicularly, the quantity of electricity should be Large circle 14-02 Two at 36 13-15 24 12-72 18 12-28 The quantity of] elfectricity] in the wire 72 inches long and -19 thick seems to be nearly equal to that in the circle of 18-5 inches. Therefore if we suppose quantity of electricity in a cylinder to be proportional to its length divided by the logarithm •982 1-096 to N. log. I I-2II , length quantity of elec- of -r^- — , M . .. J. -4266 thickness tncity in cyhn- , length der is to that in ofr -, ,. .4761 to tab. log. < —or as £ thickness globe whose dia- of length meter = length J thickness ' of cylinder as and the quantity of electricity therein is to that in a circle of the same dia- meter as •6627 1-526 f- •74 to tab. log. or as 1-704 to N. log. J -8173 1-882 l- 455] A trial plate for Leyden vials consisting of two plates with rosin between. S — 2j sep. neg. rather doubtful L — i pos. rather doubtful Double plate A, computed power = 11-04. L - 3^ sep. a little pos. , S - 4 a little neg. Double plate B, computed power = n-i. L - 3 a little pos. , S - 4^ a little neg. Large circle on silk strings. L — 3^ a little pos. „ S — 4! a little neg. Globe on silk strings. L — 4^ a little pos. j_ S - 4f a little neg. 456] Therefore the quant, el. in these bodies seems as follows : Trial plate 17^ A 18-4 B 18-3 circle 18-5 globe 18-8 * [See Note 12.] Trials of charges in plates of air 219 Diameter of the globe = 12-1, therefore quantity of electricity in globe is to D° in circle of same diameter as 1-56 to i*. 457] Two trial plates were made on a piece of the large bit of ground glass, one 2-37 inches diameter on place where the thickness = 1-80, computed power =31-2; the other 2-57 inches diameter where thickness = 1-90, com- puted power = 34-8. The first is called S the other L. fThe plates of ground glass E and F were each coated on one side with a circle 7-95 inches diameter communicating with coating on the other side. These plates were kept from touching by three bits of sealing-wax. When the coatings were kept at distance -39 from each other this is called plate of air •39 thick, &c. A piece of wire of the same thickness as the other was made to slide thereon. When the plate of air was tried against trial-plate S with wire drawn out 12 inches it is expressed plate air — S + 12 &c. Double plates A and B S + 29^ sep. a little pos. L + 17 sep. a little neg. plate air -343 S + o did not sep. [L] + 3 a little pos. plate air -39 S + 18 sep. a little pos. L + 3 sep. a little neg. same plate air L + 38 sep. pos.^f S + 18 did same. Tried again in afternoon of the same day. A and B 8 + 27 sep. a little pos. plate air -39 S + 19 do. A and B 8 + 29 do. A and B L + 15 sep. a little neg. plate air -39 L + 4 do. 458] The wire not drawn out is about 40 inches, and may therefore contain about 10 cyl. } inc. of electricity, id est, as much electricity as is contained in circle of 10 inches diameter. Quantity of electricity in additional wire is sup- posed to be equal to its length [divided] by 4-4. Both the trial plates together, whose computed power = 66, is equi- valent to 2A + 26 + 80 inches of wire + 45 of additional wire, id est, to 73-4 + 20 + io- 1 = 103-5 inches of electricity, therefore i inch of computed power in the glass of which trial plates are made should be equivalent to 1-41 inches of electricity. By the experiment marked ^f in [457], a difference of computed power in the trial plates = 3-6, which is equivalent to 5-08 inches of electricity, was * [See Art. 653 and Preface.] t [See Art. 341.] J [Probably "circ." See Art. 648.] 22O "Journal of Experiments, 1771 equivalent to drawing out wire 20 inches, which is supposed = 4-54 inches of air, which is as near an agreement as can be expected. By a medium of the experiments, the plate of air -39 thick required wire to be drawn out n£ inches less than A and B, the different experiments varying from 9 to 14, therefore the plate of air contains 2-6 inches more electricity than A and B, id est, it contains 39-3 inches of electricity. The plate of air '343 seemed by i experiment to contain 42-7 of electricity. Therefore plate of air -39 contains 4-94 times more electricity than a circle of same diameter, therefore quantity of electricity therein is to that in circle of same diameter as radius to thickness x 2-06 or quantity of electricity = com- puted power x -243. 459] Four irregular pieces of glass, N, O, P, Q, were coated with circles. The thickness, specific gravity of glass and diameter of circles are marked in [Art. 370], the thickness of glass being found by taking thickness with calipers at center of proposed circle, and finding a part of outside of same thickness and measuring that part by Bird's instrument*; the computed power of all being just 40. The experiments were tried with sliding wire as former[ly]. Tried with large trial plate. N . 2 + o separated constantly neg. + 3 sep. but not certain. P . I + 6 sep. + 9 doubtful. P . I + 0 did not. Q . I + 0 did not. N . again + 3 sep. + 6 rather doubtful. With small trial plates. N . + 9 seP- Pos- + 6 did not. Q +o sep. considerably. O + o sep. considerably, but not so much as Q. P +6 doubtful. + 9 sep. plainly. The afternoon when these were tried, hygrometer corks closed in about 20 seconds. The trial plates being inlarged, tried with large trial plate. P +42 doubtful. + 39 do. + 24 sep. + 28 doubtful. O + o very little, rather doubtful. Q + o did not sep. N +21 sep. a little. P +24 sep. a little. * [Arts. 341, 517.] Charges on coated plates of different substances 221 With small trial plate. P +28 did not. + 36 did. Q 4- o separated rather more. O +9 sep. a little. + 18 sep. about as much as Q at o. N +28 sep. a little. These experiments were tried in the morning. In the afternoon hygrometer corks closed in about 30 seconds. 460] The plate B was coated with a circle 279 inches diameter, computed power = 40, and the plate D was coated with a circle 2-73, computed power = 46. A piece of the white glass was also coated with a circle 2-85 in. diameter where the thickness was -182, computed power 44-6. They were tried with the same trial plates. With large trial plate. D + o sep. neg. + 3 very little, rather doubtful. B +33 very little. N +21 very little. D + 3 rather doubtful. With small plate. B +48 very little. D +15 do. N +39 do. White + 32 sep. a little pos. B +48 did not quite sep. White + 18 nearly same as B. + 24 sep. supposed nearly same as ist time. N +27 sep. very little. + 30 nearly same or rather more than W at 24 with large plate. N +14 sep. a little neg. W + 10 do. B +32 do. W + 8 do. N +14 do. 461] The plate A was coated with a circle 2-16 inches diameter, computed power = 22-6 ; a plate of rosin also, the first which was pressed out after hard- ening, was coated with a circle 2-51, thickness -102, computed power = 2-51*; they were tried with the trial plates described in p. 16 [Art. 457]. Tried with small plate. Rosin + 19 sep. a little pos. A + 36 do. Double plates A & B + 36 do. Rosin + 16 do. * [Should be 61-7.] 222 "Journal of Experiments, \ 77 1 With large plate. Rosin + o sep. very little, rather uncertain. A + 17 sep. a little, rather uncertain. + 14 sep. a little. Double plate + 15 do. 462] Hence it appears that A contains as much electricity as the two double plates. The rosin plate required the wire to be drawn out 18 inches less than them, therefore rosin plate contains 40-7 inches of electricity, and therefore quantity of electricity therein = comp. power x *. A contains 36-7 inches of electricity, and therefore as A and B are of the same kind of glass, the quantity of electricity in them = computed power x 1-62 = -21056, and B contains 64-96 inches of electricity. The whitish glass plate required the wire to be drawn out 27 inches less than B, D requires 33 less and N requires 14 less, P requires 3 more than N, 0 21 less, and Q 37 less than N, therefore W contains 71-2 of electricity, D 72-5, N 68-2, P 67-5, O 73 and Q 76-7. Therefore f D — 1-58 W = 1-60 B = 1-62 P = 1-69 spe. gra. N = 1-71 O = 1-83 Q = 1-92 Quant, el. in.f comp. power 2-973 2-787 2-674 2-752 2-682 2-514 2-504 463] Experiments to determine whether the quantity of electricity in coated plates bore the same proportion to that in other bodies whether el. was weak or strong, or whether it was positive or negative J. On the side of corks was placed plate A with circle 2 inches in diameter, containing 31 inches of electricity. On the other side there was no coated plate, but the wire was drawn out 23 inches and made to rest at further end on the sliding wooden plates. The heavy corks required more than 2ce the force to make them separate than the light ones. With light corks S — o sep. a very little neg. heavy S — 5 sep. a little. L — 5^ sep. a little pos. light L - 7 do. * [So in MS. See note to Art. 464.] f [The "real charges" here given are in "circular inches," and the computed power is 8 times the true value, so that the numbers here given must be multiplied by 8/1-57 = 5-I to compare them with those given in Art. 370. The diameters of the coatings in these experiments are not the same as those in Art. 370 which are taken from Arts. 508-515 and 672.] t [Art. 355.] Whether capacity is independent of charge Tried with the usual corks. With the electricity neg. L - z\ sep. a little. pos. L - 3f do. neg. L — 2j do. According to these experiments the plate should seem to contain 223 4 x 4 _ 7 3 - TFT — 1 th r*orf Part more electricity in proportion when electrified by heavy corks than light, and about ¥Vh more when electrified pos. than neg. 464] A plate -345 inches thick was pressed out of exper. rosin and coated with circle 3-41 inches diameter, therefore computed power = 337. This was compared with double plate B by help of the sliding coated plate mentioned in [Art. 442]. Breadth of coating on sliding plate Rosin 29 sep. a little neg. 22 sep. a little pos. B 20 sep. a little pos. 26^ sep. a little neg. Therefore the plate contains 18-3 x -^y = 20 inches of electricity*. 465] Side of square equivalent to trial plate. Small plate o = 1072 drawn out to i = 11-26 2 = 11-80 -54 3 = 12-35 4 = 12-83 5 = I3-3I 6 = 13-78 \ -48 7 = 14-26 8 = 14-74 Large plate o = 14-49 drawn out to i = 15-03 2 = 15-57 \ '54 3 = 16-10 4 = 16-64 ' 5 = i7-J2 6 = 17-60 7 = 18-08 8 = 18-56 \ -48 9 = 19-04 ro = 19-52 ii = 20-00 * [This would make the specific capacity of rosin 20 x 5-1/33-7 = 3. The numbers in Art. 462 make it 3-3.] [ 224 ] EXPERIMENTS, 1772* {Journal: from MS. N°. 13. See Table of Contents at the beginning of this volume. The footnotes refer back to the formal account of results. } 466] Plan of usual disposition of vials and bodies to be tried &ca drawn in the true proportion and shapef. 8 is the trial plate, B the body to be tried, A and a the vials, mM and rR the touching wires. mM} MN = 41, XT . n rm = 83 inches, \ = 27, „,, N« = 24, AC = 10. rK. ) Kb = 01, Height of body and trial plate above ground = 4-2 below horizontal bar = 3-1 1. All the wires were about -07 thick. [East] [North | [South] \E [West. Scale A] 467] Comparison of quantity of electricity in a tin plate one foot square, according to the different situations in which it was electrified. The trial plate was suspended on waxed glass, the plate to be tried on silk strings J. Description of the different ways in which it was tried. Fore Observation — The plate horizontal and placed as in figure, the touching wire also as in figure but extending to different distances upon the plate [called 2nd and 3rd way in Art. 266]. * [This is the heading of this bundle of the Journal, though the dates up to Art. 475 belong to 1771.] f [See Art. 240.] } [See Exp. in. Art. 265.] Variation of capacity due to connecting wire 225 Bent Wire — the same as former except that the touching wire was bent into the shape rTR, the distance rR remaining as before, the arch rTR being vertical and its greatest distance from the straight line rR being about 15 inches [5th way]. Cross Wire — The same except that the touching wire rR had a cross wire Ee placed horizontally fastened on within 3 inches of r, the touching wire being of the same length as before, and Ee 23 inches long. The touching wire was made to extend so much on the plate that Ee was about i inch distant from the edge of the plate [4th way]. Back Observation — The touching wire removed into the situation xy, the wire yzS being 13 feet 5 inches long and passing nearly perpendicularly over B and at the height of 3'. 7" above it [6th way]. Plate Vertical — The plate hanging in a vertical plane nearly perpendicular to the right line joining it and the vial. The touching wire touched it about the middle of the upper side [ist way]. 468] Sat. Dec. 14 [1771]. Th. 53°. S. H. 19. C. H. + 7*. Back observation. Touching wire extends 4 inches. Side of equivalent square diff. J sum B - 2 sep. a little neg. r£ very little I very little, rather doubtful D 3 do. 12-33 1 2 -O6 1178 8-93 | 2-85 io-35 2 sep. pos. 8-45 Fore observation. Touching wire extends 9 inches over. D - 5 very little, rather doubtful 9-84 4 sep. B - 3 sep. a little 2j very little, rather doubtful 9'39 12-85 12-59 2-75 11-21 Fore observation, wire extends very little over. B - 3 very little, rather doubtful B - 3^ sep. a little D - 5 very little, rather doubtful 12-85 13-10 9-84 [ 3-(>i "•34 4 sep. 9'39 Touched by bent wire near middle. D - 3£ sep. a little 4 very little, rather doubtful B - 3j extremely little 3 rather doubtful 9-17 9-39 13-10 12-85 -3-46 11-12 Th. 55°. Smeaton's Hygrometer i8J. Common Hygrometer + 5. * [Th. — Fahrenheit's Thermometer: S. H. — Smeaton's Hygrometer. See "De- scription of a new Hygrometer by John Smeaton." Phil. Trans. 1771, p. 198. C. H. — Common Hygrometer.] c. p. i. 15 226 Journal of Experiments, 1 6 Dec. 1 77 1 469] Monday, Dec. 16 [1771]. Trials of time in which electricity of stone square, &c. was destroyed. The squares were supported on glass, and a piece of tinfoil about i| inch square fastened on each corner. On one of these pieces was fastened a wire from which the pith balls were suspended. The square was then electrified by applying a charged vial, and then a wire communicating with the wall was applied to the other piece of tinfoil. With slate the corks closed in 10" Portland 15 Bremen 8 gummed glass 5 The stones had been kept in fore room for several days. The gummed glass had been kept in fore room till the gum began to crack. It was then kept in back room for about 5 hours, and then kept in fore room about ij hour. Th. 54. S. H. 22. C. H. + 14. Hygrometer corks closed in 4'. The glass being then wiped they closed in 7'. Being then suffered to stand uncovered lor 2 or 3 hours, the corks closed in 5'. Th. 54. S. H. 2oJ. C. H. n. 470] Tuesday, Dec. 17 [1771]. Th. 53. S. H. 20. C. H. + 9. Experiments of [Art. 468] continued. Plate vertical. Side sq equiv ^ C — 2 sep. a little pos. 10-09 B - 3^ do. neg. 13-10 • 3-14 D — 5 do. pos. 9-84 , Fore observation. Wire extends very little over. C — 2 sep D-5 B — 4 sep . a little pos. 10-09 1 more 9-84 j- 3-25 . a little 13-34 } Fore observation. Wire extending 9 inches over. B-4 C- i ?• I3'3? 3-78 do. 9-56 Bent wire. C- J B-3i do. 9-28 3-82 do. 13-10 Cross wire. B-2 D- 2| do. 12-33 do. 8-69 Back observation. . D- ^\ B-2 do. 8-69 3-64 do. 12-33 Th. 55. S. H. i8J. C.H. + ( J sum n-53 11-71 n-45 11-24 10-51 10-51 Capacities of similar bodies Plate vertical Fore obs. at extremity do. wire 9 inches over Bent wire Cross wire Back observation 471] Wednesday, Dec. 18 [1771]. Th. 50°. S. H. 17^ C. H. + 3. Trials of flat plates of different substances about i foot square*. 227 This night ist night 11-71 - -18 - -0 11-34- ° - -26 - 'IS •47 - '22 — i -20 — I-2O - -99 Tm plate Slate Portland stone Bremen stone Glass coated with tinfoil Pasteboard Glass coated with salt and gum-water Do. with charcoal powder C — 2 sep. about TV in. _ g do - -5f - 2j do. Side of equiv. square diff. 3'73 \ sum "'95 I4'°6} 10-35 / 371 12-20 g_ J ~ ' — i? -5 Z 5j fC — 2 JB - 5 fB - 5 \C - 2 fC - 2\ \B-5i 14-29! 3'7° 12-44 10-59} 3-70 12-44 9-96) I3-82/ 3-86 n-89 13-941 9-96J 3-98 ir-95 13-82} 3-73 "•95 I3-82J 3-73 "•95 10-22") I3-94/ 3-72 1*08 same as first tried Th. 50°. S. H. 17. The subject is continued in Art. 480. 3-86 11-89 C. H. 472] Comparison of two tin circles 9-3 inches in diameter with one of 18-5 ; the two circles being placed in vertical planes parallel to each other and per- pendicular to the vertical plane joining their centers and the trial plate, their centers being both in the above-mentioned plane f. There was a distinct touching wire to each plate meeting each other at R, the two wires were kept asunder by a slender glass tube, and about i inch of the end of the wires bent at right angles horizontally in order to touch the plates by being let fall on their edges. When the large circle was tried, this [Exp. iv, Art. 269.] f [Exp. v, Art. 273.] 15—2 228 journal of Experiments, 30 Dec, 1771 double touching wire was removed and a single one used in its room, which was sometimes fastened to the middle of the glass tube, and sometimes used without it, as will be expressed. The height of the top of the circles above floor = 4'. 3". The center of the large circle when that was used, or the middle point (of i(\" / // / " -J from lvial ^ (middle of trial plate) ' The circles were suspended by silk strings. The length of the touching wires for the circles was 36 inches. 473] Monday Dec. 30 [1771]. Th. 50°. S. H. 18. Two small circles at 18 inches from each other. Equivalent diff. J sum Proportion B — S scp. about TV 13-821 3-47 12-08 i-ooo C - -2\ do. 10-35} The same at 26 inches distance. C — 4 do. 11-07) B-6J do. 14-51} 3'44 I2'79 I'°59 at 36 distance. C - 4^ do. 11-31 B - \ do. 11-37 4'°8 13-38 1-108 A — 14^ do. 15-42 Large circle, touching wire being fastened to glass tube. A - 17* do. 16-04 B- 3 do. 12-85 4'°9 I4'89 I-233 Do. without glass. B - 3 12-85 4-00 14-80 1-233 A - 17^ 16-94 The Proportions by theory, vide P. 14 of calculations*, are as follows f. Calculation Experiment .Small circles at 18 i-ooo i-ooo at 26 1-044 I'°59 at 36 1-074 1-108 single plate 1-160 1-233 474] The same experiments repeated in the same manner except that the distance of the center of the large circle, or of the middle point between the * ["P. 14 of Calculations" refers to a rough calculation in parcel No. 6, which is an early form of Props. XXIX and XXX. See Arts. 140-143. "P. 14" contains the following remark, which fixes its date after Art. 456, "By exp. P. 15 [Art. 456] quant, el. in circle is to that in globe of same diam. as i : 1-56 :: £ : -78, therefore = -78." Here n is the reciprocal of p in Art. 140.! 2 + 2W f [See Art. 68 1 and Notes u and 21.] Capacity affected by proximity to other bodies 229 centers of the small ones, was 5'. 3" from the vial, and the middle point of the trial plate 8'. 2" from vial, and that some boards forming a floor about 4 or 5 feet square was placed under the circles 14 inches from the ground, and that a perpendicular bar of the same breadth as those of the frame was placed 5 inches nearer to the circles than the other, so that the distance of the center of the large circle from the vial and the ground, and also the distance of the nearest small circle from the perpendicular bar when they were placed at 36 inches distance, were diminished in about the ratio of 2 to 3*. 475] Tu. Dec. 31 [1771]. Th. 51°. S. H. 18. Small circles at 18 inches distance. B — 6 sep. C - 4 do. 14-29 11-07 3- Do. at 26. B- B- isep. 8 do. 11-51 I5-I7 3' Do. at 36. B- A- 2 do. 15! 12-33 16-07 3' Large circle with glass. A- B- i8f 5 17-54 13-82 3- Do. without glass. B- A- 5i 20 14-06 18-11 4" Th. 53- S. H. 15*. 12-68 Proportion I-OOO I3-34 I-052 I4-20 I-I2O 15-68 1-237 16-08 1-268 476] Comparison of 2 wires 3 feet long and Tlff inch in diameter with i of 6 feet long and -185 in diameter f. The wires were placed parallel to each other, horizontal and perpendicular to the horizontal bar. They were touched almost close to one extremity by the same wires and in the same manner as the circles in the former experiment. That end of the wires near the part which was touched was suspended by silk, the other end was supported on waxed glass. The distances were the same as in [Art. 472]. 477] Fr. Jan. 3 (1772). Th. 50°. S. H. rgj. C. H. + 2. Short wires at 18 inches distance. L — 4 sep. 11-07 B-8 do. 15-17 at 24. A I 14* £15 13-12 3-64 13-33 Proportion -847 -860 [Art. 275.] f [Exp. vi, Arts. 279 and 683.] 230 ^journal of Experiments, 3 Jan. 1772 Short wires at 36 inches distance. Proportion Single wire without glass. B- 3isep. A - 191 do. A -19 sep.less B- 3isep. 13-10 A - 191 do. 17-89 B- 4 do. 13-34 Two wires at 18, repeated. Th. 52°. S. H. 18. C. H. 44. By theory [Art. 152], the proportions should be between those of i -9323 -9053 -8827 and i -8926 -8597 -8353 478] Comparison of different substances tried in the usual manner*. The large tin circle suspended by silk. B- 4jsep. [Article] B-^*-* ,£. „ I5.85 w B- 5 do. The globe suspended on silk. A: 4 £ %% ™ ** w Coated double glass plate Af. A -20 do. 18-11 fr t] B - 5J do. 14-06 Double plate B. ":/„ r 3S «•« "•* w The large circle supported on waxed glass. B:26} A tin plate 15-5 square, on do. B- 5 A - 20 A tin plate 17-9 by 13-4, on do. £~2°, l8'^ 4-05 16-08 [7] B - 5i 14-06 * [See Arts. 653, 654, 682.] f Double plate ground glass A, thickness -3, diam. coating 1-82, comp. power 11-04. - B, - -31.- 1-855. - "-I- - 5 13-82 6 A - 20 18-11 Capacities of different bodies compared 231 A tin cylinder 35-9 inches long and 2-53 in diameter, on do. [Art.] l~,l Sg 3-83 .6-64 n A tin cylinder 54-2 long and -73 in diameter, on do. A - igi 17-89 B- 5 13-82 4'°7 I5'85 @ Brass wire 72 inches long and -185 in diameter, on do. B — 44 13-58 4-08 15-62 [iol A - 19 17-66 Th. 50°. S. H. i6J. C. H. -8*. 479] According to the 5th and 6th articles of last .page, the quantity of electricity in the square is to that in a circle of the same area as 1-08 to i, and that in square to that in oblong of the same area as -991 to i. By comparing the 2nd article with the 3 last, the quantity of electricity in /"thick cylinder I thin cylinder may be to that in a globe whose diameter equals the length of [wire cylinder length I io§ contains as much electricity as plate F of Naime. Therefore i division on 2nd sliding plate contains -Jf I of the electricity 3rd in plate D, E, F, or G of Nairne. 7 inches of additional wire answers to r inch of computed power in plates of Nairne. 2 trial plates were made for the plates I, K, L and M of Nairne out of 2 of the ground plates first got from Nairne. The dimensions of the coating of the small one was about 3-3 by 3-1, and that of the large one 3-7 by 3-4, the thickness of glass unknown. Two trial plates were also made for the plates A, B and C of Nairne out of the old ground plates E and F. F, the smallest, was 5-7 square, and E was 6-3 by 6 nearly. Two trial plates were made of crown glass for the plate H of Nairne, the small one 5-7 by 5-1, the other 6 by 5-9. 489] Tuesday, Feb. 4 [1772]. Th. 47°. S. H. 17. C. H. - 5. Trial of plates D, E, F and G of Nairne, and of the 2 double plates, the plates E, F and G being cased with cement : tried by means of additional wire f. * [See Art. 297.] f [Art. 318.] Capacities of condenser plates compared 237 Length of Plates additional Trial tried wire plate D q B G o B F o B G 2 B 2 doublel plates / 9 B D 9 B D 16 A 2 double! plates / 18 A G 9 A F 7 A G 7 A 2 double plates y I If let down and up immediately, sep. neg. about -Jy inch. If it rested at bottom 2" or 3", rather less, do. do. do. do., but closed sooner. do. sep. about ^ pos.; much the same if it rested at bottom 2" or 3". do. if let down and up immediately, rather more if resting at bottom 2 or 3". do. do. do. do. 490] Feb. 4 continued. Comparison of the three plates E, F and G together with the plates I, K, L and M, tried by the two above-mentioned trial plates and the i8' and 2n" sliding plate*. Sliding Plates tried plate and breadth of coating Trial plate ; thereon E(F, G Is1 9 S I 24 E, F, G 9 M — 16 K 24 L 24 K I E, F, G M E, F, G 2nd 17 17 15 7 9 7 sep. pos. about T\p D° if resting 2 or 3". sep. rather less than ^v, rather more if resting 2 or 3". same as before. sep. about ^. D° if resting 2 or 3". DO DO Large. Sep. neg. about y1^: rather less if resting 2 or 3", the separation more after a little time than at first, and closed very slow. DO D" DO DO DO [Art. 318.] 238 "Journal of Experiments, Feb. 5, 1772 491] Trials of the same kind as those in [Art. 487]. Large trial plate for the experiments of this page — balls closed in 13" Small do. Trial plate A B E of Nairne F G D Double plate B A M of Nairne I K L — 10 or 15 15 15 20 20 20 5 5 7 20 20 35 25 492] Wed. Feb. 5 [1772]. Th. 49°. S. H. 17^. C. H. 4$. Comparison of I, K, and L together, with A, B and C by means of the trial plates E and F, and of A, B and C together, with H by means of the two crown glass trial plates*. sep. about ^ pos. Much the same if resting at bottom 2 or 3". • sep. i diam. neg. Much the same if kept at bottom 2 or 3". Kept increasing for a short time, do. do. the same, only rather less if resting at bottom 2 or 3". the same as before, the same as before. Sliding Plates plate and Trial to be tried breadth of plates coating F ? I, K, L 2 ml 8 B 3r<1 8 D« A 3r,l 8 D° C DO D° I, K, L 2n(1 10 D° C 3r" 8 D° E s C 3r" 10 A 3r(1 10 { B ii K, L 6 t C ii t I, K, L — 6 t * [Art. 318.] Capacities of condenser plates compared 493] Comparison of A, B, C together, with H*. 239 Plates to be tried Sliding plate and breadth of coating A.B.C 3'" 18 H DO A, B,C D° H D° H 3r" 6 — 24 H 3r• , •?!• supposed Uac li- I" wax J. rosin 955 i -06 wax at Ist place -0130 2nd -0123 rosin -0131 lac '0143 * [See Art. 343. The inches of electricity are circular inches, and to reduce them to globular inches must be multiplied by 12-1, the diameter of globe, and divided by 18-8, the diameter of a circle which has the same charge. The com- puted power here is the square of the diameter divided by the thickness, and this must be multiplied by 8 to get the computed power as denned in Art. 311.] •f [With the "usual degree of electrification" Lane's electrometer discharged at •04 inch. See Art. 329. The electric strength of wax, rosin, and lac is therefore about three times that of air.] 254 "Journal of Experiments^ y an. 1773 521] The quantity of electricity in a Florence flask tried with and without a magazine. The quant, el. in a Florence flask was tried by putting it on negative side, and some of the jars &c. on the other, the battery of 6 Florence flasks being used instead of the jars. With the i8', 2nd, 3rd jar with sliding plate 6 — 40 sep. neg. rather more than i diam. 4 jars + white cyl. sep. a little pos. i, 2, & 3 jars + 6 — 48 D° neg. Sat. Jan. . Th. 56. N. 19. The same thing tried again in same manner with the 4 jars and white cyl. sep. about i diam. pos. with i, 2, & 3 jar D° neg. 4 jars + white cyl. D° pos. Tried without mag. With 4 jars and white cyl. sep. at Ist about i diam. but soon closed, with i, 2, & 3 jar sep. a good deal neg. with i, 2, & 3 jar + wh. cyl. + gr. cyl. 2 after a time sep. near i diam. With 4 jars and the 2 cyl., sep. at Ist a good deal, after a time sep. about I diam. Sun. Jan. Th. 56. N. 21. A coating of tinfoil to a part of the Florence flask out of water. With 4 jars + wh. cyl. + gr. cyl. 2 sep. rather more than i diam. The case was much the same whether wire was suffered to rest at bottom 2" or 3", or less than i". With 4 jars + wh. cyl. + 6 — 16 sep. less than i diam. With i, 2, & 3 jars + 6 - 16 D° neg. Without mag. With 4 jars sep. a little neg., increased after a time to full i diam. By the Ist night's experiments the flask contains 12126 inc. el. by the 2nd 11694 and by the 3rd "495 Without magazine by 2nd night it contained 13205 inc. el. The true quantity is supposed 11700 522] Computed power of above flask. The diameter of the flask at the surface of the water in tin pan on Saturday was 1-7; the height of that part above the bottom 5-1 ; the height of top of tinfoil coating above bottom 6-55; and the diameter of that place, -68; and the cir- cumference at the widest part 13. The weight of that part under water was i .. 2 .. 7*, and that of the part between that and the top of coating was 2 .. 4. * [Troy weight.] Residual charge : comparison of resistances 255 If the spheroid agdm does not differ much from a sphere, and ab does not differ much from ad, the surface afea is nearly equal to the circumference of gm x ab x - — j^— , ^surface the -! thickness of the part under water was Icomp. pow. ( 62 (-5-3 | -0127, and that of the part above J -0179, and the 1 6200 1.375 comp. power of the whole part below top of coating 6575, the specific gravity of the glass being supposed 2-68. Therefore inc. el. by comp. pow. = 1-78. 523] As it appears from the above experiments that the Florence flask contains more electricity when it continues charged for a good while than when charged and discharged immediately, it was tried whether the white globes would do the same. This was done by putting the globe 3 on positive side and the white cylinder and trial plate 6 on negative side, and first charging and discharging them in the common manner, and then discharging the magazine and charging it again, while the end c of the wire Cc rested on Bb, while the end C was prevented from resting on A a by a silk string. When the magazine was charged, and had continued so for a little time, the end C was let down on Aa and the wire Cc immediately drawn up again so as to discharge the globe &c. The event was as follows, in common way, wh. cyl. + 6 — 20 sep. near i diam. pos. globe elect, first, +6-24 D°. in common way, +6 — 47 D° neg. globe elect, first, +6-48 D°. By these experiments the globe contains 45 inc. el. or about ^1T less when electrified in the common way than when charged before the rest, which is as much as is contained in i inch in length of the uncoated part of the neck (the whole neck being ij inches), so that supposing the experiment exact it seems as if the globe contained rather more electricity when it continued charged a considerable time than when charged and discharged immediately *. 524] Diminution of shock by passing through different liquors^. Tried in November [1772]. The electricity was made to pass through 42 inches of a saturated solution of sea salt in a thermometer tube of a wide bore, and the two jars charged in * [These phenomena are connected with the "residual charge." A careful in- vestigation of them has been made by Dr Hopkinson, Phil. Trans, vol. 167 (1877), P- 599'] {Reprinted in his collected Scientific Papers.} •f [This is the first experiment on electric resistance.] 256 Journal of Experiments, Nov. 1772 such manner as that a slight shock should be felt in [the] elbows : it was then made to pass through rain water in a tube of a rather greater capacity, and the electricity made rather stronger. The wires were obliged to be placed within •18 of each other in order to feel the shock in the same degree. Therefore the electricity meets with more than 230 times the resistance in passing through rain water than salt. The above jars were electrified till light paper cylinders began to separate, and the shock made to pass through a tube filled with rain water. The wires were obliged to be brought within -48 inches of each other in order that the shock should be just felt in the elbows. When the same tube was filled with saturated solution of sea salt diluted with 29 its bulk of rain water, a much greater shock was felt when the wires were at i6J inches from each other. Therefore electricity meets with much more than 34 times the resistance from rain water than from a saturated solution of sea salt with 29 of rain water. When the same tube was filled with kitchen salt in 1000 of rain water, the wires must be brought within 4-4 inches; with pump water within 2 inches, and with spirit of wine almost close ; therefore the resistance of Pump water } . (4! „ ., . ... } is < " less than that ot ram water. S. salt in 1000 of ram water) [9 Mon. Nov. 16 [1772] with straw electrometer. With sea water a shock was felt when the wires were igj inches distant; with rain water when they were at about -19 inches distant. Therefore resistance of sea water is about 100 times less than that of rain water. G A 525] Exper. Whether force with which two bodies repel is as square of re- dundant fluid in them*. Tried by pith balls hung by threads. A and B are the coated plates A and B, the bottoms of which communicate with the ground, D and d are two bits of wood resting on them, supporting the pith balls E and e. G is a bit of wood for making a communication between them. The wire for electrifying the plates rests on B, and is so contrived that when that is lifted up the wood G is let fall on the plates. The pith balls E had bits of wire made to run into them in order to increase their weight. A paper with divisions was placed 6 inches behind the pith balls and a guide for the eye 30 inches before them. * [Arts. 386, 563, 567.] Relation of Repulsion to charges 257 Tu. Oct. 26 [1773]. Th. 60. Com. - 6J. N. 2i£. One of the balls E with its string weighed -5 gr. and its wire 1-4, the other •6 gr. and its wire 1-7. The two balls and strings together — the weight of one of the strings, weighed 1-05 gr., the weight of the string about -05, the weight of the two wires together was 3-2. When the wires were taken out of the balls E, and a communication made between the two plates, while the electrifying wire rested on B, then when balls r sep. ] , balls E sep. -! U-o8 (.!•] •14 The wires were put into balls E and the jars electrified while the electrifying wire rested on B. When the balls E sep. 1-3 inc. the electrifying wire was lifted up and the electricity of the plates taken away, immediately after which the electrifying wire was let down and immediately drawn up again when the balls e separated to 1-44. The electrifying wire being then let fall on B and suffered to remain, the balls E separated to 1-14. The jars were charged, and the electricity diminished by alternately drawing up and down the electrifying wire and discharging the electricity of the plates till the balls e separated to 1-2; then letting the electrifying wire rest on B, the balls E separated to 1-08. Wed. morn. The new heavy electrometer made with large wood ball and pith ball separates when the balls E separate to 1-52, and new light electrometer separates when the balls e separate to 1-44. When balls e separate to 1-44, balls E separate to -96. The new heavy electrometer above mentioned separates about J or J inch when old light cylinder electrometer just separates. Result of these experiments. Balls E without weight separate .-\ farther than balls e with the same degree of electrification. 1*22 If balls separate with i part of redundant fluid, balls of \ weight separate with A part of redundant fluid. 1-25 If balls of given weight separate 1-5 with given degree of electrification, balls of 4 times weight separate -96, therefore if balls of given size are electrified in given degree, the distance to which they separate is inversely as -- power of their weight. Therefore, in last paragraph, if balls of given weight separate J , balls of I*Q 1*22 * their weight will separate to _ , therefore if balls of given weight with c. p. i. 17 258 Journal of Experiments, Oct. 1773 given quantity of redundant fluid separate to given distance balls of , that weight separate to same distance with half that quantity of redundant fluid. 526] Whether the charge of plate E bears the same proportion to that of another body whether the electrification is strong or weak: tried by machine for Ley den vials. Wed. Oct. 27 [1773]. Th. 61. Com. 8J. N. 2oJ. Plate E of Nairne on neg. side against sliding tin plates placed at end of long wire [20 observations]. Result. Therefore with light electrom. the plate E is balanced , 14-03 + 8-17 by a square of - — ' + x = n-i + x, IO-OQ + 12-33 with heavy el. by - 2 - + x = 11-21 + x, 10-50 + 11-23 — + x = 10-91 + x. 2 The plate E is balanced by 37 inc. el. 527] Plain wax and 3rd dephlegmated wax with E + F and 5th rosin with double plate A and B. Also small ground crown with D + E 4- F, and large do. with C. The coatings were taken off from 4th rosin, and coatings 1-79 inc. diam. put in their room. This is called 5th rosin. A plate of dephlegmated bees wax was also made [-120]* inc. thick and coatings put on 3-525 inc. in diam. This is called 3 dephlegmated bees wax. A plate of plain bees wax was also pressed out [-119] * inc. thick and coatings put on 3-475 inc. diam. A piece of thick crown glass was procured from Nairne about -26 thick and ground down equally on both sides to about -07 inc. thick. Two circular coatings were put on, one 3-54 inc. in diam. the other 2-035. Wed. Jan. Th. 56. N. 27 £ [16 observations]. 528] K, L and M compared with D + E + F at distance and close together; also large ground crown with C and small one with D + E + F; also 3rd dephlegmated wax and plain wax with E + F; also 5th rosin with double B. Friday, Jan. 29 [1773]- Th. 3$. N. i6£. Tried with middle sized cork balls and a new white large trial plate [18 observations. Art. 656]. 529] K + L + M compared with A, B, and C; also A + B + C with H. Sat. Jan. 30 [1773]. Th. 50^. N. i6£. [20 observations. Art. 657.] * [These measures are left blank in the Journal. I have supplied them from Art. 371.] Law of partition of charges 259 530] K + L + M compared with B with electrification of different strengths. Sun. Jan. 31 [1773]. Trial plate F enlarged. [14 observations with light and heavy electrometer alternately. Arts. 656, 658.] 531] K + L + M with A, B, and C; also D + E + F with K, L, and M; also small crown with K, L, and M; and D + E + F and large ground crown with A, B and C and K + L + M. Mon. Feb. i [1773]. Th. 48. N. 16. [20 observations. Art. 657.] 532] On light visible round edges of coated plates on charging them*. Mon. Feb. i [1773]. Th. 48. N. 16. Some coated glass plates were placed on pos. side and electrified in usual manner in dark room in order to see whether any light was visible round their edges. With the plates M and L of Nairne and with the small ground crown glass a light was visible round the edges when the light electrometer was used, and nearly equally so with the large ground crown glass. The light seemed of the 2 rather stronger with the plates F and A of Nairne; no light was visible when light electrometer was used, but it was with the heavy electrometer. 533] Crown A and C and large ground crown with C; also 3rd dephlegmated wax, plain wax and sliding plate 3 with E + F; also 2 double plates with E, F, and D. Mon. evening. Th. 53. N. 15. [25 observations. Art. 655.] 534] Charge of the triple plate— the three plates A, B and C placed over each other, with bits of lead between coatings]. The three plates A, B and C were placed over one another with the coatings nearly perpendicularly over each other, with bits of lead between them, so as to keep them at the distance off inches from each other. This compound plate was tried in the usual manner. Tu. Feb. 2 [1773]. Th. 50. N. 17$. [9 observations. Art. 677.] 535] Whether the charge of plate D bears the same proportion to that of another body whether the charge is strong or weak: tried with machine for Leyden vials§. [Art. 664.] Th. Feb. 4 [1773]. Th. 48^. N. 13*. Tried with smallest cork balls and the light straw balls as electrometers'. The plate D placed on the neg. side and the sliding tin plates at 23^ inc. dist. from wire. 17 — 2 * [Art. 307.] f [A""*- 38°-] } [So in MS.] § [Arts. 356, 664.] 260 ^Journal of Experiments, Feb. 1773 Div. on electrometer] * Div. on sliding plate Side square equiv. to trial plate Diff. Sum. I + 3 2-2 4 17 sep. neg. D° pos. 10-09 16-70 6-61 26-79 Tin plates at 17^ inches dist. i + 3 2 5 D° pos. D° neg. 17-42 n-54 5-88 28-96 3+ i 3 Ti 4 15 D° neg. D° pos. 12-06 15-68 3-62 27-74 i + 3 4 *8£ 2 5 D° pos. D° neg. 17-42 11-54 5-88 28-96 3+ I 3 ij DO 12-06 ^88 28-00 4 X5i D° pos. 15-94 The same repeated with neg. elect. 4-15 3 4 2 4i 4 i7i D« D° neg. D» D° pOS. 15-68 12-06 11-31 16-94 3-62 5-63 27-74 28-25 536] H with slits and a crown glass with oblong coating compared with white cylinder; also A and C with slits compared with B. The coatings were taken off from the plates A, C and H, and oblong coatings with slits put in their room; an oblong coating without slits was also put to a piece of crown glass, vide Measures [Art. 593]. Tu. Feb. 9 [1773]. Th. 50. N. 12^. 50 observations. [Art. 660.] These plates were tried with middle cork balls. Spreading of el. on surf. A & C. Balls at first sep. wider. Closed in about 10". B. D°, but rather sooner. As it was supposed that this proceeded from the wires not conducting ready enough, the machine was moved slower, there was then but little of this and B was a great while before it closed, C about 5", H a great while. It was suspected that this increase of separation of the balls before they closed was owing to the wire designed to carry off el. to earth f not conducting fast enough. To try this, the next evening a long wire was insulated, and the cork balls hung to it. It was electrified sufficiently to make them sep. about an inch. They closed instantly on touching the wire with a bit of iron either communicating with wire for carrying off el. to ground, or whether it was only held in the hand. The air was as dry as the night before. * [Divisions and quarter divisions.] f [Art. 258.] Spreading of electricity 261 537J Crown with slits and H with D° compared with white cylinder; and A and C with oblongs compared with B *. The coatings were taken off from the plates A and C and oblong coatings without slits put in their room. The coatings were also taken from the crown glass, and oblong coatings with slits like those put to C put in their room. Fr. Feb. 12 [1773]. Th. 49. N. [34 observations, Art. 660.] 538] Experiment of p. 61 [Art. 535] tried with small ball blown to the end of a thermometer tube. A ball rather less than | inch diam. was blown at end of glass tube and was coated on outside with tinfoil, the inside being filled with $. This was used instead of plate D in exper. to see whether charge of Leyden vial bore the same proportion to that of another body whatever force it was electrified with. It was found that 12 inches of this tube when coated contained as much el. as K + jj^D, and therefore the spreading of the el. ^ inch on surface of this tube increases its charge by ^%D, whereas the spreading of el. ^ on surface of D increases its charge by — j D. 5s Th. 49. N. 13$. Tin plates at 17 inches from wire. With electrometer at I + 3. Div. on sliding plate 4 22 3 3i 3 ' 6 4 *9i sep. about i diam. pos. D° neg. With electrometer DO D° Equiv. to trial plate Diff. 19 5'9 t 3 + I- I4-3 17-9 3-6 Sum. 32-1 32-2 Fringed rings on plate of crown glass &c. f Sat. Feb. 13 [1773]. It was found on looking at the plate of crown glass that there were narrow fringed rings of dirt all round the edges of the coatings, the space between these rings and the coating being clean. This was supposed to be done by the ex- plosions. The distance of these rings from the edge of the coating seemed nearly the same both within the slits and without, but of the 2 seemed less within the slits. The mean distance seemed about -105 inc. which seems to shew that the electricity spreads pretty nearly the same both within the slits and without. 'Something of this kind has been frequently observed in the sliding trial plate i and sometimes I believe in some of the coated glass plates. Sun. Feb. 14 [1773]. Th. 49. N. 17. Last exper. repeated. [At 1 + 3, Sum = 29-6, at 3 + i, Sum = 28-3. Plate D gave 26 and 27-5 respectively. See Art. 664.] * [Art. 321.] f [Art. 308.] 262 journal of Experiments, Feb. 1773 JS7 539] Experiment to determine whether the charge of a Leyden vial bears the same proportion to that of another body when elect, is very weak as when it is strong *. AB is a tin cylinder 14 feet 8-7 inches long and 17-1 inches in circumference. DC is a brass wire 37-1 inches long and -15 in. diameter; both supported by non-conductors; with the middle sized cork balls hung at D. FE communicates with the prime conductor and is charged till light paper electrometer sepa- rates. A brass wire is suspended by silk, so as to be made alternately to touch E and DC. Mon. Feb. 15 [1773]. Th. 55. N. 22. The cylinder AB and wire DC were elec- trified negatively till the balls separated about i diameter. On touching DC twice with the wire, the corks separated about as much positively. The wire was 27-6 inches long and -15 in. diameter. The cylinder AB was then taken away and the plates D and E placed under the wire DC. The wire was obliged to be changed for one 20-8 inches long to exhibit the same phenomenon. [See Art. 666.] Tu. Feb. 16 [1773]. Th. 57. N. 20. Same exper. repeated. Cylinder touched twice with wire 31 inches long; changed from about i diam. neg. to D° pos. D and E with wire 24 inches D°. cyl. with wire 31 D°. cyl. with 27^ did not. [See Art. 666.] 540] Lane's electrometer compared with straw and paper electrometers. In the afternoon. Th. 56$. N. 19. I tried the distance to which the spark- would fly by Lane's electrometer. Distance [Lane] Knobs touched •027 •038 •044 •047 •051 •053 •038 knobs at -965 inc. dist . Divisions on electrometer -f- o+5 0 + 48 i+ 5 i+ 15 1 -I- 20 1 + 25 1 + 27* i+ 5 25 + 28 Straw elect, sep. 1 + 3 2 + ij 2 + 2\ 2 + 3 3 + oi 3+ i light paper elect, just sep. * [See Arts. 358, 606, and Note 25.] f [Revolutions and 6o"> parts of a revolution. One revolution = -038 inch.] Measures with condensers 263 541] Crown and H with slits compared with white cylinder; also on the exci- tation of electricity by separating a brass plate from a glass one. Wed. Feb. 17 [1773]. Th. 55. N. 21. [6 observations, Art. 660.] Fr. Feb. 19 [1773]. Th. 53^. N. i8J. A plate of glass nj inches square, coated with tinfoil 8 inc. in diameter, was supported on waxed glass. A brass plate 8 inc. in diameter was supported over it by silk strings in such manner as to lye on the plate perpendicularly over the tinfoil, and to be drawn up till it touched a piece of wire supported on waxed glass with the middle sized cork balls suspended from it. This was done in order to see how much of the charge of the plate was contained in the coating. It was found that though the plate was not electrified, yet on lifting up the brass plate the balls separated some inches if the tinfoil communicated with the ground, but if it did not communicate, the balls, as well as I remember, separated considerably less. Some bits of thin silk thread were placed between the glass and brass plate. In the afternoon. Th. 54. N. 17^. The experiment repeated with bits of card between the glass plate and brass. . , .. fcommun. ) . , fi . When tinfoil { ,., > with ground, balls sep. about {, inch, (.did not commun.J (.f When there was nothing between the glass and brass plate, they sep. 1-4 inc. whether the tinfoil communicated with the ground or not. In all these cases the brass plate was negative. The glass plate was found to be pos. if the tinfoil did not communicate with the ground, but I could not perceive it to be at all electrified if it did com- municate. The next morning the experiment was repeated, but the balls separated much less than before. The temper, of the air was much the same. 542] It was tried whether when three tin plates i foot square were placed near to and parallel to each other, the line joining their centers being perpendi- cular to their planes, the middle plate would receive much electricity on electri- fying the plates*. The experiment was tried with the same apparatus and nearly in the same manner as the experiment with the globe f, except that the two outer plates were suspended by two sticks of waxed glass turning on hinges. The wire too by which the plates were electrified was made so as to touch all three plates at the same time. Four bits of sealing wax were stuck to the middle plate, two on each side, to prevent the outer plates coming too near. * [Exp. vin, Art. 288 and Note 23.] t [Art. 218.] 264 "Journal of Experiments, 21 Feb. 1773 Sun. Feb. 21. Th. supposed about 55. N. 2oJ. If the bits of sealing wax were of such size that the distances of the outer plates were about j , the middle sized cork balls separated about j | . The light paper electrometer was used in this experiment. If the globe 2 was electrified in the same degree, and its electricity communicated to and the middle tin plate electrified by one of these jars (the (i, 2 & 4 ]ars two outer being drawn aside) and the cork balls then drawn up against the plate, they separated about 1 1 . <.s Ist (8 In the nd case the electricity of the globe was diminished < , [times], and therefore when the outside plates were at j , the quantity of electricity in the middle plate was about < * of what it would have received by the same IT degree of electrification if placed by itself. 543] Charge of A, B, and C laid on each other without any coatings between; also charge of I8t thermometer tube. The coatings were taken from the 3 plates A, B and C of Nairne, and the plates cleaned and placed one on the other without anything between them, and stuck together by dropping some melted wax on the edges. The outside surfaces were then coated with circles 6-6 inc. diam. This is called Triple Plate*. A thermometer tube was coated with coatings n inch long, the inside being filled with $, with wire let into one end, and the ends stopped with cement. The tube was 12-7 inc. long; weighed i .. 3 .. o, and the bore held 22.gra. of water, the specific gravity of a piece of the same tube weighed twice over was II- N.B. The comp. pow. of this tube is about goj. This is called Tube i f. Mon. Feb. 22 [1773]. Th. 53 J. N. 20 J. [8 observations. Art. 675.] 544] Lane's electrometer compared with straw and paper electrometers; also charge of plate rosin with brass coating made to prevent spreading of electricity. Lane's elect. Revolutions] Divisions] Light paper just sep. when [Lane's] el. at i 13 Straw at i + 3 o 54 3+i i 36 Knobs touched at o 7! * [Art. 380.] t [Art. 382.] Comparisons of electrometers 265 A plate of rosin and bees wax of the same proportions as for exper. rosin A c was cast of the shape of figure, ABDC and abed being brass plates 2-45 in. diam. their distance before the rosin was poured in being about -12 inc. Tu. Feb. 23 [1773] in afternoon, the rosin plate being cast that morning, the hygrom. as well as I remember being about 22. [4 observations, comparison with E.] Wed. Feb. 24 [1773]. Th. 54. N. 20. [4 observations.] Spreading of electricity on surface. Rosin closed in about 7", sep. again in 35. E was irregular. 545] Second thermometer tube; also comparison of charge of cylinder used in [Art. 539] with D + E. A thermometer tube whose length was 22-1 inc., weight = 2, 17, 21 and weight water which filled bore 14 gra. was coated with tinfoil 15-5 long, conseq. comp. power = * the spec. gra. of a part of the same tube being 3-243. Fr. Feb. 26 [1773]. Th. 52. N. 20 £. The cyl. used in [Art. 539] compared with the plates D and E, the wire Mm of machine being drawn out to 39^ inches, and resting on the cylinder as in that experiment. A sliding trial plate on neg. side. [6 observations. See Art. 666.] 546] Charge of second thermometer tube; also that of rosin plate with brass coating; also that of A, B, and C laid on each other without coatings between. [10 observations. Art. 675.] The same things were tried the day before, Th. 55, N. 17^, but the wire for making communication between machine and ground was forgot to be fixed. [14 observations. See Art. 666.] 547] f The quantity of electricity in plate D compared with that in a tin circle of 36 and another 0/30 inches diameter by means of the machine used for comparing simple plates J, the trial plate being a tin cylinder inches long, and § in circumference, fastened to the end of the usual sliding trial plates, with another cylinder of the same size sliding within it. T«ried with elect, of usual strength and with the middle sized corks. Also the double plate A compared with the circle of i8J inc. * [So in MS.] • t [Arts. 356, 664.] t [Art. 240.] § [So in MS.] 266 "Journal of Experiments, March, 1773 Wed. March 3 [1773]. Th. 56. N. 21. [16 observations.] 548] Charge of plate of experimental rosin designed for compound plate of glass and rosin; tried both when warm and when cold *. A plate of experimental rosin near 8 inches square was pressed out between two glass plates with tinfoil coatings fastened on by oil, the heat being such that it required very little weight to press out the5 rosin. The thickness of the plate was much less toward one end than the other, varying in different parts of the coated plate from -137 to -108, but the mean thickness was -122. It was coated with circles of tinfoil 6-61 in. diameter. Its charge was compared with that of the plates K, D and E of Nairne by means of a sliding trial plate made of the plate f of Nairne. Sat. March 6 [1773]. Th. 55$. N. 17. Tr. si. pi. K + D + E ros. plate In the afternoon. Th. 57^. N. 16 ros. plate K4- D+ E 24 19 25 19 sep. neg. D° pos. D° neg. sep. pos. D° neg. D". The rosin plate was then warmed before the fire between two glass plates with flannel between them and the rosin till it would not support its own weight without bending. As soon as it was strong enough to bear its own weight it was compared as before. rosin plate sep. pos. did not sep. In about 2 or 3 hours after, when it was quite cold, it was tried again : 2o£ 26 rosin 25 sep. pos. 19 D° pos. i8J DO. 24^ D° neg. 549] Whether charge of glass plate is the same when warm as when cold. The same afternoon the charge of a glass plate when hot and cold was compared together in the same manner. The glass was nj inches square, used for jEpinus experiment {, coated on one side with a circle of 8 inc. diameter, and a brass plate of same diameter used for the other coating. The glass and brass plate were both heated before the fire till almost as hot as I could bear my hand on, and then tried by the help of the 6th sliding plate, * [Arts. 381, 678.] t [So in MS.] } [Arts. 134, 341, 517.] Measures with various dielectrics 267 when the breadth of the sliding plate was required to be 37 in order that it should sep. pos. After the plate was cold it was tried again, the breadth of the sliding plate was obliged to be 36. Hence it would seem as if the charge both of glass and of rosin plate was the same when hot as when cold, the small difference between them being most likely owing to the electricity spreading more on the surface of the warm plate than of the cold one. 550] Crown with slit coat-ings and H with oblong compared with white cylinder; also second thermometer tube with D + E + F. The slit coatings were taken from H and plain coatings, 6-03 square, put in their room. Sun. March 7 [1773]. Th. 56. N. 15. Straw elect, at 2 + 3, which is equivalent to light paper electrometer [4 obs.]. Elect, at 3 + i [6 obs.]. Elect, at i + 3 [7 obs. Art. 660]. Mon. Mar 8 [1773]. Th. 54. N. 14^. [4 obs.]. 551] Quantity of electricity in plate D and rosin with brass coatings compared with that of tin circle of 36" and one of 30" by machine for trying simple plates*; with different degrees of electrification]. Tu. Mar. 9 [1773]. Th. 51. N. 15. The exper. of p. 78 [Art. 547] repeated, only using square tin plates of different sizes made to fasten on to sliding cylinder instead of the sliding trial plates. The tin circles and the square plates both supported on silk. Straw el. at inner marks N° 2. Square Inc. cyl. plate drawn out circ. 36" 5 24 sep. a little neg. — 3 II DO pos. E i 26 DO. 5 9 D° neg. rosin 3 X7 D°. i 4 D° pOS. circ. 30" i 20 D° pOS. 3 28 D° neg. Electrometer] at outer marks. circ. 30 3 20 DO. i 29 D° pOS. circ. 36 4 34 D° neg. 2 28 D° pos. E 4 21 D° neg. 2 24 D°. * [Art. 240.] f [Art. 664.] 268 journal of Experiments, March ', 1773 The electricity was found to break through the rosin plate when electrified with this strength, but there was no hole made in the plate, as it was found not to break through after that with the weak degree of electrification. It seemed not to pass over the surface, as no light was perceived. 552] Charge of compound plate of glass and rosin. The rosin plate of p. 79 [Art. 548] without its coatings was included between the plates B and H of Nairne and the outside surfaces coated with circles 6-6 inc. diam. and is called Compound Plate. Th. Mar. n [1773]. Th. 53. N. 17. [4 comparisons with K.] Fr. Mar. 12 [1773]. Th. 53^. N. 13$. [20 observations, Art. 664.] 553] Circle of i8£" compared with double plates, also plate D, plate air and the two double plates compared with circles of 36" and 30". A sliding trial plate was made of deal, with an additional piece to fit on, the breadth was 31 inches, the length when not drawn out, and without the additional piece, was 15, and the additional piece increased the length rof inches. The number in the 2nd column shews the number of inches by which the sliding piece is drawn out. March 3 Inc. el. Difi. Mean Circle 30 on silk I* 30 27'3_ .8 34'3 26-5 7-0 33'5 30-0 D° on glass 14-7 4 36 27-0 35-6 +I'° 28-9 36-6 7 7 327 D° on silk n-3 5* 36 24-6 + 1-7 32-9 *4 »> 30-4 E 157 i* 38 T3 + 1-9 36-1 T 8'8 33-6 Circle 30" •11 I8-7 on silk 8 33'9 ° 33-9 Tu. Mar. 9. [Electrometer] At inner marks. At outer marks. Difif. Mean Diff. Mean Circle 36" n-6 35-6 5-8 36-3 E 12-2 32-5 6-9 33-2 Circle 30" 11-4 30-4 7 30-8 March 12. [14 observations.] Sat. Mar. 13. Th. 55. N. 12. [12 observations. See Art. 649.] Mon. Mar. 15. Th. 54. N. 14. [15 observations. See Arts. 649, 655.] 554] The same with addit. four small rosin plates. Four plates of rosin and bees wax were cast 4 inches square and about •22 thick and coated with circles 1-8 in. diam. A tin trial plate was also made 6 inches long and 5 broad. It is called N. The plates of rosin were connected by bits of brass wire like that used for connecting the two double plates. Compound dielectrics 269 Fr. Mar. 19. [20 obs. Arts. 649, 651.] Tu. Mar. 23. [21 obs. Art. 649.] Wed. Mar. 24. [22 obs. Art. 649.] 555] Sun. Mar. 2iat [1773]. Th. about 55. N. about 15. It was tried whether the 4 rosin plates contained the same quantity of electricity whether they were placed close together or at a distance, and what is to be allowed for the connecting wires, &c. This was tried with the usual machine*, the rosin plates being placed on the positive side and sliding plate 3 on the negative side, the sliding plate re- maining always at the same division, the small variations of the charge being found by the additional wire. They were tried in 5 different ways. Ist way. The plates placed close together near the end m, the usual wires V resting on the plates, with the connecting wires put on the plates. 2nd way. D° without the connecting wires. 3rd way. The connecting wires suffered to remain, and also one of the wires V, but the 3 others removed towards end M , placed at 4 inches distance from each other, and supported in their usual situation by silk strings. 4th way. The same, except that the 3 wires V were taken quite away. 5th way. The rosin plates placed at as great a distance from each other as possible id est f inches with the usual wires V, but without the connecting wires. 3rd way, with connect, wires, usual ones re- moved to end 4th way, without usual wires Ist way, with connect- ing wires and usual also 2ni1 way, without con- necting wire 5th way, removed to distance 556] Whether charge of white glass thermometer tube is the same when hot as when cold\. Sun. Mar. 21 [1773] afternoon. Th. about 55. N. about 15. A ball about I inch in diameter was blown at the end of a thermometer tube with a bulb 4-3 inches above. This was filled with § sufficient to rise into * [Art. 295. See Art. 337.] f [So in MS.] J [See Art. 366 and Note 26.] Inc. el. on addit. wire Sliding plate Inc. el. on addit. wire Sliding plate ect. re- t ° 3---I4 sep. pos. I 3...I2f D° neg. ;ual } a* DO 2 DO sct- ual | i DO 2 DO on- 2 DO 2i DO to 1 X| DO 4 DO 270 Journal of Experiments, March, 1773 the bulb. The tube was coated 3-4 inches from the ball with gummed paper dipped in salt water and bound on with iron wire. This ball was placed in a glass of $ surrounded with iron filings and placed on machine near M, and heated by a spirit lamp, the $ in which the ball was immersed being made to communicate with the ground, and a bit of iron wire bound round the wire Mm being dipped into the $ in bulb. The crown glass plate * and the plate A of Nairne, which was coated as a sliding plate, being put on negative side. The Ist column being the number of square inches which it was necessary to give to the coating of the sliding plate in order that the balls might sep. pos. and the 2nrt column that they might sep. neg. The charge of the crown glass plate being equal to that of the sliding plate when its coated surface is 33 square inches. Sep. pos. Sep. neg. Heat of 5 in which ball was immersed 12-9 15 21 26-6 29-4 3i-8 29-4 19-6 17-2 14-8 12-9 29-4 33 cold 170 210 27O 300 elect, passed through glass pretty fast. 305 passed through much faster. 290 235 160 145 cold 33 30-6 Tu. Mar. 23 and Wed. Mar. 24. [43 obs. Art. 649.] 557] Allowance for connecting wires in p. 86. [Art. 554.] The allowance to be made for the charge of the connecting wires was en- deavoured to be found by suspending the two circles of 9-3 inc. horizontally by silk lines at n inches distance from each other and finding their charge by means of the forked electrifying wire as in 1772 p. 7 [Art. 472], both when the plates were connected by a wire similar to that used for connecting the rosin plates, and without any connection. The event was as follows. Fr. Mar. 26th [1773. 8 obs. See Art. 647.] 2i Therefore the plates contain about J square inc., or 1-41 inc. el. more with the connecting wire than withoutf- Sat. Mar. 27 [1773]. It was tried by usual machine whether the 4 rosin plates contained more el. when at a distance than near. The trial plate B id est the largest trial plate used for D &a being placed on neg. side. * [So in MS.] f [See Art. 647.] Tests 'with various electrometers 271 With a quantity of additional wire = to gj inc. el. the balls sep. pos. when the plates were at as great a distance as possible. When they were placed close together they seemed to require rather more additional wire, and as well as I could judge, a quantity = about | inc. el. 558] Excitation of electricity by separating brass plate from glass one. Sat. afternoon. Th. 60. N. 9. The experiment of p. 71 [Art. 541] was repeated. It was found that the brass plate was electrified on lifting up as before, though the plate was not electrified before. But if the plate was first charged and discharged again before the plate was lifted up, it was found to be stronger electrified. I then took a piece of tinfoil of the same size as the brass plate, with a silk string fast- ened to it near the edge, and laid it on the glass and lifted it up gently by the silk string. The tinfoil was found to be electrified thereby. 559] Comparison of Henly's, Lane's, and straw electrometer. Th. about 58. N. Sun. Mar. 28 [1773]. about 8. The two conductors of Nairne were placed end to end, and Henly's electrometer placed on that furthest from globe* parallel to con- ductor and the cork pointing from globe. The four jars were also joined to the usual wire with the straw electrometer hung to it, the wire and jars being placed at such a distance from the conductors that the electricity was found not to flow sensibly from them to the jars. The globe 3 f was then applied to that con- ductor nearest the globe and electrified till Henly's electrometer stood at 90°. The globe 3 was then removed from the conductors and its electricity communicated to the jars{. The straw electrometer separated to 2 + J. * [Of Nairne's electrical machine.] f [Globes 2 and 3 are glass globes coated as Leyden jars. See Art. 505 for their charges.] J [For the charges of these jars see Art. 506.] [Henly's Electrometer, from the original figure, Phil. Trans. 2. P- 359-] 272 "Journal of Experiments, March, 1773 The experiment was repeated several times and was found to agree together pretty well. The jars were then electrified, they and the straw electrometer standing in the same place, and it was found that Lane's electrometer fastened to one of them discharged at 0-53^ with that degree of electrification, the same jar being applied to the conductor and electrified till Henly's electrometer stood at 90°, Lane's discharged at 12-15. The conductors being then taken away and the jars and straw electrometer placed in usual position, Lane's discharged at 1-17 when straw stood at 2 + 3, and at I + 2 when light paper electrometer just separated. The knobs touched at 0-4. Sun. eve. Th. 58. N. 8. The globe 3 electrified till Henly stood at 90°, and its electricity com- municated to i, 2, and 3 jars, straw electrometer separated to 2 + if. Lane's with that degree of electrification discharged at 1-7. When Henly's stood at 90°, Lane's discharged at 12 -20. Jar 2 charged till straw electrometer separated to 4, and electricity com- municated to jar i, straw separated to 2 + \. When straw electrometer separated to 4 Lane's discharged at 2-0 2 + i -52 2 + 3 1-19 light paper just separated i-i 560] Excess of redundant fluid on positive side above deficient fluid on negative side in glass plate and plate air &c. * Mon. Mar. 29'" [1773]. Th. 58. N. 7. The ii J inch plate coated with circles of 8 inches diameter was supported on waxed glass. I charged this by touching the top with a vial charged till the straw electrometer separated to 2 + 3 while I touched the bottom with a wire. At the same time an assistant stood ready with a bent wire in his hand ready to discharge it as soon as I took the jar away, the wire was fastened to a stick of waxed glass and had the pair of cork balls commonly made use of hanging to it, the cork balls separated about i inch. I then charged the jar 4 to the same degree and communicated its electricity to the jars i & 2 and touched the upper side of the plate with one of the jars, but without touching the bottom with the wire. The corks separated very nearly the same as before, but of the 2 rather more. I then charged the jar till the straw electrometer separated to 2 + 2 and diminished its electricity as before, the corks now separated rather less than the first time. The experiment was repeated several times with very nearly the same event. I could perceive no difference in the separation of the cork balls whether the wire of the jar with which I touched the plate was 17 inches long or only 2f . * [See Note 30.] Difference of charges on parallel disks 273 If the four jars were charged to 2 + 3 and its electricity communicated to globe 3, it was diminished to 2 4- 2. The plate air 4 was charged by jar charged till straw electrometer stood at 2 + o, and if jar 4 was charged to the same degree and its electricity communi- cated to jar 2, the corks separated the same if bottom was not touched. With plate air i the charge was obliged to be reduced by communicating jar 2 to jar 4 to make the same separation when bottom was not touched as when it was. Tu. Mar. 30 [1773]. Th. 56. N. 8. The same experiment was repeated, only putting a piece of sealing wax with marks on it supported by glass about 2 inches below the corks to serve by way of comparison. Compound plate of [Art. 552] Plate air i Plate air 4 2+1 2+i 2+1 Jar i commun. to 2 + 4 jar i to 2 i to 2 2 4. TJ * ~ A 2 2+1 2 The second column is the distance to which the straw electrometer separated in charging jar with [which] the plate was electrified when the bottom was touched in order that the cork balls should separate equal to marks on wax. The third column is the ratio in which the electricity of the jar was diminished when the bottom was not touched, and the fourth column shews the degree in which the jar was electrified (as expressed by distance to which the electro- meter separated) in order that ..he balls should separate to the required distance. N.B. The paper of divisions used for the electrometer was different from that used before, but the divisions nearly of same strength. The marks on sealing wax used for compound plate were nearer than those for plate air. The jars i, 3 & 4 being charged till straws separated to 3 + o and the elec- tricity communicated to jar 2, they separated to 2 + i, and the electricity of jar 2 being destroyed and the electricity of the others again communicated to it, they separated to i + 3*. Therefore diminishing the electricity in ratio of 95 to 126 diminishes distance to which the balls separate in ratio of 126 to 165, or diminishing the electricity in ratio 1-33 to i diminishes distance in ratio 1-31 to i. Result. On Monday the excess of redundant fluid on the positive side above de- ficient fluid on negative side in ii £ inch plate with 8 inch coating \ •3 J Plate air i L is Plate air 4 1-88 i / 2-14 * The smaller divisions are equal to ^ of large ones. C.P.I. 1 8 274 "Journal of Experiments, April, 1773 of the quantity of electricity which is given to it with the same degree of electrification if the bottom plate is not touched. Compound plate On Tuesday D° excess in Plate air i I'OO Plate air 4 2-16 561] Fr. Apr. 2 [1773]. Th. about 55. N. about 10. It was tried whether a parallelepiped box included within another box of the same shape and communicating with it would receive any electricity on electrifying the outer box*. The experiment was tried just in the same manner as that with the globe in p. 26 [Art. 513]. The inner box was 12 inches square and 2 thick. The outer box was 14 inches square and 4 thick on the outside, and 13 square and 3-4 thick within. The boxes were made of wainscot and well salted. I could not perceive that the inner box was at all over or undercharged, for if I previously electrified the cork balls positively sufficiently to make them separate in touching the inner box, they would separate as much if I previously electrified them negatively in the same degree. Globe within hollow globe tried again f . 562] Sun. Apr. 4 [1773]. Th. 58. N. n. The globe included between the 2 hemispheres was tried again in the same manner, except that the hemispheres were coated with tinfoil and were made to shut closer. I could not perceive the inner globe to be at all electrified either way. In order to see how small a degree of electricity I could perceive this way, I separated the two hemispheres as far as in the experiment, and electrified the 2na thermometer tube with the same strength of electricity as was used in the experiment, and communicated its electricity to the jars i and 2, then touched the inner globe with one of those jars and drew up the cork balls, previously positively electrified, against the globe. I found them to separate very visibly. I then repeated the experiment in the same manner except that the balls were negatively electrified in the same degree. The elect, of the thermometer tube was diminished by communicating to the 2 jars in the ratio of 105 to 6339 J, or of r to 60, so that if the redundant fluid in the globe had been so much as ^ of that in the hemispheres, I must have perceived it. * [Exp. n, Art. 235.] t [ExP- I- Art. 218.] J [Charge of 2n closed •! f on straw { on ball, blighted] (2j (.10 The light straw N° i was soaked in salt paper at night for 3^ hours. Wed. Jan. 27. Th. 57. N. 23. When heavy sep. to 15, light at 14, but increased after a time to near 15. As it was suspected that this increase might be owing to the air being electrified, I tried and found the air to be much electrified in all parts of the room. ( straw , 2" or 3" . N° i resting on < , „ closed in (ball 90 straw 20" N° 2 on , .. closed in , ball very slow. The ball of N° i was then moistened with salt water. Heavy sep. to 15, light to 13, but increased to near 14. In order to avoid in some measure the inconvenience from electrifying the air, Richard turned the globe, by which means the electricity was not made so strong. heavy to , light to 10 10 N° i closed in about 4" whether resting on ball or straw. N° 2 was soaked in salt water for 2\ hours till 3 in afternoon, about 5 or 6 it was tried. heavy to , light to , Ist time, for several times after to 14. 10 On straw On ball N° 2 4" 4 I 3 or 4 3 or 4 fair 2 or 3 8 blighted 2 or 3 9 Wed. Feb. 3. Th. 46^ N. 12. As it was found the preceding day that the straws conducted ill, they were kept about 3 or 4 hours in the morning in salted paper, at about 3 they were taken out of the paper and hung up to dry. In the afternoon they were tried, a screen being placed to keep them from the fire. 278 Journal of Experiments , February, 1773 Globe 3 elect. Globe 2 elect. Heavy Light Heavy Light 15 i6J 15 17! 15 16 15 J7i 12 12 15 Z7i 12 I2i 12 I4j 10 loi 12 13^ 10 io| 12 13 8 8J 10 iii 8 8 IO "I 8 8J 8 9l 8 cS 9i 10 3 IO nj 10 10 10 nj 10 10 12 14 12 13 12 I3j 12 12 15 17^ 12 12 15 J7i 15 16 15 X5l 15 15^ The blighted heavy straw closed in fair On straw 25" 10 On ball I . 30" not near closed in 2' Weight with addition Without Distance of pin from cent. grav. Fair Blighted 14-85 17-85 6-05 7-05 5-07 5-155 566] After the additional wire had been taken from the heavy electrometer, the two electrometers were electrified and compared together without the process of communicating the electricity from one globe to the other, when they stood as follows. Heavy straw electrometer without additions 17 15 13 12 If globe 2 was electrified till D° electrometer separated to 17, on com- municating electricity to globe 3 it separated to gj. The light straw electrometer was then placed instead of the paper electro- meter, and a paper with divisions placed behind it. It was found that when Heavy Light 8 9 Heavy paper •2 TTT 10 iof electrometer very little 12 15 ia| 15} Light do. TTJ very little 12 12} IO IOJ 8 84 Sensitiveness of electrometers 279 heavy straw electrometer separated to ', divisions, the light straw electrometer separated to Small divisions Large divisions 567] As the straws seemed not to conduct well enough, they were gilt. The gilding was not perfect in several places, but it was sufficient to conduct the shock of a jar very weakly electrified. Added weight 12 Weight Cent. grav. from pin Wire length N. r 7'55 5-25 2'45 N. 2 6-55 5-17 2-OI CN Heavy electrometer < ' Tu. Apr. 13. The globe 2 electrified and communicated to globe 3. IO-I Heavy el. 13 12 IO 8 Light 154 14 12 104 8 ro 12 13 Globe 3 communicated to 2 8 Wed. Apr. 14. Th. 51. N. 13. Globe 2 communicated to 3 94 n| 14 154 It was found that some electricity ran from the electrifying wire to the knob of the globe to which electricity was to be communicated, on which the knob was removed to such a distance that no sensible electricity ran from one to the other. 10 12 13 104 13 14 Globe 3 communicated to 2 13 12 10 iqj 8 8| Globe 2 communicated to 3 13 12 14 N.B. The holes where the wires were put in were gilt over. N. 2 N ' > of heavy electrometer were found to weigh 16-65 19-65 ' The wires were then taken out, the holes stopped up with wax and gilt over. It was then found on electrifying the globe without communicating its electricity to the other, that when the heavy electrometer stood at 8 9 ™ the light stood at "f 13 14! 280 "Journal of Experiments, April, 1773 N. i N. 2 Weight 7-6 6-65 Cent. grav. from pin 5-36 5-285 35'i 136-1 N. I N. 2 Force requisite to separate straws without wires 40-8 with wires 159^9 Therefore force required to separate heavy electrometer falls short of four times force required to separate light electrometer in the ratio of 296 to 303-6, or of I to 1-027. 568] Separation of Henry's electrometer by different strengths of electrification. Nairne's jar being tried against the two trial plates for plate H, the pith balls separated a little after a short time the same way as the two trial plates. Therefore Nairne's jar is supposed to contain about ±£ of plate H, or 16 times as much as plate M. The two conductors of Nairne were set end to end with [Henly's] electro- meter on furthest, and the jar applied to the same, the furthest conductor being without any point, and the plate M was placed near it, set on a conductor communicating with the ground. When the electrometer was raised a little above 90°, the nearest conductor was removed and the electricity of globe taken away. Then as soon as the electrometer was sunk to 90° a communication was made between conductor and plate M and immediately taken away again, and the figure to which the electrometer sunk wrote down and the electricity of plate M discharged, after which a communication was again made between the conductor and plate M. The results of the experiments are contained in the following Table, where the first^column is the number of times that a communication has been made between the conductor and M. Number of times Elect, in jar ISt Mum 2 oers on e 3 lectron 4 leter 5 6 Difi. Supposed tn Elect. Number in jar on elcctr. 1C Diff. 2nd difl by first I 2 3 4 5 •938 •879 •824 •773 •725 70 32 20 16 M 73 36 21 16 14 73 44 23 17 15 79 63 31 19 16 77 58 35 18 14! 80 63 3° i8J 151 063 59 55 8 I-OOO •938 •879 •824 •773 90 80 63 32 18-5 IO !7 31 .13-5 3 160 290 564 262 62 6 •679 •637 •597 12 IO 9 12 II 10 13 12 ioi H 12 II 13 ITi 10 J I2i nf IOJ T1 46 42 •725 •679 •637 J5'5 13 n-5 *) 2'5 i'5 T 55 35 9 •560 8 9 10 IO IO 9i 4° •597 10-5 £ 2(> 10 •525 1\ 8 §1 37 1 C •560 9'5 J II •492 7 7\ 8 J.T •525 8-5 12 •461 6 <>.'. 7 33 •492 8 "5 T 13 M •433 •406 5i 5 6 5l 61 5i> 31 28 •j -7 •461 •433 7 0-5 •5 j 25 15 •380 5 27 •406 5'5 16 •357 44 I7> •334 4 18 •313 4 19 •294 3* 20 •276 3 Calibration of Hen ly electrometer 281 The second column shows the quantity of electricity in the jar, which must diminish each time in the ratio of 15 to 16, and the other column is the number which the electrometer stood at in the different experiments. The above experiment is supposed to have been made in the autumn of 1772. 569] Separation of Henly's electrometer when fixed in the usual way and on an upright rod. Aug. 13, 1773. Th. about 78. Henly's electrometer was stuck on a thin wooden rod 25 inches long, the end of which was fixed into the hole made in the conductor for receiving the electrometer, being parallel to the conductor as usual. The conductor to which this was fixed was connected to the other conductor which received the elec- tricity from, the machine by a brass wire about 10 inches long, and a jar with Lane's electrometer fastened to it was made to communicate with this last conductor, so that the rod to which the electrometer was fastened was about * inches from the globe and * inches from the jar. Henly's electrometer was then compared with Lane's while in this situation, and when this was done the wooden rod was taken away and Henly's placed on the conductor in the usual manner, everything else being the same as before, and compared with Lane's as before. N.B. In both trials the cork ball of Henly's was turned from the globe f. The result was as follows: — Hence it appears that when Henly's [electrometer] is fixed on the rod it is more sensible towards the beginning of its motion than afterwards, whereas when put in the usual way it is the contrary. 570] Result of P. 70, 75, & 95 [Arts. 540, 544, 559], being a comparison of the different electrometers. Lane Henly Rev. div. On rod Usual way 4-30 6-30 8-30 21 37 38 5 10 18 10-30 40 32 Straw electrometer at P. 70 Th. 5(4 N. ly P. 75 P. 94 Th. 53i Th. 58 N. 2oJ N. 8 P. 95 Th. 58 N. 8 i + 3 43 4Ci 2+ i 48 2+ | 5« 2 + ij Co 2+ if 63 2 + 2| 70 2 + 3~ 75 73 75 3+ i 80 3+ i 824 88£ 4 nC Light paper elect, just sep. Co 64^ 58 Henly's at 90° 73 1 736 [bo in MS.] [Of the electrical machine.] 282 "Journal of Experiments, Aug. 13, 1773 The three last columns are the distances at which Lane's electrometer dis- charged, expressed in divisions, or 6oth parts of a revolution of the screw. By p' ^ [Art. 551] the distance at which Lane's discharges is as the j power of the quantity of electricity in the jar, and the quantity of electricity when the straw electrometer is at 2 + 3, id est the usual charge is to that when Henly's is at 90° as i to | ,_ j* . 571] Comparison of Lane's electrometer with light straw electrometer in different weather. Lane's electrometer was compared with the light straw electrometer by the apparatus represented above. A being the globe, B a conductor, CD a wooden rod supported on two waxed glass pillars, having a pin at D almost in contact with the conductor, the straw electrometer being hung to C. £ is a jar with Lane's electrometer fastened to it, supported on a bracket fixed to glass pillars, the wire of which touches CD. The distance of C from the globe is 54^ inches and from the nearest glass pillar 32 inches. The height of the pith balls above the floor is 36} inches. A small board with divisions on it, not represented in the figure, supported on an upright wooden rod, is placed behind the straw electrometer 25 inches from it, and a bit of tin with a narrow notch in it for an eye sight is placed at the same distance before the electrometer. The outward divisions on the board, or those called the 4th, are at 5 inches asunder, the 3r" at 4 inches, the 2nd at 3 inches, and the Ist at 2. As I found it impracticable looking attentively at both balls of the electro- meter, I looked only at one, which, as my eye was guided by a narrow slit, was sufficient, and when I had made the experiment looking at one ball I repeated it looking at the other, so that the mean would be right though the slit was not right placed. A wire was continued from the coating of the jar to the earth. Shock related to character of the discharge 283 Wed. Aug. 18, 1773. Th. 63°. N. 19. Bar. 29-64. With two more jars communicating with E by wire. Knobs of Lane's electrometer touched at 0-29. st ( 2"d i1'43 I 3™ division; Lane discharged at J2-27. Ct at i 4th U-ii With only one jar; straw at 3rd division, Lane discharged at 2-27. A slip of tinfoil was then pasted on CD the whole length so as to touch the wire of the jar and the frame of the straw electrometer. The result with only one jar was then as follows. Sri' 2*26 Straw at ,. division. Lane at 4th 3'i Th. Sept. 2. Th. 65°. N. 19. Bar. 29-865. ord I-SSi Straw at .. division. Lane at . 4th 2-41 Wed. Sep. 8th. Th. 62°|. N. 19$. C. 18. Bar. 29-235. ord 2*22 Straw at ,. division. Lane at 4th 3'i In the afternoon. Th. 62°. N. 19. C. 17. Bar. supp. 29-37. ord 2"^^ Straw at ... division. Lane at . 4th 3'0 Fr. Sept. 17. Th. 58°^. N. 28^. C. 29. Bar. 29-61. Straw at Lane at 4 2-59 572] Comparison of strength of shocks by points and blunt bodies. The wooden rod used in P. 118 [Art. 571] was supported on waxed glass with the straw electrometer at the end, and some tinfoil wound round part of the rod. The white glass cylinder was put in contact with it, electrified in such a degree that I felt a slight shock in discharging it with a piece of brass wire with a round knob at the end. If it was then electrified in [the] same degree, and discharged [with] a like brass wire with a needle fastened to the end, I could perceive no shock, and but a very slight sensation, even though the point was approached pretty quick. The distance to which the straw electrometer separated was about 1-8 inches. The white cylinder was then changed for one of the large jars, the shock was not very different whether it was discharged by the knob or point unless the point was approached very slow. The distance to which the electrometer separated was about -9 inch. The wooden rod was taken away, and the white glass cylinder made to rest on the conductor with Henly's electrometer on it, and electrified till it stood 284 "Journal of Experiments, NOT.}. 1773 at 90°, and to prevent the shock being too strong it had its choice whether it would pass through my body or some salt water, the wires in the salt water being brought within such a distance that the shock was weak when taken by the blunt body. I then found that if I took it with the point I could scarce perceive any spark. The experiment was tried in the same manner with a large jar. The shock was very sensibly less though the point was approached almost as fast I could. 573] Whether shock of one jar is greater or less than that of twice that quantity of fluid spread on four jars*. It was found that if the jars 3 and 4 were electrified in a given degree, and their electricity communicated to the jars i and 2, the shock produced by dis- charging them was nearly the same, or of the two rather more, than that pro- duced by discharging the jar i or 2 by itself. The shock of the jar 3 was found to be very sensibly greater than that of jar 4. It was tried with the wooden rod, the jars to be electrified being placed in contact wtih the tinfoil thereon, and when they were sufficiently electrified those to which the electricity was to be communicated being approached till they touched the rod, all four standing on the same tin plate. The jars were electrified till the straws separated -9 inch. N.B. The jars i and 2 contain pretty nearly the same quantity of electricity and their sum is nearly equal to the sum of jars 3 and 4. The quantity of elec- tricity in jar 3 exceeds that in jar 4 in the ratio of 37 to 27, or of 4 to 3 nearly f. 574] Comparison of the diminution which the shock receives by passing through water in tubes of different bores, and whether it is as much diminished in passing through 9 small tubes as through the same length of one large tube the area of whose bore is equal to that of the 9 small ones%. Nov. 1773. It was tried whether a shock was as much diminished by passing through a glass tube filled with water, 37 inches of which held 250 grains of water, as in passing through 9 tubes, 37 inches of all which together held 258 grains of water, the length of water which it passed through being the same in both cases, namely about 40 inches. Two jars were used, and charged till the straw electrometer separated to 3 + o. The water in the tubes was mixed with a very little salt, and the shock just enough to be perceived. I could not be certain that there was any difference, but if any, that with the single tube seemed greatest. The shock was then made to pass through 7 of the small tubes, 37 inches of which hold about 200 grains of water. The shock was then sensibly less than with the large tube. It was afterwards tried through what length of a tube, 37 inches of which held 44 grains, the shock must pass, so as to be as much diminished as in passing through 44^ of the large one. * [Art. 406 and Note 31.] f [Art- 685-] t LSee Art- 5°6.] Resistance of iron wire and salt water compared 285 It was found that when it passed through 5-2 inches the shock was sensibly greater, and when it passed through 8-4 sensibly less than with the large one, so that it is supposed it would be equal if it passed through 6-8. 44 i -08 6-8 44i 250 so that the resistance should seem as the ro8 power of the velocity. N.B. The quantity of water which the tubes held was not measured very exactly. 575] The tubes used in p. 123 [Art. 574] were measured by follows : and are as NO Length col. $ Weight [Troy] [oz. pwt. gr.] Length o column wh Straight end : same en near Bent end Weight of 37 inches in grains I 37-i 16 . 12 20-9 20-2 395 2 37'3 14 . 2 23-65 22-9 335 3 38-4 1.0.8 24-5 21-8 470 4 38 ii . 6 24-5 24-7 263 5 377 17 . 17 21-7 23-3 417 6 36-8 14 . 10 20-4 20-3 348 7 38-8 15 . 22 26-6 22-3 364 8 38-6 17 . 17 24-8 21-6 407 9 39-8 16 . 18 26-3 22-2 374 10 37-8 I . 10 . 0 16-9 17-4 7°5 ii 37-3 I . 3 . 20 22-8 22-2 567 large 447 8 . 15 . 8 3480 37 inches of the 9 first tubes, which are what was used in p. 123 [Art. 574], held together 3373 grains, therefore the shock was very nearly the same, but if anything rather greater when it passed through one tube, 37 inches of which held 3480 grains of $, than when it passed through 9 tubes, 37 inches of all which together held 3373 grains. By p. 124 the shock is as much diminished in passing through 6-8 inches of a tube, 37 inches of which hold 567 grains, as through 44^ of one, 37 inches of which hold 3480, so that resistance should seem as the 1-03 power of the velocity. 576] Comparison of diminution of shock by passing through iron wire or through salt water*. In order to compare the conducting power of iron wire and salt water, the shock of two jars had its choice whether it would pass through 2540 inches of nealed iron wire, 12 feet of which weighed 14-2 grains, or through my body, each end of the iron wire being fastened to a pretty thick piece of brass wire which I grasped tight, one in one hand and the other in the other, and with them discharged the jars. * [Art. 398 and Note 32.] 286 yournal of Experiments, Nov. 1773 It was found that when the straw electrometer separated to i + o, I just felt a shock in my wrists, and when it separated to 2 -f- o, I felt a pretty brisk one in them but not higher up. I then gave the shock its choice whether it would pass through my body, or 5-1 inches of a column of a saturated solution of sea salt contained in a glass tube, i inch of which holds 9-12 grains of fresh water, the wires running into the salt water being fastened to brass wires as before. I found the shock to be just the same as before, and found too that in- creasing the length of the column of salt water not more than J of an inch made a sensible difference in the strength of the shock. Therefore the electricity meets with the same resistance in passing through 2540 inches of wire whose base is 0 - - = — as through 5-1 inches of salt 78 x 144 79 water whose base is 9-12. Therefore, if the resistance is as the 1-08 power of the velocity, the resistance of iron wire is 607,000 times less than that of a column of salt water of the same diameter*. 577] Comparison of conducting powers of saturated solution of sea salt and distilled water. The shock of i jar charged till the straw electrometer separated to i + o£, ( *8 discharged through a column of < inches of a mixture of saturated solution t greater of sea salt with 99 of distilled water in tube 6, was -j ? than when it was discharged through 35^ inches of saturated solution of sea salt in tube 2. By a former experiment, the shock passed through ' > of the mixed water was j| r than through 40 J of saturated solution. By a mean, the resistance of one inch of the mixed water is equal to that of 38 of the saturated solution, therefore allowing for the different bases of the tubes, the resistance of the mixed water is 39 times greater than that of the saturated solution. The shock of two jars, charged to 4 + 0, and discharged through ~~ ( CTf*3.tf*I* of distilled water in tube 5, was < ° ' than when it was discharged through 23 J of the above-mentioned mixed water in tube 8. ( *R By a former experiment, the shock passed through | of distilled water was |f than through 23 J of the mixed, (less * [If the resistance is as the velocity, resistance of saturated solution of salt is 355.4°° times that of iron wire. By Matthiessen and Kohlrausch it should be about 502,500. See Note 32.] Whether there is surface resistance 287 By the mean, the resistance of 1-3 of distilled water = that of 23^ of mixed. 10-9 inches of tube 5 in the place where used holds 120 grains of $, or 37 inches holds 408 grains, which is the same as tube 8: therefore the resistance of distilled water is 18 times greater than that of mixed, or 702 times greater than that of a saturated solution of sea salt. 578] Whether the electricity is resisted in passing out of one medium into another in perfect contact with it. The Qth tube of P. 126 [Art. 575] was filled with 8* columns of saturated solution of sea salt inclosed between columns of £, the end columns being §• The tube 7 was filled with one short column of § at the bent end, and a long column of saturated solution of sea salt. It was found that the shock of one jar, charged till the straw electrometer separated to i-o£, passed through a column of the salt water in tube 7, ' [• inches long, was rather j diminished than in passing through the mixed column in tube 9, the wires used in tube 9 being immersed in the end columns of £, and those used in tube 7 being immersed one in the short column of $ at the end and the other in the column of salt water. The length of the mixed column in tube 9 was 43-5 inches, its weight was 10-5, the weight of a column of £ of the same length was 18-10, therefore the sum of the lengths of all the columns of salt water was 21-8 inches, and by the experiment the shock was as much diminished by passing through 24-4 inches of salt water in tube 7 as through this. But as the bore of tube 7 in that part which was used was greater than tube 9 in the ratio -±- ' x — — = 1-06 to i 22-3 37'4 nearly, the shock should be as much diminished in passing through a column 22-94 long in tube 9 as through one of 24-4 in this. Therefore the shock is as much diminished in passing through a mixed column, in which the length of salt water is 21-8 inches, as through a single column of the same size whose length is 22-94 inches. The difference is much less than what might proceed from the error of the experiment. 579] A slip of tin was made consisting of 40 bits soldered together, all i\i inch broad and all about \ inch long. They were made to lap about ^ inch over each other in soldering. I could not perceive that the shock of a jar was sensibly less when received through this than through a slip of tin of same length and breadth of one single piece. If the jar were charged pretty high and a double circuit made for it, namely through this piece of tin and my body, I could not perceive the least sensation. 580] Made at Nairne's with his large machine. A long conductor was applied to the electrical machine and a smaller con- ductor to its end, a Henly's electrometer was placed on the middle of the long * [8° in MS. Perhaps 80.] 288 'Journal of Experiments, Nov. 1773 conductor, and a small jar with a Lane's electrometer fastened to it was made to touch the short one. When Henly's stood at 3° Lane's dis- <7 + 35 = "668 55 charged at '7 + 5« = -678 inch. 70 19 + 30 = -741 The jar was then changed for one of rather more coated surface and a much smaller knob. When Henly's stood at 30 or 35, Lane's discharged at 17-7 = -650, so that Lane's discharged at nearly the same distance with the same charge, whichever jar was used. Henly's electrometer was then placed on an upright rod, touching the long conductor near the furthest end, Lane's electrometer with the first jar being placed as before. Henly then rose to 55 or 60 before Lane discharged at 17-55 = -681 inch. Henly being then lifted higher it rose to 65, Lane remaining as before. It was then lifted still higher, when it rose to 6s I7'55 = '631 before Lane s discharged at 35 or 40 6-55 = -263 Lane's being then separated to 27-55 = 1-060, the jar once discharged over surface of glass and once to the electrometer, but there seemed reason to think that Henly's rose no higher than before, namely 65. My Henly's electrometer usually rose to 90 when Lane's discharged at 12-20 = -467 inches. Therefore the distance at which Lane's discharges, answering to different numbers on Henly's, is as follows : I [Lane] Henly on highest rod 65 1-060 65 50 35 or 40 Henly on conductor .70 55 30 •68 1 •377 •263 •741 •678 •668 •469 My Henly on conductor 90 The distance at which Lane's discharges with a given jar is nearly propor- tional to the quantity of electricity in the jar, for if a jar is charged to a degree at which Lane is found to discharge at a given distance, and its electricity is communicated to another jar of the same size, so as to contain only J as much electricity as before, Lane will then discharge at nearly \ the former distance. [ 289 ] M[EASURES] (From MS. N°. 20. See Table of Contents at the beginning of this volume.} [These "Measures" are on a set of loose sheets of different sizes marked M. i to M. 21, and another set marked M. i to M. 12.] 581] Comparative charges of jars and battery * M. i. If jar i is electrified till straw electrometer separates to ij, and its electricity is communicated to jars 2 + 4, pith electrometer separates 5j. There- fore charge required to make pith balls separate 5f is to that required to make straw electrometer separate i\ as 3184 to 8909, and that to make pith separate 5j to that to make straw separate if as 2920 to 8909. f5 Jars i and 2 being electrified by wire and jar 1 6 by coating till pith electro- (-7 meter separated ij and a communication being then made between them in 51 the manner used for trying Leyden vials, pith balls separate 5^ negative, 5i 5 ri3i6t therefore charge of jar 6 should be -j 1273 . 7 (.1231 Charge of 1 + 2 + 3 + 4= I2544- Jars 1 + 2 + 3 + 4 being compared in the same manner with jar pith balls did not separate at all. M. 2. If the charge of jars i + 2 + 3 + 4 is called 4 jar i or 2 is nearly = i 5. 6, or 7 4 I row of battery = 22 whole battery = 154 Jar 8 being electrified it was found that it must be touched 7^ times by white cyl. to reduce the quantity of electricity to J. The 4 jars must be touched 8£ times by do. Therefore charge of jar 8 = 3|. A piece of crown glass i foot square of which weighed 10-12 was coated with tinfoil about 10 inches square. * [Art. 411.] f [These numbers are given as in the MS. They should be each multiplied by 10. See also Art. 585, where the numbers seem to be deduced from some other experiment.] C.P.I. 19 290 Records of Measures M. 3. The charge of each row of the battery was found by charging to a given degree by electrometer and touching it repeatedly with jar 4 till the separation of electrometer was reduced to that answering to \ the charge. *The Ist, 2nd, 3rd, 4th, 5th, 6th, 7'" row required to be touched 18, 19, 17, i8£, 17, 17, 18 times, therefore charge Ist row = 26 charge of jar 4 2nd = 27-4 3'd = 24-6 4"> = 26-7 5" = 24-6 6»» = 24-6 7th = 26 and charge of whole battery = 180 times that of jar 4 and real charge = 321000 and if real charge by computed of white glass = 7-5, computed charge = 42800 which answers to 187 square feet of glass whose thickness = T'ff. Therefore charge of jar 4 answers to 1-04 square feet of D° thickness. The coating is about T^- of a square foot, and therefore the mean thickness = -058. 582] M. 4. Let jar be touched n times f by jar which is to first as x to i, it will be reduced in ratio of i to (i + x)n, therefore if it is reduced to \ thereby (l + x)n = 2. Therefore let N. L 2 = a and N. L (i + x) = px, pxn = a, i pn and x a x^ / x\ but N. L (l + x) = x nearly, = x ( I J , therefore p = i - - nearly, = i - — - nearly, therefore - = - ( i ) nearly, x a \ 2nJ = " - J nearly, whence we have the following Rule for finding ratio of charge of 2 jars, supposing the charge of first to be reduced to J by touching n times by 2nd. Charge of Ist is to that of 2nd :: i '44471 - \ to i. * N.B. The left-hand row is supposed to be called the Ist row. [If Jar 4 = 2675 circ. inc. (see Art. 506) whole battery = 481,500 circ. inc. or 321,000 glob, inc., counting i glob. inc. = 1-5 circ. inc., as Cavendish seems to do here.] t [Art. 413.] Comparison of Ley den jars ana1 batteries 291 583] M. 5. jar i -i 3184 [circ. inc.] 2 = 3050 3= 3635 4= 2675 5 = 11816 6 = 12544 7 = 11816 8 = 10761 jst row = 64538* Quantity of electricity communicated to whole battery f by B + 2A = 3-61 + 2A 2B + 2A = 7-07 + 2A 3B + 2A = 10-36 + 2A 36 + C + 2A = 13-16 + 2A R = 20-58 R + B = 23-66 D = \ R + 26 = 26-74 R + 36 = 29-83 Quantity of electricity communicated to i8' row by A = -95 B + 2A = 2-56^ 2A=i-8 26+ =4-58 1 3A=2-6 36+ -6-17 1 4A = 3-3 {?4} 3B + = 7-54] Charge of Ist battery of Nairne. 584] M. 6. Electricity of Ist row of old battery was reduced to J by touching nj times by crown glass of 10 inches square. Therefore charge of Ist row to that of crown glass as 15! to i. The first row of new battery appeared by that means to contain 10-7, the 2nd row II, and the 3rd 11-4 times the charge of the same plate. The mean area of the convex coating of each jar seemed to be 14 x iz\ = 175 inches, to which adding 5, id est T% of area of bottom, whole coating may be estimated at 180 square inches of same thickness as sides. fist ( 10 2 row of new battery was reduced to J by touching -j loj 3 1 10 j-13'94 times by jar i, therefore charge = jar i x \ 14-66, and charge mean row U3-94 = jar I x 14-18 = 45,149 inc. el. * [See Art. 506.] f [Here A seems to be the charge of one of the first 4 jars taken as unit, B that of one of the others taken as 4, and K that of the row taken as 22, the battery being 154, as in M. 2.] 19 2 292 Records of Measures By top leaf its charge should be - '• — — = 46390 inc. el., therefore J / 3 its computed charge = = 30100, and thickness of glass should seem _ 180 x 6 x « x fj = 1 30100 585] M. 7. Whether shock of battery is sensibly diminished by imperfect con- duction of the salt water in the jars. An uncoated glass jar like the coated ones was filled with fresh water and put into a glass jar of fresh water, a brass wire with knob being put into it, and a slip of tinfoil into the outer jar, it was charged till straw electrometer separated to 8 and tried by shock melter* filled [with] sea water, wires about 3 inc. dist. The water in inner jar was then changed for sat. sol. s. s. f and that in outer for about equal parts of D° and fresh water, and tried in the same manner. The shock seemed rather greater, but was plainly less when electrometer was at 7. When shock was taken without shock melter* it was as strong with el. at 5 as with D° at 8. Jar 2 being charged to 8 and its electricity communicated to jar, the electrometer separated to 4^. 586] M. 8. Feb. 28, 1775. Specific gravity bottle filled with salt water from torpedo trough weighed 8.4.18 by ingraved weights. Th. at 49. Specific gravity = 1-0254. Being mixed with ^-^ = -3525 its weight of rain water, specific gravity bottle weighed 8.4.1, Th. at 49 \, specific gravity 1-0190. Excess of specific gravity above unity of stronger is to that of weaker as 1-335 to i. The quantity of salt in them is as 1-3524 [to i]. Therefore the excess of specific gravity above i differs pretty nearly, but not quite, in as great a ratio as the quantity of salt in them. M. 9. April i. D° Specific gravity bottle with water from torpedo trough weighed 8 . 4 . 22 by D° weights. April 29. Torpedo trough filled with water to within i inch of top, and 58 oz. salt added. Specific gravity bottle filled therewith, Th. at 70°, weighed 8.4.12. At 54 J same water weighed 8.4.16^. One bottle of sea water weighed 8.4.11, Th. at 67. Another bottle weighed 8.4.19!, Th. DO. Specific gravity bottle with rain water weighs 8. i . 22^. [M. 10 blank.] * [This word occurs also in Arts. 622 and 637. See facsimile at Art. 622.] t [Saturated solution of sea salt.] Investigations on salt water 293 M. II. Rule for finding the quantity of salt in water by its specific gravity. , quantity of salt Let the specific gravity of the solution at 46^ = S, and - .,,,,,,;„„ = *• If S is above 1-0675 1-0261 - = ^ solution I •779 S - i + -0033 •719 X S — I + -O022 •789 779 = 9-8917 L -719 = 9-8568 •784 = 9-8942 vide Heat p. 98*. 587] In 2nd Lane's electrometer or Ist detached do. 40 threads screw = i£ inches, or i division of plate = For 3rd Lane D°. incn- 588] M. 12. June ii. altin Bt Not salting 2 . 19 . 5 3 - 15 - 15 2 . 16 . 10 3 . 8 . 21 3 • ii . I 4 • 5 . 8 3 • J4 • IO 4 • 7 • 9 2 . 4 • 10 2 • 13 . 12 2 . ii . 8 2 . 18 • 13 2 . 12 . 14 3 • 4 . 22 Mahogany Wainscot Beech Ash Alder Lime Deal Weight of the unsalted ones on June 18, and number of vibrations of a pendulum J inches long, in which the electricity of i row of the battery was reduced from 2 to i by pith balls by touching with them, the ends being wrapt round with tinfoil fastened on with gum. Weight Number of vibrations Loss of weight Mahog. 3 • 14 • 12 34 I • 3 Wainscot 3 • 7 • 2O 19 I . I Beech 3 • 15 • 5 36 10 . 3 Ash 4 . 0 . 16 6 6 . 17 Alder 2 . II . 18 200 i . 18 Lime 2 • 15 • 14 22 2 . 23 Deal 3 • 3 • 12 60 I . IO * [Mr Vernon Harcourt, in his Address to the British Association (B.A. Report, 1839, p. 48), has given extracts from Cavendish's MS. on Heat, p. i to p. 50, but he does not mention any page 98.] {See Vol. n of this Edition.} t [Art. 609.] { [So in MS.] 294 Records of Measures M. 13. The salted ones taken out of water two or three hours weighed Mahogany Wainscot Beech Ash Alder Lime Deal 3 • 15 • 14 3.9.0 4.8.0 4 . 14 . 12 3 . 9 . 22 3 . 17 . ii 3-1-4 June 19'". Bits of tinfoil were fastened round the ends of these pieces of wood with gum. 26 being electrified to ij and its electricity communicated to the whole battery gave a slight shock when received through the Lime, Alder, Ash and Beech, but most through the Lime. iR + 36 through wainscot and 2R + 36 through deal gave much the same shock, and 3R was just sensible through Mahogany. 589] M. 14. Dimensions of coatings made to pieces of glass D, E, F, G; A, B, C, I, K, L, M, H. [See Art. 324.] M. 15. Bluish-green ground glass from Nairne called R and S, M. 16. Logarithms for calculations of these plates. M. 17. Do. M. 18. Straight piece of elect[rifying] wire, thickness -15, length 30. Increase of quantity of electricity in wire of that thickness by increasing its length from 33 to 53 inches = 4-53 inches, therefore increase of quantity of electricity in wire = increase length x -226. The two trial plates of white plate glass, which contain together 66 inches of computed power, or 66 x 1-6 inches of electricity, were balanced by twice the sum of the double plates A and B + 48 of additional wire = 73-4 + 10-85 = 84-2 inc. el., therefore 10-7 inc. el. is to be allowed for the usual length of the wire. [Rules for making trial plates.} M. 19. By p. 21 [Art. 459] it should seem that the difference between two trial plates ought to be to their sum as L + S + 20 inc. of wire to L + S, or as 20 x -226 . 3-6 -I 7 — to 66, or as 32 : 330. {D 12-16 E of Nairne are to be coated with circles -j 2-16 in diameter. F [2-19 The mean quantity of electricity in the trial plates should be 47-4 inc. if nothing is allowed for additional wire, therefore if this is increased by ^ to allow for uncertainty, and the plate „ is used for , a trial plate, the com- Conductances of salted substances 295 puted power should be ' ,'j , and [M. 20] the coating should be a square 33'°° whose side = 2-27 Quantity of electricity in small thin plates to be uo-r, computed power = 67-8, diameter of circles to be I = 2-299 K = 2-286 L = 2-358 M = 2-207 The trial plates to them to be made of plates I and L quant" el" of that comp. power glass supposed = 1-95. Computed power of mean between the two plates to be I2° x -- - = 68 1-95 10 = a square of 1-933, the thickness of the glass being -07, therefore Small = L) , (2-126 , Large = I } = ''933 long and {^ Abroad. 1-62 IL 1-74 were made to I Oblong coatings 1-82 long and \ (2 2-14 K M. 21. j > trial plate for large thick plates |F to be coated with oblong square |^ by 6. Dimensions of trial plates. Length Breadth A 16-4 II-8 B 13 97 C 10-4 7-8 D 8-5 6-4 Sliding Plates. Value of i division in Number of Plate Inc. el. Parts of D Ist -75 -0208 2nd 1-50 -0416 3rd 3'37 -0940 4th 8-57 -238 5'" 19-0 -530 6th 18-0 -500 I inch additional wire -226 -0063 296 Records of Measures [From this table it appears that D is supposed to contain 36 "inc. el. Now, by Art. 655, D contains 26-3 "globular inches," which is equal to 41 "circular inches," or 36-7 "square inches."] [Specimen of Measurements of thickness by dividing engine.] 590] 2nd rosin plate, [Arts. 371, 500] mean diameter 5-6. M. 23. At 2- 1 10 knobs coincided, 2-306 1 05 1 center 2-3057 06 1 } one inch [from center] 2-3045 04 047 2- no coinc. 2-IIO coinc. 2-306' 04 06 05 oo 02 ij inc. from center 02 2-303 OO 02 02 02 2-110 come. Mean thickness =-195. 591] M. 32. Measures of thickness of crown glass [Arts. 370, 500] measured in the middle of each i6th square part, the numbers being placed in the same situation as the squares. C. At i-88r the knobs coincided. 1-944 48 51 48 48 52 52 44 53 53 46 38 53 46 40 34 mean 1-947, thickness -066. Measures of glasses for condenser plates 297 {From MS. N°. 13.} 592] M. r*. List of Plate glasses. First got. Made into trial plates and cased in cem[ent] of a greenish colour inclining to blue with a great want Of transparency. not used. coated, comp. pow. = 46. Same sort of glass as A and B, but from their greater length and breadth I could not so well judge of their ... , colour. Made up into trial plates. Same kind as C and D. Remains not approp. H is marked on side with single scratchof file, I with 2, and so on to L. Made into trial plates and broke except L. More transparent than the thick plates, not used. The thickness was measured in the middle of each side, beginning with that side to right of letter, the letter being held towards eye. Thickness Diam. coating Comp. power Double plate ground glass A -3 1-82 11-04 B -31 1-855 "'I Ist got from Nairne. 2 thickish plates of 8 inc. made into trial plates for 2nd sort, called S and L. Another cut into 4 pieces for trying effect of different varnishes. A 4th not used. 2 thin ones of bluish glass coated in order to serve for trial plates to largest plate, and called L and S, but not used. 2 thick plates and i thin one rough. 2 white glass plates from Nairne. 4 pieces out of same piece with different sorts of surface. A large piece of whitish plate glass divided into 3 pieces, one used for sliding trial plate. 4 irregular shaped pieces called N, O, P, Q. [Art. 459.] 2 thinnish pieces 5 inches square with very thin plate rosin between. M. 2. i piece of much the same kind fastened to piece of crown glass with cement between, used for sliding plate. * [Here follows another series of measures oil loose leaves of different sizes.] 298 Records of Measures 593] M. 3. N airne's plates of same piece *. Out of water Loss in water 4 thin pieces 7- 1-14 2. 12. 21 7-079 4 thick do. 19. 3.11 7- 3- 4 19-173 large thin piece 7. 0. 2 2.12. 7 7-004 A 19. 6.17 7. 4.10 19-335 B I9.I2.II 7. 6.13 19-623 19. 1.16 7. 2.13 19-083 2-644 2-6774 7-158 2-6785 2-6i5 2-6785 7-221 2-6776 7-327 2-6782 7-127 2-6775 Mean 2-6779 I cub. inc. water = -5278 oz. I oz. of glass = 9-84973 cub. inc. [The weights in Ist & 2nd column are in ounces, pennyweights and grains (Troy), in the 3rd and 4th in decimals of an ounce, and the 5th is the specific gravity. The number 9-84973 is the logarithm of the number of cubic inches in an ounce of glass.] M. 4. [Gives Ist the length of each side of each piece of glass, and the distance between the middles of opposite sides to hundredths of an inch. 2nd the thickness at each corner and middle of each side to thousandths of an inch. 3rd specific gravity and mean thickness deduced from it for plates A to M of Nairne. The results are given in M. 5. The thicknesses are as follows: Thickness calculated Measured Diff. A •2112 •2095 •0017 B •2132 •2109 23 C •2065 •2057 8 D •2057 -2047 10 E •2065 •2055 10 F •2115 •2IOI 14 G •2O22 •2103 9 H •07556 •0735 21 I •07797 •0759 21 K •07712 •0755 16 L •08205 •0804 16 M •07187 •0707 12 [The thicknesses given in Art. 324 are those calculated from the weight in and out of water and the measurement of the sides. They are greater than the measured thicknesses in every case.] 594] M. 6. Measures of thickness &a of green glass cylinder. Longest cylinder : a mark made with file near middle. The i8' column is the distance in inches of the point to which cylinder is immersed in water from the scratch. * [Art. 314.] List of measured cylinders and Ley den jars 299 The 2nd column is weight required to balance it in that position. The 3rd is the same thing in the 2nd trial. The 4th is the difference of these numbers, or bulk of intermediate portion of glass. The 5th is the same thing in 2nd trial, and The 6th is the mean between them. The 7th is the circumference in the middle of that space. Bulk int. space Towards I»< 2nd by wide end tri[al] tri. ,st 2"<1 Mean Circum. 13 II . 12 . 15 12 . 22 1 . 13 I . 12 I . 12 . 5 3-595 12 II . II . 2 II . IO 2 . 22 2 . 22 2 . 22 3-435 10 II . 8. 4 8 . 12 2.18 2.17 2 • 17 • 5 3-265 8 II . 5 . 10 5 -19 2 . 20 2 . 21 2 . 20 . 5 3-140 6 II . 2 . 14 2 . 22 2 . l6 2.18 2.17 3-020 4 IO . 19 . 22 17 . io 2.18 2 . l8 2.18 2-940 2 10.17. 4 17 . io 2 .23 2 . 21 2 . 22 2-905 0 10 . 14 . 5 14 • 13 [after this a table for the narrower half of Ist cylinder, and in M. 7 for 2nd, 3rd and 4th cylinders. M. 8 and M. 9 is a table of n columns. Ist column, distance from mark. 2nd Mean loss [of weight] for 2 inches. 3rd Suppfosed] mean circumference. 4th Log. loss. 5th Log. supp. circumference]. 6th Log. thickfness] x p. 7 Thick, x py> = ratio of circumference to diameter]. 8 True mean circ. * 9 Log. do. 10 Log. comp. power of i inch. 11 Comp. power of i inch.] M. io. Measures of the circumference and substance of glass in jars and cylinder. Marks with file are made at the extremities of the whole space, and the numbers begin with the space marked with double mark. * By mean circumference is meant the mean between the inside and outside circumference. 300 Records of Measures The circumference was measured by a slip of tinfoil put round, and the intersection marked with knife. The substance of glass was found by hanging it to end of sliding ruler fastened to one end of balance, and weighing it in water; and by sliding the ruler I made more or less of it to be immersed, and knew the difference of the space immersed. M. ii. Specific gravity of different pieces of white glass. Large jar 3-253 3-253 small D° 3-256 3-257 long cylinder 3-281 3-279 thick flat glass 3-280 3-279 thin do. 3-280 3-284 The small jar being broke, a 2nd was measured. Thickness measured by calipers in 4 different rows parallel to axis and in 5 different places in each row, beginning at a scratch with a file near bottom. [Here follow the measures.] The thickness was then tried in 4 different parts of circumference at 4-4 inc. distance from scratch. It was then weighed in water in the same manner as the others. The jar was dried before each trial, and before the 3rd was rubbed with solut. p. ash*, which made the water stick less to side, for which reason it is supposed most exact. The circumference was measured in two parts of the middle space, and they came out both the same. 595] M. 12. Measures of coatings to jars and cylind.] A coating made to 2nd small jar extending to 4-4 inqhes from scratch. Comp. power = 680-7. Coating to white cylinder extends 9-86 inches from double mark. Comp. power = 684-1. A coating made to 4th green cyl. extending 7 inches from mark. Comp. power = 318-2. A mark was made on wide part, extending 7-16 inc. from new mark. Comp. power 600-7. M. 13. A mark made on 2nd green cylinder 11 inches from first towards thick end, and the tube cut off about i inch from Ist mark. A coating made to the thick part extending 8-55 inches from 2nd mark. Comp. power = 600. * [Pearl ash.] f [See Art. 383. The computed power here is 8 times the true value, and there is no correction for spreading of electricity.] EXPERIMENTS WITH THE ARTIFICIAL TORPEDO [1775] {From MS. N°. 20. See Table of Contents at the beginning of this volume.} 596] Torp. i in water touching sides*. 3 rows ijf felt plain shock in hands. 4 - more brisk in D°. 7 - more violent in D°. 2 plain in D°. I sensible. + 2 + 3t 4+1 + 5 + 6+ 7 — but just sensible. Out of water. 4+1 uncertain. 4+1 + 2 sensible. 4+1 + 2 + 3 D°. 5 + 4+1 sensible in elbows. 5 + 6 gentle in elbows. 5 + 6 + 7+1 + 2 + 3 + 4 strong in elbows, i row more violent. Uncoated, out of water. 4 scarce percept. 4+1 sensible. 4+1 + 2 gentle. In water. 5 + 6 + 7 perceptible. Without any torped. jar 4 was perceptible. I could not perceive any sensible difference in the conducting power ot the water I used & of sea water, but the difference caused by mixing ^ part of rain water with the sea water was scarcely perceptible. (distilled water\ I i are to each < Tfi go io §N.B. resistance of -jsat. sol. in "j. other nearly •< IOO (sat. sol. as (702 * [Art. 415.] f [3 rows of battery electrified till the electrometer separated to ij.] { [These numbers are those of the jars of the first row of the battery. See Art. 583.] § [This should be conducting power, instead of resistance. The numbers then agree with those in Art. 684.] 302 Torpedo 'Experiments^ April, 1775 so that there seems no reason to think that the resistance of water about the saltness of sea water varies in a quicker ratio than that of the quantity of salt in it. Without torpedo jar 1 + 2 + 4 was very sensible in elbows, but 1 + 2 was felt only in wrists. 597] Let a given charge be passed by double circuit through your body and another circuit; let the quantity of electricity which passes along the second circuit be to that which passes through your body as * to i ; the rapidity with which the fluid passes through your body is the same whatever is the value of x, and the quantity which passes through your body is * as i + x. If the resistance which the electricity meets with before it comes to the double circuit is to that which it would meet with in passing through your body alone as a to i, the force required to drive electricity through the whole circuit in given time is as a + - - , and therefore the time in which it is i + x I T. I V discharged = = , and the velocity with which it passes i i + a + ax a + - i + x through your body is as — , and the strength of shock is as i + a + ax (i + x} (i + a + ax) ' In trying resistance of liquors by double circuit, if the quantity of elec- tricity which passes through the liquor is to that which passes through your body as x to [i], the quantity of electricity which passes through your body is as - — , and the rapidity with which it passes through your body is given. I ~T~ X In trying it with single circuit, if resistance el. in passing through liquor is to that in passing through your body as x to i, velocity of electricity is as - , and the quantity is given, therefore in both ways of trying it, the I ~T~ X greater x is, the more exact will be the method, and both methods will be equally exact if x is given or very great, supposing the strength of the shock to be as the quantity of electricity into its velocity f. (16 598] Shock produced by charge -i 22 in water bears the proper proportion (44 f 6 to that caused by charge j 8 out of water. Ii6 * [Should be inversely as i + x. The rest is a correct statement of the strength of derived currents according to the law afterwards published by Ohm. See Art. 4I7-] f [The "velocity" is what is now called the strength of the current. The strength of the shock is assumed to be proportional to the energy of the discharge. See Arts. 406, 573, 610, and Note 31.] Electric current in divided circuits 303 It is supposed that it required about 2f the charge to give a proper shock in water as [it does] out, or it is supposed to require 5 times quant, el. It is supposed too that it requires 2ce charge of 3 times quant, el. to give same shock with torp. out of water as without torp. I body | i torp. be as J2 , if quant, el. which water la passes through torp. is increased to zn, quant, el. which passes through your body || in wat. ... , , will be 4 , therefore out wat. a + 2 + i must = - , or in + i 3x5 i5« + 30« + 15 = 2na + 6n + a + 3, n (za + 6 — 30) = 14* + 12, 140 + 12 n = - - . which if a = 60. is 2« - 24 I4« 7 * 5 = 20. x | 4 and therefore it should require about 9 times quant, el., or about 5j times the charge, to give the same shock out of water as at present. 599] Tu. Mar. First leather Torpedo*. Out of water. i row jars el. to ij by straw el. and commun. to rest, a shock just sensible in elbows. 1 + 2 + 3 + 4 + 5 + 6+7: just sensible in hands. D° + r row: stronger than NO i. In water. 2 rows : plain in hands, 1 row: just sensible, 3 rows : rather stronger than 2 D° out of water. 600] Tu. Apr. 4 [1775]. 2nd leather Torpedo. Out of water, 5 + 6 + 7 : very slight in fingers. 2 rows : only in hands, there seemed to be something wrong. 4 rows: brisk in elbows. 2 rows: briskish in elbows. * [Art. 416.] 304 Torpedo Experiments, May, 1775 In water. 2 rows just sensible in hands. 3 rows stronger. 4 rows pretty strong D°. Ist leather Torpedo in water. 4 rows nearly same, but I believe not so strong as last. 2 rows very slight. Out of water. 2 rows slight in elbows. 4 rows strong in elbows. 601] Sat. May 27 [1775] with 2nd leather Torpedo under water, 3 rows charged to i\ on electrom. * Shock with one hand to one person seemed stronger, to another weaker than with both. Communication being made with metals instead of the hands, no shock was felt, but when all the rows were charged to 3, Mr Ronayne felt a small shock. With wooden Torpedo, i row to i\; shock passed across 27 links of heavy chain with light. It also passed across 4 links of small chain with light, but not across 6. Without Torpedo, 5 + i + 2 to i|; shock passed with light through elec- trom., no candle in room; also with torp. charged as in trial. On a former night in trying wooden Torp., charged I believe much the same as this time, no light was perceived, though Mr Hunter felt a shock, but very weak. One candle in room, hid as well as possible behind screen. With Gymnotus, all rows charged to 3$. Doubtful. Dr Priestfley] and Mr Lane touching with i hand at same time, Dr Priestly felt shock extend to elbow. A former night, 3 rows charged to \\, Mr N. thought the shock extended to elbow; no one else thought so. Sat. May 27 [1775]. 602] Old Torp. out of water 26 + A (8-i)f, tried with metals, weak shock; New torp. B + A (4-6) as strong as former. The old Torp. tried with one hand holding metal against bottom side, in other hand holding bright link. * [Art. 419. The (artificial) Gymnotus is not elsewhere mentioned.] f [The numbers in brackets are the charge communicated to the battery or the row. See Art. 583.] Shocks in and out of water 3°5 3A (3) no shock, with B (3-6) a very slight shock when torp. was just wetted, none else. With long link, not bright, 3 A, (3), sometimes left it, not always; with 2 A never. With wire of same size bright without link, seemed not to feel it so well. With small link not bright no shock with B + A (4-6), but there was with B + 2 A (5-6); with bright wire without link felt shock with B + A (4-6), but not with B (3-6). With dirty link 2B + A (8-1), sometimes a small shock, not always; with 28 + 2A (9-1), certain. 603] Tried with Lane's electrom. ; dirt unaltered. Rows of batt. to which el. is comm. Jars el. Equiv.* I R+ 2B 26-7 shock 7 1 R+ B 237 none. I I J B + 2A 4-56 small shock. 1 1 B + A 3-56 : none. 7 I R-f- B 23-7 shock 7 1 R 20-6 none. -7 I R+ 26 26-7 shock 7 1 R+ B 237 none. I I B + 3A 5-6 shock 1 \ B + 2A 4-6 none. 7 1 R+ 26 26-7 shock 7 ( R+ B 237 none. r 1 B + 3A 5-6 shock 1 i B + 2A 4-6 none. Tu. May 30 [1775]. 604] It was tried whether distance on Lane's electrom. at which jars dis- charged was the same at the same separation of straw & pith ball electrom. whether number of jars was great or small f. This was tried first by laying small knob'd Lane on wire while jars were charging, and afterwards by charging jars, without Lane lying on wire, to a little greater and little less degree by electrom. than what it was before found that they discharged at; then touching them with Lane, I could not perceive that the number of jars made any difference. It was tried by comparing i & 4 jars with straw el. at 2 and by comparing i and 7 rows of battery with pith balls at i. It was also tried whether the number of jars electrified affected the separa- tion of straw el.: by connecting 4 jars to the wire & then withdrawing 2 of them. It was not found to be at all affected. * [See Art. 583.] f [Art. 402.] c. P. i. 20 306 Torpedo Experiments, May, 1775 Tu. May 30 [1775]. 605] Charge required to force el. through 4 links of small chain, and also through 2 loops of machine*, 5 links of chain in each loop. Rows of Batt. Jars el. Equiv. 7 R 20-6 passed through 4 links 38 + C + 4A 17-1 did not old R 20-6 passed through 2 loops torp. 3B + C + 4A I7-I did not 36 + C + 4A I7-I passed through 4 links 26 + 4A II-I did not new R 20-6 passed through 2 loops torp. 36 + C + 4A 17-1 did once, failed once R 20-6 passed through 4 links ' 36 + C + 4A 17-1 did not 2nil R + 36 + C 33 passed through 2 loops h leather R 20-6 did once, failed once torp. 36 + C + 4A 17-1 did not , leather torp. R = 20-6' old 2B + A = 8-1 gave same new B + 3A = 6-6 shock. without torp. A + D — 1-5 Tried with new Torpedo. Rows Batt. Jars el. Equiv. 7 I B + A 3A + D 4-6 3 I gave same shock. 7 2B + 2A 9-1 gave same B + 3A 5'4 I shock. Trial of charge required to pass through 4 links of chain. i 3A 2-6 sometimes passed, sometimes not. 7 36 + C + 4A 17-2 D°. i 4A 3'3 passed. 7 R 20-6 passed. 7 i 36 + C + 4A 3A 17-2 2-6 > did not. Tried with 2 loops of machinef. [Rows Jars el. Equiv.] 7 36 + C + 4A 17-2 [ did not. I 4A 3-3 f I B + A 3-6 1 did. 7 R 20-6 1 i B + 2A 4-6 did not. i B + 3A 5-6 did. 7 R 20-6 did. i B + A 3'5 did not. i B + 2A 4'5 did. i B + A 3'5 did not. i B + 2A 4'5 did. * [Art. 433.] f [Arts. 433, 605.] Shock through loops of chain 307 3B + C + 2A = (9-2) commun. to i row, 2ce passed through 2 loops, once missed, once did not pass through 3, never through 5. R communicated to 7 rows = 20-6 was tried 3 times without ever passing through 3 rows. Wed. May 31 [1775]. 606] i jar was elect, and commun. to i row of battery, and shock taken without torpedo. There seemed a little difference in the strength of the shock according to which row it was communicated to, but hardly more than was observed at different times from the same row. Result of exp. May 30. 607] By mean, quant, el. req. to give same shock with 7 rows is to that with i :: 18-3 : 11-5 :: 1-6 : i*. Charge req. to force through j b with 7 rows is to that with I in rat. (6-6 to i Sr j6-2 to i KTI mn ^ j6~4 to i to i ' ^— . w^-w (6-6 to i „ (6-2 to i (6-4 between < & < , by means as { \5-7toi 1 3-7 to i' (4-8 Tu. June 6 [1775]. 608] The 2nd leather Torp. was tried in sandf wetted with salt water. The Torp. lay flat on sand and was covered by it all but pos. elect, parts & middle of back. With 3 rows charged to ij, felt a shock whether I laid bare hands on torp. & on sand 16 inc. dist. from nearest part of D°, or whether I touched torp. with metals. In latter case shock seemed much the same as shock 10 inch plate crown glass { received through Lane's el. at - - inc. If I laid pieces of sole leather§ which had been soaked in salt water for a week and then pressed between paper with £ hundred weight for J day to drain out moisture on torp. and on sand, and received shock with metal that way, shock was about equal to that of 10 inc. plate with Lane at - 1600 The torp. taken out of sand and tried with metals in usual way gave shock about equal to D° plate, Lane at i8J. Being tried in same manner with i row, shock was weaker than in sand through leathers, & with 2 rows stronger than without leathers. The spe. gra. bottle with water which came from sand weighed 8.4.11. Th. at 69, so that the water with which it was moistened appears to be of right strength. 609] Bits of beech, wainscot & deal|| about f inch square were soaked in salt water for 3 or 4 days, then taken out and wiped and exposed to the air in dry room for about 6 hours. * [Arts. 406, 573, 610, and Note 31.] t [Art. 422.] J [Arts. 411, 430.] § [Art. 423.] || [Art. 588.] 20 2 308 Torpedo Experiments, June, 1775 The shock of the Torp. was received touching pos. el. part with metal and neg. with one of these bits, the end which touched the torp. and that part which I held in hand being bound round with tinfoil. With 6 rows elect, to ij, I felt slight shock through wainscot: dist. tinfoils 2 inc. With D° charge through deal, tinfoils at i inc., none. With 3 rows to ij; received shock through beech, tinfoils at 4f inc. dist., about as strong as with ij rows when touched with metals on both sides. With D° charge through 4^ inches of dry deal dipt in salt water and tried the instant it was taken out, none. Taking hold of tail in one hand & touching pos. side with metal, brisk shock. When touching neg. side with metal much slighter, the exper. tried with each pos. and each neg. part. Mon. June 12 [1775]. 610] Jar i elect, to 2j by pith el. seemed to give shock of same strength as B + 2A comm. to whole battery; it was weaker than 2B and stronger than B commun. to D°, but as there is a good deal of difference between the sensa- tions of the 2, it is not easy comparing them. According to this exp. the numb, jars which el. should be divided amongst in order to produce given shock should be as the 2| power of quant, el., and therefore el. 2 jars should be comm. to 5^ more in order to produce same shock as i jar*. Mon. June 18 [1776 f]. iR + 36 + C + 2 A comm. to 7 rows = (34^), & el. to a given mark on pith el. gives shock equal or rather greater than i row el. to same degree and not commun. to rest. iR + 36 + C + 2 A elect, to i J on straw el. and comm. to rest always passed through i loop of machine. The same elect, to i sometimes passed, sometimes failed. i row charged to i and not commun. to any more passed 3 times through 5 loops without once failing. iR + 36 + C + 2A el. to i and comm. to rest would never pass through 2 loops. 611] 2nd Leather torpedo tried under water with metals with glass tubes on them, all rows charged to 4 gave briskish shock, which was much greater than shock out of water with i row to i \, but rather less than with 2 rows to D°. The shock received in same manner with i row not communicated to rest was less when el. to ij, and about equal when el. to 2j. * [Arts. 406, 573, and Note 31.] f [Probably June 19, 1775.] Shock through various substances 309 With 7 rows el. to i £ shock of D° Torp. when received through the salted lime tree wood gave slight shock about equal to 3A passed through same wood without torpedo. Charge of 7 rows el. to 4 is to that of if row el. to ij as - — =— : i : : 12 to i. 3 612] Tu. July 4 [1775]. 2nd leather torp., the wire belonging to convex side fastened to outside of battery and inside of battery touched by wire of flat side. 3 rows of battery charged to i\ and comm. to remainder. Under water no sensible diff. whether I touched convex or flat side with one hand. Out of water, touching tail with one hand and one side of one elect, organ with metal, a much greater shock if I touched convex side than flat side. The event was the same if it was elect, by neg. elect. Touching convex side of both organs with one hand, only standing on electrical stool, a shock in that hand, but I think scarcely so strong as under water. Touching flat side in same way, much the same. Laying i finger on convex surface of one organ & another finger of same hand on the middle of the convex surface, a very slight shock. Laying one finger on convex surface of one organ & the other on the nearest edge of the torpedo, a considerably greater shock, but not strong. Laying one finger on convex and another on flat side of same organ, a con- siderably greater shock, but do not know how to compare it in point of strength with that taken the usual way. Tried without any torpedo *. 613] 36 being comm. to 7 rows and passed through i loop of 26 links of small chain. If the chain was not stretched by any additional weight, the shock did not pass. If the middle link was stretched by a weight of 7 pwt. it passed, & the light was visible in a few links. If it was stretched by a weight of 13^ pwt. no light was seen. There was no remarkable difference in the strength of the shock, whether it was received through chain tended by 13^ pw. or without chain. The chain was fastened to the same machine that was used in a former experiment, it was 7-9 inc. long and the distance of the supports 5-1. The room was quite dark, it being tried at night without any candle in the room. 3 rows of battery were elect, till pith el. sep. to i, its el. was then comm. to the rest of the battery, & I received the shock of I row, the elect, having its choice whether it would pass through my body or through some salt water. * [Art. 437.] 310 Torpedo Experiments, July, 1775 I then elect, i row of battery till pith el. sep. to same degree, and commun. its elect, to rest of battery and received the shock of 5 rows of it in same manner. The shock seemed to be nearly of same strength, perhaps rather less. Therefore shock of 5 rows elect, to a given degree seems about equal or perhaps rather less than that of i row el. to 3 times that degree. 614] The mean thickness of the section of the elect, organ in the section given in Mr H.* paper, in which the breadth is 10-3 inches, that is, the same as I2l my torpedo's, is 1-3 inc.; the area of one organ is 2-5 x 5j x = gj sq. inc., as found by cutting out a piece of paper of that size and weighing it. And according to Mr H. there are about 150 partitions in i inch, therefore comp. charge both organs reckoned in old way is 19 x 1-3 x 150 x ^ x 150 = 748,000, and the real charge is 1122,000 inches of el. supposing the partitions to consist of plates of white glass ^^ inc. thick, which is about 2\ times as much as my battery, that being = 451,000 inc. el. 615] Tried with the 2nd leather torpedo, new covered, in large trough full of water, the torpedo laid flat as in figure, the electrical organ being (as supposed) 3 inches under water. If torpedo was tried out of water with i row to i\ comm. to 7 and touched with hands in usual manner, the shock was just felt in hands, and if touched with metals, was just sensible in elbow. Tried under water in above-mentioned manner with 7 rows el. to 4, the upper surface being touched with the pestle of a mortar held in one hand, the other hand dipt into water as far as wrist, a shock in the wrist of the hand in the water I believe full as strong as the former. The place where the hand was dipt into water was about n inc. from the front of the fish, and conseq. about 14 from elect, organ. Tried in the same manner as before, except that the fish lay in an open wicker basketf, just big enough to receive it, and which had been soaked for some days in salt water. The shock seemed much the same. Holding hand in water in same manner as before without touching torpedo — no sensation. With three rows to ij out of water, the shock was stronger if I touched convex side with one hand laid flat on elect, organs than if I touched flat side in same manner, but the difference was not great. Charge of 7 rows el. to 4 is to that of i row el. to ij as 19-6 to i. The water appeared by its spe. gra. to contain .^ of salt. * ["Anatomical observations on the torpedo." By John Hunter, F.R.S., [Phil. Trans. 1773]. Art. 436.] t [Art. 421.] [ 3" ] [EXPERIMENTS ON] RESISTANCE TO ELECTRICITY [1776] •From MS. N°. 19. See Table of Contents at the beginning of this volume. See also near the end of the Introduction.} 616] Comparison of conducting power of salt and fresh water in the latter end of March and beginning of April, 1776. Tried with Nairne's last battery, 6 jars being chose, each of which held very nearly the same quantity of electricity; the wires run into the bent ends of the tubes being made to communicate with the outside of the battery, and the wires run into the straight ends being fastened to separate pieces of tinfoil. The six jars were all charged by the same conductor: the communication with that and each other was then taken away, and the jars discharged through the tubes, one after the other, by touching the above-mentioned bit of tinfoil by metal held in one hand, and the wire of the jar by metal held in the other hand, the shock being received alternately through each tube. 617] Exp. i. Distance of wires In tube 15 t4 6-5 inc. 5-8 3'5 4-2 5'3 40-7 Sat. sol. S.S.* in tube .14, salt in 69 of water in tube 15 in short tube than in long one very sensibly less sensibly less sensibly greater scarce sensibly just sensibly less Straw electrom. = 4. Th. = 57. [Resistance = 390000 Ohms, f] Resistance of 4-7 inches in tube 15 supposed equal to 40-7 in 14. Therefore sat. sol. conducts 8-6 times better than salt in 69 of water. Exp. 2. The same solution tried in tubes 22 and 23. Tube 23 22 electrom. at i \. Th. = 58. [R. = 118000] f. 3'3 5'5 sensibly greater. less in same proportion. 4-4 inches in tube 23 = 41 in tube 22. Therefore sat. sol. conducts 8-94 times better than salt in 69 of water. * [Saturated solution of sea salt.] •f [The resistance of the saturated solution in Ohms, calculated from the measure- ments in Art. 635 by Kohlrausch's data, is given for each tube within brackets to indicate the absolute value of the resistances compared.] 312 On Resistance to Electric Current Exp. 3. A new saturated solution and solution in 69 of water made and tried in tubes 15 and 14. [R. = 390000.] 3-5 40-7 just sensibly greater. Electrom. = 3. 3- 1 very plain. Th. = 57. 5-5 sensibly less. 5-0 just sensibly less. Therefore new saturated solution conducts 9-61 times better than new solution in 69. Exp. 4. Salt in 69 of water compared with salt in 999 of water in tube 22 and 23. • [R. = 1230000.] 23 22 Electrometer = if. 3-1 41-1 sensibly greater. "*• = 57- 3-5 scarce sens. 4-3 scarce sensibly less. 4-9 just sensib. 5-3 very sensib. Resist. 4-1 in tube 23 supposed equal to 41-1 in 22. Therefore salt in 69 conducts 9-57 times better than salt in 999. Exp. 5. Salt in 999 compared with distilled water in tubes 12 and 20. [R. = 462000.] 20 12 Electrom. = 3. Th. = 58. •78 43-5 sensib. greater. 1-2 scarce sensib. less. 1-4 diff. more sensib. than in i" trial. 1-05 supposed right. Therefore salt in 999 conducts 36-3 times better than distilled water. The distilled water changed for rain water. 1-9 3-3 2-55 sensib. greater. Electrom. = 3. Th. = 58°. less, rather more sensib. than former, supposed right. Therefore rain water conducts 2-4 times better than distilled water, or 15-2 times worse than salt in 999. The rain water changed for distilled water with ^fo^ of salt in it. 5-3 2-7 sensib. less. about as much greater. Therefore salt in 20,000 of distilled water conducts [3-67] times better than distilled water, or 9-92 worse than salt in 999. Solutions of sea salt compared 3 i 3 [6] Saturated solution and salt in 69 of water (the new solutions) compared in the same manner, only using the jars i and 2 instead of the battery; with the tubes 5 and 17. 17 5 [R. = 25100.] 2-6 41-1 sensib. greater. 5-5 sensib. less. Therefore saturated solution conducts 10-05 times better than salt in 69 of water. 618] The electricity of the 6 jars was found to be as much diminished by being communicated to 3 rows of the battery as that of i row is by being communicated to 4 rows, therefore quantity of electricity in the 6 jars is to that in one row as 3 to 4. Exp. 7. Saturated solution and salt in 69 (the new solutions) tried in the same manner with battery; i row being electriffed to 2, and its electricity communicated to remaining rows, and one row used at a time. Tried in tube 5 and 17. [R. = 25300.] i? 5 5-4 41-4 plainly less. 2-6 about as much greater. 3-0 scarce sensibly greater. 5-0 just sensib. less. 3-95 supposed right. Therefore sat. sol. conducts 10-31 times better than salt in 69. Exp. 8. Saturated solution compared with salt in 29 in tubes 22 & 23 with Nairne's jars. 8-7 4-8 22 24-9 Electrometer i. Th. 63. [R. = 65000.] just sensibly less, about as much greater. The bore of that part of tube 23 which was used is supposed ^ greater than that of whole tube together. Therefore sat. sol. conducts 3-51 times better than salt in 29 of water. Exp. 9. The solution in 29 diluted with i J of water, id est, solution of salt in 69, compared with sat. solution in same tubes. 23 22 Electrom. = i. Th. = 63. [R. = 65000.] 2-0 24-9 greater. 3-8 about as much less. Therefore sat. sol. conducts 7-79 times better than the diluted solution, and the diluted solution conducts 2-2 times worse than solution in 29. 3*4 On Resistance to Electric Current Exp. 10. Saturated solution compared with salt in 69 in same tubes. 23 22 [R. = 65000.] 3-1 24-9 sensib. less. Electrom. = i. Th. = 63. 1-9 as much greater. Therefore sat. solut. conducts 9-02 better than the solution in 69. 619] Examination whether salt in 69 conducts better when warm than when cold. Salt in 69 in tube 17 placed in water; solution in 29 in tube 23 out of water, the distance of wires in tube 17 being not measured, but remaining always the same. Electrometer = f . 23 8-1 . sensib. less 5 about as much greater) 4 plainly less ) . , , v heat of water = 105. 2-6 as much greater j Therefore salt in 69 conducts 1-97 times better in heat 105 than in that of 58J*. 620] Examination whether the proportion which conducting power of sat. sol. and salt in 999 bear to each other is altered by heat. Sat. sol. in tube 15, salt in 999 in tube 19, both in water; distance of wires in tube 15 not altered. 19 Electrom. = r} h« of water = 58 J. 3-25 2-15 2-25 3'5 sensib. less \ sensib. greater) just sensib. greater heat of water 50. electrom . = i. rather more sensib. less) heat of water 95. Therefore the proportion seems very little altered by heatf. 621] Jan. i, 1777. Salt in 2999 of water compared with water distilled in preceding summer in tubes 12 and 20. Electrom. = 4^. 20 1-4 12 43-5 rather greater. Column of 1-6 in tube 20. plainly less. Supposed equal to 43-5 in tube 12. greater. Therefore allowing for different bores of tubes, salt in 2999 conducts 24 times better than distilled water. * [By the experiments of Kohlrausch, this ratio would be 1-59. See Art. 691 and Note 33.] | [This agrees, with the results of Kohlrausch.] Distilled and salt water compared 3 1 5 Jan. 2 M. Same experiment repeated with the same water, which had been left in the tubes all night. 20 12 1-4 plainly greater. 1-9 seemingly less. 2-1 plainly less. Therefore salt in 2999 conducts 22 times better than distilled water. The same experiment repeated, only the water in the tubes was changed for fresh by pouring out the old and putting in fresh by small funnel, without taking out the wires. plainly less. i-i •35 7 plainly greater, plainly less. Therefore salt in 2999 conducts 72 times better than distilled water. The same experiment repeated, only the distilled water changed for that used in the preceding year. •4 considerably greater, i-i plainly less. -8 supposed equal. Therefore salt in 2999 conducts 47 times better than distilled water. Jan. 3. Experiment repeated with the same water left in. •8 plainly greater. 1-2 plainly less. Therefore salt in 2999 conducts 38 times better than the distilled water. The distilled water changed for the new distilled water. •28 plainly greater. •6 plainly less. Therefore salt in 2999 conducts 86 times better than distilled water*. Salt in 2999 compared with salt in 150,000 in same tubes. 1-2 43-5 sensib. greater. Electrom. = 4j. 1-7 sensib. less. Therefore salt in 2999 conducts 26 times better than salt in 150,000. The experiment repeated with the same waters, only the wires in tube 12 brought nearer. •3 12-5 sensib. greater. Electrom. = ij. •45 sensib. less. * [See Art. 690.] 3 1 6 On Resistance to Electric Current 622] Examination whether comparative resistance of salt in 2999 and salt in 150,000 was the same when tried in the above-mentioned manner, or when passed through 2 wires in glass of wafer, as in fig. * Jan. 6. The tubes 12 and 20 filled with salt in about 105 of water: salt in 150,000 of water in glass. 2 jars electrified to if and communicated to the rest. oo.e flcSS If the distance of wires in tube 12 was the shock was sensibly { 18-5 ' (greater than that through the wires in glass. The same tried as before, only with the jars electrified to 2 and the shock received with shock melter*. If the distance of wires in tube was f ^ ^ shock was plainly / than \2O-3 i greater through wires in glass. The glass filled with salt in 2999 and the shock compared with that through tube 20 with same solution of salt in 105. The jar electrified to 2 and received with shock melter f. If dist. wires in tube 20 was / shock was (f r than through wires \i- \less in glass. N.B. Great irregularity was found in trying this last experiment, the cause of which I am unacquainted with. Therefore salt in 2999 conducts 31-5 times better than salt in 150,000. The same salt in 150,000 which was used in this experiment was saved and compared with salt in 2999 in the usual manner with tubes 12 and 20, electro- meter at 4^. ( T«2 I PTf13.tfir If distance of wires in tube 20 was -! shock was plainly -! than ^1-85 (.less through tube 12 with wires at 42-4 inches distant. Therefore salt in 2999 conducts 24-6 times better than salt in 150,000. The thermometer in all the foregoing experiments of this year supposed to be about 45°. 623] Exp. ii. Saturated solution in tube 14 compared with salt in 149 of water in tube 15. Tube 15 1-6 2-6 41-8 Electrometer at 3^. Th. = 45. [R. = 474000.] " sensib. greater, sensib. less. Sat. sol. conducts 20-5 times better than salt in 149. * [See figure in facsimile of MS. on opposite page.] f [The reading here is doubtful; see facsimile of MS. on opposite page. Cavendish says, Arts. 601, 602, 616, that he took the shock with metals in each hand, but the word here cannot be read "metal." The word occurs also in Arts. 585 and 637.] Shock melter 3 1 7 /' 9iSa#*i Cf C • ' 3 1 8 On Resistance to Electric Current Exp. 12. Jan. 8. Sat. sol. in tube 22 compared with salt in 149 in tube 23. 'Tube 23 Tube 22 Electrom. i\. Th. = 42. [R. = 146000.] i-6 i-8 2-4 2-2 2-O 1-8 1-8 + 2-1 . plainly greater. seeming, greater, but doubtful. plainly less. rather less. not sensib. different. seemed greater. in tube 23 supposed = 41 in tube 22. m Therefore sat. sol. conducts 19-6 times better than salt in 149. Exp. 13. Salt in 149 in tube 5 compared with salt in 2999 in tube 17. 317 5 Electrometer = . 1-8 2-8 40-5 sensib. greater, sensib. less. Salt in 149 conducts 17-3 times better than salt in 2999. By new measure of tubes. Exp. 14. Same solutions in tubes 18 and 19. Tube 19 2-2 2-4 3-o 2-8 18 42-8 Electrometer = if. [R. = 308000.] sensib. greater. » not sensib. sensib. less, seemed less, but doubtful. 2*2 I 2'Q - in tube 19 supposed equal to 42-8 in tube 18. Salt in 149 conducts 16-7 times better than salt in 2999. Exp. 15. Jan. 9. Sat. sol. in tube 22 compared with salt in 29 in tube 23. Tube 23 22 97 9.4 6-6 6-9 6-3 35-8 Electrometer = ij. Th. = 42. [R. = 128000.] sensib. less. seemed less, but doubtful, seemed greater, not sensib. gr. sensib. greater. 6-5 + 9-7 supp. = 35-8 in tube 23. Sat. sol. conducts 4-38 times better than salt in 29. Solutions of "various salts compared 319 624] Comparison of water purged of air by boiling and plain water. Jan. 12. Salt in 2999 in tube 12. Salt in 150,000 in tube 20. Tube 20 . 12 Electrometer = 4^. Th. = 50. 1-2 plainly greater. 1-4 seemed greater, but doubtful. 1-8 seemed less, but doubtful. 2-0 plainly less. The water was then boiled over lamp in the same vial in which it had been kept some time, and then cooled in water and compared in the same manner. 2-0 sensib. less. 1-8 seemed less, but doubtful. 1-2 seemed greater, but doubtful. i-o plainly greater. Therefore if anything water conducted better before boiling than after, but the difference might very likely proceed from the error of the experiment. In order to see whether the water had absorbed much air by being exposed to the air in the trial, some of the boiled water was exposed to the air as much as that which was tried in the tube was supposed to have been, and boiled over again in a vial. It did not begin to discharge air till it was heated to 190°, and then discharged but little. Some more of the boiled water which had not been poured out of the vial seemed to discharge as much air. But some distilled water which had not been boiled began to discharge air almost as soon as heated, and discharged a great deal before it began to boil*. 625] Comparison of water impregnated with fixed air and plain water. Some distilled water was impregnated with fixed air produced by oil of vitriol and marble, and compared with salt in 2999 in same tubes and manner as in former experiments. Electrometer = 4^. Th. = 55. 1-6 1-4 2-4 2-6 2-8 seemed greater, but doubtful. plainly greater. not sensibly less. sensibly less, scarce doubtful. plainly less. The same water deprived of its fixed air by boiling, and tried as before. Tube 20 1-2 i-o •9 •6 7 12 [See Art. 692.] plainly less. sensib. less. seemed less, but doubtful. plainly greater. not sensib. greaterf. t [See Art. 693.] 320 Chemical equivalents ,* JLlectric resistances of solutions of 'various salts 321 626] 2-3 of Sal. Amm., 3-2 of Sal. Sylvii, 3-17 of Quadr. nitre, 2-21 of calcined Glauber's salt and 14-10 of calc. S. S. A.* were dissolved in water, the solution of each being 3.10.12, that is, such that the quant, acid in each should be equiv. to that in a solut. salt in 29 of water. Jan. 13. Sal. Sylvii in tube 15 compared with salt in 29 in tube 22. Electrometer = 2. Th. = 55. [R. = 253000.] seemed greater, but doubtful. plainly greater. seemed less, but doubtful. seemed less. plainly less. right. Jan. 14. Sal. amm. tried same way. seemed less, but doubtful, plainly less, sensibly greater. Tube 15 22 5 18-2 ' 4'5 7 77 8-2 7'4 + *i — — n-7 cnrtrinc^/-! 7-2 7-9 5'3 5-8 seemed greater, but doubtful. Calc. S. S. tried same way. 4-0 4'5 6-0 5'5 plainly greater, scarce sensib. gr. plainly less, sensib. less. Salt in 29. 4'5 7-0 6-5 Glauber's salt. Tube 15 4-2 3-8 4-2 4-4 4-6 3'4 3-6 22 plainly greater, scarce sensib. greater, plainly less, scarce sensib. less. plainly less. no sens. diff. scarce sens. less. do. just sens. less. sensibly greater. scarce sensib. less. * [See facsimile on the opposite page. The results are given in Art. 694. See Note 34, p. 430, and Introduction.] C. P. I. 21 322 On Resistance to Electric Current Quadrang. nitre 4-0 4-3 6-0 6-2 plainly greater, seemed greater, but doubtful, seemed less, rather doubtful, plainly less. 627] 2-0 of oil of vitriol, 2, 5-10 of spirit of salt 2, and 5-19 of f. alk. D, were diluted with water, the solution being 3 . 10 . 12. Consequently the quantity of acid in 2 first were equivalent to that in salt in 59 of water, and the alk. in last was equivalent to that in salt in 29; compared in the same manner as the former. scarce sensib. greater. seemed greater, but doubtful. plainly greater. plainly less. seemed less, but doubtful. sensib. greater. not sensib. sensib. less. not sensib. seemed less, rather doubtful, seemed greater, rather doubtful. Jan. 15 F. alk. Th. = 5 4'5 4-0 37 57 5-4 Diluted oil of vitriol. 4-0 4'3 47 Diluted spirit of salt. n-8 8-0 Another diluted spirit of salt was made of same strength as the former. Being tried with wires at 9-9 inch, distance no sensible difference was per- ceived, which agrees with former. Another diluted oil of vitriol was made and tried, Jan. 16. 5-2 77 sensib. greater, sensib. less. EXPERIMENTS IN JANUARY, 1781 *. 628] Some basket saltf was dried before fire, and a saturated solution made with it which contained 378 of saltj, and also other solutions of different strengths, all being made with distilled water. * [The results of these experiments are collected in Art. 695. See Note 33.] f ["Salt made up in form of sugar loaves, in small wicker baskets, which is thence called loaf salt or basket salt." Rees' Cycloptzdia.] { [26-45 per cent. Saturated solution at 18° C. is 26-4 per cent, by Kohlrausch.] Dependence on concentration of solution Sat. sol. in tube 14, salt in 69 in tube 15. [R. = 399000.] 323 3-6 5-8 5'4 14 39' i Electrometer 3^. Th. = 53. sensib. greater. plainly less. sensib. less 4'5 suPPosed "ght- Sat. sol. conducts 8-63 times better than salt in 69. Same solutions in same tubes. 5'4 plainly less. seemed rather less. scarce sensib. greater. 4'3 SUPPOSed n8ht' sensib. greater. 3-6 3-3 Sat. sol. conducts 9-03 times better than salt in 69. Sal. sol. in tube 14, salt in 29 in tube 15. El. = 3^. 7'3 II-O sensib. greater. sensib. less. 9' i supposed nght. Sat. sol. conducts 4-1 times better than salt in 29. The same solutions in same tubes. 107 7'5 7-8 97 seemed rather less, sensib. greater, seemed rather greater, supposed right. Sat. sol. conducts 3-85 times better than salt in 29. The same solutions in same tubes. El. = ij. [R. = 136000.] 2-6 2-6 37 3'5 3'3 13-3 seemed rather greater. D° scarce sensib. plainly less. sensib less. 2-95 supposed nght. seemed rather less. Sat. sol. conducts 3-95 times better than salt in 29. Sat. sol. in tube 14. Salt in n in tube 15. El. if. 15 14 [R. = 1360 47 13-3 sensib. greater. 8 plainly less. 7-6 do. 7-2 sensib. less. 5-95 supposed true. Sat. sol. conducts 1-92 times better than salt in II. 21 — 2 On Resistance to Electric Current The same again. 7 4'9 5'1 seemed rather less. sensib. greater. 6-05 supposed right. seemed rather greater. Sat. sol. conducts 1-88 times better than salt in n. The same again. 4'9 7 seemed rather greater, but doubtful. sensib. greater. sensib. less. 5'95 supposed true. Sat. sol. conducts 1-92 times better than salt in n. 629] Salt in 142 put in tubes 5 and 15 in order to find what power of velocity the resistance is proportional to. Electrometer = 3. [R. = 579°°°-] plainly less. do. scarce sensib. less. supposed right. plainty greater. DO. sensib. greater, seemed rather greater, sensib. less. Therefore log. vel. in 15 by do. in 5 = 1-2122, log. length in 5 by do. in 15 = 1-1829. = -976 power of velocity. J5 5 3'3 41-9 2-9 2 2-2 2-4 2-6 Therefore resistance is as The same repeated. 1-2122 15 3 2-6 2-7 sensib. less. hardly sensib. seemed sensib. greater. sensib. greater. 2>g5 supposed true. hardly sensib. Log. vel. in 15 by D° in 5 = 1-2122, Log. length in 5 by D° in 15 = 1-2122. Therefore resistance is directly as velocity*. * (This is the first experimental proof of what is now known as Ohm's Law.] Ohms Law of resistance determined 630] Salt in 69 in tube 22. Salt in 999 in 23. Electrometer = 3^. [R. = 1335000.] plainly less. 325 23 22 4'9 4-6 41-5 4-3 3-6 37 3'4 3'4 scarce sensib. less, sensib. greater, scarce sensib. greater, seemed greater, plainly greater, sensib. greater. Salt in 69 conducts 9-91 times better than salt in 999. The same repeated. 3 '4 seemed greater. 3'6 scarce sensib. greater. 3'2 sensib. greater. 4'3 scarce sensib. less. 4'5 sensib. less. Salt in 69 conducts 10-3 times better than salt in 999. The same liquors in tubes 5 and 17. 4 supposed true. 3-85 supposed true. 17 5 Electronic 4-2 42-2 plainly less. 4 sensib. less. 3-8 hardly sensib. 3'i sensib. greater. 3-3 hardly sensib. 3-55 supposed right. Salt in 69 conducts 11-31 times better than salt in 999. The same repeated. 5 3'3 hardly sensib. greater. 3-1 sensib. greater. 4 not sensib. less. 4-2 seemed rather less. 4'3 DO. 4-4 sensib. less. Salt in 69 conducts 10-75 times better than salt in 999. Salt in 999 in tube 12; distilled water in tube 20. El. = 2\ [R. = 494000.] 20 12 43-3 seemed rather less. -326 On Resistance to Electric Current 2 or 3 hours after it seemed rather greater at -5. Next morning was plainly greater at -7. The water being changed for fresh, seemed rather less at -3. The distilled water changed for salt in 20,000. 2-1 sensib. less. 2 not sensib. less. 1-7 sensib. greater. 1-8 seemed rather greater. 1-95 supposed right. 1-9 not sensib. greater. 2-1 sensib. less. Salt in 999 conducts 20 times better than salt in 20,000. Salt in 20,000 conducts about 7 times better than distilled water; therefore if distilled water contains j^^nis °f sa^t their conducting powers will be as the quantity of salt in them. The same repeated. Electrometer — 2. 2-1 not sensib. less. 2-2 seemed rather less. 2-3 D°. 2-4 D°. 2-5 plainly less. 2 supposed nght. 2-3 seemed rather less. 1-7 seemed rather greater. 1-6 plainly greater. Therefore salt in 999 conducts 19-5 times better than salt in 20,000. The waters changed for fresh. El. = z\. 20 12 2 scarce sensib. different. 1-9 D°. 1-8 sensib. greater. 2-1 not sensib. less. 2-05 supposed right. sensib. less. Salt in 999 conducts 19 times better than salt in 20,000. The same repeated. El. = 2. 42-9 sensib. less, scarce sensib. less. seemed rather greater. _ 1-95 supposed nght. sensib. greater. Salt in 999 conducts 19-8 times better than salt in 20,000. 2-3 2-1 1-8 1-7 1-6 Resistance of mixed liquids Salt in 69 in tube 22. Salt in 142 in tube 23. 327 7'3 7-5 6-3 6 22 I2-65 El. = 2. [R. = 407000.] seemed rather less, sensibly less, not sensib. greater, sensib. greater. Salt in 69 conducts 174 times better than salt in 142. 6-75 supposed right. 6-45 supposed right. The same repeated. 6 5-8 5-6 5-8 7-3 7 6-8 Salt in 69 conducts 1-84 times better than salt in 142. Salt in 999 in tube 12, distilled water in tube 20. El. = 2\. [R. = 494000.] seemed rather greater, doubtful, plainly greater, not sensib. greater, plainly less, seemed rather less, scarce sensibly less. •83 7 sensib. less. N.B. The tubes had been measured sensib. greater. between the last trial and this. The distilled water was then changed for fresh. •3 | | sensib. less. Another bottle was filled with distilled water and tube 20 filled up again with that. •3 | | seemed rather less. 631] The tube 20 filled with the same distilled water mixed with ?fas of spirits of wine. •3 | | seemed not sensibly less. Same mixture mixed with -fa more of spirits of wine, id est, sp* wine in 18 of distilled water. . -3 | | scarce sensib. less. Equal bulks of sp* wine and distilled water. •3 | | seemed scarce sensib. less. Pure spirits of wine. •3 | | seemed of 2 rather greater. Therefore there is not much difference between the resisting power of the above distilled water and spirits of wine and mixtures of the 2 : but of the 2, spirits of wine resists least. 728 On Resistance to Electric Current 632] Tube 14. [CALIBRATION OF TUBES.] Dist. mid. col. from str. end Length col. 3-6 4-08 9-2 13-6 18-1 4-03 3'9 3-7 25-5 36-8 • 3-54 3-46 3-09 42 2-8 Tube 15. - 3-6 + 1-7 5-32 5-16 + 7-9 4-95 + 9'9 4-47 col. = 2-45. 40-6 inc. = 28-5 gr. 4-26 = 3 gr. 12-2 inches of tube next to bend contain \ part of of that in col. 42-5 long. col. = 3-25 gr. 4-67 After it was measured 7 inches were cut off from straight end, and the numbers in the first col. are the distances from the shortened end. A new bend was also made 12-8 from new end, and the part where the tube is equal to tube 14 is at 10-3 from D°. 633] Jan. 1781. The following tubes were measured over again by intro- ducing a col. $ and measuring its length in 3 different places, the beginning of the Ist col. being at J inch from bend, and the beginning of the second at the end of the first. Another column was afterwards introduced whose length was pretty nearly equal to the sum of the 3 former, and weighed. NO of ist 2nd 3rd tube col. col. col. 14 12-2 14-3 16 41-8 inc. = 29-3 gr. 15 3-47 371 3-86 n-55 = 77 22 13-03 I3-65 14-6 41-8 = 100 23 3-6 3'3 3-09 10 24-5 5 12-65 14 13-5 42-1 = 489 17 3-25 3'iS 3-08 9.9 = 116 634] The two following tubes were measured by stopping up the end near bend and weighing them with different quantities of $ in them, and measuring the distance of the top of the column from straight end, whence it was found that in long beginning 1448 at \ inch = 2777 from bend 4033 long beginning 270 at \ inch from 543 bend weighed 881 14-8 N° 12 a col. 28-6 42-8 3-17 N° 20 a col. 6-27 9.97 Calibration of tubes 329 635] In the following result the column whose length is given in the 2nd column is supposed to begin at \ inch from the bend. By the resistance of each is meant grains £ in each inch [The resistance of a column of mercury one inch long weighing one grain is -13 Ohms, and the resistance of saturated solution of salt at t° Centigrade is to that of mercury as io8 is to 2015 + 45-1 (t — 18). Hence the resistance as given by Cavendish must be multiplied by 6907 + 82-2 (59 — T) to convert it into Ohms when the tube contains saturated solution at T° Fahrenheit.] RESULT. N°. Length column Resist. Log- do. Resist, for each inch Log. do. 14 12-2 26-5 42-5 14-99 35-58 61-36 1-1758 I-55I2 1-7879 1-229 1-343 1-444 •0894 •1280 •1595 15 3'47 7-18 11-04 4-907 10-518 16-591 •6908 1-0219 1-2199 1-414 1-465 I-503 •1505 •I658 •1769 22 13-03 26-68 41-28 5-157 10-817 17-294 •7124 1-0341 1-2379 •3958 •4054 •4190 9-5975 9-6079 9-6222 23 3-6 6-9 9-99 I-588 2-923 4-093 •2009 •4658 •6l20 •4412 •4237 •4096 9-6446 9-6270 9-6124 5 12-65 26-65 40-15 1-030 2-291 3-463 •OI26 •3600 •5395 •08138 •08596 •08626 8-9105 8-9343 8-9358 17 3-25 6-43 9-51 •2844 •5566 •8121 9-4539 9-7455 9-9096 •08750 •08656 •08539 8-9420 8-9373 8-9314 12 14-8 28-6 42-8 •1513 •2946 •4552 9-1798 9-4692 9-6582 •01022 •OIO3O •01064 8-0095 8-0128 8-0268 2O 3-17 6-27 9-97 •03722 •07243 •11293 8-5708 8-8599 9-0528 •OII74 •OII55 •OII33 8-0697 8-0626 8-0541 330 On Resistance to JLlectric Current COMPARISON OF RESISTANCE OF COPPER WIRE WITH THAT OF SAT. SOL. 636] The wire was wound on reel on bars of glass about f inch broad, the distance of one round of wire from the next on same bar being -6. The mean circumference of reel = 46-7 x a\/2*. There were 8 rows of glass bars, and 28 rounds of wire on each row, and on one row there was \ round over. Therefore whole length of wire = 93-4 x \/2 x 8 x 28 + \ = 29,623 inches. This weighed 2967 grains, consequently there are 9-984 inches to i grain. N.B. There were many knots in the wire. 637] The resistance of this wire was attempted to be compared with that of sat. sol. in tube 17 by shock melterf as in former experiments, but without success. It was therefore compared by the sound of the explosion by discharging the jars by a wire without its passing through my body; but in this there was considerable difficulty, as the light of the spark passed through the wire was very different from that passed through the water, the first being reddish and the latter white. The sound also was of a different kind, the latter being sharper. Distance of wires in tube 17. El. = 4. •68 not sensib. diff. •6 scarce sensib. stronger. •55 doubtful. •5 seemed rather greater. •45 sensib. greater. •9 seemed sensib. less. i do. 1-2 sensib. less. - El. = •g scarce sensib. less, i not sensib. less. 1-2 seemed rather less. •6 plainly greater. •7 not sensib. greater •4 not sensib. gr. •3 seemed rather gr. •2 plainly gr. •8 seemed rather less. 1-2 plainly less. * [The reel was probably square, with glass bars at the corners, the length of the diagonal being 46-7 inches.] f [See Arts. 585 and 622.] Copper wire compared with solutions in tubes 1-2 plainly less. 331 •8 scarce sensib. less. •4 sensib. gr. •5 scarce sensib. •5 sensib. gr. •6 seemed rather gr. •7 not sensib. diff. i seemed rather less. El. = 3- El. = 4. 638] Two Leyden vials were made of barometer tubes filled with £ and coated on outside with tinfoil. The quantity of electricity in them was found to be very nearly the same, but that in N° i rather the greatest. The charge of each of these tubes is about 714 inches, and that of the large jars about 6100, and that of the three jars i, 2 and 4 together is also 6100*. The shock of these tubes was received through my body in the same manner as in trying the large jars, either by making the shock pass through the copper wire or through the sat. sol. or receiving it in the simple manner without passing through either: the experiment being tried as usual by charging both tubes from the same conductor and receiving the charges of one one way and the other the other. 639] It was found by repeated trials that the shock received through the copper wire was plainly greater than the simple shock. When received through the sat. sol. with wires f in contact not sensib. less than simple. at -i dist. seemed rather less, but doubtful. •5 i 2 4 6-6 D°. scarce doubtful. not doubtful. D°. considered less. The tubes charged to ij by old electrometer. 640] It was also found by the small jars i, 2 or 4 that the shock received through the wire was stronger than the simple shock. The shock through the wire was also much greater than the simple shock when the covering which was put over the wire to defend it from accidents was taken away. It was also plainly greater when the shock passed through only 3 rows of the wire instead of the 8. * [Probably globular inches. The numbers do not agree with those in Art. 583.] •f {See end of Note 31.} 332 On Resistance to Electric Current If the shock was received through 166 inches of the same wire not stretched upon glass, without any knots in it, it seemed not at all greater, but if anything less than the simple shock. It was the same if received through a piece of wire of about the same length with 37 knots in it. 641] Some more of the same wire was stretched by silk into 32 x 12 rows, each 78-7 inches long; consequently the whole length was 30,220 inches. It weighed 3272 grains, id est, 9-24 inches to a grain. The shock of the above-mentioned tubes was sensibly greater when received through this last wire than when received simply, but was considerably less than when received through the first wire. They were then compared by sound with the same tube charged to sj, when the sound of the shock passed through the new wire was sharper, and the other fuller. The sound of the shock passed through the new wire seemed full as brisk, and the light as white as of that passed through -55 of sat. sol., but not near so strong as when the wires in sat. sol. were in contact, the sound and light, however, seemed nearly of the same kind. When distance in tube was i-i the sound was evidently less loud than that with the wire. When the shock was allowed to pass through both wires, the sound, I thought, seemed much of the same kind as when passed through new wire singly. The shock passed through both wires felt plainly greater than the simple shock, and the difference seemed greater than that between the new wire simply and the simple shock. In the foregoing the shock passed at the same time through both wires, but it was then tried so that it should first pass through old and from thence through new wire. The shock felt then evidently stronger than the simple shock or that through new wire alone, but I could not tell whether it was greater or less than that through the old wire alone. 642] A piece of the same wire was wound about 150 times round one of the slips of glass, and was laid flat on another of these slips which lay flat on a table. The shock of these tubes seemed rather greater when received through this wire than when received simply, but the difference was not considerable, but it seemed evidently less than the shock received through the new wire. 643] The wire was taken from off the reel with the slips of glass, and all except a small part of it stretched round the garden in 14 rounds. The shock of the above-mentioned tubes received through this wire felt plainly greater Copper wire compared with solutions in tubes 333 than that passed through the wire stretched by the silk threads, and much greater than the plain shock. The shock passed through the sat. sol., wires in contact, seemed about equal to the plain shock. The spark passed through garden wire seemed rather redder than that through the silk wire, but the difference was not remarkable. The spark passed through garden wire seemed about as strong as that through about -8 of an inch of saturated solution, but sensibly redder. 644] The reel was altered, and some copper wire silvered stretched upon it. The mean circumference of reel = 44-05 x 2 Vz. There were 12 rows of glass bars and 42 rounds of wire on each row, therefore whole length of wire = 88-1 x A/2 x 12 x 42 = 62,790 inches. This weighed 5747 grains. Consequently there are 10-93 inches to i grain. The shock received through this wire felt vastly stronger than the simple shock; the shock of tube 2 received through the wire with electrometer at ij seeming little less strong than the simple shock with the same tube and the electrometer at if, but considerably stronger than with electrometer at ij. 645] The above-mentioned wire compared with sat. sol. by sound. 1-46. Seemed more brisk. The light of salt water white, the other very red. 1-7 D°\ 2-5 DO 3-5 EL = - 5-5 8-7 I believe nearly the same. 8-3 seemed much weaker. El. = 3. 6 seemed rather greater. 7-5 doubtful. 8-5 seemed rather weaker. 6 seemed rather stronger. 7-2 doubtful. El. = 3. 8-5 seemed rather weaker. 6 doubtful. 5 D". 4 seemed stronger. 8-5 seemed rather weaker. 8-5 doubtful. 9-5 I believe rather less, certainly a sharper sound, but I believe rather less loud. 7 seemed greater. 334 Resistance of Copper Wire 1-65 _ 2 1-8 = '9 ^=•55 U . .65 1-6 = •8 14-5 2 12-5 = 7-25 = 6-25 2 = 8'25 372 - 74 21-75 = 7-25 646] 74 of sat. sol. in tube 17 is equivalent to 29,623 inches of copper wire, 9-984 inches of which = i grain. 7-25 of sat. sol. in do. = 62,790 of copper wire, 10-93 of which = i grain*. [Length of wire 29,623 62,790 Resistance of pure copper calculated from Matthiessen annealed hard drawn Resistance of saturated solution in tube 17 calculated from Kohlrausch 424 984 433 1004 413 4046] [ 335 ] RESULTS (OF EXPERIMENTS ON COMPARISON OF CHARGES. ARTS. 438—595} {From MS. N°. 16. See Table of Contents at the beginning of this volume.} 647] 1773, p. 92 [Art. 557]. The connecting wire to the two plates of 9-3 inches contains 1-4 inc. el. The connecting wire to the rosin plates of p. 86 [Art. 554], should contain rather more in proportion to its length than this, id est, rather more than -28. By p. 93 [Art. 557], the 4 rosin plates seemed to contain about \ inc. el. less when placed close together than at dist. Let us therefore suppose that the charge of 2 rosin plates placed close together with connecting wire between them exceeds twice the charge of i plate by -28 inc. el., and that the charge of 4 plates exceeds 4 times the charge of i by z\ times that quantity, or -7 inc. el. Let us suppose, too, that the charge of the 2 double plates A & B with connecting wire exceeds twice the charge of I by -28. 648] 8 square inches of elect. = 9 circular inches. L.* •1880. Res. p. 5 [Art. 654]. = -649 = 9-8120. glob. inc. el. circ. inc. el. circ. inc. el. glob. inc. el. N.B. By inc. el. is meant circular inches of electricity. 649] Mar. 13. P. 85 [Art. 553]. [Side of square equivalent to trial plate when the balls separate negatively, positively.] Difference Mean Circle i8i 17-66 13-34 4-32 I5-50 Double B 17-89 13-34 4-55 15-61 Double A 17-89 13-34 4-55 15-61 Circle 36 33-65 26-56 7-09 30-10 2 doub. 3I-38 24-08 7-30 27-73 D 29-61 22-53 7-08 26-07 * [These logarithms are correct only to three places of decimals, they should be 0-1875 ar"d 9-8122. See Note 35.] 336 Results of Experiments Mon. Mar. 15. P. 85. [Side of square equivalent to trial plate when the balls separate negatively, positively.] Difference Mean Circ. 36 33-65 27-18 6-47 30-41 Circ. 30 28-42 28-10 Plate air 30-87 24-39 6-48 27-63 •2 doub. 3I-I3 24-39 6-74 27-76 D 29-86 22-84 7-02 26-35 Doub. B 18-22 13-82 4-40 16-02 Doub. A 18-22 13-82 4-40 16-02 Circle i8£ 18-11 I3-58 4-53 15-84 Mar. 19. P. 86. Circle 9 9-28 6-48 2-80 7-88 Rosin i 10-59 7-13 3-46 8-86 2 10-47 6-91 3-56 8-69 3 10-59 7-24 3-35 8-91 4 10-35 7-02 3-33 8-68 1 + 2 Rosin 18-56 I4-5I 4-°5 i6-53 3 + 4 18-67 14-62 4-05 16-64 Circle i8£ 18-00 13-82 4-18 I5-91 Circle 36 33'9° 27-49 6-51 30-74 4 rosin 32-14 25-94 6-20 29-04 Mar. 23. P. 90 [Art. 554]. Circle . 9-3 9-28 6-48 2-80 7-88 Rosin i 10-22 7-13 3-09 8-67 2 IO-O9 7-02 3-07 8-55 3 IO-22 7-I3 3-09 8-67 4 10-22 7-13 3-09 8-67 Rosin 1 + 2 I8-56 14-06 4-50 16-31 3 + 4 I8-56 14-06 4-50 16-31 Circle i8J 17-66 13-34 4-32 I5-50 Circle 36 34-40 26-56 7-84 30-48 4 rosin 33-40 26-25 7-15 29-82 Mar. 24. P. 91. Circle 36 33-65 27-49 6-16 30-57 Plate air i 30-75 25-01 5-74 27-88 4 rosin 31-76 25-32 6-44 28-54 rosin 1 + 2 18-34 I4-5I 3-83 16-42 3 + 4 18-78 I4-5I 4-27 16-64 Circle 18 18-11 13-82 4-29 15-96 Circle 9-3 9-56 6-48 3-08 8-02 Rosin i 10-83 7-35 3-48 9-09 2 10-83 7-46 3-37 9-14 3 10-83 7-46 3-37 9-14 4 10-83 7-46 3-37 9-14 on comparison of charges 337 650] [Results of Art 649.] By Mar. 13. [Art 553.] Double plate = circ. i8J + -n sq. inc., or -12 inc. el. Circ. 36 = 2 doub. + 2-67 inc. el. without allowance for communi- cating wire, &c., or 2-95 with. D = 2 doub. — i -60 with allowance. Circ. 36"! (+ 3-19 \ = Circ. i8i x 2 { *. D J \- 1-36 By Mar. 15 [Art. 553]. Doub. pi. = i8J + -20. D I ,- -91 (- 1-51 pi. air ! = circ. i8J x 2 \ + -53 = 2 doub. j I- -13 with allowance, circ. 36) (+ 3-66 1+ 3-26 651] All the following are with allowance. Mar. 19 [Art. 554]. i ros. = circ. 9-3 + i-oi. circ. i8J = 2 ros. - -47 = circ. 9-3 x 2 + 1-55. circ. 36 = 4 ros. + 2-61 = circ. i8J x 2 + 3-55. Mar. 23 [Art. 554]. i ros.= circ. 9-3 + -85. circ. i8f = 2 ros. - -63 = circ. 9-3x2 + 1-07. circ. 36 = 4 ros. + 1-44 = circ. i8J x 2 + 2-76. 1-32 Mar. 24 [Art. 554]. i ros. = circ. 9-3 + 1-25. circ. i8J = 2 ros. - -36 = circ. 9-3 x 2 + 2-14. circ. 36 = 4 ros. + 2-98 = circ. i8£ x 2 + 3-70. Plate air i = circ. 36 - 3-03 = circ. i8J x 2 + -67, By mean of all circ. 36 = circ. i8| x 2 + 3-37. circ. i8£ = circ. 9-3x2+ 1-59. Therefore charge of circle of 37 inc. , i8i by 4-47 1, . exceeds 2ce charge of circ. of , i8£ inc. 9^ by 1-69 37 inc. exceeds 4 times charge of g| by 7-85. 652] *If charge circle is greater than it would be if placed at a great dis- tance from any other body in ratio of a : a — 36, charge circ. of i8£ should exceed in ratio of a : a - i8J and so on. Therefore, if we suppose a = 167, 1 36 (9-89 charge circ. Ji8J should exceed its true charge by ^2-31 , b-3 I '55 and charge circ. 36 should exceed 2ce charge of i8J by 4-27 , . f -90 greater ' , which is \ 4 times charge of 9-3 by 6-49 |/oo less * [See Art. 338, and Note 24.] c.p. i. 22 338 Results of Experiments than by experiment, and charge circ. i8J should exceed 2ce charge of 9-3 by i-ii, which is -58 less than by experiment. We will therefore suppose that the charge of circ. i8J or of globe 12-1, as found by experiment, exceeds the true charge in the ratio of 9 to 8, as it should do if a = 167. 653] 1771. P. 15 [Art. 456]. doub. B contains A f-2i . . V sq. inc. or { circ. inc. less than circ. i8i. doub. A contains J {-14 1772. P. 12 [Art. 478]. doub. B , . -ii -12 . . contains sq. me. or , circ. inc. more than circ. 18*. doub. A -23 -26 1773. P. 85 [Arts. 553 & 650]. Each doub. plate contains -16 circ. inc. more than circ. i8£. 1*25 654] P. 15. 1771 [Art. 456]. Globe cont. - - sq. inc. or -35 circ. inc. more 4 than circ. 18-5. P. 12. 1772 [Art. 478]. Globe contains same as circ. By mean, globe of 12-1 = circ. of 18-67, or globe of 12 inc. = circ. of 18-5. Therefore i circ. inc. = -65 glob. inc. or i sq. inc. = -73 glob. inc. DEF. The charge of globe i inc. diam. placed at great dist. from any other body is called i glob. inc. The circ. 18-5 = 13-5 glob. inc. * The doub. plate A or B is supp. = 13-6 glob. inc. 655] P. 18, 1772 [Art. 483], D, E, F & G cont. -68 inc. el. less than 2 doub. P. 19, 1773 [Art. 509], D & F cont. i inc. less than do. P 59. 1773 [Art. 533], D, E & F cont. 1 1 inc. less than do. P. 85, 1773 [Art. 553], — D cont. 1-6 less than 2 doub. — D cont. 1-31 less than do. D cont. 1-36 less than 2ce circ. i8J. D cont. -91 less than do. D is supposed to cont. 1-3 circ. inc. or -85 glob. inc. less than 2 doub., id est, 26-3 glob. inc. * [See Note 35, p. 433.1 on spreading of electricity 656] 1773- P. 28 [Art. 515], M cont. i inc. el. more than D + E + F. P. 29 [Art. 515], M cont. same as P. 54 [Art. 528], M cont. 2i) K & L _ more than D + E + K N. i6|. 1773, P. 57 [Art. 530], M cont. 2 K £ L r more than D + E + F. N. I4J. P. 57 [Art. 530], K & L C more than D + E + F. N. 16. It is supp. that 7 more than D + E + F, id est, 8°'7 glob. K & L — 1-5 79.9 5 inc. el. 657] 1773, P. 55 [Art. 529], B or r cont. 3| 3 inc. el. less than K + L + M. N. 15. P. 57 [Art. 530], each cont. 33-7 less than do. N. 14^. P. 58 [Art. 531], each cont. 38-6 less. * N. 16. It is supp. that A, B, and C each cont. 34-8 inc. less than K + L -t- M, id est, 29-1 less than gD, id est, 217-8 glob. inc. 658] By exper. of 1772, F or G cont. 2 inc. more than D. E 1-6 M cont. 3-86 less than E + F + G. K & L 12-02 less. F 10-72 less. Therefore E + F + G cont. 5-6 more than 3D. M 1-7 more. K or L 6-4 less. F 5-1 less. A, B & C each contain 15-2 less than F + K + L. or 33-1 less than cjD. 22 — 2 340 Results of Experiments 1773. P- 56 [Art. 530], H cont. 10 inc. more than A + B + C. 1772, P. 29 [Art. 493], H cont. the same as A + B + C. H is supposed to contain 654 glob. inc. * 659] Instantaneous spreading of el.\ Measures P. 19 [Art. 593]. A = 33-9 20-6 The area of the old coatings of C = 33-2 and circumf. - 20-4 H = 36-3 21-4 A = 31-8 /73'5 Area of slit coatings of -_ and circumf. j ' crown = 24-7 (69-6 A = 34-1 23-4 0 — ^^''•? 2^*2 Area of oblong coatings of .. & circumf. H = 36-4 24-1 crown = 29-0 21-6 660] P. 15, 1773 [Art. 504], White Cyl. cont. 7 inc. el. less than H. P. 13 [Art. 502], 5 By mean it cont. 6 less than H. P. 62 [Art. 536], H with slit coat. cont. 77-5 more than white cyl. crown with oblong coat. 33-7 N. 1.2. P. 63 [Art. 536], H with D° cont. 99-1 more than wh. cyl. N. II. crown 43-8 P. 65 [Art. 537], H with D° 70-8 more than wh. cyl. N. 14. crown with slits 34 P. 66 [Art. 537], crown D° cont. 20 more than wh. cyl. N. i2j. P. 71 [Art. 541], H D° cont. 74-1 more than wh. cyl. N. 21. crown 67-3 * [See Art. 318.] \ [See Art. 3i<».l P. 8r [Art. 550], H with obi. cont. H crown H crown on spreading of electricity 20-2 more than wh. cyl., st. el.* at 2 + 3 34 3+i 57-3 9 less than wh. cyl. i + 3 14-6 more than 341 P. 82 [Art 550], H 18-5 more than wh. cyl. A and C with circ. coatings are supposed to contain same as B. P. 62 [Art. 536], A r with slit coat. cont. ] more than B us. el.t v< 13-5 1 A C i + 3 A 337 I N- C 337 1 irreg. / P. 63 [Art. 536], A C 18-51 15-2) us. el. A C 13-5) lo-ij i + 3 A 18-51 C 18-5} 3+1 very irreg. P. 65 [Art. 537]. with obi. - 4 1 more than B \* 5-IJ us. el. A 5-i C 1-7 1 + 3 A o C 17 less than B 3+ i P. 66 [Art. 537]. A more than B us. el. C 5-r N. 15. N. N. ii. 14. N. 12$. 661] By mean H with slits cont. 78 inc. el.l \ more than wh. cyl. with oblong 19 — — J Crown with slits contains 27 inc. el. more than wh. cyl. oblong 39 - N.B. This is meant in dry weather & with usual deg. el. The crown with slits exceeded wh. cyl. by 427 more with electrom. at 3+1 than at i + 3, and H with oblong exceeded wh. cyl. by 43 more with * [Straw electrometer. See Art. 560, note.] f [Usual degree of electrification. See Art. 329 and Note 10.] 34 2 Results of Experiments electrom. at 3 + i than at i + 3, but it must be observed that this was only one day's observ. A 16 With usual deg. el. p exceeded B by with electrom. at i + 3 by &at 3+ i by 14-3 ii 26-1 26-1 A with oblong exceeded B with us. el. by with electrom. at i + 3 by 1-7 and at 3 + i by 662] Hence we have the following results: — L. inc. el. in each sq. inc. circ. or obi. coa. Inc. el. in slit coat, more than in oblong Sq. inc. coating answering toD" Sq. inc. of slit coat, equiv. to obi. Sq. inc. in obi. Dili. Excess s& SP,«f «* above oblong A with us. el. 9-959 12-6 I-27 30-53 34-i 3-57 50-1 -072 el. at i + 3 9-2 •93 30-87 3-23 •065 el. at 3 + i 26-1 2-63 29-17 4-93 •098 C with us. el. 0-050 9-4 •91 29-49 33-3 3-81 53-3 •071 el. at i + 3 9'3 •92 29-48 3-82 •072 3 + ! 27-8 2'75 27-65 5-65 •106 H with us. el. 4-437 59 2-12 31-18 36-4 5-22 45'0 •094 Crown do. - 12 - '33 25-03 29-0 | 3-97 48-0 •083 663] Inc. el. In oblong coating - D° in circular Sq. inc. of coating equiv. toD° Sq. inc. of circular coa tin K equiv. to oblong Sq. inc. in oblong Diff. Excess circumf. oblong above circular Sq. inc. equiv. to excess of spreading of elect, in oblong above that in circular A 3-4 •34 34-24 34'1 •14 2-8 •20 C 5-1 •51 33-71 33-3 •41 2-8 •20 H i-3 •46 36-76 36-4 -36 2-7 •25 It is plain that the numbers in the 8th or last col. ought to be equal to those in the 6th, as is nearly the case. 664] Whether charge of coated glass bears the same proportion to that of another body whether el. is strong or weak *. P. 61 [Art. 535], E on neg. side tried against sliding tin plates on pos. Charge of E was B?ff part less with straw el. at 3 + i than at 1 + 3, the diff. between neg. and pos. el. was much too small to be certain of. * [Arts. 356, 451, 463, 535, 539, 551.] on dielectric plates of air 343 P. 66 [Art. 538], a ball blown at end of therm, tube tried in same manner. Charge just the same whether electron! . at i + 3 or 3 + i. P. 68 [Art. 538], charge D° ^ less with el. at 3 + i than at i + 3. P. 82 & 84 [Arts. 551 & 555], tried with machine for finding quant, el. in common plates. No perceptible diff. between charge of E whether tried with el. at i + 3 or 3 + i. 665] By P. 9 [Art. 661], it should seem that el. spread. -034 inc. more on surface with greater degree of el. than with smaller, and therefore, as the diam. coating of E or D is 2-16. So that it should seem as if the charge of a coated plate in which the spreading of the el. was prevented would be at least ^ less with the stronger degree el. than with the weaker. 666J By exper. of P. 69 [Art. 539], it appeared that the charge of tin cyl. was to that of D + E when electrified very weakly as 1-28 to i, and by P. 70 [Art. 539] as 1-24 to i. By mean as 1-26 to i*. By mean of P. 76 [Art. 545], the charge of the same cyl. was to that of D + E when electrified in the usual degree as 1-33 to I. By mean of P. 77 [Art. 546], it came out as 1-37 to i, but this last can not be depended on, as wire for making communication with ground was forgot to be fixed f. 667] It should seem that the charge of D and E is increased \^ by spreading of el. when elect, in usual degree, therefore if we suppose that the spreading is insensible when electrified in very small degree, the charge of a glass plate is less in proportion to that of another body when electrified with usual degree el. than when elect, with a very small one in ratio of 1-26 to 1-51, or of 5 to 6. 668] On plate air •{. [By Art. 517], P. 32 pi. air i cont. i inc. el. more than D) , > by mean I more than D. 33 f I The same plate air contained 2 inc. el. less when resting intirely on machine than when resting by i corner. * [See Arts. 358, 539, 545.] f The comp. charge of the cyl. is 48-4 glob. inc. The real charge, supposing that the wire contains 3-6 glob. inc. less when joined to cyl. than to D + E = 73-6, and therefore its real charge exceeds the computed in the ratio of 1-52 to i. [See Note 25.] { [See Art. 340.] 344 Results of Experiments [By Art. 517], PI. air 2 cont. i inc. el. less than D + E. P. 32, pi. air 3 10-5 inc. el. less than D + E + F. P. 33, pi. air 4 i inc. el. less than D + E + F. P. 36, pi. air 5 J more than D. P. 37, Do. By res. P. 5 [Art. 653], D, E, and F cont. 26-3 glob. inc. Therefore pi. air i contains 27 glob. inc. 2 52 3 72-1 4 78-3 5 26-5 669] [Table of plates of air given in Art. 343.] 670] Plate air Log. diam. by thickness I 1-1017 •7919 7452 6928 6332 2 1-4375 •9426 8689 7799 6679 3 1-6013 1-0163 9235 8054 6427 4 I-6525 •9747 8566 6939 4307 5 I-3895 •9458 8809 8045 7117 The- * diam. real charge (pet rrJnmnc arA Tru> Incr nt v PYPPQ IsT T3 9* T-S8 (-*• rr Xf p i 91 Salt in 69 92 1-74 T>RA salt in 142 22 & 23 2 I 1-79 Salt in 69 9-91 salt in 999 3i J 10 3 , 10-57 11-31 K. 17 Ii Salt in 999 10 75 20 salt in 20,000 12 & 2O | r>l 19-6 X9 ™.S 2t Salt in 20,000 conducts about 7 times better than distilled water. 696] Therefore the resistance of water with different quantities of salt in [it] are as follows J : Qu^tiy Resistance Log. do. Resist, x quant, salt Log. do. i by 3-78 I 12 1-91 •2810 •602 9-7793 30 3-97 •5988 •500 9-6992 70 8-8 •9445 •475 9-6769 143 15-75 I-I973 •416 9-6195 1000 93-02 1-9686 •352 9-5461 2OOOO 1823 3-2608 •345 9-5373 ' [Art. 628.] f {Stated in Art. 628 as if} J [See Note 33.] [ 352 ] NOTES BY THE EDITOR {JAMES CLERK MAXWELL} i See Table of Contents at the beginning of this volume. } NOTE i, ARTS. 5 AND 67. On the theory of the Electric Fluid. The theory of One Electric Fluid is here stated very completely by Cavendish*. The fluid, as imagined by him, is not a purely hypothetical sub- stance, which has no properties except those which are attributed to it for the purpose of explaining phenomena. He calls it an elastic fluid, and supposes that its particles and those of other matter have certain properties of mutual repulsion or of attraction, just as he supposes that the particles of air are indued with a property of mutual repulsion, but according to a different law. See Art. 97 and Note 6. But in addition to these properties, which are all that are necessary for the theory, he supposes that the electric fluid possesses the general properties of other kinds of matter. In Art. 5 he speaks of the weight of the electric fluid, and of one grain of electric fluid, which implies that a certain quantity of the electric fluid would be dynamically equivalent to one grain, that is to say, in the language of Boscovich and modern writers, it would be equal in mass to one grain. We must not suppose that the word weight is here used in the modern sense of the force with which a body is attracted by the earth, for in the case of the electric fluid this force depends entirely on the electrical condition of the earth, and would act upward if the earth were overcharged and downward if the earth were undercharged. Cavendish also supposes that there is a limit to the quantity of the electric fluid which can be collected in a given space. He speaks (Art. 20) of the electric fluid being pressed close together so that its particles shall touch each other. This implies that when the centres of the particles approach to within a certain distance, the repulsion, which up to that point varied as the «th power of the distance, now varies much more rapidly, so that for an exceedingly small diminution of distance the mutual repulsion increases to such a degree that no force which we can bring to bear on the particles is able to overcome it. We may consider this departure from the simplicity of the law of force as introduced in order to extend the property of "impenetrability " to the particles of the electric fluid. It leads to the conclusion that there is a certain maximum * For an earlier form of Cavendish's theory of electricity, see "Thoughts con- cerning electricity" (Arts. 195-216), and Note 18. The theory of a single electric Jiuid 353 density beyond which the fluid cannot be accumulated, and that therefore the stratum of the electric fluid -collected at the surface of electrified bodies has a finite thickness. No experimental evidence, however, has as yet been obtained of any limit to the quantity of electricity which can be collected within a given volume, or any measure of the thickness of the electric stratum on the surface of conductors*, so that if we wish to maintain the doctrine of a maximum density, we must suppose this density to be exceedingly great compared with the density of the electric fluid in saturated bodies. A difficulty of far greater magnitude arises in the case of undercharged bodies. It is a consequence of the theory that there is a stratum near the surface of an undercharged body which is entirely deprived of electricity, the rest of the body being saturated. Hence the electric phenomena of an under- charged body depend entirely upon the matter forming this stratum. Now, though on account of our ignorance of the electric fluid we are at liberty to suppose a very large quantity of it to be collected within a small space, we cannot make any such supposition with respect to ordinary matter, the density of which is known. In the first place, it is manifestly impossible to deprive any body of a greater quantity of the electric fluid than it contains. It is found, indeed, that there is a limit to the negativef charge which can be given to a body, but this limit depends not on the quantity of matter in the body but on the area of its surface, and on the dielectric medium which surrounds it. Thus it appears from the experiments of Sir W. Thomson and those of Mr Macfarlane, that in air at the ordinary pressure and temperature a charge of more than 5 units of electricity [per cm.2,] positive or negative, can exist on the surface of an electrified body without producing a discharge. In other media the maximum charge is different. In paraffin oil, and in turpentine, for instance, it is much greater than in air J. In air of a few millimetres pressure it is much less, but in the most perfect vacuum hitherto made, the charge which may be accumulated before discharge occurs is probably very great indeed. Now this charge, or undercharge, whatever be its magnitude, can be accu- mulated on the surface of the thinnest gold leaf as well as on the most massive * [The modern molecular theories of the phenomena of galvanic polarization touch on this subject.] t [The phenomena of discharge in dielectrics, especially of negative electrons as indicated in the text, are of course now much more thoroughly understood. Of. Sir J. J. Thomson's treatise on Conduction of Electricity through Gases, or Prof. J. S. Townsend's book on The theory of ionization...by collision.] J By Messrs Macfarlane and Playfair's experiments the maximum electromotive intensity is 364 for paraffin oil and 338 for turpentine. For air it is 73, between disks one centimetre apart. (Trans. R. S. Ed. 1878.) They have since found that the electric strength of the vapour of a certain liquid paraffin at 50 mm. pressure is 1-7 times that of air at the same pressure, and that the electric strength of a solid paraffin which melts at 22°-^ C. is 2-5 when liquid and 5 when solid, that of air being i. c. p. i. 23 354 Note i : on the theory of the electric jiuid conductors. Suppose that there is a deficiency of five units of electricity for each square centimetre of the surface on both sides of a sheet of gold leaf whose thickness is the hundred thousandth part of a centimetre. We have no reason to believe the gold leaf to be entirely deprived of electricity, but even if it were, we must admit that every cubic centimetre of gold requires more than a million units of electricity to saturate it. But we have by no means reached the limit of our experimental evidence. For Cavendish shows in Art. 49 that if in any portion of a bent canal the re- pulsion of overcharged bodies is so great as to drive all the fluid out of that portion, then the canal will no longer allow the fluid to run freely from one end to the other, any more than a siphon will equalize the pressure of water in two vessels, when the water does not rise to the bend of the siphon. Hence if we could make the canal narrow 'enough, and the electric repulsion of bodies near the bend of the canal strong enough, we might have two con- ductors connected by a conducting canal but not reduced to the same potential, and this might be tested by afterwards connecting them by means of a con- ductor which does not pass close to any overcharged body, for this conductor will immediately reduce the two bodies to the same potential. Such an experiment, if successful, would determine at once which kind of electricity ought to be reckoned positive, for, as Cavendish remarks in Art. 50, the presence of an undercharged body near the bend of the canal would not prevent the flow of electricity. But even if the electric fluid were not all driven out of the canal, but only out of a stratum near the surface, the effective conducting channel would thereby be narrowed, and the resistance of the canal to an electric current increased. Now we may construct the canal of a strip of the thinnest gold leaf, and we may measure its electric resistance to within one part in ten thousand, so that if the presence of an overcharged body near the gold leaf were to drive the electric fluid out of a stratum of it amounting to the ten thousandth part of its thickness, the alteration might be detected. Hence we must admit either that the one-fluid theory is wrong, or that every cubic centimetre of gold con- tains more than ten thousand million units of electricity. The statement which Cavendish gives of the action between portions of the electric fluid and between the electric fluid and ordinary matter is nearly, but not quite, as general as it can be made. Since the mode in which the force varies with the distance is the same in all cases, we may suppose the distance unity. Two equal portions of the electric fluid which at this distance repel, each other with a force unity are defined to be each one unit of electricity. Let the attraction between a unit of the electric fluid and a gramme of matter be a. Since we may suppose this force different for different kinds of matter, we shall distinguish the attraction due to different kinds of matter by different suffixes, as a1 and «2. Let the repulsion between two grammes of matter entirely deprived of electricity be rn, these two portions of matter being of the kinds corresponding to the suffixes i and 2. Saturated bodies 355 Now consider a body containing M grammes of matter and F units of the electric fluid. The repulsion between this body and a unit of the electric fluid at distance unity is F - Ma. (i) If this expression is zero, the body will neither repel nor attract the electric fluid. In this case the body is said to be saturated with the electric fluid, and the condition of saturation is that every gramme of matter contains a units of the electric fluid. From what we have already said, it is plain that a must be a number reckoned by thousands of millions at least. The definition of saturation as given by Cavendish is somewhat different from this, although on his own hypothesis it leads to identical results. He makes the condition of saturation to be (in Art. 6) " that the attraction of the electric fluid in any small part of the body on a given particle of matter shall be equal to the repulsion of the matter in the same small part on the same particle." Hence this condition is expressed by the equation Fa = Mr. (2) But as the essential property of a saturated body is that it does not disturb the distribution of electricity in neighbouring conductors, we must consider the true definition of saturation to be that there is no action on the electric fluid. Now [following Cavendish's ideas] consider two bodies of different kinds of matter Ml and M2, and let each of them be saturated. The quantity of electric fluid in the first will be F! = Mjalt (3) and that in the second F2 = M 2a2 . (4) The repulsion between the two bodies will be FIF* ~ FiMza2 - F2Af ^ + MjMfu , (5) or, substituting the values of Fl and F2 , and changing the signs, it will be an attraction equal to AfjAf.teaj-fu). (6) Now we know that the action between two saturated bodies is an attraction equal to M^Jt, (7) where k is the constant of gravitation. Hence we must make •A - »u "" * (8) for every two kinds of matter, k being the same for all kinds of matter. According to Baily's repetition of Cavendish's experiment for determining the mean density of the earth*, (centimetre)3 k = 6-506 x io-* - —3 . (9) gramme . second * Baily's adopted mean for the earth's density is 5-6604, which, with the values of the earth's dimensions and of the intensity of gravity at the earth's surface used by Baily himself, gives the above value of k as the direct result of his experiments. [Cavendish's value 5-45 has been shown by modern determinations to be too small by less than two per cent.] 23 2 356 Note I : on the theory of the electric Jiuid This number is exceedingly small compared to the product a^, which is of the order zo20 at least. Hence rlt, the repulsion between two grammes of matter entirely deprived of electricity, is of the same order as a^. If we consider the attraction of gravitation as something quite independent of the attractions and repulsions observed in electrical phenomena, we may suppose - so that two saturated bodies neither attract nor repel each other. Now we have adopted as the condition of saturation, that neither body acts on the electric fluid in the other. But since neither body acts on the other as a whole [gravitation now being a separate phenomenon] , each has no action on the matter in the other, so that our definition of saturation coincides with that given by Cavendish. Lastly, let the two bodies not be saturated with electricity, but contain quantities F1 + El and F2 + Ez respectively, where Fl = a^M^, and F2 = a^M^, and El and E2 may be either positive or negative, provided that F + E must in no case be negative. The repulsion between the bodies is (Fl + EJ (F2 + E2) - (F, + £x) M2«2 - (F2 + E2) M.a, and this by means of equations (3) (4) and (10) is reduced to Theory of Two Fluids. In the theory of Two Electric Fluids, let V denote the quantity of the Vitreous fluid and R that of the Resinous. Let the repulsion between two units of the same fluid be b, and let the attraction between two units of different fluids be c. Let the attraction between a unit of either fluid and a gramme of matter be a, and let the repulsion between two grammes of matter be r. If a body contains V1 units of vitreous, Rt units of resinous electricity, and M 1 grammes of matter, its repulsion on a unit of vitreous electricity will be VJ) - Rf - M&, and the repulsion on a unit of resinous electricity - VjC + RJ - M ,«!. The definition of saturation is that there shall be no action on either kind of electricity. Hence, equating each of these expressions to zero, we find as the conditions of saturation The theory of two fluids 357 The total repulsion between the two bodies is If we now put V1 = A/\ ~— + ^S,^ + ££1( o — c the total repulsion becomes „ „ b + c „ „ b — c £,£2 — + S,S2 -j- - The first term of this expression, with its sign reversed, represents the attraction of gravitation, and the second term represents the observed electric action, but the other terms represent forces of a kind which have not hitherto been observed, and we must modify the theory so as to account for their non- existence. One way of doing so is to suppose b = c and a^ = «2 = o. The result of this hypothesis is to reduce the condition of saturation to that of the equality of the two fluids in the body, leaving the amount of each quite undetermined. It also fails to account for the observed action between the bodies themselves, since there is no action between them and the electric fluids. The other way is to suppose that S1 = S2 = o, or that the sum of the quantities of the two fluids in a body always remains the same as when the body is saturated. This hypothesis is suggested by Priestley in his account of the two-fluid theory, but it is not a dynamical hypothesis, because it does not give a physical reason why the sum of these two quantities should be incapable of alteration, however their difference is varied. The only dynamical hypothesis which appears to meet the case is to suppose that the vitreous and resinous fluids are both incompressible, and that the whole of space not occupied by matter is occupied by one or other of them. In a state of saturation they are mixed in equal proportions. The two-fluid theory is thus considerably more difficult to reconcile with the facts than the one-fluid theory. 358 Note 2: distribution of attracting ftuid NOTE 2, ARTS. 27 AND 282. [Distribution in spheres and ellipsoids.} The problem of the distribution, in a sphere or ellipsoid, of a fluid, the particles of which repel each other with a force varying inversely as the nth power of the distance, has been solved by Green*. Green's method is an ex- tremely powerful one, and allows him to take account of the effect of any given system of external forces in altering the distribution. If, however, we do not require to consider the effect of external forces, the following method enables us to solve the problem in an elementary manner. It consists in dividing the body into pairs of corresponding elements, and finding the condition that the repulsions of corresponding elements on a given particle shall be equal and opposite. (i) Specification of Corresponding Points on a line. Let A^AZ be a finite straight line, let P be a given point in the line, and let Ql and Q2 be corresponding points in the segments A-f and PA% respectively, the condition of correspondence being It is easy to see that when Ql coincides with Alt Q2 coincides with Az, and that as Ql moves from Al to P, Q2 moves in the opposite direction frOm At to P, so that when Ql coincides with P, Q2 also coincides with P. Let Qi and Q2' be another pair of corresponding points, then i i i i Qt'P Af ~ PQt' PA2 • Subtracting (i) from (2) — — — — Q,'P Q,P PQ2' PQ2' QiQi C/Pi QSP . Q,P PQ2' . PQZ • If the points Ql and Qv' are made to approach each other and ultimately to coincide, QjQi ultimately becomes the fluxion of Q, which we may write Qi, and we have * "Mathematical Investigations concerning the laws of the equilibrium of fluids analogous to the electric fluid, with other similar researches," Transactions of the Cambridge Philosophical Society, 1833. Read Nov. 12, 1832. See Mr Ferrers' Edition of Green's Papers, p. 119. in an ellipsoid 359 or corresponding elements of the two segments are in the ratio of the squares of their distances from P. Let us now suppose that A^PA^ is a double cone of an exceedingly small aperture, having its vertex at P; let us also suppose that the density of the redundant fluid at Ql is plt and at Q2 is pz; then since the areas of the sections of the cone at Q1 and Q2 are as the squares of the distances from P, and since the lengths of corresponding elements are also, by (5), as the squares of their distances from P, the quantities of fluid in the two corresponding elements at Q1 and Q2 are as piQ^P* to p2PQ2*. If the repulsion is inversely as the «th power of the distance, the condition of equilibrium of a particle of the fluid at P under the action of the fluid in the two corresponding elements at Ql andn " T~P • ...... (7 1 QJP Multiplying the corresponding members of equations (i) and (7) and omitting the common factor A^P .PAt, we may therefore write, instead of equation 6, Pi (A 1Q1 . Q1A ^ = p, (A jQs Let us now suppose that A^A2 is a chord of the ellipsoid, whose equation is aa 6" ca If we write X2 V2 Z' A2 lir\ - 02- p-^2-/)> then the product of the segments of the chord at (?j is to the product of the segments at Q2 as the values of p2 at these points respectively, or We may therefore write, instead of equation (9), If, therefore, throughout the ellipsoid, p = Cp"-*, (14) where C is constant, every particle of the fluid within the ellipsoid will be in equilibrium. 360 Note 2: distribution of an attracting fluid We have in the next place to determine whether a distribution of this kind is physically possible. Let E be the quantity of redundant fluid in the ellipsoid; then /•. C I p"-* \Ttabc p (i - p'rfdp .'a = 4-nabcC pn~3 (i - />2)4 dp ...... (15) r r 2 Let p0 be the density of the redundant fluid if it had been uniformly spread through the volume of the ellipsoid, then ...... (17) and if p is the actual density of the redundant fluid, When n is not less than 2, there is no difficulty about the interpretation of this result. The density of the redundant fluid is everywhere positive. When n = 4 it is everywhere uniform and equal to p0 . When n is greater than 4 the density is greatest at the centre and js zero at the surface, that is to say, in the language of Cavendish, the matter at the surface is saturated. When n is between 2 and 4 the density of the redundant fluid at the centre is positive and it increases towards the surface. At the surface itself the density becomes infinite, but the quantity collected on the surface is insensible compared with the whole redundant fluid. When n is equal to 2, F (— — J becomes infinite, and the value of p is zero for all points within the ellipsoid, so that the whole charge is collected on the surface, and the interior parts are exactly saturated, and this we find to be consistent with equilibrium. When n is less than 2 the integral in equation (15) becomes infinite. Hence if we assume a value for C in the interior parts of the ellipsoid, we cannot extend the same law of distribution to the surface without introducing an infinite quantity of redundant fluid. We might therefore conclude that if the quantity of redundant fluid is given, we must make C = o, and suppose the redundant fluid to be all collected at the surface, and the interior to be exactly in an ellipsoid 361 saturated. But, on trying this distribution, we find that it is not consistent with equilibrium. For when n is less than 2, the effect of a shell of fluid on a particle within it is a force directed from the centre. If, therefore, a sphere of saturated matter is surrounded by a shell of electric fluid, the fluid in the sphere will be drawn towards the shell, and this process will go on till the different parts of the interior of the sphere are rendered undercharged to such a degree that each particle of fluid in the sphere is as much attracted to the centre by the matter of the sphere as it is repelled from it by the fluid in the sphere and the shell together. This is the same conclusion as that stated by Cavendish. Green solves the problem, on the hypothesis of two fluids, in the following manner. Suppose that the sphere, when saturated, contains a finite quantity, E, of the positive fluid, and an equal quantity of the negative fluid, and let a quantity, Q, of one of them, say the positive, be introduced into the sphere. Let the whole of the positive fluid be spread uniformly over the surface of the sphere whose radius is a, so that if P' is the surface-density, Green then considers the equilibrium of fluid in an inner and concentric sphere of radius b, acted on by the fluid in the surface whose radius is a, and shows that if the density of the fluid is p = 2 P'a sin "-^ 77 (a2 - 62)^" (a2 - r2)-1 (62 - r2) ~2~ , there will be equilibrium of the fluid within the inner sphere. The value of p is evidently negative if n is less than 2. Green then determines, from this value of the density, the whole quantity of fluid within the sphere whose radius is b, and then by equating this to — E, the whole quantity of negative fluid, he determines the radius, b, of the inner sphere, so that it shall just contain the whole of the negative fluid. The whole of the positive fluid is thus condensed on the outer surface, the whole of the negative fluid distributed within the inner sphere, and the shell between the two spherical surfaces is entirely deprived of both fluids. At the outer surface, the force on the positive fluid is from the centre, but the fluid there cannot move, because it is prevented by the insulating medium which surrounds the sphere. In the shell between the two spherical surfaces the force on the positive fluid would be from the centre. Hence if any positive fluid enters this shell, it will be driven to the outer surface, and if any negative fluid enters, it will be driven to the inner surface. But all the positive fluid is already at the outer surface, and all the negative fluid is already in the inner sphere, where, as Green has shown, it is in equili- brium, and thus the fluids are in equilibrium throughout the sphere. It may be remarked that this solution, according to which a certain portion of matter becomes entirely deprived of both fluids, is inconsistent with the 362 Note 2: distribution of an attracting fluid ordinary statements of the theory of two fluids, which usually assert that bodies, under all circumstances, contain immense quantities of both fluids. In the two-fluid theory, by depriving matter of both fluids, we get an in- active substance which gives us no trouble, but in the one-fluid theory, matter deprived of fluid exerts a strong attraction on the fluid, the consideration of which would considerably complicate the mathematical problem. [In connexion with this remark and with Note 3 a quotation from Green's Memoir of 1833 (§ 6) is relevant. " In order to explain the phenomena which electrified bodies present, Philosophers have found it advantageous either to adopt the hypothesis of two fluids, the vitreous and resinous of Dufay for example, or to suppose with jEpinus and others, that the particles of matter when deprived of their natural quantity of electric fluid, possess a mutual repulsive force. It is easy to per- ceive that the mathematical laws of equilibrium deducible from these two hypotheses ought not to differ, when the quantity of fluid or fluids (according to the hypothesis we choose to adopt) which bodies in their natural state are supposed to contain is so great, that a complete decomposition shall never be effected by any forces to which they may be exposed, but that in every part of them a farther decomposition shall always be possible by the application of still greater forces. In fact the mathematical theory of electricity merely con- sists in determining p the analytical value of the fluid's density, so that the whole of the electrical actions exerted upon any point p, situated at will in the interior of the conducting bodies, may exactly destroy each other, and conse- quently p have no tendency to move in any direction. For the electric fluid itself, the exponent n is equal to 2, and the resulting value of p is always such as not to require that a complete decomposition should take place in the body under consideration; but there are certain values of n for which the resulting values of p will render $pdv greater than any assignable quantity; for some portions of the body it is therefore evident that how great soever the quantity of the fluid or fluids may be, which in a natural state this body is supposed to possess, it will then become impossible strictly to realize the analytical value of p, and therefore some modification at least will be rendered necessary, by the limit fixed to the quantity of fluid or fluids originally contained in the body, and as Dufay's hypothesis appears the more natural of the two, we shall keep this principally in view, when in what follows it may become requisite to introduce either."] Infinite plate with plane parallel surfaces. The distribution of the fluid in an infinite plate with plane parallel surfaces is given in the general solution which we have obtained for a body bounded by a quadric surface, namely, p —- Cpn~*. In the case of the plate we must suppose it bounded by the planes x = + a, and x — — a, and then p is defined by the equation x2 = a2 (i - />»). in disks and thin rods 363 If a is the quantity of fluid in a portion of the plate whose area is unity, /•+ rt = I pdx = Ca • J -a r /«- \ 2 in disk. The distribution in an infinitely thin disk may be deduced from that in an ellipsoid by making one of the axes infinitely small. It is better however to proceed by the method which we have already employed, only that instead of supposing the line AtPA2 (Fig. p. 358) to be a double cone, we suppose it to be a double sector cut from the disk. The breadth of this sector is proportional to the distance from P, so that the condition of equilibrium of the repulsions of two corresponding elements whose surface-densities are cr, and at is ,r-f)_P 3-n _ - n P 3-n whence we find, as before, that if the equation of the edge of the disk is then the surface-density at any point is a = Cpn-\ The quantity of fluid in the disk is found by integrating over the surface of the disk, and is 2 abC , ...... (3) r* = a«(i - M2) (p* - I). ...... (4) If the surface-density of the electricity on the disk is a function of the distance from the axis, it may be expressed in the form a = a0 + or2 + &c., ...... (5) where an= --A^P^(^), ...... (6) and P2n is the zonal harmonic of order 2,n. Only even orders are admissible, for since every element of the disk corresponds to two values of fi, numerically * See Ferrers' Spherical Harmonics, p. 135. 378 Note 1 1 : electrification of two disks equal but of opposite signs, a term involving an harmonic of odd order would give the surface-density everywhere zero. The potential arising from this distribution at any point whose ellipsoidal co-ordinates are (°) = 22nM!n! 2 ' The potential at any point of the disk is therefore the sum of a series of terms, the general form of which is On the axis, p = i and av = z, and the potential is the sum of a series of terms, the general form of which is U*n = Atn±-_Q'2n(v). ...(15) Since we have to determine the value of the potential arising from the first disk at a point in the second disk for which z = c at a distance r from the axis, and if we write r2 = j« (x _ p*)t ...... (16) * See Heine, Handbuch der Kugelfunctionen, § 28, 20. on the same axis far apart 379 where b is the radius of the second disk, and p is a quantity corresponding to /i in the first disk, then the most convenient expression for the potential due to the first disk at a point (p) in the second, is . . -*{l-p) + -- -(I- p) - &c where U denotes the value of the potential at the axis, and where, after the differentiations, va is to be made equal to c. To investigate the mutual action of the two disks, let us assume that the surface-density on the second disk is the sum of a number of terms of which the general form is -^W- ...... (18) The potential at the surface of the second disk arising from this distribution will be the sum of a series of terms of the form The potential arising from the presence of the first disk is given in equa- tion (17). Having thus expressed the most general symmetrical distribution of elec- tricity on the two disks and the potentials thence arising, we are able to calculate the potential energy of the system in terms of the squares and products of the two sets of coefficients A and B. If W denotes the potential energy, W-*ffoV4s, ...... (20) when the integration is to be extended over every element of surface ds. Confining our attention to the second disk, the part of W thence arising is Trb* I aVpdp, ...(21) ./o and the part arising from the term in the density whose coefficient is Btn is f>toW4^ ...... (22) The part of the value of V which arises from the electricity on the second disk itself is the sum of a series of terms of the form (19). The surface-integral of the product of any two of these of different orders is zero, so that in finding the potential energy of the disk on itself we have to deal only with terms of the form ™ 77 1 (an!)2 i . . 2" 4 b 24" (n !)4 4« + i ' The energy arising from the mutual action of the disks consists of terms 380 Note i i ; electrification of two disks whose coefficients are products of A's and B's, and in calculating these we meet with the integral * I (i - p2)mPon (P) dp = (— i)n — — ...(24) Jo 2tn + 2n + i ! m — n ! n ! n ! We have, therefore, for the harmonic of order zero. — A i Surface-density on the first disk, 2) ra . 4 4 . 6 a2 " 7 '* Potential at first disk, T/ - Z. j l2 • 32 [35 4 _ 30 , 31 1 4 ~ 2a A* 22 . 4* L 8 M 8 ^ ' 8J ' Potential at second disk, 4 2 . 4 c s • 7 • 9 7 • 9 • _A^aW±-J?)r2_±6_& -i 2.4 22c' L 7 • 9 J and so on. * I am indebted for the general value of this integral to Mr W. D. Niven, of Trinity College. [See Sir W. Niven's memoir in Phil. Trans. 1879.] on the same axis far apart 381 We have next to calculate the energy arising from this distribution on the first disk, together with a corresponding distribution on the second disk, the coefficients of the harmonics for the second disk being B, B2, B4, &c. It will consist of three parts, the potential energy of the first disk on itself, of the first and second on each other, and of the second on itself. The first part will involve only terms having for coefficients the squares of the coefficients A , for those involving products of harmonics of different orders will vanish on integration. The third part will, for the same reason, involve only squares of the coeffi- cients B. The second part will involve all products of the form AB. Performing the integrations, putting a = ex and b = cy, <4a a 4 * a 4 22 . 5 * a 4 2" + R2 1 1L + B 2 - - * i- B 2 - - — ' b 4 4 ^ b 4 2* . 5 4 ^4 b 4 2« + £(*8 + V8 — ^ * * 2'3'5 *) • 0 I— / / / - 4^« - 3 . 4««y« - 1^-5 ^y _ l^y + &c J 4-5 3 -ii ^5 %2>;2 _ &c J 3-5 -7 II *V _L_ rx _ 4_7 ^2 _. 2 &c 1 c 3-5 -7\- " c 5-7 In this expression for the energy of the system the coefficients A2, At, Ba, B4 are treated as independent of A and B. To determine the nearest approach to equilibrium which can be obtained from a distribution defined by this limited number of harmonics, we must make W a minimum with respect to At, Bt, A 4 and B4'. 382 Note 1 2 : electric capacity We thus find for the values of these coefficients 2 22 f" ^ 7 23^ ~I A.= - B - - *3 i - ^^ x'' - 2v* + i*4 + ^ *2y2 + 3v4 - &c. v 3 L 7 7 J ? - v3 [i - 2*2- i^y + 3*4 + — 3 - 5 Lv4-&c.] We are now able to express the energy in the form where A and B are the charges, and pu, p12, and pZ2 are the coefficients of potential, the values of which we now find to be 77 i 2s 6» T a2 12 62 a4 a262 2 . 3 . 13 b* Pu= - • -a 1 1 — 4 3 - --J+IO-J-+I2--+- — ^ -j - &c. . 2« TT 32 . 5 c6 L c2 7 c2 c4 c4 5 . 7 c4 (a2 + i2) T~ i i a2+62 i a* + b* 2 «262 I fl6 + fc6 i ~ 3 —3- + 5 —jr- + 5 -p- - 7 C7 12 a2 62 2. 3. 13 a4 ~ NOTE 12, ART. 151. Ow ) 2 I ~2 I then the potential, iftn, at the given point (a, |8), due to the distribution An, is where Pn is the same zonal harmonic as in equation (19), and Qn is the corre- sponding zonal harmonic of the second kind*, and is of the form ™ I T n(a), (22) a - I where Rn (a) is a rational function of a of n — i degrees, and is such that Qn (a) vanishes when « is infinite. The values of the first five harmonics of the second kind are \ o fr 4 i o/ then iji0 = ^40Z-, I- 2), ? I\ ,r ,s L~3)> (28) I5|2+3\ (£_2B) These values of the potential are calculated for the axis of the cyb'nder. The potential at the curved surface may be found from that at the axis by remembering that within the cylinder V2^ = o. At a distance b from the axis the potential is therefore , i i d^ us i d^ w w, = w — is b -f- 2. ~+K O — utC.i (2Q) where the values of t/j and its derivatives are those at the axis. For a uniform distribution d2Ji . (I — £ I + A jf* = ~AO( JT + -JT) • (3°) which is approximately - — p , when £ = o, and j , when £ = ± I. Hence, I 2/ when the length of the cylinder is many times its diameter, the potential at of a long narrow cylinder 387 the axis may be taken for that at the surface in approximations of the kind here made. We have next to find the integral of the product of the density into the potential. We may consider the product of each pair of terms by itself. If we write ^i for the value of L when £ = /, or approximately (31) ,3,, - - iAtAtl, The charge is E = $Xdx = zAJ. (33) Determining A 2 so as to make /(A,, + A-J (fa + fa) dx a minimum, we find A x A n -* ^2 ' T"0 T 101 ' *• 3tr and we obtain a second approximation to /f , I (34) 36 t< - W- This approximation is evidently of little use unless the length of the cylinder considerably exceeds 7-245 times its diameter, for this ratio makes the second term of trie denominator infinite. It shows, however, that when the ratio of the length to the diameter is very great, the true capacity approximates to the value of K0 given in (18). We may proceed in the same way to determine A2 and A± so that /(A,, + A2 + A4) (^TO + ift^ + ifit) dx shall be a minimum, and we thus find a third approximation to the value of the capacity, in which u _ :'3 73 Q _ ill ^4 — £yj v -rsis~ ^4 _ ^9 ^ 101\ lu _ «^«»9\ _ 45 ' "4 ' ^TT^'O /g __ 1 u II \ /y 8»89\ 45 so that when \i is very large the distribution approximates to The value of the inferior limit of the capacity, as given by this approxi- mation, is K , 5 ~ __ __ _ _ ~,f. <. 101 ^ru-i (.1 101\I7tt 101\/o «98»\ 461 3° * ~ -^TT 4°° U - TnrJ LI* TnrJ I* ntm TWJ As « increases, /^ approaches to the value found by the first approximation. 25—2 388 Note 13: electric distribution on two cylinders To indicate the degree of approximation, the value of f and of the successive terms of the denominator are given below. 8 Denominator of (34) and (35) b ist term 2"d term 3r"l term 10 3-68888 2-68888 - 0-43151 20 4-38203 3-38203 - 0-13680 30 478749 378749 - 0-09775 50 5-29832 4-29832 - 0-07191 100 5-99146 4-99146 - 0-05291 - 0-13566 looo 8-29405 7-29405 - 0-02818 - 0-00892 The observed capacities of Cavendish's cylinders may be deduced from the numbers given in Art. 281 by taking the capacity of the globe of 12-1 inches diameter equal to 6-05, and their capacities as calculated by the formula of this note are given in the following table. Capacity by As measured by Length Diameter formuia Cavendish 72 -185 5-668 5-669 54-2 -73 5-775 5754 35-9 2-53 5-907 6-044 The agreement of the calculated and measured values is remarkable. NOTE 13, ARTS. 152, 280. [Electric Distribution on] (wo cylinders. In the case of two equal and parallel cylinders at distance c, _the linear densities being uniform and equal to At and A2, the part of the potential energy arising from their mutual action is -i jX^dx = fafadx - AA (4! log r - 2f) , \ / where r2 = 4/2 + c2. If the two cylinders are in electric communication with each other A, — A2 , and the capacity of the two cylinders together is approximately _ 2/ _ 4/ r 2l r - c ' If a cylinder is placed at a distance d from a conducting plane surface and parallel to it, then the electric image of the cylinder will be at a distance c = zd, and its charge will be negative, so that the capacity of the cylinder will be increased. The capacity of the cylinder in presence of a conducting plane at distance \c, is , . 4/ . r + zl r - c log J- -i- log — +-J- Thus in Cavendish's experiment he used a brass wire 72 inches long and 0-185 i'1 diameter. Tin: capacity of this wire at a great distance from any other On capacity of a condenser with curved plates 389 body would be 5-668 inches. Cavendish placed it horizontally 50 inches from the floor. The inductive action of the floor would increase its capacity to 5-994 inches; Cavendish, by comparison with his globe, makes it 5-844. To compare with this he had two wires each 36 inches long and o-i inch diameter. The capacity of one of these at a distance from any other body would be 2-8697 inches, or the two together would be 5-7394 inches. The two wires were placed parallel and horizontal at 50 inches from the floor. Each wire was therefore influenced by the other wire, and also by the negative images of itself and the other wire. The denominator of the fraction expressing the capacity is therefore Wire Other Own Other itself wire image image 18 6-2724 + 0-8256 — 0-1759 - 0-1754 = 6-7467 24 6-2724 + 0-6596 - 0-1759 - 0-1733 = 6-5828 36 6-2724 + 0-4672 - 0-1759 — 0-1678 = 6-3959 The numerator of the fraction which expresses the capacity of both wires together is 36, so that the capacity of the two is From Cavendish's results At 18 inches 5-334 4-967 24 5-469 5-026 36 5-629 5-277 Wire of 72 inches 5-994 5'844 NOTE 14, ART. 155. Lemma XVI. If we suppose the plate AB to be overcharged and the plate DF to be equally undercharged, the redundant fluid in any element of AB being numeri- cally equal to the deficient fluid in the corresponding element of DF, then what Cavendish calls the repulsion on the column CE in opposite directions becomes in modern language the excess of the potential at C over that at E. Hence the object of the Lemma is to determine approximately the difference of the potentials of two curved plates when their equal and opposite charges are given, and to deduce their charges when the difference of their potentials is given. [Compare Green's formula, Essay, § 8.] NOTE 15, ART. 169. On the Theory of Dielectrics. Cavendish explains the fact discovered by him, that the charge of a coated glass plate is much greater than that of a plate of air of the same dimensions, by supposing that in certain portions of the glass the electric fluid is free to move, while in the rest of the glass it is fixed. 390 Note 15: on the theory of dielectrics Probably for the sake of being able to apply his mathematical theorems, he takes the case in which the conducting parts of the glass are in the form of strata parallel to the surfaces of the glass. He is perfectly aware that this is not a true physical theory, for if such conducting strata existed in a plate of glass, they would make it a good conductor for an electric current parallel to its surfaces. As this is not the case, Cavendish is obliged to stipulate, as in this proposition, that the conducting strata conduct freely perpendicularly to their surfaces, but do not conduct in directions parallel to their surfaces. The idea of some peculiar structure in plates of glass was not peculiar to Cavendish. Franklin had shown that the surface of glass plates could be charged with a large quantity of electricity, and therefore supposed that the electric fluid was able to penetrate to a certain depth into the glass, though it was not able to get through to the other side, or to effect a junction with the negative charge on the other side of the plate. The most obvious explanation of this was by supposing that there was a stratum of a certain thickness on each side of the plate into which electricity can penetrate, but that in the middle of the plate there was a stratum im- pervious to electricity. Franklin endeavoured to test this hypothesis by grinding away five-sixths of the thickness of the glass from the side of one of his vials, but he found that the remaining sixth was just as impervious to electricity as the rest of the glass*. It was probably for reasons of this kind, as well as to ensure that his thin plates were of the same material as his thick ones, that Cavendish prepared his thin plate of crown glass by grinding equal portions off both sides of a thicker plate. [Art. 378.] It appears, however, from the experiments, that the proportion of the thickness of the conducting to the non-conducting strata is the same for the thin plates as the thick ones, so that the operation of grinding must have re- moved non-conducting portions as well as conducting ones, and we cannot suppose the plate to consist of one non-conducting stratum with a conducting stratum on each side, but must suppose that the conducting portions of the glass are very small, but so numerous that they form a considerable part of the whole volume of the glass. If we suppose the conducting portions to be of small dimensions in every direction, and to be completely separated from each other by non-conducting matter, we can explain the phenomena without introducing the possibility of conduction through finite portions of glass. It was probably because Cavendish had made out the mathematical theory of stratified condensers, but did not see his way to a complete mathematical theory of insulating media, in which small conducting portions are disseminated, that he here expounds the theory of strata which conduct electricity perpen- dicularly to their surfaces but not parallel to them. * Franklin's Works, 2nd Edition, vol. I, p. 301, Letter to Dr Lining, March 18, Residual discharge 391 In forming a theory of the magnetization of iron, Poisson was led to the hypothesis that the magnetic fluids are free to move within certain small portions of the iron, which he calls magnetic molecules, but that they cannot pass from one molecule to another, and he calculates the result orfthe supposition that these molecules are spherical, and that their distances from each other are large compared with their radii. When Faraday had afterwards rediscovered the properties of dielectrics, Mossotti, noticing the analogy between these properties and those of magnetic substances, constructed a mathematical theory of dielectrics, by taking Poisson's memoir and substituting electrical terms for magnetic, and Italian for French, throughout. A theory of this kind is capable of accounting for the specific inductive capacity being greater than unity, without introducing conductivity through portions of the substance of sensible size. Another phenomenon which we have to account for is that of the residual charge of condensers, and what Faraday called electric absorption. The only notice which Cavendish has left us of a phenomenon of this kind is that recorded in Arts. 522, 523, in which it appeared "that a Florence flask contained more electricity when it continued charged a good while than when charged and dis- charged immediately." To illustrate this phenomenon, I gave in "Electricity and Magnetism," Art. 328, a theory of a dielectric composed of strata of different dielectric and con- ducting properties*. Professor Rowland has since shownf that phenomena of the same kind would be observed if the medium consisted of small portions of different kinds well mingled together, though the individual portions may be too small to be observed separately. It follows from the property of electric absorption that in experiments to determine the specific inductive capacity of a substance, the result depends on the time during which the substance is electrified. Hence most of those who have attempted to determine the value of this quantity for glass have obtained results so inconsistent with each other as to be of no use. It is absolutely necessary, in working with glass, to perform the experiment as quickly as possible. Cavendish does not give the exact duration of one of his "trials," but each trial probably took less than two or three seconds. His results are therefore comparable with those recently obtained by HopkinsonJ, who effected the different operations by hand. * [See J. Hopkinson's collected Scientific Papers for theory and experiment.] f American Journal of Mathematics, No. I, 1878, p. 53. J Proceedings of the Royal Society, June 14, 1877; Phil. Trans. 1878, Part r, p. 17. [Reprinted in collected Scientific Papers.} 39 2 Note 1 6.- mutual influences of condensers The results obtained by Gordon*, who employed a break which gave 1200 interruptions per second, and those obtained by Schiller f by measuring the period of electric oscillations, which were at the rate of about 14,000 per second, are much smaller that those obtained by Cavendish and by Hopkinson. Hopkinson finds that the quotient of the specific inductive capacity divided by the specific gravity does not vary much in different kinds of flint glass. As Cavendish always gives the specific gravity, I have compared his results with those of Hop*kinson for glass of corresponding specific gravity. Electrostatic capacity of glass. Flint-glass ......... 3-279 7-93 Do., a thinner piece 3-284 7-65 Light flint ......... 3-2 6-85 3-013 2-96 Dense flint ......... 3-66 7-4 3'O54 3-66 Double extra-dense flint ... 4-5 10-1 3-i64 Very light flint ...... 2-87 6-57 5-83 Plate-glass ......... 2-8 8 6-10 6-43 Crown-glass ......... 2-53 8-6 3-108 NOTE 16, ART. 185. Mutual Influence of two Condensers. To find the effect on the capacity of a condenser arising from the presence of another condenser at a distance which is large compared with the dimensions of either condenser. Let A and B be the electrodes of the first condenser, let L and N be the capacities of A and B respectively, and M their coefficient of mutual induction, then if the potential of A is I and that of B is o, the charge of A will be L and that of B will be M , and if both A and B are at potential i the charge of the whole will be L + zM + N, and this cannot be greater than half the greatest diameter of the condenser. Let a and b be the electrodes of the second condenser, let its coefficients be I, m, n, and let its distance from the first condenser be R. Let us first take the condenser AB by itself, and let us suppose that the potentials of A and B are x and y respectively, then their charges will be Lx + My and MX + Ny respectively. At a distance R from the condenser the potential arising from these charges Will \)(* {Lx + M(x + y) + Ny} R-i = P, * Proc. R. S. Dec. 12, 1878. f Pogg- Ann. 152 (1874), p. 535. and conductors 393 and if the second condenser, whose capacity when its electrodes are in contact is / + 2m + «, is placed at a distance R from the first and connected to earth, its charge will be - P (I + 2m + n) = Q. This charge of the second condenser will produce a potential QR"1 at a distance R, and will therefore alter the potentials of A and B by this quantity, so that the potentials of A and B will be x + QR~l and y + QR~l respectively. To find the capacity of A as altered by the presence of the second con- denser, we must make the potential of A = i and that of B — o, which gives x - {Lx + M (x + y) + Ny} (I + 2m + n) R-* = i, y - {Lx + M (x + y) + Ny} (I + 2m + n) R~z = o. Hence x = y + i, and y = {L + M + (L + 2M + N) y} (I + 2m -| n) R-'2, (L + M)(l+2m + n} R~* i - (L + 2M + N) (1+ 2m + n) R~2 ' and the capacity of A is Lx + My or L + (L + M) y, or (L + M)2 (I + 2m + n) [AA] = L of B is M [AB] = M + af a and b [Aa] = - 2 - (L + 2M + N) (I + 2m + n) ' The charge of B is MX + Ny or M + (M + N) y, or (Z. + M) (M + N) (I + 2tn + n) R*-(L+2M + N) (l + 2m + n) ' The charges of a and b are — (I + m) P and — (m + n) P respectively, 01 R (L + M)(l + m) [Ab] = A'2 - (L + 2M + N) (I + 2m + n) R (L + M) ( m + n) R* - (L + 2M + N) (I + 2m + n) ' In these expressions we must remember that M is a negative quantity, that L + M and M + N can neither of them be negative, and that their sum L + zM + N cannot be greater than the largest semidiameter of the condenser. Hence if R is large compared with the dimensions of the condensers, the second terms of the values of [A A] and [AB] will be quite insensible, and even if the condensers are placed very near together these terms will be small compared with L, M, or N. If a, instead of being part of a condenser, is a conductor at a considerable distance from any other conductor, we may put m = n = o, and if A is also a simple conductor, M = N = o, and we find L2/ [AA] = L + ^5- Tl , RLl ~^' by which the capacities and mutual induction of two simple conductors at a distance R can be calculated when we know their capacities when at a great distance from other conductors. See Note 24. 394 Note 17: theory of Cavendish s trial plate NOTE 17, ART. 194. Theory of the Experiment with the Trial Plate. Let A and B be the inner, a and b the outer coatings of the Leyden jars. Let C be the body tried and D the trial plate, M the wire connecting A with C, and N the wire connecting b with D. Let £ be the electrometer with its connecting wires. Let the coefficients of induction be expressed by pairs of symbols within square brackets, thus, let [(A + C) (C + D)] denote the sum of the charges of A and C when C and D are both raised to potential i and all the other con- ductors are at potential o. First Operation. — The insides of the two jars are charged to potential P0, the outsides and all other bodies being at potential o. The charge of A is [A (A + B)] P0, and that of b is [b (A + B)] P0. Second Operation. — The outside coating of b is insulated, the charging wire is removed, and the inside of B is connected to earth. The charges of A and of b remain as before. Third Operation. — A is connected to C by the wire M, and b is connected to D by the wire 2V. The charge of A is communicated to A , C, and M , and the potential of this system is Plt and the charge of b is communicated to b, D, and 2V, and the potential of this system is Pg. Hence we have the following equations to determine P1 and P2 in terms of PC, [(A + C + M) (A + C + M)] Pl + [(A + C + M) (b + D + 2V)] P2 = [A(A+B)]P0 (i) [(A + C + M) (b + D + N)] Pl + [(b + D + 2V) (b + D + 2V)] P2 = [b(A+B)]P0 (2) Fourth Operation. — The wires M and 2V are disconnected from C and D respectively, and the jars A and b are discharged and kept connected to earth. The charges of C and D remain the same as before. Fifth Operation. — The bodies C and D are connected with each other and with the electrometer E, and the final potential of the system CDE is observed by the electrometer to be P3. Equating the final charge of the system CDE to that of the system CD at the end of the fourth equation, [(C + D + E) (C + D + E)] P3 = [(C + D)(A + C + M)] Pl + [(C + D)(b+-D + N)]P, (3) in terms of coefficients of induction 395 Eliminating P1 and P2 from equations (i), (2) and (3), P3 [(C + D + E)2] {[(A + C + M)2] [(b + D + N)*] - [(A + C + M) (b + D + N)]*} (\A(A + B)} {[(C + D)(A + C + M)] [(b + D + N)*] \ -l(C + D)(b + D + N)]((A + C + M)(b + D + N)}} \ 0 [b (A + B)] {[(C + D)(b + D + N)][(A + C + M)*} -[(C + D)(A + C + M)] [(A+C + M)(b + D + N)]}) By means of his gauge electrometer, Art. 249, Cavendish made the value of P0 the same in every trial, and altered the capacity of D, the trial plate, so that P3 in one trial had a particular positive value, and in another an equal negative value. He then wrote down the difference of the two values of D as an indication to guide him in the choice of trial plates, and the sum of the two values, by means of which he compared the charges of different bodies. He then substituted for C a body, C', of nearly equal capacity, and repeated the same operations, and finally deduced the ratio of C to C' from the equation C : C' : : D, + Dt : £>/ + £>,_'. The capacities of the two jars were very much greater than any of the other capacities or coefficients of induction in the experiment, and of these [b (B + b)] was less than half the greatest diameter of the second jar, and may therefore be neglected in respect of [b2] or [Bb]. We may therefore put [Bb] = - [ft2], and in equation (4) neglect all terms except those containing the factors [A*] [b2] or [A2] [Bb]. We thus reduce equation (4) to the form P3 [(C + D + E)2] = P0{[(C + D) (A + C + M)] - [(C + D) (b + D + N)]} - [£>*] - [D (b + N)] + [D (A + M)]} ....... (5) The bodies to be compared were either simple conductors, such as spheres, disks, squares and cylinders, and those trial plates which consisted of two con- ducting plates sliding on one another, or else coated plates or condensers. Now the coefficient of induction between a coated plate and a simple con- ductor is much less than that between two simple conductors of the same capacity at the same distance, and the coefficient of induction between two coated plates is still smaller. See Note 16. Hence if both the bodies tried are coated plates, the equation (5) is reduced ^3 ([C2] + [Z>2J + [£2!) = P0 ([C2] - [fl2]), ...... (6) so that the experiment is really a comparison of the capacities of the two bodies C and D. But if either of them is a simple conductor, we must add to its capacity its coefficient of induction on the wire and jar with which it is connected, and subtract from it its coefficient of induction on the other wire and jar. These two coefficients of induction are both negative, but that belonging to its own 396 Note ij: theory of Cavendistis trial plate wire and jar is probably greater than the other, so that the correction on the whole is negative. Hence in Cavendish's trials the capacity deduced from the experiment will be less for a simple conductor than for a coated plate of equal real capacity. This appears to be the reason why the capacities of the plates of air when expressed in "globular inches," that is, when compared with the capacity of the globe, are about a tenth part greater than their computed values. See Art. 347. It would have been an improvement if Cavendish, instead of charging the inside of both jars positively and then discharging the outside of B, had charged the inside of A and the outside of B from the same conductor, and then con- nected the outside of both to earth, using the inside of B instead of the outside, to charge the trial plate negatively. In this way the excess of the negative electricity over the positive in B would have been much less than when the outside was negative. With a heterostatic electrometer, such as those of Bohnenberger or Thomson, in which opposite deflections are produced by positive and negative electrifi- cation, the determination of the zero electrification may be made more accu- rately than any other, and with such an electrometer P3 should be adjusted to zero. But the only electrometer which Cavendish possessed was the pith ball electrometer, in which the repulsion between the balls when at any given distance depends on the square of the electrification, and in which therefore the indications are very feeble for low degrees or electrification. Cavendish therefore first adjusted his trial plate so as to produce a given amount of separa- tion of the balls by positive electrification, and then altered the trial plate so as to produce an equal separation by negative electrification. In each case he has recorded a number expressing the side of a square electrically equivalent to the trial plate, together with the difference and the mean of the two values. He seems to have adopted the arithmetical mean as a measure of the charge of the body to be tried. It is easy to see, however, that the geometrical mean would be a more accurate value. For, if we denote the values of the final potential of the trial plate by accented letters in the second trial, we have P,' ([C*] + [D*] + [£2]) - P0 ([C«] - [£"]) (7) Since P3 + P,' = o, we find by (6) and (7) [C*\ ([C«] + [£*]) - [D*] [D'"] + J [E*] ([/>*] + (D'*}). If we neglect the capacity of the pith ball electrometer, which is much less than that of the bodies usually tried, this equation becomes [C2]8 = [£>2] [D'*}, or the capacity of the body tried is the geometrical mean of the capacities of the trial plate in its positive and negative adjustments. Note 1 8 : Cavendislis early views on electricity 397 NOTE 18, ART. 216. On the " Thoughts Concerning Electricity," and on an early draft of the Propositions in Electricity. The theory of electricity sketched in the "Thoughts" is evidently an earlier form of that developed in the published paper of 1771. We must therefore consider the "Thoughts" as the first recorded form of Cavendish's theory, and this for the following reasons. (1) Nothing is said in the "Thoughts" of the forces exerted by ordinary matter on itself and on the electric fluid. The only agent considered is the electric fluid itself, the particles of which are supposed to repel each other. This fluid is supposed to exist in all bodies whether apparently electrified or not, but when the quantity of the fluid in any body is greater than a certain value, called the natural quantity for the body, the body is said to be overcharged, and when the quantity is less than the natural quantity the body is said to be undercharged. The forces exerted by undercharged bodies are ascribed, not, as in the later theory, to the redundant matter in the body, but to the repulsion of the fluid in other parts of space. The theory is therefore simpler than in its final form, but it tacitly assumes that the fluid could exist in stable equilibrium if spread with uniform density over all space, whereas it appears from the investigations of Cavendish himself that a fluid whose particles repel each other with a force inversely as any power of the distance less than the cube would be in unstable equilibrium if its density were uniform. This objection does not apply to the later form of the theory, for in it the equilibrium of the electric fluid in a saturated body is rendered stable by the attraction exerted by the fixed particles of ordinary matter on those of the electric fluid. (2) The hypotheses are reduced in the later theory to one, and the third and fourth hypotheses of the "Thoughts" are deduced from this. (3) In the "Thoughts" Cavendish appears to be acquainted only with those phenomena of electricity which can be observed without quantitative experi- ments. Some of his remarks, especially those on the spark, he repeats in the paper of 1771, but in that paper (Art. 95) he refers to certain quantitative experiments, the particulars of which are now first published [Art. 265]. The "Thoughts," however, though Cavendish himself would have con- sidered them entirely superseded by the paper of 1771, have a scientific interest of their own, as showing the path by which Cavendish arrived at his final theory. He begins by getting rid of the electric atmospheres which were still clinging to electrified bodies, and he appears to have done this so completely that he does not think it worth while even to mention them in the paper of 1771. 398 Note 1 8: GaroenduKt early views on electricity He then introduces the phrase "degree of electrification" and gives a quantitative definition to it, so that this, the leading idea of his whole research, was fully developed at the early date of the "Thoughts." Several expressions which Cavendish freely used in his own notes and journals, but which he avoided in his printed papers, occur in the "Thoughts." Thus he speaks of the "compression" or pressure of the electric fluid. Besides the "Thoughts," which may be considered as the original form of the introduction to the paper of 1771, there is a mathematical paper corre- sponding to the Propositions and Lemmata of the published paper, but following the earlier form of the theory, in which the forces exerted by ordinary matter are not considered, and referring directly to the " Hypotheses " of the " Thoughts. " The first part of this paper is carefully written out, but it gradually becomes more and more unfinished, and at last terminates abruptly, though, as this occurs at the end of a page, we may suppose that the end of the paper has been lost. I think it probable, however, that when Cavendish had advanced so far, he was beginning to see his way to the form of the theory which he finally published, and that he did not care to finish the manuscript of the imperfect theory. The general theory of fluids repelling according to any inverse power of the distance is given much more fully than in the paper of 1771, and the remarks [at the beginning] on the constitution of air are very interesting. I have therefore printed this paper, but in order to avoid interrupting the reader with a repetition of much of what he has already seen, I have placed it at the end of this Note. CAVENDISH'S FIRST MATHEMATICAL THEORY FROM MS. BUNDLE 17. Let a fluid whose particles mutually repel each other be spread uniformly through infinite space. Let a be a particle of that fluid; draw the cone baft continued infinitely, and draw the ,j section bf$: if the repulsion of the particles is inversely as any higher power of the distance than the cube, the particle a will be repelled with infinitely more force from the particles between a and b/3 than from all those situated beyond it, but if their repulsion is inversely as any less power than the cube, then the repulsion of the particles placed beyond bfi is infinitely greater than that of those between a and b/3. If the repulsion of the particles is inversely as the n power of the distance, n being greater than 3, it would constitute an elastic fluid of the same nature as air, except that its elasticity would be inversely as the n + 2 power of the At I ^ distance of the particles, or directly as the - - power of the density of the fluid. But if n is equal to, or less than 3, it will form a fluid of a very different kind from air, as will appear from what follows. His first draft of a theory 399 COR. i. Let a fluid of the above-mentioned kind be spread uniformly through infinite space except in the hollow globe BDE, and let the sides of the globe be so thin that the force with which a particle placed contiguous to the sides of the globe would be repelled by so much of the fluid as might be lodged within the space occupied by the sides of the globe should be trifling in respect of the repulsion of the whole quantity of fluid in the globe. If the fluid within the globe was of the same density as without, the particles of the fluid adjacent to either the inside or outside surface of the globe would not press against those surfaces with any sensible force, as they would be repelled with the same force by the fluid on each side of them. But if the fluid within the globe is denser than that without, then any particle adjacent to the inside surface of the globe will be pressed against by the repulsion of so much of the fluid within the globe as exceeds what would be contained in the same space if it was of the same density as without, and consequently will be greater if the globe be large than if it be small. Consequently the pressure against a given quantity (a square inch for example) of the inside surface of the globe will be greater if the globe is large than if it is small. If the particles of the fluid repel each other with a force inversely as their distance, the pressure against a given quantity of the inside surface would be as the square of the diameter of the globe. So that it is plain that air cannot consist of particles repelling each other in the above-mentioned manner. If the repulsion of the particles was inversely as some higher power of the distance than the cube, then any particle of the fluid would not be sensibly affected except by the repulsion of those particles which were almost close to it, so that the pressure of the fluid against a given quantity of the inside surface would be the same whatever was the size of the globe, but then the elasticity [would] be in a greater proportion than that of the £ power of the density. If the repulsion of the particles is inversely as some less power than the cube of the distance, and the density of the fluid within the globe is less than it is without, then the particles on the outside of the globe will press against it, and the force will be greater if the globe is large than if it be small. If the density of the fluid within the globe be greater than without, then the density will not be the same in all parts of the globe, but will be greater near the surface and less near the middle, for if you suppose the density to be everywhere the same, then any particle of the fluid, as d, would be pressed with more force towards a, the nearest part of the surface of the sphere, than it would [be] in the contrary direction. If the repulsion of the particles is inversely as the square of the distance, I think the inside of the sphere would be uniformly coated with the fluid to a certain thickness, in which the density would be infinite, or the particles would 400 Note 1 8 : Cavendish's early views on electricity be pressed close together, and in all the space within that, the density would be the same as on the outside of the sphere. The pressure of a particle adjacent to the inside surface against it is equal to the repulsion of all the redundant matter in the sphere collected in the center, and the force with which a particle is pressed towards the surface of the sphere diminishes in arithmetical progression in going from the inside surface to that point at which its density begins to be the same as without, therefore the whole pressure against the inside of the sphere is equal to that of half the redundant matter in the sphere pressed by the repulsion of all the redundant matter collected in the center of the sphere. Therefore, if the quantity of fluid in the sphere is such that its density, if uniform, would be i + A, and the radius of the sphere be called r, the whole dr3 dr3 pressure against the inside surface will be as — x — ^ , and the pressure against a given space of the inside surface will be as d2 r2. If this pressure be called P, d is as — — , and dr3 is as r-\/P. Consequently, supposing the fluid to be pumped into different sized globes, the quantity of fluid pumped in will be as the square root [of the force] with which it is pumped, multiplied by the square of the diameter of the globe. If the density within the sphere is less than without, then the density within the sphere will not be uniform, but will be greater towards the middle and less towards the outside, and if the repulsion of the particles is inversely as the square of the distance, there would be a sphere concentric to the hollow globe in which the density would be the same as on the outside of the globe, and all between that and the inside surface of the globe would be a vacuum. From these corollaries it follows that if the electric fluid is of the nature here described, and is spread uniformly through bodies, except when they give signs of electricity, that then if two similar bodies of different sizes be equally electrified, the larger body will receive much less additional electricity in pro- portion to its bulk than the smaller one, and moreover when a body is electrified, the additional electricity will be lodged in greater quantity near the surface of the body than near the middle. Let us now suppose the fluid within the globe BDE to be denser than without, and let us consider [in what manner] the fluid without will be affected thereby. ist. There will be a certain space surrounding the globe, as ftSe, which will be a perfect vacuum, for first let us suppose that the density without the globe is uniform, then any particle would be repelled with more force from the globe than in the contrary direction. 2ndly. Let us suppose that the space jSSe, BDE is not a vacuum, but rarer than the rest of the fluid ; still a particle placed close to the surface of the globe would be repelled from it with more force than in the contrary direction. 3rdly. Let us [suppose that] the density in the space between BDE and /38e is greater than without, then according to some hypothesis of the law of 'Electric fluid communicating by canals 401 repulsion a particle placed at B might be in equilibrium, but one placed at /3 could by no means be so. So that there is no way by which the particles can be in equilibrium, unless there is a vacuum all round the globe to a certain distance. How the density of the fluid will be affected beyond this vacuum I cannot exactly tell, except in the following case: — If the repulsion of the particles is inversely as the square of the distance, there will be a perfect vacuum between BDE and /?8e, and beyond that the density will be perfectly uniform, jSSe being a sphere concentric to BDE, and of such a size, that if the matter in BDE was spread uniformly all over the sphere /?§e, its density would be the same as beyond it. For any quantity of matter spread uniformly over the globe /JSe or BDE affects a particle of matter placed without that sphere just in the same manner as if the whole fluid was collected in the center of the sphere, so that any particle of matter placed without the sphere /J8e will be in perfect equilibrio. In like manner if the fluid within BDE is rarer than without, there will be a certain space surrounding the globe, as that between BDE and /JSe, in which the density will be infinite, or in which the particles will be pressed close together, and if the repulsion of the particles is inversely as the square of the distance, the density of the fluid beyond that will be uniform: the diameter of jSSe being such that if all the matter within it was spread uniformly, its density would be the same as without. Let a fluid of the above-mentioned kind be spread uniformly through infinite space except in the canal acdef of any shape whatsoever, except that the ends aghb and mden are straight canals of an equal diameter, and of such a length that a particle placed at « or d shall not be sensibly affected by the repulsion of the matter in the part gcmnfh, and let there be a greater quantity of the fluid in this canal than in an equal space without. Then the density of the fluid in different parts of the canal will be very different, but I imagine the density will be just the same at a as at d. For suppose ab and de to be joined, as in the figure, by a canal of an uniform diameter and regular shape, nowhere approaching near enough to gcmnfh to be affected by the repulsion of the particles within it. If the matter was not of the same density [at a and .d] the matter therein could not be at rest, but there would be a continual current through the canal, which seems highly improbable. c. p. i. 26 402 Note 1 8: Cavendish's earliest theory COR. Let C be a conductor of electricity of any shape, em and fn wires extending from thence to a great distance. Let a and b be two equal bodies placed on those wires at such a distance from C as not to be sensibly affected C by the electricity thereof, and let the conductor or wires be electrified by any part: the quantity of electric fluid in the bodies a and b will not be sensibly different, or they will appear equally electrified. Case i. Let the parallel planes Aa, Bb, &c., be continued infinitely. Let all infinite space except the space contained between A a and Cc, and between Ee and Hh, A be filled uniformly with particles repelling in- c versely as the square of their distance; let the 3| space between Ee and Hh be filled with fluid of the same density, the particles of which can move from one part to another; and let the space between Aa and Cc be filled with matter o SL whose density is to [that in] the rest of space h as AD to AC. Take EF = JCD, and GH such that the matter between Ee and Ff when pressed close together, so that the particles touch each other, shall occupy the space between Gg and Hh. The space between Ee and Ff will be a vacuum, that between Ff and Gg of the same density as the rest of space ; and between Gg and Hh the particles will touch one another. Case 2. Let everything be as in case the first, except that there is a canal opening into the plane Hh, by which the matter in the space EH is at liberty to escape; part of the matter will then run out, and the density therein will be everywhere the same as without, except in the space EF, which will be a vacuum, EF being equal to CD. Case 3. Suppose now that a canal opens into the plane Aa by which the fluid hi the space AC may escape. It will have no tendency to do so, for the repulsion of the redundant fluid in A C on a particle at a will be exactly equal to [the] want of repulsion of the space EH. Case 4. Let now the space between Aa and Cc be filled with matter whose density is to the rest of space as AB to AC. Then the space between Hh and Gg will be a vacuum, GH being equal to JBC. In the space EF the particles of matter will be pressed together so as to touch each other, the quantity of matter therein exceeding what is naturally contained in that space by as much as is driven out of the space GH ; and in the space between Ff and Gg the matter will be of the same density as without. of an electric fluid 403 Case 5. Suppose now that a canal opens into the plane Hh as in Case 2, then will matter run into the space EH, and the density will be everywhere the same as without, except in the space EF, where the particles will be pressed close together, the quantity of matter therein exceeding the natural quantity by as much as is naturally contained in the space EC. Case 6. Suppose now that a canal opens into the plane Aa, the fluid will have no tendency to run out thereat. Case 7. Let us now consider what will be the result if the repulsion of the particles is inversely as some other power of the distance between that of the square and the cube; and first let us suppose matters as in the first case. There will be a certain space, as EF, which will be a vacuum, and a certain space, as FG, in which the particles will be pressed close together; for if the matter is uniform in EH, all the particles will be repelled towards H if there is not a vacuum at E, nor the particles pressed close together at G, but only the density less at E than at H, then the repulsion of space EH at E will be less on [a] particle at E and greater on a particle at H than if the density was uniform therein, consequently on that account as well, as on account of the repulsion of AC a particle at E or H will be repelled towards H, but if the space EF is a vacuum and the particles in GH pressed close together, then if the spaces EF and GH are of a proper size, a particle at F or G may be in equilibrio. Case 8. If you now suppose a canal to open into the plane Hh as in the 3rd case, some of the matter will run out thereat, so that the whole quantity of matter in the space EH will be less than natural. For if not, it has already been shown that a particle at H will be repelled from A, but the quantity of matter which runs out will not be so much as the redundant matter in AC, for if there was, the want of repulsion of the space EH on a particle at h would be greater than the excess of repulsion of the space AC. Case 9. Suppose now that a canal opens into the plane A a as in Case 3; a particle at « will be repelled from Dd, but not with so much force as if there had been the natural quantity of fluid in the space EH, so that some of the fluid will run out at the canal, but not with so much force, nor will so much of the fluid run out as if there had been the natural quantity of fluid in EH. Case 10. If you suppose matters to be as in the 4th case, then there must be a certain space adjacent to Ee, in which the particles will be pressed close together, and a certain space adjacent to Hh in which there must be a vacuum. Case ii. If you suppose a canal to open into the plane Hh, some matter will run into the space EH thereby, so that the whole quantity of matter therein will be greater than natural. The proof of these two cases is exactly similar to that of the two former. Case 12. If you now suppose a canal to open into Aa, some fluid will run into it, but not with so much force nor in so great quantity as if the natural quantity of fluid had been contained in the space Hh. 26 — 2 404 Note 19: determination of law of electric attraction I have supposed the planes Aa, &c. to be extended infinitely, because by that means I was enabled to solve the question accurately in the cases where the repulsion is supposed inversely as the square of the distance, which I could not have done otherwise, but it is evident that the phenomena will be nearly of the same kind if the planes are not infinitely extended. For if the distance ag be small in respect of the length and breadth of the plane A a, a particle placed at a will be repelled by the plane Aa with very nearly the same force as if the plane was infinitely extended. It is plain that these 6 last cases agree very exactly with the laws of elec- tricity laid down in the 3rd and 4th hypotheses [Thoughts... Art. 202]. If the lines Bb and Dd touch one another so that [Here the MS. ends. ED.] NOTE 19, ART. 234. [Determination of the Law of Electric Attraction.} Cavendish's Experiment on the Charge of a Globe between two Hemispheres. This experiment has recently been repeated * at the Cavendish Laboratory in a somewhat different manner. The hemispheres were fixed on an insulating stand, so as to form a spherical shell concentric with the globe, which stood inside the shell upon a short piece of a wide ebonite tube. By this arrangement, since during the whole experiment the potentials of the globe and sphere remained sensibly equal, the insulating support of the globe was never exposed to the action of any sensible electromotive force, and therefore had no tendency to become charged. If the other end of the insulator supporting the globe had been connected to earth, then, when the potential of the globe was high, electricity would have crept from it along the insulator, and would have crept back again when, in the second part of the experiment, the potential of the globe was sensibly zero. In fact this was the chief source of disturbance in Cavendish's experiment. See Art. 512. Instead of removing the hemispheres before testing the potential of the globe, they were left in their position, but discharged to earth. The effect on the electrometer of a given charge of the globe was less than if the hemispheres had been removed, but this disadvantage was more than compensated by the perfect security from all external electric disturbances afforded by the con- ducting shell. The short wire which formed the communication between the shell and the globe was fastened to a small metal disk hinged to the shell, and acting as a lid to a small hole in it, so that when the lid and its wire were lifted up by * [By Sir Donald M<=Alister in 1878.] from charge on a globe enclosed within hemispheres 405 means of a silk string, the electrode of the electrometer could be made to dip into the hole in the shell and rest on the globe within. The electrometer was Thomson's Quadrant Electrometer. The case of the electrometer, and one of the electrodes, were permanently connected to earth, and the testing electrode was also kept connected to earth, except when used to test the potential of the globe. To estimate the original charge of the shell, a small brass ball was placed on an insulating stand at a distance of about 60 cm. from the centre of the shell. The operations were conducted as follows :— The lid was closed, so that the shell communicated with the globe by the short wire. A Leyden jar was charged from a machine in another room, the shell was charged from the jar, and the jar was taken out of the room again. The small brass ball was then connected to earth for an instant, so as to give it a negative charge by induction, and was then left insulated. The lid was then lifted up by means of the silk string, so as to take away the communication between the shell and the globe. The shell was then discharged and kept connected to earth. The testing electrode of the electrometer was then disconnected from earth, and made to pass through the hole in the shell so as to touch the globe within without touching the shell. Not the slightest deflexion of the electrometer could be observed. To test the sensitiveness of the apparatus, the shell was disconnected from earth and connected to the electrometer. The small brass ball was then dis- charged to earth. This produced a large positive deflexion of the electrometer. Now in the first part of the experiment, when the brass ball was connected to earth, it became charged negatively, the charge being about ^ of the original positive charge of the shell. When the shell was afterwards connected to earth the small ball induced on it a positive charge equal to about one-ninth of its own negative charge. When at the end of the experiment the small ball was discharged to earth, this charge remained on the shell, being about t|ff of its original charge. Let us suppose that this produces a deflexion D of the electrometer, and let d be the largest deflexion which could escape observation in the first part of the experiment. Then we know that the potential of the globe at the end of the first part of the experiment cannot differ from zero by more than ±*v fc 486 D where V is the potential of the shell when first charged. 406 Note 19: determination of law of electric attraction But it appears from the mathematical theory that if the law of repulsion had been as r~(2+9)f the potential of the globe when tested would have been by equation (25), p. 425, 0-1478 x ?F. Hence q cannot differ from zero by more than ± — jr . Now, even in a rough experiment, D was certainly more than 300^. In fact no sensible value of d was ever observed. We may therefore conclude that q, the excess of the true index above 2, must either be zero, or must differ from zero by less than j Theory of the Experiment. Let the repulsion between two charges e and e' at a distance r be f=ee'^(r), ...... (i) where (r) denotes any function of the distance which vanishes at an infinite distance. The potential at a distance r from a charge e is V = er^>(r)df. ...... (2) .'r Let us write this in the form V=cl-f(r), ...... (3) where /*W-^p. ...... (4) and/(r) is a function of r equal to if I I (r) dr\ dr. We have in the first place to find the potential at a given point B due to an uniform spherical shell. Let A be the centre of the shell, a its radius, a its whole charge, and a its surface-density, then a = 47r«2o-. ...... (5) Take A for the centre of spherical co-ordinates and AB for axis, and let AB = b. Let P be a point on the sphere whose spherical co-ordinates are 6 and tf>, and let BP = r, then rz = a2 — lab cos 6 + bz. ...... (6) The charge of an element of the shell at P is aaasin8d8d= - a The potential at P due to this element is aaasin8d8d= - asm9d6d. ...... (7) r (8) Theory of charge on an enclosed globe 407 and the potential due to the whole shell is therefore Integrating with respect to (/> from o to 2ir, ...... (10) Differentiating (6) with respect to 9, rdr = absinOdO. (n) Hence, V == £\ ±f (r)dr = \ ^ {/ (rz) -f (,,)} (12) the upper limit r2 being always a + b, and the lower limit rl being a — b when a > b, and b — a when a < b. Hence, for a point inside the shell for a point on the shell itself and for a point outside the shell -«)}- (15) We have next to determine the potentials of two concentric spherical shells, the radius of the outer shell being a and its charge a, and that of the inner shell being b and its charge /?. Calling the potential of the outer shell A, and that of the inner B, we find by what precedes, B = A/ (26) + JL {/(fl + b} _f(a _ b)} ....... (iy) In the first part of the experiment the shells communicate by the short wire and are both raised to the same potential, say V. Putting A = B = V and solving equations (16), (17), we find for the charge of the inner shell B-2Vb - -- lflffl t)f(2a)f(2b} - {/(«+'6) -f(a - b}}* ' In the original experiment of Cavendish the hemispheres forming the outer shell were removed altogether from the globe and discharged. The potential of the inner shell or globe would then be Bl=^J(2b). ...... (19) In the form of the experiment as repeated at the Cavendish Laboratory, the outer shell was left in its place, but was connected to earth, so that A -= o. 40 8 Note 19: determination of law of electric attraction In this case we find for the potential of the inner shell when tested by the electrometer M. " . } Let us now assume with Cavendish, that the law of force is some inverse power of the distance, not differing much from the inverse square, that is to say>let #(r)-r-'^. ...... (21) then /(,) = _£_,!-,. ...... (22) If we suppose q to be a small numerical quantity, we may expand / (r) by the exponential theorem in the form ~ q log r + (q log r)~ ~ •- ....... (23) and if we neglect terms involving qz, equations (19) and (20) become I a r [~a . a + b 4 (r) = Cl ^ . We may notice, however, that though the assumption of Cavendish, that the force varies as some inverse power of the distance, appears less general than that of Laplace, who supposes it to be any function of the distance, it is the most general assumption which makes the ratio of the force at two different distances a function of the ratio of those distances. If the law of force is not a power of the distance, the ratio of the forces at two different distances is not a function of the ratio of the distances alone, but Note 20: capacity of a thick disk 409 also of one or more linear parameters, the values of which if determined by experiment* would be absolute physical constants, such as might be employed to give us an invariable standard of length. Now although absolute physical constants occur in relation to all the properties of matter, it does not seem likely that we should be able to deduce a linear constant from the properties of anything so little like ordinary matter as electricity appears to be. NOTE 20, ART. 272. On the Electric Capacity of a Disk of sensible Thickness. Consider two equal disks having the same axis, let the radius of either disk be a, and the distance between them b, and let b be small compared with a. Let us begin by supposing that the distribution on each disk is the same as if the other were away, and let us calculate the potential energy of the system. We shall use elliptical co-ordinates, such that the focal circle is the edge of the lower disk. In other words we define the position of a given point by its greatest and least distances from the edge of the lower disk, these distances «(« + j8) and a (a - )8). The distance of the given point from the axis is r=aap, ...... (i) and its distance from the plane of the lower disk is z = a (a2 - i)* (I - p*)l. ...... (2) If AI is the charge of the lower disk, the potential at the given point is ifi = Aa~l cosec"1 a, ...... (3) or, if we write a* = y2 + i, ...... (4) ...... (5) If A 2 is the charge of the upper disk, the density at any point is A a = (6) where p* = «-2 (a2 - r2) = I - «2j32. (7) Putting z = b in equation (2), b2 = a2y2 (i - £2) or j8* = I - -£i • (8) 62 62 Hence p2 = -^- - y2 + —„ . (9) «2y2 a? * [This implies that such parameters are of sensible magnitude, and not deter- mined by the dimensions of the electron.] 41 o Note 20: capacity of a thick disk We have now to multiply the charge of an element of the upper disk into the potential due to the lower disk, and integrate for the whole surface of the upper disk, i 2 Jo \2 / = A1Ata-*(?- jT'tan-iy^) (10) Between the limits of integration we may write with a sufficient degree of approximation, , /h\l\ r h\i\~1 tan-1 y = y = - -ji + (-J I ]/'+(") I • (IJ) At the centre of the disk p = i and At the circumference, •y = - , which agrees with (9). p = o and y = (-) + o(-) by (9), whereas the equation (n) gives fb\* L b rrU) +** so that when b is very small compared with a, the value of y cannot differ greatly from that given by equation (n). Hence we may write the expression (10) 12 The corresponding quantity for the action of the upper disk on itself is got by putting A^ = A% and 6 = 0, and is ^22«-1f- (13) In the actual case A± = Az = J£, where E is the whole charge, and the capacity is or, since in our approximation we have neglected f-J , our result may be ex- pressed with sufficient accuracy in the form (15) showing that the capacity of two disks very near together is equal to that of an infinitely thin disk of somewhat larger radius. If the space between the two disks is filled up, so as to form a disk of sensible thickness, there will be a certain charge on the curved surface, but at the same time the charge on the inner sides of the disks will disappear, and that on the outer sides near the edges will be diminished, so that the capacity of a disk of sensible thickness is very little greater than that given by (15). Note 2 1 : capacity of two circles on the same axis 4 1 1 We may apply this result to estimate the correction for the thickness of the square plates used by Cavendish. The factor by which we must multiply the thickness in order to obtain the correction for the diameter of an infinitely thin plate of equal capacity is — log T . 27T O a i a Tin plate 600 1-017 Hollow plate n 0-381 Portland stone, &c 30 0-540 Slate 75 0-686 The correction is in every case much smaller than Cavendish supposed. NOTE 21, ARTS. 277, 452, 473, 681. Calculation of the Capacity of the Two Circles in Experiment VI. The diameter of one of the circles was 9-3 inches, so that its capacity when no other conductor is in the field is — = 2-060. The distance between their 7T centres was 36, 24, and 18 inches, which we may call clf ca, and c3. The height of the centres of the circles above the floor was about 45 inches, so that the distance of the image of the circle would be about 90 inches and that of the image of the other circle would be about r = (90* + c«)* . Hence, if P is the potential of the circles when the charge of each is i, p _ TT i 2 a2 o _! _ _i 2a c 3 cs where the first term is due to the circle itself, the second and third to the other circle, as in Note 11, and the two last to the images of the two circles. We thus find for the three distances PI = 0-3438, P2 = 0-3567, P3 = 0-3689. The capacity is 2P"1, and the number of "inches of electricity," according to the definition of Cavendish, is 4P-1, or 11-636, H-2I2, 10-844, for the three cases. The large circle was 18-5 inches in diameter and its centre was 41 inches from the floor, so that its charge would be 12-69 inches of electricity. Hence the relative charges are as follows: Calculated The large circle i-ooo i-ooo The two small ones at 36 inches -917 -899 24 -884 -859 18 -855 -811 412 Note 22: capacity of a square plate NOTE 22, ART. 283. Electric Capacity of a Square. I am not aware of any method by which the capacity of a square can be found exactly. I have therefore endeavoured to find an approximate value by dividing the square into 36 equal squares and calculating the charge of each so as to make the potential at the middle of each square equal to unity. The potential at the middle of a square whose side is i and whose charge is i, distributed with uniform density, is 4 log (i + A/2) = 3-52549- In calculating the potential at the middle of any of the small squares which do not touch the sides of the great square I have used this formula, but for those which touch a side I have supposed the value to be 3-1583, and for a corner square 2-9247. A B C C B A B D E E D B If the 30 squares are arranged as in the margin, and __,_,„„„ if the charges of the corner squares be taken for unity, __,_,_,, the charges will be as follows : R n F F D R A B C C B A A B C D E F I-OOO -599 -562 -265 -210 -2OI and the capacity of a square whose side is i will be 0-3607. The ratio of the capacity of a square to that of a globe whose diameter is equal to a side of the square is therefore 0-7214. In Art. 654 Cavendish deduces this ratio from the measures in Art. 478 and finds it 0-73, which is very near to our result. If, however, we take the numbers given in Art. 478, we find the ratio 0-79. From Art. 281 we obtain the ratio 0-747. The ratio of the charge of a square to that of a circle whose diameter is equal to a side of the square is by our calculation 1-133. In Art. 648 Cavendish says that the ratio is that of 9 to 8 or 1-128, which is very close to our result, but in Arts. 283 and 682 he makes it 1-153. The numbers in Art. 281 from which Cavendish deduces this would make it 1-1514. The numbers given in Art. 478 would make it 1-176. Cavendish supposes that the capacity of a rectangle is the same as that of a square of equal area, and he deduces this from a comparison of the square 15-5 with the rectangle 17-9 x 13-4. It is not easy to calculate the capacity of a rectangle in terms of its sides, but we may be certain that it is greater than that of a square of equal area. and of a cube 4 1 3 For if we suppose the electricity on the square rendered immoveable, and if we cut off portions from two sides of the square and place them on the other two sides so as to form a rectangle, we are carrying electricity from a place of higher to a place of lower potential, and are therefore diminishing the energy of the system. If we now make the electricity moveable, it will re-arrange itself on the rectangle and thereby still further diminish the energy. Hence the energy of a given charge on the rectangle is less than that of the same charge on the square, and therefore the capacity of the rectangle is greater than that of the square*. NOTE 23, ARTS. 288 AND 542. On the Charge of the Middle Plate of Three Parallel Plates. The plates used by Cavendish were square, but for the purpose of a rough estimate of the distribution of electricity between the three plates we may suppose them to be three circular disks. First consider two equal disks on the same axis, at a distance small com- pared with the radius of either. If the disks were in contact, the distribution on each would be the same as on each of the two surfaces of a single disk, and it would be entirely on the outer surface. If the distance between the disks is very small compared with their radii, the force exerted by one of the disks at any point of the other will be nearly but not quite normal to its surface. The component in the plane of the disk will be directed outwards from the centre, so that the density will be greater near the edge than in a single disk having the same charge, but as a first ap- proximation we may assume that the sum of the surface-densities on both sides of any element of the disk is the same as if the other disk were away. But the density on the outer surface of the disk will be increased, and the density on the inner surface diminished, by a quantity numerically equal to the normal component of the repulsion of the other disk divided by 477, and the whole charge of the outer surface will be increased, and the whole charge of the inner surface diminished, by a quantity equal to the charge of that part of the other disk, the lines of force from which cut the disk under consideration. * [Approximate results may be readily obtained for such problems by the principle that the potential energy of a system is stationary in the neighbourhood of a position of equilibrium. Thus the energy of a given charge on a square plate is very nearly the same as on a circular plate of equal area: therefore the capacities of the two plates are nearly the same — according to Maxwell's result the capacity is greater for the square plate, in the ratio 1-0027, in agreement with the final argu- ment in the text. So also a cube may be reduced to a sphere of equal volume. The degree of error may be elucidated by comparing the known results for elliptic and circular plates of equal area, or for ellipsoidal and spherical bodies of equal volume. 414 Note 23: charge of middle plate of three Hence the charges of the inner and outer surfaces of the disk are — w and — (a — o>) a a v respectively, where the value of the elliptic co-ordinate cu is that corresponding to the edge of the other disk. If a is the radius of either disk, and c the distance between them, _ If we now place another equal disk on the same axis at a distance c from one of them, the potential being the same for all three, the new disk will greatly diminish the charge of the surface of the disk which is next to it, but it will not have much effect on the charges of the other surfaces. The result will therefore be that the charges of the two outer disks will together be greater, but not much greater, than that of a single disk at the same potential, but the charge of each of the surfaces of the middle disk will be the same as that of one of the inner surfaces of a pair of disks at distance c. Hence the charge of the middle disk will be to that of the two outer disks together as o> to a. If we substitute for the square plates of twelve inches in the side disks of 13-8 inches diameter which would have nearly the same capacity, then if the distance between the outer disks is 1-15 inches, c = -575 and co = 1-936 and a = 3-5 w, or the charge of the middle disk would be 3-5 times greater if the outer disks had been removed. If the distance between the outer disks is 1-65 inches, c = -875 and o> = 2-293, whence « = 2-2 co, or the charge of the middle disk would have been 2-2 times greater if the outer disks had been removed. It is evident, however, that in the assumed distribution the potential is less at the edges of the outer disks than at their centres. The electricity will therefore flow more towards the edges of the outer disks, and, as this will raise the potential near the edge of the middle disk, the charge of the middle disk will be less than on our assumption. I have not attempted to estimate the distribution more approximately. Cavendish found the charge of the middle disk \ and J of what it would have been without the outer disks. This is much less than the first approxi- mation here given, but much greater than Cavendish's own estimate, founded on the assumption that the distribution of electricity follows the same law in the three plates. Note 24: Cavendish's formula for disturbed capacity 415 NOTE 24, ARTS. 338, 652. On the Capacity of a Conductor placed at a finite distance from other Conductors. Cavendish has not given any demonstration of the very remarkable formula given in Art. 338 for the capacity of a conductor at a finite distance from other conductors. We may obtain it, however, in the following manner. If the distance of all other conductors is. considerable compared with the dimensions of the positively charged conductor, C, whose capacity is to be tried, the negative charge induced on any one of the other conductors will- depend only on the charge of the conductor C and not on its shape. This induced charge will produce a negative potential in all parts of the field; let us suppose £• that the potential thus produced at the centre of the conductor C is - — , where E is the charge of C and # is a quantity of the dimensions of a line. If L is the capacity of C when no other conductor is in the field, then the £• potential due to the charge £ will be j , and the potential, which arises from ft E the negative charge induced on other conductors, will be - — , so that the x actual potential will be E ( j - -) . Dividing the charge by the potential we obtain for the actual capacity " x-L' or the capacity is increased in the ratio of x to x - L. The idea of applying this result to determining the value of x by comparing the charges of bodies, the ratio of whose capacities is known, is entirely peculiar to Cavendish, and no one up to the present time seems to have attempted anything of the kind. The height of the centre of the circles above the floor seems to have been about 45 inches. If we neglect the undercharge of other conductors and consider only the floor, x would be about 90 inches in modern measure, but as a capacity x is reckoned by Cavendish as zx "inches of electricity," the value of x in "inches of electricity" would be 180. If we could take into account the undercharged surfaces of the other con- ductors, such as the walls and ceiling, the "machine," etc., the value of x would be diminished, and it is probable that the value obtained from his experiments by Cavendish, i66J, is not far from the truth. 4 1 6 Note 25: calculated capacities of cylinder and -wires NOTE 25, ARTS. 360, 539, 666. Capacities of the large tin Cylinder and Wires. The dimensions of the cylinder are given more accurately in Art. 539. It was 14 feet 8-7 inches long, and 17-1 inches circumference. Its capacity when not near any conductor would be, by the formula in Note 12, 22-85 inches, and when its axis was 47 inches from the floor it would be 31-3 inches, or in Cavendish's language 62-6 inches of electricity. Cavendish makes its computed charge 48-4, and its real charge 73-6. See Art. 666. Now the charge of either of the plates D and E was, by Art. 671, 26-3 inches of electricity, so that tin cylinder = 1-19 (D + E). The capacities of the different wires mentioned in Arts. 360 and 539 are, by calculation, length diameter capacity 29 J 2-67 22 J 2-09 37 "IS 3-13 27-6 -15 2-46 20-8 -15 1-88 31 -15 2-71 24 -15 2-28 The ratio of the charge of the first of these wires to that of the second is 1-37. NOTE 26, ART. 369. Action of Heat on Dielectrics. The effect of heat in rendering glass a conductor of electricity is described in a letter from Kinnersley to Franklin* dated i2th March, 1761. He found that when he put boiling water into a Florence flask he could not charge the flask, and that the charge of a three pint bottle went freely through without injuring the flask in the least. Franklin in his reply describes some experiments of Canton's on thin glass bulbs, charged and hermetically sealed and kept under water, showing " that when the glass is cold, though extremely thin, the electric fluid is well retained by it." He then describes an experiment by Lord Charles Cavendish, showing that a thick tube of glass required to be heated to 400° F. to render it permeable to the common current. A portion of a glass tube near the middle of its length was made solid, and wires were thrust into the tube from each end reaching to the solid part. The middle portion of the tube was bent, so that a portion, including the solid part , * Franklin's Works, edited by Sparks (1856), vol. v. p. 367. Note 26: influence of temperature on glass 417 could be placed in an iron pot filled with iron-filings. A thermometer was put into the filings; a lamp was placed under the pot; and the whole was supported upon glass. The wire which entered one end of the tube was electrified by a machine, a cork ball electrometer was hung on the other, and a small wire, reaching to the floor, was tied round the tube between the pot and the electrometer, in order to carry off any electricity that might fun along upon the tube. "Before the heat was applied, when the machine was worked, the cork balls separated at first upon the principle of the Leyden phial. But after the middle part of the tube was heated to 600, the corks continued to separate, though you discharged the electricity by touching the wire, the electrical machine continuing in motion. Upon letting the whole cool, the effect remained till the thermometer was sunk to 400." Experiments on the conductivity of glass at different temperatures have been made by Buff*, Perryf, and Hopkinson J . Hopkinson finds that if B is the specific conductivity divided by the specific inductive capacity and multiplied by 477-, then for glass N°. 2, log B = 1-35 + 0-04150, glass N°. 7, log B = 4-17 + 0-02830, where 6 is the temperature centigrade. Glass N°. 2 is of a deep blue colour; it is composed of silica, soda, and lime. Glass N°. 7 is "optical light flint," density 3-2, composed of silica, potash, and lead; almost colourless, the surface neither "sweats" nor tarnishes in the slightest degree. This glass at ordinary temperatures is sensibly a perfect insulator. The conductivity of glass when heated makes it very difficult to determine its capacity as a dielectric. It appears from the experiments of Hopkinson on glasses of known composition, that the glasses made with soda and lime conduct more, and are also more subject to "electric polarization " and "residual charge " than those made with potash and lead. Both the conductivity and the susceptibility to residual charge increase as the temperature rises, and this makes it very doubtful whether the apparent increase of dielectric capacity, which was observed by Cavendish and also by recent experimenters, is a real increase of the specific inductive capacity, or merely an effect of increased conductivity. The experiments of Messrs Ayrton and Perry § on wax at different tem- peratures would seem to indicate a real increase of dielectric capacity, as well as of conductivity, as the temperature rises up to the melting point. During the process of melting the capacity decreases and at higher temperatures begins to increase again, but the conductivity continues to increase as the temperature rises. * Annalen der Chemie und Pharmacie, xc. (1854), P- 257- t Proc. R. S. 1875, p. 468. } Phil. Trans. 167 (1877), P- 599- § Phil. Mag. August, 1878. c. p. i. 27 41 8 Note 27: dielectric capacities NOTE 27, ART. 376. Electrostatic capacity of different substances. Cavendish Boltzmann Wiillner Gordon Shellac* 4-47 2-95103-73 2-746 Rosin 2-55 Rosin and bees'-wax . . . 3-38 Dephlegmated becs'-wax 3-7 Plain bees'-wax 4 Sulphur SchiJto 3-84 2-88 to 3-21 2-579 Ebonite 2-21102-76 3-15 2-56 2-284 Paraffin 1-81102-47 2-32 1-96 1-994 Black caoutchouc 2-12 vulcanized 2-69 2-497 NOTE 28, ART. 383. Capacity of a Cylindrical Condenser. The rule by which Cavendish computed the charge of a condenser consisting of two cylindrical surfaces having the same axis is given at Art. 313. If R is the external and r the internal radius, and / the length of the cylinders, T 7? -1 V then Cavendish's expression for the "computed charge" is - R-_ -- /. The true expression for the capacity is i / 2 log R - log r when the logarithms are Naperian. We may express log R - log r in the form of the series R - r 2 /R - A3 2 /R - 2 /R - A3 2 /R - n5 , „ U + ~r) + 5 \M + r) + *°" R+~r 3 and we thus find as an approximate value of the capacity r\« f) 4 R - 4 R-r I - 3 \FTf ~ 45 T J' The first term agrees with Cavendish's rule, for the "capacity" is half the "inches of electricity," but the other terms show that Cavendish's rule gives too large a value for the computed charge. * [In Kaye and Laby, Physical and Chemical Constants, 191 1, the value for shellac is given as 3 — 3-7 and for rosin as 1-8 — 2-6. The value for crown glass is given as 5 — 7 and for flint as 7 — 10, both well above shellac, as Cavendish found, but in a different order. Cavendish's results are tabulated in Note 15, supra. It is found by Eguclii, Proc. Phys. Math. Soc. of Japan, 1 920, that a mixture of resin and beeswax, solidified under pressure, exhibits permanent polarization, which is absent in the separate substances.] i Note 28: capacities of cylindrical condensers 419 The following table gives the charge as computed by Cavendish compared with that given by the correct formula. Flint jar cylinder Cavendish 85-9 87-1 True 72-55 73-^Q Observed charge by computed 9-88 8-83 Therm. I. II «.->/ i II-O II-I / j oy 8-37 7-84 9-58 IO"2Q Green cyl. i 2 77'2 76-6 / ^T1 65-92 6l-S4 11-15 11*22 3 40-8 JT- •*4-2O TO-2O NOTE 29, ART. 437. Electrical Fishes. The fishes which are known to possess the power of giving electric shocks belong to two genera of Teleostean Fishes and one of Elasmobranch Fishes, and the position and relations of the electric organs are different in each. In every instance, however, the electric organ may be roughly described as being divided in the first place into parallel prisms or columns by septa, which we may call (with reference to the organ, not the fish) longitudinal septa, and in the second place each column is divided transversely by diaphragms, the structure of which is different in the different families, but in every case the terminations of the nerves lie on that surface of each diaphragm which during the discharge becomes its negative surface. In the large family of the Torpedos the electric organs are formed of a large number of short columns, the columns running from the belly to the back of the fish. The nerves terminate on the ventral surface of each diaphragm, and the electric discharge is from belly to back through the organ, or in other words, the back of the fish becomes positive with respect to the belly. There seems to be but one species of Gymnotus. It is a long eel-like fish. Its electric organs consist of a smaller number of very long columns running from the tail to the head of the fish. The nerves terminate on the posterior surface of the diaphragms, and the electric discharge is from tail to head through the organ, or the head of the fish becomes positive with respect to the tail. There are three species of Malapterurus which are known to be electrical. In these the electric organs run longitudinally. Bilharz, observing that the nerves appear to terminate in an expansion like the head of a nail on the posterior surface of the diaphragms, concluded that the electric discharge must be from tail to head through the organ, as in the Gymnotus. Ranzi* however, and afterwards, independently of him, Du Bois Reymondf found that the discharge * Nuovo Cimento, Tomo II, Dicembre 1856, p. 447, quoted by Du Bois Raymond "Zur Geschichte der Entdeckungen am Zitterwelse," Archiv fur Anatomie u. Physio- logic, &c. Leipzig, 1859, p. 210. f Monatsbericht il. k. Akatl. Berlin, 1858. 27—2 4.20 Note 29: electrical fishes is really from head to tail through the organ, so that the tail becomes positive with respect to the head, and Schultze, who had been led to believe, from a comparison of his own observations on the organs of pseudo-electric fishes with the drawings of Bilharz, that the nerves might pass through the diaphragms and terminate on their anterior surfaces, found, on examining the preparations sent him by Du Bois Reymond, that this was really the case in Malapterurus, so that we may now assert that in every known case the terminations of the nerves are on that side of each diaphragm which during discharge becomes negative. The origin of the nerves which supply the electric organs is different in the three families. In the Torpedos the electric nerves are derived from the posterior division of the brain. Irritation of this lobe produces an electric discharge of the organ, but no muscular contraction. Irritation of other parts of the brain produces muscular contractions, but not electric discharges, unless the disturbance pro- duced affects the electric nerves. In the Gymnotus the electric nerves arise from the whole length of the spinal cord, and in Malapterurus the electric organs are supplied by the 2n<1 and 3rd pair of spinal nerves. The electric nerves are so called because they govern the discharges of the electric organ. No essential difference has been observed between the electric phenomena in these nerves and those in other nerves. They must be classed, with respect to origin as well as function, among the motor nerves. The only difference is that their function is to govern the electric discharge of a peculiar organ, instead of the contraction of a muscle. The experiments of Dr Davy* and those of Matteuccif showed that the discharge of the Torpedo produces all the known phenomena of an electric discharge. Faraday J did the same for the Gymnotus, and Du Bois Reymond § for the Malapterurus. M. Marey[| has recently investigated some of the electrical phenomena of the discharge of the Torpedo. He employed three methods of indicating the discharge, the prepared leg of a frog, which is extremely sensitive to the feeblest current, but has the disadvantage that the time required for the contraction of the muscles, and still more the time required for their relaxation, is many times the period of the recurrence of the electric discharges of the Torpedo, so that the rapidly changing phases of the discharge cannot be distinguished by this method. The second indicator used by Marey was the electromagnetic signal of M. Deprez, which can register 500 electric currents in a second by the motion of a tracing point over the smoked surface of a revolving cylinder. The action * Phil. Trans. 1834. f Comptes Rendus, 1836. J London Medical Gazette, 1838. § Berlin Monatsb. 1858. II Travaux du Laboratoire de M. Marey, in. (1877). Experimental investigations 42 1 of this instrument was sufficiently prompt to register the number of the separate currents of which the "continued discharge" of the Torpedo consists. It was not, however, sufficiently sensitive to trace the curve of the intensity of the current when the strength of the current was less than that required to work the tracing point, and the trace therefore represents only the phases of greatest strength of current in each separate discharge. M. Marey calls each separate discharge of the Torpedo an electric flux. The whole discharge consists of a rapid succession of these fluxes, at the rate of from 60 to 140 per second, gradually decreasing in intensity, but re- maining sensible sometimes for a second or a second and a half. In one of the tracings 120 fluxes may be counted quite distinctly, with a somewhat irregular continuation of feebler fluxes. The electromagnetic signal, however, depending on the attraction of a soft iron armature, is acted on by a force varying nearly as the square of the strength of the current. It is therefore unable to respond to feeble currents, and it does not indicate the direction of the currents, even when improved in certain par- ticulars by M. Marey. The third indicator used by M. Marey was the capillary electrometer of M. Lippmann. In this instrument a capillary glass tube is filled in one part with mercury and in the other with dilute sulphuric acid. The pressure of the mercury is so adjusted that the division between the two liquids appears in the middle of the field of a microscope. The electrodes of the instrument are connected with the two liquids respectively, and when a small electromotive force acts from one electrode to the other, the surface of separation of the two liquids is seen to move in the same direction as the electromotive force, that is to say, the mercury advances if the electromotive force is from the mercury to the acid, and retreats if it is in the opposite direction. This instrument, therefore, is admirably suited for the investigation of small electromotive forces, and the mass of the moving parts is so small that it responds most promptly to every variation of the electromotive force. Its only defect is that its range is limited to the electromotive force required to decompose the acid, and the electromotive force of the Torpedo, as we know, is of far greater intensity than this. M. Marey therefore used a shunt, so as to diminish the force acting on the electrometer to such a degree as to be within the working limits of the instrument. He thus ascertained that the back of the fish is positive with respect to the belly, not only on the whole, but during every phase of each flux, and that it does not sink to zero between the fluxes. The modern researches on the electric fishes would seem to point to the conclusion that the electric organ is not like a battery of Leyden jars in which electricity is stored up ready to be discharged at the will of the animal, but rather like a Voltaic battery, the metals of which are lifted out of the cells containing the electrolyte, but are ready to be dipped into them. 422 Note 29: electrical Jishes There seems to be no electric displacement in the organ till the electric nerve acts on it. The energy of the electric discharge which then takes place is not supplied to the organ by the nerve; the nerve only sets up an action which is carried on by the expenditure of energy previously supplied to the organ by the materials which nourish it. During the discharge certain chemical changes take place in the organ. These changes involve a loss of intrinsic energy, and the chemical products found in the organ after repeated electric discharges are similar to the products found in muscles after they have performed mechanical work. The organ, by repeated discharges, becomes incapable of responding to stimulation, and can only recover its power by the gradual process by which it is nourished. Faraday proposed to try whether sending an artificial current through the Gymnotus would exhaust the organ, if sent in the direction of the natural discharge, or would restore it more rapidly to vigour if sent in the opposite direction. The only experiments on the effect of electricity on electric fishes seem to be those of Dr Davy, who found that an artificial current did not excite the electric organs of the Torpedo, though it had an effect on the muscles, but less than on those of other fishes, and of Du Bois Reymond, who found that Malapterurus was very slightly affected by induction currents passing through the water of his tub, though they were strong enough to stun and even to kill other fishes. When the induction currents were made very strong, the fish swam about till he had placed his body transverse to the lines of discharge, but did not appear to be much annoyed by them*. The most valuable experiments hitherto made are probably those of Dr Carl Sachs, who went out to Venezuela in 1876 for the express purpose of studying the Gymnotus in its native rivers, with all the resources of Du Bois Reymond's methods. Dr Sachs lost his life in an Alpine accident in 1878, and as he did not himself publish his researches, it is to be feared that their results are lost to science. * A somewhat extensive account of the subject is given in a dissertation, De' Pesci elettrici e pseudoelettrici, per Stefano St. Sihleanu (di Bucuresti, Romania), Napoli, 1876. [Much attention has more recently been given to the subject by physiologists. It appears from microscopic observations (cf. Bayliss' I'hysiology, 1917, p. 661) that in Malapterurus the electric organ consists of a large number of parallel plates arranged along the fish, all innervated from a single neurone on each side: it gives a discharge at about 450 volts, lasting about -005 sec. The manipulations of polari- zation and arrangement of cells by which discharges of high tension were obtained by Plant6 from his secondary batteries about thirty years ago may perhaps be regarded as in analogy with the organic activities that go on in mutual correlation in the electric organ of the fish.] Note 30: inequality of opposed condensed charges 423 NOTE 30, ART. 560. Excess of redundant fluid on positive side above deficient fluid on negative side of a coated plate. When two equal disks have the same axis, the first being at potential V and the other connected to the earth, the algebraic sum of the charges of the two disks is just half the charge of the two disks together if they were both raised to potential V. If the two disks are very near each other, the charge of the two together is very little greater than that of one by itself at the same potential. Hence the excess of the redundant fluid above the deficient, when one of the disks is raised to potential V and the other connected with the earth, is very little greater than Tr~laV , where a is the radius. (See Note 4.) NOTE 31, ART. 573. Intensity of the Sensation produced by an Electric Discharge. Cavendish tried this and several other experiments (Arts. 406, 573, 597, 610, 613) to determine in what way the intensity of the sensation of an electric shock is affected by the two quantities on which the physical properties of the discharge depend, namely the quantity of redundant fluid discharged, and the degree of electrification before it is discharged, the resistance of the discharging circuit being supposed constant. He seems to have expected (Art. 597) that the strength of the shock would be "as the quantity of electricity into its velocity," or in modern language, as the product of the quantity into the mean strength of the current of discharge. Since the electromotive force acting on the body of the operator is measured by the product of the strength of the current into the resistance of the body, which we may suppose constant, Cavendish's hypothesis would make the in- tensity of the shock proportional to the work done by the discharge within the body. According to this hypothesis, if a jar charged to a given degree produces a shock of a certain intensity, then a charge equal to n times the charge of this jar, communicated to n2 similar jars, and discharged through the same resistance, would give a shock of equal intensity. By the experiment recorded in Arts. 406 and 573, in which n = 2, it appeared that the shock given by four jars charged with the electricity of two jars, was rather greater than that of a single jar. In the experiment in Art. 610 Cavendish compared the shock of jar I electrified to 2j, with that of B + 2.A electrified to the same degree and com- municated to the whole battery. Here the capacity of B + 2A was equal to 6 times jar i, and that of the whole battery was 154 times jar i, so that 6 times 424 Note 31: measures of sensation the quantity of electricity communicated to 154 jars gave a shock of about the same strength, though as Cavendish remarks, "as there is a good deal of difference between the sensations of the two, it is not easy comparing them." Here 154 is the 2g power of 6, so that the shock seems to depend rather more on the quantity of electricity than on the degree of electrification. This is the only experiment which Cavendish has worked out to a numerical result. By the other experiments recorded in Art. 610, 34^ communicated to 7 rows, gives a shock equal to 22 communicated to one row. This would make the number of jars as the 4-3 power of the charges. By Art. 613 the number of jars would be as the 3-3 power of the charge. Cavendish had not the means of producing a steady current of electricity, such as we now obtain by means of a Voltaic battery, so that he could not discover the most important of the facts now known about the physiological action of the current, namely, that the effects of the current, whether in pro- ducing sensations, or in causing the contraction of muscles, depend far more on the rapidity of the changes in the strength of the current, than on its absolute strength. It is true that a steady current, if of sufficient strength, produces effects of both kinds, but a current so weak that its effect, when steady, is imperceptible, produces strong effects, both of sensation and contraction, at the moments when the circuit is closed and broken. But although this may be considered as established, I am not aware of any researches having been made, from the results of which it would be possible to determine, from the knowledge of the physical character of two electric discharges, which would produce the greater physiological effect. The kind of discharges most convenient for experiments of this kind is that in which the current is a simple exponential function of the time, and of the form _* X" Ce"'' , where x is the strength of'the current at the time /, C its strength at the beginning of the discharge, and r a small time, which we may call the time-modulus. In this case the whole physical nature of the discharge is determined by the values of the two constants C and r. The intensity of the sensation pro- duced by the discharge through our nerves is, therefore, some function of these two constants, and if we had any method of ascertaining the numerical ratio of the intensities of two sensations, we might determine the form of this function by experiments. We can hardly, however, expect much accuracy in the com- parison of sensations, except in the case in which the two sensations are of the same kind, and we have to judge which is the more intense. According to Johannes Miiller, the sensation arising from a single nerve can vary only in one way, so that, of two sensations arising from the same nerve, if one remains constant, while the other is made to increase from a decidedly less to a decidedly greater value, it must, at some intermediate value, be equal in all respects to the first. produced by various kinds of electric discharge 425 In the ordinary mode of taking shocks by passing them through the body from one hand to the other, the sensations arise from disturbances in different nerves, and these being affected in a different ratio by discharges of different kinds, it becomes difficult to determine whether, on the whole, the sensation of one discharge or the other is the more intense. I find that when the hands are immersed in salt water the quality of the sensation depends on the value of T. When T is very small, say o-ooooi second, and C is large enough to produce a shock of easily remembered intensity in the wrists and elbows, there is very little skin sensation, whereas when T is comparatively large, say o-oi second, but still far too small for the duration of discharge to be directly perceived, the skin sensation becomes much more intense, especially in one place where the skin may have been scratched, so that it becomes almost impossible so to con- centrate attention on the sensation of the internal nerves as to determine whether this part of the sensation is more or less intense than in the discharge in which T is small. There are two convenient methods of producing discharges of this type. (i) If a condenser of capacity K is charged to the potential V, and dis- charged through a circuit of total resistance R (including the body of the victim), F C-~, r=KK. K The whole quantity discharged is Q = CT = VK, and if r is the resistance of the body of the victim, the work done by the discharge in the body is (2) If the current through the primary circuit of an induction coil is y, the coefficient of mutual induction of the primary and secondary coils M, that of the secondary circuit on itself L, and the resistance of the secondary circuit R, then for the discharge through the secondary circuit when the primary circuit is broken, - * ~ R ' 2 L R- I first tried the comparison of shocks by means of an induction coil, in which M was about 0-78 and L about 52 earth quadrants, and in which the resistance of the secondary coil was 2710 Ohms. By adding some German silver wire to the primary coil, its resistance was made up to nearly I Ohm, and the primary thus lengthened, another wire of the same resistance, and a variable resistance Q, were made into a circuit. One electrode of the battery was connected to the junction of the two equal resistances, and the other was connected alternately to the two ends of the resistance Q, so that the current through the primary was varied in the ratio of the primary P to P + Q, while the resistance of the battery-circpit remained always the same. When the smaller primary current, 426 Note 31 : measures of sensation y, was interrupted, I took the secondary discharge through my body directly, but when the larger current, y', was interrupted, I made the secondary dis- charge pass through a capillary tube filled with salt solution as well as my body. The resistance between rny hands when both were immersed in salt water was 1245 Ohms, making with the secondary coil a resistance of 3955 m the secondary circuit, so that the time-modulus of the discharge was T = 1-3 x io~3 seconds. The resistance of the first capillary tube was 370,000, so that when it was introduced T — 1-4 x io~5. By a rough estimate of the comparative intensity of the shocks I supposed them to be of equal intensity when y' = 8-^y, and therefore if we suppose that two shocks remain of equal intensity when C varies as TP, p = 0-468. By another experiment in which a tube was used whose resistance was 450,000, p = 0-534. When the shocks at breaking contact were nearly equal, that at making contact was very much more intense with the small primary current and small secondary resistance than with the large primary current and large secondary resistance. I then compared the discharges from two condensers of i and o-i micro- farads capacity respectively, charging them with a battery of 25 Leclanche cells, the electromotive force of which was about 36 Ohms. The resistance of the discharging circuit for the microfarad was 11,200 Ohms, including my body, so that r = 1-12 x io~2 seconds. The resistance of the discharging circuit of the tenth of a microfarad was 3600, so that T' = 3-6 x IQ-*. The values of C were inversely as the resistances, so that if the two shocks were, as I estimated them, nearly equal, the value of p would be 0-670. This experiment was much more satisfactory and more easily managed than that with the induction coil, and I thought it desirable to apply the same method to the comparison of the contractions of a muscle when its nerve was acted on by the discharge. I therefore availed myself of the kindness of Mr Dew-Smith, who prepared for me the sciatic nerve and gastrocnemius muscle of a frog, and attached the preparation to his myograph. The discharge was conducted through about 0-4 cm. of the nerve by means of Du Bois Reymond's unpolarizable electrodes, the resistance of the electrodes and nerve being 35,000 Ohms. When the electrodes were in contact their resistance was 23,000, leaving about 12,000 as the resistance of the nerve itself. I used two condensers, one o-i microfarad, and the other an air-condenser of 270 centimetres capacity in electrostatic measure, or about 3 x io~4 micro- farads. The first was charged by one cell and the second by 25. The resistances were arranged so that the contractions produced in the muscle we,re much less produced by various kinds of electric discharge 427 than a third of a maximum contraction. The discharges were made alternately every 15 seconds, and when the resistances were 35,000 and 140,000 respectively, the alternate contractions as recorded on the myograph were as follows: Small condenser Large condenser 144 146 147 148 147 147 146 146 147 145 Here the time-modulus was 1-05 x io~B seconds for the small condenser and 1-4 x io~2 for the large one, and the values of C were as I to 100, so that p = -640. If we suppose that Cavendish took the shocks through pieces of metal held in his hands, the resistance of the circuit would depend on the state of his skin. He occasionally used a piece of apparatus, which he nowhere describes, but which he names in three places* a shock-melter. From Art. 585 it would appear that it was filled with salt water, even when fresh water was the subject of the experiment, and from Art. 637 Cavendish seems to have considered it his last resource as a method of receiving shocks. I therefore think that it must have been an apparatus by which his hands were well wetted with salt water, so that the resistance of his body would be between 1000 and 2000 Ohms. The capacity of his battery of 49 jars was 321,000 glob, inc., which comes to rather less than half a microfarad. The discharges of this through 2000 Ohms would have a time-modulus of about one-thousandth of a second. The following table gives the different results obtained by Cavendish and by myself, with the time-modulus of the discharges compared. The quantity p is such that the ratio of the initial strength of the two discharges is inversely as the p power of the ratio of the time-moduli when the shocks are equal in intensity, or Q _ ^ 'c, W the frozen part exhibiting, in other cases, a tendency to approach to this standard. Mr Keir had found that sulphuric acid, of the specific gravity 1-78, froze at 46°, and that it had another maximum when it was very highly concentrated*. 15. On the Conversion of a Mixture of Dephlogisticated and Phlogisticated Air into Nitric Acid, by the Electric Shock. (Phil. Trans. 1788, p. 261.) Some difficulties having occurred to the Continental chemists in the repetition of this experiment, it was exhibited with perfect success, by Mr Gilpin, to a number of witnesses. This was an instance of condescension, which could scarcely have been expected from the complete conviction, which the author of the discovery must have felt, of his own accuracy, and of the necessity of the establishment of his discovery, when time should have been afforded for its examination. 16. On the Height of the Luminous Arch, which was seen on Feb. 23, 1784. (Phil. Trans. 1790, p. 101.) Mr Cavendish conjectures that the appearance of such arches depends on a diffused light, resembling the aurora borealis, spread into a flattened space, contained between two planes nearly vertical, and only visible in the direction of its breadth : so that they are never seen at places far remote from the direction of the surface; and hence it is difficult to procure observations sufficiently accurate for determining their height, upon so short a base: but in the present instance there is reason to believe that the height must have been between 52 and 71 miles. 17. On the Civil Year of the Hindoos, and its Divisions, with an Account of three Almanacs belonging to Charles Wilkins, Esq. (Phil. Trans. 1792, p. 383.) The subject of this paper is more intricate than generally interesting; but it may serve as a specimen of the diligence which the author employed in the investigation of every point more or less immediately connected with his favourite objects. The month of the Hindoos is lunar in its duration, but solar in its commencement; and its periods are extremely complicated, and often different for different geographical situations: the day is divided and sub- divided sexagesimally. The date of the year, in the epoch of the Kalee Yug, expresses the ordinal number of years elapsed, as it is usual with our astronomers to reckon their days : so that the year 100 would be the beginning of the second century, and not the tooth year, or the end of the first century, as in the European calendar: in the same manner as, in astronomical language, 1817 December 3id. i8h. means six o'clock in the morning of the ist of January 1818. * [Compare with these two papers the modern investigations of coexistent chemical phases, and their applications to metallurgy and other sciences.] by Dr Thomas Young 443 18. Experiments to determine the Density of the Earth. (Phil. Trans. 1798, p. 469.) The apparatus, with which this highly important investigation was conducted, had been invented and constructed many years before by the Reverend John Michell, who did not live to perform the experiments for which he intended it. Mr Cavendish, however, by the accuracy and perseverance with which he carried on a course of observations of so delicate a nature, as well as by the skill and judgment with which he obviated the many unforeseen diffi- culties that occurred in its progress, and determined the corrections of various kinds which it was necessary to apply to the results, has deserved no less gratitude from the cultivators of astronomy and geography, than if the idea had originally been his own. The method employed was to suspend, by a vertical wire, a horizontal bar, having a leaden ball at each end; to determine the magni- tude of the force of torsion by the time occupied in the lateral vibrations of the bar; and to measure the extent of the change produced in its situation by the attraction of two large masses of lead, placed on opposite sides of the case containing the apparatus, so that this attraction might be compared with the weight of the balls, or, in other words, with the attraction of the earth. In this manner the mean density of the earth was found to be 5^ times as great as that of water; and although this is considerably more than had been inferred from Dr Maskelyne's observations on the attraction of Schehallion, yet the experiments agree so well with each other, that we can scarcely suppose any material error to have affected them. Mr MichelTs apparatus resembled that which M. Coulomb had employed in his experiments on magnetism, but he appears to have invented it before the publication of M. Coulomb's Memoirs. 19. On an Improved Method of Dividing Astronomical Instruments. (Phil. Trans. 1809, p. 221.) The merits of this improvement have not been very highly appreciated by those who are in the habit of executing the divisions of circular arcs. It consists in a mode of employing a microscope, with its cross wires, as a substitute for one of the points of a beam compass, while another point draws a faint line on the face of the instrument in the usual manner. The Duke de Chaulnes had before used microscopical sights for dividing circles ; but his method more nearly resembled that which has been brought forwards in an improved form by Captain Kater; and Mr Cavendish, by using a single micro- scope only, seems to have sacrificed some advantages which the other methods appear to possess : but none of them has been very fairly tried ; and our artists have hitherto continued to adhere to the modes which they had previously adopted, and which it would perhaps have been difficult for them to abandon, even if they had been convinced of the advantages to be gained by some partial improvements. Such were the diversified labours of a philosopher, who possessed a clearness of comprehension and an acuteness of reasoning which had been the lot of very few of his predecessors since the days of Newton*. Maclaurin and Waring, perhaps also Stirling and Landen, were incomparably greater mathematicians; * [As regards Cavendish's dynamical manuscripts, see the end of the second volume of this edition.] 444 1-tfe °f Cavendish but none of them attempted to employ their powers of investigation in the pur- suit of physical discovery: Euler and Lagrange, on the Continent, had carried the improvements of analytical reasoning to an unparalleled extent, and they both, as well as Daniel Bernoulli and d'Alembert, applied these powers with marked success to the solution of a great variety of problems in mechanics and in astronomy; but they made no experimental discoveries of importance: and the splendid career of chemical investigation, which has since been pursued with a degree of success so unprecedented in history, may be said to have been first laid open to mankind by the labours of Mr Cavendish ; although the further discoveries of Priestley, Scheele, and Lavoisier, soon furnished, in rapid suc- cession, a superstructure commensurate to the extent of the foundations so happily laid. "Whatever the sciences revealed to Mr Cavendish," says Cuvier, "appeared always to exhibit something of the sublime and the marvellous; he weighed the earth; he rendered the air navigable; he deprived water of the quality of an element"; and he denied to fire the character of a substance. "The clearness of the evidence on which he established his discoveries, so new and so unexpected as they were, is still more astonishing than the facts them- selves which he detected; and the works, in which he has made them public, are so many master-pieces of sagacity and of methodical reasoning ; each perfect as a whole and in its parts, and leaving nothing for any other hand to correct, but rising in splendour with each successive year that passes over them, and promising to carry down his name to a posterity far more remote than his rank and connections could ever have enabled him to attain without them." In his manners Mr Cavendish had the appearance of a quickness and sensibility almost morbid, united to a slight hesitation in his speech, which seems to have depended more on the constitution of his mind than on any deficiency of his organic powers, and to an air of timidity and reserve, which sometimes afforded a contrast, almost ludicrous, to the sentiments of profound respect which were professed by those with whom he conversed. It is not impossible that he may have been indebted to his love of severe study, not only for the decided superiority of his faculties to those of the generality of man- kind, but even for his exemption from absolute eccentricity of character. His person was tall, and rather thin: his dress was singularly uniform, although sometimes a little neglected. His pursuits were seldom interrupted by in- disposition; but he suffered occasionally from calculous complaints. His retired habits of life, and his disregard of popular opinion, appear to have lessened the notoriety which might otherwise have attached to his multiplied successes in science; but his merits were more generally understood on the Continent than in this country; although it was not till he had passed the age of seventy, that he was made one of the eight Foreign Associates of the Institute of France. Mr Cavendish was no less remarkable in the latter part of his life, for the immense accumulation of his pecuniary property, than for his intellectual and scientific treasures. His father died in 1783, being at that time eighty years old, and the senior member of the Royal Society: but he is said to have suc- 'ceeded at an earlier period to a considerable inheritance left him by one of his by Dr Thomas Young 445 uncles. He principally resided at Clapham Common ; but his library was latterly at his house in Bedford Square ; and his books were at the command of all men of letters, either personally known to him, or recommended by his friends: indeed the whole arrangement was so impartially methodical, that he never took down a book for his own use, without entering it in the loan book; and after the death of a German gentleman, who had been his librarian, he appointed a day on which he attended in person every week for the accommodation of the few, who thought themselves justified in applying to him for such books as they wished to consult. He was constantly present at the meetings of the Royal Society, as well as at the conversations held at the house of the President ; and he dined every Thursday with the club composed of its members. He had little intercourse with general society, or even with his own family, and saw only once a year the person whom he had made his principal heir. He is said to have assisted several young men, whose talents recommended them to his notice, in obtaining establishments in life; but in his later years, such instances were certainly very rare. His tastes and his pleasures do not seem to have been in unison with those which are best adapted to the generality of mankind ; and amidst the abundance of all the means of acquiring every earthly enjoy- ment, he must have wanted that sympathy, which alone is capable of redoubling our delights, by the consciousness that we share them in common with a multitude of our friends, and of enhancing the beauties of all the bright prospects that surround us, when they are still more highly embellished by reflection "from looks that we love." He could have had no limitation either of comfort or of luxury to stimulate him to exertion; even his riches must have deprived him of the gratification of believing, that each new triumph in science might promote the attainment of some great object in life that he earnestly desired; a gratification generally indeed illusory, but which does not cease to beguile us till we become callous as well to the pleasures as to the sorrows of existence. But in the midst of this "painful pre-eminence," he must still have been capable of extending his sensibility over a still wider field of time and space, and of looking forwards to the approbation of the wise and the good of all countries and of all ages: and he must have enjoyed the highest and purest of all intel- lectual pleasures, arising from the consciousness of his own excellence, and from the certainty that, sooner or later, all mankind must acknowledge his claim to their profoundest respect and highest veneration. "It was probably either the reserve of his manners," says Cuvier, "or the modest tone of his writings, that procured him the uncommon distinction of never having his repose disturbed either by jealousy or by criticism. Like his great countryman Newton, whom he resembled in so many other respects, he died full of years and honours, beloved even by his rivals, respected by the age which he had enlightened, celebrated throughout the scientific world, and exhibiting to mankind a perfect model of what a man of science ought to be, and a splendid example of that success, which is so eagerly sought, but so seldom obtained." The last words that he uttered were characteristic of his unalterable love of method and subordination: he had ordered his servant to leave him, and not to return till a certain hour, intending to pass his latest moments in 446 Life of Cavendish the tranquillity of perfect solitude: but the servant's impatience to watch his master diligently having induced him to infringe the order, he was severely reproved for his indiscretion, and took care not to repeat the offence until the scene was finally closed. Mr Cavendish died on the 24th of February, 1810; and was buried in the family vault at Derby. He left a property in the funds of about £700,000, which he divided into six equal parts, giving two to Lord George Cavendish, the son of his first cousin, one to each of his sons, and one to the Earl of^Besborough, whose mother was also his first cousin. Some other personal property devolved to Lord George as residuary legatee; and a landed estate of £6,000 a year descended to his only brother, Mr Frederic Cavendish, of Market Street, Herts, a single man, and of habits of life so peculiarly retired, that any further increase of income would have been still more useless to him than it had been to the testator. Much as Mr Cavendish effected for the promotion of physical science throughout his life, it has not been unusual, even for his warmest admirers, to express some regret that he did not attempt to do still more after his death, by the appropriation of a small share of his immense and neglected wealth, to the perpetual encouragement of those objects, which he had himself pursued with so much ardour. But however we might be disposed to lament such an omission, we have surely no reason to complain of his determination to follow more nearly the ordinary course of distribution of his property, among those whose relation- ship would have given them a legal claim to the succession, if he had not con- cerned himself in directing it. We may observe on many other occasions, that the most successful cultivators of science are not always the most strenuous promoters of it in others; as we often see the most ignorant persons, having been rendered sensible by experience of their own deficiencies, somewhat disposed to overrate the value of education, and to bestow more on the improve- ment of their children than men of profounder learning, who may possibly have felt the insufficiency of their own accomplishments for insuring success in the world. But even if Mr Cavendish had been inclined to devote a large share of his property to the establishment of fellowships or professorships, for the incitement of men of talents to a more complete devotion of their lives to the pursuit of science, it is very doubtful whether he could have entertained a reasonable hope of benefiting his country by such an institution: for the highest motives that stimulate men to exertion are not those which are immediately connected with their pecuniary interests: the senators and the statesmen of Great Britain are only paid in glory; and where we seek to obtain the co- operation of the best educated and the most enlightened individuals in any pursuit or profession, we must hold out as incentives the possession of high celebrity and public respect; assured that they will be incomparably more effectual than any mercenary considerations, which are generally found to determine a crowd of commercial speculators to enter into competition for the proposed rewards, and to abandon all further concern with the objects intended to be pursued, as soon as their avarice is gratified. To raise the rank of science in civil life is therefore most essentially to promote its progress : and when we compare the state, not only of the scientific associations, but also of the learned by Dr Thomas Young 447 professions in this country and among our neighbours, we shall feel little reason to regret the total want of pecuniary patronage that is remarkable in Great Britain, with respect to every independent department of letters, while it is so amply compensated by the greater degree of credit and respectability attached to the possession of successful talent. It must not however be denied, that even in this point of view there might be some improvement in the public spirit of the country: Mr Cavendish was indeed neither fond of giving nor of receiving praise ; and he was little disposed to enliven the intervals of his serious studies by the promotion of social or convivial cheerfulness: but it would at all times be very easy for an individual, possessed of high rank and ample fortune, of correct taste and elegant manners, to confer so much dignity on science and literature by showing personal testimonies of respect to acknowledged merit, as greatly to excite the laborious student to the unremitting exertions of patient application, and to rouse the man of brilliant talent to the noblest flights of genius. [ 449 ] INDEX TO CAVENDISH MANUSCRIPTS The references are to the Articles. [See also Table of Contents] A, coated plate of glass so called, "First got," 589, 592; Nairne's, 314, 593 A, Double, 333, 451, 455, 461, 478, 483, 487, 489, 491, 508, 509, 533, note 35 Absorption, electric, 523, note 15 Accuracy of measurements, 261 Adjustment of charges of coated plates, 316 /Epinus (Franz Ulrich Theodor, b. 1724, d. 1802), i, 134, 340, 549 -Epinus' experiment, 134, 340, 549 Air between plates, not charged, 344, 345, 511, 516; communication of electricity to, 118-125, 208, note 9; electric pro- perties of, 99; electrified, 117, 256; molecular constitution of, 97, and notes 6 and 18; electric phenomena illus- trated by means of, 206 ; dielectric plate of, 134, 34°. 457. 517. 560 Apparatus for trying charges, 240, 295 Assistant, 242, 560 Atmospheres, electric, 195—198 Attraction, 106-117, J97> 2O2- 2I°. n°te 8; not caused by Torpedo, 408 B, coated plate, 593 B, Double, 455-457, 478, 483, 489 Baking varnished plates, 496 Barometer tubes as Leyden vials, 636 Basket for Torpedo, 615 Basket salt, 628 Battery of Florence flasks. 521; of 49 jars, 411, 432, 581; Nairne's, 585, 616 Beccaria, Giacomo Battista (1716—1781), 136 Bees'-wax as dielectric, 336, 371, 376 Breaking of electricity through plates, 520 Calc. S. S. A., 626, 694 and note 34 Calibration of tubes, 382, 383, 632-635 Calipers, 459 Canal for electric fluid, 40, 68, 69; bent, 48, 49, 84—95 and note 3 Canton, John, F.R.S. (1718—1772), 117, 205 Cement, 303, 484, 497 Chain battery, 433, 605, 613 Charge defined, 237; does not depend on material, 68; of similar bodies as dia- meters, 71; of thin plate independent of thickness, 73; of condensers not affected by other bodies, 317, 443, 555; of coated plates greater than by theory, 332; 'intended,' 316; 'computed,' 311, 326, 377, 458; 'real,' 313, 377; with strong electrification, 356, 357, 451, 539; with weak, 358, 463, 539; with negative, 463; effect of temperature, 366; measurements of, see Tables; of battery, 412; divided, 288 Charging jar, 223, 225 Circles, charges on, 273 Circuit, divided, 397, 417 Coated plates, 300, 314, 441; theory of, 74, 1 60, 169; lists of, see Tables Coatings, electricity does not reside in, 133 Communication, 100, 219; of charge to bat- tery, 414, 618 Comparison of charges, 236 Compound plate, 379—381, 560, 677-679 Computed charge, 311, 312 Condensation distinguished from compression, 200 Conduction by hot glass, 369 Conductivity, 469, 491 ; of straws. 565 Conductor defined, 98 Cone, attraction on particle at vertex, 7 Conical point, escape of electricity from, 124 and note 9 Contact, 306; never realized, 196 note; of brass and glass, 541, 558 Copper wire, resistance of, 636—646 Cork balls, 116, 117, 441, 451 Crown glass, 301, 330, 378, 411, 430, 585, 595 Cylinder, 54, 148-151; charge of, 281, 285- 287 and note 12; two, 152 and note 13; glass coated, 382, 454, 479; large tin, 358, 539 and note 25 D, coated plate, 483, 487 Deficient fluid, 67, note DEFINITIONS: Canal, 40 Charge, 237 Communication, 100 Compression, 199 Computed charge, 311 Condensation, 200 Conductor, 98 Deficient fluid, 67, note Electrification, 102, 201 Immoveable fluid, 12 Inches of electricity, circular, 458, 648, globular, 654, square, 648, 654 Incompressible fluid, 69 Insulation, 100 Non-conductors, 98 Observed charge, 325 Overcharge, 6, 201 Real charge, 313 Redundant fluid, 13 Saturated body, 6 Undercharge, 6 Degrees of electrification, 329, 356; of electrometer, 560, note Dephlegmated wax, 371, 375, 518 Discharge, divided, 397, 417, 576, 597, 613 Distance to which electricity spreads, 309, 323, 328 45° Index to Cavendish Manuscripts Dividing machine, 341, 459, 517, 591 Divisions of trial plate, 297 Double plates, 333 Earth connexion, 258, 271 Electricity an elastic fluid, 4, 195; limit to density, 20; diffused through bodies not electrified, 216; inches of, 647, 648 Electrification, degree of, 102, 201 and note 7 Electrodes, larpe, 258, 271 Electrometer : Cavendish's discharging, 402, 405, 427, 43°. 434; gauge (paper cylinders), 224, 248, 295, 495, 511, 524, 542, 559; new wood, 525, 563 Divisions of, 560, note Henly's, 559, 568, 570, 571, 580; on rod, 5»9 Lane's, 263, 329, 559, 569, 570, 571, 580, 589, 603, 604 Paper cylinders, 486 Pith ball, 581 Straw, 249, 404, 559, 570, 571, 581; with variable weights, 387; corks, 441, 451, 566 Testing, 244, 296, 358, 359 English plate glass, 301, 496 Equivalent thickness of compound plates, 379 Error, greater with coated plates than with simple conductors, 299 ; probable of esti- mation of capacity, 250, 261; in Exp. I, 234; due to unequal charging, 250 Excess of redundant fluid in coated plates, 560 and note 30 Experiment I, 218, 233, 291, 512, 562 and note 19 II, 235, 292, 561 III, 265, 467 IV, 269, 293, 471, 480, 481 and note 20 V, 273, 447", 448, 452, 454, 472, 473, 474, 475, 681 and note 21 VI, 279, 453, 476, 477, 683 VII, 281, 448, 478, 682 and note 13 VIII, 288, 542 and note 23 f. alk., 627, 694 Floor, effect of, 335 Florence flask, 521; battery, 521 Fluid, electric, 195, 216, note i ; real, 91 ; incompressible, 69, 94, 236, 273. 276, 278, 294, 348 and note 3 Force, near an electrified surface, 154; in- versely as square of distance, 232, 512, ' 5J3. 5°2 and note 17 Fore and back room, 469 Frame placed below circles, 274 Frames, 221 Franklin, Benjamin, F.R.S. (1706-1790), 350 note, 363 Fringe of dirt on coated plates, 308, 326, 538 Garden, copper wire stretched round ,643 Gauge electrometer, 224, 248 General conclusions, 291 Gilt straws, 249, 394, 567 Glass, different electric qualities of, 301, 322 Glass house, 378 Glauber's salt, 626, 694 Globe, charge of compared with that of circle, 237, 282, 445, 455, 450, 654, 681, 687, note 35 Globe, electrified, 20-27, 28°; capacity of, 281, 282; compared with double plate, 333, 334 Globe, charge of the terrestrial, 214 Globe of electrical machine, 248, 495, 563, 568, 569 Globe charged within hemispheres, 218, 512, 562, note 19 Globes, coated, 523, 542, 559, 563 Gradual spreading of electricity, 302 Guide for the eye, -249, 525, 571 Gum lac, 371, 374, 376 Gymnotus, 437, 601 Hamilton, Dr, Prof, of Philosophy, Dublin (Priestley, p. 429), 126 Heat, effect on charge of glass, &c., 366, 368, 548, 549, 556, 680, note 26 Heat produced by current, 212 Height and size of room, 335 Hemispheres, hollow, 219 Henly (William, F.K.S., d. 1779, linen draper in London), his electrometer, 559, 5"8, 569, 580 Hissing noise before spark, 213 Hot glass a conductor, 369, note 26; com- pared with cold, 366, 368 Hunter (John, F.R.S. , b. 1728, d. 1793), 436, 601, 614 Hygrometer, corks, 459; Smeaton's, 468; common, 468 Hypothesis, electric, 3, 202 Immoveable fluid, 12, 351 Inches of electricity, 458, 648, 654 Incompressible fluid, 40, 236, 273, 276, 278, 294, 348 and note 3 Increase of charge of globe due to induction, 339, °52 and note 24 Induction, 44-47, 175-194, 202 sq., 275, 277, 287, 288, 334, 335; calculation of, 338. See Specific Instantaneous spreading of electricity, 307, 310-323, 326 Insulation, 100 Iron, conductivity of, 398, 576, 687, note 32 Jar, 223; capacity of jars, 573, 581 Kinnerslev (Ebenezer, Physician in Phila- delphia, b. 1712), 126, 136, 213; see new experiments of electricity, Phil. Trans., 1763, 1773 Knob for discharging, 511, 572 Lac, 371, 374, 376, 518, 520 Lac solution, 494 Lane, Timothy, F.R.S. (b. 1734, d. 1804), 136, 213, 601 Lane's electrometer, 263, 329, 540, 544, 559, 569, 57°. 571, 58° Law of electric force from Exp. I, 291, note 19 Leakage, electric, 260, 264, 393 Leather torpedo, 608 Leyden vial, 128, 206, 313, 363, 389 Light, Newton's fits, 354 Index to Cavendish Manuscripts Light round the edge of coating, 307, 326, 532; brightest at first charging, 310 Linen thread, 244 Lines of discharge of torpedo, 400 Loops of chain battery, 43^, 605 Machine, electric, 242 Machine for trying coated plates, 295, 337, 340, 366, 495 ; new for measuring thick- ness, 517 .Magazine of electricity, 207, 521, 565 Matter, electric fluid excluded, 4 Maximum density of electric fluid, 20 and note i Measurements of apparatus, 219, 255, 273, 275, 466, 472 Mechanism for Exp. I, 222 Mercury, 366 Metals, conducting power, 397, 398 Method of the work, 2 Method of trying charges, 241, note 17 Michell, Rev. John, F.R.S. (d. 1793), 354 Mineral water warehouse, 415 Moist wood, 392 Moment, statical, 388 Moveable electricity in glass, 350 Moveable fluid, 12, 350 Nairne, Edward, F.R.S. (d. 1806); Mr N., 601; plates from, 482 (315); jar, 568; electric machine, 559, 568; his own large one, 580; his manner of lacquer- ing, 496; his batteries, 585, 616 Needle discharger, 572 Negative electrification, 463 Newton, 18, 19, 97 Newton's fits, 354 Nuremberg glass. 301, 376, 497 Oblong, charge of, 284, 479; coatings, 320 Oil of vitriol, 626, 694 Overcharge, 6 p- ratio of charge spread uniformly on disk to that collected in circumference, 140; estimated value by experiment 276 281, 289 Penetration of electric fluid into glass 132 -169-174, 332, 339, 349, 355, 363 Pennsylvania, Phil. Soc. of, 437 Pith ball electrometer, 220, 240, 244, 358, 359 Plate of air, 134, 340; concave, 155 /circular, 55-65, 140; thin, 73 Plates, coated, lists of, 315, 324, 325, 370; theory of, 129; separated circular, 74] 82, 141-144 Points, discharge of electricity by, 123, note 9 Positive electrification, 100, 101 ; defined to be that of glass, 217; gives same pro- portion of charges as negative, 364 Potential, 199 (note) Priestley (Joseph, F.R.S., LL.D. Edin., b. 1733, d. 1804), 125, 126, 213, 354, 408, 60 1 Prime conductor, 241, 295, 359, 539 Prop, ix, 292, xvin, 269, xix, 140, xxn, cor. 5, 140, xxiv, 144, 150, xxix, 282, xxx, 289, xxxi, 285, xxxiv, 311, xxxv, 351, xxxvi, 365 Pulleys, 295 45 Quad, nitre, 626, 696 Rain water, 524 Real charge, 313 Real fluid, 91, 94 Reciprocity of induction, 334 Reduced charge, 270, 272 Redundant fluid, i ^ Reel, 636, 644 Repulsion, 106; of balls as square of re- dundant fluid, 386, 525, 563 Resistance, electric, varies as length of con- ductor, 131; what power of velocity 574. 575, 629, 686; effect of heat on, 619, 620, 690 Richard, his attendant, 511, 565 Ronayne, Thomas, 601 Rosin, 336, 371, 461, 464, 488 Rosin varnish, 497; experimental, 514, 520 548) plates, 518, 555, 560, 594 Roughness dissipates electricity 387 Rows of battery, 581 Rules for trial plates, 592; for strength of salt water, 588; for measuring charge of battery, 412, 441, 582 Sal Amm., 626, 694 Sal Sylvii, 626, 694 Salt water, resistance of, 398, note 33 Salted threads, 259; straws 394 zftc Sand, wet, 608 " Saturated solution s.s., 524, 617 Saturation, electric, 6 Scale of electrometer, 249, 560, 571 Sea water, 524 Sealing-wax, 219, 340, 511, 542 Sensitiveness of electrometer increases with charge, 246 Shock, 207; increased by passing through copper wire, 639 ; by points and knobs compared, 572 Shock melter, 586, 622 Shock of torpedo, 397, 436; intensity, law of, 573. 607, 610, note 31 Silk strings, 241, 266, 295, 358, 447, 45o, 472, Similar bodies, charge of, 66, 72 Sliding coated plate, 488 Slit coatings, 321 Sound, before spark, 139 ; resistance tried by 637. 645 Spark, electric, 135-139, 212; none from torpedo, 401 ; length does not depend on number of jars, 402, 604, note 10 Specific gravity of salt water, 587, 588 Specific inductive capacity, 332 339 notes 15, 27 Spherical shell, force inside, 18, 19 Spirit of salt, 627, 694 Spirit of wine, 524, 631 Spreading of electricity, 299-367, 484, 485, 512; gradual, 494-500 Springing wire, 296 Square plate, charge of, 282, 283, 479 and note 22 ; plates of various substances, 269 Steam, cause of explosion by lightning, 137 Stool, electric, 420, 612 Strata, conducting, in glass, 351, 354 Strength of electrification, 355; effect on capacity, 356, 451, 463, 539 452 Index to Cavendish Manuscripts System of coated plates, 316 Tables Coated plates, 315, 324, 325, 370, 442, 462, 482, 500, 592, 593, 662, 663, 671 Cylinders, 383, 503, 596 Electrometers, 568, 570 Exp. Ill, 267; Exp. IV, 269, 270 Exp. V, 274, 275, 454, 473, 649, 681 Exp. VI, 279, 449; Exp. VII, 281, 682 Hot glass, 368 Jars, 573 Plates of air, 343, 519, 670 Plates of wax, &c., 371 Sliding plates, 589 Solutions of salt, &c., 689, 694, 695, 696 Specific gravity, 595 Trial plates, 465 Tubes, 575, 632, 633, 636 Thermometer tube, 383, 562 Thickness of plates, effect on charge, 269, 272 ; of coated plates, 314; of air plates, 341; measurement, 517, 594, 595 Three parallel plates, 288 Tinfoil, 222; discharger, 426 Torpedo, ist wooden, 409, 415, 596; 2nd leather, 416, 600, 608, 611, 612, 615; in basket, 421 ; in sand, 422 ; in net, 424. See note 29 Touching, to compare charges, 413, 441, 582, 583 Trial plate, theory of, 153 and note 17; list of, 590; description of, 238, 239, 296, 297, 298, 454, 457, 465, 592; charge as square root of surface, 247, 251, 284; sliding wire, 447; sliding cylinder, 547, 567 Trough, torpedo, 410, 587 Tubes, measures of, 632-635 Undercharge, 6 Usual degree of electrification, length of spark ,i>j inch, 263, 329, 359, 520; why so weak, 264 Vacuum, 99, 212, 213 Varnish, 304, 494 Vermilion, 494, 497 Vessel, conducting, 51-53 Vial, Leyden, 240 Vial, third made, 441 Vitriol, oil of, 626, 696 Walsh (John, F.R.S., M.P., d. 1795), 395, 396, 401, 415, 421, 424, 430 Wasting of electricity, 393, 394, 486, 487 Water, resistance of, 398; distilled, 617, 621, 688; rain, 617; purged of air, 624, 692; impregnated with fixed air, 625, 693; pump, 684; sea, 524, 684 Wax, 387 Waxed glass, 255, 271, 295, 447, 450, 476, 54'. 563 Weather, effect of on coated plates, 304 Weight of electric fluid, 5 White glass, 301, 460 Wilcke (Johann Karl, b. 1732, d. 1796), 134 Williamson, Hugh, M.D., 437 Wilson (Benjamin, F.K.S., b. 1721, d. 1788), 125 Wind, electric, 125 Wire, 219, 240; charge of, 279, 479, 683; trials of, 447, 448; connecting, allow- ance for, 337; in straw electrometer, 387. 388 Wires compared with canals of incompress- ible fluid, 94, 278 and note 3 Woods, conductance of soaked, 561, 588, 609 "Work," MS. so called, 349 End of The Scientific Papers, Volume I CAMBRIDGE: PRINTED BY j. B. PEACE, M.A., AT THE UNIVERSITY PRESS 0 BINDING ps^T. JUL23 19731 Q 113 C38 v.l Physical & Applied Sci. Cavendish, Henry Scientific papers