wi ia? Vip ge ees COs os 4 ee ee ee ere Pyat ey eyah he OE eee SUEY hat doe t ’ ery g hie “EA ge Verses yada de dae py peed ao Seabed AAR a AUR i Hvd ve AHA a) ys Mets WA bay yes ees tat i eR ICE) rey aoe CA ee | vpawe ws Fors My 4 FUG EN rie Pe) Irate Lobe aera Va beth ieded badd bad gba eta choad bia. a4 ‘ Vibes ’ ‘ in Vda wee DRA OCCT RO ORC CR a A 4 area We) wh eh SOR EKER In Hem \ py Hs) Ay 4nF Whi bay ded bad a eee da wel ee ONT rt aL vw 4 AO ‘ a uy ae f a ae Ve lacite a4 WR i ae) a yey MY EA va ree] ae oe yews » ‘ ne Pag AAW hh ya ah se wari vate have ue YAN ms ge BAAS ith Weert *. we ’ 3 PN Rae aunty ‘ \ Py ih? ) HEN vA Ryda? ae POR UU ORES RIE FE Syn te dicts Mua yet aah Semele ts ae fat o A ashes suite ni ME sy teG - Be Leas * pat nf oe ah ia Shen . Ary vena Ny - AR Mea Read fi} Hit Bra oo 1) a ( ne Ss ies ‘ See Big ’ it aes bi eit sve ty sented ete, is tet “ ‘ yy a ie Nia Ri AMA te ‘ a , gow! THE SCIENTIFIC PROCEEDINGS OF THE ROYAL DUBLIN SOCIETY. defy Series. VOLUME V. DUBLIN: PUBLISHED BY THE ROYAL DUBLIN SOCIETY. -RINTED AT THE UNIVERSITY PRESS, BY PONSONBY & WELDRICK. 1886-1887. = Tux Society desires it to be understood that they are not answer- able for any opinion, representation of facts, or train of reasoning, that may appear in this Volume of their Proceedings. The Authors of the several Memoirs are alone responsible for their contents. SOb,4T ly TO VOLUME FIVE, WITH REFERENCES TO THE SEVERAL ARTICLES CONTRIBUTED BY EACH. Barzy, Wituum H., F.L.S. PAGE. On a New Species of Pentremite, from Carboniferous Lime- stone, Co. Dublin; and Remarks upon Codaster trilobatus (M‘Coy), from Carboniferous Limestone, Co. Kilkenny (Plates), ees, en. Sse : : : é Seow Batu, V., M.A., F.R.S. Zine and Zine Ores, their Mode of Occurrence, Metallurgy, and History in India; with a Glossary of Oriental and other Titles used for Zine, its Ores and Alloys, F 6 BMA _ On the Existing Records as to the Discovery of a Diamond in Ireland in the year 1816, . ; ‘ s : > Bee BaRRETT, W. F., M.R.I1.A. On a New Form of Calorimter, . GaSe cal oh eld (ELS ' On the Double Quadriform Lighthouse sais , : ae 7A On the Physical Properties of Manganese Steel, . ; . 3860 Drxon, G. Y., M.A. Notes on Two Irish Specimens of EHdwardsta timida (Quatre- “fages) (Plate VI.),.- . . Sete : : . 100 Dixon, 8. M. On Twisted Copper Wire, . 5 : , : : . 646 rh List of Contributors. Firz Geratp, Guo. Fras., M.A., F.T.C.D., F.RB.S. On the Limits to the Velocity of Motion of the Working Parts of Engines, . : : : : ; : On the Temperature at various Depths in ae Derg after Sunny Weather, . ; : : } a a Gruss, Sir Howarp, F.R.S. Notes on some Improvements in Equatorial Telescope Mountings, Note on a Graphical Method of or Certain meee Problems, : ‘ & i . Happon, Aurrep C., M.A. Note on Halcampa chrysanthellum (Peach), . Suggestion respecting the Epiblastic oe of the Segmental Duct (Plate X.), . : : : < Note on the Arrangement of the Miczonteriag i in the Parasitic Larva of Halcampa chrysanthellum (Peach) (Plate XI.) Hartiey, W. N., F.B.S. Note on Lackmoid and Litmin, . The Black Marble of Kilkenny, . Analysis of the Beryls of Glencullen, Co. Wicklow, Haveuton, Rev. Dr., F.R.S., S.F.1.C.D. On the Liassic Fossils of M‘Clintock’s Expedition, Hutt, Epwarp, LL.D., F.B.S. On the Occurrence of an Outlying Mass of Lower Old Red Sandstone and Conglomerate in the Promontory of Fanad, Co. Donegal, . On the different Varieties of Irish Paving-setts, . On the Effect of Continental Land in Altering the Level of the Ocean, PAGE 160 169 107 40 94 649 List of Contributors. JoLy. de. BE On a Method of Determining the Specific Gravity of Small Quantities of Dense or Porous Bodies, Notes on the Minerals of the Dublin and Wicklow Granite. I.—The Beryl and Iolite of Glencullen coe Il., IIL., and IV.), : : On the Permanency of fleece and a ca Con- nexion therewith with Oldhamia radiata and O. antiqua, . On the Occurrence of Harmotome at Glendalough, Co. Wicklow, On a Hydrostatic Balance Plate VII.), On a Peculiarity in the Nature of the Impressions of Oldhamia antiqua and O. radiata, The Phenomena of Skating and Professor J. Thomson’s Thermodynamic Relation, Kinanan, G. Henry, M.B.I.A. A Table of the Irish Lower Paleozoic Rocks, with their Probable English Equivalents, : ; ‘ : On Irish Metal Mining, On Irish Marbles and Limestones, On Irish Marbles and Limestones. Supplemental, The Lisbellaw Conglomerate, Co. Fermanagh, and Chesil © Bank, Dorsetshire (Plate XII.), Arenaceous Rocks of Ireland :—Sands, Sandstones, Grits, Conglomerates, Quartz-rocks, and Quartzytes, Deal Timber in the Lake Basins and Peat ree of North- east Donegal, . Gravel Terraces; Valleys of the ce Sua, and Roste, Counties of Tyrone and Donegal, ‘ 5 : Lavis, H. J. Jonnston, M.D. The Relationship of the Structure of Rocks to the Conditions of their Formation, ‘ ; : ‘ d : PAGE 156 165 347 445 453 34 200 372 489 504 507 629 636 118 vi List of Contributors. Mutten, Bensamin H., B.A. PAGE On a Cloge Almanack in the Science and Art Museum, Dublin (Plate V.), . 79 O’Renuy, J. P., C.H. On the Gaseous Products of the Krakatoa Eruption, and of those of Great Eruptions in general, , 17 On the Antipodal Relations of the New Zealand ashe District of June, 1886, with that of Andalucia of Decem- ber, 1884 (Plate 1X.), 455 Preston, Tuomas, B.A. On the Inversion of Centrobaric Bodies, 639 Rampaut, A. A. On a Mechanical Method of Converting Hour-angle and Declination into Altitude and Azimuth, and of Solving ‘other Problems in Spherical Trigonometry, 642 Reynoups, J. Kuerson, M.D., F.R.S. Note on a Brilliant Meteor seen at Strasburgh on the 15th of August, 1886, .. 889 Sonzas, W. J., HELD), D.Sc. Note on the Artificial Deposition of Crystals of Calcite on Spicules of a Calci-sponge, ; : : 73 On a Classification of the Sponges, 112 Preliminary Account of the Tetractinellid Sponges Dredged ‘by H.M.S. “Challenger,” 1872-76. Part 1—The Choris- tida, : § ‘ ‘ : . Be dys On the ‘‘Cocal Processes” of the Shells of Brachiopods Interpreted as Sense-organs, . 5 5 ; ols On a Specimen of Slate from Bray Head, traversed a the Structure known as Oldhamia radiata, F 355 Supplementary Remarks on Oldhamia (Plate VIII.), 358 On a Separating arcu for use with Heavy Fluids (Plate xe) : 5 é : . 621 On a Modification of cone rece for Determining the Specific Gravity of Solids (Plate XIV.), - 623 List of Contributors. Stoney, Grorce J., M.A., D.Sc., F.B.S. Curious Consequences of a well-known Dynamical Theorem, Stoney, Greraup, B.A. An Experimental Method of Determining Moments of Inertia, Trouton, Frep. T., B.A. A Thermo-electric Current in Single Conductors, Watsn, A. R. An Experiment on the Surface Tension of Liquids, WERNER, Emin. Note on a Specimen of Adulterated Guano, . Wynne, A. B. Notes on some recent Discoveries of Interest in the Geology of the Punjab Salt Range, Note on Submerged Peat Mosses and Trees in certain Lakes in Connaught, o6 Vil PAGE 448 000 171 484 345 85 499 DATES OF THE PUBLICATION OF THE SEVERAL PARTS OF THIS VOLUME. Part 1.—Containing pages 1to 40. (Jan., 1886.) 3 ee 94 a 41 to 112. (April, 1886.) A , 11810176. (July, 1886.) 4 », 177 to 820. (Oct., 1886.) " » 9821 to 446. (Jan., 1887.) 447 to 498. (April, 1887.) Re ,, 499 to 628. (July, 1887.) 3 », 629 to 656. (Nov., 1887.) COE Coe SMe aS o N Haat hoe) i MN THE SCIENTIFIC PROCEEDINGS OF THE , ROYAL DUBLIN SOCIETY. I.—NOTEK ON AHALCAMPA CHRYSANTHELLUM, PEACH. By ALFRED C. HADDON, M.A., M.B.I.A., Professor of Zoology, Royal College of Science, Dublin. [Read, November 18, 1885.] T the corresponding meeting of the Society last year I read a Paper on ‘‘ A New Species of Halcampa (H. andresii), from Malahide,” which was printed in the Procecdings, n.s., vol. iv., pp. 396-398, pl. xvt., figs. 1-4. Since that date I have, through the kindness of my friends Mr. H. W. Jacob and Mr. G. Y. Dixon, seen several specimens of Halcampa from Malahide, and I find that every one has some variation in colour or marking. This fact has led me to reconsider the characters upon which I based the new species just alluded to, and it has resulted in the opinion that it would be wiser to withdraw that name, and to regard our Dublin specimens as the first known Irish examples of H. chry- santhellum, Peach. While regretting the fact of introducing what I may term a stillborn synonym (especially when coupled with the name of my friend Professor A. Andres), the figures at all events convey a much better idea of the species than the very unsatisfactory ones on plate vii. in Gogse’s Monograph, and so far the Paper is not altogether valueless. SCIEN. PROC., R,D.S.—VOL. V. PT. I: B 2 Scientific Proceedings, Royal Dublin Society. In order to substantiate my present view, I propose to give a brief account of all the descriptions we have of H. chrysanthellum, together with a short description of the specimens which have passed under my notice. This will, I hope, have the further effect of putting other naturalists on their guard, and of tending to give some idea as to the specific characters of this form. The following is the bibliography of this species :— Actinia chrysanthellum, . Peach, 1847, in Johnston’s Brit. Zooph., 2nd ed., p. 220, pl. xxxvu., figs. 10-15. * Edwardsia duodecimcirrata, Sars, 1851, Nyt. Mag. for Naturvid., vi., p. 142. Cocks, 1851, Rep. R. Cornwall Polytech. S0C., 1X., p. 6, Pl. 1, tesa Ose Landsborough, 1852, Pop. Hist. of Brit. Zoophytes. Peachia (?)\; -.. . & =) Gossey) U8bo, | Trans. Linn. econ mmxeate Tee Parfit n m . Gosse, 1855, Manual, Marine Zool., i., Deol. Milne Edwards, 1857, Hist. Nat. des Coral- liaires, p. 288. Haleampa, . . . . . Gogse, 1858, Ann. Mag. Nat. Hist. (8), i» p. 418. Edwardsia duodecimcirrata, Danielssen, 1859, Nyt. Mag. for Naturvid., X1., p. 45. Liitken, 1860, Naturhist. Foren. Vidensk. Meddel., p. 196. oe - . Gosse, 1860, Actinologia Britannica, p. 247, pl. vu., figs. 9, 10, and woodcut. fe ; . Hincks, 1861, Ann. Mag. Nat. Hist (8), Viil., p. 363. Xanthiopus bilateralis,. . Keferstein, 1863, Zeitschrift fur wiss. Zool., xil., p. 34, pl. 11., fig. 22. Xanthiopus vittatus, . . Keferstein, 1863, loc. cit., p. 34, pl. m., figs. 15, 16. Edwardsia duodecimeirrata, Meyer and Mobius, 1868, Archiv. fiir Na- turgesch, p. 70, pl. m1. figs. A-D. Happon—Wote on Halcampa chrysanthellum, Peach. 3 Halcampa chrysanthellum, Dana, 1872, Corals and Coral Islands, p- 25, fig. 38. Grube, 1878, Mittheil. iiber St. Malo und Roscoff u. d. dortige Meeres-besonders ; die Annelidenfauna, p. 88. Fischer, 1875, Nouv. Arch. Mus., x., p. 204. Andres, 1884, Fauna und Flora d. Golfes v. Neapel., ix., p. 101. Halcampa kefersteem, . . Andres, 1884, zbid., p. 102. Halcampa farinacea, . . Andres, 1884, in part (not of Verrill), ibid., p. 102. Halcampa andresii, . . Haddon, 1885, Proc. R. Dub. Soc. (n. 8.), iv., p. 396, pl. xv1., figs. 1-4. Halcampa chrysanthellum, Pennington, 1885, British Zoophytes, Dee livia Johnston’s diagnosis of the species is as follows :—“ Body cylin- drical, smooth, striped; tentacula twelve, uniserial, sub-marginal, annulated with brown.’ He quotes the following from Peach’s ms. :-——“‘ This Actinia I find under stones buried in sand in Fowey Harbour between the tide-marks. Body pale, nearly white, with six broad stripes, and three narrower ones between each of the two broader ones, the centre one of the three the broadest—all running the whole length of the body, but are nearly lost before reaching the lower end: these stripes are again divided -by transverse nar- row ones. ‘The tentacula are invariably twelve; the mouth is in the centre, and surrounded by brown flower-like markings. It does not attach itself, but les buried in sand, with its head just above.” . “‘The species readily assumes various shapes, as shown in the figures of it. It is quick in its motions, and buries itself in the sand when disturbed.” Cocks merely quotes an abbreviation from Peach’s diagnosis, and adds:—“In pools with sandy bottoms, Gwyllyn-vase, Pen- nance, &c.; not uncommon.” His figures are very unsatisfactory ; in both only eleven tentacles are represented, although the text says “tentacula twelve”; in fig. 20 they are banded, but not so in fig. 21; in both the disc is quite plain. In fig. 20 the animal is B2 4 Scientific Proceedings, Royal Dublin Society. drawn in a vertical position, its base being expanded and attached to a stone; although it can stand upright in the water when in con- tact with a hard substance, it does so owing to the tenacity of the suckers of its physa, and not, so far as | am aware, in consequence of the latter forming a basal disc. Fig. 21 merely gives a fore- shortened view of the disc and tentacles, and below it is an indis- tinct figure which is not referred to, and which apparently is intended to represent the aspect of the tentacles, &c., when buried in the sand. I mention this Paper and figures in detail to obviate the necessity of future reference, as the Annual Report in which it occurs is not easily accessible. Gosse, in his Paper in the Transactions of the Linnean Society, 1855, adds no new facts; he speaks of its ‘ sensitiveness to alarm, and the spring-like rapidity of its motions.” He considered that there was a posterior aperture. Size, “very minute.” In his Marine Zoology, 1855, and in his Synopsis of the British Actin, 1858, Gosse merely alludes to the species; in the latter, he cor- rectly constituted it the type of a new genus, to which he gave the name Halcampa. In his Monograph, 1860, Gosse mentions that he had upwards of a dozen specimens sent him, in 1858, from Fowey. As these came from Peach’s locality, their identity with the discover’s spe- cies is beyond doubt, but the marking seems to be quite different from the original figure (/.c. pl. xxxvir., fig. 13). The latter, how- ever, 1s very unsatisfactory. Gosse’s description of the markings of the disc, also, does not particularly well agree with the woodcut he gives. The description is as follows :— Column.—* Drab or dirty white; septa as white longitudinal lines; the swollen bladder-like extremity translucent. ' Disk.—“ Marked with. a pretty star-like pattern, consisting of a pale-blue area inclosed in a pale line, and surrounded by twelve triangular rays of a dark-brown hue; each triangle surmounted by a pale, W-like figure, which incloses a dark-brown area, according to the accompanying pattern. Tentacles.—“ Pellucid brown, the front crossed by six semi-rings of opaque white, of which the second, the fourth, and the fifth (counting from the foot upward) are angular, the second pointing downward, the fourth and fifth upward. ... The pellucid inter- spaces are tinged with brown, deepest on the first, second, and Happon—Wote on Halcampa chrysanthellum, Peach. 5 fourth ; and the first white ring surrounding the foot is sometimes tinged with sulphur-yellow.” The description of the specimens dredged by Sars, in twenty fathoms, at Ure, Lofoden Island, and also at Bergen, agrees so closely with some of the Malahide forms that there can be little doubt as to their identity. He describes the body as cylindrical, white; hyaline, with a brown epidermis; tentacles twelve, white; hyaline, with two brown rings; twelve brown spots round the mouth. The shape of tentacles and other points are identical in the two forms. The brown “epidermis” probably refers to the slimy sheath being beset with sand or other foreign particles. The careful account of Meyer and Mobius leaves no doubt con- cerning the identity of their specimens with Peach’s. They state that the body is smooth, flesh-coloured, with pale longitudinal lines; it generally covers itself with a tube of slime and sand erains. The tentacles are quite colourless, with two or three red- dish-brown transverse bands, and similar longitudinal stripes at their bases; there are brown spots on the disc, each corresponding with the tentacle. The authors refer to the extreme transparency of the dilated body, and to the presence of a pair of fine lines in the alternate broad red bands of the body, referring, of course, to the small secondary mesenteries (fig. 4, p. 12), and of which they give (pl. m1., fig. C) a characteristic drawing. ‘They found eight to eleven ten- tacles in their forms—length, 20-25 mm.; diameter, 2-3 mm. In mud, Bay of Kiel, 6-9 fathoms. They further identify with this species the two specimens found by Dr. Litken, at Helleback in the Sound; but Andres (/. c., p. 96), considers this a true Kdwardsia, which he names F. Jithend. Dr. Andres correctly placed Sars’ species in the genus Hal- campa; but he believed that it was identical, save for characters ‘“‘of the smallest importance,” with Halcampa farinacea, Verrill, and, “rather than preserve a record of the two species,” he unites them into one. Whether Verrill’s species is identical with any Huropean form is very doubtful, and the evidence would seem to point the other way: for the present, at all events, his name must stand. The great range of variation of H. chrysanthellum suggests a critical examination of the two species which Keferstein described 6 Scientific Proceedings, Royal Dublin Society. from St. Vaast la Hogue (Manche, N. France), and for which he constituted the new genus Xanthiopus; his definition of this genus agrees so exactly with that of Halcampa, as defined by Gosse, that there is no doubt they are synonymous, and the latter has the pre- cedence. The two species are yellowish in colour, and were found in the small chinks in the granitic rocks at extreme low water. Haleampa (Xanthiopus) bilateralis.—The tentacles corresponding to the ends of the mouth are differently formed and without trans- verse bands, as in the other ten, and which bear two yellow trans- verse bands. All the tentacles are continued over the oral disc as triangular swellings to the opening of the mouth. About 40 mm. long. H. (X.) vittatus.—All the twelve tentacles are similarly formed, with four yellow transverse bands; they do not run over the oral dise to the mouth. Mouth in the middle of asmall, conical, raised, yellow ring. About 20 mm. long. These two forms are undoubtedly the same species. Andres, also, is of the same opinion; but he, contrary to the British rules of Zoological nomenclature, re-names the species as H. kefersteini, consisting of “var. a vittata; tentacles equal; small size; and var. (3. bilateralis ; Gonidial tentacles different from others by lacking the annulations; larger size.” The pale colour and different appearance of the gonidial tentacles of the first species is not unfrequently met with in many of our British sea-anemones (e.g. Tealia crassicornis, Mull., Actinoloba dianthus, Ellis, and Heliactis bellis, Hill. and Sol.). The only other distinctions between the two species are different num- ber of yellow bands on the tentacles, and the presence or absence of distinct radii on the oral dise—characters too slight to alone constitute specific distinctness. The conclusion at which we must arrive at:is, that these two forms are merely varieties of H. chry- santhellum. Dr. Ed. Grube found H. chrysantellum (sic) at Roscoff, buried in the sand at low water. He states that it only occurs in a single zone. “A few steps nearer the sea and one no longer finds it. These and the nearly allied Edwardsias are so completely hidden in the sand that their presence is not betrayed.” He describes it as a perfectly white polyp, of the thickness of a swan’s quill, with twelve short tentacles, and a single black point between each. The Happon—Wote on Haleampa chrysanthellum, Peach. 7 lower portion of the body is described as being glandular, in the habit of forming a sheath for itself, having a revolving motion, and becoming swollen and transparent; he also noticed that its posterior end could adhere a little. Landsborough, Milne Edwards, Hincks, Dana, Fischer, Andres, and Pennington, merely repeat previous descriptions more or less fully, but add nothing new thereto, so it is unnecessary to refer at length to them. . Previous observers have accurately described the general ap- pearance and habits of this interesting little anemone. I need add only a few supplementary notes.’ In my former Paper I have figured what may be regarded as the general form of the animal when about half extended; but, as all observers have noted, the shape may be very varied. The physa is usually in a state of more or less distension ; occasionally it assumes a very thin, rod-like appearance. (The physa is in this state when boring into the sand: compare the similar appearance of Peachia hastata, Gosse—Haddon and Dixon—Proceedings of the Royal Dublin Society (n. s.), vol. iv., pl. xvitt., fig. 7.) I have been unable to see a terminal posterior orifice, but there is a small per- foration in each intermesenterial chamber close to its posterior ter- 1 My friend Mr. G. Y. Dixon has kindly allowed me to copy the following from his aquarium notes :— ““ November 5, 1885.—Only one Halcampa survives [from September 26]. It, how- ever, is in splendid health, and has grown considerably, being, when fully expanded, 2 inches long; scapus, $ of an inch in diameter; capitulum, 4 inch. When fully dis- tended it is quite transparent, and its oesophagus can be distinguished quite plainly running the whole length of the capitulum as a narrow, straight, pale-orange tube, which terminates just at the constriction which usually marks the limit between the scapus and capitulum. ‘The twelve mesenteries are very conspicuous in the scapus, their inner free edges being orange, and,shining through the pellucid body wall. With an inch objective you can distinctly see round glands (?) imbedded in the convoluted and swollen edges. The mesenteries are arched above where they run in to join the cso- phagus, and are gradually sloped away as they come down towards the constriction which usually marks off the physa from the scapus. The clearness and transparency of the whole animal, but above all of the scapus, almost surpasses belief. I cannot find any marks on the physa like those in Peachia hastata.’’ [This, of course, refers to rows of pores alluded to in our joint Paper.—A. C. H.] “Four pairs of mesenteries are longer than the rest, and are more convoluted on their edges and more orange in colour; between each of these pairs is a mesentery which does not run down so near the physa; its edge is not so swollen or convoluted, and is more of a straw-colour than orange. Is it possible that this points to an affinity 8 Scientific Proceedings, Royal Dublin Society. mination. Similar pores, which by the way are very difficult to observe, were found in Halcampa clavus, Quoy and Gaim, by R. Hertwig, and I have also seen them in the so-called Halcampa fulton, St. Wright. These perforations enable the physa to be suddenly emptied of its contained water. They exist in large numbers in Peachia hastata, both Mr. Dixon and myself being now satisfied that such is the true explanation of the appearances we described (/.c., p. 403). The whole body is continually under- going slow waves of alternate contraction and expansion. As Gosse states, the body is capable of great extension (“ extending to ten times its diameter or more). . . Specimens reach to an inch and three-quarters in length, and one-eighth of an inch in average diameter; the extremity is frequently inflated to one-fourth.” My longest specimen was about 50 mm. (2 inches) in length, and about 3°5 mm. (2; of an inch) in diameter at the middle. Other specimens measured about 31 mm., 38 mm., 44 mm., &e. (13 in., 13 in., 1} in.) in length. In nearly every case the tentacles, although monocyclic and perfectly uniform in size and shape, appeared to consist of two series. Those of the first series, which for the sake of conveni- ence. I term the primaries, are usually carried more or less arched forwards and inwards, and are also almost invariably more pro- with the octoradial Edwardsie?’’ [In connexion with the last paragraph I would quote the following from Dr. R. Hertwig’s Report on the Actiniaria, Challenger Re- ports, Zoology, vi., 1885, p. 95.]:— ‘‘The constitution of the septa in Haleampa cavus [Quoy et Gaim] shows further peculiarities worthy of notice, which seem to me to indicate its relation to the Edwardsiz. As I was preparing a series of sections through one-half of the physa of the larger spe- cimen, it struck me that three septa [mesenteries] (including the pair of directive septa [mesenteries]) were not so strong as the other septa, inasmuch as their longitudinal muscular cords became sooner indistinct (pl. x111., fig. 7.) In the second smaller Hal- campa, in which I was able to make sections through the entire body, four septa were somewhat smaller than the eight others; and, finally, Strethill Wright has described a parasitic Halcampa living on Meduse (Halcampa fultoni), in which he can distinguish four stronger and eight weaker septa (Ann. and Mag. Nat. Hist., ser. 111., vol. viii., p. 188, 1861). All this shows that an unequal development of the septa, and, consequently, a difference in their morphological value, is not unusual in Haleampa. If we assume that the eight stronger septa are homologous with the septa of Edwardsia, whilst the four other septa are new formations, then the genus Halcampa would present us with transition forms between the Edwardsie and the Hexactinie.’’ [As the present com- munication is merely a critical note on the identity of the species in question, I do not intend on this occasion to follow up the line of thought here suggested.—A. C. H.] ‘ Happon—WVote on Halcampa chrysanthellum, Peach. 9 minently marked and coloured. As they are prolongations of those mesenterial chambers which have no secondary mesenteries (see fig. 4, p. 12), and as one of them is situated at each end of the slit-like mouth, they therefore correspond to the primary tentacles of other Actiniz. The tentacles of the second series (secondaries) usually bend outwards and downwards, being slightly recurved at the tip. Their colouration and pattern is often paler and more or less obscure. The colour of the scapus is usually whitish, sometimes tinted with buff, and rarely opaque orange. As previously noted, when mature, the ovaries shine through the translucent body with a creamy orange colour. The insertions of the mesenteries appear externally as longitu- dinal white lines: between each alternate pair of mesenteries there is a pair of small mesenteries, which appear on the outer surface as two thin white lines. ‘This explains Peach’s account of the stripes of the column, the “stripes” being the darker, 7.e. translucent, areas between the mesenteries. The transverse stripes noticed by Peach are merely external corrugations due to the contractibility of the body. (See fig. 2, p.12.) The capitulum is subject to considerable variation in ornamentation: usually it is buff, sometimes with a brown band. The white or pale-yellow bracket-marks alluded to in my former Paper appear to be very constant in their appearance. It is, however, in the disc and tentacles that the greatest amount of variation occurs. I have therefore briefly described a number of variations to prove how careful one should be in laying any stress upon colour or markings, in dealing at all events with this species. 1. Disc opaque white. Tentacles very pale buff, with five paler bands ; the lowermost two are waved or [-shaped. White bracket- ’ marks externally at base of tentacles. 2. Dise pale lemon-yellow. Tentacles very pale buff, with five white bands, and some indistinct brown bands, which are much more distinct on the six primaries. A brown band round the eapitulum, and pale bracket-marks. 3. Dise rusty colour, with distinct paler radiating lines (mesen- teries), forming twelve dark-coloured wedges. ‘T'entacles of same rusty colour, with five pale bands, the four upper of which are straight, and the lowermost is \/-shaped. The inverted triangular 10 Scientific Proceedings, Royal Dublin Society. area left between this and the lowest straight line is dark in colour. : A. dark ring all round the base of the tentacles. 4, Disc pale, with a lenticular dark-brown mark in each radius, and external to it at the base of each tentacle a brown line. The six primary tentacles have the lowest half ring, dark in colour, and V-shaped, with a dark spot between the two limbs of the \/; the other lines pale. ‘The six secondary tentacles have pale indistinct markings, the lowermost of which is M-shaped. White external brackets. 5. Disc pale-buff round mouth, separated from the pale-yellow peripheral portion by a chain of dark-brown lenticular marks, which practically form a ring. At the base of each tentacle is a transverse dark-brown line; base of tentacle white ; remainder pale- buff, the two colours being separated by a dark [yj-mark; there are also one or two indistinct pale-brown markings. At the base of each tentacle externally there is a lateral dark line, which shghtly converges towards its fellow. 6. Disc pale, with alternate dark (primary radii) and light (secondary radii) lenticular marks. The primary tentacles are very dark; there is a basal [f-mark, with a dark triangular mark a little way above. ‘The external bracket-marks are prominent, and below each is a pair of dark spots. 7. Dise pale-orange, a white spot opposite each tentacle. Ten- tacles with five pale rings, the lowermost [f-shaped. There is a small pale basal mark. The external bracket-marks are very plain. 8. Dise pale-buff; an indistinct pale \V-mark in the centre of each radius. Tentacles with five pale rings, of which the lower- most is M-shaped. One or two other varieties were seen, but a sufficiently careful note of the colour and pattern was not made. The variations of the disc and tentacles are so many, that at first sight it seems almost hopeless to give any character which would be of service for specific determination. I have, however, ventured to give a drawing (fig. 3, p. 12) of what I take to be the general pattern of the disc and tentacles. The following diagnosis will, I hope, be found to be essentially correct :— : Happon—WNote on Halcampa chrysanthellum, Peach. 11 Haleampa, Gosse. Body elongated, cylindrical, divided into a capitulum, scapus, and physa; the mesenteries are more or less apparent throughout their whole length ; except when fully extended, the body is corru- gated; physa with minute suckers. ‘Tentacles twelve, monocyclic, marginal, cylindro-conical. Disc plain; mouth linear, slightly pro- minent. British species— Hi. chrysanthellum, Peach. Form.—Body vermiform, extending to about ten times its dia- meter; smooth, or only secreting a mucous tube. Capitulum and tentacles completely retractile; physa large, non-retractile. Colour.—Column whitish, occasionally slightly yellowish or buff, rarely orange; capitulum often more or less buff-coloured; a pair of pale bracket-marks () usually present below the angles between the tentacles. The orange-coloured ovaries, when ripe, shine through the walls of the scapus, giving it a creamy-orange colour. The in- sertions of the mesenteries appear throughout the whole length of the body as white lines, and the suckers appear as white dots on the otherwise transparent physa. Dise white, pale-yellow, or pale-buff; may be quite plain, or ornamented with variable brown markings. Tentacles pale-buff, with five or six light or dark bars on their internal aspect, of which the basal is usually straight—the second M-shaped, the third V-shaped, the three (or four) upper being usually more or less straight. Hxternally, at the base, dark lines or spots are generally present. | Size.—30-50 mm. (14 to 2 in.) long, when fully extended. About 3°5 mm. (23; in.) in diameter. Habitat.—In Send or crevices of rock at low water, and down to 20 fathoms: S.W. England, EH. Ireland, N. Fr ance, Norway, and Denmark. This is the only recorded British species; but last summer I dredged a well-marked second species at a depth of forty fathoms off the mouth of Kenmare river, a description of which will in due time be laid before the Royal Irish Academy. ~ | Halcampa fultom, St. Wright (Proc. Phys. Soc., Edinb., ii., p- 91, 1859), is, undoubtedly, an immature form. I obtained specimens of it which were parasitic on some Hydromeduse 12 Scientific Proceedings, Royal Dublin Society. (“ Thaumantias”’), in June, 1885, at Kingstown, county Dublin. I have observed several phases of its development, but could not obtain a sufficiently complete series to definitely state of what Actinian it is the larval form. My opinion, however, is, that it will prove to be the young of H. chrysanthellum. The above communication is but a further contribution to the systematic knowledge of our British Actinie. I am fully aware of the morphological interest connected with the free Actiniz, and though I have made some anatomical investigations on this form, I refrain from publishing them till I have examined a sufficient number of other sea-anemones to render a description and com- parison profitable. Fig. 1.—Side view of a fully extended Halcampa chrysanthellum, magni- fied about 2 diameters. 2.—Generalized diagram of markings of oral disc and tentacles. 3.—Side view of capitulum and tentacles. 4.—Transverse section through the lower portion of the capitulum. The following points should be noted :—The arrangement of the muscular bands on the twelve mesenteries; the ex- istence of a pair of very small secondary mesenteries in the alternate intermesenterial chambers; the existence of a pair of deep sagittal cesophageal grooves, which are pro- vided with long cilia, and of five obscure furrows on each side of the ciliated cesophagus. [Figs. 2,8, and 4 are placed in the same relative position, and are not drawn to scale. |] [ 18 ] IT.—ON A NEW FORM OF CALORIMETER. By W. F. BARRETT, Professor of Physics in the Royal College of Science, Dublin. [ Read, June 16, 1885.] AN accurate mode of determining the specific heat of bodies, with- out the serious corrections that have to be introduced in the ordi- nary method of mixtures, is much needed. Mr. Joly has lately devised and described before the Royal Dublin Society a novel and ingenious method depending on the amount of steam con- densed by the body; but I have not found this method answer so well for determining specific heats as for latent heats of vaporiza- tion; in the latter case it leaves little to be desired.! The method devised by Professor Bunsen is well known. A con- venient modification of Bunsen’s calorimeter was made some time ago by Professor Emerson Reynolds, wherein the calorimeter takes the form of an alcohol thermometer with a large bulb, and having an arbitrary scale, the value of which is determined separately. The instrument I now beg to submit to the Society resembles the fore- going in so far as the cup for holding the body under experiment forms a portion of the thermometer, which, however is mercurial, and has a very open scale. The instrument is shown in the wood- cut on next page, and its present form is mainly due to the valu- able suggestions made, in the course of working with it, by Mr. J. M‘Cowan, the Demonstrator of Physics in this College. Asa piece of glass-blowing it is, I believe, unrivalled, and is a testimony to the skill of Mr. Hicks of Hatton Garden, London, who under- took to make it for me, and who informs me that the cup is blown out of a single piece of glass tubing.’ The cup, A, has a capacity of about 4 cubic centimetres; it is surrounded by a jacket of polished metal,® to prevent any slight loss 1 { understand Mr. Joly has since improved his apparatus for finding specific heats. 2 Since this Paper was read, Mr. Hicks has made several of these instruments, and can now produce them at a moderate cost. 3 A simpler expedient is to silver the outside of the bulb of the thermometer by Liebig’s process. 14 Scientific Proceedings, Royal Dublin Society. of heat by radiation, and is provided with a little silvered cover, G. The stem, B, is supported horizontally, and is graduated from — 5° to 70° or 80° Centigrade, and reads easily to tenths of a degree Centigrade. Supported immediately over the cup is a small burette, C, the level of the liquid in which can be very accurately read, owing to the fact that only a longitudinal, narrow chink of clear glass is left in the centre, the sides being of opaque enamel. The mouth of the little burette is funnel-shaped, and its neck can be closed by the thermometer, D, it carries, the end of the thermometer bulb being ground to the neck or made water-tight by a small rubber ring. This thermometer is short, but has an open scale, and is graduated from about 30° to 100° C. Into the burette is placed the warm water or other liquid: by loosening the thermo- meter the liquid is allowed to run into the calorimeter, A, below ; the mean temperature of the issuing liquid is thus accurately deter- mined as it flows past the bulb. When the cup, A, is nearly full the burette is closed by pushing down the thermometer, D, and the cover, G, quickly placed over A.: the highest reading on the stem, B is now taken. ‘The volume of the liquid used is then read from the burette, and the operation is complete. But as the volume of the liquid has been measured, its weight must be found by taking its specific gravity for the temperature at which it was used. To obviate this inconvenience, the weight of the liquid can be found directly in the arrangement shown in the figure. Here the thermometer is turned into a balance, the stem being Barretr—On a New Form of Calorimeter. 15 supported by knife edges, H, somewhere near its centre of gravity. From the end of the stem a pan, I’, depends, and beyond this a pointer, fixed to the stem, moves over a graduated are. ‘The pan is made of the right weight to exactly equipoise the arrangement at a given air temperature. The weighing of the liquid in the cup, A, is taken at this temperature ; otherwise the varying length of the thread of mercury in the stem, B, would derange the balance. Except as a thermometer-stopped funnel for the liquid, the burette is, of course, not required in this arrangement. In making a determination of the specific heat of a liquid with this instrument we require no cool liquid in A to mix with the warm liquid from C, for the bulb of the thermometer, A, itself forms both the containing vessel and the cool material to be warmed. All that is necessary is a careful determination, made once for all, of the heat capacity of the instrument. This constant factor, K, may in fact be found and stamped upon the base of each instrument before it leaves the maker’s hands. As the constant is determined in precisely the same way that subsequent measure- ments are made, it includes, or rather it enables us to evade, all corrections, such as those due to the heat capacity of the vessel and of the thermometer, and also the loss of heat due to cooling if the same range of temperature be employed; and indeed, if otherwise, the silvered jacket and cover (which latter is necessary to prevent loss from evaporation) render the correction from this source negli- gible in ordinary work. The constant, A, is found as follows :— Let W be the weight of water used, 7 its original temperature (viz. that indicated by the thermometer-stopper) ; let ¢ be the ori- ginal temperature of the calorimeter (given on the stem, B), and 0 its highest reading after the water has entered. As the heat lost on the one hand is equal to the heat gained on the other, and the specific heat of water is unity, W (T-0)=K (0-12); whence When a determination of the specific heat, S, of a liquid has to be made, warm the liquid, and pour it into the burette ; note as before 16 Scientific Proceedings, Royal Dubin Soctety. its temperature, 7, as it issues, and afterwards find its weight, W’; note the rise of temperature of the calorimeter from ¢ to 0; then K @-¢t SW T6 A few minutes suffice to complete the whole determination to within a limit of error of one per cent. It will be obvious that for ascertaining the specific heat of small quantities of rare liquids this form of calorimeter will be found particularly applicable; and as the determination of the specific heats of organic liquids can thus be readily and accurately made, the instrument may be of use to chemists in the investigation of the molecular weights of such compounds. The instrument is not quite so applicable for the specific heat of solids as of liquids; but it may be used for the former when they are in powder or in small fragments. In this case the calorimeter may first be heated by a known quantity of warm water, and the solid at the temperature of the air be dropped in; but this method does not yield good results, there being no turning point in the temperature. It is better to heat the solid in a small steam or water bath, and drop it into a known quantity of water contained in the cup of the calorimeter, the heat capacity of which is in- creased by this amount, so that its constant now becomes Aj. The solid may, of course, be weighed beforehand, so that the simpler unbalanced calorimeter can be employed. getigan | III.—ON THE GASEOUS PRODUCTS OF THE KRAKATOA ERUPTION, AND THOSE OF GREAT ERUPTIONS IN GENERAL. By J. P. O'REILLY, C.E., President, Royal Geological Society of Iveland. [Read, November 16th, 1885. ] Tue subject of the following Presidential Address is one suffi- ciently recent, and, owing to its magnitude, sufficiently important, to justify recurrence to it, notwithstanding the many points of view from which it has been already treated, and the fulness of the reports which have had for their object its description. I do not propose to enter into a detailed examination of the different phases of this great event, so far as they have been recorded, but rather to call attention to certain aspects of the phenomena which, from the very first, seemed to me of the very highest importance, and as opening up a very wide and interest- ing field of inquiry. I allude to the gaseous agents and products of the great Hruption as manifested by the quantity and nature of the ejected matter, the intensity and range of the explosions, the resulting commotions of the atmosphere, and by the singular atmospheric phenomena which subsequently became visible all round the world, and even still manifest themselves daily. In commencing, I will ask leave to refer to the article which, shortly after the arrival in Europe of the first accounts of the Krakatoa Eruption, appeared in Nature, September 13th, 1883, entitled ‘Scientific Aspects of the Java Catastrophe.” With reference to this article, I wrote, on the 16th September, the following letter to that journal, which appeared in its issue of 27th September, and therefore, as will be seen, previous to the arrival of news relative to the wonderful appearances of the morn- ing and evening skies :— “Your excellent leading article on this great event omits to call attention to a factor which I have long maintained to be of SCIEN, PROC. R.D.S.—VOL. Y. PT. I. C 18 Scientific Proceedings, Royal Dublin Society. the greatest interest and importance from the points of view of meteorology and geology in general. I allude to the quantity of gaseous vapour emitted during the eruption. This must have a direct relation to the quantity of matter emitted (whatever its form), and also to the height and distance to which the matter may be ejected or carried. Now, I hold that such vast quantities of gases as must have been liberated on this occasion cannot be passed over, or taken as having no action on our atmosphere. Whatever the addition made, temperature and air currents are influenced by it, either locally, or over great extents of the earth’s surface; and if it were possible to take account of the height — attained by the gases, their temperature at liberation, and the point of the globe whence proceeding, some judgment might be attempted of their action. In the present state of meteorology we know nothing of these quantities, but it is justifiable to assume that the upper currents of the air may be thus profoundly influ- enced, and that in certain cases cyclones may thus be generated. The present very fine dry weather we are enjoying here, with the high and steady barometer, may be a result of the great eruption, and it will be worth while to note if any abnormal conditions of atmosphere be found to prevail during the coming months.” It was not until October 11th that an article appeared, noticing ‘a green sun in India;”’ therefore, quite subsequent to my letter. During the following months the wonderful “ glows” which illu- mined the heavens, more particularly after sunset, interested men of science of every country, and they have been very generally attributed to the presence of vast quantities of dust in the upper regions of the atmosphere—this dust being generelly presumed to have resulted from the Krakatoa eruption. I may therefore, in some degree, claim to have anticipated the appearance of these sky glows, in so far as it is accepted that they are due to emissions from Krakatoa. I now propose to examine more extendedly the con- siderations upon which I based this anticipation. It may not be out of place to remark, that in the study of natural phenomena we are easily led to attribute a relatively greater importance to agents which impress our senses than to those more occult in their action, and more particularly which do not leave distinct evidence of their influence. Thus, it is only quite recently that the ré/e of dust in the formation of rain has O’Reitty—On Gaseous Products of Great Eruptions. 19 been demonstrated by Atkin, and the wondrous organic life of the ocean is essentially due to the presence of gases in relatively small quantity. Now, no class of agents in nature more easily escape attention or baffle investigation than gases, unless they present themselves physically or chemically fixed, so as to allow of their determination and measurement. The reason of this is obvious. Almost all the gases acting at the surface of the earth have densi- ties less than that of air; consequently, unless restrained or brought into combination, they tend after emission to rise in the air, and becoming mixed with the atmosphere, pass to a very great extent beyond our observation and our control. That the geologist should therefore attribute to them a rather subordinate and ill-defined part in the series of phenomena which he is called on to study can be understood. Brought, as he is, face to face with the rock masses forming the crust of the earth, or with the water masses which cover three-fourths of its surface, he natu- rally attaches importance to them, rather than to the gases which have ever acted, and are acting continually, from the interior or at the surface of that crust, but which by their very nature escape his attention even while still active agents, and which are so difficult of determination and measurement. There is, therefore, some justi- fication for my calling attention, in this respect, to those earlier phases of the earth’s development, which are usually treated as either purely of the domain of astronomy, or are not admitted _ as being tangible for the geologist. Whatever the hypotheses which may be accepted as to the con- ditions of development of the earth, it is generally taken for granted that the successive phases of its existence have been similar in nature, if not in degree, to those which Science has been led to attribute to the other heavenly bodies. Thus we are led to believe that it has passed through all the phases observable in one or other of these heavenly bodies: from that of a nebula, becoming more and more condensed, to that of a sun; and from that of a sun through successive stages to the condition of things with which geology usually commences, that is, of a globe, having a crust or solid exterior, and therefore in a relatively cooled state, and ca- pable of allowing the condensation of water on its surface and the existence of organic life thereon. Now spectroscopy and observa- tion have shown that in the nebul, as in the comets and as in the C2 20 Scientific Proceedings, Royal Dublin Society. suns, gases play a very important part, if they be not the only con- stituents. For certain of these bodies it has been shown that car- bon, and hydrogen, and hydrocarbons, are essential elements, both chemically and physically. Are we not, therefore, entitled to as- sume that these elements and combinations were abundantly pre- sent, and very active agents, in the first stages of the development of the earth, and if so, that traces of their influence may still be found both in our atmosphere and in the interior of the globe? Is it not reasonable to suppose that, in the slow and continuous process of contraction, very great masses of gases became retained or occulted by the cooling matter, and that these occulted gases have been the essential agents in balancing tensions in the con- tinually contracting sphere ?—that this continuous contraction led to the pressure of masses of these gases until heat was liberated in more or less degree, and frequently to the point which brought into play chemical affinities; and that thus the whole series of phenomena, which have tended and are tending to modify the form of the earth’s surface, are intimately bound up with the existence and action of gases in the interior and at the surface thereof ? : Thus, from the very earliest period, we are called upon to re- cognize the continuous presence of gases as essential constituents of the earth’s mass, and, so far as analogy allows us to judge, as most active agents and products of alteration. or the period dur- ing which the crust was not yet formed they must have been pre- dominating agents; while for the subsequent periods, during which the temperature decreased and the crust increased in thickness, their intensity of action must have gradually diminished, and their emis- sions become more and more spasmodic, or of longer period, until conditions were established which we now designate as voleanie, that is, when contraction could only take place by reason of the sinking of masses of the crust, with accompanying vuleanism and earthquake phenomena, such as we witness at the present time, one of the most important and constant of which is the emission of gases. Leaving aside speculation as to the initial constitution, volume, and state of the atmosphere, and coming down to the period during which the earliest stratified rocks were being formed, we are led to imagine for that period a globe greater in diameter than at present, O’Remty—On Gaseous Products of Great Eruptions. 21 having a crust relatively thinner and very differently constituted from what now exists; and, since we suppose an ocean of some depth and an erosive action, we are led to admit the formation of strata under conditions, in some sort, corresponding to those of the present state of things. Therefore we should represent to ourselves, at that period, an atmosphere having a direct relation, both as re- gards quantity and constitution, with the then phase of cooling and contraction of the earth. Moreover, we must suppose surfave rocks, more or less altered, fissured, and penetrable, in which became re- tained chemically and physically a certain amount of gases which previously existed as atmosphere; and, finally, we have to picture to ourselves an ocean in which, as at present were retained in solu- tion gases, also part of the then atmosphere, in quantity and qua- lity relative to the temperature and constitution of the then ocean mass, and relatively to the prevailing atmospheric pressure. These conditions have continued to prevail up to the present time, but in degree and in proportions which must have depended, and must continue to depend, upon the successive phases of contraction and the surface changes of the earth. We can even imagine a last » stage when contraction will tend to cease, when, therefore, the emission of gases will consequently become less frequent and more and more diminished, when the atmosphere as well as the ocean will become more and more chemically and physically retained by the rocks forming the crust, and when finally our earth will cease to have either an atmosphere or an ocean. If I have thus ventured so far back into time, it is in order to distinctly establish the sequence of relation and the dependency which I conceive to have existed at all times between the cooling and contracting sphere and the atmosphere. And if we might comprehend under that term the sum of the gases existing— (a) Free at the surface of the earth ; (0) In chemical combination with, and physically retained by, the rocks forming the crust; and (c) The gases held in solution by the ocean and other waters ; then we might consider the sum (a + 4 + ¢) as representing, or as being proportional to, the total amount of contraction effected since the period of the commencement of formation of the crust, 22 Scientific Proceedings, Royal Dublin Society. The “atmosphere,” properly so called, would be that sum minus (b +¢). Now one of the most interesting deductions arrived at from the examination of the fossil remains of the different geological formations is, that our atmosphere has certainly varied both in constitution and (most probably) in quantity, and if my assump- tion of an intimate relation of the atmosphere with contraction be correct, or admissible, there must have been periods or phases of marked contraction, and therefore of very active vulcanism and accompanying emission of gases, during or about these periods. Such geological data as we already possess certainly do point to periods of great volcanic activity, manifested by outbursts of lava and alterations of the earth’s surface, and corresponding changes in the relations of land and ocean. The tertiary period may be cited as an example in this respect. Turning now from what may, perhaps, be considered as mere speculation, to the phenomena of the Krakatoa eruption, it will be easily understood that, influenced by the considerations already developed, my attention was particularly drawn to- wards the ré/e of the gases in this case, and that I was led to attribute to them an importance proportional to the magnitude of that event. Moreover, that very magnitude seemed to promise some phenomena of a nature capable of demonstrating that actual additions have thus been made to the atmosphere, and a due consideration of the details furnished of the event lead, in my opinion, very distinctly to that conclusion. From the very careful reports made by their engineers to the Dutch Government, as well as from other sources, we have an estimate given us of the quantity of ashes emitted, which had fallen in such proximity to the locality, as to allow of an approxi- mate measurement being attempted. Thus in the report which appeared in Nature, vol. xxx. p. 10, the author says: “I found that on calculating as accurately as possible the quantity of ejected solid substances, they reached 18 cubic kilometres as a safe esti- mate. These 18 kilometres represent a weight of more than (36 x 10”) kg.” He adds: “the volume of ejected gases was, perhaps, hundreds of times greater.” Furthermore, he says: “However large the quantity may be, it does not nearly reach that which Tamburu produced in 1815, which Junghuhn estimated O’Retiy—On Gaseous Products of Great Eruptions. 23 at 317 cubic kilometres. This computation, however, rests on but few data, so that, in my opinion, a quantity of 150 to 200 cubic kilometres will come nearer the truth.” The quantity thus estimated for the Krakatoa eruption is evidently but a part of the total emission of solid matter: what proportion this heavier part of the ejected ash bears to the finely- comminuted matter, to the presence of which in the atmosphere the continuously recurring glows have been attributed, it would be impossible to say. How much more must be allowed for the still finer matter, which continues suspended at very great altitudes, which evidently encircles the earth, and to the presence of which is attributed the faintly coppery haze visible round the sun’s image ever since the eruption, it is still less possible to estimate ; but we can with safety say, that the quantity of vapour and gases emitted must have been in some degree proportional to the total quantity of ejected matter. We are further justified in assuming that the quantity of gas and vapour brought into action was not. the minimum strictly necessary to project the totality of this solid matter into space; therefore any estimate of the quantities of these gases that may be attempted from the data accessible ean only be much beneath the truth: indeed this is precisely one of those cases where, wanting any term of comparison, the mind is simply unable to exaggerate, even were there the will to do 80. Considering, therefore, only the portion of the ashes the volume of which has been estimated, and the data as to the height to which they attained, it is possible to arrive at a term of comparison for the quantity of gases emitted by comparing with the results produced by the use of gunpowder or other explosives. In Berthelot’s remarkable work, Sur Ja force de la Poudre, 1872, there is a table at p. 190, wherein for each explosive examined by him he gives the amount in volume of gases gene- rated per kg. of consumed explosive matter, and the temperature in ealorics attained. By the aid of this table an approximate value for the gases having acted explosively in the case of the Krakatoa eruption can be attempted. Let us consider in the first place the work done in the case of the discharge of a 100 ton gun, for which I find in Nature, vol. xxvii. p. 385, the 24 Scientific Proceedings, Royal Dublin Society. following data :—shell = 2000 lbs.; charge = 772lbs. The ex- treme range of these guns is about 10 to 12 miles Eng. Now, as regards the height to which the ashes were shot up, we have the following statement (Nature, vol. xxx. p. 13):—“ The steam cloud, according to the measurements taken on board the German man-of-war ‘ Elizabeth,’ which left Anjar that morning at nine o’clock, must have reached a height of at least 11,000m. During the much more violent explosion of Aug. 26th-27th the height, if the above report may be relied on, may very well have attained 15 to 20 km.” (that is from 9°3 Eng. miles to 12°4 Eng. miles) — a height about equal to the extreme range of the 100 ton gun in question, and without taking into account the increased range which should be attained by a projectile shot vertically through air of continuously decreasing density. Now, admitting that a comparison may be drawn between the action of gunpowder in such a cannon, and that of the gases or steam in the vent of a volcano, we have merely to take the estimate of the quantity of ashes thrown up during the Krakatoa eruption, and determine from that the corres- ponding charge estimated as gunpowder. According to the re- port in question, this quantity of ashes is given as 36 x 10” kg.; and as the charge in the case of the 100 ton gun is to the projectile as 3472,, we may take as charge in the case of the emitted ash, 386 x 10” x =472, = 36 x 10” x 0°386, or approxi- mately 386 x 10° x 0-4 = 14:4 x 10” kg. powder. The table gives the amount of gases generated per kg. of powder as 0-225 me. Therefore we have by the explosion of this supposed charge of powder 14:4 x 10” x 0°225 me. = 3°24 x 10” me. at the pressure 0°76mm. = 3,240,000,000,000 me. | To appreciate what this cube means relative to our atmo- sphere, we may take this as having a height of about 5 miles, or in kilometres, about 8 km. high: dividing, therefore, this cube of gases by 8000 m., we have 405,000,000 kms. as the surface which would be occupied by a volume of air of that cube and 8km. high: this would represent 405 kms., that is a surface of about 20km. x 20km. = 12:2 miles x 12:2 miles. But the height was really greater than 20km., and has been variously estimated at 40 to 50 miles = 64'4km. to 80°5km. The quantity of ashes was much greater than that calculated, while O’Reitity—On Gaseous Products of Great Eruptions. 25 the author of the report in question considers “that the volume of the ejected gaseous substances was perhaps hundreds of times as large”’ as that of the ashes. A similar calculation for the Tamburu eruption would give us a proportionally greater volume of gases, and in both cases merely terms of comparison, since, according to all the authors who have had occasion to describe eruptions witnessed by them, the quantities of gases and vapours emitted are great beyond all comprehension. What, however, it is quite necessary to bear in mind, when considering this question is that, simultaneously with the Krakatoa eruption, gases and vapours were being emitted from a great number of vents over the earth’s surface—some mere hot springs, from which the quantity of gas issuing, though continuous, is not taken account of; others, volcanoes of every degree of activity and violence, but only receiving attention when their violence is such as to compel observation, but in totality representing a volume of vapour and gas immensely greater than any estimate that can be attempted, since no term of comparison nor any measurement is at our disposal. It may naturally be remarked that I include both gases and vapour, or steam, together, and that, according to the received ideas, the steam was essentially furnished by the sea-water which penetrated to the depths where the explosion originated. ‘This is not, however, by any means proved. It is to be remembered that the amount of water held by the rocks, either chemically or phy- sically, is estimated by Delesse to be much more than that of the ocean, and this water may sometimes be brought into action. But even admitting that all the water ejectcd as steam came originally from the sea, the sudden transformation of such a quantity of water into steam, and the sudden projection of such quantities of it into the air, must have influenced both the sea currents and the atmospheric currents, and in this way merit ‘being taken into consideration. But-in eruptions, along with the steam, or independently of it, gases are most certainly projected into the air. That such were notably present in the Krakatoa eruption is certainly stated by an eye-witness, a captain of one of the vessels which happened to be in the neighbourhood, who says ‘‘the presence of a powerful marsh gas was also easily 26 Scientific Proceedings, Royal Dublin Society. detected.” — Nature, vol. xxix. p. 29. Moreover, from the obser- vations of Fouqué at Santorin, and of St. Claire Deville at Vesuvius, we know that hydrogen occurs as one of the emitted gases. The following is a Table given by Fouqué, p. 227 of his work on Santorin, of the gases collected on the 17th March, 1877, at that place :— I 100 la a aR ras ee es aN ere Th va ae SH Trace 0 CO? 37:04 | 37°24 | 86°42 | 36°60 0:07 1:49 | 78°44 C?H* 0°43 0:47 0°86 0°81 0:71 0:42 0°64 Oars: 0°41 0°51 0:32 1-46 | 21°56 | 18°45 o37 INGE: 35°02 | 83:66 | 32°97 | 32:04 | 76:04 | 79°64 | 87-55 a's 27:10 | 28:12 | 29:48 | 30:09 1°62 0:00 0:00 I.—Taken in fissures. I{.—Taken at the surface of the sea. | It must further be remembered, that very frequently, previous to eruptions of active volcanoes, gases are emitted from the craters and cracks of the voleanoes, and that the emission continues long after the cessation of eruptive activity, and may continue for centuries when the voleano passes into the state of a hot spring. Finally, all over the world, both on land and in the ocean, as has been already remarked, this emission is going on continuously from the active volcanoes, the hot springs, and simple jets of gas, and the daily total of this quantity of gas must be something past all calculation. It may be objected that were there such continuous additions being made to our atmosphere, Science wotld already have ascer- tained the fact by comparative barometric observations. But it must be remembered that such barometric observations should embrace the whole earth’s surface, and have been recorded for a sufficiently long time to allow of any effective comparison—that the observa- O’Rertuy—On Gaseous Products of Great Eruptions. 20 tions made at sea must be limited to a relatively small number of points or zones—that the polarregions must be perhaps for ever closed to observation. Again, the constitution of the upper parts of the atmosphere, above 7 miles = 11,000 m. height, are quite unknown to us, and will probably ever remain so, since no living being can exist at that height. Lastly, that account must be taken of the porosity of the surface rocks and soil, and of the ocean, which can absorb and retain quantities of gases, variable relatively to temperature and pressure. Thus supposing the volume of theatmosphere to be actually doubled by volcanic emission at a given moment, it does not at all follow that the barometer would show that increase of volume in totality and at once, since the pressure on the surface of the earth would cause a certain portion to be taken up by the soil and rocks, and a certain other part by the water. In this respect, indeed, we should perhaps look to the ocean as a far more reliable witness to variations of volume in our atmosphere ; and were the analyses of ocean water sufficiently numerous, both as regards local distribution and depths, and extended over a sufficiently long period of time, they would manifest by changes in the quantities of contained gases much more accurately, and with much more chances of sound comparison, variations in the volume of the atmosphere, than would barometric measurement. Here there is room to remark that the quantity of gases contained in the ocean and other waters must be in intimate relation with their organic life, and that, consequently, the greater or lesser abun- dance of fossils in certain formations must bear some relation to the quantity and nature of the gases contained in the sea in which they were deposited, and these gases were in relation to the volume _ and constitution of the then atmosphere. Thus we have probably, in the fossils of the different formations, real measures of the atmospheres, corresponding to the periods of their deposition. Were it possible to determine directly the gases given forth from any one of the existing active volcanoes, no more valuable scientific work could be attempted, but the difficulties are evidently immense, if not insurmountable, unless in the case of some small volcanic cones, where it might be possible to make such an attempt. But these difficulties only enhance the value of all measurements and determinations of the emissions of gaseous hot springs and 28 Scientific Proceedings, Royal Dublin Society. cold springs, which may be considered as bearing some relation to the total voleanie activity. The oil-springs of America and of the Caspian must be con- sidered as coming into this category, since, by their constitution, they are akin to certain of the gases which accompany volcanic action, and nothing yet absolutely proves their organic action. With this continuous emission of gases and steam must in some way be connected the slow movements of the earth’s surface, which are now being more attentively studied than had been the case; and did we posses sufficient data in respect of these emissions in toto, it might be possible to foresee the recurrence of volcanic eruptions, or of earthquakes, and of disturbances of the earth’s surface. Still more important is the bearing of this total emission of gases and vapour on the question of the radiation of earth heat into space. As the points from which the gases come are certainly situated at relatively great depths, and in the case of such eruptions as that of Krakatoa most certainly at a very great depth, the surface radiations must be considered as forming part of a total radiation, some terms of which correspond to points deep in the interior of the earth. That the seat of the great explosion of Krakatoa was very deep may be inferred from at least two facts—the one, that the ‘ recoil’”’ (to use the expression) of the explosion was felt at or near the antipod of that point, as observed by Monsieur Forel in Nature, March 26, 1885. He states that underground noises were heard at Caiman-Brac, in the Caribbean Sea, in August, 1883, contemporaneously with the eruption, the exact antipod of Krakatoa being the middle of the State of Colombia, on the Magdalena river, between the towns of Antigua and Tunja. _ Another fact which would lead one to infer that the seat of the explosion lay very deep was, that the island was split according to an east-to-west direction, so that the whole northern part became detached, and sank to a depth of 200 m., or more. “Inthe place where the fallen part of Krakatoa once stood there is now every- where deep sea, generally 200 m.—in some places even more than 300m.deep” (Nature, vol.xxx. p.12). Now this splitting in an east- to-west direction may perhaps be considered as the result of the lateral pressure and intense friction of the solid matter, when being ejected, against the west side of the vent, since coming from a O’Remty—On Gaseous Products of Great Eruptions. 29 great depth, and having only the initial angular velocity corre- sponding to that depth, it should lag more and more as it rose to the surface of emission. This lateral pressure and friction would, to a certain extent, explain the comminution of the lava, and the formation of the very fine dust. That Krakatoa, and indeed the whole of Java, having for antipod the north-western coast of South America, must in like manner, to some extent, feel the “‘recoil”’ of eruptions and earth- quake shocks happening in the latter localities, may be expected, since we have here the occurrence of the exceptional case of land having for antipod land, and as can be seen at a glance of the map exhibited, showing the antipodes of the countries of the Hastern Hemisphere, South America, and part of Asia correspond in a very remarkable manner, while at the same time they represent the most active seats of volcanic and earthquake action. Were the soundings of the ocean and our bathymetrical maps complete in this respect, and could these soundings be verified periodically, it would perhaps be found that, corresponding to the volcanic and earthquake actions which take place in one hemisphere, move- ments of the bottom of the ocean take place in the opposite hemi- sphere, and that thus the deformations resulting from a continual contraction are being balanced, so as to maintain the uniformity of the earth’s movement. There is one last point relative to the great eruption to which I venture to call attention; it is that of the periodicity of such great outbursts. One of the remarks made relative to Krakatoa in the article of Nature already referred to, vol. xxx. p. 10, is, that the volcanoes of the Straits of Sunda had been in a state of quietude during 200 years, and that during the latter years a great many earth- quakes took place along the fissure on which they are situated. Now, in the same vol., p. 435, is a very interesting article on the frequency of earthquakes in Japan, It is stated that the Japanese have attempted to prove that earthquakes run in well-defined cycles, a by no means novel or very modern idea. Wernich, in his Geographische Medicinische Studien, says “that severe earthquakes occur in Japan every 20 years.” The Japanese journals, working on records relative to the period included between the dates 30 Scientific Proceedings, Royal Dublin Society. A.D. 628 and a.p. 886, have divided it into 26 periods of 10 years, between which the following intervals occur :— 40 years between the 2nd and 6th, COte i da oy Aida. 40 ,; i thy Sy llothe 40 ,, a NGthin es, 20th 40 ,, i 20th Zande and from ‘the author’s explanatory notes a still more correct table can be deduced, by means of which the cycle of earthquake intensity is finally put at 33°3 years, or 38 x 11:1, that about three times the sun-spot cycle (Lockyer gives 10 years; Flammarion 112). A further deduction is made, that earthquakes of a disastrous nature occur once every 59 years, so that the next great catastrophe may be expected in 1913. Now it will be remarked that the interval of 200 years of rest mentioned for Krakatoa so far corresponds to a multiple of the short period of 10 years, adopted as interval of groups, represent- ing also the period of sun-spots. | Admitting that the earth were once in a state somewhat as 1s now the sun, may it not have had in a similar manner a recurrence of phenomena such as the sun-spots, and may not this recurrence be still observable in the existence of a period or cycle in volcanic and earthquake action? When working at the Catalogue of European earthquakes which I submitted to the Royal Irish Academy last April, I noted a recurrence of a period or interval of 10 years in many cases, but so exceptionally that I could not point to it as a law; however, a further examination of the data existing may be more conclusive in this respect. [-—) 31] IV.—ON A NEW SPECIES OF OROPHOCRINUS (PENTRE- MITES), IN CARBONIFEROUS LIMESTONE, COUNTY DUBLIN. ALSO REMARKS UPON CODASTER TRI- LOBATUS (M‘COY), FROM CARBONIFEROUS LIME- STONE, COUNTY KILKENNY. By WILLIAM HELLIER BAILY, F.L.8., Htc. (Prats 1.) (Read, February 16, 1885. ] ORoPHOcRINUS (PENTREMITES) PRELONGUS (n.8.) : This Blastoid is remarkable for its size and elongated charac- ter, compared with others of the genus. Its general outline is that of a lanceolate body (calyx), with a pentagonal summit, its greatest diameter being at the termination of the ambulacra eight-tenths of an inch from the summit, decreas- ing regularly towards the base and terminating obtusely, without any trace of stem. The basal plates, conical in shape, extend upwards to about one-third of its length, measuring nine-tenths by seven-tenths of an inch; the radial plates are oblong, one inch and a-half by three- quarters of an inch at the widest part; the deltoid plates are small and triangular, extending only to about three-tenths of an inch from the summit, the five plates forming a pentagon when viewed from above. : The ambulacra are narrower than in O. inflatus; the small plates composing each are arranged in two alternating series, with a deep groove down the centre, and are inclined towards each other at an angle of about 15°; there are sixteen of these plates in the space of a quarter of an inch. The mouth, which was small and central, and ovarian apertures are not sufficiently well shown for description. Length, two inches and five-tenths; breadth at widest part, one inch and six-tenths. Plate 1., figs. 1, la, 2, 2a, 2. Localities.—St. Doolagh’s and Raheny, Co. Dublin, in fouee carboniferous limestone; collection, Geological Survey of Ireland. 32 Scientific Proceedings, Royal Dublin Society. CoDASTER TRILOBATUS AND acuTus, M‘Coy: Of this genus (belonging to the same class of Hchinodermata, the Blastoidea), established by M‘Coy under the above name,’ he describes two species which appear to be identical. Some years ago I was fortunate enough to collect several well- preserved specimens of this fossil, which I refer to C. trilobatus, as indicative of the most usual form, resembling very much that of a hazel nut, although there are gradations between both that and the variety M‘Coy has figured under the name of C. acutus. As I believe it has never yet been recorded from Ireland, I now bring it before the notice of this Society. Our specimens were obtained from shales between the carboni- ferous limestone at an old quarry at Lisdowney, near Ballyragget, county Kilkenny; collection, Geological Survey of Ireland. Its locality in England is stated in the Synopsis to be Bolland, Derbyshire. Plate 1., figs. 3, 4, 4a, 48, 5, 5a. NOTE ADDED IN THE PRESS. Since this Paper was read, Messrs. P. Herbert Carpenter and Robert Etheridge, Junior, who are studying the subject, requested a loan of the specimens, which, at their request, were submitted to them for their examination. Although agreeing with me that figs. 1, la represent a new species (Pentremites prelongus), they consider the form represented on figs. 2 and 2a as a different species (Orophocrinus pen- tangularis, Miller sp.). 1 Synopsis of British Paleozoic Fossils, 1885, pp. 122, 123, pl. 3p, figs. 7, 8; Ann. and Mag. Nat. Hist., 2nd series, 1849, vol. iii. 251. Batty—On a New Species of Pentremite, &c. 33 EXPLANATION OF PLATE I. Fig. 1.—Orophocrinus (Pentremites) prelongus, Baily. Lateral view, -, AID, <1 Ya =D Oy 9 Ao IDO, a4 | Pol Doe s, 45 De, > 4 ID e. », 48.—Do. 5 b> SD. 3) OA. Do. natural size, from carboniferous limestone, St. Doolagh’s, Dublin. do. Section of ditto. do. Natural size, carboniferous limestone, Raheny, Dublin. do. Natural size, view of the summit. do. Portion of ambulacral area enlarged three dia- meters. 3. —Codaster trilobatus, M‘Coy. Lateral view, natural size. do. var. acutus, M‘Coy. Lateral view, natural size. do. do. Ventral surface of same, showing pen- tagonal mouth and ovate anal aper- ture, natural size. do. do. One of the ambulacral areas of same, showing perforated plates, and in- termediate jointed ridges, enlarged four diameters. do. do. Small ovate specimen, natural size.. do. do. Basal view of same, natural size, show- ing convex central disk perforated for attachment of stem. Figs. 3, 4, and 5 from specimens obtained in shales of lower carboni- ferous limestone, Lisdowney, near_ Ballyragget, county Kil- kenny. SCIEN. PROC. VOL. V. PT. I. Scientific Proceedings, Royal Dublin Society. 34 “ULIUOAR(T TOMO 917} Jo syueTvAmbe oyy ‘sdey -10d “10 ‘SUvIIN[Ig oy} pur (sueLmjrg-or1queg) SULIOIAOPIQ OY} WooMyoq .,Spoq-asessed,, 01} ‘qxued ur 4svo je ‘A[quqoad ore spoq yore oY, *(SUBLINTIG-o1qmLD) sMBIOTAOPICQ, OT} 0} Suojaq Ajqeqord e1om Aoyy Fr se savedde 41 ynq ‘suet “NITY oY} UL spoq [Nvoseuy oy} papnypout osye soyne “SUBIINTIG 9y} JO speq zoddn jo yred wv ore pue ‘speq 9[surq oy} Fo sjuereAmmbe oy} ore Ayqeqord ,, “ouojspueg poy pO 12407 ,, sv passeyo ‘eddy snosoeuere pat oy} JO syoor 9y} orOTLAL -os[q “Auer, pur ‘puvysy orry9 “Ysainqstno'T qe ‘Avg morQ qnoqe ‘okvyy Ayun0o og} ur pue * SOLIOS STP CAVITY ‘Aitey Teuag ‘yI0Q “AA “9 —! SOT}I[VOOT YS] SUIMOT[OF oY} UL punoyz AyUO Ajqeqord ore ,,spaq-aSessed ,, os94} 10 soa eyues -o1der oT, “ShOseJTUOGIeD oT} puL suLTINITG oy weeMjoq spoq-esessed oy} ‘a2 ‘(saynr) ouoyspueg POW PIO SY} JUL sprvmdn oyenpeis sys yes “UTD PUL, ‘SIS FuvsuepyH oy} Ur saying Jo euoz y | pue ouojspueg poy pio 1aA0T ‘SHUVWAYY " * -‘seuToyspueg [pTAvy “wagqmgy “(4) OTH AA “dagng ‘(4) MOTPN'T ‘UVIUOAGTT JOMOT pur suoJspuLY pe PIO JeaoT ‘UBIMOAO(] IOMO'T “SINHTIVAINOW HSITOND * “speq sorted e ‘gpeq 8A0D 10911107 soe ‘speq UljTeMYysvorg as * ‘speq e[Surg ‘ATO | ‘sys Quesuapy | °° ees ‘y109 “SHILITVOOTT ‘SdN0UX) HSIUT ‘(ANOLSGNVG GG GIQ ALMOTT “0 SNVINOATCL buspnzou:) SNVIUNTIG ‘Lesst ‘st Avy ‘peoyy] ‘OLE “VIN ‘NVHVNIN AUNHH “9 4d ‘SLNAIVAINOG HSTIONG WIAVAOUd YIAHL HIIM ‘SHOOU O1OZOWIVd UNMOT HSIUI AHL JO aTaVE Vices 66 30 Paleozoic Rocks, &e. h Lower ds Ir KinauHan—On the *‘posodxo speq yuseq oy} A[UQ “vere suTeZUNOTT euoyUY oy} JO yZLou oy} 0} Yoyed SutAyno uy *snoroypissog ATqeqord ere seuojseTuT] 94} JO ouMlos ‘ sezLING JO seuoz OY sdeysed 10 ‘aug “SLING FO OU0Z BV UTL]MOO OS[e OSOTT, ‘okey pue ‘Avmyey ‘Array ‘yION Jo syoor oy} 0} Iv[IUIIS soylINy JO ouoz vst wey UT “sedAy doperIeDg Jo ere “ToAaMOT ‘toy, Jo Moz ve $adhy yootue A, pue AreAopuryy jo Arpedroursd sptssoy SULUTE}WOD SHOOT o1v ssVU Iv[MOTUOT v sv THON} TO9AJOqd UL SUIMIOD ynq ‘somoJspurg pey PIO IOMO'T ore ‘ATTVoTSOTOTIT ‘syoor ayy ‘eAoqe pus AojOG sodA} MOTpUT jo omos WIM ‘sedAy yoopuo A, fo ATedrourtd ere Aoy} ‘suop pur ‘Adojueg ‘epriqiry ye ‘uozTI OY [VOIsO[OIS olMLS OY} WO 4nq ‘pleAqsve oTITLAL ‘sodAq Aroaopueyy Fo ATpedroursd ore s[issoz oy} ‘IOJCMYOV[Y OY} PUL UNLLMOD 4v “pAvA4seM OT} OT, ‘sod.43 oopered Jo are s[Issoy oy YOIA Ul SUZ B SI O1OY} SOTIOS YON YSno'Ty oy} uy ad Ay AroAopueyy raddq we fo oq 0} uospraAeg Aq pres SI [IssOF sHOLoUINU 4s0u OTT, ‘saddy ooprrey fo sTissoy Surureyu00 SYOOL JI YIM pajvroosse SurAey IofZ o[qeyreu -o1 st sdnoxs aseq} JO oseq oY} wet 10 4e ouOZ W (6 a6 66 "UBIMOAO(T IOMO'T IO OUOJSpULG poy PIO AOT (3) AteAop “UCT pues ULIMOADG, IoAOTT IO euojspuBeg Pry PIO TOMOT 66 66 66 “UBTUOAR(T IOMO'T IO eUOJspuYg pay P[O TeMOT "yooTua AA pus ‘AroAopuvyy geddq ‘uvmoAeq = aoMOT ‘ouUO}SpUBG pay plo wAOT er 3100] *sprssox AraAopuryy seddq ° ° ° ° ° ° "(3) Moppr'yT "UBIMOAO(T IOMOTT PUB OULO}spuBy Psy PIO 1eMO'T *AIOA -opusry seddq pue yoopuo \\ ‘eyBIOMO| U0 UNpueysnyD ‘JOITISTP UMOJSIOMBICy ‘spoq UleyUNOT, vu0jUT,T * » ‘speq oqueystaniq “‘speq UreyUNOT, ASTM) * ‘Solos TeeLIOpByseT[ eg, ‘geL19S Suop puv ‘oprrqiry ‘mnepAoy ‘SOLIOS O}LING OT} U}TM soltes yon YsnoyT ‘Joq¥[S Yoorpeg ‘sdnois Apvoyeusi0oy, pue vorljoayy * - + ‘dnoxrd unsqunesser9 ‘speq 66 ce > ‘onyuy ‘fazepuopuo'y 66 (5 ‘10481, nog pur qSneuu0y 48ve-T]}10\y 2 66 3 66 ce cs ‘KB MTCH) 49OAL-YIO NT Proceedings of the Royal Dublin Society. 36 “IOISUN], PUL I9}SUIET UT SOLIS IOMOT PUL o[pprut 94} FO SYOor oy} FO syuoTvAtnbe oy} oq 0} tvedde Aoy} nq “porejpe sso] 10 oaotH o1e syOOL osoy} [TW ‘sadAy AroAopuryy asddg fo oq 0} pres o18 swos YSnoyye ‘edd, vieq-oopereg fo oq 0} avodde spissoy fo ATqmosse [e1oues OTT, *sodAy vpeg-oopwrey fo ore ‘TaAoMOY ‘MOT @ ‘sed4y eoptepuvpy yo Ayedreutad o1v spissofz ou, “sedA} oojlepuryy jo STISSOF o1e O10} soleys Hovyq oyvurproqns ouos ur ynq ‘sodéq elvg-oopereg yo orev pur ‘dnoid appr oy} 0} peuyuoo ore Ajatos AjTrvau spits “SOF OY, “dnowh umojzunog 94} 10 saqnjgy uaety pun pay sanoT oy3 pure ‘dnowh syoos-aaydnag Io appiyy 943 ‘dnowb amganayg 10 ajnjgy waaly pun poy waddQ oy} oyUt paptArpqns oq Avut os0TJ, -sodAq Araaopuryy saddgq fo Auojoo @ way) Ut St ereq} ‘are[D Ayun0d “avoATTEg ye yng ‘soedAq oopearey jo Ayjedroutsd ore s[tssox ou, *‘SHUVNGY e ° ° ° ° ° “90 [lopueyT “QO[LopuLyy] puL vegq-ooperen “BTBY-IOpeClVyg “ao[fepueyT “e[eg -o0pBred “00p -vreg pue ATeAOpUBTT TOMOT “SINATVAINOY HSITONG * ‘sores YSnO[oo ‘get1es yormyed -Ysv0lg §=pue woeTpnute9j0"7 oe Remsen ‘spoq [neoseuy * BOLIES OTBYG YLVC 10 1aMory ‘setaos AouowATTeG 10 9TPPIPL * ‘oheyy > ‘okey pue Avapey ‘ALIOYT ‘Solos WIT PASTY 10 reddq } *‘aojsunpl pue 10}suteT “SdNOUy) HSIUT “NVIPNATIQ-OUENV’) 10 NVIOIAOGUGC, *SHILITYOO'T a” Kinanan—On the Irish Lower Paleozoic Rocks, &¢. “SOLIOS qoddn oy} JO syoor oy} sv uwozttoy ous oq} uo ATqeqord ore ‘Tesouog Ayun0d 04 Jo YNOs OY} Ul sv ‘sIeqjo Ing -1oJSUN PL pure x0ysuTATT TO SOMOS LOMOT PUL O[PprIUA Oy} Fo esoy} sv uOZTIOY [eoTs00es ouLes 94} UO oq 0} avodde uray} Jo eumos ‘ posoydiomrejamt ssoy 10 10m [Te oe SsyOI osoqy, ‘sortes AoLoMIOg OT} JO Syoor oy} Tey} WozTLoY Laaoy ATWYST]S v uo oq 07 avodde osoqy, ‘saddy Area ~OpUL['T LOMOT Fo oxo oq 0} Wey} poLoprIsuod SLY UOJSUBMG “AA Jnq ‘eddy dopvaeg ve fo ox0UL *AIoAOp “UCT ]T IeMOT IO ou0\spues TyAvy, yxed ut sdeysog “OO[ApuUL[T puvw v[eg-oopereg ° ° ° 2 ° ° ° “dOpRIeyD *9ml0]8 -pues TuAemw wed ut 20 ° ‘esouog pue ‘Arzrep ss + + + + | -wopuoy ‘mosh 7, W107 * ‘solos AMUTTOGsTIT | ° © © © ‘GY8vuriuzaT Proceedings of the Royal Dublin Society. 38 IO 9[pprur ey} Jo syueTeAmmbe eyy oq Avia Aoyy yey epqissod se ojyimb st 41 ynq ‘dnors Stusty ey} Jo sjyuepeaAmnbe oy} eq Avm oq} ATqQIssog -jeanjoefuod ajinb st oSv mey} pue ‘emmsodxe : SuIATJNO poyoujop poyepost uv sv twodde syoor eseyy, | * ° * ° ° (4) dnors Sraory | ‘sortes (ueexepeqserpeq) eSiny "poyses.ons weeq svy sv ‘suBIUOINYT OT} FO syueTeAIMbe ore ia Be Aoyy yer} opqeqorduar Axoa st 31 4nq {suvliqmeg ey} JO woyrod v jo szueyeaAmmbe ore ATqeqoad Aoyy ‘sueroraoprg oy} Jo uorys0d v Jo syusTeatnbe ey} ATJUeprAe ore YoryA ‘syd01 payeroosse oy} ULYY Iopjo ore Ao FT *O.M} OY} TOOMJoq 4STXE 07 sulees 10 poAord weaq sey AqITIqvIMIOFUOOUN ou 4a ‘ STOATOSO JUIDEI OO puB YWILD Aq wsy} ug} IOp[O eq 0} potepisuod o1EM pu ‘SHOOK pozvto -OSSB OY} ULY} polo}[e ALOU Yon ole syooreseyy, | ° ° ° ° * *(4) suUBIIquIeD ‘sores puopy sii | ° ° ‘okey 4SOM-YIION “‘suvLIqmUD Surf] -Iapun oY} pue sstuery oy} JO syueTeAmmba oy} ‘ose ‘etquqord ore ‘wiley UL UOIIUMeYLOUL TL pue ‘okey ur y10djsoAy uoomyoq ‘esuer ure} -UNOP XO OY} UI M990 YOTYM syoor eps sso] IO 910M 1OyIQ ‘“posoydiowvjeu ssey 10 oL0Ul [Te ie ‘roAemoy ‘Aoq} ‘sueriqmieg Surdy1epun oy} yo uonsod e pue dnois stuery ey} Fo ywoyeAmMba 84} OG JSNUL (SoItes Ysno[oog) speq soptepury'yT ey} JO sJUeTBAINDe UMOUY oy} MOTEq vyeIYS JO SSOUYOLY} JVOIS OY} VIVMGUUOD UT “AouTay LOA "(2 reddy) suermqureg ° ‘SoTIOs AAO] BIBTIOTUOD -ING [BOISOT[OOH OY} UL WOATS WOT}OES 94} FO Q 07 T ‘SO1109 OLOULIOY ‘mIitery puv "SON Sdno1s 04} opnour solies JeMoy vIeMaUUOD ey, | ° ° ° * ° ‘dnoas Suery | -jory oy} puv oxAyworpy qeery | ‘oStig ‘odey_ ‘Avmrey “SMUVNE YY “SENDIVAINOW HSITONG “SdNOUx) HSIUT *SaILITVOO'T ‘(SdUd-aDVSSV) ANOUH OINGIW 077 bupnjow ‘sNVIMaNVD 39 Kinanan—On the Irish Lower Palwozoic Rocks, &e. “STOY}ZO OY} UL} YZa.19S~p ‘CQ 0} pore or0ul Peuloes PUNOF sfissoF OY} JoOI4SIp MouUBg oy4 UL OyTYy A “unbrjzwn *(¢ Jo sqtq MOF BOVE a10qy soovyd 104}0 UL YSnoyye ‘vyvypys ‘¢Q st yuepunqe osowE ©} MYST o10Tye) oy} Ur § mpa1as~p ‘CQ ATTwIOUES SI ULIOF 04} dnoxs yoreD oy} ut : JuBpuNnge ATeoo] ore yore pur mnbyuv -¢ qoq poy Avrg ut ‘ punoy ueeq sey ATuO onbuun ‘GQ dnois ‘sdnois Mou GAO 94} Ul ‘syo0r oseyy Fo OTISTIEjOVIVTTO -ueg pue ‘arosurey ‘or0yep “pqOFxXO Ay OI vja0sIp “Q pue “nmpns GQ ‘wnbigup DUDYypIgQ |"* ° ° “SUVITGUBD TOMOT | “Fore ‘peexT Avig ‘{}M0F | pur ‘MOPPOLM “UITqnG “ATG *VUIOFTOOUN WB IO yNBT v toyyIe Aq suLIoTAOpIQ popeToosse O44 wWorF poyeredes oq 0} moos Loy], ‘SULIIQUBD eq yYstut Aoy} yey} poysesSny 400.7 ‘syoor peoy Avrg ay} 04 SOUGHT MONO Demme WO) fe Ou Neg) O° OO poet] aM) | 0 0 ‘prloysuoTy “WOT; UL punog Used oAvY 4oA SB sTISSOF ON ‘o8e rey} oq A\qrssod 44 Stun Yons jvy} poysosSns zo£o Nn yuNOVOR Yory.A uo ‘SUBIIQUIBD “AM OTOT AA Ayunoo ‘proxy Avag 04} ox] oe yoodse Wp PERCE | 22 9 SOO 8 (hintaan || Sd 8 RINNE GD) | Fo 9) UMO ‘peaoid Ayr10zovsyes ueeq 4ou sey Wons peropisuoo oq 0} wrefo arey} yoh se ynq > AeMyey Jo Sury - A “tq Aq punog ox0.a sptssoz DEPTAOPIO ay} JO owos oy] sSuryxwm omosqo UY} UT =«—suvLIqme) SurAyjzepun oy} Jo ous FO Wedd 10 ‘sdno1s Stusry oy Jo soatyeiuosorder aq} oq Avtar wey Jo otmog ATqissog ‘erqeqoaduat : eq 0} sulees “toAoMoy ‘sI) {aSev UBIyUEINVT Fo ATqissod aq 03 soxnp Aq poysesSns ueeq oavy yey SyOI Orv Tedouog Ayun00 oy} Fo USP AOU! MELUGT 02 OO Uh atacand Story | ° ‘UBUaLOVUTYy pus ysvpsog > + Seseuoq "(semovaopug) setres Aorew0g OT} JO SPOOL poyzeroosse oy} uvy} s0pro youu ere Loy opr ‘dnosg STUSLY ot} FO Saat eyuOs -a1dex oy} eq 0} poraprsuoo dav pra ‘Kempen ; ommpr Tn LE a ee A Sod Gee Jj 2a Sl pprok bared « VI.—ON THE OCCURRENCE OF AN OUTLYING MASS OF SUP- POSED LOWER OLD RED SANDSTONE AND CONGLO- MERATE IN THE PROMONTORY OF FANAD, COUNTY DONEGAL. By EDWARD HULL, LL.D., F.R.8., Director of the Geological Survey of Ireland. [ Read, December 16, 1885. | Tue district where this mass occurs lies between Lough Swilly and Mulroy Bay, and is formed chiefly of metamorphic beds of quartz- ite, schist, trap, and crystalline limestone.- The tract of Lower Old Red Sandstone lies along the northern base of the Glenalla Hills, rising into a high ridge of quartzite, &c., which strikes across the promontory in a N.H. and 8.W. direction, and attains to an eleva- tion of 1,196 feet. The beds of sandstone and conglomerate are let down by a large fault against the older rocks, and form a'low, rocky tract, lying for about two miles along the northern base of the mountain, and were recognized by the officers of the Geological Survey when engaged in that district during the summer of this year. They consist of alternating beds of reddish soft sandstone, generally pebbly, and often forming massive conglomerates, with large blocks of quartzite, schist, limestone, and trap. The dip of the beds is 8.8.E., or towards the base of the quartz- ite ridge; and, measured across the strike, the mass is one-quarter of a mile across, and the estimated thickness is about 800 feet. Red shales, and flaggy sandstones also occur, and are seen resting unconformably on the quartzite beds of the metamorphic series. From the general resemblance of these beds to those referable to the age of the Lower Old Red Sandstone in the district of Omagh and Dromore to the south, as also on the coast of Antrim and Scotland in an easterly direction, I am disposed to refer them to this formation, rather than to one of a more recent period, such as the Carboniferous; but in the absence of fossils and the entirely isolated position of the beds, the question of their geological age must remain somewhat indeterminate. They seem to have been formed within the limits of a basin separated from any of the other basins of Lower Old Red Sandstone either in Ireland or Scotland, and will prove a new feature in the Geological Map of Ireland. ye se VII.—_ON A METHOD OF DETERMINING THE SPECIFIC GRAVITY OF SMALL QUANTITIES OF DENSE OR POROUS BODIES. By J. JOLY, B.E., Assistant to the Professor of Civil Engineering, Trinity College, Dublin. Read, January 20, 1886. y v, A muTHOD of determining the specific gravity of a small quantity of a heavy mineral is often a desideratum in the course of inquiries into the composition of rocks, sands, volcanic ash, &e. The mineralogist is indeed frequently called upon to determine the nature of minerals distributed ,but sparsely throughout his specimen, or even when abundant—from the intimateness of their intermixture with other substances—only procurable in very small fragments, and, except with the expenditure of much time and labour, in very small quantities.; The same case arises when it is not desirable to deface an implanted specimen of rare beauty of form. Finally, the chemist is often called upon to determine the physical properties of minute quantities of matter, as in the case of the rare elements. Whether as a characteristic for discrimination, or as a physical property to be placed on record, the quality of specific gravity is of sufficient importance to justify me in calling your attention to amethod of determining it, specially applicable for dealing with small quantities of very dense bodies, and also with small quanti- ties of porous, fibrous, or very cleavable bodies. The method,now in general use for the micro-determination of the specific gravities of silicates, &., of low density is by balancing in a liquid of a specific gravity, adjustable to that of the specimen, and subsequently determining the density of the solution em- ployed. This method fails altogether— (a) When the substance has a specific gravity—over four. (0) When the substance is of a porous nature. In the first case the method fails, for want of a liquid of sufficient density to equilibrate the solid. Indeed we cannot E SCIEN. PROC., R.D.S., VOL. V. PT. II. 42 Scientific Proceedings, Royal Dublin Society. readily extend the method above the specific gravity 2:77, that of Thoulet’s solution (the mutually-saturated solutions of biniodide of mercury and iodide of potassium). The solutions necessary to extend the range above this are either costly or difficult to work with: some can only be used by maintaining them at a high temperature (as lead chloride at 400° C.). In any case the range of density hardly passes that of garnet, 3-4 —- 4:3, and [ am not aware of any other published method of dealing with small frag- ments of minerals of a specific gravity exceeding this. In short, if a few milligrams of any of the host of minerals ranging above 4-5 in density—about 90 per cent. of the unsilicated mineral species—be presented to the ano 8 he is unable to deter- mine this eharacteristic. In the second case—the case of porous bodies—the impossi- bility of freeing the body from contained air, when immersed in liquids of the nature of those to which we are restricted, renders the method fallacious. ‘The air-pump or the application of heat. will generally be found of little avail. In this case we must again seek a large quantity of the substance, so that we may be able to weigh it in a liquid of low-surface tension, or of a ‘ creeping’ nature, such as turpentine or alcohol. Small quantities cannot be dealt with. The method to be now described enables the specific gravity of substances to be determined under both these conditions—that is, whatever their density or whatever their state of aggregation—in extremely minute quantities, with an accuracy limited only by the sensitiveness of the chemical balance, and by the aid of solutions of a density varying from about that of water to say twice that of water: but this is under our own control. Unfortunately, it is inapplicable to the purpose of effecting the separation of bodies of different specific gravities. Briefly, the theory of the method is as follows :—The mineral by itself will not foat in any known solution, suppose. If, how- ever, we mix it with another substance of much lower specific gravity, there is easily found such a proportion for the constituents as will enable the mixed bodies to be equilibrated by dilution of the specific gravity liquid. We may, in short, adjust the specitic gravity of the mixed substances to be as close to that of either of them as we please. Joty—On a Method of Determining Specific Gravity. 43 We require to know— W the weight of the mineral, w . ap » buoyant substance, o » sp. gr. ,, buoyant substance, s Be Re », mixed substances, in order to determine S, the specific gravity required. Then, as ih iy di weight P- Br volume’ W . Wiw w are hae Wes o PG Gio) aH By this means, then, we can evidently deal theoretically with bodies of any specific gravity; and, further, if for the buoyant substance we chose one which, when brought to a liquid state, will creep into and surround the substance, we may evidently be inde- pendent of conditions of aggregation, and all trouble with con- tained air, or bubbles adhering to the surface of a rough fragment, avoided. How the method is practically carried out I now proceed to describe. The specific gravity of a piece of translucent, homogeneous paraffin, free from bubbles, is taken by any of the ordinary methods—weighing in water with a sinker, or balancing in a. mixture of alcohol and water, and then determining the density of the solution. The value found is what I called o above, the specific gravity of the buoyant substance. There is no better paraffin for our purpose than that sold in the form of candles; nor do I see any reason to seek any other substance. It fulfils all requirements, its penetrativeness when melted and its trans- lucency when solid leave nothing to be desired. K 2 44 Scientific Proceedings, Royal Dublin Society. From this piece of paraffin a little disk-shaped piece—about 3 or 4 mms. in diameter, and 1°5 mm. thick—is cut with a sharp knife, cleanly paired and smoothed on the edges by gently rubbing between the fingers. The disk is larger or smaller according to the quantity of mineral at our disposal, and if great accuracy be desired we determine its specific gravity, thus avoiding any assumption as to the homogeneousness of the piece from which it is cut. There will be in general, however, no need of doing so: thus compare the two following specific gravities obtained—(1) on a piece of paraffin weighing over 11 grms.; (2) on a little disk removed from this, and weighing about °04 gram. (2) was deter- mined’ by balancing in dilute alcohol :— (1) 0:9204 (2) 0-9208 An inappreciable difference of specific gravity. The disk removed is next weighed in a delicate balance. If: as small as described above, the balance should read definitely to 0-2 mgr. Its weight is w in the equation. It is in all cases manipulated by use of a clean ivory forceps. If very minute it is weighed on a tarred watch-glass, and so need not be manipulated at all after preparation. Removed from the balance, the small frag- ment (or fragments) of mineral is placed upon the surface of the disk. The extremity of a slip of copper, about 5 mms. wide, is now heated in a smokeless flame—it is better to use a little copper ball, drilled and fitted on to a fine steel knitting-needle—and held above the fragment of mineral, care being taken not to approach it so closely as to endanger the paraffin being volatilized or of its being melted so far as to risk loss by running over. Preferably the disk of paraffin should rest on a piece of wet filter paper, or on an anvil of clean copper; this will keep the lower surface cool. In point of fact, the mineral in general absorbing heat more freely than the paraffin, melts the paraffin beneath it by conductivity, and there is little risk of loss. The heating is continued till the mineral is seen to be completely soaked with the paraffin—every erack and cranny is then filled, the paraffin welling up and swallowing the specimen and expelling all trace of air. Joty—On a Method of Determining Specific Gravity. 45 _ When cold it is placed in the balance and weighed. By sub- tracting w from the weight found, we have W, the weight of the mineral. There is probably no loss of paraffin in this process. Thus it will be found that if such a pellet be very carefully balanced in a solution, removed, dried, and melted on the hitherto unaltered face of the disk, and then replaced in the solution, there is, if anything, a slight decrease of density ; on complete cooling this decrease is inappreciable. The pellet is now dropped into a specific gravity solution. A saturated solution of common salt and water (sp. gr. about 1:2) will in many cases be found sufficient to float it. If so, we have merely to adjust by adding water. Otherwise we resort to Thoulet’s solution (“ Minéralogie Micrographique”’, Fouqué et Lévy, p. 118). I have prepared no pellets approaching this density—2:77— but I prefer the use of this solution in all cases; it seems to con- centrate less rapidly by evaporation, and is more “creepy”. It should be preserved and reconcentrated by evaporation after use. In this operation of balancing it is advisable to use a camel’s hair-brush for stirring, and also for conveying small quantities of liquid when finally adjusting—a process of much delicacy. The brush is also used for removing bubbles from the pellet, which, however, will be found to give little trouble if the solutions be previously boiled to expel air. If the mixed solutions containing the pellet be left standing for some hours before finally adjusting, ‘it will be found on examination with a lens that bubbles will no longer gather on the paraffin. Should it be desired to preserve the adjusted solution for any little time, the final adjustment should be effected in a stoppered bottle, otherwise concentration will occur in a very short time on exposure to the air. The last operation is finding the specific gravity of this solution, which gives us s in the formula. ‘This is most accurately done in a Sprengel tube, holding about 5 ces.; the bottle may also be used. The following Table records the results of ten experiments, made in verification of the method. I have altogether made ‘but twelve experiments—one was spoiled by overheating and losing some of the paraffin by overflow; the other by inadvertently touching with the heater, and thus drawing off a little paraftin. 46 Scientific Proceedings, Royal Dublin Society. I went through with these experiments, and obtained results revealing sensibly the loss of buoyant material. Thanks to the translucency of the paraffin we are able to examine minutely the appearance and condition of the mineral when imbedded. J have here under the microscope the pellets made up for these experiments. If you will examine with this 1” objective the appearance presented by the gold of experiment 7, of the cuprite of experiment 10, you will obtain some notion of the efficacy of the melted paraflin to penetrate and surround loose and dendritic bodies. The fragment of cuprite is about twice the size of a pin’s head; it is a maze of little exquisite octahedrons, — deep blood-red in colour, and with fine translucency. Around it the disk of paraffin is uniformly translucent; through it the paraffin has permeated completely, not a crack or bubble visible. Similarly, the gold seems not less perfectly embalmed beneath its silvery veil—free from any visible blemish to mar the accuracy with which we measure its volume. Of experiments 4 and 9 it is interesting, perhaps, to note that 4 was undertaken with the notion that the mineral being dealt with was barite. Its weight, as a hand specimen, was deceptive, it being penetrated by sphalerite. On getting the result (2°78) it was concluded that an oversight had been made somewhere in the measurements, and experiment 5 was undertaken; this giving 2°77, the specimen was appealed to. Tests then showed it to be calcite. I have thought well to include in the Table some of the quanti- ties obtained in working the formula, as bearing on the scale on which the experiments have been made. It is evident that the method can be applied on a much smaller scale still. -u0d fyouseu Aq pozervdeg ‘aTqvavepo pue asooy A190 A. ‘o[qvave o pue asooy A104 “pozrypeyshio § OTIpUO(T “Sg 8B uow1oads owes WOL "poztyyeysAr9 TT AA “Asso org (Cuyqng op “weqtnowey 9) "p 8B uatiroads OWes MOLY “Poyerpoy (“OTOL AA *09) -suoyysaedAy surey ("Ysy vozexeryy) } (‘urquq *09) “SNOILVAUASEO 0669-1 1420-0 | 1400-0 169-1 8920-0 | 2800-0 1968-1 T¥¥0-0 | 6800-0 (miog) | 9128-1 ZZE0-0 | Z0Z00-0 160-1 GhF0-0 | 6400-0 1968-1 1190-0 | 9&200-0 LEGT-1 1980-0 | 1%¢00-0 1981-1 $990-0 | 61400-0 (392T9G) | FEFI-T 69G0-0 | 64800-0 GhGO-T 7190-0 | 81900-0 “SIUMUDLY) 179) “qn ‘JTd JO | “uppereg | “[erourpy AYIAB.L) fo aXe) opedgy | WYSeAy | oeunfoA 0FC0-0 | GI-9-18-¢ 18: GFZ0-0 L-L-GG-L SIL €860-0 L-L-GG-1 16-2 6960-0 | $-61-9-ST GP-Lt 8610-0 €-€-6-6 86-6 1060-0 | §-€-@.% LL-3 €910-0 G-E-G-G 8L-G 600-0 G:9-6-F 18-7 L€60-0 9-6-G-% 99-6 6910-0 9-6-G-G €9- “SAUD. ‘Terouryy, | *(eueq) “punoy fo Aqrarug APLAR TSIM | oBfoedg | oytoedg (‘706-0 Upjereg Jo «18 ‘dg) “SUNHWIYVHdXH HO WIAVE ‘ayradng “eueTey “gueTey * plon ‘QUI[BULINO J, 000) “‘aq0[e9 ‘aqTjOUSe PL ‘osvpoouq4i¢, ‘asvpoouqO su, 2 o Ht © 8S KF © O ) | ws 48 J VIII.—NOTES ON THE MINERALS OF THE DUBLIN AND WICKLOW GRANITE. I.—THE BERYL AND IOLITE OF GLENCULLEN. By J. JOLY, B.E., Assistant to the Professor of Engineering, Trinity College, Dublin. (With Prares II., II11., and IV.) [Read, November 18, 1885. ] Tne beryls described in the following pages occur in the granite exposed in the quarries of Glencullen, Co. Dublin, close over the little stream, Cookstown River, which flows into the village of Enniskerry, some three miles further on. ‘These quarries are situated about one mile from the junction of the granite with the schist. Other and larger quarries opened higher up on the same side of the valley yielded, on examination, only one small specimen. In the lower quarries these beryls occur in abundance—an abun- dance equalled by no other locality in the Dublin and Wicklow granite, so far as I know. I can find no previous mention of this locality anywhere in published records.1_ In Weaver’s remarkable and beautiful work on the geology of Eastern Ireland’ the locality is unmentioned. Weaver was the first to find beryls in the granite. It is strange that the Glencullen beryls escaped notice so long. The quarries are very old, and beryls have occurred in them, I am informed by the quarrymen, from the first. The crystals, which are sufficiently remarkable in habit and structure to justify close investigation, occur in veins and bunches throughout the granite, generally coarsely crystallized in their immediate neighbourhood. Orthoclase, especially, occurs in re- 1 Prof. J. P. O’Reilly’s visit (Proc., R. D.8., vol. iv., p. 505) was made some months after mine, which took place in January, 1836. 2 «‘ Memoir on the Geological Relations of the East of Ireland,” by T. Weaver. From vol. vy. of the Transactions of the Geological Society of Ireland, 1819. This work is too much neglected: the engravings of mountain profile are exquisite; the letterpress, with all the freshness of ‘‘ the Complete Angler,’’ is a record of patient and conscientious research. Joty—On the Minerals of the Dublin and Wicklow Granite. 49 markably fine crystals. Tourmaline, which most generally is part of the immediate matrix of the more highly altered beryl, occurs plentifully. Mixed with kaolinized matter, it is moulded often in very large masses to the beryl, rarely penetrating the hexagons. I possess, however, a specimen of beryl—from the Ballybetagh quarry—in which a crystal of tourmaline, to all appearance, passes through a well-formed hexagon from side to side. The beryl has been altered, however, which, as we will see, probably affords an explanation. The beryls of Glencullen present three types: normal crystals, _ radiating crystals, and altered crystals. 1. Norma BrEryu. Pale apple-green; semi-transparent to translucent. Also yellow; semi-transparent to translucent. Only faces detinitely shown, base and prism. The yellow varieties often present, on breaking the crystals across, a core of green-coloured beryl. Specific gravity = 2°722; taken on a large green hexagon weighing 86 grammes. Sections of these beryls, taken parallel to prism faces or to basal faces, show numerous enclosures, vitreous with bubble or liquid with bubble ; congregated in nebule or arranged in strings. These, taken at right angles to optic axis, show want of uniformity in extinction between crossed nicols. There is a cross-hatched appear- ance, as if the mineral was not crystallographically homogeneous throughout. Des Cloizeau, on optical grounds, considered beryl as probably possessing two optic axes close together.—Minéralogie, p- 366, vol. 1. These normal beryls cohabit with muscovite, which often closely adheres over their prismatic faces. In size, crystals measuring a couple of centimeters across the prism face are not uncommon. Some years ago I took a crystal from the small opening in the granite at Ballybetagh, which measured about 4:5 cm. across the prism faces. Interpenetration by orthoclase is common in these crystals. I have not seen any definitely penetrated by either mica or quartz. Beryl is not a phosphorescent mineral: if, however, some of these crystals be heated in a dark room they will be found to 50 Scientific Proceedings, Royal Dublin Society. become luminous here and there over their surface. This, I ascer- tained, was due to the fragments of orthoclase adhering to the hexagons. Mr. Moss has been aware of this peculiarity of the Dublin orthoclase for many years, having, like myself, discovered it accidentally. 2. RavDIATING BERYL. This second type differs from the first in habit only, but this habit is one not noticed in the descriptive mineralogies, and evidently, at any rate, developed in the crystals found at Glen- cullen to a rare degree of perfection. The crystals radiate in the most regular and striking manner, not alone fanwise, but as cones or sphere segments. The pris- matic form seems fully preserved in the individual crystals, but each crystal is tapered, dwindling at last to the common centre of radiation. For some distance around this centre no structure, other than radiating lines, is indeed noticeable: further out the crystals individualize, and their prismatic form is apparent. If a chip from near the centre of one of these cones is placed between crossed nicols it is found to extinguish parallel to the radiating lines ; hence, the fact that the axis of the prism lies along these lines is almost assured. A section taken through the centre of a small group of radiat- ing crystals revealed strongly-marked cleavage along the radii, a cleavage at right angles to this also well marked, and faint cleav- age lines intersecting at about 100°, this angle being external to the centre, and bisected by the radii. Countless enclosures, mostly vitreous, are present, generally elongated along the cs these “are very minute. These radiating beryls are pale-green, inte -green, yellow, and yellow-brown; translucent to opaque, when they are often quite white in colour. Sometimes they are highly altered when they fall under the third type, where they will be described. Basal cleavage cracks cross the radii in lines roughly circular round the centre of radiation. The crystals easily break along this cleavage, producing a stepped appearance along the radii. The groups are all more or less fan-like in section, that is, the cone seems never to merge into the sphere; they are occasionally Joty—On the Minerals of the Dublin and Wicklow Granite. 51 very small, often only a couple of centimeters in diameter, and frequently appear on the surface of the granite in great numbers imparting a very extraordinary appearance to the rock. The figure on plate 1v. from a photograph, shows a very lovely speci- men full size. It is of a delicate pale, bluish-green colour; trans- lucent. The radii pass through the block of granite removed with it, appearing in coarse, crowded, hexagons on the other side, and ‘mixed with tourmaline. They are there of a rusty-brown colour. Some of the crystals must scale over 15 cms. in length. This specimen was found by Mr. Gerald Stoney, in company with - Mr. K. Doyle. The specific heat! of Glencullen beryl, taken by the method of condensation, was found to be 0:21401. The specimen used was a green crystal taken from a group of radiating prisms. EXPERIMENTS ON LOSS OF CoLouR. It has long been known that emeralds calcined at a low red heat lose colour, becoming white and opaque, and parting with water and organic matter. Such are the results of Léwy’s experi- ments, who ascribes the colour of emeralds to the presence of organic matter. It appeared of interest, as throwing some light on the history of these beryls, and on that of the granite containing them, to repeat the experiment, and if possible fix an inferior limit to the decolourizing temperature. Experiment 1.—A preliminary experiment on some fragments of green beryl showed that a temperature far below that of red heat sufficed to bleach and render opaque. The fragments were heated on copper foil, over a fire for a few minutes, they could almost be handled immediately on removal. Experiment 2.—Fragments of green and yellow beryl, dropped into a test tube containing boiling mercury, lost nearly all colour after about one hour’s heating. Experiment 3.—Fragments of green and yellow beryl, sealed 1] hope shortly to publish an account of this method of investigation, and of the means by which I hope to make it generally ayailable. 52 Scientific Proceedings, Royal Dublin Society. in a glass tube containing air, and dropped into a tube containing boiling mercury, lost nearly all colour after an hour’s heating. Experiment 4.—Fragments sealed in a glass tube containing air, and heated for five hours to a temperature of 180°C. (in a bath of boiling carbolic acid) suffered no change. Experiment 5.—Other specimens, heated by means of a sul- phuric acid bath to a temperature of 200° C., rising to 250° for about six hours, showed no change. Experiment 6.—Bits of green and yellow beryl 'placed in an air bath, retaining a temperature of about 230° C. for thirty hours showed a decided Joss of colour. Experiment 7.—Boiling in water did not restore colour to the decolourized specimens; nor has it returned since (after forty days). ‘The specimens of experiments 2 — 7 retain translucency. Conclusions.—It appears from experiments 2 and 3 that a temperature of 357° C. (the boiling point of mercury) is sufficient to deprive both green and yellow beryls of colour in a very short time, and that whether in contact with the air or not. Hxperiment 6 shows that the temperature of alteration may be taken, probably, as well inferior to 350° C.; with long-continued heating possibly below 250° C. On the nature of the change effected in these beryls by heating I am unable to give an opinion. Their continued translucency shows at any rate that the change is not produced in a mechanical way—as it might be—by the development of very numerous eracks. I would suggest that this phenomenon bears on the history of rocks containing this mineral. These green and yellow beryls to be found nested far and wide throughout our Dublin granite are in short so many maximum thermometers. Their delicate and beautiful colours indicate a major limit to the changes of tempera- ture experienced by the granite since their formation to the present day. 3. ALTERED BERYL. The third type, which may be described as altered beryl, includes the larger portion of the total number of crystals coming from Glencullen. I have found also similar crystals at Ballybetagh and in Killiney granite. JoLty—On the Minerals of the Dublin and Wicklow Granite. 58 Externally they show well and sharply-developed faces, both prismatic and basal, and the angles of the hexagonal prism. But here the resemblance to beryl ends ; they are neither transparent nor translucent. The vitreous surface and homogeneous appear- ance of beryl are wanting. They are opaque, dull, rough, and piebald: some dull green and white, some dull green and dull rusty brown. ‘They are in fact a different mineral from beryl in all but external form. They are found up to about half a kilo in weight. Sometimes the cores of the hexagons are eaten out into a cavernous tube lined with rusty matter. Occasional cracks crossing the prism recall the imperfect basal cleavage of beryl. Their specifft gravity shows at once that they are not, or only in part, composed of beryl. I found it to be 2°620 taken on a specimen of average appearance, free from hollows, weighing fifty grammes. The lowest specific gravity recorded by Dana is 2°63; by Des Cloizeau 2°67. I have mentioned that the specific gravity of a specimen of normal beryl from Glencullen was found to be 2°022. The specific heat is hardly abnormal so far as my experiments on beryl go. ‘Three experiments were made on the same specimen used in ascertaining specific gravity :— (a) 0:21554. (0) 0:21446. (c) 021691. Mean specific heat = 0°21563. On breaking up the crystals they are found to present inter- nally the same appearance as regards colour and lustre as exter- nally. T have seen no complete hexagons of this altered beryl. This is noteworthy. One side or one end of the hexagon invariably passes insensibly into the orthoclastic matrix, that again insensibly passing into granitic mixture with quartz and mica. ‘Tourmaline abuts against the faces in many cases, but is easily peeled off, leaving a clean, smooth surface beneath. It does not penetrate or grow into the prism. With the orthoclase it is different. It is in that case impossible to say, on a fractured surface, where ortho- clase begins or prism ends. Nor are these crystals ever found o4 Scientific Proceedings, Royal Dublin Society. implanted on quartz only, as is common with normal beryls from Glencullen. I had a section from one of these crystals prepared for the microscope by Mr. Gregory, of London; it was, by my directions, taken parallel to one of the prismatic faces. ‘The specimen was in colour mottled green and white, with some rusty marks. On examination in the polarizing microscope it appeared, in the first place, that more than one mineral entered into the com- position of these erystals. ‘The fundamental constituents were evidently two in number. There was a constituent presenting the appearance of a felspar, and there was a more homogeneous con- stituent, which I suspected to be beryl. ‘These were mixed, archi- pelago-like, in wild confusion, but always quite distinct. The felspathic part extinguished locally or in plumed shadows, which crept over the field as the stage was rotated. Faint cross-hatching, checquered or wavy marks, recalled microcline: these marks appear in fig. 3, pl. m1. Such are, however, common in well-authenti- cated orthoclase. It showed, too, the habitually quiet colours of that felspar, slate-grey in this case; and in fact I had little doubt it was orthoclase. Lately, however, examination of the cavities eaten in these crystals by decomposition has set the question at rest. In these, bunches of small laminate crystals, resembling white orthoclase in appearance, branch from the walls in tufts and plumes; their grouping suggestively recalling the plume-like extinctions obtained on the sections. Fragments of these tufted crystals, removed and placed in a diffusion zone above Thoulet’s solution, according to the simple and accurate method devised by Professor Sollas, float side by side with the Glencullen orthoclase. Their specific gravities are, therefore, identical, Again, when compared with Glencullen orthoclase on the Meldometer their melting points are found to be identical. There is little doubt, then, that this constituent is orthoclase. It is seen at once on the section that this orthoclase includes a ereat many sharply-defined, brilliantly polarizing crystals, present- ing a very beautiful appearance. ‘hey are very small, and, with great probability, are iolite. In the second principal constituent extinction is not local, but takes place simultaneously all over the field, leaving the felspar standing out in luminous veins and patches.—Fig. 1, pl. u. (x 18 Joty—On the Minerals of the Dublin and Wicklow Granite. 55 diams.) It polarizes in bright colours uniformly, and generally appears limpid and clear, save for conspicuous cleavage streaks. It is bordered where abutting on the felspar, with a dark margin, due to difference of refractive index. | It will be evident that if this constituent is beryl, and the streaky lines alluded to basal cleavage, not only should we expect simultaneous extinction, but we should expect it to occur when these lines are in the plane of analyzer or polarizer, the axes of elasticity of the section being then contained in these planes. On trial it is found to happen so. Again, in the case of a section cut in a plane at right angles to the one being described—that is, at right angles to the axis of the prism—this same one of the two constituents should behave as if amorphous: that is, remain dark all round between crossed nicols. I had a section cut in this direction from the same specimen, and it behaved as expected, save that it showed the cross-hatched appearance before alluded to as being noticeable on normal beryl so cut. ‘There was no appearance of cleavage. The analysis subsequently made confirming the presence of beryl, it may be considered certain that this second constituent is indeed that mineral. It contains no iolite. There is no crystallographic relation discernible in the distri- bution of these two chief constituents, orthoclase and beryl. Indeed, so far from such being apparent, the felspar seems to wander at random through the beryl; branching veins, sharply defined and often of extreme fineness, spread over the field. Rivers of felspar they look like—now widening into lakes and again dwindling to mere streamlets. Scattered through- out, the iolite glows with exquisite colour, like many-coloured flower blossoms that have fallen and are borne along by a dark river. | Where broadest these veins are sometimes clouded over—a muffed glass appearance—where probably the felspar is kaolinized by water action. There is present also, chiefly through the beryl, a chloritic mineral most nearly resembling Dana’s prochlorite in its habit—ropy, radiating, and vermiform. Some of these radiating spheroliths—often extremely minute and closely crowded—show the extinction cross with branches remaining along the sections of the nicols as the stage is rotated, indicative of a structure radiating 56 Scientific Proceedings, Royal Dublin Society. along the axis of elasticity. Their colour is dark green to yellow. They are probably an alteration mineral, occurring principally near the surface of the hexagons. To this constituent the dull green colour of the crystals seems to be due. A little pyrites and hematite are also present. The question that now presents itself for consideration is this :—Here, in the field of the microscope, are two minerals, both in the crystalline state—one true to the external hexagonal form in molecular arrangement, while apparently separated into innumer- able isolated portions by the second substance, which, in its optical behaviour, shows no sympathy with the planes which limit in common the extension of both minerals. From our knowledge of its nature, it would indeed be altogether anomalous that it should show such sympathy. Are we to suppose that we are here dealing with a erystal of beryl which has been eaten into and replaced, at some period of its history, by orthoclase, or with the result of simultaneous inter- crystallization of beryl and orthoclase in the first instance ? In favour of this last hypothesis it is to be observed that it is evidently quite unnecessary to suppose isolation of the beryl really to exist, as unnecessary (and indeed obviously more so) as to sup- pose, when looking at a map, that there was no connexion between the patches of land islanded by the seas. In addition to which, in consideration of the evident harmony of orientation of the beryl molecules throughout, it is unthinkable. As, then, continuity of the hexagonal matrix is in this crystal assured, are we to regard the orthoclase as an inclusion merely—that the clustering laminze and veins of felspar were formed progressively with the beryl, although no crystallographic relation between the two bodies is visible, or to be expected—that the phenomenon was due to the compelling power or hexagonal virtue of the beryl? Now this compelling power is generally effective in a different way, or to much less extent. It may, indeed, force an abnormal symmetry in a very partial degree on a body crystallizing in juxta- position: cases of this are known. It may more commonly com- pel into order the molecular confusion outside the parent crystal: this may be merely growth, or it may give rise to an envelope of smaller crystals of the same species as the parent crystal. It may exert itself by taking up a cloud of fragments already formed, and Joty—On the Minerals of the Dublin and Wicklow Granite. 57 give the whole nebula a symmetrical shape as crystallization pro- gresses. ‘This is symmetrical inclusion. The inclusions may be mixed throughout the crystal in such abundance as to relegate the parent crystal to fill the ré/e of a form-producing paste only ; such inclusions might form from the magma as the growth of the parent erystal progressed. But such of these phenomena as are applicable to the present case would surely be accompanied by confirmatory optical pheno- mena. Will they again serve to explain the simultaneous stoppage of growth of felspar and beryl?—those large patches of white ortho- clase visible over the surface of the hexagons, but perfectly smooth and flush with the prism faces. How did the hexagonal virtue extend its influence to the centre of those areas of the monoclinic mineral? Within, in the cavities, the felspar crystals suggest an independent growth—a growth independent of the hexagonal virtue of their matrix. Had the hexagons ceased growing at that stage, were abruptly-produced faces out of all relation with the symmetry of orthoclase—necessarily so as the laminate crystals are oriented in every direction—to be expected? Elsewhere in normal beryl the felspar behaves after the general manner of inclusions—pro- jects its solid angles out of the beryl, or, if the beryl be sufficiently grown, is swallowed up. The distribution of the orthoclase in converging veins might also be urged against the intercrystallization hypothesis; but there is a more direct argument forthcoming. It appeared that if the alteration hypothesis was correct, and if the seat of the attack was to be sought for at the junction of the prism with the orthoclastic matrix, then, in this region, con- firmatory phenomena or the reverse might be expected. The con- tinuity of prism and orthoclase has already been pointed out. It appeared highly probable, on the alteration hypothesis, that this junction was the seat of the reaction in the first instance. Sub- jected to the influence of a potash felspar in a state of hot solu- tion, the beryl was assailed and replaced, it may be at a very slow rate. Such replacement may have been of the nature of alteration merely, the berylium probably being removed, a re-arrangement of the molecules occurring, and the crystalline net of orthoclase replacing the original symmetry. On these grounds, however vague, I had a section cut from a SCIEN. PROC., R.D.S.—VOL. VY. PT. II. F 58 Scientific Proceedings, Royal Dublin Society. well-defined hexagonal prism, close to its junction with the ortho- clase, but well within the hexagon, and at right angles to the principal axis of the hexagon. In this section the phenomena are so eloquent as to set the question at rest. The attack is, in a word, seen at a much ad- vanced stage. The beryl has broken down completely. Uni- formity of extinction, which here, if normal, should be persistent between crossed nicols, is no longer seen. Here and there hexa- gonal forms, left standing by the invading orthoclase, remain quite true to their original position, though veined and worn. These behave as amorphous, save for the cross-hatch marks. Other hexagonal outlines, with angles projected out of 120°, partially restore illumination as they are rotated between the crossed nicols. In short, patches of beryl are found, fallen in the fight, and cut at such various angles with the optic axis, that they can hardly be differentiated by colour or extinction—on the one hand from beryl cut at right angles to that axis, and on the other from beryl cut along that axis. Fig. 2, Plate u. (x 18 diameters), presents a remarkable pic. ture of dismemberment and solution. The large, broken, and incomplete hexagonal outline there shown was on the alteration hypothesis originally a homogeneous portion of the parent crystal. It is now girdled round with felspar, and broken up. Its cracks are in continuity from side to side. It was even attacked and veined by a primary inroad of felspar before the final attack eat out a path, severing the primary vein and parting the mass. Islands of beryl left standing, or borne down from its banks, mark the course of this felspar flood. More than this, so com- plete has the final solution been, and so simultaneous all round, that movement of the dismembered hexagon after its isolation is apparent. Thus it will be seen that the edge a is no longer parallel to the edge d. It is, in fact, according to measurement, about 14° removed from parallelism. This measurement was taken on the photograph; it is then independent of the readings of the angles of the hexagon. Placing now the cross wires of the microscope along the edge b, and along the edge c, an angle of 182°, about, is scaled on the section. This is fairly concordant with the observation made on the photograph. It should read 134°, to agree with it. There is then evidence of movement of the detached fragments relatively to each other. Joty—On the Minerals of the Dublin and Wicklow Granite. 59 It will be noticed in this section that tourmaline is present in tufts and dark masses encroaching on the edge 5, and generally mixed through the felspar. Elsewhere it is conspicuously of secondary origin to beryl, and my crystal penetrated by tour- maline, before-noticed, is explained by alteration of a similar character to this. It is to me inconceivable that this jumble of fragments of beryl, with molecular orientation in every direction, scattered through a sea of felspar, owes its external hexagonal form to the hexagonal virtue of the beryl. If, in short, the beryl was not able to keep itself in order, how, on the intercrystallization hypothesis, was it able to shape into order, against their normal molecular tendencies, the molecules of felspar P What were the nature and circumstances of the reaction which led to this alteration or substitution? Was it hydro-igneous or simply igneous ? It seems probable, in the first place, that intermixtures like this of bodies of very different melting points is most readily ex- plained by hydro-igneous formation of one or both the bodies. Thus Daubré, by attack with steam at 400°C., obtained crystals of quartz and pyroxene imbedded in an easily fusible matrix, derived from the glass tubes employed. Other arguments for low temperature origin of the felspar exist. ‘Thus we find a beryl moulded round by felspar: the edges of the beryl are sharp and well defined, although its melting point is far below that of orthoclase. Again we find the beryl coloured yellow, green, or blue, but it loses all colour, according to experiment, at 350° C., after an hour’s heating. There is internal evidence too. Hxamined with high powers the sections reveal innumerable enclosures. Some glass, but some composed of liquid, with movable gas bubble. These are plenti- ful, both in beryl and felspar. In places they range in veins and strings, resembling fluxion structure. Tiny crystals (?) accom- pany in shoals. With inclined microscope the gas bubbles may often be induced, on tapping the stage, to travel from end to end of the cavity. It seems probable, then, that the change experienced by these beryls was effected at low temperature, or hydro-igneously. The F 2 60 Scientific Proceedings, Royal Dublin Society. pseudomorphous nature of that change is sufficiently accounted for by supposing the reaction as engaging with the beryl only, not with the tourmaline matrix. In speculating on the circumstances attendant on, and which led to, the reaction, I may be pardoned perhaps for venturing to suggest a theory of the formation of beryl and tourmaline through- out the granite. The remarkably local nature of the distribution of the beryl in the granite is well known. ‘There are no crystals worth mention- ing in the quarries situated close above those in which this abun- dance of beryl is found. Rochetown Hill is mentioned by Weaver, writing in 1819, as affording beautiful specimens. I searched the quarries recently. The mineral is worked out. I found but one small specimen. In a similar way the Killiney quarries have ceased to yield; they are now represented by Kingstown Pier, where speci- mens may be found imbedded in the blocks used in its construc- tion. At Ballybetagh a mere opening on the surface yielded a group of crystals contained in a vein of porphyritic granite, which, pursued further down, ceased to yield. The habitat of beryl is in short the pocket or the vein, and, when the vein, generally close to the surface. In all these respects it resembles that other accidental mineral of the granite, tourmaline. Nowit is most thinkable to suppose the rare elements plucintin and boron originally diffused more or less uniformly throughout the region, in which we will suppose the elements of granite to be in a state of slow progressive crystallization in presence of _ water. As cooling and solidification advanced, a concentration of those elements would occur, which failed to take part in the molecular arrangements going on throughout the magma, and pockets of highly concentrated mother liquor would be formed. Many of these pockets, imprisoned at great depths, would re- tain their position till loss of heat enabled, first, beryl, and then tourmaline, to crystallize out. Many of these pockets again, as solidification advanced, may be conceived as pressed out, and uniting in one outflow, forcing their way to the surface in cracks left by the shrinking rock; only crystallizing when from loss of pressure, or by conductivity to Joty—On the Minerals of the Dublin and Wicklow Granite. 61 the upper and cooler layers of rock, they have attained a suf- ficiently low temperature. In these veins the erystals of beryl, forming in deeper and hotter regions than the tourmaline, and taking toll from the pass- ing waters, grow and gather in bunches; the zone of solidification retreating downwards as cooling progresses. Similarly, tourmaline, forming always higher in the vein than beryl, but, like it, ever forming deeper and deeper in the granite, covers up finally with a schorlifferous covering the beryl already deposited. These beryl and schorl veins may be seen in perfection at Glencullen. Sometimes they are euritic in texture: more gene- rally porphyritic, when they yield beryl and schorl, intermingled with overgrown crystals of felspar. If it is allowable to reason on these lines, it is perhaps sufficient to seek for the cause of the alteration experienced by the beryls in a change of temperature, it may be, of the upwelling waters, where- by dissolution and replacement of the beryl was brought about; or it may be in a change of constituents—more highly alkaline water. Or, finally, both causes may have operated. Those other changes—cavities eaten out, chlorite developed near the surface of the crystals, kaolinizing of orthoclase and beryl—are most probably changes of tertiary formation. It is probable that water action, at the ordinary temperature, has effected some of these changes. Thus the most advanced cases of decomposition have been taken from the wettest veins in the quarry. JI have, from these veins, removed hexagonal shapes, which, crushed between the fingers, crumbled into a rusty-brown kaolin. Percentage Composition of the altered Beryls. It is interesting to note the extent to which replacement by orthoclase is carried in some cases. This may be investigated in three ways: by specific gravities, by specific heats, and by chemical analysis. 1. The specific gravity of beryl from Glencullen was found to be 2:722 ; the specific gravity of orthoclase from Glencullen, 2-510. The specific gravity of the mixed minerals was, in the specimen dealt with, 2-625. The weight of this specimen was 50-400 grams, 62 Scientific Proceedings, Royal Dublin Society. Neglecting the influence of the small quantity of iolite present, and also the influence of the chloritic mineral, this gives a percen- tage composition— beryl. 5 . O44 Orthoclase, . . 45:6 2. It is evident from the figures previously given that the specific heats will not enable a direct percentage estimation to be made. Thus the specific heat of Glencullen beryl was found to be 0:2140; of the mixed crystal (the same used in investigation by specific gravity), 0°2156; while the following results were obtained for Glencullen orthoclase :— OV ee GED CONE aed a er eROTG giving a mean of 0:1979. Hence, a specific heat lower, and not one higher, than that of beryl was to be expected. In fact, calceu- lating it in the percentages obtained above by specific gravity, the specific heat of such a mixture would be about 0:207. It is re- markable that the large percentage of water (1:4) revealed in the analysis of this specimen will just account for the discrepancy. Beryl normally contains no water, and this orthoclase, by Gal- braith’s analyses, 0°58 per cent. only. Assuming this as high as 0-3 per cent. of the whole, an abnormal quantity of water, equal to over one per cent., is present. ‘Taking it as low as one per cent., and re-calculating, the theoretical specific heat is found to he 0-2150. 3. According to microscopical examination, orthoclase is the only mineral present which is known to contain an appreciable amount of potash. Analysis shows that there is 5:11 per cent. of K,O in the mixed mineral, the same specimen being used that had served for the previous investigations. Now, as the result of Prof. Galbraith’s seven analyses,’ the felspar of this granite contains 12-2 per cent. of potash. On these data we find orthoclase 42 per cent. If, however, we calculate the percentage of beryl by the per- centage of BeO given below, and by the result of Mallet’s analysis of Killiney beryl (he obtained 13-09 per cent of BeO—Dana), so 1 Journal of the Geological Society of Ireland, vol. vi., p. 226, Joty—On the Minerals of the Dublin and Wicklow Granite. 63 much as 74 per cent. of beryl is obtained. This suggests that only a small quantity of the oxide was removed in the process of alteration. If we assume 58 per cent. of beryl present, then, on _ Mallet’s analysis, 7-59 per cent. of BeO is to be expected, leaving 2°16 per cent. of that body “free” or mixed through the ortho- clase to the extent of 5 per cent. of its weight. It is also open for us to assume that the deficiency from the normal percentage of BeO for the entire mass is due to weathering only; that, in short, none of the oxide was removed by the primary alteration ; but that the subsequent weathering of the beryl con- stituent into kaolin and the formation of a chloritic mineral are alone accountable. On this hypothesis the orthoclase would con- tain about 13 per cent. of BeO. We are, indeed, driven to suppose that. alteration had the effect of reducing the percentage of BeO, at all events in some degree; for the examination of these crystals goes to show that it is the beryl constituent which is most readily kaolinized or replaced by chlorite; and the analyses of kaolinized beryl (Dana’s min.) reveal a diminution or nearly complete re- moval of glucina. The question, however, obviously cannot be discussed on the results of one analysis only. Analysis of altered Beryl. Sp. gr., 2°625. 810, : , : : 57°73 Al,O; : : : : 20:06 Fe,0, ‘ ‘ ‘ : 4°56 K,O “he : : 5:11 Na,O ; : oN 64 BeO : . : : 9°75 MnO ‘ i ‘ trace MgO ‘ : : trace CaO : s : ; trace Ignition (H,0) : 1-44 100°29 1 Made with Mr, W. Harly’s kind assistance, and chiefly under his directions. 64 Scientific Proceedings, Royal Dublin Society. The glucinum, along with some of the iron, was separated from the alumina by carbonate of ammonia, subsequently precipitated by ammonia, and weighed as the oxide along with some iron, which was then estimated volumetrically. This sample of mixed beryl and orthoclase may then be consi- dered, with little doubt, as containing some 42 per cent. of the latter mineral, and originally some 58 per cent. of beryl. The percentage composition of four other crystals, all showing well-marked hexa- gonal faces, was also investigated by taking specific gravities. 1. White homogeneous crystal, with beryl lustre. Very hard all over surface. Weight, 24'803. Sp. gr., 2°69. Beryl, : av 486 Orthoclase, . dle 2. Same appearance as 1. Weight, 9°764. Sp. gr., 2°67. Beryl, eae Orthoclase, = 1 Oe. 3. Piebald crystal. Heterogeneous appearance. Weight, 20°554. Sp. gr., 2°59. Beryl, . =) 39 Orthoclase, 5 oe 4. Same appearance as 3. Weight, 21:152. Sp. gr., 2.57. Beryl, : oO Orthoclase, 3 OTE These computations assume the specific gravity of beryl as 2°722 ; of orthoclase as 2°510. It is to be remembered that other values are assignable, but that these seem fairly well borne out by the analysis. JoLty—On the Minerals of the Dublin and Wicklow Granite. 65 Briefly summing up the results of these various observations, it appears, with great probability, that the heterogeneous crystals were primarily composed entirely of beryl: subjected secondarily to reaction with a potash felspar in a state of hot solution, they were partially replaced, and that to very different degrees; that the primal seat of this reaction is, in general, traceable to one region of the crystal, now the implanted surface, in which direction the replacement is most complete, the original structure of the crystal being often completely broken down; and that this reac- tion, being confined between beryl and felspar, allowed of the hexagonal form being preserved within the schorlifferous matrix, the result being a variable mixture of felspar and beryl pseudo- morphous after beryl. The felspar so mixed with the beryl is orthoclase, containing a mineral in general foreign to Ivish rocks, iolite, and, further, containing, there is reason to believe, glu- cina; but this question is not gone into in the present Paper. Subsequently, and probably as the effects of hydration, the mixture has been kaolinized to variable extents; and, asa tertiary alteration also, a chloritic mineral has been formed through the beryl. The beryls of Glencullen often radiate in beautiful conical bunches, with a completeness and regularity not noticed in de- seriptive mineralogy. These are often of delicate green and yellow hues; and such, in common with crystals of normal habit, lose nearly all colour after being exposed for a short time to a temperature of about 350° C. The Iolite of Glencullen. I now turn to the consideration of the very minute crystals developed through the felspar, and absent from those portions of the sections composed of beryl. The crystals appeared in two types :—a wide polygonal form, often with twelve edges, extinguishing along two edges situated at right angles to each other on the polygon; a rectangular elon- gated form, extinguishing most generally along the edges, but often at variable angles with the edges. oliation in thin plates 66 Scientific Proceedings, Royal Dublin Society. was common over the surface of the polygonal form: cleavage was generally parallel to the ends of the rectangle in the rectangular forms. On first approaching the subject, I formed the hypothesis that some of the symmetrically extinguishing rectangular forms were beryl cut parallel to axis of prism. The absence of hexagonal sections threw doubts on that hypothesis. Some of the other rectangular forms I thought were orthoclase developed on the zone ph’ (Levy). Such a zone shows large base, rectangular, with extinctions parallel to sides; orthopinacoid large, with extine- tions parallel to sides; clinopinacoid small, with extinctions paral- lel to sides in ‘‘orthose non-deformé,” at 5° in “orthose deforme.”’ But this zone should show, when cut squarely, the axial angle of 63° 33’. It was never found thus in the sections. The colours of polarization, too, were not those of orthoclase. It was evidently possible, also, to account for the appearances by supposing the crystals orthorhombic, in which case, further, both forms might be supposed to be different views of one and the same crystal. Now the angles of the polygon were all about 150° when twelve-sided ; and in eight-sided figures, not uncommon, one set of faces produced intersected at 90°, another at 60° and 120°. To what orthorhombic mineral were such angles to be assigned? Not being acquainted with any such, I had set the mineral for the most part down as “doubtful,” with the suggestion that some of the forms might be orthoclase, when I had recourse to an apparatus I devised about this time for investigating the melting points of small fragments of minerals. This apparatus is briefly described in Nature (vol. xxxiii., p. 15), where I call it a “meldometer,” or measurer of melting points. By the help of this apparatus I differentiated them from every substance I had ever suspected as being present. I must explain, however, how I succeeded in obtaining the crystals isolated and free of the matrix. I mentioned before the cavities eaten by decomposition in the large hexagonal crystals of mixed beryl and orthoclase. These cavities appeared filled in part with a rusty-brown powder, and in part with a frail skeleton of hard matter (felspar) clinging to the walls or loose in the cavity. On removing this debris, crushing Joty—On the Minerals of the Dublin and Wicklow Granite. 67 the lumpy parts, washing and cleaning in boiling hydrochloric acid, clear, glassy crystals, of extremely small size, appeared in countless numbers through the residue. These, mounted in Canada balsam, proved to be the identical crystals visible in the sectlons—some beautifully sharp and clear, some partly decomposed and overspread with a filiform, branching growth of olive-yellow colour. Micrometric measurements gave 0:1 mm. as the length of the larger specimens showing good angles. With such dimensions it was difficult to deal with them singly. Again, by breaking up the hexagons and crushing the felspa- thic matrix containing these crystals, treating carefully with hydrofluoric acid, specimens were obtained fairly clean. But the first source, where decomposition had removed the beryl and some of the orthoclase, but had spared the small sharp crystals, was my great source of supply. In these hollows slow-acting decomposi- tion has effected a fairly perfect isolation, and I have opened cavi- ties from which the tiny crystals could be poured in great numbers, only requiring cleansing from their rust-coloured coating to be ready for the microscope. The slides composed of these crystals present a spectacle of such perfection of form, and, in the polariscope, such richness of colour, as would far surpass any power of description. Feeling this, I will, instead, refer the imagination of my reader to the soft crimsons, purples, and tender blues of those cloud islands and vistas seen at sunset, where the colour is not the dead brightness of opaque reflection, but is living with transmitted light. And I would remind him, that while in that case the imagination is affected. by the far-off peace of those regions to clothe them with an unreal richness and tenderness of tint, these children of the rocks are not so seen with the eyes of dreamland. I will ask him, then, to pic- ture a precision of form and matchless depth of colour which, to none but the scientific imagination, are as breathless objects of adoration, as the infinite oceans of sunset. Having obtained the mineral thus isolated from its matrix, it was resolved to treat some of the little crystals on the meldometer along with orthoclase, and also compare their behaviour at high temperatures with topaz, quartz, &c. I had only just begun to use the apparatus, and was desirous of testing its value as a means of differentiation ; for although no determinations of melting points 68 Scientific Proceedings, Royal Dublin Society. were obtainable to render numerical results of value, yet the com- parative test was easily applied, and would probably throw some light on the nature of the mineral. Comparison with Orthoclase.—The orthoclase used was from Belleek, and also from Co. Dublin ; respectively red and white in colour—subtranslucent. The unknown crystals were transparent and colourless. The orthoclase fused first, and gathered into transparent beads of glass containing large bubbles. At a much higher temperature the unknown mineral rounded and turned milk-white in colour, developing no bubbles. 7 The experiment was more than once repeated. The unknown mineral had evidently a much higher melting point than orthoclase, and its behaviour in other respects, also, differentiated the two substances decisively. Comparison with Topas.—Fragments of clear topaz and the - unknown mineral. Both rounded simultaneously, and both turned milk-white. The topaz, however, emitted a gas which raised blisters and blue bubbles on the melting surface of the fragments. On the breaking of these bubbles, threads of glass were thrown about the hob, and the gas attacking the platinum deposited rings of colour around. Probably the gas contained in these bubbles is fluorine, liberated at the high temperature employed. The coloured rings, fluoride of platinum. No such phenomena occurred with the unknown mineral. They probably contained no fluorine. Comparison with Quartz.—Clear rock crystal showed a much greater resistance to the temperature of the hob, only fusing at the extreme limit of endurance of the platinum itself. The melting point of the unknown mineral was therefore fixed as above that of orthoclase, and below that of quartz. » These results, together with the knowledge of its angles already gathered from the microscope, led me to think for a time that I might be dealing with a new species. More accurate crystallo- graphic measurements were desirable. By manipulating one solitary crystal, obtaining extinctions along its faces, and measuring its angles, its orthorhombic charac- ter, both by symmetry and elasticity, was determined beyond doubt. Its specific gravity was now taken by Professor Sollas’ method. It was found to be 2°58. To face page 60.) ID) LO} Tal 18 © ILI, ORTHORHOMBIC. TA T=119° 10’ and 60° 50’ TA i-3 =150° i Ai-3 = 150° 25° i-3 A i-3 = 120° 50’ = ON T= 90° Cleavage, 1-7 distinct ; 7-2 and O indistinct. Crystals, foliated parallel with 0. Twins, composition face J. Transparent. Dichroic, blue to yellow, but feeble in small crystals. Lustre vitreous. Colour, blue shades. Spec. grav. = 2°59 Hardness = 7-775 Fuses at 5:5, loses transparency. Chemical Composition (Mean). Silica, SiOz, 50-0 Alumina, Al20s, 31:6 Ferrous Oxide, FeO, . 6°6 Magnesia, MgO, 10-4 Calcium Oxide, CaO, 0-6 Manganese Oxide, MnO, 0-4 Tegnition, (H,0), 1-4 Fracture, sub-conchoidal. LO eae ORD Shi Rt mB. ORTHORHOMBIC. v 5. Fig. 4. Fig. 6. Fig. 5. Transparent. Dichroism uncertain. Lustre vitreous. Colour, pale blue. Spec. gray. = 2°58 Hardness about 7. Fuses with Iolite, turns opaque white. Analysis of Impure Specimen. 56°7 20°7 13-9 4:2 trace trace 2°0 97°5 To face page 69.) ORTHOREH | I \ T= 119° 10' and € IA i-3 = 150? it i-3 A i-3 = 120° 50’ Cleavage, i-% distinct ; i-7 and O indis} Crystals, foliated parallel with O. Transpar¢ Dichroic, blue to yellow, but Lustre vitr Colour, blue Spec. grav. : Hardness = Fuses at 5:5, loses Chemical Compos: Silica, S102, Alumina, Al2.0s, Ferrous Oxide, FeO, . Magnesia, MgO, Calcium Oxide, CaO, Manganese Oxide, MnO, Tenition, (H20), JotY—On the Minerals of the Dublin and Wicklow Granite. 69 The characteristics ultimately determined are recorded in the annexed Table, in the right-hand column. The characteristics of Iolite, the Cordierite of the French school, appear in the left. Taken collectively the evidence is, I think, irresistible that these small crystals are iolite. Figure 1 on the Table, right-hand column, depicts the basal face of the crystal. It shows foliated habit and twin-line, or trace | of composition plane J. The angles I had in the first instance determined as the mean of many measurements were so close to 150° each, that I decided to enter them as such. This gives nearly the same values as Dana and others record: J A Tis 120° and 60°, and the secondary face in the zone 11 becomes nearly i — 3. Extinction is along 7-7 and ¢ — #, shown by the arrow- ner The face i — 3 is often absent, and always small. Fractured corners, as in fig. 1, are common. ‘The cleavage is then well seen. Figure 2 is elevation of zone 11. Extinction, as shown. Figure 3 is section on ¢ — 2, showing cleavage. Figure 4 is end-elevation of zone 11. Figure 5 is section oni - %. Cleavage very obscure, or absent. Figure 6 is a hemihedral form respecting i - 3; not very un- common. Looking down the column, I need only observe that the colour is only seen when a large number of crystals are superimposed, as in a narrow test-tube, and viewed by transmitted light. The hardness was only very approximately determined by press- ing a number of the crystals into the end of a lead wire, and then, using the wire as a handle, proceeding as usual. The fusibility was determined to be about the same as iolite by comparison with an authenticated specimen on the meldometer. It is perhaps a little higher than that of the specimen used; nor did the known iolite whiten to any great extent. The loss of transparency experienced by iolite on fusing is however well known. Lime is generally present in this mineral: its absence might account for exceptional behaviour in this respect. An analysis, made with Mr. Harly’s assistance, is added. The material for this was obtained as follows:—The powder obtained from the hollows in the hexagons was boiled for a few minutes in strong hydrochloric acid, and thoroughly washed in water: 70 Scientific Proceedings, Royal Dublin Society. separated from free quartz, orthoclase, and tourmaline, by Thoulet’s specific gravity solution. The crystals thus obtained were freed of | large mixed fragments and very fine particles by descent through a long column of still water ;—a method described by me elsewhere (Proc. R. D. S., vol. iv., p. 291). The large rough fragments so removed were found on microscopic examination to be very im- pure, the medium-sized crystals fairly pure, the fine dust very heterogeneous and impure. A few of the larger of the medium- sized crystals being sorted out for photographing and mounting, the remainder, weighing about two decigrammes, was devoted to analysis. The percentages obtained in the analysis hardly approximate to the numbers for iolite given in the left-hand column. This was to be expected from the impurity of the sample. The presence of 4 per cent. of MgO is, however, important, as there was probably no source of impurity present capable of affording an appreciable weight of that body. I think it highly probable that glucina may enter into the composition of these crystals, replacing the magnesia, the elements Be and Mg being isomorphous. Glucina was not looked for in the analysis. J¢ is remarkable that these crystals seem present only in orthoclase, thus imtermixed with beryl. In other sections of Glencullen orthoclase, as well as in sections of granite! from Co. Cavan, Co. Mayo, Newry, Killiney, Warrenpoint, and from the Mourne Mountains, I could detect none of these crystals. As in the case of their felspathic matrix, I have little doubt of the correctness of my diagnosis of the mineral species. Whether perfectly normal in chemical composition or not, can however only be decided by further and more careful analysis. The formula to be deduced from the analysis, such as it is, is— 10 SiO, .2(Al,0,. FeO). MgO . H,0, which, be it observed, affords a bisilicate oxygen ratio, instead of a unisilicate ratio. As a microscopical mineral, this iolite will be recognized by its basal angles of 150°, 120°, or 60°; its generally symmetrical extinc- tion on elongated rectangular sections, and the transverse cleavage on such sections. ‘he foliation, or plating on O, and the oblique 1 Kindly lent by Professor Hull. Joux—On the Minerals of the Dublin and Wicklow Granite. 71 twining line parallel to Z, are also frequently met with. Occa- sionally the crystals occur in radiating groups. When thus arranged, it will be found that the basal faces have a sort of symmetrical arrangement, being all oriented into planes perpen- dicular to the plane of radiation, so that it is seen as radiating in rectangular forms only. I may also observe, that so minute are these crystals that they are freely contained and propped into every conceivable position within the small thickness of the section. This fact, coupled with the simultaneous focus of pinacoid, or prism faces, on opposite sides of the plane of symmetry, renders necessary considerable caution in deciding on the nature of the forms in the field. The angles are generajly sharp. Enclosures are rare ; generally glass. Mutual interpenetration is very common. They present all the appearance of having been formed antecedently to their felspa- thic matrix. Colours are generally exquisite, but they will, of course, vary with the thickness of the section in the field. Pale- grey forms are not therefore to be put down necessarily as felspar— they are not uncommon. ‘The dichroism is too feeble, seemingly, in such small crystals to be of value in diagnosis. Branching veins of a translucent greenish decomposition product cover the faces in some cases. Iolite is known in many decomposition forms. Figure 4, plate u1., is a photograph showing a group of iolite crystals sorted from those prepared for analysis, as described. ‘They are exceptionally large specimens. Enlargement, 18 diameters. Figure 3, plate 111., more highly magnified (x 70 diameters), shows iolite in situ. A polygonal form, slightly turned up, so as to show the faces i - iand J conspicuously, as well as the basal face O, occupies the centre of the field. The other forms are mostly rectangular, parallel, more or less, to the face i - 7. Some of these show the i—% cleavage. They nearly all extinguish longitudinally. The chequered appearance of the felspar is displayed over the field. veo EXPLANATION OF PLATES ILI., IIL, anv IV. Prats II. Figure 1.—Veins of Felspar traversing Beryl. Section through a crystal of altered Beryl, parallel to axis of hexagonal prism. Light polarized. (x 18 diameters.) Figure 2.—Broken down Beryl. Section ifear base of mixed Beryl and Orthoclase. Light polarized. (x 18 diameters.) N.B.—As the letters have been omitted, the edges referred to may be identified thus :—lowest left-hand edge (about one centimetre in length) is the edge d; the adjoming edges c; the uppermost edge broken by the fissure is b, and the next adjoining edge is a. Puare III. Figure 8.—lolite im situ, showing markings of Orthoclase. Section in altered Beryl. Figure 4.—Group of Iolite crystals removed from cavities in mixed Beryl and Orthoclase. Light polarized. (x 18 dia- meters.) N.B.—The description of these two last figures has been transposed on the Plate. Puate LV. Figure 5.—Radiating Beryl in granite matrix. ted IX.—NOTE ON THE ARTIFICIAL DEPOSITION OF CRYSTALS OF CALCITE ON SPICULES OF A CALCI-SPONGE. By PROFESSOR SOLLAS, D.Sc. [Read, June 15, 1885.] Some acerate and triradiate spicules of a calci-sponge, after having been left to stand for some days in water containing an excess of calcium carbonate, were found to have become incrusted with an abundant crop of minute crystals of calcite. The exact form of the crystals was not ascertained; but, as on rotation between crossed Nicols, they extinguished simultaneously with the spicules on which they were seated, and underwent the same changes in refractive index, we may conclude that the optic axes of the cal- cite forming a spicule, and the crystals incrusting it, are similarly orientated. A curious feature in the distribution of the crystals is worth notice. ‘They do not cover the whole of a sagittal triradiate, but are confined to opposite sides of the paired rays and the extremity of the unpaired ray; an acerate, is, however, often covered with them for its whole length, but usually only on opposite sides. Thus the crystals are deposited only on those regions which show the greatest liability to solution:' thus it would appear that the polarity which leads to solution also determines deposition. 1 Vide Sollas, on ‘‘ Physical Characters of Calcareous Spicules,”’ &c., Proceedings Royal Dublin Society, vol. iv., N.S., p. 385. SCIEN. PROC., R.D.S.—VOL, V. PY. II. G Ee A X.—THE DOUBLE QUADRIFORM LIGHTHOUSE LAMP. By PROFESSOR W. F. BARRETT. [Read, December 16, 1886. ] Ir may be of interest to lay before the Members of this Section of the Royal Dublin Society some observations which I have recently had the opportunity of making upon the fog-penetrating power of the new system of lighthouse illumination devised by Mr. J. RB. Wigham, of Dublin. As Professor Tyndall has remarked in a recent letter to The Times, when Mr. Wigham began his experiments the best light- house lamp in general use was the four-wick oil-lamp, and the augmented illuminating power in lighthouses which exists at the present day is very largely due to the competition which Mr. Wigham’s superior light has called forth. As is well known, Mr. Wigham is the inventor of gas illumination for lighthouses, and the adaptability of gas for this purpose has enabled him to build up a series of three, four, and now eight lights, with their appropriate lenses, within one lighthouse. The high temperature within the lantern produced by so many lights has not, I under- stand, in any of the trials made in Ireland, been found to be dan- gerous to the lenses, and whilst a high temperature is favourable to the illuminating power of coal-gas, it would, I imagine, be fatal to the employment of mineral oils instead of gas. ‘The latest and most powerful arrangement which Mr. Wigham has made is the so-called Double Quadriform light (figs. 1 and 2). This consists of four superposed 88-jet gas-burners (B.B., &c.) placed alongside of four similar superposed sets, the eight lights being in one plane: parallel to this plane, and at the proper focal distance, are placed eight annular lenses on one side, and eight similar lenses on the other side of the gas-burners. Over each of the burners a chimney is fixed ; these lead into a central flue, C, so arranged that no appreciable interference with the light is produced. The recent experiments made at South Foreland show that similar superposed lights blend into one within 1500 feet from the lighthouse ; and when this occurs (43) Barret1—On the Double Quadriform Lighthouse Lamp. GENERAL VIEW‘ )F APPARATUS. SEcTION THROUGH FocaL PLANE. Scale—+ inch to a foot. G 2 76 Scientific Proceedings, Royal Dublin Society. a beam of eight-fold the intensity of a single light is obtained from the Double Quadriform.' An ingenious contrivance allows the whole arrangement to be rotated without disturbing the gas supply ; thus the entire horizon can be successively illuminated with a beam of light of surpassing power. The Commissioners of Irish Lights have for some months past been testing this new Double Quadriform light, which they have had erected in an experimental house at Howth Head, some 100 .yards distant from the Bailey lighthouse, the well-known powerful first-order light at the entrance to Dublin Bay. The Bailey, it may be mentioned, is also a gas lighthouse that can, by the addition of concentric rings of burners, be rapidly raised when fog prevails from 28 to 48, 68, 88, or 108 jets. Alongside the Bailey light is a powerful siren trumpet, driven by a gas-engine, and blown by com- pressed air at minute intervals during heavy fogs. It so happened that on both the evenings when I had arranged to observe the new light a fog had settled over the Bay of Dublin. My position of observation was near my own house at Monkstown, where, in clear weather, an uninterrupted view over the bay can be obtained, my standpoint being distant six miles, as the crow flies, from the experimental lighthouse. Evening of November 18.—Owing to the intervening fog no trace of the Bailey light could be seen, though its position was well known. The first experiment was the trial of a series of gas- jets fed with ‘“albo-carbon” vapour and oxygen, placed in the focus of a first-order annular lens, such as is used for revolving lights. Brilliant as was the light so produced, it was completely cut off by the fog before it reached me, though the beam was di- rected on to the position I occupied. With a large opera glass I was however just able to make out the light, and saw also the Bailey near it, as a fainter speck of light. Suddenly, at the pre- arranged time, a clear well-defined pillar of light sprung into view, easily visible to the naked eye, and appearing as a large distinct light through the glass. This was the Double Quadriform. In ten minutes, as had been arranged, that was extinguished: complete darkness again covered the horizon. With great difficulty, and 1 The South Foreland experiments were made with a light of half this power. Barrett—On the Double Quadriform Lighthouse Lamp. 77 only by the aid of an opera glass, the Bailey light was occasionally found. After another interval the Double Quadriform was again lighted, and this time made torevolve. As before, it was a striking object to the naked eye, arresting the attention at once, and the period of its revolution was easily noted by the unaided eye. Evening of November 23.—This night the experiments were repeated under still more crucial conditions. A much thicker fog, with drizzling rain, hid all lights from view except those near at hand. ven the two fine lights at the “‘ Poolbeg,” one of them a first-order revolving oil light, were completely obscured, though these lights were less than half the distance of the experimental light. ‘The Bailey hght itself was entirely cut off, and could not be picked up even with a powerful glass. It was then burning, as I learnt next day, its maximum light of 108 jets. Not the faintest trace of the fog siren at the Bailey could be heard, though, as after- wards ascertained, it was sounding with its full power during these experiments. Precisely at the time appointed for the lighting up of the Double Quadriform a sudden glare was seen on the horizon. With the opera glass the shape of the light was easily defined, but - no trace of the adjacent Bailey light could be found, even after the most careful search through the glass. There were in all 632 gas-jets burning, and as these, by prearrangement, were raised and lowered, a flashing light was produced readily seen by the naked eye. The double triform arrangement was next tried: this could be seen faintly with the naked eye. ‘The biform was now tried, but this was invisible even with the glass. This is important as showing the advantage of the multiple lights; for, in this experiment, the character of the lights and lenses were the same as the double quadriform, only of one-fourth the total power. The double quadriform was again put on, and, as before, its glare was at once seen and its position determined with the naked eye, the exact quadrangular shape of the light being easily made out with the glass. All the other lights remained utterly invisible, even with the aid of a good glass and a knowledge of their exact position. I cannot but think that the facts here recorded are worthy of attention. ‘They demonstrate that the double quadriform arrests the attention, as a conspicuous glare to the naked eye, and as a clearly-defined object in an opera glass, through a fog of suf- 78 Scientific Proceedings, Royal Dublin Society. ficient depth and density to cut off a first-class light shining through an annular lens at half the distance, and to quench the sound of a fog-siren adjacent. to the double quadriform. Tt would have been important to have made a comparative experiment with a single electric light of similar intensity, having its beam concentrated by a single annular lens. There were, however, no means of trying this. ‘The recent elaborate Board of Trade investigation at South Foreland led the eminent men of science who conducted the inquiry to the conclusion that the electric light has a slightly greater penetrative power in fog than the triform oil or quadriform gas-lamp with which it was com- pared, the two latter being practically equal, light for light, in all conditions of weather.' Nevertheless, it is much to be desired that some representa- tives of the Trinity Board, or of the Board of Trade, should, whilst the double quadriform is in its present position, come over to Dublin, and in foggy weather test a gas-light twice as powerful . as any they have yet tried, and under conditions exactly similar to those which prevail in the practical use of the light at sea. No doubt, the cost of the double quadriform light is consider- able, both as regards initial expense and consumption of gas. On the other hand, it must be borne in mind that a powerful light of this kind is only intended for the more important points on the Coast, and it is only under exceptional conditions of fog that the full consumption of gas need be resorted to. Moreover, as Mr. Howard Grubb, F.R.S. (who, independently of myself, has recently tested this new light), has remarked in his Report :— “ Heonomic considerations fade into insignificance before the one broad fact that, when occasion does require a powerful light, this arrangement of Mr. Wigham’s gives the power of producing a revolving light unequalled by any existing arrangement.” ! These conclusions, however, seem to be contradicted by, at any rate, one observer (p. 29 of the Report), who, after comparing the lights in ‘‘ drizzling rain and dense fog,’”’ remarks: ‘‘In honesty, I award B [that is, the quadiform gas], the most points, for I consider it the best light from first to last.”’ Deacon XI.—ON A CLOGG ALMANACK IN THE SCIENCE AND ART MUSEUM, DUBLIN. By BENJAMIN H. MULLEN, B.A., Dus. (Puate V.) [ Read, December 16, 1885. ] For many years past this Clogg has been in the Museum, and my attention was first drawn to it by Mr. T. H. Longfield, who had seen somewhat similarly carved sticks in the British Museum exhibited as Norwegian. ‘This account has been prepared and the Clogg figured with the permission of the Director of the Science and Art Museum. It is made of oak, and in length is 1 ft. 8 in., while its breadth is 42 inches. It isin shape a rude and long oval, flat, and from 2 to 3in. thick. The centre portion was cut away, thus leaving four edges (two inside and two out) and four flat surfaces. Two holes for suspension were cut, one at either end; but these were made in a gnarled part of the wood, and it would seem that at some period of its existence it was broken at this weakened part, and bound together again with two fastenings of iron, of which one only remains. At one end there is some carved decoration. This is a very simple design, being merely a line cut into the wood at a distance of about a quarter of an inch from the edge, and running parallel to it ; having at each side of it notches cut in a triangular form; while in the middle are the initials “S. EH.” Beyond what I mention, there is no ornamentation whatever. Almanacks of wood have, I gather, being used from time im- memorial. Dr. Robert Plot, in his Natural History of Staffordshire (folio, 1686), speaks of “An ancient sort of almanacks they call cloggs, made upon square sticks, still in use here among the meaner sort of people, which I cannot but think must be some remains of the Danish Government, finding the same with little difference to have been used also formerly both in Sweden and Denmark, which being a sort of antiquity so little known that it hath scarce been yet heard of in the southern parts of England, and understood 80 Scientific Proceedings, Royal Dublin Society. now but by few gentry in the northern.” He tells us that “there are some few of brass .. . but the most of them of wood, and these chiefly of box; others there are of fir, and some of oak, but these not so frequent . . . and others inscribed in a hollow bone. All people, no question, made them of such materials as they thought fittest for their purpose.” And as to their sizes, he says “there are some public, of a larger size, which hang commonly here at one end of the mantletree of their chimneys for the use of the whole family, and others private, of a smaller size, which they carry in their pockets.” He gives a sketch of one which was “in use in his native country of Staffordshire” at the time he wrote. The usual form was that of a razor-strop, some having four equal surfaces, and others being about 2 inches wide and 3 inch thick. The former, probably a later form, bore the marks for a quarter of the year on each surface; and the latter had the days of half the year on each side. Some were of an elaborate description, showing the Moon’s Changes and the Golden Numbers; but few were so perfect. They were first made centuries before the inven- tion of the printing-press, when a vast majority of the people were unable to read, and were probably originally employed in con- nexion with the churchmen, to whom, in early times, learning was confined. It is likely that one was kept in a public place in every parish or hundred ; and later, one might be found in every house, suspended by a cord or ring, or hung on a nail beside the fire-place in the hall or principal room, where every member of the household might use it. The days were marked on the edges by notches; and every Seventh day was indicated by a longer notch; while Holy Days and Saints’ Days were denoted by signs (peculiar to the occasion) on the flat surfaces, proceeding from the notches in the edge. I cannot find that cloggs similar in outline to that in the Museum were usual. A cursory glance at it would lead one to imagine that it is of some antiquity. In the first place, its shape is very inconvenient for handling. The squared staff with a handle is much less so; and I merely follow the laws of development in assuming that the improved form is of a date posterior to the other. And again (what much more surely goes to prove the local earliness of this class of clogg) the symbols which represent the MuLten—On a Clogg Almanack. 81 Saints’ Days and Festivals are not numerous, nor are the daily notches always correct. A reasonable way to account for this is that when it was made such almanacks were not in very general use, and the signs to denote the different saints not being hitherto necessary were, with a few exceptions, unknown—at all events in the locality in which this clogg was made. The four edges are notched evenly and cleanly, and evidently with a sharp instrument, for in all cases the notches are made by two oblique incisions. The Sunday notches are carried round to one surface, and the signs to the other. Before I go seriatim through the principal days, I wish to say that in identifying the Saints’ Days I have received much valuable assistance from a Paper by Mr. John Harland, F'.S8.A., published ~in 1865 in The Antiquary. The Almanack does not begin with Ist January, but with 14th April, which was reckoned as the commencement of Summer. The carving and initials | mentioned are here, and this alone would lead one to imagine that it is here the reading of the clogg begins. And from the position of the letters “S. H.” this carved end must be the top. Hach quarter reads downwards; the first, from 14th April (Pl. v. fig. 1), goes down the left half for thirteen weeks ; then, turning the stick (fig. 2), it continues on the same half (now at the right hand) from 14th July for another quarter; cross- ing to the other half it goes (always reading downwards) from 14th October for the third quarter; and, again turning (fig. 1), the fourth quarter is read from 14th January. Beginning with Apri/ 14, I find a tree, Valerianus; April 16, St. Magnus, sign, probably some implement for loosening the soil, to signify the commencement of tilling; Apri 25, St. Mark, an unknown sign’shaped like a bottle; May 1, SS. Philip and James, a cross, one arm wanting ; May 3, Invention of the Cross, a cross ; May 14, an unknown sign, perhaps some local festival or family commemoration; May 15, St. Hallvard, a cross; May 18, a scythe : the first hay crop would be about this time; June 10, Eve of St. Barnabas, a cross; June 17, St. Botolph, a cross; June 24, St. John the Baptist, a cross; June 29, St. Peter, a sign, pro- bably meant to represent a key (Janitor); July 2, Visitation of the Virgin, a three-branched candlestick; July 8, a “'T” or rake. This is the last sign in the first quarter; but there is one day too 82 Scientific Proceedings, Royal Dublin Society. many which, if it occur before the 8th, would bring the “T’”’ to the 7th, the Translation of St. Thomas a Becket; or, occurring after, the sign would mark St. Sunniva (July 8), a great holiday. Turning the clogg, I find on July 14 an unknown sign, the middle of the summer-half; July 20, St. Margaret, a cross; July 22, St. Mary Magdalene, a cross leaning to one side, perhaps to show its position when being borne by our Saviour; July 25, St. John the Apostle, an unfinished sign, the previous one being in the way; July 29, St. Olaf (Danish King and Saint), an axe; August 8, the day on which his body was found, a smaller axe; August 10, St. Lawrence, a gridiron, signifying the manner of his death; August 15, Assumption of Mary, a three-branched candle- stick; August 24, St. Bartholomew, a sign shaped like a knife; . September 1, St. Giles, a cross; September 8, Nativity of the Virgin, an unknown sign; September 14, Exaltation of the Cross, an unknown sign; September 29, St. Michael the Archangel, a peculiar sign like a vane or rude balance: this day is not far past the Equinox; October 4, St. Francis, a simple cross. October 13th ends this quarter. Crossing over to the top of the other half, October 14, St. Cal- listus, a fir-tree; October 21, 11,000 Virgins, a cross; October 28, SS. Simon and Jude, a cross; November 1, All Saints Day, a three- branched candlestick ; November 11, St. Martin, a cross, with a second on one arm; November 18, a rude cross or sword ; November 23, St. Clement, a cross; November 25, St. Catherine, a cross; Movember 30, St. Andrew, a cross; December 4, St. Barbara, a sign of un- finished appearance, probably on account of the close proximity of the next; December 6, St. Nicholas, a cross; December &, Concep- tion of the Virgin, a cross; December 13, St. Lucy, a cross; December 21, St. Thomas, a long line, possibly meant for a spear ; December 25, Christmas Day, a circle with radiating points, very likely to represent the guiding star; January 1, Circumcision, a circle with a line running through it; January 6, Hpiphany, a cross; January 11, St. Brictiva, a cross; January 13, St. Hilary, twenty days after Christmas, an unknown sign, similar in form to that on July 14, and probably marks mid-winter, as the latter did mid-summer. ‘This ends the third quarter, and turning the clogg I come to the last. Here is one mark too many. January 17, St. Anthony, a MutLEN—On a Clogg Almanack. 83 cross; January 20, St. Sebastian, a cross; January 25, Conversion of St. Paul, a cross; February 2, Purification of the Virgin, a cross; February 3, St. Blaise, a very rude cross; February 24, St. Matthias, a cross; March 12, Annunciation of Mary, an erect cross, with a “St. Andrew’s cross’’ superimposed, forming thus eight arms. ‘This is the last sign or symbol on the almanack. I have gone through them all; but counting the days to the end of this quarter I find three too many, that is five altogether. These are evidently some of the original markings; but the outside edge at one end bears, besides these, forty-three additional notches. These seem to be much more recent than the others, and to have been made by a different hand, and are neither as deep nor so carefully cut as they. I imagine that some individual found the stick (per- haps a century or two ago), and, supposing it to be an ornament for wall-decoration, thought he would complete the carving left unfinished by the former whittler, and so continued the notches along the edge. The date “3Ist July, 1778,” and some letters, of which part of an “ H” and “en” are plainly seen, were scratched, as with a needle, on one end. But this, I should say, is of com- paratively recent execution. Now with regard to the manner of using this almanack. Every ordinary year ends on the same day of the week which commenced it, and so the next year must begin with the following day (or, after Leap Year, with the second day following); and it would seem that it was a matter of memory with the owners to move back one or more days of the week—the long notches being sufficient to remind them that every seventh day must be set apart for worship. For instance, this clogg begins with a Sunday notch—a long one. Next year this must mark Monday ; so the user would merely have to remember during that year that each notch really signifies the next day of the week; or, in other words, the series of names of the seven days, fifty-two times repeated, is moved back one notch. And so, for Leap Year, two notches. Thus the notches represent the days of the year, one in every seven being devoted to divine worship, to intimate which it is marked with a longer notch. So it is not strictly correct, however convenient, to speak of the long marks as “ Sunday notches.” Speaking of the symbols on the very complete ‘Staffordshire clogg,” Dr. Plot says they “all carry with them a rational impor- 84 Scientific Proceedings, Royal Dublin Society. tance, some of them pointing out the offices or endowments of the Saints; others their martyrdoms ; and others some eminent action or other matter some way relating to the Saint; or else the work or sport in fashion about the time when the feast is kept.” From this extract, and the above description of the.clogg in the Museum, it will be seen that, owing to the frequent use of the cross and the fewness of symbols peculiar to certain saints, either (1) these signs were unknown to the maker, or that (2) he was too indolent to make them. But I think that the carved deco- ration at the commencement, the careful manner in which the original notches, crosses, and other signs are cut, would completely overthrow the latter assumption. Thus it would seem that it was made very many years ago; or, at all events, if so lately as the 17th century, in some remote dis- trict which had but little communication with any centre of infor- mation. Some of the symbols are similar to the Gothic Characters (Dominical Letters) engraved upon the Danish rimstocks and Nor- wegian primstaves (vide Plot’s Nat. Hist. Staf, folio, 1686, p. 421, &c.), but do not seem to occur with any regularity. Vide also Stephen’s Old Northern Runic Monuments of Scandi- navia and England. London and Copenhagen, 1866-7. Vol. 1. pede] _ XII.—NOTES ON SOME RECENT DISCOVERIES OF INTE- REST IN THE GEOLOGY, OF THE PUNJAB SALT RANGE. By A. B. WYNNH, F.G.S., F.R.G.S.1. [Read, February 17, 1886. ] Havine written several Reports and Papers upon the Geology of the Salt Range, I may be excused from any lengthened discussion of the subject now; but it is necessary here—at the distance of some 9000 to 6000 miles from that region—to allude briefly to the position of the Range, and to some of its general features in order that the points I have to notice may be better understood. Geographically, the Salt Range is somewhat peculiarly situated, subtending an angle formed by the meeting of two great moun- tain systems, the Himalaya on one side, and the Suliman Range, associated with the mountains of Afghanistan and Beluchistan, upon the other. From the thrust, apparently, communicated by these ponder- ous mountain masses the Salt Range seems to have been distorted along its general line of direction, as if forced to adapt itself to narrower limits than its full extent would occupy. It presents a grand facade of bold escarpments towards the plains and desert to the south, rising above these generally some 2000 feet, with a cul- minating elevation at Sakésir Peak of more than 5000 feet. From a northerly aspect, the whole range and its plateaux form, rela- tively speaking, a much less lofty feature, bordering the steppe-like upland, undulating country, called the Potwar, or Rawul Pindi District, which rises say 1600 to 1700 feet above the sea. Eliminating the numerous fractured or more complete curva- tures of its strata, the Salt Range may be regarded as presenting, otherwise, a generally uniclinal or semi-anticlinal structure, the outcrops in most cases being presented to the south, and the whole series of which it is formed taking ground so as to pass beneath the Potwar, northwards. Amongst its many interesting features, it may be noticed that the Salt Range is both geologically and economically 86 Scientific Proceedings, Royal Dublin Society. important—geologically, because it 1s one of the only instances within the great realm of India affording the opportunity of studying the structure of more, very much more, than the mere surface deposits overspreading the border lands which intervene between the almost totally distinct areas of the ancient peninsular Indian formations, and the, geologically speaking, as a rule, more ‘modern systems, of which the Himalayan and Suliman mountains are composed. In these two great regions, even though certain contemporaneous formations may exist, the representative groups belonging to each are found to possess most marked dissimilarity of character. Hconomically, the Salt Range is important by reason of the inexhaustible mineral wealth represented in its enormous deposits of rock-salt. Hxtending through a distance of 130 miles, with a known thickness in parts of 550 feet, these deposits have de- manded the construction of a special railway, and the bridging of a great river, the Jhelum (or Hydaspes of the Ancients), to facili- tate the transport of the salt, while the latest information at my command showed the (then increasing) annual salt revenue, to equal £382,653 sterling, although but a few of the mines known were being worked by Government, and the railway I have alluded to was not in existence. One strikingly-pronounced peculiarity of the geological sections displayed by the whole range is, that the series, as found in the centre and at either end, differ all three as to their com- prehensiveness ; groups present in the east die out to the west, while others come into those sections, notably the Carboniferous and Ceratite-beds, and at times some portions, like the typical Olive-beds, disappear both to the east and to the westward. The whole arrangement, though accompanied by some considerable evidence of overlap, shows a continuous tranquillity of deposition and succession, without intervening violent disturbance of any kind, between two constant horizons, that of the salt marl below, and that of the Tertiary formation at the top of the series—that is to say, from a period not newer than Silurian (according to com- petent Palzeontologists) through all the sons of Paleozoic, Meso- zoic, and Kainozoic time, up to the date of the Miocene or later disturbances to which the Salt Range, as well as the Himalaya and Suliman mountains, mainly owe their origin. Wynne—WNotes on the Geology of the Punjab Salt Range. 87 One may well pause before accepting as real this apparent tranquillity of succession throughout so vast a range of geological chronology, but nevertheless the signs of a contrary state of things, so far as the Salt Range is itself concerned (and despite it being now an active earthquake region), if present at all, are so slight and so obscure as to evade the recognition of all but the most visionary of observers. With regard to the Salt Range series generally, after mature deliberation on the evidence as it stood, and after frequently ex- pressed concurrence, from its paleeontological aspect, on the part of Dr. Waagen when in consultation, it has been found to contain groups or divisions reckoned from above downwards, synchronous with the five newest principal divisions of the general geological scale. The Lias was not recognized, but the presence of a Per- mian horizon, at first included in our Carboniferous group, was subsequently recorded by Dr. Waagen (Pal. Ind., ser. x111., Pro- ductus Limestone Group, 1879, etc.).1 This carboniferous or Productus Limestone, &c., is largely developed in westerly localities. Beneath it there are two azoic, or as yet unfossiliferous groups of uncertain age, but below them comes the Silurian or Obolus zone, the age of which was long since determined by the late Drs. Oldham and Stoliezka from the Obolus or Siphonotreta which I had found in it.? This zone rests upon a thick mass of purple sandstones (dying out to the west), which overlies the lowest and oldest group of all, the bright-scarlet Tn this publication, since our joint determinations were reached, Dr. Waagen has in several cases cast doubts upon these results, always avoiding any allusion to his own share therein. In his most recent Paper, Records Geol. Sur. Ind., vol. xix. pt. 1, 1886, p. 22, received since most of the present communication was written, the same habit still seems to cling to him, as where, at p. 33, he relegates the Salt-pseudomorph zone, for which a Triassic age was indicated, at his own suggestion, to the Paleozoic period as not greatly different from older Carboniferous. ; This ‘‘Carboniferous group,’’ as originally undivided, is remarkable for having afforded the earliest known Ammonite, and the very peculiar Brachiopoda, Lyttonia and Oldhamina (Waagen), these or allied forms being only found in two or three other distant eastern localities—one in China, another in the Ural, and again in the Alpine Rheetic. The Oldhamina had previously been described, apparently from a single specimen, as a Bellerophon by de Koninck, whilst the interiorly-ribbed valves of Lyttonia had been mistaken for fish-teeth. Specimens of the fossils were laid before the meeting, and afterwards presented to the Museum, Trinity College, Dublin. (See Pal. Ind. ser. xiil., Salt Range Fossils 1., Productus Limestone Fossils rv. (fas. 2), 391 e¢ seq.) See my Report on Salt Range, Mem. G. 8. Ind., vol. xiv. pp. 95, 221. 88 Scientific Proceedings, Royal Dublin Society. and crimson, gypseous, Salt-bearing marl. In their regular natural order, the newest uppermost, these groups have been classified thus :— (11. Kainozoic~ Siwalik and older, 10. Eocene, Nummulitic, Sandstones and clays. Chiefly limestone, with coaly beds at the very base. ~ ( 9. Cretaceous, Olive and other sandstones, and boulder beds. Mesozoic 8. Jurassic, Variegated sandstones and shales. 7. Triassic, Red flags, greenish shales, &e. 6. Carboniferous (and Per- limestones chiefly, contain- Eee ae SS mian of Waagen), . . Speckled Sandstones, ing the oldest known Am- monite. Sandstoneg, shales, clays. P , 4, Magnesian Sandstone, . Pale or whitish sandstones. aleeozoic 8. Silurian, Dark, clunchy, sandy shale. .2. Purple Sandstone, Sandstone, carthy below. 1. Salt Marl, . Red gypseous marl and salt. Premising that this list is compounded from various sections of the whole range, it will be observed that it includes no established representative of the Devonian or Old Red Sandstone period. Having thus briefly acquainted ourselves with some general features of the range, we may turn attention to the recent very interesting discovery of several determinable fossils by H. K. Warth, Ph.D., in a thin layer of conglomerate occupying a posi- tion near the top of the boulder-beds in the lower part of group No. 9 of the foregoing list, and of others at the base of the over- lying group No. 10. The locality which has furnished the fossils is in the eastern part of the range, about a place called Pid, at some distance north and north-west from the principal salt mines, named the Mayo Mines (after our distinguished fellow-countryman, Lord Mayo, whose brilliant career as Viceroy of India was brought to a melan- choly close by his assassination at the Andaman Islands). Many years ago Dr. Oldham found fossils just beneath the WynneE—Wotes on the Geology of the Punjab Salt Range. 8% coal crops at the base of the Nummulitic limestone hereabouts, but the credit of this discovery of the organic remains, at the lower level just above the local boulder-beds, belongs entirely to Dr. Warth, who has lived ere this, for years, in the salt range, as superinten- dent of the salt mines and Salt Revenue Collector, and who has lately been employed there by Government under the Board of Works, to conduct explorations and boring operations along the irregular, but laterally extensive, coal deposits. Being familiar with the local geology, notices of which have largely entered into his reports on the mineral ground; my friend Dr. Warth was most competent to search the country in even greater detail than my own opportunities afforded means of doing, at any one particular place ; and in this instance he has been most successful. The ,sections of the range in and about this region exhibit the following succession of beds :— 11. Tertiary sandstone. 10. Nummulitic limestone, with the coal beds! in a shaly zone at its base. i a. Pale or light-coloured, and reddish sandstone. 9. ( b. Dark shales and olive sandstones with boulder-beds con- stituting the ‘‘ Olive series’”’ or group. These boulder-beds of g. b. resemble those of the Talchir group of Central India, according to the descriptions given and also verbal communication from Mr. W. Theobald. (I have not seen the Talchir boulder-beds myself.) They occur generally in the lower part of the Olive group, and they include a variety of rounded and sometimes glaciated metamorphic rocks, the glaciation of which was first noticed by Mr. Theo- bald. 7. Red flags usually covered by a mass of red clays, the flaggy beds, characterised by their surfaces being often thickly covered with pseudo-morphic casts of cubical salt crystals. The beds have been doubtfully considered Triassic in my report, at the suggestion of Dr. Waagen. 4. Pale magnesian, and silicious sandstone, and some shales— beds often ripple-marked, generally quite unfossiliferous or obscurely fucoidal. 1 Specimen exhibited of a superior sample. SCIEN. PROC., R.D.S. VOL. V. PT. II. A 90 . Scientific Proceedings, Royal Dublin Society. 3. Obolus band—dark, clunchy, micaceous shales, with small Obolus or Stphonotreta. 2. Purple sandstones of several hundred feet thickness. 1. Salt marl, with salt beds and much gypsum. Except the groups Nos. 3, 10, and 11, of this list, most of the series has proved hitherto unfossiliferous, but in disturbed portions of the group No. 9, presumed to be Cretaceous, I found a few lanceo- late leaves and obscure shells, and in No. 4, some sharks’ and other teeth. It is in the upper portion of the (presumed) Cretaceous zone, with its glaciated boulders, and also in the basal portion of the almost immediately succeeding early Hocene or perhaps partly Creta- ceous group, that Dr. Warth’s recent discoveries of fossils have been made. He writes that at, and below, the outcrop of the coal he found more than one carapace of fossil turtles three-fect in length, accompanied by Belemnites, and fish teeth, all in the same band, probably latest Cretaceous or of earliest Eocene age. He has sent me none of the Chelonian remains, but specimens of the Belemnites and fish teeth, include, according to his own label- tickets, Lamna sp., Otodus sp., Hemipristis sp., and Capidotus sp. Ata lower horizon, but near the last, he found, in the Olive series, a thin: band of conglomerate absolutely continuous for several miles, many of the pebbles in which enclose small Conwlaria,! and a few other shells. ‘They occur also in the matrix in a rolled state, for one specimen, to which Dr. Warth calls special attention, is palpably an abraded, rolled Conwlaria, itself a pebble of the bed, taken from the matrix in this state—according to its label.’ 1 Specimens exhibited, and presented with the others to Museum, T. C. D. ; ? Dr. Waagen in his Paper (‘‘Note on some Palezoic Fossils, recently collected by Dr. H. Warth in the Olive group of the Salt Range.’’—Records G. 8. Ind., xix. p. 22, just to hand) does not agree in this statement of the case. He asserts the pebbles to be concretions and the beds to contain the fossils in sitw. I have other evidence that he spoke of these pebbles as concretions in October, 1885. His Paper had not reached me when I wrote the passage describing the mode of occurrence of the fossils, and my statement was made, both on the authority of Dr. Warth, who is perfectly competent to distinguish pebbles from concretions, whether in, or away from, the bed that had enclosed them ; and also from several examinations of specimens of these pebbles which I had received from Dr. Warth. They are of fine, grayish or brownish non-calcareous sandstone, of even homogeneous texture, well-rounded and worn, the surfaces cutting across the enclosed fossils, and they present no trace of any internal concretionary structure. Even if they have once been possibly nodules, they now bear the entire aspect of worn transported pebbles. i Wynne—Wotes on the Geology of the Punjab Sait Range. 91 The genus Conularia (according to Nicholson) ranges from Older Palzeozoic up to Liassic, but those found by Dr. Warth have been at various dates attributed by Dr. Waagen to different Palao- zoie periods. In March, 1885, he considered them probably Silu- rian;' in October he called them Devonian,’ and early in the present year (1886) he most strongly asserts them to be of Carboni- ferous age.? The several fossils of this thin conglomerate layer, as found by Dr. Warth, have been determined by Dr. Waagen as tollows:—Conularia levigata, Morris; Conularia tenuistriata, M‘Coy ; Conularia, cf. irregularis, Kon.; Bucania, cf. Kuttaensis, Waagen ; Nucula, sp. indet.; Atamodesma (?) warthi, Waagen, n. sp.; Avi- culopecten, cf. limeformis, Morris; Discina, sp. indet.; Serpudites warthi, Waagen, n. sp.; Serpulites tuba, Waagen, n. sp. All of these except the Bucania are figured in Dr. Waagen’s plate, accom- panying his Paper.* The question remains, whence came these fossiliferous pebbles which do not seem to have been transported for any very great distance? Their material recalls nothing with which I could absolutely identify them from memory in the older groups of the Salt Range, their pale colour only—if even this is an original characteristic—might be more suggestive of their connexion with the ‘Magnesian Sandstone (in which I could, however, detect no fossils) Writing about them, from their very locality, Pid, under date December, 1885, Dr. Warth says, ‘‘ From Choah-Saidun-Shah to Mackrach, I have found the thin con- glomerate bank with the pebbles which enclose Conwlarie, and two or three other shells, absolutely uninterrupted in the ‘ Olive series’ (upper portion). I send you a single Conularia (No. 16) which was found in a rounded-off state in the conglomerate. It is evident that the Conularia have not become fossils on the spot, but have been brought from a distant mountain as pebbles.’’ The label of this specimen, No. 16, states, in Dr. Warth’s writing, that he took it ‘‘in its present state from the face of the bed.”’ No person who inspects this rolled specimen can for a moment doubt the accuracy of Dr. Warth’s description or the derived character of itself and the other fossiliferous pebbles. Dr. Waagen’s account of them, for which indeed he advances no valid reasons, must therefore be received with caution or rejected, and with it almost the whole of his speculative deductions regarding the pebbles themselves, the layer which contains them, the ‘glacial boulder beds” of the Range, and his elaborate Paleontological views of the paleozoic and mesozoic geology of the eastern hemisphere and other regions. 1 Records Geol. Soc. Ind., vol. xix. pt. i. p. 1. 2 MS. Correspondence, London, October 9, 1885. 3 Records cit., vol. xix. p. 29. 4 Records cit., p. 25, etc., which reached me only in time to add the list of species given in the Press. H2 92 Scientific Proceedings, Royal Dublin Society. than any other of these older sub-divisions, but there is still the difficulty that a fossiliferous conglomerate band, having an extent of several miles, would indicate the existence of the parent beds within measurable distance, while none of the layers of the Mag- nesian Sandstone group have given encouragement hitherto towards a hope that fossils would ultimately be found in them. Tfwe turn, unwillingly, from the possibility that the fossils were derived from this source, and look for another outside the Range itself, I know of no rocks in the outer Himalayan region to the northwards and north-east, more likely to have furnished the pebbles, and to the southward the flat alluvial plains and desert stretching away towards Sind are unbroken except by a small group of hills on the Chenab River, called the Korana Hills, separated by some forty miles from the Salt Range. I have seen these only from the range itself, but Dr. Fleming has described their rocks in a Paper to the Asiatic Society of Bengal (vol. xxii., new series, 1853), as dark, ‘‘ coarse-brown ferruginous quartzose sandstone, alternating with beds of a greenish quartzite, which in many places passes into silicious clayslate,” the sandstone being traversed by numerous quartz veins containing masses of hematite. Another observer, my former colleague, Mr. Theobald (JJ. As. Soc., Rengal, vol. xxi. p. 674), describes the rocks of these hills as deeply ripple-marked slate—the slaty structure feebly developed, gray in colour, stained red and yellowish, weathering to a deep- burnished brown, &c. ‘The whole of these characters stamp the rocks as widely different from any of the Salt Range groups: this of itself may favour the supposition that they formed the basal portion of a series, some part of which may have existed as the land ‘from whence the Conularia-pebbles were derived. I have elsewhere mentioned the occurrence at more than one widely separated Salt Range horizon' of conglomeratic zones 1 My view as to the difference of horizons at which these boulder-beds occur is not accepted in Dr. Waagen’s recent Paper in the Indian Records previously referred to. He regards the whole of these boulder-beds as glacial, and as occurring upon one horizon (p. 34). Stratigraphic conclusions are only geologically valuable when based upon carefully observed and compared facts and observations. My conclusions are the results of such examinations, and Dr. Waagen has advanced nothing which leads me to abandon them, while, I regret to say, the more I consider the matter the less reason I see far adopting his views to the contrary, these being directly at variance with strati- graphical facts. : Wrnne—Wotes on the Geology of the Punjab Salt Range. 98 having usually a soft matrix and intensely hard metamorphic pebbles and boulders. ‘They are found just at the upper surface of the salt marl in the west part of the range, and at one or two other stages before being again largly developed in the lower part of the Olive group, which contains the Conularia-layer, apparently at a slightly higher horizon. There is no known source for any of the various metaphoric rocks to be found in these boulder-beds, includ- ing a red granite which would be easily recognized either among the Himalayan or Afghan mountains, if it existed in any force, so that here again an old metamorphic region, lying to the southward, suggests itself as forming land at various periods during the long record of the Salt Range rocks. Whether this may have formed, or not, a portion of the lost continent, Lemuria, supposed to have at one time united Africa with India, it is not for me to say; but failing the future discovery of similar forms or others of similar age in the hitherto azoic beds of the older portion of the Salt Range series, | am disposed to think these pebbles must have come from lands and rocks long since buried beneath the country southwards of the Salt Range, now occupied by the arid plains and deserts - which lie in this direction. By Wes oi XIII.—ON THE DIFFERENT VARIETIES OF IRISH PAVING- SETTS. By PROFESSOR EDWARD HULL, LL.D., F.R.S., Director of the Geological Survey of Ireland. [Read, February 17, 1886. ] Tur Royal Dublin Society seems the most suitable place for the discussion of all questions connected with the industrial products of Ireland, amongst which may be reckoned paving-stones. The production of paving-stones (or paving-setts, as they are generally called) is comparatively recent in Ireland, as this country has for a long time been dependent on imported stone, particularly from North Wales, notwithstanding that there are equally good sources of supply in various parts of Ireland itself. The discredit of depending on a foreign supply for a material which is abundant at home is happily being removed; and it is not improbable that, ere long, the course of this trade will be reversed; and that, instead of being a large importer, Ireland will become a large exporter of this useful commodity ; in fact, I may say that the current has already changed. In considering the question of the utilization of paving-setts, we have first to consider their qualities; next, the varieties of mineral composition and mode of formation; and, lastly, the sources of supply; which, as far as this Paper is concerned, will be specially restricted to those now existing in Ireland. I. Qualities requisite for Paving-setts—The qualities requisite for paving-setts may be described under three heads :— (a2) Uniformity of texture and composition, which we may call “ homogeneousness” ; (6) Toughness; and (c) Roughness of surface. A few observations may be made upon each of these heads :— (a) Uniformity of Texture and Composition.—This is an essen- tial quality in paving-setts, as it will be evident, on reflection, Huri—On the Different Varieties of Trish Paving Setts. 95 that should the stone be wanting in homogeneousness it would be liable to break down under traffic, the softer portions giving way before the harder, and thus causing the blocks to collapse. It will be found that all the rocks used for the production of setts possess this quality, though differing from each other in other respects. (b) Toughness—I prefer the term to hardness, inasmuch as many very hard rocks—such as flint, chert, and quartzite, are deficient in toughness; and are, consequently, liable to crack, and splinter upon percussion. Such rocks are therefore unfitted as materials for paving-setts, which ought to be capable of with- standing the percussion caused by the sudden shock of the wheels of heavily-laden vehicles passing over their surfaces, not to speak of those caused by the iron-shod feet of dray-horses. (c) Roughness of Surface.—This is a quality not less valuable than that of toughness, and the best varieties of paving-setts are those which combine these three qualifications. It has been found by experience that some of the harder kind of paving-setts are liable, after some wear and tear, to have the surfaces worn smooth, and actually to become polished. In this state they become dan- gerous for street traffic; and, notwithstanding their durability, they are held in less favour in the large manufacturing towns of the North of England than was formerly the case; and other kinds of stone, though somewhat softer and less durable, are preferred, in consequence of their ability to maintain a rough surface. II. Varieties of Stones for Paving-setts.—I now pass on to con- sider briefly the varieties of stone suitable for the manufacture of paving-setts, and therefore combining in a greater or less degree the qualities previously enumerated. ‘They may be considered under three heads :— (a) Those of sedimentary origin, such as grits and sand- stones. (b) Those of igneous origin, of a granitoid character; including quartz-porphyries. (c) Those also of igneous origin, but belonging to the variety commonly known as “ whinstone”; in- cluding basalt, dolerite, diorite, and felstone, 96 Scientific Proceedings, Royal Dublin Society. (a2) Grits and Sandstones.—The formation which yields this class of paving-setts in greatest quantity is the carboniferous; and beds belonging to the millstone grit division in Lancashire and Yorkshire are largely worked for paving-setts. ‘This rock, owing to its granular structure, is probably the softest of all the varieties of stone capable of being used for paving purposes; still, it is very largely used in the streets and roads of the North of England for pavements; and is found, when properly selected, to answer well where the traffic is not excessively heavy. Gritstones have the useful quality of preserving a rough surface; and can be set quite close, side by side. As far as I am aware, there are no paving- setts made from the carboniferous rocks of Ireland, though I have no doubt some of the beds of grit of this formation in the counties of Sligo, Fermanagh, Leitrim, Donegal, &c., are capable of pro- ducing them. In Belgium the gritstones of the Upper Devonian formation, known as the ‘ Psammite du Condroz,” are very largely used for paving the streets of the manufacturing and other towns. (6) Granitoid Varieties. —This group includes not only granites, but quartz-felstones and porphyries ; in which the constituents are quartz, felspar, with mica or hornblende as accessories. ‘These components are, more or less, in a crystalline condition, and have solidified from a state of igneous fusion. In consequence of this, the mineral constituents are firmly bound one to the other, and a condition of “toughness” is imparted to the mass favourable to its use for paving-stones. The presence of mica, if in large flakes, would prove a source of weakness, in consequence of its want of cohesion with the other minerals; but when in minute flakes, this mineral, by its disintegration, enables the stone to preserve a con- stantly rough surface. Paving-setts belonging to this group are worked at Bessbrook, Goragh Wood, and Castlewellan, in Ireland; and at Mount Sorrell, in Leicestershire. (c) Whinstones.—The stones belonging to this third division differ from those already described in texture and composition. They consist of crystalline aggregates of felspar and augite, or felspar and hornblende, together with magnetic iron-ore dis- seminated in minute grains, and with occasionally other minerals, such as olivine, and chlorite, in small quantities. The presence of Huti—On the Different Varieties of Irish Paving-Setts. 97 iron gives to these rocks a higher specific gravity than those of the granitoid class, in which iron is either absent or ocours in exceed- ingly small proportions. Thus, while the average specific gravity of granitoid rocks may be taken at 2°65, that of the whinstones may be taken at 3:0; so that, in the case of a contract for purchase by weight, the granitoid rocks are in favour of the purchaser. : The rocks of the “ whinstone” class are generally exceedingly tough, and setts taken from them are capable of withstanding the heaviest traffic ; but their chief defect is the tendency to wear into smooth surfaces and become slippery. Being essentially compact in structure, the component minerals are incapable of individually disintegrating, and thus preserving a rough exteridr where subjected to wear and tear. This is the case, at least, with regard to the finer and denser varieties; and it is therefore important, in select- ing a stone of this class for paving purposes, to see that it is largely crystalline-granular, as such varieties will be less liable to wear smooth. Quarries for making paving-setts from whinstone have been for some time past opened at Ballintoy, Co. Antrim, and Arklow, Co. Wicklow. The Welsh setts from the quarries at Penmaen Mawr belong to this group, and have been largely used not only in England but in Ireland, where stone of similar or identical qualities is to be found in abundance. The great obstacle to the manufacture of paving-stones in this country has been—not so much want of capital or enterprise on the part of the employers of labour—as want of knowledge in the art of shaping the stones on the part of workmen. This want is now being supplied, as Irish stonemasons are being instructed by workmen from Wales and England ; and as we possess abundance of the raw material, we may look forward with hope to a large and flourishing trade in various parts of the country. In considering the qualities of different varieties of paving- setts, and the purposes to which they should be applied, I think we may fairly come to the conclusion :—that for streets subject to excessively heavy traffic, the whinstone varieties, especially those of largely-crystalline structure, are the more suitable; while for streets with ordinary traffic, those of the granitoid class will be found sufficiently durable, and, from wearing rough, more advan- tageous. 98 Scientific Proceedings, Royal Dublin Society. Trish Localities for Paving-setts.—Having personally visited most of the quarries from which paving-setts are now being obtained, I will, in conclusion, give a short account of each, commencing at the north coast of Co. Antrim. Ballintoy Quarry.—This quarry is worked by the Eglinton Chemical Co., Limited. The rock consists of a largely-crystalline dolerite, forming a cliff 80 feet in height, in rude columns, and about 200 yards in length. The stone is shipped at the little harbour of Ballintoy and sent to Glasgow, Londonderry and other places. It consists of a crystalline aggregate of augite, plagio- clase, olivine, and magnetite. I understand that paving-setts could be delivered in Dublin, at 22s. per ton. Goragh Wood.—This quarry belongs to Messrs. J. Robinson and Son, of Belfast, and is opened by the side of the Great Northern Railway at the junction for Newry and Armagh. The rock consists of fine-grained granite of quartz, felspar, and black mica in small flakes. The paving-setts are sent to Belfast and other parts of Co. Antrim, and have likewise been used in Man- chester, Oldham, Liverpool, Rochdale, and other towns in England ; and the stone for building and decorative purposes, takes a fine polish. It can be delivered in Dublin at prices varying from 18s. 6d. to 21s. per ton, according to the size of the “ cubes.” The Castlewellan granite is considered more suitable than the Goragh Wood stone for paving, being somewhat harder; and is being used by the Belfast Harbour Commissioners for paving the street along the Donegall-quay, where the traffic is naturally heavy. For building purposes the stone was selected, amongst other places, for the Bishop Rock Lighthouse at St. Mary’s Island, Scilly. Paving-setts of this stone can be delivered in Dublin at prices varying from 19s. 6d. to 22s. per ton, according to the size of the “ cubes.” Bessbrook, near Newry.—These quarries, which belong to the Bessbrook Granite Co., Limited, are opened in granite, consisting of quartz, felspar, and black mica in small flakes. The rock is ex- tensively worked both for setts and also for building and ornamental purposes, and the stone is shipped at Newry, or sent by rail. I understand the company have offered to supply paving-setts to Dublin at 22s. 6d. per ton, though the regular price is 24s. The stone is used in various parts of England, including Manchester, Hurti—On the Different Varieties of Irish Paving-Setis. 99 Chester, and Wigan, and for several of the approaches to railway stations where there is heavy traffic. Arklow, Co. Wicklow.—These quarries, which belong to Mr. Parnell, M.P., produce three separate varieties of stone. From the samples I have received they may be described as belonging to the whinstone class. No. I. is a coarse-grained crystalline diorite, or greenstone, of a dark-green colour, consisting of felspar, hornblende, and some magnetite. It occurs in the form of a dyke penetrating the Silu- rian slate along the banks of the Aughrim river, about a mile above Wooden Bridge Inn. The rock breaks with a rough surface, and shapes well into setts. No. IT. is a coarsely-crystalline felstone of a dark-blue colour, with a little pyrites in distinct crystals. It breaks with a rough surface, and is lighter than No. I. No. III. may be described as a compact felstone of a bluish colour, with even fracture. Setts from this rock would be liable to wear with a smooth surface, on which account it is, in my opinion, inferior to Nos. I. and II. The stones from the Arklow district are now being largely used in the city of Dublin; and I understand from Mr. Parke Neville, the Borough Engineer, that the price paid under last contract was 24s. per ton delivered at Harcourt-street Station or on the Quays. Tn offering these few remarks on the nature and sources of Irish paving-stones, I have no intention of personally recommending any special stone to public favour; but only of affording data on which selections may be made for special purposes and localities. It will be gathered from what I have stated that, in my opinion, different varieties of stone have their own special uses ; and that, in provid- ing for the requirements of a large city, certain varieties may be- more usefully employed in one part than another, according to the nature and amount of the traffic. [ 100 ] XIV.—NOTES ON TWO IRISH SPECIMENS OF EDWARDSIA TIMIDA (QUATREFAGHS). By G. Y. DIXON, M.A. (With Prats VI.) [ Read, January 20, 1886. ] Edwardsia timida (Quatrefages). HistToricat. Edwardsia timida, . . Quatrefages, 1842, Ann. des Sci. Nat., Nex. 2) Xvill., sp. 7.0, pl 2aarosmle Edwardsia harassi, . . Quatrefages, 1842, idid., p. 71, pl. 2, fig. 2. Edwardsiella harassi, . Andres, 1884, Die Actinien, Fauna u. Flora, d. Golfes, v. Neapel, ix. p. 94. Edwardsiella tinuda, . Andres, 1884, ibid., p. 96. Tus species has previously been recorded from only one dis- trict—Chansey, Manche (North France), where it was found by Quatrefages.. Last autumn, however, I had the good fortune to find two specimens at Malahide, county Dublin. With the excep- tion of an immature Edwardsia found by Professor A. C. Haddon at Salthill, Dublin Bay,’ this is, I believe, the first example of this genus recorded from Ireland. Quatrefages separated E. timida from E. harassi on four grounds:—(1) the tentacles in E. timida, he thought, were in a single row, while those of E. harassi were arranged in two rows. I believe this distinction ig only due to the different state of extension of the disk. For when the animal is much extended the tentacles appear to be uniserial; but when it is not extended to its full size they seem to be in two distinct rows, alternately arranged. (2) Quatre- fages describes the mouth and disk of H. timida as flat, and those of E. harassi as being raised so as to form a terminal papilla. This distinction also I believe to be based on a merely temporary condition : in both my specimens the mouth and disk were continu- 1 Proc. Roy. Ir. Acad., 2nd ser., vol. iy., p. 527. Dixon—On Two Trish Specimens of Edwardsia timida. 101 ally undergoing changes of form, being sometimes flat, sometimes raised into a pointed cone, with the lips protruded and folded back. (3) Quatrefages makes the consistence of the investment a further ground of distinction. Andres, however (/.c., p. 93), refuses to give any weight to such a matter as this, as a specific distinction among the Edwardsidae, considering that the nature of the invest- ment largely depends on the environment of each individual. In connexion with this question, too, it should be borne in mind that Quatrefages found the one example on which he rests his L. harassi . in a different locality from where he found the specimens which he referred to LH. timida. (4) Lastly, £. timida measures 6-7 em. in length, while #. harassi only measures 55cm. This would not appear to me to be an important difference, but merely to depend on the temporary elongation or contraction of the animal. Quatrefages referred all Hdwardsidae to one genus, Kdwardsia. Andres has constituted two genera in the sub-family, reserving the name Kdwardsia for all such species as have sixteen tentacles, and classing under the name Edwardsiella all those that have twenty or more tentacles, including, of course, the EL. timida and EL. harassi of Quatrefages. In the present state of our knowledge no advan- tage would seem to follow from multiplying the genera, and there- fore I have adhered to the nomenclauture of Quatrefages. My two specimens evidently belong to the same species, but as they differ somewhat from one another, I have described both. All the features in the following description are common to both specimens, except where a separate description is given of each under the several designations of a and 3. DESCRIPTION. Form.—Column thin, very much elongated; divided into physa, scapus, and capitulum. Physa—delicate, smooth, retractile within the scapus ;- when fully distended exceeding the scapus in diameter, and sometimes rising from it by an abrupt step; studded with minute suckers ; divided into eight segments by eight lines, which correspond with the insertions of the mesenteries ; no terminal pore is present. Scapus—long, slender, vermiform, slightly tapering towards either extremity, cylindrical, smooth, without tubercles or longitu- dinal ridges or furrows; clothed with a transversely corrugated 102 Scientific Proceedings, Royal Dublin Society. : investment, which is opaque, leathery, flexible, and rough; the investment breaks off abruptly at each of its extremities, and is more deeply furrowed and wrinkled, and studded with particles of sand at its anterior end. When the animal is much contracted eight longitudinal ridges sometimes rise at the anterior extremity, and extend for a very short way down the scapus: no other longi- tudinal marks are visible except when the animal is much dis- tended, in which case the lines corresponding to the insertions of the mesenteries can be seen through the investment, especially in the region towards the physa. When the investment is removed the insertions of the mesenteries are seen in the body-wall as in Peachia hastata. Capitulum—delicate, retractile within the scapus, columnar ; its body-wall is divided perpendicularly into eight broad regions, separated by as many narrow flutings; the broad regions (which apparently correspond to Gosse’s “ invections”’), being somewhat swollen. Tentacles—marginal in two rows, the inner usually pointing upwards, the outer extending horizontally ; obtuse, slender, hardly tapering towards the top. aa—tentacles 22 in number, 8 being arranged in the inner row, one at each end and three at each side of the mouth. ach of the inner tentacles thus occupies the centre of one of the inter-mesen- terial chambers. From between the mesenteries which run into either end of the mouth (“the directive mesenteries’’) there rises but one tentacle. At one end of the mouth each of the chambers adjoining that formed by the directive mesenteries have four ten- tacles—one in the inner and three in the outer row. ach of the remaining chambers gives rise to three tentacles—one in the inner and two in the outer row. ((—tentacles twenty in number, arranged ten in the inner and ten in the outer row. Disk—usually elevated into a cone; each inter-mesenterial space being arched upwards between the mesenteries, and having a some- what puffed and swollen appearance. Mouth—prominent ; lmear; lips frequently protruded and, folded back over the disk. Colour.— Physa—pellucid white, marked with eight white lon- gitudinal lines. Dixon—On Two Irish Specimens of Edwardsia timida. 108 Scapus—(1) Investment ; brownish-orange for two-thirds of its entire length ; at the anterior end it grows darker, till it becomes almost black at the top. (2) Body-wail—pellucid pale pinkish flesh-colour, showing the insertions of the septa as whitish longitudinal lines. When the scapus is much distended the orange convoluted edges of the mesenteries may be seen hanging free in the interior. - Capitulwm—transparent brownish red, deeper above, paler below; each invection bears an arrow-head mark of pure opaque cream-white pointing upwards, and about one-third of the total length of the capitulum below the tentacles. Between these arrow- heads and the scapus, on either side of each invection, closely adjoining the arrow flutings, there is an opaque white linear spot, running parallel to the direction of the flutings. When the animal is viewed by direct light, the flutings and invections seem to be separated by lines of transparent white; but when the animal is seen by transmitted light these markings disappear, and the opaque marks mentioned above seem black. The red colour of the cesopha- gus may be seen through the body-wall of the capitulum. When the animal is contracting, rings of pale brownish-red appear to encircle the capitulum, and are especially conspicuous across the white arrow-heads. These rings are really wrinkles caused by the process of contraction. Their presence proves that the white marks are imbedded in the substance of the body-wall. Sometimes the white colouring on the disk shines through the tentacles so as to be quite visible at the margin, when the animal is seen from the side. ‘This effect, at the first view, would almost lead one ta sup- pose that the margin, or top of the capitulum, or the back of the tentacle foot, was marked with a white band; but this is not really so, the back of the tentacle foot and the margin being quite mono- chromatic. Tentacles—brownish-red, transparent, apparently with a core of the same colour, only denser. No bands or markings are present, the colour being uniform throughout. Disk a—cream-white, with the eight septa showing through as brownish-red lines; the gonidial and gonidular tentacles have a dense white blotch at their base, but no other mark. Lach of the remaining six primary tentacles has a band of white which encloses the front, but does not extend round to the back of its foot. Below 104 Scientific Proceedings, Royal Dublin Society. this band there is a V-shaped brownish-red mark, the apex of which points towards the mouth ; while on either side of the mouth are two slightly-curved short linear marks running towards the mouth. There are no markings on the disk which correspond with the secondary tentacles. Disk (—translucent pale brownish-red, with no coloured mark- ings corresponding to the mesenteries; the bright-red oesophagus shining distinctly through in the centre; the mouth encircled with an opaque white band, which was shaded off gradually into the brownish-red which forms the general colour of the disk. Hach tentacle is marked at the foot with a crescent of opaque white : these crescents, though they come very close to each, do not coalesce, but are separated by a thin streak of the brownish-red which is prolonged between them. ach crescent is shaded off into the general colour of the disk on the side towards the mouth, while the side next the tentacle is sharply and definitely drawn. Mouth a—with brownish-red lips; on the inner edge of the lips are six pairs of small white spots, which correspond with the six lateral primary tentacles. Mouth (s—with bright-red lips, quite plain, without marks or spots. Dimensions.— Length—contracted, 35-40 mm. A expanded, 65-70 ,, Expanse of disk and tentacles, 8 mm. Diameter of scapus, greatest, 5 ,, ” 12) least, 2 ” Locality.— Malahide, county Dublin, south bank of the estuary, opposite the Hotel; in mud, among stones, at extreme low water. I cannot conclude this description without stating that I am well aware of the difficulty raised by the account given of the arrangement of the tentacles in example 8. However, I can only say that, after repeated observations made during the three months the animal was alive—observations always made, I may add, almost in the hopes of ascertaining the contrary to be the fact—I am quite certain that ten, and not eight, was the number of the ten- tacles in the inner row. In connexion with this point it is worthy of note, that Quatrefages, in his description of the disk of the very Drxon—On Two Irish Specimens of Edwardsia timida. 105 species now under consideration, says, five lines of a violet black run from the circumference of the disk to the mouth, and that in the intervals between these lines five others of the same colour, only less marked, are to be seen. Agassiz, too, is evidently of opinion that there need not be an absolute conformity between the tentacles and mesenteries in Edwardsia. In describing the de- velopment of a larval Edwardsia (Arachnactis), he says: ‘ Les nouveaux tentacules se forment independamment des cloisons ova- riennes, et je n’ai pas pu en suivre l’indice exactement, relativement aux huit cloisons principales; mais comme je l’ai deja indiqué, les jeunes tentacules se forment toujours vers une des extremités— a V’extremité opposée de la bouche ou se trove le long tentacule impair.”—Archiv. Zool., 1873, vol. X11, p. XXXVill. Hapsits. The habits of my two specimens during the few months they lived in captivity were very much the same as those described by Quatrefages and by Andres in his description of a kindred species (Intorno all’ £. claparedii, Mittheil. Zool. Stat. z. Neapel, 1881, 11., p. 129). I kept them in a small glass jar with about one-fourth inch of sand. They sometimes adhered to the sides of the glass vessel by the physa, sometimes burrowed in the sand, leaving only the capitulum protruded, and sometimes they wallowed about on the surface of the sand quite free: in the last-mentioned condition they were usually distended more fully than when fixed in the sand, or when adhering by the physa. Their shape and dimensions varied greatly according to the degree of their distension, but I think hardly to the extent observable in other free anemones, the presence of the investment seeming to limit them somewhat in this respect. There was generally a constriction marking the division of the scapus from the physa; and sometimes, when the animal was contracted, the capitulum was separated from the scapus in the same manner ; but I never saw these constrictions passing up or down the body, as one sees in Halcampa or Peachia; on the contrary, they appeared to be fixed and constant in their position. The physa was frequently covered with particles of sand, which seemed to be adhering in a thin coating of slime, for if the physa, SCIEN. PROC., R.D.S. VOL. Y. PT. IT. 106 Scientifie Proceedings, Royal Dublin Society. when in this state, was suddenly drawn up into the scapus, the particles of sand formed a ring round the posterior portion of the investment. When alarmed, it withdraws its disk and tentacles into the capitulum, and the capitulum itself into the investment, by a process of invagination. During the earlier stages of this process the white markings on the disk and on the capitulum may be detected through the body-wall, their position being inverted by the invagination. NOTES ADDED IN PRESS. Since the above Paper was written I have obtained six more specimens of E. timida at the same locality. In colour the new specimens differ considerably from each other, and from those already described. I have set out the points of difference of all the individuals I have seen in the accompanying Table. The constant characteristics of the species seem to be— 1. The ratio of the length to the diameter, 1 to 18. 2. The pellucid pink colour of the capitulum, disk, and tentacles, varied with opaque white marks. 3. The absence of tubercles and longitudinal ridges. EXPLANATION OF PLATE VI. Edwardsia timida (Quatrefages). Fig. 1. Side view of animal, natural size. » 2. Side view x 4 diam. », 98. Diagrammatic sketch of the disk of a x 8 diam. ,, 4. Disk of 6 x 8 diam. », 9. Capitulum closed x 6. Numb Specimen. of Tentac a 22 20 Y 20 ) 18 E 92 j 21 n 29 0 24 ur of Disk. haracteristic marks in e). with white crescents of the tentacles, and a ound the mouth. pink: at the foot of e is a white mark like very broad cross-bar : sed in a white ring. , with decided white und the feet of the ten- the mouth inclosed in a rose, with decided white pees the feet of the rom each of which two radial lines run towards which is inclosed by a lucid pink, with white wee the feet of the ten- he mouth inclosed by a , but speckled with very Ke spots; the feet of the closed in white cres- houth inclosed in a white ot observed. | (Zo face page 106. Colour of Investment. Tawny orange, black above. Tawny orange, black above. Pale drab throughout, with a black irregular stain on the scapus. Tawny orange, paler above. Tawny orange, black above. Tawny orange below, pale drab above. Tawny orange, black above. Tawny orange, black above. Specimen. Number fo) Tentacles. Colour of Tentacles. Colour of Capitulum. Colour of Gsophagus. Cok ur of Disk. (Zo face page 106. Colour of Investment. a y 22 20 20 18 22 21 22 24 Pellucid brownish-pink, not tipped with white. Pellucid brownish-pink, not tipped with white. Pellucid pink; tipped with white, which is scarcely perceptible in full expansion. Pellucid pink ; tipped with cream- white, and marked with minute brackets )( on the back at the foot. Pale pellucid rose, tipped with white cream. Very pale pellucid pink, with con- spicuous white tips. Pellucid pink, with faint white tips. Pale rose, not tipped with white. Pellucid brownish-red, with decided arrow-heads and linear marks. Pellucid brownish-red, with decided arrow-heads and linear marks. Pale pellucid pink, with blunt ar- row-heads, and no linear marks. Pale pellucid pink, with irregular white marks instead of arrow- heads, and with very conspicuous linear marks. Pellucid pink, with arrow-heads and linear marks. Very pale pellucid pink, with slight and flattened arrow-heads, and no linear marks. Pellucid pink, with irregular marks instead of arrow-heads, and with the usual linear marks. Pellucid pink, with arrow-heads and linear marks. Brownish-red. Brownish-red. Brownish-red. Brick-red, with white longi- tudinal marks, which may be seen through the capi- tulum. Brick-red, with white longi- tudinal marks, which may be seen through the capi- tulum. Yellow ochre. Brick-red. Brick-red. White, with «characteristic marks in red (as abo ve). Pellucid pink, with white crescents at the feet of the tentacles, anda white ring round the mouth. Pale pellucid pink: at the foot of each tentacle is a white mark like a H, with «1 very broad cross-bar : mouth inclosed in a white ring. Pellucid pinlx, with decided white crescents rcund the feet of the ten- tacles, and he mouth inclosed in a white ring. Pale pellucid rose, with decided white crescents inclosing the feet of the tentacles, from each of which two short white radial lines run towards the mouth, which is inclosed by a white ring. Very pale pelllucid pink, with white crescents round the feet of the ten- Tawny orange, black above. Tawny orange, black above. Pale drab throughout, with a black irregular stain on the scapus. Tawny orange, paler above. Tawny orange, black above. Tawny orange below, pale drab above. tacles, and he mouth inclosed by a white ring.) } Pellucid pink, but speckled with very minute white spots; the feet of the tentacles inclosed in white cres- cents, the niouth inclosed in a white ring. [Not observed. ] Tawny orange, black above. Tawny orange, black above. “F } DAK Do Sait @ ‘ ae IDOE Pom, i XV.—NOTE ON SOME IMPROVEMENTS IN EQUATORIAL THLESCOPE MOUNTINGS. By HOWARD GRUBB, F.R.S. [Read, January 20, 1886.] New Declination Slow Motion.—The slow motion arrange- ments usually used in Equatorials are of either of two forms, viz. :— (a) an endless screw working into a sector or portion of a toothed circle of long radius; or, (0) A screw applying, or pushing directly against an arm, that arm being kept in contact with the screw by a spiral or some other form of spring having a considerable range of motion. The first (a) possesses the disadvantage that, however carefully made, it is impossible it is quite free from “loss” or “ back lash”’ ; and, consequently, the position of the telescope is not perfectly determinate in declination, which fault is inconvenient when deli- cate measures are required. The second (0) has practically no “ back lash,” as spring keeps the arm in perfect contact with screw, but it has the disadvantage, that whatever range of motion is required, the spring must be capable of working through the same range; consequently the spring will be much stronger in action at one end of the range than the other, unless it be made very long indeed, in which case its action is uncertain and unpleasant. To remedy these defects the author has devised the following, which possesses the advantages of both :— ABOD (fig. 1) is a portion of the arms attached to telescope, or cradle, on which is planted the block (4), forming the bearing of the screw. ‘The nut (7) is in the form of a ball working in a socket on the extremity of the clamp-arm EFG. A short stiff spring (S) is attached to this clamp-arm, bearing, not directly against any part of other arm, but against end of a second screw of same pitch as the main screw, the nut of which (00) is toothed on edge, and works into a wheel of equal size (yp) on main screw. The point of this second screw, therefore, advances as much in one direction as the frame ABCD is carried in other, according as the milled head 108 Scientific Proceedings, Royal Dublin Society. is turned; and, consequently, the point of the screw does not sen- sibly vary in its position with respect to the clamp-arm EFG. A short stiff spring can therefore be used, and the disadvantage above- mentioned disappears. New Position Finder.—The inconvenience of having to rise from the observing-chair to read the Right Ascension and Declina- tion circles of an Equatorial has tempted opticians to devise many contrivances by which the circles may be read from eye-end of tele- scope. In some cases the following piece of apparatus will probably be found useful. It can be attached at any convenient position near eye-end of telescope. It (fig. 2) consists of a circular level Gruss—IJmprovements in Equatorial Telescope Mountings. 109 mounted on two axes at right angles to one another, thus allowing of universal motion. The apparatus is so mounted on telescope that one of the axes (aa), which may be called its declination axis, is parallel to declination axis of telescope. If, now, telescope be pointed to equator, and meridian, and circle (cc) on declination of axis of position-finder made to read zero, the other axis (pp), which may be called its polar axis, will be parallel to polar axis of equatorial. The bubble of level L is now adjusted to centre when the circle (45) on its polar axis reads zero. It is evident now that the Right Ascension and Declination circles of position-finder will read the same as the Right Ascension and Declination circles of telescope, at any position provided the bubble be brought to centre of glass. To find any object, it is only necessary to set the circles of this little position-finder to same readings as the Right Ascension and Declination circle of telescope itself would have to be set to, and turn instrument round till bubble becomes level. Addition to Existing Arrangement for Slow Motion in Right Ascension.—The slow motion in Right Ascension - FIGS \\ i} 1] ty Be if Vi which the writer generally applies to his instruments has often been described. It consists (fig. 3) of a pair of differential wheels (dd’) fixed on the adjoining ends of a pair of shafts (SS) in line 110 Scientific Proceedings, Royal Dublin Society. with each other, into which wheels a pinion p is geared, this pinion being carried on a stud fixed to a disc (e) revolving free on shaft: when not in use the pinion acts as a clutch, and both wheels and shaft, pinion and disc, all revolve together by clock. When a fine motion is required in either direction, a cord passing over a eroove in disc is pulled in one direction or other; the pinion revolves round differential wheels, and as the wheels have not exactly the same number of teeth, produces a differential motion which practically accelerates or retards clock-movement as long as cord is pulled, but the moment the cord is released all revolve together, as before, at normal rate. The only objection that has ever been made to this motion is, that it requires two hands to work it—one to keep the cord a little “taut,” and the other to pull, as otherwise the cord would slip round without gripping. There is more difficulty in overcoming this objection than may at first sight be apparent, for it will not answer to apply anything which will produce friction between cord and pulley, except at the moment the cord is pulled. The following plan has, however, proved quite successful :— A little frame (aa) is fixed over the pulley disc in such a manner that it is capable of a rocking motion in centre (a). This frame carries four rollers (0, 0’, c,c’). The pulleys (0, 0’) are simple grooved rollers; (¢, ¢’) are covered with india-rubber rings. When cord kf is pulled, the whole frame slightly tilts, and brings the rubber-covered roller (¢’) into good contact with cord on disc pulley, and prevents it slipping. When cord /’ is pulled the other rubber-covered roller (c) is brought into contact. The moment either end of cord is released the rollers return to their normal position out of contact. As the roller which is brought into contact is nearly a whole cir- cumference from the point where the cord is let off, the cord has a good grip on the pulley, and never slips. New Slow Motion im Right Ascension.—The recent advances in celestial photography have rendered it desirable to have a more delicate and accurate slow motion in Right Ascen- sion than has hitherto been required. ‘The necessity for this is partly due to the fact that up to the present no clock-work has been found sufficiently accurate to keep the star absolutely steady on the photo plate for the long period necessary to obtain an image of faint stars; and consequently it has been the practice Grusp—Improvements in Equatorial Telescope Mountings. 111 for the operator to have a very powerful finder-telescope with cross-lines set on a particular star, and to watch this star during the progress of exposure, and if he saw it vary its position by the smallest quantity to bring it back again by the slow motion of the instrument. Anyone who has experience in these matters will know how very difficult it is to obtain a slow motion which is perfectly certain in its action, has no back lash, and acts promptly, without and at same time setting the instrument into swing. The new slow motion which the writer has devised is not subject to these faults, and may thus be described :— In the slow motion by differential wheels, described above, it is evident that if dise carrying pinion be simply stopped, a retarda- tion or acceleration (according to relative positions of wheels) will be produced, to a slight extent. Suppose the wheels to have twenty- nine and thirty teeth, the speed will be altered =, part quicker or slower. Now, suppose two such differential sets of wheels be placed side by side on the shaft (which of course should be cut in two places), but with wheels so arranged that a stopping of one disc (and pinion) will produce an acceleration of 3', and the stopping of the other will produce a retardation of 34. Comptes rendus, 1878. t. Ixxxyii., p. 961. 148 Scientific Proceedings, Royal Dublin Society. requires a temperature of at least 115° C., whereas by solution in carbon bisulphide we may obtain crystals far more perfect at the ordinary temperature of the air. We must, therefore, look upon leucite as dissolved in a medium which is liquid at a bright red heat, and only gives up this, as well as other minerals, by a lower- ing of temperature, in the same way that a mixed boiling satu- rated solution of salts of various solubilities separate out (far below their fusing-point) as the solvent cools. Precipitation might also depend upon withdrawal from the mixture of one or more of its elements for the formation of a mineral that has already commenced to separate. If we take a solution of mercuric biniodide in a solution of potassic iodide, and add some substance that will seize upon the iodine in the latter salt, such as argentic nitrate, we have an immediate precipitate of the mercuric bin- iodide proportional to the amount of potassic iodide broken up. Stoppani gives the example of nitrate of potash dissolved in water, which is precipitated immediately if alcohol is added.t The fact, therefore, of leucite crystallizing far below its fusion-point proves the solution of that mineral in that glass or some other. This would explain the crystallization of the two minerals simultane- ously, as at Roccamonfina; for as the lowering of temperature took place in the magma as the pyroxene crystallized out, the remaining would become supersaturated with leucite, which would have to separate. We might possibly imitate this con- dition in freezing a saturated solution of a salt in water. It is also possible that the leucite does not form until the potassic chloride in the magma has been broken up, and the HCl has escaped in the vapour. In the formation of rocks we have a process of fractional ex- haustion of the original amorphous medium, in which secondary combinations can hardly be conceived to take place until some portion assumes definite crystalline form, the kind of which will depend upon the elements that enter into the composition of the mixture, and the train of conditions which that undergoes in passing from a higher to a lower temperature. Starting, for example, from an amorphous mass of fused silicates, we may suppose that condition 1 is favourable to the formation of mineral 1 Corso di Geologia, vol. ii1., p. 131. Lavis—On the Structure of Rocks. 149 B, but as this separates, A can no longer remain in solution, so this also separates until the magma is deprived of as much of the elements as these minerals A + B can take up, and the glass is then suitable for the growth of C which comes next, and in its turn may be followed by D, and so on. The resulting rock will be composed of the minerals A+ B+C+D, &. Let us again start with the same magma, and suppose that condition 2 comes into play, which is favourable to the formation of A, which will separate, exhausting the magma to a point that it is suitable to the forma- tion of X, in preference to any other, which now carries the exhaustion on, till the magma approaches Y in composition, which in turn continues the exhaustion, till the unformed material is - suitable for the crystallization of D. We should thus obtain a rock containing the minerals A + X + Y + D, both of which would be identical in ultimate chemical composition. Now, condition 1 may have been favourable to rapid expansion, and eruption such as pumice results from, whilst condition 2 we may take to represent the gentle outflow of lava. The reality of this somewhat rough illustration will be more apparent if we compare the vitreous pumices of Phases III. and VI. of Monte Somma, in which leucite is absent, and sanidine abundant, with the highly leucitic basalt lavas of the same volcano, in which sanidine at the most is a very unimportant element, remembering at the same time the practi- cally complete identity in chemical composition of the mass of either. An interesting point in connexion with this is the fact that Messrs. Fouqué and M. Lévy obtained a leucitic rock from fusing together orthoclase and biotite. Prof. Samuel Haughton! was, I believe, the first to treat the mineralogical composition of a lava on the principle of the exhaustion of the element of the magma or paste, the different minerals competing for certain oxides which are necessary for their formation, so entirely devoting himself, with remarkable ingenuity to the chemical side of the question, but disregarding the physical, which, however, hardly entered into the scope of the subject discussed. We must, however, not forget the varying conditions under which cooling, in an igneous rock, takes place, such as time, pressure, water, volatile acids, and their corre- sponding salts, which must be most important elements in modify- Op. cit. pp. 68 and 188. 150 Scientific Proceedings, Royal Dublin Society. ing the ultimate mineralogical composition of the solidifying rock. Let us take two groups of the mineral elements of Vesuvian essential ejectamenta; we have leucite antagonistic to amphibole, nepheline, and mica, all competing for the potash. Now, in the pumices of the great explosive eruptions of Phases III. and VI. we find amphibole, sanidine, and biotite using up the potash, and being the principal crystalline ingredients, whereas in the lavas that cooled under quite different conditions we find these minerals reduced to a minimum, whilst all the potash has been seized upon by the leucite, and sometimes a little nepheline. How can we account for such phenomena, otherwise than in change of condi- tions P Again, we find pyroxene, antagonistic to olivine, amphi- bole, and biotite, competing for the magnesia. Again, in the Vesuvian pumices, amphibole and mica prevail, as these had pro- bably formed under great pressure, whilst in the same pumices that escaped more slowly, and in the lavas, itis the pyroxene that mono- polized the magnesia. We know that olivine (?), amphibole, and biotite are met with in their greatest perfection in plutonic rocks, whilst pyroxene is remarkably characteristic of rocks slowly cooled near the surface, and under low pressure. ‘The fact of the former of these having resisted all attempts at artificial production points to conditions which have not yet been adopted in the laboratory, whilst leucite and augite are produced with ease and certainty. We therefore must conclude that antagonism of mineral species in crystallizing from a medium depends not only on the composition of that medium, but also of the surrounding physical conditions. Prof. Haughton’ admits that, according to his theory, olivine ought to prevail, as it has only to contest for iron and magnesia, whilst pyroxene, amphibole, and biotite, are weakened in the additional fight for lime or alumina. He attempts to explain this by a theoretical principle which he calls that of minimum paste, which would not have been requisite had the physical conditions been taken into account. Again, this theory in its incomplete form is proved insufficient by the joint author, Prof. H. Hull,’ in the same memoir, although it was undoubtedly a great step in the direction of an important principle. 1 Op. cit. 2 Op. cit., p. 141, Lavis—On the Structure of Rocks. 151 M. Bourgeois' accounts for the crystals of pyroxene in leucite to be the crystallization of the glass cavities. This is obviously not the case, for the following reasons :—In the leucites of Rocca- monfina and Vesuvius the crystals of pyroxene entirely traverse, project their ends on each side, whilst the leucite material is accurately moulded on the crystal facets of the pyroxene, which form leucite could not give to a glass space. Besides, many pyroxene crystals bear no relation whatever, either in size or position, to the remaining cavities, which themselves do not show such crystallization. Their crystals are often imbedded in the leucite mass, and project into a glass cavity, the latter portion being no thicker than the former, which was entirely enveloped in the leucite mass. Where much growth of crystals in glass cavities take place, that portion surrounded by the vitreous paste of the glass cavity should have increased in size. That the artificial conditions employed in the laboratory fairly represents the natural ones in the production of leucite there exists little doubt; the varia- tions in temperature were just such as we meet with in the forma- tion of that mineral at Vesuvius. Besides, the two minerals were identical in crystallographic characters, both externally and inter- nally, as seen by polarized light, and also the great resemblance as exhibited in the strata of glass cavities. That leucite may separate or any rate increase in size, after expulsion of lava, seems to be demonstrated by the observation of Scacchi,” that the scoria of the lava of 1855 did not contain large crystals, and that in the lava the distribution of them was irregular, which seems to show that recut at least increased their size. ; In describing leucite I have considerably erred from the direct road, led on by the train of argument, based principally on the physical and chemical properties of this interesting mineral. Biotite, though commonly met with in volcanic rocks, could not be obtained as a distinct form by Messrs. Fouqué and M. Lévy. In lavas we generally meet with this mineral in large, well-formed crystals, as also in pumices. In some basic pumices of Monte Somma (Phase III.) very beautiful hexagonal micro- 1 Encycl. Chim., vol. ii., Metalloids, [°° Appendice. Reprod. Artif. des Roches, p. 212. 2 Guarini, Palmieri, Scacchi. Mem. Sul. Incend. Vesuy., 1855, p. 152. 152 Scientific Proceedings, Royal Dublin Society. lithic plates, and small crystals may be seen scattered throughout the magma, and often enclose crystals of orthoclase. In the more highly crystalline pumices and lavas this mineral occurs generally as well-formed crystals. Although it is not very uniform in its occurrence, I am disposed to regard it rather as pre-eruptive in formation, or, at any rate, in part. Magnetite is another mineral that cannot be obtained by simple fusion, but requires solution in a fused medium, from which it separates during cooling within a great range of tem- perature,’ provided the formation of other minerals renders the magma supersaturated, from time to time, with this oxide, so that various crops of crystals may result, forming so many periods of consolidation. ‘This is the only way we can explain its formation as with quartz, leucite, &c. Scheerer pointed out long ago the granite-forming minerals separated inversely to their fusion- points. Pyrowene, as well known, is a common product in furnace slags, and is easily obtained by simple fusion of its elements with a very short recwit. Messrs. Fouqué and M. Lévy found it to be produced in a microlithic condition after a few moments’ vecwtt, and prolonging this a little, fine crystals, such as are met with in voleanic rocks, were obtained. Such a fact convinces us of the extreme rapidity with which basic pumices, at any rate, must have passed from the fluid to the solid condition, as in many of the Italian basic volcanoes the first products of some of their explosive eruptions were practically without even microliths of pyroxene, striking examples of which are to be met with in the deposits of Phase III., period 1, and Phase VTI., periods 1 and 38, of Monte Somma. ‘The above-mentioned authors found the limit of temperature rather wide in which this mineral crys- tallized, which accounts for its inclusion in others that separate at rather higher temperatures. ‘The pyroxenic glass seems to be the principal medium in which the other silicates and oxides are dissolved in basic rocks, whereas an acid felspathic glass seems to perform the same function in acid ones. We may regard the magma from which results an igneous rock as a variable mixture of acids and bases, as pointed out by ! Bull. Soc. Géol, 2° serie, tom. iv. page 478, Liavis—On the Structure of Rocks. 153 Abich. Now, as consolidation takes place, great excesses of either, especially the feebler ones, such as magnetite, are com- pelled to separate; and as the rock completes its crystallization, the excesses of either form the last crystals, unless the rock suddenly cools before all the vitreous matter has been converted into formed material. ‘Thus,in the acid rocks we have quartz, and in the basic ones magnetite, being the last formed minerals, although the two most infusible of rock-forming minerals, which alone is sufficient to demonstrate that fusion-point has little or nothing to do with the order of separation of the minerals. We should therefore be more justified in determining whether a rock should be regarded as acid or basic by its microscopical structure, than by adopting 60 per cent. of silica as rigidly dividing the two, since the different bases vary much in alkalinity, and combining proportions, and a magma containing 60 per cent. of silica, might give an acid or an alkaline reaction, according to the quantities of different bases it contained. Limit of space prevent further consideration of the different mineral species which go to make up igneous rocks ; the above, being most common, are sufficient to indicate the line of argument followed out. Before, however, quitting the subject, there is one more point worthy of our consideration in relation to the separation of mineral species from a solvent. Different species have been easily obtained from fusion of their components in a saline sub- stance, such as a chloride or sulphate. Thus, for instance, M. Lechartier’ obtained pyroxene in crystals, a centimeter long, by fusion for a couple of hours in calcium chloride, or sodium sulphate. In the same way wollastonite, apatite,” and many other minerals have been obtained by EH. Belmen as very perfect crystals from solution in fused chlorides, and other salts, such as vanadates. These facts go to confirm what has been said about the solution of the more infusible silicates in the more fusible ones, and at the same time may account for the occurrence of some minerals that are eruptive, or post-eruptive, in time of their formation. The large amount of sulphates, but especially chlorides, that are vapor- 1 Comptes rendus, 1868, vol. Ixvii., p. 41. * L. Bourgeois, Eneycl. Chim., vol. ii., Ie’ Appendice. Reprod. Artif. des Roches, p- 10, 154 Scientific Proceedings, Royal Dublin Society. ized during an eruption is hardly credible until a few facts convince us that such is the case. I have seen fumarole chimneys having in a short time their whole interior glazed by a mixture of chlorides, one to three centimeters thick, and from the intense heat as trans- parent as an ice covering, which was, without doubt, the result of sublimation, and not decomposition, as the rocks upon which it was deposited were quite unaltered. Another proof of the large amount of saline substances ejected by a volcano is the quantity met with in the falling ashes during a lava eruption. The outburst in 1872 produced an ash asserted by Prof. Palmieri' to be poorer in soluble constituents than any other since 1855, yet it contained from 4 to 9 per cent. of saline matter, chiefly sodic chloride. As this erup- tion was lateral, the principal part of the ash was derived from the crater edges and chimney walls, which would tend to lower the amount of soluble portion. It was observed in the eruption of 1855° that the alkaline chlorides were only evolved sometime after the lava had been cool- ing—that is to say, saline crusts only formed around the fumaroles at a late date; and I have noticed the same thing. Scacchi sup- posed that it may be a spontaneous rise in temperature in the lava in cooling, similar to that developed in phosphate of lead, nitrate of copper, or argentic’ iodide when passing from the amorphous to the crystalline condition. Or again, to their early union with other elements of the lava. This may possibly be so, the combi- nation being broken up by a lowering of temperature (?), leaving the chlorides free to besublimed. It seems to me that the chlorides must be continually escaping, but that they are not deposited until the scoria and fumarole sides are cooled enough to allow such to occur. The liquids included in cavities in Cr are generally solutions of chlorides or sulphates. There is little doubt that these saline materials must form a very important constituent of the magma; but whether they play much part as a solvent medium for certain minerals is a thing yet to be experimentally verified, though one is inclined to think that they really do perform a very important function in that way. 1 Annali del Reale Osserv. Meteor. Vesuviano, 1874, p. 73. 2 Guarini, Palmieri, Scacchi. Mem. s. Incend. Vesuviano del mere di Maggio, 1855, &e., pp. 141, 148, and 149. 3G. F. Rodwell, Phil. Trans. Rk. S., Part iii., p. 1184. Lavis— On the Structure of Rocks. 155 One point open to speculation is whether the presence of sodic and potassic chlorides and sulphates is not the determining cause as to whether the magma shall contain leucite haiiynite, nosite, or sodalite. or instance, we find Monte Vultura producing at different epochs basalts, leucitic basalts, and haiiynite basalts, which might result from the accidental introduction of such salts from the sea or other sources. We might suppose that the salts are decomposed and dispersed as acids, whilst the bases are seized upon by the silicic acid which, in a magma at high temperature, has powerful acid properties, and so forms minerals of the leucite or felspar groups. In this Paper I have brought together a considerable number of observations, and endeavoured to glean from them the clue to some of the most important problems of geological science. The train of argument is somewhat disorderly; but from the large number of circumstances that enter into the question of the forma- tion of igneous rocks, the subject is difficult of arrangement. it is unmistakably evident that if the young science of petrology is intended to be carried beyond the simple dry description of rock masses, it must be brought to bear upon the various modifications and derivatives of them, in any given district, and also that it will never supersede field investigation ; but by the two going hand-in- hand they may open the doors and show us the secrets of Nature’s great chemical laboratory—our globe. (se: ay XVIII.—ON THE PERMANENCY OF FROST-MARKS, AND A POSSIBLE CONNEXION THEREWITH WITH OLD- HAMIA RADIATA AND O. ANTIQUA. By J. JOLY, B.E., Assistant to the Professor of Engineering, Trinity College, Dublin. [ Read, March 24, 1886. ] Tue object of this note is more to draw attention to a line of inquiry, possibly not unfruitful, than, with the present amount of evidence, to demonstrate any hypotheses. ‘The experiments neces- sary to throw light on the hypothesis suggested demand more time than I will for many months be able to spare. Some few experiments have, indeed, been made, and, for more than a year seeking for leisure to continue them, I have postponed bringing the very simple matter before the Society. In the Christmas holidays of 1884, I, in company with some friends, was engaged on ashort excursion through the Co. Wicklow. The weather was frosty, freezing at night, and thawing by day in the sunshine. There had been rain, and the roads, where the thaw prevailed, were soft and muddy. In this mud, just outside Roundwood, we noticed very regular marks, evidently left by the frost. The frost was gone, and the mud was soft and wet; but in ruts and empty pools, wherever a smooth surface obtained, the frost had channelled its impress. The appearance was that of tufts, regularly radiating from a centre in rays which straggled over the slime in long tendrils, these being again often sub- divided into more numerous tendrils. The effect produced so closely resembled the tufted appearance of Oldhamia radiata, that the thought was immediately suggested of the possible common origin of the two, and I drew the attention of my companions to the resemblance, which one of them, Mr. Crosthwaite, was well able to appreciate, being familiar with the Oldhamia marks. Similar marks were subsequently met with in abundance that day, and again noticed in Glendassan the ensuing day. I have since observed them after every trost. Joty—On the Permanency of Frost-Marks. 157 How the marks are caused, it is not hard to understand. Ifa surface consisting of loose small particles, holding water in the interstices, be exposed to a low temperature, certain of the more prominent particles, exposing a capillary surface of water more freely than their neighbours, become centres of crystallization, from which crystallogenesis is propagated, the molecular forces at work being sufficient to disturb the loose sand particles, so that they shall take up a position accommodating to the form and direction taken by the ice spicules. These spicules, or rays, would, if forming freely, extend, indeed, ever as straight lines; but here, hampered by the jamming or fixity of occasional par- ticles, they wander minutely, now diverted a little in one direction, and again in another, so that the sharp definition of crystalline shape becomes modified into a straggling growth, resembling the radiate straggling of Oldhamia radiata. There is another conspicuous variety of Oldhamia, known as Oldhamia antiqua. I traced, indeed, some marks remotely resembl- ing this; but, although we might a@ priori expect such a form to occur, I have not succeeded in finding anything fairly resembling it since, nor have I, in the few experiments made, succeeded in reproducing it. These experiments consisted in washing out the finer constituents of some earth, and exposing this, while saturated with water, to frost. I also froze a slab artificially, by placing immediately above it, in a well-padded box, a metal tray contain- ing a freezing mixture: freezing was produced by radiation from the surface of the mud to the bottom of the tray, which was coated with lamp-black. In this way, it was hoped, the conditions obtaining in nature would be preserved. In general, marks more or less resembling the Oldhamia radiata’ were easily obtained, but the Oldhamia antiqua could hardly be said to be reproduced. I said that we might expect a different result. This will appear if we consider the simple arrangement of such marking—a zigzag of nearly straight lines, with tufts at the bends or meeting-points. How such an arrangement might occur in the case of fine sand, interspersed with larger particles, is quite conceivable. Finally, anyone who has observed closely the symmetrical forms of frost ! This is by far the more common variety. My 158 Scientific Proceedings, Royal Dublin Society. on smooth surfaces will not think it improbable that on the sur- face of fine sand we should find it simulating organic form. My failure in obtaining the O. antiqua artificially may have been due to the texture of sand employed, to its degree of satura- tion, or, possibly, to the nature of the matter dissolved in the water. Thus, it might not be amiss to try experiments on the freezing of sea-water in mud or fine sand; and a sand made of the silurian slate itself, crushed to dust, commends itself, a as going towards realizing past conditions. The subsequent preservation of these marks in the mud during thawing and drying may be perfect, and conditions necessary for their continued preservation, as rock-marks are no harder to con- ceive than the conditions which have preserved to us the rain- marks so perfectly that we can pronounce, it is said, on the direc- tion of the wind prevailing during the shower. We have only to suppose alternations of high and low water— the silt-laden water creeping very quietly over mud flats which, frozen during exposure, were again thawed and dried before the incoming water deposited a fresh covering. It is noteworthy that the grosser spicules appearing on the surface of frozen mud leave, so far as I have observed, no impress. They are, in fact, formed merely in surface-water. It was hoped at first that evidence might be obtained from a comparison of the angles made by the bifurcating branches of the frost-marks with the angles easily measurable on the silurian slate. But as the crystallographic directions were found to be completely disguised in the first case, the comparison was futile. In bringing these observations to the notice of the Society, I hope it will be understood that I no more than venture a sugges- - tion, worthy, it is thought, of further elucidation, and not to be lightly dismissed. Even if, on further consideration, it be deemed improbable, it is perhaps not without interest, and, pos- sibly, not without important bearings in other directions to point out that the fragile and beautiful frost flowers, fleeting as they are, can leave an impress of a nature capable of being preserved through an eternity of time. | 169 J XIX.—NOTE ON LACKMOID AND LITMIN. By W. N. HARTLEY, F.R.S. [Read, March 24, 1886. | Last year Mr. H. N. Draper introduced to the notice of the Physi- eal Science Section of the Royal Dublin Society a new substance ealled lackmoid, which appeared to have the same, or very similar, properties to litmus. He kindly forwarded to me small specimens of lackmoid and litmin. The following notes show, first, that these are different substances; secondly, that they may be of a similar constitution; but we have no decided evidence. Lacknoid.—0:01 gram. was dissolved in 20 cubic centimetres of alcohol, of 0°8 sp. gr., and mixed with 20 cubic centimetres of water. The substance is soluble in strong alcohol, but insoluble in water. Soluble in alcohol of 50 per cent. by volume. It re- tained its colour with but slight alteration for several months, the sole change being the acquirement of a blue tinge. This may be due to the alkalinity of the glass of the bottle in which it has been preserved. Litmin.—0:01 gram. dissolved in 20 cubic centimetres of water and 20 cubic centimetres of alcohol, of 0°8 sp. gr. added. This substance is insoluble in strong alcohol, but soluble in alcohol of 50 per cent., and in water. The solution has become bleached by keeping, notwithstanding that the bottle has been carefully stop- pered and not exposed to bright light. The spectra photographed for each solution after dilution were not remarkable ; the actinic absorption of the two substances being much the same, even after the addition of acid. Lackmoid has the more intense absorptive power in the visible spectrum; in solution it is undoubtedly a better reagent than litmus. The alcoholic solution may be added to water and used precisely as a litmus infusion. [Pe aLoOr 3) XX.—ON THE LIMITS TO THE VELOCITY OF MOTION OF THE WORKING PARTS OF ENGINES. By GEO. FRAS. FITZGERALD, F.T.C.D., F.B.S. [Read, March 24, 1886. ] Eneinets are used for transforming one kind of energy into another. Mechanical engines are of two great classes—ones that trans- form potential or statical energy into work, and those that trans- form kinetic energy into work. Slow-moving overshot waterwheels may be taken as types of the first class, and windmills as types of the second class. In all cases, it is of course possible by mechanical contrivances, such as levers, pulleys, wheels, &c., to obtain any velocity of moving parts; but the velocity I am calling attention to is the velocity of the parts that move with the working substance. Now, in the case of waterwheels it is evident that when the wheel turns so fast that the water in the buckets is descending as fast as it would fall freely, there can be no work being done by the water on the wheel, and so this limits the rate of working of the wheel. It is to be remarked that in the limiting case the efficiency is zero, while the power is zero when the efficiency is a maximum, i. e. when the wheel is turning most slowly, and that there is a rate of working intermediate between these for which the power is a maximum. In the case of windmills, when the sails turn so - fast that the wind blows on unstopped, there is similarly no work being done, and, just as in the other case, this limits their velocity. Heat engines are of a different class, as they are for the transformation of irregular into regular motion; but their mechanical, as distinct from their thermal, arrangements may be grouped as in the last case. Ordinary steam engines work by means of the energy in the steam doing work by pressing on a piston, and evidently this piston cannot move faster than the steam can follow it up. Professor Osborne Reynolds has in the Firzcrratp—On Limits to Velocity of Motion of Engines. 161 March number of the Philosophical Magazine this year, called atten- tion to the way in which the velocity of flow of a gas into a vacuum is limited, and this limits the velocity of motion of the piston in an engine. He has, however, omitted to notice that there is a greater velocity than the velocity of sound with which a gas can move into a vacuum, namely, at the rate at which its particles are moving. ‘This only comes into effect when the space is so small compared with the free path that we cannot deal with the molecules, as making an indefinite number of encounters on their way across the vessel. In the case, for instance, of a piston in a vessel full of a gas moving suddenly from rest, with a velocity - equal to that of the average velocity of the molecules of the gas, which is greater than the velocity of sound in the gas, it is evident that all the molecules that were just on the point of striking the piston would follow it up, and that those that happened to be moving normally to it would keep following it up, and so would be diffusing into this vacuum, at a greater rate than the velocity of sound in the gas. This leads to a diffusion velocity of energy in a vacuum small compared with the free path, quite different from the velocity of sound, and upon which evidently radiometer action depend. It is this that would ulti- mately limit the rate at which the piston could be moved by the gas. I have explained this at my lectures on the Theory of Steam Engines for some years back. Steam may also be used kinetically, as in Giffard’s injector, and Hero’s engine; and in these cases velocity of motion is limited by the velocity of flow of the steam. : In the case of most of these engines that transform kinetic energy into work, it is to be remarked that when moving slowly there is a very small power produced at the expense of a great expenditure. For example, in Hero’s engine and engines of this type, if the steam runs out freely without moving the engine, there is certainly the maximum pressure tending to move the parts, but no power is produced, even though a great deal of steam is being employed. It is not the same with pressure engines, like ordinary steam engines. They may be worked slowly, and the power produced is proportional to the steam employed. The same distinction holds in the case of water engines working pistons and turbines. In the case of the kinetic SCIEN. PROC. R.D.S.—VOL. Y. PT. III. N 162 Scientific Proceedings, Royal Dublin Society. engine we must work rapidly if we are to get a good efficiency, for the efficiency vanishes at the slow limiting velocity. In the case of statical engines, the efficiency is a maximum when they are working at their slow-limiting velocity, and vanishes when working at their quick-limiting velocity. In the case of a perfect turbine, the efficiency is a maximum when going at its quick- limiting velocity. In the case of water engines there is evidently a limiting velocity also depending on the rate of propagation of energy by the water, i.e. its rate of propagating sound. Gas engines have similarly a limiting rate of working, depending on the rate of explosion, i.e. of propagation of energy by the working substance. Capillary engines and muscles have probably limits of rates of working analogous to those depending on the rates of diffusion of the molecules of the working substances at the working sur- faces. We know that muscles like kinetic engines have a zero efficiency when working at their zero limit of velocity, and there is almost certainly a maximum limit to their rate of working. Capillary engines, like M. Lippmann’s, are evidently limited by the rate of diffusion of the molecules at the capillary surfaces, i.e. of the superficial energy. Electric engines have got analogous properties. There are the two classes—electro-static engines, such as a reversed Holtz machine, and electro-kinetic engines, such as ordinary magnetos and dynamos. ‘The former can be worked as slowly as we please, without waste of energy; but the latter require to be worked at near their limiting velocity to have a good efficiency. A limiting velocity in the case of dynamos is well known, and is attained when the inverse electro-motive force of the dynamo is equal to the driving electro-motive force; but with a given electro-motive force it does not seem at first sight as if there were any limit to the rate of working of a Holtz machine or any electro-static engine. If we, however, consider the electro-magnetic action of moving electricity, it becomes evident that the forces between the different parts of an electro-static engine must diminish ag its velocity of motion increases, until its parts have a relative motion equal to the velocity of light, when there will be no more forces between them. If it move faster than this it will become an electro-magnetic FirzcEraLp-—On Limits to Velocity of Motion of Engines. 168 engine, for the electro-magnetic forces will become greater than the electro-static. ‘The way in which this acts is as follows :—Suppose a charged body, e.g. the carrier in any of the multiplier forms of electro-static engines, move near a conductor, it induces on this latter an electric charge which moves along with the moving carrier. I must neglect the resistance of the conductors, because it being of the nature of friction in ordinary engines limits the velocity in quite a different way from the ways I am considering. Now, if the carrier move with the velocity of light, it and its induced charges will have no action on one another, and so there will be no forces tending to move the carrier. Similarly, if a plate with a charge on it move parallel to a conducting-plate, the moving electrification while its velocity is increasing induces a current in the conducting- plate which is permanent, because the conducting-plate is supposed to be a perfect conductor, and the electro-magnetic action of these two, when the moving-plate moves with the velocity of light, is equal and opposite to their electro-static attraction. Thus it appears that the velocity of light isa limiting velocity to the rate of motion of these engines, just as the velocity of the particles of steam is a limit to the rate of motion of the piston ina steam engine. There is the same limit to the rate of working of electro-magnetic engines. Consider a very simple case. Suppose a wire sliding on two parallel rails with a magnetic force at right angles to their plane, and an electro-motive force driving a current round the circuit. If the magnetic force be feeble enough there seems at first sight no limit to the ultimate velocity of motion of the wire. If _ we consider, however, what takes place when the electricity goes across from the rails to the moving wire, we see that the reason it goes across is because an electrification on the rails induces a charge on the moving wire, and these attract one another and combine, this action being kept going constantly by the fresh charges supplied by the battery. Nowif the wire move with the velocity of light, there will be no longer any action between these charges, and so the wire will act practically as a non-conductor. A conductor moving with the velocity of light acts in other respects as a non-conductor, for it is evident that we can have any desired distribution of electricity in it or on it without any tendency for it to change. It would be more correct to describe it as a region in which the electro-static | inductive capacity was infinite, and where, consequently, ee | | q 164 Scientifie Proceedings, Royal Dublin Society. charge produced no force in its neighbourhood. ‘There is another way of looking at this question, and one that leads to another view of the reason for this limiting velocity. It depends on the theory put forward by Professor Poynting that the energy given out at any point in an electric circuit is transferred there through the ether, and as energy is transferred through the ether with the velocity of light, it cannot keep up with a moving body that moves with a greater velocity than this. This completes the very remarkable analogy between the way in which the rate of motion of a piston by a gas is limited by the rate of propagation of energy in the gas, and the rate of motion of electric engines is limited by the rate of propagation of energy in the ether. ettoon a XXI.—ON THE OCCURRENCE OF HARMOTOME AT GLEN- DALOUGH, CO. WICKLOW. By J. JOLY, B.E., Assistant to the Professor of Civil Engineering, Trinity College, Dublin. (Read, April 21, 1886.] As I can find no previous mention of the occurrence of harmotome, or indeed of any member of the zeolite family of minerals, in Co. Wicklow, it may not be amiss to call attention to its presence. I have the more excuse for writing a note on the occurrence of this one mineral, as, since the work of Daubré, a special geological and mineralogical interest is attached to the beautiful group of which it is a member.! The harmotome of Glendalough occurs in the out-put from the Luganure lode, which traverses the granite close to its junction with the schist, and extends into the vale of Glendasan. Much of the gangue has been thrown out at the upper end of the lake, and from this debris I took, some few years ago, a very small specimen of the zeolite—so small that I could not be assured of its identity as harmotome till I was so fortunate recently as to find another and larger specimen. The out-put otherwise indicates hydro-ther- mal action in the lamellar deposits of quartz and calcite. Here also may be found fluorite, sphalerite, barite, strontianite, galenite, pyrite, siderite, chalcopyrite, manganocalcite, and some decompo- sition products. Specimens of hexagonal calcite, sometimes found here implanted in solitary whiteness on ice-like drusy quartz, are very beautiful. The zeolite, in both the specimens found, occurs implanted on a quartz matrix, and in one case the little crystals curved over a crystal of sphalerite. The largest of these harmotome crystals is not quite one centimetre in length. They present principally a 1 Formation Contemporaine des Zedélithes. The zeolites observed by Daubré were engendered in the matrix rather than deposited. I think it evident that the Glenda- lough zeolite was deposited. Daubré’s harmotome or christianite, however, is the lime- potash zeolite philipsite of Dana, and is quite distinct from the harmotome Gescrie! above, which is the barium zeolite, 166 Scientific Proceedings, Royal Dublin Society. characteristic cruciform twinning ; but a more obscure lamellar form, of the same mineral probably, is intermingled with the larger crystals. These larger crystals have a high vitreous lustre, and are white, translucent, transparent. The lamellar forms are duller in lustre and are white, nearly opaque. Crystallographic character.—The accompanying figure, in iso- metric projection, shows the nature of their crystallographic appear- ance. It differs somewhat from that ascribed to harmotome by Dana, Des Cloizeaux, &c., due to the conspicuous development of the hemihedral form 1 (copying the notation of Dana), while still pre- serving the holohedrism of the prism I. It will be seen that this development has reduced one set of the prism faces to minute dimensions. Indeed they can hardly be seen on the specimen without the use of a lens. Im any other specimens I have examined the prism is either predominant—1 having the appearance of a mere bevelling of the edge OI, or otherwise, it is eliminated altogether, I becoming a hemihedral form. The effect is that the JoLy—On the Occurrence of Harmotome at Glendalough. 167 crystal looks as if terminated with four smooth planes, and only on very close examination is it apparent that the pyramid is trun- cated and replaced by the four prismatic faces. Many of the erystals are terminated thus at both ends. Working with a defective goniometer, the following values were obtained :— Onvnl=90°; Ip os 1s 20’, mean of nine observations ; Ta I = 110° 20’, mean of four observations. Dana records harmotome as orthorhombic, and | Tal =124°47’; LT = Le ae, Thus the measurements are evidently sufficiently in accord with a right rhombic prism of 124° 47’. Further, the angle I I agrees satisfactorily with the recorded value. Observations with the polariscope confirms the crystallographic characters ascribed to these faces, but, owing to the generally imperfect translucency of the crystals, are not very definite. Specific gravity.—I mentioned opaque, white, lamellar forms. To these optical or crystallographic investigation could not be ex- tended. Thinking they might be a distinct zeolite, it was thought advisable to compare their sp. gr. with that of the other implanted crystals. Otherwise, also, it was evidently advisable to determine the sp. gr. of both forms. In a diffusion zone above Thulet’s solution, according to Pro- fessor Sollas’ method, a fragment of authentic harmotome was placed. On putting in, now, fragments of both the Glendalough forms, they were found to float exactly in the same horizon with the authentic harmotome. Orthoclase of a sp. gr. 2°51 floated below them, analcite floated much above them, stilbite higher still. By calculation, then, asp. gr. of 2°46 (Dana 2:44-2:45) was ascribed to the Glendalough harmotome. This is a very distinctive test, as the only other members of the zeolite family with so high a sp. gr. are the monoclinic varieties, scolocite and brewsterite. 168 Scientific Proceedings, Royal Dublin Society. Fusibility—Compared with authentic harmotome on the mel- dometer it was found that the fusion of both occurred simultane- ously at a very high temperature. ‘The specimens also blanched below a red heat. It was interesting to compare this behaviour with that of some other zeolites. The result is the following order of fusibility with increase of temperature :— Chabasite Stilbite almost simultaneously. Heulandite J Natrolite (Orthoclase) Harmotome. Harmotome is, in fact, separated from the others by a wide interval. Orthoclase fuses in this interval, and, indeed, decomposi- tion or ebullition of the orthoclase takes place before the melting- point of harmotome is reached. Recent experiments gave me for the melting-point of orthoclase the temperature of 865° C. It is likely that the fusion of harmotome does not occur under 900° C. T had not time to go through with the measurement independently. I would point out, however, that there is very little liability to error in comparing the fusibilities of two substances, placed thus under exactly the same conditions and observed simultaneously in the field of the microscope. On the other hand, not only is the blowpipe a powerful chemical agent, and thus obscures the pheno- mena of fusion with secondary effects, but with it it is impossible to be sure of fair comparison. ‘The meldometer has shown me that the order of Van Kobel’s scale is incorrect. Thus the order it assumes for the fusibilities, almandine, green actinolite, orthoclase, should be orthoclase, green actinolite, almandine ; and it is, I think, allowable to assume that similar misleading phenomena account for the fusibility of harmotome being recorded as 3°5 on the scale of Van Kobel. The test of fusibility, like that of sp. gr., is thus a distinctive one in the case of harmotome. A test of its hardness showed that it scratches fluorite, and is scratched by apatite; hardness, therefore, 4:5. In the dlowpipe it fuses without intumescence. It does not gelatinize with, but is decomposed by, hydrochloric acid. ‘These tests confirm its identity with harmotome. [ehoons] XXII.—-ON THE TEMPERATURE AT VARIOUS DEPTHS IN LOUGH DERG AFTER SUNNY WEATHER. By GEO. F. FITZGERALD, F.T.C.D., F.R.S. Read, April 21, 1886. p Tue measurements upon which this Paper is founded were made by me in the month of July, 1876, and I would have hardly thought them worth recording only that I have lately seen it noticed as a new fact that the isothermal surfaces in the Lake of Geneva are not level surfaces; and that this was so in Lough Derg was one of the special features I remarked in my observations of nearly ten years ago. I made experiments with a maximum and minimum thermo- meter, attached to a sounding-line, and the differences of tempera- ture observed were so great that there could be no doubt, even with rough experiments. The observations were made after a long continuance of hot, sunny weather, during which the day temperatures ranged from 73° FB. to 75° F., and the night temperatures from 55° F. to 65° F. The temperature of the surface of the lake rose rapidly during sunshine, at a rate of nearly a degree per hour. In the deep water the temperature of the surface did not rise so fast as in the shallow water. About 3:30 in the day the temperature of the surface water in the deep parts was 71° F., and in the shallows 75° KF. From a calculation of the amount of heat that enters the water, it seems that only about =5th, or less, was used in heating it, the rest being probably spent in evaporation. During the evening the temperature of the surface fell slowly, until in the morning it was uniform, to a depth of about five yards, this being the depth, apparently, that the convexion currents during the night reached. This temperature was, on the night I observed it, eleven degrees above the night temperature of a thermometer exposed on grass. In the shallow water the temperature fell more rapidly until it was about 2° colder than the surface water in deep parts, and nearly the same as that of the water at the bottom of 170 Scientific Proceedings, Royal Dublin Society. the deep parts of the lake. It thus appears that the cold water supply for the bottom of the lake may be kept up by the cold night water from the shallows. On laying out a series of afternoon isothermal lines, it appears that they are closer together in the shallow water than in the deep water, the bottom in the shallower water being in general colder than at the same depth in deep water, though, of course, in the very shallow water, where the surface was several degrees hotter than elsewhere, the whole of this very shallow water was warmed up, and was hotter than water at the same level elsewhere. The rate of change of temperature downwards was very regular, from a depth of from five to six yards, to the bottom. At the depth of five to six yards, it changed more rapidly, and from that up to the surface was the region that was affected by the diurnal changes of temperature. During the day the upper layers in this region became much hotter, and during the night the whole of this region gradually became of the same temperature throughout. The depth of this region was observable, during the days I observed it, by the variation in the rate of change of temperature that occurred at this depth; the change of temperature was more rapid here than in either the subjacent or in the immediately superincumbent layers. From the rate of decrease of temperature in the superficial layers I calculated that the coefficient of absorption of heat per yard was ‘71, but as it is known that this is very different, for different rays of the spectrum, it is probable that the coefficient of absorption of the first layers is very much greater. I had not any sufficiently accurate method of measuring the temperatures at near points to determine the rate of change of temperatures for small distances near the surface, but it was certainly very much more rapid than even at a short distance below the surface. XXIII.—A THERMO-ELECTRIC CURRENT IN SINGLE CON- DUCTORS. By FRED. T. TROUTON, B.A. [ Read, March 24, 1886.] Ir a flame be placed under an iron wire in circuit with a galvano- meter, and be so moved along the wire that the part in the flame is always white-hot, a current is indicated which flows in the direction the flame is carried. The electromotive force is generally in the fourth decimal place. In looking for an explanation of this, it was observed that in front of the flame the fall in the temperature along the wire is more rapid or steeper than behind it. So that, if a difference in the rate of transference of heat in opposite direc- tions in a wire causes a current, as some have supposed, there would be one in this case. The rate of flow of heat is greatest in the direction the flame is moved, for the fall in temperature along the Wire is most rapid in that direction. The current, then, and the greatest flow of heat are in the same direction. The amount of the current would thus obviously depend on the difference of the gra- dients in temperature in either direction along the wire. By making the gradient in front as steep as possible, and that behind the flame more gradual, we should expect an increase in the current. Or again, by making the gradient behind the flame steeper, by cooling it more rapidly,than the air can, say by applying water, we should get a decrease in the current, and even a reversal if the gradient became steeper than in front. It was with no small surprise, then, that the opposite was observed on trying the experiment. For, cooling with water behind the flame as it moved along was found to increase the current. That this could not be due to chemical action was ascertained by applying various substances to cool the wire. Thus, whether bodies of a reducing or oxydizing nature were employed the result was always the same. 172 Scientific Proceedings, Royal Dublin Soctety. In order to simplify matters by observing the current when only one side of the flame changed, a row of burners were so arranged that one after the other could be lighted beneath the wire. The current, on turning on the burners in succession, was in the direction that the ignition travelled, or to the side of the steepest gradient in temperature. On turning the burners out in reverse order, one after the other, the current now flowed in the opposite direction to that indicated in the first instance. And if was in- ereased when the cooling was hastened by applying water. ‘The steep gradient is, in both cases, on the same side; that is, both while the flame is spreading out, and again while it is going back. Yet the currents are in opposite directions. However, though the steep gradients are on the same side, it is to be remarked that everything is not in the same condition in both cases; for in one the temperature is everywhere rising, while in the other, that is as the flame goes back, the temperature is everywhere falling. So that it ela be insufficient to consider the electromotive force / B= (F \ but must rather be « = @ (o> up 6 being the tempera- dx b) ture at se point at a distance w along the wire from a fixed point, and ¢ denoting the time. Direct experiments were made to determine if a difference in the flow of heat in opposite directions in a wire was sufficient alone to produce a current. ‘Thus, along a wire on one side of a heated place a moist thread was laid and kept moistened. On coming to a permanent state no appreciable current was observed, though there must be a very great difference in the rate of flow of heat to either side, due to the great difference in the temperature gradients. I find a similar experiment was made by Le Roux,' who came also to the conclusion that no current whatever was produced by a dif- ference in the flow of heat in opposite directions in a wire. In another experiment no current was observed in a wire kept heated at the place where it came up out of a vessel of water. So that : dd dd there can be no term in «= @ a aa =| containing at ;, alone ; but ad’ it probably consists principally of = dt. 1 Annales de Chemie et de Physique, quatriéme séries, tome x., p. 208. Trovron—On Thermo-Electric Current in Single Conductors. 173 We may picture what occurs when the high temperature spreads out along the wire somewhat as follows:—When the temperature of a portion is raised to a bright heat, let us suppose the structure to be altered, and with it the electrical potential. Let mn represent the wire, and the ordinates of the curve the temperature at each point. Then, for simplicity, let us for the moment suppose that the difference from the altered part to the unaltered is sudden in the Ai ion we encore ba AB BA Me wire and not gradual. Say, at 4B and again at BA, so that from A to B there is a difference in the potential, and again of the same amount, but in the opposite sense at AB. Now, if the temperature spread out on one side, as represented by the dotted line, the junc- tion BA will go out to BA’. However, if we suppose the high temperature to travel out faster than the junction, while the junc- tion.is behind its final position, itis at a higher temperature than the junction at AB; and there will be a current, flowing from m to x, if the potential of the centre part was originally higher than the rest of the wire. The reverse occurs when the high temperature goes back. The junction follows slower and is at a lower tempe- rature than AB until it arrives at the final position. The fall in the potential is meanwhile less than at AB. So the current in this case flows from x tom. Now, if we suppose a great number of these junctions beginning with the unaltered wire, and ending with the completely altered, each will have its own normal temperature and can act justas described above in the case of one. By supposing a sufficient number of these we have at length a continuous alteration in the structure of the wire, which is what probably takes place. peti. Bas 2) ee SSS In the case of the moving flame the junction in front is at a higher, and the one behind at a lower temperature, than the tem- 174 Scientific Proceedings, Royal Dublin Society. perature when at rest, which is shown on either side in the figure by the dotted lines of equal length. The arrow shows the direc- tion the flame is moving. If water be applied to one side of a heated part of the wire, there is a very rapid cooling and a current flows, due to the higher temperature on the other side, until the junction slowly travels in to the point at the normal temperature, when the current ceases, as was described above.t Again, on stopping the water, the current flows for a while in the opposite direction. So far it has been assumed that the iron, as the flame moves on, cools and returns to its original state; but it does not do so com- pletely. However, if the flame be passed several times over the same part, the iron seems after that to undergo no further altera- tion. There is a permanent heterogeneousness or alteration found from the place where the heating by the flame began to where it ended, similar to that between the wire and another metal. Hither of the ends of this gives a current on heating. In some cases, especially in steel, the currents were easily observed, even at 100° C. The current, as in the case of the temporary alteration in the wire, flows from the altered to the unaltered metal at the hot junction. It follows from this, that the first time the flame is moved along the wire the current is somewhat greater than subsequently, it being the sum of both effects; though afterwards it appears not to alter sensibly in amount on repeated heatings. ‘That currents due to permanent alteration in the structure of metals could be obtained, was long ago shown by Magnus. Of other metals examined, nickel acts like iron; copper, silver, and platinum appear not to—that is, an alteration once made in their structure remains on cooling; while iron and nickel return partly to their original state. This difference may be owing to the more or less pasty condition iron and nickel assume at tempe- ratures considerably below their melting points; and, probably, both copper and silver raised to temperatures just beneath their melting points would behave like iron or nickel. The difficulty of " That Le Roux did not observe these currents may be due to his not employing as high a temperature. Trouron—On Thermo-Electric Current in Single Conductors. 175 doing this is considerable, especially in silver, for long below its melting-point it appears to lose tenacity almost completely. Platinum was examined at temperatures approaching its melting point with the oxyhydrogen flame; but the currents obtained were very small, and were due to irregularities in the structure of the wire. As the flame was being carried along in one direction the needle kept to one side or the other, according to the part of the wire the flame was at. A thin rod of carbon examined in the oxi- hydrogen flame gave a small but regular current as the flame was moved along when water was applied to cool the carbon behind the flame ; without this the carbon does not cool quickly enough to give a current. A difference in the potential along a wire of the nature sup- posed above, that is due to a temporary change in structure from temperature, could not be discovered by means of a galvanometer, owing to the symmetry on either side, except the temperature alter more rapidly than the structure. For otherwise it would always be equivalent to introducing another metal, and keeping the two junctions at the same temperature. To state shortly the conclusions finally arrived at, there is, first, a permanent alteration effected in the structure of a wire when it has been once heated. So that, if one of the points between the altered and unaltered metal be warmer than the other, a current flows similar to what would happen if a second metal were introduced into the circuit instead of the altered part. Secondly, that there is, at least in some metals, a temporary alteration of a somewhat similar nature to the permanent one, which lasts while the wire is at a high temperature; and that it is possible to obtain currents from this, is solely due to the fact that, both in appearing and in disappearing, the alteration may take place more slowly than a change in temperature, which ultimately effects the alteration. What this alteration is, whether stresses similar to what Sir William Thomson found could produce thermo-electric hete- rogeneousness in a single metal, or whether of the nature of molecular rearrangement of the nature of annealing, may be doubtful. 176 Scientific Proceedings, Royal Dublin Society. A better knowledge of the circumstances under which currents can be obtained in one metal may, perhaps, yet afford ground for some molecular theory of thermo-electric currents, the con- ditions to be considered being reduced in having only one sub- stance in different states to deal with. elvan XXTIV.—PRELIMINARY ACCOUNT OF THE TETRACTINELLID SPONGES DREDGED BY H.M.8. CHALLENGER, 1872-76. By PROFESSOR W. J. SOLLAS, LL.D., D.Sc. Part 1.—Tur Cuortsripa. [Presented, July 15, 1886.] Tue following short abstract of my forthcoming Report on the Challenger Tetractinellid Sponges is published by kind permis- sion of Dr. John Murray, Director of the Challenger Expedition Reports :— Trise I.—TETRACTINELLIDA, Marshall. Skeleton characterized by quadri-radiate spicules, or “ Lithistid”’ sclerites. Order I. Cuortstrpa, Sollas.—Quadri-radiate spicules are present, but not “ Lithistid” sclerites. Order II. Liruistripa, Zittel.—The chief skeleton consists of “Vithistid” sclerites articulated to form a consistent network. Quadri-radiate spicules may be present or not. Order 1. CuHoristTIpa. Sub-order 1. Tsrrapina.—The chief spicules of the choano- some are tetrads, amphitetrads, candelabra, or modified triana. Sub-order 2. Trrantna.—The heads of the adult trianine spicules are confined to the ectosome. Sub-order 1. TErTRApDINA. Family 1. PLAKINIDA.—The canal system is eurypylous. Candelabra are present. Family 2. PACHASTRELLIDZ.—The canal system is either eurypylous or aphodal. The tetrads are simple. Family 3. CORTICIDA.—The canal system is aphodal ; ths characteristic tetrads are candelabra, or forks with trifurcate arms, or forks with the surface ornamented by spines, or amphitetrads. SCIEN. PROC. R.D.S.—VOL. V. PT. 1V- O 178 Scientific Proceedings, Royal Dublin Society. Sub-order 2. TRIANINA. Family 1. TETILLIDA.—Flesh spicules are arculi or spirule ; the triana are characteristic; the canal system in the lowest forms is eurypylous, in the highest, aphodal; the ectosome in the lower forms is the outer epithelium and a thin layer of collenchyme ; in the higher, a highly differentiated cortex ; choanosome, a collen- chymatous mesoderm in the lower forms, sarcenchymatous in the higher. Family 2. THENEIDA.—The flesh spicule is a spini-spirula ; stellates are absent; the canal system is eurypylous; the ectosome is not differentiated to form a cortex; the mesoderm is collen- chymatous. Family 3. STELLETTIDA.—The characteristic flesh spicule is a stellate; other forms may also be present; the canal system is aphodal, but approaches the eurypylous type in the lower forms; the ectosome may, or may not, form a cortex; the mesoderm of the choanosome a sarcenchyme. Family 4. GEODINID#.—The characteristic spicule is the globate; the canal system always aphodal; the cortex always well - differentiated ; the mesoderm of the choanosome a sarcenchyme. — Sub-order 1. Family 1. PLAKINIDZ, Schultze. Genus 1. Epailax, g.n.—Plakinide, with large acerate spicules and small quadriradiate spicules. Epallaz callocyathus, sp. n.—Sponge, vasiform, expanding towards the upper margin, which is rounded, and gently undulat- ing, produced into a short, strong slender stalk below, by which it is attached; walls thin; oscules small, opening into the interior of the cup in longitudinal linear series irregularly alternating ; pores, in sieves on the outer surface, overlying the incurrent canals, which interdigitate with the excurrent canals, both being wide- branching sinuses produced by a folding of the choanosome. Both surfaces hispid; ectosome thin, collenchymatous ; choanosome, a collenchymatous mesoderm; eurypylous flagellated chambers. Spicules—(1) acerate, 3:04 by 0°078 mm.; (2) acerate, 3:93 by \ Sortas—On Tetractinellid Sponges. — 179 0:039 mm.; (3) calthrops, usually quadriradiate, but frequently tri- and bi-radiate, or sometimes quinqui- and sex-radiate; one ray of a tetrad, 0°0276 by 0:004 mm.; (4) stellates: these differ from the calthrops by possessing more numerous and smaller rays. Habitat.—Station 192, lat. 5° 49’ 15” 8.; 182° 14’ 15” E.; 140 fms. Family 3. CORTICIDA. Genus 1. Thrombus, g.n.—Corticidz, containing spined forks like those of Corticium kittoni, Carter (Thrombus kittont), see Ann. Mag. Nat. Hist., ser. 4, vol. xiv., p. 24. 1874. Thrombus challengeri, sp. n. Ee Mcodena: a collenchyme which contains numerous oval granular cells, 0°016 to 0:02 mm. in diameter. Spicules like those of Thrombus kittoni, but larger ; fork, shaft, 0'1 by 0°012 mm.; arms, 0°055 by 0:012 mm. Habitat.—Station 177; lat. 16° 45’ 8.; long. 168° 7’ W.; off Api, New Hebrides, 130 fms. Sub-order 2. Family 1. TETILLIDA. Genus 1. Tetilla, O. Schmidt.—The ectosome never forms a cortex, and is not provided with special spicules; the mesoden is a collenchyme, and the canal system eurypylous. ‘ Tetilla sandalina, sp. u.—Sponge small; more or less ellipsoidal, or fusiform ; a single lateral oscule at one il ectosome not deve- loped ; flagellated chambers large. Spicules—(1) fusiform acerate, 2°326 by 0:0237 mm.; (2) trichite acerates, 0°395 mm. long ; immeasurably thin; (8) trifid forks with filiform proximal ends ;, arms of unequal length ; one about 0:197, the other two 0-0513 mm. long; (4) arculi and sigmelle about 0025 mm. long; anchors absent. Habitat.—Azores, lat. 87° 26’ N.; long. 55° 13’ W. 1000 ome Tetilla leptoderma, sp. n.—Sponge small; somewhat spherical ; a single oscule, lower surface produced into slender rootlets, ectosome thin ; flagellated chambers large. Spicules—(1) a fusi- form acerate, 4:185 by 0:0474 mm.; (2) trifid forks, filiform at one end, rays of unequal length at the other, 4:03 by 0:0118 mm. ; 202 180 Scientifie Proceedings, Royal Dublin Society. the longer ray is 0°197, the two shorter, 0°106 mm. long ; (3) trichite forks, similar to the preceding, but smaller, and of hair-like fineness; shaft, 1:162 mm. long; (3) somal anchor, a fusiform shaft, with a filiform end, 6:0 by 0:01 mm.; arms, 0°118 by 0:012 mm; (4) radical anchors similar, but with a more mas- sive head, and a distal mucrone; shaft, 6°8 by 0:0276 mm.; arms, 0:154 by 0:0237 mm.; (5) arculi and sigmelle about 0:0125 to 0:019 mm. long. Habitat.—Lat. 37° 17’ S.; long. 538° 52’ W. 600 fms. Tetilla grandis, sp. n.—Sponge large, massive, sub-cylindrical, or sub-ellipsoidal, seated on a massive base of tangled anchoring spicules; oscules numerous, simple; surface hispid; ectosome, a fibro-vesicular collenchyme. Spicules—(1) fusiform acerate, 6:07 by 0:075 mm.; (2) trifid fork ; shaft cylindrical; a filiform end ; 8°67 by 0:016 mm., to 11°8 by 0:082 mm.; rays, 0°15 by 0:0118 tm. ; (3) trichite fork, with one ray longer than the other two ; (4) somal anchor, a fusiform shaft with filiform end, 12:14 by 0:02 mm.; rays, 0°16 by 0:012 mm. ; spread, 0:16 mm. ; (8) radical anchors, similar, but with a thicker head and shorter, stouter rays ; shaft, 31°50 by 0°315 mm.; rays, 0-1 by 0°024 mm.; spread, 0:1 mm.; (6) arculi and sigmelle, 00118 mm. long. In small specimens the spicules are smaller; thus, in one 18 by 13 mm. in diameter, the acerate is only 30 mm. long, in another, 32 by 26 mm., it is 4°65 mm. long. Habitat.— Kerguelen and Christmas Island. 10-150 fms. Tetilla pedifera, sp.n.—Sponge small, somewhat thumb-shaped ; surface hispid ; oscules numerous, small ; ectosome thin, supported by numerous acerates lying parallel to its surface. Spicules— (1) fusiform acerate, 3:2 by 0:03 mm.; (2) forks, a slender shaft, with a filiform end; arms of unequal length, varying from 3 to 1 in number ; shaft, 2°38 by 0:012 mm.; arms, long ray, 0°15 mm. ; two short rays, 0:06 mm. long; (3) anchors; arms reduced to one, so that the spicule somewhat resembles a shepherd’s crook ; shaft, 4°46 by 0:0276 mm.; ray. 0:13 mm. long; spread, 0°055 mm. Habitat.—Lat. 0° 48’ 30” 8. ; long. 126° 58’ 80” H. 826 fms. Genus 2. Chrotella, g. n.—The ectosome is a fibro-vesicular Sottas—On Tetractinellid Sponges. 181 collenchyme, with acerate spicules strewn through it in various directions, but not at right angles to the surface ; the mesoderm is a granular collenchyme; the canal system eurypylous, or aphodal. Chrotella simplex, sp.n. Sponge somewhat spherical; surface pilose ; oscules, one or more, minute. Spicules—(1) fusiform - acerate, 3:0 by 0:0237 mm. ; (2) trifid fork; shaft, with a filiform end, 3-4 by 0:02 mm.; rays, 0°158 by 0-016 mm.; (8) anchor; shaft, with a filiform end; axial fibre produced distally beyond the origin of the rays; shaft, 5°35 by 0:016 mm.; (4) sigmella and arculus, 0:0118 mm. long. Habitat.—Lat. 16° 50’ N.; 25° 8’ W. 260 fms. Chrotella macellata, sp.n.—Sponge spherical, depressed, with a flat base ; oscules multiple, each leading into a large cloacal chamber ; surface, hispid ; flagellated chambers small. Spicules—(1) fusiform acerate, 5°7 by 0:055 mm.; trifid forks, with short prongs, highly porrectate, 0:08 by 0:02 mm. ; shaft, fusiform, 7-95 by 0:0276 mm. ; (3) trifid fork, with longer rays, less porrectate, 0°23 by 0:02 mm. ; shaft, 2°5 by 0:24 mm. ; (5) two-pronged (dicellate), and one- pronged (macellate) forks, derived from No. 4 by reduction in the number of the rays; shaft, 3°49 by 0:0316 mm. ; prongs of dicel- late form, 0°44 by 0:0316 mm. ; of macellate, 0°58 by 0:0316 mm. ; (6) anchors, shaft, 6°5 by 0:°016 mm.; rays, 0:06 by 0:014 mm. ; (7) arculi and sigmelle from 0:012 to 0°016 mm. long; (8) a sig- mella with two turns (= a spirula), characterizes the cortex, 0:03 to 0:04 mm. long. Habitat.—Lat. 11° 37’ N.; long. 123° 31’ H. 18 fms. Genus 3. Craniella, O. Schmidt.—The cortex is differentiated into an inner fibrous, and outer collenchymatous layer; the latter excavated by intercortical cavities; the former traversed at nght angles by cortical acerates; the mesoderm of the choanosome is a sarcenchyme ; the canal system is aphodal. Craniella bowerbankii, sp .—-The spicules include—(1 fusiform acerates of the body, 3:26 by 0:047 mm., and of the cortex 1-4 by 0:04 mm. ; (2) forks, with a shaft, 5-12 by 0°024 mm.; rays, 0°12 mm. long.; spread, 0:06 to 0:07 mm.; (8) anchor, 5°8 by about 0°02 mm. The axial fibre of the shaft is continued into the head past the origin of the arms. Arculi andjsigmelle absent. 182 Scientific Proceedings, Royal Dublin Society. Habitat.—Port Jackson, var a.; Sydney, 35 fms., var. 6.; Zam boanga, var. c.; lat. 10° 80’S.; long. 142° 18’ H.; 8 fms. This is probably one of the two very different sponges which were named T. simillina by Bowerbank. Craniella pulchra, sp. n.—Spicules—(1) fusiform acerate 4:6 by 005 mm. Small acerate of the cortex 1:2 by 0:0395 mm. ; (2) trifid fork, shaft 7-1 by 0:°0225 mm.; prongs 0.125 mm. long. ; (3) anchor, shaft, 8°57 by 0:0165 mm. ; rays, 0:0484 by 0:012 mm. ; the axial fibre of the shaft extends into the head beyond the origin of the rays. Habitat.—Lat. 16° 50’ N.; long. 25° 8’ W. 260 fms. - Craniella carteri, sp. u.—Cortex, distinguished by curious cell- ageregates, distributed through its outer collenchymatous layer. These parenchyma-like masses of cells are sharply distinguished from the surrounding tissue, they scarcely stain with reagents, and contain ochreous-coloured spherical granules. Spicules— (1) fusiform acerate, 2°6 by 0:035 mm., and a smaller acerate of the cortex; (2) trifid forks, shaft, 3:5 by 0:014 to 0-016 mm.; rays, 0°0868 by 0°012 mm.; (4) anchors, with rays not quite terminal, the shaft being continued far enough to give a double curvature to the distal margin: shaft, 6°75 by 0°02 mm.; rays, 0°06 mm. long. Arculi and sigmelle absent. _ Habitat.—Bahia. Craniella schmidti, sp. n.—Spicules—(1) fusiform acerate, 1:34 to 2°23 by 0:03 mm.; and smaller acerates of the cortex, 0°414 by 0:0276 mm. long; (2) trifid fork, two varieties which pass into each other ; one with short, stout, rays, 0°127 by 0:0237 mm.; the other, with longer, slenderer, rays, 0°142 by 0:012; (8) anchors, rays, 0°075 by 0:016 mm.; spread, 0°01 mm.; the axial fibre extends into the head; (4) arculi and sigmelle, 0°0197 mm. long. Habitat.—Lat. 38° 30’ N.; long 31° 14 W.; 1000ims. ‘This sponge is probably one of those which O. Schmidt has named Sraniella cranium, which is a purely northern species, and it appears doubtful whether Schmidt had ever seen it. Genus 4. Cinochyra, g.n.—The ectosome forms a cortex, which consists chiefly of a dense fibrous felt; cortical acerates Sottas—On Tetractinellid Sponges. 183 traverse it transversely ; the innermost layer of the cortex is free from spicules ; the cortex is not excavated by intercortical cavities ;' the oscules and pores are confined to special flasked-shaped recesses ; the mouth of each flask is sphinctrate; the walls are perforated by pores which communicate with the incurrent or excurrent canals, as the case may be; the mesoderm of the choanosome is a granular collenchyme; the canal system is eurypylous. Cinochyra barbata, sp. n.—Sponge sub-spherical or sub-cylin- drical, seated on a dense mass of its own anchoring filaments. Oscules and pores as in genus. Spicules—(1) fusiform acerate, 8:03 by 0°71 mm.; and a smaller acerate of the cortex, 0°892 by 00355 mm. ; (2) forks, a fusiform shaft, 13°21 by 0:0296 mm.; rays, 0:178 mm. long; (8) trichite forks, shaft, 0:13 by 0-004 mm. ; rays variable in length, one longer, about 0:03 mm. long; two shorter, about 0:016 mm. long; (4) anchors confined to the lower part of the sponge ; shaft from 20-0 to 40-0 by 0-024 to 0-03 mm. ; rays, 0°103 by 0:016 mm.; spread 07118 mm.; (5) arculi and sigmelle, about 0:0156 mm. long.; (6) globules, 0:0585 mm. in diameter. Habitat.—Kerguelen, 10 to 150 fms. Family 2. THENEIDZ. Genus 1. Thenea.—Sponge of symmetrical form, with special- ised poriferous areas. The triana are bifurcated forks, with long secondary rays; and anchors. ; Thenea muricata, Bwk.—Occurs in the northern regions of the North Atlantic, not present in the Challenger collection. Thenea schmidti, sp. n.—Sponge similar to T. muricata, Bwk., but distinguished by the large size of its calthrops spicules, and by the comparative thinness of the collenchymatous layer about the canal walls; the rays of the calthrops from 0°175 to 0°205 mm. long. Habitat.—Station tv., lat. 36° 25’ N.; long. 8° 12’ W.; 600 fms. ; station 73, lat. 38° 30’ N.; long. 381° 14’ W.; 1000 fms. ; ‘and (O. Schmidt) Florida, 198 fms. T. grayi, sp. u.—Sponge with a more or less flattened summit and rounded base, which in young forms is hemispherical. Oscule, 184. Scientific Proceedings, Royal Dublin Society. large round, laterally placed, poriferous area, also lateral on the opposite side to the oscule: both oscular and poriferous margins fringed with long spicules. Rootlets few and slender. Flagel- lated chambers, 0:063 mm. in diameter. Spicules—(1) fusiform acerate, 10:07 by 0:026 mm., and 78 by 0:08 mm. ; (2) porrectate forks, shaft, 5:88 by 0:087 mm.; arms, 0°828 by 0:083 mm.; (3) bifurcated forks, shaft, 5°88 by 0:087 mm.; primary rays, 0:238 by 0:0725 mm. ; secondary, 1:193 by 0:06 mm.; (4) somatic anchor, shaft, 1:07 by 0:006 mm. ; rays, 0:048 mm. long; spread, 0:09 mm.; (5) radical anchor, 10°33 by 0°0175 mm. ; rays, 0°09 to 0012 mm. ; spread, 0:123 mm. ; (6) calthrops small, with slender rays, a single ray, 0°143 mm. long; (7) smaller calthrops of usual form; (8) spini-spirule, a stout spiral body, 0:0118 mm. long; spines, 0:016 mm. long. Greyish-white. Habitat.—Station 164 ¢c., lat. 34° 19’ 8.; long. 157° 31’ E. 400 fms. Thenea wyvillii, sp. n.—Sponge, upper surface rounded, cushion-like or flat, with a central, shallow, basin-like depres- sion, in which the excurrent canals open by small, numerous, oscula. Equatorial margin sharp, thin, without a spicular fringe, projecting over the lower surface, which is produced into several strong rootlets, ending below in a tangled spicular base. Poriferous membrane continuous round the equatorial area. Spicules— (1) acerate, 7°85 by 0:07 to 0:084 mm.; (2) porrectate fork, shaft, 6°8 by 0:072 mm.; arms, 0°5 mm. long; (8) bifurcate forks, distinguished by the crooked form of these shafts, which measure 4:28 by 0:0968 mm.; primary arms, 0:178 by 0:08 mm. ; secon- dary, 0°54 by 0:064 mm. ; (4) somatic anchors, shaft, 0-876 by 0-008 mm.; rays, 0:95 mm. long; spread 0:1 mm.; (5) radical anchors, 18:2 by 0:011 mm.; rays, 0°1 by 0°014 mm.; (6) cal- throps, very regular, triradiate and quadriradiate, as well as other forms; one ray of a quadriradiate measures from 0:08 to 0:09 by 00118 mm. ; (7) small calthrops; rays, from 4 to 10 in number, about 0:02 mm. long; (8) spini-spirule, a slender spiral shaft, and numerous spines, total length, 0:02 to 0-025; length of a single spine, 0:004 mm. Yellowish-white. Hubitat.—Station 209; lat. 10° 14’ N.; long. 128° 54’ W. 95 fms. Sottas—On Tetractinellid Sponges. 185 T. fenestrata, O. Schmidt. 3 T. delicata, sp. n.—Sponge, small symmetrical, a conical upper half, sharply defined from a hemispherical lower half; upper surface hirsute; oscule apical; flagellated chambers, 0-087 by 0-067 mm. Spicules—(1) acerate, 6°3 by 0:044 mm.; (2) por- rectate forks, shaft, 4:10 by 0:02 mm.; arms, 0°35 mm. long; (3) bifurcate forks, shaft, 4°82 by 0°065 mm.; primary rays, 0°143 by 0:06 mm.; secondary rays, 1:07 by 0:06 mm.; (4) somatic anchors, shaft, 0°954 by 0-008 mm.; rays, 0:075 mm. long ; spread, 0-876 mm.; (5) anchoring spicules terminate in rounded elub-like heads; shaft, 5°35 by 0:04 mm.; head, 0°0645 mm. wide ; (6) calthrops few, small, tending to a spiral form; rays, 0:08 by 0-008 mm.; (7) spini-spirule, shaft short and straight, spined at the ends; total length, 0:04 mm. Greyish-white. Habitat.—Station, 147., lat. 46° 16’ 8.; long. 48° 27’ W. 1600 fms. T. wrightii, sp. n.—Sponge depressed, a flat or obtusely conical upper surface, bearing the oscule; and a flat base ; margin more or less lobate ; equatorial recess discontinuous ; forming a number of circumscribed poriferous areas. Oscular and poral areas not defended by projecting spicules; rootlets absent. The flat cake- like form of the sponge is characteristic. Habitat.—Station 302, lat. 42° 43’ 8.; long. 82° 11’ W. 1450 fms. Genus 2. Normania.—Sponge without specialized porous areas, like those of Thenea ; triana; simple forks, without anchors ; quadriradiate spicules, as well as calthrops, occur in the choano- some ; mesoderm of the choanosome a collenchyme ; canal! system, eurypylous. Normania schulsti, sp. n.—A plate-like erect sponge, bearing pores on one surface, and oscules on the other; distinguished from Normania crassa by the size of its spicules; the acerates, 3°57 by 0-071 mm.; the forks, shaft, 0-714 by 0°071; arms, 0°357 mm. long. Habitat.—Station 150; lat. 52° 4’ 8. ; long. 71° 22’ EB. 150 fms. NV. crassiuscula, sp. u.—A plate-like sponge similar in character 186 Scientific Proceedings, Royal Dublin Society. of its spicules to WV. schulzii, but distinguished by the course of the excurrent canals, which run obliquely and longitudinally upwards through the plate to open in patent oscules on one face of the late. Habitat.—Porto Praya, St. Jago. 100-128 fms. NV. goliath, sp. n.—Sponge massive, surface raised into sharp undulating ridges, with deep intervening furrows; surface hispid ; oscules numerous on the sides and summits of the ridges. Spicules— (1) fusiform acerate, 2°475 by 0:08 mm.; (2) calthrops, each ray 0:684 by 0:05 mm.; (38) acerella, 0°316 by 0:008 mm. ; (4) echi- nella, 0°16 mm. long; (5) globules, 0-16 mm. in diameter. Habitat.—Station 122; lat. 9° 5’ S.; long. 34° 50’ W. 350 fms. NV. laminaris, sp. n.—Sponge, a thin lamellar expansion 4 to 5 mm. thick; oscules small, dispersed on the inner face. Spicules— (1) a stout fusiform acerate, 3:5 by 0°05 mm. ; (2) a slender cylin- drical acerate, 5°3 by 0:008 mm.; (3) fork; shaft, 0°678 by 0:06 ; arms, 0357 by 0:06 mm.; calthrops, acerella, echinella, and spini- spirula also present. Habitat.—Amboyna. NV. tenuilaminaris, sp. n.—This chiefly differs from the preced- ing species by the greater thinness of the wall, which is from 3 to 3°5 mm. thick. I now only provisionally distinguish it, reserving a final decision to the completed report. Habitat.—Station 236, lat. 34° 58’ N.; long. 189° 29’ E.; 238-775 fms. _ Genus 3. Vulcanella, ¢. n.—Spicules similar to those of Nor- mania; sponge distinguished by the specialisation of the oscula, each the large patent opening of a shallow cloaca, which is lined by a coarsely fenestrate membrane. Vulcanella cribrifera, sp. n.—Sponge egg-shaped, bearing one or more large oscules on the upper surface; margins of oscules strongly hispid. Spicules—(1) fusiform acerate, 3:04 by 0:067 mm. ; (2) slender hispidating acerate, 7-5 by 0-032 mm.; (8) fork, shaft, 1:0 by 0-04 mm.; arms, 0°25 by 0-032 mm.; (4) calthrops Sornas—On Tetractinellid Sponges. 187. (possibly not proper to the sponge), rays from 0°28 to 0-64 mm. long; (5) acerella, 0:011 mm. long; (6) spini-spirula, 0-016 to 0:02 mm.; (7) cylindrical spicules, with rounded ends (sausage- shaped), 0:357 by 0:028 mm.; these are confined to the cloaca. Habitat.—St. Jago, Porta Praya. Genus 4. Characella, g, n.—Similar to Normania, but dis- tinguished by the absence of forks in the choanosome; and by possessing only one form of flesh-spicule, which is an amphiaster form of spini-spirule. Characella aspera, sp. n.—Sponge irregular in form; growing into irregular ridges, lobes, and folds; oscules numerous ; pores generally dispersed or collected within circular depressed areas. Spicules—(1) acerate, 1-476 by 0-073 mm.; (2) forks, shaft from 0-2 to 0-4 by 0:04 to 0:074 mm. ; arms, when simple 0°2 to 0°64 mm. long; when bifurcate, primary rays, 0:143; secondary, 0°27 mm. long; (3) acerella, 0-4 by 0:008 mm.; (4) amphiaster, 0:0276 to 0:0434 mm. long; (5) globules 0:05 mm. in diameter. Habitat.—Station 122; lat. 2° 5’ S.; long. 84° 50’ W. 350 fms. Family.—STELLETTIDZ. The genera of the family Stellettida may be arranged in sub-families, as follows :— A. Stellettides with but one form of stellate. 1. Sub-family. HOMASTERINA. Ectosome not a cortex—Myriastra. Ectosome a cortex.—Pilochrota. Asterella. B. Stellettides with more than one form of stellate (Heteras- terina). (a) Both forms are stellates. 2. Sub-family. STELLETTINA. Stellates are the only flesh spicules. Without a cortex—Anthrastra. With a cortex—Stelletta. Trichite sheaves are also present—Dragmastra. 188 Scientific Proceedings, Royal Dublin Society. (5) One form is a stellate, the second a sanidaster. 3. Sub-family. SANIDASTERINA. No other flesh spicules are present—Tribrachium. Trichite sheaves are present as well—Tethyopsis. (c) One form isa stellate, the second an amphiastrella. 4. Sub-family. STRYPHNINA. A single genus—Stryphnus. (d) One form is a stellate, the other a spined bacillus. 5. Sub-family. PSAMMASTERINA. A single genus—Psammastra. Although this classification appears to be wholly based on the flesh-spicule, it is not so in fact; but it happens as a remarkable coincidence that differences in the flesh-spicule are as a rule asso- ciated with other and profounder differences in the organism: we might easily have brought the latter more prominently forward in this classification, but it would have involved more space than we can here afford. Genus 1. Myriaster.—Sponge small; oscules distinguishable from pores; ectosome thin, mainly collenchymatous, excavated by widely extending sub-dermal cavities, which are never restricted to form chones. Flesh spicules, chiasters only. (‘The chiaster is a small stellate, with an excessively minute centrum, hair-like rays either abruptly truncated at the ends, or capitate; usually few in number. ‘The typical forms, with few rays and capitate ends, may be fancifully supposed to represent the Greek letter x, hence the name chiaster). ‘The mesoderm is a sarcenchyme, the flagellated chambers small, usually about 0:02 mm. in diameter; they open by short abiti into the excurrent tubes. Distribution chiefly in Australian seas. Myriaster subtilis, sp. n.—Sponge small, lobate; a few small oscules. Spicules—(1) acerate, 1°35 to 1:5, by 0°082 mm.; (2) fork ; shaft, 1:2 by 0:04 mm.; rays bifurcate ; primary rays, 0°042; secondary, 0:16 mm. long; (3) anchor, shaft, 1:16 by 0:°012 mm. ; Sortas—On Tetractinellid Sponges. 189 rays, 0°04 mm. long ; (4) chiaster ; rays capitate, 0:008 to 0:016 mm. in diameter. Habitat.—Kobei, Japan. 8 to 50 fms. Myriaster simphicifurca, sp. n.—Sponge small; a single oscule on upper surface. Spicules—(1) acerate, 2:0 by 0:0316 mm. ; (2) fork, shaft, 2°325 by 0-055 mm.; arms, simple, 0:37 by 0:054 mm.; (3) anchor, shaft, 1:86 by 0:03 mm.; rays, 0:12 mm. long; (4) chiaster, 0:012 mm. in diameter. Habitat. —Station 186, lat. 10° 30’ 8. ; long. 142° 18’ E. 8 fms. Myriaster toxodonta, sp. n.—Sponge small ; a few small oscules. Spicules—(1) acerate, 3°42 by 0:032 mm. ; (2) fork, shaft, 3-5 by 0°05 mm; arms, bifurcate; primary rays, 0:095 to 0:127 mm. long; secondary, 0-29 to 0°32 mm. long; (8) anchor, shaft, 3°6 by 0-024 mm. ; rays, 0'1114 mm. long ; (4) chiaster, 0°01 to 0:°016 mm. in diameter. | Habitat.—Station 208, lat. 11° 6’ N.; long. 123° 9’ EK. 20 fms. Myriaster clavosa, Ridley. Habitat.—Stations 186 and 208. Myriaster quadrata, sp. u.—Sponge small, a single small oscule. Spicules—(1) acerate, 2°56 by 0016 mm.; (2) fork, shaft, 3-2 by 0028 mm.; arms, bifurcate; primary rays, 0:11 mm., secondary rays, 0°27 mm. long; (3) anchor, shaft, 3:14 by 0:02 mm.; rays, 0-1 mm. long; (4) chiaster, 0-008 mm. in diameter. Habitat.—Station 212, lat. 6°54’ N.; long. 122°18’ E. 10 fms. Genus 2. Pilochrota, g. n.—Oscules distinct, pores in sieves overlying incurrent chones; ectosome, thick fibrous cortex; flesh spicules, chiasters; choanosome, as in Myriaster. Distribution : Australian seas, Tahiti, West Indies, 8. Atlantic. Pilochrota haeckeli, sp. n.—Sponge sub-globular ; oscule single. Spicules—(1) acerate, 2°07 by 0-046 mm.; (2) fork, shaft, 2°18 by 0:055 mm.; arms, simple, 0:24 to 0:32 mm.; (8) anchor, shaft, 3°03 by 0:035 mm.; rays, 0°16 mm. long; (4) small acerate of the cloaca; (5) chiaster, 0:016 mm. in diameter. Habitat.—Zamboanga. 10 ims. 190 Scientific Proceedings, Royal Dublin Society. - P. anancora, sp. n.—Sponge small, spherical, depressed, oscule single. Spicules—(1) acerate, 1°68 by 0:023 mm., to 3:18 by 0:023 mm.; (2) fork, shaft, 1°63 by 0:0276 mm. ; arms, simple, 0127 mm. long; (8) chiaster as usual. Habitat.—Bahia. 7-20 fms. P. gigas, sp. u.—Sponge massive ; several large oscules on the upper surface. Spicules—(1) and (2), 3-18 by 0-024 mm. ; acerate, 1:7 by 0:039 mm.; (8) fork, shaft, 1:96 by 0-039 mm.; arms, 0-223 mm. long; (4) chiaster, capitate rays, 0°013 mm. in dia- meter. Habitat.—St. Paul’s Rocks. P. tenuispicula.—Sponge small, oscule single. Spicules— (1) acerate, 1:35 to 2°3, by 0°016 mm.; (2) fork, shaft, 1:6 by 0-016 mm. ; arms, 0°12 mm. long; (38) chiaster; rays not capitate, 0:012 mm. in diameter. Habitat.—Bermuda, W. Indies, P. pachyderma, sp. n.—Sponge massive, lobate, free, two or more oscules on the upper surface; cortex very thick. Spicules— (1) acerate, 1:193 by 0:0178 mm.; (2) fork, shaft, 1:114 by 0:022 mm.; arms, simple, 0:12 mm. long; (3) anchor, shaft, 1°35 by 0:0158 mm. ; rays, 0-067 mm. long; (4) chiaster, rays abruptly truncate, but not capiate, 0:006 to 0-011 mm. in diameter ; colour, purplish. Habitat.—Tahiti. 30-70 fms. P. crassispicula, sp. n.—Sponge irregularly spherical ; free ; oscule single. Spicules—(1) acerate, 3°5 by 0:°024 mm., and 2:3 by 0:052 mm. ; (2) fork, shaft, 2°36 by 0:08 mm. ; arms, 0:254mm. long; (8) chiaster, rays capitate; from 0-012 to 0-02 mm. in diameter. | Habitat.—Bahia. 7 to 20 ims. P. purpurea, Ridley. P. longancora, sp. n.—Sponge small; a single circular oscule, having the margin fringed by minute acerates projecting radiately in the plane of the apertures. Spicules—(1) acerate, 1:63 by Soritas—On Tetractinellid Sponges. ‘191 0°085 mm. ; (2) fork, shaft, 2:1 by 0:047 mm. ; arms, simple, 0°35 mm. long; (38) anchor, shaft, 3°56 by 0:024 mm.; rays, 0075 mm. long; (4) minute acerate of oscular margin; (5) chias- ter, 0:009 mm. in diameter in the ectosome, 0:012 mm. in choano- some. Habitat.—Torres Straits. 3-11 fms. Genus 3. Anthastra, g. n.—Sponge usually more or less spherical ; oscules distinguishable from the pores or not; ectosome thin, chiefly collenchymatous, excavated by extensive sub-dermal cavities which never form chones; choanosome as in Myriaster. Flesh spicules an anthaster and usually a chiaster. (The anthaster is a stellate with conical or bacillar microspined rays, which may be numerous but are usually few in number, and may be reduced to two, when a spined bacillus is the result.) Distribution: Australian seas, and Japan. Anthastra communis, sp. n.—Sponge more or less spherical, free or attached ; oscules not distinguishable from the pores. Spicules —(1) acerates 4:2 to 5:6 by 0:06 to 0-09 mm. (2) fork with bifur- cated arms, primary rays projecting forwards and outwards, some- times more outwards than forwards, sometimes the reverse, then giving the head a cyathi-form appearance, secondary rays horizon- tal, shaft, 4:4 to 5:7 by 0:09 to 0-11 mm.; primary rays, 0°14 to 0-16; secondary, from 0°52 to 1:114 mm. long; (8) anchor, shaft, 3'0 to 43 by 0°32 to 0°39 mm.; rays, 0°127 to 0:16 mm. long. ; (4) anthaster, rays few, 0:02 to 0:03 mm. long; (5) chiaster, spines numerous, 0:006 to 0:008 mm. long; colour, greyish-white, some- times russet-red (owing to presence of algal cells ?). Baers Habitat.—Station 162, lat. 39° 10’ 30” S.; long. 146° 37’ E.; 388 fms. Station 162a; lat. 36° 59’ 8.; long. 150° 20’ E.; 150 fms. Port Jackson, 6 to 15 ims. Anthastra pulchra, sp.n.—Sponge small, globular, free, a single oscule. Spicules—(1) acerate, 2:4 to 3°1 by 0:0315 mm.; (2) fork with simple arms, shaft, 2°6 to 2-9 by 0:0474 mm.; arms, 0:26 mm. long; (3) anchor, shaft, 2°6 to 2:9 by 0:0315 mm.; rays, 0:125 mm. long; (4) anthaster, rays few, 0:016 mm. long; ‘O) chiaster, variable in character, rays seldom capitate. Habitat.—Station 163a.; lat. 36° 59’ S.; long. 150° 20’ E. 150 fms. | 192 Scientific Proceedings, Royal Dublin Society. Anthastra parvispicula, sp. n.—Sponge small, spherical, free, a single small oscule. Spicules—(1) acerate 1:3 by 0-02 mm.; (2) fork with simple arms, shaft, 1°75 by 0:02 mm.; arms, 0°21 mm. long; (3) anchor, shaft, 1:3 by 0016 mm.; rays, 0:045 mm. long ; (4) anthaster as in A. pulchra ; (5) chiaster, rays not capitate, 0:0118 mm. long. Habitat.—Station 161; lat 38° 21’ 30” 8.; long. 144° 36’ 30” H. 30 fms. Genus 4. Ecionema, Bwk.—Similar to Anthastra, but with the oscules confined to the summit, the excurrent tubes running longi- tudinally and vertically through the sponge. Ecionema ridleyi, sp. u.—Sponge ovate, several small oscules on the summit. Spicules—(1) acerate, 4:07 by 0118 mm. ; (2) fork, with simple arms, 4:3 by 0118 mm.; arms, 0:27 to 0°32 mm. long; (8) anchor, shaft, 3:6 by.0:03 mm.; rays, 0:103 mm. long; (4) anthaster, small; rays few or numerous; a single ray of a tetrad form, 0-01 by 0:004 mm. ; (5) chiaster, rays slender, hair-like, capitate, 0'016 mm. in diameter. Habitat.—Port Jackson. 30-35 fms. Ecionema pyriformis, sp. n.—Sponge obconic, attached by flat base, summit bearing numerous small oscules; pores in sieves, generally distributed over the sides ; chief excurrent canals vertical. Spicules—(1) acerate, 3°14 by 0°095, to 4 by 0104 mm. ; (2) fork, shaft, 3°02 by 0:095, to 3°72 by 0°163; arms bifurcate ; primary rays, 0°1114, secondary rays, 0-1114 to 0-175 mm. in length ; (3) anchor, shaft, 2°1 by 0°023 mm. ; rays, 0:016 mm. long; (4) anthaster, bacillary rays with rounded ends, microspined, usually 4 to 7 in number; a single ray of a tetrad form, 0:013 by 0:004 mm.; (5) chiaster rays capitate, 0°008 mm. long. Habitat.—Port Jackson. 30 to 35 fms. Genus 4. Stelletta, Schmidt.—Hctosome a thick cortex, traversed by chones. Spicules, two kinds of stellates, one with conical pointed rays. Stelletta phrissens, sp. n. Kneis, globular or cylindrical, attached ; surface hispid, with spicules which project 6 to 7 mm. beyond it; oscules small, congregated ; pores in sieves; cortex thick, Sottas—On Tetractinellid Sponges. 193 the outer collenchymatous layer without spicules. Spicules— (1) acerate, 4°75 by 0:07 mm.; (2) fork, shaft, 3:5 to 4:2, by 0-12 mm.; rays bifurcate; primary rays about half the length of secondary, which are 0°3 mm. long; (3) anchor, shaft, 8°72 by 0:06 mm.; (4) stellate sharp conical rays, small centrum; rays from 0:02 to 0-027 mm.; (5) pycnaster, a comparatively large centrum, provided with numerous short spines, with truncated ends, 0:01 mm. in diameter. Habitat.—Station 308, lat. 50° 8’ 30” §.; long. 74° 41’ W. 175 fms. Genus 5. Astrella, g. n.—Like Stelletta, but with only one form of stellate, a pycnaster, i.e. with a small centrum, and short blunt, numerous, rays. | Astrella vosmaert, sp. n.—Sponge, beehive-shaped, oscules not distinguishable from the pores. Spicules—(1) acerate, 3-14 by 0:06 mm.; (2) fork, shaft, 3:02 by 0:08 mm.; arms bifurcate ; primary rays, 0-088, secondary, 0-24 mm. long; (8) anchor, shaft, 3°61 by 0:028 mm; arms, 0:04 mm. long; (4) pyenaster, a com- paratively large centrum and short, thick, truncated rays, 0-012 to 0:016 mm. in diameter. Genus 6. Dragmastra.—Like Stelletta, but with a layer of trichite sheaves in the cortex. Type, Dragmaster (Stelletta) normant (Sollas), Norway. Genus 7. Stryphnus, g. n.—Stellettidee distinguished by the absence of a radiate arrangement of the spicules of the choanosome, only those which immediately approach the surface of the sponge being arranged at right angles to it; by the comparatively small size and rarity of the fork spicules as compared with the acerates, and chiefly by the presence of a curious irregular flesh-spicule— the amphiastrella. The cortex is a vesicular collenchyme contain- ing pigment cells. Stryphnus niger, sp. n.—Sponge, compound, massive, oscules large, collected in groups. Spicules—(1) acerate, 2:4 by 0-61mm. ; (2) fork, shaft, 0-446 by 0:0356 mm.; arms bifurcate; primary rays, 0:055, secondary, 0°079 mm. long; (3) anchors; (4) stellate, a small centrum and numerous slender conical-shaped pointed rays, 0:014 mm. long; amphiastrella, various, typically a short cylin- SCIEN. PROC. R.D.S.—VOL. V. PT. IV. P 194 Scientific Proceedings, Royal Dublin Society. drical shaft with a whirl of spines at each end; the spines may be sharp, but are more usually stunted and rounded off, or the spines may be given off quite irregularly from all parts of the shaft; 0:016 by 0:012. Colour, deep puce black. Habitat.—Port Jackson. 30-835 fms. Stryhnus unguicula, sp. u.—Sponge similar to 8. niger. Dis- tinguished by the forks, the arms of which are bifurcate, with the primary rays extending, only slightly forward, and the secondary rays diverted backward ; each pair of the latter, also, after diverg- ing from each other in the usual way, are approximated so as to run parallel to each other for the last half of their course ; shaft, 0508 by 0:°032 mm.; primary rays, 0°0276, secondary rays, 0:04 mm. long. Habitat.—Port Elizabeth, 8. Africa (not in Challenger Collec- tion). Genus 8. Tribrachium, Weltner.—Sponge, a spherical body, produced into an excurrent tube, but not into a special incurrent tube. Spicules—forks, with only two arms in the excurrent tube, with three arms in the cortex of the body ; acerates, anchors, rarely stellates, and numerous sanidastra. Genus 9. Tethyopsis, Stewart.—Sponge, a special poral tube at one pole of the spherical body and a special oscular tube at the other; canal system arranged on a radiate plan, primitively four excurrent canals, alternating with four incurrent canals. Spicules— reduced forks in the excurrent tube; forks with three arms, or only two or one in the cortex of the body, acerates, but no anchors; in the poral tube acerates, no forks or anchors; flesh-spicules are stellates, sanidastra, and trichite sheaves. Genus 10. Psammastra, g. n.—Sponge, with a thick fibrous cortex incorporating grains of sand; oscules, two or more; surface raised into conuli; spicules—a stellate with short rays and large eontrum, and another form with smaller centrum and larger rays, also, and most numerous spined bacilli ; forks of very peculiar character, rays very short, appearing merely as spines of an acerate spicule with a rounded distal end. — Sottas—On Tetractinellid Sponges. 195. Psammastra murrayi, sp. u.—Sponge spherical, with two or _ three oscules; surface raised generally into conuli, and produced here and there into strong fibrous bands for attachment; cortex thick, containing imbedded grains of sand. Spicules—(1) acerate, 4:65, and over, by 0-065 mm. ; (2) fork, 3:9 by 0-071 mm.; arms simple, regularly curved outward and forward, 0-097 to 0:116 mm. long ; spread, 0-161 to 0°175 mm.; (8) modified fork; a conical spicule, with rounded distal base, and three short spines given off near the distal end; the axial ray of the spines descends outwards and downwards through the spicular shaft, but bends into hori- zontal position as it enters the rays or spines, which may be simple or bifurcate, the bifurcation taking place in a horizontal or vertical. plane; (4) stellates, a variety with large centrum and short rays, 0-012 to 0.616 mm. in diameter, passing into a second variety with small centrum and longer rays, 0-016 to 0-024 mm. in dia- meter; (5) bacillus, a cylindrical rod with rounded ends, micro- spined irregularly over the whole surface; sometimes constricted in the middle, 0:018 to 0:016 by 0:004mm. Colour, russet brown on upper surface where exposed to the light ; pale grey below. Habitat.—Station 162, lat. 39° 10’ 30” 8.; long. 146° 37’ BE. 38 fms. Family. GEODINIDZ. Genus 1. Erylus, Gray. Genus 4. Synops, Vosmaer. » 2 Caminus, Schmidt. 5, 0. Isops, Sollas. » 98 Cydonium, Miller. » 6. Geodia, Lamk. Of the genus Geodia no examples occur in the Challenger Collection. Synops is an exceedingly natural genus, characterized, not only by the restriction of the oscules to one surface, but also by the general characters of its spicules; anchors rarely occur, and the arms of the forks are usually simple. DEscRIPTION OF SPECIES. Lrylus formosus, sp. n.—Sponge massive, growing into ridges and lobes, attached ; oscules round, few; pores large, each the simple opening of an incurrent chone. Spicules—(1) acerate, 0-9 by 0:°024 mm. ; (2) fork, shaft, 0-4 by 0:024 mm. ; arms simple; ~ P2 196 Scientific Proceedings, Royal Dublin Society. (3) globate, shaped like a finger biscuit, or shuttle-shaped, or lozenge-like, surface granulated, 0-14 by 0-032, to 0°175 by 0:026 mm., or narrower and longer, 0:2 by 0°024, or shorter and wider, 0122 by 0:048 mm. ; thickness, from 0:008 to 0°01 mm. ; (4) fusite, 0:07 by 0:006 mm. ; (5) large stellate, with few rays, 0:063 mm. in diameter, a single ray, 0°032 mm. long; (6) small stellate, a small centrum, and numerous short rays, truncated, or capitate at the ends, 0°016 mm. in diameter. Habitat.—Bahia. 7-20 fms. Caminus spheroconia, sp. n.—Sponge massive, with massive vertical lobes, attached ; oscules on summits of lobes, large, leading into large cloacas; pores in sieves, roofing incurrent chones. Spicules—(1) acerate, 0°5 by 0:016 mm.; (2) fork, shaft, 0°32 by 0°016 mm.; arms simple, 0:2 mm. long; (3) globate, 0°0553 mm. in diameter ; (4) globule, a minute, smooth sphere, 0°004 mm. in diameter ; this serves both as ectaster and endaster ; colour, purplish when exposed to the light; yellowish below. Habitat.—Bahia, shallow water. This sponge is very similar to Caminus vulcani, O. 8., which also contains true forks and globules; it differs by the absence of stellates, which are present in C. vulcani, and by the less length of its acerate spicules (0:08 by 0:016 mm. in C. vulcani), and by the smaller size of the globule (0.1 mm. in diameter in C. vulcani). The cortex is about 0:8 mm. thick, and consists of an ecto-cortex formed of vesicular tissue, 0°05 to 0°24 mm. thick, of a globate layer, 0°65 mm. thick, and an inner fibrous layer, 0-05 to 0:08 mm. thick. — Cydonium glariosus, sp. n.—Sponge, more or less spherical, attached ; the collenchymatous ecto-cortex is crowded with coarse grains of sand, and traversed by pencils of short acerates, which are entirely confined to it. Spicules—(1) acerate, 1°86 by 0-026 mm. ; (2) small acerates of the cortex, 0°35 to 0:4, by 0:016 mm. ; (3) fork, shaft, 2°86 by 0:052 mm. ; arms simple; (4) second form of fork, shaft, 5°36 by 0:03 mm.; arms simple, 0:08 to 0:11 mm. long; (5) anchor, shaft, 4:65 by 0°012 mm.; rays, 0:08 mm. long ; (6) globate, spherical, 0:05 to 0:058 mm. in diameter ; (7) ectaster, small centrum, short rod-like rays, 0:01 mm. diameter; (8) en- Sottas—On Tetractinellid Sponges. 197 daster, centrum small, rays conical pointed, or rod-like truncated, 0-016 to 0:0193 mm. in diameter. Colour, purplish white. — Habitat.—Bahia. 7 to 20 fms. Cydonium magellant, sp. u.—Sponge large, attached ; surface hispid. Spicules—(1) acerate, 3-93 by 0:052 mm., to 2°71 by 0-058 mm. ; (2) fork, shaft, 3:93 by 0:064, to 4:82 by 0:09 mm. ; arms bifurcate; primary rays, 0°13, secondary, 0°275 mm. long ; (3) anchor, shaft, 7-4 by 0°02 mm. ; rays, 0°15 mm. long; (4) glo- bate, spherical, depressed, 0:123 by 0:103 mm.; (5) ectaster; a fairly large centrum, numerous rod-like rays, 0°0118 mm. in diameter ; (6) endaster, a globo-stellate, 0-217 mm. in diameter. Habitat.—Stations 308 and 3811. 175 and 245 fms. Cydonium hirsutus, sp. n.—Sponge irregular lobate; surface hispid, spicules projecting 8 or 9 mm. beyond it, cortex thick. Spicules—(1) acerate, 4:5 by 0:06 mm. to over 9:0 by 0-032 mm.; (2) fork, shaft over 4-46 mm. long by 0:084 to 0°05 wide; arms bifurcate, primary arms, 0:13; secondary, 0°35 mm. long; (3) second form of fork, shaft long, diameter, 0°2 mm., arms simple 0:18 mm. long; (4) anchor, shaft, long, 0:°018 mm. in diameter; rays, 0:036 mm. long; (5) glohate, a flattened prolate ellipsoid: 0-306 by 0:245 by 0-161 mm.; (6) ectaster, a small centrum, and blunt conical rays, 0012 mm. in diameter ; (7) en- daster, a small centrum, and a few slender conical rays, 0:02 mm. in diameter: a small globo-stellate is present, but does not belong to the sponge. Habitat.—Station 192; lat. 5° 49'15” 8. ; long. 182° 14° 15” W.; 140 fms. Synops vosmaeri, sp. u.—Sponge cylindrical, a cup-shaped depression at the summit, erect, attached, oscules confined to the summit; pores in sieves on the sides, roofing incurrent chones. The ecto-cortex contains ectasters scattered throughout it; the globate layer is thin, and the fibrous layer remarkably thick. Spicules—(1) acerate, from 1:3 by 0:016 to 1-7 by 0-008 mm. ; (2) acerate of the cortex, 0°3 by 0:004 mm.; (8) fork, shaft, 1-1 by 0:039 mm.; arms, simple, 0:29 mm. long; (4) globate, small, spherical, 0°04 mm. in diameter; (5) ectaster, a small centrum, short spines, with rounded ends, 0:004 mm. in diameter; (6) en« 198 Scientific Proceedings, Royal Dublin Society. daster, long hair-like rays, not numerous, 0-026 mm. in dia- meter. Habitat.—Station 122; off Barre Grande. 350 fms. Synops nitidus, sp. u.—Sponge plate-like, horizontal, oscules numerous, small, restricted to the upper surface over which they are dispersed ; pores in sieves on the opposite surface; cortex—beneath the epithelium is a layer of small globo-stellates, this is sueceeeded immediately by the globate layer, which constitutes almost the whole of the cortex. Spicules—(1) acerate 1:25 by 0°026 mm.; (2) fork, shaft, 1:07 by 0°039 mm., arms simple, 07183 mm. long; (3) ectaster, a globo-stellate, 0'0135 mm. in diameter ; (4) endaster, a small centrum, and long conical microspined rays, usually few in number, 0°044 in diameter. Habitat.—Port Jackson, Sydney. The smooth, shining, upper surface is very characteristic, and no other species of Synops presents the same horizontally spreading form. Synops neptuni, sp. n.—This is the largest, tetractinellid sponge known. It has the form of a somewhat conical cup with a large central cavity, rising from a base of 12 cm. diameter to a height of 40 cm.; where broadest its diameters are 22 cm. and 31 cm. Its wall is intricately folded. The oscules are confined to the inner surface of this cup. Habitat.—Station 122; off Brazil. 32 fms. Isops pachydermata, sp. u.—Sponge, irregular, massive ; surface smooth ; oscules and pores singly perforating small rounded bosses ; cortex thick, constituted almost entirely of the globate layer; beneath the epithelium a layer of globo-stellates. Spicules— (1) acerate, 1:96 by 0:052 mm. ; (2) fork, shaft, 1:07 by 0:039 mm. ; arms simple, 0°27 mm. long; (8) globate, a compressed ellipsoid, 0:24 by 0°19 mm. in diameter; (4) ectaster, a globo-stellate, 0-016 in diameter; (5) endaster, centrum small, spines conical, sharply- pointed, tew; single ray of a triad form, 0-064 mm. long; (6) a stellate intermediate between (4) and (5). Habiiag —Station 56; lat. 32° 8’ 45” N.; long. 64° 59’ 35” W. 1075 fms Sortas—On Tetractinellid Sponges. 199 DEFINITION oF TERMs. Ectosome.—The outer layer of the sponge, not containing flagellated chambers. Choanosome.—The “mark” or “parenchyma,” distinguished by the presence of flagellated chambers. Eurypylous.— When the flagellated chambers communicate by wide mouths directly with the excurrent canals. Aphodal.—When they do so by narrow canaliculi. Collenchyme.—Gelatinous connective tissue. Sarcenchyme.—A. collenchyme in which the codlenchytes or branch- ing stellate cells are replaced by granular polygonal contiguous cells. Triana.—Tetrad spicules with a differentiated shaft—forks, and anchors. [ 200 |] XXV.—IRISH METAL MINING. By G. H. KINAHAN, M.R.I.A., Ere. [Read, March 24, 1886.] Tue lists of mines published by Griffith in the Dublin Quarterly Journal of Science (1861) were corrected and revised in chap. XXI. section v. pp. 361, &e., of the Geology of Ireland (1878) ; but these now require revision. Itis therefore proposed to again revise and, at the same time, to re-arrange them, first giving separate lists for each mineral arranged in counties, or in “fields” where the ores are bedded, with, subsequently, short County Histories of the mines, thus dividing the subject into two parts. In both parts the Counties, as far as possible, will be arranged alphabetically. In Part I. the lists include all the places where the different minerals are recorded as found in appreciable quanti- ties ; and in Part II., when possible, the present state of the lodes will be stated ; butin both Parts, in the majority of cases, the infor- mation given as to the work done, on account of the unsatisfactory way in which the old mining records and statistics were kept, will be on hearsay evidence. ‘The statements, therefore, cannot be taken as perfectly satisfactory, as a large portion may require to be substantiated. The history of the early Irish mining adventures is very scant, the records being vague. The ancient mines are referred to by Griffith, Kane, and other modern explorers; but necessarily the remarks had to be more or less vague, and do not give much infor- mation. Griffith, however, states :—‘‘ Many of our mining exca- vations exhibit appearances similar to the surface workings of the most ancient mines in Cornwall, which are generally attributed to the Phoenicians.” Krnanan—Irish Metal Mining. 201 The late R. Rolt Brash published an interesting Paper on “The Precious Metals and Ancient Mining in Ireland” (Journal Roy. His. Arch. Ass. Ireland, vol. i., fourth series, p. 509) ; but it more particularly refers to the “finds” of gold and silver articles ; these metals having been worked and mined at an early date. Bronze implements are also very ancient, and possibly iron; but the latter metal corrodes away so fast that all ancient implements must have disappeared long since; though traces of them may sometimes be found. It may be mentioned;that deep down among the records of the earliest inhabitants of the large crannog in Lough Rea, Co. Galway, I found a rod of rust that evidently was the remains of an iron implement; it must have been 2000, or 3000, or more, years old. Of Ancient Metal Mining, or its Adjuncts.—A. very early record occurs in the Annals of the Four Masters, a.M., 3656, where gold is mentioned as procured in Foithue Airthir Liffe, or in the moun- tains of Dublin and Wicklow; while at Lyra, Knockmiller, about two miles southward of Woodenbridge, Co. Wicklow, the ancient timberings in a placer mine were found. We also learn from the Annals that in a.m. 3817 silver shields were made at Argetios (Silverwood) on the Nore, Co. Kilkenny. In this neighbourhood are the remains of ancient mines at Ballygallion and Knockadrina— places at which in recent years native silver has been found. It appears probable that, in those early times, some at least of the silver was procured at those mines; there are, however, other prehistoric mines that probably were also sources from which silver was procured. There is also mentioned in the Annals ; silver, got at Rosargid (which also means Silverwood), near Toomavara, Co. Tipperary. That name has not descended to us; but at Garrane, adjoining Kilnafinch, a little southward of Toomavara, is the debris of an ancient mine, locally called the “Silver Mine.” Further westward, south of Nenagh, are the village and mines of Silvermines. Some of the mines at this village were worked so long ago, that when opened, about the year 1860, the attals ( pyrite and sphalerite) in the stulls and old levels were found to have undergone a complete chemical change—into peroxide of iron, with carbonate and silicates of zinc. In recent years some of the lead from this locality has given as much as eighty ounces of silver to the ton, in addition to some native silver. Still, further west- 202 Scientific Proceedings, Royal Dublin Society. ward, at Garrykennedy, on Lough Derg, “old men’s workings” were broken into about the year 1855, and in them were found a man’s skeleton and the remains of wooden and stone tools. To the westward of the Shannon, at J/ii/town, near Tulla, Co. Clare, a mine was worked in ancient times. Here there is native silver; the oaken shovels and large iron picks found suggesting that the workings were not as old as some of the others. At Carhoon, near 'Tynagh, Co. Galway, there are the relics of an ancient mine of which the traditions are extinct. In south-east Ireland, at the Magpie or East Cronebane (Ovoca), Co. Wicklow, there are “old men’s workings,” on the “ gossan lode,” and in them were found stone and wooden implements. Here native silver was also found. From so many of these ancient mines being on silver-lead lodes, it may be suggested that the “old men” understood a process for separating the silver from the lead. Nennius, who wrote in the ninth century, mentions the mines of Lough Leane, Millarney ; while about the year 1804, when Col. Hall was working the lead mine at Ross Island, he found primitive levels, stone implements, and other records of ancient work. At Derrycarhoon, near Ballydehob, Co. Cork, in an old work- ing, there were wooden and stone implements, a curved tube of oak, and a primitive ladder—the latter being an oak pole, with rude steps cut in its sides. This working must have been very ancient, as when found all traces of the surface entrance were smothered up by a growth of peat, over fourteen feet deep; this ought to represent a period of, at the least, 3000 years or more. About the year 1850 wooden tools, shod with iron, were found in ancient galleries, in connexion with the coal seam of the Bally- castle coal-field, Co. Antrim; while wooden scoops were found in an old working for bog-iron in the Queen’s County, some of them being now in the Royal [nish Academy Museum. During the rush after Irish mines, about twenty-five or thirty years ago, their characters were considerably prejudiced, and the working of them retarded, by a class of ‘‘ Promoters,” who mis- represented them; also by incautious Analysts, who represented the ores more favourably than they were entitled to. Such proceed- ings are most damaging to a mine; for although it may be good of its kind, and be capable of paying well, if judiciously worked, when it cannot give the “riches” promised, it gets into disrepute; Kinanan—On Irish Metal Mining. 203 or, if it is injudiciously over-worked, to try and keep up its fic- titious character, it will be robbed and its future prospects ruined. In the history of the mining during those years, it is now well known, that more than one Promoter exhibited specimens as repre- senting the ordinary minerals of a lode, while in reality his sample exhausted all the mineral of that class to be found in the veins. Also, some Analysts, after examining a specimen, allowed their analyses to be published as if they were the representative analyses, although they were ignorant whether the portion submit- ted to them was a true specimen, representing the average ore of the lode, ora picked one that only represented its riches. An honest, true representation of the value of the minerals of a lode is most important, and the neglect of such, or the intentional misrepre- sentation of the value of the lode, has led to most disastrous results, not only in Ireland, but all over the world. Careless analysts and intentional misrepresentations cannot, therefore, be too highly censured. In drawing out the lists of Irish mines and minerals the pro- ducts have been arranged in the following order :—Gold, tin, native silver, lead and zinc, copper, sulphur ores and gossen, barytes, iron, manganese, antimony, arsenic, cobalt, graphite, nickel, titanium, molybdenite, alum and copperas, apatite, salt and gypsum, steatite and pyrophylhte: the products being ar- ranged as much as possible in regard to the natural grouping of the ores in the veins. Some of the minerals in the above list Hage been very spar- ingly looked after, and their occurrence may be much more fre- quent than is inaraetieen mentioned, as the lists are compiled from the localities observed and recorded by the different explorers. This may be specially the case in reference to some minerals that, although observed, have not been recorded. Boate, in his notice of the silver mines, Co. Tipperary, records quicksilver as found prior to 1640. In modern times no trace of this ore is recorded. Some of the Irish rocks are said to be Pre-Cambrian, but the only pretension for classing them as Laurentians is their litho- logical characters. Some ot these so-called Pre-Cambrian, both Petrologically and Palsontologically, are evidently, in one case Ordovician and in another Cambrian; while elsewhere they appa- rently belong to one or other of these periods. 204 Scientific Proceedings, Royal Dublin Society. In the Lists the Names used for the Geological Groups are those given in the following Table :— TABLE OF GEOLOGICAL STRATA. Names. REMARKS. 5 g Pliocene. N Lam [ee] fo) e Hog Miocene. AA < a © | Eocene. 2 3 Cretaceous. A g 9 Zz o Of Jurassic. Oo nn is) te! wn a | Triassic. Permian. Passage beds. mn ; | 22 Carboniferous. Coal Measures and Limestones, &c. = = D 2 ° R 3 > Devonian. Passage beds (Yellow and Old A los sal ye Red Sandstone). < {| 5°4¢ Silurian. Upper Silurian. e| ea a Mayhill Sandstone or Llandovery.| Passage beds. ral an ie f b & | -8-=4 Ordovician. Cambro- or Lower Silurian. S| Eco : s Arenig beds. Passage beds. H o@ ss 4 E = | Cambrian, Primordial appears to be preferred Hn or on the Continent and in America. Primordial. The Passage beds, Arenig and Devonian, are complete in the Trish strata ; the others, Mayhill Sandstone and Permian, are only in part represented. (See “ Irish Lower Paleozoic Rocks,” Scien. Proc. R. D. S., vol. 111., p. 34, May, 1885.) Kinanan—On Irish Metal Mining. 205 Pazt I.—LIST OF THE IRISH MINES AND MINERALS. [The localities where there were mines or trials are printed in italics. The nearest town and the names of the Rock-formation are given in the column of Remarks. ] eo gS s =] u ) ° CounTiEs. | 65 26 Antrim, Carlow. Donegal. Dublin. Londonderry. Wicklow. GOLD. LocaLitizs. Slieve-an-Orra. St. Mullin’ s. Carrigacat or Dhurode. Kilerohane (Sheep Head). Knaderlough. Ballinascorney and Rathfarnham. Moyola River. Darragh-water or Augh- rim River. Ballymanus. REMARKS. Glendun— Diluvium.—Said to have been found about thirty years agoin Glen- dun burn. St. Mullin’s—Diluvium.—The exact place where the gold was found is unknown, but it is supposed to have been in the streams of Slievebaun (White Mountains). Crookhaven— Yellow Sandstone, or De- vonian.—In the gossan of the copper loads. Near Ballydehob, in this pro- montory, is the copper mine of Skeaghanore (whitethorn bush of the gold). No gold, however, has been recorded from this mine. Ballyshannon — Cambrian (?).— See County Histories. Dublin—Dilwium.—In the gravel of the River Dodder. Draperstown—Diluviwm.—This is a lo- cality mentioned by Gerrard Boate, A.D. 1652; but no gold has been found in recent years. The nature of the rocks and minerals in the county where this river rises would suggest the possibility of there being stream-gold in the valley. Woodenbridge—Diluvium.—In the gra- vel of this valley and the tributary valleys; namely, Goldmine valley and its tributaries, Kilacloran stream, Coolballintaggart stream, valley of the Ow and its tributaries, and the Kilmacreddan burn. Aughrim—WMetamorphic Ordovician.— Particles of gold in a quartz vein, discovered by Gerrard A. Kinahan. Scientific Proceedings, Royal Dublin Society. | REMARKS. 206 SEy Countizs. | 58 Locauitizs. Aan S) Wicklow. | 35 | Castlemacadam. 09 85 | Ballymurtagh. ” 35 | Tigroney. 99 85 | Cronebane. 99 35 | Connary. 99 835 | Kilmacoo. 99 40 | Ballycoog. 59 40 | Ballinasilloge. ” 39 | IMoneytiegne. ” 8 | Greystones. ry) 8 | Bray Head. ‘Wicklow and Kildare. Liffey and Slaney Valleys. | Ovoca—Diluvium.—In the gravel of the Ovoca river; south of the Rail- way Station. Ovoca—Ordovician.—-In the gossan and gossan lodes of the mines on the Ovoca mineral channel gold has been detected ; also in places in the regular ores of the lodes. The gossan lode of East Cronebane (Magpie Mine) seems to haye been richest. In places, the Kilmacooite, or ‘‘ Blue- stone,’’ of the Magpie and Kilmacoo are also auriferous. Greystones — Glacial drift.—In the washings of the sea-cliffs to the northward of the village; associated with black magnetic sand. Bray—Cambrian.—Particles in a small quartz vein, discovered by Francis Codd. Diluvium.—According to: the Annals, gold ‘‘placers’’ were worked in the val- ley of the Liffey, and probably also in the valleys of the head waters of the Slaney. The river systems of the Slaney and Liffey have changed from what they were originally ; asat one time the Liffey occupied the valley from Ballymore-Kustace to Baltin- glass, and joined there into the Slaney valley. This change cannot have been at a very distant period. The Slaney also at one time seems not to have gone through the Granyte range ; but at Tulla to have gone south-west- ward. This, however, was a much earlier change, as the river was* . banked into its present course by the “‘Ksker sea gravel.’? The ancient workings are supposed to have been somewhere near Ballymore-Eustace. Places that? gold might be looked for are: in Glenimale and the other head valleys of the Slaney; and in the ancient river course of the Liffey between lBallymore-Eustace and Baltimore. KinaHan—On Irish Metal Mining. 207 TIN. CounrTIEs. Loca.irttts. REMARKS. No. of Sheet vo q 3 is} Ko) iI ie) Dublin. 23 | Dalkey. Kingstown—Granyte.—With lead and zinc. The mine worked for the lead. The only place in Ireland where tin is at present known to have occurred as an ore in a lode. It is reported to have been found at Kil- crohane (Sheep Head), Co. Cork, but the find has not been authenticated. Kerry, Lough Leane (?) Killarney—Devonian ?— Although tin has not been found here in recent years, Nennius, writmg in the ninth century, Historia Britonum, mentions tin, lead, iron, and copper, as occurring in this vicinity. All of these except the tin have since been found and profitably worked. Smith, in his Natural History of Kerry, states he found an ore containing tin near the lake, but does not give par- ticulars. Wicklow. 40 | Goldmine River. Woodenbridge — Diluviwn. — With stream-gold and magnetic sand. In this locality there is possibly a lode containing the tin, but it has still to be discovered. [See ‘‘On the Pos- sibility of Gold being found in the Co. Wicklow,’’? Sci. Proc. Royal Dublin Society, February, 1883. ] NATIVE SILVER. [In the following lodes and localities, native silver has been found, but only in small quantities. Silver-lead (argentiferous galenite) occurs in numerous other places, and in a few places silver-copper (argentiferous chalcopyrite) | :— o wo CouNnrTIEs. 6a 3 Locanitizs. REMARKS. \ ZERO S) Clare. 35 | Milltown. Tulla— Carboniferous. — Ancient lead mine, in which were found stone and wood implements. : Norz.—A ‘‘silver mine’’ is recorded in James I.’s time ‘‘adjacent to the O’ Loughlin Castle,’’ in the barony of Burren. The ore, however, was | probably silver-lead. . 99 208 CounrTIES. | Cork. Dublin. Galway. Kilkenny. Leitrim. Limerick. Sligo. Tipperary. Scientific Proceedings, Royal Dublin Society. Ordnan’e Sheet. Ge fo} ° a 147 26 122 107 and 117 30 30 32 11 20 22 26 26 35 35 | 35 LocatitiEs. Boulysallagh. Ballycorus. Caherglassen. Carhoon (?) Lissooleen. Clogher. Bailygaltion. Twigspark. Ballysteen or Bally- canauna. A bbeystown. Garrane. Silvermines. Shallee. Cronebane. Connary. Kilmacoo. REMARKS. Crookhaven — Devonian. — Associated with lead and copper ores. Goldenball—Ganyte.— With lead ore. A large piece was accidentally put into the smelting-pot with the lead ore, and the silver ran into the brick- work of the furnace (ane). Gort—Carboniferous.—With lead ore. Pieces said to have been of a fair size. Tynagh— Carboniferous.—A very an- cient mine, possibly one of the sil- ver mines mentioned in the early Annals. Tralee — Carboniferous. — Threads and particles of silver in the lead ore. Castleisland— Carboniferous. — Threads of silver in the lead ore. Inistioge —Carboniferous.—A very an- cient mine, supposed to be the Arge- tros (Silverwood) of the Annals, when silver shields were made, A.M. 3817. Lurganboy — Carboniferous. — In mi- nute specks and strings in the lead ore. Askeaton— Carboniferous. — Thread of silver in the lead ore. Ballysodare — Carboniferous. — Strings and particles in lead ore. Toomavara. — Carboniferous. — Adjoin- ing the mearing of Kilnafinch there is a very ancient mine, supposed to be the Rosargid (Silverwood) of the Annals. Nenagh—Carboniferous.—Very ancient mine. In these mines and the newer mines to the westward at Shallee, native silver associated with lead, and in some lodes with copper. Ovoca— Ordovician. — Associated with the lead ore of the Gossan lodes, and with the Kilmacooite. See Lead ore List. Kinanan—On Trish Metal Mining. — . 209° LEAD AND ZINC. [Except in a few localities the ores of zinc are accompanied by those of lead. In many. places are found more or less grouped together the sulphides of lead (galenite), zinc (dlende or sphalerite), and iron (pyrite or sulphur ore), and more seldom the sulphides | of copper (chalcopyrite), arsenic (arsenopyrite or mispickel), and antimony (stzbnite), with the sulphate of baryta (barite). ‘Thelead ore is often argentiferous, and.in a few places the copper ore. In some places are found the carbonates of lead (cerussite), zine (calamine), and copper (malachite), also the silicate of zinc (Smithsonite). | Counrizs. one Locatiriss. REMARKS. 4 52 Armagh. | 25 | Carrickgallogly. aoa i 5 | 25 |) sdvonaneeanen: Belleek— Ordovician.—Lead. ke 28 | Dorsay. Crossmaglen— Ordovician.—Principally a 31 | Tullyard. lead. “a | 19 | Clay. Keady—Ordovician.—Principally lead. aA | 19 | Doohat, or Crossreagh. At Clay there is also manganese. At ys 19 | Drummeland, or » Carryhugh Glen there are two silver- Derrynoose. lead lodes, called the Red and Blue i 19 | Carryhugh. lodes ; the first being i in a ferriferous 9 19 | Darkley. stuff, and the other isa bluish flucan. . 19 | Tullyhawood. o 15 | Tamlaght. Middletown— Ordovician.—Lead. 9p 22 | Drumbanagher, or Newry—Ordovician.(?)—Lead. Church Glen. 56 25 | Ballintemple. Newtownhamilton— Ordovician.— Lead : se Finiskin. Cullyhanna—07dovician.—Lead. 56 22 | Kilmonaghan. Goragh Wood (Gerrard’s Pass)—Ordovi- cian.—Lead. 18(?)| Ballymore. Poyntzpass— Ordovician. (?)—An ancient | mine; its exact site being now un- determined.—(Grifith.) Cavan. 22 | Cornanurney. Cootehill—Ordovician.—Lead and‘ sil- “5 22 | Cloghstrukagh. ver-lead. 22 | Drumfaldra. f 51 29 | Shercock. ; South east of . . —Ordovician.—Lead.. ‘7 10 | Ortnacullagh (Bally- Belturbet— Carboniferous.—Silver-léad. connell). Clare 6 | Cappagh. Bally vaughan— Carboniferous.—At Be 6 | Moneen. Cappagh there are silver-lead, copper, . 6 | Ailwee. and manganese. At Sheshodonnell 99 6 | Mogoahy. only carbonate of zinc, which octurs 53 6 | Glencrawne. in botryoidal masses. At Lisnauroum 99 6 | Sheshodonnell. copper is associated with the lead: is 8 | Lough Aleenaun. while in the other localities lead only ah 9 | Lisnauroum. is recorded.—See note, Native silver, BA 8 | Doolin Castle. Co. Clare. ! SCIEN. PROC. R.D.S.—VOL. V. PT. IV. Q 210° CounrTIEs. Clare. Scientific Proceedings, Royal Dublin Society. 26 34 35 35 51 43 Loca.irTIzs. Glendree. Carrownakilly. Rathlaheen West. Newmarket. Ballyhicky. Castletown. | Moyreish. Monanoe, or Kilbreckan. Ballyvergin. Knockaphreaghaun. Milltown. Carrahin. Crumlin. Doolin. Ballykelly. Rathlaheen South. Knocksnaghta. Ballyhurly. Cahir. Ballynagleragh. Kilkinnikin. Killaconenagh. Gortacloona. Killoveenoge. Rooska. Lissaremigq. Ballycummisk. Kilkilleen. Leheratanvalley. REMARKS. Feakle—Ordovician.—Lead. Newmarket-on-Fergus— Carboniferous. —At the first the ore was silver-lead, while at the second it was associated with sulphur ore. Quin— Carboniferous.—Pockets of lead- ore occurred at these places; they are now worked out. They consisted principally of silver-lead. At Mona- noe, or Kilbreckan, the peculiar mine- ral called Kilbreckanite was found, in which lead and antimony were mixed in such proportions as those used for printers’ type. Tulla—Carboniferous.—Silver-lead prin- cipally. At Ballyvergin there was also copper and sulphur ore. At Milltown, avery ancient mine, native silver occurred; while at Carrahin tumblers only have been found. The deposits in general seem to be worked out; but near Ballyvergin and Mill- town are untried calcspar veins. Broadford — Ordovician.—Supposed to be worked out—silver-lead princi- pally. Sixmilebridge—Ordovician.—Lead and sulphur ore. Tumblers of lead were found at Gallows Hill, close to the western continuation of the great fault of Silvermines, Co. Tipperary. —See list, Co. Tipperary. Tomgraney — Ordovician. — Principally lead. Bearhaven—Carboniferous Slate—Lead. In the latter townland traces of lead and copper in different places. Bantry—Carloniferous Slate.—Silver- lead, silver-copper (grey copper ore), iron (chalybite), copper, and arsenic. Ballydehob— Yellow Sandstone, or Devo- nian.—Lead and copper. At Bally- cummisk, also barytes.—See Copper list. CounriEs. | . Cork. 99 75 & 106 107 103 108 107 Kinauan—On Irish Metal Mining. - Locatitigs. Coosheen. Boulysallagh. Kilmoe (Spanish Cove). Cooladerreen. Rabbit Island. Duneen. Ringabella. Minane. Carrigtohill. Bundoran. Abbey Island. Abbey Lands. Finner. Ballymagrorty. Carricknahorna. Tonregee. Welshtown. Carrowmore, or Glen- togher. Fanad. Drumreen. Ards. Keeldrum. Marfagh. Drumnacross. Fintown, Loughnam- breddan. Gwebarra River. Kilrean. Mutllantiboyle. Scraig Mountain. ait REMARKS. Skull— Yellow Sandstone, or Devonian.— Lead, copper, and iron. Crookhayen— Yellow Sandstone, or Devo- nian.—Lead and copper. Silver-lead and silver at Boulysallagh. Leap—Carboniferous Slate—Silver-lead. Castletownsend— Yellow Sandstone, or De- vonian.—Lead, antimony, and copper. Clonakilty— Carboniferous Slate.—Lead, barytes, and copper. Worked prin- cipally for barytes. Nohaval— Carboniferous Slate. aes lead and lead. Vicinity of .. nin hite Slate.— Lead and zinc. Vicinity of . . —Carboniferous.—Lead and copper traces. Ballyshannon—Carboniferous.—At the first three, silver-lead, zinc, and cop- per; at the others principally lead. At Carricknahorna also iron; worked in 1883. Ballybofey— Metamorphic Ordovician(?) —Lead and iron. Carndonagh—Cambrian, or Ordovician. —Silver-lead, zinc, and sulphur ore. Glinsk—Cambrian. (?) —Lead and cop- per traces. Carrigart— Cambrian. (?)—Lead. Dunfanaghy— Cambrian, or Ordovician. —Lead, copper, and sulphur ore. Ex- cept at Ards, the lodes were worked out by the Mining Co. of Ireland. Glenties—Ordovician.—Lead, zinc, and - sulphur ore; but principally lead. In Scraig Mountain traces of lead and copper. Q2 242° Scientific Proceedings, Royal Dublin Society. see Countizs. | 553 Locatitizs. REMARKS. Z§u Donegal. 64 | Iniskeel. Naran— Ordovician.(t Voeee and cop- per. i 89 | Malindbeg. Killybegs— Ordovician. (? J Sika tent and manganese. A 44 | Derryveagh (Gartan). Church Hill—Cambrian.(?)—Lead. iy 53 | Knockybrin. Letterkenny—Ordovician.—Lead at the Re 53 | Woodyuarter. mearing of Knockybrin and Wood- 5 45 | Lough Gannon. quarter. Further northward tum- blers of lead in Lough Gannon. Notr.—The ages of the Metamorphic Rocks in north and west Donegal are undetermined; they are probably Or- dovicians and Cambrians. Down, 53 | Glasdrumman. Annalong—Ordovician.—Lead and cop- per. ial hie 45 | Ardtole. Ardglass—Ordovician.—Lead. At Gun’s uauiy 89 | Gun’s Island. Island, also, copper and ‘barytes. 7 48 | Fofanny. Bryansford—Ordovician.—Lead. 63 55 | Leitrim. Kilkeel— Ordovician, and Granyte.— AC 52 | Mourne Mountains. Lead with, in places, copper. &e. s 44 | Ballydargan. Killough — Ordovician. — Lead, wih Hp 45 | Killough. barytes at Rathmullen. 59 45 | Rathmullan. op 45 | Rathdrum. is 43 | Moneylane. Dundrum — Ordovician.— Principally ap 43 | Wateresk. lead. “A 81 | Corporation. Killyleagh—Ordovician.—Lead. 56 31 | Tullyralty. Strangford—Ordovician.—Lead and cop- SC 81 | Castleward. per; also zinc at Castleward. $5 21 | Dromore. Vicinity of . . —Ordovician.—Lead and manganese. ie 6 | Whitespots (Conlig). Newtownards—Ordovician.—Lead. A | peculiar lode. A highly metallifer- ous whinstone dyke, so rich with lead that it could be profitably worked as an ore. 1 | Ballyleidy. Crawford’s burn--Ordovician.—l ead. S54 CouNTIES. E 23 Dublin. 18 _ 17 a 14 : 19 33 * 3? a be) a 18 & 17 a 18 Ns 18 35 26 aA 26 ci 26 a 16 s 23 rf 23 Fermanagh. Galway. 117 Sd 107 & 117 5 117 a 118 i 103 % 103 Kinanan—On Trish Metal Mining. 218 Lova.itizs. 14 &| Ashtown. Castleknock. Cloghran. Clontarf. Killester. Crumlin. Dolphin’s Barn. Kellystown. Kilmainham. Pheenix Park. Baliycorus. Rathmiehael. Shankhwll. Howth. Dalkey. Mount Mapas. Magheramenagh. Crannagh. Carhoon. Quarry Hill. Ballymaquiff. Muggaunagh. | Parkatleva. REMARKS. Dublin—Carboniferous Limestone (Calp division).—Lead was the principal ore, except at Dolphin’s barn, where there was also zinc. The lodes at the places printed in italics are sup- posed to be worked out. Golden Ball—Granyte.—Here are situ- | ated the lead-reducing works of the |} Mining Company of Ireland : the: lead lode is said to be worked out. Native | silver found here.—See Native silver. Golden Ball—Granyte.—Lead : said to > be worked ‘out. Vicinity of . . —Cambrian.—Lead: worked out. ; Kingstown — Granyte.—Worked out. | Zinc and tin associated with lead | ore. In no other place in Ireland, in modern times, has tin, as an -ore, been found in a vein.—/See Tin list. Killiney Hill— Ordovician, —Copper and lead: worked out. Belleek— Carboniferous.—Lead in =a quantities : worked about 1872. Tynagh — Carboniferous. — Principally | lead. For the works at Carheor: see |. Native silver hist. Ardrahan—Carboniferous.— The paying |: portions of the known veins are work- |: ed out. Lead oepciated with copper at Muggaunagh. 214 CounrTirs. Galway. th) 9 Scientific Proceedings, Royal Dublin Society. 108 LocatiriEs. Caherglassaun. Killeely. Rinvile West. Cappanaveragh (Lena- oy). Spiddal West. Kilroe West. Inverin and Minna. Tully. Rossaveel. Derroogh South. Booroughaun. Keeraunbeg. Carrowroe south. Clynagh (Crumpaun). Lettermuckoo (Carra- finla). Derrynea (Loughaun- weeny). Leenaun (Benwee). Griggins. Derrylea. Bamanoran. Lettershask Lough. Roundstone. Claremount. Tonweeroe. Ardvarne. Illaun-na-creeva, Moyvoon East. Lemonjield. Eighterard. Cregg. Portacarron. REMARKS. Gort—Carboniferous.—A rich lode, sil- ver, and silver-lead. A large mass of the latter was exhibited at the Dublin Exhibition, 1851. Unfortu- nately, on account of the cavernous nature of the limestone, the tide’s ebb and flow affect the water of the mine, and prevent the deep ore from being followed. Kilcolgan—Carboniferous.—Lead. Oranmore— Carboniferous.x— Lead and zine. Galway—Granyte.—Lead. Spiddal—G@ranyte.—Lead, copper, and sulphur ore. At Minna there is a fair show of copper. Costelloe, or Cashla Bay.—Granyte.— Principally lead; copper at Derry- nea and Rossaveel. In the Carrow- roe promontory, bearing about N.N.E. and 8.S.W., is a large reef of quartz that, in places, has a slight mineral staining. Leenaun—Si/urian.—Lead and silver- lead; also barytes at Griggins. Clifden—Metamorphic Cambrian and Ordovician.—At Derrylea there was a large excavation in search of gold, not a particle of which was found. Vicinity of .. —Granyte.—Lead. Oughterard — Carboniferous.—Lead : principally. CouNTIES. Galway. 39 99 o> 2? Kildare. 99° KinaHan—On Irish Metal Mining. LocatirtiEs. Barnagorteen. Curraghduff North, Middle and South. Derroura. Barratleva. Rusheeny. Canrawer. Cregg. Clooshgereen. Glengowla East. oP West. Corranetlistrum. Gortmore (Wormhole). Drumsnauy (Doon). Carrowgarriff. Curraghmore. Knockroe. Ardfert. Clogher. Annagh East. Meanus. Ballybrack. Ballinglanna. East of Cashen River. Lixnaw. Caher West, or Shana- garry. Killowen. Public Garden. Cahernane. Ross Island. Ballybeggan. Ballymullen. Lissooleen. Oakpark. Ardclogh. Wheatfield Upper. 215 REMARKS. Oughterard— Metamorphic Cambrian and Ordovician, with intrudes of Granyte, &c.—Where the rock is limestone or granyte the ore is principally lead; but elsewhere lead, copper, zinc, ba- rytes, and sulphur ore occur more or less together. At Glengowla East the gangue in part was crystalline green fluorspar. Moycullen—Carboniferous.—Principally lead. The Wormhole mine is along- side Lough Corrib, and it is difficult to keep the water down, as there ‘is leakage from the lake. Maum Bridge—Metamorphosed Ordovi- cian.—Lead, copper, manganese, and 1ron. ; Headford—Carboniferous.—Lead and sulphur ore. Monivea—Carboniferous.—Lead. Vicinity of . . —Carboniferous.—Lead. Castleisland — Carboniferous. — Silver, silver-lead, and copper. Castlemaine — Carboniferous. — Silver- lead; with zinc at Annagh, and a little copper at Meanus, Causeway— Carboniferous.—Lead; with a little copper on the coast to the . east of Cashen River. Kenmare — Carboniferous.—Lead. At Shanagarry, a sub-division of Caher West, silver-lead and copper are asso- ciated. Killarney— Carboni ferous.— Silver-lead at Cahernane. Lead, zinc, and cop- per at Ross Islend. Tralee — Ca ‘bonij erous.— At Oukpark only lead is recorded; at the others copper was associated with silver-lead. Native silver at Lissooleen. Celbridge—Carboniferous.—Lead; with some zine at Wheatfield. 916 Kildare. Kilkenny. | Leitrim, 29 CounrTIES. Scientific Proceedings, Royal Dublin Society. 3 82 43 27 12 36 36 | 25 | Loca.itizs. REMARKS. Freagh. Ballygation. Dunkitt. Knockadrina (Flood Hall). Monasterorts (Blundell Mines). Slieve Bloom. Barrackpark. Twigspark. - Ballyeanauna, or Bally- steen. Graiguelough. Askeaton. Kilcolman. Bailydoole. Ardgoul South. Freagh. Boolaglass. Ballingarrane. Cloghatrida. Ballinvirick. Mahoonagh. Tower Hill. Edenderry — Carboniferous. — Lead : worked out. Inistioge—Carboniferous.—Silver-lead. Kilmacow— Carboniferous.—Lead. | Knocktopher — Carboniferous. — Silver and silver-lead ; a very ancient mine. See Native silver lst. Edenderry — es — Lead: worked out. Kinnity—In the Ordovician rocks of Slieve Bloom, lead and copper have been recorded in several places, but whether together or separate is ‘not mentioned. Lrarganboy — Carboniferous. — Silver- lead in dolomitic sand. Askeaton—Carboniferous.—Lead ; with some zinc and pyrites at Graigue; at Ballysteen there was silver-lead and silver. The known deposits in these places, except Askeaton, worked out. Pallaskenry — Carboniferous. — Cover and silver-lead. Rathkeale—Carboniferous.—At Ardgoul —discovered when making the rail- way—there is a good show of silver- lead. Freagh and Boolaglass un- |. proved. The other places, where there was silver-lead, zinc, copper, and pyrites, are worked out. Newcastle — Carboniferous. — Lead : worked out. Pallasgreen— Carboni ferous.—Lead. Kinanan—On Trish Metal Wining. 217 CountIEs. es Locatirizs. REMARKS. a & n Limerick. 25 | Oola Hill. Oola—Carboniferous.—Silver-lead, car- bonate of lead, copper, and barytes. » 25 | Carrigbeg, or Coonagh | Doon—Carboniferous.—Lead. Castle. Londonderry.| 25 | Scriggan. Dungiven — Carboniferous.— Tumblers and fragments of lead (galenite). Longford. 14 | Longford. Two miles H.S.E. of ..—Carboniferous. —Silver-lead. Louth. 23 &| Oldbridge. ~ Drogheda—Ordovician.—Lead and cop- 24 per. se 7 | Crumlin, Dundalk—Ordovician.—Lead. At Fair- ae 7 | Fairhill. hill tumblers were found in the trials miade. -s 16 | Salterstown. Togher— Ordovician.—Lead and cop- per. Mayo 108} Ballynastockagh, or Pallyhauniss= Centon jeraus atta Bellaveel. 75 | Bolinglana. Newport — Carboniferous.—Silver- lead, - 65 | Srahmore. copper, and pyrites. 55 107 | Tawneycrower(Sheefry).| Westport—Ordovician.—Silver-lead. is 121 | Ballymacgibbon. Headford — Carboniferous.—Lead and 3 121 | Gortbrack. pyrites. Meath 33 | Cloghan. Ardcath—Ordovician.—Lead; very an- | cient mine.—(Griffith.) x9 29 &| Athboy. South of . . —Carboniferous.—Lead. He 35 i Ne 26 | Dollardstown. Slane (Beaupark mine)—Carboniferous. —Lead and copper. Monaghan. {19 &| Corbrack. Ballyboy — Ordovician. — Principally 24 lead. . ; ia 19 | Cornamucklagh North. < 19 5p South. ss 19 | Dernaciug. 14 | Derrylush. a 24 | Sra. i 8 | Derryleedigan—Jackson. | Bellanode— Carboniferous.—Lead ‘ and zinc. a 25 | Cornalough. Castléblayney —Ordovictan.—Lead, * or 5 25 | Cleggan. silver-lead; barytes at the first ‘two. i 25 | Carrickagarvan. , The deposits are supposed ue be | 25 | Dromore. worked out. 218 CounrTizs. Monaghan. 9 29 Queen’s Co. 29 99 Roscommon. Sligo. 99 > YD Tipperary, 39 99 9 99 Scientific Proceedings, Royal Dublin Society. S Bau a8 Locatirtizs. ZEO 6 15 | Annaglogh. 19 | Annayalla. 14 | Avalbane. 14 | Avelreagh. 14 | Carrickaderry. 14 | Carrickanure. 14 | Clareoghill. 14 | Coolartragh. 14 | Cornamucklagh North. 14 | Croaghan. 14 | Crossmore. 14 | Glassdrumman East. 14 | Grig. 14 | Kilcrow. 14 | Latnakelly. 14 | Lemgare. 15 | Lisdrumgormly. 14 | Lisglassan. 14 | Tassan. 14 | Tonnagh. 14 | Tullybuck. 18 | Dysart. 82 | Coolbaun. $2 | Ballickmoyler. 20 | Abbeystown. 20 | Lugawarry. 6 &9| Glencarbury. 9 | Tormore. — Seafield (Knocknarea), 22 | Garrane. 19 | Corbally. 13 | Garrykennedy. 19 | Laghtea. REMARKS. Monaghan—Ordovician.—Lead is the principal ore at these localities; it being associated with zine at Aval- reagh, Kilerow, and Coolartragh. barytes also occurring at the latter, At Lisglassan and Tullybuck it was accompanied by antimony ore. At most of the places printed in italics the paying portions of the veins were taken out. Maryborough—Carboniferous.—Lead. Ballickmoyler—Carboniferous.—Lead. Ballysadare—Carboniferous and Cam- brian.(?)—Lead. Native silver at the first: the old deposits in both places worked out. New veins since discovered. King’s Mountain, Sligo—Carboniferous. —Lead, copper, and barytes. The deposit at Glencarbury is principally barytes. Toomavara — Carboniferous. — Locally called the ‘‘ Silver mine ;’’ supposed to be the Rosargid of the ‘‘ Annals.”’ —See Native silver list. Portroe — Ordovician.—Lead. Garry- kennedy was a very ancient mine, stone and wood implements, &c., hav- ing been found in the ‘“‘Old Men’s Workings.” CounrIEs. 99 Tyrone. 99 Waterford. 99 Westmeath. Kinawan—On Trish Metal Mining. 219 REMARKS. 74 18(?) 18(?) 24 25 39 40 29 Ballygowan. Cloonanagh. Cooleen. Garryard ast and West. Gorteenadiha, or Gort- nadyne. Gortshaneroe, or Bally- noe. Knockanroe. Lacka. Shallee East and West. Aherlow Vale. Crockanboy. Teebane West. Ballydowane. Knockmahon. Monminane. Cruack. Mine Head. Monatray. Camphire. Borrisoleigh—Ordovician.—Lead. Silvermines, near Nenagh— Carboniferous (sandstone and limestone).—These are all sub-denominations of the great ‘(SILVERMINE Serr.’’ In these mines have been found silver, silver-lead, lead, silver-copper, copper, zinc, and pyrites. They were worked in pre- historic times, and the attals in the old stulls have lain so long that, by chemical change, new minerals have formed. The fault at Silvermines, on which the lodes are situated, can be traced eastward to Toomavara, and westward to Gallowshill, near Sixmilebridge, Co. Clare. Tipperary—Carboniferous.—Silver-lead, copper, and manganese. Gortin—Ordovician.(?)—Lead ; worked in 1854. Bunmahon — Ordovician.— These are portions of ‘‘BunmaHon CopreR Mrnzs.’”’ At both places there was silver-lead associated with copper; while at Knockmahon zine and co- balt were also found.—See Copper list. Carrick-on-Suir—Ordovician. (?)—Lead. Tramore—Ordovician.—An ancient lead mune. Ardmore— Yellow Sandstone, or Devoe nian.—Silver-lead. Coast opposite Youghal— Car boniferous(?) —Lead. Lismore— Carboniferous.— Silver-lead ; worked about the year 1825. Traces of lead found in different places. 990 Wexford. ? 99 +) Counties. Scientific Proceedings, Royal Dublin Society. Ge 3 ) a 45 45 Locatiti£s. Clonmines. Barrystown. Gibberpatrick. Killian. South Slob, intake. Bishopswater. Aughathlappa. Caim. Killoughrum. Mangan. Douce Mountain. Powerscourt. Glen of Lough Tay. | Lough Dan. Boleylug, or Moatamoy. Shillelagh. Carrigroe. Brockagh. Lugduff. 17 &| Camaderry. 23 REMARKS. Carrick-on- Bannow.— Ordovician. —At Clonmines there is the debris of very — ancient mines, supposed to have been worked by the Ostmen. Here in Charles I.’s time there was a mint. At Barrystown there were workings on a lode containing ster and zine. Duncormick — Carboniferous. — Lead ; veins of dolomite sand with strings of lead. Wexford — Carboniferous.— Lead and barytes veins cut in the canal at the South Slob. Strings of lead found when sinking the well at Bishops- water Distillery. Enniscorthy — Ordovician. — Lead, or silver-lead. At Caim there were also some zinc, copper, iron, and sulphur ore. The profitable portion of the veins are supposed to be worked out. Enniskerry—Granyte and Mica-schist. —Lead and copper. Holly wood—Metamorphic Ordovician. Lead. Togher, or Roundwood—Granyte—Lead, with at Lough Dan copper and zinc. At Carrigeenduff, Lough Dan, the vein worked out. Baltinglass—Granyte, or Micaeschist.— Lead. Vicinity of . . —Granyte.—Lead. Tinahely—Granyte.—Lead. An ancient mine. GuEenpaLoveH Lrap Mines.—Granyte and Mica-schist. — Luganure and Glendassan are sub-denominations of Brockagh. Lead, silver-lead, zinc, iron, a little copper, &c. Kinanan—On Irish Metal Mining. 221. seas CounrTIEs. ge 3 LocaLiti£s. Remarks. 6" Wicklow. 22 | Lugnaquillia (North Rathdrum, GLenmaLurE Minres— Prison). Granyte—Extending in places into the is 23 | Ballinafunshoge. mica-schist. All are in Glenmalure, 5 22 &| Ballinagoneen. the valley of the Avonbeg. In many 23 places with the lead there are zinc and 3 23 | Ballyboy. copper. At Barayore there is supe- 23 | Baravore. rior barytes, and at Clonkeen iron AG 22 | Camenabologue. and zinc. At the North Prison, Lug- . 23 | Clonkeen. naquillia, there is a promising-looking 4 22 | Clonvalla. lode, but the place is very inaccessi- % 23 | Corrasillagh. ble. i 23 | Cullentragh Park. . 35 | Ballinaclash. a 28 | Aghavannagh. Aughrim—Granyte.—Lead and copper. 35 40 | Ballintemple. Woodenbridge — Metamorphic Ordovi- 5 40 | Clonwilliam. cian.—Lead. At Clonwilliam only strings have been found. . 35 | Shroughmore. Ovoca— Metamorphie Ordovician. — a 35 | Kilmacoo. These belong to the EastOvoca Mines 35 | Connary. In all of them the lead is more or less As 35 | Cronebane. associated with copper and pyrites. Native silver (auriferous) has been found in east Cronebane (Magpie), Connary, and Kilmacoo; also the peculiar mineral called Kilmacooite, or ‘‘ Bluestone,’’ which is a mixture, of the sulphides of copper, lead, zine, iron, antimony, arsenic, and silver, with a trace of gold. ; Redcross — Metamorphic Ordovician.— x 35 | Kilmacrea. Zinc and lead. | eed ae ert 222° Scientific Proceedings, Royal Dublin Society. COPPER. [Copper is recorded as having been found native in the mines at East Cronebane and Connary in cracks or slight shrinkage fissures in the veins, while the mine water has deposited it on the metals in the old working. Native copper, sometimes in geodes, was found at Kilduane, Bonmahon, Co. Waterford, and sparingly in some of the lodes in 8.W. Cork. Yellow copper ore (chalcopyrite) is often found associated with lead in the limestones of Carboniferous age, but usually in too small quantities to be of any value. In the sandstones, whether high up or at the base (Lower Carboniferous sandstone), the copper usually predominates. In the Devonian rocks it princi- pally occurs as the yellow ore (chalcopyrite), and grey ore (tetrahedrite); and on the backs (gossan lodes) of some of the lodes, the carbonates (malachite and agurites), and oxide (melaconite). Generally it is only associated with sulphur ore or mundic (pyrite) ; but sometimes lead (galenite) and barytes (barite) are present; the latter in places being so mixed as to deteriorate or ruin the ore. ‘The ores are most prevalent in the Metallic Shales, or the upper zone of the Devonians. In the unaltered Silurians, Ordovicians, and Cambrians, also in the granyte, the yellow ore, similarly as in the Carboniferous, usually occurs associated with the lead ores; but only in small quantities; while in the metamorphic rocks it is in larger quantities ; sometimes being independent, but more often associated with pyrites, lead, zinc, or barytes. Some of the pyrite or sulphur ore at Ovoca was a poor ore of copper containing from 2 or 3 to 8 or 10 units; and the copper in the ash of such ores, after the sulphur is abstracted, is found to be remunerative. At Carrigacat and Kilcrohane, Co. Cork, and Ballymurtagh, Co. Wicklow, the copper ore (coppery pyrite) is in part auriferous, while most of the old coppery lodes in the great Ovoca channel probably contained some gold. At Garryard, Gortnadyne, and Gort- shaneroe, Co. Tipperary, and near Bantry, Co. Cork, the copper ores are argenti- ferous. | see CountTIEs. oes LocaLirrEs. REMARKS. a 5° Armagh. 31 | Tullydonnell. Crossmaglen— Ordovician. 5 22 | Kilmonaghan(Gerrard’s,| Newry—Ordovician. or Tuscan Pass). Carlow. 24 &| Carricklead Mountain. Graiguenamanagh—Granyte. (?) 26 Cavan. 20 | Farnham Demesne. Cavan—Carboniferous. Clare 6 | Cappagh. Bally vaughan — Carboniferous.— In . 6 | Glenulla. small quantities with lead. iG 9 | Lisnanroum. Ae 20 | Corrakyle. Feakle—Ordovician. 56 20 | Leaghort. as 34 | Ballyhickey. Quin—Carboniferous.—In small quan- tities with lead and zinc. 99 26 | Ballyvergin. Tulla—Carboniferous.—With lead and pyzites. 56 ae Shannaknock. Broadford—Ordovician.—With pyrites. CounrtIEs. Cork. 29 ’e No. of Ordnnn Sheet. 140 140 140 149 140 140 140 140 140 140 181 140 140 140 Kinanan—On Irish Metal Mining. 223 Locatities. REMARKS. Allihies. BEARHAVEN Mines— Devonian.—Yel- Cahermeeleboe. low copper ore; with a large pocket of Caminches. the carbonates in the north mine. Cloan. The veins both horizontally and in Coom. depth seem to have passed out of the Kealoge. ‘metallic shales,’’ (upper zone of the Devonians) and to have become un- profitable. Killaconenagh. Bearhaven—Devonian.—With lead. Esk Mountain. Glengarifi— Devonian. Carravilleen. Bantry— Yellow Sandstone, or Devonian. Clashadoo, or Four- —At Derreengreanagh associated with mile Water. barytes. At Lissaremig and Rooska Lissareniig. grey argentiferous ore, with silver- Rooska. lead, arsenic, and iron (chalybite). Derreengreanagh. Glanalin. Gortavallig. Hollyhill. Killeen, North. Kitcronane Mines (Sheep Head)— » South. Yellow Sandstone, or Devonian.—A Knockroe. large lode of sulphur-ore, with strings Kilcrohane. or thin veins of yellow copper. Along the bedding are beds containing grey coppes (argentiferous and auri- ferous (?)), and on the back of the lodes and beds, carbonates and oxides’ of copper. Worked by the South Bear- haven Co. At Kilcrohane there is a thick sulphur-ore (mundic) lode. Ballycummisk. Ballydehob— Yellow Sandstone, or De- Cappaghglass. vonian.—BALLYDEHOR AND AUDLEY Fowlnamuck. Mines. There are different lodes in Horse Island. each sett, some with grey ore, others Rossbrin. with yellow. Some of the yellow ore Ballydehob. lodes are good, others more or less Boleagh. deteriorated with barytes. Lead is Cooragurteen. sometimes also found in small quan- Kilcoe. tities, as at Ballycummisk, and in the Skeaghanore. gossan, at Horse Island. Skeagha- Derreennalomane. nore is a peculiar name, as if gold was once found there. Kitkilleen. Ballydehob— Yellow Sandstone, or De- Laheratanvally. vonian.—RoaRInG WatTER MINEs. Leighcloon. Copper and lead. Scientific Proceedings, Royal Dublin Society. 224 Cees CounriEs. ge 2 LocatLitigs. REMARKS. 26h Cork. 148] Castlepoint. Sxuui Mines— Yellow Sandstone, or De- 30 149| Castleisland. vonian.—Generally more than one i 139 | Coosheen. lode in each sett. Principal ores the & yellow and grey! but at Coosheen 144 there was a back of carbonates and 5 140| Gortnamona. iron. At Mount Gabriel_there is also 3 148 | Longisland. barytes. of 148 | Skull. i 148 | Leamcon. us 139 | Mount Gabriel. i 148 | Altar. CrooKHAVEN Mines —VYellow Sand- ae 147} Ballydivlin. stone, or Devonian.—Y ellow and grey 6 147| Ballyrisode. ores. In some setts more than one 5 147| Balteen. lode. At Carricat the gossan was ns 147| Carrieat, or Dhurode. auriferous, at Boulysallagh there a 147 | Boulysallagh, were silver and lead, and at Spanish A 147) Callaros. i Cove silver-lead. At Balteen a quartz 5 146 | Cloghane (Mizzen Head). lode was worked for gold, although ie 147 | Crookhaven. no gold had ever been detected in it. ‘S 147| Kilbarry. aA 152| IMudllavoge (Brow Head). a 147 | Kilmore (Spanish Cove). 50 147 | Lackavaun. 965 148 | Zoormore. 3 151| Bawnishall. Skibbereen— Yellow Sandstone, or De- vonian. Ress 142} Rabbit Island. Castletownsend— Yellow Sandstone, or Devonian.—Also lead and antimony. 5 142 | Aughatubrid. Roscarberry—(GuanpoRE Mines) Yel- a 143 | Derry. low Sandstone, or Devonian.—At 6 142) Drom. Aughatubrid there is a back of iron - 142| Keamore. and manganese that extends eastward BS 143 | Kilfinnan. to Roury Glen and Roscarberry (see ti 148 | Gortagrenane. list, Iron ores). At Little Island there a 143 Little Island. is barytes. 5 144| Duneen. Clonakilty— Yellow Sandstone, or Devo- nian.—Also lead and barytes: the mine worked principally for the latter. A 107 | Derreens. Dunmanway — Devonian, or Yellow 5 107 | Coom. Sandstone. i 107) Inchanadreen. We 78 | Knockadoon. Youghal— Devonian, or Yellow Sand- 9 78 | Capel Island. stone.—At the Fever Hospital there of 67 | Fever Hospital. is a strong coppery-looking spa. . 5p 63 &| Rathpeacan. Cork—Yellow Sandstone, or Devonian. -74.. —Yellow ore, with a little carbonate. 38 | Millstreet. Vicinity of . . —Devonian. (?) CounrTiEs. Donegal. Fermanagh. Galway. oe) No. of Ordnan’e Sheet. 106 91 79 90 90 90 Kinanan—On Irish Metal Mining. 225 Locatitizs. Bundoran. Abbeyisland. Abbeylands. Finner. Saltpans. Serably and Carrygally. Clonea. Casheleenan. Marfagh. Fanad. Iniskeel. Glassdrumman. Gun’s Island. Mourne Mountains. St. John’s Point. Tullyratty. Seapoint. Malahide. Lambay. Loughshinny. Rossbeg, or Castle Cald- well. Inverrin and Minna. Derrynea. Rossaveel. Maumeen Island). Teeranea. (Gorumna SCIEN. PROC., R.D.S., VOL. V. PT. IV. REMARKS. j | Vicinity of ..—Carbonifirous.—Alsoleaa. | Ballyshannon — Carboniferous. — With lead and zine: worked for the lead ore. Rathmullen — Ordovician. —Thin vein yellow ore; a quartz lode, to the northward, coppery. South of Letterkenny—Cambrian.(?)— A copper-stained quartz lode, with N.E. and 8.W. line of coppery spas. Carndonagh—Ordovician. (?) Kilmacrenan—Ordovician. (?) Dunfanaghy—Cambrian.(?)—Also lead, pyrites, and iron: worked for the lead principally. Glinsk—Ordovician.(?)—Also lead. Naran—Ordovician.(?)—Also lead. Annalong—Ordovician.—Also lead. Ardglass—Ordovician.—Also lead and barytes. Kilkeel—Granyte and Ordovician.—Also lead. Killough—Ordovician.—Also pyrites. Strangford—Ordovician.—Also lead. Blackrock—Granyte.—Traces. Vicinity of . . —Carboniferous. Skerries—Ordovician.—Also iron. Rush— Carboniferous. Belleek— Carboniferous. (?)—Also iron. Norr.—At Magheramenagh, between Castle Caldwell and Belleek, copper was raised by the late Mr. Johnston in the Carboniferous limestone. Spiddal—Granyte, or allied rocks. —Ores very mixed; lead and pyrites usually present : which, in general, are more abundant than the copper. 226 Scientific Proceedings, Royal Dublin Society. CountTIEs. 3hi Locatitizs. REMARKS. xu) S Galway. 54 | Bunnagippaun. Oughterard— Metamorphic Cambrians, 59 54 | Canrower. or Ordovician.— Lead, pyrites, or 99 54 | Cregegs. pyrrhotite, are generally present; 99 54 | Clooshgereen. sometimes zinc and barytes. If the 99 54 | Glengowla West. lode isin limestone, as at Glengowla, | ay 89 | Barratleva. the ore is principally lead. In the 9 89 | Derroura. Curraghduffs there were good bunches 99 39 | Curraghduf — West, of yellow copper ore. Middle, and South. a, 39 | Derreenagusfoor. 39 389 | Curraunbeg. 99 39 | Shannawagh. An 89 | Derroura. i 99 40 | Gorteenwalla. ” 40 | Ballygally. 9 39 | Drumsnauv. Maum Bridge—Metamorphic Cambrian. » 39 | Maumwee. —At Drumsnauy there were also lead, manganese, and iron; while at Maumwee the ore was princi- pally pyrrhotite. a 11 | Leenaun (Benwee). Leenaun Hotel—Stlwrian.—Principally lead. ” 49 | Ballyconneely. Roundstone—Metamorphic Ordovician, 5 50 | Tallaghlummanmore. Granyte, &c. 39 63 | Murvey. 39 63 | Dogs Bay. 4p 63 | Errisbeg, West and Kast. 39 9 | Cleggan Tower. Clifden — Metamorphic Ordovician, or ‘ 9 | Tullymore. Cambrian.—In the Rinvyle district, 55 21 | High Island. Dawrosmore (sheets 10 and 23), Cloon- 39 22 | Cloon (Cleggan Mine). looaun (9 and 10), Cashleen (9), &e., as 22 | Boolard. trials have been made in search for 45 22 | Doon. copper and iron, but not with good an 22 | Dooneen. result. This tract lies to the N.W. op 35 | Ardbear. of Kylemore Lake. 39 85 | Fakeeragh. 39 24 | Kylemore and Gleni- | Recess — Metamorphic Cambrian.(?)— nagh. Also sulphur ore. 96 386 | Barnanoran. Kerry. 30 | Clogher. Castleisland—Carboniferous.—With sil- 99 ver and lead: worked for the lead. 3 47 | Meanus. Castlemaine— Carboniferous.— With lead: worked for the latter. 36 9&c.| Coast east of Cashen Causeway—Carboniferous.— With lead. River. 3 52 | Dunquin. Vicinity of . . CounrtIES. Kerry. Kildare. bed Kilkenny. King’s Co. Limerick. 2) 106 78 & 106 11 11 KinaHan—On Irish Metal Mining. — 22k Loca.irtigs. Greenlane. Cromwell’s Fort. Mucksna. Ardtully (Clontoo). Caher West (Shanna- garry). Caher East. Gortnacurra. Kenmare, west of. Muckross. Ross Island. Garrough. Staigue. Ballybeggan. Ballymullen. Lissoleen. Finnies Upper. Oughquick. Clynacartan. Garranearagh. St. Crohan, or Behag- hane. Punchersgrange. Dunmurray. Knocktopher. Monasteroris. Slieve Bloom. Skreeny. Gortnaskeagh. Poliboy. Shanvans. Ballydoole. Charter School. REMARKS. Kenmare—Carboniferous and Devonian. —With silver-lead at Caher West. Killarney—Carboniferous.—Very ancient mines. Cobalt and sulphur ore at Muckross; lead: and zinc at Ross Island: the latter worked princi- pally for lead. Mines mentioned by. Nennius, a ninth century writer. Sneem— Yellow Sandstone, or Devonian. Tralee — Carboniferous. — Principally lead. At Lissoleen there is native silver. Cahersiveen— Devonian, or Silurian. Westcove—Devonian.(?) Newbridge—Ordovician. Kildare—Ordovician. Vicinity of . . —Carbonifercus. Killan, on Grand Canal.—Carboniferous. Kinnity— Carboniferous Sandstone, and Ordovician. Manorhamilton—WMetamorphie Cam- brian. (?) Lurganboy—Hetamor. ‘phie reeks ; Cam- brian.(?) Pallaskenry— Carboniferous.—T he mine at Ballydoole was woried for lead. R2 228 Scientific Proceedings, Royal Dublin Society. BAIT E CounTIEs. cae LocaLirizs. REMARKS. Abu Limerick. 20 | Ballingarrane. Rathkeale—Carboniferous.—Also silver- 99 20 | Cloghatrida. lead, zinc, and sulphur ore. The deposits, which were wrought for the lead, worked out. i 25 | Oola Hill. Oola—Carboniferous.—Also lead, zine, and sulphur ore: the lead in excess. Louth. 22 | Clogher. Drogheda—Ordovician.—Also lead at i 23 &| Oldbridge, West of. Oldbridge. 24 +5 16 | Salterstown. Togher—Ordovician.—Also lead: seems to have been principally worked for the latter. Mayo. 6 | Ballydergmore. Ballycastle—Carboniferous. ” 5 | Geevraun. ss 7 | Doonadoba. Seacoast N.E. of Ballycastle—Car- boniferous. 5 86 | Louisburgh. Vicinity of . . —Silurian.—Also sul- phur ore. Re 114) Bojin Island. Cleggan — Ordovician. — Also sulphur ore. Pr 75 | Bolinglana. Molrany, Corraun Mrnzs. — Ordovi- 5 65 | Srahmore. cian. (?) Meath. 26 | Dollardstown. Slane, BeavparK Minzes—Carbonife- 6 26 | Painstown. rous.—Also a little lead. as 32 | Brownstown. Walterstown—Car boniferous.—W orked “ 82 | Cusackstown. in 1800: veins said to be worked es 382 | Kentstown. out. Roscommon. | — _ —— Sligo. 6&9} Glencarbury. Sligo (King’s Mountain)—Carboniferous. 0) 9 | Tormore. —Also lead ; but principally barytes. Tipperary. 33 | Gortnahalla. Borrisoleigh (Clodiagh Valley)—Ordovi- cian.—An ancient mine. as 88 | Lackamore. Newport—Ordovician.—At Lackamore 60 88 | Zooreenbrien Uppere ancient tools were found in the ‘‘ old mens’ ’” workings. 7 19 | Derry Demesne. Portroe—Ordovician. KinaHan—On Irish Metal Mining. 229 cy) Ciel 5 Countizs. | 523 Locauitrss. An Tipperary. 17 | Rathnaveoge. > 82 | Coolruntha. np 26 | Garryard East. AG 26 % West. ‘ 26 | Gorteenadiha. of 26 | Gortshaneroe. es 26 | Knockanroe. 9 26 | Shallee East. ss 26 » West. 5 31 &| Ballyhourigan. 32 20 74 | Aherlow Vale. 5 45 | Clonmurragha. ee 45 | Gleenough Upper. A 45 | Lackenacreena. . 45 | Reafadda. ‘ 45 | Ballycohen, or Holly- ford. Tyrone. 37 | Sluggan. 35 44 | Ballintrain. a 45 | Crannogue and Knock- naclogh. x 45 | Glenbeg. sn 45 | Aghafad. 9 45 | Shanmaghry. % 45 | Lurganeden. Waterford. 25 | Knockane 55 25 | Woodstown. Ss 25 | Ballydowane. oD 25 | Ballynagigla. a 24 | Ballynarrid. 30 24 &| Ballynasissala. 25 ae 25 | Kilduane. 0 25 | Kilmurrin. a 25 | Knockmahon. es 25 Lankardstown. 55 24 | Templeyvrick. 99 24 | Seafield. 99 13 | Carrigroe. Ae 5 | Knockatrellane, or Bally- macarbery. ” 32 | Hillelton (Lady’s Cove). 29 24 | Kilminnin. REMARKS. Dunkerrin—Carboniferous. SILVERMINES, Nenagh—Carboniferous. —Principally in the sandstone. At the Garryards, Gorteenadiha, and Gortshaneroe there was silver-lead ; the copper being also argentiferous. At Knockanroe and Shallee there was also lead, &c.—MSee Lead list. Tipperary — Carboniferous.—Also lead and manganese. Cappawhite—Ordovician.— Pomeroy—Silurian, or Devonian (?)— Old working at the southern boun- dary of Crannogue; spas at the northern boundary. Coppery gossan at Shanmaghry and Lurganeden:. more or less coppery spas in the other townlands. This country is as yet unexplored. Norr.—These Tyrone rocks may in part be the representatives of the English Lower Devonian. Annestown— Ordovician. Bonmanon Mines— Ordovician. — Mi- ning in operation at an early age, as in some of the old working at the Stage lode, Knockmahon, rude stone and wooden implements were found. In this lode there were also silver-lead, zine, and cobalt; at Ballydowane silver-lead, and at Kilduane native copper.—WSee Cobalt list. Ballynamult — Silurian (?) or Devo- nian (?) Stradbally—Ordovician. 230 Scientific Proceedings, Royal Dublin Society. CountrEs. sas Locairizs. 250 Waterford. | 17 | Ballykinsella. Westmeath. | — — Wexford. 46 | St. Tenants. as 41 &| Forth Mountain. ‘| 42 a 42 | Kerlogue. -t | 19 | Caim. Wicklow. 8 | Bray Head. Seed 12 | Douce Mountain. &c. | Powerscourt. ” 7 &e. Be 12 | Lough Tay. 3 17 | Lough Dan. is 25 | Ashford. 3p 25 | Ballymacahara. ie 22 &| Glenmalure Mines. 23 3 28 | Aghavannagh. Me 34 | Aughrim, Lower. a 39 | Moneyteigue. os 38 | Tinnahely. 5 39 | Ballinagore. a 89 | Ballinvalley. 3p 389 | Ballycoog. . 39 | Ballinasilioge. | a 40 | Knocknamohill. i 135 &| Ballinapark. | | 40 | | ap | 85 | Killeagh. i 06 | 85 | Ballymoneen. REMARKS. Tramore—Ordovician. Traces of copper and lead in places. (Lewis.) Duncormick—Carboniferous Sandstone. Wexford—Cambrian.—Also sulphur ore. Wexford— Carboniferous. — Malachite. Enniscorthy—Ordovician.—Silver-lead, zinc, iron, and sulphur ore: worked for the lead. Bray—Cambrian. Enniskerry — Near the junction of Granyte and Mica schist (Ordovician). —Lead also. Togher, or Roundwood—Junction of Granyte and Mica schist.—With lead and zinc. Ballinalea—Ordovician. Rathdrum—Junction of Granyte and Mica schist—In the lead mines a little copper occurred at Ballinagoneen, Camenabologue, and Ballinacarrig, Lower.—See Lead List. Aughrim— Metamorphie Ordovician (°) Ancient mine at Moneyteigue. North of . . —Ordovician.—Iron ochre and malachite. Woodenbridge, Carysrort MutneEs Metamorphic Ordovician.—With iron and sulphur ore. SoutHweEst Ovoca, or KnockNnAmo- HILL, Mines—WMetamorphie Ordovi- cian.—Old mines worked for iron; the copper and sulphur ore worked a little. The prospects at Killeagh are bad; also those in }the north portion of | Ballymoneen. } Kinanan—On Irish Metal Mining. 231 ee CountrEs. 3s 3 Locatitiss. REMARKS. Zan Wicklow. 35 | Ballymurtagh. West Ovoca, or BALLYMURTAGH, MINES af 385 | Ballygahan, Upper. —Metamorphie Ordovician.—The old 9 35 is Lower. mines were worked for copper, sul- BA 35 | Tinnahinch. phur ore and iron. The prospects at 06 35 | Kilqueeny. Kilcashel and Knockanode not good. 99 35 | Kilcashe?. At Tinnahineh and Kilqueeny no 3 85 | Knockanode. trials have as yet been made. pe 85 | Tigroney. East Ovoca, or CronERANE, Minrs— ra 85 | Cronebane. Metamorphic Ordovician. — Worked a 35 | Castlehoward. principally for sulphur ore, copper, Bp 35 | Avondale (Meetings). iron, and ochre; at Hast Cronebane 3 85 | Shroughmore. (Magpie), Connary, and Kilmacoo also an 35 | Connary, Upper. forlead. At the latter mines there is 36 35 | ilmacoo. the peculiar mineral, Kilmacooite.— See Lead list. 50 35 | Kilmacrea. Redcross— Metamorphie Ordovician. 3 36 | Templelyon. Associated with sulphur and iron ores. $3 35 | Ballykean. Some good looking ‘‘tumblers’’ of copper picked up at Ballykean. ess 30 &| Ballycapple. Wicklow, BaLLtycappLe Minrs—Weta- 31 morphie Ordovician.—Worked about 5 31 | Ballard. 150 years ago for iron ore, which is a back to copper and sulphur ore. SULPHUR AND GOSSANS. [Sulphur occurs native, as concretions in thé Carboniferous Limestone, in the counties of Galway, Mayo, and Wexford; but the principal Irish ore from which it is obtained is the sulphide of iron (pyrite): but in the Co. Galway pyrrhotite, or magnetic pyrites, is found, and has also been minel. These ores usually contain some units of copper (chalcopyrite) : the more of the latter present, the greater the value of the ore; as after the sulphur is obtained copper can be abstracted trom the ash. Some of the pyrrhotites are nickeliferous. Some conspicuous gossans and strong chalybeate springs will be included in this list; in some cases they may only indicate the presence of iron, yet in many cases they come from pyrite veins. The localities where the quantity of pyrite is small and valueless are not given. | CounTIES. oes Locativizs. REMARKS. 23a Cavan. 4&6) Legnagrove. District of Glen, Native sulphur (?) 39 5 | Dowra. (Given in Lewis, but not of late years verified.) Clare. 26 | Ballyvergin. Tulla—Carboniferous.—Sulphur, lead, and copper. A 36 &| Shannaknock. Broadford—Ordovician.—Coppery sul- 44 phur. 232 CounriEs. Cork. Donegal. Scientific Proceedings, Royal Dublin Society. No, of Ordnan’e Sheet 107 & 108 67 146 20 15 36 62 28 45 34 34 28 & 35 LocaLirtiEs. REMARKS. Demesne. Fever Hospital. Kilcrohane. Carrowmore, or Glen- togher. Marfagh. Scraig’s Mountain. Carlan. Goldrum and Cash- eleenan. Ballyscanlan (Fern Fycorranagh. Spa Cottage. St. John’s Point. Lisnasliggaun. Tanvally. Finnisbridge. Dunmanway—Devonian (?)—Said to be mundic, or poor ore. Youghal—Devonian (?)—Strong spa. Crookhaven — Devonian. — Thick lode sulphur ore with copper. > Carndonagh—Ordovician, or Cambrian. Sulphur, silver-lead, and zinc. Dunfanaghy— Cambrian, or Ordovician. Sulphur, copper, lead, and iron. The lode was principally worked for the lead. Fintown—Ordovician, or Cambrian.— Sulphur, lead, and zinc. Carrowkeel—Ordovician.—Very strong, large, reddish spas. Kilmacrenan—Ordovician (?)—N. 10 W. lode, 3 feet wide; im part flucan, and in part quartz, with coppery sulphur ore; underlying eastward at 75°. Also a N. 20K. quartz lode, with coppery stains and strong coppery spa. Millford—Ordovician.—A nearly N. and 8. line of strong spas. Letterkenny — Cambrian (?) — Strong, reddish spas in the glen at the north- western boundary of the townland. Norr.—In the metamorphic rocks (Ordo- vician, or Cambrian) there are numerous spa springs; some are solely due to the leaching of the iron (carbonate ?) out of the rocks; but when in lines along a line of break, or dyke, they may possibly point to mineral lodes. Ballynahinch—Ordovician.—Iron spa. Killough — Ordovician.—Sulphur and copper. Banbridge—Ordovician.—Iron spas. Notr.—For sulphur ore in the Co. Galway Carboniferous limestone see Lead and Copper lists. Kinwanan—On Irish Metal Mining. 233 oS agpce CouNrTIES. a8 Locauitiks. REMARKS. a 6a Galway. 54 | EKighterard. Oughterard—Carboniferous Limestone. <3 54 | Carrowmanagh. —Concretions of native sulphur. 50 04 | Fough. 5 40 | Ballygally. Oughterard—Wetamorphie Cambrian, or 3 40 | Gowlaun. Ordovician. — At Derreennagusfore i 40 | Gortnashingaun. the ore is magnetic pyrites (pyrrho- 95 40 | Farravaun. tite). In some of the copper mines - 40 | Drumminnakill. in this district there are considerable es 40 | Newvillage. quantities of sulphur ore.—See Lead ‘5 64 | Derryeighter. and Copper lists, and Geological Survey a 53 | Leam East. Mem. Ex. Sheets 93, 94, 95, and 105. Ae 58 | Letterfore. The mine at Ballygally was one of 5 39 | Currane. the first opened; it was worked by oF 39 | Derreennagusfore. Nimmo. a 39 | Derry. 5 94 | Galway Dock. Galway—Ordovician. on 90 | Mawmeen. Gorumna Island — Granyte.—Coppery S 90 | Zeeranea. sulphur ore. Galway. 27 | Ashtord. Cong—Carboniferous. 45 40 | Doorus. 35 Ordovician. iS 39 | Doughta. Maum Bridge — Metamorphic Cam- i 39 | Maumwee. brians (?)—At Maumean, Lackavrea, eS 39 | Lackavrea. and Maumwee the ore is coppery ss 38 | Maumean. pyrrhotite, in part slightly nickle- Bs 38 | Teernakill, South. iferous. 5 25 | Cur. i 25 | Teernakill, North. “p 10 &| Dawrosmore. Clifden—Metamorphie Cambrian (°) 23 35 9 &| Cloonlooaun. 10 45 9 | Cashleen. - 21 | High Island. - 22 | Boolard. . 35 | Drimmeen. 5 24 | Kylemore. Recess—Metamorphie Cambrian,—The Ss 24 | Gleninagh. Ore is pyrrhotite. A little west of Recess are gossany ‘‘shode stones.”’ Limerick. — — Nore.—For sulphur ores see lists of the Co. Limerick Lead and Copper mines. Mayo. 86 | Louisburgh. Vicinity of . . —Silurian.—Coppery sulphur. 234 CounrIEs. Mayo. bed 99 Tipperary. Tyrone. Wexford. Wicklow. Scientific Proceedings, Royal Dublin Society. 121 121 25 LocatLitizs. Achill Island. Clare Island. Curraun Achill (Gubna- binnia Bay). Bojin Island. Ballycurrin. Gortbrack. Aghafad. Shanmaghry. Lurganeden. Glenbeg. Bree. BALLYCAPPEL Mrinzs. KOLMACREA 98 East Ovoca ne West Ovoca M5 Soutu-West Ovyoca MINEs. Carysrort Minzs. REMARKS. Molrenny (Clew Bay)— Metamorphic Ordovician (?)—Coppery sulphur. Cleggan — Metamorphic Ordovician.— Coppery. Headford — Carboniferous. — Sulphur and lead. Nors.—For sulphur ore in the Mayo Lead and Copper Mines, see Lead and Copper lists. At Lackamore mine, near Newport, and in different places in Silvermines, there is sulphur ore associated with the lead, &c. In the latter (Cloona- nagh) there is a great ‘‘ramp’’ of poor ore (mundic).—WSee lists Lead and Copper. Pomeroy—Stlurian.—Coppery gossans; none of the lodes proved.—Sce Copper list. In the country hereabouts, and to the westward in the large tract of Silurian rocks of the Lower Devonian type, are many good-looking indica- tions of minerals. Enniscorthy—Ordovician.—Mundie. Norre.—The iron ore at Ballybrennan (see Iron list) may possibly be the back of a sulphur ore lode. The principal minerals in these mining setts, all of which lie in the mineral channel of the Ovoca valley, are coppery sulphur ores. Some of the best of these, however (in old times), were worked solely for the copper in them.—See Copper list. KryaHan—On Irish Metal Mining. 235 BARYTES. [Only the localities where the ore is known to be in quantity are given. ] CounrTIES. Cork. Limerick. Monaghan. 99 bP) Sligo. Wexford. 29 Wicklow. Londonderry. 3 : Locattirizs. (e) 118 | Derreengreanagh. 118 | Derryginagh. & 119 140} Ballycummisk. 139 | Mount Gabriel. 143 | Little Island. 39 | Gun’s Island. 51 &| Dromore. 54 45 | Rathmullen. 54 | Clooshgereen. 54 | Canrawer. 54 | Crege. 25 | Griggins. 42 | Bunnaconeen. 25 | Oolahill. 40 | Cavanreagh. 25 | Carrickaganran. 25 | Cornalough. 14 | Coolartragh. 6&9} Glencarberry (King’s Mountain). 43 | Killane. 43 | South Intake. 23 | Baravore. REMARKS. Bantry— Yellow Sandstone, or Devonian. —With a little copper. Ballydehob— Yellow Sandstone, or Devo- nian.—The ore in one lode is so mixed with copper ore that both are value- less. Skull— Yellow Sandstone, or Devonian. —A little copper. Roscarberry— Yellow Sandstone, or De- vonian.—Some copper. Ardglass—Ordovician.— With lead and copper. Vicinity of . . — Ordovician.—With lead. Killough—Ordevician.—With lead. Oughterard—Metamorphic Ordovician, or Cambrian.—With copper and sul- phur ore. Griggins is in the Maum Valley. Headford— Carboniferous. Oola—Carboniferous.—With lead and copper. Draperstown—Carboniferous.—Veins in sandstone. Castleblaney — Ordovician. — With silver-lead. Monaghan—Ordovician.— With silver- lead and zinc. Sligo—Carboniferous.— With some cop- per and lead. Wexford—Carboniferous.—With lead. GLENMALURE Mrnes, Rathdrum — Granyte and Mica schist. — With lead and zinc: very pure. 236 Scientific Proceedings, Royal Dublin Society. IRON. [The Irish iron ores occur in bedded masses and in veins. In the recent accumulations, principally the alluvium and bog, iron occurs very frequently, often associated with manganese (Wad) as bog-iron-ore. In the Cainozoic rocks of Antrim and Derry are allied ores known in the trade as the ‘‘ Belfast Aluminous Ore,’’ which occur as bedded masses in the Eocene (?) Dolerytes. In the rocks of the Carboniferous period are clayey chalybites, as nodules and layers in the Calp and Coal Measures, while in the purer limestones of the same period, and the older Devonian, Ordovician, and Cambrian rocks, are regular veins and bunches of hematite, limonite, and chalybite. Some of the iron ores, however, in these older rocks, seem in part to be bedded or to partake of the nature of the veins known as Jay in day, that is, they underlie in the bedding of the associated rocks. Some, however, seem, and may be, more intimately connected with the associated strata, as a portion of a bed or beds may haye been ferriferous, thus forming a bedded ‘‘ bunch of ore.”’ The localities where ‘‘ bog-iron-ore’’ occur are so numerous, that it would be impossible to enumerate them, but when particularly conspicuous they will be referredto. During the smelting operation in the 16th and 17th centuries, when the Irish iron industry appears to have been at its height, these bog ores seem to have been extensively worked to mix with the other ores. At the present time a peaty variety is at times extensively exported to England and Scotland, principally from Donegal, to be used for the purification of gas and other purposes. In general, it is found as layers in the peat, and may be from blackish to a dirty white in colour, but more often it is of a pale yellowish green; these, when exposed to the air, rapidly oxidize, changing in colour to yellow or reddish yellow. The bog-iron-ore is employed by gas manufac- turers to purify the gas from sulphuretted hydrogen. In the process the ore becomes charged with sulphur, thereby becoming very valuable for the production of pure sulphuric acid. The residue (drown ochre), is also valuable, being sold for the manu- facture of paint. It appears remarkable, that the older deposits, especially in the alluvium, are of much greater magnitude than any that are now accumulating. This possibly may be due to the older masses being, in a great measure, the leaching from the surface rocks ; which leaching process, being now long since accomplished, the present depositions have to depend solely on the iron brovght up in springs from more or less deep- seated rocks]. Kunanan—On Irish Metal Mining. 230 BEDDED IRON ORES. [These are arranged in groups, beginning with the younger formation, which necessitates the counties not being arranged in alphabetical order. ] Eocene (?) bse CotnrIEs. ee Locauirizs. . REMARKS AbD Antrim. — | Knockbay. Antrim Iron Measures—Limonite.—In 5 — | Ballylig. lenticular bedded masses in the dole- ay — | Broughshane. ryte; apparently on different geologi- 3 — | Glenravel. cal horizons: the better and richer a — | Cargan. beds being higher than the others. 55 '— | Newtown Crcmmelin. Associated with lithomarge (ferriferous a — | Glenariff. clay), bole (a poor clayey iron ore}, f: — | Carnlough. alumyte (alum clay), and lignyte—(see i — | Glenarm. Alum and Copperas list). The best de- 9 —— | Killymurrish. veloped beds occur principally in the - — | Shanehill. eastern and northern portions of the nn — | Larne, west of. county. The iron ores proper con- 5 — | Island Magee. sist ot the First, or pisolitic ore, and a — | Ballypalady. the Second, or alwminos ore ; but in aS — | Port Moon. some cases in the underlying litho- #6 — | Rathlin Island. marge are lenticular masses of bole of * — | Kellygar. a quality equal to the ‘‘ Second ore.’’ a — | Swanstown. At Killymurrish, according to the a — | Tully. records of a bore-hole, the [ron Ore a — | Kinboe. Measure rested on White Limestone, cf — | Cullaleen. as at Craig-na-Shoke, Co. London- 35 — | Pharis. derry. Londonderry. | 85 | Craig-na-shoke. Limonite.—Two miles N.N.E. of ms 35 | Moydamlaght. Moneyeany there is a bed at the 3 35 | Bohilbreaga (Dunmur- base of the Eocene dolerytes, asso- ray). ciated with lignyte and the basal 5 Al | Sheve-Gallion-Carn. Chalk (White Limestone) conglome- rate. There is a tradition that Rennie, about 1600, worked a simi- lar ore on Slieve-Gallion-Carn, but none of the ore can now be seen. COAL MEASURES (Carboniferous). Countizs. | 323 Locatirizs. REMARKS. Zen Carlow. — | Lemystrr anp East | Layers of nodules and thin seam of Kilkenny. — MunstTER CoaL- clay-iron stone on different horizons. Queen’s Co. | — FIELDS. The most productive beds occur a Tipperary. Busy little below the lowest coal (Gale Hil, or Cullenagh, coal), and were extensively worked in the Queen’s County in the 16th and 17th centuries. These ores were used at the furnace near Mountrath (Coote’s) to mix with Bog and Carboniferous ores.—(S¢ee County History.) Scientific Proceedings, Royal Dublin Society. REMARKS. 288 te 3 a Counties. | 528 Locatirizs. a 6" Cork. — | West Munster Coat- Kerry. — FIELDS. Limerick. = Clare. — Mayo. — | Slievecarna. Sligo. — | Connavcut CoaL- Roscommon. FIELD. Leitrim. Fermanagh. Tyrone. 46 | Drumglass (Dungannon). BS 47 | Annagher. # 46 &| Coalisland. 47 89 | Annaghone (Tulla- hogue). Layers and nodules of clay-iron stone : principally associated with the lower coals—they were worked very ex- tensively in the 16th and 17th centu- ries in the counties Limerick and Clare adjoining the Shannon. Iron ore was smelted at Glin, Loghill, &c. ; but a portion of the ore seems to have been sent up the Shannon, to the furnaces on Lough Derg, to be mixed with Bog and Ordovician ores. —(See County History.) The hills northward of Balla.—Clay- iron stone associated with the lowest coal.—(See County History.) This field, although in general called after the province’of Connaught, lies nearly equally in the province of Ulster. ‘The iron-producing measures are in the Middle Coal Measures, and considerably below the geological horizon, in which the more profit- able beds are found in Leinster and Munster. The iron (clay-iron stone) was extensively smelted formerly, and apparently at a later date than in the southern province—the fires having been put out when the wood- fuel was exhausted. In the Co. Fer- managh, at the foot of the Cuilcagh mountains, there were extensive ex- cavations, furnaces, and mills; also in the Co. Leitrim—the last fire, at Drumshambo, having been put out in a.p. 1765. In the Co. Roscom- mon the three brothers O’ Reilly first attempted in Ireland to smelt iron with coal: they, in 1788, establish- ing the Arigna Iron Works, and opened coal pits—the adventure, by them and others, being carried on till 1808. Since then others have tried. Full particulars of the more recent works are given hereafter in the County History. Tyrone CoaL-FIELD.—These are more or less detached. In none of them has much clay-iron stone been re- corded. This possibly may be due to the measures—which in Connaught and elsewhere have produced most ore—being in this country more or less covered up by deep drift, and con- sequently not explored. Kinanan—On Irish Metal Mining. 239 CALP (Carboniferous). Remarks. See CountTIzs. sae Locatitizs. S Antrim. — | BattycastLe Coat- FIELD. Dublin. 5&8} Baldongan Hill. s 8 | Donabate. Londonderry.| 41 | Drumard. Bp 41-| Mormeal. 4 41 | Brackaghiislea. Mayo. 29 &| Crossmolina. 38 i 9 &| Tallagh. 10 Tyrone. 29 &| Kildress. 38 = — | Drvmaurn Catp AREA. Wexford. 49 | Woarway Bay. Clay-iron Stone-—Worked in ancient times with the coal; also in the beginning of the eighteenth century, the ore having been smelted at Bally- castle by Mr. Boyd.— (See County History.) Skerries—Poor Clay-iron stone. Draperstown — Clay-iron Stone. — Worked principally in Drumard, by Rennie, about 1600, and ‘‘ smelted at the Drumlamph Iron Works.”? At the Moyola River, in the south part of Drumconready, there are the ruins of an old furnace. Barony of Erris—Carboniferous (?)— The exact position where the iron was raised for the use of Sir George Shaen’s furnace near the Mullet, and Mr. Rutledge’s, on the River Deel, is now uncertain; but it would appear as if the ore was procured, in part at least, from the Calpy limestone (clay-iron stone). , Rutledge was the last to work, his fires being put out for want of fuel.—(See County History.) Cookstown—Limonite and Hematite.— Extensive trials made about 1880 by the Barrow Hematite Company; but the works were stopped on account of the low prices for iron. Omagh—Nodularbedsof Clay-iron stone. —Here, as near Draperstown and Cookstown, there are rocks belonging to the Ulster ‘‘ calp type,’’ in which the clay-iron stone is of a fair charac- ter. . Hook Promontory, Fethard—Poor Olay- won stone.—The ore is of a quality like that near Donabate, Co. Dublin. The associated rocks are also some- what similar, but they rest on Car- boniferous conglomerate (Upper Old Red Sandstone) ; in this locality they are probably a littoral accumulation. 240 Scientific Proceedings, Royal Dublin Society. IRON ORE IN VEINS. [The mode of occurrence of some of the ores in this list is not as true veins; yet at the same time they are not in true beds. Like the ores of the Eocene and Coal Measures, they are apparently of a secondary formation, a part of a bed or beds becoming ferriferous, the ore being found in an irregular ‘‘ bunch’’ or ‘‘ shoot ”’ that underlies with the stratification of the associated rocks. This is espe- cially the case with some of the ores in the Ordovician rocks which have been de- scribed as ‘‘ beds of ore.’? The localities of some of the ancient iron mines are now quite unknown, while the exact sites of others are uncertain. In the latter cases the places in the neighbourhood of which the mines were probably situated will be mentioned. The localities are arranged in counties. | CounTIES. Locatirizs. REMARKS. No. of Ordnan’e Sheet Cavan. 16 | Claragh. Redhill—Ordovician.—Ochre and limo- nite (?) The veins lie with the bedding of the rocks: ores worked in 1875. Clare. 19 &| Glendree. Feakle — Ordovician Limonite (?) — 27 Worked prior to 1700. The adit of the ancient mine is still to be seen; but the exact position or nature of the lode is unknown. ‘Tradition says that the ore was smelted at the pre- sent village of Furnace, a few miles eastward of Feakle. One mile N.E. of Feakle church are old burrows, where there is said to have been an ‘iron mine.’? The exact position of the lode is uncertain, without explorations. 43 &| Ballykelly. Broadford—Ordovician. 44 — | Knocksnaghta. Sixmilebridge — Ordovician.— Hematite and Limonite, with Graphite. 28, | Ballymalone. Tomgraney — Ordovician. — Limonite. &e.| Bealkelly. Worked rather extensively in the 16th(?) and 17th centuries, princi- pally for the furnaces along the shore of Lough Derg between Mt. Shannon and Woodford, where it was mixed with bog-iron-ore raised in that country, and ‘‘ore brought up the Shannon,”’ probably from the Coal Measures, counties Limerick, Kerry, and Clare. Cork. 128} Bear Island. ~ Bearhaven, or Castletown—Carbonife- rous Slate-—A well-marked vein of hematite, associated with micaceous iron ore. Kinanan—On Irish Metal Mining. 241 CouNTIES. Locatitizs. REMARKS. No. of Ordnan’e Sheet Cork. 142) Aghatubrid. Rosscarbery—Yelluw Sandstone, or De- Pe 143 | Roury Glen. vonian.— Limonite associated with i 143 | Rosscarbery. manganese, the latter being in shrinkage fissures in the iron ore. The iron ore seems to occur as the back of a copper lode. at 118 | Coomhola. Glengariff— Carboniferous {Slate (?) or (?) Yellow Sandstone (?)—A ‘mine 1s re- corded in this locality by Smith, in his history of Cork, 1750. Worked by the Whites, who had a furnace in the vicinity. Cork. — | Aghadown. Roaring-water Bay and Tallow Bridge.— 5 — | Araglin. These localities are also mentioned by Smith, the first being worked by the Whites, the second by the Earls of Cork. According to Smith, 1750, iron was smelted by the Whites at Coomhola and Aghadown, and by Lord Cork at Araglin, ‘‘near the eastern extremity of the county ;”’ while Gerrard Boate (1652) states the iron was smelted at Tallow Bridge. A few miles eastward of the latter, at Salter’s Bridge, in the Co. Waterford, are the remains of old iron works, said to have been worked in the 17th century.—See Drumslig, Co. Water- ford. The sites of the mines near Roaring-water Bay and Araglin are now unknown, but they were pro- bably in the Yellow Sandstone, or Devonian, rocks of the vicinities. 117| Rooska. Bantry—Carboniferous Slate.—Chaly- beate (carbonate of iron), with lead and copper: worked for the lead. Donegal. 68 | Welshtown. Ballybofey— Ordovician. —With lead: the mine worked for the latter. u 15 | Marfagh. Dunfanaghy—Ordovician (?) or Cam- brian (°?)—With lead, copper, and sulphur ore: the mine worked, princi- pally for the lead. 9) 36 | Skreen, Lower. Milford—Ordovician(?)—Limonite. In a mass of schist caught up in an intrude of whinstone. In the vici- nity is a quantity of slag, as if smelting had formerly taken place. SCIEN. PROC., R.D.S.—VOL. V. PT. IV. S 242 Scientific Proceedings, Royal Dublin Society. CounTIEs. Locatirizs. REMARKS. No. of Ordnan’e Sheet. Donegal. 53 | Meenreagh. Letterkenny — Cambrian (?) — Impure chalybeate ; appears to be more or less in bedded masses in the associated rocks. Notr.—As has been pointed out by different recorders, the remains of ancient bloomeries and forges, used in the smelting of iron prior to the woods of the country haying been used up, are found in different places scattered over the County. Down. 35 | Deehommed. Banbridge — Ordovician.— Hematite. | This vein has only been discovered about ten years. ‘The ore appears to be of a good quality; but on account of the depression in trade it has not been worked. AG 28 | Spa Cottage. Ballynahinch— Ordovician. 2 28 | Slieve Croob. Dromara— Ordovician. (?)—In this tract &e. of mountains, Griffith records iron in the townlands of Begny, Gransha, Leganany, Moneybane, &c. an 14 | Carnreagh. Hillsborough—Ordovician. Dublin. 9 | Lambay Island. Skerries—IJntrusive Rocks.—Blocks of hematite recorded by Du Noyer, as occurring a little 8.W. of Raven’s Well, near Bishop’s Bay. Supposed to be from the back of a copper lode. Fermanagh. 9 | Rossbeg (Castle Cald- Belleek — Carboniferous (2) —Limonite. well). Supposed to be the back of a copper lode. At Magherameragh a little copper was raised by the late Mr. Johnstone. Galway. 39 | Drumsnau (Doon). Maum Bridge— Metamorphic Ordovi- cian.—Hematite (?); with manganese, copper, and lead : worked for the lead. Galway.* 35 | Derreen. Clifden — Ordovicia.— Limonite in | limestone. * Inthe west of this county iron ore veins are not recorded ; but in olden times ore was smelted in places, such as Lough-na-Furnace, Screeb, and in other places on Galway Bay or its inlet. In these places, however, it may have been bog-iron ore that was used, mixed with imported ore—as the records inform us that iron ore was imported into places along the west coast to be smelted, on account of the abundance of timber; the old iron being made with wood charcoal. In the south-east of the county there were extensive furnaces and mills adjoining Lough Derg, the last in work, that of Woodford, haying its fires put out about the year 1750. The iron ores for these furnaces and mills were procured in the vicinity (bog-tron ore) near Tomgraney, Co. Clare (/imonite), and from the Lower Shannon, Kinanan—On Trish Metal Mining. 243 o | ; Sea { Countizs. | 552 Locatitigs. Remarks. a5 ean Cake Kerry.* — — — Kilkenny. 28 | Grenan. Thomastown—Ordovician.—Red hema- tite (micaceous). Leitrim. 35 | Gortinee. Drumsna—Ordovician.—Limonite raised here ; probably in the 16th or 17th century. When making the rail- way from Longford to Sligo three bed-like veins of slaty limonite, bear- ing nearly N.E. and S.W., heading S.E. at 60° were cut. Subsequently they were worked, two shafts being sunk for a depth of thirty feet about the year 1870, by which the ore was proved to improve in depth. On the depression in the iron trade the works ceased (See County History). Limerick. 11 | Askeaton. Askeaton—Carboniferous Limestone, — | Kilcolman. Silicious Limonite.—The ore at Kil- colman was worked about the 17th century, and subsequently about the years 1870-75. 99 Londonderry.| 31 | Carrick Mountain. Dungiven—Ordovician (?) BS 29 | Glenrandal. Stranagallwilly—Ordovician.—Mass of Ochre. : 40 &| Tullybrick (Altihaskey). | Draperstown— Ordovician (?) —Red 45 Hematite. One of Rennie’s mines (a.D. 1600) is said to have been in this townland, but the site is now un- known. 45 | Beaghbeg. Tonaragh—Ordovician (?)—Red Hema- tite (micaceous). counties Limerick and Clare (clay-iron stone). ely Dulton, in his Statistics, History Co. Galway, 1824, states:—‘‘Iron ore was formerly raised in the neighbourhood of Woodford, and after being mixed with that brought up the Shannon from Killaloe by a Mr. Crossdale, was smelted near that village, part of the estate of Sir John Burke. The works were carried on so extensively, that they devoured all the great oak woods with which that country abounded, and were then abandoned. Mr. Berry, I understand, at present raises ore on part of Lord Clanricarde’s estate.”’ * At the present time there are no records of mines solely worked for iron, but along the coast-line are the remains of different furnaces. According to tradition these belonged to Petty (ancestor of the Lords Lansdowne), who imported iron ore about the year 1600, to smelt it with charcoal, made in the wood which then abounded in the country. Nennius, writing in the ninth century (Historia Britonwm) mentions iron as being worked in the neighbourhood of Killarney Lakes; but the site of the old mine is now unknown. ‘The remains of very ancient bloomeries and furnaces have been found at Killarney and Blackstones (See County History). 82 244 CounTIES. Londonderry. Longford. bd Louth. Mayo. 29 Meath. Scientific Proceedings, Royal Dublin Society. 46 45 & 46 22 75 2&3 Queen’s Co. |13 & 18 27 Locatirizs. (Unagh) Slieve Gallion Carn, Tirgan and Carndaisy. Slievemoyle. Cranny (Glenview). Oleenragh. Enaghan. Clogher Head. Carricknahelty. Curraun Hill. Corratober. Dysart. Dunamase. Ballynakill. REMARKS. Moneymore—Granyte.—Hematite in a four-foot vein of ferriferous quartz : worked by Rennie in 1600, and re- cently, about 1875. Moneymore—Granyte.—Four-foot lode, being N.S.S.W., and hading 8.W. at 8°; rich fibrous hematite (kidney ore), and ved ochre: worked by Rennie, and recently. Moneymore—Wetamorphie Ordovician. —Hematite and barytes: worked a little in 1875. A narrow, nearly ver- tical vein, with a north-westerly course. Desertmartin—Metamorphie Ordovician. —Hematite and barytes. A narrow, neatly vertical, lode, with a north- westerly course: worked a little in 1875. Arvagh — Ordovician.—These bed-like veins of limonite are similar to those at Gortinee, Co. Leitrim; but the ore at Cleenragh is of a better quality, while that at Enaghan is not as good. Worked in the 16th or 17th century, and rather extensively, by Dr. Ritchie of Belfast, between 1860-70. Clogher— Ordovician.—Limonite. Molrany—Ordovician.—Limonite. About two miles to the south-east of Kingscourt are numerous tumblers and fragments of hematite. Source not known ; possibly near at hand. Maryborough— Carboniferous Limestone. —Limonite: worked extensively in the 16th and 17th centuries, the ore having been brought to be smelted to Coote’s furnace, at Mountrath. Riverstown—Carboniferous.— Hematite veins in the bedding lines. An ancient furnace clos: to the mineral veins. Kinanan—On Trish Metal Mining. 245 REMARKs. Ballysadare.—There are old iron mines recorded at Ballintogher. At the base of the Ox Mountains were very extensive workings; while furnaces and mills were situated at Screevena- muck; the fire having been put out in 1768 for the want of wood-fuel (See County History). Cappaghwhite— Ordovician. In the valley of the Clodiagh, Borriso- leigh — Ordovician. —Limonite. A very old mine; when and by whom worked is not known. The iron ore seems to be the back of a copper or sulphur ore lode. Tradition says there was a second mine to the N.E., near Roscrea, but the site seems to be now unknown. Cookstown— Carboniferous.—Hematite, limonite, and ochre, with manganese. Worked in 1600 by Rennie, and sub- sequently between 1865 and ’75. Pomeroy—Wetamorphie Cambrian (?)— This occurs in a mass, and appears to be an intrude of whinstone highly impregnated with magnetite. It has been worked as an iron ore, but not Pomeroy—Granyte.—An impure chaly- beate in an irregular vein. Carrick-on-Suir — Ordovician. —Hema- tite (micaceous-iron-ore). Dungarvan—Devonian, or Yellow Sand- stone. — Hematite discovered and worked by Walter Raleigh about, or a little before, 1600. Subsequently worked between 1850 and 1860. Ardmore—Devonian, or Yeliow Sand- CouNTIES. nae Locatiries. Azan Sligo. 21 | Ballintogher. Tipperary. 45 | Scotchman’s Coom. Ap 83 | Gortnahulla. Tyrone. 29 | Lissan. 56) 837 | Bardahessiagh. succes-fully. ” 37 | Limehill. Waterford. 7 | Killerquile. 9 85 | Dromslig. 08 35 | Grallagh. on 39 | Mine Head. 40 | Ardmore. stone.—Limonite. Probatily worked in the 17th century 246 CouNTIES. Scientific Proceedings, Royal Dublin Society. Wexford. Wicklow. tr) 99 38 29 & 40 LocaLirtigs. Ballybrennan. Ballynastragh. Courtown Harbour. Ballymoney. Cloghleagh. Knockatillian. Aughowle Upper. Tinnahely. Mucklagh. Moneyteigue. Ballycoog. Ballynasilloge. Mongaun. REMARKS. Enniscorthy—Ordovieian.—The work- ings here appear to have been ancient, as nearly all traces of them are obliterated. Gorey—Ordovician.— These accumula- tions are inj part of the nature of ‘beds. At and in the neighbourhood of Ballynastragh portions of a bed or beds of purple slate are highly ferri- ferous (limonite). Near Courtown the same ore occurs as strings or veins in the rocks, while northward of Ballymoney Fishery there are lenticular beds of poor chalybeate. Blessington (Glenasplinkeen) — Meta- morphic Ordovician.—Limonite, hema- tite, and manganese; worked a little. Shillelagh—Metamorphie Ordovician. Limonite. Some trial made on the vein about 1875. Iron ore is said tot’ have been raised in this locality in Bacon’s and Chamney’s time (16th{. and 17th century); but the sites of their works are now unrecorded. — North of . . —Metamorphie Ordovician. —A ramp of limonite partaking of the nature of bog-iron-ore; for the most part at the surface, or only under a thin drift: in places it is copper- stained. No traces [of old or recent works in connexion with it are appa- rent. Rathdrum—A rather extensive ferrife- rous conglomerate on Metamorphic Ordovician (?). Unsuccessfully open casts were made in part of it (1875), to try and find its source. Woodenbridge, Carysrort Mines— Metamorphic Ordovician.—Limonite : the backs of copper and sulphur- ore lodes. Very ancient working appears to have existed here; while in recent years some tons of ores have been raised at Moneyteigue. Arklow — Metamorphic Ordovician. — A large ferriferous mass, somewhat like that at Mucklagh. No trials have been made to seek for its source. Kinanan—On Irish Metal Mining. 247 CounrtIEsS, No. of Ordnan’e Sheet. Locatirigs. REMARKS. H> i=) 35 & oo > aoe 35 | Knocknamohill. Ballinapark. Ballymoneen. Ballymurtagh. Castle Howard. Cronebane. Connary. Kilmacoo. Templelyon. | Ballycapple. Ballard. Soutu-west Ovoca, or Knocknamo- HILL Mrines—Wetamorphic Ordovi- cian.—Limonite : the backs of copper or sulphur-ore Jodes; worked in the 17th century, the ore being sent to Chamney’s furnaces at Ballynaclash, Shillelagh, &e. West Ovoca Mines — Metamorphic Ordovician.—Limonite with copper- staining on the shrinkage fissures, and ochre. The back of the North sulphur lode was not worked till recent years, and iron is at present being raised : of late the ochre has been worked. East Ovoca Mines—WMetamorphic Ordo- vician.—Limonite and ochre. Worked in late years; ochre at present being raised and manufactured. The backs of copper and sulphur-ore lodes. Redcross — Metamorphie Ordovician Limonite. Wicklow—WMetamorphie Ordovician.— Limonite, magnetite, chalybeate, and ochre, with manganese: seems to be the back of a copper or sulphur-ore lode. Here there were extensive works in the 17th century, the ore being smelted by Chamney in the Vale of Clara, at Ballynaclash furnace, &c.; the old mines are still called the ‘‘ Clash pits.”’ MANGANESE. [This mineral is very universally distributed, but generally more or less minutely ; it is very often associated with bog-iron-ore, or other iron peroxides. In many cases it is valueless. In this list are only given the localities where it might possibly be worked profitably as a bye-product with the associated minerals. | CounrmTIEs. oe Locatitizs. REMARKS. Zé OG Armagh. 19 | Clay. Keady—Ordovician.—With lead; not in large quantity. Clare. 6 | Cappagh. Bally vaughan — Carboniferous..— Asso- ciated with lead. s 27 | Glendree. Fcakle—Drift.—(Diallogite). 248 CounrTIES. Cork. 99 99 Donegal. Galway. Monaghan. Tipperary. Wicklow. Scientific Proceedings, Royal Dublin Society. LocatLitigEs. REMARKS. Aghatubrid. Roury Glen. Rosscarbery. Malinbeg. Drumsnaw (Doon). Corduff. Aherlow Vale. Cloghleagh. Knockatillane. Ballycapple. Ballard. Rosscarbery — Yellow Sandstone, or Devonian. ‘These mines are on one channel. In considerable quantity associated with iron and copper. Killybegs—Metamorphie Ordovician (?) —With silver-lead. Maumbridge—Ordovician.—With cop- per, lead, and iron. Bellatrain— Ordovician. Tipperary—Ordovician.—With silver- lead and copper. Blessington (Glenasplinkeen) — Mica Schist.—With iron. Wicklow—Ordovician.—With iron and copper. ANTIMONY. [It, in general, occurs as the sulphide (s¢i/nite) associated with lead (galenite). | CouNTIES. BE 3 as n Clare. 34 Cork. 142 Louth. 1 Monaghan. 14 » 14 » 14 Tyrone. 12 & 19 Wicklow. 85 ” 35 Locaitres Monanoe, or Kilbreckan. Rabbit Island. Jonesborough. Lisglassan. Tullybrack. Clontibret. Munterlong Mountain. Cronebane (Magpie). Kilmacoo (Conunary). REMARKS. Quin— Carboniferous. —With silver- lead.—See Lead list. Castletownsend— Yellow Sandstone, or Devonian.—Associated with lead and copper. Vicinity of . . —Ordovician. Monaghan — Ordovician.— With lead. At Clontibret the vein of stibnite is four inches wide. Newtownstewart — Ordovician. — Re- corded by Griffith. Ovoca —WMetamorphice Ordovician.—In the Kilmacooite.—See Lead list. Kuwanan—On Irish Metal Mining. 249 ARSENIC. [This mineral is very often present in small quantities associated with sulphur-ore (pyrites), and sometimes with lead. At Cronebane and Connary, Co. Wicklow (sheet 35), it occurs as arsenopyrite, locally called ‘‘ Jack Martin,’’ with the sulphur- ore, and in the Kilmacooite (see Lead and Zinc); at Lackamore, Co. Tipperary (sheet 38), it occurs as arsennopyrite associated with copper ore; but in some places it occurs independently, as on the east shore of Adrigole Bay, Co. Cork (sheet 118), and at Gubnabinniaboy, near Molranny, Co. Mayo (sheets 65 and 75). In some of the mines of south-west Cork, as at Lissaremig, near Bantry (see Lead List), it occurs in considerable quantities. ] COBALT. [Cobalt in quantity has only been recorded as occurring at Muckross, Co. Kerry, where, unfortunately, most of the ore (erythrite, or arsenate of Cobalt) was thrown into the lake before its value was discovered.—(Kane.) | CouNTIES. Donegal. Dublin. Kerry Waterford. LocaLitizs. No. of Ordnan’e Sheet. 35 | Barnesbeg. 15 | Sutton. 44 | Muckross. 25 | Knockmahon. REMARKS. N. of Kilmacrennan.—Traces in pyr- rhotite crystal. (Scott.) Howth—Carboniferous.—With manga- nese. Discovered by Dr. Stokes. Killarney — Carboniferous.—Associated with copper and pyrites. The major portion of the cobalt ore was thrown into the lake before its nature was discovered by IZ. Raspe in 1794. Bunmahon — Ordovician. — Associated with copper, silver-lead, and zinc. Discovered by J. H. Holdsworth. 290 Scientific Proceedings, Royal Dublin Society. GRAPHITE (Plumbago). [Graphite has been very little utilized, although in some places it seems to be in sufficient quantity to have been worked as a bye-product with the associated minerals. | wai Countizs. | 522 Locauitrss. REMARKS. Z2g2 Clare. 43 | Knocksnaghta. Sixmilebridge —Ordovician.—In a vein with iron. Donegal. 26 | Sheephaven, near Ards Dunfanaghy and Conyoy.-—Found as House. rolled pieces in Gravel. = 69 | Burndale. Kilkenny. — | Castlecomer Coal-field. Carboniferous.—Fomerly associated with | the ‘‘ old Three-Foot Coal.”’ Mayo. 65 | Toorreyagh. Achill Island — Ordovician.—Graphitic | micalyte to the east of Doonaglass | Point. (ditchell.) Tipperary. 40 | Gleninchinaveigh. Upperchurch—Ordovician.—In a lode, associated, or mixed, with anthracite. The lode was worked to a depth of ten fathoms, when the walls closed | in and cut it out. Wexford. 7 | Ballymoney. Courtown —Ordovician.—Disseminated — in beds of black shale. aa i 20 | Greenfield. Enniscorthy— Ordovician. i. 25 | Craan. Wilton—Ordovician.—In a vein, asso- | ciated with anthracite. ss 31 | Doonoony. Taghmon — Ordovician. —In a vein, associated with anthracite. Wicklow. 80 | Rathdrum. N.E. of Rathdrum, Ovoca—Ordovician. a 35 | Avondale. —In these places it occurs dissemi- 3 35 | Cronebane. nated in black shaly clays locally called Coal-ground. Kinanan—On Irish Metal Mining. 251 NICKEL. [This mineral as yet has not been found in sufficient quantities to be profitable. It has, however, been detected in the pyrrhotites of the Maam and Gleninagh Valleys, Co. Galway. Hardman has found it in serpentine or allied rocks ; such as ophiolyte, Lissoughter ; tadeyte (?) Mullaghglass, Co. Galway ; ophyte, Croagh Patrick; steatyte, Bofin, Co. Mayo; and ophyte, or eklogyte, Slishwood, Co. Sligo. In America there is a magnesian rock which is worked profitably for the nickel it contains ; therefore attention may be directed to a rock found 8.W. of Leenaun, to the north of Glenisky Peak, Co. Galway, and to a similar one in Achill Island, Co. Mayo; as in appearance they are very like the American rock. As yet neither of these have been tested for nickel. Magnetic pyrites (pyrrhotite) crystals that occur at Barnesbeg, Co. Donegal, were found by Scott to have traces of nickel and cobalt. ] TITANIUM. [Titanium is rare in Ireland, or has not been recorded. Specimens of rwtilite, or rutile, the native oxide, have been found at Cushanacurragh, near Burrishoole, to the north- east of Clew Bay, Co. Mayo. In the Co. Donegal, Sir C. Giesecke records it as found in quartz peebles, River Dale, and in mica slate, Arranmore, while Mr. J. V. Stewart, records it at Malinbeg and Ards. Recently bunches of small crystals have been found in Rosscuile, in the same county. ] MOLYEBDENITE. [| Phis mineral appears to occur in rather considerable quantities disseminated in a wide endogenous granitic vein in the townland of Murvey, near Roundstone, Co. Galway (sheet 63). Elsewhere it does not appear to be recorded in quantity. Haughton found it in oligoclase veins at Garvany, near Castle Caldwell, Co. Fermanagh; while R. H. Scott found it in an elvan at Lough Laragh, near Glenties, and J. V. Stewart at Lough Anure, both in the Co. Donegal. ] ALUM AND COPPERAS. (Alum shales frequently occur in the Lower Coal Measures, especially in the Province of Munster, while pyritous shales, suitable for the manufacture of copperas, are also found, especially in the Upper Coal Measures. 'To the pyritous shales special attention was directed by Kane, in 1844, but since then no one seems to have endeavoured to utilize them. Near Castleisland, Co. Kerry, are pyritous shales, called Lapis Hibernicus Auctorum ; these at one time were used in the manufacture of copperas at Tralee. Some few years ago Mr. Walter Jameson, of Glenarm, discovered an alum-clay (alumyte) in connexion with the lithomarge and iron ores of the Co. Antrim, This is at present worked in different places, but more especially near Ballintoy. ‘The alumyte must not be confounded with the French Beauaxyte, or the German Woheiryte, both of which are ferriferous, and in aspect more or less similar to some of the varieties of the Antrim lithomarge and bole. The lithomarge and bole have not as yet been worked for alum; yet they seem to be allied to the alumyte, the latter appearing as if it was a secondary product ; having been at first lithomarge, out of which the iron was leached by the associated lignyte, as the alumyte is always accompanied by the latter.—See County History. ] 252 salt. ] Scientifie Proceedings, Royal Dublin Society. SALT AND GYPSUM. [In Ireland salt and gypsum are only found in the Triassic rocks of two counties, and are more or less associated. the borings, gypsum has been found; but in different places the latter occurs without In all the sinkings for salt, although not in the CounrTIESs. Antrim. Tyrone. Monaghan. No. of Ordnan’e Sheet 20 41 53 52 63 & 67 30 Locatitizs. REMARKS. Cushendall. Ballylig. Eden. Dunerue. Mullaghearton, or Mul- tikartan. Coagh. Derrynasrobe. Knocknacran. Raloaghan. Neweastle. Keernaghan. Near to . . —Gypswm.—Found in the “ Keuper Marl.” Three miles south-east of Larne.—A bore-hole was put down in 1839, while making trials for coal, to a depth of 174 feet; at 150 feet Salt Measure was met, but the trial was abandoned before it was proved if a good bed of salt existed. On Belfast Lough. PAGE 240 209 247 251 251 254 252 207 204 231 207 251 209 258 Scientific Proceedings, Royal Dublin Socicty. Part I].—Brier Country Histories. TuxEsE County Histories are placed in alphabetical order. In Part I., THe Lists or tHE Minzrat Locaririzrs—places where salt, gypsum, steatite, pyrophylite, and other useful products oceur— are given, as the workings to obtain them are included under the general name of “Mines,” although legitimately speaking they do not belong to “ Metal Mining.” On the same principle the localities for coa7 ought to have been mentioned, more especially as the coals are more or less connected with clay-iron-stone. Coal workings, however, are so important that universally they have been separated from Metal Mining, and have been given a distinct place of their own. Nevertheless, in these County Histories, it seems impossible to pass them over; they will, therefore, be briefly referred to, in the Counties in which they occur, in con- nexion with the iron-ores, the working of both being more or less connected. The Irish coals are of Hocene (7), Carboniferous, Or- dovician, and perhaps of Cambrian ages. Some of the statements made hereafter have not been’ verified, and in such cases the authorities will be mentioned. Much infor- mation can be learned from Lewis’s Yopographical Dictionary. The name of the writer of the geological descriptions is not given ; but, as tar as I have been able to test them, they appear trust- worthy. Unverified statements, however, will be given on Lewis’s authority. The English writers on Ireland, such as Spencer, Raleigh, Ledwich, Boate, and others, insinuate, or positively state, that the Trish, before the English came to the country, were perfectly incapable of finding or working minerals. ‘This, however, the researches of the Antiquarian have proved to be perfectly incorrect, as the early Irish were eminent workers in gold, silver, brass, and, I believe, iron. Their trade degenerated, and perhaps altogether 1 From the style adopted in these descriptions, I would suggest that Weaver was probably the writer. Jaxnanan—On Irish Metal Mining. 259 ceased, during the internal wars before and after the advent of Strongbow and his mercenary companions. The statements of these writers as to early mining cannot, therefore, be relied on, although they may be quoted in reference to works that were in existence when they wrote. In the early times gold and silver were recognized productions, especially gold, as pointed out in the Paper by the late Gerrard A. Kinahan, On the mode of Occurrence and Winning of Gold in Lre- land (Proc., R. D.8., vol. 111., pt. v.). The English, prior to 1640, discovered and worked three silver-lead-ore veins in Antrim, Sligo, and Tipperary. The site of the mine in Antrim is now unknown, but probably it was somewhere in the Ballycastle Metamorphic rocks district. The Sligo mine was in Coney Island, but it also appears to be now unknown, or to be given a different name; while that in Tipperary was the Silvermines near Nenagh. The last, although claimed as an English discovery, had previously been worked by the Irish. Boate (16) would have us believe that the English were the first to smelt and work iron. Chicester, however, in his report (1609), states he found, in Ulster, smiths at work, making steel out of the native iron, which they wrought much more easily than it could be made in England. The English and Scotch however, who came over after his report, developed an extensive trade; which seems to have been at its maximum at the time of the rising in 1641. The Iron-works were of different kinds: some Iron-masters had furnaces and mills; others, especially in Ulster, smelted the iron in bloomeries at the places where the timber was most plenty; while others had their furnaces near the coast of Ulster, Connaught, and Munster, importing most of the ore from England and Scotland. The principal Iron-masters at this time, whose names are recorded, were—Lord Cork, furnaces, mills, and mines in divers places in Munster ; Wandsworth (Wandesford), furnaces, mills, foundry, and mines, Carlow and Kilkenny ; Sir Charles Coot (Coote), mines and works, Queen’s County, Leitrim, and Roscommon ; Lord London- derry, mines and works, Queen’s County; Lord Hly and Piggot,' 1 Piggot’s works may haye been in the Queen’s County.—(See description, King’s County, page 285). T 2 260 Scientific Proceedings, Royal Dublin Socicty. mines and works, King’s County ; Sir John Dunbar and Sir Leonard Bleverhasset (Blennerhasset), mines and works, Fer- managh ; London Company, mines and works, Clare, Limerick (2) ; Sir William Petty, works, Kerry; Lord Stafford, mines and works, Wicklow and Carlow(?); Rennie, mines and works, Lon- donderry and Tyrone; and Sir Walter Raleigh, mines and works, Waterford. Boate states that the large furnaces and works, except those on the coast-line, were each built convenient to a mine; while the bloomeries were moved from place to place, where the fuel was most abundant. We may therefore suppose that formerly iren-mines existed close to most of the above-mentioned furnaces. The majority of these iron-works were destroyed in 1641, during the troubled times; but many of them were afterwards reinstated, while other works and mines were also started. Later in Wicklow an Englishman of the name of Bacon erected works at Shillalagh, and introduced the importation of pig-iron from Wales. These works were carried on by his son-in-law Cholmondeley, who changed his name to Chamney, and the latter, or his descendants, are said at one time to have had fifty-two works, between founderies, mills, furnaces, and bloomeries, in the counties Wicklow, Wexford, and Carlow; the Chamneys, besides importing ore, worked mines in different places. In Cork, at Coomhola and Roaring Water, were the mines of the Whites. In Clare and Galway, the Bradys of Raheen, the Burkes of Marble Hill, and others, opened new mines and established works; while in Mayo, the Gildeas of Port Royal were large Tron-masters. There were also elsewhere mines and works, that sprung up, to die out subsequently, as the forests were gradually exhausted. At the present time the Bog-iron-ore is exported from Donegal, Londonderry, and elsewhere, to be used in the puri- fication of gas. The raw product, in itself, is of little value; but after it has taken up the gas impurities the ‘Gas Wastes,” as it is called, is so valuable that the exporters find it profit- able to supply, free of cost, the Gas, on the condition that they are returned all the “Gas Wastes.” The latter are used for the manufacture of very pure sulphuric acid and brown paint. Kinanan—On Trish Metal. Mining. 261 Coal must have been worked at a very early time in Antrim,’ but the English were the first to discover and work it elsewhere. Between 1630 and 1640 coal was discovered by Christopher Wan- desford at Idrone in the Co. Carlow, while rising iron-ore; subse- quently (1728) it was looked for and found in Coolbawn Hill, Co. Kilkenny; but it was not till later, when the woods began to be exhausted, that elsewhere it was more generally looked for and found. The geological sketches at the beginning of each county description are necessarily very brief, and many important details have had to be quite ignored. ANTRIM. The rocks of this county belong to the Cainozoic, Mesozoic, and Palaeozoic Periods ; but the exact groups to which the first and last belong have not been determined. The oldest rocks are metamor- phosed, and may possibly be of Ordovician age, but probably are Cambrian. Next to them are rocks belonging to the Calp group of the Carboniferous, while the Mesozoic is represented by portions of the Trias, Jurassic, and Cretaceous. The Cainozoic consists nearly solely of sheets of Doloryte and their adjuncts, and in the latter are plant remains, that, some say, indicate a Miocene, others, an Eocene age. 'The mines worked have been principally for coal and iron, while at the present time alum-clay (alwmyte) is also a source of industry. In the Eocene (?) are beds, or portion of beds, of coal (ignyte). alumyte, litomarge (ferriferous clay), bole (aluminous limonite), and iron-ore (limonite and magnetic); with steatyte, near the Gobbins Island Magee. Various attempts have been made to work the lignyte profitably, but all seem to have failed. In the alumyte works (although in some of the mines there is a considerable thick- ness of lignyte) it is considered perfectly valueless, and is run out on to the attals (spocl, or waste heaps), or is used as filling stuff in the old workings (stwils). The probable origin of the alumyte (alum-clay) has been given in a Paper on the “Irish Crystalline Irish-ores,” Scien. Proc., 1 The coal mines in Antrim seem to have been the oldest in England, Scotland, or Treland.—(See Co. Antrim, page 264.) 262 Scientific Proceedings, Royal Dublin Society. Ji. D. 8., vol. 1v., 1884, p. 311, and need not be here re-given. At the present time only this clay is worked for the manufacture of alum, although the associated lithomarge and bole are very similar in aspect to the ferriferous varieties of the French and German clays (beauryte and woeheinyte). It would, therefore, appear expedient that the bole and lithomarge should be more minutely tested, especially the light-coloured varieties of the latter. The mining in the alum-clay (alumyte) is quite of recent date. Its value was first discovered by Mr. Walter Jemerson in 1873, who began to work it in 1874: since then the trade has largely developed. The following are analyses of the alumyte, beauxyte, and woeheinyte, procured through Mr. Jemerson :— Alumyte. | Alumyte. | Beauxyte. | Beauxyte. Baa. Glenarm. | Ballintoy. | Dahm’s. | Margeilleo. Alumina, . : 42°45 52°37 63°19 67°83 57-04 Peroxide of Iron, 1°54 129 3°72 00°47 1-08 Lime, . 4 ; 0°46 0-48 — — — Magnesia, . i Trace. Trace. - -- = Potash and Soda, 0:04 0:06 — — — Silica, . : 5 27°50 13°16 11:47 10°64 19-60 Titanic Acid, . 9°40 OO) fu = = Sulphuric Acid, . G08) 7 min Or 5m hne aed eh Phosphoric Acid, None. None. — — — Organic Matter, . Trace. Trace. | — = — Combined Watcr, 18-53 27°13 16°32 15°80 17°46 100-00 100-038 — — — The analysis of the alumyte was made by John Pattison, Noweastle-on-Tyne. In the French and German analyses the alumina is both hydrated and anhydrous. As sulphuric acid, in the process of alum making, only extracts the hydrated alumina ; Kinanan—On Irish Metal Mining. 263 in the continental minerals, by all known processes, there is a loss of from 6 to 8 per cent. that cannot be abstracted; on this account the Irish clays compare much more favourably with the continental than the Table suggests. Many of the beauxytes and woeheinytes contain much more iron than the above, iron having been made from a variety of the latter. Of beauxyte Dana gives three analyses; containing of iron respectively, 27-6, 3:0, and 34:9 per cent. The Irish clays contain much more silica than is found in the French or German. The Beauxyte, however, which gave 3°0 Iron is white in colour and gives 21-7 of silica. The Canizoic (Hocene ?) iron-ore trade is also of recent develop- ment. In 1609 Chichester mentions ore, while in 1683 Dobbs uggested that it existed in Island Magee; but it would appear that it was not generally known before 1861, when Dr. Ritchie specially directed public attention to those iron-ores. Afterwards they were successfully worked, until the slack in the iron trade, since which time, although not as successful as previously, there is a sufficient demand for the ore to keep some of the workings still going.! The occurrence of the pisolitic-ore is peculiar ; for, although it appears asif bedded, its genesis probably was long subsequent to the formation of the associated rocks. The pisolitic iron-ores fill horizontal shrinkage fissures, the accumulations having characters more or less analogous to those of standing lodes.—(See Scien. Proce Ds S., vole ive, 1884p. 312.) The steatyte at the path to the Gobbins Island Magee was formerly worked as “‘ French chalk.” In places the doleryte is decomposed into a rich ochre. Of ochre found at Mr. M‘Arthurs, near Ballymena, Apjohn writes : “The silex of the basaltic ochre is at present in a state of extreme division ; and from this circumstance, and the great depth and beauty of its colour, it appears well suited to the purpose of a red paint for gates, railings, and other descriptions of outdoor work. The Jurassic beds (Lias) are very sparingly represented ; but in them are apatitic nodules (phosphates). ‘These, however, have not been found in sufficient quantity to be utilized. 1Quite recently (1885) arrangements have been made to work an accumulation found in Rathlin Island. 264 Scientific Proceedings, Royal Dublin Society. In the Trias, near Cushendall ; in the Forth River Valley; in the Woodburn Valley, between Kilroot and Whitehead; and in the Valley of the Lagan, gypsum occurs in the marls; but although the veins in places are numerous, none that are known are thick enough to pay for working. The Salt mines at Duncrue are of recent date, the salt having been discovered in 1850 while boring in search of coal. As mentioned in Part I., page 252, the Salt Measures may extend east- ward towards Eden, and northward towards Larne, as saline wells are found in those directions. In remote and recent years there have been workings for coal and iron in the Batiycasrie CoaL-rieLp. The rocks are com- monly called Coal Measure; but correctly they are a portion of the Calp division of the Carboniferous limestone: they are, however, the equivalents of the so-called ‘ Lower Coal Measures ”’ of Scotland. The earliest works were during the time that “stone implements”? were in use, as about 1770, during the mining operation, then in progress, old galleries, having in them wicker-work baskets and stone implements, were broken into. In recent years the Macgildowneys were those who worked the coals, the royalties at the time belonging to the Boyds. At what time, or by whom, the ancient galleries were driven is now unknown; but it is evident the industry ceased and was forgotten. In 1700, Ballycastle! was quite a poor place, contain- ing some sixty-two house-holdings, and extending over an area of about three acres. But about the year 1784 it had advanced, and became a prosperous town, having its iron works of various kinds, its manufactures of salt and soap, its weaving and bleaching establishments, its tanyards, its glass-house, and brewery. The enumeration of these is in part foreign to the present inquiry; but as they were in a great measure adjuncts of the mining operation, it may be allowable to refer to them. The prosperity of the place was in a great measure due to the energy of Hugh Boyd, the proprietor, and it began to decline about 1670 or 1680, after his death, the decline being aided by ' This place got its present name from the castle built in 1609 by Randolph, Earl of Antrim. Correctly the coal and iron works should be called the Culfeightrin collieries ; but this name has been quite superseded by that of Ballycastle. Kinanan—On Irish Metal Mining. 265 the London Society (Londonderry) having successfully opposed a grant of money to improve the port. It may be mentioned that the glass industry seems to have been of a very ancient date, possibly prehistoric, as some au- thorities suggest that this was one of the places in which the ancient glass beads and such like were made. It was induced by the excellent sand of the vicinity, due to the weathering and washing of the sandstones of Carboniferous age. The glass trade, which was principally an export one to Scotland, gradually declined as the native coal increased in price, and seems to have finally ceased in 1850, or thereabouts, when the glass-house was destroyed by lightning. The higher coals, or those above the level of the sea, are worked out. There are, however, two coals, called the “sea-coals,”’ below the sea level, still unwrought ; which have been estimated to contain about 18,000,000 tons of coal; but as far as triais have been made they are unprofitable, on account of the drainage of the sea into the workings: very little, therefore (if any), of this coal can be profitably raised. Mr. Knowles of Ballymena has found prehistoric beads made of sotsite, or jade de saussare (saussaurite), in the Alolian sands in places along the coast-line in connexion with Kitchen midding and such like early traces of man; while Mr. M‘Henry has discovered small veins of similar jade in the metamorphic Cambrians(?). In, or associated with, the older rocks (Iletamorphosed Cambrians?) gold is said to have been found in Glendun, near Cushendun; and in 1825 the Glenarm and Antrim Mining Association proposed to work the gravels of the river. This Company are also reported to have found in Sheve-an-orra and neighbouring hills, traces of copper and lead; but the extent to which they carried their researches in quest of these minerals is uncertain, as there are not any published records of the places where these minerals were found. As already stated, in this county was situated one of the three lead mines discovered by the English prior to the rising of 1641; whereabout it was situated Boate does not state, but he gives a most glowing description of it, stating: ‘for as much as with every thirty pounds of lead it yielded a pound of pure silver.” At the present time it 1s quite unknown. 266 Scientific Proceedings, Royal Dublin Seaery. In the National Museum, Leinster House, Dublin, are some fine specimens of Onyx, said to have come from Rathlin Island. ARMAGH. The major portion of this area is occupied by Ordovicians in part metamorphosed with which to the 8. E. are associated Grranyte and allied rocks. These to the N. W. are succeeded by Carboni- Jerous limestone, while the latter, at the N. W. of the county, are overlaid by Triassic sandstone or marl, and to the N. E. by the Tertiary or Cainozoic rocks or the Lough Neagh beds. Some of the rocks near Armagh and to the N. HE. at Benburb have been said to be Permian: their position and fossils, however, seem to prove this conjecture to be erroneous. The recorded minerals occur nearly solely in the Ordovicians or the associated Giranyte and allied rocks. The principal mineral in the lodes was lead, but copper occurred in the veins at Jerret’s Pass, near Newry, and Tullydonnell, near Crossmaglen. Griffith records an ancient mine at Ballymore, near Pointzpass, but states its “exact position is not ascertained.” | Lewis reports antimony as having been “found in a few spots.” Westward of Slieve Gallion in the western slopes of the hill near Larkin’s mill, and not far from the edge of the Granyte, either Steatyte or Pyrophyllyte, probably the latter, has been found. CaRLow. _ The major portion of the area, included within the limits of Carlow, is occupied by Granyte, a part of the Leinster range. To the extreme S. W. of the county is a small tract of Coal Measure a portion of the KinkENny Coat-FIELD, which lies on the Carboni- Jerous limestone of the valley of the Barrow, the latter overlapping the Granyte. ‘These limestones are supposed to lie direct on the Granyte ; but a few small outlyers of Carboniferous Sandstone have been found, which may suggest that elsewhere rocks of this class intervene, but are unknown, being obliterated by the envelope of Drift. Kinanan—On Irish Metal Mining. 267 Farther northward, in the Co. Kildare, Metamorphic rocks (Ordovicians) intervene between the Granyte and the Carboniferous rocks, but they do not extend southward into the Co. Carlow; to the eastward of the range, however, at Clonegall and Newtown- barry a tongue of these rocks extends from the Co. Wexford into this county. This county does not appear in Griffith’s lists; but in the Coal Measure there are some seams and nodular beds of clay-iron stone that were mined between 1600 and 1641 by Christopher Wands- worth (Wandesford) ; who had also works, including a foundry for ordnance, at Idrone.—(See Leinster Coal-field,Co. Kilkenny). In latter years iron was raised near Shillalagh, Co. Wicklow, and probably also in this county. Except the clay-iron stone there are no authentic records of minerals or veins. Gold, indeed, is said to have been found not many years ago in one of the valleys N. H. of Graguenamanagh : this has not, however, been authenticated. Lead is also said to have been found in one of the same valleys, and some trials were | made unsuccessfully. It may be pointed out that these trials were injudicious, and not in the places where lodes would probably be found. CAVAN. About Lough Sheelin, at the south of the county, and extend- ing in from Westmeath, is the edge of the great central tract of Carboniferous Limestone, while in the vicinity of Stradone there is a small outler. The north-western portion of the area is solely occupied by Carboniferous rocks; in places there being Coal Measure; as in a small tract between Ballyconnell and Swan- linbar; and in the hill country, to the N. W., of which Cuilcagh, partly in Leitrim, is the highest summit. At Cavan there is a. limited tract of Carboniferous Sandstone, and 8. W. of it is an in- trude of Granyte, while the rest of the area is occupied by Ordovi- clans. The mountain tract to the N. W. is a portion of the ConnavGHT CoaL-FIELD ; including portions of the counties Cavan and Fer- managh (Province of Ulster), with parts of Sligo, Leitrim, and Roscommon (Province of Connaught). As all are part of the one field, they may here be described together. 268 Scientific Proceedings, Royal Dublin Society. Tn old times, but more especially in the sixteenth and seventeenth centuries,! there was extensive mining, smelting, and milling, of iron, which lasted till the woods were exhausted, the fuel being wood-charcoal. As the woods disappeared the fires were put out, the last extinguished being Drumshambo, Co. Leitrim, in 1765. Shortly afterwards, in 1788, the three brothers O’Reilly tried to revive the industry, and smelt the iron ore with the coal—the first attempt of the kind in Ireland. They erected a furnace and mills at Arigna, Co. Roscommon, and sent into the market some excellent pig and bar iron; the coal being procured at the Rover and Aughabehy collieries; respectively, about one and three miles distant. The adventure, however, did not prove successful on account of English competition; and after passing through the hands of other speculators the enterprise was abandoned in 1808. In 1818 Griffith made a favourable report of the iron ore of the district: this, coupled with his statement before a Committee of the House of Commons in 1824, induced the Ivish, the Hiber- nian, and the Arigna Companies to take setts for the working of coal and iron in the Co. Roscommon. ‘The first and second had their mining setts in the Cashel Mountain, or Slieve Curkagh, the range of hills north of the Arigna River; while the workings and works of the Arigna Company were to the southward of that river in the Bracklieve range ; but now more generally called the Arigna Mountain, after the name of the site of the furnace and mills. Practically the Hibernian Company did no work, the report of their surveyor being considered unfavourable. The Irish Company opened some pits, the largest being at Tullytawen, where the coal for a time gave a profit; but the most extensive works were those of the Arigna Company. The original works of the O’Reillys at Arigna appear eventu- ally to have become the property of the Latouches of Dublin, because from them, in 1824, the new Company obtained a lease of the works and mines. They commenced work with a large staff of 1 Before the rising in 1641, Sir Charles Coote, besides his Iron Works at Mount- rath, Queen’s County, had others in the counties of Leitrim and Roscommon. ‘The Leitrim Works may have been at Creevelea, and those of Roscommon were somewhere in the valley of the Arigna, all these works were burnt in 1641. Kinanan—On Irish Metal Mining. 269 English artizans and engineers, and from November, 1825, to May, 1826, the works were prosperous, some 280 tons of iron being manufactured at a cost of £8 4s. per ton. Then unfortunately, through some mismanagement, the furnace was choked ; which led to an expensive Chancery suit, lasting for ten years, when it was decided in favour of Mr. Flattery, who recommenced the smelting and manufacture of iron in 1836. Flattery worked for some years very spiritedly, opening, besides O’Reilly’s collieries, another at Gubberudda, where the coal was of a better quality. But eventu- ally he could not compete with the English and other iron-workers, and his fires had to be put out. Since Flattery’s time iron has not been smelted in the district, but the coal has been worked profit- ably for a local trade. In the Sheve-an-ierin district, to the east of Lough Allen, counties Leitrim and Cavan, the clay-iron stone is richer than in Co. Roscommon, and in former times, while the forest lasted, was extensively mined and worked, the name of the hill anglice “‘ moun- tain of iron,” suggesting pre-historic workings. Since the Drum- shambo furnace was put out, in 1765, no iron has been smelted, _ while very little work has been done in the coal, apparently on account of the great quantity of peat fuel. According to Boate, iron was worked, in 1650, “in a place called Doubally,” Co. Cavan, and “upon Lough Erne,” Co. Fermanagh. To the N. W. of the Co. Leitrim, in the barony of Drumahaire, the clay-iron-stone was formerly also extensively raised. Of this a considerable quantity was carried to Ballynakill, south-east of Colloonoy, and to a furnace near Ballysodare, both in the Co. Sligo, to be mixed with other ores and smelted. It was also smelted at the Creevalea Iron Works, townland of Gowlaun. In this town- land, and the adjoining one of Tullynamoyle, there are various beds, or nodular beds, of clay-iron-stone, the richest, as pointed out by Griffith and Jukes, being one about eleven inches high, which is as good, or perhaps better, than any of the seams in Slieve-an-ieran. According to the record, Sir C. Coote appears to have had works here in 1640, while the last furnace for smelting iron with wood- charcoal, was extinguished in 1768. The works, however, were resumed, in 1852, by a Mr. Currie, who, laid out large sums in blast furnaces, kilns, tramways, engines, and workmen’s houses; but became bankrupt in 1854. Afterwards the woiks were rented by 270 Scientific Proceedings, Royal Dublin Society. Mr. Potts of Dublin, who smelted a little iron with peat charcoal ; they, however, were abandoned in 1858-59. In this field the amount of clay-iron-stone is considerable: some of it, however, is inferior. Of coal there cannot be much; perhaps some 10,000,000 tons, of which only a portion could be economi- eally wrought, especially during the present low price of coal and high rate of wages. The coal in part is gaseous. Other minerals in Co. Cavan occur in veins in the Ordovicians, such as copper in Farnham, near Cavan, and lead near Cootehill, Shercock, and Ballyconnell. In the Ordovicians of Kill, near Kilnaleek (sheet 37), there is a bed of anthracyte. This, when discovered in 1854, was sank on, and according to Dr. Whitty’s report, was, in one place four feet thick. This, however, appears to have been a local swelling of the bed, as elsewhere in the strike and in depth it was only a few inches wide. About two miles southward of Shercock are beds of anthracitie shales: these in bad winter, when fuel was scarce, have been worked for fireing; they were, however, only a make-shift in the place of better, because at present they are of no commercial value. It is, however, possible that here, as in Canada, anthracitic and car- bonaceous shales may point to underlying oil or gas cisterns. This seems worthy of further research. CLARE. The rocks of this county belong to the Carboniferous and Ordo- vivian periods. Nearly half the western portion of the area is occupied by Coal Measures, the northern portions of the extensive West Mvunsrrer Coa-FreLp ; while to the east, in the neighbour- hood of Lough Derg, hills of Ordovician rocks protrude up through the Carboniferous. In Munster, especially Limerick and Clare, below the Ca/p and Fenestella limestone (lithologically divisions of the Carboniferous rocks) leady lodes often occur; below the Fenestella limestone the lead is usually accompanied, more or less, with copper and sulphur ores. On both horizons the minerals do not occur in re- gular lodes, but in pockets and “ shoots,’ which, when worked out, have no leaders to other deposits. Different, very rich pockets Kinanan—On Trish Metal Mining. 271 have been found on both horizons, which were remunerative to the first adventurers, but more or less disastrous to their suc- cessors who have attempted to follow what they supposed to be “leads.” Pockets of this class are indicated by calespar, associated with dolomitic sand. In the limestones of the Burren type numerous small veins of lead and zinc have been found, but none of them of promise; yet we learn from the records that, in the time of James the First, there was a “‘silver-mine”’ in the Burren, adjacent to O’Loughlin’s Castle, now called Castletown, while there are misty records of much more ancient mines. Fluor or fluorspar was found in different mines, associated with the lead, In the Coal Measures, near the Shannon, below the horizon of the lowest coal, some of the shale-beds are very rich in nodules of clay- iron stone. ‘The coals in this county are of very little account. Near the Shannon, to the south, there are some thin beds, that were worked in old times along the outerops, but as they are traced northward they thin, till eventually the horizons are only marked by fire-clays, with stems of stigmaria. The iron-ore beds also appear to become poorer as they are followed northward. In the old times the latter were worked to the southward, in the vicinity of the estuary of the Shannon. Some of this ore seems to have been smelted in the vicinity of the mines, but much of it was carried inland, or was sent up the Shannon by boats, to be mixed with Ordovician and other ores at the furnaces on Lough Derg or elsewhere. This clay-iron stone is mentioned as worked in 1650, while it was smelted and wrought by a London Company at furnaces and mills near tle mines. Iron ore in the Ordovician rocks was extensively raised in Glendree, westward of Feakle, also at Ballymahon and Bealkelly, near Tomgraney. Hast of Feable, at the hamlet now called Furnace, are the remains of considerable works, apparently prin- cipally for smelting purposes; while the iron raised at the mines near T'omgraney is said to have been sent by boat, to be smelted and milled at the different furnaces and works between Mount Shannon, Clonrush, and Woodford, west of Lough Derg, Co. Galway. According to the records, three classes of ore appear to have been in use for mixing at the furnaces, and these, from Gerrard Boate’s descriptions, were evidently the bog-iron-ore, the ore from the Ordovician rocks, and the clay-iron stone from the Die Scientific Proceedings, Royal Dublin Society. south of the county and the Co. Limerick. These furnaces and mills were at work until the woods were exhausted; the last fire put out (Woodford), about the year 1750, belonged to the Burkes of Marble Hill.’ . In the Ordovician rocks in different places are found, besides the iron ore (limonite), small veins and indications of lead, sulphur- ore, copper, anthracite, plumbago, &c.; but up to the present time none of them have been worked very successfully. Cork. The rocks of the premier county of Ireland are both interesting and peculiar. North of the valley from Dingle Bay, Co. Kerry, to Dungarvan, Co. Waterford, there is one type of Carboni- ferous rocks, while south of that line there is another. In the north-west part of the county, in the Ballyhoura and Galtee Mountains, there is Carboniferous Sandstone, within the latter a small exposure of Ordovicians. Over the sandstone lies the Carboniferous Limestone, and on the latter Coal Measure, a part of the Wesr Monster Coa-FIELD. But south of Dingle Bay and Dungarvan Valley the rocks have lithological characters, more or less peculiarly their own, which have lead to various classifications and nomenclature. The petrology, or the geological relative positions, of the different groups have been very successfully worked out by Griffith and Jukes ; but to suit the present ideas their names require revision, or rather modi- fication. In this area there is very little hmestone, it only being found to the eastward, while elsewhere it is replaced by shales, slates, and grits (Carboniferous Slate) ; these towards the west are of considerable thickness, being much thicker than the Carboniferous 1 In the Geology of Ireland (1878), chap. xxi., p. 852, and in other writings on the subject, I have suggested as probable that the last furnaces in which wood charcoal was used for smelting iron were those of Woodford in Galway and Port Royal in Mayo. Since then I find that the Port Royal works appear to have been in existence subse- quent to those of Woodford; while in Leitrim and Sligo there were fires alight in 1764 and 1768, or nearly twenty years later than at Woodford. The fires at Shillalagh, Co. Wicklow, were put out a few years before Chamney’s death, which took place in 1761. The Port Royal works seem, however, to have been more recent than those of Sligo and Leitrim, as, about the year 1860, the old mill was partly in existence, the forge anvil being still in sitw.—(See Mayo, p. 290.) Kinanan—On Irish Metal Mining. 273 Limestone of the Central plain. Under the Carboniferous Slate is the Yellow Sandstone (Griffith) or Upper Old Red Sandstone (Jukes): it graduating downwards into the Devonian or Lower Old Red Sandstone, and the latter into the Glengariff Grits (Jukes) or Silurian (Griffith). The equivalents of the groups, as nearly as possible, are as follows :— Cork Tyrer. CENTRAL IRELAND TYPE. Carboniferous limestone and CURGVERGUS BHENE, Lower limestone shales. 3. Yellow sandstone, . . . Lowercarboniferous sandstone. Devonian, or | Lower Old Red Sandstone, Lower Devonian (?) (England). 1. Glengariff Grits,. . . . Silurian. The Glengariff Grits are evidently the representations of the upper beds of the Silurians of the Dingle promontory, Co. Kerry. The Devonian (Lower Old Red Sandstone) are in part the equivalent of the Lower Devonians of England. In Co. Cork they form a regular unbroken passage from the Carboniferous rocks down into the Silurian; but in Slieve Mish, Co. Kerry they are only in part represented, the lower strata being absent, while the higher ones lie direct, but unconformable, on the Dingle Silurian.! Elsewhere in Ireland, except, perhaps, the Fintona Mountains, counties Fermanagh and Tyrone, the Devonian rocks are not represented. The Yellow Sandstone (Upper Old Red Sandstone)’ is an im- 1 In Slieve Mish, above the unconformability (‘‘Inch or Park conglomerate’’), and below the Lower Limestone Shales, there is a thickness of some 5000 feet of strata. These must represent part of the rocks (called by me Devonians) below the Carboniferous Slate, Co. Cork. This fact seems to be ignored in the proposed new — classification of the Cork rocks. 2 Jukes’ names for the Cork rocks, Upper and Lower Old Red Sandstone, has been the cause of considerable controversy in the Mining Community, they apparently not understanding that they are petrological or group names, and do not specially refer to lithological characters, and that the rocks of the groups may be either argillaceous (shales and slates) or arenaceous (sandstones). In Jukes’ groups, as a general rule, argillaceous rocks (Killas of the miner) are more prevalent in the Upper, and arenaceous rocks form the majority in the Lower. In the Yellow Sandstone, or Upper Old Red, of the Co. Cork most of the Copper veins occur, they not being of any value in the Lower Old Red. SCIEN. PROC., R.D.S.—VOL. V. PT. IV. U 274 Scientific Proceedings, Royal Dublin Society. portant group, as at its base are the Metallic schists and their associated copper lodes. The above divisions appear to be the true natural grouping of the South Cork rocks. Of late another, of a lithological character, has been attempted ; but both petrologically and paleeontologically, and even in part lithologically, it is evidently incorrect. In the extensive Wrest Munster CoAt-FIELD, only in this county, have productive coals been found; while here they seem solely to occur in a narrow strip along the Blackwater valley. Tn this strip the coals stand at a high angle, and appear to be cut off in depth by nearly horizontal faults. On this account, unless an elaborate system of bore-holes were put down, it is perfectly impossible to even guess, at the quantity of unwrought coal. The coal (anthracite) is of two distinct qualities—hard and soft—the soft flakey kind, or cu/m, being greatly in excess of the hard and more valuable variety. The latter is very sulphurous, but gives a strong heat. These coals have been working continually for a century and a-half. According to the writings of Gerrard Boate and Smith, clay-iron stone appears to have been raised here, to mix with bog-iron and the Devonian ores, for smelting at the furnaces presently mentioned. In the Carboniferous Limestone and Sandstones, only a few mineral lodes are recorded. In the Devonians, however, in the seventeenth century there appears to have been a large iron industry. During the time Sir Walter Raleigh lived at Youghal, he was an iron-master, having mines and works in the Devonians, Co. Waterford; but it seems uncertain if he did any work in this county. Lord Cork, however, had works in divers places. Smith, writing in 1750, mentions Lord Cork’s works at Araglin, near the eastern extremity of the county, and those of the Whites, at Coomhola near Glengariff, and Aghadown near Roaring-water bay. LBoate, a century earlier (1652), states that Lord Cork’s works were near Tullow Bridge, and the ores used were of three kinds—bog-iron ore, clay-iron stone, and limonite or hematite—the latter probably being raised in the Devonian rocks. During the present century there has been considerable copper- mining, induced principally by Colonel Hall’s discovery, in 1810, of a valuable lode at Allihies (Berehaven Mines). These lodes occur in Kinanan—On Irish Metal Mining. 279 the Metalliferous beds at the junction of the Yellow Sandstone and the Devonian rocks, and whenever they passed out of the Metallife- rous beds, either horizontally or in depth, they became valueless. Here the strata occurred advantageously, being in a half bowl, across which the lodes (counter Jodes) ran both E. and W. and N. and S. Some of the continuations of the lodes at the surface are massive, but, unfortunately for the Mines, once they pass the limits they lose their copper. These lodes at the first produced large returns; but after 1860 they began to fall away, and now appear to be nearly valueless.’ Elsewhere, in the south of the Co. Cork, there are a few counter lodes ; but?most of the copper and other lodes run more or less with the strike of the rocks, only cutting across the beds in depth. On this account they are not so productive; nor are they so continuous in depth; because, when going down, if they have to pass through one of the massive grits, they split up into strings, and nearly invariably die out. It has been suggested that if these massive grits were sunk through the lodes would again be found : this, however, seems improbable, because, in some of the cliff sec- tions, it can be seen that such split-up veins do not again mass into one. Some of the so-called lodes are regular beds of killas, highly impregnated with grey copper ore. In different places rich pockets have been found close to the surface, while in depth the lode lost its minerals. As pointed out by Jukes, the copper is very widely disseminated in the rocks, and “it will be obvious thata large quantity of poor ore, easily accessible, may be more productive than rich ore, or even the metal itself, which is disseminated in small quantities, or in situations requiring great trouble and expense for its extraction.” In this portion of Cork the lodes are very deceptive, and it “is a district where, perhaps more than others, requires great caution, as well as skill and prudence te mine with profit, and is a most delusive district to the speculator, from its containing so many of these specimens of rich ore, many of which have not indicated the existence of much more ore than was actually seen in the specimens.” In the Metallic shales of the Yellow Sandstone the prevailing * On account of the Igneous rocks in the vicinity (Cod’s Head, &c.) it is possible, if tried in depth, Zin might be found. U2 276 Scientific Proceedings, Royal Dublin Society. ores are yellow and grey copper; but when passing from these into ~ the Carboniferous Slate, and also in the latter, the ore is principally lead. There are, however, associated with the copper ores, the ores of various other minerals (see Lists) enumerated in Part I. A peculiar lode occurs at Glandore and at Rosscarbery. It is associated with a dyke of fault-rock, and has a back of iron ore— in the latter fissures formed, which are nowifilled with manganese: ore. It has been worked both for the manganese and iron, but has not been proved in depth. Probably it is a coppery lode. Within the last few years there has been a*movement in favour of the West Cork mines, especially those in’ the Sheeps Head pro- montory. Near Kilcrohane, and north-eastward thereof, there have been workings on the large coppery sulphur-ore lodes, and on some of the bedded grey copper lodes. In these lodes there is a considerable quantity of arsenic ore (arsopyrite), and in places the carbonate and oxides of copper occur, as profitable “ backs” to the lodes. There are in some localities large accumulations and veins of barytes, while the copper ores at Dhurode (Carrigagat) and Kil- crohane (Sheeps Head) are auriferous, while the grey copper ore of Lissaremig and Rooska is argentiferous. With the silver-copper there is also silver-lead, while in the old workings at Rooska they raised a considerable quantity of carbonate of iron (Chalybite), which still remains in the atta/s, or waste heaps. Anthracite is stated to have been Feu at Twomilebridge and Strancally, near Youghal. Very good amethysts have been found in places in the Devo- nians, and were formerly utilized. DONEGAL. The principal portion of this county is occupied by Granitic and Metamorphic rocks, they having in places on them small patches of Carboniferous Sandstones, Shales, and Limestones. The Metamorphic rocks, in 1884, were discovered by the late Gerrard A. Kinahan to belong to two geological periods, the younger are Ordovicians, and the older must be either Cambrians or Laurentians. Kinanan—On Irish Metal Mining. 277 It is not only absurd but also frivolous, to draw in them imaginary boundaries, and call a part Laurentian and a part Ordovician, as has been proposed. The larger portion of the Granyte is intrusive, but associated is some Metamorphic Granyte, and a considerable area of Granitic gneiss. Since the beginning of the present century various explorers have published lists of minerals; but, although examined by so many, only a few valuable mines have been discovered. Some good silver-lead was found in the Carboniferous Limestone near Ballyshannon, and in Metamorphic Limestone at Kalldrum, to the south-westward of Dunfanaghy ; elsewhere there are not any metal mines of note, although in places there are very fair- looking indications. At Carricknahorna, near Ballyshannon, there is a lead lode with a “back ” of iron and manganese in the Car- pboniferous Limestone: this was worked for the iron-ore in 1884; and 30 tons of ore was shipped for Ballyshannon, to Mostyn, on the River Dee, by Messrs. Fathem and Kidd. Cainstone, or pyrophyllyte, has been recorded in a great many places, and the harder varieties were formerly used for archi- tectural purposes, while the finer kinds have been mined and sent into the market as steatyte. 'Thin beds of anthracyte are recorded as having been found at Dromore and Kintale, on Lough Swilly ; while gold is said to have been detected in a small quartz lode in the stream that flows from Lough Knadas, one mile due east of Ballyshannon. | As long as the forests lasted iron was largely smelted, and the remains of the bloomeries and mills are found in different places. Some bog-iron, and perhaps other native ores, were used ; but the records state that large quantities of ore were imported into the country from Scotland and England. At the present time there is an export trade of bog-iron-ore, to be used in the process of cleaning gas. Very fair beryls occur in some of the exogenous Granyte veins §.E. of Dungloe, at Doocharry, and Slieve Snaght, barony of Boylagh; while Giesecke reports having found greenish-gray jade at Crohy, in the same barony. 278 Scientific Proceedings, Royal Dublin Society. Down. The area within the limits is nearly solely occupied by Ordovicians, which towards the south are in part metamorphosed, having associated with them Granitic rocks of different ages—Or- dovician, Triassic (?), and Eocene(?). At the’extreme south of the county, also in the neighbourhood of Castle Espie, N. W. of Strang- ford Lough, are very small tracts of Carboniferous Limestones. On the shore of Belfast Lough is a small exposure of dolomyte,, having fossils of Permian types; while in the valley of the Lagan, to the N.W. and W. of the county, the Trias is capped with Cretaceous and Kocene(?) rocks. In the Cainozoic rocks are thin, valueless beds of lignyte, and in the Trias gypsum, but in too thin veins to be valuable. | In the Ordovicians are numerous small veins and indications. of lead and copper, but only in a few places have they been found rich enough to work. sss Organic matter, . 22°10 °/,, containing nitrogen = 0°02 °/, 3 = GUO" o 2S Gesaihaell Mig gp COLI | op - 06 °/, ‘Organic and Volatile ( ‘ih 40°55 °/, Total nitrogen, . 4:08 °/, As is seen from the analysis, the amount of insoluble matter (sand) is still exceptionally high—nearly twenty-five per cent.: the 346 Scientific Proceedings, Royal Dublin Society. other constituents forming the fixed matter call for little or no comment with the exception of the phosphoric acid, which for a highly adulterated guano is much above the average; the mag- nesium oxide and nitrates, both of which were present only in very small quantity, were not directly estimated, the amount being determined by difference. A remarkable feature in this guano is the nitrogen, which, besides being naturally low, is en- tirely present in the form of ammoniacal salts: the minute amount of organic nitrogen, ‘02 -per cent., shown in the analysis, is no doubt due to partial conversion of the nitrogen of nitrates into: ammonia during the ignition with soda-lime in presence of the organic matter. In order to give a better idea of the extensive adulteration of the sample, I append below the calculated composition of a ton of the original guano. Composition oF A Ton oF OriGinaAL Guano. Or eanic matter, ali otal nitrogen, cwt. lbs. Sand, stones, &c. (adulteration), c 6 . ¢ & aO Q : 6 0 : 5 é : 1 96 P05, 2 30 SOs, 0 37 K.0, 0 89 MgO and nitrates 0 32 Water, 28 3 0 19 The deficiency here is due to the fact that the calculation is not carried beyond pounds, and the ammonia in the guano is calcu- lated to nitrogen only. ‘The extensive adulteration in the above case is probably the work of the exporters of the guano; never- theless the Dublin merchants who supplied it are not without blame, on account of either ignorance or carelessness in the selec- tion and examination of their own purchase. eee -XXXIIIL—ON A HYDROSTATIC BALANCE. By J. JOLY, B.E., Assistant to the Professor of Civil Engineering, Trinity College, Dublin. (Plate VII.) [Read, June 9, 1886.] Tur Hydrostatic Balance described in this Paper will be found il- lustrated on Plate VII., reference to which will enable its principle to be the more readily understood. It will be seen from figure 1 that it consists essentially of a vessel provided with one narrow tubulure opening, and suspended so that this tubulure is down- ward. Within is a second vessel; this vessel is closed, and is made of such shght material that it floats buoyantly in water. A fine wire is attached to the lower end of this inner vessel, and passes through the tubulure. The tubulure of the outer vessel is on a nozzle which, when screwed off, and the vessel turned up, enables the space surrounding the float to be readily filled with water. When filled, and the nozzle replaced, the vessel is hung up, as in the figure, with the tubulure downwards. The diameter of the tubulure being only some 8 mms., there is perfect security against outflow: indeed the apparatus may be shaken or rolled about upon a table with impunity. When the balance is hung it is obvious that the inner vessel or float, in virtue of its buoyancy, will be urged to ascend within the liquid, and if, as in fig. 2, we hang a pan on the wire, and load weights on the pan, we find that we can add weights up to a certain point, when the pan descends with the sinking of the float within the vessel. This weight —just adequate to cause the pan to descend—we assume for the present to be constant, and equal W, suppose. W é is evidently equal to the weight of a mass of water having a volume equal to the dis- placement volume of the float, less the weight of the float, of the wire, and of the pan attached to the wire. We can evidently ascertain, now, the weight of any mass not heavier than W. It is as if we were using a balance, one arm of which was loaded with an unalterable weight W. Thus, we place the substance to be weighed on the pan, and add weights till the pan descends. 348 Scientific Proceedings, Royal Dublin Society. At this point we know that a total weight W is in the pan. If the added weights amount to w, suppose, then x = W —- w. Practically, however, W is a quantity variable with the tem- perature of the float and of the water, their densities altering to different extents. When, therefore, accurate results are required, we cannot assume any constant for the balance, but must determine afresh the force W with each determination of w. Or, what is the same, we proceed by simply removing # when equilibrium has been obtained with x + w, and substituting a weight w,, so that equilibrium is again obtained, when w, is the required value of z. It is easy to guard against change of temperature in the brief interval necessary to effect the successive equilibrations. The process of weighing is, in short, the well-known one of substitu- tion, and with the usual correction for unequal air displacements of the weights, and the substance is accurate to a degree depending on the sensibility of the float to indicate a small change of load, when the downward acting forces are very nearly in equilibrium with the upward acting forces. ‘This consideration, 7. e. the degree of sensitiveness possessed by the arrangement, next claims atten- tion. The system as described is, in principle, identical with the Nicholson hydrometer, used as a weighing machine, the latter arrangement being supposed inverted while still retaining the liquid. But the inversion of the hydrometer introduces this important difference, that the stem supporting the pan of the hydrometer, a compression member, becomes in the hydrostatic balance a tension member, and hence, stiffness being no longer a requisite, may be made of extreme fineness, and the retarding | effect of the adhesion of the liquid on the wire at its circle of " emergence is much reduced. If, indeed, we assume the effect of this rillhaston of the surface- _ film to increase in direct proportion with the radius of the circle of emergence, it would appear—observing that the tensional strength of the wire increases proportionally to the square of this radius— that the sensibility to a small fraction of the entire load falls off only as the square of the carrying capacity or load which the balance will bear. There is, in short, reason to expect that, as we increase the size and carrying capacity of this kind of balance, no diminution of the fractional sensibility occurs, but rather an Joty—On a Hydrostatic Balance. | 349: increase; the sensibility increasing approximately as the square. root of the power of the balance. Thus, if we double the diameter: of the wire, the balance will now indeed indicate nothing smaller than double the least weight formerly causing displacement; but, on the other hand, we may assume a quadrupled carrying capacity. This leaves out of consideration the effect of viscosity of the- liquid. The effect of viscosity will hardly be to reduce the sensibility, but rather to render more tedious the use of floats having large. displacements. As, however, the tangential resistance to the motion of a solid surface, in the act of communicating a shearing strain to a liquid, is proportional to the extent of surface, and as this area increases at a slower rate than the volume inclosed by it, it appears that the tediousness attending operations is, again, not fairly assumed to be an attendant disadvantage which increases. proportionally with increase of power of the balance The effect is indeed, probably, complicated by the presence of currents or eddies. in the liquid. As regards the effects of solid friction, contact between the movable and immovable parts might, indeed, be altogether avoided. ‘Thus we might attach the wire externally to a flat cantilever, or flat spiral spring, so that it is retained in the centre of the tubulure by the horizontal rigidity of the spring, while the spring may possess such small vertical rigidity as not to interfere with the sensibility of the balance. It will be seen, however, from the figures, that this plan is not resorted to. It appears indeed unnecessary to do more than guard against contact down the wall of the tubulure ; and this is provided for in the little projecting collar placed at the point where the tubulure meets the wider nozzle. ‘The diameter of the passage here provided for the wire is about 1:5 mm.; the tubulure is about 3 mms. in diameter. The edge of the collar is sharpened to a knife edge all round, but just burnished smooth. With this arrangement, if the precaution be taken of using a smooth piece of wire, there appears but little retardation due to friction: this, doubtless, is partly due to the position of the collar within the liquid, the liquid acting as a lubricant. The effect of substituting a collar of burnished agate for the brass collar has been tried as in the balance, fig. 2, but with hardly appreciable gain in freedom. This little balance (fig. 2) 350 Scientific Proceedings, Royal Dublin Society. is represented in its actual dimensions. The float is a sphere of slight blown glass, weighing about 12 grammes, its diameter being about 6:3 cms. The outer vessel is of brass, parting, in a screw- joint, into hemispheres. or convenience of weighing by replace- ment, a double pan of slight brass is attached to the wire. This pan, together with the suspending gear, weighs about 11 grammes. The suspending wire traversing the surface of the liquid is of brass ; its diameter is 0°09 mm. Its breaking strength is 403 grammes: the stress it is called upon to bear in the balance does not ordi- narily exceed 120 grammes. A suddenly added or removed load might, indeed, act to some extent as a live load, and an increased stress result. Experience, however, seems to show that the strength is ample. The balance is protected from draughts and sudden changes of temperature by a glass case, from the roof of which it depends, hanging freely... The weights are introduced at a half door in the lower part of the case. The case needs no levelling screws. At 6° C. the load carried in the pan, when equilibrium obtains, is 104-660 grammes. Kine’s County. Except in Slieve Bloom and in Croghan Hill, the rocks of this- county are limestones, some being of excellent quality and well known. - Banagher.—In this vicinity the rocks are of the Calp type. Dark-blue or grey, inclined to black, earthy, in part flagey, and difficult to dress; can be raised in large blocks suitable for coarse work, and were used extensively in the works for the improvement of the Shannon navigation ; also in the buildings in the town and neighbourhood. Skerough.—A mile from Birr or Parsonstown. Grey; compact,. semi-crystalline; uniform in colour; easily worked ; has been used very much in the public buildings of Parsonstown. Clonmacnoise (Seven Churches).— Grey; thin-bedded ; some- beds very fossiliferous ; weathers unevenly. Stones of large size, but modern thickness, can be obtained. This stone was very much used in the old buildings at Clonmacnoise, and in the works on the- Shannon. The fossiliferous beds full of encrinite stems (locally called ‘‘screws”’) when polished have a quaint appearance, and have been much used for chimney-pieces, &c., having been formerly very extensively wrought at the Killaloe marble works. Wilkin- son remarks, in connexion with the ruins at Clonmacnoise :—“ In the doorway of one of these churches this stone has been used for delicate carving, and the surface of the door-jambs is polished, doubtless to display what was considered a beautiful material.” Upper Eglish.—Eighteen miles from Parsonstown. Grey, com- pact, easily worked. A great deal is sent to Parsonstown, being cheaper than the stone in that neighbourhood. Killane.—Near Edenderry. Grey, compact, easy to work. Bailydule (‘Tullamore).—Grey, with purplish tinge, crystalline, . massive, thick-bedded, and can be obtained in large blocks. It takes a fine polish, and is then of a dove-colour, clouded with a darker tint. It is very much admired in chimney-pieces and or- namental slabs. This well-known and beautiful stone has been used in the tracery, windows, and dressing, in St. Patrick’s Ca- thedral, Dublin; for columns and cornices of the Club-house, Kauldare-street ; the Roman Catholic Church, Monasterevan ; and. in numerous other places. Formerly more used in Dublin than. 430 Scientific Proceedings, Royal Dublin Society. at present, the Ballinasloe stone having, in a great measure, taken its place. This seems to be due to the cheaper carriage of the latter stone. Lime, in general, is very good and cheap in the King’s County. Le&ITRIM. Although a large portion of this area is limestone, yet this being, in general, of a calpy character, the best cut-stones are usually brought from the neighbouring counties. The caps on the gate-posts of the King’s Demesne, near Drumsna, came from Ballinrobe, in the Co. Mayo. In the north portion of the county there are in some places very good stones, but no quarry of more than local note seems to be worked. Mealwood.—Three miles and a-half from Carrick-on-Shannon. ‘Greyish-blue; crystalline; compact; splintry; difficult to work: large blocks can be procured. Formerly this stone was much used, but of late better stone is brought from Hughes’ Wood, in the Co. Roscommon. Castleslavin. Three miles from Carrick-on-Shannon.— Whitish- grey, crystalline ; fairly easy to work ; retains its colour. Ballinamoe.—The stone here similar to that at Mealwood. Kilbride.—One mile from Drumsna. Bluish-grey; not very good for tool-work. Lime in this county good; of superior quality near Manor- hamilton. LIMERICK. More than half of this county is occupied by limestones of dif- ferent qualities, the rocks being more distinctly and regularly grouped than elsewhere in Ireland, as previously pointed out (page 375). Margining the exposure of sandstone is the dark- blue, coarse, grey bedded Lower limestone, having over it the unbedded Fenestella limestone, and above that the Calp, ranging from a coarse slate and shale to marble; and above all, under the Coal-measure shales, the Burren-type rock. Oorgrig. A. little S.S.H. of Foynes.—Dark-blue and grey, crystalline; in part earthy; works fairly well; flat-bedded; ca- pable of being raised in very large blocks. Used extensively in — pier-work on the Shannon, both in Clare and Limerick. Kinanan—On Irish Marbles and Limestones. 431 Askeaton.—The Fenestella limestones of this neighbourhood were used extensively in the old castle of the Geraldines, and in Askeaton Abbey. The beauty of the stone, its qualifications for eut-stone purposes, and its durability, are displayed in the orna- mentation of the banqueting-hall of the castle and the windows of the abbey, but especially in the pillars of the cloisters. The latter are beautiful examples of carving, while at the same time they exemplify the fact that this stone is capable of taking a good and lasting polish. The exact place where these stones were quarried is not known; they are speckled greys, with tints of pink and dove-colour. Kylethane (near Kathkeale).— Dark calpstone, inclined to blackish ; in part shaley; hard, but works evenly except across the grain. Churchtown (Newcastle West).—Dark grey. Works freely, but is very wasteful. Drumroe.—Seven miles from Newcastle. A somewhat similar stone, but better than that at Churchtown, and generally preferred to it, butit is very brittle. Ballycummin —About three miles from Tene Bluish-grey ; works well. Rosbrien.—Near Limerick. Very similar tolast; a good stone. Limerick.—Thomond Gate.—Greyish-black; fine, and close- grained; some of the beds formerly worked for marble of a superior quality. Bridge quarry.—Grey ; compact; a good sound stone. Carey’s-road.— Dark grey; semi-compact. Gillogue.— Blackish ; very close-grained; good hydraulic lime. Railway Quarry.—Grey, black, and green. The black stone was worked for marble many years ago, and was good, being sent to the London market; the green is tuffose and arenaceous; works easily; friable; not durable; used extensively in the new railway station. The grey stones and those in the other quarries work more or less freely and well. They have been extensively used in Limerick and the neighbourhood. Charleville.—Dark-grey; crystalline; compact; a free-working stone. Quarry Hill, Knockany.—¥ our miles from iKeilenaliloe es Greyish- blue; close-grained; very easy to work. It would appear from the nature of the stone that it was from these quarries that 432 Scientific Proceedings, Royal Dublin Society. the stones were procured to build the Abbey, and the Geraldine town of Kilmallock. In the latter, a few years ago, there were excellent examples of this ancient cut-stone work; but during the last twenty-five years nearly all these old structures have been removed. The lime in this county, in general, is good; but that made from the Churchtown stone (Newcastle West) is poor in strength, and slacks slowly : the lime made from the Calp, near Rathkeale and Adair, is also poor. At Robertstown, between Barrigone and Foynes, there is a stone that gives a good hydraulic lime, which was used at Askea- ton Mills. In Gilloge Loch quarry, two and a-half miles north- east of Limerick, there is a good hydraulic limestone, which was used extensively during the building of the new dock at Limerick. LonDONDERRY. This county is another of those in which there is very little Carboniferous limestone; it only being found in a tract between Maghera and Magherafelt. It is principally quarried for lime- burning, some of it being hydraulic. Along the margin of the doloryte plateau, White Limestone appears in places, and is rather largely quarried, but principally for lime-burning, as its brittleness and jointy character make it yield unequally to the hammer, and unfit for fine tool-work. It can, however, be scabbled into blocks of small dimensions, which can be used in rough masonry. In the hill-country, especially south and south-west of Dun- given, there are many beds of metamorphic limestone (Ordovician ?) quarried principally for lime-burning. The principal quarry in the Cretaceous rocks is at— Spring Hill (Moneymore).—White; very pure; hard; fissured and cracked. Cannot be raised in large sound blocks. Can be scabbled into blocks of small size. Extensively used in Moneymore when building the princfpal houses. The quarries in the Carboniferous limestone are as follows :— Desert Martin.—Bluish and. brownish; rubbly; some beds yellowish-grey ;- solid; finely granular; crystalline, magnesian, and hydraulic. Used almost entirely for lime-burning. Kinanan—On Irish Marbles and Limestones. 433 Drumbally.—Very similar to the limestone at Desertmartin, and, as there, the yellowish rocks are hydraulic. The limestones from the metamorphic rocks in the Tirkeeran Hills (south and south-west of Dungiven) give a good, strong, dark- coloured lime; while those of Carboniferous and Cretaceous age give purer and clearer products, and also yield a larger return. At Desert Martin and Drumbally there are good hydraulic limestones, which were extensively used during the building of the bridges over the Bann, at Coleraine, Portglenone, and Toome. LoneForp. Except to the northward, where the older rocks are exposed, this county is principally Carboniferous rocks. They, however, are nearly invariably more or less obscured by surface accumula- tions, such as drift and bog. Lisryan. Four miles from Granard.—Dark-grey, earthy, com- pact ; pyritous in places; principally in layers; partly shaly. Crossrea. Near Granard.—Dark-grey; spotted when polished; coarse ; in part fossiliferous. Crewes. Three miles from Longford.—Light-grey. In the upper portion the beds are from 23 inches to 3 feet thick, but the lowest bed is over 18 feet thick. From the 23-inch bed flags 30 feet square or more could be procured. From the bottom, blocks 10 feet long and 6 feet wide can be raised. The stone is very highly thought of, and was used in the building of Carrick- glass House. Richmond Harbour. Five miles from Longford.—Greyish- blue ; can be raised in very large blocks. Used extensively in the Shannon works at ‘Tarmonbarry. . Ratheline. Near Lanesborough.—Dark-grey ; compact; works freely and polishes well. It was used largely in the works on the Shannon in the vicinity of Lanesborough. The lime of this county is generally good. Lovutu. A very small extent of Carboniferous limestone is found. It eccurs in the valley of the Boyne, at Ardee, north and north-east of Dundalk, and near Carlingford. Greenore and Carlingford.—Bluish-grey. eset sive quarried SCIEN. PROC. R.D.S.—VOL. VY. PT. V. 2G / 434 Scientific Proceedings, Royal Dublin Society. to supply the south portion of the Co. Down and Dundalk with lime and cut stone. In some beds very large blocks can be raised ; principally quarried for lime; not very good for tool-work. Kileurly. ‘Two miles from Dundalk.—Greyish-blue; compact ; crystalline ; works freely. Ardee.—Dark-grey ; semi-compact; difficult to work. Drogheda.—Dark greyish-blue, inclined to black ; earthy ; com- pact; in part shaly. The old buildings in which it has been used are very much weathered. Sheephill. Three miles from Drogheda.—Light bluish-grey ; crystalline; compact; works freely. A very good stone, very unlike any other in the county, being more like those at Lough Sheelin, in the Co. Meath (Ross Castle). It has been used in some of the public buildings in Drogheda, and extensively in the adjoining portion of the Co. Meath, and in the restoration by Mr. Roe of Christ Church Cathedral, Dublin. Lime strong and good, but dark-coloured. Mayo. As in the adjoining county of Galway, there are here also extensive crags or sheets of bare limestone, especially in the neigh- bourhood of Lough Mask; and the good quality of the limestone has prevented other stone being wrought or even looked for. Cong and Ballinrobe.—In various places in the neighbourhood of these towns, varieties of grey and blue; crystalline; compact ; sound; works easily; splits easily; can be raised in very large blocks ; suitable for all kinds of cut-stone purposes. Westport.—Two quarries in the vicinity, the larger called Farm Quarry. Greyish-blue; very good quality; bedded from 14 to 2 feet thick. At the Farm Quarry there is a clearing of about 20 feet of soil and 16 feet of bluish sandstone. A peculiarity of the limestone is the occurrence of invisible joints, called ‘ threads”’ by the quarrymen. These do not detract from the value of the stone, as it does not weather, nor, when in work, do the stones crack along them. They are of great use to the workmen, as by experience they have learned that, if they throw water on the face of a bed, they can see the “threads” when it is drying off, and subsequently, by the judicious application of the wedge, they can readily split the stones. Kirnanan-—On Trish Marbles and Limestones. 435 Wakefield, or Black Quarry (Castlebar).—Dark-erey or blackish, of the Calp type; very coarse; can be scabbled, but not fine- worked ; very large blocks can be raised. Moneen. One mile from Castlebar.—Bluish-grey; fairly easy to work ; was used when building the gaol and infantry barracks. Crossmolina.—Dark-grey to blackish ; compact; dense; earthy. It is quarried near Rosserk Abbey, which was partly built of it. Wilkinson points out that it is not a stone to be recommended, as it is brittle, and liable to break off when in work, which, he points ~ out, can be seen in the windows and doorways of the Fitzgibbons’ Castle, a few miles north of Castlebar, where a similar stone was used. Ballina.—In this neighbourhood the stone is very similar to that of Crossmolina. Moyne. Seven miles from Ballina.—Dull-grey; has an irre- gular fracture, but can be worked in any direction, and can be procured in very large blocks. A superior stone for any cut-stone purposes. It occupies a considerable area between Rosserk and Killala, the latter town being built on it; it also occurs at Moyne Abbey. The durability of the stone and its excellent qualities are exhibited in the Round Tower of Killala, the Abbey of Moyne, and the cut-stone in Rosserk Abbey. This stone was also used in the mansion of the Knox-Gores, near Ballina, and for cut-stone in the Roman Catholic cathedral. Excellent lime is made from the Carboniferous limestone ; also from boulders in the Drift. A Silurian limestone near Toorma- keady is said to be hydraulic. Near Cong there is a clay which, if mixed with lime, makes it hydraulic; used extensively at Cong in the river works, and at Lord Ardilaun’s fountain. Meratu. Carboniferous limestone occupies the principal part of the county, but it is divided into north and south districts by a tract of arenaceous and slate rocks. The stones in the southern district partake very much of the Calpy nature of the rocks in the Co. Dublin, while very superior stones are procured in the northern division, the quarries of Ardbreccan and Rosscastle, or Cashel, being extensively known ; also the neighbouring quay of Crossagh. 262 436 Scientific Proceedings, Royal Dublin Society. Ardbreccan. Three miles from Navan.—Brownish-grey ; when dressed, grey, very crystalline; works very freely ; can be obtained of very large sizes; a very superlor working-stone. Has been exten- sively used at Navan, Trim, Kells, Slane, and elsewhere—even at great distances. Crossdrum.—Two miles west of Oldcastle. Whitish-grey ; very pure; works freely. Can be obtained in blocks of large sizes. Rosscastle or Cashel.—Seven miles from Oldcastle, close to Lough Sheelin and the mearing of the county; a very superior stone and in much request. It is like the Crossdrum stone, but of a finer tex- ture and lighter colour; is extensively used in this county and in Cavan and Longford, the columns in the R. C. Church of the latter having been procured there. It was also used in the building of Loughcrew House. Crossagh, near Rosscastle.—The stone is very similar, but coarse : yet it is more preferred by the builders in Dublin. Trim.—Dark-blue to blackish ; of the Calpy type; earthy, but compact ; even-bedded ; a good workable stone for plain building, but will not dress well. Has been used in most of the public build- ings in Trim, also in the old Norman castle and ecclesiastical struc- tures; but in the latter sandstone has been employed where cut stone was required. Drogheda.—Near Drogheda the stone is, in general, grey and brittle ; but to the eastward it is dark-grey to blackish; of a Calpy nature, and can be raised in very large blocks suitable for rough work. Large quarries were opened at the east margin of the town, from which were procured the stones to build the Boyne Viaduct ; the dressing and cut-stone work being brought principally from Ardbreccan or Milverton, near Skerries, Co. Dublin. Farther east- ward, adjoining the river flats, there are the Corporation quarries, from which were procured the stones for the extensive harbour improvements. Lime very good; made from the Carboniferous limestone and from the boulders in the drift. Monacuan. The limestone is of Carboniferous age, and is generally of a Calpy nature, not suitable for tool-work. Some of the best stones in the Kinauan—On Irish Marbles and Limestones. 437 neighbourhood of Clones and Monaghan are situated in such low ground that they are liable to be flooded, and are, therefore, too expensive to work. The best quarries suitable for cut-stone purposes are in the neighbourhood of Carrickmacross. Barley Hill. Five miles from Carrickmacross.—Dark bluish- grey ; hard; well suited for tool-work, but rather difficult to work. Lime good, but often dark-coloured. QuEEN’s Counry. Carboniferous limestones occupy the central portion of this county. In some places the stone is of very good quality, but in others it is inferior, being of a Calpy type. Stradbally.—Light brownish-grey to grey ; close-grained ; i suited for cut-stone purposes. Has been largely used in this and the neigbouring county of Kildare. In all the public buildings at Maryborough it has been used; also at Monasterevan and else- where. Dunamase. Two miles from Stradbally.— Grey; compact ; slightly splintery ; but otherwise a good stone. Spire Hill.—F ive miles from Mountmellick. Grey; oolitic; slightly silicious; does not work freely. Thornbury (Abbeyleix).— Dark greyish-blue; silicious, and difficult to work. Ballyullen. One mile from Abbeyleix.—Greyish-blue. This is kinder and more easily worked than the Thornbury stone, and is more generally used in Abbeyleix. Portarlington.—Good stone for rough work; quarried in | dite ferent places, but not approved of for tool-work. Graigue. On the edge of the county, a suburb of Carlow.— The quarries here were principally worked for marble. The asso- ciated stones being burnt for lime. Lime very good, cheap, and abundant. RoscoMMon. Nearly the whole of this county is occupied by Carboniferous limestone, only some very subordinate tracts of older rocks appear- ing up through it. The rocks are very varied in character, from bad Calpy stones to those of the Burren type. There are, however, 438 Scientific Proceedings, Royal Dublin Society. dispersed over the county, many quarries capable of producing a good class of stone. Crisnagh. Near Boyle.—Grey; semi-compact; crystalline ; works well and freely. French Park. Near Boyle.—Grey; close, and compact; a free- stone; works well. The quality of the stone near Boyle, and its suitability for tool work, were not formerly recognised. . When Rockingham House was built, the stones were brought sixteen miles from Ballinafad, Co. Sligo. Some of these stones polish well, and are used for tombstones. Hughestown. A few miles from Carrick, near the Shannon.— Light greyish-blue; some of a better class become of a lighter colour when worked. ‘This stone has been used in Carrick-on- Shannon in preference to the stone at Mealwood. Castlereagh.— Between this town and Boyle there are different quarries ; but the stone is more or less of a Calpy nature, and diffi- cult to work. Mount Sandford House, near Castlereagh, was built of stone brought from Bellanagore, about nine miles distant. Bellanagore. Seven miles from EHlphin, the quarries being situated a few miles to the west and south-west of the village.— Dark to light grey; much freer than the stones near Castlereagh ; but inferior to those near Boyle. Aughris. About two miles from Roscommon.—Dark to light grey ; fine; crystalline ; works freely. Scardaun. About four miles from Roscommon.—Dark to light grey ; works freely ; in character very like those of the barony of Burren, Co. Clare. Lecarrow (Knockcroghery).—Grey; finely crystalline; regularly bedded; in parts cherty ; works fairly well. Taghmaconnell_—In this stony district the rocks are of types similar to those in the barony of Burren, Co. Clare. Good stones might be procured, but no quarry of note has been worked, as the stones needed in the neighbouring towns of Athlone and Ballina- sloe are more easily procured at the latter, in the Co. Galway, and at Clonmacnoise, in the King’s County. The lime in this county is excellent and cheap. Kinawan—-On Irish Marbles and Limestones. 439 S1ieo. In this county, as in Mayo and Galway, there are extensive erags and cliffs of Carboniferous limestone. The rock, however, is not, in general, as good a class of stone; those about Lough Arrow, to the south, and some beds near Ballysodare, being con- sidered of the best quality. Many of the Sligo stones are more or less of a Calpy type, and difficult to dress; yet in the old abbey at Sligo the local blackish stone was used for all purposes; and in the ruins are different examples of excellent work still in good preservation ; but of late years the Killea sandstone, Co. Leitrim, seems to have been preferred for cut-stone purposes. Ballysadare.—Greyish-blue ; crystalline ; semi-compact; easily worked ; takes a good polish; has been used for tombstones. Ballinafad. On the south-west shore of Lough Arrow.—In different places, grey and blue; crystalline; semi-compact; easily worked. Formerly much used before the quarries at Boyle, Co. Roscommon, were opened; the stones for Rockingham House, near Boyle, having been brought from this neighbourhood. Lime of the county good and cheap, but often dark-coloured. TIPPERARY. Except in portions of the barony of Lower Ormond, where it is of the Calp type, the limestone of this county is of a very uni- form blue colour, and compact. It has been very generally used in some of the best ancient ecclesiastical structures. On this sub- ject Wilkinson writes :—‘ At Cashel, with the exception of the sandstone used in the construction of Cormac’s Chapel and the Round Tower, limestone is the material with which all the build- ings have been erected. At Holycross this stone has been used 5 and the beautiful ruins in both these places show the excellent quality of the stone, both as regards the fine work it is capable of receiving, and its durability ; for the mouldings of the oldest parts are still fresh and sharp on the ses and even preserve the marks of the tools used in preparing them.” Fir Quarry, Ballinderry. Not far from Carrick-on-Suir. Gye close; even-grained ; difficult to work. Camus. A short distance from Cashel.—Light-grey ; easy to work. 440 Scientific Proceedings, Royal Dublin Society. Lewagh (Holycross). A little north of Thurles.—Dark-grey ; semi-compact; a very superior stone for all fine work. This ap- pears to have been the stone with which Holycross Abbey was built. . Castle Meadow. One mile from Thurles.—Grey; free work- ing; very good for dressed work. Ballinacurra. Four miles from Clonmel.—Dark greyish-blue : coarse and earthy beds; rather difficult to work, and more suitable for rubble than dressed work. Lisbunny. Near Nenagh.——Dark-blue, compact; earthy; in general not difficult to work. Some beds are more argillaceous than calcareous. Loughalton. Two miles from Nenagh.—Dark-blue to blackish ; some beds lighter, and greyish ; works easily. Loughorne. Three miles from Nenagh.—Variable in colour; shades of light-grey, dark-grey, and blue; in general compact ; the blue stones very earthy ; works easily. Ballinillard. Near Tipperary.—Greyish-blue. A light-coloured magnesian limestone lies below the blue ; works well. Portland.—Near to Portumna Bridge. Dark-blue to blackish ; earthy ; in part shaly; large blocks can be raised. Used exten- sively in the works on the Shannon. In this portion of the barony of Lower Ormond the rocks are of the Calp type, and are not in general suited for cut-stone purposes. In general very good lime ; some dark-coloured. Some of the Calp beds either will not burn, or will do so with difficulty. _ Tyrone. In this county are found Cretaceous, Carboniferous, and Meta- morphic limestones. The White Limestone (Cretaceous) occurs to the north-east, near Coagh and Stewartstown ; the Carboniferous occupies more or less scattered and semi-detached tracts; while the older limestones are found in bedded masses among the meta- morphosed rocks of Ordovician and Cambrian (?) ages in the north-west of the county. Dolomyte, containing Permian fossils like those at Cultra, Belfast Lough, Co. Down, has been found at Tullyconnel, near Ardtrea, a mile to the west of this place; and in sinking a coal-pit at Templereagh, adjoiing the Annaghone colliery. Koanaunan—On Irish Marbles and Limestones. 44] These Permian rocks have not been utilized. The Cretaceous are used principally for lime-burning, and so are also the Meta- morphose limestones, and in a great measure the Carboniferous. ‘Limestone is not, in general, used for cut-stone purposes, as sand- stones of excellent qualities occur in different places, and they are usually preferred. Cookstown. At Railway Station.—Various shades of grey to pink and red; fossiliferous; crystalline; some beds compact, and take a good polish. In beds from an inch to 4 feet thick. A little east of the town is a limestone of a purplish-grey colour; compact ; erystalline ; works fairly. Broomhill. A mile north of New Mills.—A bed of hydraulic limestone ; 12 feet thick proved by boring. Drumreagh. Three and a-half miles north-east of Dun- gannon.—A thick bed of close-grained blue hydraulic limestone ; under 37 feet of thin-bedded rock. Keeran’s Oross. Three miles south-east of Pomeroy.—A thin bed of light-brown hydraulic limestone. Castlecaulfield—Three miles west of Dungannon. Grey ; com- pact; crystalline ; in places flagey, or with shaly partings between the beds; works fairly well. The Carboniferous limestone, in general, is impure and hard to burn, or gives a dark-coloured lime; but at Cookstown an excel- lent white lime is produced. The White Limestone in general gives a rich lime. In the granite to the north-west of Pomeroy, at Limehill, there is a peculiar compact white limestone burned for lime, but not of a good quality. Hydraulic limestones, as above mentioned, are found at Broom- hill, Drumreagh, and Keeran’s Cross. WATERFORD. The Carboniferous limestone occurs nearly altogether in long east and west basins—one in the Youghal valley, and another in that of Dungannon, with a small tract in the valley of the Suir. The limestone used in this county for dressed-stone purposes is principally brought from the south portion of the county of Kil- kenny, being procured in the quarries in the neighbourhood of Jcilmacow. 442 Scientific Proceedings, Royal Dublin Society. Whitechurch. South of Cappoquin.—Light-grey ; hard; diffi- cult to dress; has been used in the town of Dungarvan, five miles distant ; also in the railway and other bridges. Shandon (Dungarvan).—Dark-grey ; not good for dressed- work; much inferior to that of Whitechurch, but more easily dressed ; used in building the Courthouse; gives superior lime. ’ Oughboy.—A. mile. from Lismore. Light-grey; hard, but brittle; coarse; easy to work. : Between Lismore and Dungarvan there are in places small quarries, where fair stone for tool-work has been procured. Some beds take a good polish, and have been used as marbles. Dunkitt.—Here, and also on the north side of the Suir (Co. Kil- kenny), limestone has been extensively quarried, to be sent down the Suir and up and down the Barrow, to supply the counties of Wex- ford, Kilkenny, and eastern Waterford, with stones for lime-burning. It is a thin-bedded, shaly, earthy stone; but as it can be cheaply carried by water to Waterford, it has been very extensively, though not always advantageously, used there. Good lime, but dark-coloured in general. WESTMEATH. Except in a few isolated places, Carboniferous limestones occupy the whole of this area. The rock is, however, comparatively speak- ing, seldom seen; and when it comes near the surface it is usually of the Calp type; or of a character unsuitable for cut-stone material. For this purpose limestone is principally obtained from Clonmac- noise, King’s Co., and Ballinasloe, Co. Galway, and formerly from Rosscastle, Co. Meath. A good stone, also used as a marble, occurs near Moate, while others have been extensively quarried about Mullingar, and used in that town: the stones, however, near Mul- lingar do not give fine or durable work. Hall. Three miles south-west of Moate.-—Grey, with splashes of white and red: of good quality, worked as a marble; extensively used in the new Exchange, Manchester, and in other places in England. Bunbrosna and Multyfarnham.—Dark-blue to blackish ; even- bedded. Various quarries, at which the stones are principally raised for rubble work and flagging. Kinanan—On Ivish Marbles and Limestones. 443 Pakenham Hall. A mile from Coole.—Dark-grey ; crystalline ; fossiliferous; earthy ; a fair stone. Kerry. Three miles from Mullingar.—Dark-grey to blackish ; compact; earthy; in part shaly; works freely; used in the Catholic Church, Mullingar. Fulmore.—Seven miles from Mullingar. Dark-grey to blackish ; Calp type. Large stones can be raised, which were used in the Railway Works and Mullingar. | Lime good, but dark-coloured. Hydraulic limestone occurs at Donore, where other beds give a very good lime. WEXFORD. In this county there is very little Carboniferous limestone, as it only occurs near Wexford, in a strip running south-west from the south of the harbour to the sea, near Duncormick, and in the promontory of the Hook. It is not much used for building pur- poses, although formerly much quarried for lime-burning. It is more or less of the Calp type, and not well suited for cut-stone purposes. Large blocks can be raised, and the stone from the Drinagh quarries, south of Wexford, were used in the construc- tion of the new pier at Ballygeery in the South Bay. The quays also, and other buildings, have been built from similar stones, procured here or in the quarries in the neighbourhood. ‘The lime- stone at Drinagh is in part hydraulic. In the Ordovician rocks there are beds of limestone and calca- reous tuffs. The limestones are used principally for lime-burning, especially one bed near Courtown Harbour, which is in part hydraulic. The tuffose limestones dress easily, and have been used in the railway bridges, but they do not appear to be durable. Good strong but dark-coloured lime from the Carboniferous limestone; the Ordovician limestones also give strong dark-coloured lime, but not good returns. In old times, even at considerable distances from the coast, sea-shells were burnt into lime. Hydraulic lime can be made from some of the beds in the Drinagh quarries, while a poorer hydraulic limestone occurs at Courtown. 444 Scientific Proceedings, Royal Dublin Society. WIcKLow. This is the only county in Ireland in which Carboniferous rocks have not been found; nor is it likely that any outlying patches occur under the superficial accumulations. It was also generally believed that no limestone of any kind exists; but of late years this has been proved to be incorrect. In the Glenart demesne, near Arklow, to the westward of the Castle, there is a very impure thin bed of limestone. Westward of Castlemacadam, near the church, in the brow of the hill, there are beds of flaggy limestone, which seem to have been worked to a small extent in former times; and to the north-east this limestone again appears in the brow of the hill, west of the Ovoca railway station. A bed of limestone was cut in the Avonmore valley when driving up the level from the old Glebe to Connery mine ; while limestone also occurs near Westaston, some few miles eastward of Rathdrum. None of these limestones have, at least in late years, been quarried ; but they appear to be of a quality very similar to the Courtown limestone, Co. Wexford. [ 445 ] XXXVII._—ON A PECULIARITY IN THE NATURE OF THE IMPRESSIONS OF OLDHAMIA ANTIQUA AND O. RADIATA. By J. JOLY, B.E., Assistant to the Professor of Civil Engineering, Trinity College, Dublin. [Read, November 17, 1886.] Recentiy, while examining some fragments of slate from Bray Head showing marks of Oldhamia, I noticed that on such speci- mens as displayed both varieties of marking, O. antiqua and O. radiata, the following peculiarity appeared :—A sunken or de- pressed delineation of one variety accompanied a raised or relieved delineation of the other variety. Thus, if on any specimen O. antiqua appeared as a depression, on that same surface the O. radiata appeared in relief. I verified this relation over such specimens as were in my possession, twelve in number, collected by myself at various times from certainly not less than two distinct localities on Bray Head: one of which is the well-known locality close to the Periwinkle Rocks. ‘These specimens are on the table. From this observation it appeared probable, if any meaning was to be attached to the relation, that a further relation would be found to obtain between the mode of delineation and the position in the rock. 'This was easy of investigation, as such further rela- tion might be sought for wherever either variety of mark was to be found in situ. Examination revealed the expected relation, in this order:—On the upper surface, or what was most probably the surface of deposition (the cleavage of the Cambrian slate of Bray Head coincides generally with the plane of bedding), the O. radiata appeared invariably as a depression, the O. antiqua in re- lief. In four localities this was verified. In one only, at the south entrance to the new tunnel, was there any doubt. Here the folding is so extensive and complicated that it was uncertain what surface was uppermost, and the marks also were obscure. Close to this fifth locality clearer marks on less contorted beds are in accord with the relation. It is apparent, indeed, that in the event of the relation being more extensively verified, it might in such cases be applied to determine whether or not inversion had occurred. 446 Scientific Proceedings, Royal Dublin Society. An explanation of this peculiarity—which at all events evi- dently obtains extensively in the Bray Head rock—is not easily offered; but I think the polarity of the marks respecting the plane of deposition is of importance in this, that it establishes a relation between the phenomena giving rise to them and that plane. Thus, for example, any hypothesis ascribing their origin to something in the nature of crystallization of the materials of the rock must account for a direction of cleavage differing in the two varieties respecting the plane of bedding. ‘This would appear to render a frost-mark theory (these Proceedings, antea, p. 106) in- adequate to explain both forms, although the polarity in the case of the O. radiata would accord with the theory. On the other hand, it need not necessarily, I think, be opposed to an organic origin for both forms. It is observable that if fragments be peeled off the slate, it is often found that the marks have been transmitted, or extend, to layers beneath, so that lines on the upper are seen as continued on 7 2 the adjacent lower surface; this, too, for thicknesses exceeding a millimetre. The accompanying woodcut recalls the appearance of a surface Joty—On a Peculiarity in Oldhamia antiqua and O. radiata. 447 from the Periwinkle locality. It is seen that it is not quite a plane surface, but one which has developed somewhat con- choidally. It is rough, too, and unlike the usual bedding sur- face. Nevertheless the O. antigua branches over the ridges without sensible loss of distinctness, and undeviated. This is not an un- common case. The specimen in question shows the O. antiqua in relief, the O. radiata depressed. The specimen has been placed in the Science and Art Museum, Kildare-street. SCIEN. PROC. R.1).8.—VOL. V- PT. VI. 21 (2 J XXXIX.—CURIOUS CONSEQUENCES OF A WELL-KNOWN DYNAMICAL THEOREM. By G. JOHNSTONE STONEY,, M.A., D. Sc., F.R.S., a Vice-President of the Society. [Read, January 19, 1887.] THERE is a well-known theorem in the science of Dynamics, re- lating to a system of bodies in motion, which may act on each other, but are not acted on by any external force. The theorem in question is, that if at any instant the velocities of the several bodies of the system be reversed, without any other change being made (?.e. without altering either their masses or the laws accord- ing to which they attract or otherwise act on one another), then will all the bodies of the system retrace their steps, traversing in the reverse direction the same paths which they had previously described, and in such manner that any position through which any one of these bodies had passed in its onward progress, at a certain time before the reversal, will be repassed with the same velocity, but in the opposite direction, at the same interval of time after the reversal. | Now, if we regard the universe as a dynamical system, it is exactly such a dynamical system as this theorem presupposes. Its several parts act on one another, but are not subjected to any other forces. And it is of interest to study what would be the result if such a reversal as the theorem supposes were to take place throughout the whole universe. We must, of course, suppose that the reversal affects all the motions of the universe, not only its ‘molar motions, but its molecular motions also; and not only the motions of its ponderable matter, but also the motions of the ether. In order to be in a position to study the effects, let us first suppose that we are spectators of this far-reaching change, without being ourselves affected by it—that we are, from an intellectual standpoint, as it were outside the great system whose future — history we want to trace, simply observing everything that takes place, and not in any way interfering with it, nor ourselves in any way transformed by the change. Stonry—On Reversal throughout the Universe. 449 To such a spectator the past history of the universe would repeat itself in reverse order, and many of the conditions under which it would do so would appear to him very strange. The bird which was shot to-day by the sportsman, and which is now lying in his kitchen, will, if the reversal of the universe were to take place at this instant, be restored by the keeper to the game- bag, will be carried by him, walking backwards, to the place where the pointer had fetched it in, where he will take it out, and lay it on the ground. Thence the dog will lift it in his mouth, and, trotting backwards, will reach the spot where the bird fell, where, however, it will now rise to the height at which it was shot, from which it will fly away backwards unharmed. Meanwhile, the vapours into which the powder had been dissipated will stream back into the barrel of the fowling-piece, and condense themselves again into gunpowder, while the grains of shot will rush towards the muzzle of the gun, and crowd into its breach. It is of importance to observe that, under the new conditions of the universe, all true dynamical laws will remain the same as at present, but many quasi-dynamical laws will be reversed. Thus, the first law of thermodynamics—the law of the equivalence of energy—will remain unaltered, but the second law will become its converse. Instead of a warmer body tending to impart heat to a cooler body, as at present, the new condition of things will tend to make their temperatures more divergent. Heat will become mechanical energy directly, and without requiring the accom- panying degradation of energy which now takes place. Friction, instead of retarding the progress of bodies, will help them forward. The air, instead of impeding a missile passing through it, will urge it on. And, when reviewing a system so divergent from what we find in the actual universe about us, it is very instructive to bear in mind that the wniverse, under the new conditions that we suppose, would be as perfect a dynanucal system as the actual universe is. This places before the mind in a very strong light the grave error which is too often made when such laws as I have referred _ to—the second law of thermodynamics, &c.—are supposed to be true dynamical laws. This naturally leads up to the consideration whether the laws of causation would be affected. Those relating to true causes would not be affected: those relating to quasi-causes would all be 2H2 450 Scientific Proceedings, Royal Dublin Society. inverted. ‘True causes never precede their effects; they are always strictly simultaneous with them. The science of Dynamics recog- nises true causes only. All change of the motion of a body is in that science attributed to forces acting while the change is taking place; and the persistence of a body in motion while no forces are acting on it is due to the inertia of the body, #.e. the body itself is the cause of it. It is because the inertia of a body is a sufficient, cause for its continuing in motion that time can elapse between events in nature. Whether the motion changes or does not change, the effect and its true cause are accurately simultaneous. The dispute as to whether action takes place at a distance does not disturb this statement. Everyone who does not suppose that the sun attracts the earth from a distance and without lapse of time, supposes that some medium pervading the intervening space com- municates the action; and it is not the distant body, but the sur- face of this medium where it touches the body acted on, that upon this view can alone be recognised in the science of Dynamics as the true immediate cause of the changes of motion of the second body. Thus, in all cases, dynamical effects arise along with, and not after, their causes. But in popular language, and indeed in all but very carefully strict language, many events are spoken of as caused by events that have preceded them. Thus, in the usual loose way of talking, we may speak of a ball’s having been re- acted on by the ground as the cause why it is now ascending, although a moment’s reflection would show that, in strict lan- guage, the reaction of the ground has caused only those changes of motion that occurred while the ground was pressing against the ball, and that the ball’s afterwards continuing to ascend is due to its inertia. Sometimes the two classes of causes are distinguished as immediate and remote. Now the change which we have sup- posed the universe to undergo would in no way affect immediate, that is, true causes; but all that we now recognise as an antecedent or quasi-cause would, to the spectator looking on at the universe from without, be changed into the effect, and that which is now the effect would to his apprehension occur first and become the cause. | These seem the first lessons which the study we have entered upon impresses upon us. But it is capable of giving further in- struction. Hitherto we have supposed the altered universe looked Stoney—On Reversal throughout the Universe. 451 at by a spectator who was himself unaffected by the change. But we are all ourselves parts of this universe, and the series of thoughts that occur in our minds are quite as much events that happen in the universe as the motions we see around us. Such a reversal of all the velocities of the universe as I have supposed, if it really took place, would affect us and the motions in our brains as well as everything else in the universe; and we have now to consider what the effect of this would be, and how it would modify our observation of what is going on around us. From the instant of the supposed reversal, the thoughts which had occupied our minds previous to it will recur, repeating themselves backwards, just like every other event in the universe. The memory of having eaten our breakfast will present itself first; the sensation that we are eating it will come on afterwards: at least this is the order in which we must as yet describe these thoughts in our mind as occurring; it is the order in which they would appear to that outsider whom we before supposed to be surveying the universe. But the relation of the one thought to the other in our own mind —of the memory to the sensations remembered—will be after the re- versal exactly the same’ asit was when these same thoughts occurred before in their right order. Now, TIME IS ONLY AN ABSTRACT TERM REFERRING TO ALL SUCH RELATIONS, just as mankind is an abstract term referring to the individuals that are men. And just as it is individual men who have a real existence, and not mankind in the abstract, so is it the individual time-relations occurring between real thoughts or real events that have a real existence, and not time itself, which is a mere word. But as we have found that the time-relations between our thoughts after the supposed reversal are absolutely the same as the time-relations between these same thoughts when they occurred before the reversal, then to us, if we share in the reversal, our thoughts and the events in the world about us will seem to occur in the same order of time as they did before the reversal, and the moment of reversal will in both cases appear to us to occur last in point of time. In other words, our sup- position of the reversal of all the motions of the universe, when it 1 Tn fact, the time-relation between the two states of mind amounts to this, that a part of the one state of mind is a memory of the whole, or of a part, of the other state of mind ; and this is equally the case after as before the reversal. 452 Scientific Proceedings, Royal Dublin Society. embraces the whole universe, ourselves included, does not really involve a repetition of the events in reverse order, but only a second way of reviewing the past history of the world. These considerations do not seem altogether unfruitful. They emphasise the distinction between true and quasi-dynamical laws» they clear our thoughts with reference to the relation of cause and effect, and, above all, they help to dispel from our minds the prevalent error that time has an existence in itself independently of the particular time-relations that prevail between the thou ghts that really occupy our mind, or between events! that actually occur in the universe about us, or between those events and our thoughts. In reality, the aggregate of these individual time-relations is the whole of what exists in nature as a background for our conceptions about time. ' Thoughts in other people’s minds are some of the events that occur in the universe about us ; that is, in the rest of the universe, excluding ourselves. 4581) 4 XL.—THE PHENOMENA OF SKATING AND PROFESSOR J. THOMSON’S THERMODYNAMIC RELATION. By J. JOLY, B.E. [Read, December 15, 1886.] Proressor J. THomson’s Thermodynamic Relation dt T(v-m) dp L entails that in the case of a substance such as ice, in which the consequence of the transference to the substance of a quantity of heat, Z, is to produce a negative change of volume, the value a is negative, and a lowering of the melting-point, results from the application of pressure. I would suggest that to the many phenomena which have found an explanation in;this physical fact might be added those attending skating, 7.e. the freedom of motion, and, to a great extent, the “biting” of the skate. The pressure under the edge of a skate is very great. The blade touches for a short length of the hog-back curve, and, in the ease of smooth ice, along a line of indefinite thinness, so that until the skate has penetrated some distance into the ice the pressure obtaining is very great; in the first instance, theoretically infinite. But this pressure involves the liquefaction, to some extent, of the ice beneath the skate, and penetration or bite follows as a matter of course, the amount of penetration being roughly a measure of the extent to which liquefaction ob- tains. As the blade sinks an area is reached at which the pressure is inoperative, 7.e. inadequate to reduce the melting-point below the temperature of the surroundings. Thus, estimating the pres- sure for that position of the edge when the bearing area has become = of a square inch, and assuming the weight of the skater as 140 Ibs., and also that no other forces act to urge the blade, we find a pressure of 7000 lbs. to the square inch, sufficient to insure the melting of the ice at - 3°5° C. With very cold ice 454 Scientific Proceedings, Royal Dublin Society. the pressure will rapidly attain the inoperative intensity, so that it will be found difficult to obtain bite—a state of things skaters are: familiar with. But it would appear that some penetration must ensue. On very cold ice, ‘ hollow-ground ” skates will have the: advantage. This explanation of the phenomena attending skating assumes. that the skater, in fact, glides about on a narrow film of water, the solid turning to water wherever the pressure is most intense, and this water, continually forming under the skate, probably resum- ing the solid form when relieved of pressure. From the thermo- dynamic point of view, the skater is the external agent, putting the ice through a reversed Canot’s cycle. Fluid shearing takes the: place of solid friction, and as the resistance thus arising is propor- tional to the area over which shearing obtains, that temperature at which the skater just obtains the requisite bite to impel himself will be the most conducive to freedom. Other phenomena, such as tearing and crushing, doubtless attend the skater’s motion, but such must necessarily be detrimental to freedom ; indeed, the fact that such phenomena do often attend the easy motion of the skater might be regarded as evidence against the popular notion that the possibility of skating is to be ascribed solely to the smooth- ness of the ice. It is quite certain, I think, that skating on so smooth a substance as plate-glass, for example, more expecially if accompanied with incidental tearing of the surface, would be quite impossible. Again, it is observable that skating on very rough ice is possible. Only, indeed, when the phenomena of solid fric- tion give place to those attending the motion of lubricated surfaces is there at all a comparable degree of freedom. Walking on a pavement greasy with fine mud occasionally recalls the aecidental treading on a “slide.” In the expression “as slippery as ice” there is revealed a con- sensus of opinion as to the abnormal nature of ice respecting friction. F455) XLI.—ON THE ANTIPODAL RELATIONS OF THE NEW ZHALAND EARTHQUAKE DISTRICT OF 101TH JUNE, 1886, WITH THAT OF ANDALUCIA OF 25rnH DE- CEMBER, 1884. By J. P. O'REILLY, C.H., M.R.1.A., Professor of Mining and Mineralogy, Royal College of Science, Dublin. (Plate IX.) [Read, January 19, .1887.] In an address delivered before the Royal Geological Society of Treland on the gaseous products of the Krakatoa Eruption, I took occasion to call attention to the antipodal relations of Java with the north-west coast of South America, and argued from the fact of there being, in this case, two districts of marked seismic activity directly antipodal, that in cases where such relations exist, marked seismic action may be expected to manifest itself. J had, in ano- ther Paper read before the Royal Irish Academy 14th Novem- ber, 1881, argued that in centres affected by earthquake action the points of greatest activity generally lie on coast lines, or on the boundary lines of geological formations: this was subsequently illustrated by an earthquake map of Great Britain and Ireland, annexed to the catalogue of earthquakes having occurred in these countries, submitted to the Royal Irish Academy, 28th April, 1884. The antipodal relations above referred to, as also the connexion of earthquakes therewith, and with coast lines and coast line di- rections, have recently received a remarkable illustration in the great earthquake of Andalucia of Christmas, 1884, and January, 1885, taken in connexion with the earthquakes and volcanic erup- tions which occurred in June last in the Northern Island of New Zealand. In order to show these relations between the two countries in question, I have prepared a map (Plate IX.) presenting the projec- tion, of the antipods of the northern island and of part of the middle island of New {/ealand, on the map of Spain. ‘This projection is shaded, and the zone of maximum voleanic intensity in the northern island is represen'cd by cross-hatching, being limited in one direc- 456 Scientific Proceedings, Royal Dublin Society. tion by the Tangaroro volcano, and on the other by White Island in the Bay of Plenty, also volcanic in its nature, and at present (Sep- tember, 1886) in active eruption. The seat of the Andalucian earth- quake, as also the points more markedly affected thereby, are within circles, the zone of greatest intensity being more deeply marked. It will not be out of place to state summarily the main facts relative to the two earthquakes thus brought into relation. That of Andalucia was described in Nature, vol. xxxi., p. 199 (January Ist, 1885); also in an article, “‘The Earthquake in Spain,” p. 237, and in a note, p. 277, giving a reswmé of Mr. Jos. Macpherson’s remarks on the event, made before the Spanish Natural History Society, January 7th, 1885. From these it may be learned that a series of very violent earthquakes occurred in Andalucia during a period of some weeks, commencing at Christ- mas, 1884; that while the motion was felt so far north as Madrid, the district most severely visited lay in the provinces of Granada and Malaga, forming a parallelogram measuring about 70 miles from east to west, and about 35 miles from north to south. The eastern part of this district passed into the great range of the Sierra Nevada, of which the highest peaks rise to between 11,000 and 12,000 feet above the level of the sea. The area of maximum destruction lay in the western sierras, and covered the ground to the north and south of them. The greatest amount of damage was done at Alhama, which was almost entirely ruined. In Arenas del Rey 40 persons were killed; in Albuqueros 150 ; in Olivar 10; in Cijar 12; and numbers of like magnitude were reported from many towns and villages of the three provinces affected. The number of persons killed was estimated officially at more than 1000 persons. In the sketch-map published in Nature, vol. xxx1., p- 199, the following cities, towns, and villages, are indicated as having suffered shocks :—Madrid, Cuidad-real, Cordova, Jaen, Seville, Archidona, Granada, Antiquera, Cadiz, Malaga, Torrox, Almufiecar, Alham, Alfarnetejo, Periana, Jayena, Olivar, and Albufiuelas. From the remarks made by Mr. Macpherson (vol. xxxi., p. . 278), the following additional particulars are gathered :— The earthquake presented marked coincidences with the geo- logical structure of the country affected, and was divided by him into three successive phases—one of relatively slight importance, O’Reitty—The Earthquakes in New Zealand and Andalucia. 457 which occurred in the early morning of December 22nd, and which was confined to the western portion of the country, its effects being felt only in Galicia and Portugal; another, of the highest importance, which occurred three days later, namely, at 9 p.m. on the 25th; while the third phase included the oscillations having taken place during a certain period subsequently in the districts most severely affected by the earthquake of the 25th. ‘The earth- quake extended over a very considerable surface, the district affected to an appreciable degree, including approximately, it would seem, the whole country lying between Cadiz and Cabo de Gata, and between Malaga and the Guadarrama range. The shock was quite perceptible in Madrid, the direction of oscillation having been from north to south. The movement gained in intensity as it proceeded southwards, more especially after leaving the southern border of the central table-land, limited by the fault of the valley of the Guadalquiver. He called atten- tion to the relation of the phenomena with the geological structure of the peninsula, and to the broad zone of great masses of granite, porphyry, diabase, and other kinds of rocks which cross the pen- insula from Galicia to the valley of the Guadalquiver, and which, geologically speaking, divides the peninsula into two distinct parts. “his huge belt (he says), which may be regarded as one of the most striking features of the peninsula of our day, cuts and divides the archaic formations, interrupting them in the Guadar- rama central chain between the Sierra de Gata and the Hstrella range in Portugal.” This zone he considers as corresponding to a great line of fracture which crosses the peninsula from north-west to south-east, in the prolongation of which lies the region of earth- quake shocks described by him. He concludes :— “The two principal coincidences observable between the phe- nomena of the earthquake and the geological structure of the peninsula are— “(1) That the disturbance of December 22nd was confined to the regions lying to the west of the zone described ; and _ “(2) That the most violent shocks of December 25th were ex- perienced in the region intervening between the Sierra Nevada and the Sierra de Ronda, and precisely on the very belt which encloses the arciiais mountain mass of the Sierras Tejea and 458 Scientific Proceedings, Royal Dublin Society. Almijara, broken and torn by the secular ‘disturbances of our globe.’ “There stood Alhama, now prostrate in the river bed; there Periana, a heap of ruins 3m. high; there Albufiuelas, which exists no longer; there Zafarraya, Nerja, Torrox, and many other towns and villages, all testifying to the fragility of these faults, which, though dating back to the Silurian period, are still apparently not completely welded.”’ The examination of the map shows that the zone particularly referred to by Mr. Macpherson corresponds precisely to the axis of the antipodal projection of the North and Middle Islands of New Zealand on the map of Spain: that is to the antipodal projection of the zone of maximum volcanic intensity of the North Island. Moreover, the projection of the Coromandel promontory (New Zealand) not only coimcides in its limits with the coast line of Malaga, but corresponds to the district represented as having been most affected. Alhama, the point of greatest destruction, lies exactly on the projection of the coast line of the promontory, as also Velez Malaga, while Malaga lies on the projection of the narrow headland which projects in a north-west direction from that promontory. It may thus be asserted that the zone of maximum intensity of the Andalucian earthquake has for antipod the promontory forming the Thames and Coromandel districts of the North Island of New Zealand, the continuation of which, to the south and east, is the Tauranga, or volcanic district, the seat of the disturbance of June the 10th, 1886. As regards this, not only has it been fully described by the local press of the country, but it has also formed the subject of two Government Reports—the one by Dr. Hector, Inspector of Mines, the other by Mr. Percy Smith, Assistant Surveyor-General, Auckland—Reports which have the signal merit of being both well done and quickly published. The following extract from Mr. Percy Smith’s Report (page 1) gives a description of the district affected :— “Tf a line be drawn nearly south-west (true) from the top of Ruawahia, it will be found to indicate very closely a line of ther- mal action, extending from the base of that mountain to Orakako- O’Reitty— The Earthquakes in New Zealand and Andalucia. 459 rako, along which, from time immemorial, have existed hot springs, geysers, and fumaroles, in immense numbers. “Such a line will also pass along the wall-like western face of the Paeroa Mountain, at the base of which, in several places, hot springs and fumaroles have always existed. “A little to the north of Paeroa is the Maounga-onga-onga Hill, on which no signs of recent action is apparent; but immediately to the east of it a country with innumerable hot springs, boiling mudholes, and lakelets, having on the east side the Kakaramea Mountain, where thermal action is very active, the greater part of the mountain having been steamed, and boiled, and coloured by subterranean vapours from top to bottom. In many places it is only necessary to make a hole in the surface to see the steam come forth. Further to the north-east the same line strikes through Rotomahana. It is thus obvious, that this line indicates an old line of activity and consequent weakness of the crust of the earth, and it is easy to show by varying its direction very slightly, or by treating it as a band of moderate width, that its production north- _ wards would strike White Island, whilst in the opposite direction Tongariro and Ruapechu form the terminal points of activity southwards. ‘A reference to the four-mile map attached to the Report shows that the recent eruptions have followed very closely this line. Taking Wahanga as the most northerly point of activity, and Okaro Lake as the most southerly, it will be found to have extended a distance of nine and a-half miles. Along this line there may be said to be eight craters or points and groups of eruption (usimg the term crater in a somewhat extended sense, to include eruptions of a dissimilar character). “ Karthquake Cracks.—The heavy earthquake at 2 a.m. on the morning of the 10th June, and the constant and frequent shakes and tremors since, have caused cracks in several places. In the Waikorua Basin on the Rotorua-Galatea Road (a place where several cracks, one of about half a mile long and twenty yards wide, have been known from the earliest times), several new cracks have appeared, but of no great extent. We counted five across the path, but only one was as much as a foot in width. They invariably take the line of the older cracks running north-east and south-west. Mr. Morgan describes the cracks on the south side of Kakaramea to be very numerous, and in one place a spur from 460 © Scientific Proceedings, Royal Dublin Society. that mountain is cracked and broken up to an extent to make crossing it very difficult. The north of Maounga-onga-onga is also much cracked.” In Dr. Hector’s Report, page 2, is given a description of the “ Great Fissure.” “This is the most remarkable and characteristic feature of the late eruption and the chief origin of the disastrous results which attended it. The fissure seems to commence in a narrow rift at the northern end from the great rent which has been formed in the south end of Tarrawera Mountain. This rent is a most wonderful feature. It is not a slip from the mountain side, but appears as if a portion of the mountain, measuring 2000 feet x 500 x 300 deep, had been blown out, leaving a ragged, rocky chasm, from which steam was being discharged in rapidly- succeeding puffs. Its general direction, as far as could be ascer- tained, is N. 50° E., which is the general line of direction that would connect all the more active geysers between Tangariro and White Island.” It may be concluded from these details that the most signifi- cant feature of the eruption and concomitant earthquakes was the oreat fissure extending from Tarawera Mountain to Okara Lake, a distance of about nine and a-half miles. The antipod of this fissure projects itself on the map of Spain in the immediate vicinity of the celebrated defile of Despefiaperros in the Sierra Morena, which connects the plateau of La Mancha with the great valley of Anda- lucia, and from the gorge of which a magnificent view of the valley is obtained. If the direction of the middle course of the Guadal- quiver be produced, it cuts the antipod of the northern extremity of the fissure, that is, the point representing the antipod of Tara- wera Mountain. There is thus brought into relation three very interesting lines. of earth fissuring—that traversing Spain from N.W. to 8.E., that constituting the axis of the volcanic zone of the North Island, New Zealand, and the line of faulting which corresponds to the valley of the Guadalquiver. The very remarkable mine of Almaden (which forms part of a great band of mineralized ground, extending in a line nearly east and west between the village of Chillon and a point to the east of Almadenejos), lies within the space covered by the projection of the O’Re1tty—The Earthquakes in New Zealand and Andalucia. 461 antipod of the North Island, and about 70 kilometres to the west of the projection of the antipod of the axis of maximum volcanic activity in the Northern Island. It is further to be remarked that the earthquake mentioned by Mr. Macpherson as having occurred December 22nd in Galicia and part of Portugal affected a space representing the antipod of the northern part of the middle island of the New Zealand group, the outline of which corresponds in places with the coast line of Galicia. Moreover, as Mr. Macpherson states that the shock took place to the west of the N.W. and S.E. zone which crosses Spain as described by him, it is evident that its seat was close to the west coast of Galicia, which corresponds so remarkably with the antipod of the N.H. coast of the Middle Island. An equally interesting feature of the comparison established by the map is, that the antipod of the western and more open portion of Cook’s Straits corresponds to the mountain ranges of Sierra de Gata and Sierra de Gredos; the former, very wild, and but imperfectly explored as yet, attains a height of 1753m. at the peak known as Pefia de Francia; the latter, equally wild and grand in its scenery, attains a height of 2661 m. in the summit known as La plaza del Moro Almonzor. That is to say, a strait in New Zealand, said to be deep, corresponds as antipod to very lofty and wild mountain ranges in Spain, and necessarily the seats of vast geological disturbances. As if to point out more strongly these seeming antipodal relations, there have occurred within the last three months two further earthquakes in Spain, as regards the relations of which with the antipodal points of New Zealand pro- jected on the map, the following details are of interest :— In Nature, vol. xxxv., p. 59, occurs the note: ‘‘A shock of earthquake was felt in the district of Beira Alta (Portugal) on the 11th inst. (November, 1886). This district is described in Vivien de St. Martin’s, “Dictionnaire de Geographie Universelle,” as being watered by the affluents of the Deuro, the Vouga, and Mondego rivers; the principal towns are Vizeu and Guarda. This district lies, therefore, in that part of Portugal whereon falls the projection of the antipod of the Collingwood District, north-western extremity of the Middle New Zealand Island. Vizeu lies at about 32 kilo- metres, = 193 miles, from the projection of the coast line, while Guarda corresponds very exactly as antipod to Cape Farewell. 462 Scientific Proceedings, Royal Dublin Society. The other earthquake recorded is that of 31st December, 1886, which occurred at Almeria, the antipod of which falls in the Bay of Plenty, at about 42°7 English miles north by east of White Tsland, the extremity of the line of the earthquake movements which shook that part of New Zealand the 10th of June last, and which island since is in a state of eruption. t ee 7 XLI.— SUGGESTION. RESPECTING THE EPIBLASTIG ORIGIN OF THE SEGMENTAL DUCT. By A. C. HADDON, M.A., M.R.1.A., Professor of Zoology in the Royal College of Science, Dublin. (Plate X.) [Read, February 16, 1887.] To Dr. V. Hensen is due the credit of first discovering the epi- blastic origin of the segmental duct in the rabbit (Lepus cuniculus). He first recorded the fact in 1875 (5); but the observation appears to have been universally discredited, and even Balfour makes no mention of it in his “Treatise on Comparative Embryology.” In 1884 Dr. G. F. Spee (11) found that the same occurred in the guinea-pig (Cavia cobaya), and in 1886 Professor W. Flemming (2) confirmed Hensen’s account for the rabbit. Towards the end of 1886, Dr. J. W. van Wijhe (18) announced that the segmental duct arose from the epiblast in the thornback ray (Raja clavata), and lastly, Dr. J. von Perényi (8) has very recently (January, 1887) extended this mode of origin to the frog (Rana esculenta) and to the lizard (Lacerta viridis). The origin of the segmental duct from the epiblast being now known to occurin Elasmobranchs, Anura, Lacertilia, and Rodents, we are justified in assuming that this is a general and probably primitive mode of formation. With the above-mentioned excep- tions, all embryologists who have recorded observations on the development of the duct agree in stating that it is at first placed immediately below the epiblast, and that it gradually sinks within the mesoblast, until it comes to lie close to the peritoneal epithe- lium; they also all agree in deriving the duct from the somatic mesoblast. . The duct arises in the Rodents as a linear proliferation of the epiblast in the region opposite to the intermediate cell-mass (“ Grenzstrang”’ of Hensen). Flemming points out that the area is of variable length, not even being symmetrical. The separation of this solid cord of cells from the epiblast takes place trom before backwards, and first oceurs at a time when the mesoblastic somites SCIEN. PROC. R.D.S.—VOL. V. PT. VI. QI 464 Scientific Proceedings, Royal Dublin Society. are still entirely continuous with the ventral (somatic and splanch- nic) mesoblast. Hensen, Spee, and Flemming conjectured that the primitive kidney is itself developed from the epiblast in these Mammals, but of this they produce no direct evidence. It is more probable that the nephridia are of mesoblastic origin, as in other Vertebrates. Fig. 1.—Transverse Section or Empryo Ragsir (4 mm. in length, stage of 16 somites). [After Flemming. | The section is taken just in front of the posterior termination of the intestine. The right side of the figure is the left of the body. There is a small rupture in the left (right of figure) mesoblastic somite. a/., mesenteron (intestine); ce., coclom (body-cavity) ; ep., epiblast; hy., hypoblast; %.c.m., intermediate cell-mass; n.¢c., neural canal; s.d., segmental duct ; som., somatic mesoblast; sp., splanchnic mesoblast. Van Wijhe finds that in the ray the pronephros (Vornier) arises, at the commencement of Balfour’s stage I., as a continuous evagination from the somatopleur on each side of the body throughout five somites. When the hinder end of this evagina- tion reaches the skin, it fuses therewith, and the place of fusion is the rudiment of the duct of the pronephros (segmental duct). This grows posteriorly, gradually separating from the skin, so that its latest formed end is always fused with it. The meso- nephros (Urnier) is developed shortly after the appearance of the pronephros. ; In the frog Perényi finds that the duct develops as a canal- like separation from the inner (nervous) cell-layer of the epiblast, which later associates itself with the mesoderm cells of the inter- mediate cell-mass (Grenzstrang). According to the usually-received account, formation of the segmental duct may take place in two ways—(1) either by the closing in of a continuous groove of the somatic peritoneal epi- thelium (Cyclostomi, anterior end only; Lepidosteus; Teleostei ; Amphibia) ; or as a solid knob, or rod of cells derived from the Havpon—On the Epiblastic Origin of the Segmental Duct. 465 somatic mesoblast, which grows backwards between the epiblast and the mesoblast (Cyclostomi, posterior portion ; Elasmobranchii ; Amniota). Balfour (1), appreciating the difficulties concerning the mor- phology of the duct, wrote thus :—“It is quite certain that the second of these processes is not a true record of the evolution of the duct; and though it is more possible that the process observable in Amphibia and the Teleostei may afford some indications of the manner in which the duct was established, this cannot be re- garded as by any means certain.” One question always presents itself: this is—How did the seg- mental duct acquire its posterior connection with the cloaca? In the development of the duct this communication is effected later than its first appearance, but this, evidently, could not represent the ancestral condition. There are also several difficulties con- cerning the general homology of the nephridia themselves. Balfour (1) discusses the problem in the following words :— “Tt is a peculiarity in the development of the segmental tubes, that they at first end blindly, though they subsequently grow till they meet the segmental duct, with which they unite directly, without the latter sending out any offshoot to meet them (Sedg- wick maintains that the interior segmental tubes of the Chick form an exception to this general statement). It is difficult to believe that peritoneal infundibula ending blindly, and unprovided with some external orifice, can have had an excretory function, and we are therefore rather driven to suppose that the peritoneal infun- dibula, which became the segmental tubes, were either from the first provided each with an orifice opening to the exterior, or were united with the segmental duct. If they were from the first pro- vided with external openings, we may suppose that they became secondarily attached to the duct of the pronephros (segmental duct), and then lost their external openings, no trace of these structures being left, even in the ontogeny of the system. It would appear to me more [probable that the pronephros, with its duct opening into the cloaca, was the only excretory organ of the unsegmented ancestors of the Chordata, and that, on the elonga- tion of the trunk and its subsequent segmentation, a series of metameric segmental tubes became evolved, opening into the seg- mental duct, each*tube being in a sort of way serially homologous 212 466 Scientifie Proceedings, Royal Dublin Society. with the primitive pronephros. With the. segmentation of the trunk the latter structure itself may have acquired the more or less definite metameric arrangement of its parts.” “ Another possible view is, that the segmental tubes may be modified derivatives of posterior lateral branches of the prone- phros, which may at first have extended for the whole length of the body cavity. If there is any truth in this hypothesis, it is necessary to suppose that, when the unsegmented ancestor of the Chordata became segmented, the posterior branches of the primi- tive excretory organ became segmentally arranged, and that, in accordance with the change thus gradually introduced in them, the time of their development became deferred, so as to accord to: a certain extent with the time of formation of the segments to which they belonged. The change in the mode of development which would be thereby introduced is certainly not greater than that which has taken place in the case of segmental tubes, which, originally developed on the Elasmobranch type, have come to de- velop as they do in the posterior part of the mesonephros of Salamandra, Birds, &c.”’ In his “ Comparison of the Excretory Organs of the Chordata and Invertebrata” (/. c. p. 607), Balfour states :—“ The excretory organs of the Platyelminths are in many respects similar to the provisional excretory organ of the trochosphere of Polygordius. and the Gephyrea on the one hand, and to the Vertebrate pro- nephros on the other; and the Platyelminth excretory organ, with an anterior opening, might be regarded as having given origin to the trochosphere organ, while that with a posterior opening may have done so for the Vertebrate pronephros (this suggestion has, I believe, been made by Furbinger). ‘‘ Hatschek has compared the provisional trochosphere excre- tory organ of Polygordius to the Vertebrate pronephros, and the posterior Cheetopod segmental tubes to the mesonephric tubes, the latter homology having been already suggested, independently, by both Semper and myself [ Balfour]. With reference to the com- parison of the pronephros with the provisional excretory organ of Polygordius, there are two serious difficulties :— “‘(1) The pronephric (segmental) duct opens directly into the cloaca, while the duct of the provisional trochosphere excretory organ opens anteriorly, and directly to the exterior. Happon—On the Epiblastic Origin of the Segmental Duct. 467 (2) The pronephros is situated within the segmented region of the trunk, and has a more or less distinct metameric arrange- ment of its parts; while the provisional trochosphere organ is placed in front of the segmented region of the trunk, and is in no way segmented. “The comparison of the mesonephric aoe with the seg- mented excretory organs of the Chetopoda, though not impossible, cannot be satisfactorily admitted till some light has been thrown upon the loss of the supposed external openings of the tubes, and the origin of their secondary connexion with the segmental duct.” The difficulties concerning the phylogeny of the segmental duct led Sedgwick (9) to the hypothesis that the duct may be com- pared with “the circular canal of Meduse, which might easily be conceived transformed into the Vertebrate segmental duct, the excretory organs themselves being developed from the outer part of the radial canals.”” Ata more primitive stage in the evolution of Chordata he suggests that “the primitive alimentary canal acquired a well-arranged system of ducts, by which the peripheral excretory matters were carried to the part of the alimentary canal near the hind end of the primitive mouth (future anus); that, in consequence, the excretory pores [such as occur in the circular canal of Meduse] were not wanted, and were either never deve- loped, or, if developed, lost.” Sedgwick summarises his conclusions thus :—‘‘ With regard to the endodermal organs, the pouches [archenteric diverticula] have become differentiated into two kinds— “¢(1) Anteriorly a certain number retain their communication with the exterior and with the gut. “©(2) The majority, however, lose their connexion with the gut and with the exterior, but remain connected by the peripheral canal, which behind retains (by means of a pouch ?) its communi- cation with the gut. ‘“©(3) A. posterior pouch loses its connexion with the gut and with the longitudinal canal, and gives rise to an abdominal pore. “The first group of pouches become the gill-slits, the second become the cwlom, while part of each of them become differentiated into nephridia, which opens into the longitudinal canal (pronephric or segmental duct). The last pair of pouches gives rise to a part 468 Scientific Proceedings, Royal Dublin Society. of the colom, and retains its connexion with the exterior as an abdominal pore.” Lang (7) appears to have been the first to compare the pores which put the gastro-vascular system of Coelenterates into direct communication with the exterior with structures found outside that group. He says:—‘In certain Polyclades [Turbellaria] ramifi- cations of the intestine open to the exterior by excretory pores, either on the dorsal surface (Planaria aurantiaca d. Ch:), or on the lateral edge (as in a very interesting new genus of the family of Proceride), thus forming a complete analogy with the ex- cretory pores which are found at the edge of the bell in certain Medusee. ‘“‘'The aquiferous system characteristic of other Platyelminths does not occur in the Polyclades. The secretory organs of these animals are formed after the type of those of the Coelenterata. excretion in the two groups is performed by means of diverticula from the intestine which open to the exterior.” Van Wijhe (13) believes that “the primitive Craniotes pos- sessed no pronephric duct, the pronephros opening to the exterior by a pore laterally from the gland. This orifice migrated later posteriorly, and its outer border developed into the duct, and coming into contact with the cloaca, opened into it.” He further goes on to say, that the epiblastic origin of the segmental duct will not be welcome to those who hold that the Chordata were descended from Annelids; but, for his part, he cannot admit the relationship between these types. Without at all committing myself to a belief in the ancestry of the Chordata from Cheetopod Worms, I would offer the following considerations as tending to show that the Vertebrate excretory - system is readily comparable with that of Annelids, now that the epiblastic origin of the segmental duct has been established. It is perfectly well known that the nephridia of all Inverte- brates open directly to the exterior, and in the segmented Worms. there are typically a pair of nephridia for each somite. The diagrams (Plate X., figs. 1 and 2) schematically represent this arrangement. It is generally admitted that the early (mot necessarily the primitive) Chordata were segmented, and it is not unreasonable to suppose that the nephridia were segmentally disposed, as there is Happon—On the Epiblastic Origin of the Segmental Duct. 469 usually a marked segmental arrangement of the nephric tubules in ontology. ‘The peripheral orifices of the nephridia must either have opened directly to the exterior, or from the first debouched into a longitudinal canal. Various theories have been framed to explain the latter arrangement; but the former condition is un- doubtedly more easily conceived, one difficulty in this supposition being— What has become of the primitive external openings ? Accepting the proposition that the primitive Chordata ne- phridia opened directly to the exterior, we have only to assume that the lateral area along which they opened was grooved, and that this groove extended posteriorly as far as the anus (Plate X., figs. 8-5). From the analogy of the neural groove, there is no great diffi- culty in further supposing that the nephric groove was converted into a canal, which, becoming separated from the overlying epi- blast, might sink into the deeper-lying parts of the body. If a suggestion may be hazarded concerning the advantage of converting the nephric groove into the nephric duct, it may be pointed out that the lateral openings of the nephridia would not be far removed from the branchial clefts, and the need of pure water for respiratory purposes is emphasised by the now acknow- ledged fact, that each cleft was provided with its own sense-organ (now metamorphosed into the “thymus gland”). The develop- ment of the duct from before backwards supports this view. From recent researches on the Lamprey [Shipley, 10], Newt | Alice Johnson, 6], Alytes [ Gasser, 4], and Frog [Spencer, 12], it has been proved that in these forms the blastopore never closes up, but persists as the anus (¢.e. the opening of the mesenteron into the cloaca). We are justified in assuming the persistence of the blastopore as the anus in early Chordata: thus, if the nephric groove were continued round to the anus, it would practically open into the extreme hinder end of the mesenteron, in other words, into the urodeum [Gadow, 3]. Probably about the same time that the nephric groove was being converted into the nephric canal (segmental duct) the proc- todeeum was being invaginated. The latter would push before it the posterior orifice of the nephric canal, as is represented in Plate X., fig. 6. 470 Scientific Proceedings, Royal Dublin Society. The nephridia themselves appear to be of mesoblastic origin. It is possible that the archinephros extended throughout the greater length of the body, as in Chetopod Worms, but that in time an anterior section (pronephros) came to be developed earlier than the posterior portion (mesonephros). The precociousness in the development of the segmental duct in ontogeny is not necessarily a difficulty, as it can be paralleled by many other organs. On the hypothesis just sketched out, the nephridia always open by their original epiblastic pores—primitively, directly to the ex- terior ; secondarily, into a canal separated from the epiblast : also the archinephros could be equally effectively functional throughout the whole period of its modification. List oF PAPERS REFERRED TO IN THE FOREGOING PAPER. 1. Batrour, F. M., . Treatise on Comparative Embryology, vol. u1., 1881. 2. Fiemmine, W., . ‘Die ektoblastische Anlage des Urogenital- systems beim Kaninchen.” Arch. f. Anat. u. Phys.-Anat. Abtheil, 1886. 3. Gapow. Hee. . ‘Remarks on the Cloaca and on the Copu- latory Organs of the Amniota,” Proc. Roy. Soc., 1886. 4, Gasser, E., . . “Zur Entwicklung von Alytes obstetricans.” Stizungsber. d. Marburger Naturgesell, 1882. 5. Hensen, V., . . ‘*Beobachtungen tiber die Befruchtung und Entwickelung des Meerschweinchens und. Kaninchens,”’ Arch. f. Anat. u. Phys., 1875. §. Jounson, A.,. . “On the Fate of the Blastopore and the Presence of a Primitive Streak in the Newt (Triton cristatus),’’ Quart. Journ. of Micr. Sct., xxiv., 1884. s 10. ite 12. 13. Happon—On the Epiblastic Origin of the Segmental Duct. 471 . Lane, A., . PERENYI, J. VON, Sepewick, A., Suretey, A, E., Sresz, G, F., . Spencer, W. B., Wise, J. W. van, «Sur les Relations des Platyelmes avec les Celentérées d’un cété et les Hirudinées de Vautre,’’ Arch. de Biologie, u., 1881. “Die ectoblastische Anlage des Urogenital- systems bei Rana esculenta und Lacerta viridis,’ Zool. Anz., X., 1887. ‘On the Origin of Metameric Segmentation and some other Morphological Questions,” Quart. Journ. of Micr. Sci., xxiv., 1884. ‘©Qn the Formation of the Mesoblast, and the Persistence of the Blastopore in the Lamprey,” Proc. Roy. Soc., 1885. ‘“‘ Ueber directe Betheiligung des Ektoderms an der Bildung der Urnierenanlage des Meerschweinchens,” Arch. f. Anat. wu. Phys. Anat. Abtheil., 1884. ‘Some Notes on the Early Development of Rana temporaria,’ Quart. Journ. of Micr. Sct., Suppl., xxv., 1885. “Die Betheiligung des Ektoderms an der Entwicklung des Vornierenganges,’’ Zool. Anz., 1X., 1886. [Expianation oF Puate X. 472 Scientific Proceedings, Royal Dublin Society. EXPLANATION OF PLATE X. Diagrams Inuustratinc THE PRopasBLE EivoLutTIoN oF THE SEGMENTAL. (ArcuinepHRic) Duct. a., primitive anus, or urodzum (blastopore) ; al., alimentary canal ;. ao., dorsal aorta; cw., celom; ¢.o., external orifice of nephridium ; gl., glomerulus of archinephros; gr., nephric groove; 7%.0., internal (ccelomic) ciliated orifice of nephridium; pr., proctodeum (epi- blastic cloaca); s.d., segmental (archinephric) duct. Fig. 1.—Horizontal view of the arrangement of the nephridia in Seg- mented Worms. », 2.—Transverse section through the body of an Karthworm (Lum- bricus). », 9.—Transverse section through the trunk of a hypothetical primitive representative of the Chordata. » 4.—End view of the same, to show the anus lying within the nephric groove. : », 9.—Horizontal view of probable disposition of the nephridia of the same. -,, 6.—Horizontal view of ideal archinephros of the lower Verte- brates. Lee XLIII.—NOTE ON THE ARRANGEMENT OF THE MESEN- TERIES IN THE PARASITIC LARVA OF HAL-— CAMPA CHRYSANTHELLUM (Peach). By A. C. HADDON, M.A., M.R.I.A., Professor of Zoology in the Royal College of Science, Dublin. (Plate XI.) [ Read, February 16, 1887. ] In 1859 L. Agassiz recorded from the east coast of North America: an Actinia parasitic on Meduse, which he named Bicidium para- sitica. This has since been found by Verrill in 1862, and by A. Agassiz in 1865. Still more recently (1884), Mark ' has given a preliminary account of a larval Edwardsia, which is parasitic within the gastro-vascular canals of the Ctenophore Mnemiopsis. leidyi. On this side of the Atlantic, T. Strethill Wright, in 1859, gave an account of a small Actinia, also parasitic, on Hydromeduse,. from the Firth of Forth, which he named Halcampa Fultoni; and, in the following year, F. Miiller described a similar form, which he named Philomedusa vogtii, from the Santa Catherina, on the Italian Riviera. EH. Graeffe described, in 18838, a parasitic Hal- campa from the Adriatic, which, “as the development of Halcampa chrysanthellum is not known, this form must, provisionally, be separated from H. chrysanthellum as H. medusophila.” The author exhibited, and made remarks upon, two specimens of a parasitic Haleampa at a meeting of the Royal Irish Academy,, on June 22, 1885, and a record was published in the following year. In this communication it is stated that Prof. A. Macalister of Cambridge (late of Dublin) had informed the author, by letter, that he had met with this Halcampa, and perhaps another form, but neither of them in Dublin Bay. Specimens were also obtained in Dublin Bay in June, 1886, and on June 6, in the same year, off 1 «¢ Selections from Embryological Monographs,’ compiled by A. Agassiz, W. Faxon, and E. L. Mark, Bull. Mus. Comp. Zool., Harvard Coll. (Camb., U.S. A.),. p- 43, pl. xii. 474 Scientifie Proceedings, Royal Dublin Society. Ballycotton, Co. Cork. On the same day Halcampa chrysanthellum was dredged from fifty-two fathoms. Breuiograpyy oF Larva Actintm Parasitic on MeEpusa. North European Seas. Peachia fultoni, t . TT. Strethill Wright, 1859, Proc. Roy. Soc. Edinb., 11., p.91, 1860 ; New Edinb. Phil. Journ., xi., p. 156. Halcampa, ,, ‘ . Reprinted in Ann. Mag. Nat. Hist. (8), viii., 1861, p. 132. 9 5 ; . G. Leslie and W. A. Herdman, 1881, Jn- vert. Fauna of Firth of Forth, p. 68 (merely repeats Wright’s record). Philomedusa ,, ; . A. Andres, 1888, Le Attinie, Atti. Ace. Rom, (8 4). xiv. (Fauna, u. Fl. d. Golfes v. Neapel (1884), p. 114.] Halcampa chrysanthellum, A. C. Haddon, 1886, Proc. Roy. Dublin Soc. (N.;8.), Vv: p. 115 Proc. Roy: Irish Acad. (2), iv., Sci., p. 527. (Noted in Zoologist, 1886, p. 7). There can be little doubt concerning the justice of considering the above to be the larval form of Halcampa chrysanthellum ; the form, colour, structure, and histology support this conclusion. In the only three localities where the parasitic larva has been hitherto found the adult Halcampa chrysanthellum has also been obtained, viz. Firth of Forth (Leslie and Herdman, Joc. cit., p. 62, on the authority of F. E. Schulze, “ Zoologische Ergebnisse der Nordseefahrt,” 111. Coelenterata, p. 140: Berlin, 1874), Dublin Bay, and Cork (A. C. H.). In a former paper [Proc. Roy. Dubl. Soc. (x.s.), v., 1886, p. 1] I have endeavoured to show that the forms known as Edwardsia duodecimeirrata, Sars (from Norway and E. Denmark), Zanthiopus bilateralis, Kef., and X. vittatus, Kef. (from N. France), are one and the same with this species. If this be so, the parasitic larva must have an equally North European range. Happon— On Parasitic Larva of Haleampa. A475: Mediterranean. Philomedusa vogtvi, . . Fritz Muller, 1860, Wiegmann’s Archiv f.. Naturg., xxvi., p. 57 [reprinted in Ann. Mag. Nat. Hist. (3), vi., 1860, p. 482.] A Aan . A. Andres, 1888, Le Attinie, Atte Acc. Rom. (84), xiv. [Fauna u. Fl. d. Golfes v. Neapel (1884), p. 112]. Halcampa medusophila, . H. Graeffe. 1883, Boll. d. Soc. Adriatica di Sct. Nat. Trieste, vii. As Halcampella endromitata (Andres), is the only Mediterranean example of the Halcampide, the above-mentioned forms are pro- bably the parasitic larva of that species. Coast of New England—North-East America. Bicidium parasiticum, . A. Agassiz, 1859, Proc. Boston Soc. Nat.. Hist., vil. (1861), p. 24. Ms . A. E. Verrill, 1862, Mem. Boston Soc. Nat. Hist. 1. (1866); p. dil; pli, nese 14, 15. H.C.and A. Agassiz, 1865, Seaside Studies in Natural History, Boston, p. 15, fio. 14. Peachia parasitica, . . A.K. Verrill, 1866, Proc. Boston Soc. Nat. Hist., x., p, 388. A. BE. Verrill, 1873, Report U. S. Fish Com., 1., 1871-2, p. 739. Philomedusa ,, és . A. Andres, 18838, Le Attinie, Atti. R. Ace. Lincet, Rome (84), xiv. (Fauna uw. Fl. d. Golfes v. Neapel, 1884, p. 112, fig. 9. 99 29 From Verrill’s accounts (1862 and 1866) there can be no doubt that the above parasitic Anemone is really a Peachia; it must, therefore, be known, for the present, as P. parasitica ; but in the latter paper Verrill states that it is very much like Stphonactinia (Peachia) Beckii (Dan. & Kor. 1856) in form and colour. The 476 Scientific Proceedings, Royal Dublin Society. colour is purplish-brown, or red, and the length 32 mm. - to 46mm. With the exception of two specimens of very large size found buried in the gravel, at low water-mark, at Eastport, Maine (Verrill, 1873), this form is only known as parasitic in the lip-folds of Cyanea arctica, from Cape Cod to the Bay of Fundy. Southern Ocean. Actinia clavus, : . Quoy et Gaimard, 1833, Voyage de lV’ As- trolabe, p. 150, pl. x., figs. 6, 11. Iluanthos ,, : . Milne Edwards, 1857, Hist. Nat. des Coral- liatres, 1., p. 284. Philomedusa clavus, . . Andres, 1883, Le Aittinie, Atti. Acc. Rom. (3 a) xiv. [Fauna u. Fl. d. Golfes v. Neapel (1884), p. 114.] Halcampa a : . RK. Hertwig, 1882, Actiniaria, ‘‘ Challenger ”’ Reports, p. 92. Quoy and Gaimard found several specimens of this Halcampa entangled (engagés) in the tentacles of a medusa. It was 7-8 lines long in its greatest extension, and only three when con- tracted; translucid white in colour; 12 short tentacles. They obtained it in Bass’ Straits, Australia, lat. 38° S. R. Hertwig identifies an Halcampa dredged by the Challenger at Kerguelen (25-120 fathoms) as this species. It is interesting to observe that certain (at least) of the members of the three families, Hdwardside, Halcampide, and Siphonactinide, pass through a stage during which they are para- sitic on Medusee or Ctenophores. ‘There is now a good deal of evidence in favour of the view, that the Hdwardside and Halcam- pidse are more closely related than was formerly thought to be the case; and, so far as my investigations on Peachia have gone, I am led to believe that the Siphonactinide are closely related to the latter. Be this as it may, the genus Philomedusa must now be discarded. As before mentioned, in 1885 I found one or two specimens of the larval Halcampa in Dublin Bay, and again in 1886, in July of that year, I also found a specimen off the coast of Cork. ‘They Happon—On Parasitic Larva of Haleampa. 477 were usually attached to the stomach on the sub-umbrella (Pl. X1., figs. 1, 2) of different species of Leptomeduse. Occasionally they adhered to the margin of the disc. With a little care they can be kept alive some time, and will feed on small pieces of meat when medusze are not to be had. When first obtained some specimens measured a little under 3 mm. in length, and one grew to about 5 mm. in length. The body was sub-conical in form, the column not being dis- tinctly divided into the three regions (capitulum, scapus, and physa) so characteristic of the adult. The middle portion was especially corrugated, and indented at the insertion of the mesen- teries. ‘The body could be slowly lengthened or contracted ; it was uniformly clothed with small cilia. There were only eight short tentacles. At first they were very short, but afterwards they grew relatively longer. The Medusa appears to be but little incommoded by the parasite ; but it probably succumbs in time to its guests. In its ordinary condition the Anemone sinks in the water when taken from the Medusa; but it can extrude its mesenteries through its mouth for a considerable distance (Pl. XI, fig. 5). These enable it to float at the surface of. the water, and, at the same time, to attach itself to passing Medusx. This is probably the manner by which it secures a continual supply of food. They had a uniform yellowish flesh-colour, with eight rudi- mentary tentacles. The tentacles grew longer, and were tinged with brown and yellowish white. The disc also became variegated with brown, and the body translucent, revealing the yellow ceso- phagus. At the last observed stage the body was almost colour- less—the cesophagus yellow, the capitulum possessed a pair of cream-coloured spots below each tentacle, and the insertion of the mesenteries were of the same colour—the eight tentacles had on their oral surface two transverse bars of white at the base, and a single bar half-way along their length. Above this was a large brown spot, and a pair below it; and above the basal lines, between the two brown spots, is a small white one. The disc was prominent, with white radial lines, the areas being brown, finally speckled with white, each having prominent white spots at the mouth. Although there were eight tentacles there were twelve mesen- teries. The tentacles were arranged in two groups of three, and a 478 Scientific Proceedings, Royal Dublin Society. single tentacle between each group. A deep siphonoglyphe, was present, thus causing the mouth to be T shaped. The siphono- glyphe, being in the axial line, indicates the disposition of the tentacles. On reference to Pl. XI., fig. 4, it will be seen that the intermesenterial chamber on each side of the axial or directive chamber is produced into a tentacle. Of the three remaining lateral chambers, only the centre possesses a tentacle. All the previous accounts of the parasitic larva of Halcampa agree in the fact of twelve tentacles being present. This can only be accounted for by supposing that the larvae were more developed than mine. This was certainly the case in Strethill Wright’s specimens, and in my oldest examples I found indications of the sprouting of some of the missing tentacles. It is, of course, possible that the Mediterranean form acquires its twelve tentacles very early. Meyer and Mobius (Arch. f. Naturg., 1863, p. 70) mention that in their adult examples of “ Kdwardsia duodecimcirrata,” Sars. [ Halcampa chrysanthellum |, the number of tentacles varied from eight to twelve, but never more than the latter number. By making a series of transverse sections I was enabled to trace out the arrangement of the mesenteries ina more satisfactory man- ner than could be effected by an examination of the living animal. In the esophageal region, the twelve mesenteries appear to have equal importance. The siphonoglyphe causes what may be termed the ventral directive mesenteries to be much bent. At the lower extremity of the cesophagus four of the mesenteries fall short of joining the cesophagus. The siphonoglyphe extends for a short distance beyond the cesophagus proper (Pl. XI., fig. 8). In the gastric region of the body there are eight large mesen- teries, which alone bear the swollen digestive borders. It will be noticed that it is those intra-mesenterial chambers, bounded by a strong and a weak mesentery, which are not prolonged into ten- _tacles. The dorsal directive mesenteries also appeared somewhat smaller than the remaining six. The same general arrangement occurred at the posterior end of the body, except, of course, that the mesenteries have no thickened edges. It is probable that at a slightly earlier stage only the eight strong mesenteries are present, as an increase in the number of tentacles with the growth of the animal is characteristic of most Havpon—On Parasitic Larva of Halcampa. 479 sea-anemones, and in our species the adult has twelve rudimentary mesenteries in addition to the twelve primaries [ cf. Proc. Roy. Dub. Soc. (N.S.) v., 1886, p. 12, fig. 4]. The same occurs in H. arenacea, Haddon’; but according to R. Hertwig, there are only the twelve primaries in H. clavus, Quoy et Gaimard. The brothers Hertwig' first insisted upon the systematic im- portance of the disposition of the muscular bands on the mesenteries. A comparison of the diagrams on Pl. XI. will demonstrate the fact that the eight strong mesenteries of the larval Halcampa perfectly corresponds with the eight mesenteries of Hdwardsia. The Hert- wigs have further shown that the normal Hexactina pass through a stage in which there are eight strong and four weak mesenteries (Pl. XI, figs. 10, 11); but it will be seen that these mesenteries do not correspond with those of the larval Halcampa and adult Edwardsia on the one hand, or with those of the Octactiniz on the other. The inequality in the development of the septa of the adult Halcampa was first pointed out by R. Hertwig? (Actiniaria, “ Chai- lenger”” Reports, Zoology, vi., 1882, p. 95). He found that four were somewhat smaller than the eight others. I have quoted (doc. cit. pp. 7, 8, footnote) an observation of Dixon’s confirming this, and Strethill Wright found the same in his larval form. He says :— “Hight septa were continued downwards to the lower extremity of the body, and had their free edges bordered by a convoluted cili- ated band, furnished with cnidee, or thread cells; the intersepta (¢.e. the four smaller mesenteries) bore no convoluted bands.” On a future occasion I propose to give a detailed account of the anatomy of Halcampa chrysanthellum; for the present I would merely state that I find that, in the adult, the generative organs only occur on six mesenteries. These correspond with the eight strong mesenteries mentioned above, less the dorsal pair. The axial, or directive mesenteries, which support the siphonoglyphe, are here considered as the ventral, and the opposite pair as the dorsal. The Hertwigs also pointed out that the Actinide (larval forms) 1 First Report ‘‘On the Marine Fauna of the South-west of Ireland—Actinozoa,’” Proc. R. Irish Acad. (2) iv. (Sci.), 1886, p. 616. 2 Die Actinien (Studien zur Blattertheorie), O. and R. Hertwig, Jena, 1879. SCIEN. PROC. R.D.S.—VOL. V., PT. VI. 2K 480 Scientific Proceedings, Royal Dublin Society. Edwardsie, and Alcyonaria exhibit three different ways in which the eight mesenteries may be disposed. ‘They regarded the mesen- teries as symmetrical—/.e. four dorsal and four ventral in the Actinide, as six dorsal and two ventral in the Edwardsiz, while in the Alcyonaria all the eight mesenteries are dorsal. Although my observations are incomplete, I have thought it desirable to place them on record, as it may be some time before I am able to discuss the question at greater length. For the present, we may assert that, although the adult Halcampa closely re- sembles the ordinary Actinize in the ratio of its tentacles, and the disposition of its mesenteries, the larval form is undoubtedly more nearly related to the Edwardsie. EXPLANATION OF PLATE XI. (Figs. 6-14 are purely diagrammatic.) Fig. 1—Thauwmantias globosa, Forbes (Phialidium variable, Heckel), with parasitic Halcampa; nat. size. 2.—The same; magnified 4 diameters. 3.—Parasitic larva of Halcampa chrysanthellum, older than that of fig. 1; magnified 5 diameters. 4.—Oral disc of a still older larva, with eight tentacles, but twelve mesenteries, and showing the siphonoglyphe. 5.—Oral aspect of larva with extended mesenteries; about 5 diameters. 6.—Transverse section of larval Halcampa through the middle of the cesophagus (stomodzum). », %.—Transverse section of larval Haleampa through the lower portion of the cesophagus (stomodeum). _ » %—Transverse section of larval Halcampa immediately below cesophagus (stomodeum). Havpon—On Parasitic Larva of Halcampa. 481 Fig. 9.—Transverse section of larval Halcampa in the gastric region. », 10.—Transverse section of young larva of Aptasia diaphana (after R. and O. Hertwig). », 11.—Transverse section of slightly older larva of Aptasia diaphana (after R. and O. Hertwig). », 12.—Transverse section of adult Hdwardsia tuberculata through the cesophagus (after R. and O. Hertwig). +, 13.—Transverse section of adult Alcyonium digitatum through the cesophagus. +, 14,—Transverse section of adult Funiculina quadrangularis through the cesophagus (after A. Milnes Marshall). 2K2 be J XLIV.—NOTE ON A GRAPHICAL METHOD OF SOLVING CERTAIN OPTICAL PROBLEMS. By HOWARD: GRUBB, F.R.S. [Read February 16, 1887.] In the calculation of curves of optical lenses it is frequently re- quired to add and subtract reciprocals; and formule of the form 1 ip teal at ave are of constant recurrence. In the study, where a logarithm book is available, the arith- metic of this is generally very simple; but in the workshop or laboratory a graphical method of solving the problem is often more convenient, particularly in the hands of workmen who have not had a mathematical training. In the working out of some optical diagrams on logarithmic paper I accidently arrived at the following graphical solution, which I have found very useful, and on the principle of which I am constructing a calculating machine suitable for solving these particular problems :— Draw a horizontal line = the a of above formula, and erect at one extremity a vertical = 3. Join the extremities of these two lines. Bisect the right angle, and produce the bisecting line till it reaches the line joining the extremities of the lines a and 8. From the Grupp—Graphical Method of Solving Optical Problems. 483 point of intersection drop a perpendicular on the line a, and the length of this perpendicular on the same scale will be equal to in above formula, or = mec 3 at B According to this principle, a machine can be constructed in which the various quantities can be read off by scales, without any calculation whatever. I hope shortly to be able to exhibit such a machine to the Royal Dublin Society. r 484 J XLV.—AN EXPERIMENT ON THE SURFACE TENSION OF LIQUIDS. By A. R. WALSH. (Communicated by F. T. Trovuton, B. HE.) [Read, February 16, 1887.] ' THE fact that an oily needle will float on the surface of water has. been known for a long time, and is often referred to as an experi- ment illustrating the tension of the surface between water and air. If a medium-sized needle (No. 6) is placed floating on water, and olive oilis gently poured on the surface of the water, until the needle is covered by the oil, the needle sinks to the bottom of the water. But if the same experiment be made, using this time petroleum instead of olive oil, the needle will remain floating on the surface of the water. The depression formed by the needle and oil resembles a boat, the sides of which are formed by the depressed surface of the water, while the contents consist of the oil and the needle. If the needle used in the two experiments be the same, the amount of oil in the boat depends upon the specific gravity of the oil; while the amount of oil the boat will bear without the sides giving way depends upon the strength of the sides, that is to say, on the superficial tension. Let V and be the volume and density of the water displaced ; V’ and &’ be the volume and density of the oil in the boat ; V’ and 8” be the volume and density of the needle ; then Wa WSs eX (1) [es ok. IM, (2) 7 ae = Ye (3) Since o’ is always nearly equal to 6, and small compared with 8”, Watsu—On the Surface Tension of Liquids. 485: the value of the fraction in (3) depends upon the value of o. The volume of water displaced, therefore, varies as V” and as 0. The following Table, taken from the memoir of M. Quincke, gives in grammes weight per lineal metre, the tension of the surface at 20° C., separating water from air, olive oil, and petro- leum :— Superficial Tension in Grammes Weight per Lineal Metre. Between water and air, : ‘ . 8:253 Between water and olive oil, . . 2:096 Between water and petroleum, . 6 PPI: Specific Gravities. Olive oil, . : ; 3 : Sco) le Petroleum, . ; : : 5 SeOA0. When olive oil is poured on the surface of water upon which a needle is floating, the high specific gravity of the oil, and the weakness of the surface separating it from water, combine together to sink the needle. In order that a needle should be able to float between olive oil and water, it would be necessary for the weight of water dis- placed to be twice as great as the weight of water displaced when the same needle floats between petroleum and water. With a certain needle, the volume of the water displaced was found to be thirty-five times the volume of the needle. In order that the same needle might float between olive oil and water, the volume of water displaced would require to be seventy times the volume of the needle. It is possible for a very small needle to float on water which is covered by olive oil; for by halving the volume of the needle, the volume of the water displaced is at the same time halved. [ 486 ] XLVI.—THE BLACK MARBLE OF KILKENNY. By W.N. HARTLEY, F.R.8., Professor of Chemistry, Royal College of Science, Dublin. [Read, February 15, 1887.]} Tus well-known marble is highly esteemed on account of its jet- black appearance and the high polish which it is capable of receiv- ing. Last April I visited the quarries from which it is procured, and observed certain properties belonging to it of which I can find no description. It is mentioned in Sir Robert Kane’s work on “The Industrial Resources of Ireland”? that the exposed and weathered surfaces of the rock possess a yellow ochreous colour. This might be due to the colour of the freshly-hewn stone being caused by the presence either of ferrous sulphide or of ferrous carbonate, which, in presence of carbonic acid and air, became dis- solved and oxidised. ‘The disappearance of the black colour from the surface was remarkable. On striking a block of the marble with a hammer or large stone it emitted a ringing metallic sound. When portions were broken off, the fractured surface smelt of sul- phuretted hydrogen. Under similar circumstances the German “Stinkstein”’ is said to smell of bituminous matter. The con- stituents of the mineral were determined by Mr. J. HK. Purvis, a student in the Royal College of Science; the results of his exami- nation are here given :— CuEmicaAL ANALYSIS. When the mineral was finely powdered and thoroughly mixed its colour was a little lighter, but still what may be described as black. Carbon dioxide was determined by Fresenius and Will’s method: the escaping gas smelt of sulphuretted hydrogen. Estimation of Sulphuretted Hydrogen.—It was found by Mr. Fred Ibbotson, who made a qualitative examination of the mineral, that sulphuretted hydrogen was liberated by acetic acid, also that precipitated ferrous sulphide is decomposed by acetic acid; therefore nothing could be learnt by dissolving the HarriEy—On the Black Marble of Kilkenny. 487 mineral in acetic acid. The gases evolved by hydrochloric acid acting upon ten grams of the substance were passed through two U tubes containing acidulated solution of copper sulphate: a brown precipitate formed only in the first limb of the first tube; this was collected on a filter, washed, dried, and weighed. It was considered that as the quantity collected was very small, and water was contained in the mineral, that the sulphu- retted hydrogen was in solution in fluid enclosures too small to be visible, and that possibly it was present as calcium sulphydrate. A large quantity of the substance was crushed under distilled water, and on testing the liquid with lead paper a black stain of Jead sulphide was obtained. The aqueous solution was filtered ; the filtrate was evaporated to dryness, and a light-brown residue was left. Hxamined with the spectroscope, the residue was found to contain a compound of calcium only. Another portion, crushed under water, filtered, and treated with ammonium chloride, am- monia, and ammonium oxalate, yielded a white precipitate, small in amount, and consisting of calcium oxalate. A portion of the residue left after evaporation of the aqueous solution was oxidised with nitric acid, and tested with barium chloride, by which treat- ment a precipitate of barium sulphate was obtained. Copper.—After solution of the mineral in hydrochloric acid and evaporation to dryness, to separate silica in the usual way, a current of sulphuretted hydrogen, passed for some time through the hot solution, separated a small quantity of copper sulphide. This was filtered, washed, dried, transferred to a crucible, heated with a few drops of stroug nitric acid, and the iron precipitated by ammo- nium chloride and ammonia, dried, and weighed. Calcium and Magnesium.—These were precipitated in the usual manner. Organic Matter.—The black residue, insoluble in hydrochloric acid, was collected on a weighed filter, washed well with hot water, and dried at a temperature of 100°C. A weighed portion of this was placed in a platinum boat, and burnt in a current of oxygen ; a very slight residue, apparently ferric oxide, remained. The carbon dioxide and water were collected in the usual manner and weighed. The organic matter was almost entirely carbon: no hydrogen could be calculated from the amount of water collected, hence the car- bonaceous matter was apparently of the nature of anthracite. 488 Scientific Proceedings, Royal Dublin Society. To ascertain whether bituminous substances were present, the crushed mineral was treated with pure alcohol, which was first proved to leave no residue on evaporation. The liquid was filtered, the filtrate evaporated to dryness, and a light-brown residue obtained. A portion of this was moistened with a drop of hydro- chloric acid, and an addition of ammonium chloride, ammonia, and ammonium oxalate yielded a precipitate of calcium oxalate. Another portion, treated with nitric acid and subsequently with barium chloride gave a precipitate of barium sulphate. A similar result was obtained by treatment with pure ether. In neither Instance was any organic matter dissolved. These extracts by alcohol and ether prove the existence of calcium sulphydrate in the mineral; hence the odour when the mineral is broken. The ana- lytical numbers are the following :— (al) (2.) Per Cent. Per Cent. CO, . . 140-409 . . 40-409 CaO, . . 90°360 . - 94:920 FeO, .. : 0-342. : 0°290 CuOn |e inO: 0545 ee 0067 MeO; 4.) 0248 5. =» 0.249 SiON fare) ee lea gGr eee eT aOs Water, . 5 OriOG 5 5 Carbon, . a ASB ~7 27091 Sulphur, 5 MOS 99°935 99°331 1 Mean of three determinations. F 489.4 XLVII—MARBLES AND LIMESTONES. By G. H. KINAHAN,. M.R.I. A. [Read, February 16, 1887. ] [This Supplement to the Paper on Marbles and Limestones (vide ante, p. 372) is a list of some limestone quarries used of late years in public and private works, pro-- eured through R. U. Roberts, Esq., Commissioner of the Board of Public Works. Each detailed description, where possible, has the name of the Officer (in brackets) after it. This list being supplementary to the previous Paper, for the most part only refers to quarries not therein mentioned, except in those cases where, in connexion with recent buildings, the stones have been procured from some of the well-established quarries. | ANTRIM. CRETACEOUS. Drumnasol—Drumnasol Lodge. The rock locally called White Limestone (indurated chalk). This rock occurs all round the coast of Antrim: it is used mainly for lime; but sometimes it is used for dressing. It is too full of joints to look well, or to stand frost (W. Gray). ARMAGH. CARBONIFEROUS. Glasslough.—Used in the spire of Corporation-street and Carlisle Churches, Belfast; also in Robinson Villa, Cultra, Co. Down. ““Of a good high colour; works freely; durable” (W. Gray). t CAVAN. CARBONIFEROUS. Rocks.—One mile from Cavan.—Surface rock; no regular quarry. Used in the Masonic Hall, Cavan (built 1885), for wall- ing. The stone seems to be durable, and works freely. The dressings are of sandstone from Lisnaskea, Co. Fermanagh. 490 Scientific Proceedings, Royal Dublin Society. Ardhill.—Six miles south-east of Cavan.—School; built 1886. The local stone only used for walling and rubble; those for the dressings being procured from Crossdrum, Co. Meath. Mount Nugent.—Drumrora School; built 1886. The stone is only suitable for walling, and is said to be durable. The dress- ings from Ross, Co. Meath. CLARE. CARBONIFEROUS. - Bushy Park.—Ennis Courthouse, in entire building ; ; in Prison, for dressed work. Light colour; worked easily. Rosslevin.—Ennis Prison, used with the Bushy Park stone. Dark colour. Klfenora.—Knnistymon Church. Dark colour; worked hard (W. D. Williams). CORK. CARBONIFEROUS. Carriglass and Conna.—Carriglass School and Conna Glebe- house. Used for the rubble-work and quoins; but it is of too small dimensions for the sills of windows and doors (A. 7. Williams). Ballydaniel or Pothouse.—Ballydaniel Schoolhouse and Resi- dence solely built of these stones. The stone has also been largely used for heavy railway works, but is not suitable for sills, or in general for ordinary building purposes (A. 7. Williams). Cloyne.—School. The local stone runs in small sizes; and for ' large scantlings the Carrickacrump stone is used. Carrickacrump.—Yor the description of this well-known stone, see page 416. Mr. Williams points out that it has been exten- sively used in the Cork harbour and Haulbowline works. Ballintemple. —School. This stone is another that is well- known, having been made historical by Macaulay (page 416). Ballintubber (Kanturk).—Used in the dressings for the Church, Killarney, Co. Kerry. Light-coloured; a very superior stone. Mitchelstown.— Between the town and the workhouse. A marble; grey; a good working stone (J. Newstead). Kinanan—On Marbles and Limestones. 491 Boreenmanagh and Haulbowline Island, near Cork.—Reddish ; slaty character ; formerly used to some extent for chimney-pieces. About one mile south-west of Cork there is a vein about three or four inches thick in the ordinary limestone. Ballyclough, near Mallow.—Reddish; hard; slaty character; suitable for flagging ; formerly used a little for chimney-pieces. DONEGAL. MetamorpnHic CAMBRIAN ? on ARENIG? Dunlevey.—A marble, used in Dunlevey Church for dressing, walling, and rubble. In Glenalla Church, near Rathmullen, for dressed work in the windows, doors, and buttresses. Capable of good and fine work ; a superior stone, but cannot be raised in large sizes. Ballymon.—Sheephaven Coastguard Station. An inferior marble, used in the quoins, piers, and sills; very hard to work; very durable (J. Cockburn.) Gienree (“‘Cooskeagh Quarry ’’). South-west of Carrigart.— Whitish, grey-clouded, and greyish. A marble. Free and kind; durable; a good stone for inside and outside work. Used for the dressing of the Millford Union Workhouse ; dressing but- tresses and pulpit Glenalla Church; chimney-pieces Glenalla House; inside work Carrigart Roman Catholic Church. The fonts at Ramelton and Glenalla Churches were cut out of one block (J. I‘ Fadden). Barnes Lower (O’Donell’s Quarry). North-west of Kilma- crenan.—Greyish-blue; durable; a good stone for hammered, dressed, and rubble work. Quarry opened in 1846, when building Kilmacrenan New Church; since has only been worked for lime- burning (J. IM‘ Fadden). Carn Lower. North-east of Rathmelton.—Limestone; hy- draulic. [In this county, more than any other in Ireland, are the metamorphous limestones capable of being used for cut-stone purposes. See p. 417] CARBONIFEROUS. Ballyshannon (various places in vicinity).—Convent of Mercy, Ballyshannon. Hand-punched for facing and quoins; it works. 492 Scientific Proceedings, Royal Dublin Society. freely and well. Also for internal work, with sandstone, in the Belfast Banking Co. Buildings (J. Cockburn). DUBLIN. CARBONIFEROUS. Milverton (Skerries).—Balbriggan Coastguard Station. Used on the base of the octagon tower, sills, and dressings; also in Rockabill Lighthouse. A hard limestone, rather stiff to work (see description, p. 420). Howth.—Grey ; magnesian; makes good hydraulic lime. GALWAY. CARBONIFEROUS. Angliham.—Queen’s College; Model School; Parapet of the Tower of St. Nicholas’ Church, all in town of Galway. Used for the sills, quoins, and dressings ; works freely, and found durable. [In this neighbourhood (Angliham), as previously mentioned (p. 425), there are acres of most superior stone. As these lie in nearly horizontal beds, they ought to be invaluable, if worked on the American principle of cutting them by machinery in situ in the quarries. An enterprising Company might ‘‘run a big thing in stones’’ from the Port of Galway for the English market, more especially as the freights from all the west coast of Ireland are low, most vessels having to leave it in ballast. KERRY. CARBONIFEROUS. Livnaw.—Dominican Church, Tralee. A marble, close-grained, uniform texture, and capable of a high polish. Used for the moulded bases and the columns of nave. Bailylaggan (near Tralee).—St. John’s Church, Tralee. Used for the dressing in the new addition. Light-coloured, superior stone; free, durable; works out in large blocks. Castleisland.—Roman Catholic Church. A marble capable of a high polish. Colour, light red. Used in the piers of the chancel. KILKENNY. CARBONIFEROUS. Kilkenny (vicinity of).—Used in the Kilkenny Model School, Lunatic Asylum, Agricultural Museum, and other public buildings, Kinanan—On Marbles and Limestones. 493 for punched, chiselled, or moulded work. The stone is of a good grey colour; hard and durable; it flies well before the punch and chisels to a good surface, but not so fine as that of the Ardbreccan stone, or of that of Sheephouse, Co. Meath (If. Mellen). Ballykilboy and Strangs Mills— Waterford City, in the Govern- ment offices and public buildings. Granite and limestone dressings in both buildings worked freely (W. D. Williams). LEITRIM. CARBONIFEROUS. Carrick Klevy Station.—Carrick-on-Shannon Roman Catholic Church. Durable; squares well under the hammer. For chiselled work the stones were brought from Lanesborough and Creeve, Co. Longford. LONGFORD. CARBONIFEROUS. Creeve. Near Longford.—Used for dressings in the Roman Catholic Church, Carrick-on-Shannon ; in the Bishop’s Palace, and in the Asylum, Mullingar ; in the Crummy School, half-way between Carrick and Ballinamore, Co. Leitrim; and in Cloon- morris School, between Dromod and Newtown Forbes. Lanesborough.-—For dressings used in the Ballymahon School ; in the Roman Catholic Church, Carrick-on-Shannon ; and in the new Convent, Sligo. Ballymahon.—Very brittle; hard ; difficult to work; durable. Used for rubble in the National School. MAYO. CARBONIFEROUS. Moyne (Ballina).—Used for dressing and walling in the Roman Catholic Cathedral, Ballina, and in various buildings, both modern and ancient, as given in the descriptions of the Mayo quarries. “Works freely ; found durable; but weathers of a bad colour” (R. Cockrane). 494 Scientific Proceedings, Royal Dublin Society. MEATH. CARBONIFEROUS. Ballymadrin. Three miles from Ratoath.—Is fairly good and durable. Used in the walling of Ratoath Dispensary ; built in 1886. The stones for the dressing procured from Crossdrum. Stirrupstown. Near Crosskeys.—Hard, and only fit for scab- bled work. Used for walling in the neighbouring Constabulary Barrack. The stones for the dressings were procured from Cross- drum. Ross.—This well-known stone is very generally used for cut- stone purposes in various parts of Ireland (see description, p. 436). Crossdrum.—Another well-known stone (see description, p. 436). QUEEN’S CO. CARBONIFEROUS, Stradbally and Bailullen.— Maryborough Churches, Prison, and Asylum; Mountmellick Churches and Convent. In Abbeyleix Churches, with Slieve Bloom sandstone; both being used in the dressings (W. D. Williams). ROSCOMMON. CARBONIFEROUS. Carrowroe. Two miles from Roscommon.— Works pretty freely ; is durable. Used for walling and rubble in the new Con- vent, Roscommon. The stones for the cut-work were procured from Lanesborough, Co. Longford. SLIGO. CARBONIFEROUS. Ballysodare.—A. uniform stone; works well into mullions and tracery, and is durable. Used in St. John’s Church, Sligo, in the new east window, vestry-room, and organ-chamber (R. Cochrane), and in the Roman Catholic Church and Presbytery for both dressed work and rubble. KinaHnan—On Marbles and Limestones. 495 Scarden. Three miles from Sligo.— Hard and flinty ; durable. Used for rubble and the pitched faces of the walls in the Town Hall, Sligo. The dressings are of sandstone, from Mount Charles, Co. Donegal. Carrowroe. Two miles from Sligo.—Works pretty freely ; is durable. Used for walling and rubble in the new Convent, Sligo; the stones for the dressing being procured from Lanes- borough, Co. Longford. [In the hills to the north-east of this county there ought to be excellent limestone for all dressed purposes; as, however, there are no quarries opened, they send to great distances for stones for dressing and other cut works. | TIPPERARY. CARBONIFEROUS. Ballinillard.—Tipperary Town Churches. Appears to have worked freely. TYRONE. -CARBONIFEROUS. Omagh. YVicinity.—Used for rubble in the Military Barracks. The sandstone used for quoins and dressing is of an inferior qua- lity, being the stone known as the “‘ Red Beds” from the Gortna- glush quarry, near Duncannon, which is easily worked, but is not durable (J. Cockburn). WATERFORD. CARBONIFEROUS. Whitechwrch.—As dressings in the Churches, Dungarvan, and Lismore Castle. Shorough.—Lismore Roman Catholic Church, with sandstone dressings (W. D. Williams). SCIEN. PROC. R.D,S.—VOL. Y., PT. VI. oL 496 Scientific Proceedings, Royal Dublin Society. WESTMEATH. CARBONIFEROUS. Cullion. Two miles from Mullingar.—Rather hard and splintery for chiselled work ; very durable. Used in the Bishop’s Palace, and in the Asylum, Mullingar, for walling, rubble, and part of the dressed work ; but in both buildings most of the stones for cut purposes were procured either from Creeve (Co. Longford), or Ross (Co. Meath). soa] XLVITI.—ON THE LIASSIC FOSSILS OF M‘CLINTOCK’S EXPEDITION. By REV. DR. HAUGHTON, F.R.58. [Read, January 19, 1887.] Tue following correspondence throws further light on the fossils found by Sir Leopold M‘Clintock at Wilkie Point, Prince Patrick’s Land [lat. 76° 20°N.; long. 117° 20’ W.], and described by mein this Journal (vol. 1., pl. ix.) The letters sufficiently explain themselves, bearing in mind that I had originally stated my opinion that the fossils were of Jurassic age (probably Liassic.)—S. H. N.B.—These fossils were presented by Sir Leopold M‘Clintock to the Museum of the Royal Dublin Society, and can now be seen in the Science and Art Museum, Dublin. “‘GronogicaL AND Naturat History Survey, ‘¢ Musbum AND OFFICE, SUSSEX-STREET, OTTAWA, “5th November, 1886. ‘‘ Dear Srr—In endeavouring to work up a small general Geologi- cal Map of the Northern part of the American Continent, which may be published in connection with our reports, I have had frequent occasion to refer to your Appendix to M‘Clintock’s Voyage, which gives, I think, practically all the facts available for the northern portion of the Arctic Archipelago. ‘“T have not access to the earlier Papers in the Journal of the Royal Dublin Society, but presume the Appendix (edition of 1860) may contain a sufficient reswmé of the whole. ‘The point on which I take the liberty of addressing you, particularly at the present moment, is the character of the fossils described as Liassic, and figured in the Journal of the Royal Dublin Society, vol. i., pl. ix. ‘Ts it possible, in your opinion, that these fossils may indicate a horizon the same with that of the so-called ‘ Alpine Trias’ of the western part of North America? From the occurrence of a Monotis, western analogies would rather tend to this view of the case, which, however, the fossils themselves may be sufficient to disprove. If not troubling you 498 Scientific Proceedings, Royal Dublin Society. too much, I should be glad to have the benefit of your views on this sub- ject. The Fauna of the ‘Alpine Trias’—which occurs high up on the west coast—is well illustrated in Exploration of 40th Parallel, vol. iv., plates 10 & 11, and in Palzontology of California, vol. i., plates 3-6. “Yours truly, ‘“‘GEORGE M. DAWSON. “¢ Rev. Pror. 8. Haucuton, F.R.S. ‘¢ PRAGUE, “31st December, 1886. ‘My pear Barr—You must excuse me that I did not answer your kind letter earlier, but it had somehow miscarried, so that I received it about a fortnight later than the book. ‘The fossils about which you wish to have my opinion have aroused curiosity already on several sides, and about a year ago Professor Neumayer, of Vienna, sent me a number of plaster casts of the species, taken from the originals at Dublin, to ask my opinion about them. ‘As far as I can judge the matter, it seems to me that there cannot be much doubt that Ammonites M‘Clintocki is a Jurassic species, but rather of middle Jurassic than of Liassic affinities. This opinion has also been expressed by Neumayer in the Denksch. d. Kais. Acad. der Wissensch., Vienna, vol. i., Die Geographische Verbreitung der Jura Formation, p. (141), 1885, where the species is redescribed and figured. ‘The Avicula that has also been found at the same localities might be Triassic, but just as well it might be Jurassic, and there can be drawn no conclusion from that species. So, on the whole, the probability remains that in these high latitudes Jurassic beds are exposed. ‘The Triassic species described by White from Idaho, in his Contri- . butions to Paleontology, and later on in the 40th Parallel Report, are quite different things, and only the Avicula show at all any similarity. Such a similarity is, however, of no value whatever. “‘Very sincerely yours, “W. WAAGEN. “V. Batt, M.A., F.R.S.” [ 499 ] XLIX.—NOTE ON SUBMERGED PEAT MOSSES AND TREES IN CERTAIN LAKES IN CONNAUGHT. By A. B. WYNNE, F.G.S. [ Read, March 28, 1887.] THE object of this communication is to place before the Society a few observations upon what might be regarded as evidences of relative changes in the level or superficial distribution of land and water in the regions referred to. There are, doubtless, several cases besides those to which I shall refer, wherein peat bogs, with trees of a former period, are to be found permanently submerged in various parts of the country, and in present conditions totally different from those under which these trees and growths flourished. It will be sufficient, however, to take the instances of the basin of Lough Arrow, a few miles from Boyle, and of the River Garwogue, connected with and running from Lough Gill, through the town of Sligo. _ As far as regards present circumstances, the basins of both of these lakes are extensively encumbered with “ drift,” and the water is retained, in both cases, practically in rock basins: that is to say, river action has denuded the drift in the direction of outflow, and the surplus water escapes over beds of the solid carboniferous lime- stone of that country, lying in a nearly horizontal position, or undulating at low angles. In both cases the margin of the water is formed here or there by rock, drift, or the ordinary bogs of the country, the latter indicating, perhaps, a formerly wider extension of wet, swampy ground around these lakes or of their own proper areas. The River Garwogue leaves Lough Gill as a broad, sluggish stream, until its rock-bar is reached at Ardachowen. Thereafter the stream becomes more rapid, falling some twenty feet in the short distance between Ardachowen and the tideway, which enters the town of Sligo as far as the Victoria Bridge. ‘I'he last reach of the comparatively still water, just above Ardachowen—one of the most beautiful parts of that picturesque locality—is underlaid from side to side by peat, with numerous trunks of trees. It is plain SCIEN. PROC. R.D.S.—VOL. V., PT. VII. 2M 500 Scientific Proceedings, Royal Dublin Society. that the water here could never have escaped at a lower level than that of its present retaining rock-bar, so as to permit of the sunken forest trees having flourished in the air, without the supposition of earth movements having taken place since the peat and trees occu- pied the subaerial surface, movements which had considerably altered the position of the ground to be drained with regard to previously existing levels. Further seaward, along Sligo Bay, there are indications, in raised beaches, that an upward movement of the land took place ; and I found, many years ago, shells of the common sea mussel in a sand-pit, not far from the old coach-road between Sligo and Ballysodare, upon part of the high drift-covered ground lying between Lough Gill and Ballysodare Bay. In these cases the indication is of an elevation in recent times, which might here or there pond back the terrestrial water, but which must have had regions of singularly local intensity, if it can be at all supposed to have caused limited land spaces to become permanently submerged, as in the case near Ardachowen, on the Sligo river. Turning now to Lough Arrow, near Boyle, we find this to be a large lake, with irregular outline, four and a-half miles in length, by a mile to two and a-half miles in breadth, bordered by hog- backed hills of drift near its margin, similar hills forming islands within it, while it is surrounded by nearer, or more remote, moun- tainous elevations, suchas the Geevah Hills, formed of coal-measures, on one side, or the carboniferous limestone elevations of Knockna- horna and Kesh, on the other, or the termination of the pre-carbon- iferous Curlew Mountains towards the upper, or Boyle end of the lake. The lake itself is peculiar in having no rivers to supply it beyond the little brook from the Curlews, which empties itself into it at Ballinafad. The lake water is clear, and is probably largely sup- plied by springs, seeing that a considerable stream issues from the lake, passing over a rock barrier near where it starts, at Annagh or Ballyrush, and eventually reaching the sea at Ballysodare. Another peculiarity is that this large lake is at one point sepa- rated by a distance of only a few hundred yards from Lough Key, one of the lakes of the basin of the Shannon, with which that of Lough Arrow has no connexion. The shores of Lough Arrow, where not formed of drift, are im various places composed of peat, locally known as “ ‘The Black WrynneE—On Submerged Peat Mosses and Trees. 501 Banks,” particularly around the deeply-indented bay called Lough Brick, and at the lower end of the lake about Ballyrush, Annagh, and Castlebaldwin. Where this is the case the bottom of the lake is often also formed of peat with trees, while in other places huge masses of the local rocks washed out of the drift, like that called the “Rock of Muck,” on the Annaghcloy shore, may be seen, scattered over the bottom, through the clear water, when this is calm. Under similar circumstances, off the point of Aughanah, on the property of; Colonel Ffolliott, where the almost horizontal limestone comes to the surface of the lake, at the shoal called the “ Quarries,” or the “ Flag of Aughanah,” one can see, down be- neath the lowest level to which the water ever falls, the stools and stumps of large trees, so thickly accumulated in places, that when in the little strait between ‘‘ The Slab” and the point, boat- men exert more than usual caution to avoid “snags.’’ Most of the trees appear to be in their position of growth, with, in some cases, but little, if anything, intervening between them and the limestone slab on which they¢rest. Here again the case recurs that the lake could scarcely have stood at a lower level while its escape lay in the present direction, on account of its retaining rock barrier; and the conditions which would have placed these trees in their natural subaerial position, would require either the occurrence of earth movements of subse- quent date, or such a balance between the supply of lake water and its exhaustion by means of evaporation, that the water should be maintained at a lower level than at present, when of course the lake could have had no river outlet at all. : I have been acquainted with both of these lakes since child- hood, and I have repeatedly visited Lough Arrow at the season of the Ephemeral June Carnival of Salmo ferox. Lough Brick, of which I have spoken, was, within my memory, almost a small separate lake, partly surrounded, and nearly divided from Lough Arrow, by bog banks. Through a gap in these banks a boat could just pass; but the banks have since been almost entirely washed away—one islet?remaining near where the gap was, on both sides of which boats can pass freely now. On Captain Gethin’s property at Ballindoon, towards the other end of the lake, there is a small recess in the boggy bank of the lake, called “‘Poolnaperches.” Here a projecting promentory of 2M 2 902 Scientific Proceedings, Royal Dublin Society. peat bore some trees of considerable size. The promontory became an islet, and this has been washed away by the waves of the lake, on which I have seen a heavy sea often rise as rapidly as has been noticed in many other lakes all over the world (from Lough Gill to the Lake of Kashmir, or in the opposite direction). Now, taking this wasting by wave action of the boggy margin of the lake into consideration, in discussing the problem of the sunken trees with Captain Gethin’s steward (Sergeant Ross), whilst fishing off ‘Poolnaperches,” one day last summer, he seemed to me to hit upon an explanation which would account most satisfac- torily for the submerged forest trees of Aughenagh Point, and may be capable of a wider application in many similar cases of such submergence. We both observed that the stools of the old, as well as those of the modern, trees in these bogs, spreading their roots horizontally, retained their position thus until the boggy ground they grew in had been almost entirely removed. Deprived of the leverage which their stems—previously broken off—would have given, they had less to disarrange their natural pose; and thus, when some storm of greater force than usual acted, the retaining roots snapped or drew, and each water-logged mass sub- | sided to the bottom, settling upon its broadest surface, still in its natural position of growth; so that afterwards, looking down through the water, the trees would appear to have grown where seen, though entirely beneath the water of the lake, and associated in cases with a recomposed peaty deposit. As to the extent to which this action may have affected the shores of Lough Arrow, Sergeant Ross further stated that, under a particular effect of light, upon a stormy day, he had seen from Ballindoon House, which stands high upon one of the drift hills, a long, dark channel, reaching sinuously from the river at Bally- rush through the middle of the lake, between Ballindoon and Bell’s Island opposite. The lake, at its lower end, from one side to the other across this channel, appears to have both boggy banks and a boggy bottom. Hence it is not improbable the channel he saw may have marked a former bed of the river, before the bog on each side had been eroded away; and the definition of this channel may have been aided by the storm having disturbed the marly substratum that not unfrequently underlies our Irish bogs. I am not quite prepared to say how far these observations may Wrynne—On Submerged Peat Mosses and Trees. 3038 account for the supposed submergence of peat mosses, with forest trees, in all cases in inland lakes of the West of Ireland; but the explanation seems to be capable of affording a satisfactory solution of the question regarding Lough Arrow and the Sligo river, without making any unnecessary overdrafts upon possibilities as to local or considerable earth movements at very recent periods, and even though it may deprive the subject of a certain halo of mystery—if I may be allowed to adapt to this subject the well- known lines of our national Bard—it would supply some answer to an inquiry frequently made: ‘¢ When on these waters the fisherman strays, Or becalmed in his boat reclining, He sees the old forests of other days In the wave beneath him shining.”’ eT L.—LISBELLAW CONGLOMERATE, CO. FERMANAGH, AND CHESIL BANK, DORSETSHIRE. By G. H. KINAHAN, M.R.I.A., Erc. (Plate XII.) [Read, March 23, 1887.] Ir would appear that the process of formation, and the agents at work during the accumulation of the ‘ Lisbellaw Conglomerate,” have been a puzzle to those who have examined it, or rather to those who have published the results of their examination. It ought not, however, to be so hard to understand, as similar accumulations are due, not only to the artificial groynes erected on beach-lines, but also to natural groynes, as they occur on the south- east coast of Ireland. As the accumulations due to groynes, arti- ficial or natural, seem not to have been studied by those observers, it may possibly be allowable to give an epitome of the effects due to them, and their general characters. In general, artificial groynes are placed as near together as to form a continuous permanent shingle beach; and if they are ju- diciously erected, that is, raised plank by plank as they fill, much in connexion with the present inquiry cannot be learned from them. But in many places on coast-lines more or less isolated groynes have been put down to project individual portions of a coast-line, as is the case in places along the coast of Waterford. From such individual groynes we learn, if we follow the “ flow-tide” stream towards the groyne, that the accumulations gradually become wider, and, in general, the materials coarser, till at the groyne there is a “massive shingle accumulation. This seems to be invariably the case on the coast of Waterford, and also in various places on the English coast; but in other places, as presently mentioned, where the tidal-drift is solely a fine sand, the accumulation, although it will increase in bulk, yet the sizes of the materials will not do so. On the down-stream side of a groyne, like those on the beaches of Waterford, the accumulations will be small in dimension, and the material composing them much finer than those on the up-stream side. Kinanan—Lisbellaw Conglomerate, Co. Fermanagh, &c. 505 On the coast of south-east Ireland (Co. Wexford), as the normal drift of the county for a large part is fine sand, the drift due to the “ flow-tide ” current is in general of a similar character; and the big accumulations on the up-stream side of the groyne are in general sand. This, however, is not the case in the beach to the north of the Blackwater. Here, to the north-east, Cahore Point acts as a groyne, and south-west of it, at the head of the current from the Blackwater, there is a shingle beach. This is some- what like the “ Lisbellaw Conglomerate,” gradually down-stream becoming coarser and larger, but dying out before the extremity or point of groyne is reached. The reason for the ending of a shingle beach before it quite reaches the natural groynes is due to the “on-shore, or half counter-tide currents.” As this has been previously explained in different Papers already published, it is unnecessary to again repeat it. There is, however, a much more parallel accumulation in that of the Chesil Bank, Dorsetshire; although what is now taking place at the latter is on a much larger scale than the work done in Silurian times at Lisbellaw. The Chesil Bank travels eastward along the shore of Lyme Bay, with the “flow-tide” current accelerated by the prevailing winds from the westward, to be stopped by the natural groyne— Portland Bill. If this beach is followed from the west eastward, the accumulation gradually increases in size, and also in the di- mensions of the materials, till eventually it forms a mass of more or less coarse material to the westward of the Bill. But, on the other hand, in Weymouth Bay, eastward of The Bill, the accumu- lation is at a minimum, and of fine materials. As may be seen in the accompanying diagrammatic plan (Plate XIT.), the relation between the adjuncts of the Chesil Bank and, on a smaller scale, those in connexion with the “ Lisbellaw Conglo- merate,” is very similar, except that while the “ flow-tide” cur- rent in the first set from the west eastward, that in the Silurian sea must have ran south-westward. To the north-eastward of Lisbellaw, in Silurian times, there was a shore-line trending north-eastward, and immediately west of the village a spit of Ordovician land, somewhat like the Port- land Bill, while westward of this spit was a bay that may be compared with Weymouth Bay. 506 Scientific Proceedings, Royal Dublin Society. The Silurian beach that accumulated along the north-east and south-west shore-line has similar characters to that on the north shore of Lyme Bay; that immediately west of the north end of Lough Eyes, being of small dimensions and finer materials, while, as it is followed south-west, to Lisbellaw, it increases in bulk and the size of the materials. This beach, as it is now much over- lapped by the newer carboniferous rock, cannot be entirely seen ; but it seems to end suddenly before the point of the Ordovician land is reached, while westward of that spit of land the Silurian rocks are of quite a different character, being sandstones and shales. Thus there is more or less a very complete similitude between the two. As in each case there is a breach gradually getting larger and coarser, till it nearly reaches the point of the groyne, where it ends; while at the other side of the groyne the accumulations are at a minimum, and of a much finer character. 507 LI.—IRISH ARENACEOUS ROCKS—SANDS, SANDSTONES, GRITS, CONGLOMERATES, QUARTZ-ROCKS, AND QUARTZYTES. By G. H. KINAHAN, M.R.I.A., Ere. InTRoDvcTION, [Read, March 23, 1887. ] CONTENTS. GroLoGicaL ErirroME :— Cambrian and Arenig—Ordovician—Llandovery or Mayhill Sandstone— Silurian and Devonian—Carboniferous—Permian—Triassic—J urassic —Cretaceous—Tertiary—Drift—Sand and Grayvel—Glass, Antrim, Armagh, . Carlow, Cavan, Clare, Cork, Donegal, . Down, Dublin, Fermanagh, Galway, . Kerry, Kildare, County Historizs :— Arenig or Ordovician, Silurian, Carboniferous, Triassic, Cretaceous, &c.; Flints, Agates, Sand and Gravel, Glass, . : . 5 : é ° Ordovician, Carboniferous, Permian, Triassic, Sand and Gravel, . . 3 3 3 : 6 : 6 Carboniferous, Sand and Gravel, Ordovician, Carboniferous, Sand and Gravel, Ordovician, Carboniferous, Sand and Gravel, Silurian and Devonian, Carboniferous, Sand and Gravel, Cambrian and Arenig, Ordovician and Llandovery, Carboniferous, Sand and Gravel, . 6 C Ordovician, Carboniferous, Triassic, Sand and Gravel, . Carboniferous, Buildings, Sand and Gravel, Glass, 9 Ordovician, Silurian, Carboniferous, Fermanagh Series, Coal Measures, Enniskillen Quarries, Sand and Gravel, Cambrian, Arenig, and Ordovician; Silurian, Carbon- iferous, Sand and Gravel, Ordovician, Llandovery, Devonian and Carboniferous, Coal Measures, Sand and Gravel, Glass, Carboniferous, Sand and Gravel, . 508 Kithenny, « King’s Co., Leitrim, . Limerich, . Londonderry, Longford, . Louth, Mayo, : Meath, . Monaghan, Queen’s Co., Roscommon, Sligo, Tipperary, Tyrone, . Waterford, Westmeath, Wexford, « Wicklow, . Donegal Co., Dublin Co., Scientific Proceedings, Royal Dublin Society. County Historres—continued. Ordovician, Carboniferous, Flags, Sand and Gravel, « Carboniferous, Sand and Gravel, . 6 0 Arenig or Cambrian, Ordovician, Silurian, Carbonifer- ous, Sand and Gravel, . . 3 3 ¢ : Ordcvician, Carboniferous, Sand and Gravel, 5 : Ordovician, Silurian, Carboniferous, Triassic, Jurassic, Cretaceous, Flints and Agates, Sand and Gravel, . Ordovician, Carboniferous, Sand and Gravel, : : Ordovician, Carboniferous, Sand and Gravel, 9 4 Cambrian or Arenig, Ordovician, Silurian, Carbonifer- ous, Sand and Gravel, . : : Ordovician, Carboniferous, Triassic, Sand and Gravel, . Ordovician, Carboniferous, Fermanagh Series, Sand and Gravel, . 5 . : 4 5 : : 5 Lower Carboniferous Sandstone, Coal Measures, Sand and Gravel, . 9 . 0 3 : ° Ordovician, Silurian, Lower Carboniferous Sandstone, Coal Measures, Sand and Gravel, . Z : 5 Cambrian, Arenig, and Ordovician, Silurian, Carbonifer- ous, Lower Carboniferous Sandstone, Coal Measures, Sand and Gravel, . , 6 6 < Ordovician, Devonian, Carboniferous, Lower Carbon- iferous Sandstone, Coal Measures, Sand and Gravel, Ordovician, Silurian, Calp, Ulster type Calp, North of Coalisland; Fermanagh Series, Coal Measures, Sand and Gravel, . Ordovician, Devonian, and Carboniferous, Sand and Gravel, Glass, : 4 0 : 0 Sandstones, Sand and Gravel, Fi é 5 2 Cambrian, Ordovician, Carboniferous, Sand and Gravel, Cambrian, Ordovician, Sand and Gravel, Glass, Nores ADDED IN THE PRESS :— PAGE 572 576 578 580 681 584 585 586 591 592 594 596 599 600 604 610 614 615 617 619 619 Kinanan—On Irish Arenaceous Rocks. 509: INTRODUCTION. A stupy of the history of the Irish sandstone rocks is interesting, they seemingly having been the favourites with the early builders. The primitive inhabitants of the country appear nearly invariably to have utilized the hardest stone nearest at hand, so that in many places they used the granite erratics; but in such places where there were both granite and sandstone erratics, they seem to have chosen the latter; while, if the rock had to be quarried, it was nearly always the sandstone that was selected. After stone with mortar was introduced, at first sandstone still seems to have had the preference in the districts in which it occurred, except in a few places where there were good slate-rocks ; as these, in certain localities, were extensively used, and are still used, for architectural purposes. This, however, will be more par- ticularly mentioned in a subsequent paper on Slates and Clays. It may, however, be here mentioned that some of these slate-rocks, although producing good and durable work, were not at the same time capable of giving the fine and embellished cut-work to be found in the granite, limestone, and sandstone structures. Later on, as has been pointed out by Kane, Wilkinson, and others, the sandstone was superseded by limestone, the latter rock having been often carried for great distances into the sandstone areas. This probably was due ina great measure to the workmen, who had a preference for the stone to which they were accustomed. Various examples in modern time in support of such a supposition are on record. When the Scotch workmen were building Muckross Abbey, Killarney, about forty years ago, they ignored the ex- cellent limestone of the neighbourhood, and imported sandstone from Chester, that being the nearest place where they could get sandstone similar to that with which they were accustomed; and in different places, the engineers of the Ballast Board, when building lighthouses, have brought Dublin granite to the dif- fferent localities. This may be seen, besides, in various other places, at the West Sound into Bearhaven, Co. Cork—a locality famous for its good sandstone. Kylemore Castle, Co. Galway, was contracted to be faced with granite, and although the locality 010 Scientific Proceedings, Royal Dublin Society. is on the edge of the great granite tract of Galway, yet the con- tractor elected to bring the stone from Bullock, Co. Dublin—a stone he was accustomed to. We find also the same thing in earlier times. ‘The Normans, for dressing and other cut-stone purposes in their castles and cathedrals, brought from their native country, Caen- stone into England, while their descendants, the Anglo-Normans, did the same in regard to Ireland. ° [It seems to be the general opinion that there is no home stone at present in the market equal to the Caenstone for fine inside work; but during the late restoration of Christ Church Cathedral, Dublin, some of the old cut-stones (a.p., 1008) were found, which the architect seems to have insisted were ‘‘Caenstone.’’? But the builder (Mr. Sharpe) was not of this opinion, and, after considerable research, he was able to prove that the stone was procured ina once famous quarry at Eyebridge (?), about twelve miles from Glastonbury, Somersetshire. He visited the place, and the stones seem to have been brought from the quarries by a canal, the remains of which can be traced. From Mr. Sharpe’s practical knowledge he is convinced that this stone was used in Mellifont Abbey, Co. Louth; St. Mary’s Abbey, Dublin; and St. Kevin of Glendalough, Co. Wicklow—stones which in general are supposed to be Caen-stone. Mr. Woodward, the author of the Geology of England, in reply to inquiries, states :—‘‘ The stone you inquire about must be the Doultery stone, east of Shepton-Mallet ; used largely in the construction of Wells’ Cathedral and Glastonbury Abbey. ] But’ the pre-Anglo-Norman builders in Ireland, as already mentioned, as also many of the early Anglo-Normans, used the native sandstone. It is conspicuous in different places, as here- after mentioned, that although the local sandstone used in building of the earlier structures was good, yet all the later structures are built of limestone brought from a greater or less distance. Other reasons for the introduction of limestone may have been that the builders early understood the crushing stones were capable of bearing,' and were aware that if a column in a building was to be massive, they might use sandstone; while if the column had to be slender, and at the same time support an equal weight, limestone was preferable. This is illustrated, as pointed out by Wyley, in the small limestone columns of Jerpoint Abbey, Co. Kalkenny. They also must early have learned that limestone could be more finely, more easily, and more cheaply worked than the 1 Yet Wilkinson specially points out that some builders had no such knowledge, and illustrates instances in which buildings had failed through the want of knowledge as to the crushing the stone would bear. KinanwAan—On Irish Avenaceous Rocks. 511 ordinary sandstone of the country, many of the latter requiring the tools to be frequently sharpened. Although the strength of the limestone, and the facility by which it could be worked, may have led to a preference for it, it should also be remembered, that as the country became occupied by foreigners, the chief centre of the population—that is the towns— were principally in the plains, or the valleys, on the limestone areas, and the artificers, becoming cunning in the working of limestone, preferred to use it, even when they had to transport it a considerable distance. In many places, however, they had water-carriage ; that made the transport comparatively easy and cheap. Or the use of limestone may have been due to fashion. At the present day many rich men will only use a stone his poorer neighbour cannot procure. ‘This seems to have been a mania in remote ages as well as recently, and not without a certain value, as in many places the old buildings are pointed out as “ not having in them a stone to be got in the whole country,” while in modern times Rothschild’s French Chateau has brought him historical fame on account of the English stone and workmen used in its building. Elsewhere on the Continent, in America, besides in the home countries, buildings are pointed out, not for any architectural beauty, but solely to record that the stones in them were brought from a great distance, and at great expense. The mania for foreign stones appears to have been very pre- valent in Ireland at the beginning of the present century, as in the majority of the buildings erected between 1800 and 1840 the stones for the dressed work were imported. This is very conspicuous in Dublin, as hereafter exemplified in the list of places from which the sandstone used in its principal buildings was pro- cured. As previously pointed out, the early builders, in most cases, seem to have selected stones on account of their durability ; but at the present time there seems to be, in many cases, a running after stones—not on account of their durable qualities, but that they can be easily worked, and are therefore cheaper. [The Ballycastle stone, Co. Antrim, if it had been well selected, everywhere gave good and durable work; yet, at the present time, in the neighbouring towns it is in dis- repute, while inferior sandstones are used solely because the first-cost is less. This apparently is false economy; for although the first-cost may be less, yet the after 012 Scientific Proceedings, Royal Dublin Society. redressing, or painting, or otherwise doctoring of the stones induce expenses which in a short time eat up any little saving there may have been at the first in using inferior material. This can also be seen in different places in Dublin, which need not now be mentioned, as this subject will be alluded to further on. In general, sandstone now in use, except the Caenstone, does not appear to be capable of receiving as minute work as limestone. However, if we examine the old structures, we find in some of them beautiful and elaborate work, but in such cases the stones are much harder than those now in request. The exquisite door- way of Maghera Church, Co. Derry, cut in the local stone, is so durable, that the brushing of the tools can still be seen; but this stone would not now be looked at, being considered “too hard.” According to the records, as left by our ancient buildings, it would appear that the soft and more easily worked limestone, sandstone, and granite, are best for inside work; but if the work is to be exposed to weathering, the durability depended on the quartzose nature of the stones, they ranging in the following order—quartzose sandstone, quartzose limestone, and quartzose granite. The sandstones, apparently, taking in our climate the first place. There are, indeed, in a few places very quartzose granites and limestones of a high order, but they are exceptions to the general rule, as the majority of our best preserved old work nearly inva- riably is in sandstone. Outside these groups there are, however, some stones, but not very commonly met with, that show durable work, such as the Camstone, and some of the basalts. Quartzose stones, when dry, nearly invariably are difficult to work. ‘This is the case with the “ Park stone,’ Wexford, which, when worked in its “quarry water,” as exemplified in Roche’s Churches, turns out good work. Our ancestors may have under- stood this peculiarity in the stones, or it is possible they may have overlooked first-costs, and speculated solely on the subsequent durability of their work—they working in hard stones that now would be condemned. [Some sandstones which occur not uncommonly in the Carboniferous formation have a latent silicious or carbonaceous cement, and when newly raised, and in their quarry water, are soft and easily worked, but subsequently, when dry, they become as Kinanan—On Irish Arenaceous Rocks. 513 hard as a silicious grit. Some stones contract considerably during the drying, and stones of this class, before being used, ought to be given time to dry and contract, as otherwise they will dry unevenly, and show not only unsightly open joints in the work, but are also liable to cause uneven settlements. ] The cements of the sandstones are silicious, calcareo-silicious, and argillo-silicious. Usually in a contrary order they cut the more easily, while their durability is the reverse, except in some eases, that is, where they are micaceous, as many such stones, otherwise good, are not durable. Other examples of well-preserved sandstone carving, besides the previously mentioned doorway at Maghera, Co. Derry, are exem- plified in the doorway at Killeshin, Co. Carlow, cut in the local eoal-measure sandstone; in the massive and beautifully carved crosses at Monasterboice, Co. Louth, the stone being a clean- grained silicious sandstone. St. John’s Gate, Drogheda, in the same county, was built of mixed limestone and sandstone, and it exemplified the unequal weathering and durability, the latter being perfect, while the others have decayed considerably : it must, however, be allowed that the limestone was of a very bad class. The dressed work at Mellifont shows the durability of the sand- stone. In the latter the bad effects of mica is also exemplified, the micaceous sandstones that were used having sadly weathered. [The old ruins at Mellifont, during the late repairs under the Board of Works, had the rubbish removed, and, as pointed out by Mr. Lynam, County Surveyor, the sand- stones thereby re-exposed have rapidly weathered. This I have observed elsewhere, not solely in regard to sandstone—as the stones in different ruins, when exposed to the drying effect of the atmosphere, have rapidly decayed. This may be seen, as well as elsewhere, at Devenish, Lough Erne, where the re-exposed sandstones have suffered, and in St. Kevin of Glendalough, Co. Wicklow, where many of the old disentombed sculptured schist slabs have, in a few years, been greatly defaced. A cupped stone, now in ‘‘ Saint Kevin’s Kitchen,” when first raised, had all the tool markings; but these were obliterated by its being allowed to weather for a year. It may appear re- markable that stones, when in their natural saturation, that is, having their ‘‘ quarry water,’’ harden when exposed, while stones subsequently saturated, when dried, de- cay. To explain this, it may be suggested that the first water, that is, the ‘‘ quarry water,’’? was in combination with either silica or carbon, the mineral matter consolidat- ing as the water evaporated, while in the subsequent saturation, the moisture was solely water that had saturated the pores and other vacancies in the stone, thereby ab- sorbing the cement, and when this water with the absorbed cement was withdrawn, it left the stone more or less a friable mass—at least as far in depth as the absorption had effected it.] 514 Scientific Proceedings, Royal Dublin Society. In Boyle Abbey, Co. Roscommon, the stone shows excellent work; it is also durable, as in places it still retains the tool markings. [In America, and also in England, many stones, even when in the quarry, are sawn, or otherwise worked and sculptured by machinery ; very little work, however, of this kind goes on in Ireland. In some workshops there is sawing and planing ; but there does not seem to be a quarry in which the stones are cut in situ: while if a building is in progress you generally hear the hammer and chisel, and not the saw or plane, at work. However, saws, at least, were known to the early Irish builder as in many of the ancient structures the stones, especially sandstones, were sawn, not chiselled. The only instance that I can learn of saws being used to cut stone in situ, was in the Angliham marble quarry, Co. Galway, where, somewhere about the year 1860, Mr. Abbott erected a sawing-frame and engine; but when the block was about half cut through, the saws broke off, leaving, as Mr. Sibthorpe points out, a puzzleite for future geologists to explain how parallel narrow seams of oxide of iron occur in the blocks. | On reviewing the records of the different Counties, it is con- spicuous in how many places the sandstones or conglomerates were wrought into millstones. In some places there was a large trade not only for home but also for Hnglish uses. This trade, how- ever, seems to be altogether a thing of the past, as nowhere, as far as we can learn, is it now followed. The manufacture of stones for flax-crushing necessarily died out when the new modes of crushing, or manipulating, were introduced; but the decline in the demand for corn millstones seems to have been solely due to the repeal of the Corn Laws, which starved out the industry, and caused it to be abandoned. Since then the few stones required are imported, principally from France. At the once famous quarries of Drumdowney, Co. Kilkenny, there has not been wrought a pair of stones since 1875, and then only one pair. To some of the good class sandstones not now in request, as those near Thurles and Dundrum, Co. Tipperary ; Doon, Co. Limerick ; and others mentioned hereafter; public attention may be specially directed. [When the modern sandstone buildings are tabulated, it at first appears remarkable that so many, even in towns at great distances from one another, are all built of stones from one quarry. On inquiry, this appears to be due to their having been built by one contractor, or under the orders of one architect, the ‘contractor or architect having an interest in, or liking for, a certain stone. In Dublin, many of the recent Insurance (Offices have in them the same stones, they all having been built by the one contractor. But this is more conspicuous in the country towns, especially in the Banks—as the Kinanwan—On Irish Arenaceous Rocks. 515 offices of one company through a large range of country will all be built of one stone, while in all those belonging to another company a different stone is used; the stones often being brought from a distance, although better stones could be procured in the vicinity. | GEOLOGICAL EPITOME. The Arenaceous rocks range all through the different geo- logical groups. It is therefore expedient, before entering into detail, to give an epitome of the present state of Irish Geology. In this the classification of the groups is that adopted in the Taste or Srrata in the first Paper of this series on Irish Economic Geology (ante, “ Metal Mining,” p. 204). CAMBRIAN AND ARENIG. [These groups are so mixed up as to necessitate their being described together. ] From the latest fossil evidence brought before the public, which is, that supposed Arenig type fossils have been found in the gneiss and schist series at Fintown, it would appear that it is now incon- testably proved that the oldest rock in Donegal cannot be more ancient than Cambrian. Consequently, all the other similar rocks in Ireland, which some have called Laurentian, are probably of the same age or younger: that is, these metamorphosed rocks must be the equivalents of either the Ordovician, Arenig, or Cambrian. In 1862 Jukes, and in 1863 Sterry Hunt (after Laurentian rocks were proved to exist in Scotland), suggested the possible Laurentian age of the Donegal gneiss. In 1865 Murchison an- nounced the existence of Laurentian rocks in the Twelve Pins (Bennabeola), Connemara, Co. Galway; but immediately after- wards he withdrew this statement. In the Geology of Ireland (1878), and subsequently in various Papers read before the Royal Irish Academy, the Royal Dublin Society, and the Royal Geo- logical Society of Ireland, I pointed out that some of the meta- morphic rocks of Donegal, Antrim, Tyrone, Leitrim, Sligo, and Mayo were probably Cambrians, but possibly Laurentians ; while Dr. Hicks immediately afterwards suggested that the rocks called SCIEN. PROC. R.D.S.—VOL. V. PT. VI. 2N 016 Scientific Proceedings, Royal Dublin Society. by me Cambrians in the Co. Tyrone were possibly Laurentians; and this was followed by Dr. Callaway, who, in 1881, stated that patches in my Cambrians, Co. Wexford, were Laurentians. Sub- sequently came Dr. Hull, who seems to consider that all the tracts of highly metamorphic rocks, except those in Wexford previously claimed by Dr. Callaway, are of Archsan age (“ Laurentian Rocks in Donegal and Elsewhere in Ireland,” Trans. Roy. Dub. Soc., vol. i., ser. ii., p. 245). It seems remarkable that, while the rocks of the Mullet, in North-west Mayo, are included in this Paper, those of South-east Wexford should be left out, more espe- cially as the rocks in both localities are lithologically, microscopi- cally, and apparently stratigraphically similar, if not identical. The Wexford rocks claimed by Dr. Callaway to be Laurentians are, as he has described them, “ a mosaic of irregular fragments” (!) protruding into a tract of undoubted Cambrian rocks, as proved by their fossils. Nowhere else in the world have the Laurentian rocks appeared after this fashion, and I do not believe in their existence in the Co. Wexford, as the so-called Laurentians are only metamorphic intrudes of Igneous rocks and their associated tuffs, similar to the intrudes found elsewhere in every group of Trish strata, from the Carboniferous down to the Cambrian. [From Dr. Callaway’s Paper, “ Metamorphic and Associated Rocks South of Wex- ford’’ (Geol. Mag., Nov., 1881), it is evident that the writer had my memoir, but, at the same time, that the maps he was consulting were those published some quarter of a century prior to my being in the county or my examination of the rocks. How anyone could possibly imagine that my description was that of the obsolete maps is hard to conceive; more especially as on these maps are printed the dates of their publication and the names of the Surveyors. | The Galway metamorphosed rocks that are said to be Lauren- tians are undoubtedly the equivalents of the English Ordovicians, - as proved by the fossils in the unaltered portions. This will be more fully discussed when treating of the rocks of that county, while the supposed Laurentian gneiss of the Co. Donegal ought now to be disposed of, if the markings exhibited by Dr. Hull at the British Association Meeting, 1886 (Birmingham), are Arenig types of graptolites, which there now seems to be every reason for supposing; for if this be so, it unquestionably proves that the gneiss of Donegal, which is part of the same series, cannot possibly be more ancient than Cambrian: that is, these rocks must be the Kinanan—On Irish Arenaceous Rocks. 517 equivalents of the rocks of the groups suggested by me in 1878, in my Geology of Ireland. In the Co. Galway there are no rocks that can possibly be of Laurentian age, and the same thing may now be said of the Co. Donegal. It is, therefore, only sensational geology to say that in the intervening area (Mayo, Sligo, Leitrim, and Tyrone) there are Laurentians, more especially as the metamorphic rocks therein found are lithologically, and apparently stratigraphically, iden- tical with the rocks in Galway and Donegal. In the descriptions of those counties in which Laurentians are stated to exist more special details will hereafter be given. [As it has been assumed in some of the official memoirs that the existence of Archean rocks in Ireland has been proved, this subject has to be more promi- nently mentioned than would otherwise be necessary. This recent finding of Archean has been very sensational from the first. Up to the end of 1880 Professor Hull insisted that my classification was probably wrong, as the oldest rocks in ‘Connaught and Ulster were proved by the work of the Survey to be of Lower Silurian (Ordovician) age. But in January, 1881, when Drs. Hicks and Callaway suggested that some of my Cambrians were Arehean, quite suddenly Professor Hull ‘discovered Laurentians in Donegal and elsewhere in Ireland. After seven years of steady work in the Counties Galway and Mayo, I classified the older rocks, and subsequently traced them from Mayo into Sligo, Leitrim, Donegal, and Tyrone. The rocks of the Twelve Pins (Bennabeola), Co. Galway, are lithologically more similar to the Huronians of Ontario, Canada, than the rocks in any other place in Ireland. These are the rocks which, after Hozoon Canadense had been found in them, Murchison atone time suggested might be Laurentians; but the rocks in the same county, said by Professor Hull to be of Laurentian age, are evidently the youngest in this part of Galway, and in the westward portion of his area, where some of the rocks are very little altered, fossils possibly may at some time be found, for as yet they have not been properly searched. The rocks of the Slieve Gallion district (Co. Tyrone) and those of the Pettigoe district (Counties Fermanagh and Donegal) are partly like those of Ontario, but in them are not found the calcareous rocks so well represented in Benna- beola, Co. Galway. ‘There are also other rocks in Donegal that are partly like the Ontario rocks, such as those in the long tract embracing the Gartan Lakes (Loughs Beagh and Akibbon), and extending from them north-easterly by Lough Keel to the south end of Mulroy Bay—bits in which area are very similar to Ontario and Assina- boia, as seen north of Lake Superior. The rocks of Crann Mountain, Co. Wexford, are also somewhat like. As to the gneissose rocks, those of Galway, on the north of Galway Bay (which evidently are metamorphosed Ordoyicians), are lithologi- cally more like the Laurentians of the Dominion and the States than any other rocks in Treland, if we except some small patches of very limited extent in Mayo, and perhaps little bits in Sligo and Leitrim; but the gneiss and schist of Donegal lithologi- ally are very unlike, while apparently they are identical with the metamorphosed Ordovicians of the Schuyllkill River}valley, Pennsylvania (Mount Alban series, Hitch- cock, or Hudson series, Dana). In 1884 and 1885 the late Gerrard A. Kinahan, as previously mentioned (ate, p. 276), worked out an unconformability in central Donegal 2N2 ols Scientific Proceedings, Royal Dublin Society. between the later less altered rocks and the rocks of the older series—gneiss with their- associated schists (Gartan series). This unconformability in connexion with those previously found by Griffith to the north-east, in the Glen valley, and to the south- east, between the rocks of the Slieve Gallion district and those to the northward, com- bined with M‘Henry’s discovery of ARENIG FossILs in the ‘ Gartan series,’’ ought to- make the geology of at least Ulster quite plain ;—the gneiss and associated ‘‘ Gartan series” being the equivalents of the Arenig and Cambrian, while the later metamorphic rocks represent the upper part of the Ordovician and more or less of the Llandovery (May Hill sandstone or Passage beds), the lower portion of the Ordovician (Llandeilo) being absent in this province. ] The Cambrians or Arenig of Antrim (?), Donegal, Leitrim (?),. Sligo (?), Mayo, and Galway are all more or less altered into schist, gneiss, or even granite; and in these, at the present time, no fossils are recorded, except the recent finds in the rocks of the Co. Donegal. In Co. Galway they are found in the Ordovicians, but not in the underlying Arenigs or Cambrians (?). In places, especially in the Co. Donegal, some of the gneiss and quartzyte are very little changed, but in general all the arenaceous rocks are more allied to quartzyte or quartz rock (greisen) than to sandstone or grits. In Dublin, Wicklow, and Wexford, some of the Cambrians are metamorphosed, especially in the latter county, where, to the south-east, they are changed into gneiss and granite; but in places in them are quartzyte and quartz rock (greisen), and in the unaltered portion grits and sandstones. ORDOVICIAN and LLANDOVERY. [In the Table of Geological Strata, ‘‘ Mrrant Minine”’ (ante p. 204), the Passage: beds between the Ordovicians and Silurians are called “ May Hill Sandstones,’’ or “‘Llandovery.’’ In this Paper the latter name will be used. In Clare, Tipperary,. and south-east Galway, the Llandoveries are more nearly allied to the Ordovicians ; but in the Dingle promontory, Co. Kerry, they are joined on below the Silurians. | Many of these rocks are metamorphosed, as more fully men- tioned in the descriptions of the counties. Some of the grits and sandstones are capable of dressing well; but only a few of them are now in request for cut-work purposes, as the younger and: softer stones are preferred. They were, however, used in many of the early structures, and proved good and durable stones. They were also used in many of the Pre-historic megalithic structures, as they were capable of being raised in massive slabs. Kinanan—On Irish Arenaceous Rocks. 519 SILURIAN and DEVONIAN. [Except in south-west Ireland (Cork and Kerry), these rocks seem to be rather mixed up. The Devonian proper are the equivalents of the ‘‘ Lower Old Red Sand- stone,’’ or Passage beds between the Silurian and Carboniferous; but in many places, either stratigraphically or lithologically, it is hard to determine whether the rocks should be called Devonian or Silurian, as the lower beds of the Silurian (Smerwick beds), ‘the upper beds of the Silurian (Dingle beds), and the Devonian, are all, lithologically, ‘more or less identical. Their exact age, therefore, cannot be positively stated, except in such places as Cork and Kerry, where good continuous sections across the strata are exposed (see Kerry, p. 567). The lower rocks in the Silurian are usually reddish, or purplish, and over these are light-coloured fossiliferous rocks (shades of grey, green, and blue) ; but still higher up on these, in all the Irish tracts, there are rocks more or less similar to those below. Hereafter, in these descriptions, the reddish rocks will be called of the ‘‘ Old Red Sandstone type,’’ and the lighter-coloured rocks ‘‘ Typical ‘Silurians.”’ | In some of the new maps there has been a curious dividing up of the Silurians: this is especially conspicuous at Lisbellaw, Co Fermanagh. This is an interesting locality, as the condition under which the “ Lisbellaw Conglomerate”? accumulated, must have been very identical with what is now going on at the Chesil Bank. In Lyme Bay the “flow-tide” current runs from the westward ; and this current, accelerated by the wind-waves, carries the Chesil Beach along with it, to be accumulated in the bight behind, or west- ward of, Portland Bill, which acts as a groyne. Chesil Bank, or beach, becomes coarser and larger as it is followed east, till it forms a massive heap of shingle to the west of the Bill; but eastward of the Bill, in Weymouth Bay, there are finer accumulations. In Silurian times similar forces were at work in the neighbourhood of Lisbellaw. Running north-eastward from Lisbellaw was a coast- line, while west of the village there was a spit, or “ Bull,” of Or- dovician, and west of the latter a bay. Along the north-east and south-west shore the “ flow-tide” current ran south-west to Lis- bellaw, the shore accumulations increasing in magnitude and coarseness from the north-east towards the south-west. Thus we find at the north of Lough Eyes their conglomerates lying un- conformably on the Ordovician ; to the south-west is the massive “ Lisbellaw Conglomerate” accumulated against the Ordovician spit, that acted as a groyne; while in the bay, west of the latter, sandstones and shales accumulate. ‘Thus, there is a parallel in both places, as along the shore-lines the beach gets coarser and 020 Scientific Proceedings, Royal Dublin Society. larger down the current, till it comes to the groyne, when it accu- mulates, while westward of the groyne the accumulations are fine and small. On the map, for no perceptible reason, the “ Lisbellaw Conglomerate ”’ is made to belong to one? geological group, and the conglomerates of Lough Hyes to another. (Antea, p. 504.) In these groups there are in places sandstone: these, from the ancient structures in which they were used, are proved to be du- rable, and capable of producing good work; now, however, they are not much sought after, except for [local purposes, partly on account of their hardness, but more generally on account of lime- stone being found in their vicinity—the latter rock, in such lo- calities, being now more generally preferredjfor cut-stone purposes. Quite recently, however, in a few localities, they seem, in some measure, to be rising in public estimation. CARBONIFEROUS. The Carboniferous sea in the Irish area must have been of different depths, besides having in it islands varying greatly in dimensions. ‘he rocks deposited in the greater depths seem, for the most part, to have been arenaceous and argillaceous (Lower Carboniferous Sandstone and Shale, or Yellow Sandstone—Grifiith) ; but similar rocks were also afterwards ‘deposited as littoral accu- mulations on different geological horizons, even up into the Coal- measures ; therefore rocks of this class’are formed not only under all the hmestones, but also at different higher levels; they solely indicating different localities near ancient land in the Carboni- - ferous sea. After atime, in some parts the bottom of this sea seems to have grown up, or to have been moved up, causing the _ water to become shallow, and the conditions more or less like those at the first, so that sandstones and shale (Ca/p), somewhat like those at the original bottom (Lower Carboniferous Sandstone), were again deposited. : In Munster, the adjoining portion of Leinster (ing’s and Queen’s Counties), and in north-western Connaught (Mayo), nearly everywhere the Lower Carboniferous Sandstone occurs, margining” the older rocks, and separating them from the limestone. This, however, in general, is not the case in the rest of Ireland. In the Co. Wexford, to the north-west of the limestone, are such shore KinauHan—On Irish Arenaceous Rocks. 52k accumulations, while south-east of the trough there are none, ex- cept a few thin subordinate sandstones. West of the Leinster range, coming up from the south, these shore-rocks gradually thin out, and disappear south of Bagnelstown, not to be met further north except in small patches, such as at Newcastle, south-east of Celbridge (i/dare), where, we may suppose, there was a cape, alongside which a beach accumulated. In connexion with the Chair of Kildare, and the other small exposures of Ordovicians, that seem to have been islands in the Carboniferous sea, these shore-beds only occur at one side of the older rocks. Margining the large protrusions of Ordovicians in the central plain of Ire- land, the Lower Carbonifereus Sandstones are very continuous, while in the west of the Co. Galway, margining the older rocks, they are only found at Oughterard and Cong, in places that must have been bays. In western Mayo they are very continuous ; but in the rest of that county, in Sligo and Roscommon, they, in general, only occur to the south or south-east of what was the old land: the exceptions being the tracts north-west of the western end of the Curlew Mountains (north-east Mayo), and those north-west of the Ox Mountains (Co. Sligo). In the large south- west and north-east bay, between the Ordovician land, south and south-west of Lough Neagh, and the Silurian land, between Loughs Neagh and Erne, the Lower Carboniferous Sandstone, ex- cept in the north-east portion, was very continuous; but to the north of Lough Erne the Carboniferous Limestones, like as at Oughterard, were accumulated against an old cliff, sandstones only being deposited to the north-east, in the Termon River valley. In the tracts of Carboniferous to the northward (Donegal, Londonderry, and Tyrone), the shore-beds nearly invariably only occur to the north, as in the tracts at Donegal Bay, and westward of Omagh. At Feeny, however, westward of Dungiven, there is a small tract that seems to have accumulated in a small bight, or bay, where the shore-beds were to the southward; while in Fanad, west of Lough Swilly, is the small tract to which attention has lately been di- rected by Messrs. Hull and Cruise, in which the conglomeritic accumulations, as pointed out in a paper by Mr. Mahony, occur along the southern shore, and silts occur along the northern. [In the Lower Carboniferous Sandstones, and also in the subsequent ‘‘shore accu- mulations,’’ there are two distinct types, the lowest beds and those on higher horizons O22 Scientific Proceedings, Royal Dublin Society. adjoining the shore-line, respectively, being generally of reddish or purplish colours, and more or less coarse, often conglomerates. But not always so, as sometimes they are fine red shales. Above these, or farther out from the shore, the arenaceous rocks become yellow and grey sandstone, with more or less subordinate grey and bluish shales. This graduation generally takes place upwards, but not always; as in Galway and Mayo, near Oughterard and Castlebar, you can trace, along the strike of the bedding, conglomerates graduating into sandstones, and the latter into pebbly lime- stones. This also can be seen in various other places, as between Ballyshannon and Pettigoe, Counties Donegal and Fermanagh. Griffith was aware that sandstones of both these colours and textures were the basal beds, or ‘‘shore beds,’’ of the Carboniferous limestone; but, to meet the nomenclature of the day, he called the dark-coloured rocks ‘‘ Old Red Sandstone,’’ and for the light-coloured he introduced the term ‘‘ Yellow Sandstone.’’ Jukes, however, adopted a different course, as he included both together in his Upper Old Red Sandstone. Of late years this merely lithological distinction has again, in places, been intro- duced and given an unnatural value; so that we find on the new maps little spots called ‘ basins of Old Red Sandstone,’”’ solely because the rocks are of dark colour and coarser texture, while in other places exactly similar rocks are given their natural _ place: that is, they are grouped as the basal or shore beds of the Lower Limestone. In Western Mayo the rocks are placed in their true position; but this has not been done in Eastern Mayo, although, as pointed out by Symes, the classification into two distinct formations is “chiefly lithological’? (Geological Survey Memoirs, sheets 41, 58, and 64, page 14, and footnote by Dr. Hull). From the description of the rocks of Western Mayo it will be seen that, similarly as Griffith mapped them, these ought also to be ‘‘Old Red Sandstone’’ in the eastern area: that is, if there is ‘‘ Old Red’’ in the east of the county, it must also occur in the west, if the lithological character had been given the same value in both districts (Geol. Mem., sheets 39, 40, 51, 52, and 62, page 16). Griffith, and subsequently Jukes, were gradually bringing Irish geology out from the mists of the past, and it seems regrettable that it should now be plunged back again into the dark ages. | The fauna of the lower group (Lower Carboniferous Sandstone or Yellow Sandstone), although it was unsuited for the clearer and deeper waters in which the associated limestones accumulated, did not die out, but emigrated to the congenial littoral shallow waters, afterwards to again spread out in later times (Calp), when the accumulations and conditions were favourable. Thus, we find in the Lower Carboniferous} sandstones and shales, in the Littoral sandstones and shales, and in the Calp accumulations, that the rocks and their fauna are more or less similar. ‘There is, how- ever, in places in the Calp, a marked change in the accumulations, they being more or less calcareous, and even in places good lime- stone. Yet it is remarkable that in them, as in the shaly lime- stone of the Rathkeale district, Co. Limerick, the assemblage of the fossils is very similar to that of the Lower Carboniferous sandstone, in both being found many forms which are not to be met with in Kinanan—On Irish Arenaceous Rocks. 523 the intervening Lower or Fenestella Limestone. It might be said that, as the fauna creeps upwards in the littoral beds from the Lower Carboniferous Sandstone and Shale to the Calp, it should have crept up by similar means from the latter to the Coal-measures. This, indeed, may possibly have happened, if John Kelly’s classifi- cation of the Slieve Beagh series of rocks (Counties Fermanagh, Tyrone, and Monaghan), now favoured by Professor Hull, is correct, as these rocks, according to Baily, from paleeontological evidence, ought to be classed with the Lower Carboniferous Sandstones and Shale. At the same time, however, a very great change seems to have taken place when the major portions of the Coal-measures were accumulating, as they are not essentially littoral deposits, but must, at least in part, represent land and fresh-water accumula- tions. Griffith’s term, “ Yellow Sandstone,” seems better, as a general one, than “‘ Lower Carboniferous Sandstone,” as it does not express on what horizon the rock accumulated, while it suggests that the accumulations were marginal between the Carboniferous and older rocks; but the latter name seems now to be more gene- rally preferred. In south-west Munster the Carboniferous rocks are different, they being of the “Cork rypE” (Carboniferous Slate and Yellow Sandstone). These consist, in a great measure, of slates and shales, and they graduate downwards into the Devonian. The arenaceous rocks in them are below the Yellow Sandstone, and higher up, on different horizons, are the sandstones called by Jukes Coomhoola grits. In a few isolated places the Carboniferous slate graduates upwards into Ooal-measures ; but in the latter the grits and sandstones are of small or no account. Going eastward towards Cork Harbour, the Carboniferous Slate becomes split up and inter- stratified with limestone ; while further eastward it loses its indi- viduality, being replaced by rocks more or less of the “ CenTRAL IRELAND TYPES.” In the rest of Munster there are below, and also as littoral accumulations, the Lower Oarboniferous or Yellow Sandstone (Upper or Carboniferous Old Red), and still higher up the grits and sandstones of the Coal-measures. The Calp here (more or less argillaceous) is a middle division in the limestone, but having in places arenaceous calcareous rocks, or, as at Castle Lambert, Co. Galway, an impure coal seam. These, however, as sandstones, 524 Scientific Proceedings, Royal Dublin Society. are not of much account, except that in some places they produce good flags. Here it may again be mentioned that, in the lime- stones of the Calp of the Co. Limerick, there are many Lower Carboniferous Sandstone and Shale fossils. In Leinster and South Connaught the Carboniferous rocks are very similarly cireumstanced to those of North Munster, but in North-east Connaught and Ulster there are marked changes. In the south portion of Ulster and adjoming part of Connaught there comes in as a middle group in the limestone, or as indepen- dent groups or beds on different horizons, very pure arenaceous. rock; they, the Calp Sandstones, being quite distinct from the Yellow Sandstones below and the Coal-measures above. In these Calp sandstones, the ‘‘ Fermanagh sandstones,” and the Calp of the Ulster type, are procured the stones now of most note in the market. Asarule, the sandstones in the Coal-measures are con- sidered too hard, although in Leinster some of them are really good stones; while the Lower Carboniferous stones are often ignored. This, however, may be due to prejudice or some other cause, as near Thurles and Dundrum, Co. Tipperary, there are: stones said by the builders who have worked both to be better than any of the “ Dungannon stones” (Ca/p). At the present time the geology of South Tyrone, the asian north part of Monaghan, and the adjoining portions of Fer- managh seems to be mixed up. In this area, in Slievebeagh, Carn- more, and in the country to the eastward, there are sandstones and shales that Griffith mapped as Calp, because apparently they were identical with the Calp near Dungannon, in Co. Tyrone. John Kelly, however, stated that they belonged to the Coal-measures,. and called the highest group “ Millstone Grits;” and in the recently published maps of the Geological Survey, J oan Kelly’s classifica- tion has been followed, and they have been mapped as Lower: Coal-measures, the lower portion being called by Phillips’ local English name, Yoredale beds ; it being here divided into Yoredale sandstone and shales, while the upper sandstones are called Mili- stone Grits. [It seems very questionable if it is advisable to introduce English local terms into- Trish geology, more especially when they are inapplicable. Anyone who has compared. the Irish Coal-measures with those of England should be aware that the first ean only be compared with the ‘‘ Culm-measures’’ of Devonshire, while there is no similitude- Kinanan—On Irish Arenaceous Rocks. 525: between them and those of Yorkshire, where Phillips’ name was introduced. What English geologist would attempt to divide up the Devonshire ‘‘ Culm-measures”’ into Yoredale beds, Millstone Grits, and Coal-measures? The section of the Carboniferous rocks in Fermanagh and Monaghan (?) is different to any elsewhere in Ireland. Be- ginning below, there is—(1) Lower Carboniferous Sandstone; (2) Shales; (3) Dark- blue,. thin-bedded Limestone, with Shale partings ; (4) Amorphous Limestone (Fenestella Lime- stone) ; (5) Shales and Limestone ; (6) Sandstone ; (7) Shales ; (8) Amorphous Lime- stone under cherty Limestone ; (9) Sandstones ; (10) Shales ; (11) Sandstones, §c. The groups 9, 10, and 11 belong to the Lower Coaut-mzEasurzs, and 9 and 10, or Lower Coal-measures, may be called the Fermanagh series, after the county in: which they are- best developed, and not after ‘“‘ Yoredale,’’? where the rocks are different. Group !1 is- a portion of the Middle Coal-measures. Groups 1 to 4 are somewhat like the rocks of Munster; but groups 5 to 16 are of different characters and arrangement | This tract is interesting. If we begin to the eastward, we find sandstones and shales, with small coals, to the north of the Tyrone Coat-FieLp (Dungannon), where undoubtedly they belong to the middle or Calp division of the Limestone. In them, as pointed out by Hardman (G. S. I/.), there are fossils of Coal- measure types. South-west and westward of Dungannon are small tracts of similar rocks; also farther south-west—unorth-east, south-east, and south of Aughnacloy, all of which appear on the new maps as Calp sandstone ; but immediately after we cross. the Blackwater—that is, leave the Aughnacloy area, and go south- west—the apparently similar rocks in the district of Shevebeagh are mapped as Yoredale beds and Millstone Grits. Baily contends that these rocks ought to be mapped as Lower Carboniferous Sand- stones and Shales, as the fossils are of these types; while Kulroe states it is difficult to see any difference between the rocks of the Slievebeagh district and those of the Calp (G. S. I/.). In these rocks of this Fermanagh series (as it will hereafter be called) and in the acknowledged Calp the sandstones are very similar, the ‘‘ Dun- gannon stone” in the Calp and the “ Lisnaskea stone” in the Fermanagh series being of one class and equally in repute. In the Calp sandstones north of the Tyrone Coal-field and in the Lis- naskea quarries have been found similar large fossil trees, while the assemblage of fossils in the Fermanagh series, according to Baily, is that of the Lower Limestone Sandstone and the Calp, and. is not like that of the Coal-measures. But as the section in South-east Fermanagh, between Lisnaskea and Slievebeagh, is identical with that of the known Coal-measures in Belmore and Cuilcagh (West Fermanagh), it is evident that these rocks of the- 526 Scientific Proceedings, Royal Dublin Society. Shevebeagh district must, at least in part, represent the Lower Coal-measures, although they are so different lithologically from those of the Tyronr Coat-Friexp to the eastward. But it must be remembered, as pointed out in my Geology of Ireland (1878), that in the Coal-measures of North Con- naught there is a marked change, the lithological characters of the Lower Measures being very different to those elsewhere in Ireland ;. as below, immediately above the Upper Limestone, a more or less thick group of sandstones appear, with subordinate argillaceous and calcareous strata; while in the Middle Measures there are three coals, one of value. In Tyrone also, but not else- where, are found workable coals in the Middle Measures. In North Ulster there are other peculiarities, as the rocks appear to have accumulated in bays or seas of limited extent ; and the different groups of rocks, elsewhere capable of being separated, become mixed up; the red and yellow sandstones, the different types of limestone, and even shales, identical, except in fossils, with those of the Coal-measures, being more or less mixed up. ‘These rocks, which may be called the Unsrer Catp rypPE, occur nearly altogether north of a line drawn from Lower Lough Erne along the Silurians of the Fintona district to Lough Neagh, excepting the rocks near Cookstown, Co. Tyrone, which are south of this line, and have some characteristics allied to those of the ““ Ulster Calp type.” The upper group, or the Coat-mEasurgs, has, as Lower Measures in East Ulster, some five hundred to seven hundred feet thickness of shale, over which, in the Iiddle Measures, are- naceous rocks predominate, while in the Upper Measures there is a mixture of arenaceous and argillaceous rocks, with coal. But in North Connaught, and the adjoining part of Ulster, there are im- mediately above the upper limestone more or less arenaceous strata, and above these shales, and these combined represent the Lower Measures. Above these are the Middle Measures, which are for the most part arenaceous, but having in them workable coals. In Eastern Ulster (Tyrone), although the strata of the Coal-measures occur in a very similar arrangement to those of Leinster and Munster fields; yet in the Middle Measures there are valuabl coals. At the present time the Coal-measures Sandstone of Ireland, Kowanan—On Irish Arenaceous Rocks. K276 except those of the Fermanagh series, are not in repute, although, as displayed by some of the ancient structures, they are capable of good and durable work. This will be hereafter mentioned in connexion with the respective counties. In the West Munster Coal-fields the stones are nearly inva- niably hard and chippy, and although they can be dressed on the face of the beds, they cannot be worked across, as they chip and fly at the edges. In places they produce excellent flags, but to give good joints, the edges of them generally require to be sawn, as they chip on the face if dressed. These flags, if the edges are sawn and the surface planed, make a beautiful even flooring. In the Hast Munster (Tipperary) and Leinster Cval-fields there are some good stones for dressed work, as hereafter mentioned. In the Tyrone or Ulster Coatl-field some quarries have been worked, but the stones are not in request, as better can be procured in the ad- joining calp; while in Monaghan and Fermanagh are the well- known Lisnaskea stones; and in the ConnauGcut CoAL-FIELD there are stones said to be good; but as they are very inaccessible, and far from any market, very little seems to be known about them. Good flags, however, have been sent from this field into the market; at one time extensively. [The flag trade has peculiar features. About fifty years ago, according to the records left by Lewis, the footpaths of very few towns were flagged; but just at that time it seemed to have become the fashion, and the different towns were looking out for places in which to procure flags. This general demand caused many flag quarries to be opened up, and in some places instituted a large industry. But after the towns were flagged the demand decreased, some of the quarries having been scarcely worked since, while in those places where a trade had been for a time established, it has since died out, on account of asphalt being now more generally used than flags. However, there seems to be a slight reaction in the favour of flagging, as the asphalt in many places seems to be getting into disrepute. In various places in Ireland there are large flag quarries, where hundreds of hands were employed, that now are quite idle. Belgium sends into the market a large quantity of chimney-pieces, made of flag very like that of our Coal-measures; and fifty years ago a large trade in somewhat similar work was carried on at Killaloe, Co. Clare, and other places, the Killaloe chimney-pieces ‘‘ being in very general request.’’ Now a “‘ Killaloe chimney- piece’’ is not heard of, the trade having totally died out; while in the Moneypoint flag quarry, on the Lower Shannon, from which the flags came, instead of hundreds of workmen, you will rarely find half a dozen. Very superior work of this class used also to be turned out from quarries near Mountmellick, Queen’s County, and other places hereafter mentioned. The Belgians do their work ‘‘by the piece.’? A man is. paid so much for the job ; and he, his wife, and his children, down to a child that can scarcely walk, are put todo something, at which they work early and late. In Ireland, 628 Scientific Proceedings, Royal Dublin Society. however, such things are nearly invariably done by days’ work, in limited hours, con- sequently in one case the work can be done much cheaper than in the other, and the goods sent into the market much cheaper. The Belgian chimney-pieces now in the market are enamelled, which was not the case with the Irish chimney-pieces formerly in the market. It is for a similar reason—‘‘ cheap labour’’—that the Belgian red marbles have cut out, in the English markets, the ‘‘ Irish reds,’’ although the latter are superior. | PERMIAN. In a few places there are conglomerates and sandstones said to ‘be of this age; but in some places those supposed to be Permian are probably Carboniferous, and in others probably Triassic; they being the upper beds of the first, and the lowest bed of the other. TRIASSIC. The sandstones, or Redfree, as they are generally called, are free-working stones, and capable of producing fine work. They, however, except in a few places, are not durable, also most of them are liable to discolour; and although the stones may be selected with great care, yet nearly always some will become unsightly, spoiling the general effect; still bwldings with dressing and quoins -of these sandstones, and walling of limestone, or even basalt, have an effective appearance. Exceptions to these general characters are the stones of North Down, Scrabo, and Dundonald, as from these, especially the latter, stones of good repute are procured. The hard texture of these may possibly be due to the associated igneous rocks. JURASSIC, CRETACEOUS, EOCENE, AND DRIFT. In the groups of strata later than the Triassic the few sand- stones that occur are of little account for building purposes, they nearly invariably being too frail to be thus used. Some of the drift sandstones are only in course of formation at the present time, sand and gravel being cemented together by water percolating through them, charged with carbonaceous, silicious, or ferriferous matter. Kinauan.—On Irish Arenaceous Rocks. 529 SAND AND GRAVEL. In a few of the older rock groups there are sands that occur as rotten or disintegrated portions of beds of sandstones or other rocks. These, however, are comparatively rare, as the principal places in which the sand and the gravels are found are as portions -or beds of the Drift, Alluvium, and Dilucium. Under the latter cir- eumstance they often occur in considerable quantities; in some places younger drifts being made up nearly altogether of them. They have been used in the manufacture of glass, for building purposes, for manure, and many of the gravels for road metal. The coast sands, that is, those found in the tracts and dunes of AMolian sand, which occupy such long and sometimes wide tracts in places round the coast-line, seem capable of being made much ‘more remunerative than they are at present. Jf no other use can be found for them they ought to be planted, as has been done in ‘Gascony, and other places on the wild coast of the Bay of Biscay. Their frail nature, and tendency to travel, has given them a bad name; but experience in France proves that they will grow fir timber profitable for {turpentine and pitch; while after the woods are established, the shedding of the leaves and the roots of the trees fix the sand so, that portions, if judiciously cleared, can be converted into excellent and remunerative tillage-land. It should, however, be mentioned, that in Ireland, in a few places, by judicious management, they have been made more or less remunerative. Many of these Atolian sands, especially when Calcareous, ought to be extensively used as manure. Some of them were utilized for this purpose formerly ; but of late years nearly all are ignored, as the artificial manures can be more easily procured, although even- tually at a much greater cost. There are other sands, also gravels, valuable as manure ; these will be mentioned in their respective counties. For the ancient bronze castings the mould in general seems to have been cut in sandstone, as many such moulds are found in the old settlements. In modern times they are generally made of sand. As to where the sand used for these moulds in the different foundries was procured we can give very little information. Adjoining the Arklow Chemical Works a barricade of upright timbers was erected to prevent the mass of At¥olian sand, during 530 Scientific Proceedings, Royal Dublin Society. east and north-east gales, from drifting and blocking up the quay and entrance to the works. ‘Through the fine joints of the timbers in this barricade a minute silicious sand drifted, and this has been found to be highly valuable for use with the saws of the: marble and other stone-cutters, it being sent to Dublin for these: purposes. Ireland seems to be remarkably deficient in “sharp- sand ’’ suitable for stone-cutting, most of it being imported. Here, therefore, there appears to be a suggestion as to the introduction of a new industry; for in different places along these Arklow ffiolian sands, or on the other accumulations of silicious sand along the south-east coast, similar barricades to that at Arklow might be: erected, and the fine sand drifted through them sent into the market to meet the present deficiency. Guass.—As to the former Glass trade, we have the records of when it was established ; but in most cases it is impossible now to find out where the sand came from. In some cases, however, we know that Irish sands were used. As glass beads are common as Irish antiquities, they seem to suggest that in old times our sands, in different places, were used in the manufacture of glass. In different cases, as will be hereafter seen, the qualifications. of a stone is a vexed question; as what one authority approves, another disapproves. Where the opinions are conflicting, the names of the authorities are given. In many cases this disagree- ment may be more apparent than real, as in most quarries there are different classes of stone—one sent to one market, another to another—so that the opinions expressed, although apparently in reference to one and the same stone, may not be so. Also, in some of the quarries all the good stone, once in good repute, may be now exhausted. Fifty years ago all the builders knew the ‘Slush stone,” Co. Fermanagh; while if you ask the men of the “present day their opinion of it, probably they never heard of it, its day having long since passed away, as the good stone in it has now become too expensive to work on account of the “off baring.” Necessarily, in a Paper of this kind, some of the statements may require modification, or other correction; while there may be quarries left out of the lists that ought to have been mentioned. Such omission, however, will, as far as possible, be corrected hereafter in an Appendix. Kananwan—On Lrish Arenaceous Rocks. 53l The descriptions are given in the counties, arranged in alpha- betical order, under the different Geological groups, as adopted in the Table of Strata in the Introduction to the Paper on Merar Minine (ante, p. 204). The records of the Sands and Gravels are not as full as they ought to be; but on these subjects it is hard to get satisfactory information, as most previous writers have, in a great measure, ignored them, except in general description, from which very few details can be learned. In the compiling of this Paper, as in the previous one on “‘Marbles and Limestones,’ I have necessarily been greatly in- debted to Wilkinson’s standard work; and of all stones mentioned by him his descriptions are given, except that his arrangement is modified to suit mine. I have also consulted Lewis, and the Memoirs of the Geological Survey, the quotations from the latter being initialed G. S. 17. But the information from Lewis cannot be specially acknowledged, it being too general, and having after- wards to be verified. I have also received valuable information from the Officers of the Board of Works, through Mr. Commis- sioner 8. U. Roberts; some of the County Surveyors, and various private individuals; whose aid, when possible, has been acknow- ledged ; but in many cases this was impossible, as the same in- formation was received from different sources, or the different information about one place had to be incorporated. COUNTY HISTORIES. ANTRIM. AReENIG (?) or Orpovictan (?).—'To the north-east of the county, principally in the barony of Cary, now better known as the Ballycastle district, is a considerable tract of metamorphic rocks, probably the equivalents of either the Ordovician or Arenig. Among these are some rocks that still in part partake of the nature of grits or quartzyte, but none of them are eminently suitable for cut-stone purposes. SCIEN. PROC. R.D.S.—VOL. V., PT. VII. 20 O32 Scientific Proceedings, Royal Dublin Society. Srrur1aAn.—On the east coast, in the neighbourhood of Cushen- dun, there are massive conglomerates associated in places with sandstones. ‘These rocks seem evidently to be a portion of the littoral or shore beds of the Ulster and Connaught Silurian Basin, heaved northward by the faults of the Lough Neagh valley. In places some of the conglomerates can be raised in blocks very suitable for piers and other rough work, while some of the finer beds can be used for cut-stone purposes. “‘ The fine beds at Cave House were at one time largely quarried, and shipped to Belfast for building purposes” (G. S. JL). CarsonireRous.—Near Benmore, or Fairhead, is a small tract of Ulster-type Calp, where there were some workable beds of coals, for which reason it is commonly known as the BaLiycAstLE CoaL- FIELD (see Antrim, “ Metal Mining,” ante, page 264). Here are some stones of great durability ; but as some beds are better than others, they should be selected with care and judgment. The best stones are whitish or creamy, finely granular, nearly entirely sili- cious, but slightly micaceous, and having a few iron spots. Some beds, although otherwise good, are liable to discolour. Ballyory Quarry.—Three miles from Ballycastle, where there is a railway station. Wilkinson thus describes the stones: “ Best stone very fine-grained and friable, almost entirely silicious- grained, slightly micaceous, and with a few iron spots; works easily and well. In selecting the stone, blocks showing iron spots should be rejected.”’ But Mr. Gray says: “ Irregular in texture, gritty, and in many beds soft. Carefully-selected stones stand exposure ; but as a rule it is not a good stone.” In colour it is pink-white or creamy. Of the latter there are two kinds, one coarse-grained and very strong, admirably - suited for bridges, piers, and other strong work. It has been used for many of the bridges in the Co. Antrim, including the via- duct, in places 90 or 100 feet high, over Glendun, in the latter having been used in all the most particular and trying parts. This viaduct has now been a great many years built, and there are not the slightest symptoms of decay in any of the Ballycastle stones used therein. The Ballycastle bridge, after it was carried away, was rebuilt in 1852 with this stone, and the chisel brushings are now nearly quite fresh. Here the durability of the stone has been considerably tested, as during spring-tides they are wet, and KinaHaAn—On Irish Arenaceous Rocks. 533 at other times, especially during the heat of summer or in frost, quite dry. ‘These tests the stone has stood well. The second is a fine stone, taking a beautiful edge, and suitable for the finest work. It can be worked on any surface, where it is equally durable, as it does not require to be laid on its own bed. The spire of Ballycastle Church, built in 1756, is of this stone, and has remained perfect ever since. It was also used for dressing, facing, and other purposes at Doon Hill, Co. Londonderry, built by Lord Bristol, then bishop, in 1783 to 1785, and the cornices and fine work are still quite fresh. In Belfast it contrasts favour- ably with other sandstones. The spire of the Charitable Institute, built 1774, is of this stone, and also the portico of St. George’s Church. The latter was originally in Lord Bristol’s palace of Ballyscullion, and was removed to Belfast after the palace was burnt down. These have shown no signs of decay, while English, Scotch, and other stones in the Belfast structures have had to be painted or re-dressed. This stone was also used for the dressings in the Grain Market; and in Coleraine for the inside dressings ain the church. It was formerly used largely for Tombstones, but at present only a little. In Ballymena, the nearest large town, it is not now used, as the Scotch stones are cheaper. The Dungannon stones, Co. Tyrone, are, however, still cheaper, costing 4s. a ton, while the Scotch is 10s. ‘The spire and dressings of the west church are of the Dun- gannon stone, while it is also generally used for window-sills and such like. The quarries about Dungannon yield different stones. From Bloomhill come the stones most used and preferred in Bally- mena; but in Belfast they prefer the Ranfurly and Carlan stones. Fair Head.—Red. Works freely ; durable; used throughout in the Ballycastle Coastguard Station. (J. Cockburn.) Triassic.—This occurs more or less as a fringe, margining the later rocks to the eastward. It is commonly known as “ Red Free.”’? This sandstone works easily and finely, but almost inva- riably it is very friable and weathers quickly. Some of the hardest, stones are quarried in the vicinity of Red Bay and at Bank Head, near Larne. There are also various quarries in the valley of the Lagan. For Belfast the ‘‘ Red Free” is usually brought from Scrabo and Dundonald, Co. Down, where the stone is much harder and 202 oo4 Seientifie Proceedings, Royal Dublin Society. better than in the Co. Antrim. The principal sandstones used in Belfast are given under Co. Down. Creraczous.—In places, under the White Limestone (Indurated Chalk), are sandstones, supposed to represent the Hnglish Green- sand. These are locally known as mulatto stones. They oc- casionally are firm enough to be used as building stones; but in general, as pointed out by Wilkinson, they are “too friable and loose-grained to be suitable for good work.’’ Du Noyer has stated that, in the Cretaceous rocks of Colin Glen, there are some fine-grained, thin-bedded sandstones, which were used for litho- graphic purposes. Fruints.—The flints in the White Limestone, as mentioned in the Paper on “ MarsiEs anp Limestonss” (ante, page 413), were, in prehistoric times, largely used for the manufacture of arrow- heads and other implements, being exported into the neighbouring counties. In later times they were wrought into gun flints. So. late as 1840 there was a large export of flints from the Whiterock quarries, near Dunluce, to supply this trade and the Staffordshire potteries. Since then flints have been exported from Glenarm and other places for the English potteries and that at Belleek, Co. Fermanagh ; while the Eglinton Chemical Co. grind up the flints, and from the powder manufacture silicious bricks, that can stand any heat, and are in great request for the lining of steel furnaces. AGatEes.—Some of the flints on Rathlin Island are ribanded, and appear capable of producing beautiful “ onyx” and “ sardonyx,” if we may judge from the specimens in the Science and Art Museum, Leinster House, Dublin. As is well known, the old Greeks and Romans, who ranked agates high among their precious stones, in- vented a method of staining them. This for years remained a secret with the Italians, till an Italian and German, at one and the same time, both agate cutters, got into trouble in Paris, and while in prison together the Italian cummunicated the secret to the German. Since then the great trades in agates at Oberstein in Germany has sprung up, the major portion, if not all, the rough agates being imported from the La Plata River, America, the German quarries falling into disuse after the American cheaper supply came into the market. As far as we can learn, there seem to be no records of these Rathlin agates im Leinster House as to whether they are the KinaHan—On Irish Arenaceous Rocks. » O39 stones as found iz situ in the island, or if rough agates that afterwards were stained. In the Ballinascreen Hills, northward of Draperstown, Co. Londonderry, the “chalk conglomerate,” the basal bed of the Hocene, is in a great measure made up of broken flints, that were baked by the subsequent over- flow of basalt. In all the naturally stained agates I have seen the colours developed are shades of red, they being of the “carnelian” type, as may be seen in the flint fragments i s¢éw, and in the flint implements found in the valley of the Lower Bann, Co. Londonderry. Symes states that the agates of this class are common everywhere in the North of Ireland, where the basalt lies direct on the Hocene basal conglomerate, that is the rock due to the breaking up and re-arrangement of the surface of the lime- stone. He suggests that the staining is due to an iron solution, combined with the baking due to the overflow of hot basalt. ‘The process must be more or less allied to the artificial production of “‘carnelians;”’ but as the natural ones are more opaque than the artificial, an iron solution, as suggested by Symes, may be present. At present we are unable to say if the Rathlin “ onyx ”’ and “ sar- donyx,” as seen in the Science and Art Museum, Leinster House, Dublin, have been procured in situ, or if they were afterwards artifically stained. The stones, however, whether naturally or arti- ficially stained, give such good results, that they ought to be worth looking after; not, however, for a trade in the island in cutting and polishing, for labour is so cheap in Germany that it would be impossible to compete therewith ; but the raw material might be exported to Germany, as it is at the present time from the River La Plata. [In the ‘‘Gronoey or Inp1a,”’ Pt. iii., pp. 506, &c., Ball gives an interesting and exhaustive account of agates, and how the colours are produced. Many of the raw Indian agates are identical with those from Antrim, while their origins seem to be very similar, both being baked by overflow of basalt. Besides being used for orna- mental purposes, they are largely manufactured into burnishers. | Sanp anp Graver.—As a subordinate adjunct of the flows of Eocene basalt, Lewis records a rough tripoli found at Agnew Hill. In various places in connexion with the Drift, the alluvium and the diluvium, are sands and gravel. In the drift near Ballycastle O36 Scientific Proceedings, Royal Dublin Society. there are valuable sands, due to the weathering of the sandstones of the “ Ballycastle Coal-field ”’ (Ca/p), mentioned under Glass here- after. Red sand suitable for foundry purposes is procured in the valley of the Lagan, and exported from Belfast. In the valley of the Bann is a deposit of Diatomyte, or “Diatomaceous clay.” This, although properly a sand, is so fine that it has come to be regarded as a “clay,” and the notice of it in this and other counties will hereafter be given in a subsequent paper on “Slates and Clays.” For mortar, excellent »iver-sand is procured from Lough Neagh,, near Antrim. Near Lisburn and Ballymoney there is pit-sand ; but as the latter is mixed with clay bands, it has to be carefully raised. At Hollywood there is good sand; at Ballycastle, as already mentioned, there is also good sand; and at Larne there is sea-sand on the beach. In some places on the coast-line there are Molian sands, that are carted inland, to be used as manure, especially on peaty soil. At Red Bay the Atolian sands bring large rents, they being rented and cultivated by the inland farmers for potatoes, to change the character of the seed, a worn-out stock being renovated after it has been grown in these sands. Guass.—In the neighbourhood of Ballycastle there is an excel- lent sand, due to the weathering and washing of the Carboniferous. sandstone. ‘This seems to have induced the manufacture of glass. at a very early period, possibly in prehistoric times (see ante, page 265). Of late the glass trade was for the most part an export of bottles to Scotland. It declined as the native coal increased in price, and finally died out when the glass-house was destroyed by lightning in 1850, or thereabouts. ARMAGH. A considerable portion of the county is occupied by Orpovi- ctANs ; but none of these sandstones, or grits, seem to be favourably received as a building stone. To the north of the county, in the Blackwater Valley, are CARBONIFEROUS sandstones. Some of these, of reddish colours, were said to be of Permtan age; but the fossils in them suggest Kinanan.—On Irish Arenaceous Rocks. B/ that this cannot be correct. Some of these sandstones will dress fairly well, but they are not in general request. Grange. North-north-east of Armagh.—A_ free-working, fine sandstone, considered to be inferior to the ‘“ Dungannon stones,” Co. Tyrone, and those of Lisnaskea, Co. Fermanagh. It was used during the restoration of the Armagh Cathedral in 1835; but for the dressed work foreign stones were used, as presently mentioned. At Armagh there are conglomerates that are said to be Per- mians. Possibly they may be of that age, that is, the ‘‘ Passage rocks,” from the Carboniferous to the Trias; but it seems more probable that they are the basal beds of the latter. They lie nearly horizontal, as do also the Carboniferous rocks below, and the Trias rocks above, so that their exact age is hard to determine. These formerly were rather extensively used for ordinary building purposes, and some beds for flagging in Armagh. Trrassic.—Sandstones, or “ Red Free,” occurs to the North of the county, in the valley of the Blackwater, and at Armagh, and seem formerly to have been utilised; but of late they are not of repute. Between 1840 and 1846, when repairing the Cathedral at Armagh, “ English reds” were used for the carved head, while about the same time Scotch stones were imported for Lord Lurgan’s — new house. In the vicinity of Armagh, near Redbarn, at the bottom of the red beds, either in the Trias or the so-called Permian, is a Calcare- ous, hard, red breccia that has been used for flagging in Armagh. Sanp AND Gravet occur in the drift alluvium and diluvium. Good sharp sands for building purposes are found on the shores of Lough Neagh, near Lurgan, while good river-sand occurs about two miles from Armagh. CARLOW. The only sandstones and grits belong to the CaRBoNIFEROUS. They occur in the Lower Coal-measures that extend from Kail- kenny and Queen’s County into the western portion of the county. Although not now in request, being only used for local building purposes, they are capable of fine and durable work, as may be seen in the exquisitely carved and beautiful doorway of the an- cient church in Killeshin Glen. The principal quarry in them is 538 Scientific Proceedings, Royal Dublin Society. at Killeshin, about two and a-half miles from Carlow, on the road to Castlecomer. The stone occurs in nearly horizontal beds, from 10 to 24 inches in thickness, of a brownish-grey colour, silicious, naturally jointed, and easily raised. From the same strata are procured the so-called ‘‘ Carlow flags.” The principal quarries for these flags are, however, in the Co. Kilkenny, as is afterwards mentioned. SanD AND GraveL.—Sand is found in the alluvium and dilu- vium, while the upper drift (Esker drift) above the boulder clay or glacial drift is nearly altogether gravels and sands. ‘These, in places, are cemented into a conglomerate bed, having associated with them beds of brick clay, to be subsequently mentioned in a Paper on Slates and Clays. Good pit-sand can be procured in all the pits, which are numerous in the valley of the Barrow, but perhaps more in the Queen’s County (west of the river) than in Carlow. There is a large extent of good pit-sand and gravel at Carlow town, about the railway station, and along the roads running out at that side, where they form the lower stratum of the alluvial soil for a considerable distance. CAVAN. The sandstones belong to the Ordovician and the Carboni- ferous. Orpovictan.—These rocks, although of considerable extent, contain few rocks eminently suitable for cut-stone purposes. Some, indeed, work fairly well; but as good limestone or sandstone of a later age are conveniently situated, they are not looked after. Scrably. North of Lough Gowna; eight miles from Granard.— Brownish, ferriferous, slightly calcareous; works fairly, but is hable to lose its colour. Carponirerous (Lower Carboniferous, or Yellow Sandstone).— In this group, in the neighbourhood of Cavan, there are some easily-worked stones of a yellowish-grey colour, that have been extensively used in the town. Latt and Ballyconnell (Cavan).—Yellowish-grey, silicious, dur- able ; works freely. Used in the Cullen College, built 1871. Kinauan—On Irish Arenaceous Rocks. 539 To the north-west of the county, in the Coal-measure of the Cuilcagh and Benbrack Hills, there are said to be some beds of good stones. These, however, have been rarely worked, and, for the most part, are unknown on account of their backward situa- tion, and the difficulty and expense of bringing them into the market, railway charges being so high. They were, however, once largely wrought into millstones, and next to those from Drum- downey, in Kilkenny, were highly esteemed. Sanp and Graver.—Usually these are scarce in the county, especially near the capital town, as for building purposes sand has to be procured from a considerable distance. At Bailieborough there is a red pit-sand, but not very good. CLARE. OrpDovVICIANS occur in the mountain groups of Slieve Aughta and Slieve Bernagh. In these are grits and sandstones, but not of much account, except for rough work. There is also a green rock, full of little round bits of quartz, from the size of shot to that of peas, locally called “ Porphyry.” It isa hard massive stone, good for heavy work, but rises in unsightly blocks. CarBoniFERoUs.—Margining the Ordovicians, and in a small outlying exposure between Newmarket and Bunratty, are Lower Carboniferous Sandstones (Upper Old Red). The stones vary much in colour, from nearly white to yellow, reddish-yellow, and red or purplish. Good stone can be got in many places; but there are so many good and large surface-blocks, that only a few quarries have been opened. The stones in the hills, about ten miles from Scariff, have very silicious grains in a felspathic cement ; they work rather easily, but wear the tools rapidly. Ballyheique. Near Scariff.— Yellowish, gritty, with little cement; ferruginous spots; not difficult to work. In 1842, and following years, this stone was extensively used in the works for the improvement of the Shannon at Killaloe, and subsequently was used for the Workhouse, Scariff; but in Scariff it is not much used, as they prefer the stones procured in the hills, about ten or twelve miles distance. A vein of excellent stone, equal to the Tyrone stone, is said to 540 Scientific Proceedings, Royal Dublin Society. exist near Mount Shannon, at the bounds of the Co. Galway and this county. As pointed out by Wilkinson, the stonework of the ancient Crypt and Cathedral at Killaloe attest the durability and quality of the sandstones of that neighbourhood. To the west of the county, in the Coal-measur es, the sandstones and grits are usually thin-bedded, brownish, and bluish-greys, close-grained, and compact. They are very good for general building purposes, being very durable, and having flat beds, make very strong, good work; otherwise, they are not much used, being expensive to quarry, on account of the great head (over- | baring) of drift. They are also difficult to dress, and for cut- stone purposes limestone is generally used in the district. Ennistimon.—In beds or layers, from 2 to 8, or 10 inches thick. Dark-grey ; close and compact; very silicious. Makes good wall- ing. Very difficult to work. Crag. One mile from Kilrush.—Flags like those at Money Point. Money Point (on the Shannon).—Flags somewhat like the Car- low flags, but much darker; rough on the surface from tracks of marine worms and other animals. They have been extensively quarried, and exported to different places along the coast of the south-west counties. Formerly they were extensively manufac- tured into chimney-pieces, at the Marble Works, Killaloe, where there was machinery for cutting them and planing their surfaces. At one time the Killaloe chimney-pieces were well known in the market, and the Works employed a large staff of men, women, and children. Some thirty years ago, however, this trade seems to have died out, and now the “ Killaloe Marble Works” exist only in name. [The history of the Killaloe Marble Works I have not been able to unravel. Kil- laloe is most favourably situated, having the command of the greatest water-power in Treland, and ought to be one of the great centres of industry; but for some reasons all this great water-power is allowed to remain idle. Prior to 1850, the Killaloe Works were a great source of employment, not only in the town, but in the flag quarries on the Lower Shannon, and in various marble quarries, principally in Counties Tipperary and Limerick. All of these quarries seem to have failed when the Killaloe Works ceased. | Sanp anp GraveLt.—Very superior crystalline sand is found on Kcinanan—On Irish Arenaceous Rocks. 541i the shores of Loughs Graney and Coutra. The former were exten- sively used for the manufacture of scythe boards, the sands being carried for that purpose into the neighbouring counties, as boards made from them were considered far superior to those made from English sands. This sand is the detritus from the Lower Carboni- ferous sandstone, in which there are beds that were formerly wrought by hand into scythe stones. These were carried by hawkers, and sold to the traders in Ennis, Limerick, Nenagh, &c., or at the different markets and fairs in the neighbouring portions of Connaught, Munster, and Leinster. Before the ‘“‘bad times” in 1848 and subsequent years, very few mowers along the Shannon and its tributaries used any but “Clare stones” and “Clare boards;” but during that time the making of them ceased, and Hnglish and Scotch stones had to be used. A few of the makers who survived the famine attempted to revive the trade, and in 1860 there were a few families in Glenomera and Glendree, near Feakle, working at them. The foreign stones, however, held their own, as they could be sold much cheaper ; also they suited the scythes then in the market, as those imported are much softer than those previously made in the country, the former wearing out much quicker than the latter. Fifty years ago a mower on the Callow, along the Shannon, would have a scythe to last him two or three seasons ; now the imported scythes never last more than one. ‘The cheap seythes retard the work considerably, as the mowers have to stop so often to whet their seythes. [As pointed out in the Paper on ‘‘ Metal Mining ’”’ (ante, page 306), the Irish iron was much superior to that now in use. There are not now, as far as I can learn, any authentic records as to the quality of the steel, except the traditions of certain smiths who could make a scythe that would ‘‘cut wool floating on water,” or a scythe that had not to be whetted for an entire day. Such legends are still to be heard in the neighbourhood of the Shannon and elsewhere. ] In the barony of Burren sand and gravel are scarce, being nowhere in abundance. In the neighbourhood of Ennis there is good pit-sand; three miles from Scariff there is good river-sand ; while at Lahinch and Kilrush there is good sea-sand. In places along the coast-line there are duns or accumulations of Molian sand, and in the estuary of the Shannon manure or shell sand, formerly extensively utilized. 542 Scientific Proceedings, Royal Dublin Society. CORK. In this county sandstones and grits are the principal rocks, they being of Silurian, Devonian, and Carboniferous ages. (See note on Old Red Sandstone, under Kerry, page 568.) SmturR1AN AND Devontan.—The rocks of the hill country to the north and west of the area nearly all belong to one of these divi- sions, Carboniferous rocks only being found in portions of the valley. The Silurians (Glengariff grits) and Devonians (Lower Old Red Sandstones) are locally cailed “brown stone” and ‘red stone,” while the Carboniferous sandstones (Vedlovw sandstones and. Coomhoola grits) are known as “ grey stone.” In numerous places in the Silurian and Devonian excellent and durable stones for tool-work could be procured, as is exhibited in the various ancient buildings, Limestone, however, is now generally used for dressings and other cut-stone purposes. This, in a great measure, seems to be due to the architects and workmen, who have learned and live in the cities where limestone is used, objecting now to use the sandstone; the workmen especially, as sandstones are much harder on their tools than limestones. Lime- stone, however, in early times, in places superseded the sandstone, as at Cloyne, where the sandstone in the Round Tower was pro- cured between its site and the shore; while the other ancient structures, but more recently built, are of limestone brought from a distance. The Round Tower of Cloyne, just mentioned, displays the excellent qualities and durability of the stone of the neighbour- hood. It is of a light, brownish-coloured sandstone, the work being good, especially round the doorway. Of the work Wilkinson ‘states that the stones are notched one into the other in a peculiar manner ; also that their state of preservation shows the durability and sound quality of the material. From the list given (page 545) and descriptions, for which I am indebted to Mr. Williams of the Board of Works, it would appear that some of the South-west Cork sandstones are well worthy of more attention than they now receive. Sherkin Island, off Baltimore Harbour.—The stone, when first raised, 1s greyish; then it becomes tinged with green, probably Kanauan—On Trish Avrenaceous Rocks. O4e: due to minute particles of grey copper. It afterwards loses the greenish tinge, but never returns to its primitive colour. It has been extensively used in Skibbereen, where it displays good work, especially in the Roman Catholic church; while its durability is tested in the older buildings. This vein of stone is of considerable. extent, being found to the westward in Clear Island, and eastward on the main to the south and south-east of Baltimore Harbour. Horse Island.—A. loose, friable, brown freestone, which has been extensively quarried. Drumcona, six miles from Skibbereen.—Greenish ; hard; semi- vitreous, with calcareous patches; cuts and dresses well. This is a superior stone to those on Sherkin; but the quarry is very inacces- sible. Glandore.—A. good greenish grit, formerly much used. In the ruins of Ballymoney Castle its durability is tested. It was also. used in Kilcoleman House, four miles from Bandon. The quoins and chimney shafts at Aughadown House, in the east division of the barony of West Carbery, are good examples of the stones of the neighbourhood. Knockarowra and Cloghlucas, near Mallow.—Brownish-grey ; slightly argillaceous; suitable for plain work. Rahan Mountain, four miles from Mallow.—Reddish; ferru- ginous ; fine-grained. A superior stone to those nearer Mallow. Quarry Mountain, near Mallow.— Reddish; silicious, but slightly calcareous; semi-crystalline. Mountain between Mallow and Kanturk. — Dark-brown ; quartzose ; semi-vitreous; hard. Knightfield, three miles south-east of Banteer Railway Station (commonly known as the “ Kanturk Quarry’’).—Used for the quoins and sills of the Lismore school, six miles from Kanturk. [The following two localities in the Knockmealdown range may be in the “ Yellow Sandstone.” | Killemera, near Glanworth.—A nice sandstone for walling purposes. Araglin, north-east of Fermoy.—Grit stone ; gives well-shaped, superior paving setts. Two miles south of Fermoy is a very good variegated stone, that cuts and dresses well. It was much used formerly, but after- 544 Scientific Proceedings, Royal Dublin Society. wards was in a great measure superseded by limestone. Bishop’s Wood, near Fermoy, supplies flags. Glanmire Road, Cork.—A. deep-red, fine-grained stone. Templegall, or Whitechurch, seven miles north-west of Cork.— Good building stones and flags. YVoughal.—A red stone, lighter in colour than the Cork stone. In places there is a conglomerate (trappean), which can he worked into good square blocks, best suited for heavy work, such as bridges, foundation walls, and the like. CarBoNnIFEROUS.—In this formation there are sandstones and grits at the base (Yellow Sandstone); and higher up in the Carbonije- vous Slate, at different horizons, are the Coomhoola grits. In places many good stones could be procured, but they are not much sought after, being hard and silicious, and quickly wearing the workman’s tools. A good freestone has been worked on Horse Island ; also near ‘Castletownsend; while, in the Devonshire property, near Bandon, and in the Herrick estate, Innishannon, there are extensive quarries. Tn the parish of Brinny, north-east of Bandon, are flags of ex- cellent quality, and in Kilbrogan there is freestone that has been extensively used in Bandon. A little north of Cork, on the north of the River Lee, the stones in the quarries vary. They are thus described by Wilkinson :-— Yellowish-white, close, compact quartzy grains, with felspathic cement, and semi-vitreous; also, green, silicious, close, dense, very compact, but with numerous fissures and bedded portions, the latter causing the stone to fail. Belleview Quarry. Near Cork.—A good and free-working stone; but the workmen prefer the limestone, to which they are accustomed. | Coolconing. Two and a-half miles north of Kinsale. — Yellowish, brown, and discoloured, silicious, open, small imbedded particles of slate ; cuts fairly well. Shippool. Kinsale.—Yellow-shaded green ; semi-granular and quartzose; slightly calcareous. Baillymartel. Kinsale.—Stones varying; best, yellow, fine- grained, compact, but slightly micaceous. Coat-mrasuRES (Ba/linaquila. South-west of Dromina).—A quarry of good flags, and quarries of sandstone. Or Kinanan—On Irish Arenaccous Rocks. Ral LISTS AND NOTES BY A. §. WILLIAMS, BOARD OF WORKS. (The localities are in the Devonian and Carboniferous.) Baltimore. Hull back of Coast-guard Station.— Light-grey. National school and residence. Fit for any description of work, and improves on exposure. Has been used in some of the ancient structures near this place. (Vide page 542. Stones of Sherkin Island and the main- land to the eastward.) Ballyalley. Seven miles from Skibbereen.— Grey grit. Coast-guard Station. This stone, if ob- tained at a reasonable depth from the surface, is fit almost for any sort of work. Rosscarbery. ‘The Beamish quarries, west of the town.— Brownish and yellowish. National Schools, Rosscar- bery. Good stone for ordinary work, and, if selected, fit for dressings. Can be raised in very large scantling. Onion Hall.— Blue argillaceous and slaty grit; very hard. Union Hall and Glebe. Only suitable for rubble and walling. Ballydonegan. Twelve miles west of Bearhaven.— Brownish. Coast-guard Station. Stone hardens on exposure. Is fit for any description of work. Lehanemore. Sixteen miles westward of Bearhaven.— Grey grit. National Schools. Only used in rubble and walling. Very durable, but not fit for chiselling. Derrincorrin. Seventeen miles north-westward of Bantry.— Brown. National Schools. Can be raised in fair- sized blocks. Very durable, but not suitable for dressed or chiselled work. 046 Scientific Proceedings, Royal Dublin Society. Dromore. Hight miles westward of Drimoleague.— Grey grit. National Schools. Suitable for building, or can be raised in large dimensions, suitable for flagging. Can be dressed for quoins, and improves on exposure. Dunnycove Bay. South of Clonakilty.— Liver coloured. Ardfield National School, six miles. from Clonakilty. Used in walling and rubble, window and door-sills of limestone, which is usual in this neigh- bourhood. Timoleague.— Blueish, flaggy grit. National School, Timoleague. Never used except in dressing for opes and sills. It is easily raised in blocks of large scantling; well suited for piers or other harbour works. Borleigh. Hight miles from Bandon.— Grey to brownish sandstone. School and residence, Borleigh. This quarry is historical, the stone having been used in the Timoleague Abbey and other ancient struc- tures. Rahavoon. Six miles from Bandon.— Brown. National Schools. Very hard ferriferous vein ; only fit for walling. Milistreet.— Reddish-yellow. Millstreet Dispensary. A superior building stone, suitable for any description of cut-stone purposes ; largely used in church work. Dromagh.—— Grey grit (Coal-measures?). Dromagh Glebe. An ex- cellent stone, suitable for all dressed work of small scantling, as it cannot be obtained in large dimensions. Lismore. Six miles from Kanturk.— Brown. National School and residence. Hard stone ; similar stone very common in the county, and used for walling and rubble, the quoins and sills being procured from the Kanturk and Keelin quarries. Kinanan—On Irish Arenaceous Rocks. 547 Boherbwe. Hight miles from Kanturk.— Brown. Dispensary. Stone similar to that at Lis- more. Dressings from Kanturk and Keelin quarries. Inchageela. Quarries in adjoining hills.— Grey and greenish; flagey. Inchageela National School and Kilmichael (Tareton) Glebe. Stone hard; with difficulty can be chiselled, but is not fit for dressing. Sanp anD GRAvEL.—Good sand for building purposes is pro- curable in various places in the different valleys. Pit sand occurs in the neighbourhood of Cork and Macroom ; while good river sand is obtained five miles from Bantry, in the River Snave; in the Lee, three miles from Cork; in various places along the Bandon river and the Blackwater; in the Islin river, near Skibbereen ; and in various streams. In numerous places along the coast there is good sea sand. In Bantry and the neighbouring bays there are accumulations of rich shell sand, or rather coralline sand. Before 1848 there was a large trade in these sands for agricultural purposes, it supporting a large fleet of boats, which dredged the sand, and brought it into Bantry and the other quays, from whence it was carted inland, even over the hills into the Co. Limerick. At the same time there was also a fleet of 35-ton lighters at Youghal, engaged in similar shell sand dredging. Good pit sand occurs about a mile from the Blarney Railway Station. It is very generally used in the Co. Cork. Near Mitchelstown, on the Kingston estate, is excellent pit sand ; also river sand in the River Funcheon. Near Glanworth, at Dunmahon, very superior pit sand occurs on Mr. Dilworth’s farm. At Ballydonegan Bay there is a peculiar sand, due to the crushing of the copper ore. Previous to the Allihies mines being worked, there was no holding-ground for anchors in the bay, and at the mouth of the river there was a gravelly beach. Now there is good holding-ground in the bay and a sandy beach. For moulding purposes in the foundries the sand is principally procured from Belfast (valley of the Lagan) ; but some of an infe- rior quality is got in the neighbourhood of Bishopstown. SCIEN. PROC. R.D.S., VOL. V., PT. VII. py 12) 048 Scientific Proceedings, Royal Dublin Society. Gxiass.—In Cork there were two large glass-houses for the manufacture of flint-glass, with extensive premises for cutting, engraving, &c., attached to each. One ceased to exist about 1835, and the other before 1840. The sand used seems to have been imported. DONEGAL.* For the most part this county is occupied by granitic, eneissose, and schistose rocks. ‘These, from recent researches, are known to belong to two distinct geological groups, the older probably repre- senting rocks equivalent to the Cambrian and the Arenig, while the later represent the Ordovician and perhaps, in part, the Llan- dovery or May Hill Sandstone. On these older rocks, in places, such as at Ballymastocker Bay, Fanad; Muff, Lough Foyle; along the mearing of the Co. Fermanagh, to the northward of Pettigoe ; and in the neighbourhoods of Killybeg, Donegal, and Bally- shannon, there are Carboniferous rocks of greater or less extent, that in Fanad being a mere patch. CamMBRIAN AND ARENIG.—The sandstones, grits, and quartz- rocks which occur in the strata supposed to represent these geological groups are now all more or less altered into quartzytes, gneiss, and foliated granite. But some of the quartzytes, especially some of those in the gneiss and foliated granite, are even-bedded, and, when also regularly jointed, they are excellent material for walls and such like; but they will not bear dressing. Many of the altered quartz-rocks are splintery. In places, however, they are massive, and capable of being raised in large blocks; and, under such circumstances, they are more or less suitable for foundations, sea walls, and other heavy work. OrpDovicIAN AND LLANDOVERY (?).—The sandstones and quartz- ‘rocks which are supposed to belong to the rocks equivalent to some of these groups are, in a great measure, altered into quartzyte. Some, however, are unaltered or very little altered, as sandstones occur in the Rathmullen district, between the ridge called the Devil’s Backbone and Lough Swilly; also in the barony of Raphoe, south of Lough and Glen Swilly. In the Rathmullen district some of these stones dress fairly well, but are liable to discolour. ‘Those in Creeve Mountain, about three miles north- * See ‘‘ Notes added in the Press.” Kinanan—On Irish Arenaceous Rocks. 549 west of Rathmullen, have been used for facing in Ramelton. In the valley about a mile south of Creeve Mountain, in the townland of Oughterlinn, there are flags; these are good, hard, and silicious, and can be raised of large dimensions—12 feet long by a width of 4 to 6 feet. ‘They have been usedin Ramelton; but the place is very inaccessible, the road being very bad. ‘To the north of Rathmullen, in places near Lough Swilly, there are also flags that have been worked for local purposes, especially in the neighbourhood of Long Lough. In the quartzyte range of Knockalla some of the quartzytes are thin-bedded. They are silicious and hard, and appear as if they could be raised in marketable sizes. ‘These, as yet, have not been opened on; but, if they could be obtained of sufficient sizes, they should be valuable. Up to the present the place has been very inaccessible; but as a pier has been erected in Ballymastockan Bay, at Croaghros, they are now near a port. At the opposite side of Lough Swilly, in Dysertegney, Inishowen, these beds are worked, and produce good flags, that ought to be more utilized than at present. There are also veins of more or less similar flags in the north of the county, near Crossroad and Dunfanaghy, which are locally used. [The age of the rocks in the north of Donegal is still undetermined. For some reasons they might be supposed to belong to the later groups, while there are also reasons for supposing they are portions of the older. The geology, however, here- abouts is so complicated, the younger and older strata being folded in sharp inverted curyes, that it is quite possible that their exact age will never be satisfactorily known. | In the barony of Raphoe none of the sandstones have been considered specially suitable for cut-stone purposes, although they are very useful for walls. Those which can be raised in large blocks are good for coarse and heavy work, suck as foundations and the like. In a few quarries, however, the stones have been used for dressed work, and they cut fairly well. ‘They, however, are liable to discolour. Muckish. ‘Three miles from Dunfanaghy.—Quartzyte; open and porous; pure white; semi-crystalline ; slightly foliated ; very slightly calcareous. Kinclevin. Nearly a mile from Dunfanaghy.— White quartzyte. with minute divisions of mica. G2) 92 550 Scientific Proceedings, Royal Dublin Society. Errarooey. Near Crossroads.— Yellowish ; improves in colour on exposure; silicious; durable; free-working ; can be plugged, and hammers well; can be raised in long scantling, and is capable of long bearings; was used in the foundations and coping-stones of Myra Bridge and in the Roman Catholic Church and School-house,. Crossroads. ‘The vein extends eastward and westward. Minnagran. Seven miles from Glenties.—Here the rocks are: very much altered, and appear to be more of a gneiss than a quartzyte. The stone is used for dressed work, and in the vicinity it is called “millstone.” At Carrick, eight miles northward of Milford, and in places to: the westward, there is a reddish, porous quartzyte, that squares fairly well, but will not cut. It is a good building stone, and was largely used in the building of Manorvaughan, or Mulroy House. It keeps its colour, and has a good effect. Locally it is called “red granite.” Killyclug. North of the Letterkenny Waterworks.—Quartzose sandstone; rises in long massive flags; capable of long bearings ; good for rough building, such as lintel and posts in farm buildings. CarponirERous.—In the already mentioned Carboniferous: outlier at Ballymastoker Bay, Fanad, there are red conglomerates and sandstones. The first were formerly used, to a small extent, to be wrought into flax-crushers, while the sandstones were used for local purposes. Tn the parish of Muff, on the west of Lough Foyle, and to the north of Derry, the rocks consist principally of reddish sandstones. and conglomerates, which are used for local purposes. To the south-east of the county, margining the Co. Fermanagh, that is, northward of Pettigoe, there are in places stones of yellow- _ ish-grey shades. At Lettercrann, about three miles from Pettigoe, were procured the stones for the stations on the Enniskillen and Bundoran Railway. , In this tract some of the stones are specially suited for flax- crushers and millstones, and forty or fifty years ago many were. made. In the Carboniferous rocks, near Donegal and Ballyshannon, some of the sandstones are of good characters. They are from pale cream-colour and nearly white to reddish and purplish ; from very fine to coarse conglomerates. Formerly from this county Kinanan— On Irish Arenaceous Rocks. 561 there was a large trade in flax-crushers, they being sent on carts into the other portions of Donegal and the neighbouring coun- ties, or shipped from Donegal town to different places along the coast-line. This trade seems to have been very short-lived. Formerly flax was kiln-dried, the old disused kilns being scattered over the county. In general, the inhabitants cannot tell you what they were for; a few, however, state that in their grandfather’s time, some sixty or seventy years ago, before the stone-crushers were invented, all the flax was “beetled,” that is, crushed by hand with wooden beetles, and, before doing so, it had to be kiln-dried. The kiln-drying ceased when the crushers came into fashion; and the trade in the latter appears to have died out some ten or fifteen years ago, partly on account of the failure in the flax crops, partly because mills were erected in which the flax was crushed, and partly because, by some of the new modes of obtaining the fibre, the flax does not require to be crushed, but is sold in the unbroken state. The unsold flax-crushers are to be seen every- where about the town of Donegal; lying in heaps, as if some giants had been playing a game of quoits. They are now put to innumerable uses. The stones near Mount Charles have lately been greatly brought into notice by the Drumkeelan stone being selected for the new Museum and Library, Leinster House, Dublin. Wilkinson, in 1845, stated that the best stone is yellowish-grey, or pale cream- colour, free, felspathic, slightly micaceous, with a silicious ferri- ferous cement. Of it Mr. Cockburn states:—“It is good and durable, but hard to work ; and has been used in the dressing, Town Hall, Sligo; also for quoins and dressing, with other sand- stones, in the Killybegs Coast-Guard Station. ‘The Provincial Bank, Ballyshannon, was contracted to have been built with this stone; but, when half up, the supply of good materials seems to have failed, the upper portion being stones from Dungiven, Co. Londonderry ”’ (see Dungiven, p. 583). Altito. Three miles from Donegal.—Dirty yellow. Varying from granular to conglomeritic ; very quartzose; semi-crystalline ; hard; cement felsphatic. Formerly largely wrought into mill- stones and flax-crushers; also heavy kerbing-stones. Used for ashlars in Lough Hske Castle. 002 Scientifie Proceedings, Royal Dublin Society. Drumkeelan. Three miles from Mount Charles Pier.—Creamy, to nearly white; felspathie; slightly micaceous, with slightly cal- careous cement. Dresses and cuts well; hardens on exposure. Good strong flags can be obtained here; used in the town of Donegal. Three thousand tons of this stone have lately been shipped by the Messrs. Beckett, to build the Museum and Library for the Science and Art Department, Leinster House, Dublin. Beauwin.—Used in Killybegs Coast-Guard Station for boat- house and slip. ‘Coarse and uneven in grain, with large quartz pebbles. There are some beds of a fine texture and a beautiful tint in this place, but there is no regular quarry, the stones being raised off the surface, and where they can be had with least trou- ble” (J. Cockburn). Kildoney. Four miles from Ballyshannon.— White, micaceous, silicious grains, with argillaceous silicious cement. This stone dresses and cuts fairly well, and is very durable; used for wall- facing. It is near the sea, and therefore easy of transport, but is not thought as much of as the stones from the Dog’s Mountain. [In this neighbourhood, in the cliff overhanging the sea, is an anthracite, about 7 inches thick. In boring in search of this coal, a sort of emery was struck, 12 feet from the surface. | Dog’s Mountain. Fifteen miles from Ballyshannon.—Light yellow, ferruginous, fine-grained, slightly micaceous; works freely and well. Excellent flagging (was used at the Parish Church, Ballyshannon) can be obtained here. To the south of Bundoran, in the ridge of Calp sandstone, partly in this, and partly in the adjoining counties, is excellent freestone, which was largely used in the buildings in the town. SAND AND GraveL.—Near the top of the north face of Muckish. ‘occurs a very superior silicious sand for glass-making. A little of this at the beginning of the century was shipped to Belfast and Scotland. The place, however, is very inaccessible, and the cost of getting was so great, that it was undersold in the markets by foreign sand. [£2 a-ton is what it was then sold at. It is coarser-grained than the Belgian sand,. but of a better quality. The best Belgian sand at the present time can be delivered in. Dublin for 15s. a-ton.] The Muckish sand occurs as a disintegrated bed in quartzyte. Kinanan—On Irish Arenaceous Rocks. 553 Only the washed and weathered-out crop can be seen and ex- amined. How far it extends into the hill, and its quality when followed in, cannot be known unless a level was driven in on the bed. [Lewis states there is a similar sand near Lough Salt. This, however, after minute inquiry, I cannot find ; it seems to be unknown. ] Kane points out that, “In several of the bays of Donegal the sand thrown up by the Atlantic storms is of great purity, and fully equal to that in ordinary use amongst glass manufacturers.”’ Donegal sand was used at the Glass Bottle Works, Ringsend, Dublin, “and found very good;” but owing to the price having risen, the use of it was discontinued. In some of the streams westward and south-east of Letter- kenny, there are sands also due to the disintegration of quartzyte or sandstone in situ. Those known are, however, more or less im- pregnated with iron. A rather quartzose sand occurs along the railway from Letter- kenny to Derry, at Ballyboe and Monclink. The sand from the latter was largely used as ballast on the line. Pit sand for mortar in general is not very plentiful; it how- ever occurs in Inishowen and near Milford; while there is inferior pit sand in the neighbourhood of Dunfanaghy and Falcarrah. A very good greenish pit sand occurs a little north-east of Kilma- crennan. A fine sharp sand occurs in small hills in Tullybeg, east of Lough Fern; while about two miles westward of Rathmelton, in the valley of the Leanane, in small esker-like ridges, there is a clayey sand, used in Ramelton. River sand from the streams and rivers is, however, in general good; excellent sand for use in Donegal being found in the Dunmurry and Legacorry streams. Other good river sands occur near Glenties; above Letterkenny, in the Swilly ; in inexhaustible quantity in the Foyle, south of St. Johnstown, used in Derry; in the Finn river, at Lifford ; and in various other places. Good sea sand is got in places along the coast-line. There are on the west and north coasts very extensive dunes and tracts of Molian sand. “ Close to the village of Muff, fine sharp white free sand occurs ; used extensively in the neighbourhood and Derry (six miles distant) for scouring steps and such like. In this neighbourhood some of the sandstones are very soft and friable.” (A. IC. Stewart.) 554 Scientific Proceedings, Royal Dublin Society. DOWN. Rocks of Ordovician age occupy the major portion of this county; but in these to the southward, among the Mourne Moun- tains, in the vicinity of Carlingford Lough, are intrudes of granite and other Exotic rocks. Two very small tracts of Car- boniferous rocks occur, one on the margin of Carlingford Lough, and the other in the vicinity of Castle-espie, at the north end of Strangford Lough; while to the north-west and north, in the valley of the Lagan, northward of Comber, and in the neighbour- hood of Newtownards, are Triassic. In the valley of the Lagan, over the Trias, are other Mesozoic rocks, and the Locene (?) dolerytes, with their accompanying basal beds. Orpovictan.—The various grits that occur in places in the rocks of this group seem to be only used for local purposes, as in the area there is no quarry of note. In the district the slate rocks are usually used for rubble work; and granite, or Trias sandstone, for groins, dressings, and other cut-stone purposes. At Ballygowan there is a stone used in the National School, which Mr. Grey reports as “very hard, durable, and dark-coloured—nearly black.” Near the “ Stone Circle,” Millan Bay, and to the south-west of Slievenagriddle, flags of large size can be obtained. Triassic.—In the quarries along the valley of the Lagan the stone, nearly invariably, is of a deep-red, or brick-colour, and more or less soft and argillaceous. It has been largely used for local purposes, especially for the bridges of the Ulster (now the Great Northern) Railway. There is a considerable quarry at Kalvarlin, near Moira. To the north of the county, at Scrabo Hill, near Newtownards, there is a better class of stone. Here there are different quarries, in which the stone varies greatly in colour and quality, there being shades of grey, yellow, and red; some are argillaceous, others silicious, while they may he friable, or have concealed joints or vests ; therefore they have to be selected with great care if good and uniform work is required. [Blasting is too prevalent in this quarry. Good stones, with a little extra trouble, might be raised by the crowbar and wedge, while, if raised with powder, they are KinauaAn—On Trish Arenaceous Rocks. 550 shaken, and more or less valueless. This remark is not only applicable here, but also in various other sandstone quarries, where the character of the stone is spoilt by the mode of raising the blocks. | All the stones are free-working, and, if raised with care, and well-selected, are durable. Formerly they were very extensively used in Belfast, but of late years they have been cut out by a very general introduction of Scotch stone. These quarries also supply good strong flags, from 2°5 to 3 in. thick. Newtownards is built nearly solely from these quarries; the large Town Hall, as pointed out by Wilkinson, displaying some good work. The Scrabo stones have been used in Belfast, in the Albert Memorial, St. Enoch, Fortwilliam, Sinclair’s, Elmwood, and Donegal-street churches; the Academy, in the offices of Robinson and Hewits, and the warehouse of Robinson and Cleaver, the last two being from the Glebe Quarry. They were also used in Stor- mount Castle and the Model School and Strain Church, New- townards. Mr. William Gray, M.R.I.A., says of the stone, that it is “very variable in colour and texture, stands fairly well when selected and set on bed, but tilted on edge it will not stand. It works freely, and, as a rule, is of a light-brown colour.” And of the “Glebe Quarry” :—‘“It yields a light-coloured stone, of very even texture, and good colour. It is soft, but stands fairly well, and makes a good building stone. Dundonald. Four miles from Comber :—Red ; fine-grained ; like the Dumfries stone (Scotch), and has been used for it. The quarry does not yield a very large quantity. Has been used in Belfast in the Spencer basin ; cottages and villas at Knock ; Preston, Smith & Co.’s Warehouse, &e. (Wilkam Gray.) The principal Irish sandstones used in Belfast are from the Scrabo and Dundonald quarries, Co. Down; Dungiven, Co. Londonderry; Ballycastle, Co. Antrim; Cookstown, and different quarries near Dungannon, Co. Tyrone; those from Ranturly, Mullaganagh, Bloomhill, and Carlan being most preferred. Sanp AND GraveL.—Good pit sand occurs in the valley of the Bann, also at Saul, between three and four miles from Down- patrick, in the neighbourhood of Newtownards, and in other places. There is good river sand in various places along the streams and 556 Scientific Proceedings, Royal Dublin Society. rivers ; while near Kilkeel and Newry the sea sand is also good. Red sand suitable for foundry purposes, and exported from Belfast to Dublin, Cork, &c., is procured in the valley of the Lagan. Frint-Guass was formerly largely manufactured in Newry. Although this was in existence in 1840, yet now it seems hard to get information about it. There was a second manufactory at Ballymacarret, a suburb of Belfast. To this, at the beginning of the century, a few cargoes of Muckish sand—Ards, Co. Donegal—was brought, and found to be very superior; but the expense of getting the sand, and the consequent high price when delivered, drove it out of the market. DUBLIN.* There are arenaceous rocks among the Ordovicians to the north and south-west of the county, the latter in part being metamor- phosed. In the Rathmichael Round Tower, quartz-rock and clay- slate were used ; but the masonry is very rude. As beds of limited thickness in the calp division of the Carboniferous there are argil- laceous sandstones, and there are also sandstones in the Lower Coal- measures. CaRrBonrIFERouS.—In some of the calp quarries there are ar- gillaceous calcareous sandstones, or arenaceous limestones, capable of being raised in large blocks, and suitable for heavy work, such as. foundations, for which they have been extensively used. In some quarries they are thin-bedded, and give good flags. ‘This was specially the case in one set of beds in the old “ Windmill Quarry,’ Rathgar, and some years ago there was an extensive trade in them. As, however, the “ overbaring,” and conse- . quently the expenses of the quarry, increased, the trade dropped. In the north division of the county there are patches of Lower Coal-measure rocks. In these there are some grits and sandstones ; but although some of them are fair stones, none of them appear to have been used, except for local purposes. In the city of Dublin sandstone is largely displayed in the public buildings; but none of the cut stone seems to have been obtained in the county, while most of it, especially in the buildings during the last century, and in the beginning of the present, is * See *‘ Notes added in the Press.” Kinanan—On Irish Arenaceous Rocks. aoe English stone. Portland stone, according to Wilkinson, was used in the following structures :—Old Parliament House, now called the Bank of Ireland; Trinity College, except the Provost’s House, for which the stone was procured in the neighbourhood of Liver- pool; Royal Exchange; Post Office; Rotundo; King’s Inns; Law Courts; Custom House; the dressings at the Castle; the statue, Nelson’s Pillar; St. George’s Church; St. Thomas’s. Church ; Roman Catholic Cathedral, Marlborough-street. It has stood well, but is much discoloured. For some years past it has fallen off in demand. Its present price in Dublin is two shillings per cubic foot, and one shilling per square foot for working. From information procured by Mr. R. Clarke we learn the following as to buildings erected since Wilkinson wrote :— “‘ Subsequently oolite limestone, or Bathstone, was in demand, which may be here mentioned, although somewhat out of place. At present there are four qualities in the market, which are delivered at two shillings and two pence per cubic foot, and dressed at one shilling per square foot. It has been used in the following offices during the last twenty-five years :—Provincial Bank, College-street ; Guinness’s mansion, Stephen’s-green ; Standard Life Assurance,, Sackville-street ; Trinity Chambers, Dame-street; Royal Insur- ance (?), Dame-street; Crown Life Insurance (?), Dame-street ; Commercial Union Assurance, College-green; Law Life Insur- ance, Sackyille-street ; and Lancashire Insurance, Sackville-street. “‘Caen-stone is used for finer kinds of work than either. the Portland or Bath, such as all kinds of inside work. “Drumfries stone has been used in many of the insurance office buildings. “Runcorn red was also used in many of the insurance companies’ offices as well as in other structures, principally for bands to set off lighter sandstones, or granite. It, however, isnot durable, as may be seen in the Augustinian Friary Church, John- and Thomas-streets, where the Runcorn stone has decayed so rapidly, that although only built twelve years, it is now being taken down and replaced by granite. “‘ Furness Abbey red stone has also been imported. “Of late red sandstone has been brought from Dundonald, near: Comber, Co. Down, and has been largely used in building the new portion of the Great Northern Railway Terminus, Amiens-street. 508 Scientific Proceedings, Royal Dublin Society. This stone has a good reputation in Belfast, where it has been largely used.” | “Dungannon stone,” from Mullaganagh, or the Ranfurly quarry, Co. Tyrone, was used in the new additions to the Royal University, and has held its colour well. The creamy sandstone from Mount Charles, Co. Donegal, has been used extensively in the new building for the Science and Art Department, Leinster House. This seems to be the first place of note in Dublin where it has been tried. SanD AND GraveL.—In this area, in the ground that is below the two hundred and fifty feet contour line, but more especially below the one hundred feet contour line, there are large accumula- tions of sand and gravel. In some localities, however, especially those below the lower line, the gravel and sand has extensively been worked out for road and building purposes, large areas being cleared of the accumulations that once existed, so that anyone now mapping the edges of the gravel terraces would draw lines quite different to those of the margins of the original sea-beaches. This is specially the case in the tract between Booterstown and Dublin. As, however, these sands and gravels are so prevalent in the county, good pit sand can be procured in numerous places. The Drift Cliffs of Killiney Bay are for a large part composed of these gravels, and the sands, the washing from the cliffs, have within the last thirty or forty years come into great repute, so much so, that now, almost as fast as the beaches form, they are carted away, to the great detriment of the owners of the ad- jacent land, as their land, being deprived of its natural protection, is rapidly carried away by the sea. This removal of the sand, and consequent waste of land, has led to various lawsuits. [Within the last forty years, since the great trade in Killiney gravel has been in- stituted, the cliffs, from a want of their natural protection, are receding backwards at a rate of at least one foot every year; while, in certain places, the destruction is even much more extensive, exceeding two or even three feet per annum. From careful calculation made on the coast of Wexford, where the natural waste of the drift-cliffs at the present day is greater than deere in Ireland, the average waste is one foot per annum, the excessive waste in two or three other places being three feet per annum, and in one or two as much as four feet and five feet. These wastes on the coast-line are very interesting, some being evidently due to artificial structures. Thus, the intaking of the north and south slopes in the Slaney lagoon (Wexford Harbour) changed not only the character of the Dodder Bank, at the mouth of the lagoon, but also that of the Lucifer Shoal, six miles off its entrance. And these Kinauan—On Irish Arenaceous Rocks. 509 changes in the banks have affected the infringement of the currents on the north-= ward coast, so that since these intakes have been made the coast-line of the North Bay, that is between Wexford and Cahore, has been much more rapidly denuded. On the other hand, on the South Bay, or as it is now called on the recent charts, Bally - geary Bay, the erection of the new pier at Ballygeary has quite changed the features of the shores of the bay, by accumulating fulls at the base of the cliffs that previously were rapidly being denudedaway. ‘This is especially the case between Ballygeary Pier and Greenore, where there are now ‘‘ fulls’’ and apparently permanent beaches in places. that ten years ago showed a clean-washed rock surface up to the base of the drift-cliff ; these beach accumulations covering up most interesting geological sections, that pro- bably will never be seen again until Ballygeary Pier has disappeared. On the south coast of Wexford the Ballyteigue flats were intaken; here also the change has had great effect, as since the intake the landimmediately west of the entrance to the lagoon has been rapidly denuded away ; but further westward, in the vicinity of Cullenstown, a foreshore has grown out. If it were necessary, various other cases could be enumerated where there are also changes due to human agencies. In other places changes are taking place from unknown and hard-to-be-explained natural causes, fulls forming or being cut out for no apparent reason. The most remarkable case that has come under my observation is the tidal effect on the middle island of Arran, at the entrance of Galway Bay, where the effects of the tidal currents of late years are perfectly different to those a quarter of a century ago, while there seems no apparent reason for a change. | Good pit sand for building purposes can be obtained at Knock- more, Valley of Diamonds, and Ballywaltrim, Dargle-road, Bray ; also at the Moat, Old Connaught. ‘The last isa very superior sand, very clean and sharp (silicious). It is in Lord Plunket’s demesne, and is not for sale, but is used”by special permission for any very particular stucco plastering rough-cut work. There is no sand equal to it, certainly none to surpass it, in the Co. Dublin. (ZT. B. Grierson.) The foundry sand (red) used in Dublin is im- ported from Liverpool and Belfast, costing, delivered, about 15s. per ton. At one time good sand came from Co. Cork, but it does not seem to be used now. Guass formerly was largely manufactured’; but in 1886 there were only two flint glass and seven glass bottle manufacturers. Through Mr. White of Dublin we learn that at the Ringsend Bottle Co.’s works the common bottle glass is “made by the fusion of the following materials: sand, from the adjoining Sandymount strand; blue clay, from Sutton strand ; waste lime, from Bewley and Draper’s chemical works ; kelp waste ; broken red tiles, to give body; rock salt, from Drogheda; refuse manganese ; a small quan- tity of coarse fluor-spar, and oyster shells. “The materials now used for the finer glass are Antwerp sand, 560 Scientific Proceedings, Royal Dublin Society. French chalk, carbonate of soda, oxide of manganese, fluor-spar, and arsenic. “Ground granite was used formerly for the finer varieties of glass, but was discontinued in consequence of the high temperature required for its fusion. Donegal sand was also used, and was found very good; but, owing to the price having risen, the use of it was discontinued.” FERMANAGH. To the north-west of the county there is a small tract of meta- morphic rocks coming in from those of the Co. Donegal. They are probably the equivalent of the Arenig, or perhaps Cambrian. East of Lower (North) Lough Erne are Silurian of the “ Lower ‘Old Red Sandstone” type. The rest of the area is occupied by Carboniferous rocks. The age of the Carboniferous rocks occupying the tract at the south-east of the county, of which the highest summits are Slieve- beagh (1255 feet) and Carnmore (1034 feet), is disputed. Griffith - considered them “‘ Ca/p,” or the middle group in the Limestone ; John Kelly, whose opinion is adopted by Dr. Hull, calls them Coal-measures ; while Baily states the fossils prove them to be Lower Carboniferous. A8 previously stated, we believe that they are Coal-measures, and will refer to the lower sandstones as “ Fer- managh sandstone.” (See Introduction, page 524.) West of Lower Lough Erne, extending 8. 8. H. from Lough Erne, past Derrygonnell to the Arney river, is another tract of Calp ; while north-east of Lower Lough Erne, in the Kish district, the rocks are of the “ Ulster Calp type,” capped to the south-west of Kish by a small tract of “ Fermanagh sandstone” (Lower Coal- " measures). | In the western part of the county are Coal-measures, part of the ConnaucHt CoaL-FIELD, which, as previously mentioned, extends into the province of Ulster. Orpovician.—The grits of this group can be used for walling and rough purposes; but, as there are usually better stones in the vicinity, they are only very locally used. SirurtAn.—The sandstones, which are in the majority in the mass, are generally shades of red, brown, and purple, although Kinanan—On Irish Arenaceous Rocks. 561 some are yellowish or variegated. In many of them there are argillaceous or shale spots and specks. At Lisbellaw, in connexion with the exposure of Ordovicians, a massive conglomerate abruptly comes in, as if it had been a shingle mass against a head, that acted as a groyne at the end of an ancient strand. The pebbles in it are remarkably hard, and are much used for road metal. The evident circumstances under which the “ Lisbellaw conglomerate” accumulated have been given in a Paper on this subject (page 504, ante). These Silurian sandstones are in general too coarse for dressed work, though well adapted for ordinary or coarse work. ‘The finer kind was extensively used in Necarn Castle, near Irvine—or Lowtherstown—the dressing being the Calp sandstone from Lis- naskea. At Castle Archdall, however, in the same neighbourhood, it was used for the quois and dressing, while the walling is an impure limestone. In Ardlogher Quarry, near Irvinestown, the stone varies, being shades of reddish-grey. It is granular, semi-crystalline, hard, ‘compact, and slightly calcareous. Lower beds mahogany-red to red; argillaceous; laminated and micaceous ; works fairly well. Mullaghfarm. Four miles from Irvinestown.—Brittle and hard to work; used for quoins and common dressing. Kerlish. TWileven miles from Irvinestown.—Various; generally coarse, conglomeritic, quartz-grain, felspathic cement, and slightly ferriferous ; others finer in texture. CarBoniFeRous.—In the disputed area of Slievebeagh dis- trict, here described as Fermanagh sandstone, there are some noted quarries. In the neighbourhood of Lisnaskea most of the stones are creamy, yellowish, or slightly greyish, good, free- working, and have been extensively used in Lisnaskea, besides other places in this and the neighbouring counties, such as Irvines- town, Enniskillen, Clones, Monaghan, and Newtownbutler. They do not, however, seem to have gone into the Dublin or other distant markets, although some of them are well worthy of notice. Stones from these quarries were used as quoins and dressing at Crom Castle, and at Necarn, near Irvinestown, for ornamental work. Tannyby. Near Lisnaskea.— Yellowish-white to reddish-grey ; finely silicious-grained ; felspathic cement; ferriferous spots; free- 562 Scientific Proceedings, Royal Dublin Society. working ; many houses in Clones and Lisnaskea are built of this: stone; but the quarry seems to be now closed. Slush Hill. Two miles from Lisnaskea.—Greyish-white and yellowish ; silicious-grained; scarcely any cement; ferriferous: stains ; some beds very friable; easily worked. Some fifty years. ago this was the principal sandstone used in Enniskillen, Clones, and Lowtherstown (now Irvinestown). Dartry mansion, Co. Monaghan, and Farnham, Co. Cavan, were built of stone pro- cured here. Now, however, the quarry is not worked, on account of the “ overbaring.”’ Kilturk, or Mount. Between two and three miles from Lis- naskea.—A somewhat similar stone; splits into long scantlings. Nearly all the gate-posts and the cut stones for the buildings of the- Great Northern Railway westward of Dundalk were procured from this quarry. Knocknalossett. Seven miles from Lisnaskea.—The stones for Monaghan College and smaller buildings were procured here. Crocknagowan. 'Two miles from Lisnaskea.—Stones used in Pres= byterian churches, Belturbet and Aughnamullan, Co. Monaghan, Clones Gas Works, and Tempo House; also wrought into tomb- stones. Eshbralby. Three miles from Lisnaskea.—Stones used in Inish- more Hall, and for pillars and dressing in Crom Castle, and in the. new work, Hnniskillen Church. It is also wrought into tombstones, and some of the beds into scythe stones. Altnabrock, or Aughnabrock. Near Lisnaskea.—Clean, fine- grained, and massive; Ulster Banks, Enniskillen, Lisnaskea, and Clones; seems to be much sought after at the present time. . Corraghy, or Elderwood. Three miles from Brookborough.—Not in repute for cut-stone purposes. Carnmore.— Pebbly, silicious sandstone; good; hardens on exposure; easily worked when first raised. ‘This stone formerly was extensively wrought into mill-stones and flax-crushers before these industries declined. To the north-east of Lough Erne, in the Calp of the “ Ulster type”’ of the Kesh district, there are good stones to be procured in Inishbo (Cow Island) in the north portion of the lake, and in different places north-east of Kesh. According to Mr. Plunkett, Kinanan—On Irish Arenaceous Rocks. 563 M.R.I.A., the beautifully sculptured cross on Devenish is cut in stone from the latter locality. [The quarries north and north-east of Kish are in the Calp sandstone; while those south-west of Kish are in a small outlier of Fermanagh sandstone. | Good hard silicious stones may be procured in the Derrygonnell Calp area, to the west of Lower Lough Erne—as in the neigh- bourhood of Church Hill. About Monea they are in general massive, with subordinate flaggy beds. Kerbstones were procured here for the village of Lisbellaw ; and in 1800 the town of Ennis- killen was paved with setts procured from this neighbourhood (G. 8. I). Some excellent stones have been noted in the CoaL-mEAsuRES to the west of the county. ‘They, however, are far away from any market or town, and are more or less difficult to get at: on which account, and also as good sandstone can be had more conveniently, they are not sought after. For the following list of quarries, with their distance from Enniskillen, we are indebted to Mr. John Wray, the Borough Engineer :— Carnmore, 23 miles; parish of Clones; Clones Church and Market-house. Mount, 15 miles; parish of Galloon; Railway Bridges from Clones to Enniskillen. Eskbradley, 15 miles; parish of Galloon ; Newtownbutler Market-house, Irvinmore Hall. Aughnabrock, 13 miles; parish of Aughavad; Ulster Bank, Enniskillen. Stonepark, 14 miles; parish of Kinawley ; Derryglin churches. Leighan, 7 miles; parish of Devenish; Bridges, Lillias river ; Kerbs, &c., Enniskillen. Rossanuremore, 15 miles; parish of Devenish; Bridge and Church, Garrison, Ballyshannon. Gilenashaver, 15 miles; parish of Innismacsaint ; Bridge be- tween Derrygonnelly and Garrison. Killroskagh, 14 miles; parish of Cleenish ; Belcoo and Holy- well Bridges. Aghnaglack, 12 miles; parish of Boho; Derrygore House, Enniskillen. SCIEN. PROC. R.D.S.—VOL. Y. PT. VII. 2Q 064 Scientific Proceedings, Royal Dublin Society. | The round tower on Devenish, in Lower Lough Erne, is built of local sandstone, and displays good work, with ornamental mouldings at the base of the cone. There is also the very hand- some cross that was exhumed when the tower was repaired about 1878. It displays elaborate and careful work. Since it has been placed in its original site it has considerably suffered from the weather. The stone, as already mentioned, seems to have been procured from the Kesh sandstone to the north-east of the lake. Sanp AND GraveL.—There is good pit sand near Irvinestown. Good river sand can be procured in many of the rivers and streams. That used at Lisnaskea is brought about two. or three miles, and what is used in Enniskillen is principally brought by boat from the River Arney, and from near Pettigoe. There is also good river sand near Irvinestown. GALWAY. The rocks north of Galway Bay are more or less granitic, and Professor Hull has stated that he considers that they are of Lau- rentian age, this opinion being grounded solely on their lithological characters. Unfortunately for this theory, although the rocks in the vicinity of Galway are more altered than elsewhere in the county, they graduate northward and westward into rocks only slightly altered, the fossils in which prove their true ages. The slightly altered rocks to the northward are not included in Pro- fessor Hull’s Laurentians, as in them are found fossils of Ordo- vician type; those, however, are to the westward. In the latter as yet no fossils have been found, but they have not been properly searched. The fossil evidence in the rocks to the northward proves that these so-called Laurentian rocks are some of the youngest of the metamorphic rocks of the Co. Galway. [It is evident that the time of the metamorphism which gives their present gneissose characters to the rocks was post-Ordovician; also that the granitic and schistose characters of the rocks are solely due to this metamorphic action, and not to the age of the rocks. | In West Galway the Ordovicians appear to have graduated downwards through the Areniy into the Cambrian, so that all are now more or less represented. In the more altered portions Kinauan—On Irish Arenaceous Rocks. 565 (Ordovician) there are quartzytes and quartz rock (gneissen), while in the less altered portions to the north and to the westward (the latter classed as Laurentians) there are grits. To the east of the county, in the mountain groups (Slieve Aughta), there are also Ordovician rocks; they are not, however, metamorphosed. To the north of the county, from the Atlantic eastward to Loughs Mask and Corrib, is a long tract of Silurian, while margining the Slieve Aughta Ordovicians, and in two places on the shores of Lough Corrib—at Oughterard and Cong—are Carboniferous sandstones. In the Calp, north-east of Athenry, are calcareo-argillaceous sandstones. CampriANn (?), ARENIG, AND Orpovician.—In general the quartzyte and quartz rock are splintery, or break irregularly; in no case are they fit for dressed work. As much better stone can easily be procured, they are rarely used, except for local rough work. Some of the grits in the less altered Ordovicians are fair stones. Situr1aAn.—Good stones from fine to coarse conglomerates. Yellowish-greens, browns, and reds; some easily worked, but not in use, as the localities are backward, and there is no demand. Have only been used in local works. When building Maam bridge, although there was excellent and suitable sandstone in the vicinity, Nimmo brought limestone by water from Cong, Co. Mayo, as he considered it cheaper. CaRBonIFEROUS.—Some of the stones are well suited for cut- stone purposes. Those at the mearing of the county, to the west of Mount Shannon, have been already mentioned (Co. Clare, p. 539). To the east of the county are other good stones, locally used in Woodford and Portumna. A little south of Cappagh, and north of Featherstone Lodge, westward of Woodford, there are stones capable of being ground to a smooth surface, and of making flagging similar to the “ Kin- nity flags,” King’s County (p. 576). Benmore. ‘Two miles from Woodford.—A fine freestone ; can be raised in large blocks ; suitable for all cut-stone purposes. Sleve Dart. North of Dunmore, to the north of the county, and partly in the Co. Mayo.—The massive pebbly grits were formerly extensively wrought into millstones. In this hill, not very long ago, was raised very extensively a very thin laminated 2Q2 566 Scientific Proceedings, Royal Dublin Society. smooth flag, locally known as Dunmore slate. This, in old times, was used for roofing instead of slate, as will be seen on the old houses in Dunmore, Tuam, and the neighbouring towns in the Co. Mayo. It made a good substantial roof, the weight of the “‘slates”’ being suitable to the heavy gales and storms of the county. They were not very unsightly; far less so than the “Stourbridge slate,’ used in Oxford, England. They, however, required heavy timbering to support them. In the vicinity of Cong and Oughterard, the tracts of Lower Carboniferous Sandstone are of limited extent, and the sandstone is but little used on account of the excellent limestone in such ex- tensive tracts in those localities. As loose stone in the islands, and along the shores of Lough Corrib, are some peculiar sandstones. They have not been ob- served in situ, and possibly may be of Silurian age; but in appearance they are more like the Carboniferous rocks. In weathering, excrescences like small gooseberries grow out from some, while others become pockmarked, small concave hol- lows weathering into them. The latter stones, when weathered, are extremely durable, as can be seen in the chancel arch of the ancient church on Inchnagoill, in Lough Corrib. This arch was restored some years ago by the late Sir B. L. Guinness, Bart., the missing stones being supplied by ashlers cut from similar stones picked up along the shore of the island. The old and new stones were so similar, that now, after a lapse of thirty years, it is hard to say which are the new ones. It is hard to explain the cause of the growing on the sur- face of the stone of the “ gooseberries.” We learn, however, from breaking a block that the “pockmarks” are due to small globular secretions of ferrifero-chloritic matter, that rapidly de- cay even when exposed to the air. After they are gone, the rest of the stone is very durable. Sanp AND GraveL. -These in this county are interesting as well as useful. In the low country, east of Galway Bay, and ex- tending northward into the adjoining counties, are the Eskers that are found more or less continuously across the central plain of Ire- land ; and where they occur there is a plentiful supply of good sand for building purposes, and also gravel for road metal. Out- side the limits of the plain, good pit sand ‘can be obtained at Kinanan—On Irish Arenaceous Rocks. 567 Knocknacarra, near Barna, three miles west of Galway, and in various places in the hills of Connemara, but more especially in the ridges between Kylemore Lake and the sea. In the West Galway hills there are also in places large accumulations of fine sand, locally called “ Rabbit Sand,” considerable dunes of it oc- curring in the valley northward of Lough Inagh. Tn connexion with many of the lakes there are considerable accumulations of good sand, that at the east end of Kylemore Lough being remarkable for its size, as apparently it is quite recent. At Lough Cooter, in the south of the county, is silicious sand which, as in the neighbouring county of Clare, already men- tioned, is famous for its use in the manufacture of scythe-boards. In the rivers and streams there are excellent sands, those of the Gort river and neighbouring hills (Slieve Aughta) being su- perior. In the north of the county there is also sand worthy of note in the Hrriff river that flows into the Killary, it being of good quality and silicious, being made up of the detritus of the Silurian sandstones from the adjoining highlands. Some of these sands appear to be suitable for glass purposes, although none of them ever seem to have been so utilized. The sea sands are of importance. Some are very suitable for building purposes; while in many places along the seaboard are tracts or dunes of blown sand (Holian drift) of greater or less extent. All of these are valuable as manure for the boggy land, some eminently so, being very calcareous, containing from fifty to seventy-five per cent. of limy matter. In the north Sound, Gal- way Bay, there are banks of sea sand made up of broken pieces of nullipores. Formerly these were extensively utilized; but they have not been as much sought after since the introduction of arti- ficial manure. [If the bog-land is impregnated with iron, the bog must he first drained before sand is applied, as otherwise the sand does more harm than good. It changes the iron into a soluble carbonate, in which state it is sucked up into the pores of the plants, where it becomes oxidyzed, and kills or deteriorates them. | KERRY. The geological groups in which sandstones and grits occur are the Ordovician, Liandovery, Silurian, Devonian, and Drift. In the Dingle promontory is a narrow tract of Ordovicians, 068 Scientific Proceedings, Royal Dublin Society. called by Jukes and Du Noyer the Anascaul beds. Adjoining these are Silurian, the upper group of which has been called the Dingle beds, and the lower group the Smerwick beds, the typical Silurians occur- ring between, as other groups. The Smerwick beds are probably in part the equivalents of the Llandovery or May Hill sandstone. These passage beds between the Ordovicians and Silurians are very similar in aspect and composition to the Devonians, or passage beds (Dingle beds and Glengariff grits) between the Silurian and Carboniferous, they both belonging to the red types, formerly. all included in the “‘ Lower Old Red Sandstone.” [The term Old Red Sandstone once included all red or reddish sandy rocks below the Carboniferous limestone; but by degrees, group after group, as geological knowledge increased, were given special names, and separated from it, till eventually the rocks that remained were those that lay between the Carboniferous limestone and the typical Silurian. Now, however, it is learned that of this remainder the upper portion belongs to the Carboniferous and the lower to the Silurian, while the intermediate passage beds are all that remain to be called either Lower Old Red Sandstone or Devo- nians. ‘These beds above the Silurians, also those below them (Mayhill sandstone or Llandovery), are very similar in aspect and composition ; so that in places one has been mistaken for the other. This wiil be referred to hereafter when describing the rocks the counties Mayo, Roscommon, and Sligo. | To the south-west of the county are the reddish to greenish type of Silurians that have been called Gilengariff grits. They in part represent the upper portion of the Dingle beds, and in part higher strata. ‘These Glengariff grits graduate upwards into the Devonians, and the latter into the Carboniferous. The Carbo- niferous rocks in this part of Kerry, that is in the neighbourhood of the bay called Kenmare river, are for the most part of the “‘ West Cork type,” they, except near Kenmare, being Carboniferous slate and Coomhoola grits ; but at Kenmare there is a small tract of _ limestone, and lower limestone shale intervening peculiarly. In the Dingle promontory margining the Silurians, and lying unconformably on them, are Devonians. These evidently are the equivalents of the Devonians to the north and south of Kenmare river, and in the adjoining portion of Cork; but in the south part of Kerry and in Cork the upper portion of the Glengariff grits is present, while in the Dingle promontory it is absent, thus necessi- tating the Devonian of the Dingle promontory to lie uncomform- ably on the Silurian (Dingle beds). In the neighbourhood of Kerry Head there is an isolated tract of Devonians. The Devo- Kinanan—On Trish Arenaceous Rocks. 569 nians of the Kerry Head district and Slieve Mish graduate upwards, through the Lower Carboniferous Sandstone (Yellow Sandstone) and Lower Limestone Shale into limestone, while to the east of the county, on the latter, are the Coal-measures. [The types here are quite different to those in the Kenmare River Valley, except as mentioned, in the vicinity of Kenmare, where the rocks are allied to those of the north-east. ] The sandstones, especially those in the Devonians and Coal- measures, were much more used in old times than at present, as now limestone is generally preferred for cut-stone purposes. The sandstones of the county were, however, principally used in the early Norman architecture; and, from these ancient structures, as exhibited at Ardfert, and in different other ancient ecclesias- tical buildings, they seem capable of making good and durable work. Oxpovictan.—The grits and sandstones of this age are not of much account at the present time, except for local purposes, as the localities in which they occur are more or less inaccessible. Some of the early structures in the area would suggest that they were capable of being used in good and durable work. Luanpovery or Passage Bens (Smerwich series) and SILURIAN. —In the Smerwick series there are many excellent stones of reddish, purplish, and brownish colour, none of which are in demand on account of their isolated and inaccessible position. In the groups next above (Ferriter Cove and Croaghmarhin series) there are some good beds; but in general they do not appear to be eminently suited for cut-stone purposes ; but in the highest group, Dingle beds, there are some first-class stones, suitable not only for cut-stone purposes, but for all sorts of heavy work, being capable of being raised in blocks of large dimensions. ‘There is, however, only a small market for them, and they seem to be used nearly solely for local purposes. In the county south of Dingle Bay, in Glen, or the valley adjoining St. Finan’s Bay, there is the old structure called after that saint. It is a cloghaun, or bee-hive house, built of a fine-grained sandstone of the locality (Glengaryff grits), without mortar. The stones in the interior of the cell were so neatly joined and put together, that when visited some twenty- five years ago they presented a perfectly smooth and even sur- 570 Scientific Proceedings, Royal Dublin Society. face, while the joints were so perfect that it was nearly impossible to insert the blade of a knife between them. Minnard. Seven miles from Dingle.—Red ; very fine; a good colour; very durable; can be raised in large blocks; was used for ashlars and face-work in the Roman Catholic church, Dingle. Mr. Deane also mentions “a green stone in the Dingle dis- trict, used for building purposes.” Ventry. — Yellowish-brown ; compact; not heavy; easily worked. Killarney.—Dark-grey ; very silicious; slightly granular. Ballycarberry (Iveragh).—Purplish-grey; very silicious; slightly micaceous. DEVONIAN AND CarBonirERous.—These vary from coarse conglo- merates to a fine-grained sandstone or grit. They are often flaggy, and for the most part are reddish, purplish, or yellowish in colour. In general they are durable, and many of them can be raised in blocks of greater or less dimensions, being eminently suitable for rough work, such as piers, bridges, and foundations. They are also capable of producing good, sound, fine work, as exemplified in the ancient structures. Rattoo Round Tower, in the Kerry Head district, appears to have been built from a hard quartzose sand- stone, procured in the vicinity; and it displays a cut-stone band round the doorway in good preservation. In Derryquin Castle, which is principally built of the slate rock of the locality, some of the quoins are, to quote Wilkinson, “of a grey-coloured sandstone resembling pumice-stone, which is soft, and works in any direction, but hardens and becomes very durable on exposure. Itis found in a long, narrow vein, adjoining the red sandstone, and occurs near the coast, continuing inland towards the Staigue fort.” Poulawaddra Wood. Three miles from Tralee.—Red; soft ; fair-working; Lord Kenmare’s castle, Killarney; new Railway Station, and various houses in Tralee. Tonenane. Three miles from Tralee.—Similar stone to that at Poulawaddra; used in both of the Roman Catholic Churches, Tralee, and other smaller structures. There are other smaller quarries in Slieve Mish besides those mentioned. Mr. W. H. Deane, County Surveyor, considers the Kinauan—On Irish Arenaceous Rocks. 571 sandstones to be easier worked than the limestones, but not as durable. From near Glenbehy were procured the stones for the ashlar work in Aghadoe, Lord Headly’s mansion, near Killarney, built some fifty years ago. - CoaL-MEASURES.—As already mentioned, there are excellent stones in places in this area, but now in general superseded by the limestone. At Barleymount is a quarry, from which the stone was taken for walling-in Aghadoe mansion. Armagh. North of Milltown.—A quarry in a good brown stone. In different places in the “ Flagstone series,”’ near the base of the Coal-measures, flags have been raised. They are not, how- ever, as well developed as in the Oo. Clare, to the north of the Shannon ; while there is nearly invariably a considerable “‘head”’ of drift, that makes them expensive to quarry ; consequently, they are rarely looked after, it being cheaper to use the “Clare flags.” At Ballylongford there are fair flags, with black shale partings, at one time quarried for the general markets; while elsewhere are small quarries, that were opened for local purposes. SAND AND GraveL.—Pit sand and gravel occur near Kenmare, near Tralee, and in the neighbourhood of Killarney; while good river sand is procurable in most of the rivers and streams, especially those having their source in Slieve Mish, which carry down a red, sharp, clear sand, used extensively in Tralee. In several places on the coast of Tralee Bay is a sea sand, which is used in Tralee with the stone saws for cutting blocks. Holian sand dunes occur in places along the coast. Tormerly the calcareous varieties of these sands, as also the shell sands dredged up in the bays and the estuary of the Shannon, were highly valued as manure, especially for boggy land. ‘These used to be carried for great distances inland on horseback, even across the hills into the Co. Limerick. Guass.—There seems to be no records of glass being manufac- tured in this county, although some of the fine sands from the Devonian hills seem well suited for the purpose. O72 Scientific Proceedings, Royal Dublin Society. KILDARE. In this county there are not any sandstones that are now used for cut-stone purposes, while the places in which sandstones occur are of very limited extent. Stones required for dressed or cut purposes are obtained from the limestone quarries at some distances, or from the granite range in Wicklow or Carlow. In the Orpovicians to the east margin of the county, and in the small protrudes at the Chair of Kildare and Red Hill, there are some subordinate grits and sandstones; while there are Car- BONIFEROUS conglomerates and sandstones margining them in places, and coming in from the Co. Dublin, at the Hill of Lyons, to the southward of Celbridge. At Newtown, some miles west of Maynooth, in an outlying patch of CoaL-mEasurss, there are also some subordinate beds of grit. CarBoniFrerous.—Red Hill, a quarry at the northern end.—Red conglomerate ; formerly quarried for millstones. Hill of Alien.—Grits ; formerly extensively quarried for mill- stones. Baillindolan. North of Edenderry.—Blackish flags ; argillaceous. and slightly calcareous; used in Kdenderry, King’s County. SAND AND GraveL.—These are common everywhere in the low country ; but some of the sands require to be washed before being used for building. In places there is a sand with a latent calca- reous cement: this, when opened in the pits, stands with a perpen- dicular wall, which does not weather or slip. This sand is valuable as a manure, and formerly was extensively used. KILKENNY. To the south-west, coming in from the Co. Tipperary, and to the south-east, coming in from the Counties Wexford and Water- ford, are limited tracts of Ordovicians (?), in the latter partly altered and associated with granite intrusions; while margining these areas are Carboniferous Sandstones. To the north of the county are Coal-measures, part of Slieve-Margy, but now more generally known as the Castlecomer Coal-field. KinaHan—On Irish Arenaceous Rocks. oe In this county, as so common elsewhere in Ireland, sandstone formerly was extensively used, but afterwards was superseded by limestone. As pointed out by Wilkinson, the ancient structures testify to the beautiful finished and durable work the stones were capable of producing, as specially exhibited in the exquisite door- way of the church in Killeshin Glen, a little south of the road from Carlow to Castlecomer. According to Wilkinson, the local sandstone was used, and this doorway, as also the doorway of the Round Tower, Timahoe, Queen’s County, were “evidently con- structed by the same workmen.” The same authority states that the columns, mouldings, and other dressings in Jerpoint Abbey also show what the Carboniferous. Sandstones are capable of being put to. Its dressings are of the Lower Carboniferous Sandstone from the neighbourhood, and still show the chisel marks after seven hundred years. It is generally believed that the stone was got within a mile of the Abbey, where there are any amount of blocks on the surface. On the authority of Wyley, it is stated that the sandstone in Jerpoint Abbey was procured in the southern portion of the townland of Ballyhowra. ‘‘The stone is very soft, composed of grains of quartz and earthy felspar, with mica to a small amount.” ‘The tradition is that, when the particular beds of stone were. reached, they were wrought underground in the form of a tunnel.” He considers the stone unfit for outside work. Wyley, in referr- ing to the ruins of an old church half-way between Knocktopher and Newmarket, states that the stone is similar to that used in Jerpoint, but that it may have been procured either in the Knock- topher or Newmarket quarries. (G. S. IZ.) As mentioned by Mr. Langrish, “ Brownstone House,”’ on éhe left bank of the Nore, between Thomastown and Inistioge, is built of a highly silicious stone of the district, greenish to purplish in colour, hard to cut, but looks very well. Some of the dressings of Inistioge Abbey, founded 1262, are of this stone and of the hard purple conglomerate which shows in Coolnahan Mountain, between Inistioge and Waterford. It is remarkable how shallow the mouldings were in comparison with those cut in the limestone. At Coalcullen, in the Coal-measures, about four miles from Castle- comer, is a stone of a light-brown tint, and easily worked; it was largely used in the restoration of St. Canice’s Cathedral, O74 Scientific Proceedings, Royal Dublin Society. Kilkenny. A similar stone occurs near Rosenallis, at the foot of Slieve-Bloom. Both are excellent for inside work. The fine-cut stone house of Castletown, near Carrick-on-Suir, built by Arch- bishop Cox more than one hundred years ago, has the south front of a darkish sandstone, apparently got in the neighbourhood. The Coolnahan conglomerate, above mentioned, rises in large squared blocks, eminently suitable for the coping of quay walls and such like works, as do also the rocks in the glen at Catsrock, near Tory Hill. Aghavaller Round Tower is built of a brown, slaty-textured grit stone, in irregular courses. Orpovician.—The grits and sandstones in this group are almost invariably hard and splintery, not being adapted for cut- stone purposes. ‘hey are, however, used for rough local work. CaRBONIFEROUS.— Very excellent stones occur in various places both in the Lower Carboniferous Sandstone and in the Coal-measures, as just now mentioned. The hill of Drumdowney was formerly famous for its millstones, which were said to be equal to the French. ‘They were sent by water to England, Dublin, Cork, Waterford, and elsewhere. Some of the largest were 5 feet in diameter, and 16 inches in the eye. ‘They were shipped with ease on the Barrow, at the base of the hill. ‘The last stones, wrought about 1876, are in Saul’s Mills, near the locality. On the same hill there was also a vein of white stone, fit for all cut-stone pur- poses of small dimensions. . Lower Carponirerous Sanpstone.—Baunbree. Near Scagh eross-roads, four miles from Carrick-on-Suir.—Brown, reddish, and yellowish ; kind; apparently durable ; used in the Roman Catholic church at Tallaghast. Annefield, or Tullynacranny, and Oldcourt. Five miles from Carrick-on-Suir.— Yellowish. The stones, except the quoins, which are limestone, for Pilltown New Church were got from Bregaun Hill, near the Annafield plantation. Drumdoney. Four miles from Waterford.—Red sandstone. Mr. P. Burtchael, County Surveyor, points out that, although there are now no quarries open, good stone ought to be procurable from the Lower Carboniferous Sandstones in the neighbourhood of Thomastown, Jerpoint, Kiltorcan, and Callan, as attested by the ancient ecclesiastical and other structures. At Coolhill, near Kil- Kinauan—On Irish Arenaceous Rocks. OVO: lamery, there are conglomerates suitable for rough work ; while at Kalmaganny there is a nice, durable yellow stone, used for cut- stone purposes in the entrance gate, Rossenarra, and in houses in the village. In the Lower Coat-mzasures at Shankill, Kellymount, and Conahy, are procured the flags known as CarLtow F acs, on account of their being carted to that town, and sent from thence by water to the different markets. The Shankill flags were considered the best, and ranged in thickness from 4 inches to half an inch. They could be raised as large as 12 or 14 feet square, but in general from 8 to 10 feet long, and 3 to 4 feet wide. At Kellymount the flags were very similar, but of a lighter colour. At Conahy they were considered inferior. Some of them were so thin, that formerly they were used for roofing. Formerly there was a very extensive trade in these flags; but as the “ clearing” or “baring” increased on the flag strata, so did the expense of getting them, and they were undersold by other flags. Since then the introduction of asphalt and other artificial footways has greatly lessened the demand for all flags here and elsewhere. In Conahy, as pointed out by Mr. Burtchael, some of the stones have natural dressed surfaces (‘“‘ edgers’’), which show well as quoins or facings, having the appearance of “‘ nice square cut- stone blocks.” Kiltown. Half a mile from Castlecomer.—Yellow and grey ; durable; easily worked ; used in the Roman Catholic Church and the wing of the Wandesforde mansion, Castlecomer. Coolcullen. Five miles from Castlecomer, and nine from Carlow.— Yellowish, kind, and works easily. Used in interior work during the restoration of St. Canice’s Cathedral, Kilkenny, and recent work at Freshford Church. Mr. Burtchael points out that the carvings of the ancient doorway of Freshford Church are greatly worn and disintegrated, the stone apparently being like the Coolcullen stone. Red Sandstone from the vicinity was used in Thomastown Abbey for the capitals of the pillars between the nave and side aisle. On them the carved foliage is much weathered, having been for centuries exposed to the elements, although originally under cover. (J. G. Robertson.) Mr. Robertson points out that, in St. Canice’s Cathedral, Graigue-na-Managh Abbey, Jerpoint 576 Scientific Proceedings, Royal Dublin Society. Abbey (?), and Grenan Castle, in this county, the stone is the same as that so largely used in Christ Church, Dublin, and in the Co. Wexford, in St. Mary’s New Ross, and in Bannow Church. Sanp AND GRAvEL.—Good pit and river sand is very general throughout the county. According to Mr. Langrish, the best sand in Kilkenny is in the valley of the Nore, at the town. There are good banks else- where along the river, but near Thomastown it is mixed with clay. The fine sand for the Kilkenny Marble Works is procured out of the Nore at Three Castles, four Irish miles from the town. Mr. Burtchael points out that excellent pit sand was got at the site of the new glebe-house, Piltown, while the adjoining town- land is called “ Sandpits.”” Good sand is also to be obtained near Goresbridge, Inisnag, Thomastown, Castlecomer demesne, and Massford; Kiltormer, near Callan; also Ballincreas, about five miles from Waterford, Ballylusky, one mile, Ballida, two miles, and Knockhouse, three miles from Mullinavat or Kilmacow Railway Station; Ballyhahy, between four and five miles from New Ross ; and, in fact, very generally over the county. In a cave at Serville Lodge, one mile from Kilkenny, on the Callan road, is a very fine sand, but quantity very small. A sand with a calcareous cement was formerly most extensively used as manure; some of the pits are so extensive, that it has been calculated that they have been worked for at least one thousand years. A sand, considered specially good on hilly ground, was known as Kilmacow sand, probably from having first been found or used in that neighbourhood. Along the tidal portions of the Nore and Suir there is a large tract of what is called manure sand, which used to be loaded into barges at low water out of the banks. It contains a large per- centage of very fine sand, and was good for heavy soils. KING’S COUNTY. The principal localities for arenaceous rocks are the Ordovicians and overlying Carboniferous Sandstones (Upper Old Red) in the portion of Sleve-Bloom that comes into the south-east of this county. ‘To the south of the county, in the vicinity of Moneygall, Kinanan—On Irish Arenaceous Rocks. OV”d coming in from the Oo. Tipperary, are small tracts of similar rocks; while at the western margin there are sandstones on the eastern flank of Knocksheegowna, that may extend into this county. At the present time none of these stones are in demand for cut-stone purposes, although some of them are eminently suitable, and were used in the ancient structures. In the ecclesiastical settlement at Clonmacnoise, although in the limestone district, and close to an excellent stone of that class, sandstones of a thin, flat- bedded character were used in some of the churches, while the old crosses were wrought out of a fine-grained quartzose sandstone. This is interesting, because, although in places such as Cloyne (Co. Cork), Cashel (Co. Tipperary), and elsewhere, the first structures were built of the local sandstone, in the subsequent ones limestone brought from a distance was used. CaRBONIFEROUS.—Kinnity.—In various places more or less near this town, along the north-west flanks of Slieve-Bloom, are small quarries. In some quarries the stones are from 1 to 4 feet thick, and are capable of being easily worked. In other quarries there are flags of a warm yellowish colour, that are excellent for inside work, as they are capable of being finished so finely as to give an even surface, in which the joints are scarcely perceptible. At Gurteen, about nine miles from Roscrea, flags are raised for use in that town; they vary from 1°5 to 3 inches in thickness. The monument to the Duke of Cumberland in the public square of Birr, or Parsonstown, is of sandstone from the Slieve Bloom district, but whether from bad construction or bad selection of the stone, it does not now give a good appearance. Sanp AND GRAVEL.—The Eskers are numerous in this comahy, and they supply an unlimited quantity of good sand; also excellent gravel for road metal. ‘The limestone gravel is much used for manure, the best being found in hillocks or at the foot of the hills. This gravel, when burnt in heaps with the paring of the bogs, gives a very rich manure for tillage. Guass was formerlyJextensively manufactured in Birr, or Par- sonstown; but when Lewis wrote, in 1837, only the ruins of the glass-house remained. In 1652 Boate wrote: ‘“ Several glass-houses set up in Ireland ; none in Dublin or other cities, but all of them in the country ; 578 Scientific Proceedings, Royal Dublin Society. amongst which the principal was that of Birre, a market town, otherwise called Parsons-town, after one Sir Laurence Parsons. .. » From this place Dublin was furnished with all sorts of window and drinking glasses, and such others as commonly are in use. One part of the materials, viz. the sand, they had out of England ; the other, to wit, the ashes, they made in the place, of Ashtree, and used no other. The chiefest difficulty was to get the clay for the pots to melt the materials in ; this they had out of the North.” LEITRIM, At the south-east of the county, margining Longford and Cavan, also in a small exposure near Drumod, are Ordovicians, on which reposes the Lower Carboniferous Sandstone. A. small exposure: of Silurians, associated with Lower Carboniferous Sandstone, occurs. near Drumshambo, to the south of Lough Allen: adjoining that lake there is a considerable tract of Coal-measures, a portion of the ConnauGut CoaL-FIELD; while farther northward there is a small outlying patch of similar rocks to the south-west of Lough Melvin. ‘T'o the west, coming in from the Co. Sligo, is a ridge of metamorphic rocks running north-east to and past Manorhamilton. These rocks have been said to be Laurentian, but this is highly improbable (page 517) ; and for the reasons given when describing” the Donegal rocks (page 548), it is probable that they are the equivalents of the Arenig or Cambrian. ARENIG (?) oR CaMBRIAN (?).—These rocks consist of green quartzyte and other schists. None of the quartzyte is suited for cut-stone purposes, but it may be used for flags, in rough work, or for road metal. OrpoviciAn.—Some of the grits and sandstones belonging to ' this group seem not to be suited for cut-stone purposes, but locally they are used for rough work. Siturran.—There is only a very small area occupied by these rocks. Good stone can be procured in quantity in some places, but they are not sought after; they are, however, used for local purposes. CaRrBONIFEROUS.—In places, but especially in the south of the county, the strata adjoining the older rocks are reddish or purplish in colour, and range from conglomerates to fine sandstone. Some Kinanan—On Irish Arenaceous Rocks. 579 beds, however, here and elsewhere are lighter in colour, being grey and yellow. Greenan. Four miles from Mohill, loose masses of sand- stone. Between four and five miles from Mohill there are several quarries in whitish and brownish-yellow stone, from which large blocks can be obtained. Between Dromod and Drumsna, eastward of the road, are different quarries. Whitish, clean, even-grained, quartzose, thick- bedded; irregularly jointed but very large squared stones can be obtained; it dresses well, but is hard to work. This is not much used; but the ashlars, groins, and sills for the Aughamore Roman Catholic church were obtained here, and have produced sharp and durable work. Cloonmorris. Between Dromod and Newtownforbes.—School- house, rubble and walling ; free-working and durable. Crummy. North-east of Carrick-on-Shannon.—School-house, rubble and walling; very free-working and durable; dressing from Creeve (limestone), Co. Meath. Curnagan, Parish of Fenagh.—A quarry once well known for its millstones. Willea. Seven miles from Manorhamilton.—Stones vary in colour and composition. The best is whitish. Fine-grained, sili- cious, works freely ; large blocks can be obtained. Other beds are greyish, slightly argillaceous or micaceous. The quarry was largely worked, but expensive, on account of a heavy bearing, and the upper stones being deteriorated by stains. Glenfarn. Nine miles from Manorhamilton.—Greyish-white, coarse-grained, silicious, argillo-silicious cement, works well. In various localities in the Coal-measure hills there are said to be good stones; but they are difficult of access. In places are seams of thin-bedded sandstone suitable for flagging, the natural surface being quite even, and, as they are hard. they are very durable. The flags from the Arigna Hills have been used in Carrick and Mohill, and those from Glenfarn in Manorhamilton. Sanp AND GravyeL.—In the country to the eastward of the Shannon the pit sand in general is good; but westward of that river, for the most part, it is inferior. Good river sand occurs in different places all over the area, but often in limited quantities. SCIEN. PROC. R.D.S.—VOL. V., PT. VII. 2R 580 Scientific Proceedings, Royal Dublin Society. LIMERICK. To the east of the county, coming in from Tipperary, are Ordovicians, overlaid by Lower Carboniferous Sandstone. Also to the south of the county, in Slieve-na-Muck and the Galtees, there are Ordovician exposures, with Lower Carboniferous Sandstone mar- gining. In the plain of Limerick are a few outlying exposures of the latter rocks; while in places in the limestone, as adjuncts of the subordinate inlying traps, are tuffose sandstones. To the west of the county are Coal-measures, a part of the Munsrer Coau-FIELD, while small outliers of similar rocks are found at Ballybrood and Slieve-na-Muck. Orpovictan.—The grits in this group, as elsewhere, are of little value for cut-stone purposes, although useful locally. Carponirrrous.— These range from a conglomerate to fine sandstone and grit. Although not now much in demand, in places there are superior stones in the Lower Carboniferous Sandstone. Doon.—In this neighbourhood there is specially fine freestone, which at one time was largely shipped to Hngland and other places. The stone is tough, equal to heavy bearings, and can be raised in long scantlings—on which account very suitable for stair- cases. It was used for the staircases in Clarina and Adare manors. Glenstal Castle was built of a good whitish stone procured in the neighbourhood of Morroe. St. Oswald’s, near Ballingarry, was built with stone procured from [nockfierna. Some of the stones in the quarry were easily worked, while other beds were as hard as flint. The house has been built over thirty years, and Captain Wilkinson states the -stones seem to have hardened. Stone from near this quarry was used in the Ballingarry Court-house and Church, but not for cut- stone purposes. Mr. Horan, County Surveyor, is of opinion that good stone might be got in this hill if a quarry was opened sut- ficiently. At present the stone is principally used for rubble work. Near Ailmeady there are quarries in silicious grits. In the Slieve- na-Muck range, near Galbally, fair stones might be procured. At places in the limestone associated with the intruded and bedded igneous rocks are tuffs, that range from massive agglo- merates through conglomerates into fine sandstones, often calca- Kananan—On Irish Arenaceous Rocks. 581 reous. They are purplish, reddish, and greenish in colour. Where fine-grained they cut easily and well, but are not durable. A green variety, raised out of an adjoining quarry, was extensively used in the building for the new railway station at Limerick. An agglomerate, that rises in massive, squarish long blocks, was used in the ancient megalithic structures in the neighbourhood of Lough Gur. In general the CoaL-MEASURE grits are very quartzose, and hard to cut or dress, and are not favourably thought of. They have, however, been used in many of the bridges. In places there are excellent flags, similar to those imported from Money Point, Co. Clare. ‘These have, to some extent, been worked in the neigh- bourhood of Athea, and also at Barna; and the latter were used in Newcastle and Rathkeale. When first raised, they are soft and easily tooled, but afterwards they become very hard. They also occur in the hills near Glin. Sanp AND GRAVEL.—Pit sand occurs in the neighbourhood of Limerick, near Kilmallock, near Rathkeale, and in other places. Good river sand can be procured from the Shannon above Lime- rick, in the Deel river, near Newcastle, and in greater or less quantities in the mountain streams. Shell sand for manure was formerly procured from the estuary of the Shannon. ‘There are also in places, at about the 240 feet contour line, accumulations of gravel suitable for road purposes. LONDONDERRY. The sandstones occur in the Ordovician, Llandovery (?), Silurian, Carboniferous, Triassic, and Jurassic groups. ‘To the south of the county, coming in from the Co. Tyrone, are older rocks, probably the equivalents of the Arenig or Cambrian, that are metamorphosed into gneiss and schists. Orpovicrans AND LiaNnpDoveRy (?).—These are more or less metamorphosed. Some of the less altered sandstones cut fairly well, but are not in request, as better stone can be procured in the Carboniferous. A peculiar, finely-laminated sandstone (book or leaf sandstone) ; is very good for walling purposes, and has been exten- sively used in the neighbourhood of Derry. Prehen (Derry).—Bluish ; of a slaty nature. Does not stand 2R2 582 Scientific Proceedings, Royal Dublin Society. well, except on the beds, as it is liable to peel and to break at the joints. Used in the Public Offices, Diocesan Seminary, Foyle College, Gwynn’s Institution, Roman Catholic Cathedral, &e. Sirurtan.—The rocks belonging to this formation are of the “ Lower Old Red”’ type, being reddish and purplish conglome- rates and sandstones. ‘They occur to the west and south-west of Draperstown. They are not a desirable stone. -CarsoniFerous.—There are some first-class stones in these rocks, as hereafter mentioned. They have not, however, been as much in demand as they ought to be, on account of the expense of land carriage, which has allowed them to be cut out of the market by stone imported from Scotiand. These stones range from coarse quartzose conglomerates into. fine silicious grits and sandstones of yellowish shades. The latter are easily worked when first quarried, and harden on exposure. They are good for both inside and outside work, and in the old buildings, in which they were very generally used, they exhibit their soundness and durability. Gort-a-hurk, near Maghera.—Oreamy-white, with subordinate greenish beds; very silicious, granular, but little cement; does. not work freely. The beautifully and elaborately sculptured door- way of Maghera ancient church, wrought out of this stone, proves its eminent durability. It has been used in Magherafelt. Fullagloon and Ranaghan. ‘Three to four miles north-west of Maghera.—F lags, tombstones, door-steps, sills, and scythe-stones. procured in different places; principally worked near the road to the south of Ranaghan. Carnamoney (Moyala river). Four miles south-westward of Maghera.—Grey and yellowish, silicious; easily worked; used for tombstones, sills, quoins, &e. Drunard. Near Draperstown.— Bluish. This stone, some years ago, was opened on by the Grahams of York-street, Belfast, and was considered by Mr. A. P. Sharpe, of Dublin, to be a first- class stone. At that time, however, on account of backward situa- tion, and the great expense of getting the stone from the quarry to the market, the enterprise had to be abandoned. At one time the stones from this part of the county were in considerable demand, and were carted to Ballyronan, on Lough Neagh, where they were shipped to Belfast and other places. Kinanan—On Irish Arenaceous Rocks. 583 Drumquin.—Y ellowish, fine-grained, works freely; when raised, very wet, but dries on exposure; not very durable. ‘This stone was formerly much used in Coleraine and Limavady. Altmover. West of Dungiven.— Various quarries, varying from white and creamy to reddish greenish-grey; semi-crystal- line; argillo-silicious cement; some beds with sand holes. Thin- bedded stones used as flagging in Limavady. From these and other quarries are procured the stones known as the Dungiven stone; and in these different quarries special beds must be better than others, as there is a diversity of opi- nion as to its quality. From a quarry then known as “ Bally- hagan” were procured most of the stones for the Bishop of Derry’s (Lord Bristol’s) palace at Ballyscullion ; but the portico was built of Ballycastle (Co. Antrim) stone (page 532). To the north of Dungiven a quarry has been opened of late years, from which a very superior stone is procured. Of the stone sent to the Belfast district Mr. Grey states: “This is very excellent stone, of light colour, free from iron, very durable, hammers and tools well; works freely for dressings, sills, and quoins, as well as for rubble work. Has been used in Coleraine Church; in Parish Church, Northern Bank, and Pres- byterian Church, Kilrea; Protestant Hall, Belfast; and in the Coastguard Stations at Moville and Rathmullen, for-quoins, sills, and dressings.” They have also been used in the Diocesan Seminary, London- derry; in the Lunatic Asylum (see Gortnagluck List, Co. Tyrone, page 608) ; in St. Columb’s Cathedral and the Roman Catholic Parochial Hall. The Provincial Bank, Ballyshannon, Co. Donegal, was to have been faced and dressed with Mount Charles stone ; but, when it was half up, the supply seems to have failed, and the cut-stone in the upper portion is from Dungiven. Of the latter Mr. J. Cockburn writes: ‘“‘The stones seem to have been carefully selected, as they are better than most specimens of it to be seen elsewhere in evenness of texture, firmness, uniformity of colour, and freedom from sand holes.”” They have been used for steps and dressings in different private residences in north-east Donegal. Glenconway. Hight miles from Limavady.—Yellowish ; easily worked; has been used in Limavady, Londonderry, and else- where. 084 Scientific Proceedings, Royal Dublin Society. Walk Mills. Three miles east and south-east of Limavady.— Brownish and reddish flags, from 8 to 5 inches thick. Triasstc.—Reddish and orange ; locally called “‘ Red Free ;”” very easily worked, but friable, and in general not durable; used locally. J uRassic.—Thin-bedded sandstones occur as subordinate layers in the band of Lias that margins in places the Cainozoic plateau of Antrim dolomyte. They have been used as flagging, but are soft, and liable to get damp. Formerly they were in great request as scythe stones, a considerable trade in them having been carried on at Magilligan. Creracrous AND Hocene.—The arenaceous adjuncts of these rocks are the Frinrs and Acatzs, the latter occurring principally in the lower Eocene Conglomerate. Anciently they were wrought into war implements. They have been previously mentioned in the description of the Co. Antrim (page 534). Sanp and GraveLt.—Good pit sand, if well selected, can be procured near Coleraine, and Magherafelt, in Bishop’s Demesne, Derry, and in the vicinity. Good river sand is found near Derry and near Newtownlimavady, being very good along the River Roe. A fair quality of sea sand is procured from the sand-banks at. Magilligan. In Londonderry, in 1820, a glass manufactory was established in the old sugar refinery, Sugar-house-lane, but was closed after a few years. It is not now known where they got their sand. LONGFORD. To the north of the county, coming in from Leitrim and Cavan, are Ordovicians, which are margined by Lower Carboniferous Sand- stones. At Granard, however, there are peculiarities, the sandstones being interstratified with the limestones. In the neighbourhood of Longford also, south-west of Ardagh, there are outlying expo- sures of Ordovicians associated with more or less marginal belts of Carboniferous Sandstone ; while in the Cap there are also arenaceous rocks, some of which will be mentioned. Orpovictan.—Here, as elsewhere, the grits and sandstones do not seem to be known, except locally, as none of them appear to be eminently suited for cut-stone purposes. Kinaunan—On Irish Arenaceous Rocks. 589 Carsonirerous.—These rocks, although of small extent, are locally in fair request, notwithstanding that excellent limestone can. be easily obtained in the neighbouring counties; and, as men- tioned in the previous Paper, the latter class of stone for some years has been principally sought after for cut-stone purposes. In the Granard district, in general, the stones are whitish-grey or bluish, splintery, and hard to work, and are seldom used, except for walls. There is, however, in some beds, a better class of stone, of a yellowish colour, that works freely. Ballinacrow. Two miles from Granard.—Yellowish; quartz grains, little cement, micaceous ; spotted with iron and calcareous matter. Dalystown. Four miles from Granard.—Steel-grey; hard, silicious; spotted with calcareous matter. Ballinamuck. Twelve miles from Granard. — Yellowish ; coarsely granular, white grains in an argillo-silicious cement. Here are also to be obtained hard flags of good sizes, that have been used in Longford. Ardagh.—Greyish-white ; open and porous, white grains in a silicio-caleareous cement; ferruginous spots; used in Granard. Glack. Near Longford.—Over a large tract of country there 1s a coarse conglomerate. On this conglomerate, in the quarries near Longford, there are sandstones. The latter are yellowish, but becoming white on exposure; coarse, white quartz grains, with yellowish argillo-silicious cement; can be raised in blocks, 6 feet square, and 4 feet thick; used for the buildings in the town, and also wrought into millstones for oat bruising. Edgeworthstown.—In the Calpy limestone are good flags, very similar in appearance to the Carlow flags. Sanps anp Gravets.—Pit sands procured near Granard, Bally- mahon, and Newcastle; elsewhere scarce. LOUTH. The major portion of the county is occupied by Ordovicians. To the north, at Carlingford, and on the south-east flanks of Sheve- Foye, are small thicknesses of Oarboniferous Sandstone, and also to the westward, near Ardee. In the Oxpovicrans there does not appear to be any quarry of 086 Scientific Proceedings, Royal Dublin Society. much note, although in various places there are quarries. "When of fair sizes, they are worked for local purposes. Although the stones are hard, some of them dress fairly well. CarBoniFERouS.—According to Traill, the sandstones near Carlingford are not of much value. (G. S. IL) Kilpatrick. Near Ardee.—Grey, weathering pale-brown, cal- careous cement; used for building purposes. Similar rocks are exposed in the bog, two miles N. N. W. of Ardee. (G. S. IL) In the celebrated ecclesiastical ruins of Mellifont and Monaster- boice the sandstone dressing used, according to Wilkinson, seems to be Carboniferous Sandstone from the Co. Meath. They and the two large crosses at the latter place are in good preservation, except some badly-selected micaceous stones. In St. John’s Gate, Drogheda, the unequal weathering of sandstone and limestone is illustrated. Where the sandstone came from is not known. [ Mr. Sharpe, the well-known Dublin builder, who has carefully traced up the sand- stones in some of the ancient buildings, is of the opinion, as already mentioned (Intro- duction, page 510), that the stones at Mellifont are from Doulting, near Glastonbury. | SAND AND GRAvVEL.—Good pit sand occurs near Ardee, and a loamy sand near Dundalk. River sand is obtained in the Boyne, at Oldbridge, for use in Drogheda. On the coast are dunes and tracts of A#lolian sands, at one time in request as an agent for making the stiff clays of the county friable. They seem now to be very little used; they ought, however, to be valuable fertilizers. MAYO. To the south of Clew Bay are metamorphic rocks, with subor- dinate intrudes of granite. These, to the south and eastward, are overlaid by Silurian or Carboniferous rocks. North of Clew Bay, occupying the north-west portion of the country, and extending in a narrow tract eastward by Westport and Castlebar across the county into the Co. Sligo, there are also metamorphic rocks and granites, which are overlaid either by Silurian or Carboniferous. Of the metamorphic rocks in the east and north-west portions of the county it has been stated that they are of Laurentian age ; Kinanan—On Irish Arenaceous Rocks. 587 ‘but, as already pointed out, this is highly improbable, if not impossible. Some of them, undoubtedly, are the equivalents of the Ordovicians, and the rest are probably the equivalents of the Arenig, or possibly part of the Cambrian. North of Balla, to the eastward of Castlebar, is a small outlying mass of Coal-measures. CampriAn, or Arentc.—These, as just now mentioned, are, for the most part, metamorphosed into schist, gneiss, or granite. There are, however, some quartzytes and quartz-rock, capable of being raised in large blocks suitable for rough work ; but they are seldom used, as other stones, as easily procured, are preferred. They can also be utilized as road metal. Orpovictan.—These, like the older rocks, are in general meta- morphosed; but in places, more especially to the eastward, north of the eastern continuation of the Erriff valley, they are not. In the unaltered portions there are some very massive grits and sand- stones that would be valuable for piers, foundations, and such rough massive work, but that they are backward and very inacces- sible. There is also a pebbly quartzyte, very suitable for piers ; but it does not appear to have been much utilized. Between Foxford and Swinford are flags of great dimensions. Symes considered that they are due to water freezing in the joints that split off huge plates, some as large as the side of an ordinary —eabin. They might be more utilized than they are. In the north-west of the county (Erris), ‘‘ between Benmore and Belderg Harbour, also along the coast of Broad Haven, between Dawish Cellar and Blind Harbour, flaggy quartzytes, in unlimited quantities, light-browns and greys, may be had of any sizes and thick- nesses; these are well suited for street flagging, and some beds are easily and cheaply wrought into paving setts. ‘The flags between Dawish Cellar and Blind Harbour could be shipped from either - Gubatnockan or Belmullet, and those of Benmore from Belderg. lt is proposed to join the latter quarries by a tramway to the harbour and erect a pier there.”—(A. If Henry.) Sinurtan.—These rocks are both of the ordinary and “ Old Red Sandstone” types, the latter predominating, and consisting, for the most part, of purplish or reddish conglomerates and sand- stones, while the others are principally shades of grey, blue, and green argillaceous rock, in which are grits and sandstones. In one tract, east and south-east of Louisburgh, they are in part meta- 588 Scientific Proceedings, Royal Dublin Society. morphosed. Some of the purplish sandstones and conglomeritic rocks can be raised in large blocks, and would be suitable for cut- stone purposes; but, on account of the facilities for procuring excellent limestone, they, in modern times, have been rarely thought of, except near Newport, where some of them have come into favour. In 1845, Wilkinson thus writes of the sandstone then in favour in that town :—‘‘ It varies from a conglomerate or coarse-grained sandstone to a very hard red and brown and whitish-coloured grit. This stone is now generally used for all purposes, and is quarried within a mile of the town on the east. The bridge of Newport has the spandril erected with a fine red- coloured grit obtained from the neighbouring mountains.” [In this neighbourhood the Silurians of the ‘‘ Old Red type”’ and the Lower Car- boniferous Sandstones are rather mixed, being often very similar in colour and texture, so that, except from personal examination in the quarry, one cannot be distinguished from the other. Most, if not all, of the sandstones mentioned by Wilkinson as used in Newport seem to have come from the tract of Silurians a little eastward of the town ; but some of them may possibly have been obtained from the Lower Carboniferous. Sandstones of the vicinity. ] To the east of the county, between Charlestown and Ballagha- derreen, there is a tract of Silurians. In this the rocks above and below are of the ‘‘ Old Red Sandstone” type, while between, are green sandstones, with subordinate calcareous and shaly beds that contain Silurian or Llandovery fossils. [The green sandstones are peculiar, because, except in colour, they are identical in composition with the rocks above and below them. The fossils occur in three horizons. Those below are of Llandovery types; the middle beds contain fossils of Wenlock types, while in the upper beds they are again of Llandovery types. This, therefore, is an example of the places in which fossils typical of English groups cannot be taken - as a positive indication of age ;—these rocks, as suggested by Griffith, Jukes, and Foot, are probably in part the equivalents of the ‘‘ Dingle beds’”’ and the ‘‘ Glengarriff grits’’ of the counties of Cork and Kerry: that is, the upper beds of the Silurian closely allied to the Devonians or the Passage Beds between the Silurian and the Carbo- niferous. | In both the rocks of the reddish and greenish types are some good workable stones, that have been extensively used for building purposes, both in Ballaghaderreen and Charlestown. Some of them seem to be capable of producing good dressed work; but, as they have been principally used in rough walling, their capacities Kinanwan—On Irish Arenaceous Rocks. 589: have not been fairly tested; more especially as only the surface. stones have been used in these buildings. CarponiFrERous.—For the most part these occur as bands mar- gining the older rocks, but in places in the limestone they are interstratified ; some of them are fit for all cut-stone purposes, although none of them have come very prominently forward on account of the good-class limestone of the county, which is pre- ferred by the workmen. Meelick. Near Killala.—Brownish grey ; quartz-grained, with little cement; easily worked, large blocks can be procured; ex- tensively used in the piers and quay-wall at Ballina, and in the neighbourhood. Crossmolina. A good freestone to the westward of the Deel river. Between Foxford and Swinford are flags, some so thin that formerly they were used for roofing instead of slates. Farm quarry. At Westport there is a peculiar stone. It occurs in the upper beds of the limestone quarry. It is thin- bedded and square, on account of the systems of joints that cut across it, these joint-lines being glazed with a film of quartz. One system of the joints is perpendicular, the other slightly oblique ; but if the stones are properly selected and laid, the natural faces. produce a perfectly even perpendicular wall, having a surface that looks like finely-cut limestone, laid in narrow courses; they were used in Lord Sligo’s house at Westport, the dressings and other cut-stone being of hmestone. In the new church at Westport, Carboniferous Sandstones were used; but, unfortunately, dry stones and newly-quarried stones were mixed promiscuously, and consequently the drying and shrinkage of the latter have caused ugly open joints and uneven settlements. The old church and round tower at Awghagower were built of the local red stone. It seems to have worked freely and well, but is not very durable. Pouilsharavogen. Six miles from Swinford.—This stone, although at the east of the county, is in general similar to that described as occurring at Meelick, near Ballina. In places, however, the stone is conglomeritic or pebbly ; and, under such circumstances, Wilkin- son considered it better adapted for cut-stone purposes. This. 090 Scientific Proceedings, Royal Dublin Society. ‘stone has been very generally used in Swinford, Claremorris, and the neighbourhood, and of it was built the round tower of Meelick, south of Swinford (not the Meelick previously mentioned, near Kcillala), of which the stones are now in good preservation. Stones that have been used for flagging are recorded as fol- lows :—Thin-bedded sandstones at Carrickryne, Ballycastle, Meelick, and Carns; used in Ballina. Glenisland, soft when quarried, but afterwards hardening; used in Castlebar; Gormancladdy, Killedan, Balla, and Carrowcastle; used in Swinford; and Curveigh, for use in Westport. There is a very thin, smooth flag, called “‘ Dunmore slate,” raised principally in the Lower Carboniferous Sandstone of Sheve-Dart, near Dunmore, partly in counties of Mayo and Galway. These, in old times, were extensively used in place of slate, as will be seen on the old houses in Castlebar, Crossmolina, Ballinrobe, and other places. This “slate” has been previously mentioned in the county Galway. Besides Slieve-Dart, it also occurs in some of the other localities for Lower Carboniferous Sandstone, as between Foxford and Swinford, but was not as extensively worked as in Slieve-Dart. Sanp AnD Gravet.—Good pit sand for building purposes can generally be easily obtained in the low country ; the Eskers in the “Plains of Mayo” affording not only that, but good sand for manure, and gravel for road metal. The river sands are also good ; they occur in various places along the rivers and streams. There is also sea sand in different places; near Ballina there is a consider- -able supply. On the west coast of the barony of Murrisk there are olian -sands, some parts of which are in cultivation and yield good crops, ‘especially potatoes. ‘There are also extensive tracts near Blacksod Bay, and smaller ones near Broadhaven; these seem to have been extensively cultivated formerly for potatoes and barley, but not so much of late years. 2 A. good glass sand occurs near Belmullet, which has been used. a little for glass manufacture. KonanaAn—On TInish Avenaceous Rocks. 59k MEATH. To the east of the county, near Balbriggan, coming in from the county Dublin, to the north-east coming in from Louth, and to the north-west coming in from Cavan are Ordovicians—the last two being connected by the strip of similar rocks in which Kells is. situated. In general sandstones are not exposed at the base of the Carboniferous, and in places there appears to be no room for them; they, however, appear near Oldcastle, to the westward of Kells, and between Navan and Drogheda; while Mr. Cruise states there. is a small patch of conglomerate on the Ordovicians at Stramullen, at the mearing of the Co. Dublin to the west of Balbriggan. Elsewhere beds of sandstone have been observed interstratified with the limestone. On the Carboniferous Limestone to the north, near Nobber, between Drogheda, Navan, and Maynooth, and near Trim, are outlying patches of Coal-measures in which are fair stones. At the extreme north of the county, near Kingscourt, there is a small tract of Trias. Orvovician.—None of the sandstones or grits of this age seem to have been, or are at present, in favour for cut-stone purposes, nor have they been much used for general work, as the associated slate rocks, except in the tract near Balbriggan, are eminently suited for such work, and in old times and subsequently were, and are, much used. CarsonireRous.—In the small patches of Lower Carboniferous Sandstone, near Oldcastle and westward of Kells, there are sand- stones of reddish, brownish, and yellowish shades of colour. These were used as quoins in the old church of Kells, while the round tower was nearly entirely built of them. ‘They are not very dur- able, but are of an even texture, and have weathered evenly. Between Navan and Drogheda, along the margin of the Carboni- ferous rocks very similar stones have been quarried in places. They vary a little in colour; some are streaky or variegated, while they may be argillaceous or quartzose, some being very hard. They are not a good class of stone, yet they are very generally used, and the Round Tower of Donaghmore was built of them. Here, as also in the localities to the westward, some beds are capable of O92 Scientific Proceedings, Royal Dublin Society. being wrought into flags, and these have been used in Kells and elsewhere. Hayestown. Fourteen miles from Kells.—Brownish to yel- lowish; quartz grains; calcario-silicious cement; not very durable ; works easily. To the north-west of Navan there are some sandstone quarries locally used. In the tracts of Coal-measures there are some good stones reported; but if local use is ignored, none of them have been worked except in the Nobber district, and there only sparingly, as the bad roads and accommodation make the quarries difficult of access. Some of the thin-bedded sandstones, as near Garristown, make good and strong flags; English flags, however, being easily and cheaply obtained, seem to have prevented their being much worked. Cortubber. Near Kingscourt; greyish-white; quartz grains; very little felspathic cement; finely granular; works freely and well. Carricklick. Seven miles south of Carrickmacross. Greyish- white, but unevenly coloured; silicious grains; very little cement ; fine-grained ; works freely and well; large blocks can be procured. Lough Fea House was built of this stone; used extensively in Carrickmacross. A limited quantity of flags can be raised here, which can be manufactured into hearth-stones. Trras.—The “Red Free” of this area seems to have been very little used, and only locally. Sanp AND GraveL.—Pit sand, excellent for building purposes; is very general; although sometimes it is loamy. In the cutting for the Meath Railway an inexhaustible supply of sand and . gravel suited for road purposes is exposed; some of it is good manure sand, but is not much used, so much of the county being under grass. MONAGHAN. Occupying all the central portion of the county are similar Ordovicians to those that have been described in Armagh and Cavan, which lie respectively to the north-east and south-west. Here, as in those counties, the grits are very little used, the Kinanan—On Trish Arenaceous Rocks. 593 associated slate being much preferred for general purposes ; although not capable of being used in dressed work. Fair flags have been raised in a few places, as in Dartree, which lies north and north-west of Clones. To the south of the county, in the neighbourhood of Carrick- macross, is a small tract of Carboniferous rocks, principally lime- stone: this is overlaid by Coal-measures, and the latter, uncon- formably, by Triassic rock ; the principal portions, however, of the outlier of the later rocks are situated in the neighbouring counties of Cavan and Meath. To the north of the county there is a second area of Oarbo- niferous limestone. And margining this to the southward, and lying on the Ordovician, is a narrow tract of Lower Carboniferous Sandstone, on which Clones and Monaghan are situated; while further northward are the rocks of the “ FERMANAGH SERIEs,” or Lower Coal-measures of the Fermanagh type (ermanagh, p. 560). In the Fermanagh portion of the Slieve-Beagh district there are different quarries of former and present note; but eastward in this county there are none, although the “‘ Fermanagh Sandstones”’ extend into it; also in places on the flanks of Carnmore superior stone have been procured. In Castleblayney, Monaghan, and Clones, most of the stones used for cut-stone purposes were brought from the quarries in the Fermanagh portion of Carnmore or quar- ries in the Lisnaskea district, or from the Clogher district (Lower Carboniferous Sandstone), Co. Tyrone. In the south of the county, at Carrickmacross and its neighbourhood, the sandstones have been brought from Carrickleek, Co. Meath. Carnmore.—Yellowish-reddish. Chiefly quartz grains; fer- riferous spots; somewhat friable; works freely. On the summit of the mountain there was an extensive quarry for millstones ; which, after being wrought in the quarry, were let roll down the mountain, and conveyed to Scotstown, where there was a depdt. On the northern side of the hill there is a soft whitish freestone, and on the southern a hard reddish grit. Knocknatally.—A. good freestone, formerly extensively quar- ried for use in the neighbourhood. Emyvale. Southward of.—Fermanagh Sandstone (?), used in Monaghan. In the parish of Donagh, to the north of Monaghan, excellent 594 Scientific Proceedings, Royal Dublin Society. freestone was formerly quarried in different places, and the great entrance to Caledon House was constructed of this stone. Sanp AND GraveL.—Pié sand of a good quality is very general in the county, while river sand can be obtained in the: rivers and streams. Gravel can be procured from the Hskers: those in the Tehallan district being noted for their wearing qualities, they for the most part being made up of hard jasperry pebbles. [In the high level portions of the counties Monaghan, Tyrone, Fermanagh, &c., there are gravel ridges that have been called ‘‘ Eskers’’; they are not, however, true Eskers similar to those of the great central plain of Ireland. The true Eskers are of marine origin, the ridges being due to the colliding of tidal currents, and all occur below fixed levels, which are the maximum heights of the Esker Sea; their height varying a little, as in the seas of the present day, the tides rising higher in the bays than in the open. The gravel ridges of the high levels, and in some places even on the lower levels, of the above-named counties, are for the most part of a different origin, being similar in aspects to the sands, gravels, and other drifts found in the: valleys and plains and slopes associated with the Alpine regions, such as those found in connexion with the ‘‘ Foot Hill’’ of the Canadian Rockies. In some of the low counties, Monaghan and Fermanagh, &c., the marine and glacial gravels seem in part to be- mixed or to graduate into one another. | QUEEN’S COUNTY. The greater portion of this area is occupied by Carboniferous- Limestone ; but to the north-west, surrounding small exposures of Ordovicians, are tracts of Lower Carboniferous Sandstone ; while to. the south-east, in Cullinagh and the northern portion of Slieve- margy (Letnster CoaL-FIELD) are Coal-measures. The Ordovician grits are rarely used, even for local purposes, the associated slates. being preferred. Lower CarsoniFrerous SanpstonE.—In colour these are from. whitish-yellowish to brownish, and streaked. Some are argilla-. ceous, they not being as durable as those having a silicious cement. These sandstones have been very generally used in the neighbour- hood. ‘They have been largely used in Mountmellick, a soft, sili- cious stone in that neighbourhood being at one time extensively manufactured into chimney-pieces and hearthstones. In the churches of Abbeyleix, Slieve-Bloom sandstone and Ballyullen limestone were used in the dressings. Ballyfin House and the chief entrance lodge in the Slieve-Bloom district were built of locak KinaHan—On Irish Arenaceous Rocks. 598d stone; in the latter are some hastily selected, which have stood badly. At Clonaslee and Rosenallis there is a thin-bedded stone, very extensively used in the county for flagging; they cannot be obtained of large sizes, but are very dry; when first raised they are soft, but rapidly harden. Stones for cut work can also be procured; but, on account of the ungainly shapes of the blocks, are expensive to dress. Clara Hill, Clonasiee.—Yellowish ; very silicious ; fine-grained ; micaceous ; ferriferous spots. Tinahinch. Three miles from Clonaslee. — Greenish-white ; silicious-grained ; argillaceous cement; partially carbonaceous matter. Glenbarrow. Three miles from Clonaslee.— Grey ; silicious- grained ; ferriferous spots. Rosenallis Mountain. — Westward of Mountmellick. Very similar to the Clara Hill stone. Baillysally. Ten miles from Roscrea, where it has been much used.—Yellowish to lightish-brown. Is soft when raised, but hardens on exposure. Works easily. CoaL-MEASURES.—In general, these stones are not now looked after, yet that they are capable of good work can be seen in the previously-mentioned doorway of Kalleshin Church, Co. Carlow (page 537). In some of the ancient buildings a thin-bedded grit has been used, also in latter years at Clogerennan. As those used at Cloggrennan were not suited for cut-stone purposes, other material was used for the dressings. Cloggrennan.—Dark-greenish grey; fine-grained; close; dense ; flagey ; not good for cut work. Corgee and Hollypark. In the Collieries.—Good strong flags were formerly rather largely worked. ‘These flags, on an average, could be raised 12 feet square, the largest raised being 22 feet long and 12 feet wide (G’. S. IL) ' Derryfore. Hast of Abbeyleix.—Olive, thick sandstones and flags. SanpD AND GrAvEL.—Both of excellent quality occur plenti- fully in the Eskers. In some of the streams coming down from both the Lower Carboniferous Sandstone and Coal-measure hills there are sharp silicious sands. SCIEN. PROC. R.D.S.—VOL. V., PT. VII- 258 596 Scientific Proceedings, Royal Dublin Society. ROSCOMMON. To the north and south-west of Lough Allen are Coal-measures— a small portion of the Connaveut Coat-Fietp. To the southward of these, extending from the north-west margin of the county eastward, past. Lough Key nearly to the Shannon, are Stlwrians of the “ Old Red Sandstone” type, which are margined southward and eastward by Lower Carboniferous Sandstones. To the west of the county, both north-east and west of Castlerea, and farther south-west in Slieve-Dart, are patches of similar rocks, as also south-west of Roscommon; while to the north-east of the same town, in a south-west and north-east direction, is Slieve-Baun, near which small exposures of Ordovicians are margined by Lower Carboniferous Sandstone. The Orpovictan grits, which are of small dimensions,-are more or less inaccessible, and are very little used, even locally. Srnurtan.—These occur in the Curlew Mountains. Of these there is a great thickness, and some of them are fair working stones; but in general they are hard, gritty, and of bad working quality and colour. ‘They are not in request, as limestone is pre- ferred; and if sandstone is required, those belonging to the Lower Carboniferous Sandstone are used. Associated with these sandstones are felspathic tuffs. Although these are more of the nature of argillaceous than arenaceous rocks, they ought here to be mentioned, as in places the one graduates into the other. Some seem as if they would cut well; but as they are in general in somewhat inaccessible or inconvenient places, they have only been used for farm purposes. Lower CaRBonirerous Sanpsrone.—In the different exposures of these rocks there are stones of more or less note. At Tarmon, near Boyle, there is a bluish-grey stone, hard and compact; but, on account of the numerous joints, it is incapable of being raised in large lengths. The strata varies from 10 to 24 inches in thick- ness; it has been used in many of the buildings in Boyle, but is more suitable for rubble than cut-stone purposes. St. John’s Hole. . An historical quarry.—This lies north of the river near Boyle. Greyish; good, but hard; hasfbeen used ex- tensively in Boyle and the neighbourhood, as in the bridge and Konanan—On Irish Arenaceous Rocks. 097 other public and private buildings. According to Wilkinson, it was also used in the old house of Rockingham that was burnt down some years ago; the new house, built in 1863 and 1864, is of limestone from Ballinafad, Co. Sligo. In the bed of the river adjoining “St. John’s Hole”’ is said to have been situated the quarry from which the stones were pro- eured to build Boyle Abbey. Of this ancient structure, Wilkinson writes :—“ Excellent work of every kind, from common dressed stones to carved mouldings and ornaments, and its lofty arches display a skill in construction far superior to the present day. The stone has resisted exposure to the weather well, some of the marks of the tools being still visible.” Further, he states in refe- rence to the site of the old quarry :—“ It is likely that by well- directed efforts the bed of the river was temporarily diverted in order to get at stone which, from being constantly saturated, had — not become so hard as that which was comparatively in a dry position.” [This raising of stones out of the bed of a river or stream seems to have been not uncommon with the early builders, as in different places holes are pointed out so situated, which tradition states were quarries where the stones were procured for adjoining structures. Besides other places, such is the case in the river at Drombogue, ‘In the parish of Kilmacrenan, Co. Donegal, as from an excavation in the bed of the stream it is said the stones to build the adjacent Abbey of Douglas have been procured. A few years ago, during a dry summer, this hole was pumped out, and a rude set of steps were found from the surface to the bottom. | In this county, as is so common elsewhere at the present time, the masons prefer the limestone for cut-stone purposes, so that the sandstone is in general only used for walling and rubble work, as it is easily roughly squared ; in some cases it is used for quoins, window-sills, steps, and such like, while from St. John’s Hole can also be procured excellent flags, with a natural smooth surface, of large sizes, and from 5 to 6 inches thick. They, however, are ex- pensive and difficult to get at, on account of the necessary pumping to keep the quarry dry. Felton. Near Boyle.—Yellowish; micaceous; ferriferous. French Park. Within a mile of the town.—A silicious sand- stone, used for building purposes. In the tracts north-east and westward of Castlerea, good stones have been raised in different places, but no quarry more than of 252 098 Scientific Proceedings, Royal Dublin Society. local note has been worked. About three miles from the town there is a thin-bedded stone in the bed of the River Suck. It is in much request for walling, but is not good for cut-stone pur- poses. The stone can only be procured in the summer, when the river is low. On the tract to the north-east, between the town and French Park, there are many large field-stones, or “‘ tumblers,”’ which have been extensively used for local works, especially bridges, as they split easily. They have been of considerable profit to the occupiers, who sold them to those who required them. In the same area, near Bellanagane, are finely-laminated stones like the “‘ Dunmore slates,’ which in the vicinity have been used for roofing pur- poses; they are also found in the north-east portion of Slieve- Dart that enters into this county at the extreme south-west. In Slieve-Dart are also found the stones formerly so much wrought into millstones, but perhaps more in the Galway portion than in this county. Eastward of Bellanagane, between it and Mantua. is a calcareous stone containing si/iciows nodules more or less similar to rough agates and cornelians. Sandstone can also be obtained.in the tract to the west of the Suck and south-west of Roscommon. In the parish of Fuertry there is a quarry of excellent gritstone of peculiar solidity and hardness. In Slieve-Baun there are some good brownish and yellowish stones; but they are now principally used for local purposes, the limestone being preferred for dressed work. ‘To the south-east of Strokestown, in the south-west portion of Slieve-Baun, there are stones particularly adapted for millstones, and fifty years ago they were made in considerable quantities for sueR as the adjoining counties to the eastward of the Shannon. CoaL-MEASURES.—Lhese only occur at the north-west of the county. Some of the sandstones are reported to be of excellent quality, “ equalling the Tyrone stone”; but they are so out of the way and inaccessible that very little is positively known about them. rom the Coal-measures, however, are procurable excellent flags, somewhat like the Carlow flags, that formerly had a good sale; they were principally raised at Keadew and Arigna. SanD AND GRAvEL.—In the low country there are Eskers which give an inexhaustible supply of excellent pit sand and gravel ; some KinaHan—On Irish Arenaceous Rocks. 599 of these, when of limestone-gravel, are excellent as manure, others of a different character are not. River sand also occurs very generally. SLIGO, In the little promontory (Rosses) between Drumeliff and Sligo Bays is a small outlier composed of metamorphic rocks ; while coming in from Mayo, near the centre of the west mearing, and extending north-east across the county, is a portion of the Ox Mountain range. These hills, as has already been mentioned, have a nucleus of metamorphic rocks, which are probably the equi- valents of the Arenig, or possibly of the Cambrian (“ Introduc- tion,” page 515; Mayo, page 587), and margining them in places are Lower Carboniferous Sandstones. To the extreme south, in a small portion of the Curlew Mountains, there are Silurians of the “Old Red Sandstone” type, coming in from the neighbouring counties, Mayo and Roscommon, which are margined to the south- ward by Lower Carboniferous Sandstones. 'To the east of the county are Ooal-measures, a small portion of the Connaucur CoAL-FIELD ; while to the westward of the main mass are small outliers, lying east and west of Lough Arrow. In recent times sandstone has not been much used in this county for cut-stone purposes, as in general limestone is preferred. Camprians (?), ARENIG, AND Orpovicran.—The rocks that probably are the equivalents of those of these groups are all more or less metamorphosed. There are, however, in them some quartz- rock and quartzyte, suited for heavy rough work and for road metal. SrturtAn.—In the small area included in this county the rocks are similar to those adjoining, in the Co. Roscommon. They are of inferior quality for cut-stone purposes, being generally coarse and hard or argillaceous. They are, however, in places locally used. CarsonirErous. Lower Carboniferous Sandstone.—Some of the beds near Lough Gara, on the south slopes of the Curlew Moun- tains, are very similar to the rocks utilized at Boyle, in the Co. Roscommon ; but here they do not seem to have been worked. Westward of Ballysodare Bay and the neighbourhood of 600 Scientific Proceedings, Royal Dublin Society. Dromore West (parish of Kilmacshalgan) there are quarries of freestone. To the west of the county, near Kilmacteige, and in other places farther eastward, margining the Ox Mountain range on the southward, there are in places fair-looking stones, but, as previously mentioned, not in request. To the north-west of the Ox Mountains, in the neighbourhood of Dunowla, and to the south-west thereof, in the tract and strip of Lower Carboniferous and Calp (?) Sandstones, some of the stones appear as if they might be suited for dressing; but in no place are they sufficiently opened up to test their qualifications. South-east of Dromore, in Doonbeakin and Ballyglass, flags about 4 inches thick and up to 6 feet square have been quarried. CoaL-MEASURES.—Reports state that some of the beds of stone in this area are of good quality. They, however, are so inaccessible that they are not properly known. From these hills, however, are procured flags of the same class as the “ Arigna flags,” which have been largely used throughout the county. Sanp AND GraveL.—Pit sand is not very plentiful, and varies in sharpness. It can, however, be got good about four miles from Sligo. In some of the rivers and streams there is good river sand and gravel. Sea sand, which can be collected in great quantities along the shore, is an excellent manure for potatoes, but should be spread for some months before the crop is put in, as otherwise its proper effects are not experienced. In places near the shore-line is a stratum of shell sand or gravel, for the most part made up of oyster-shells. This, in some places, is at least 60 feet above the present high-water mark. This deposit is not only itself a valuable manure, but it imparts its fertilizing qualities to the sand above _and below it. TIPPERARY. The sandstones of this county, although now not much heard of, have a history; as both in ancient and the present times they have been very much used in preference to other kinds, even in places outside the margin of the sandstone areas. At — Cashel, the older structures (Cormac’s Chapel and the Round Tower), are of sandstone, except that in the Tower some of Kinanan—On Irish Arenaceous Rocks. 601 the lower courses are of limestone, but in the adjoining churches, which were subsequently built, limestone was used. Some of the sandstore hereafter mentioned, if known, would be more sought after than it is at present. The major portion of the area is occupied by limestone. We find, however, to the north-east, a little S. S. W. of Birr (Parsons- town), the small but conspicuous hill of Knocksheegowna, mostly Ordovician, but margined to the north-east and south by Lower Carboniferous Sandstone. Somewhat similarly, in the Arva Moun- tains, that lie to the east of the south arm of Lough Derg; in the group comprising the Silvermine Mountains and Sleve-Phelim ; in Slieve-na-Muck, to the south of Tipperary; and in the portion of the Galtees that is included in this county there are Ordovicians, margined by Lower Carboniferous Sandstones. The Hill of Cullen, to the north-west of Tipperary, is Lower Carboniferous Sandstone ; but the rocks of Knockmeeldown, to the south-east of the county, are probably in part Devonians, coming in from the neighbouring Counties Cork and Waterford. To the south-east, in the neighbourhood of Killenaule and north-east of it, are Coal-measures, the Hast Munster CoAu-FIELD ; while south-westward of the principal area are small, detached patches as outliers, which lie north of Cashel; north-east and south- west of Fethard; north-west of Clonmel; in Slieve-na-Muck, brought down by a great fault against the Ordovicians ; and at Ballyporeen, in the valley between the Galtees and Knockmeeldown. Orpovician.—These are, in general, in more or less inaccessible positions. When otherwise, nearly invariably the grits are in bad repute, as the associated slate rocks are preferred for local building purposes. : Devontans.—The rocks of Knockmeeldown seem to be in part the representatives of the Devonians of the County of Cork, that is, the Passage-beds between the Silurians and the Carboniferous ; while it is not impossible that the lower rocks of the Galtees to the northward, and of Slievenaman to the north-eastward, may be in part of this age, as the great thickness of the arenaceous rocks under the Carboniferous Limestone, as found in all these places, sug- gests that the Passage-rocks may be in part represented. Knockmeeldown. In different places brownish, reddish, and yellowish. Free-working; durable. Has been extensively used in 602 Scientific Proceedings, Royal Dublin Society. Cloghreen, although the latter is in the limestone. A brown sand- stone from these hills was used in the ancient castle at Cahir. Mount Anglesey. A few miles from Cloghreen.—Brownish- yellow; silicious-grained ; argillaceous cement; fine, but granular; friable; works freely and well; used for quoins, jambs, and other dressings; can be raised in long scantlings, and is capable of long bearings. In the slopes of the Galtees, included in this area, good stones occur in numerous places: they vary from whitish to reddish and brownish in colour, some being more silicious than others. In general they work freely, and have been used in Cahir in pre- ference to the limestone. These were used in the repairs of the old castle some forty or fifty years ago. CarBoniFrERous.—Lower Carboniferous Sandstone. These stones range from coarse reddish or brownish conglomerate to fine sand- stone, in shades of light yellow, reddish, and brown or purplish. In Clonmel, where sandstone has been most used, it has been pro- cured from the other side of the Suir, in the Co. Waterford. A similar remark is applicable to Carrick-on-Suir. Tinnakilly. Six miles north-east of Carrick-on-Suir.—Yellow to brownish ; silicious-grained; with little cement; ferriferous; very slightly micaceous. From here, and from Millvale, Co. Waterford, have been procured most of the sandstone used in Carrick. Dundrum. About a mile from.—Yellowish-grey; very good texture; suitable for all kinds of dressed work. Mr. Sharp, the well-known Dublin builder, states that he believes this stone would be very generally used if it were known. Drumbane. About seven miles southward of Thurles.— Whitish or light-grey ; quartz-grains; argillaco-silicious cement; slightly ferriferous ; works freely ; can be raised in large scantlings. Was used in the Court-house, Nenagh, twenty miles distant, and in the Model School, Clonmel. This, like the Dundrum stone, ought to be more generally known; it is an admirable material, more — durable than limestone, and very suitable for staircases, as it can be obtained in nearly any scantlings, and is capable of long bearings. Carrick. Near Roscrea.—Light-brown; silicious; very little cement; fine-grained; dense. Kowauan—On Irish Arenaceous Rocks. 603 In Roscrea, both in ancient and modern times, the local sand- stone has been extensively used. A better quality has been brought from Ballinsally, Queen’s County; but the old structures, as men- tioned by Wilkinson, seem to be built of the local stone. In Cro- nan’s Church and the Round Tower, the original working, as far as now preserved, seems to have been good; but the stones were not well selected, some now being very much disintegrated. The stones in the old castle are fine and thin-bedded, and although not so much weathered, they seem to have been weak, as some are cracked at their edges. In other localities where the Lower Carboniferous Sandstone occurs margining the Ordovicians, good stone can in places be procured, and has been used locally. The conglomerates and coarse sandstones have been in request for bridges and walls, for which they are. admirably suited, while in places they were for- merly wrought into millstones. 'Thin-bedded stones, used as flag- ging in Cashel, are raised near Dundrum, and similar stones for flagging in Tipperary have been procured at Shrough, seven miles distant; they have also been used extensively in the military bar- racks there, and at Fermoy, Oo. Cork.—(James Newstead.) [As very superior stones are known to exist near Dundrum, and at Drumbane, southward of Thurles, similar veins ought also to occur elsewhere in the county margin- - ing the tracts of Ordovicians. But they have not been looked for, the stones of this county, as already mentioned, not being in the market, and, except locally, are not of note; but if inquired after they would probably be more in request than some now sought after. | CoaL-MEASURES.—In different places there are good stones for walling and rubble; but as they in general hammer badly, the quoins, sills, and other stones for dressed work are procured from the Devonian or Yellow Sandstone quarries. In places in the Killenaule district, below the lowest coal, good flags can be raised. Sanp anp Gravet.—Near Roscrea, Thurles, and Tipperary, are Hskers, from which can be procured an unlimited supply of pit sand and gravel. Good sand can also be got near Clonmel and Nenagh, and an inferior kind near Cashel. River sand occurs in places in the Suir and the other rivers and streams. The Esker sands, and also a marly gravel was formerly exten- sively used as manure. The latter was called Corn gravel, as it 604 Scientific Proceedings, Royal Dublin Society. gave excellent crops of wheat; but since the change in the climate which prevents the wheat from properly yielding and ripening, and the consequent falling off in that crop, it is not much used. TYRONE. This, at the present time, is the premier sandstone country : not, however, as regards quantity, but as to the quality to suit the present market; and also as to variety, they being of different colours, textures, and hardness, and belonging to various Geological groups and sub-groups. To the northward, extending from near Omagh, north-eastward into Londonderry, is the tract of metamorphic rocks, suggested by Dr. Hinck as possibly of Lawrentian age; but, as shown in the * Introduction” (page 515), more probably the equivalents of the Ayeng, or even possibly of the Cambrian. In the vicinity of Pome- roy, against these rocks is a small tract of rocks that possibly may in part represent the Llandovery, which, as given in the Table of Strata (Part 1., page 204), are the Passage-beds between the Silu- rian and the Ordovician ; these rocks, however, are evidently nearer allied to the last than the first. On the southward of these strata is a considerable and wide tract of Silurian, of the “ Lower Old Red Sandstone” type—the eastern portion of the area already mentioned when describing Fermanagh (page 560); and still further to the southward, in places margining these rocks, is a narrow band of Lower Car- boniferous Sandstone. North of the Tyrone Coat-Fiexp there is a tract of Calp Sand- stone brought up by a fault, while there is a second south-west of Dungannon (Dungannon Park). Farther south-westward, north- east and south-east of Aughnacloy, are tracts of somewhat similar rocks that have been classed among the Calp Sandstone; but it should be pointed out that they are also more or less like the | rocks of the Mermanagh Series (Lower Coal-Measures) of the Slieve- Beagh district, counties Fermanagh and Monaghan (page 561) ; while in the neighbourhood of Aughnacloy they appear to join into one another. It seems possible that in the latter neighbour- hood the geology has not been properly worked out, and hereafter (north of the Tyrone Coal-field), it will be found that the Coal- Kinaunan—On Irish Arenaceous Rocks. 605. measures and Calp Sandstone are brought together by a fault, a downthrow to the south-eastward. [All these lithologically similar rocks to the north-east of the Blackwater (Aughna- cloy) are called on the new maps Calp, while west and south-west of that river they are called by the unappropriate English sub-group names, Yoredale beds and Millstone grits. | The well-known sandstones of the Co. Tyrone are all of Car- boniferous age; but they may belong to the Lower Carboniferous Sandstone, the Calp, or the Coal-measures. The rocks in the neighbourhood of Aughnacloy, as already mentioned, may belong to either of the latter groups; here, provisionally, they will be described with those of the Calp. The Calp is of the two types, the ordinary, and the “ Ulster type;” the rocks in these will be given separately. [The subdivisions of ‘“ Upper and Lower Calciferous Series’’ adopted in the Geolo- gical Survey Memoirs are only lithological ; the reddish pebbly rocks forming the latter. These dark-coloured rocks may, however, occur on any geological horizon, their colour and composition being solely due to islands, or other shore lines in the Carboniferous. sea, they always being found adjoining a protrude of the older rocks. | These rocks have been used in the county—very generally in Dungannon, Coalisland, Clogher, Omagh, Cookstown, Castlederg, and Caledon; while in Strabane, and other places in the schist regions, they are used for quoins and other dressed-stone purposes. At Baronscourt they were used, except the Portland stone for the staircases, and in a few other places. Out of the county they have been extensively used for cut-stone purposes. Near Benburb, at the south margin of the county, are sand- stones that have been said to be of Permian age; but on account of the assemblage of fossils in these and the associated rocks, and also of their position, Baily and the writer have suggested that they must belong to the Carboniferous. In the northern portion of the county, at Cookstown and Kil- dress, at Omagh and south-east of Strabane, are tracts of Calp, of the “ Ulster type” (vide “ Introduction”); while north of Dun- gannon, and further northward at Annaghone are Coal-measures (Tyrone Coau-FreLps). Near Cookstown and Coagh, and extend- ing southward past Dungannon into the Co. Armagh, Zias (“ Red. Free”’) is found. 606 Scientific Proceedings, Royal Dublin Society. The Orpovictan grits are very little used even for local pur- poses, the associated slates being preferred for ordinary work. At Strabane, Castlederg, and other places in the north of the county the metamorphosed Ordovicians (Micalyte, Argillyte, &c.) are used for walling, the cut-stone work nearly invariably being Carboni- ferous Sandstone. Near Strabane flags are procured. Sirur1an.—These range from conglomerate to fine sandstones ; in general being silicious, but often argillaceous, or even carbona- ceous. Similarly, as in the Co. Fermanagh, they have been used a little for cut-stone purposes, and are very suitable for coarse work, such as bridges and walls. Formerly, in some places, the very silicious varieties were wrought into millstones. Lacagh. About two miles south-east of Fintona.—Purple and reddish ; conglomeritic; yields sills and quoins; used in the build- ing of Fintona new bridge. Dungoran. Near Fintona.—Yellowish; grains white quartz ; a little argillo-silicious cement. Raweagh. Near Fintona.—Brown; makes good rubble; used in Raveagh House. . Dundiven. ‘Three miles south-west of Fintona.—Cream colour, greyish-white, and greenish-grey. Rather argillaceous and fel- spathic; partly calcareous; granular ; fine-grained; free-working. Lackagh. Three miles from Fintona.—Dark-purplish ; semi- erystalline. Pomeroy. A mile from.—Dark-purplish grey ; semi-crystal- line; granular; micaceous; works fairly well. Lower Carponrrerous SANDSTONE.—Generally greyish or yel- lowish in colour; some, however, reddish; more or less silicious ; unequal grained; works freely, but soon wears the tools. In places some of the more silicious varieties were wrought into mill- stones. Derrynascope. One mile from Augher.—Greyish and yellow; silicious-grained, with, in some beds, a reddish felspathic cement. Dernasill. Four miles from Augher.—Greyish-white to yel- lowish; silicious; argillo-silicious cement; granular; micaceous; in some beds ferriferous. Altaven. Five miles from Augher.—Greenish-white, with yellow seams; very quartzose; unequally grained. Ballymagowan. One mile from Clogher.—Yellowish ; white Towauan—On Irish Arenaceous Rocks. 607 silicious grains; a little felspathic cement; when ferriferous they have a reddish tinge. Elderwood. Three miles from Fivemiletown.—Reddish ; sili- cious grained ; felspathic cement. Cavey. One mile from Ballygawly.—Yellowish; silicious; a little cement; fine-grained; ferriferous. The conglomerates near Ballygawly were formerly wrought into millstones and flax- crushers. Carp (Ulster type)—Many of them are beautiful stones— creamy or yellowish in colour, or with a bluish tint. In general they are free-working, open-grained, and capable of producing good work; some, however, are not suitable for heavy bearing. From the ancient buildings in which they were used they seem to be very durable. These sandstones occur in limited thicknesses of strata, the “‘over-bearing’”’ or cover-rocks being limestones or shale. This, as the quarry is worked in on the dip (which is low) of the stone, very often becomes excessive, so that the expense of removing it may become greater than the value of the stone. In other quar- ries the good stone occurs in more or less lenticular or other masses, adjoining which the stones are inferior. For these causes, quarries once famous are now worked out or abandoned. Cookstown. In different quarries in the vicinity of.—Yellowish, creamy, or with a bluish tint; silicious-grained; a little argillo- silicious cement; open-grained; slightly micaceous; soft, and not suitable for heavy bearings. Mr. Dickinson states:—‘‘Some of the beds are hard and excellent for all kinds of masonry.”” From Tamlaght quarries were procured the stones used in the Lower Bann navigation works, while those used in the building of Killy- more Castle came from the quarry nearly a mile north-west of the workhouse. Stones from the Cookstown quarries were also ‘used in the Provincial Bank, Belfast: a light, tough sandstone, hard to dress, and does not stand.’—(W. Grey.) Kildress. Stones very similar to those of Cookstown. Loughrea. South of Cookstown.—Similar stone. Trinmadan. Nearly two miles from Gortin.— Yellowish ; quartz grains; argillo-silicious cement; granular. Carrickmore, four miles from Gortin; Douglas Bridge, eight miles _ from Strabane; Mullinavarra, three miles from Castlederg ; Derry- 608 Scientific Proceedings, Royal Dublin Society. guinna and Longfield, where most of the stones used in the building of Baronscourt were procured; and Drwmquin, west of Omagh. In these quarries the stones'are more or less similar to those of Cookstown. From the Drumquin quarries were procured the stones for the pillars in the Omagh Courthouse. At Cookstown, Drumquin, and Carrickmore, especially the latter, flagging has been procured for the neighbouring towns. Catp.—These rocks occur to the north of the CoaLisLtanp- CoALFIELD, and in tracts of less or greater dimensions in the county, west and south-west of Dungannon. As pointed out pre- viously, they are in some respects similar to the rocks of the Slieve-Beagh district. Bloom Hill. About four miles north of Dungannon, and three from the Donaghmore Station, Great Northern Railway.—Two quarries, of different qualities and colour. Creamy, greyish-white, and reddish-yellow; the latter, or Red-beds, being inferior. Prin- — cipally silicious-grained, very little cement, fine-grained. Some beds, especially the reds, are in part argillaceous and micaceous or ferriferous. Mr. Hardman states:—“The stone much resembles — that at Gortnagluck and Carlan (presently mentioned), is equally good for building purposes, and has been much used.”—(G*. S. IL) It has been much used in Dublin and other places. In the Belfast banks, Donegal and Baliyshannon, it has been found very durable. Gortnagluck and Carlan. About half a mile apart, and appa- rently on one set of strata, about two miles from the Donaghmore Station, Great Northern Railway.—Of slightly varied colour and quality; creamy, yellowish, greyish, white and reddish—the Red- beds being inferior. Silicious-grained ; very little cement; slightly micaceous and ferriferous; cuts freely and well; can be raised of good scantlings; gets hard from exposure, and is durable when worked on its bed. It is a favourite for cut-stone purposes in Ballymena, Co. Antrim, where it is considered the best of the ‘Dungannon stone;”’ the Belfast people, however, seem to prefer the Ranfurly (Mullaghana) stone. It was used for all cut-stone purposes in Raveagh House, near Fintona; Convent of Mercy, Ballyshannon, Co. Donegal ; Roman Catholic Church, Maghera- felt, Co. Derry; Harbour Offices, Londonderry; and in various other places. Kawnanan.—On Irish Arenaceous Rocks. 609 Spademill. An old quarry, now not of note.-—Some of the beds excellent for scythe stones. Ranfurly or Mullaghana. Joined by a siding to the Dun- gannon Railway Station.—Creamy and yellowish; silicious; very little cement; fine-grained; lasting colour; difficult to work. The quarry, after being for some time closed, was recently worked, but is now (1887) again closed. ‘Was used in the Post Office and Northern Bank, Belfast, and Northern Bank, Fintona; also in the addition to the Royal University, Dublin, where it has been found durable and to retain its colour. The “ Dungannon stone,” from some one or other of these diffe- rent quarries, has been extensively used in Dungannon. Accord- ing to a list, to which I am indebted to Mr. Dickinson, some of the principal buildings are: the Provincial Bank, Parish and Roman Catholic Churches, Shiel’s Institution, Police Barracks, and Paro- chial Hall. Elsewhere it has been used at Roxborough Castle, Moy ; bridge over the Ballinderry river, near Coagh (cost £5000); the clock tower, and St. Patrick’s Church, Belfast. “These Dungannon stones, with those from Dungiven (Co. Londonderry), and Cooks- town, were used promiscuously in the public offices (Post-office, Cus- toms, and Inland Revenue), and the Apprentice Boys’ Memorial Hall, Londonderry ; also with the Dungiven stone only in the Lunatic Asylum, where the stones from each quarry were used in a separate building. Bloomhill, for the gate-lodge and offices; Gortnagluck, for two separate wings; Carlan, in the doctor’s residence; and the Dungiven, in two octagonal wings and the front of the old portion of the asylum. In the military barracks, Omagh, Dungannon stone, of the inferior quality known as the Red-beds, was used ; it works easily, but is not durable.’—(J. Cockburn.) Aughnacloy.—Greyish to yellowish; silicious-grained. Also quarried three miles south-east of Aughnacloy. Glencall. One mile from Aughnacloy.—Greyish-white ; slightly stained with iron; very silicious; silicious cement; a little mica. Brantry. Six miles south of Dungannon.—Purplish-grey ; slightly variegated; semi-crystalline; granular; micaceous. CoaL-MEASURES.—Some of the arenaceous rocks of this sub- group, unlike those that in general occur in the measures of Munster and Leinster, are free-working stones. Rarely, however, can they be raised profitably, on account of the “clearing” or 610 Scientific Proceedings, Royal Dublin Society. “over-bearing”’ of drift, or useless rocks, that overlie them ; they are, however, inferior to the Calp Sandstone, and no quarry in them seems now to be worked. Edendork. Two miles northward from Dungannon.—Reddish ; fine-grained ; slightly micaceous; soft; not now worked. Sanp AND GraveL.—Hskers extend from Killymoon, near Cookstown, to Dungannon, and thence by Ballygawly, Clogher, and Fivemiletown into the county of Fermanagh ; in them there is an unlimited supply of good pit sand and gravel. Some of these so-called Eskers, as in the Pomeroy valley, are evidently Glacial yiwer gravel. (See Monaghan, p. 592.) Good pit sand can also be procured near Gortin. River sand occurs in the Foyle, at Lifford Bridge, near Strabane ; in the Moyne, near Omagh, and elsewhere ; near Castlederg, and in many of the rivers and streams from the hills. WATERFORD. Occupying a considerable area in the east of the county is a large tract of Ordovicians. Overlying this, to the west, in the Monavullagh and Comeragh Mountains, are massive conglomerates, sandstones, and slates, which to me seem to be littoral aceumula- tions of the West Cork and Kerry Devonians.* If this suggestion is correct, portion of the younger rocks, in the Galtees, to the northwest, and Slievenaman to the north, ought to be also Devo- nians. ‘These Devonians, as in Cork and Kerry, seem to graduate upward without any quick or decided change, into the Yellow Sandstone or Lower Carboniferous Sandstone ; as in general the dips in both groups of rocks are similiar. ‘This, however, is ‘not always so, as in the neighbourhood of Glenpatrick, to the southward of Clonmel and Kilshelan, there is a sudden change in the direction of the dips, the later rocks dipping northward at low angles, and the older southward at high ones. This change may possibly only be due to a line of fault; but it may be caused by an unconformability: it should, however, be more carefully ex- amined into. However, to the southward in these hills, and also 1 John Kelly, I think, was of a similar opinion, but I do not know exactly where he stated it. Kinanan—QOn Irish Avrenaceous Rocks. 611 farther west in Knockmeeldown, one group appears to graduate into the other; the Yellow Sandstone margining the Devonian. The Yellow Sandstones also occur in places eastward (estuary of the Suir), and in a band to the northward of the Ordovicians. In the south division of the county, that is south of the valley from Dungarvan to the Blackwater at Lismore, there are, east and west, ridges of sandstones, separated by troughs of Carboniferous limestones or shales; and in these ridges, as in Cork, farther west, if there is a sufficient thickness of strata exposed, the Yellow Sand- stone (Lower Carboniferous Sandstone) is found to graduate down- ward into the Devonian. In the Bonmahon mining district, in two or three places, very small patches of red or purplish conglomerate and sandstone have been found lying on, or partly in, the Ordovician. These must be either of Silurian or Devonian age, probably the latter: that is, small outliers of the Comeragh conglomerates. Orpovicran.—The major portion of the grits and sandstones are not fitted for general cut-stone purposes, although some dress on the bedded surfaces; nor are they in much repute for common walling purposes, the associated slate being preferred, except in a few cases. There are, however, some green tuffose sandstones that are associated with the Exotic bedded rocks; these do not seem to have been much utilized in this county, although very similar rocks have been used during ancient and modern times, in the Co. Wexford, where they have produced good and durable work. Grange Hill. Waterford.—Here there is a slaty grit that has been much used. It is very strong and hard, but very difficult to raise, on account of the absence of back joints; it dresses well on the face, but not on the edges. It was used in the ancient round castle, called Reginald’s Tower, which shows the durability of the stone. ‘The dressed work round the opening in this structure is of Carboniferous Sandstone, which has weathered much more, but evenly, than the Grange Hill stone. DeEvonian AND CarBonirERoUS.—In the Co. Cork, the Sidu- rians and Devonians are intimately connected, and hard to separate. They were, therefore, grouped together. In this county, however, it is not the beds below the Devonians but those above them that are intimately connected. It therefore is expedient here to group SCIEN. PROC. R.D.S.—VOL. V., PT. VII. Ziel 612 Scientific Proceedings, Royal Dublin Society. the Devonians with the Lower Carboniferous Sandstone (Yellow Sand- stone), and to describe the stones that occur in both together. These stones are very generally used throughout the county, either for cut-stone or rubble purposes. The stones usually are shades of brown, green, and yellow. In the west of the county different varieties of stone are very much mixed up; as quite distinct stones very often occur together in one quarry. At Skorough, eastward of Lismore, in one quarry, there are four varieties, interstratified, ranging from finely-laminated slate to a gritty sandstone. A soft, earthy, felspathic, and micaceous stone, from Ballysaggart, was used in the dressings of the Roman Catho- lic Church, Lismore; while, about three miles eastward of the town, in one quarry there are roofing-slates, good flags, and free- stone, all of which were formerly worked. ‘These slates, however, were eventually cut out by the Welsh slate. In the same town- land, but nearer Lismore, there is a stone fit for cut-work ; but it varies in quality, the best being in beds from two and a-half to three feet thick. ‘There are also other quarries, nearer to the town, but difficult of access. For the buildings in Lismore sand- stone has principally been used ; but in the church erected about fifty years ago limestone was used, and also in the mullions and windows of Lismore Castle. Glenniveene. About five miles from Lismore.—Flags ; difficult to dress, as they are liable to chip at the edges. Slieve-Grian. In different places.—Light-coloured, silicious, felspathic cement; slightly micaceous; even-grained; porous; good quality; works freely. Very generally used for dressed work in Dungarvan, from which the quarries are distant some seven to nine miles. In Cappoquin, the stone most used is a local thin-bedded, gritty, silicious, speckled sandstone. Oappagh.—An excellent dry stone, but difficult to work, as it has no regular bedding or soles. Used in the new house at Cappagh. Green flags have also been procured in the neighbouring hills. Ballyhavahan and Killongford. Near Dungarvan.—Brownish and yellowish, but more usually variegated. Generally soft, fine, argillaceous, and micaceous on the bedded surfaces; porous, and easily worked. In the quarries there are some subordinate, felspathic, and more coarsely-grained. beds, from twelve to fifteen Kinanan—On Irish Arenaceous Rocks. 613 inches thick. Generally used, but often with limestone, for rubble and walling in Dungarvan, the dressing being Slieve- Grian stone or Whitechurch limestone. Ardmore.—The ancient round tower, as pointed out by Wil- kinson, “‘is a fine example of cut-stone masonry, and demon- strates the durability of the sandstone of the neighbourhood.” “Walling in squared coursed work of reddish-grey sandstone, is in good preservation.” “ Clonmel Quarry.” Half a mile from Clonmel.—Whitish to greenish ; silicious; in some beds an argillaceous, silicious cement ; works well. The sandstone generally used in Clonmel. Millvale. Two miles from Carrick-on-Suir.—Reddish ; silicious ; with a little silicious cement; ferriferous. Has been largely used in Carrick. Waterford.—The conglomerate that lies unconformably on the Ordovicians seems to be rarely used, except for road metal. About a mile from the town there is a quarry in reddish-brown, good sandstone; but as it is difficult of access, it is not now much used. Brown Head Promontory. Wast of Tramore Bay.—Dark-red sandstone. It is very effective, with granite mouldings, in New- town House, near Waterford. To the east of the county, adjoining the estuary of the Suir and Barrow, there are limited tracts of conglomerate and sand- stone well adapted for heavy work, such as piers and sea-walls, as they are capable of being raised in large squarish blocks. At Dunmore Hast there are good workable beds in the red sandstone cliffs, which have been locally used in sea-works; in the town and the coastguard-station : they are not durable. New Ross pier, Co. Wexford, is built of this class of stone; which was brought. either from one of these tracts, or from that at Ballyhack and Arthurstown, Co. Wexford. Mr. Langrish states :—‘ The stone, from its hardness and roughness of surface, ought to make splen- did coping for a quay wall, preferable to granite or limestone, which wear quite smooth.” SAND AND GRAVEL.—Pit sand and gravel are dispersed over the county, but generally not in quantity. In many cases the sand is very fine. At the round hill near Lismore there are good building and moulding sands, the latter used in the Cappoquin Foundry; also close to Ballyduff railway station. River sand is found in some of 2T2 614 Scientific Proceedings, Royal Dublin Society. the rivers and streams. For Waterford, they procure it about sixteen miles up the Suir, near Portlaw. “At Bonmahon there is a sea sand (AXolian) fit for almost any building or concrete. It is artificial, being due to the washings from the stamps when the copper mines were at work.”—(W. S. Duffén). Guass.—LHarly in the century glass bottles were made opposite to Ballycarvel; and subsequently, about fifty years ago, there was a large glass manufactory. The “ Gatchell or Waterford glass” was famous, this “ Irish glass”” having a name even in India, to which it was largely exported. It ceased about 1845, after the death of George Gatchell, as on his death the lease of the premises expired, and the landlord wanted to double the rent. This, com- bined with his widow wishing to retire to Hngland—her native country—broke up the industry. pSSOBVIpg 40 - pzOPVLvZ 6 op hun] od w wo FUPIULLA 5 5% q toy ¢ isa ss ° DILL ues = ers a “ pruanbig 20 Fat eta ves ean, . S Vv ! uy n J [JPSSOPO GV] ON PETE) —— A sobbing? UME 5 msa.AhHT a > Uy | : s By pi wrho ila eta 2 y oped q < wey fie pee mY 7 West, Newman& Co. photo-hth. fv E fl a 4 a i oD AL » = Me) rl 9 ee we bea ap} a A.C.H.del. ae ae ‘: tee oe Proc.,R.D.S.,N.S.,Vol.5. West, Newman & Co. lith. del Bl AC. be , eG fy See me SUNT as Proc. R.D.S., N.S., Vol. 5. Plate XT. Ordovicivans s S £6 iii = = soe West, Newman & Co.lith. Fe ‘ Plate XI Proc. R.D.S,,N.5., Vol. 5. ous nh : areal UES ret naga _ 3 9088 013 aor