es dogs ay. ta dF Pe 4 Ob ae ease Ay) ov Mie N Sa PLOWS OF THE ROYAL SOCIETY OF EDINBURGH. PRANS ACTIONS OF THE PO YA SOCIETY OF EDINBURGH. VOL. XXX. EDINBURGH: PUBLISHED BY ROBERT GRANT & SON, 107 PRINCES STREET, AND WILLIAMS & NORGATE, 14 HENRIETTA STREET, COVENT GARDEN, LONDON. MDCCCLXXXVII. Part I. published . Dee. 3, 1883. PARm ‘ : ; . Nov. 29, 1884. Part III. 53 ; . Feb, 13, 1886. Part IV. 3 ; . duly 9, 1887. TT. IV. VII. VIII. CONTENTS. PART I. (1882-83.) . The Pycnogonida dredged in the Fare Channel during the Cruise of H.M.S. “ Triton” (in August 1882). By Dr P. P. C. Hoex, Member of the Royal Academy of Science of the Netherlands. (Plate 1), . Bright Clouds on a Dark Night Sky. By Professor C. P1azzi SMytu, Astronomer-Royal for Scotland. (Plates II.—XIV.), Note on the Little b Group of Lines in the Solar Spectrum and the New College Spectroscope. By C. Piazzt Smytu, Astronomer- Royal for Scotland. (Plate XV.), Observations on the Annual and Monthly Growth of Wood in Deciduous and Evergreen Trees. By the late Sir Rosert CHRISTISON, Bart., and Dr CHRISTISON, . . A Contribution to the Chemistry of Nitroglycerine. By MattHew Hay, M.D., Assistant to the Professor of Materia Medica in the University of Edinburgh, . The Elementary Composition of Nitroglycerine. By MattrHrtw Hay, M.D., and Orme Masson, M.A., B.Sc., Report on the Tunicata collected during the Cruise of H.MLS. “Triton” in the Summer of 1882. By W. A. Herpmay, D.Sc., Professor of Natural History in University College, Liverpool. (Plates XVI.-XX.), ; : Report on the Pennatulida dredged by H.M.S. “ Triton.” By A. Mines MarsHatt, M.D., D.Se., M.A., Fellow of St John’s College, Beyer Professor of D olony 3 in Ona — (Plates XXI.-XXV.), ; PAGE ia: 37 45 67 78 93 119 vi XI. XII. pGHOE ZY XV. XVI. CONTENTS. Asteroidea dredged in the Faerie Channel during the Cruise of H.M.S. “Triton” in August 1882. By W. Percy SLApEn, F.L.S., F.G.S. Communicated by Joun Murray, F.R.S.E. (Plate XXVI_), . . On a New Species of Pentastomum (P. protelis) from the Mesentery of Proteles cristatus; with an Account of tis Anatomy. By W. E. Hoyiz, M.A. (Oxon.), M.R.C.S., Naturalist to the “Challenger” Commission. (Plates XXVITI., XXVIII), On Superposed Magnetisms in Iron and Nickel. By Professor C. G. Knott, D.Sc. (Plate XXIX.), On the Relative Electro-Chemical Positions of Wrought Iron, Steels, Cast Metal, &c., in Sea Water and other Solutions. By THomas AnpreEws, A.M., Inst. C.E., F.C.S. (Plates XXX.-XXXIV.), PART II. (1883-84.) Report on the Tunicata dredged during the Cruises of H.M.SS. “ Porcupine” and “ Lightning” in the Summers of the Years 1868, 1869, and 1870. By Professor Hrerpman, F.R.S.E. (Plates XXXV., XXXVTL), Note on Sir David Brewster's Line Y in the Infra-Red of the Solar Spectrum. By Professor Piazzi Smyvu, F.R.S.E., Astronomer- Royal for Scotland. (Plate XX XVII), On the Formation of Small Clear Spaces in Dusty Air. By JoHN AITKEN, F.R.S.E. (Plate XX XVIII), On Stichocotyle Nephropis, a New Trematode. By J. T. Cun- NINGHAM, B.A. (Plate XX XIX.), XVII. The Enumeration, Description, and Construction of Knots of fewer than Ten Crossings. By Rev. T. P. Kirkman, F.R.S. (Plates XL.-XLIIT.), PAGE 153 193 204 219 233 239 273 281 XVIII. XIX. XXIV. XXV. XXVL XXVIL. xx viLE CONTENTS. On the Approximation to the Roots of Cubic Equations by help of Recurring Chain-Fractions. By Epwarp Sane, LL.D., F.R.S.E., On Knots. Part II. By Professor Tarr, Sec. R.S.E. (Plate XLIV.), Appendiz.—Note on a Problem in Partitions. By Professor Tait, Sec. R.S.E., . On the Philosophy of Language. By Emeritus Professor BLACKIE, F.R.S.E., . The Old Red Sandstone Volcanic Rocks of Shetland. By B. N. Peacu, F.R.S.E., and Joun Horne, F.R.S.E. (Plates XEV XLVI.) : ; : : . Observations on a Green Sun and Associated Phenomena. By Professor C. Micuiz Smits, F.R.S.E. (Plate XLVIL), . An Example of the Method of Deducing a Surface from a Plane Figure. By Professor L. Cremona, LL.D. Edin., Hon. F.R.SS. Lond. and Edin., PART III. (1884-85.) Micrometrical Measures of Gaseous Spectra under High Dis- persion. By Professor C. Prazzi SMytu, F.R.S.E., and Astro- nomer-Royal for Scotland. (Plates XLVIII-LXXVIIL.), On Bipartite Functions. By Tuomas Murr, LL.D., . The 364 Unijilar Knots of Ten Crossings, Enumerated and Described. . By Rev. Toomas P. Kirxman, M.A., F.R.S, On Knots. Part III. By Professor Tarr. (Plates LX XIX.- LXXX1.), ; A New Graphic Analysis of the Kinematics of Mechanisms. By Professor Roserr H. Smirx, Mason College, Birming- ham. (Plate LXXXI1.), Vil PAGE 311 327 340 343 309 389 411 415 461 483 493 507 vill X XIX. XXX. XXXII. XXXII. XX XI. XXXIV. XXXV. CONTENTS. The Visual, Grating and Glass-lens, Solar Spectrum (in 1884). By Professor C. Prazzi Smytu, F.R.S.E., and Astronomer- Royal for Scotland. (Plates LX XXIII.-CXLIIL), Observations on the Recent Calcareous Formations of the Solomon Group made during 1882-84. By H. B. Guppy, M.B., F.G.S., Surgeon H.M.S. “Lark.” Communicated by JOHN Murray, Ph.D. (Plates CXLIV., CXLV.), Observations on Atmospheric Electricity. By Professor C. Micuig Suiru. (Plate CXLVL), Note on Ectocarpus. By Joun Rarrray, M.A., B.Sc., Scottish Marine Station, Granton, Edinburgh. Communicated by JoHN Murray, Ph.D. (Plates CXLVII., CXLVIIL), Anatomy and Physiology of Patella vulgata. Part I. 2 aQ |e) o|] 2 So] Sco S an 73) =| = | Be| A | F | ds [= S/Se8/ a1 | 8 | #8 2 g = ag a> 4s: D4 J < “a | 3? Bree Se Sse ee ae ins. _ . Z gr. brs. F { 30°54| 4-7 | 4-3 | o-9 02| 93 | & | 26 63 Nicaea 2a 08 30°60| 41-1 | 38-7 | 24 06] 81 | EB | 22 es | & . 67| 43-2 | 40°8 | 2-4 6 | 81 F | RG 23 | MESURE, it { 30°71 | 39-0 | 38:7 | 0:3 o1| 93 | E | 2-9 aes ca 30-68 | 43:2 | 408 | 2-4 o6 | 81 | B | 2-2 05 | a. 0 | 0-0 162 feet. 8 | 30-67 | 39-2 | 38-3 | 0-9 0-2] 9 |NE| 26 LO Tats GiT) Nil ee FEETNrria| Ex a aa an ee ea Se Tong. 81". | {|8052/ $87 | 867 | 20 05 | 84 | SE. | 17 35 | g5| 4 | 00/0 e eee 30°37 | 36-7 | 35-7 | 1-0 02 | 92 |S.E. | 20 - a |.) 1) eee acy 19 §| 80°25 | 38-4 | 37-7 | 0-7 o2| 24/1] | 22 BBall ee | 0 30°17 | 36-9 | 34-7 | 22 05 | 92 | E | 20 Means,.. 30:52 | 39:9 | 38-4 | 15 0-4 | 88 23 ~ §|30°52| 39-7 | 37-9 | 1°8 05 | 86 |N.E.| 1-0 8 , 6 { 30°57 | 35-0 | 343 | 0-7 02| 93 | NE} 0-2 i \ Clear and fair. BRAEMAR, 7 §| 3059) 30-0 | 28-8 | 12 o4| 8 | & | oO Fog. \ 7 No. 2. { 30-64 | 36-9 | 33:5 | 3-4 os | 73 | BE. | oO cs . 1114 feet. 30°60 | 36-7 | 321 | 4-6 09 | 6 | BE | 0 8 | 30-54 | 37-7 | 35-2 | 2-5 06 | 80 | E | 0 ; Clear and fair. Lat. 57° N. Le peeks eae | ee ee Se ee ee Long. 3° 24’ W. 30-41 | 37-7 | 325 | 5-2 11| 6 | B | oO E 9 { 30°31 | 39-4 | 36-7 | 27 06| 79 | & | o ' Clear and fair. 19 §| 30716 | 422 | 37-7 | 45 10| 69 |SE. | 0-2 3 a { 30-14 | 34-4 | 32:8 | 1-6 o4| 84 | BE | O 1 . Means, . ; 30°45 | 37:0 | 34:2 | 2°8 OO affth 01 4 30:47 | 40°5 | 39°5 | 1-0 0-2 | 92 | N.E.| 4-0 Mist.| 9 Pe By 30-53 | 37-5 | 36:5 | 1:0 02] 91 | BE | 4-0 Nimb. a Hass " 30°60 | 40°5 | 38:1 | 2-4 06 | 81 |SE. | 4-0 Bt ap cra pod ‘ {| 30°63 | 32:5 | 31:5 | 1:0 02] 88 | B 4-0 0 80°61 | 42°5 | 36°8 57 1:2 62 a0) 4-0 0 Sad 1c Hoar frost. 1150 feet. 8 1| 30-54] 33:5 | 29:5 | 4-0 08 | 61 | EB | 40 o | 2] : \ Clear fine day. Lat. 55° 48°. [ rac gl aes Para hic <=. oh 30°43 | 321 | 31-5 | 0-6 o1| 92 |SE. | 4-0 Fog. an ee Long. 3°21’ W. | 9 { 30-29 | 31-5 | 29:5 | 2-0 0-6 | 74.| N. | 10 0 7 Cirro-stratus, fine. 10 { 30°18 | 47-5 | 43:5 | 4-0 10 | 74° | N. | 1-0 pages 30°10 | 35:5 | 33:5 | 2-0 0-4 | 82 | Var. | 4-0 5 Means, . 30°44 | 37:4 | 35-0 | 24 0:5 | 80 34 BRIGHT CLOUDS ON A DARK NIGHT SKY. 2 = | Hygrometer Rivuamncissanll Wind Date. ae fee Con ee Besnles, rae Cicer. ne ——| e= : oa , 3 5 8 g é STATION. g 2 S aS ef si Z é 3 a zg 3 REMARKS. Ba| 4 | 4/3, ]£ 2/225 See eee (|e eel gS a Bt a & gS fuego] sse| x. . 28 5 ry allese is | o | Se ee oboe | ee eeetbecasiie ti) Be Spee l(e | 6 | £3 PS 8) Soca eee tesail s | “E = 2: a= Io ales] Es etic fa) 4 2 | a a le ale alee baer & | ins. 4 6 e grs.| gr hrs. 30°39 | 41 | 401 | To] 37] 63] 92 | B | 40] B | 10 | 45 30-48 | 39-0 | 36-4 | 26] 22| 06] 8| & | 10} B | 2 | @ WANLOCKHEAD, 7 30°55 | 42°9 | 88°5 | 4:4 7 2:2) 10) 70 E. CON Ieee 0 12 No. 4. { 30°58| 37:0 | 365 | 05 1°24] 02] 96 | & | o2| 2. | o | *@ ist tect. | (| 3057| 403 | 360 | 43] 20] 10) 68 | w. | 02 0 | 45 { 30-47| 40:5 | 33-7] 68] 15 | 14] 53 |S.w.] 0-2 ie) Be ca oe ns Paik eae) ii «eaters A Sane tas 3 inl Ta Long. 3°48 W. | {|30-40| 302 | 299] 03 | 19] 01] 9 | w. | o2] .. | © | a3 30-29 | 36-3 | 35-21 11] 221 03| 90 | w.| 02] w.] 1 iy f\oote| 28 )| 20-00 28] 625! OF | ayo low. |or | s. |) a |g { 30-08 | 36-1 | 36-0 | 0-1 | 25 | 0-0 | 99 |N.w.| 0 6 i Means. .| |30-40| 386 | 362 | 24] 22] 06 | 82 |... | 1-0 g {| 30°49) 43° | 39° 23 | 009) | elem eGo} [m0 fh og { 30°57 | 43° | 42: 29| 03/92 | & | 90/ BE | 8 MaRrcHMONT 7 { 30°66 | 41° 39° 2°5 0°5 84 i. 1:0 E. 8 6 (Berwick), 30°66 | 38° | 37° 24) 03] 91 E. 4:0 0 0. 5. eas Bouees Shee | rian sees = aa = BNE sees g §|30:67| 41° | 39° Paylh O | ra4 "| Pw) [| Ptoh ls L. ||i8 |b og 500 feet. { 30°59 | 39: | 38° 25 | 031 92 | E | 40] & | 10 Lat. 55°44” N. | 4 {|30°50| 39° | 36: Pen | Aw. le-ol |B. p10 |) ay Long. 2° 25’ W. { 30°34 | 34° | 34° 23 | 00/100 | B. | 40] B | 5 10 §|30-24| 35° | 34° 21 | 03 | 90 | NE} 40/NE/ 10] 4 { 30-14] 36- | 35° 22 | 03] 91 |NE.| 40] N-E.| 10 Means. 30-49 | 38-9 | 37°3 2-4 | 0-4 | 87 eI | 4 30°54] 45-7 | 41-3 | 44 | 25 | 10 | 70 | NE 30-60] 43-0 | 405 | 25 | 26) 06 | 1 | NE 30°68 | 45°3 | 41-5 | 88 | 26 | 09 | 74 | NE 1 ee Ta 30-68 | 39°5 | 385 | 10 | 26 | 02 | 92 | NE 30°69 | 45:5 | 42-0 | 35 | 26 | 08 | 7 | NE etl <=: piece. 8 4) 30-61 | 37-0 | 35-5 | 15 | 22] 0-4 | 87 | N, a Meme mOtONG se co lancco|l age | a7 tal a ee 30-521 39:5 | 375] 20] 23 | 05 | 84 | B ts eet We | 9 { 30°36 | 360 | 35:5 | 0-5 | 2-4 | O-1 | 96 [BNZ, im 10 { 30-26 | 38:5 | 37-7 | 08 | 26 | 0-2 | 94 [HSE ie 30-18 | 37:3 | 355 | 1:8 | 22 | o5 | 85 | w. es Means,. 30°51 | 40-7 | 386 | 2:2 |.25 | 05 | 84 g §|30:50| 445 | 482°) 18. | 30 | 03 | 90 | F a1 eee AN aca 30-61] 423 | 402] 21 | 26 | 05 | se | E 8 6 30-67 | 44:5 | 42:2 | 23 | 28 | 06 | 83 | E 3 Siete re 7 { 30°68 | 38-0 | 37-0 | 10 | 24 | 03 | 91 | E ee Bes a pile a0 Rs 30-70| 44-5 | 42-71] 18 | 29 | 05 | 87 | E 2 4 mUvOHfeet. 8 { 30°63 | 37°5 | 36-2 | 13 | 23 | 03 | 89 | & 34 lms bes Lat. 56°3'N. [| 7 Ft nc oc | OG Ae 30°51] 405 | 382 | 23 | 24 | 06 | 82 | B 8 4 Long. 2° 40''W. | 9 { 30°39 | 36-5 | 352 | 13 | 22103 | 89 | B 2 ee Tes 0 { 30-27 | 39:0 | 382 | 0-8 | 26 | 0-2 | 94 | B G blame let 30-19 | 33:5 | 32:8 | 0-7 | 21 | o1 | 92 | E 2 5 Means, . ci 30°52 | 40-1 | 38°6 | 1°5 2°5 0-4 88 24 C. PIAZZI SMYTH ON 3 a Hygrometer cose ‘ical Wind Sx 9 AM. yeTemeticr 9 ass. Clouds. 3s oe a bane Computed Results. ee WSS Six ; 3 a = =z 3 ZS 5 STATION. 3 = 2 Peles fa 2 s a E é REMARKS. 2) Ee ih. Pelee = fhe | S| 4 B24] 13 2 /¢.15 8/382 £2 a He : eres a oat ac 8$|FzE8 os § S 2 |g.| | 3 | 22 [S52 |225| fe] 2 | gz| s | § = | ee | & | © | Bs [e(ai28| 271] = | es) 2) & SSE Be Js vo 2°) er |B ise 1 wea Mos yo ey aye i= Ves St NsiI a 8 re ins. A - grs. ‘ { 30°53 | 43-0 | 40-5 26 0-2 0-10 30°57 44:8 | 393 22 0-2 a. : 67 | 46-0 | 43-0 0-2 man ie 7 \|30-67 | 39-0 | 37-0 2°3 0-2 . 30°67 | 46-2 | 43-5 29 | 0 0-2 — 90 feet. 8 { 30-62 | 38-0 | 36-0 22 | 05 | 83 0-2 Eat, 55°59! N. 30°51 | 41-0 | 37-9 23 | 07 | 76 0-2 Long. 216 W. | 9 4) 30-35 | 363 | 355 19 | 07 | 76 0-0 * { 30:25 | 40-0 | 38-0 2-4 | 0-5 | 84 0-2 30°15 | 35°5 | 32-8 18 | o¢6 | 76 0-0 Means, . : 30°50 | 41-0 | 38-2 iS) o ° wa a = re) jected faedeodetihs 5 present Inquiry. Sa! 44:2 | 43-7 41-2 | 40°5 30°66 | 46°0 | 44-5 30°67 | B85 | 39-0 240 feet. 8 { 30°68 | 45:2 | 44-0 Sy ee 30°58 | 36°2 | 37-0 top e OTN | ——— ee ee Long. 2° 47’ W.. 9 { 30°49 | 48-5 | 48-2 30°35 | 36°5 | 36°5 10 ‘ 30°21 | 43-2 | 44:2 30°16 | 86°0 | 35-2 HADDINGTON, No. 9. O1) 98 |K.N.E} 1-0 0:0 | i100 | N.E.} 1:0 aa! oct E. 1:0 02 | 93 E. 1:0 Means, . “ 30°49 | 41°6 | 41°3 in the This Station’s results are re 7 30-47 | 420 | 41-0 | 10 | 28 | 08 | 92 | B. 30°57 | 40-0 | 38-0 | 20 | 24 | 05 | 84 | BE -61| 42:0 | 40:0 | 2:0 | 26 | 05 | 85 | E se ey 7 { 30°65 | 38-0 | 36-0 | 20 | 22 | 05 | 98 | E. wie esol) (eat laschcee Dace Mh eae beta, sMecseces ates 8 Ines | 3 | are 30°63 | 40-0 | 33-0 | 70 | 5 | 1-4 | 51 | Nw e 600 feet. 8 4/30:55| 36-0 | 35-0] 10 | 22] 03] 91 | o | .. 5 Lat. 55° 35° N. Sree ee a | > Soa eee ay ape 30-49 | 36-0 | 33:0 | 3:0 | 1:8 | 0-7 | 74 | &. Long. 3° 25" W. 30°33 | 34-0 | 33-0 | 1-0 | $1 | 02 | 89 | BE 30-20 | 40-0 | 32-0 | 80 | 1-4 | 15 | 46] S. 30°13 | 390 | 37-0 | 20 | 23 | 05 | 84 | E Means, k 30-46 | 38:7 | 35-8 | 29 | 22 | 0-6 Ko} PL ee SOS 2S a a | uy 3 | ee 30°54| 44- | 43: 0 BE. | 40 aa 30-52| 45: | 44° 0 BE. | 1-0 &o|| Cupar (Fire), 30°69 | 44: | 43- 0 BE. | 1-0 . $3 No. 11. 30-69 | 45- | 43- 0 E. | 1-0 3 Ba}| 210 feet. 3071| 45° | 44- | 1-0 BE. | 10 a oo || 30°63 | 46° | 44- 0 Bt ead ss iS *|! Lat. 56710'N. aie ES lin es sna a Hane __ 26.1! Long, 376’ W. 30°49 | 37: | 36° 0 BE. | 1-0 &e 30:36 | 38: | 37: 0 BE. | 1-0 35 30:26 | 38 | 36° 0 E. | 1:0 on 30°17 | 39: | 38: 0 E. | 1-0 | Means, . 30:51 | 42-1 | 40-8 3 ena | BE \ BRIGHT CLOUDS ON A DARK NIGHT SKY. REMARES, { Hard frost at night. oe Hygrometer Hvenometrical Wind Date. PE ban es Gomnited Results. Sic. ‘Clouds. aes SraTIon. B< 5 z be; 53 ge e c= é See | 2 is [be elgs® ae = 1 =) ap oS eapes. | 2 | So tee slays Sembee se |e | eo | os ee | A A | 82 |[sselesal so Ha | ie) is = apes |e | & | Be Ter Sls ee betes fea loeemie ss: || s 2 | o|iA | © | es |S Blas] elie | ge) 2 | gz & as oF 2 3 = ae & | &* AY |e ale Sige jaa 5 ins s é grs.| gr. hrs. g {| 30°50 | 45°0 So} 29 | 05 E.S.E| 9:0 is { 30°57 | 42°5 3-0 | 2-4 | 0-7 ES.E.| 40 Grascow, , | 30°64) 44:5 35 | 26 | 0-8 B. | 4-0 No. 12. ( { 30-67 | 40-5 25 | 24] 0-6 SE] 10] 1. ‘ 54 feet. g f | 80°67 | 44-0 3-0 | 26] o-7 E | 40 3 { 30-60 | 41:5 50 | 20] 1-41 E. | 10 a Lat. 55°53’N, |__— = = 2 lee oe ee ee S Long. 4°18 W. | {| 30°51] 39°5 25 | 22] 06 ESE] 1-0 { 30°34 | 41-5 15 | 2:6 | 0-4 ES.E| 1-0 19 § | 30°23 | 34-0 0-0 | 2:3 | 0-0 | 100 |S.S.B.| 0-2 { 30-14 | 39:5 2-0 | 2:4 | 0-5 E.S.E| 0-2 A Means, . | 30-49 | 41-2 a5] 24] 0-6 25 g § | 30°83 | 45° m4 | 3-1] ond N.E.| 9-0 | ... : | 30-63 | 41-7 2:6 | 24) 06 N.E.| 90 | ... BALLOCH CASTLE, a 30°67 | 44-5 2°9 27 rd N.E.| 4:0 A W No. 13. 30°71 | 40-5 19 | 25] 0-5 we | #0) 2. 98 feet. g {| 80°70 | 46-0 54 | 23 | 13 N.E.| 40 a 30-63 | 41-0 24 | 2-4 | 0-6 BE. | 0-0 a 12 eh a a eae Be | antes Rained Readbetl Es Long. 4°35’ W. | ; 30-54 | 37-0 12 | 23] 03 BE. | 0-0 6 30°39 | 47-5 19 | 3-2] 0-5 S.E. | 0-0 19 §| 3027 | 37-0 0-4 | 25] O71 SE. | 0-0 7 30-18 | 41-5 17] 26] 0-4 SE. | 00] ... Meons, . ~ | 30-52 | 42-2 2-2 0-5 . | 30 g f| 80°48 | 42-1 0-5 0-1 saa ee 30°55 | 37-1 10 03 see: Nez CaAsTLE-DouGLAS, 7 { 30°61 | 36-1 1-0 0:3 d Mies ee No. 14. 30-65 | 35-1 1-0 03 : sak Be 783 feet. ; 30-64 | 38-1 1-0 0-3, 7 ea R= ...,.. 30°56 | 35-1 1-0 0:3 ee Ih Be Aa ase ———— a a ee Long. 3°52 W. | 9 {| 30-45] 31°6 1-5 05 30°35 | 37-1 1-0 03 19 § | 30°24| 33-1 1-0 0-2 { 30°14 | 34-1 1-0 0-2 Means, . 30°47 | 36-0 1-0 0:3 & .. | 45°8 7 ee ae 6 { 30°54 | 42-0 7 a4 Morrat, 7 { 30°62 | 46°8 2 No. 15. 30-63 | 43-0 BT ie 350 feet. g § | 30°61 | 53-0 -0 | 100 ey cy 30°54 | 42°8 5 AiO ean | \\————— | \ aa | eae Long. 3°27’ W. | 9 {| 30-48| 43-5 1-2 { 30-35 | 40-0 0:5 ‘te j 30-22 | 45-0 0-5 30-11 | 40-5 18 6 S Means, . 30-46 | 44-2 0-7 | ected J ivy. in the present Inqu This Station's results are re — 26 ©, PIAZZI SMYTH ON | g a Hygrometer Hygrometrical Wind | Date. 3 e a ae Gap Results. rahe Clouds. A 5 - 3 = ay eel & 3 5g 3 Ss S?ation. Ty 3 < 3 : Ze S cs s sg REMARKS. Be.) eS We feu ie) iliges Boge eas el & z a. a 5 s class gS = i 3 ee | & A $3 [Sse |/25e| be a | se] 8 E = [eo 0 2 © | 28/2 elss2|s4 | 2 | 22] 8 5 a2 |[Es| 2 | F | es |S Biee3| 21] 2 | gale | & a a5 a= JP Oso) sa tea ESS a < < [-2) (=) Fale | Ba a i) na ell ys : ES.) ete hrs. 7 { 30°52 | 44: 41 Bb 3:6 07 77 E. 4:0 be 30°59 | 39° 36 3 2 0-7 77 = ae 7 { 30°66 | 42° 39 3 2-4 07 78 E. 0-2 STRONVAR, 30°64 | 37° 35 2 21 0°5 83 xi a No. 16. = Sees (eae ee See |e ees meen aie, coeiien ey Eee Se a 8 30°66 | 42° 38 4 2°2 0-9 72 E. 1:0 428 feet. 30°57 | 36° 34 2° 2°0 0°5 82 ae 3a Lat. 5620.N. | 9 { 30:49| 32° | 3l- | 1 | o2| 87 | BE | 02 BE Long. 4° 20 W. 30°33 | 34 33 I: 0-2 89 Pe 10 { 30°23 | 36° 35 iE 0:3 91 N.E 1:0 30°13 | 42° 39 3° 0:7 78 oan = has. 30-48 | 38-4 | 36-1 | 05 | 81 ee es er ae ; 6 { 30°51 | 44:2 | 42:2 0°5 84 E. D2, 4 10: = 30°54 | 47°2 | 42°7 ior} 70 E. 1:0 0 GREENOCK, 7 { 30°64 | 42:2 | 38-7 0:3 | 7 E. 2:2 5 No. 17. 30°61 | 53°2 | 46°7 uc7f 62 E. 0:2 0 was 233 feet. 8 30°66 | 43:2 | 37°9 1:2 63 E. 22, 5 30°57 | 55°2 | 42:9 31 40 E. 1:0 0 Lat. 55°57’ N.| | ———/—_ —|—__ —|—_— —— |_| — | — | | ——_. Long. 4° 45’ W. 9 { 30°52 | 36:0 | 383°9 0°5 81 i. 0-2 10 30°35 | 49:0 | 44:9 ial 72 W.. 1:0 0 10 { 30°22 | 37:2 | 36°7 01 96 E. 1:0 Nimb. 30°14 | 48:2 | 43:7 alae 70 i. 0-2 5 an Means,. . 30-48 | 45-6 | 41-0 li] 7 ie | aere al De 4 30-49 | 45-1 27 | 071 78 | BE 20 bg : 30°56 | 43°6 23 | 10! 6 | a PAISLEY, 7 j 30-62 | 44-1 23|10| 6 | E 10st aa ; No. 18. 30°65 | 426 22 | 10] 69 |-S.B. iy mi 88 feet. J 30°65 | 37-6 | 36-1 23 | 041 87 | SH. LO di 30°56 | 42°6 | 37°6 21| 11| 66 | E. es acts BO" GO NE [ed Laan ESIGN PARAGARGO pc Penh Pei APA | Bee eee Se) Long. 4°27 W. | g 30-48 | 39-1 | 36-1 21 | 07 | 77 | B. 1610 |) be 30-43 | 43°6 | 40-1 25 | 08 | 74 | NE. 4 10 | 30-21 | 35-1 | 39-1 17/07] 72 | Be Ldm || tg 7 30°14 | 41-1 | 38-6 24 | 08] 81 | E. ‘Means, . | 30°48 | 41-4 | 38-0 08 | 74 i { 30-48 | 52-0 | 47-0 14] 6 | BB | 10 2 ‘ 30°57 | 87°5 | 36-0 0-4 | 87 | NE] 1-0 0 Canutox-Mor, | j | 49°0 | 43-0 15 | om |) ar |) 1 1 . No. 19. 30-65 | 41-5 | 39-0 06 | 81 | BE | 10 0 135 feet. g § | 30°63 | 546 | 41-5 30] 38 | B | 10 Seel! ig a Sa oes 1 | 30°55 | 42:5 | 41-5 0-2 | 92 | N.EB.| 10 0 a at. 56° 5’ N. ——— | —_— | | FS - | | -—- —_ — —_- Long. 5°28 W. | g 30-48 | 45:5 | 40-0 12] 6 | B-| 1-0 fiom) 30°34 | 37-5 | 36-0 04 | 87 | EB. | 10 0 10 { 30-23 | 47°5 | 45-0 06 | 88 | E. | 1-0 9 . 30°12 | 36:5 | 35-0 o4| 87 | N | 10 0 2-4 | 1:0 | 75 1-0 | | Means, . . ated 44°4 | 404 BRIGHT CLOUDS ON A DARK NIGHT SKY. 27 Sa Hygrometer Hepraietrieal Wind Date. 3% aes Coniputed Results fades et || eae 38 : oa ae oS & =3 | b 3 4 ag tia = Ze es 4 3 REMARKS. Sration. se i ok Me a o|2,°3 Zo 7 g S 4 ieee = lie | Sele ee lees cose || = tS lice ly & d | ge) @ | 2 | 22 [see/Eze/ ee | 2 | 2a] 2 | : B S ay Ss ol ae a x jae A < ey) 43 Bees? > dee pea hs ins 5 é " ers. | gr. hrs. g {\s048| 4 fae | s | oe) on me] Bm | 10 3 30°53| 43: | 40° | 3: | 25] 07] 78 | & | 1-0 EALLABUS, 7 { 30°61] 47° | 42° 5: pee lees Gr E. 1-0 No. 20. 30-62| 47° | 43- | 4 | 27] 10] 73 | B | 9-0 71 feet. /g s/goe1{ 49° [a | 8 | 21] 19] 53 | B | 9-0 30-51 45> | 46 ob 52 |Pos | 14 bes |) me |) 10 Lat. 55° 47' N. Le i oii sae i Se | Eee eee eee Long. 6°15" W. | 0-46] 58 | 4 | 9: | 28) 22) 51 [Calm] 0-0 30-351 36° |-35° | 1: | 22 | 0-3 | 91 |Calm| 0- 10 {| 3025] 43° | 43° | 0: | 3:2 | 0-0 | 100 |Catm| 0-0 30-12| 38° | 37° | 1- | 24 | 0:3 | 91 | Calm] 0-0 Means, '30-45| 446 | 40-7 | 39] 25 | 0-9 | 75 2-2 4 { 30:56| 45-5 | 426 | 29 | 28 | 07 | 79 | S.B 30-60 | 381 | 36-0 | 21 | 2-2 | 0-5 | 82 | SB. 30-64| 44:8 | 40-0 | 4:8 | 23 | 11 | 67 |S.w. Seon CASTLE, De 30-64 | 43-0 | 36-5 | 65 | 1:8 | 1-4 | 56 |S.W. c ae eee | Se eee ee be Lee ) = 2s iI i= Ae A || cB | 99-0 | 12-3 |€-2| O-ar | SFP 76 08 | 69-0 | 71-6 | 9-6] 0-GF | 9-FF |] 98 | 9F-0 | 11-3 |8-T| 6-OF | L2F || 84 | 62-0 | 88-4 |%-e| Ger | L-9F || 6Z | 94-0 | 16% | L-e| 9-eF | 29% |] 28 | 29-0 | F6-3 | 9-3] G-eP | T-9P eai8 = G2 | 66-0 | GLB | 9-€| 8-Zh | F-9F || 98 | 8F-O | 83-3 | 6-1] 22h | 9-FF || ¥2] 80-1 | 16-6 |8-e| GFP | 49 |] e2 | ZO | 28-3 | oF] L4m | L8F | 92 | co-0 | ces | ¢-¢] LFF | o-8F oy ¢ Te | OL | 08-6 | 4-5] FFF | 88h || 84 | 98-0 | 00-€ | aE] T-oF | &-8F |] 89 | GET | 96-5 | TG] 9-9F | ZT¢ || OL | 92-1 | 86.3 | LP] G9h | GIG || IZ | 2a | 0-8 | 9.7] 69% | ¢-1¢ 229 De 69 | 96-T | BBS | 8-F| 09h | 86h || TL | PEE | 0-8 |G-F| 6.9F | F-19-|| 19 | 96-T | 16-3 | 8-9] GBF | e-g¢ | 99 | 96-1 | Toe | 9-¢] 2-2> | ¢-eo || 12 | oe T | 9¢-2 | 94] o-6F | B-ee EvaG Ei 69 | 86-1 | 06-6 | 6-7) 6-9F | 8-09 |] 2 | FET | GES |e-F| GBF | 8-29 || T9 | 80-4 | 9Ge | 0-2] 8-0¢ | B4¢ | 99 | TAT | 6L-€ | 2-4] €-6F | 0-99 || 29 | FET | 9-€ | 2-9] ¢-09 | 0-2e er a 69 | 96-L | 76-6 | 8-F| G-9F | 0-19 |] OL | FF-T | SEE |6-F| L-6F | 9-7E || 99 | 22-1 | T9-€ | 6G] 0-z¢ | 6ZE || 19 | 66-1 | eae |6-9| G09 | T-2g || 6g | 9a-3 | ae |9-2| GIG | -6¢ ere sl TL | GeT | 26-6 | 24) G-9F | 6-09 || 99 | FAT | OF-€ | 8-9] ¢19 | T-29 || Lg] 28% | ewe |62| L-19 | 0-69 | 19 | €0-2 | eae |0-2| Gog | e-z¢ |] 09'| OF-2 | 09-¢ 19-2 | ¢-e9 | 0-19 ec | 89 | 4E-T | 86-6 | 1-9] ¥-9F | GI || #9 | 00-3 | 99-€ | 9-9] eo | 8-89 |] 8G | Fez | cee |8-2| ¢-19 | e6¢ || 6¢ | oT-2 | ote |¢-2| 0-09 | g-2¢ | 09 | gz | oe |o-2| 299 | 29 || wat HT Imolatalie tole cle en ee 1 : ttBast Linton 5b n } \ as Y te 76: 9 Haddington. : 7 : 2, 4V Esk Reservoir é 4 fe ns. Roy. Soc. EpIN VoL_. XXXII. Pate IIT Slatians Acre , xfther Eolr burgh , arvang 2) in order of height. a : a ee nips oo .57 WN: mei UW reft.| April 6. Te alge alacwl RM, A RM, Baer | A es mSemval 3 Po PM. Naten| fe AY ‘i MU Worth Esk pests Ne 3 sil Dall “USO feet Lat- eae Dons Rg Abrel 6.) 7a. Humid! Aprel 6. ip GAME BM. ae ry Ie PM Ati PM AM PM.\-cby. 1A m| RM. a al Nee A.M RP Bre A Braemar, ie 2. ee Wh fee Lat = 57. aM. Long. es Ww: Defrefs. |Aprel 6. (Oo - Huind-| Aprel 6. 0. ee. GAMPRM A.M, (am ae An Anil maVaeA Rwli-y. |Am/aalam| em bal pM. a PM. oes ee mn il Appendix tf. Flate 2. os OY. OC. EDIN* VoL. XXXII. PLATE IV. pple erat? seat wee 1, eS bins Lot -55,35-N. , Lor - sane We T React RM Aah Sl a P.M A. M. ane aT Pe — Oo} || 8 met Stolo Castle ;, Ai lo. Herjzkt = 6am feet Lat 2SSn35 N. Lory 3..a5¢ Haurnd- Aprel 6 ~'h |AM|PM. 7, I 10 » THOAMIGRM | AM | PMN AMICM. AULA M.| AMIR M. | March ment (Bermisl) is, Higit« Soufest Trateshde «Taye ta6 N35. LLeight= Soofeet. a = A.N.} P.M. | ALM. | Pl. ~rhy A.M.19 PM AM fe S) ~MIgP. MM. MN. A. ra ae Siri iy a aN Tet ree | eae IN| Greenock. WP yy. FZargh eigah = 233 feek i a ae Does ee 27s marth lan Pra ies aad an ae ara E (ao go 72 fe ic) 8% &o 2 \ 72 2 is aN 6% : Ss Appendix IT. Plate 4. upar we ae ame. Lat : $6. ee sn 3%. =a eeu jeleu! es erases ae P.M, ee PN. gA.MIg RM. ile =a A.M eeu jeleu! P.M. ae PM. Pel PEEL Le a Dalkesth mae pale = meee Lat = 55.5% M. Le “an we Hes clea Fumit| Aprile iin 7 PM. i Lee al PM. eee P.M. Hes pm.|- ty. |gaa een. red PM. PANNE vw MLL a ae =e ca beSUed Lats $¥.,2) DW. See 3.27 We See Abr i lE a Api le ee ae A.M FM] A.M. sh 4M. Ve ae PM. Ai Tem - |JAM\9 are PM. ee PM. ee PM. UTA i ‘iil Wmeaton. oka 4) foe __Wmeaten. Wey Heisht= too feet Lat 86.5 Di Loong tito 56.3 DV. sa 2.40 W. endef ES ul 4. u.| PM P.M.|| 4M! PM. ze PM. ||-é 4. a TF &4 Gaccauncanak Appendix IT. Plate 5. ae ioe es P.m| AM pea TRANS. Roy. Soc. EDIN* re ae VoL. XXXII. Puate VII. Balleck ase I 13. al aii Let= $6.1 Lang, eRe pro] Write Lad 7) mat.| April © ae [Eafe GANID PM el pm|l aw. ew. 4.M[PM. | 4 MPM. oe. 7A. MIG PN Ail P.M. AM. | PM. Poa PM. elon lee ARE ot “ fast Linton, WN 8. see Lat.x S&., ae ia ZS WW. Beem) April & ta) ae fee ~0ty. |g Am PEG P.M. ie melon A.M) CM. A ML JL | E Paisley a a call $§ de Mi ide Lat= 5Fn So ees, = Ze oa [Depreyr | MaKe 6 | > (| Aprile Wer 8. A.M. Pat / Eedlalus N20. Feghkt= Ji fet. Let=SF,4yX. Longe 6.15 Wo te oH aie Oe to P2 $8 2-0 &% So 3-0 Jo 72 4O 68 66 ro $0 SO Ce $2. | ; fo a Appendix IT. Plate 6. a Sles gow BW 42. LLecpht = eae Lot=s8; 53 ve ie = ae WW, ee Oe MM. 4s] P.M, we ee Hastealannaladien a mien ro oe | | 4°O Fg | Basser, aaa a MW 26. Height = poet —— SF FN. Ze So ig eh (42) Tia m'~ ‘Cant i 0A. MIP M sila sien ped ee ay ae oe Pens ee, 53 =| ae os oe ae 9A. MIG P.M. ail eal ahem: are PM. il ia | ir | i Q /\ ramet ca cay gA.M19 PM, a PM|A.mM.| PML AM. ama oS erik Baud PEL Cem, Me Revo eZ 1€@ Counecl N°2 a 9A. (U. : a PM. Atle pai none ieee ye fee eae Eee ; ri Ls 3 -<)77] i: Appendix II. Plate 7. ‘ANS. Roy. Soc. Epin® VoL. XXXII. PLare IX. o = Dat = Si Hawid.| Apres | > | em 2 (6 -h&y, 19am. |9 2U.|9AW19 PM lo alo Palo ams CM 9 Ampr. nM. TH] olatts| Cov Aly SO-+-O. | II Kor 9 +O | 61 7 ah SR ee C) ig i ' 4 = — U) Zuni Gerad etl Gerad GP MIA. M. (ce en lew Dies : Tr i TT SNNIER Ta Lnvern sft, H? 24 (Addlisnel Statin). Hight Uhjt Latah Lory ehh = 2:3 sees lanel eiiatt as EIS Liak = x 2+. Long. = 4.13 w Wer-B, 7A.N.\9PM.)A.N. dev A.M. fe Si PM. re ee -0 A.M 1g RM ae 9PM. | A. MIP M [LAM] PM AMR OM. ; BR UN CATT 2- c=——o, a= So | 3-0 4:0 | o Appendix II. Plate 8. . o We+ B. | 9AM | 9 PA.MYEM.\194 M PM, || A-M. 9 P_M-[94. M.|9eM. re Curvvl|) ay Marparg "4 PL ‘aay fo p00 sqr;y J YNOD VA fo HVA VoL. XXXII. Puate XIII. Tras. Roy. Soc. Epin® /832., Lk 7. § oMt2 £6 8 WO fmr~ lh 6 8 10M } PLATE XIV XXXII. VOL. Soc. Epin® NS. Roy. tT 4| - 2 wet 3 ¥ tuys 897 =, 4 2.14 Sty 78 9 4 Tuo! 8 9 ¥ Z 6 pty 7 89 7% cuvonoH $ 5 4 @ | "8 704g 4 ot 9 ¥ wus § g » F- £ wedy 4 78 9 7 TwHfo, < o 7 "2881 9 2udy £5 US} ah) ee of ‘ F72LIIO XN) 97274, / | OY yh ucy,, ve ? t8 * Yada“ is beetles tag?) heopen.casng (7 Pey” OP ‘70 PAY ae ‘ALIGINOH Zz ‘ Y dO, OAL BSI a (8%) TII.—Note on the Little b Group of Lines in the Solar Spectrum and the New College Spectroscope. By C. Piazzt Smytu, Astronomer-Royal for Scot- land. (Plate XV.) (Read June 1883). Every spectroscopist is perfectly aware that the group of dark Fraunhofer lines in the Solar Spectrum, known as “little b,” is composed of the biggest, broadest, most colossal lines in all the brighter part of any and every spectrum depending on Sunlight, whether direct from the Sun or reflected from the earth’s atmosphere, the Moon, or any of the planets. How the apparent misnomer came about, was not on the principle of the biggest gun ever made by our military, being termed “the Woolwich infant ;”’ but because after FRAUNHOFER had spaced out the spectrum into nearly equal lengths, so far as the majority of the chief lines allowed, and called them by capital letters, beginning with great A in the ultra red and ending with great H in the ultra violet,—he then began again at the red end, and marked all the notable intervening lines by small letters. Whence it came about that those sometimes very imposing bands of telluric water-vapour lines “little a” are found between great A and great B; and those grand and truly solar lines in the green, little 6, are found, by accident as it were of Nature, between great E and great F. In the smaller class of pocket spectroscopes and on the faint light of the Sky, observers merely recognise two strong lines ; the first from the red end is b*, and the second, considerably thicker, is 67. A very little increase of power, however, easily shows b? to be composed. of two lines, 6? and 63; and Fraun- HOFER himself had announced it. But that such J? was still further composed of two lines was I believe first discovered by Professor Swan, and published in our Transactions as part of his now classical spectrum paper of 1855 and 1856. For therein (vol. xxi. p. 427) he mentions most clearly—though calling our b*, 67, b? by the names 8, 0’, b? that “on the 20th of May, about 7° 10™ p.m. when the sun was rather low on the horizon, but free from clouds, he observed with a magnifying power of 21 (on his large theodolite telescope, directed to a single prism of 60°) the line 6? (our 63) to be very finely but distinctly double ; so that,” he adds, “ the group consists of 4 lines” (our 0", b?, 63, and b*). While on page 426 he had already expressed his admiration for the group “as being one which, whether we regard the singular configuration or the strength of the lines which compose it, is perhaps the most notable in the solar spectrum.” In the Philosophical Transactions of the Royal Society (London) for 1860, VOL, XXXII. PART I. | G 38 C. PIAZZI SMYTH ON THE there is a picture by Sir Davip Brewster and Dr GLapsTONE confirming these four grand lines of little b, and adding some thinner intervening lines and faint broad bands. But before that could produce much effect on men’s muids, it was utterly eclipsed by the far grander Solar Spectrum map, first of Prof. Kikcuorr, and then of Professor ANGsSTROM, whose exquisitely engraved, and certified, map still remains for many purposes the Normal Solar Spectrum Map of all the human race. Now let us take a new start from that last map, date 1868, in order to ascertain something of our present degree of knowledge touching the visible characteristics of these four remarkable lines ; for however many thinner ones there may be, the principal members of the group are four only, and have over- whelming importance. Two of these moreover, viz., b' and b? were represented by Anastrom physically different from the others, be slightly bordering them with haze. In -1875 the Royal Society published a map in their Philosophical Transac- tions, where they represented (though by a very exceptional kind of symbolic marking, looking really like something else very different but very important if true) these haze borders of 0* and b? as still broader; but made b? and 54, pale in a high, dark in a low, sun, as though they were atmospheric or telluric lines, which they certainly are not. In 1880 M. Fievez, in the R. Observatory of Brussels, represented several lines hazy, though he left 6* quite sharp and black. But in the same year Professor VoGEL, of the Astro- Physicalischen Onsen tory at Potsdam in Prussia, and armed with a new spectroscope of immense power, published a very superior spectrum map wherein he represented 0", b? and 6‘ all equally and very broadly hazy, but kept b? quite sharp, well defined and black, besides adding many thin lines, some single and others double. In the following year at Madeira I had the opportunity, besides confirming Professor VoGEL on all the four great lines, of adding thereto the further physi- cal distinction that the lines themselves, inside the envelopes of haze of b', b?- and 6* were all of a peculiarly faint material; and of presently still further discovering both that the 6* line, within the compass of its own haze, was double ; and that 6’, without any haze, appeared not actually double, but to promise certain resolvability into it, had my apparatus been only of a slightly better order. At the time I could hardly believe my eyes; but have learned since then that the duplicities of b? and b+ had been just previously to that date ascer- tained with some of the splendid spectroscopes in America; as they were also subsequently by a second very powerful spectroscope built up, and employed by M. Frevez at the Royal Observatory, Brussels, in 1882. But perhaps I am going on too fast; for certain learned parties, to whose LITTLE 6 GROUP OF LINES IN THE SOLAR SPECTRUM. 39 extensive knowledge implicit respect has hitherto been generally paid, have not yet taken any notice of either M. Frevez or the American observers. 60°30 0°60 | 0:45 015 0:50 | 0:50 » (Craigiehall), . 1880 | 135-00 = ang 0-50" |, 60765.) 0:60 és ni, Ce ; 1878 116°35 0:80 | 060] 040] 035 | 0°65 # - is 61°75 0:60 | 0:30 O50). 30:50 (0°70 3 co Oi ; 1. 71:85 0-70 | O50] 0:55 0°65 0°85 Lime, . 3 : ; 1878 76°10 050) 0-15 0:00 065 | 0°55 Birt} 5 ’ : i 42°70 O70) O40!) O15 0°25 0.40 » (Craigiehall), . a * 99°65 0-20), Oris O08) 20:25.) 5 Ora Sweet chestnut, . F ;, 70°80 LO; 0:90) 0:65 5 LO) 0-90 Tulip tree, . , ; me (5770 K-00") 040) 030 0°55 | 0-50 Horse chestnut, . ; ‘ 48°75 O°75) 07505 10-35) 0°70. |b O10 Hawthorn, . : 3 aA 38°00 0:80 0:10 0:75 0:35 0:65 Flowering ash, . 4 ; 75°30 Co0n SO405 0:30) 0775 | 0°50 Sycamore, : as _58°60 0:50 0:20 0:15 0°30 0:40 English oak (Craigiehall, 4 69°45 0°65 0:50 0°20 0°35 0°35 Turkey oak, 4 1880 73:00 ae Se 0°70 P25 0:90 : : 1878 41:90 0-60. |. 0:65 | 0:35 0°60 | 0:65 American ‘oak, : ; Ks 30°80 050 | 040] 030 0:30 | 0:40 Hungary oak, : i 23°60 ISO? es P70. |) L40"+> TPSb Ie ess x f 3 : 1880 16°45 5 abs, TLO|, S EGON Hile-90!. . ‘ ; : 33 13°50 ee me 110i OR eet 50 Hornbeam, . ‘ : 1878 44:50 O40 | 035°" 0-10) 5 Oboe" 0°50 Total increase of 22 trees first marked in 1878, ee Ke. L500; P05 1 8 fomiei2- 90. | 13°75 Average per tree, its oF 068 | 050] 040] 058 | 0-62 The same, with 5 added in 1880, . 7 box a. . a Ae 12°55 | 18°65 | 19:10 Average per tree, we seg - one 0°46 0°69 0°71 48 SIR ROBERT CHRISTISON AND DR CHRISTISON ON THE TABLE IJ,— ANNUAL INCREASE IN GIRTH OF EVERGREEN TREES, All in the Botanic Garden or Arboretum, except those marked “ Craigiehall.” Increase, Date and Girth Trees. when first measured. 1878. 1879. 1880. 1881. 1882. Inches. Inches. | Inches. | Inches. | Inches. | Inches. Douglas pine, . . | 1878 | 5610 | 0-60] 0:45] 045] 0:60] 0°50 ‘i a : : » 64:30 080 | 0:30 | O35): 0:35) 040 Pinus excelsa, . ; 5 30°90 035 | 020) 005 0:30} 015 ce ie ; . > 32°70 040 |} 0:20] 035 | 0:35) 0-40 Sequoia gigantea,. . » 23°95 Ti5| 0:30) 1:00) 035 | 070 a hae : » 23°95 75s ps6. SO, SO ee ay oD A . ”» 18°95 1°85 1:50 1:50 1:30 179 . 5 : 5 » 23°85 1:25 170 1:55 1°35 1°65 Deodar, 5 : “ » 26:10 1-10 |, 0°70.) 0°45 |. 0:35.) 0:95 . : ; . oe 64:00 1:20 0°60 0:40 0°25 0:70 Picea Lowei, : F » 15:00 40) 1:25) 1:40) 0:90)" G05 _Araucaria, . : : ” 18:10 0:60_|...0°50.| 0:55 | 050 |. 0-45 : f ; 3s 20°20 050} 0:90] 075] 0601] 0:85 - (Craigiehall), 1879 17:90 tie 0-85 | 065 | 0-45 | 0-70 Atlas cedar, . ; ; 1878 27-55 | 1°65 | 1:40 | 1:75. ). 240)) “60 Evergreen oak, . 1879 29:05 ie 0-40} 010] 010} 0:25 Yew, .. ; : 1878 |- 67:60 0:60 | 060) 0:35 | 050] 0:50 34:10 0:50] 015] 020] 0:30] 0:45 . : ¢ : ; 1879 37°50 060 |} 040] 0-40] 0:55 se ' 4 ; ; 9 23°50 ie, 030 | 035] 045) 0:55 o ; : ; : 2 33°30 on 045} 040] 035 | 0-45 copula Mpa nd 1880 SAD. Ot = hae = 015 | 0-15 |) (O26, Cypress (Craigiehall), . 1879 14:20 <> =| O80) 15.) 270:'36. | > 085 Total increase of 16 trees first measured in 1878, . ; ‘ at A 15°70 | 12°90 | 12:90 | 10:90 | 13:50 Average per tree, me or 0:98 | 080; 080] 068] 0-84 The same, with 7 added | in 1880, . ; ‘ at oy -. gfe 16°10 |" 13% | T7-2s Average per tree, fet hie .* ee 0-70 | (0:59 |. O75 The most remarkable result from the whole series of observations is the want of correspondence between the deciduous and evergreen classes in the increase and decrease of the growth of wood in the different years under review. Thus, as the tables show, a remarkable decline took place in both classes in 1879 as compared with. 1878, the average growth of each tree for these years in the deciduous class being 0°68 in. and 0:50 in., and in the evergreen class 0°98 in. and 0°30 in. But in 1880, while the deciduous average declined still further,—to 0°40, the evergreens remained quite stationary ;* and in 1881, when * Sir Rozerr Curistison believed that they also had declined, although to a less extent, but he was misled by an error in the figures of his MS. GROWTH OF WOOD IN DECIDUOUS AND EVERGREEN TREES. 49 the deciduous average rose decidedly,—from 0°40 to 0°58, the evergreens suffered a decided fall,—from 0°80 to 0°68. In 1882 the difference was not so remarkable, as the average of both rose, but in the case of the evergreens to much the greater extent of the two. I shall endeavour to explain the causes of these differences at the conclu- sion of this paper, under the head of the connection of weather with the growth of wood. Sir Ropert CHRIstiIson was inclined to attribute to the oak tribe a greater power of resisting inclement winters than other leaf-shedding trees possessed. At page 84, part iv. of his paper, he states that while leaf-shedding trees in general suffered a reduction of 41 per cent. in their increment in 1879 as compared with 1878, seven oaks measured by him lost only 10 per cent. Unfortunately, for various reasons, all these oaks are not available for comparison in subsequent years, but at page 168, part v., he showed that the average increments of fifteen leaf-shedding trees in three successive years down to 1880 were 0°80 in., 0°45 in., and 0°35 in., and that the corresponding numbers for four of the oak tribe were 0°82 in., 0°77 in., 0°54 in., a result still favourable to the oaks, although not so much so as in the previous instance. But if the facts be examined in detail, it is evident that this apparent superiority of the four members of the oak tribe is really due to one of their number—the hardy and quick-growing Hungary oak —and that the other three, although they suffered little loss in 1879, fell off greatly in 1880. It must be considered also that all these trees, with the exception of the hornbeam, which Sir Rosert classed with the oaks, are of foreign origin. If we reckon the growth of the hornbeam with that of the only two British oaks whose measurements are at all reliable, the result is most disastrous for our native oaks; for while their united growth in 1878 was 2:05 in. and in 1879 1°65 in., it was only 0°70 in. in 1880. In these experiments the number of trees may be too small to give thoroughly reliable results, but it certainly seems probable that the foreigners—the Hungary, American, and Turkish oaks—stand severe winters, in our neighbourhood at least, better than our native oaks, the Hungary oak being much the hardiest of ail, while the British oak comes out worse than any other species of tree under observation. The yew seems to form an exception to the rule that the increment of wood in evergreen trees continued to decline in 1881, notwithstanding the remarkable rally made in the leaf-shedding class in that year. We have seen that the average growth of all the evergreen trees declined from 0°80 in. in 1880 to 0°68 in 1881 ; but if we take the yews alone, five in number, we find that their average growth rose from 0°35 in. in 1880 to 0°40 in 1881. Thus in the wave of decline and rise during the three severe winters they followed the deciduous group, and not their relations the evergreen Pinacee. 50 SIR ROBERT CHRISTISON AND DR CHRISTISON ON THE II. MontTHLty OBSERVATIONS. - Encouraged by the results of his annual measurements, Sir Roserr CuristTison selected in 1880 five deciduous and six evergreen trees, already ascertained to be quick growers, as suitable for monthly observations. These trees comprised two beeches, three Hungary oaks, four Sequoias, one Araucaria, and an African cedar. They were measured at the end of May, June, July, August, and September. The operation was repeated by himself in the same months, with the exception of May, in 1881; and again by me in 1882, with the exception of August. Thus a tolerably complete record of the monthly increments of these trees was obtained for three seasons. As the number experimented upon, however, was both too limited and comprised too few species to give altogether reliable results, I commenced in 1882 to make monthly measurements of a considerably larger number, and henceforth twenty- eight- deciduous and eighteen evergreen trees, including twenty-two species, will be under observation. I shall now proceed to consider the conclusions to be derived from these measurements in the solution of the following questions :—1. What are the months to which the growth of wood ts confined (a) in deciduous trees as a class and (b) in evergreens as a class? 2. In which month is the growth of wood most active in these two classes (a and b)_ respectively? 3. What are the peculiarities in these respects of different species of trees ? In the Tables III., IV., and V. the facts will be found in detail on which the subsequent conclusions are founded. Table III. gives the three years’ measurements and average growths of the smaller number of trees originally selected by Sir Rosert; Tables IV. and V. the results of a single year’s observa- tions on the larger number, measured for the first time in 1882. The trees in this list only partially correspond with those used for annual observations, as a considerable number of the latter, from growing too slowly or from other causes, are not reliable for minute measurements, 1, a. The Months to which the Growth of Wood is confined in Deciduous Trees, From the measurements made in 1880 on his five selected trees, Sir RoBERT came to the conclusion that the growth of wood in leaf-shedding trees is con- fined in general to the months of June, July, and August. I think however that he underrrated the importance of the May growth, It amounted to 12 per cent. of the annual total, which it must be admitted is a substantial sum. It was due however almost entirely to the three Hungary oaks, the increase in the two beeches having been scarcely appreciable. Unfortunately the measure- ments for 1881 were not taken till the end of June, so they are not available for this inquiry. But after the unusually mild winter of 1882 the May growth GROWTH OF WOOD IN DECIDUOUS AND EVERGREEN TREES. 51 was nearly twice as great as in 1880, amounting to 21 per cent. of the annual increase. Again no doubt it was mainly due to the Hungary oaks, their pro- portionate growth for May having been 24 per cent. of their annual increase ; still the beeches were not idle, their corresponding growth amounting to 10 per cent. And although the Hungary oak—exceptional among deciduous TABLE IJ].—MontTHLY INCREASE IN GIRTH, IN HUNDREDTHS OF AN INCH, OF FIVE DECIDUOUS AND S1x EVERGREEN TREES IN THE BOTANIC GARDEN. — trees for its early vigour—unduly raises the average in so small a number of trees, a substantial increase in May nevertheless did take place among deciduous trees in general. For if we include the whole of them, twenty-five in number, other than Hungary oaks, which were measured for the purposes of this inquiry for the first time in this same year, their average growth in May proves to be 12 per cent. of the annual increase. Including the three Hungary oaks the pro- portion amounted to 16 per cent. 1880. | 1881. 1882. May May | Lay Agee May. June. and | July.| Aug. |Sept. |) and | July. |} Aug.|Sept.|| May. June and jJuly.} and June. June. June Sept. Deciduous Trees— Beech, . (00 == 25) = -25 | 50 | 10-00 | 20) -25'| -35'| 051) 10: + -35 — 45} 40 | -30 is HiOe-= SO 410) 20) -She-Oael oo 1 Sa) 15) 05") tb 4-30 = 451-30) 35 Hungary oak, { 30 + 40 = ‘70| 40] -30) 00 || 60] 50] -65| -05 | 30 + -45 = -75) -60| ‘50 # Re Oh = 420) = 45 130) 30-05 | 765) 45) 50) 00) 85 + 50 = -85 1) 55 | -50 f , Ors or == >) 50") 25) 05 I-60!) soa) 50") 00 “65 + “15 = -80) 50) 20 Total, . |0°65+1:65=2:30 |1:70 |1:30 |0°15 ||2°40 12°10 [2°15 0-15 11:55 +1:753= °30 |2°35 |1°85 peer | 0-13 +.0°33=0°46 |0-34 |0-26 [0:03 ||0-48 [0-42 |0-43 |0-03 || 0:31-+0:35=0°66 [0°47 |0°37 Monthly aa 12+ 30= 42/31] 24] 3 | 35/31/32] 2 | 214 23= 44] 31 | 25 centage, ; Evergreen Trees— Sequoia, 40+ -25= -65| -40/ 05} -00|| -40/] -00] 15) -00 |) 25+ -30= -55] 10] -05 + = 5+ *50=1:05} :70| 15] :00 |1°00) 05) 45) 00] 45+ -65=1:10)| -20 | -10 ss F OS 40 — tO) | 008-00 I-85) “2 20) 00) “To 65=1-40)5:25.| 10 x , 5+ 40= 95] 45) 00) -00} "75| :30] 30) 00) °55+ -55=1:10} -40] 15 Araucaria, 40 olor —e oon lpclion | OoNeO0) e-SonpeOnmaton "OON) “Abit TO" 5:5) elon) “15 Atlas cedar, . A oOo 0) | SO Obes) 35) 505) “O0N) Bo-ee40—. "75 40 | 45 Total, . |3:05+2-00=5-05 |2:40 |0°75 |0-05 |/3-90 |1:05 [1-75 10-00 | 2804+ 2°65=5-45 |1-50 |1-00 agg at 0-51+0:33=0°64 |0:40 |0-12 |0-:01 110-48 |0-17 |0-29 |0-00 |) 0-46 +.0:44—0-90 |0-25 |0:17 Monthly per- ye one es) eee ae ees Tips eae Eoatage, \ oie 24— 61730 | 9 0 | De Pisco | O Sb-EeSSs— GSO ie on Wo SIR ROBERT CHRISTISON AND DR CHRISTISON ON THE At the conclusion of the growing season the limit is probably more fixed. Neither in 1880 nor in 1881 was a greater increase than a twentieth of an inch recorded in any tree in September. So small an amount as this comes within TABLE [V.—MoNTHLY INCREASE IN GIRTH OF TWENTY-EIGHT LEAF-SHEDDING TREES IN THE BoranNic GARDEN, ARBORETUM, AND AT CRAIGIEHALL IN 1882. _ Increments in hundredths of an inch. No. Trees. Girth 31st March. May. June. July. August. 7 | Beech, : ; c : 5 75°05 ‘10 35 ‘40 30 8 o ; ; : , : 64:30 “15 30 30 35 14 x ; : ; ; ; 13D 05 ‘20 ‘20 “15 38 . : ; : ; : 62:00 00 “185, 30 =) "05 8 -|..,, Craigiehall, . : . | 1386-15 ‘00 sof “25 15 9 = 5 : ; . | 118°45 ‘10 “15 25 15 14 te 5 , , : 63°70 a5 ‘10 "25 ‘20 15 D » : ; : 74:30 15 ‘20 30 20) 22 Rs ‘ 4 : : 98°35 ‘10 ‘10 ‘20 ‘05 40 | Hungary oak, . : ‘ : 30°35 30 “45 ‘60 50 54 ms aes A ; ; ; 19°15 ‘OO ‘50 "HD 50 55 i tealg 3 ; ; : 16°30 65 "12 ‘50 20 44 | American oak, . : , ; BI 1515) ot) ‘10 1 00 43 |Turkish oak, . , 2 : 44:20 ‘10 “15 30 “L!5) 10 ; » Craigiehall, . : 74:95 ‘20 20 30 “20 12 | English oak, : : ; TL'15 05 05 ‘10 “5 33 | Hornbeam, ; 2 ‘ 45°90 "15 "15 15 05 28 | Sycamore, . mie ; . 59°75 00 25 15 05 58 mB. Y ; : 63°50 ‘00 05 05 00 7 wf Craigiehall, : ee Pala TD ‘00 “25 aii 05 18 | Lime, ; : : : ; 44°20 05 5) ‘20 ‘00 21 » Craigiehall, . ; ~* | 100-35 ‘00 05 “15 25 3 } Ash; . ; ; : , : YW 3) ‘20 “5 “ey 00 6 » Craigiehall, ' ‘ 2) aAOe te iO 15) 05 05 4 |Spanish chestnut, . : “ 74:75 ‘05 ‘20 "30 "39 9 | Horse chestnut, ; 5, ; 51:05 ‘00 05 “05 ‘00 6 | Tulip tree, : : ; P 78:15 1 £00 05 20 25 5 | Birch, Craigiehall, . ; : 57-15 ‘00 "15 20 ‘10 Average of the 28 trees, e at 18 "24 ‘16 . 3 Hungary oaks, : re ee lb) ‘37 ‘53 ‘40 _ 25 others, . ; ; : = ‘O7 alts) ‘20 gi) e 9 Beeches, . 5 ; : ae 09 "19 27 18 - Monthly percentage of 28 trees, . F oe 16 26 35 23 ‘3 - 3 Hungaryoaks| ... 25 20 31 24 : a 25 others, 5 TH 13 27 36 24 ‘ 53 9 Beeches, . Ra 12 26 hi 25 the limit of probable error ; it may be doubted, therefore, whether any increase really took place in that month ; but as the differences between the records of GROWTH OF WOOD IN DECIDUOUS AND EVERGREEN TREES. 53 August and September, trifling though they were, all indicated an increase, it is probable that a slight and altogether immaterial growth did occur, Measure- ments kindly made for me by Mr Sap.er in 1882 to test this question further TABLE V.—MontTHLY INCREASE IN GIRTH OF EIGHTEEN EVERGREEN TREES IN THE BOTANIC GARDEN, ARBORETUM, AND AT CRAIGIEHALL IN 1882. Increments in hundredths of an inch. No. Mapas Girth 31st ; H March. May. June. July. August. Inches. 25 | Sequoia, . : . : ; 27°55 "25 30 ‘10 05 27 - : : . : : 30°65 45 65 ‘20 10 if Z : ; é : 25°10 25 65 “25 10 2 % : : , ’ : 29°70 55 55 i EO oh 05) 29 | Deodar, . ; 3 L i 28-70 10 20 30 st) 30 : ' ; : ; 66°45 ‘00 20 30 "20 34 | Araucaria,. ; 3 : ; 20°25 AD ‘10 05 05 35 a ! . f : : 22°95 “45 ‘10 5 5s + - Craigiehall, : ; 19°85 25 25 ‘10 ‘10 31 | Picea Lowei, . 5 ; : 19°95 45 ‘20 20 20 5 | Douglas pine, . : : 58°20 15 25 10 05 2 | Austrian pine, Craigiehall, , ‘ 21°55: 65 “40 20 30 39 | African cedar . Re 33°75 cats “40 “40 ‘45 1 | Cypress, Craigiehall, . ; : 17-00 35 "25 “20 05 41 | Yew, : : F ; 69°65 10 hd 10 AS 48 5 F . ; 2 , 38°90 gid ay ‘20 05 49 a 4 ; : j : 24-60 “20 10 od a) 10 eel 45 : : : : ; 32°50 ‘20 00 05 Ny Average of 18 trees, . : : ; ee 31 i 19 15 4 Sequoias, . : 2 sige ‘50 "bo "24 ‘10 3 Araucarias, . : : ve | 15 10 10 4 Yews, . : : : ae 16 10 “LA: ‘11 2 Deodars, . : : ir 05 ‘20 30 27 Monthly percentage of 18 trees,. Ace 34 29 21 16 4 Sequoias, . ice 36 39 28 7 3 Araucarias,. O54 47 23 15 15 4 Yews, ; ee 33 20 25 Dy, 2 Deodars, . Se 6 24 37 35 | proved unfortunately unavailable, owing to inaccuracies in the tape used. But as the increment for August and-September combined was less than in the two previous years, it is fair to conclude that there could have been no material growth in the latter month. 1, b. The Months to which Growth of Wood is confined in Evergreen Trees. From the monthly measurements in 1880 of the six originally selected trees, Sir RoBert concluded that the evergreen class begins to increase materiallyin girth VOL, XXXil. PART I. I 54 SIR ROBERT CHRISTISON AND DR CHRISTISON ON THE in May, a month earlier than leaf-shedding trees. This conclusion is amply con- firmed by the measurements of the two succeeding years. In 1881, indeed, the proof is not positive, as the first measurements did not take place till the end of June; but as 51 per cent. of the whole annual growth was accomplished by that date, it is fair to conclude that a considerable proportion of the increase must have taken place in May. In 1882 there is no room for doubt. The increment till the end of that month actually exceeded the increment of any other month, and the only question is whether a portion of that remarkable growth was not due to April. Unfortunately, as no measurements were taken at the end of that month, this point must remain doubtful. But the reliability of results obtained from so limited a number of trees and species may justly be questioned. At all events, it may be held that, although true of these species, they may not be true of evergreens in general. Fortunately, however, these results are amply corroborated by observations on the larger number of evergreen trees, first measured for monthly comparison in 1882. The proportion of annual increment in these eighteen trees due to May was 34 per cent., almost identical with that of the selected six, which was 35 per cent. The limit of the growing season in evergreen trees is better ascertained at the end than at the beginning. Of the six selected trees only one—the African cedar—showed the slightest trace of increase in September, and that only in one of the two years in which observations are available. The increment recorded, moreover, was so slight as to come within the limit of probable error. In August the proportionate growth seems to be much less in evergreen than in deciduous trees. In August 1880 the increment of the six selected evergreen trees was only 9 per cent. of the annual increase, while in the deciduous group it was 27 per cent. In 1881 there was a greater equality, the respective percentages being 31 and 34, But in 1882 that of the evergreens again fell to 13, while the deciduous percentage reached 25. The results for the latter year were confirmed by the observations on the larger number of eighteen evergreen trees, whose proportionate growth for August was only 15 per cent. of the annual increase. On the whole, the conclusions to be drawn from all these observations are— First, that in ordinary seasons the growth of wood in deciduous trees is mainly confined to June, July, and August. In September it is scarcely appreciable. In May however a small growth does take place, which in favourable seasons may become of no insignificant amount. The Hungary oak not only grows with exceptional vigour in May, but probably in favourable seasons makes a start in April. Secondly, that evergreen trees as a class begin to grow probably a month earlier than the deciduous group. They make substantial progress in May, and some of them perhaps make a start in April. On the other GROWTH OF WOOD IN DECIDUOUS AND EVERGREEN TREES. 55 hand, the measurements indicate that they stop growing somewhat earlier than the deciduous class. Thus Sir Ropert Curistison’s conclusions are substantially confirmed; although the growth of deciduous wood in May is probably of somewhat greater importance than he supposed. It must be remembered, however, that these rules apply only to the neighbourhood of Edinburgh. In the milder climate, aided by a richer soil, of the south-western districts of Britain, where the leaves expand two or three weeks earlier than here, it is to be expected that the growth of wood will also be correspondingly earlier. Other leaf- shedding species besides the Hungary oak may also be found to be exceptional in the early vigour of their growth, as Sir RoBeErt’s observations and my own include but a small proportion of the numerous native and foreign trees which thrive in our islands. A greater irregularity in the distribution of the monthly growth of the evergreens as compared with the deciduous trees occurred in all the three years during which monthly measurements were made. Thus, while the July percentages of growth in deciduous trees as shown in Table III., were 31, 31, and 31 in these three years, in the evergreen group they were 30, 18, and 19. In August the differences were still more striking, the respective figures being 24, 32, 25 for the deciduous group, and 9, 31, 13 for the evergreen. It is remarkable that in 1881 the growth of the six evergreens, which in July amounted to only 18 per cent. of the annual increment, became vigorous again in August, when it reached 31 per cent. The deciduous group seemed to partake in this exceptionally vigorous growth in August 1881, but to a much less degree, the proportions being 31 per cent. for July and 34 per cent. for August. In treating of the influence of weather on the growth of wood I shall endeavour to explain these apparent anomalies. 2, a. The Months in which the Growth of Wood is most active in Deciduous Trees. TABLE VI.—MontTHLY PERCENTAGES OF INCREASE IN GIRTH OF DECIDUOUS TREES. May May. June. and July. | August | Sept. June ; 5 Selected deciduous trees, 1880, . 12 + 30 = 42 31 24. 3 ps = 1881, . nae ane 35 31 32 2 z ie SoZ 21 + 23 = 44 Sill 25 a? 28 Deciduous trees, 1882, ; : 6-226 = 42 35 2a To elucidate this subject I give in Table VI. the percentage of growth due to each month of the years 1880, 1881, and 1882, in the five originally selected 56 SIR ROBERT CHRISTISON AND DR CHRISTISON ON THE deciduous trees, and the corresponding results for the growing months of 1882 in the larger number of trees then under observation. | The Table shows that in 1880 June and July were the best growing months for the five selected trees. The amount in these two months was nearly equal. The united growth of August and September, of which September’s share was very trifling, was not much less than that of June or July, while that of May was only half that of August. The year 1881 is not fully available for this inquiry, no measurements having been taken for May; but as the united growth of May and June but little exceeded that of July or August, it is fair to conclude that the increase in June alone was less than in either of the subsequent months. In 1882 the growth of the five trees in question was apparently distributed over a longer period. May takes a more prominent place with 21 per cent. The growth for June and combined August and September is not much greater, while July takes a decided lead with 31. The preponderance of the early-growing Hungary oak in the small number of selected trees, however, gives a false impression of the increased deciduous growth in May of this year. If we consider the whole number of deciduons trees, twenty-eight in all, under observation in 1882, the percentage for May is reduced to 16, which is still, no doubt, a substantial and probably an unusual amount. 2, b. The Months in which the Growth of Wood is most active in Evergreen Trees, TABLE VII.—MoNTHLY PERCENTAGE OF INCREASE IN GIRTH OF EVERGREEN TREES. May. June et bent July August. 6 Selected evergreen trees, 1880, OF i 24. ee 6) 30 9 . * ? *: ake 51 18 31 : 3 1882, a0 = Sos. =o oo 19 1s 18 Evergreen trees, 1882,. 34 + 29 = 63 ini 16 It is more difficult to determine from the available data the month of greatest growth in evergreen than in deciduous trees. Not only are the varia- tions in this respect in different years greater in the former than the latter, but it is doubtful whether a part of the increment attributed to May ought not to be credited to April in the case of evergreen trees. This doubt arises from Sir Roper having concluded, probably too hastily, that no growth takes place in April. I can find no evidence in his papers of his having ascertained this by measurement, and I do not know how he came to form and act upon that con- clusion. Further observations are evidently necessary to settle this doubt, and GROWTH OF WOOD IN DECIDUOUS AND EVERGREEN TREES. 57 these I hope to undertake in future years.* At present all that we can safely say is that the increase of wood in evergreen trees from the beginning of spring till the end of May probably exceeds on an average that of every subse- quent month. Table VII. shows that it did so in the case of the six selected trees in 1880 and 1882, also in the eighteen trees measured in the latter year. In 1881 the observations are incomplete, as separate measurements were not made for May and June, but August—with 31 per cent.—has a strong claim to the highest place, due I believe to exceptional circumstances. One of the most remarkable conclusions that may be drawn from the three years’ monthly observations on evergreen trees, as a class, is that they appa- rently accomplish the greater part, and sometimes much the greater part, of their growth by the end of June. Thus in 1880, 64 per cent., in 1881, 51 per cent., and in 1882, 68 per cent. of the annual increment of the six selected trees was finished by that date, and the increment of the eighteen trees measured in 1882 was almost identical with that of the six in the same period, amounting to 63 per cent. Apparently then it is not heat alone which regulates the growth of wood in many evergreen trees. By some inherent vital power they complete the greater part of their growth before the commencement of the two warmest months in the four which constitute the growing period, or else their vital power is so exhausted in the early part of the season that growth cannot be carried on with vigour when the real heat of summer comes on. In conclusion, it must be allowed’that further observations, both on deciduous and evergreen trees, are required to determine which is the best growing month in each class. At present the indications are in favour of July for the former and May for the latter, if the whole, or nearly the whole, of the growth hitherto ascribed to that month really belongs to it.* 3. Monthly Increase in certain Species of Trees. There is considerable variety in the vigour of growth in different species both of deciduous and evergreen trees in the different months of the growing season. My observations on this point indeed, on any considerable number of trees, extend only to a single year, but the results are sufficiently striking to deserve attention. In Table VIII. are given the percentages of monthly growth in seven species, which, either from the number of specimens under observation, or from the certainty of their measurement, yield the most reliable results. The Hungary oak begins to grow earlier than any other of the deciduous trees under observation. In the backward spring of 1880 the three specimens marked in the Botanic Garden were well clothed with foliage on the 15th May, * Since this paper was read, the spring measurements for 1883 show a growth in April amounting to two-fifths of that in May in twenty evergreens under observation. It appears probable therefore that June is the month of greatest growth for evergreens. 58 _ $IR ROBERT CHRISTISON AND DR CHRISTISON ON THE and after the wonderfully mild winter of 1882 one of them was beginning to expand its leaves on the 27th of March. Their growth was more evenly dis- tributed over the four growing months than that of any others of the deciduous group, and among the evergreens the yews alone rivalled it in that respect. The Turkish and American oaks seem also to be early growers. The propor- tion of their May growth was not much less than that of the Hungary oaks, still in both the first and last months of the growing season they were less active than the latter. The British oak grows poorly in this district, and besides, from the roughness of its bark, it is not suitable for minute measurements. The only one experimented upon showed no appreciable increment in May. The beeches made only 12 per cent. of their annual increment in May, about half the proportion of the foreign oaks, and as this was in an unusually early season it is probable that in ordinary years their May growth must be very trifling. TABLE VIII. MonTHLY PERCENTAGE OF INCREASE IN GIRTH OF SEVEN SPECIES OF TREES IN 1882. Tier Se June. July. August. 3 Hungary oaks, ; 25 21 31 23 2 Turkish and 1 American oalk, : Die 22 38 18 9 Beeches, . : : s ; 12 26 ot 25 4 Sequoias, : ; 5 ’ 36 39 18 i 3 Araucarias, . : 3 : : ~ 48 22 15 15 2 Deodars, . : : , Z : 6 24. on 33 4 Yews, . : : j ; 5 33 20 25 22 Among other deciduous species, which being less reliable do not find a place in this Table, the ash and the hornbeam alone showed an appreciable growth in May. It is fair to state however, that in the Edinburgh district the horse chestnut leaves were almost universally destroyed in 1882 by early frost and the ravages of insects. It is no wonder therefore that the specimen measured in the Botanic Garden grew only a tenth of an inch in the year. The Sequoias were remarkable, even among evergreens, for the early vigour of their growth. No less than 75 per cent. of their annual growth was finished by the end of June. But they ceased to increase earlier than any of the other species, their growth in August being only 7 per cent. The Araucarias also grew rapidly in the early part of the season, accomplia ing very nearly one half of their annual increment by the end of May, and 70 per cent. by the end of June. With the Deodars it was exactly the reverse, 70 per cent. of their increment taking place after June. If the observations for a single year on two trees may be trusted, the Deodar is an exception to the general rule of early growth in evergreens GROWTH OF WOOD IN DECIDUOUS AND EVERGREEN TREES, 59 The increase of the yews was nearly equally divided between the first and second periods of the season. The former had indeed a slight advantage, but the spring of 1882 was unusually early, and a longer experience may show that yews do not follow the rule of early growth which appears to hold good in most of the Pinaceez. As it may be of some interest to show the comparative rate of growth of wood in certain species of trees under observation, I give the following Table :— TABLE [X.—AVERAGE INCREASE IN GIRTH OF EIGHT SPECIES OF TREES FOR THREE YEARS. 1880. 1881. 1882. Average. Average of— Inch. Inch. Inch. Inch, 3 “Hungary oaks, : 1:20 1°72 1°75 1:55 1 American and 2 Turkish oaks, j 0:45 0°75 0°65 0:62 9 Beeches, . : Z 0°53 0°64 0°79 0°65 4 Sequoias, . : ; . 1:46 sz 1:40 1:01 3 Araucarias, F ; ' ‘ 0°65 0-51 0:66 0-61 2 Deodars, . ‘ : : ; 0:42 0°30 0:82 0:51 4. Yews, 3 : ; : . 0°31 0:37 0°50 0:39 1 African cedar, . : 5 1:75 1°40 1:60 1°58 III. INFLUENCE oF WEATHER ON THE GROWTH OF Woop. This is a complicated inquiry, so many and various are the influences which may come into play. Extreme frost, prolonged frost, the amount of heat and sunshine, drought or excessive rain, strong winds, all no doubt affect the growth of wood, their influence varying with the seasons, and not necessarily showing their effects immediately. Of all these agents cold is probably the most energetic; I have there- fore looked to it mainly for explanation of the differences in annual growth, adopting Mr Sap.ier’s record of temperature in the Botanic Garden as my guide, because the greater number of the measured trees are situated either there or in the adjoining Arboretum. The thermometers used by him are four feet from the ground, and being unprotected the readings are not strictly accurate, but for purposes of comparison with each other the observations are sufficient. Sir Roperr Curistison showed that the remarkable cold and absence of sunshine in the spring and summer of 1879 caused a great deficiency in the growth of wood, both in deciduous and evergreen trees, in that year as com- pared with the previous one ; that the deficiency was greatest in the deciduous class ; and least of all, so far as his observations went, in oaks. In 1880 the spring was favourable to the opening buds, the temperature 60 SIR ROBERT CHRISTISON AND DR CHRISTISON ON THE being considerably above average in February and March, while although April was cool it was free from severe frosts. The summer was also of an average character. The foliage was therefore, in general, rich and abundant. Nevertheless there was again a great falling off in the growth of deciduous wood. This Sir Rosert attributed to the extraordinary low temperatures of the previous December, succeeding an autumn unfavourable to the ripening of wood and formation of buds. He believed that evergreen trees had also suffered, although not to the same extent; but I find that he had been deceived by an error in copying his figures, and that their growth in 1880 was almost identical with that of 1879. It is not easy to explain why both classes should have suffered a diminution in the growth of wood in 1879, and only the deciduous class a further decline in 1880. In the first of these years the cause of deficiency was no doubt, as ‘Sir Rosert believed, the inclement spring and summer, as the cold of the previous winter although prolonged was not remarkably intense; under these circumstances both classes of trees were unfavourably influenced. In 1880 on the other hand the cold of the previous winter was both prolonged and intense, and in all parts of the country its effects were visible in the killing of tender young wood or even of whole trees. It is no wonder then that the deciduous trees showed a marked decline in addition to the serious loss they had suffered in the previous year. But why did the evergreen class escape this further loss? Possibly the explanation of this difference may be found in the earlier activity of growth in evergreens in spring. In their exposure to the intense frost of winter their circumstances must have been much the same as those of the deciduous class, but their compara- tively early buds would probably come under the influence of the genial March and April to a greater degree than the later buds of the leaf-shedding trees, which, on the other hand, would encounter a rather inclement May. Another cause that may be suggested is that the previous autumn, which was highly unfavourable to the ripening of wood, may have in some way prejudiced the evergreens less than the deciduous trees. That the evergreen trees under observation were not really hardier than the deciduous ones was proved by their fate in the following year. The winter of 1880-81 was even more protracted and severe than that of 1879-80. Both the lowness of the average temperature and the number of extremely low readings at the Botanic Garden in January, the coldest month of 1880-81, were more remarkable than in December, the coldest month of the pre- vious winter, Thus the lowest temperatures recorded in the latter month were 1°, 4°, 15°, 17°, 19°, but those of January 1881 were 0°, 4’, 7°, 10°, 11°, 12°, 12°, 12°, 13°, 14°. And this greater cold was prolonged far into the spring. On the last day of February and first few days of March 15°, 15°, 18°, and 19° were recorded, —— GROWTH OF WOOD IN DECIDUOUS AND EVERGREEN TREES. 61 and another wave of cold brought the thermometer below the freezing point on twelve nights in the first fortnight of April, the lowest readings being 21°, 22°, and 23°. On the other hand, the lowest readings in the same months of 1880 were only 23° in February, 22° in March, and 27° in April. Moreover, the total number of nights of frost in these three months in 1880 was only thirty-four, while in the corresponding period of 1881 it was fifty-three. After so severe a winter and spring it might have been expected that even more disastrous effects on the growth of wood would have resulted than after the less extreme cold of the previous year. But, on the contrary, the deciduous trees, at least, made a remarkable rally, the average growth of twenty-seven of them having risen from 0°46 in. in 1880 to 0°69 in. in 1881, an increase of nearly one-third. Very different however was the fate of the evergreen trees. Unlike the deciduous class they had successfully resisted the efforts of the previous hard winter, but now they suffered seriously, thus differing once more from the leaf-shedding trees, but in the opposite way, for their average growth, which in 1880 had been 0°70 in., was now only 0°59 in. The wonderful rally made by the leaf-shedding trees in 1881, notwithstanding the almost unprecedentedly low temperatures of the previous winter, can only be accounted for, I believe, by the favourable character of the preceding autumn, which allowed the growth of wood of 1880 to be perfectly matured, and so enabled it to withstand the rigour of the winter in 1881. But why was a similar effect not produced upon the evergreens? Is it because the maturing of wood is not so effectual with them as it appears to be with the deciduous trees in enabling them to resist a severe winter? Or shall we find the reason in the compara- tively early growth of evergreens which might expose their tender buds to the frequent low temperatures of March and April, a danger from which the buds of the deciduous class, coming out later, would be free, while they would benefit by the geniality of May? The latter seems the most probable cause, but further observations are required to settle the question. The winter of 1881-82 was one of the mildest on record. It was well suited therefore to test Sir Ropert’s suggestion that evergreens might in an unusually mild winter show some trace of growth; but none could be detected in any of the twenty-eight measured trees. Vegetation however was very early. A sycamore and a Hungary oak among the marked trees in the Botanic Garden began to expand their leaves on the 27th of March. The sycamore paid dearly for its temerity. Caught by an early frost and afterwards attacked by insects, its leaves were irretrievably injured, and its increase in girth for the year only amounted to a twentieth of an inch. A similar fate befell nearly all the horse chestnuts near Edinburgh, including a fine specimen, one of my measured trees, which grew only a tenth of an inch in the year. The Hungary oak, on the other hand, did not suffer at all. The deciduous class as a whole. VOL. XXXII PART I. K 62 SIR ROBERT CHRISTISON AND DR CHRISTISON ON THE however, were not injured in this way ; but notwithstanding the mild winter they only maintained their improvement of the previous year, without attaining the standard of growth of 1878. The reason of this failure, no doubt, was the unfavourable nature of the previous autumn for the ripening of wood, combined with the ungenial nature of the growing season, both of which were well-marked evils at the Botanic Garden, as I was informed by the late lamented Mr Sap.er shortly before his death. The evergreens, on the other hand, recovered their loss of the previous year. Apparently the frost of April had not injured them, and they had been stimulated by the mildness of May, as their growth till the end of that month bore a high proportion to the whole annual increase. This attempt to connect the annual variations in the increase of wood with temperature, and to explain the curious contrasts between deciduous and evergreen trees in their annual erowth by the effects of temperature alone, cannot be considered as altogether satisfactory. Neither are the difficulties cleared up by considering other causes which must manifestly affect the growth of wood. Violent winds, for example, must be prejudicial not only by tearing down important branches, but by damaging the leaves. Every one must have observed the injury done to foliage by storms, particularly in spring and the beginning of summer. Multitudes of leaves are blown away, and those which remain hang limp and shrivelled from the branches, their petioles twisted by the wind, and the circulation through them thus hindered by bruis- ing of the vessels. In the records of the Scottish Meteorological Society many gales are reported as having occurred at Edinburgh in the years with which we have to do, but I cannot clearly trace a connection between them and any diminution in the growth of wood. I should have expected the greatest damage to have been done in 1881. In the previous year, indeed, there were three gales in May, but it was a backward spring, and the leaves may thus have escaped. At all events we know that Sir Rosert remarked the richness and abundance of foliage in June, and there were no gales in that or the sub- sequent growing months. In 1881, on the other hand, one gale in May, three in June, two in July, and four in August were recorded ; yet this was the year in which, with all the disadvantage of a previous winter of almost unprece- dented severity, the growth of deciduous wood made a remarkable rally. But the fact is that the effects of each gale must be watched in order to know whether any general damage has been done to the leaves or not, so much depends on the strength of the wind, its direction, and the shelter which may protect the trees concerned. I should expect that differences between the annual increase of deciduous and evergreen trees might sometimes be due to this cause, as the leaves of the latter, from their shape, cannot be exposed to GROWTH OF WOOD IN DECIDUOUS AND EVERGREEN TREES. 63 the same injury as those of the former ; but in the years now under considera- tion I cannot trace any such effect. In a climate such as ours, with frequent variations from the average in the monthly rainfall, considerable effects on the growth of wood may be expected from excess or deficiency of rain at the growing season. To trace these effects may be difficult, from the possible simultaneous action of other causes immediate or remote ; nevertheless I think something may be made of an examination of the principal abnormalities in the rainfall during the three years in which monthly observations of growth were taken. I owe to the kindness of Mr Bucuan the following Table, showing the excess or deficiency of rain during the months of the period in question. The means from which these are calculated are derived from twenty-eight years’ observations at Charlotte Square, whereas the monthly rainfall is taken from observations at Cumin Place, Grange ; but the general results are not likely to be seriously affected by this difference. TABLE X.—MonTHLY Excess oR DEFECT OF RAIN AT EDINBURGH IN 1880, 1881, AND 1882. Jan. Feb. | March. | April. | May. | June. | July. | Aug. | Sept. Oct. Noy. Dec. 1880, . |-1:69} +0°03) —0-09) +0°11) —1:05 — 0-46) +1:91) — 2°46) +0°17) + 1°66) + 1°54) +1:01 1881, . |—0°70) + 2°81) +.0°13) — 0°32) — 0:04) — 0°61) + 0°52) + 3:06) +0-97) — 0°50) +.0°60) - 0°83 1882, . |—0°55| +0°01| + 1:04) + 1-00) + 0°29) +. 0-28) — 0°51) — 0°85 ef oho In comparing the rainfall with the tree-growth, I shall make use of the proportion which the monthly percentage of the latter bears to the whole annual growth. These will be found in Table VI. and VII. 1880.—The rainfall of May was less than half the average, and that of June was deficient by about a third ; but the increase of wood in both classes of trees was quite up to the average of the same period for three years. In July the rainfall was much in excess: the deciduous growth was an average one ; but the evergreen growth was much above the average. In August there was a great deficiency of rain, — 2°46, and an excess of heat, + 3°'3 ; the deciduous growth was about an average, the evergreen greatly below average. 1881.—In April, May, and June there was a deficiency of rain, but it only amounted to an inch in all, and as vegetation was completely checked by severe weather till the middle of April, the small proportionate growth of both classes _ of trees in May and June may fairly be attributed to the latter cause. In July the rainfall was slightly in excess: the deciduous growth was again an average, but the evergreen under average. In August, the memorable month of the Volunteer Review at Holyrood Park, no less than 6 inches of rain, double the 64 SIR ROBERT CHRISTISON AND DR CHRISTISON ON THE average, fell at Edinburgh; then the evergreens made a surprising rush, no less than 31 per cent. of their annual growth taking place, whereas in August 1880 the portion was only 9 per cent., and in 1882, 13 per cent. This result was the more remarkable, as the temperature of the month was 2°'3 below the average. The deciduous trees were also apparently benefited by this excessive rain, although accompanied by deficient temperature, their proportion being 34 per cent. in August and September of 1881, while it was only 27 per cent. in 1880, and 25 per cent. in 1882. 1882.—The rainfall of March, April, May and June was abundant, exceeding the average by an inch in each of the first two months, and being rather above the average in the third and fourth. In the same period the growth of ever- ereen wood was large, but this may easily be accounted for by the mild winter and early spring, without calling in the aid of the rainfall. Taking a general view of this investigation, it appears as if an abundant rainfall were favourable to the growth of wood, but much more favourable to the evergreen than the deciduous class. It must be admitted however that a longer series of observations, taken on a larger scale, are necessary to determine this point. The most striking fact shown is the extraordinary increased growth of the evergreens in August 1882, along with a very heavy rainfall and low temperature, whereas in the previous August, when the conditions were reversed, the rainfall beimg 2°46 inches in default and the temperature 3°:3 in excess, the evergreen growth was very deficient. SUMMARY. To give a better idea of the general scope of this paper, the details of which are necessarily of a somewhat dry and tedious character, I now give a summary of the chief conclusions which are scattered throughout the text. It must be remembered however that these conclusions are strictly applicable only in the Edinburgh district, and that some of them are only indications of the probable truth, and require to be confirmed by a larger series of observations. 1. The effects upon the growth of wood of the severe winters preceding the growing seasons of 1879, 1880, 1881 were not the same in deciduous and ever- green trees. In 1879 both suffered: the former more than the latter. In 1880 a further decline took place im the deciduous class, but not in the other. In 1881 the deciduous class recovered their loss of the previous year, but it was now the evergreen’s turn to fall off. After the unprecedentedly mild winter of 1882 they again differed. For while the deciduous trees made no further recovery, the evergreens regained the loss sustained in 1881; neither class however attaining to the standard of growth in the favourable season of 1878. 2. Evergreen trees probably do not increase their wood at all in winter, GROWTH OF WOOD IN DECIDUOUS AND EVERGREEN TREES. 65 however mild it may be, as not the slightest trace of growth could be detected in the measured trees after the wonderfully mild winter of 1882. 3. The British oak probably suffered a greater decline in its growth of wood from the severe winters than any other tree under observation. The Hungary oak, on the other hand, was less affected than- any other tree; and the Turkish and American oaks less than our native oak. 4. In the wave of increase and decrease in wood growth through these years the yews followed the deciduous class, and not their congeners the ever- green pines. 5. The appreciable growth of wood in deciduous trees is mainly confined to June, July, and August in ordinary seasons ; but a material increase does take place in May, particularly when the spring is unusually mild. 6. The growing season in evergreen trees includes May, and probably an appreciable start is made even in April, when the spring is favourable. 7. The proportionate monthly growth seems to vary more in evergreens than in deciduous trees. 8. The growth of wood is probably greatest in July in deciduous trees, and in June* in evergreens ; but further observations are required to settle these points. 9. On an average of three years the evergreen trees as a class accomplished 60 per cent. of their annual increase of wood before the end of June, the deciduous 60 per cent. of theirs after that date. Deodars appear to be exceptional, as they agreed with the latter instead of the former group. In yews the growth is probably pretty equally divided between the two periods. 10. Of all the species measured, the Hungary oak and African cedar proved much the quickest growers. Then followed the ‘Sequoia gigantea. 11. Thorough ripening of wood in autumn seems to be of immense con- sequence in enabling deciduous trees to stand extremely low temperature in winter. Evergreens however do not seem to be so dependent on it. 12. An excessive rainfall seems to be favourable to the increase of wood, particularly in evergreen trees. A great excess of rain in August 1881 appar- ently stimulated the growth of wood in these to a remarkable degree, although the temperature of the month was decidedly low. In conclusion, I cannot help expressing a wish that others who have better opportunities than I can command would take up a line of inquiry which Sir Rosert CuristTison has made easy by the practical rules he has laid down for its prosecution. ‘The necessary observations are not difficult to make, merely requiring precision ; and they take up little time when the trees experimented upon are near at hand. The work is interesting, and the results may prove to * See foot note, page 57. VOL. XXXII. PART I. L 66 GROWTH OF WOOD IN DECIDUOUS AND EVERGREEN TREES. be of importance in unexpected ways. I must also repeat the surprise which Sir Rosert often expressed, that little or nothing seems to have been done to ascertain the effects of manuring on tree growth. ‘ Mulches” have indeed been applied to favourite trees when in a sickly state, and often with the best results, but the farther step of trying the effect of manures in stimulating the crowth of healthy trees has not, so far as Iam aware, been taken. Perhaps the want of any reliable method of ascertaining the rate of growth of wood has hitherto stood in the way of such experiments ; but surely there is the greatest encouragement to undertake them, now that Sir Roperr has shown the ease and accuracy with which minute measurements of the girth of trees can be made, and their rate of growth thus ascertained in comparatively short periods of time. If such application of manures proved useful, but at the same time too expensive to be employed on the great scale, it should at least be welcomed by the landed proprietor to secure a more rapid growth of young ornamental wood. Note.—In Table III. the average growth of the Evergreen trees for May and June 1881 should be 0°65 instead of 0:48, and the monthly percentages 59, 15, 26, instead of 51, 18, 31. The latter errors occur also in Table VII. The conclusions in the text are not materially affected by these errors, except that the claim of August to the highest average monthly growth in 1881, mentioned on page 57, becomes very doubtful. (ares 3} V.—A Contribution to the Chemistry of Nitroglycerine. By Marruew Hay, M.D., Assistant to the Professor of Materia Medica in the University of Edinburgh. . (Communicated by Professor Crum Brown.) Introductory.—In the course of an inquiry into the physiological and therapeutical action of alkaline nitrites, and allied substances, I was struck with the strong resemblance which the action of nitroglycerine bears to that of the nitrites.* The resemblance is, indeed, so well marked, that the action of the one may be held to be identical with that of the other, unless in respect of intensity. The suggestion, therefore, naturally occurred to me, that nitro- glycerine is not a nitrate of glyceryl, as it is always represented, but a nitrite. For no ordinary nitrate, as an alkaline nitrate or nitrate of ethyl, nor any compound of glyceryl with another acid, as sulphuric acid, produces an action on the body at all resembling that of nitroglycerine. On referring to the various investigations which had been made for the purpose of ascertaining the chemical constitution of nitroglycerine, I found that none of them was sufficiently extended and exact to place beyond doubt its precise nature. The danger in manipulating so explosive a body had evidently prevented the various chemists from making a thorough examination of its composition. I at first thought that nitroglycerine might be a nitrite of glyceryl, having its nitrous acid so ‘intimately combined with the glyceryl, that the acid did not exhibit its reactions when tested for in the usual way ; just as the acids of other ethereal compounds will not yield their usual reactions, unless special means are taken to forcibly dissociate the acid from the base; for example, the acid of acetate of ethyl, or of chloride of ethyl. Certainly nitroglycerine gives no blue colour with a solution of starch and iodide of potassium and sulphuric acid, a.very delicate test for the presence of nitrous acid. In order, however, to apply the test to the separated acid of nitroglycerine, I mixed an alcoholic solution of nitroglycerine with an alcoholic solution of pure caustic potash. The potash was ascertained to be free from nitrite, which I have frequently found present in small quantity in various specimens of ordinary potash. Decomposi- tion of the nitroglycerine quickly occurred, and the fluid, when now tested for nitrous acid, was found to contain the acid in abundance, and so much of it, that for the moment I believed that nitroglycerine was, in reality, a nitrite of * MartnHew Hay, Practitioner, March and June 1883. VOL. XXXII. PART I. M 68 DR MATTHEW HAY ON THE glyceryl ; and hence the nature of its physiological action. Some estimations, however, of the quantity of the nitrous acid proved to me that whilst the larger portion of the nitrogen of the nitroglycerine appeared as nitrous acid in the decomposed products, yet a considerable portion was present in some other form. The production of a large amount of an alkaline nitrite, when nitroglycerine is decomposed by an alkali, is a fact which, very strangely, has hitherto escaped the observation of chemists. MULLER and Dr LA Rue™* have, indeed, remarked the formation of nitrous acid in the spontaneous decomposition of badly-washed nitroglycerine ; and Hess and Scuwast have even stated that nitrite of potassium is formed in addition to nitrate of potassium when potash is allowed to act on nitroglycerine, but they appear to have believed that the nitrite was formed in small quantity, and was quite a subsidiary product of the decomposition. Ever since Rarrron,{ in 1855, published his paper on ‘ Nitro- glycerine and its Products of Decomposition by Caustic Potash,” the decomposition has been invariably represented, and even in the most recent works on chemistry, by the equation :-—C,H, .3(0.NO,)+3HKOH=C,H, .30H+3(KO.NO,) ; that is, caustic potash decomposes nitroglycerine with the formation of glycerine and nitrate of potash ; and it is mainly from the supposed correctness of this equation that the formula for the constitution of nitroglycerine has been derived. Wu.i1Amson,§ in the following year, gives an account of an investigation of nitroglycerine, and with results so exactly similar, even in detail, to those of Rarron, that it is apparent that these chemists had made the investigation conjointly, although they published their results separately. Ratton supplies a more minute account of his method of analysis of the products of decomposition, and it is not difficult to understand, from a careful perusal of it, how he was led to suppose that the nitrate of | potash, which he obtained by crystallisation, was the only salt present. He | applied no tests for nitrous acid, and he made no quantitative estimation either of the nitrate of potash or of the glycerine ; and I may anticipate some of the results of the present investigation, and say that it is highly improbable - that he obtained any glycerine at all, as he probably mistook for glycerine a syrupy residue consisting of other substances. No succeeding investigator of the chemistry of nitroglycerine has examined much more minutely the decom- position products ; and the equation, therefore, remains as yet unaltered. It is evident that the constitution of nitroglycerine and the action of alkalies on nitroglycerine afford room for further investigation. * Muttver und De ta Ror, Liebig’s Annalen. d. Chemie., CIX. 122. } Hess und Scuwas, Berichte d. deutsch. chem. Gesellschft. Bd. XT. (1878), 8. 192. } Ramon, Qu. Journ. of Chem. Soe., vol. vii. p. 222. ~ § Witiiamson, Proc, Roy. Soc. Lond., vol. vii. p. 130. CHEMISTRY OF NITROGLYCERINE. 69 Action of Fixed Alkalies on Nitroglycerine.—The nitroglycerine used was made by myself and not extracted from dynamite, as has been very frequently the case with previous investigators. I shall afterwards describe the mode of preparation employed. It is sufficient in the meantime to state, that whatever was the variation practised in the method of the production of the nitro- glycerine, the products were perfectly uniform in character. The action of the alkali was examined both in aqueous and in alcoholic solutions. Nitro- glycerine is so insoluble in water that it was decidedly preferable to make use of an alcoholic solution of the ether and mix it with an alcoholic solution of pure caustic potash (crystallised from its solution in alcohol). Absolute ethylic alcohol was employed in every instance. When a moderately strong solution of caustic potash (1 in 10) is added to a solution of nitroglycerine of similar strength, the following phenomena are observed. The first few drops of the alkaline solution produce an_ orange- coloured precipitate, which, on the addition of more of the potash, assumes along with the whole fluid a deep reddish-brown colour. A large amount of heat is developed during the mixture, amounting almost to ebullition of the alcohol; a strong aldehyde-like odour is evolved, without any perceptible odour of ammonia or acrolein. The fluid quickly separates into two layers— the lower, and much the smaller, being partly of the nature of a solid precipitate, yet in great part syrupy and of a very deep reddish-brown colour, and containing nearly all the colourmg matter formed by the decomposition of the nitroglycerine. The upper layer constitutes the bulk of the fluid, and is yellowish in colour, and at first muddy, but, after a few minutes, becomes quite transparent. The application of external heat is, as I have ascertained, quite unnecessary to complete the decomposition, although in most of my experiments I have with this object boiled the fluid over the water-bath for several minutes, sometimes to the entire dissipation of the alcohol, water being added as the alcohol is evaporated. When water is so added, the syrupy precipitate, in proportion to the amount of alcohol still present, becomes partially or completely dissolved, yielding a deep reddish-brown solution. If sufficient water is added to the fluid without previous removal of the alcohol, it is still possible to obtain a perfect solution of all the substances present. It was in such diluted solutions, obtained either in the one way or the other, that I estimated the amount of nitrite of potassium formed. This was effected by means of starch, potassium iodide, and dilute sulphuric acid, a thoroughly well-boiled 5 per cent. solution of starch, and containing 2 per cent. of potassium iodide, being employed. The blue colour obtained on the addition of these reagents was compared, as regards its intensity, with the colour produced by a similar amount of the reagents added to standard solutions of nitrite of sodium placed in test-tubes of the same diameter and used in the 70 DR MATTHEW HAY ON THE same quantity as in the case of the nitroglycerine solution. The purity of the nitrite of sodium was previously ascertained by titration. with a standard solution of permanganate of potash; and the strengths employed of the standard solutions of the nitrite were 1 in 500,000, and 1 in 1,000,000. The solution of decomposed nitroglycerine was diluted with distilled water until, on the addition of the starch reagent, a depth of blue was obtained precisely similar to that given by the strongest of the standard solutions of the nitrite. The solution was then diluted with an equal bulk of water, and, for the purpose of control, compared with the weaker standard solution. From the amount of dilution needed it was easy to estimate the quantity of nitrous acid present in the solution of the decomposed nitroglycerine. This method is only approximately correct, but it is the only method available. Any error was as far as possible eliminated by making the dilutions and comparisons with extreme care, and by occasionally repeating the estimation of. the nitrous acid. The following were the results obtained. (The letters following the various specimens of nitroglycerine are for the purpose of identifying each specimen with its mode of preparation, which will be afterwards stated.) I. Nitroglycerine, A.—1:1533 grms. dissolved in about 5 cc. of alcohol, and treated with fully 1:5 grms. of caustic potash dissolved in about 12 c.c. of alcohol. Boiled over water-bath for half an hour, water being added to replace the evaporated alcohol, and heating continued until the whole of the alcohol was driven off. Fluid diluted to 30 ¢c.c. 1c.c. of this was further diluted, and employed for the estimation of the nitrous acid. A dilution corresponding to 1 of the original nitroglycerine in 620,000 of water was found to contain the same proportion of nitrous acid as the 1 in 1,000,000 standard solution of nitrite of sodium. The nitroglycerine had, 7205) corre- therefore, produced a quantity of nitrous anhydride sponding to 62 per cent. of the anhydride in Na.O.NO, or 34°143 per cent. of the weight of the nitroglycerine. A second estimation of the nitrous acid in the same solution of decomposed nitroglycerine gave 35°244 per cent. of N,Os. II. Nitroglycerine, A.—1 c.c. of a 10 per cent. solution heated to the boiling point with a small excess of alcoholic solution of potash ; diluted with two volumes of water and again heated to the boiling point, and the nitrous acid then estimated. The nitroglycerine yielded 35°24 per cent. of ee III. Nitroglycerine, A.—Same in all respects as IT. The yield of nitrous anhydride was 35:24 per cent. LY’. vel. ELT. VIII. XII. CHEMISTRY OF NITROGLYCERINE. r@! Nitroglycerine, A.—Same as II., except that caustic soda was used instead of caustic potash. The decomposition presented the same appearances as when potash was used. The yield of nitrous anhydride was 35:24 per cent. diluted with water two minutes after the addition of the potash. The yield of nitrous anhydride was 33°04 per cent. . Nitroglycerine, A.—Same as II., but no heat applied, and fluid freely Nitroglycerine, B.—1 grm. dissolved in. about 6 c.c. of alcohol, and heated with 12 c.c. of 124 per cent. alcoholic solution of caustic potash. being added to replace the alcohol. The yield of nitrous anhydride was 34°96 per cent. with excess of potash solution. The yield of nitrous anhydride was 34°41 per cent. estimation gave 34°96 per cent, as in VIL. The yield of nitrous anhydride was 34:96 per cent. . Nitroglycerine, G.—Same proportions as VII. The yield of nitrous anhydride was 35:24 per cent. . Nitroglycerine, G.—Same proportions as IX. The yield of nitrous anhydride was 34°96 per cent. . Nitroglycerine, N.—Same proportions as X. The yield of nitrous anhydride was 35:24 per cent. Nitroglycerine (from Noset’s dynamite).—Same proportions as X. The yield of nitrous anhydride was 35:24 per cent. Boiled over water-bath to dissipate the alcohol, water Nitroglycerine, D.—1 grm. dissolved in 15 c.c, of alcohol, and heated Another Nitroglycerine, F.—Same proportions of nitroglycerine and alkali SuMMARY OF ESTIMATIONS OF NiTROvus ACID IN THE ALKALINE DECOMPOSITION- Propucts oF NITROGLYCERINE. No. of Analysis. Specimen of Nitroglycerine. | Percentage of Nitrous Anhydride. L A A 341°43) 35°24 IDEM. 35°24 IV. 35°24 33:04 AVI iyi): ViLLT. s}) - TEX 34°96 | 34°41 | 34:96 | 35:24 xX. XI. G N 34°96 | 35-24 xa: Dyna- mite. 35°24 72 DR MATTHEW HAY ON THE These analyses are amply sufficient to show that the amount of nitrous acid formed during the alkaline decomposition of nitroglycerine is neither small nor variable ; and, assuming that nitroglycerine is a trinitrate of glyceryl, it corresponds remarkably with the supposition that two out of tLe three parts of nitric anhydride, which nitroglycerine contains, are reduced to nitrous anhydride; for the trinitrate of glyceryl ought theoretically to yield, if so reduced, 33°48 per cent., an amount which agrees very closely with that actually obtained, if due allowance be made for experimental error in a method © which, although the best available, cannot claim to be exact. _ It is open to suggestion, reasoning alone from these estimations of nitrous acid, that nitroglycerine is perhaps a di-nitrite of glyceryl, or a mono-nitrate di-nitrite of glyceryl. As opposed to its being one or other of those bodies, the fact that specimens of nitroglycerine, as B and D, prepared in presence of urea, were found to yield the same proportion of nitrous acid as the others, is of importance. Another weighty objection to its being a nitrite is that on passing nitrous anhydride.gas into glycerine no substance at all resembling nitroglycerine was obtainable ; although there was formed an oily liquid containing nitrous acid in combination, which, however, quickly decomposed in contact with water. This body has recently been investigated by Mr Masson,* and he- believes it to be the tri-nitrite of glyceryl. It is not probable that the di-nitrite will possess greatly different properties. Were nitroglycerine the di-nitrite, it ought to yield a much higher proportion of nitrous acid than was actually obtained. For these and various other reasons, it is not the di-nitrite, and much less the tri-nitrite. As to the possibility of its being a mono-nitrate di-nitrite, the objection as to the yield of nitrous acid is not by any means strong. For such a body ought theoretically to yield 30:89 per cent. of a 3 (nitrous anhydride), an amount tolerably close to what was actually obtained. And amongst the alkaline decomposition products of nitroglycerine, it is not difficult to separate nitrate of potassium by crystallisation. But, on the other hand, the mono-nitrate di-nitrite ought to yield 21:5 per cent. of nitrogen, whereas, — by actual experiment, Mr Masson and myself have found that nitroglycerine contains a inuch lower percentage of nitrogen. From these and other considerations, which will be referred to later on, it is impossible to avoid concluding that nitroglycerine is a tri-nitrate of glyceryl, and that two-thirds of its nitric acid is reduced to nitrous acid during the decomposition of the ether.t I shall now give a brief account of the other substances, besides nitrite of potassium, which are formed when an alcoholic solution of potash acts on an alcoholic solution of nitroglycerine. * Masson, Journ. Chem. Soc., August 1883. + Vide accompanying communication on “'The-Elementary Composition of Nitroglycerine,” CHEMISTRY OF NITROGLYCERINE. 13 Nitrate of potassium is, as I have mentioned, present in considerable quantity, and with the nitrite constitutes the larger portion of the reddish-brown, partly viscid, partly crystalline precipitate, which is formed in the decomposing fluid. I have not estimated the nitrate quantitatively; but there is every reason to believe, from the estimation of the total nitrogen by SCHLOESING’s method and from other circumstances, that the amount of the nitric acid cor- responds very closely to one-third of the nitrogen present in nitroglycerine. But nitrite and nitrate of potassium are not the only substances formed. I have also proved the presence of acetate of potassium, oxalate of potassium, and, doubtfully, of formate of potassium, neither of the two latter appearing to be present in large quantity. There is alsoa small amount of ammonia, and ofa reddish-brown, resinous body, which imparts the dark colour to the decomposing fluid. There is likewise present a very curious and very interesting substance, which possesses the unusual power of forming a firm jelly with a very large proportion of absolute alcohol. In contradiction to Ratton and WILLIAMSON, and previous investigators, I have found no glycerine, or only the merest trace of it. This is a new and most important fact. In order to ascertain the presence and nature of these various decomposition- products, 6°67 grammes of pure nitroglycerine were decomposed with excess of potash in the usual manner, the mixture being allowed to boil for five minutes, and afterwards set aside for one day, to permit of the deposition of certain of the substances dissolved in the hot absolute alcohol. The supernatant fluid, which was transparent and of an orange colour, was then decanted, and the residue was again boiled with a fresh quantity of absolute alcohol, and again set aside for a day, when the alcohol was decanted and added to the previously decanted alcohol. This process was repeated a third time. The mixed alcoholic fluids ought to have contained the excess of caustic potash and the whole of the glycerine, were any present; and in the deep reddish-brown residue I expected to find nearly all the colouring matter, and.all the salts‘insoluble in absolute alcohol, as the nitrite and nitrate of potassium. The mixed alcoholic fluids were neutralised with.alcoholic sulphuric acid in order to precipitate the potash as sulphate of potash. A voluminous white precipitate formed, which, after standing for some hours, was separated by filtration. The filtrate, although faintly acid, yielded another tolerably copious precipitate of sulphate of potash on the further addition of sulphuric acid, which was now added in distinct excess. Salts of potash were evidently present, dis- solved in the alcohol; certainly, amongst others, the nitrite and acetate, as proved by testing. The precipitate was again removed by filtration, and the alco- holic fluid was now distilled fractionally in order to remove the more volatile substances, as the alcohol and acetic, formic and nitrous acids, the less volatile glycerine, if present, remaining in the retort. Distillation was continued until 74 DR MATTHEW HAY ON THE four-fifths of the fluid had been evaporated. An equal bulk of water was now added to the residue, and distillation was continued until the alcohol was almost completely expelled. The residue was now saturated with pure barium hydrate, in order to remove the sulphuric acid, and then filtered; and the excess of barium -was precipitated by a stream of carbonic acid gas, and the fluid was again filtered. The filtrate was now evaporated over the water-bath, and was quickly reduced to five or six drops of a golden yellow viscid residue. Treated with absolute alcohol, in which glycerine is freely soluble, it at once hardened, and was almost entirely insoluble in alcohol. It evidently consisted in part of a barium salt, as ascertained by testing. The alcoholic solution or extract was filtered, and, on evaporation, yielded about one drop of a yellowish syrup, much more viscid than glycerine, and pungent rather than sweet to the taste. A few minutes’ further drying dessicated it to a hard scale. The syrup gave merely the faintest odour of acrolein when heated with acid sulphate of potash. J therefore concluded that this residue, which ought to have contained the greater part of the glycerine, were any present, contained practically none of that sub- stance. The absence of glycerine from the alkaline decomposition products of | nitroglycerine was confirmed by a second experiment, made with a still larger quantity of nitroglycerine, and in which no distillation was practised, and less opportunity therefore afforded for the decomposition or evaporation of the glycerine. The deep reddish-brown residue, laid aside at the commencement, after being well washed and extracted with boiling absolute alcohol, was next examined. Dried at 100° C. for 24 hours, it weighed 14°65 grms., and was probably not even then absolutely dry, although very nearly so. The large amount of the residue is remarkable, as it weighs considerably more than the sum of the weights of the nitroglycerine decomposed, and of the potash neces- sary, according to Rariron’s equation, for the decomposition of the nitro- glycerine. This point will shortly receive an explanation. The dried residue was perfectly soluble in water, forming even with a large volume of water a deep reddish-brown solution. A portion of the residue was dissolved in boiling water, and, after standing for some hours, large needle- shaped crystals of nitrate of potassium separated, which by re-solution and re-crystallisation were obtained in a perfectly pure form, and distinctly recognised to be nitrate of potassium. From another measured portion of the residue it was attempted to remove the nitrite of potassium and formate of potassium (if present), by treatment with strong acetic acid, and extraction with boiling absolute alcohol, in order to remove the acetate of potash and free acids thus formed, and to obtain in a tolerably pure state the nitrate of potassium for the purpose of a quantitative determination ; but the method did not succeed. One-half of the original dried residue was next dissolved in water, and CHEMISTRY OF NITROGLYCERINE. 15 treated with moderate excess of dilute sulphuric acid, and heated for a few minutes. Red fumes were evolved with brisk effervescence; and a dark _ reddish-brown precipitate was formed, which evidently constituted the colouring matter of the decomposition products of nitroglycerine, although the colour was not wholly removed by the addition of the acid. The precipitate was collected on a filter, and washed with dilute acid and dried ; it weighed 0°040 eram. It was insoluble in acid solutions, but freely soluble in dilute solu- tions of allxalies or alkaline carbonates, and was of a resinoid character, and is probably similar in nature to aldehyde-resin, or even to caramel. As regards the peculiar alcohol-gelatinising body which I have mentioned as existing amongst the products of the alkaline decomposition of nitro- glycerine, it was met with in the course of an examination of the decomposed products of 15 grms. of nitroglycerine, obtained in the usual way. The supernatant alcoholic fluid was treated with excess of dilute alcoholic sulphuric acid, in order to precipitate all the potash, both free and combined. The filtrate was afterwards neutralised, and the sulphuric acid precipitated by means of pure carbonate of barium. The evaporated filtrate yielded a residue which crystallised on cooling, and contained no glycerine, and which was very freely soluble in water without gelatinisation. It was also freely soluble in hot absolute alcohol ; but on allowing the solution to cool, even if the proportion of the residue to the alcohol was 1 to 20 or 30, the solution became a firm, partly erystalline-looking jelly, which could not be poured out of the test-tube in which it formed. This body, whatever be its exact constitution, is certainly a very exceptional organic substance, and deserves further examination. No gases are generated when potash acts on nitroglycerine in alcoholic solution. This was ascertained by placing the solution of nitroglycerine in a retort connected with a tube inverted over mercury, and boiling to drive out all the air. Alcoholic potash was then added, precautions being taken to prevent the simultaneous admission of air, and the boiling was continued for some time without any gas being formed. - These are the products formed when alcohol is the medium through which the potash attacks the nitroglycerine. Similar products are obtained when water is employed, and the only apparent difference is that, on account of the very sparing solubility of nitroglycerine in water, the decomposition proceeds with great slowness, fully two hours’ boiling over the water-bath being required to effect the decomposition of one gram. of nitroglycerine in a strong solu- tion of pure potash. Less red colouring matter is formed than when alcohol is employed, and much more oxalic acid seems to be produced ; but the amount of nitrous acid is the same. From this detailed account of the decomposition of nitroglycerine by caustic potash, it will be seen that the usual equation is very. far from representing VOL. XXXII. PART ‘I. , N 76 DR MATTHEW HAY ON THE what actually occurs. It is almost regarded as a fixed law in the chemical decomposition of compound ethers by alkalies, that the alkali unites with the acid of the ether and liberates the alcohol. This does not appear to be the — case with nitroglycerine. For no glycerine is formed, and the acid is in great part reduced. But there is no doubt that the reduction of the greater portion of the acid is to be associated with the disappearance of the glycerine, which is evidently oxidised by the oxygen lost by the acid. Therefore, instead of glycerine, we have oxidation products of it, as acetic acid, oxalic acid, formic acid, &e. When nitroglycerine is being decomposed by potash, nitric acid and — elycerine or glyceryl occur in a nascent and very active condition, the one as a powerful oxidising substance, the other as a readily oxidisable substance. As a consequence they act on each other, and two out of the three molecules of the nitric acid part each with an atom of oxygen to the glycerine or glyceryl, and this amount of oxygen is sufficient to completely oxidise and break up the glycerine, mostly, if not entirely, into certain organic acids, which, of course, will combine with a portion of the excess of. the alkali used for the decomposi- tion. That is one view; but there is another view, according to which the caustic potash may be regarded as taking an active part in the decomposition of the nascent glyceryl. When pure glycerine is melted with potash, it is well- known that acetate and formate of potash are produced along with _ hydrogen.* The action is represented by the equation,— C,H, (OH), +2KOH = KO. CHO + KO.C,H,0 + OH, +2H,. The decomposition effected by potash under these conditions may occur even in dilute solution if the glycerine be in a nascent state, more particularly if there be present at the same instant a highly oxidising body like nascent nitric acid, which is promoting the same form of decomposition, and is ready to grasp the nascent hydrogen. The amount of hydrogen set free is precisely the quantity needed to reduce two-thirds of the nitric acid of the nitroglycerine, and the other decomposition products of the equation given correspond toler- ably closely with those ‘actually ascertained to be formed. But if such a decomposition occurs, it implies that five, not three, molecules of hydrate of potash are required to decompose one molecule of nitroglycerine. In accord- ance with these views the action of caustic potash on Saiki may be represented thus :— (1) C,H,:3(0-NO,) + 3KOH=C,H, (OH), +3(K:O-NO,). Nitroglycerine. Potash. Glycerine. Potassium and Nitrate. (2) C,H, (OH), + 2KOH=KO-CHO+KO-C,H,0 + 0H, +2H,. Glycerine. Potash. Potassium Potassium Water. Hydrogen, Formate. Acetate. : * Dumas et Stas, Ann. Chim. Phys., 1xxiii., 148, CHEMISTRY OF NITROGLYCERINE. 4 (3). 3(KO.NO,)+2H,=KO.NO, + (2KO.NO)+20H,. Potassium Hydro- Potassium Potassium Water. | Nitrate. gen, Nitrate. Nitrite. or, combining these stages of the supposed reaction into one equation :— (4) ,H,.3(0.NO,)+5KOH=KO.NO,+2(KO.NO) +KO.CHO+KO.0C,H,0+30H,, Nitroglycerine, Potash. Potassium Potassium Potassium Potassium Water. Nitrate. Nitrite. Formate. Acetate. In equation (1) it might have been more in harmony with the view ad- vanced that the glycerine should have been represented as glyceryl and water, to indicate more completely its nascent state. There is every reason to believe that equation (4) is substantially and approximately correct, although in respect of the oxidation products of glycerine these may vary in their nature and proportions. Besides being in accordance with the results of the examination of the products of decomposi- tion, it is supported, as regards the amount of potash required, by the following experiments :— According to RariLTon’s equation, one part of nitroglycerine requires for its complete decomposition 0°741 parts of potassium hydrate; according to the equation just given the proportion isas1:1:235. If less of potash is used than in the latter proportion, then, if the latter equation be correct, complete decom- position will not occur, and a quantity of nitrous acid will be produced corre- sponding to the amount of potash employed ; and the solution of the products of decomposition will remain neutral until more than the requisite proportion _ of potash (1°235 to 1) has been added. In the following four experiments nitroglycerine, F’., was employed in every instance, and a certain quantity of it was dissolved in alcohol and decomposed by an alcoholic solution of a given weight of pure potash, freshly crystallised from alcohol, and as free as possible from carbonate ; the mixture being boiled for ten minutes, diluted with water, and again boiled for ten minutes. : Weight of Yield of Nitrous Anhydride : No. of Weight of De, J = Reaction of Decom- ; : 5 Potassium ressed ¢ rcentage of F Experiment. Nitroglycerine. i carat 7 SS Niomlncenine need: y posed Fluid. Calculated accord- Grms. Grms. ing to Author’s Found; equation. i al 0:80 21:68 23:23 Neutral. 1p 1 1:00 27AL 28°68. Neutral. IIL. 1 1-24 33-48 34-69 VO a, : alkaline, I. li 1:50 33°48 34:69 Alkaline, 78 DR MATTHEW HAY ON THE The degree of alkalinity of (IV.) was ascertained by titration with a stand- ard solution of sulphuric acid (30 in 1000). 6-2 cc. of standard acid were required for complete neutralisation, which is equivalent to 0-203 grms. of potassium hydrate, which, subtracted from 1°50 erms., the quantity of potash originally added, gives 1:297 grms. as the amount of potash actually used up, or a little more than the theoretical quantity. It is noteworthy in these experiments that where less than five molecules of potash, although more than three, were added to one of nitroglycerine, a quantity of nitroglycerine could be observed to remain undecomposed, as it was precipitated on the addition of water to the alcoholic mixture, proving that when potash acts on nitroglycerine in presence of excess of the latter, according to the equation I have adopted, the potash is used up in thoroughly decomposing each molecule of the nitro- glycerine, and does not partially decompose a greater number of molecules. The respective yields of nitrous acid are alone sufficient to prove this. The amount of potash required for the decomposition ‘of nitroglycerine is ‘interesting in connection with a method described by BeckERHINN * a few years ago for the estimation of the degree of acidification of the ether, whether tri-,. di-, or mono-nitrate, in which, after adding what he considered to be excess of caustic potash, he titrated the excess with normal oxalic acid. But his calcula- tions were based on the accuracy of Ramron’s equation. It is very difficult, therefore, to understand how he could possibly have obtained satisfactory results, although he claimed to have done so, and quoted two analyses. In the follow- ing year Hess and Scuwast denied the correctness of his method, and made analyses according to it, but obtained widely different results, yet still acknow- ledging Rartton’s formula, .and ascribing the faultiness of me method to various minor circumstances. Action of Ammonia—The volatile alkali seems to act on nitroglycerine in the same manner as the fixed alkalies, but not so ener getically. When excess of strong ammonia was added to an alcoholic solution of nitroglycerine, there was no immediate decomposition of the nitroglycerine; as is the case when potash or soda is added. The resultant mixture-remained colourless and showed no precipitate. It was then placed over the water-bath and heated all but to ebullition for one hour ; and in order to preserve excess of ammonia, more of the reagent was added from time to time. It now gradually assumed a deep reddish-brown colour, almost deeper than that observed in decomposition with — potash. The maximum intensity of colour was reached after half an hour’s heating, so that ammonia acts much more slowly than potash. The amount of nitrous anhydride obtained was equivalent to 345 per cent. of the nitroglycerine * Beckeruinn, Sitzwngsb. d. Wien. Akad., Bd. 1xxiii. (1876), Abth. 2, S. 235. + Hess u. Scuwas, bid., Bd. lxxv. (1877), Abth. 1, S. 702. CHEMISTRY OF NITROGLYCERINE. 79 used, or a proportion exactly similar to that produced by the action of a fixea alkali.® Action of Alkaline Carbonates.—Nitroglycerine was dissolved in slightly diluted alcohol in order to permit the solution in it of carbonate of potash, which was afterwards added in the form of a concentrated aqueous solution. The mixture slowly assumed a reddish colour even in the cold. Heated over the water-bath, the nitroglycerime tolerably rapidly underwent decomposition, and the fiuid became of a fairly deep reddish-brown colour. The, fluid was heated for one hour, and water was added as the alcohol became evaporated. The yield of nitrous anhydride was 35:24 per cent., or the same as when caustic potash is used. In a second experiment the yield was exactly the same. Using a five per cent. alcoholic solution of nitroglycerine, and boiling it with excess of carbonate of potash, it was ascertained that complete decomposition occurs in about ten minutes. Action of Phosphate of Soda (Na,HPO,).—This salt is acid in constitution, but alkaline in reaction. Added in concentrated aqueous solution to a one per cent. alcoholic solution of nitroglycerine, and heated over the water-bath, the phosphate commenced to decompose the nitroglycerine three to four minutes after the mixture was fully heated, as was evidenced by the appearance of a yellowish tint gradually deepening to an orange-red. After heating for an hour and a half, slightly diluted alcohol being added occasionally, a yield of 13:76 per cent. of nitrous anhydride was-obtained. In another experiment, after heating a similar mixture for forty minutes, 13-21 per cent. of nitrous anhydride was obtained. On both occasions the nitrous acid was estimated in one half of the fluid, and it was observed, in diluting the fluid with water, that a considerable amount of nitroglycerine was precipitated. In the second experiment, by adding potash to the remaining half of the fluid, and heating for a few minutes, and then estimating the nitrous acid, 34°41 per cent. of nitrous anhydride was obtamed, proving that no nitrous acid had been set free by the phosphate of soda, which, in the absence of sufficient alkali, * Tt is somewhat remarkable that the yield of nitrous acid was as great as when a fixed alkali _ was used; since it is well known that a solution of nitrite of ammonia readily undergoes decom- * position when heated ; and it was to be expected that the estimated yield of nitrous acid would have been diminished by the occurrence of such a decomposition in the heated fluid. In order to make certain that the result obtained was correct, and that under the conditions of the experiment such a decomposition did not occur, or occurred only to a limited extent, I have, since the paper was read, repeated the experiment. This I have done on two occasions, and with separate quantities of pure nitroglycerine. On the first occasion only 29°6 per cent. of nitrous anhydride was obtained, but, on the second, 34.1 per cent., or very nearly what was obtained in-the experiment recorded in the text. The nitrite of ammonia formed by the splitting up of the nitroglycerine would appear, therefore, to undergo very little decomposition under the conditions in which it is placed. This may be due to the excess of free ammonia always maintained in the decomposing mixture, or to the low degree of heat applied, as, in order to prevent the rapid escape of gaseous ammonia, heat was applied short of ebullition of the fluid, or, more properly, of the escape of ammonia in the form of bubbles of gas ; or it may be that the highly concentrated alcohol in which the nitroglycerine was dissolved hindered the decomposition of the nitrite. 80 DR MATTHEW HAY ON THE might have been decomposed into nitric acid and nitric oxide, or evaporated off. This form of control-analysis is the more necessary when the salt or substance employed to act on the nitroglycerine is neutral; and in such circumstances I have always made use of it. | Phosphate of soda appears, therefore, to act on nitroglycerinein much thesame manner as alkalies and alkaline carbonates, only very much less powerfully. Action of Chloride of Sodium.— Excess of a concentrated solution of the pure salt was mixed with a one per cent. alcoholic solution of nitroglycerine. The salt was not precipitated, as the alcohol contained a little water. The mixture was heated for thirty-five minutes. There was no perceptible change of colour, and the quantity of nitrous acid did not amount to more than a fraction of a_ per cent. of the nitroglycerine used. The starch reagent yielded no blue colour with the fluid until sulphurie acid was added. The trace of nitrous acid was therefore present as a nitrite. One half of the fluid was treated with potash, and from it was procured an amount of nitrous anhydride correspond- ing to 35°25 per cent. of the nitroglycerine. The chloride of sodium had not, therefore, decomposed the nitroglycerine and lost the nitrous acid by decomposition or evaporation. Chloride of sodium possesses, therefore, extremely little action on nitro- glycerine. Action of Hydrochloric Acid.—1'6 c.c. of the strong acid were diluted with 2 c.c. of water and added to 10 cc. of a one per cent. alcoholic solution of nitroglycerine ; and the mixture was heated over the water-bath for half an hour. It was then found to contain a trace of nitrous acid, not exceeding a small fraction of a per cent. of the nitroglycerine. One half of the fluid, heated with excess of caustic potash, and thus completely decomposed, yielded nitrous anhydride corresponding to 13°5 per cent. of the nitroglycerine. This showed that the hydrochloric acid had decomposed about 39 per cent. of the nitroglycerine, but whether with the formation of nitrous acid, it is quite impossible to say. For even had nitrous acid been formed, it would have been driven off by the boiling, or decomposed in contact with the water of the fluid. { Hydrochloric acid, therefore, in large excess, decomposes nitroglycerine much more slowly than a caustic alkali or even an alkaline carbonate, and not much more quickly than phosphate of soda. Action of Sulphuric Acid.—0°5 c.c. of strong sulphuric acid was diluted with 1 c.c. of water, and mixed with 10 c.c. of a one per cent. solution of nitroglycerine, and heated for half an hour. At the end of this period the fluid did not contain more than the merest trace of nitrous acid. One half of the fluid, boiled with potash, yielded nitrous anhydride corresponding to 29°'7 per cent. of the nitroglycerine. The sulphuric acid had, accondiaaa decomposed 11°3 per cent. of the nitroglycerine employed. CHEMISTRY OF NITROGLYCERINE. 81 Sulphuric acid, in the proportion used, would appear, therefore, to act less energetically than hydrochloric acid on nitroglycerine. Concentrated sulphuric acid in the cold seems to have almost no action, as is proved by the method of the preparation of nitroglycerine. Action of Sulphuretted Hydrogen—According to De Vris,* an ethereal solution of nitroglycerine is readily decomposed by sulphuretted hydrogen with a copious precipitation of sulphur. In order to test the truth of this observation, I submitted two ten per cent. solutions of nitroglycerine—the one in absolute alcohol, the other in ether—to the action of a stream of sulphuretted hydrogen gas. But although the gas was allowed to pass in a rapid stream through each solution for fifteen minutes, yet not the slightest trace of decomposition occurred, as was evidenced by no change of colour, and the absence of nitrous acid and precipitated sulphur and other decomposition products ; even although, in the case of the alcoholic solution, its temperature was raised to near the boiling point and the gas passed for fifteen minutes longer. Nitroglycerine was precipitated abundantly from both solutions on thé addition of water. These experiments were more than ' once made, and aiways with the same result. It must, therefore, be concluded that sulphuretted hydrogen has no action, or at most a very slow action, on pure nitroglycerine. The opposite experience of De Vris was probably due to his having used an impure nitroglycerine. Action of Alkaline Sulphides.—Vhese act very energetically on nitro- glycerine, and decompose it, if in alcoholic solution, as rapidly as alkalies alone do. On adding a solution of ordinary sulphide of potassium, or sulphide of ammonium, to an alcoholic solution of nitroglycerine, the mixture quickly assumes a deep reddish-brown colour, and its temperature rises; and the action of the sulphide is conipleted with a sudden and most abundant precipitation of sulphur in every part of the mixture simultaneously. No gas is given off; and, contrary to expectation, after being boiled with excess of the sulphide for half an hour, filtered to remove the sulphur, and treated: with acetate of lead and again filtered to remove the sulphuretted hydrogen of the sulphide, it yielded evidence of the presence of nitrous acid to the extent of a. little less than half the proportion yielded by a purely alkaline decomposition. It would appear, therefore, that the whole of the nitrous acid set free in the decomposition of the nitroglycerine by the alkali of the sulphide is not acted on by the sulphuretted hydrogen of the sulphide. For we may assume, since sulphuretted hydrogen does not of itself attack nitroglycerine, that it is the alkali of the sulphide which takes the initial step in the decomposition of the nitroglycerine ; the sulphuretted hydrogen playing a subsidiary part, and merely acting on the nascent products of the decomposition effected by the alkali, * De Vai, Journ. Pharm. [3], xxviii, 3; and Gmutin’s Handbook of Chemistry, x. p. 562. 82 DR MATTHEW HAY ON THE But why the whole of the nascent nitrous acid should not thus be decomposed by the sulphuretted hydrogen I do not, in the meantime, attempt to explain, beyond suggesting that the nascent nitrous acid may in part combine with the alkali; and, once so united, it is incapable of being acted on by the sulphuretted hydrogen. | But the sulphuretted hydrogen does not play an aiaeeihen passive part in the actual decomposition of the nitroglycerine itself, for when an aqueous solution of an alkaline sulphide, such as potassium sulpbide or ammonium sulphide, is poured over pure undissolved nitroglycerine, and the mixture vigorously shaken, the solution gradually becomes reddish, and the tempera- ture rises, and apparently, when the temperature has risen sufficiently, the whole or nearly the whole of the nitroglycerine suddenly decomposes with a copious formation of sulphur. In fact, the nitroglycerine seems to become suddenly converted into a mass of sulphur. It will be remembered that when potash alone is allowed to act on nitroglycerine under. similar circumstances, the decomposition proceeds very slowly. The presence, therefore, of sulphuretted hydrogen very greatly promotes the decomposition of nitro- glycerine ; but in what particular manner I have not endeavoured to ascertain. ~ Action of Water.—In order to ascertain to what extent water when boiled with nitroglycerine is capable of decomposing it, a given quantity of a saturated aqueous, and, owing to the insolubility of nitroglycerine in water, a necessarily weak, solution of nitroglycerine was heated over the water-bath. After ten minutes’ active heating, the fluid exhibited no signs of decomposition, and con- — tained no trace of nitrous acid. It was then continuously heated for three hours. It still remained colourless, and-on the addition of starch and -iodide of potassium gave no blue; but when these reagents were added along with dilute sulphuric acid, a distinct blue was obtained. The nitrous acid present was. evidently combined with some other decomposition product of the nitro- glycerine ; it was estimated and found to amount to 1°7 per cent. of the whole nitroglycerine employed. A given portion of the fluid was heated with potash, in order to learn how much of the nitroglycerine remained undecomposed, and a quantity of nitrous acid (nitrous anhydride) was obtained, equivalent to 8°88 per cent. of the whole nitroglycerine ; from which it is to be concluded that 73°48 per cent. of the nitroglycerine had been decomposed by heating with water for three hours. It is to be considered that a portion of this may have been lost by simple evaporation, although this was to a certain extent avoided by heating in a long-necked Florence flask. Action of Alcohol.—A one per cent. solution of nitroglycerine in absolute alcohol was heated over the water-bath for one hour, the alcohol being renewed’ from time to time. There was no change in colour, and nitrous acid could not be detected, even when sulphuric acid was added along with the usual reagents. A portion of the fluid was decomposed with potash, and the nitrous anhydride CHEMISTRY OF NITROGLYCERINE. 83 obtained was found to be equivalent to 33°45 per cent. of the whole nitro- glycerine, proving that the nitroglycerine had not been apparently decomposed by heating with alcohol. From this it is evident that the alcohol used as a menstruum in ascertaining the action of other substances on nitroglycerine did not of itself aid in the decomposition of the nitroglycerine. Preparation of Nitroglycerine.—After I had observed that nitroglycerine yielded, when decomposed with an alkali, a large amount of nitrous acid, and being fully sensible of the insufficiency of existing analyses to determine the elementary composition of nitroglycerine, doubts arose in my mind, as I have already stated, as to whether nitroglycerine was actually a tri-nitrate of glyceryl. I have already given some important reasons in connection with its alkaline decomposition products for regarding it as the tri-nitrate, and not as any form of a nitrite. But I have thought it advisable to supply what additional proof could be obtained of its composition from a consideration of the yield of nitro- glycerine from a given weight of glycerine. For this purpose I prepared nitro- glycerine with various proportions of glycerine and acids, in order to ascertain the highest possible yield of nitroglycerine. Another important object which I had at the same time in view was to learn how far such variations in the method of the preparation of nitroglycerine might affect its composition. The latter object was very desirable, owing to the very discrepant statements which have been made by previous investigators as to nitroglycerine consisting entirely of tri-nitrate of glyceryl, or of a mixture of the tri-nitrate with the di-nitrate and mono-nitrate. | In the preparation of the nitroglycerine, Pricr’s pure glycerine, dried for six hours in the air-bath at a temperature of 120°C, was always employed ; the specific gravity, after drying, was 1:260 at 14°C. The acids were each of two strengths—nitric acid, of a specific gravity of 1:422 (referred to as strong nitric in what follows), and 1:494 (referred to as fuming nitric acid) ; sulphuric acid, of a specific gravity of 1844 (referred to as strong sulphuric acid), and 1:984 (referred to as fuming sulphuric acid) ; all at 15:5°C. In every instance the nitric and sulphuric acids were first mixed and placed in a vessel containing salt and ice, and cooled to below 0°C. In certain cases where urea was also used, it was added to the nitric acid previous to mixture with the sulphuric acid. Into the cooled mixture of the acids the glycerine was slowly dropped and well mixed by constant stirring, the temperature, as ascertained by a ther- mometer, never being permitted to rise above 10°C. After standing for a variable time, the mixture was poured into a large and measured quantity of cold water, when the nitroglycerine was precipitated. It was now very care- fully collected, after thorough stirring with the water, and was in this slightly impure state dried in the air-bath at 70°C. It dried quickly, but assumed a yellowish tint, and had a pungent acid odour. The weight of the dried nitro-_ VOL, XXXII. PART I. 0 84 DR MATTHEW HAY ON THE glycerine, increased by the weight of the nitroglycerine known to be lost by solution in the water into which it had been thrown, and which was calculated from a solubility of 1 in 800, gave the total yield of nitroglycerine. The nitro- glycerine before being used for any other purpose, as for analysis, was thor- oughly shaken with successive quantities of distilled water until it was perfectly pure. The first precipitation and washing was, I am satisfied, quite sufficient to remove by far the largest part of the impurities, and the trace of these left did not interfere to any noteworthy extent with the actual weight of the nitro- glycerine. In certain cases I checked the weight of the raw nitroglycerine by weighing the product after it had been thoroughly purified, and, again allowing for loss by washing, according to the quantity of water used, I obtained almost the same weights. A note of the time for which the mixture of the acids and glycerine was allowed to stand before being thrown into water was always kept. Figure . Weight of Nitric Weight of Time ; Yield of Of Weight Acid. Sulphurie Acid. of Nitroglycerine, Reference oe Standing fa the par ceame. Strong. Fuming. Strong. Fuming. after Absolute. | Various Grms. Si: = — = complete x Percentage. Products. Grms. Grms. Grms. Gims. Mixture. Grms. A. 12°4 mas 30 75 nes 10 mins. B. 6:1 jurea,2 grms. 15 30 ae Stitt; an “ot C. 10-4 30 urea, 1 grm. 30 a A» 1m, 16°3 D. 8:8 25 = furea,lSgrm-| 50) ba Spopes 9-486 | 107°8 E. 10°2 30 ee 60 3 Bee 16°71 163°8 EF, 10°8 30 oe 90 ee se 18°79 1756 G. 10°6 30 sn 90 eis OOo; 19°11 180-2 Hy: 9-4 be 20 20 20 BO Ay 19-06 202°7 i, 10:2 at 20 10 30 30g 18°80 184:3 J. 9°6 30 300 30 anys BO) 9s, 2°89 30°1 K. 10°3 tt 30 90 ae a et 23°40 2271 L. 10°5 is a0) b- 30 30 30)», 24:50 233°3 M. 10°25 B56 30 20 40 50S, 23°75 Jol MN; 10:0 x07 30 60 Bi ou a 25°40 234:0 The specific gravity of each nitroglycerine was taken, and was found to vary from 1°601 to 1°604, depending on the temperature. From this fact alone, of the close agreement in specific gravity exhibited by the various products, it might be fairly concluded that they were all one and the same body. Their uniformity has, however, been more certainly proved by their all having been ascertained to contain the same percentage of nitrogen.* Indeed, in whatever way tested, whether as regards specific gravity, yield of nitrogen and of nitrous acid, and behaviour towards solvents, they were all found to agree precisely. The great difference in the amounts of the various products cannot therefore be regarded as being due to a difference in the nitroglycerine. It seems to be almost entirely caused by the differences in the quality and proportion of the * Vide Hay and Masson’s Paper on “The Elementary Composition of Nitroglycerine.” CHEMISTRY OF NITROGLYCERINE. 85 acids. The highest yield of nitroglycerine is that of N., where 234 parts of nitroglycerine were procured from 100 parts of glycerine. Now, glycerine, C,H,.(O0H);, ought theoretically to produce 246 per cent. of tri-nitrate of glyceryl, C,H,.8(0.NO,). Making allowance for inevitable loss from various intelligible causes, it may, therefore, be fairly deduced that the experi- mental yield of nitroglycerine strongly favours nitroglycerine being regarded as the tri-nitrate. If it were the tri-nitrite, C,H;.3(0.NO), the theoretical yield would be 194 per cent.; if the di-nitrite, C,H;.HO.2(O.NO), 163 per cent.; and if the mono-nitrate di-nitrite, C,H;.(O.NO,).2(0.NO), 211 per cent. The actual yield very distinctly exceeds any of these. With regard to the conclusions of practical and commercial importance which may be drawn from these various methods of preparing nitroglycerine, it is to be observed that there is a distinct advantage, as is generally recognised, in employing fuming nitric acid (compare (F) and (G) with (K)); that where fuming nitric acid is used, no benefit is to be obtained from the employment of fuming sulphuric acid (compare (L) and (M) with (K) and (N)); that two parts of ordinary sulphuric acid to one part of fuming nitric acid appears to give as good a yield as any other proportion of acids, and quite as large a yield as when more sulphuric acid is used (compare (N) with (K)); and that the yield is not to any considerable extent increased by allowing the acids and glycerine | to remain in contact for some time after mixture, as some chemists have advised (compare (F) with (G), and (L) with (M)). Characters of Nitroglycerine—I have been somewhat surprised to find that a large number of contradictory statements exist as to the ordinary physical characters of nitroglycerine. Whilst a few authors describe it as colourless, by others it is referred to as a pale yellow oil, even in the most authoritative modern works on Chemistry, as FeHtine’s Mewes Handworterbuch der Chemie* and Bremsrem’s Handbuch der Organischen Chemie.t Now nitroglycerine is per- fectly colourless when pure. As obtained from dynamite, it is certainly yellow, but the colour is due to decomposition having taken place, which, I believe, is to little or no extent spontaneous in character, but rather proceeds from the presence of a little of the weak soda which is invariably employed in the manu- facture of nitroglycerine for the purpose of removing the traces of the acids. The soda neutralises the acids, but it at the same time decomposes the nitro- glycerine, and imparts the colour so commonly ascribed to it as an inherent property. Nitroglycerine washed with distilled water has in my possession never become in the slightest degree coloured, even although kept in an open capsule, freely exposed to the air, but away from dust, for two months; in stoppered bottles it has not during the last seven months showed the least sign of decomposition. Even in solution in water, or in alcohol, it keeps almost equally well. More than one author states that it decomposes and becomes red on Bo, ii Lene) + S. 529, 1881. 86 DR HAY ON THE CHEMISTRY OF NITROGLYCERINE. being heated over the water-bath. I have heated pure nitroglycerine to the highest possible temperature over the water-bath for four hours, and have never observed the development of the slightest colour or decomposition. When it decomposes under such circumstances it probably contains free acid or alkali. Again, it is stated by Rartton* that when placed in the bell-jar of the air-pump it rapidly undergoes decomposition. In the course of the investi- gation by Mr Masson and myself, we have kept nitroglycerine for twelve days in vacuo without its exhibiting the slightest signs of decomposition. The decomposition of RarLron’s preparation must have been due to its impurity. Nitroglycerine has no odour when cold, but emits a pungent odour when heated. Although odourless in the cold, it nevertheless seems to be under- going slight volatilisation; for after working with it for a short time, and without directly touching it with the fingers, I have generally experienced its physio- logical effect in a slight degree. Its taste is sweet, and not unlike that of glycerine, but is more pungent. As regards its solubility, 1 gram. dissolves in about 800c.c. of water ; with difficulty in 3¢.c. of absolute alcohol, easily in 4c¢.c.; in 10°5¢.c. of rectified spirit (sp. gr. 0°846); in lec. of methylic alcohol (sp. gr. 0°814); in 4c.c. of methylated spirit (sp. gr. 0°830) ; in 18 ¢.c. of amylic alcohol ; in every proportion in ether ; so also in chloroform, in glacial acetic acid, and in carbolic acid ; in less than 1c.c. of benzol; in 120c.c¢. of carbon bisulphide ; and to a very limited extent, if at all, in glycerine. Method of Estimating Nitroglycerine.—In cases where nitroglycerine cannot be estimated gravimetrically after extraction with one of its solvents, a method based on the evident constancy of the amount of the nitrous acid produced in its decomposition with potash may be safely adopted. I have made use of this method for ascertaining the degree of its solubility in water, and for other quantitative estimations in the course of this investigation, and it is not difficult to apply. The materials necessary are a standard solution of pure nitrite of sodium (titrated with permanganate) of the strength of 1 in 1,000,000, a well-boiled solution of starch and iodide of potassium, dilute sulphuric acid, and pure potash, ascertained to be free from nitrous acid. Heat the fluid containing the nitroglycerine with excess of potash, and dilute with water until, in comparison with the standard solution of nitrite of sodium, it yields a blue colour with the starch mixture and sulphuric acid of precisely the same depth. From the degree of dilution required the amount of nitrous anhydride present can be readily calculated, and this amount eel de 10 ; ‘ F : multiplied by 3.. 2 (33°48 being the percentage of nitrous anhydride yielded by nitroglycerine) will give the quantity of nitroglycerine. * Op, cit. L870) VI.—The Elementary Composition of Nitroglycerine. By Matturw Hay, M.D., and OrME Masson, M.A., B.Sc. (Communicated by Professor Crum Browsx.) Nitroglycerine is commonly described as the tri-nitric ether of glyceryl, and the formula C,H;(O.NO,), is accorded to it. This theory of its composition is based (1) upon its mode of formation; (2) upon the statement, made by RAILToN, WILLIAMSON, and others, that it is decomposed by potash into potassium nitrate and glycerine ; (3) upon several estimations of the nitrogen which it contains, and one comparative estimation of its carbon. The second argument cannot be accepted, as it has been shown by one of us that the decomposition does not take place in the way stated;* and the analytical results which have been obtained by the various investigators are so incomplete and mostly so imperfect, and differ so greatly among themselves, that they cannot be taken as affording any proof of the composition of the substance. It seemed to us, therefore, desirable that some accurate estimations should be obtained, not only of the nitrogen but of the carbon and hydrogen. A brief résume of previous analytical results will show that this is the case. . RaitTon,t in 1855, attempted to estimate the relative quantities of carbon and nitrogen by Liepic’s method. The ratio of the volume of carbonic acid to that of nitrogen required by the formula is 2:1. Rariron obtained results varying from 2°156:1 to 1°912:1; so that, although they are on the whole in favour of the formula, they cannot be regarded as satisfactory. He made no attempt to estimate the carbon and hydrogen absolutely, as he found it impossible to dry his nitroglycerine, even in an exhausted receiver, on account of its great tendency to decompose. This proves that the substance was impure, as we have found pure nitroglycerine to be perfectly stable in the air and in vacuo. WILLIAMson,{ in the following year, gave an account of the composition of nitroglycerine, which agrees so exactly with Razron’s in every detail, that there can be no doubt that their experiments were made in conjunction, although published separately and without reference to each other. Hess,§ in 1874, estimated the nitrogen in commercial nitroglycerine * See the preceding paper : ‘‘ Contribution to the Chemistry of Nitroglycerine,” by MartHew Hay. + Ratton, Quart. Jour. Chem. Soc., vol. vii. p. 222, ~ Wuu1amson, Proc. Roy. Soc., vol. vii. p. 130. § Huss, Zeitschr. f. anal. Chen, 1874, S. 257. VOL, XXXII. PART I. le 88 MATTHEW HAY AND ORME MASSON ON THE obtained from various sources. He used different methods and got results varying from 13:7 to 16°6 per cent., the percentage required by the formula of elyceryl tri-nitrate being 18°5. From this he concluded that commercial nitro-— elycerine contains the mono- and di-nitrate, as well as the tri-nitrate. BECKERHINN,* in 1876, described an extremely elaborate method for the estimation of the carbon and hydrogen, but gave no results. Hess and Scuwas,t in 1877-78, made some nitrogen determinations by Dumas’s method. In one sample they found 15°72 and 15:65 per cent., and in another (from Nose.’s Zamky manufacture of 1872) they found 16°13, 16-12, and 16°12 per cent., though this was the same liquid which four years earlier had yielded Hess only 14:0 per cent. SAvER and Apor,{ in 1877, estimated by three methods the nitrogen in nitro- elycerine obtained from dynamite. First they used Reicuarpr’s modification of ScHLoEsine’s method, after decomposing the liquid with potash, and obtained from 12°3 to 14 per cent. Next they tried the ignition with soda-lime process, but found that only 2 to 8 per cent. of the nitrogen was evolved as ammonia. Finally they made four determinations by Dumas’s method, using nitroglycerine obtained from three different samples of dynamite; and in this case they obtained from 18°35 to 18°52 per cent., which agrees very closely with the per- _ centage calculated from the formula, but differs widely from that obtained by Hess and Scuwas by the same method. The nitroglycerine which we employed in our - analyses was made by adding, drop by drop, one part by weight of Price’s pure glycerine to a mixture of two parts of nitric acid (sp. gr. 1°49) and six parts of sulphuric acid (sp. gr. 1°84), the mixture being surrounded with ice and kept at a temperature never exceeding 10°C. Five minutes were allowed to elapse before pouring the mixture into water ; and the precipitated nitroglycerine was then well washed eight times with large volumes of distilled water, and dried for seven hours in an air-bath at a temperature of from 70° to 80° C. Finally, it was allowed to stand twelve days over sulphuric acid in the exhausted receiver of an air-pump. Not the slightest sign of decomposition ensued ; and it was found that. the nitroglycerine, after standing one week in vacuo, had lost less than one-tenth per cent. of its weight, which shows that it was practically dry from the first. It was perfectly colourless and transparent. Its specific gravity at 14°5C. was 1°601. The carbon and hydrogen were estimated by ignition in a tube closed and drawn out at one end and filled with copper oxide and metallic copper in the usual manner. At the termination of the ignition the drawn-out point was * Beckerninn, Sitzgsber. Wien. Akad., Bd. xxiii, Abth. ii, S. 240. + Hess wv. Sonwan, Ber, Deutsch. chem. Gesellschft., Bd. xi, 8. 192. ¢ Saver w, Avor, Jbid., Bd. x. S. 1982. ELEMENTARY COMPOSITION OF NITROGLYCERINE. 89 broken, and a stream of oxygen was passed through to ensure the complete combustion of the carbon. In our first experiment the nitroglycerine was weighed out in a short glass tube, and this was dropped into the combustion tube; but an explosion occurred at an early stage of the ignition, which, although damaging the furnace and slightly injuring one of us who happened at the moment to be within a few inches of the tube, satisfied us that the explosive force of the quantity of material employed (0°23 grm.) was not so ereat as to prevent our continuing the experiments with the adoption of very ordinary precautions. It was next attempted to burn the nitroglycerine in the form of dynamite, using pure and previously ignited Kveselguhr as the absorbent ; but this also gave rise to an explosion, though of greatly diminished violence. Ultimately it was found that the combustion could be performed without any risk of explosion by adopting the following method. A quantity of the liquid (from ‘2 to ‘4 grm.) was weighed out in a porcelain boat con- taining finely-divided copper oxide, and was then covered with another layer of the oxide. The boat was dropped into the combustion tube, and its contents were scraped out and well mixed up with the granulated copper oxide by means of a long bent copper wire. . The tube was then filled up in the customary manner. The chief difficulty attending this method is to avoid the introduction of moisture by the copper oxide and consequent raising of the hydrogen percentage. The precautions taken against this were increased in each experiment, so that the last hydrogen determination is probably the most reliable, while the first is considerably too high. All the combustions were conducted with unusual slowness. The same means was employed for filling the tube in the nitrogen determinations by Dumas’s method. Calculated. Found. “2 ; 15°86 Be a: ; 9:90 = Ne . : ; 18°50 an oe we 17:93 17:97 a 63-44 Two nitrogen determinations were also made with the same nitroglycerine before it had been placed im vacuo, and the results, though slightly higher, hardly warrant the belief that there was any difference in the Gaeanostbion. They were (1) 18:25 and (2) 18-06. We consider that the above figures prove nitroglycerine to be glyceryl trinitrate, the slight deficiency of nitrogen being possibly due to the presence 90 MATTHEW HAY AND ORME MASSON ON THE of traces of impurities (oxidised derivatives of glycerine) irremovable by the water with which the nitroglycerine was washed. We have also estimated the nitrogen in other samples of nitroglycerine, prepared with different proportions of acid, in order to ascertain whether a difference in the method of preparation causes any corresponding difference in the composition of the liquid. The results show that it is not so. In these cases Dumas’s method was not employed, but a modification of ScHLOESING’s process, which we have found to give equally good results, in spite of the contrary experience of Hess and Scuwas and of SAvER and Apor. The weighed quantity of nitroglycerine was dissolved in absolute alcohol and decomposed by boiling for ten minutes with excess of an alcoholic solution of caustic potash. Water was then added, and the whole of the alcohol was driven off by evaporation ; after which the fluid was made up to a given volume, of which a measured portion was taken for experiment. The volume of nitric oxide evolved by the reducing action of the ferrous chloride and hydrochloric acid (the reagents employed in ScHLOESING’s method) was, in each case, compared with the volume of gas obtained under precisely the same conditions of temperature and pressure from a standard solution of pure potassium nitrate, aud also, in certain instances, of pure sodium nitrite; and from these data the percentage of nitrogen was calculated. A correction is, however, necessary, inasmuch as a small portion of the nitrogen is always evolved as ammonia on boiling the nitroglycerine with potash. The amount of this was determined in a preliminary experiment, as follows :— 1:1533 grm. of nitroglycerine was dissolved in 5 c.c. absolute .alcohol and a solution of 1:5 grm. of potash in absolute alcohol added, the flask being immediately connected with a modified BoussincAvuLt’s apparatus and then boiled. After half an hour an equal volume of water was added, and boiling then continued three-quarters of an hour more. The distillate was received into standard acid; and, at the end of the operation, this was titrated with standard soda. By this means it was found that 0053 grm. of ammonia had been evolved ; so that nitroglycerine loses nitrogen during decomposition with potash to the extent of 0°38 per cent. of its weight. This amount was, therefore in each case, added to the percentage of nitrogen found by ScHLOESING’s method. In the following table the letters in the second column refer to the various samples of nitroglycerine employed. A detailed description of their manu- facture will be found in the preceding paper,* where they are lettered in the same order. Experiment IX. was made with nitroglycerine obtained from a NoseEL’s dynamite cartridge by displacement with water and desiccation over the water-bath. * A Contribution to the Chemistry of Nitroglycerine,” by Matruuw Hay, ELEMENTARY COMPOSITION OF NITROGLYCERINE, 91 No. of Nitroglycerine Percentage Corrected for loss Percentage Experiment. Employed. Nitrogen found. of NH. Calculated, I; A EGE 18:15 EE A 17-47 17°85 ITI. A 17°76 18:14 TRV. B 17°76 18:14 V. C 17°76 18:14 18°50 VI. F 17-41 agers) Vii. J 17°81 LS*19 VILL N 17°73 18°11 IX, Nobel’s gerd 18°15 These figures agree closely not only with each other, but with those obtained by us by Dumas’s method. Our analyses already given prove nitroglycerine to be glyceryl tri-nitrate : these analyses render it highly probable that it is invariable in composition, and that therefore the statements of some previous investigators, particularly those of HEss, are erroneous. If nitroglycerine at any time does contain the lower nitrates of glyceryl, it is probably owing to the nitroglycerine having been very imperfectly washed in the process of its manufacture. Nitroglycerine is only very slightly soluble in water ; glycerine is freely soluble in water; and, reasoning from chemical analogies, it is highly | probable that the intermediate nitrates possess intermediate degrees of solubility, which will readily permit of their removal by an ordinarily complete washing of the nitroglycerine with water, but may allow only of their partial removal if a limited quantity of water is used. According, however, to the published description of the various commercial processes for the preparation of nitroglycerine, the washing appears to be sufficiently thorough to remove the lower nitrates; for the amount of washing necessary to remove traces of the free acid used in the manufacture of nitroglycerine is certainly quite sufficient to dissolve out the lower nitrates. VOL, XXXII. PART 1. ; Q . } } : ‘ » - } 2 5 ’ t / } ' ’ é ‘ . 7 - 7 f ‘ . ’ . m . eer “ Pm r if . < . 4 . j . is VIL. — Report on the Tunicata collected during the Cruise of H.M.S.“ Triton” in the Summer of 1882. By W. A. Herpman, D.Sc., Professor of Natural History in University College, Liverpool. (Plates XVI. to XX.) (Read 16th July 1883.) This collection was sent to me for examination some months ago by Mr Murray. It may be conveniently divided into two very natural groups :— 1. Ascip1AceA, including the forms dredged or trawled: from the bottom of the sea. 2. THALIACEA, including the free-swimming pelagic forms captured by the tow-net at or below the surface. The small group of AscripIACcEA contains no Compound Ascidians, and only two* of the four families of Ascidiae Simplices known are represented init. The one of these families (the Cynthiidze) is represented by a single species only, while the other (the Ascidiidz) contains the remaining three species, referred to the two genera Ascidia and Ciona. One of those species of Simple Ascidians _(Aseidia tritonis) is new to science, the other three are well-known British forms. This little collection of Ascip1acza is chiefly interesting (1) on account of the depths at which the specimens were procured, and (2) on account of the locality being one in which the Ascidian fauna had not been previously investi- gated. Ascidia tritonis, though a new species, is not in any way aberrant or strikingly peculiar, and hence, as far as the Simple Ascidians of the collection go, the region explored by the “'I'riton” may readily be regarded as an exten- sion of the British fauna. The second group—the THALIACEA—is a very considerable collection, as may be seen from the following list of the different localities. The most remarkable circumstance in regard to it is that, with the exception of two specimens of Salpa, the whole series is composed of one species, Doliolwm denticulatum, of which between five and six thousand specimens were collected. List of “ Triton ” THALIACEA. 1882. August 3rd—4th. Surface. Doliolwm denticulatwm, about 100 specimens, 1 small one (2 mm. long). Ath. Tow-net at a depth of 12 fathoms. Dol. denticulatum, 8 specimens, in absolute alcohol. » 4th—5th. Tow-net at a depth of 12 fathoms. Dol. denticulatum, about 1000 specimens; and 1 specimen of Salpa runcinata (aggregate form). * See “ Postscript,” page 114. VOL. XXXII. PART I, R 94 DR W. A. HERDMAN ON August 5th (Station 2). Nets at the weights and trawl, 530 fathoms. Dol. denticulatum, about 1000 ) 7th. 7th—8th, 8th. 9th. ” 13th—30th. 18th. 20th. ” 22nd. 22nd—23rd. 24th. 28th. specimens ; also 6 specimens in absolute alcohol. Surface. Dol. denticulatum, about 30 specimens. Surface. FS 3 specimens, in absolute alcohol. Surface. 3 20 specimens. Tow-nets at a depth of 100 to 150 fathoms. Dol. denticulatum, 60 specimens ; also 20 in absolute alcohol. Tow-nets at trawl at a depth of 327 to 430 fathoms. Dol. denticulatwm, 20 speci- mens. Surface to 40 fathoms. Dol. denticulatum, 9 specimens. Surface. Dol. denticulatum, 1 specimen; and 1 specimen of Salpa runcinata (soli- tary form). Surface. Dol. denticulatum, 1 large and 3 small (2-3 mm. long) specimens. Tow-net at a depth of 40 fathoms. Dol. denticulatum, about 50 specimens. Tow-net at a depth of 300 fathoms. Dol. denticulatum, about 40 specimens, Tow-nets with 400 fathoms of line out. Dol. denticulatum, 75 specimens. Tow-nets at a depth of 400 fathoms. Dol. denticulatum, 12 specimens. Surface. Dol. denticulatum, 1 specimen, stained brown, Tow-net at a depth of 40 fathoms. Dol. denticulatwm, about 50 specimens. Tow-nets from surface to 400 fathoms. :, ime col0) > Ps atadepth of 600 ,, 3 st 450 : Tow-nets between surface and 40 ,, x 25 specimens. Surface, at night. 2 75 Mi Tow-nets at a depth of 40 fathoms. > 1 specimen. Surface. z 50 specimens. Surface down to 40 fathoms. “ about 40 specimens. Tow-nets at a depth of 40 fathoms. 35 30 specimens. Surface. Dol. denticulatum, 28 specimens, in osmic acid and absolute alcohol. » about 100 2 picrie _ ” » 180 ” osmic ” 3 ye LO, a chromic 3 Tow-net at a depth of 5to 10 fathoms. Dol. denticulatum, about 1200 specimens. Tow-nets at a depth of 10 fathoms. Dol. denticulatum, about 150 specimens, in chromic acid. Tow-nets at a depth of 13 fathoms. Dol. denticulatum, 1 specimen, in chromic acid. Tow-nets at a depth of 12 fathoms. Dol. denticulatum, about 100 specimens, in picric acid. Tow-nets at a depth of 20 fathoms. Dol. denticulatum, about 100 specimens. ” 40 ” ” 200 ” Tow-nets with 400 fathoms of line out. Dol, denticulatum, about 130 specimens. Tow-nets at weights (Station 12), 580 fathoms. Dol. denticulatum, 50 specimens. Surface. Dol. denticulatum, 100 specimens, Surface down to 40 fathoms. Dol. denticulatum, about 100 specimens, one of them small (3 mm. long). Tow-net at trawl (Station 13), depth 570 fathoms. Dol. denticulatum, 20 speci- mens. Also, obtained during the cruise of the “ Knight Errant ”: — August 10th, 1880, From a depth of 20 fathoms. Salpa zonaria, 10 specimens. The localities of most of these dates, namely, 7, 7-8, 8, 9, 18, 20, 21, 29, and THE ‘ TRITON ” TUNICATA. 95 30, are over the ‘‘ Wyvilie-Thomson” ridge, 7, 7-8, 8, 9, and 30 being towards the NW. end, and 18, 20, 21, and 29 near the centre. 22 and 22-23 are situated in the “cold area” near its southern end; while 24, 28, and 31 are in the “warm area” near the SE. end of the ridge. 3-4, 4, 4-5, and 5 are between the island of Rona and the southern end of the ridge. OrpER I.—ASCIDIACEA. Family CyNTHIID. Polycarpa pomaria, Savigny (Pl. XVII. figs. 5 and 6). I have referred a small specimen from Station 3 to this widely distributed and apparently highly variable species. I have not examined a sufficient number of specimens to be able to say much as to the range of variation from my own experience ; but from a comparison of the descriptions of other inves- tigators, it is obvious that this is one of those interesting forms out of which it is possible to make either one or half a dozen “species,” according to the state of one’s critical faculties. TrausTEpT* describes it as Styela pomaria, and gives as synonymous Cynthia pomaria, Sav., C. coriacea, Alder, C. tuberosa, Macgill, and Polycarpa varians, Heller ; while HELLERt suggests that Cynthia sulcatula and C. granulata of Alder may also be varieties merely. There can be little doubt that Savigny’s Cynthia polycarpa and C. pomaria are merely varieties of the one species now known as Polycarpa pomaria, Say. (=P. varians, Heller), and Cynthia tuberosa of Macgillivray is certainly the same species; while Alder’s Cynthia sulcatula and C. granulata may possibly be young individuals. But I cannot agree with TRAUSTEDT and HELLER in regarding Cynthia coriacea, Alder and Hancock, as another variety. The description in Alder’s Catalogue f states (1) that the ovaries are large and white, and line the mantle with cylindrical convolutions, and (2) that the branchial sac has about ten longitudinal folds, two important characters either of which would be sufficient evidence to exclude the species from the genus Polycarpa, while the second alone, if “ about ten” may be taken as meaning more than eight, cuts it off even from the sub-family Styeline. The Triton specimen, which is a small one (2 cm. in length, 1°6 cm. dorso- ventrally, and 1:2 cm. in thickness), was trawled at Station 3 (8th August 1882, at the NW. end of the Wyville-Thomson ridge, and north of the ‘‘ warm area,” bottom s. sh.) from 87 fathoms. Viewed from the side, it is rudely quadrate * Oversigt over de fra Danmark og dets nordlige Bilande kjendte Aseidice Simplices. Vidensk. Meddel, Nat. For., Kjobenhayn, 1880, p. 415. + Untersuchungen tiber die Tunicaten des Adriatischen und Mittelmeeres, Abth. iii. p. 19, Wien, 1877, { Cat. Mar. Moll. Northumb. and Durham, Trans, Tynes. Nat. Field Club, vol. i. 1850. 96 DR W. A. HERDMAN ON rather than hemispherical in outline, the anterior end being truncated and almost as broad as the base of attachment. The most projecting point of the anterior end is placed midway between the two apertures, which are far apart, and distinctly upon the right side of the extremity (see Pl. X VII. fig. 5). Probably on account of extreme contraction, they are also sessile, rather inconspicuous, and irregularly lobed: The test is thick, strong, and leathery ; greyish-white on the outer surface, and white in section. At the posterior end it has several root-like prolonga- tions from 1 to 1'2 cm. in length. The mantle is thick, strongly muscular, and closely united to the inner surface of the test. The branchial sac has eight very prominent folds, four upon each side. The two dorsal folds on each side are more closely placed than the ventral ones, and the clear spaces bordering the endostyle are considerably wider than those beside the dorsal lamina. As the branchial sac of this species has never, so far as I am aware, been figured, I give a view (Pl. X VII. fig. 6) from the inside of a part showing two folds and the interspace in their natural relations, while at the right-hand side another interspace is represented as more exposed by the removal of the next fold. The sac isa very thick one, the folds being prominent, the internal longitudinal bars numerous, and the stigmata comparatively small. Occasional wider transverse vessels occur; in some places (see fig., t7) they alternate regularly with three smaller ones (¢7’). Delicate membranes dividing the meshes are only present here and there (¢r”). At the base of each fold lies a series of large meshes (mh), each of which I found contained about six stigmata. ELLER mentions meshes with ten to twelve stigmata each; I found such only in the series adjoining the endostyle. The simple tentacles are numerous and closely placed. The dorsal tubercle is small and nearly circular in outline, being slightly elongated laterally. The aperture is anterior, and both horns are coiled inwards. The margin of the anus is expanded, and cleft into a number of blunt pro- cesses. The yellow polycarps and grey endocarps are so numerous as almost com- pletely to hide the inner surface of the mantle. Family Ascrprip/. Ascidia tritonis, n. sp. (Plate XVI.). External Appearance.—Shape ovate, flattened laterally, attached by posterior half of left side, especially towards the ventral edge; anterior end rather narrower than posterior but blunt. Dorsal edge slightly more convex than ventral. Branchial aperture terminal, sessile, wide, lobes distinct. Atrial THE “TRITON” TUNICATA. 97 aperture on dorsal edge, halfway from anterior to posterior end, sessile, wide, indistinct lobed. Surface even and soft, but finely roughened all over. Colour ereyish-brown. Test soft, cartilaginous, not stiff; thin on right side, much thicker on left, especially at the area of attachment, where it increases to 15 cm.; smooth and glistening on inner surface ; clear and transparent in section. Vessels not con- spicuous. Manile.—Shape long and narrow; siphons long, especially atrial, which is placed nearly halfway down the dorsal edge ; musculature strong on right side, almost absent on left, where the mantle is thin and membranous; sphincters moderately developed. Branchial Sac rather delicate and not plicated. Transverse vessels alter- nately larger and smaller, the larger ones with broad membranes hanging from them. Internal longitudinal bars narrow, bearing large curved papill at the angles of the meshes. Stigmata long and narrow, usually five in each mesh. Dorsal Lamina narrow, slightly ribbed transversely, and toothed on the margin ; double for a short distance at the anterior end. Tentacles numerous, of several sizes, some very long (up to 1°5 cm.), stout at the base. Dorsal Tubercle small, irregularly ovate in outline, aperture anterior, horns not coiled. Alimentary Canal not large, placed on the left side of the body about the middle. Cisophageal aperture two-thirds of the way down the dorsal edge of the branchial sac; stomach irregularly pyriform; intestine rather wide, and forming a narrow loop. Genitalia in intestinal loop. Sudrbatie vesicles extending over the greater part of the intestine. Vas deferens wide and prominent, running along the posterior and dorsal side of the rectum towards the atrial aperture. Three large specimens and one small one of this new species of Ascidia were obtained in the second haul of the dredge at Station 13 (81st August 1882, in the centre of the “warm area”), from a depth of 570 fathoms, bottom ooze. All of the specimens were more or less incrusted, especially upon the left side, with fragments of sponges and worm tubes; one of them had a few specimens of a small Tubularian zoophyte adhering, while the smallest individual had several specimens of Anomia ephippium attached to its test. The largest specimen is 13°5 cm. in length and 8 cm. in breadth, the smallest 5 cm. in length and 3 cm. in breadth. The remaining two are 9°5 cm. and 10°5 cm. respectively in length, while both measure 6°5 cm. across at the widest point. In general shape, and especially.in the position of the atrial aperture 98 DR W. A. HERDMAN ON (see Pl. XVI. fig. 1), this species shows resemblances to Ascidia lata* and Ascidia meridionalis,t but it differs greatly from both these species in internal structure. The shape of the body when the test is removed (Pl. XVI. fig. 3) is remark- | able on account of its great antero-posterior elongation, and the position of the stomach and the intestine so far from the posterior end. The appearance presented by the body when seen from the left side suggests that this peculiar relation is caused by the branchial sac having extended posteriorly beyond the stomach. The muscular pad at the base of the branchial siphon, from the lower edge of which the tentacles spring (Pl. XVI. fig. 6), is very strong. The tentacles are large, and so numerous that their bases touch. The dorsal tubercle (Pl. XVI. fig. 6) is peculiar, inasmuch as the left horn is bifurcated ; however, this is very possibly merely an individual variation. With the exception of Ascidia meridionalis, obtained during the “Challenger” expedition at 600 fathoms, off the south-eastern coast of South America, the present species was found at the greatest depth from which the genus Ascidia has been recorded. Ascidia virginea, O. F. Miiller (Pl. XVII. figs. 3 and 4). = Ascidia sordida, Alder & Hancock, Cat. Mar. Moll. Northumb., &c.) At first sight, and after a hasty examination, I was inclined to consider this ‘specimen as a new species, but after a more careful investigation of its anatomy I prefer to regard it as merely an abnormally-shaped individual of Ascidia virginea. If this form should be found to occur with sufficient frequency it might be distinguished as variety pedunculata. I remember dredging a similar individual a few years ago in the Firth of Forth, but cannot now find the specimen in my collection. The body is pyriform, shortly pedunculated, and attached by the posterior end (Pl. XVII. fig. 3); it is slightly compressed dorso-ventrally. The anterior end is narrow, but widens rapidly, especially on the right side ; the widest point is reached at a little more than one-eighth of the distance from the anterior to the posterior end. The anterior half is moderately swollen, the posterior half is much narrower, and forms a short stalk. The apertures are both near the anterior end, not distant, sessile, but conspicuously lobed. The surface is rather irregular, but smooth ; it is somewhat incrusted by foreign objects. The peduncle is slightly enlarged at its lower extremity to form a disc of * HerpMan on British Tunicata, Linn. Soc. Jour., Zool., vol. xv. p. 277. +t HerpMan, Report upon the Tunicata of the “Challenger” Expedition, part i, p. 207. Se THE “ TRITON ” *TUNICATA, 99 attachment. The colour is dirty grey. Length, 5 cm.; greatest breadth, 2 cm. ; thickness of peduncle, 1 cm. The test is thin, except at the top of the peduncle, where it is considerably thickened. The peduncle is solid, and formed of test alone. The vascular trunks enter the test at the top of the peduncle. When the test is removed the body has the appearance usual in Ascidia virginea, and the mantle is in a normal condition, strongly muscular on the right side, but thin and weak upon the left. The branchial sac corresponds in all respects with what I have found in other specimens of the species. It is longitudinally plicated to a slight degree, has strong internal longitudinal bars with no papille, and square meshes with five or six stigmata each. The dorsal lamina is strongly ribbed transversely. The tentacles are numerous, closely packed together, and of several sizes. Those of the first order are long and slender. The dorsal tubercle is simple, and elongated antero-posteriorly. The posterior three-fourths or so is enclosed in the small peritubercular area, and the end is pointed. The aperture is anterior, and the horns are not coiled (Pl. XVII. fig. 4). Ascidia virginea is one of the most variable species known, in regard to the shape of the dorsal tubercle.* The present form is rather simpler and more symmetrical than usual, and is peculiar in having the posterior end pointed. The single specimen was trawled off the Butt of Lewis, 25th August 1882, depth, 40 fathoms. Ciona intestinalis, Linn. (Pl. X VII. figs. 1 and 2). Sixteen specimens of this common British species were in the collection sent to me, four of them being preserved in absolute alcohol. They were all obtained by the trawl at Station 3 (8th August 1882, at the north-west end of the Wyville-Thomson ridge, and north of the “ warm area,” bottom s, sh.) from a depth of 87 fathoms. This is the greatest depth known to me at which this species has been found, but it is quite possible that it may have been obtained in Scandinavian seas, or in the Mediterranean at greater depths, though I have been unable to find records of such instances. The “Triton” specimens are all of fair size, and as some of them are much corrugated it is probable that they were large individuals when alive and expanded. The tests are more colourless than is usual with shallow water specimens from our own coasts, and have almost none of that dull green tint which may generally be observed even after preservation in spirit. On the other hand, * See Hzrpman, ‘‘On the ‘Olfactory Tubercle’ as a Specific Character in Simple Ascidians,” Proc. Roy. Phys. Soc. Edin., vol. vi. session cx. p. 256, 1881, 100 DR W. A. HERDMAN ON the red pigment spots at the branchial and atrial apertures and the pigment on the aggregation of glands at the opening of the vas deferens are as bright and conspicuous as is usual in the living animal. In one of the specimens preserved in absolute alcohol, which was dissected, the inner surface of the test was found to be closely ribbed longitudinally and less conspicuously so transversely. This has been caused by the test having remained attached to the mantle during the contraction of the latter, and having become impressed by the subjacent strongly developed longitudinal muscles. The papille at the angles of the meshes in the ‘iantial sac seemed larger than is usual in the species, and were certainly much larger than those represented by HEtLer* from a Mediterranean specimen. In some places their length equalled the space between two neighbouring internal longi- tudinal bars, so that when laid flat they stretched across the mesh. I have observed considerable individual variation in the branchial sac of this species. In 1881+ I noted a variability in the number of stigmata con- tained in each mesh, and since then I have met with several other points in which individuals differed. The specimens examined have been from various parts of the British seas—the Firth of Forth on the east ; Lamlash Bay, Loch Fyne, and the Sound of Mull on the west ; and Poole, Portland, and Dartmouth on the south coast. I have also specimens from the Channel Islands, the Chausey Archipelago, and the coast of Brittany, in addition to those collected by the “Triton” in the North Atlantic. I have very rarely seen the arrangement figured by Heiter { where the meshes are represented as being greatly elongated transversely, and occupied by two rows of extremely short stigmata. Usually the meshes are nearly square, and are divided into two areas by a delicate transverse membrane, which, however, does not generally interrupt the stigmata. This is shown at tr” in fig. 2, where the membrane crosses the mesh, while the stigmata extend behind. In the mesh below no transverse membrane is present, while in fig. 1 three are seen, the central one being much the strongest. This last arrangement was found to be very prevalent in the sac of the “Triton” specimen examined. In some specimens the meshes, in place of being square, are considerably elongated longitudinally—the reverse of the variation figured by HeELLER—and the contained stigmata are very long and narrow. In this case the meshes are always divided by from one to three transverse membranes. The papillae upon the internal longitudinal bars appear liable to considerable variations in their size and arrangement. In some cases they are present only at the angles of the meshes, as shown in the lower part of fig. 2, and are then all of much the same size. Where the meshes are divided there is usually a * Untersuchungen tiber die Tunicaten des adriatischen Meeres, Abth. ii. Taf. iv. fig. 6, Wien, 1875. t Jour, Linn. Soc., Zool., vol. xv. p. 332. t Loc. cit. THE “TRITON” TUNICATA, 101 papilla placed at each point of intersection with the median or chief trans- verse membrane (¢7” in the figs.) and the internal longitudinal bars. These papille are usually rather smaller than those at the angles of the meshes, but in some cases (as is shown in the upper part of fig. 2) the papillae may be all of the same size. I have found the chief papille varying in size from a little less than one-half* the breadth of the mesh to (in the case of the “ Triton” specimen) the entire breadth. In fig. 1 the papillae have been omitted, in order that the transverse membranes might be clearly seen. Returning to the “Triton” specimen, the margin of the anus was expanded and more deeply indented than is shown in HELuEr’s figure.t The oviduct was found full of ova, some of which were also discovered in the peribranchial cavity ; and the pigmented glands at the aperture of the vas deferens seemed to form a larger and more conspicuous mass than usual. Orpver II.—THALIACEA. Both families of this order, the Doliolide and the Salpide, are represented in the collection. Family I.—Do.totw 2. Doliolum denticulatum, Quoy and Gaimard (Pls. X VIII, XIX., and XX.). The five or six thousand specimens of Doliolwm in the collection are, I was astonished to find, all one form, and this I have identified with the sexual generation of Doliolum denticulatum.{ This species was first described and figured by Quoy and GaAtmaArp, the founders of the genus, in the zoology of the voyage of the “ Astrolabe,”§ in 1835. It had been found in the Malay Archipelago near the islands of Amboyna and Vanikoro. Sixteen years later Hoxtey || published his observations made upon certain Tunicata during the voyage of the “ Rattlesnake.” In this paper very considerable additions are made to the knowledge of the structure of Doliolum, and the relations in * Tn Heller’s figure they are about one-fourth of the breadth of the mesh. + Loe. cit., Taf. v. fig. 8. . { As will be pointed out in the following description, there are a number of details, especially in the branchial sac, in which these “Triton” specimens differ from the accounts of Doliolum denticula- tum given by Kererste1n and Exnurs (Zoologische Beitriige, 1861) and by GropBen (Arbeiten aus dem Zoolog. Instit. der Univ. Wien, 1882). As, however, they agree with those authors’ descriptions in the more important anatomical features, and as they could not be referred to any other known species, I prefer to consider them as a variety of Doliolum denticulatum. It is improbable that they are an undescribed species, since they are apparently so common in the North Atlantic. Doliolum den- ticulatum is probably rather a variable form. § “ Voyage de découvertes de l’Astrolabe,”’ Zoologie, T, iii, pt. 2, p. 599; Atlas, Mollusques, pl. Ixxxix. figs. 25-28. Paris, 1835. || “Remarks upon Appendicularia and Doliolium,” &¢., Phil. Trans. for 1851, part 2, p. 599, pl. XVili, ; VOL. XXXII. PART I. s 102 DR W. A. HERDMAN ON which the genus stands to Sa/pa and Pyrosoma are pointed out. Huxtey’s specimens had been obtained in the South Pacific between Australia and New Zealand. During the next few years Kroun,* GEGENBAUR,t and LeucKkartT{ worked at the Pelagic Tunicata, but their efforts, and especially those of the two former investigators, were mainly directed towards the elucidation of the remarkably complex life-history of Doliolum, and the additions made to the knowledge of the adult structure were comparatively few and unimportant. KEFERSTEIN and Euters,§ during the winter of 1859-60, investigated several Mediterranean forms of Doliolum, both as regards their anatomy and life- history. As the chief subject of their observations was Doliolum denticulatum, it has been of great advantage to have their description and careful figures with which to compare the “Triton” specimens. No works of importance upon Doliolum have appeared since, with the exception of ULrantn’s || and GROBBEN’s‘ papers, published during the last two years. These are mainly devoted to the development and life-history, which is now almost completely cleared up. GRoBBEN, however, treats also of the anatomy and histology, and to his memoir, as well as to that of KEFERSTEIN and EHLERs, I shall have to refer in the following description. Commencing with the body form, most of the “Triton” specimens are of the characteristic barrel shape (see Pl. X VIII. figs. 1, 2, 3, 4, and 9), some of them (as fig. 9, which was drawn from a specimen obtained August 4-5 from 12 fathoms) being rather wider than others. Some specimens, however (see fig. 10, which represents two specimens obtained on August 5th from a depth of 530 fathoms), are very different in shape, being narrow, elongated, and almost cylindrical. At first I separated out a number of these forms, under the impression that they were a distinct species from the barrel-shaped individuals, but found afterwards, when examining their structure, that the two kinds agreed perfectly in all the details of their anatomy. Since then I have found various intermediate shapes between those shown in figs. 9 and 10, and have consequently no hesitation in considering them all as one species. As a rule, I find it is the specimens from considerable depths, and those which have been closely packed in a tube or bottle, which diverge most from the typical barrel * “Ueber die Gattung Doliolum,” &c., Archiv fiir Naturgeschichte, 1852, p. 53. + “Ueber die Entwicklung von Doliolum,” Zeitschrift fiir wissensch., Zoologie, 1853, Bd. v. p. 13; and “Ueber die Entwicklungscyclus von Doliolum,” &c., Zeitschrift fiir wissensch., Zoologie, 1855, Bd. vii. p. 283. + Zoologische Untersuchungen, Heft ii., “Salpen und Verwandte,” Giessen, 1854. § Zoologische Beitrage, iii., “ Ueber die Anatomie und Entwickelung von Doliolum,” Leipzig, 1861. || “ Ueber die embryonale Entwicklung des Doliolum,” Zoologischer Anzeiger, iv. No. 92, p. 472, and No. 96, p. 575, 1881; also “ Zur Naturgeschichte des Doliolum,” Zoologischer Anzeiger, v. p. 429 and p. 447, 1882. {| “ Doliolum und sein Generationswechsel,’ &c., Arbeiten aus dem Zoolog. Instit. der Univ. Wien, &c., t. iv. h. 2, 1882. THE “TRITON”. TUNICATA. 103 shape, hence it is probable that the abnormal form is due either to the animal not having been killed suddenly enough or to imperfect preservation. All of the “Triton” specimens, with the exception of the five small ones mentioned in the list on page 93, are between 6 mm. and 12 mm. in length, and most of them measure 1 cm. This size is apparently much greater than that of Mediterranean specimens, as GROBBEN speaks of his as being about 2°5 mm., while KEFERsTEIN and Eaters figure one 3 mm. in length. Most of the specimens are in ordinary rectified spirit, while a few have been treated in each of the following methods :—. 1. Preserved in absolute alcohol. . Put first into chromic acid solution and then into absolute alcohol. . Preserved in a saturated solution of picric acid. . Put first into solution of osmic acid and then into absolute alcohol. . Put first into solution of picric acid and then into absolute alcohol. . Preserved in solution of chromic acid. These specimens were all in excellent condition for examination, and the different methods appear to give almost equally good results. Perhaps the best preparations for most histological points were obtained from the specimeris preserved in chromic acid by thoroughly washing in alcohol, staining in picro- carmine, and mounting in Farrant’s solution; while for some few special points the specimens preserved in osmic acid solution and absolute alcohol excelled. The test is almost absent, being represented merely by a delicate structure- less layer over the ectoderm, which covers the surface of the mantle. The mantle contains the muscular bands or hoops, which, in this form, are eight in number (m' to m*® in the figs.). The first and last of these bands form sphincters for the apertures, and usually appear to terminate the body anteriorly and posteriorly, as shown in Plate XVIII. fig. 4, the delicate denticulated margins of the branchial and atrial apertures being almost invariably turned in or directed across the opening. This denticulated margin was turned out in the chromic acid specimens examined, and was more perfectly preserved than in any of the others. It is divided into twelve lobes around the branchial aperture and ten around the atrial. The muscle bands are composed of very long non-striped fibres, closely and regularly placed, as shown in Plate XVIII. fig. 6. Sometimes, as in fig. 5 (from a picric acid specimen), the fibres are thrown into undulations. The wide branchial aperture leads into the branchial siphon, which, as there is no diaphragm and no circlet of tentacles, may be considered as extending back to the peripharyngeal band. This band, in all the specimens which I have examined, runs in most of its course between the 2nd and 3rd muscle bands, or in the 2nd intermuscular space (Pl. XVIII. fig. 11, p.p), and marks the anterior SO OF BP OD LY 104 DR W. A. HERDMAN ON end of the branchial sac, which extends back usually to between the 5th and 6th muscle bands. GRroBBEN, however, describes and figures* the peripharyngeal band as lying in the 1st intermuscular space. KEFERSTEIN and EHLERS also representt the branchial sac as extending anteriorly into the Ist intermuscular space, an arrangement which I have been unable to find in the “Triton” specimens. The arrangement of the stigmata is as follows :—A series commences on each side of the median dorsal line, close behind the 3rd muscle band (see Pl. XVIII. figs. 8 and 11, sg), and extends posteriorly for a variable distance —usually to about the 6th muscle band. The stigmata in this series differ greatly in size among themselves. The most anterior one is very short—in fact, almost circular. The next three or four increase rapidly in length till the level of the nerve ganglion (.g.) is reached, and then the increase becomes less marked. Towards the posterior end there is a slight diminution in size. Considered asa whole, the two series of stigmata diverge somewhat posteriorly, so that the space between them in the dorsal middle line is narrow in the 3rd intermuscular space, the region of the ganglion, but widens posteriorly (PI. XVIIL. fig. 11). As a result of this arrangement, when the branchial sac is seen from the side, the dorsal series of stigmata appear to slope downwards and backwards from the region of the ganglion (see PI. X VIII. fig. 4). There is also a series of stigmata upon each side of the ventral median line. These, how- ever, do not extend so far anteriorly as the dorsal series do. They commence behind the 4th muscle band, near the posterior extremity of the endostyle, and extend backwards, increasing in length rapidly at first, and then maintain. ing their size till they come to the sides of the cesophageal aperture. Here they commence to curve dorsally, and then towards each other, finally uniting in the dorsal middle line, usually near the 6th muscle band, so as to forma curve surrounding the membranous area in which the cesophageal aperture is placed (see Pl. XIX. fig. 10, sg). The membranous side wall of the branchial sac is very wide anteriorly, where it extends from the endostyle almost to the ganglion dorsally. In the 4th intermuscular space it is encroached upon by the development of the ventral series of stigmata, and as it is traced posteriorly from this point, it becomes narrower and narrower, till finally it merges upon each side into the median dorsal area through the failure of the dorsal stigmata. The exact number of stigmata in the different series varies of course according to the size of the individual. In mature specimens there are usually from thirty to fifty in the dorsal row on each side, and about thirty as an average in each ventral series. * Loc. cit., p. 13, woodcut, and pl. i. fig. 1, wb. + Zoologische Beitrdge, pl. ix. figs. 1 and 2. THE ‘“‘ TRITON” TUNICATA, 105 A glance at Plate [X. of Kerrerstern and Enters’ work suggests that the specimens there figured may have been young, and the number of stigmata shown (thirteen to fifteen in the dorsal row) is just about the number present in the smallest “Triton” specimens (2 mm. long). Perhaps this may also account for the great anterior extension of the dorsal rows of stigmata which are represented as reaching in front of the 2nd muscle band, while in the “Triton” specimens they were never seen in front of the 3rd (see Pl. XVIII. figs. 8 and 11). The ventral band, containing fifteen stigmata, is shown by KEFERSTEIN and EHLERS extending to the front of the 3rd intermuscular space, while in all the specimens which I have examined, it has terminated some place in the 4th intermuscular space. GRoBBEN* speaks of forty-two as the largest number of stigmata upon each side which he observed, KEFrERSTEIN and ExLerst say that the number may vary from twenty-six to forty-three, while the usual number in the “Triton” specimens was about seventy ! GROBBEN also describes and figures{ the series of stigmata as extending exactly one intermuscular space further anteriorly than I found to be the case. As they appear always to terminate posteriorly in the neighbourhood of the 6th muscle band, it is obvious that there must be a greater number of stigmata in each intermuscular space in the “ Triton” specimens than in those from the Mediterranean, and a comparison of my figures on theone hand, with those of GROBBEN and of KEFERSTEIN and EHLERs on the other, shows that this is the case. The bars separating the stigmata are covered in the usual manner with ciliated cells placed in such a position that the cilia project across the stigmata. These cells are not placed in a single row, as a surface view of the branchial sac such as that shown in fig. 2, Plate XIX. might lead one to imagine, but are placed in groups of four or five elongated cells placed closely side by side§ (see Pl. XIX. fig. 3). This arrangement can only be made out by viewing the bar upon which the cells are placed from the interior of the stigma. An osmic acid preparation showed with a Zeiss ;4,-in. oil immersion objective that these cells were nucleated and nucleolated, and had a striated band upon the free edge, from which the cilia project (Pl. XIX. fig. 4). At the rounded ends of the stigmata the ciliated cells are very numerous, forming many rows. They also change their character (see Pl. XIX. fig. 2), and become cubical, spherical, or polygonal in shape. The endostyle is always a well-marked feature in the ventral middle line of the branchial sac. It extends from midway between the 2nd and 8rd muscle bands anteriorly (Pl. XVIII. figs. 7 and 11, en) to somewhere in the 7 Lae cit., p. LG. + Loe. cit., p. 57. t Loe. cit., p. 16, and pl. i. fig. 1. § Grossen has figured a similar arrangement in the case of the asexual forms of the same species (Loe. cit., pl. v. figs. 34, &c.). 106 DR W. A. HERDMAN ON 4th intermuscular space posteriorly. KeErerstein and EHLERS represent it as extending rather further anteriorly, but terminating at the 4th muscle band posteriorly ; while in GrosBeEn’s figures it commences as in mine, but terminates in the 3rd intermuscular space. At its anterior extremity the endostyle is joined by the ventral ends of the two peripharyngeal bands (see Pl. XVIII. figs. 7 and 11), while posteriorly it is continued into a membrane with a free projecting edge which runs backwards over the heart, and then round the left hand side of the cesophageal aperture (Pl. XIX. fig. 10, mb). The histology of the endostyle has been minutely described by GroBBEN (loc. cit.). The prebranchial zone, the region anterior to the peripharyngeal band, is covered by squamous epithelium. In osmic acid preparations the protoplasm in these cells is found to have become contracted and aggregated around the distinct nuclei, so as to present the appearance, shown in Plate XIX. fig. 6, of stellate cells united by their processes to form a network. On the surface of the peripharyngeal band this epithelium has become modified into long fusiform cells (Pl. XIX. fig. 5) all placed with their long axes directed along the band. When not so highly magnified, or not stained properly, they give rise to the appearance shown in Plate XVIII. fig. 13. The dorsal ends of the two peripharyngeal bands meet, but at this point they are twisted round so as to form a double spiral towards the right, the left hand band performing one and a half turns, and the right a single turn only. This arrangement is shown in figs. 8, 11, and 12 on Plate XVIII., and at once suggests the form of the dorsal tubercle found in a similar position in the Ascidiacea, That organ is represented, however, in Doliolum, not by the curved dorsal part of the peripharyngeal band which has been described, but by the anterior end of the deeply funnel-shaped depression indicated by .a in figs. 8 and: 12.* The part of the prebranchial zone which is enclosed by the dorsal spirals’ of the peripharyngeal band has its epithelium modified into large polygonal cells, the outlines and nuclei of which are strongly marked. In the preparation from which fig. 7 on Plate XIX: was drawn, the protoplasm in most of the cells was aggregated around the nucleus in a stellate form. The nerve ganglion is placed in the mantle, and indicates the median dorsal line. It is small, but very distinct from its opacity. It is usually rudely cubical or nearly spherical in shape, and gives off four large nerve trunks, two at its anterior and two at its posterior angles, besides smaller nerves between. It usually lies a short distance behind the 3rd muscle band, as shown in figs. 8 * Possibly the cavity (v.a in the figures) represents merely the opening of the duct from the neural gland into the dorsal tubercle of the Ascidiacea, while the spirals (d.t, in Pl. XVIII. fig. 11) indicate the sense-organ, which I believe the dorsal tubercle to have formerly been (see Proc, Roy. Soc. Edin., p. 144, 1882-83, : - : THE “TRITON” TUNICATA. 107. and 11 on Plate XVIII., but may be further back as represented by KEFERSTEIN and Enters in their pl. ix. fig. 1. It may advance forward, so as to touch the 3rd muscle band (see Pl. XIX. fig. 1), but is never found outside the 3rd intermuscular space. The ganglion is very opaque, and it is difficult to make out its constitution. Fig. 8 on Plate XTX. shows its anterior end with four nerves, two large and two small, arising from it. GroppEn * has apparently not noticed the smaller pair (Pl. XIX. fig. 8, v’), but he describes a median anterior nerve which I could not find in any of my specimens, unless it be the nerve shown at n in Plate XVIII. fig. 12, which is drawn from an individual having apparently only three anterior nerves. As in other Tunicates, where the matter has been investigated, the nerve cells are all in the outer layers of the ganglion, and the centre is formed of a mass of delicate interlacing fibres and granular matter. Fig. 12, Plate XIX., shows this arrangement well. The nerve cells are ovate, unipolar, bipolar, or multipolar, rarely the latter. They are finely granular, and have distinct nuclei and nucleoli (see Pl. XIX. fig. 13). On the ventral surface of the ganglion there lies a dark mass which must be the neural gland, but of which I was unable to make out the structure definitely. It gives rise anteriorly to a very delicate duct which runs directly forwards to open at the prebranchial zone into the funnel-shaped depression mentioned above (see Pl. XVIII. figs. 8 and 12). This duct is wide where it emerges from below the ganglion, and its wall is formed of distinct polygonal cells (see Pl. XIX. fig. 8 2.d). It rapidly narrows, however, as it runs forwards, and the cell elements lose their distinctness, so that in the part immediately in front of the 3rd muscle band (Pl. XVIII. fig. 8, xd) it is very difficult to make out any structure in the wall. In front of this point it again becomes more distinct, and the cells vary from fusiform to squamous in their character (PI. XIX. fig. 9, n.d) up to the point where the duct joins the funnel-shaped de- pression. The length of this neural duct varies with the positions of the ganglion and of the aperture in the prebranchial zone. The normal arrangement is shown in figs. 8 and 11, Plate XVIII., while in fig. 1, Plate XIX., it is abnormally short, on account of the unusual position of the ganglion. The aperture in the prebranchial zone is always placed in the median dorsal line upon the most anterior point of the spirals formed by the peripharyngeal band, and therefore in the 2nd intermuscular space. GRoBBEN and also KEFERSTEIN and EHLERS figure it in the 1st intermuscular space, an arrangement which I have never seen. Although the peripharyngeal bands encroach upon the Ist inter- muscular space at the two sides (see Pl. XVIII. fig. 11), they always, in the specimens which I have examined, dip posteriorly at the ventral and dorsal Loe, seit.spa 9 108 DR W. A. HERDMAN ON ends, and hence the anterior end of the endostyle and the dorsal spirals come to be situated in the 2nd intermuscular space. The aperture in the prebranchial zone is small, and leads into a funnel- shaped cavity continuous with the neural duct (Pl. XIX. fig. 9). At the posterior narrower end of this cavity, the flat cells lining the duct become gradually cubical and then low columnar, and bear each a long cilium which projects into the centre of the cavity, and is directed posteriorly, This funnel-shaped cavity is apparently merely the aperture of the neural duct. I have searched in vain for any trace of a sensory apparatus. In several specimens I have suc- ceeded in tracing one of the smaller nerves given off from the anterior end of the ganglion in its entire course forwards (see Pl. XVIII. fig. 12, »). It runs alongside the duct and close to it, but passes the funnel-shaped cavity upon its left side without giving off any branch, and continues its way anteriorly to supply the lobes around the branchial aperture. The heart is situated on the ventral surface of the posterior end of the branchial sac, just between the termination of the endostyle and the cesopha- geal aperture and in the posterior part of the 4th intermuscular space (Pl. XIX. fig. 10,2). In chromic acid specimens the transverse muscle bands of the wall of the heart were well shown (see Pl. XIX. fig. 11), but each band appears to me to be composed of a large number of very fine fibres placed side by side, and not of one fibre only as supposed by KEFERSTEIN and EHLERS.* The alimentary canal, omitting the pharynx or branchial sac, which has been already considered, consists of cesophagus, stomach, and intestine, and forms a curved tube, lying mainly in the 5th and 6th intermuscular spaces (Pl. XVIII. fig. 4). The cesophageal aperture is placed at the posterior r end of the branchial sac in the middle line, and nearer to the ventral than to the dorsal surface. It lies in the membranous area prolonged back from the region around the posterior extremity of the endostyle (Pl. XIX. fig. 10), and is surrounded laterally and dorsally by the posterior end of the ventral series of stigmata. This is a notable point, since it is usual in the Ascidiacea for the oesophageal aperture to be placed on the dorsal edge of the sac, and invariably so amongst Ascidize Simplices, in some of which it is placed nearer to the anterior than to the posterior end of the dorsal edge. The cesophageal aperture is surrounded by a membranous rim, which on its left anterior edge is continued forwards to join the posterior extremity of the endostyle, while at its other end, after surrounding the aperture (see Pl. XIX. fig. 10, mb), it is continued as a spiral ridge into the cavity of the cesophagus. The cesophagus is short, and leads downwards and backwards to the anterior end of the large irregularly quadrangular stomach (Pl. XX. fig. 1, sé). From * Loc, cit., p.-58, THE “TRITON” TUNICATA. 109 the posterior end of this the short curved intestine emerges. The stomach lies in the 5th intermuscular space, and the intestine runs backwards till it almost or quite reaches the 7th muscle band, and then turns dorsally and to the right, and finally runs forwards to terminate in the anus placed in the 5th intermuscular space, over the stomach (Pl. XVIII. fig. 4). According to KEFERSTEIN and EnLers the anus is situated at the posterior part of the 5th in- termuscular space, or upon the sixth muscle band, while according to GROBBEN it lies in the 6th intermuscular space. Huxtey figures it in the fifth inter- muscular space. The epithelium lining the intestine is polygonal in surface view (Pl. XX. fig. 4) and very distinctly nucleated. In the wall of the stomach the cells are columnar and more darkly coloured. Two glandular systems, which seem to be quite distinct, are found in connection with this alimentary canal. First, along the ventral surface of the stomach, especially towards the pyloric end, and more or less scattered over the first portion of the intestine, may be found masses of rather darkly coloured glandular-looking czeca (see Pl. XX. fig. 1, g/). These branch and apparently anastomose occasionally, forming rude networks, but the branches are short and stout, and the meshes small and irregular. No duct or opening into the alimentary canal was visible. With a higher magnification the ceca present somewhat the appearance shown in Plate XX. fig. 5—masses of cells rounded or polygonal in outline, but rarely angular, having small indistinct nuclei and granular cell-contents. These clumps of branched ceca have apparently not been noticed previously, as I find nothing in the published descriptions and figures which could represent them. The second glandular apparatus is the system of fine clear-walled tubules ramifying over the intestine, which was first pointed out in Doliolum by HUXtLey,* and has since been more or less completely described by Leuckarr, GEGENBAUR, KEFERSTEIN and Enters, and GropBen. It has also been recently investigated by CHANDELONt in Perophora and Salpa, where it has very much the same arrangement as in Doliolum. CHANDELON comes to the conclusion that the system can be compared neither with a kidney nor a liver, but that it is probably a digestive gland of some kind. In the specimens which I examined this system appeared generally well developed, although it was sometimes difficult to make out, owing to the opacity of the alimentary canal caused by its food contents. In Plate XX. fig. 1, d indicates the duct of this system, which is a clear-walled, almost transparent vessel, entering the pyloric end of the stomach. From this point it may be traced upwards and backwards (Pl. XX. fig. 1, represents a specimen * Phil. Trans., 1851. + ‘‘Recherches sur une annexe de tube digestif des Tuniciers,” Bulletins de V Academie Royale de Belgique, 2™° ser. t. xxxix. No. 6, 1875. VOL. XXXII. PART I, T 110 DR W. A. HERDMAN ON in which the intestine has been turned ventrally so as to expose the whole alimentary system) to about the middle of the intestine. At this point the duct divides, and its two branches run over the wall of the intestine, subdivid- ing as they go. The twigs branch freely and sometimes anastomose (Pl. XX. fig. 3). Many of them end in short cecal projections, and in some cases these are enlarged to form terminal knobs (see Pl. XX. fig. 3, ¢), which may contain irregularly rounded bright bodies (concretions ?) similar to those described eee CHANDELON in Pevophora. The wall of the main duct is lined by regularly arranged fusiform cells placed with their long axes parallel to the length of the duct (Pl. XX. fig. 2), The tubules on the intestine are lined by flattened epithelium bulging into the lumen where the nuclei occur, and enlarged into cubical cells in the terminal knobs. The apertures of the reproductive organs lie at the posterior end of the body behind the alimentary cunal, and usually in the 6th intermuscular space. All the “Triton” specimens of Doliolum denticulatum examined belong to the sexual generation, KrrersTEIN and EHLers’ “generation A,” and have both male and female organs well developed. The ovary is an ovate mass placed usually in front of the 7th muscle band (Pl. XX. fig. 7, ov), but occasionally behind it (Pl. XX. fig. 6, ov). Ova of different sizes were almost always distinctly visible in it (Pl. XX. fig. 1, g, and fig. 13, ov). It opens on its dorsal edge into the atrial cavity. The testis, as Huxuey~* first correctly described, is in the form of a greatly elongated tube, usually nearly as long as the body, terminating posteriorly on the anterior face of the ovary, and extending forwards for a variable distance with rather an irregular course (Pl. XX. figs. 6, 7, &c.,and Pl. XVIII. figs. 1-4). At its posterior end, where it abuts against the ovary, it turns dorsally, forming a tube which may be called the vas deferens, and opens into the atrial cavity (Pl. XX. figs. 13 and 14, «d.). - The anterior end of the testis is very variable. NJEFERSTEIN and EHLERS state that it may terminate any place between the 3rd and the Ist inter- — muscular space, and they figure it at the posterior end of the 3rd in one case and the anterior end of the 4th in another. GRoBBeEn states that it extends ‘orward to the 4th muscle band, while Huxtey figures it as reaching nearly to the 1st. In most of the specimens which I have examined the anterior end is placed close to the 2nd muscle band, as shown in Plate XX. figs. 6 and 9. No previous investigators, so far as I am aware, either describe or figure the extra- ordinary variability in form of this anterior end of the testis. A glance at figs. 6, 7, 8, 9, 10, and 11 on Plate XX. shows the extent of this variability. In fig. 6 the tube becomes rapidly smaller opposite the 3rd muscle band, — * Phil. Trans., 1851, part ii. p. 602. THE “TRITON” TUNICATA. 111 and, after a short undulating course as a very fine tubule, enlarges into a pear-shaped dilatation extending to the 2nd muscle band. In fig. 9, which is drawn on a larger scale, there are two dilatations on the narrow part of the tube, while in fig. 11 the narrow part is long and convoluted, and extends forward to the 2nd muscle band. In fig. 10 the testis reaches the 2nd muscle band without any diminution in its calibre, and then, narrowing slightly, forms a loop extending almost to the 1st band, after which it curves back to- wards the 2nd, and ends in a narrow filament. The two remaining cases figured are the most remarkable of all. In fig. 8 the tube narrows rapidly opposite the 3rd muscle band, and from this point forwards almost to the 1st it remains very narrow, but with two large ovate dilatations and several smaller ones upon its course. Fig. 7 shows a case where the wider tube extends to the 2nd band and then suddenly narrows, but the fine tubule, in place of running forwards, turns posteriorly, and eventually reaches the 4th muscle band after passing through several irregular dilatations, Throughout, this male system was filled with minute granular cells (Pl. XX. fig. 12), but no distinct sper- matozoa could be made out. The most remarkable feature of this “ Triton ” collection of Doliolide is, that such vast numbers should prove to be entirely one generation of the same species, and all, with a very few exceptions, of much the same size. Questions naturally arise such as, Where have they come from? Where are the asexual forms from which they have been produced? and Why are such quantities of that species found in that locality at that time? We are not yet in a position to answer any of these questions fully. Mr Murray tells me that when captured, they were all drifting from the south-west to the north-east. This would carry them from the “‘ warm area” across the “ Wyville-Thomson ” ridge into the “ cold area,” but what part of the Atlantic they came from, or how far north they are carried, is not known. Mr Murray states that “they were abundant during the whole time of the cruise, except when we touched upon the Faroe bank water.” As far as I can judge from the numbers of specimens in the tubes collected on the different days, the configuration of the bottom and the division of the region explored into “warm” and “cold” areas has no effect whatever upon the abundance of the Doliolide. There are large quantities of specimens in the collection from the 3rd to the 5th August, halfway between Rona Island and the south-east end of the ridge; on the 29th August, over the centre of the ridge; on the 28th and 31st August, in the “warm area ;” and on 20th to 23rd August, in the “cold area.” The region from which the smallest numbers have been brought back are those explored on the 7th to the 9th August at the north-west extremity of the ridge. Mr Murray has kindly supplied me with the following extracts from his 112 DR W. A. HERDMAN ON journal, which bear upon the abundance of the Doliolide at different times, and relatively to other surface forms :— “ August 5, 1882.—Doliolums were quite as abundant to-day as yesterday; they appeared to be chiefly about 10 fathoms beneath the surface. Diatoms in the stomach as usual. The immense mass of these in this portion of the sea at this time is very astonishing. “The last year (1880), in the “Knight Errant,” the most characteristic thing in the surface gatherings was the enormous multitude of Acanthometre, and now these are almost absent. “ August 7.—There- was quite a change this morning in reference to the general character of the tow-net gatherings. The Doliolums had quite dis- appeared, and Acanthometre were now very abundant, and the most charac- teristic animals. “In the afternoon, after we had moved south from the Faroe Bank, we got again the same surface animals as yesterday and the day before, viz., vast numbers of Doliolums, some Medusze, larvee of Medusee or other Ccelenterates and Copepods. . “This is a somewhat remarkable change, and would perhaps indicate a | current of water from a different source than the more northern water of this morning. . “ August 18—The Doliolums also were observed to be phosphorescent, emitting electric-like discharges which were divided like forked-lightning, and appeared to me to follow the direction of the nervous cords or filaments... . Doliolums and Actiniz were again abundant throughout the day, sometimes in enormous abundance. “ August 24.—There are no Doliolums, and only a few Arachnactis in the © nets this morning, from about 30 or 40 fathoms. ... . Doliolums were got in some hauls at a depth.of 10 fathoms during the day. “ August 29.—There were a large number of Doliolums on thé surface during the day, indeed they masked all the other things in most of the hauls, In general, the Doliolums were most abundant about 5 or 6 fathoms beneath the surface. “ August 30.—During the day, in the tow-nets at and near the surface, Doliolums and Arachnactis were most abundant, filling the nets each time. “It is remarkable that in the tow-nets, at the weights, there were not over one or two Doliolums, but many Copepods, apparently Arctic forms, &ec. “In summary, Doliolums most abundant, masking all the other things for weeks. At times the Doliolums appeared to be in vast banks, where they were very numerous; between these banks there were always a few stragglers. J. M.” THE “ TRITON” TUNICATA. £5 Family I1.—Sa.pip-. During the “Triton” expedition only two specimens of Salpa were obtained, but curiously enough these show the two conditions—solitary and aggregated —of the same species, Salpa runcinata. In August 1880, during the cruise of the “Knight Errant” in the same neighbourhood, some large specimens of Salpa zonaria were the only Tunicata captured. Salpa runcinata, Chamisso. 1. Solitary form. One specimen, measuring 2'2 cm. in length, was obtained on the surface on the 18th August 1882. 2. Ageregated form. A single member of a chain was captured in the tow-net at a depth of 12 fathoms, 4th—-5th August 1882. This is the Salpa fusiformis of Cuvier, and has the body prolonged both anteriorly and posteriorly beyond the branchial and atrial apertures into long tapering appendages. The body proper measures 1°5 cm. in length and 1 cm. in breadth, while the anterior appendage extends beyond the branchial aper- ture for 1:4 cm., and the posterior appendage beyond the atrial aperture for 1°7 cm. Salpa runcinata is a well known Scandinavian form, and has been obtained in British seas before now. Early inthe present century, Dr Jonn MAccuLLocH described (Western Isles,* vol. ii. p. 187) and figured, under the name of Salpa monilifornis, a form which may have been the aggregate condition of S. runcinata. He found the chains occurring in abundance in autumn in the harbours of Canna and Campbellton. In the spring of 1821 Dr FLemine found many chains a foot and more in length upon the Caithness coast ; and about thirty years later Professor Epwarp Forses identified with Salpa runcinata, both solitary and aggregated, some specimens captured by Lieutenant THomas, R.N., in the Orkney Seas. In 1868 Professor M‘INrosut came upon vast quan- tities of both the solitary and the chain form of Salpa runcinata upon the east shores of North Uist, im company with both forms of Salpa spinosa, Otto, a species which ForseEs had predicted would probably be found in the Hebrides. Salpa zonaria, Chamisso. Ten specimens of this form were obtained in the tow-net, at a depth of 20 fathoms, on 10th August 1880, during the cruise of the “KnightErrant.” The specimens are well preserved, and are all about 4 cm. in length. * See Forses and Hanuzy, History of the British Mollusca, vol. i. p. 50, 1853. + See Jour. Linn. Soc., Zool., vol. ix. p. 41. 114 _DR W. A, HERDMAN ON POSTSCRIPT. Since the above was written, I have received from Mr Murray another - “Triton” specimen. This necessitates the following addition to my report — which should be inserted between “ Ascidiacea” and “ Family Cynthiide,” near the top of page 95 :— Family MoLeuLip-. Eugyra glutinans, Moller. A single specimen of this widely distributed species was obtained in the second haul of the trawl on the 22nd August 1882, at Station 8 (in the “ cold area,” near the S.E. end of the ‘‘ Wyville-Thomson ” ridge), from a depth of 640 fathoms. This is a greater depth than any from which Molgulide were obtained during the ‘ Challenger” Expedition. The incrusting sand is very fine, and the bare area around the apertures is conspicuous. In the branchial sac there are usually about eight coils in the spiral forming each infundibulum. The specimen measures 9 mm. in breadth — by 6°5 mm. in length. EXPLANATION OF THE PLATES. The objectives employed while drawing the figures were as follows :— Swift, 1 inch—magnifies about 45 diameters. nee OM rs 55 225 Fr bik een " 300 By Hartnach, No. 4 2 50 ys 4 iS = 180 s 32 r oe BOO 4 Zeiss ,!5, oil immersion ,, 950 “i The following system of lettering has been adhered to in all the figures :— at, atrial aperture. br, branchial aperture. - brf, fold in branchial sac. c, enlarged end of tubule of intestinal gland. d, duct of intestinal gland. dl, dorsal lamina. d.t, dorsal tubercle. en, endostyle. , genital mass. g!, gland at pylorus of stomach. gc, nerve cells in outer part of ganglion. h, heart. THE “TRITON” TUNICATA. 115 h.m, horizontal membrane of branchial sac. 2, intestine. 4.1, internal longitudinal bar of branchial sac. Z, lobe at branchial aperture. 1.v, fine longitudinal vessel of branchial sac. am to m8, the muscle bands in Doliolwm. mb, membrane. m.b, muscular bundle. mh, mesh of branchial sac. nN, 2’, nerves. n.a, aperture of duct from neural gland. n.d, duct from neural gland. ng, nerve ganglion. @, esophagus. @.a, cesophageal aperture. ov, ovary. p, papilla; p’, smaller intermediate papilla. p-p, peripharyngeal band. sg, stigmata. st, stomach. t, testis ; ¢’, anterior prolongation of testis. in, tn’, tn”, tentacles of 1st, 2nd, and 3rd order. tr, transverse vessel; ¢7’, tr”, smaller transverse vessels. v.d, vas deferens. 2, prebranchial zone. , Piatt XVI. Ascidia tritonis, n. sp. Fig. 1.—Ascidia tritonis, seen from the right side. Natural size. Fig. 2—A small portion of the surface of the test. Slightly magnified. Fig, 3.—Another specimen, after the removal of the test, seen from the left side. Natural size. Fig. 4.—Part of the branchial sac, from the inside. Objective, Swift, 1 inch. Fig. 5.—Small portion of dorsal lamina, showing free edge. Objective, Swift, 1 inch. Fig. 6.—Dorsal part of anterior end of branchial sac, showing tentacles, dorsal tubercle, peri- pharyngeal bands, &c. Objective, Swift, 1 inch. PEATE Neville Figs. 1 and 2, Ciona intestinalis, Linn, Figs. 3 and 4, Ascidia virginea, O. F. Miiller. Figs. 5 and 6, Polycarpa pomaria, Sav. Fig. 1.—A small portion of the branchial sac of Ciona intestinalis, Linn., seen from the inside ; papillz not represented. Objective, Swift, 1 inch. Fig. 2.—Another small portion of the branchial sac of Ciona intestinalis, from the inside. Objective, Swift, 1 inch. Fig. 3.—Ascidia virginea, O. F. Miiller, var. pedwnculata, from the left side. Natural size. 116 DR W. A, HERDMAN ON Fig. 4—Dorsal part of ee end of branchial sac of Ascidia virginea var. pediment 4 showing tentacles, dorsal tubercle, &c. Objective Swift, 1 inch. Fig. 5.—Polycarpa pomaria, Savigny, seen from the left side. Natural size. Fig. 6.—Part of the branchial sac of Polycarpa pomaria, seen from the inside, and showing two folds and two interspaces. Objective, Swift, 1 inch, PiatTe XVIII. Doliolum denticulatum, Quoy and Gaimard. Fig. 1.—Doliolum denticulatum from the right side. Natural size. Fig. 2.—A specimen preserved in chromic acid and absolute alcohol, from the left side. Natural size. Fig. 3,—The same specimen seen from the ventral surface. Fig. 4—A young individual (2 mm. in length) seen from the right side. Objective, Hart. 4. Fig. 5.—Part of a muscle band from the mantle of a specimen preserved in picric acid. _ Objective, Hart. 5. Fig. 6.—Another muscle band from the same specimen. Objective, Hart. 5. Fig. 7.—Anterior half of endostyle, seen from the interior of the branchial sac, from specimen stained in picro-carmine. Objective, Hart. 4. Fig. 8.—Nerve ganglion, dorsal part of peripharyngeal band, &c., seen from interior of branchial sac. Objective, Hart. 4. . Fig. 9.—Broad barrel-like form of Doliolwm denticulatwm, from left side. Natural size. Fig. 10.—Two specimens of the narrow elongated form. Natural size. Fig. 11.—Right side of branchial sac, &c., from interior. Reduced from Objective, Hart. 4. Fig. 12.—Nerve ganglion, neural duct, peripharyngeal band, &c. Objective, Hart. 5. Fig. 13.—Small part of peripharyngeal band, from specimen stained in osmic acid. Objective, Hart. 7. PLATE XIX. Doliolum denticulatum, Quoy and Gaimard. Fig. 1.—Nerve ganglion and dorsal part of peripharyngeal band, from a specimen preserved | in chromic acid and absolute alcohol, and stained in picro-carmine. Objective, Hart. 4. Fig. 2.—The ends of some of the stigmata, from a specimen preserved in picric acid. Objective, Swift, + inch. Fig. 3.—Some of the ciliated cells bounding the stigmata, stained in picrocarmine. Objective, Hart. 7. g. 4—Some of the ciliated cells bounding the stigmata, stained with osmic acid. Objec- tive, Zeiss, 5, oil immersion. Fig. 5.—Some of the cells from the surface of the peripharyngeal band of a specimen pre- served in chromic acid, and stained in picro-carmine. Objective, Zeiss, 45, oil immersion. Fig. 6.—Part of the prebranchial zone in a specimen preserved in osmic acid and absolute alcohol. Objective, Hart. 7. Fig. Fig. Fig. Fig. Fig. THE “TRITON” TUNICATA. 11% 7.—Part of the prebranchial zone enclosed by the coiled dorsal ends of the peripharyngeal band, from a specimen preserved in chromic acid and absolute alcohol, and stained in picro-carmine. Objective, Zeiss, p, oil immersion. 8,—The anterior half of the nerve ganglion, showing the origin of the neural duct, from specimen stained in osmic acid. Objective, Zeiss, ps, oil immersion. 9.—Anterior end of the duct from the neural gland, showing its ciliated expansion and terminal aperture, from specimen preserved in osmic acid and absolute alcohol. Objective, Zeiss, 75, oil immersion. 10.—Posterior end of endostyle, cesophageal aperture, and the neighbouring part of the branchial sac, seen from the interior, from a specimen preserved in chromic acid and absolute alcohol, and stained in picro-carmine. Objective, Hart. 4. 11.—Part of the heart, from specimen shown in fig. 10. Objective, Hart. 7. 12.—Part of the ganglion, showing the origin of one of the nerves, from a specimen pre- served in picric acid and absolute alcohol, and stained in picro-carmine. Objective, Zeiss, 75, oil immersion. 13.—A group of nerve cells from the ganglion shown in figure 12. Enlarged from Zeiss, Objective >, oil immersion, ocular 4. PLATE XX. Doliolum denticulatum, Quoy and Gaimard. 1.—(CEsophagus, stomach, intestine, digestive glands, reproductive organs, &c., of an individual preserved in alcohol, and stained in picro-carmine. Reduced from Objective, Swift, 1 inch. 2.—Part of the duct (d) crossing from intestine to stomach in last figure. Objective, Zeiss, =}, oil immersion, 3.—Part of the digestive gland forming a network of tubules over the intestine, from same specimen as fig. 1. Objective, Swift, 4 inch. 4.—Part of the wall of the intestine, surface view. Objective, Hart. 5. 5.—Part of the organ (g/) seen ramifying over the stomach and first portion of the intestine in fig. 1, from specimen stained in picro-carmine. Objective, Zeiss, 74, oil immersion. 6.—The reproductive system dissected out. Reduced from Objective, Swift, 1 inch. 7.—The same in another specimen, showing a curious anterior termination. Reduced from Objective, Swift, 1 inch. 8.— Anterior extremity of the testis of another individual, stained in picro-carmine. Objec- tive, Swift, 1 inch. 9.—Anterior extremity of the testis in another specimen, preserved in solution of osmic acid. Objective, Hart. 5. . 10.—Anterior extremity of the testis in another specimen, stained in picro-carmine. Objec- tive, Swift, 1 inch. . 11.—Anterior extremity of the testis iu another specimen. Objective, Hart, 5. . 12.—Small part of the edge of the testis near the posterior end. Objective, Hart. 7. . 13.—Opening of vas deferens close to ovary. Objective, Hart. 4. . 14.—Aperture of vas deferens. Objective, Hart. 7. VOL. XXXII. PART I. U it Vol. XXXII, Plate XVI. Ba anak Trans. Roy. Soc. Ed pease saa oe RFR a Seay F Huth, Inth® Edin® nm. Sp. TD ROUN Se, AEST Gea ie A Trans. Roy. Soc. Edin’ Vol. XXXII, Plate XVII. ‘Herdman del. ¥. Huth, Lith” Edin? EIGSI&2 ClONA INTESTINALIS, Linn. FIG? 3&4 ASCIDIA VIRGINEA var. PEDUNCULATA, FIG? 5&6 POLYCARPA POMARIA, Sav Trans. Roy. Soc. Edin™ Vol. XXXII, Plate KVIII. j ¥ Huth, lath? Edin® 1) 10) JE if fe) 1 WW hil SEN Te Wea Tu Mi Q.& C. Trans. Roy. Soc. Edin™ Vol. XXXII, Plate XIX. Lig. 8. eS S F Huth, Lith® Edin® a! . : DOLIOLU™M EON VAG OAT UM ee ec, rans Roy. Soc. Edin*™ Vol. XXXII, Plate XX. F Huth, Lith Baint Cetin 2) VIIL— Report on the Pennatulida dredged by H.M.S. “ Triton.” By A. MILNES Marsuatt, M.D., D.Sc., M.A., Fellow of St John’s College, Cambridge, Beyer Professor of Zoology in Owens College. (Plates XXI. to XXYV.) (Read 16th July 1883.) INTRODUCTION. The Pennatulida obtained by H.M.S. “Triton,” and placed in my hands for description, are of six genera only, each genus being represented by a single species. The interest of the collection is, however, far from commensurate with its size, for of the six species two are altogether new to science, a third has hitherto been met with only off the Norwegian coast, while concerning the remainder, which are well known species, the “Triton” specimens have furnished important additions to our knowledge, either of their anatomy or distribution. In arranging the species I have followed the system of classification pro- posed by KOLLIKER in his “ Report on the Pennatulida dredged by H.M.S. |*Challenger.’”* This scheme, though representing the latest results of our greatest authority on the group, cannot be considered altogether satisfactory, inasmuch as but very little attempt is made to express the mutual relations of the several groups, and highly specialised forms are mixed up with more primitive ones in a very confusing manner. I have, however, thought it better to adopt it here rather than attempt to frame a new scheme on inadequate material. The following outline of KOLLIKER’s classification shows the position occupied by the genera with which we are concerned :— Order PENNATULIDA. Section I. PENNATULEH: polyps fused together to form leaves. Sub-section 1. Penniformes: leaves well developed. Family 1. Pteroeidide. Family 2. Pennatulide. Genus Pennatula. Sub-section 2. Virgulariew : leaves small. Family 1. Virgularide. Genus Virgularia. Family 2. Stylatulide. Genus Diibenia. * Zool. Chall. Exp., part ii. pp. 38-35, 1880. VOL, XXXII, PART I. x 120 DR A. MILNES MARSHALL ON THE Section II. Sprcat#: no leaves ; polyps sessile. Sub-section 1. Funiculinew: polyps arranged in distinct rows. Family 1. Funiculinidee. Genus Puniculina. Family 2. Stachyptilidee. Family 3. Anthoptilide. Sub-section 2. Junciformes: polyps in single series or in indis- tinct rows. Family 1. Kophobelemnonide. Genus Kophobelemnon. Family 2. Umbellulide. Genus Umbellula. Family 3. Protocaulide. Family 4. Protoptilide. Section III. Renitte#: rachis expanded, in form of a leaf. Section IV. VERETILLE&: polyps arranged on rachis in radiate manner. — The following table shows the localities at which the specimens were obtained, the number taken at each, and the instrument employed in each case. — The specimens taken at Stations 6 and 7 do not belong to the “ Triton” collec- tion, but were dredged by the “ Knight Errant” in 1880 :— Station. Locality. ve Date. Name. Number. 6 | 59°37'N.,, 7°19 W. | 530 | Aug. 11, 1880 | Kophobelemnon 1 7 do. do. 530 | Aug. 12, 1880 Pennatula 1 8 | 60°18'N., 6°15’ W. 640 | Aug. 22, 1882) Kophobelemnon 2 10 | 59°40'N., 7°21’ W. 516 Aug. 24, 1882 ) 3 2 11 /59°29’30’N.,7°13'W.| 555 | Aug, 28, 1882 Pennatula 18 » 1 Virgularia 2 % 1 fragment Diibenia i Kophobelemnon 13 s 11 & 6 heads ; Umbellula 1 Sith ee \ 35-37 2 Funiculina 10 fragments Off Butt of Lewis, 40 > = Q g. 25, 1882 Pennatula 4 PENNATULIDA DREDGED BY H.M.S. ‘“‘ TRITON.” 121 Concerning the mode of capture, it will be seen from the above table that the trawl was distinctly more successful than the dredge; and the difference between the two is greater than appears from a mere comparison of the number of specimens taken, for the proportion of imperfect and mutilated specimens brought up by the dredge far exceeds that yielded by the trawl, the mutilation being in many cases clearly caused by the dredge itself. For such forms as Pennatulida the dredge is indeed a very unsuitable instrument of capture ; a point that deserves a greater amount of practical attention than it appears yet to have received.* It is certainly worthy of note that the three most interesting forms collected by the “Triton” were all _ brought up by the trawl. Concerning the nomenclature adopted, I have retained the terms polyp and zooid for the two kinds of individuals, sexual and asexual, of which a Pennatulid colony normally consists, since these names are in general use. Strictly speaking, the names are objectionable, for the term zooid is commonly and con- veniently employed in zoology to indicate any member of a colony that is produced asexually, and in this sense both kinds of individuals of the Penna- tulid colony are zootds. : For the tubular cavity into which the mouth leads, and which is commonly spoken of as the stomach, I have adopted the term stomodeum. ‘This cavity is | im no sense of the word entitled to the name of stomach, inasmuch as diges tion is effected, not in it, but in the body cavity into which it opens below. KOLLIker has proposed to call it cesophagus,t but the term stomodwum seems preferable, as indicating at once its origin by involution of the outer layer of the body or ectoderm. DESCRIPTION OF THE SPECIMENS. Order PENNATULIDA. Section I. PENNATULEA, Sub-section 1. Penniformes. Family 2. Pennatulide, Pennatula, L. ; Pennatula phosphorea, L. (Pl. XXI. figs. 4-7, and Pl. XXII. figs. 8-16.) | This species was obtained by the “Triton” at two localities, off the Butt of Lewis in 40 fathoms water, and at Station 11 at a depth of 555 fathoms. The collection also includes a single specimen obtained by the “Knight Errant” in “11980. * Cf. Nature. A new dredging implement, vol. xxvii. p. 11. } Koutixer, Anatomisch-systematische Beschreibung der Alcyonarien, p. 416, 1872. 122 DR A. MILNES MARSHALL ON THE Of this very variable species K6LLIKER distinguishes three well-marked varieties, characterised as follows :*— 1. Var. angustifolia: Leaves long and narrow; polyp heads few and wide apart. 2. Var. lancifolia: Leaves lancet-shaped ; polyp heads numerous, and close together. Of this form, which should probably be considered the typical P. phosphorea rather than a distinct variety, KOLLIkER further distinguishes four sub-varieties. 3. Var. aculeata: Leaves slender, and placed close together ; on the ventral surface of the rachis are four to six rows of long spines, connected with the zooids. Of the “ Triton” specimens those obtained off the Butt of Lewis belong to the second variety Jancifolia; while the more numerous specimens from the deeper water of Station 11 are typical examples of the variety aculeata. The two forms are so distinct that it will be well to describe them separately. P. phosphorea var. lancifolia, Koll. All four specimens are small, and of somewhat stunted appearance, the leaves being twisted in an irregular manner, so that sometimes the dorsal and sometimes the ventral border of the leaf is turned upwards. The four speci- mens, though of nearly the same absolute size and all obtained at one haul, differ a good deal among themselves as to the shape of the leaves and the breadth of their attachment to the rachis, and also as to the extent of separa- tion between the component polyps of a leaf. The zooids, which are uniform in size, cover the whole ventral surface of the rachis, except the mid-ventral eroove, and extending upwards between the leaves, become continuous with small groups of three or four zooids each situated on the dorso-lateral angles of the rachis between the leaves. In all four specimens the stalk, with the exception of the terminal dilatation, which is yellowish, is of a dark red colour, due, as in the rachis and leaves, to the calcareous spicules imbedded in it. In one specimen the colour is a deep purple of exceptional intensity. The measurements of the four specimens in millimétres are as follows :— A. B. C. D. Length of colony, i | 60 mm. 56 mm. 58 mm. 58 mm. . rachis, ; : a) 27 31 30 » stalk, : ; 28°5 29 27 28 leaves, ; ; 13 13 12 11°5 Greatest width of leaves, ; 2 2°5 3 3 No, of leaves on each side, ; 20 rail 22 20 » polyps per leaf, 3 10 9 9 10 * KOLLIKER, Anatomisch-systematische Beschreibung der Alcyonarien, pp. 130-134. — ee oa eee eee PENNATULIDA DREDGED BY H.M.S. ‘‘ TRITON.” 125 From these figures it will be seen that specimens A and B approach very closely K6OLLIKER’s variety angustifolia. P. phosphorea var. aculeata, Koll. (Pl. XXI. figs. 4-7, and Pl. XXII. figs. 8-16.) This very well-marked variety, which does not appear to have been hitherto recorded from British seas, is characterised by the long and slender shape of the leaves (Pl. XXI. figs. 4 and 5), the small number of their component polyps, their distance apart, and the extent to which they are separate from one another ; and above.all, by the fact that a number of the zooids of the veutral surface (figs. 4 and 5, f) are very exceptionally developed—assuming the form of conical spines, which project from the rachis for a distance in some speci- mens of 3°5 mm., or even more. This variety was first described in 1858 by Koren and DANIELSSEN,* who found it at a single locality near Christiansund, where it occurred rather abundantly on clay bottom at the depth of 80 to 100 fathoms. Since then it has been taken by Sars at Christiansund at a depth of 30 to 70 fathoms, and in the Throndhjemsfjord in 100 fathoms water; by CARPENTER and WYVILLE Tomson, during the “‘ Porcupine” expedition in the Atlantic Ocean, 48° 26’ N., 9° 44’ W., at a depth of 358 fathoms; and by Wurreaves in the Gulf of St Lawrence, at a depth of 160 to 200 fathoms. Of the “Triton” specimens of P. phosphorea, all those, 19 in number, obtained at Station 11, depth 555 fathoms, belong to this variety, as also does the single specimen from the “ Knight Errant” collection dredged at Station 7, in 530 fathoms water. As the variety is a very interesting one, and has not yet been satisfactorily described, I have taken the opportunity afforded by the large number of specimens available to investigate in some detail the more important structural details, directing my attention more particularly to the large ventral zooids. The following table gives the measurements of the single specimen from the “Knight Errant” and of two of the “Triton” specimens. All the latter are of small size, the specimen B being one of the largest. A. iE C. ‘ eee ‘ “Triton ” Collection. Length of colony, : : : 70 mm. 62 mm. 48 mm. A rachis, ; ; 3 31 28:5 24 x stalk, ‘ : : 39 33°5 24. » ., leaves (longest), . , 12 13 10 Greatest width of leaves, ; 4 3 1:5 1195; Number of pairs of leaves, . ; 19 14 10 Number of polyps per leaf, . ; Y 6 t Length of largest zooids, 5 ‘ 3 35 3 * Koren and Danretssen, Forhandlinger 7. Videnskabsselskabet 1. Christiania, p. 25, 1858 ; also Fauna Littoralis Norvegie, part iii. pp. 86-88, and pl. ii. figs. 8 and 9, Bergen, 1877. 124 DR A. MILNES MARSHALL ON THE KoreEN and DANIELSSEN, WHITEAVES and VERRILL, maintain the specific distinctness of this form from P. phosphorea. The measurements of the different specimens I have been able to examine show so great variability in the essential characters of the form, such as the length of the large zooids, width of leaves, &c., that I can have no hesitation in agreeing with KOLLIKER* in regarding it as merely a variety, though a very well-marked one. I cannot, however, accept Ricurarpi’st conclusion that it is not even a variety, “ma uno stato puramente accidentale di certi exemplari.” The general appearance of the form is shown in Pl. XXII. fig. 4, representing an entire specimen seen from the right side and twice the natural size. Fig. 5 is a transverse section through the rachis about the middle of its length, with one of the attached leaves and the base of the corresponding leaf of the opposite side. For the sake of comparison, I have given in fig. 6 a similar view of a normal specimen of P. phosphorea obtained from Oban. If these two figures be compared together, it will be seen that the points in which the variety aculeata (fig. 5) differs from the typical P. phosphorea (fig. 6) are the following :—The leaf is longer and much narrower; the polyps are fewer — in number, are placed further apart, and are independent of one another for a greater portion of their length. The walls of the rachis are much thicker, a condition associated with the presence of larger and more numerous spicules ; the axial calcareous stem is thicker, and the main longitudinal canals of the rachis much smaller than in the typical form. Concerning the zooids, it will be seen that a very large one (fig. 6, f) arises from the rachis immediately below — each leaf, with the ventral border of which it is fused for about a third of its — length. Nearer the mid-ventral line of the rachis there is on each side a second _ row of large zooids, usually slightly smaller than those of the outer row, but sometimes equalling them in size; and within these again other zooids occur intermediate in size between the large ones and the normal small ones, The largest zooids, those attached to the ventral borders of the leaves, have an average length of rather over 3 mm. in the “Triton” specimens; in exceptional cases they reach 4 mm. Between the large zooids are numerous small ones of the normal size and character, which extend up the sides of the rachis between the bases of the leaves. That the connection of the large ventral zooids with the leaves is of a purely secondary nature is clearly seen by tracing their gradual development in passing. upwards from the lower end of the rachis. At their first appearance they — are small, identical in all respects with the normal zooids, and quite inde- * KOLLIKER, Op. cit., pp. 134 and 366. ¢ Ricutarpi, Monografia della famiglia dei Pennatularii, p. 24. PENNATULIDA DREDGED BY H.M.S. “TRITON.” 125 pendent of the leaves, with which they become connate a) after they have attamed a considerable size. The structure of the large zooids, which does not appear to have been examined with any care hitherto, is shown in the series of figures on Plate XXII. Of these fig. 8 represents a median longitudinal section through the whole length of one of the zooids, and through the part of the rachis from which it springs ; while figs. 10 to 16 are transverse sections through a zooid at different parts of its length, fig. 10 being near to the apex and fig. 16 passing pater the base of attachment of the zooid. The general anatomy of the large zooid is well shown in fig. 8, from which it will be seen that while agreeing in essential structure with the smaller and more typical zooids, it yet presents some points of special interest. The zooid is conical in shape, arising by a broad base from the rachis and tapering upwards rather sharply, ending in a pointed apex. As shown in figs. 4 and 8 the zooid does not project horizontally outwards, but obliquely upwards, so that we can distinguish between an inner or axial surface, directed toward the rachis, and an outer or abaxial surface facing outwards. On the inner or axial surface, and nearer the base than the apex of the zooid, is the mouth (fig. 8, 2). This leads into the stomodzum s, which is lined by columnar ciliated ectoderm cells, the cilia clothing the outer or abaxial wall being of very great length, and forming with the surface of the stomodeum from which they arise the structure which Mr Hickson has recently proposed to speak of as the siphonoglyphe.* The stomodzeum opens below into the general body cavity h, which is lined by endoderm, and is in communication with the cavities of the adjacent zooids and with.the main lateral canals of the rachis, and so indirectly with the polyps. The stomodéeum is attached to the body wall by the usual eight septa, which are well shown in the transverse section (fig. 15). Below the stomodeum the two septa of the inner or axial surface, bounding the axial] interseptal cavity, remain of considerable width, and bear at their free edges the two mesenterial filaments (figs. 8 and 16, p), which are very long and much convoluted, and extend down to the bottom of the zooid cavity. The other six septa become reduced immediately below the stomodzeum to very narrow ridges (fig. 16, m), which disappear altogether a short way lower down. The body wall of the zooid consists of an outer layer of short columnar ecto- derm cells, below which is the firm gelatinous mesoderm. This latter is much thicker on the outer or abaxial surface than it is on the inner or axial, and is strengthened by a great number of large calcareous spicules (figs. 8-16, 4). These spicules are straight rods, thickest in the middle, and with rounded ends ; * Hickson, on the “Ciliated Groove (Siphonoglyphe) in the Stomodzeum of the Aleyonarians,” Proc. Roy. Soc., 1883. 126 DR A. MILNES MARSHALL ON THE the largest attain a length of 1:6 mm., with a width of ‘13 mm. In transverse section (figs. 10-16, 7) the spicules are triangular, with rounded angles, and a shallow groove running somewhat obliquely down the middle of each face. They are exceedingly numerous along the whole length of the abaxial surface of the zooid, and are arranged with their long axes parallel, or nearly so, to that of the zooid. The mesoderm is traversed by a system of irregularly branching nutrient canals continuous with those of the rachis. The muscular system of the body wall of the zooid seems to be completely absent. The relations of the inter-septal chambers in the part of the zooid above the stomodzeum are rather curious. Fig. 14 represents a transverse section through the mouth opening; it shows that at this point only five of the eight inter- septal chambers are present, viz., the abaxial, or as it is commonly called, ventral cavity, the two latero-ventral cavities bounding it on either side, and the two lateral cavities; the axial or dorsal and the two latero-dorsal cavities not extending above the mouth. In a section taken a little higher up, through the upper part of the mouth (fig. 13), the two lateral cavities have dis-— appeared, and the mid-ventral and latero-ventral cavities are alone present. Tracing them further up towards the apex of the zooid, we find that all three persist for some distance, but that after a time the middle abaxial or ventral cavity, which has been from the start the smallest (cf figs. 15 and 14), loses its lumen (fig. 12), and then disappears altogether, the two latero-ventral cavities alone persisting (fig. 11). Further up still (fig. 10), one of the two latero-ventral cavities disappears and one alone is left, which can be traced nearly, or in some cases quite, up to the apex of the zooid. The prolongations upwards of the interseptal chambers above the mouth — correspond, not to the tentacular cavities of the fully formed polyps, but to the cavities of the calyx processes ; and the whole of the part of the large zooid above the mouth is to be regarded as formed by a special unilateral development of the calyx, corresponding at its base to five, and along the greater part of its length to three calyx processes fused together, but with their axial cavities remaining distinct. That the spine of the large zooid really consists of calyx processes and not of tentacles, is, I think, proved by the perfect continuity between the wall of — the zooid itself and the spine; by the unbroken series of exceptionally large spicules extending along the abaxial wall of the whole length of the zooid, including the spine ; and by the absolute identity between a transverse section across the upper part of the spine, and one through a calyx process of a normal polyp. This latter point is well shown in figs. 9 and 10, the former being a section of a calyx process, and the latter of the spine of one of the large zooids. — ‘ ‘ PENNATULIDA DREDGED BY H.M.S. “TRITON.” 127 The agreement will be seen to be absolute, even as regards the actual size and arrangement of the spicules, which in both cases are far larger and more abundant on the abaxial or outer surface than on the axial or inner one. It is also worthy of note, in connection with the point in question, that in the development of the polyps the calyx processes appear earlier than the tentacles (vide fig. 7). | The large zooids of P. phosphorea var. aculeata agree, therefore, with the zooids of Pennatulida generally in the complete absence of tentacles, as well as in the absence of reproductive organs and the possession of but two mesenterial filaments. They are peculiar merely in their very great absolute size, and in the prolongation of the abaxial surface to form the spine. The structure of one of the normal small zooids is shown in fig. 8, ¢. It will be noticed that here also the mouth, which in the early stages of development is terminal (as shown in the rudimentary zooid between ¢ and the large zooid), becomes thrown over to the axial surface by growth forwards of the abaxial side, which forms a prominence above the mouth clearly comparable to the spine of the larger zooids. The figure shows also that the smaller zooids, like the large ones, possess the clothing of exceptionally long cilia on the abaxial surface of the stomodzeum (siphonoglyphe of Hickson). The small zooid in question (fig. 8, ¢) is an immature one, as there i is as yet no communication between the stomodzum and the body cavity of the zooid; the septa and mesenterial filaments have also not yet appeared. PANCERI™ has described and figured an interesting abnormality occurring in a specimen of P. phosphorea, in which four of the latero-ventral zooids, three on the left side of the rachis and one on the right, have the form and structure of fully developed polyps, inserted independently into the rachis, and attaining a length of 10 mm. and a diameter of 1 to 2 mm. In describing this curious modification, Panceri discusses briefly the mutual relations of polyps and zooids, points out the fundamental and essential correspondence between the two, and infers that the zooids must be regarded as abortive polyps, and that such cases as the one he describes are to be viewed as examples of reversion from the abortive to the fully developed condition. | In this view Panceri is undoubtedly right. In a colony of individuals formed by continuous gemmation, 7.¢., by a process of budding in which the several zooids remain organically connected together to form the colony, the several component individuals must be supposed to be primitively all alike and jequivalent to one another. Differences in structure and function could clearly only have arisen after the habit of forming colonies had been established for some time. Hence those colonies will be the most primitive in which there is * Pancerl, “Intorno ad una forma non per anco notata negli zooidi delle pennatule,” Rendiconto dell Academia delle scienze fisiche € matematiche, pp. 23-28, Napoli, Febbrajo, 1870. VOL. XXXII. PART I, i 128 DR A. MILNES MARSHALL ON THE. in the adult form the smallest amount of difference between the constituent individuals ; while those forms in which this differentiation reaches its greatest development will be the most highly modified forms. These principles are of great importance in framing a scheme of classification of a colonial group such as the Pennatulida, and have not received sufficient attention in the classifica- tion at present in use. - | In the ordinary P. phosphoreathe amount of differentiation is comparatively slight, and is brought about in the simplest possible manner ; the asexual zooids being simply arrested at what is merely an early stage of development in the case of the polyps. This is well shown in Pl. XXI. fig. 7, representing a side view of the lower end of the rachis, and showing the early stages of development of the polyps and zooids. The figure shows that the young polyps d are at first quite independent of one another, and that in their earlier stages they are absolutely identical with the zooids ¢; and that the differences arise from the zooids becoming arrested at this early stage, while the polyps advance further, increase in size, acquire calyx processes /, and tentacles ¢, fuse with one another at their bases, so that their further increase in length gives rise to the leaf of the adult, and acquire the full number of mesenterial filaments, and ultimately reproductive organs.’ — The differentiation is thus of the simplest possible character, the zooids being simply arrested or abortive polyps, whose function is apparently to main- tain currents of water circulating throughout the colony, for which purpose they have retained the sole structure peculiar to them—the clothing of exceptionally strong cilia on the abaxial surface of the stomodeum. As the siphonoglyphe is present in the mature polyps of many Alcyonarians, such as Alcyonium (vide Hickson, loc. cit.), it seems certain that in the Pennatulida it is a structure that has been lost by the polyps, but retained by the zooids. In the variety aculeata differentiation has advanced further; and it is a point of importance to note that the points in which the large zooids differ from the small ones cannot be considered as repetitions of any part of the process by which the polyp is developed from the zooid condition. In the young polyp all the calyx processes arise simultaneously (fig. 7), as do also all the tentacles, so that the asymmetrical development of the calyx in the large zooids must be regarded as peculiar to and acquired by them. ‘The lateral position of the mouth in the large zooids has apparently been acquired inde- pendently of and previous to the formation of the calycular spine, inasmuch as it is an equally prominent feature in the normal small zooids (fig. 8, ¢). Judging from their structure, the large zooids would seem to be protective — in function, but as to the special circumstances which determine their develop- ment in particular forms, we are in complete ignorance. Were our knowledge confined, so far as these forms are concerned, to the “ Triton” specimens, we “ PENNATULIDA DREDGED BY H.M.S. “ TRITON.” 129 should be greatly tempted to suppose that as one set of specimens—the typical P. phosphorea—is obtained from a depth of only 40 fathoms, and the other, _the variety aculeata, from 555 fathoms, that the structural differences between the two forms may be at any rate in part due to the different external condi- tions of pressure, &c. Although, however, the variety aculeata does appear to occur as a rule in deeper water than the more normal form, yet this rule is not universal, for, as we have seen above,* Sars obtained specimens of aculeata off the Norwegian coast at depths of 30 to 70 fathoms. The determining cause therefore that leads to the production of the variety aculeaia must be some other than mere depth, though this would appear to have some influence. It may be noticed, finally, that the vertical range of P. phosphorea, which K6LLIKERt puts at 30 to 300 fathoms, has been nearly doubled by the “ Triton” dredgings, which show that the species lives in abundance, though in a rather diminutive form, as low as 555 fathoms. Sub-section 2. Virgulariee. Family 1. Virgularide. Virgularia, Lam. Virgularia tuberculata, n. sp. (PI. XXI. figs. 1-3.) Specific Characters.—Polyps nearly sessile, united at bases in groups of three, the groups alternating on the two sides of the rachis. Calyx completely obliterated when the polyp is fully protruded ; calyx margin marked by eight small tubercular processes placed opposite the tentacles. Reproductive organs in the immature leaves at the lower part of the rachis. Stem cylindrical. Colour of colony, yellowish-white. No calcareous spicules in any part. Habitat.—Station 11. Of this species three specimens were obtained, all of which are imperfect. The largest specimen (Pl. XXI. fig. 1) measures 68 mm. in length, and consists of the stalk and lower part of the rachis ; its upper end is abruptly truncated, and the upper 10 mm. of the stem are denuded of the fleshy sarcosoma. The second specimen is similar to the first, but smaller in all its dimensions ; it has a total length of 36-4 mm., and consists of the stalk and lower end of rachis, the upper end of which is abruptly truncated. The third specimen is 46 mm. long, and consists of the middle portion of the rachis of an apparently rather larger specimen than either of the other two ; truncated at both ends. * Supra, p. 123. t Zool. Chall. Hxp., part ii. p. 38, 1880. 130 DR A. MILNES MARSHALL ON THE The stalk of the first specimen (Pl. XXI. fig. 18) is cylindrical, with an average diameter of 2:1 mm. It presents a slight terminal dilatation at its lower end, and is marked on both dorsal and ventral surfaces by shallow median longitudinal grooves. The stalk has a length of 15 mm., and is continuous above with the rachis, the transition from one to the other being marked by the first appearance of the leaves. The lower part of the rachis is flattened dorso-ventrally, and has a transverse diameter of 26 mm. It is marked by upward continuations of the median dorsal and ventral grooves of the stalk. As we pass from the region with immature leaves to the part of the rachis bearing fully developed polyps, the rachis gradually becomes reduced in width, and in the upper part, where the polyps have attained their full size, it becomes cylindrical, with a diameter in the first specimen of 0°5 mm., forming in fact a very thin fleshy investment to the stem. The stem is cylindrical at its upper end, with a diameter of 0-4 mm.; it remains of nearly uniform size throughout the whole length of the rachis, but tapers gradually as it passes down the stalk. It is of considerable brittleness, especially in its upper part. The polyps commence in the lower part of the rachis as small transverse ridges placed very close together, the first 6 mm. of the rachis having 20 of these ridges on each side. Passing upwards, the ridges become more pro- minent, wider, and situated further apart, each being divided at its free edge into three polyps. Of the three polyps of a ridge, the dorsal one is from the start the smallest of the three, and the ventral one the largest; and these proportions are retained throughout. As the polyps get larger, the groups move further and further apart, until the interval between successive groups on the same side of the rachis is about 3 mm., which appears to be the limiting distance. The ridges on the lower part of the rachis are so placed that while the dorsal polyps of the ridges of the two sides are almost in contact with one another in the mid-dorsal line, the ventral polyps are separated from one another by nearly the whole width of the ventral surface of the rachis, an arrangement which persists also in the fully formed polyps (fig. 2). . The groups of polyps are from the first placed, not opposite one another, but alternately, as shown in figs. 1 and 2, the right hand group being a little in advance of the left one. The polyps of each fully developed group are almost completely independent of one another, their bases alone being united together, so that it is hardly possible to speak of distinct leaves. The inclusion of the species in the genus Virgularia is fully justified, however, by the general mode of development of \ PENNATULIDA DREDGED BY H.M.S. ‘“‘ TRITON.” 131 the polyps, especially the simultaneous appearance of the component polyps of a group ; by the position of the reproductive organs in the immature polyps, the proportions of the stem at different heights, and by the existence of such forms as Virgularia bromleyi* in which the separation of the polyps is not carried quite so far as in V. tuberculata. From V. bromleyt, the new species is distinguished at once by the absence of calcareous spicules, and the presence of the tubercles marking the calyx margin. Concerning the development of the polyps, it can be ascertained by examina- tion of the immature polyps at the lower end of the rachis, that the stomodeum arises as usual as an involution of the ectoderm, appearing before the tentacles, which latter all develop simultaneously. In the early stages of development one tentacle is very commonly rather larger than the other seven, but whether this is an accidental feature or not I have been unable to determine, nor have I detected any constancy of position of the larger tentacle. In each group the ventral polyp is always the furthest developed, and the dorsal one the least so. In the smaller of the two specimens in which the stalk is perfect, the change from the immature to the fully developed polyps is a very abrupt one ; not gradual asin the larger specimen figured (Pl. XXI. fig. 1). The stalk in this smaller specimen is 8 mm. long; the first 4 mm. of the rachis bear immature leaves only, and above this point the fully formed polyps commence abruptly. The fully expanded polyp (fig. 2) measures about 2°5 mm. in length, of which the tentacles form rather more than half; its width is about 0°2 mm. Opposite the insertion of the polyp, and for some little distance above and below it, the sarcosoma of the rachis is markedly thickened (fig. 2), giving the rachis at these places a quadrangular shape. The boundary line between the body of the polyp and the tentacles is indicated in the fully expanded polyp by a row of eight small knob-like processes placed opposite the tentacles (fig. 2). _ These processes are hollow, and consist of all three layers of the body wall— ectoderm, mesoderm, and endoderm ; they appear to correspond to the calyx processes of other Pennatulida. When the polyp is retracted, as in the lower specimens of fig. 2, these pro- cesses mark the line of invagination, and become much more conspicuous, appearing as knobs placed round the edge of the calyx. In the “ Triton” specimens, retraction of the polyp is never carried further than is shown in fig. 2, the fully retracted polyp being about half the length of the fully expanded one. Retraction is probably effected slowly, as the great majority of polyps have died in an almost completely expanded state. The tentacles are rather longer than the body of the polyp; are pinnated as shown in fig. 2, and present no special features of importance. * KoiiiKer, Zool, Chall. Exp., part ii. p. 9, 1880. 132 = DR:A. MILNES MARSHALL ON THE . The anatomy of the polyp, so far as I have had the chance of investigating it, agrees with that of other Virgulariw. The reproductive organs, as in Virgularie generally, are contained, not in the mature polyps, but in the im- mature ones at the lower end of the rachis. The large specimen (fig. 1) is a male, and a small part of the rachis removed from a point 22 mm. from the lower end of the stalk, showed the mature male organs or spermatospheres. These (fig. 3) have the typical structure of the male organs of Pennatulids. They are oval or spherical bodies, the largest of which have a diameter of 0°38 mm.° Each is enclosed in a very thin capsule, the contents of which are a mass of very minute brightly refracting bodies—the heads of the spermatozoa; these are more closely packed at the periphery than in the centre, where a number of fine radiating filaments can be seen, which are probably the spermatozoa tails. The smaller specimen, in which the lower end of the rachis is present, was also examined for reproductive organs, but none were found. The third specimen, consisting of the middle part alone of the rachis, is of course devoid of reproductive organs. This specialisation of the reproductive organs to the immature polyps is undoubtedly a sign of considerable differentiation, and marks Virgularia as a less primitive genus than such a form as Pennatula. For while in the latter the component individuals of the colony are of two kinds only—zooids and polyps—in Virgularia they are of three kinds—zooids, nutrient individuals, and reproductive individuals. Whether all the immature polyps ultimately develop into mature ones is uncertain ; probably not, inasmuch as all recorded specimens of Virgularia have immature polyps at the lower end of the rachis. The abrupt transition from the immature to the mature polyps described above as. occurring in the second example of V. twberculata, may perhaps indicate the existence of a sharp line of demarcation between the sexual and the nutrient individuals. Whether zooids are present or not in V. tuberculata, I ee been unable to determine with certainty without destroying the specimens. Certain very small knob-like projections on the rachis near the base of the polyps may perhaps prove to be zooids ; if so, they are in an exceedingly rudimentary condition. As noticed above, all three specimens of V. twberculata are imperfect, and their imperfection is of some interest, inasmuch as it is very characteristic of dredged specimens of Virgularia generally. Of the type species, V. mirabilis, a perfect specimen has never yet been seen, all the specimens recorded being fractured either at one or bothends. The lower ends or stalks are occasionally found perfect, but the upper end never, the only known exception being a single specimen in the Glasgow Museum. The cause of this mutilation has been elsewhere discussed. It has been ‘ PENNATULIDA DREDGED BY H.M.S. “ TRITON.” 133 suggested * that the lower fracture, which usually occurs about the junction of stalk and rachis, 7.¢., about the point of emergence from the mud of the sea’ bottom, is caused by the dredge at the moment of capture; while the upper fracture is almost certainly effected quite independently of the dredge, and is perhaps due to the tops being browsed on as food by other animals. The great brittleness of the calcareous stem probably accounts for the readiness with which the specimens become broken, and the fact that of the three specimens of V. tuberculata, the one brought up by the dredge is broken at both ends, while the two taken with the trawl have their lower ends entire, speaks strongly in favour of the correctness of the first part of the above explanation. - The measurements of the three specimens are as follows :— A. 3 C. Upper end imperfect. Upper end imperfect. Both ends lost. Total length, are ; ; 68 mm, 36°4 min. 46 mm, Rachis, . : - : 53 28°4 46 Stalk, . : 5 : 15 8 ole Diameter of rachis, ; » Oia tor26 0:4 to 2:1 0°52 = stalk, : ; 21 It 3 e stem, ‘ : 0°4 0°38 0:4 No. of polyps per leaf, . ; 3 3 3 Length of polyp, ; 8 Eel + tentacle, ; iL ne 1-4 Distance of polyps apart (greatest), 3 8g 31, Diameter of spermatospheres, 0:38 Family 2. Stylatulide. Diibemia, Kor. and Dan. Diibenia abyssicola var. smaragdina (Kor. and Dan.). (Pl. XXIIT. figs. 17-21.) A single fragment of this species was obtained from Station 11 at a depth of 555 fathoms. The specimen, which is imperfect at both ends, and has a total length of 61 mm., is represented from the ventral surface three times the natural size in Pl. XXIII. fig. 17; while figs. 18 and 19 represent on a larger scale portions of the rachis as seen from the lateral and dorsal surfaces respectively. Inasmuch as the sole description that has yet appeared of this very beautiful form is the extremely short and imperfect account given by Koren and DANIELSSEN,+ I have thought it well to investigate and describe the “Triton ” specimen as fully as could be done without injury to it. The rachis (figs. 17, 18, and 19) is cylindrical, and only slightly exceeds in diameter the cylindrical stem by which it is traversed throughout its length. At the upper end of the specimen the stem projects bare for a length of about * Vide Report on the Oban Pennatulida, by A. M. Marshall and W. P. Marshall, 1882, pp. 57-60. + Fauna littoralis Norvegic, part iii. p. 26, and pl. x. figs, 7 and 8, 1877. 134 DR A. MILNES MARSHALL ON THE 3 mm. above the uppermost polyps, ending in an abruptly truncated and evidently broken extremity. At the lower end the fracture appears to have occurred about the junction of stalk and rachis, but the fleshy sarcosoma has been stripped off the lowermost 8 mm., leaving this part of the stem bare, and rendering it impossible to localise exactly the seat of fracture. The stem is quite as brittle as that of Virgularia, so that there can be little doubt that the cause of fracture is the same in the two cases. The entire specimen is of a pale yellowish-white colour, but has become a good deal discoloured in parts, apparently from the action of the spirit in which it was preserved. The polyps (figs. 17, 18, and 19) are arranged in pairs along the sides of the rachis, each pair being embraced at its base by the fan-shaped plate of cal- careous spicules 4, so characteristic of the family Stylatulide. The pairs of polyps are not inserted opposite one another, nor do they strictly alternate’; but those of the left side are situated a little further forward, nearer the upper end of the rachis, than the corresponding pairs of the right side. The intervals between successive pairs of polyps on the same side of the rachis (fig. 17) gradually increase in passing upwards. At the lower end of the specimen the successive pairs are almost in contact with one another, but in passing upwards they move further and further apart, the intervals attaining a maximum a short way below the upper end of the specimen, above which point they decrease slightly, the polyps themselves also becoming smaller. The characters and relations of the fan-shaped spicular plates are well shown in figs. 18 and 19. Each plate is triangular, with the apex directed downwards and inserted into the rachis, and with its free upper edge surrounding the ‘base of the pair of polyps to which it belongs. The plate is formed by the fusion of a number of radiately arranged spicules, of which the more deeply placed ones are smaller and completely fused together, while some of the more superficial ones are much larger, and not so closely fused. One of these large spicules is represented in fig. 21; it is widest near its lower end, and gradually tapers upwards to a point, which (figs. 18 and 19) projects freely for a short distance above the upper edge of the plate. These large spicules may attain a length of 2°3 mm. and width of 0-15 mm. From the apex of the spicular plate a number of smaller rod-like spicules (fig. 18) are continued for a variable distance down the rachis. The two polyps of each pair have their bases, which are covered by the spicular plate, fused together so as to form a rudimentary leaf. Above the level of the top of the spicular plate they are, however, completely free from one another. Of the two polyps, the dorsal one is always slightly smaller than the ventral one in accordance with the general rule among Pennatulida. The dorsal polyps of corresponding pairs are separated from one another by but a \ PENNATULIDA DREDGED BY H.M.S. “ TRITON.” 135 slight interval (fig. 19), while the ventral polyps are separated by the whole width of the ventral surface of the rachis. The polyps are retractile, and the extremes of contraction and expansion are represented in the two polyps of the upper pair in fig. 18. As the figure shows there is no calyx formed during retraction, and the tentacles appear to contract to a less extent than the bodies of the polyps. As in the case of Virgularia tuberculata, the fact that the majority of the polyps have died in an expanded or half-expanded condition may be taken as evidence that contraction is effected slowly. Each tentacle is supported on its outer or aboral surface by a strong rib of calcareous spicules shown on a larger scale in fig. 20. These spicules are placed for the most part obliquely, running upwards and outwards; they have an average length of 0°13 mm. and diameter of 0°02 mm. They do not extend into the pinnules. At intervals along the body walls of the polyps spicules are found similar to those of the rachis, but rather smaller and less abundant. Concerning the reproductive organs I have no observations. According to Koren and DAniELssEN,* these are normally situated in the body cavities of the fully developed polyps in the genus Diibenia ; but a large polyp from the middle of the colony, which I opened for the purpose, had no trace of reproductive organs. The zooids are few in number, and very small and inconspicuous. They occur (fig. 19, e) as small rounded swellings on the dorsal surface between the pairs of polyps, and also on the sides of the rachis just above the polyps. The genus Diibenia was established by Koren and DANIELSSEN in 1874,t and was at first named Batea, but that name being already appropriated for a genus of Crustacea, it was changed in 1877 to Diibenia. It includes those members of the family Stylatulide in which the polyps, though fused at their bases, do not form distinct leaves, the fusion not extending above the calcareous fan- shaped spicular plate. The validity of the genus has been questioned by VERRILL and by RicuiArp1, but is accepted by K6LLIKER in his Report on the “ Challenger” Pennatulida, and may be considered as established. The “Triton” specimen has all the characters of Diibenia abyssicola vay. smaragdina, as defined by Koren and DANiELssEN.[ This variety differs from the typical D. abyssicola in its more slender form, in its pale colour, and in having the polyps in groups of two instead of three or more. KoreEN and DANIELSSEN express a doubt as to whether it should not be considered a distinct species rather than a mere variety, a doubt which I must share without * Op cit., p. 24. + Magazin for Naturvidenskaberne, 1874. { Koren and Dantetssen, Fauna littoralis Norvegic, part iii. p 96, 1877. VOL. XXXII, PART I, Z 136 DR A. MILNES MARSHALL ON THE attempting to remove, as I have had no opportunity of ae specimens of the typical D. abyssicola. The variety smaragdina has hitherto only been recorded from the Rams- fjord close to Alveerstrémmen, two miles from Bergen, where it was found “at a depth of 100 to 120 fathoms on a clayey sand bottom,” in company with the typical D. abyssicola, but in smaller numbers. The measurements of the “ Triton” specimen are as follows, those of two specimens described by Koren and DANIELSSEN being given for the sake of comparison :— A. B. C. 2 phat aes aa Swedish specimens, entire. Total length, ; ; 3 61 mm. 268 mm. 200 mm. Rachis, . : : : : : 61 197 148 Stalk, . ; : . absent fell 62 No. of pairs of alae : ; : 34 54 44 Diameter of rachis, : : ; 0:36 . oe Diameter of stem (at top), : , 0°32 Length of fully expanded polyp, _.. 4:5 tentacle, . 2-4 Length of retiectal polyp (incl. tentacle), 2 - Size of large spicules of calyx, ; 2°3 x 0:15 tentacle, . 0:13 x 0:02 Size of See of body wall of polyp, 0°56 Section IT. Sprcata. Sub-section 1. Funiculinee. Family 1. Funiculinide. Funiculina, Lam. Funiculina quadrangularis, Pall. (Pl. XXIII. fig. 22.) Ten fragments of this species were obtained by the “Triton” in Loch Linnhe, off Castle Walker, in 35 to 37 fathoms of water, and at a distance of 31 miles from the shore. All the specimens are small and imperfect. Two of them, of 9:4 and 12°5 cm, length respectively, have the stalks perfect, and are broken short above at the lower part of the rachis. The remainder are all mere fragments broken at both ends, and varying in length from 5 to 34 cm.. None of the specimens have the upper ends perfect, a very unusual circum- stance with this species, which is usually obtained in perfect condition. The specimens have, however, evidently been roughly handled, and were probably — damaged at the time of capture. ‘ PENNATULIDA DREDGED BY H.M.S, “ TRITON.” 137 All the fragments belong to small and young specimens. Inasmuch as F. quadrangularis is found at other parts of Loch Linnhe in great profusion and of large size, specimens having been obtained up to 162 cm. in length, it would appear that the locality from which the “Triton” specimens were obtained is not one favourable to this species. The portion of rachis of one of the young specimens drawn in fig. 22 shows some points of interest. In the first place, it will be noticed that the calcareous spicules, which in F. quadrangularis are usually confined to the calyx, here extend down the whole length of the polyps along the lines of attachment of the septa. These spicules, which also occur in the rachis, though in smaller numbers, have an average length of 17 mm. The unusual abundance of these spicules, and their presence in such young specimens, are points of interest. The middle polyp of the figure is shown in a condition of extreme contrac- tion ; the tentacles being completely withdrawn within the calyx, the processes of which meet one another so as to form an acutely pointed cone. This figure agrees very closely with one given by K6LLIkERr,* the accuracy of which has been doubted, owing to the shape being so very unlike that of the expanded or half- expanded polyp, and the apparently exaggerated length of the calyx processes. Fig. 22 shows also the gradual increase in size of the polyps in passing from the dorsal (right-hand surface in the figure) to the lateral surface ; also the entirely independent insertion of polyps and zooids—a primitive feature ; and the total absence of distinction between the young polyps and the zooids ; also the quadrangular shape of the stem. Sub-section 2. Junciformes. Family 1. Kophobelemnonide. Kophobelemnon, Asbjornsen. Kophobelemnon stelliferum var. durum (Koll). (Pl. XXIV. figs. 23-28.) Thirty-three entire specimens of this species and seven heads (the upper polyp-bearing part of the rachis) were obtained, one of these being from the “Knight Errant” collection, the remainder from the “Triton” one. They were dredged at four different localities, Stations 6, 8, 10, and 11, and at depths varying from 516 to 640 fathoms. K. stelliferum was first found by O. F. MULLER in 1775, near Droébak, in the Christianiafjord, and described by him in the Zoologia Danica, under the name Pennatula stellifera. It has been dredged in various parts of the Christiania fjord by Loven and by Aspsornsen,t the latter of whom obtained it in con- * KouurKer, op. cit., pl. xvii. fig. 153. 7 AspsérnsEN, “ Beskrivelse over Kophobelemnon Miilleri,” Fauna littoralis Norvegie, Andet Hefte, pp. 81-85, and Tab, 10, figs. 1-8, 1856. 138 DR A. MILNES MARSHALL ON THE siderable numbers at a depth of about 40 fathoms, and of sizes varying from 20 mm. long, with only a single polyp, to 125 mm. long, with 24 polyps. A single specimen was obtained by PAnceri from the Bay of Naples,* and during the “‘ Porcupine ” expedition two specimens were obtained by CARPENTER and WYVILLE THomsont off the N.W. coast of Scotland,—one in 59° 41’ N., and 70° 34’ W., at a depth of 458 fathoms, the other in 59° 34’ N., and 7° 18 W., and at 542 fathoms depth. External Characters.—The “ Triton” specimens vary much in size, and in the number and arrangement of the polyps. The smallest specimen is 26 mm. long, and has only two polyps; the largest specimen in the collection, the single specimen obtained by the “ Knight Errant,” is 88 mm. long, and bears 18 polyps. The general appearance of one of the average specimens of the “ Triton” collection is well shown in Pl. XXIV. fig. 23; the specimen being drawn from the dorsal surface, double the natural size. The rachis, which is somewhat club-shaped, is widest a short distance below its upper end, from which point it tapers upwards to a blunt point. It bears on its dorsal and lateral surfaces the polyps, which are few in number, and of large size. Between the polyps the surface of the rachis is studded on all sides with zooids, excepting a short tract immediately below each of the polyps, which is destitute of zooids. The stalk (fig. 23, >), which forms rather more than half the entire length of the colony, and which is distinguished from the rachis by bearing no zooids, is oval in section, as shown in fig. 27, and of tolerably uniform size along its whole length, except at its lower end, which presents a terminal thin-walled dilatation. The arrangement of the polyps differs a good deal in different specimens, and it is difficult to make out any definite system. In all cases the uppermost polyps, those nearest the top of the rachis, are the largest, and the lowest ones the smallest. The most usuai arrangement is that shown in fig. 23. Here there are six fully developed polyps arranged in two sets, an upper and a lower one, each of three polyps. Of these three, one is inserted in the dorsal surface of the rachis very close to the mid-dorsal line, or actually in it, while the other two are inserted on the sides of the rachis a little way below the dorsal polyp, and not quite opposite one another, the right hand polyp being as a rule a little above the left hand one. The three polyps of each set are of about equal size, but those of the upper set are much larger than those of the lower set. Below the lower set can be seen in many specimens, as in the one figured, a third set of * Panceri, “Intorno a due Pennatularii l’uno non per anco trovato nel Mediterraneo, Valtro nuovo del nostro golfo,” Rendiconto dell’ Academia delle scienze fisiche @ matematiche, Napoli, Giugno, 1871. t, Vide Koutixer, op. cit., p. 306. PENNATULIDA DREDGED BY H.M.S. ‘“ TRITON.” 139 very small and as yet rudimentary polyps, arranged in a manner exactly corre- sponding to the upper sets. It is clear that this arrangement might also be described by saying that the polyps are arranged in three longitudinal series, one dorsal and two lateral, the members of each series decreasing in size from above downwards, and this is indeed the method usually adopted. I am disposed, however, to prefer the former mode of description, because it seems to me from an examination of a number of specimens, that the three polyps of each set arise simultaneously, or very nearly so, the dorsal polyps being often a little ahead of the lateral ones, and the right lateral polyps appearing sometimes a little earlier than the left ones. There appears, indeed, to be a fair amount of constancy in the arrangement and order of appearance of the polyps. Of twelve specimens, four had 3 polyps only, which were clearly the three of the upper set ; five had 6 polyps arranged as in fig. 23 ; one had 4 polyps, 7.¢., the 3 of the upper set and the second dorsal one ; and the other two had 4 and 5 polyps respectively arranged in an irregular manner. In specimens with a larger number of polyps than six, it is very difficult to make out any definite plan of arrangement. Structure of Polyps.—This has been very fully described by KOLLIKER,* and will not be considered here in any detail. The main points are shown in the figures 24 to 28. The mesoderm is everywhere, both in stalk, rachis, and polyps, of considerable thickness, and has an immense number of calcareous spicules imbedded in it (figs. 27, 28). Each tentacle (figs. 24 and 25) has along its outer surface a prominent rib, made up of closely packed spicules, while smaller ones extend along the pinnules, as first noticed by PANCERI. The spicules of the tentacular rib, which may attain a size of 0°66 by 0-11 mm., are of the shape shown in fig. 26, and in transverse section in fig. 25. The polyps project from the rachis nearly at right angles, as shown in fig. 23, and the polyp cavities on reaching the rachis do not stop, but bending down at right angles to their former course, are continued for some distance down the rachis, ending blindly below; the lower part of the stomodzeum, and the whole of the organs below the stomodeum being thus contained within the rachis. The greater part of the thickness of the rachis is, in fact, made up of these lower ends of the polyps, which in a transverse section of the rachis will be seen cut at various levels. Fig. 28 represents such a section. On the left side it cuts one of the lateral polyps longitudinally and horizontally (¢/ fig. 13) ; on the right side it cuts the corresponding polyp of that side lower down, the section passing transversely through the lower part of the stomodzeum. The dorsal polyp of the set is cut at a still lower level, the section passing through the two long mesenterial filaments and the ova. * Op. cit., pp. 297-304. 140 DR A. MILNES MARSHALL ON THE The section also shows four zooids cut, like the polyps, in different planes. and at different levels. Plane of Symmetry.—Each polyp of a Pennatulid colony can be divided. longitudinally into two perfectly similar halves by one plane only, which is spoken of as the plane of symmetry. This plane passes between the two long mesenterial filaments, bisecting the septal chamber bounded by the two septa which bear these filaments; it also bisects the septal chamber immedi- ately opposite to this one, and passes along the long axis of the stomodzeum, which in transverse section (fig. 28, s) is oval, not circular in shape. In Kophobelemnon this plane of symmetry of each polyp has a very definite relation to the rachis. The plane is a vertical one, and is perpendicular to the surface of the rachis to which the polyp is attached, so that if prolonged it would pass through the centre of the calcareous axis or stem. These relations will become more obvious from an inspection of fig. 28. In the case of all three polyps shown in this figure, the planes of symmetry, being vertical when the specimen is placed upright in its natural position, will be at right angles to the plane of the paper. In the case of the dorsal polyp the plane of symmetry must pass through the centre of the polyp cavity, and must also (by definition) pass midway between the two long mesenterial filaments p ; it is obvious from this figure that this plane, if prolonged, will pass through the centre of the calcareous stem ¢. So also in the case of the right hand polyp of the figure. In order to divide the retractor muscles 7m symmetrically, it is clear that the plane of symmetry must bisect the septal chamber next to the stem c, and also the chamber immediately opposite to this one; such a plane will pass along the longer axis of the stomodzum s, and will, if prolonged, pass through the centre of the stem ce. So with. all the other polyps, the plane of symmetry will always be a vertical one, will be at right angles to the surface of the rachis at the point of insertion of the polyp, and will, if prolonged, pass through the centre of the calcareous stem. It is further evident from fig. 28 that the two long mesenterial filaments are on the side of the polyp next to the stem, so that the surface of the polyp which, when the polyp becomes free from the rachis (cf fig. 23), is continuous with its upper surface, may conveniently be called the axial surface; while the opposite surface, which is furthest from the stem, and which is continuous with the lower surface of the polyp when this becomes free from the rachis, may be called the abaxial surface. I have already used the terms agial and abaxial when describing the surfaces of the Pennatula zooids,* and have done so in exactly the same sense * Supra, p. 125. , PENNATULIDA DREDGED BY H.M.S. “ TRITON.” 141 as that here proposed, the axial surface being that which bears the long mesenterial filaments. As these words express a real and an important rela- tion, they would appear preferable to the very misleading terms dorsal and ventral, which are commonly employed to denote the surfaces in question. The plane of symmetry of the zooids obeys exactly the same laws as that of the polyps, the mesenterial filaments being placed on the axial wall. Concerning the arrangement of the zooids on the rachis, it will be seen from fig. 28 that the reason of the existence of a short tract devoid of zooids imme- diately below each polyp is that this tract is really part of the abaxial wall of the polyp; and as the zooids are developed on the rachis itself and not on the polyps, there can clearly be no zooids on these tracts. Retraction of Polyps.—In spite of the great rigidity of the wall both of the polyp itself and its tentacles, due to the enormous number of spicules contained in it, the polyps can, as shown on the right-hand side of fig, 23, be withdrawn almost completely into the rachis, the tentacles entirely disappearing from sight in the fully retracted state. During the process of retraction the body wall of the polyp is thrown into transverse folds, and one specially deep fold at the junction of body and tentacles (vide the left-hand polyp of fig. 28) corre- sponds to the calyx of other Pennatulida., Structure of Stalk.—This is well shown in fig. 27, representing a transverse section taken about the middle of its length. The mesoderm is of great thickness, and is divided into inner and outer zones by the well-developed layer of longitudinal muscles Im, which forms a deeply corrugated sheath extending round the whole stalk. Of the two zones the outer one is very richly studded with calcareous spicules 7, crossing one another in all possible directions ; while the inner zone is devoid of spicules, and is traversed by a dense network of nutrient canals. The stem c is quadrangular, with rounded angles and grooved lateral surfaces. In the rachis, as we have seen (tig. 28), the stem is cylindrical; but this change in shape is by no means exceptional, occurring in Pennatula and several other genera, as well as in Kophobelemnon. The stem is invested by a mesodermal sheath, which is prolonged outwards to the body wall as four vertical septa, which separate from one another the four main longitudinal canals of the stalk, of which the dorsal dc, and ventral wc, are considerably larger than the lateral ones Jc. If these canals, which are lined by endoderm, be traced upwards towards the rachis, the two lateral ones are soon found to disappear; the dorsal one extends a short distance up the rachis, and then in its turn disappears, while the ventral one (fig. 28, vc) persists of considerable size throughout the whole length of the rachis. Of Kophobelemnon stelliferum KOLLIKER* distinguished at first two varieties, which he named mollis and dura respectively, the difference consisting chiefly * KOLLIKER, op. cit., p. 305. 142 DR A. MILNES MARSHALL ON THE in the greater number and size of the spicules of the latter, which reach in the tentacles a length of from 0°64 to 0°89 mm. and width of 0°09 to 0:12 mm. The muscular layers are also far less strongly developed in the var. dura than in var. mollis. ; At a later period* he described a specimen from the Atlantic at a depth of 690 fathoms, which was in all its characters intermediate between the two other forms, and seemed to prove them to be merely varieties, and not, as once supposed, specifically distinct. The “Triton” specimens belong clearly to the variety dura, though they differ a good deal among themselves as to the size of the spicules. The single specimen from the “ Knight Errant ” collection has much smaller spicules than any of the others, and is to be referred to the variety intermedia. The following table gives the measurements of the ‘“ Knight Errant” speci- men and of one of the typical “ Triton” specimens :— A. B. Var. intermedia Var. dura from “ Knight Errant.” from “Triton.” Total length, . : ‘ 82 mm, 45 mm. Length of rachis, : 43°5 21 a stalk, ; : 38°5 (broken at lower end) 24 No. of polyps, . ; ‘ 18 6 Size of spicules (largest), : 0:31 x 0:018 0°66 x 0-11 All the specimens of XK. stelliferum were encrusted rather thickly with sand, which adhered somewhat firmly to the ectoderm, and doubtless acted in part as a protective envelope. The internal cavities, both stomodzum, body cavity, and tentacular cavities, also contained large quantities of sand, which rendered the preparation of sections a matter of some difficulty. Whether this indicates a habit of retraction into the sand in which they live planted by their stalks, or whether the sand is purposely swallowed for the sake of food matters that may be mixed with it, I have had no opportunity of determining. Family 2. Umbellulidee. Umbellula, Lam. Umbellula gracilis, n. sp. (Pl. XXV. figs. 29-35.) Specific Characters.—Distinctly bilateral. Polypg forming a cluster on the upper end of a club-shaped rachis ; greyish in colour with dark reddish-brown tentacles. Stalk long, very slender and exceedingly flexible ; ending below in a dilated vesicular portion. Zooids numerous on the rachis between the polyps, — * Op. cit., p. 320. , PENNATULIDA DREDGED BY-H.M.S. “ TRITON.” 143 and extending a short distance below them; zooids of upper part of rachis much the largest, and each provided with a tentacle bearing a double row of pinnules ; zooids of lower part of rachis are smaller,—they may have tentacles, but these do not bear more than a single pinnule. Stem cylindrical along the ereater part of its length, becoming quadrangular in the terminal dilated part. No calcareous spicules at any part of the colony. Habitat.—Station 11; depth 555 fathoms. External Characters.—A_ single specimen of this species was obtained with the trawl. This specimen, which is in perfect condition, is represented of the natural size, and from the dorsal surface in Pl. XXV. fig. 29. It hasa total length of 290 mm., of which the upper 26 mm. are expanded to form the club-shaped rachis. This ends above in a blunt point (fig. 30), and is widest about the middle of its length, where it measures 6 mm. from side to side, and 5 mm. from the dorsal to the ventral surface. The rachis bears the polyps on the upper two-thirds of its length, and below the lowest polyp tapers somewhat rapidly, and passes without any sharp line of demarcation into the stalk. The stalk is cylindrical and very slender, with a diameter about the middle of its length of 0°8 mm. At its lower end it presents a distinct enlargement, 35 mm. long and 3°5 mm. in diameter. For the greater part of its length the stalk is extremely flexible, so much so that it can readily be coiled in circles of 5 mm. diameter without the slightest danger of breaking. The stem or calcareous axis is cylindrical along the greater part of the length of the stalk, with an average diameter of 0°5 mm. Shortly before reaching the terminal dilatation of the stalk the stem enlarges somewhat suddenly to 0‘9 mm. in diameter, becoming at the same time quadrangular in shape, and very much more rigid than in the upper part. In the terminal dilatation it gradually tapers towards the lower end. The polyps, which are confined to the upper 18 mm. of the rachis (figs. 29 and 30) are 13 in number, and gradually increase in size from above down- wards. They are inserted on all sides of the rachis, with the exception of a narrow strip 1°5 mm. wide along the mid-ventral surface (fig. 30), aud even this is somewhat encroached upon by the lowest polyps. It is difficult to make out any definite plan of arrangement of the polyps. Commencing at the top, the first polyp, which is the smallest of the lot, is inserted in the left latero-dorsal surface just below the apex. The second polyp is placed on the right latero-dorsal surface, a little way below the first. Then comes a rather irregular whorl of six polyps, of which two are dorsal, two lateral, and two latero-ventral; and finally a lower whorl of five polyps, the largest of all, of which one is mid-dorsal, two lateral, and two latero-ventral, the left one of the last pair almost reaching the mid-ventral line. VOL. XXXII. PART I. 2A 144 DR A. MILNES MARSHALL ON THE The body of the polyp is greyish in colour, and from 10 to 15 mm. in length. It is widest at its base—4 mm. in the larger polyps, and gradually narrows in its upper third to 25 mm. The upper part is marked by very distinct longi- tudinal grooves opposite the septal attachments, and is also slightly corrugated transversely. The tentacles are of a dark reddish-brown colour, and of about the same length as the polyp body. Lach is fringed by a double row of pinnules, which exhibit an irregular alternation of larger and smaller ones (fig. 31); the larger pinnules being inserted rather nearer the inner or oral surface of the tentacle than the small ones. LinDAHL™ has directed special attention to this inequality of the pinnules in the case of U. Lindahli (KOll.)+, where it appears to be much more marked than in U. gracilis. The polyps and tentacles are non-retractile, or can at most be withdrawn to a very slight extent, and there is no trace of a calyx. Structure of Polyp.—One of the polyps was removed fu the sake of studying its structure, and cut into a series of transverse sections. The anatomy presents no points of special importance. The body wall is of only moderate thickness, the body cavity and tentacular cavities being of large size. As in Kophobelemnon the polyp cavities are prolonged into the rachis, but a larger proportion of the polyp is free than in this genus; the stomodeeum and upper part of the mesenterial filaments being contained within the free part of the polyp, and the reproductive organs and lower part of the mesenterial fila- ments being alone situated within the rachis. The plane of symmetry in the case of the one polyp examined, and pre- sumably in the others as well, obeys the same laws that have been found above to apply to Kophobelemnon and Pennatula, 7.e., it is vertical and at right angles to the surface of the rachis at the point of insertion of the polyp. The axial surface of the polyp, moreover, is that which bears the two long mesenterial filaments. The single specimen obtained is a female, and the arrangement of the reproductive organs is the same as in other Pennatulida, the ovaries being the free edges of the six septa which bear, higher up, the six short mesenterial filaments. Fig. 34 represents a section of one of these fertile septa and of the part of the body wall from which it springs. The figure shows the largely developed retractor muscle of the polyp rm, and at the edge of the septum ova in various stages of development, each with a large nucleus and nucleolus, and invested in a distinct epithelial capsule. The ripe ova have a diameter of 0-1 mm. * LinDau, “Om Pennatulid-sligtet Umbellula,” Kongl. Svenska Vetenskaps-Akademiens Handlingar, Bd. xiii. No. 3, Stockholm, 1874. + Kouuker, Die Pennatulide Umbellula, Wurzburg, 1875. K6xi1Ker proposes to group together Linpauw’s U, miniucea and U, pallida under the name U. lindahli. , ‘ 1 PENNATULIDA DREDGED BY H.M.S. “TRITON.” 145 The specimen being in excellent histological condition, I have been enabled to make some observations on the development of the ova. Fig. 35 represents a transverse section through one of the ovigerous septa close to its free inner edge. The septum is seen to consist of a central mesodermal lamella z, clothed on each side by a thick layer of endodermal cells y. Of these cells the super- ficial ones form a layer of short columnar or cubical cells, while the remainder of the endoderm consists of larger cells of irregular polygonal shape, closely packed together, with large granular but rather ill-defined nuclei and granular protoplasm. Among these cells certain ones are conspicuous by their larger size and granular appearance, o’. These, which are the germinal cells or primitive ova, appear to arise in the deeper parts of the endoderm layer close to the meso- derm lamella, and as they increase in size gradually move outwards towards the surface. Together with this increase of size the ova become spherical in shape, the protoplasm becomes very granular and opaque, and the nucleus, which at first was an ill-defined granular body, becomes vesicular, and acquires a distinct nucleolus and a very well-marked nuclear reticulum. In some of the larger Ova 0, a reticular appearance is also evident in the protoplasm. The ovum, by its continued growth, reaches the surface of the septum, and pushing before it the surface layer of columnar epithelium, which forms the follicular investment, projects freely from the surface to which it remains attached by a short stalk (fig. 34). In Sagartia, according to the HErtwias,* the ova arise in the deeper layer of the endoderm, but sink into and become invested by mesoderm before com- mencing their outward passage towards the surface of the ovary. I have seen no trace of such a mesodermal investment in Umbellula, neither have I seen the peculiar polar fibrillar apparatus described in Sagartia. Structure of Zooids—The zooids of U. gracilis are unique among Penna- tulida, so far as at present known, in possessing pinnated tentacles. As shown in fig. 30, the zooids cover all parts of the rachis not occupied by the polyps. The largest zooids are those at the upper end of the rachis, and it is in this situation alone that the zooids with pinnated tentacles occur. Below the polyps the zooids get gradually smaller and smaller. Fig. 32 represents on a larger scale a group of zooids from the ventral surface of the upper extremity of the rachis, drawn with the camera. The zooids are seen to be conical, in the best marked cases tubular, projections with a mouth at the free end overhung by a single tentacle, which bears a variable number of pinnules. The pinnules may occur on one side only or on both, and in some cases form a row of five or six on each side of the tentacle. * O. und R. Hertwic, Die Actinien, pp. 95 seq. 146 DR A. MILNES MARSHALL ON THE In fig. 33 one of these zooids is represented in longitudinal vertical section, together with the part of the rachis from which it springs. The tentacle, which is hollow, overhangs the mouth on the abaxial side, a point of some interest, inasmuch as the calycular processes of the large ventral zooids of P. phosphorea var. aculeata were also found to be abaxial (of. Pl. XXII. fig. 8). The mouth leads into the stomodzum s, the abaxial wall of which is clothed with very long cilia 7. At its lower end the stomodzum opens into the body cavity h, which is lined by endoderm, and is prolonged into the tentacle. The body cavity is, at any rate in some cases, in direct communication with that of adjacent zooids. As in zooids generally, there are only two mesenterial filaments present, of _ which one is shown in the figure. These are borne by the axial septa, and are extremely long and much convoluted. In some of the larger zooids I have noticed a slight notching of the margin of the mouth, which may possibly indicate the rudiments of additional ten- tacles. ) Below the polyp-bearing part of the rachis the zooids become much smaller. The tentacles at first increase slightly in length, but become much more slender, and lose their pinnules, with the exception of a single one, which is often retained, giving a bifid appearance to the tentacle. These tentaculiferous zooids are, as shown in fig. 30, almost confined to the lateral margin of the rachis, the zooids of the dorsal and ventral surface becoming very early reduced to the condition of small wart-like knobs. These become ‘smaller in size and more irregular in arrangement as we pass downwards, and finally cease about 50 mm. from the upper end of the rachis. In possessing single tentacles the zooids of U. gracilis resemble those of U. Hucxleyi and U. Carpenteri,* two of the species obtained by the “ Challenger ” from the North Pacific and South Polar seas respectively, but differ from all other species, and indeed from all other Pennatulida yet described. In possessing pinnated tentacles the zooids of U. gracilis stand absolutely alone. “a I have pointed out above, when discussing the nature of the zooids of P. phosphorea, that zooids must be considered as abortive polyps arrested in an early stage of development. It becomes now an interesting inquiry how this unitentacular condition of the zooids of Umbellula arose. So far as is at present known, the earliest rudi- ments of all eight tentacles arise simultaneously in the Pennatulid polyps. I have described this above in the case of the asexually formed polyps of Pennatula , * KotuKer, Zool, Chall. Exp., part ii. 1880, pp. 21-24. erm, PENNATULIDA DREDGED BY H.M.S. “ TRITON.” 147 and Virgularia, and Witson * has recently shown that the same applies to the sexually produced young of fenil/a. It appears, therefore, that the unitenta- cular condition of the Umbellula zooid is not a repetition of any stage occurring in the ontogeny of the normal Pennatulid polyp. It is, however, just possible that such a stage once existed in the phylogeny of the group, but has dropped out of its ontogeny. So far as is known, a unitentacular condition does not obtain in the ontogeny of any Alcyonarian, though we must bear in mind that very few forms have as yet been studied adequately. Among Zoantharia a_ temporary unitentacular condition occurs in Actinia mesembryanthemum,t while in Cerianthus and Arachnitis four tentacles arise simultaneously, and in other cases all eight. The definite relation of the single tentacle of the Umbellula zooid to the plane of symmetry seems to indicate that it has some morphological signi- ficance, though at present we have not evidence to determine what that significance is. I would, in conclusion, direct attention to the. remarkable condition of the polyps in Scytalium tentaculatum, Koll.,t one of the “ Chal- lenger ” species, in which each polyp has but a single tentacle, as showing that a unitentacular condition may be more widely spread than is at present suspected. Our knowledge of the genus Umbellula has been very greatly increased of late years. Two specimens taken off the coast of Greenland in 1752, and very imperfectly described, were for more than a century the only examples recorded. In 1871 Linpaut obtained two specimens, one in Baffin’s Bay in 410 fathoms, and the other at the entrance to the Omenakfjord, in N. Greenland, at a depth of 122 fathoms. An Umbellula was also obtained by NorDENSKIGLD in the Kara Sea, to the east of Novaya Zemlya, during the ‘“ Vega” expedition. The ‘Challenger ” expedition added enormously to our knowledge of this genus, no less than seven new species being obtained from widely different parts of the world. Concerning the geographical distribution of this genus KOLLIKER says :—‘‘ After having known for more than a century only one locality, the North Polar Sea, near the coast of Greenland, we have now learned that this form is far and widely distributed. Umbellule have now been obtained from the North Atlantic Ocean (between Portugal and Madeira); from the North Polar Sea, coast of Greenland; from the Atlantic Ocean, under the Equator, between Africa and America, and from the west coast of Africa, north of Sierra Leone (Stud.) ; from the South African Sea, west of Kerguelen Island ; from the South Polar Sea; from the coasts of New Guinea and of * Witson, “‘ The Development of Renilla,” Proc. Roy. Soc., 1882. 7 Lacaze-Durtuiers, “ Développement des Coralliaires,” Archives de Zoologie expérimentale et générale, vol. 1. 1872, and vol. ii. 1873. { KouuiceEr, Zool. Chall. Exp., part ii, 1880, pp. 10, 11, and pl. iii. fig. 12, pl. iv. fig. 13. 148 DR A. MILNES MARSHALL ON THE Japan; and from the middle of the North Pacific Ocean. Umbellula has, therefore, of all genera of Pennatulida, the widest distribution.”* The “ Triton” specimen makes a very interesting addition both to the list — of species of Umbellula and to the localities in which it has been found. The measurements of the sole specimen of Umbellula gracilis yet known are as follows :— Total length, . 2 : . : 290 mm. Length of rachis (aieced “sea ; . ; : 26 Length of polyp-bearing part of rachis, : : ; 18 Width of rachis at widest part, ; : . . 6 Thickness, . ‘ : ; 5 Length of terminal aleiatsert of cialis : : ‘ oo Diameter, . : : ; 3°2 Diameter of stalk (middle of length), : ! 0-7 i stem, . d : : 0°5 Ee stem (widest ao , : f ; 0-9 Number of polyps, . 5 ‘ ; : ‘ 13 Length of polyp (shortest), . —.. F f : 15 a body, . . , E TS E tentacle, . , 4 . ee Length of polyp (largest), . : ; : ; 26 pi body, . : ; ; 13 tentacle, . ; : . 18 iamaire of polyp, base, : ‘ : : 5 just below feiss s : , 2°8 Length of zooid, largest, 3 ; = : 1:8 Length of tentacle of zooid, ieee ; ; : : 13 GENERAL OBSERVATIONS. Geographical Distribution. Horizontal Distribution.—The most noteworthy point is the great abundance and variety of specimens dredged at one particular locality,—Station 11. At this place there were obtained, from a depth of 555 fathoms, nineteen specimens of Pennatula phosphorea var. aculeata; three specimens of Virgularia tuber- culata, a new species ; one specimen of Diibenia abyssicola var. smaragdina, a form hitherto found only off the Norwegian and Swedish coasts ; thirty speci- mens of Kophobelemnon stelliferum var. dura; and one specimen of Umbellula gracilis, a new species ; 7.¢., example of five out of the fourteen known families of Pennatulida, of three distinct subsections, and two of the four sections of the order were obtained at this one spot. , * KouuiKer, Zool. Chall. Exp., part ii. 1880, p. 37. PENNATULIDA DREDGED BY H.M.S. “ TRITON.” 149 This extraordinary profusion mark the locality as a very exceptional one. At each of the other stations only single species were obtained. Vertical Distribution.—The “Triton” observations have increased the ver- tical range of Pennatula phosphorea to 555 fathoms, its previously recorded limit being 340 fathoms; of Diibenia abyssicola, from 120 to 555 fathoms ; of Kophobelemnon stelliferum v. durum, from 300 to 640 fathoms; and have added a new deep water Virgularia, V. tuberculata, extending to 555 fathoms, to the sole one previously known, V. bromleyi. These results, so far as they go, do not lend any very material support to KO6LLIKER’s conclusion, that “the simpler forms of Pennatulida, especially those with sessile polyps, inhabit great depths.”* KO6LLIKER ranks among primitive forms of Pennatulida the Umbellulida, which are an essentially deep water family, seven out of the twelve known species being found below 1000 fathoms and five below 1800 fathoms, and cites this distribution in evidence of the view that the lower forms of Pennatulida are, as a rule, deep water forms. Umbellula appears to me, however, to be not a primitive form but a highly modified one. This is shown by the great length of the non-polypiferous as compared with the polyp-bearing part of the colony, 7.¢., the great prepon- | derance of the purely colonial portion ; by the great difference between the polyps and the zooids ; by the extreme differentiation of some of the zooids ; and, above all, by the polymorphism of the zooids themselves, an almost unique condition among Pennatulids. In all these respects Umbellula is far less pri- mitive than Funiculina, which is essentially a shallow water form, attaining its maximum of development at about 30 fathoms depth. A point of considerable interest concerns the influence of increase in depth on | the structure and habits of Pennatulids. On this point but little can be said at , present for want of sufficient evidence. We have seen above that some of the deep water forms (below 500 fathoms) have much thicker body walls and layers, and more numerous spicules, than | those from less depths. If we compare different genera together there would appear to be no relation whatever between depth of water and development of | spicules; thus Umbellula gracilis and Virgularia tuberculata from 555 fathoms | have no spicules at all; while P. phosphorea and K. stelliferum, brought up in | the same dredge with the preceding species, have exceptionally large and numerous spicules. If, however, we confine ourselves to one species, we seem to find such a relation; thus the specimens of Pennatuia phosphorea from below | 500 fathoms have very much thicker walls, and larger and more abundant spicules, than those from 20 to 40 fathoms. In this case we have strong reason * Kouuiker, Zool. Chall. Exp., part ii. 1880, p. 39. 150 DR A. MILNES MARSHALL ON THE for thinking, from the small size and somewhat stunted appearance of the deep water specimens, that the species is typically a shallow water one, and it is very possible that the increase in development of spicules is due directly to the change of environment. All the specimens of Kophobelemnon and also those of Pennatula obtained below 500 fathoms contain large quantities of sand mixed with Foraminifera shells, both in the polyp cavities and in the tentacular cavities, and also encrusting the exterior. The specimens of Umbellularia, Diibenia, and Virgu- laria brought up at the same time are, however, perfectly clean and free from sand. Whether this indicates difference in habits or is merely accidental, I have no means of ascertaining; the specimens of Pennatula from shallow water have no sand in the polyp cavities, or but very little. Morphology.—The chief points of morphological interest on which light is thrown by the “ Triton” specimens appear to concern the structure of the zooids of Pennatula and Umbellula ; and the relations of the plane of symmetry of the polyps established in Pennatula, Kophobelemnon, and Umbellula. DESCRIPTION OF THE FIGURES ON PLATES Kee xRy, All the figures were drawn with the camera. -Figures 8, 28, and 33 are not taken from single sections, but are constructed from a number of separate camera drawings of the several parts shown. The numbers beneath the figures indicate in diameters the magnifying power — employed in each case. Alphabetical List of References, a, rachis. nm, mouth. b, stalk. 0, ovum. c, stem. o’, germinal cell or primitive ovum. d, polyp. p, long mesenterial filament. dc, main dorsal canal of rachis. 7, cilia of siphonoglyphe. dl, leaf. rm, retractor muscle of polyp. e, zooid. s, stomodzeum. t, tentacle. t’, cavity of tentacle. u, pinnule of tentacle. v, spermatosphere. ve, main ventral canal of rachis. w, ectoderm. J, large zooid. g, body cavity of polyp. h, body cavity of zooid. i, spicule. k, spicular plate. 1, calyx process, I’, cavity of calyx process. lc, main latera) canal of rachis. Im, longitudinal muscles of rachis and stalk. m, tneseutery or septum. , “, mesoderm. z’, nutrient canals of mesoderm. y, endoderm. PENNATULIDA DREDGED BY H.M.S. “‘ TRITON.” 151 PLATE XXI. Fig. 1.—Virgularia tuberculata ; ventral surface. x 3. Fig. 2.—Virgularia tuberculata ; portion of rachis, ventral surface, showing arrangement of polyps in groups of threes; also the tubercular calyx processes and the varying conditions of the calyx during retraction of the polyp. x 17. Fig. 3.—Viryularia tuberculata ; two spermatospheres from lower part of rachis of the speci- men shown in fig. 1. x 70. Fig. 4.—Pennatula phosphorea var, aculeata ; from right side. Shows characteristic shape of leaves, also both small and large zooids, x 2. Fig. 5.—Pennatula phosphorea var. aculeata ; transverse section of rachis with one entire leaf and the base of the corresponding one of the other side. Shows shape of leaf; shape and arrangement of zooids both large and small; great thickness of wall of rachis, and small size of its main canals. x 4. Fig. 6.—Pennatula phosphorea ; transverse section of rachis with entire leaf of normal form, for comparison with fig. 5. Shows great width of leaf, absence of large zooids, thinness of walls of rachis, and large size of main canals. x 4. Fig. 7.—Pennatula phosphorea var. aculeata ; lower end of rachis from left side. Shows stages in development of polyps, and especially the simultaneous appearance of the calyx processes and of the tentacles; also the primitive independence of the polyps of one another. x 17. PLATE XXII. Illustrating the anatomy of the large ventral zooids of Pennatula phosphorea var. aculeata. The reference letter ¢! in the figures on this plate should be 7. | Fig. 8.—Longitudinal section of large ventral zooid and of the part of the rachis from which it arises. Shows structure of large zovid and of one of the small zooids. x 50. Fig, 9.-—Transverse section of a calyx process of a polyp, for comparison with the succeeding figure. x 150. Figs. 10 to 16.—Transverse sections through one of the large ventral zooids at various parts of its height, fig. 10 being close to the apex and fig. 16 at the base of attachment to the rachis. x 150. ‘Fig. 10.—Through upper end of zooid, showing one calycular cavity. | Fig. 11.—Lower down; shows two calycular cavities. | Fig. 12.—Lower down still; shows three calycular cavities. Vig, 13.—Through upper part of mouth; shows long cilia of siphonoglyphe. | Fig. 14.—Through lower part of mouth; shows five calycular cavities. | Fig. 15.—Through stomodzeum about the middle of its length. Shows eight septa and septal chambers. | Fig. 16.—Through lower part of polyp cavity, showing the two mesenterial filaments, and the remains of the other six septa. PLATE XXIII. Fig. 17.—Diibenia abyssicola var. smaragdina. Ventral surface. x 3. | Fig. 18.—Diibenia abyssicola var. smaragdina. Portion of rachis from left side. Shows arrangement of polyps in pairs, each pair embraced at base by a fan-shaped spicular plate. .x 17. VOL. XXXII. PART I: 2B Fig. ig. 19.—Diibenia abyssicola var. smaragdina. Portion of rachis from dorsal surface. Shows — . 20.—Diibenia abyssicola var. smaragdina. Tentacle of polyp, showing rib of calcareous . 21.—Diibenia abyssicola var. smaragdina, one of large spicules of spicular plate. x 55, — . 22.-Funiculina quadrangularis. Portion of rachis of young specimen from left side. . 23.—Whole specimen, dorsal surface; showing typical arrangement of polyps. x 2. . 24,—Tentacle of polyp; showing rib of calcareous spicules extendirig whole length of ig. 25,—Transverse section of tentacle, showing tentacular cavity and extension into pinuules, | . 26.—Two large spicules from spicular rib of tentacle. x 55, g. 27.—Transverse section of stalk; showing arrangement of spicules and muscles; also . 28.—Transverse section of rachis passing through three polyps at different portions of . 29.—Whole specimen; dorsal surface. x 1. . 30.—Rachis; ventral surface. Shows arrangement of polyps and zooids. x Q. . 31.—Tentacle of polyp; shows alternation of large and small pinnules. x 10. . 82.—Apex of rachis; ventral surface. Shows shape and arrangement of large zoids ig. 33.-—Longitudinal section of one of the large zooids; shows the tentacle with its pinnules, 34.—Section of septum bearing ova, and of the part of the body wall of the polyp from DR A. MILNES MARSHALL ON THE PENNATULIDA, ETC. arrangement of polyps and zooids. x 17. spicules. x 70. Shows shape of polyp in state of extreme contraction; also extension of apioules 4 down whole length of polyps and on to rachis. x 7. PLATE XXIV. Kophohelemnon stelliferum var. durum. tentacle and along pinnules. x 20. 7 also arrangement and shape of spicules. x 70. shape of stem and of main longitudinal canals. x 30. their length. The left-hand polyp is cut horizontally (¢f. fig. 23), and shows stomo- dum, mouth, and tentacles; the right-hand polyp is cut transversely through the lower portion of the stomodzeum, and shows arrangement of retractor muscles and position of plane of symmetry of polyp; the third or dorsal polyp is cut trans- versely at a still lower level, and shows the two mesenterial filaments and a number of ova. The section also shows several zooids and the shape and position of the stem and of the main ventral canal. x 30. PLATE XXV. Umbellula gracilis, with pinnate tentacles. x 14. mouth, stomodzeum, mesenterial filament, &e. x 55. . which the septum arises. Shows also the disposition of the retractor muscle, x 70. ‘ : 35.—Section of ovigerous septum close to its free edge, showing various stages in the early development of the ova. x 470. Vol. XXXIL, Plate XXL Marshall del.ad nat. ¥. Huth, Lith Edin® VBR GUA Rola EN SNCA st UME eas Trans. Roy. Soc. Edin? Vol. XXXI1, Plate XXII. 1 Tae OSSPARES.~ uoSBBanes we kd cig gneN iaBeaU oT rua a0) Ro Al Vs hale Shey ®. i Cee FY “Sa Lg my os JA.M. Marshall del.ad nat F Huth, Lith® Edi PUESN-NeA T UCL A: = ts = ‘ : : rH -) g at N w re, rs) g = con 1 Se open AES A MES 4 BOA a) i esc a ; arnt 8 em eS ERENT Cou aN Ae DU BEN TA. Fig. 18. X17 farshall,del.ad nat. ans. Roy. Soc. Edin? ‘vans. Roy. Soc. Edin® Vol. XXXII, Pl. KXIV. Fig. 23. xX 2 oe ~ RAIA aaa -Marshall,del ad nat. F.Huth, lntht Edin® KO-Pe hOB Ev vE.E MN ON. Trans. Roy. Soc. Edin® . Vol. AXXI, Plate XXV. ————— Marshall del. ad nat. F Huth Lath’ Edin® VOW EB Ee UA. 1X.—Asteroidea dredged in the Faerie Channel during the Cruise of H.M.S. “ Triton” in August 1882. By W. Percy Siaven, F.L.S., F.G.S. Communicated by Joun Murray, F.R.S.E. (Plate XX VI.) (Read 16th July 1883.) The star-fishes recorded in the present communication were dredged by Mr JoHN Murray during the cruise of H.M.S. “ Triton” (under the command of Staff-Commander Tizarp, R.N.), whilst investigating the nature of the Wyville- Thomson Ridge and the adjacent portions of the Faerée Channel. All the forms, excepting these from Station 3, were obtained from deep water, and the collection, as a whole, is both rich and interesting. One species and two well- marked varieties have not hitherto been described, and two other species have only been found once previously. The series consequently forms a valuable supplement to the collections made during the cruises of H.M.S. “ Porcupine ” and the “ Knight Errant,” and is an important addition to our knowledge of the fauna of this region of the Atlantic. I propose to reserve any remarks upon the general character of the asterid fauna of the Faerdée Channel until treating of the collections obtained during the “‘ Porcupine” and “ Lightning” cruises. I am indebted to Mr Murray for his kindness in placing this collection in my hands. | | I. List oF THE SPECIES COLLECTED. 1. Pteraster militaris (O. F. Miller), Miiller and Troschel. Station 2. August 5, 1882. Lat. 59° 37’30” N., long. 6° 49’ W. Depth, 530 fathoms ; bottom temperature, 46°-2 Fahr. 2. Pteraster militaris, var. prolata, nov. (Plate X XVI. fig. 1.) Station 9. August 23, 1882. Lat. 60° 5’ N., long. 6° 21’ W. Depth, 608 fathoms ; bottom temperature, 30° Fahr. This is a remarkable form, differing greatly in general appearance from the normal type of P. militaris; and although it accords in the main with the diagnostic formula of that species, the majority of the characters differ more or ' less in degree. It is not improbable that a series of examples might ultimately warrant its being ranked as a distinct species ; but for the present I prefer to WO, XMMIL PARI" T. pa OF [54 MR W. PERCY SLADEN ON THE place the solitary specimen as a variety of P. militaris until further material is — available—a course which is sufficient to identify the form, and at the same time indicate the nearest specific affinities. The variety is characterised by the following points :—The great length and narrowness of the rays; R>37; R=58 to 60 mm., 7=18 mm. ; breadth of a ray at the base, 18 to 22 mm. extreme measure. The dorsal paxille appear usually to have one of their spinelets much more robust than the two or three com- — panion spinelets, which are remarkably fine and delicate, and the tips of the spinelets can scarcely be said to protrude through the supradorsal membrane, notwithstanding that this latter is placed rather loosely upon them, and much wrinkled. Two or three lineal series of paxillee are more or less clearly distin- guishable along the. sides of the rays. On the actinal surface the segmental apertures are remarkably large, and the aperture-papille are much broader and more robust at their proximal portion than in P. militaris. In the ambulacral spines the three inner spines of each transverse comb form a line oblique to the furrow, the comb being curved aborally at the margin of the furrow, and the position of these spines upon the adambulacral plate being also oblique in rela- tion to the plane of the ray. The actino-lateral spines are very short, and the — outer portion of the web which proceeds from the outermost ambulacral spine, i.é., the membranous continuation of the transverse comb upon the actinal membrane, is much more prominent than in the typical form of the species, and extends up to the margin of the lateral fringe. Although these differences may appear insignificant verbally, they produce when combined a striking facies, the characters of which can hardly be explained, as being simply the modifications of the normal form consequent on the conditions of a deep water habitat, since the example of P. militaris from 530 fathoms (Station 2), recorded above, differs in no way from the normal form. 3. Archaster lenuispinus (Diiben and Koren), Sars. Station 9. August 23, 1882. Lat. 60° 5’ N., long. 6° 21’ W. Depth, 608 fathoms ; bottom temperature, 30° Fahr. 4. Archaster bifrons, Wyville Thomson. Station 10. August 24, 1882. Lat. 59° 40’ N., long. 7° 21’ W. Depth, 516 fathoms ; bottom temperature, 46° Fahr. Station 11. August 28, 1882. Lat. 59° 29’ N., long. 7° 13’ W. Depth, 555 fathoms ; bottom temperature, 45°°5 Fahr. 5. Astropecten Andromeda, Miiller and Troschel. Station 10. August 24, 1882. Lat. 59° 40’ N., long. 7° 21’ W. Depth, 516 fathoms ; bottom temperature, 46° Fahr. ASTEROIDEA DREDGED DURING CRUISE OF H.M.S. “TRITON.” 155 Station 11. August 28, 1882. Lat. 59° 29’ N., long. 7° 13’ W. Depth, 555 fathoms ; bottom temperature, 45°°5 Fahr. The propriety of retaining this form in the genus Astropecten appears to be questionable. I propose to reserve the discussion of the subject until dealing with some allied forms obtained by the “ Challenger ” expedition. 6. Luidia ciliaris, Philippi. Station 3. August 8, 1882. Lat. 69° 39’ 30” N., long. 90° 6’ W. Depth, 87 fathoms ; bottom temperature, 49°°5 Fahr. I consider this form separate from LZ. Sarsii, D. and K. Both species were comprised in Forbes’ LZ. fragilissima. I regard L. Savignyi, Audouin, distinct from either. Rhegaster, gen. nov. Marginal contour subpentagonal; rays slightly produced. Abactinal sur- face more or less convex, actinal flat. The whole body covered with mem- brane, beset with crowded spinelets. Abactinal skeleton composed of irregular plates, crowded and subimbricated in places, which leave small irregularly disposed meshes. The whole skeleton is hidden in a thick membrane, and furnished with a compact covering of _ small, uniform, crowded spinelets. Papule small, numerous, isolated, irregu- larly distributed over the whole area. Infero-marginal plates large, forming the margin of the test. Supero-marginal plates superficially invisible, concealed -in the dorsal membrane. Actinal interradial areas with large subregular plates, hidden by a superficial membrane, with small crowded spinelets. -Adambulacral plates broader than long. Ambulacral spines short and thickly invested with membrane, forming a regular furrow-series and several | . . . : . subregular longitudinal rows externally. Ambulacral sucker-feet in simple pairs, with small sucker-disk. Madreporiform body small, midway between margin and apex. Anus sub- central. No pedicellariz. This genus comes within the scope of the family Asterinidw as defined by Dr VicuiEr, and appears to be well distinguished from the other genera of the group. In addition to the species now described, I include in the genus the interesting form named by Dr StuxBere* Solaster tumidus, but which has more recently been referred to the genus Asterina by Drs DANIELSSEN and Koren.t | The latter naturalists have given an admirable description, and two detail * Ofversigt af Kongl. Vet.-Akad. Férhandl., Arg. 35, 1878 (1879), No. 3, p. 31, pl. vi. + Nyt Mag. f. Naturvidensk., Bd. xxvi. hft. 2, p. 182, pls. i. and ii. figs. 6-10. 156 MR W. PERCY SLADEN ON THE figures of specimens dredged during the Norwegian North Atlantic Expedition, and a well-marked variety (var. twberculata, D. and K.) is also defined. DAntEL- — ssEN and Koren state that they place the S. twmidus provisionally as an Asterina, and mention at the same time a number of important points wherein the form differs from that genus. The determination appears to have been published with cautious hesitation, and I feel bound to express regret that the circumstance of the discovery of the new species should force upon me the undesired course of forestalling the Norwegian savants in the establishment of — a genus for the reception of a form upon which they have bestowed such care- | ful study. oe ' Through the kindness of Professor Lovin, I had the privilege of examining — Dr StuxBErG’s type specimens when in Stockholm last autumn, and I am able © to confirm the opinion of Drs DANIELSsSEN and Koren in regarding the original reference of the form to Solaster as altogether untenable. 7. Rhegaster Murrayi, n. sp. (Plate XXVI. figs. 2-7.) Station 5. August 10, 1882. Lat. 60° 11’ to 60° 20’ N., long. 8° 15/ to S 8 WW. Depth, 433 to 285 fathoms ; bottom temperature, 43°:5 to 40°°8 Fahr. Marginal contour subpentagonal, rays slightly produced; the lesser radius in the proportion of 77 per cent., or as 5:6°5. R=14'3 mm., r=11 mm. Interbrachial angles aGrsaitia indented at the median eee line, from whence the contour curves outward faintly, consequent on a slightly tumid swell- ing at the base of the ray, and is then gracefully incurved towards the tip, which is obtuse and rounded. Abactinal area high and convex over the disk, sloping down regularly to the extremity of the rays, the height at the centre of the disk being 11°75 mm. A feeble sulcus or depression is present on the outer part of the median interradial line, which emphasises the tumid character of the base of the rays. Actinal surface more or less flat, excepting that the rays are slightly turned up at their extremity, and that a rather sharp depression occurs - in the interbrachial areas along the inner reel of the median interradial line, — behind the mouth-plates. Dorsal area covered with short, delicate spinelets, all of uniform length and size, their lower portion being apparently sunken in membrane. The spinelets stand perpendicular and are closely placed, presenting to the naked eye the appearance of a fine and uniformly granular surface. When magnified the spines are seen to be slightly expanded or flaring outwardly, and to be com- posed of many rods or lamelle, with the extremity of each individual lamella terminating in a short thorn-like point. ASTEROIDEA DREDGED DURING CRUISE OF H.M.S. ‘‘ TRITON.” 157 The spinous dorsal area is punctured with numerous small but conspicuous pores, which are irregularly distributed at small but unequal distances apart over the whole area, excepting the extremities of the rays and a narrow band along the median interradial line; towards the margin the apertures are smaller, wider apart, and less frequent. Through these apertures the papulz are protruded, and under magnification a small but definite circlet of the dorsal membrane surrounding the puncture of the papula, and unencroached upon by spinelets, may be seen. No grouping of the dorsal spinelets occurs, which in any way indicates the outlines.of the underlying plates of the abactinal floor ; and the only break in this perfectly uniform covering consists of a number of most minute channel-lines, which run irregularly here and there amongst the spinelets, the only one of these maintained with any regularity being a long straight channel, similar in breadth to all the others, extending along the median interradial line. The anal aperture is subcentral and distinct, and is surrounded by slightly larger spinelets. The madreporiform body is very small, round, and with numerous strive. It is situated rather nearer to the _ margin than midway to the centre of the disk, and the surrounding portion of the test is slightly prominent. Actinal interradial areas extensive, and with their outer margin conspicu- ously festooned by the infero-marginal plates. Infero-marginal plates eight to nine in number from the interbrachial line to the tip of the ray; the contour of their outer margin is rounded, and bears a group of eight to twelve spinelets, rather larger and more robust than those of the dorsal area above described. The plates are entirely covered with spinelets—the part which falls in the side of the ray with spinelets similar to those on the dorsal area, and the ventral portion with spines similar to those on the ventral area. When the starfish is viewed in profile, the marginal plates are seen to be clearly marked out by vertical furrows as well as by their prominent tumidity ; but the junction of the infero-marginal with the supero-marginal plates, or indeed the presence of these latter at ail, is indiscernible to superficial obser- vation. Seen on the actinal side, the marginal plates are clearly defined by well-marked channels or furrows, and these run in oblique lines from the margin up to the adambulacral plates. The furrows are almost regularly parallel, hence the areas or columns they define are of nearly uniform breadth throughout. Consequent on their diagonal direction, a triangular space occurs in the median interbrachial line in the inner portion of the area, which is not conformable to the arrangement above described, the channels which traverse it converging towards the apex of the triangular space, a short distance removed from the margin of the disk. The whole ventral area is covered with small, almost spicular, spinelets, which are short, sharply pointed, and with their bases buried in membrane. The spinelets are all nearly uniform 158 MR W PERCY SLADEN ON THE — in size, rather widely spaced, and are directed outward, almost horizontally, the angle at which they stand to the actinal surface being very small. Ambulacral furrows narrow and almost uniform in breadth throughout. Adambulacral plates broader than long, bearing from five to eight spines. The ambulacral spines form a regular inner or furrow series, which arches over and almost conceals the ambulacral sucker-feet, and three sub-regular outer rows more or less clearly defined. The following is the arrangement of the spinelets on the plates :—Of the inner or furrow series there are two on each plate, which stand side by side and slightly oblique, especially towards the end of the ray. These two spines are regular throughout the ray, and are of equal size, short, compressed, lanceolate, tapering to a sharp point, and invested | in membrane, which adds to the apparent breadth of their base. The outer spines are subject to a considerable amount of variation, both in number and position. Three only may be present, each placed behind the other, external to the furrow spines, forming a transverse series on the adambulacral plate, or one, two, or even all three of these spines may be reduplified--the companion spine usually standing rather oblique. These variations do not appear to be dependent on position in the ray, but may occur in any part. All the outer spines are of uniform size, cylindro-conical in shape, rather obtusely pointed, and covered with membrane. i Mouth-plates form a triangular mouth-angle, not prominent or protuberant superficially, and perfectly conformable with the triangular outline of the inter- radial area. ‘The mouth-aperture is completely closed, and the arrangement of the armature of the mouth-plate is suggestive of that in certain Gonzasteride. The mouth-spines are short, robust, and-stand perpendicular. One odd spine is placed at the extreme angle, at the junction of the two plates of a mouth- angle, and five similar spines, all closely placed, occupy the free or furrow margin of the plate, decreasing in size as they recede from the mouth ; the odd spine being the largest, the next three slightly smaller, and the two outer ones much smaller. All the spines are cylindrical, slightly taper, and obtusely rounded at the tip. Upon the surface of the plates, and on a line with the two small outer mouth-spines, stand two short secondary or superficial mouth- spines, one on each plate, very robust at the base, conical and pointed ; and, further outward again, a second, but much smaller, spine behind each of the secondary mouth-spines; this small pair perhaps belonging to the adambu- lacral plate adjacent to the mouth-plates. A single minute spinelet, situate on the median or sutural line of the mouth-plates, stands midway between each of the pairs of secondary mouth-spines; and no other spines of any description are present on the mouth-plates. Remarks.—The form above described is nearly allied to Rhegaster tumidus (Stuxberg, sp.). The following appear to be the chief points of difference :— ASTEROIDEA DREDGED DURING CRUISE OF H.MS. “ TRITON.” 159 The length of the ray is much less in the new species, the radial proportions being for A. Murrayi, R=1°37r, and for R. tumidus R=1°97, in specimens of the same size. The rays are consequently much less defined, and are more widely expanded at the base. In &. Murrayi the marginal contour is dis- tinctly festooned by the infero-marginal plates, and each of these bears a group of enlarged spinelets, neither of the characters being present in R. tumidus. The ambulacral spines appear to be more numerous in the new form, the arma- ture of the mouth-plates somewhat different, the distribution of papule more numerous on the dorsal surface, and the character of the spinelets, both on the abactinal and actinal areas, more simple. I have great pleasure in associating this interesting species with the name of Mr Joun Murray, whose zealous labours in connection with deep-sea dredging are well known. 8. Mimaster Tizardi, Sladen. Station 10. August 24,1882. Lat. 59° 40’ N., long. 7° 21’ W. Depth, 516 fathoms ; bottom temperature, 46° Fahr. Station 11. August 28, 1882.~ Lat: 59° 29’ N., long. 7° 13’ W. Depth, 555 fathoms ; bottom temperature, 45°°5 Fahr. . 9. Hippasteria plana (Linck), Gray. Station 3. August 8, 1882. Lat. 60° 39’ 30” N., long. 9° 6’ W. Depth, 87 fathoms ; bottom temperature, 49°°5 Fahr. 10. Cribrella oculata (Linck), Forbes. (Plate XXVI. fig. 8.) Station 1. August 4, 1882. Lat. 59° 51’ 30” N., long. 6° 21’ W. Depth, 240 fathoms ; bottom temperature, 47°°6 Fahr. Station 10. August 24,1882. Lat. 59° 40’ N., long. 7° 21’ W. Depth, 516 fathoms ; bottom temperature, 46° Fahr. Station 11. August 28, 1882. Lat. 59° 29’ N., long. 7° 13’ W. Depth, 555 fathoms ; bottom temperature, 45°°5 Fahr. The specimens from Stations 10 and 11 have an abnormal appearance, even for this variable species, probably, consequent on their deep-water habitat. The variation is characterised by the comparative smallness of the disk and the greater length and narrowness of the rays, which are subcylindrical and almost uniform in breadth throughout, especially in the small examples where the expansion at the base is very slight. The single example from Station 11 | measures R=39 mm., r=5 mm., breadth of ray at the base 5°75 mm. The spinelets of the abactinal area are very small, and rather more widely spaced than in the normal form. They are conically pointed, and have the appearance 160 MR W. PERCY SLADEN ON THE of being rooted in membrane and rather thickly invested at their base, which gives the spine-groups a larger and somewhat more expanded character than usual in shallow water specimens. The three examples from Station 10 are much smaller, and their spinulation is very minute and scanty, seldom more than two to four spinelets being present in a group. The effect of this is perhaps most striking in the armature of the adambulacral plates, where the group of spines external to the furrow-series becomes - abnormally small and insignificant. The comparative length of the ray and its almost uniform breadth is very conspicuous in comparison with small specimens of similar size — of the ordinary form, in which the ray is proportionally shorter in the -young stage than in the adult. The coiour in alcohol of the specimens under notice is" a dirty greyish- brown. Considering the known variability of the species, I do not at annie feel justified in doing more than placing on record the character of the variation above noted. If a larger supply of material should ultimately necessitate the nominal recognition of this form as a deep-sea PANe it might appropriately be called cylindrella. 11. Zoroaster fulgens, Wyville Thomson. (Plate XX VI. figs. 9-11.) (Zoroaster fulgens, Wyv. Thoms, (1873), The Depths of the Sea, p. 154, fig. 26.) Station 11. August 28, 1882. Lat. 59° 29’ N., long. 7° 13’ W. Depth, 555 fathoms; bottom temperature, 45°5 Fabr. A young example. Station 13. August 31, 1882. Lat. 59° 51’ 2” N., long. 8° 18’ W. Depth, 570 fathoms ; bottom temperature, 45°-7 Fahr. A brief description and a woodcut of this handsome starfish were given by Sir WyviLLe THomson in the work cited above. As no detailed description of the species has yet been published, the following may not be unacceptable :— Rays five. R=125 to 130 mm.; r=14 to 15 mm. Rays very long, narrow, subcylindrical, and tapering throughout to a finely pointed extremity ; arched on the abactinal surface, and tumid on the actinal — surface on either side of the furrow, which is deeply sunken. Interbrachial angles acute. Breadth of a ray at the base 17 mm. The disk is rather higher than the.rays and slightly tumid. The calcareous skeleton of the whole test is formed of suboval or subhexagonal plates, disposed in perfectly regular longitudinal and transverse series. The following is the arrangement they present. Surrounding a dorso-central and five small radially placed plates are five large plates interradial in position; and outside and alternating with these are five similar but rather smaller radially placed plates.* * It will be noted that these plates represent in a remarkable manner the dorso-central, the under basals, the basals, and the radials respectively of the crinoid calyx. ASTEROIDEA DREDGED DURING ORUISE OF H.M.S, “‘ TRITON.” 161 Outward from each of the radial plates proceeds a longitudinal series of plates which extends along the median dorsal line of the ray, each plate regular in form (subhexagonal) and touching or slightly imbricating upon its next serial companion. On either side of this median line of plates is a parallel line of smaller plates, and these are succeeded bya line or series of plates nearly equal in size to those of the median line ; the outer of these lines of plates standing on the rounding which separates the dorsal and lateral areas of the ray. Between this dorso-lateral line and the adambulacral plates are five longi- tudinal and parallel series of plates, the three upper rows forming the sides of the ray and the two lower being on the tumid actinal surface. The plates of the two upper rows of the lateral series are broader than those in the three lower series. The longitudinal arrangement of all the series is perfectly regular, and the plates diminish gradually in size as they proceed outward. Excepting the median dorsal line, the plates of all the other rows form regular transverse series, as well as longitudinal. The plates of the median dorsal line are slightly larger than the others, and consequently do not correspond. All the plates are contiguous, but leave a small diamond-shaped or sub-circular mesh between the rounded corners of adjoining plates. This is covered with membrane, through which one or more small papulze proceed, and on which are usually borne one, or occasionally two, small forficiform pedicellarie. The meshes form perfectly regular longitudinal lines, and this character, as well as _ their presence, is rendered more conspicuous by the slightly tumid surface of I. . | : | the plates. The surface of all the plates is studded with a number of small, uniform, well-spaced miliary granules, on which are articulated very short ciliary spinelets thinly covered with membrane. The plates of the median dorsal line are sub-mammillated, rising to a small but definite tubercle in the middle, which gives attachment to a short, robust, conical spinelet, the sur- rounding portions of the plate being covered with the same small miliary granules and spinelets as the other plates. Isolated dorso-lateral plates are occasionally similarly mammilated and spined, and the large interradial plates on the disk are also usually thus furnished. On the plates of the three rows which succeed the adambulacral plates, there are usually one to three spinelets much longer and more robust than the accompanying miliary spinelets. These are naked, delicate, cylindrical, and taper to a fine extremity, and are generally arranged in slightly oblique lines, with the middle spine often more forward and longest when three are present, near the lower margin of the plate, and they are directed upward and appressed to the ray. The next row on the sides of the ray, 7.¢., the fourth from the adambulacral plates, has one larger spine on each plate, of equal size to the afore-mentioned. The adambulacral plates are quite within the furrow, and are short but broad, extending far upward almost. vertically. Each alternate plate is developed into a thin prominent ridge, VOL, XXXII. PART I. 2D 162 MR W. PERCY SLADEN ON THE which extends far into the furrow and entirely separates neighbouring suckers, whilst the intermediate plates are smooth, and appear to form the true furrow- wall. Four ambulacral spines, which are moderately long, cylindrical, and slightly tapering, are placed in single file at intervals along the edge of the ridge, the innermost being usually the most delicate, and the outermost is usually the shortest. Two to five small forficiform pedicellariz are attached by membrane to the extremity of the delicate innermost spine. One or two small ciliary spines may be present on the extreme outer edge of the adambulacral plate, adjacent to the first row of longitudinal plates ; and two or three similar small spines are present in the same position at the outer edge of the non- prominent intermediate plates, but no spines whatever are present on the surface of these plates within the furrow. The actinostome is deeply depressed, and the mouth-plates are entirely within the cavity, and are not apposable. They are armed only with pointed, moderately robust spines similar to the larger spines on the ridges of the adambulacral plates. The madreporiform body is small and inconspicuous, and is placed external to one of the interradial plates. The anal aperture is small, distinct, surrounded by a circlet of small ciliary spines, and is placed at the side of the dorso-central plate, and consequently slightly excentric in position. The ambulacral sucker-feet form four rows. They are rather small, sub- conical, and terminated with a small but distinct fleshy sucker. Premature Phase.—The young form, measuring R=11 mm. and 7=2'25 mm., has a very remarkable appearance, owing to the prominence and distinctness of the component plates of the skeleton. The disk is much higher than in the adult. The dorso-central plate is prominent, and assumes the shape of a rounded cone. The interradial and first radial plates are of nearly equal size, and are very tumid or almost semi-globular in form. The plates of the median dorsal line are large and distinct, occupying a large portion of the abactinal surface of the ray. The so-called dorso-lateral series of plates form the margin of the ray, and the intermediate plates are small. Between the ‘dorso-lateral” series and the adambulacral plates there are not more than two fully-developed longitudinal rows of plates, with a partially-developed series commencing to appear between the latter and the adambulacral plates. The terminal (ocular) plates are very large, somewhat resembling the shape of a serpent’s head, and — are armed with one or two pairs of comparatively large robust spinelets, near the extremity, which are directed outwards. The large plates of the disk and the median dorsal line have already a small tubercle, but only some of these bear spinelets. All the plates have a few widely spaced and very minute granules and microscopic ciliary spinelets. The ASTEROIDEA DREDGED DURING CRUISE OF H.M.S. ‘‘ TRITON.” 163 spinelets on the lower rows of plates are comparatively long and well developed. The character of the alternate prominent adambulacral plates is already dis- cernible, although not more than one or two ambulacral spinelets are present on each. The madreporiform body is outside and external to the interradial plate, and almost in the ravine of the interbrachial angle. The anal aperture is excentral, and situated between the dorso-central plate and an interradial plate, standing in the right posterior interradius when the madreporiform body is placed in the right anterior interradius. 12. Asterias Miilleri, Sars. Station 5. August 10,1882. Lat. 60° 11’ to 60° 20’ N., long. 8° 15’ to 8° 8’ W. Depth, 433 to 285 fathoms ; bottom temperature, 43°°5 to 40°:8 Fahr. Il. Stration-Lists. The following lists show the species associated at the respective stations :— Station 1. August 4, 1882. Lat. 59° 51’ 30” N., long. 6° 21’ W. Depth, 240 fathoms ; bottom temperature, 47°°6 Fahr. Cribrella oculata. Station 2. August 5, 1882. Lat. 59° 37’ 30” N., long. 6° 49’ W. Depth, 530 fathoms; bottom temperature, 46°:°2 Fahr. Pteraster militaris. Station 3. August 8, 1882. Lat. 60° 39’ 30” N., long. 9° 6” W. Depth, 87 fathoms ; bottom temperature, 49°°5’ Fahr. Hippasteria plana. Luidia ciliaris. Station 5. August 10,1882. Lat. 60° 11’ to 60° 20’N., long. 8° 15’ to 8° 8’ W. Depth, 433 to 285 fathoms ; bottom temperature, 43°°5 to 40°8 Fahr. Rhegaster Murray.. Asterias Miilleri. Station 9. August 23, 1882. Lat. 60° 5’ N., long. 6° 21’ W. Depth, 608 fathoms ; bottom temperature, 30° Fahr. Pteraster militaris var. prolata. Archaster tenuispinus. 164 MR W. PERCY SLADEN ON THE ASTEROIDEA, ETC. Station 10. August 24,1882. Lat. 59° 40’ N., long. 7° 21’ W. Depth, 516 fathoms ; bottom temperature, 46° Fahr. Archaster bifrons. Astropecten Andromeda. Mimaster Tizard. Cribrella oculata var. cylindrella. Station 11. August 28, 1882. Lat. 59° 29’ N., long. 7° 13’ W. Depth, 555 fathoms ; bottom temperature, 45°°5 Fahr. Archaster bifrons. Astropecten Andromeda. Mimaster Tizardi. Cribrella oculata var. cylindrella. Zoroaster fulgens. . Station 13. August 31, 1882. Lat. 59° 51’ 2” N., long. 8° 18’ W. Depth, 570 fathoms ; bottom temperature, 45°°7 Fahr. Zoroaster fulgens. DESCRIPTION OF PLATE XXVL. 1. Pteraster militaris var. prolata, Abactinal aspect; natural size. 2. Rhegaster Murrayi. Abactinal aspect; magnified 2 diameters. 3. . - Actinal aspect; magnified 2 diameters. 4 5 * Portion of the dorsal surface ; magnified 20 diameters. ss One of the spines of the dorsal surface, seen in profile; highly magnified. 5a. 2 The same spine seen from above ; highly maguified. 6. et Adambulacral plates and portion of the adjacent ventral sur- face ; magnified 8 diameters. i€ 5 Mouth-plates; magnified 10 diameters. 8. Cribrella oculata vay. cylindrella, Abactinal aspect; natural size. 9. Zoroaster fulgens. A young example. Abactinal aspect ; magnified 3 diameters. . 10. ;, Outline of the profile of the same specimen. ea. A Diagram of the plates of the disk, showing their correspondence with the crinoid calyx. The respective plates are marked as follows :— 1. Dorso-central. 2. Under Basals. 3. Basals. 4. Radials. : | ta ATS, LAS Be Dy Wapier roy af We RHEGASTER MURRAYI, var. PROLATA. hea PTERASTER MILITARIS, 1. & Sou Edin‘ ATitchie ZOROASTER FULGENS, lati, CYLINDRELLA, var. CRIBRELLA OCULATA, 8. ( 165 ) X.—On a New Species of Pentastomum (P. protelis), from the Mesentery of Proteles cristatus; with an Account of its Anatomy. By W. E. Hoyts, M.A. (Oxon.), M.R.C.S., Naturalist to the “Challenger” Commission. (Plates XXVIT. and XXVIII.) (Read June 4, 1883.) For the parasites which form the subject of the present communication, I am indebted to my friend Professor Morrison Watson, who found them in a male specimen of Proteles cristatus, Sparrman, of whose myology he has since published an account.* Before entering upon a description of the entozoon, it may be allowable to say a word or two with respect to its host, which is not an animal of everyday occurrence. It was first described a little more than a century ago by SPARRMAN,t the Swedish traveller, as occurring in South Africa, where it is known to the farmers as the “ grey jackal”; he gave it the name Viverra cristata. The only point in his description of any present interest is that its stomach “had nothing but ants in it, or to speak more properly, the white termites,” which might be a valuable hint for any one who had the will and opportunity to investigate the life history of the parasite before us. Since the time of SPARRMAN, it was erected into a separate genus by Gerorrroy St Hinaire, and the name Proteles was chosen as expressing the fact that its anterior extremities were each provided with five, or the perfect number, of toes. It is now generally regarded as a type intermediate between the Hyzenidee and Viverride, its appearance when alive being strikingly like that of small hyzena.{ The animal dissected by Professor Fina remained some days before the abdomen was opened, a circumstance which affected very prejudicially the histological preservation of its inhabitants, and made me hesitate for some time as to whether it would be worth while to attempt a complete account of the creature’s anatomy ; however, in consideration of the rarity of the specimens, it was resolved to make the effort, and the result has been the discovery of some interesting anatomical relations, although the account of the minute structure is in many particulars less complete than it would otherwise have been. * Proc. Zool. Soc. Lund., p. 579, 1882. t Sparrman, AnpREw, M.D., A Voyage to the Cape of Good Hope, Sc. Translated from the Swedish original, London, 1786, vol. ii. p. 177. t Fuowsr, Proc. Zool. Soc, Lond., p. 474, 1869. WOL, XXXII, PART. I, QE 166 MR W. E. HOYLE ON THE ENCcLosING Cyst. The Same! to the number of about ten, were enclosed in cysts in the mesentery, and their appearance is shown in the accompanying woodcut (fig. 1). Each is coiled into a more or less complete circle, and, in every case examined except one, the ventral sur- face formed the convexity of the curve. Fig. 1. General appear- The cyst itself presents nothing in its structure worthy of ance of the encysted : ° . Pee 5 parasite, special note ; it consists of closely interwoven fibrils of connec- tive tissue, imbedded in a quite homogeneous matrix; the wall is about 0:05 mm. thick, and it is more compact towards the inner than the outer surface. THE EXTERNAL APPEARANCE. The form of the body is (Pl. XX VII. fig. 1), speaking generally, cylindrical in the anterior half, and slightly tapering in the posterior, until it ends in a blunt cone. In some specimens the last two segments presented an appear- ance which may be aptly described in the words used by Dixstne in speaking of | another species, “‘cute externé in forma preeputii”; but this was by no means constant. The head is hemispheroidal, and is followed by a smooth cylindrical portion, gz ~=which is of very variable length ; in some cases it scarcely seems ’ to exist at all, whilst in others it measures from 2 to 3°5 mm. (cf Pl. X XVII. fig. 1, and woodcut, fig. 2). ; This is succeeded by a number of annuli, which give the a Lie ae body a decidedly vermiform appearance, although, as will be seen in the sequel, this segmentation is scarcely at all reproduced in the internal organisation. The number of the annuli varies with the sex, and also, though to a less extent, with the individual ; it amounts in the males to 16 or 17, in the females - to from 18 to 22. Each of these rings is separated by a constricted portion of the body, which may conveniently be termed the “interannular space”; these are somewhat less than the annuli, not only when measured transversely to the creature, but also longitudinally, except when it is very fully extended, under which circumstances the two sets of rings become about equal. Furthermore, the interannular spaces are of much weaker consistency than the annuli, as will be explained in treating of the internal anatomy ; and in correlation with this fact, it is to be noticed that when the animal is coiled up, it is the interannular spaces which give way to allow of this, the annuli scarcely undergoing any change at all in breadth, but approaching each other on the concave aspect of the curve. — On the ventral surface of the head, and about 1 mm, from its anterior A NEW SPECIES OF PENTASTOMUM. 167 margin, in the middle line, can be readily seen, even with the naked eye, a circular or slightly oval mark ; this is the lime which indicates the boundary of the oral papilla (woodcut, fig. 2). On either side of it are two slits, about 0°5 mm. in length, whose anterior extremities converge towards the middle line ; these are the orifices of depressions of the cuticle which contain the hooks, and the points of these may generally be seen, under a low magnifying power, protruding from them. The orifices of the sexual glands are somewhat difficult to observe, but in many cases they can be made out by careful examination, after the spirit has been allowed to evaporate from the specimens. The male genital openings are two in number, and are situated about 1 mm. behind the mouth, close to the middle line, and one at either side of it (Pl. X XVII. fig. 1, 4.0). The female genital apparatus opens also in the middle ventral line, but within less than 1 mm. of the posterior extremity. All three are perfectly simple orifices, with- out any prominence. These were all the points worthy of note observed on the external surface. I could find no tactile papille, such as are to be seen in Linguatula tenioides, although I looked for them with great care. THE Bopy- WALL. The wall of the body consists of three distinctly marked layers— 1. The Cuticle. 2. The Epidermis. 3. The Subepidermic Layer. 1. The Cuticle (Pl. X XVII. fig. 9, cw) is a thin even layer which covers the whole surface of the body, including the invaginations in which the hooks are situated, and sends inwards prolongations which line the cesophagus, the rectum, and the genital ducts. Its thickness is on the average about 0°01 mm., and presents no noteworthy changes in different parts of the body, except that it is slightly thinner in the invaginated portions. There can be little doubt, from the analogy of different forms of life, that it is composed of chitin, although I attempted no investigation on this point, beyond ascertaining the fact that it did not dissolve in boiling solution of | caustic potash. It is to all appearance quite structureless, even when a examined under high powers of the microscope ; no trace could be found of | the pores mentioned by Leucxarr in L. tenioides,* nor did the cuticle appear to be divided into two distinct layers, which was probably owing to the | immaturity of the specimens. * Bau u, Entwick. d. Pentastomen, Leipzig u. Heidelberg, 1860, p. 30. 168 MR W. E. HOYLE ON The aunuli, however, are perforated by large pores or “ stigmata,” arranged _ in from 6 to 8 irregular rows, but none of these are found in the interannular _ spaces. ] These stigmata are about 0°014 mm. in diameter, and almost circular in form, and when seen en face present a double contour, which is due to the difference in density of the cuticle immediately surrounding the stigma ; when seen in section they appear very slightly constricted, so as to approach an hour-elass in shape (Pl. XX VII. figs. 9 and 11); the cuticle immediately sur- rounding the stigma is more highly refractile, and therefore probably also of greater density than the other portions ; but there is no clear line of demarca- tion between these as indicated by Leuckart in L. teemoides.* In some cases” the portion of cuticle around the stigma is slightly thickened, although this is by no means constant. A surface view of the cuticle shows, moreover, a number of small irregularly oval markings, arranged in fairly even rings around the pores, and producing an appearance which recalls that of a transverse section of bone with its Haversian canals and lacune (Pl. XX VII. fig. 2). These marks are due to the extremities of the epithelial cells, which form the next layer of the body- wall, as was very distinctly visible in one small portion of the cuticle which had this layer still attached to it. “ While treating of the cuticle it will be well to describe the hooks which are modified portions of it. Their form is shown in the drawing (Pl. XXVIL. figs. 3 and 12) better than it can be described in words; they are seen to be — composed of two separate joints, moved by appropriate muscles, which will be treated of in the sequel. Their homology has been fully discussed by Lruckart in his classic monograph, and my investigations have not enabled me to add anything to what he has written upon this head. 2. The Epidermis, which follows immediately upon the cuticle, is a single layer of columnar epithelial cells, 0-012 to 0°02 mm. in thickness (PI. XX VII. fig. 9, ep). The cells contain a distinct nucleus, generally oval in form, and situated in varying positions in different cells ; in some cases a nucleolus was visible. 3. The Subepidermic Layer (P\. X XVII. fig. 9, par) composes the greater part of the body-wall of the animal. It varies greatly in thickness, but on an average may be taken at 0°2 mm., the extremes being about 01 mm. and 0°35 mm. ; as a general rule, it is thinnest along the dorsal surface, and in the narrow ventral intermuscular space (see p. 169) it is not unfrequently absent altogether. The cells of which it is made up are of very various sizes and shapes ; occasionally their diameter nearly equals the length of the epithelial cells, but * Loc. cit., p. 31, Tab, i, figs. 7 and 8, A NEW SPECIES OF PENTASTOMUM. 169 in most cases they are only almost one-third the size of these. They contain a finely granular protoplasm, and a small spheroidal, ovoid, or somewhat irregu- larly shaped nucleus. They are packed closely together, and occupy the whole space between the subcuticular epithelium and the longitudinal muscle bundles. Among them are scattered the large glandular cells which will be described as part of the secretory apparatus (see p. 178); and they are traversed by many of the muscle-fibres, which will also be described in a special section of the paper. Towards the body cavity this layer, or the longitudinal muscle-bundles where they interpose, is marked off in the sections by a clear definite line, which becomes deeply stained. This I take to be the ccelomic epithelium (endothelium), but unfortunately none of my specimens were sufficiently well- preserved to enable me to speak with confidence on this point. THe Muscuitar SYSTEM. When the animal is opened by a median dorsal incision, and the body-wall spread out and examined from within, an appearance is seen such as is shown in Pl. XXVII. fig. 17. Longitudinal bands are crossed by transverse bands, and interspaces, roughly speaking, rectangular in form, are left between them. The ventral median line is marked by a series of square gaps, towards the margins of which | | | are placed a number of radiating fibres. Along the lateral sides of the suc- cessive squares there stretch two broad bands (fig. 17, m./’, m./’), which are com- posed of longitudinal muscular fibres, and, though somewhat variable in their breadth, are nearly as wide as the squares. Beyond these, again, are a number (commonly 8-10) of very much narrower longitudinal bands (fig. 17, m.0). A closer examination confirms the view that these longitudinal bands are composed of muscular fibres, but the case is otherwise with the transverse bands. ‘These, as was pointed out by LEucKarr,* are cellular in structure, and consist largely of the glandular cells which will be alluded to when treating of the subepidermic cell-layer (p. 178). They correspond with the external annulations of the animal, and on focussing deeply through these bands the stigmata are seen, whilst none are visible in the spaces between them. The muscular system of this parasite cannot, however, be fully understood by means of such a preparation as has just been described; to render our knowledge complete, transverse sections are necessary ; and, when the informa- tion derived from these is taken into account, there are seen to be present three systems of muscular fibres— * Levckart, loc. cit., p. 39. 170 MR W. E. HOYLE ON 1. Transverse fibres, immediately underlying the epidermis. 2. Longitudinal fibres, arranged in bundles, lying for the most part imme- diately below the coelomic epithelium. 3. Oblique fibres, placed obliquely, however, both to the dorso-ventral plane of the body and to planes cutting it transversely. 1. The Transverse Layer of muscular fibres is very thin, it being only one fibre thick ; in some cases there seemed to be two or even three such layers, but this appearance was probably owing to a slight obliquity of those particular sections. It is situated immediately within the epithelium, so that its fibres are for the most part parallel to-the cuticle, and they lie in planes which are approxi- mately transverse to the body of the animal. 3 The appearance of this sheet of fibres is seen in Pl. X XVII. fig. 14; the fibres branch dichotomously, and at intervals unite with each other so as to form a fine network with elongated meshes, in which the cells of the parenchyma of the body-wall may be noticed. In the body proper of the animal this layer is developed almost exclusively on the sides, its fibres not often crossing the ventral, and hardly ever the dorsal median line. in one specimen about 1 mm. from the caudal extremity, I noticed a small patch of these fibres dorsally situated, but this might have been an individual — peculiarity. The cephalic region, however, shows a great change in the arrangement of this layer, for there it is best developed on the dorsal and ~ ventral aspects of the body, and to a much smaller extent on the sides. With respect to the nature of the individual fibres, but little can be said. They are very thin (about 0:001 mm.), and I could not detect in them that transverse striation which was noticed by Lruckarr.* Some of the better preserved specimens showed, however, a kind of sarcolemma, an exceedingly thin sheath with a well-defined outline, and with small ovoid nuclei (Pl. XX VII. fig. 16, nz). 2. The Longitudinal Layer varies a good deal in its arrangement in different parts of the animal, and it will be advantageous to describe it as seen at about the middle of the body. » & CG ra : = } -—~ / { | - , ‘ ) \ bY. Soc. EDINe Vou. xxxi1, PLATE XXVIII, ZO89 SLD 193 XI.—-On Superposed Magnetisms in Iron and Nickel. By Professor C. G. Knott, D.Sc. (Plate XXIX.) (Read 2nd July 1883.) The experiments which form the subject of this paper are designed, in the first place, to test the relation pointed out by MAxweLi* between JouLr’s discovery of the lengthening of iron in the direction of magnetisation,t and WIEDEMANN’S later researches into the twisting of iron under the influence of longitudinal and circular magnetisations,{ and, in the second place, to investi- gate the corresponding properties of nickel. According to JouLE’s discovery, an iron bar or wire lengthens in the direc- tion of magnetisation, and contracts in directions at right angles thereto. The extension is greater for a stronger magnetising force, and, if the metal is subjected to traction in the direction of lengthening, is smaller for a greater traction. In the experiments:to be described a wire was fixed at its upper end, and stretched vertically by means of an appended mass. It passed cen- trally through a glass tube of nearly the same length, round which a helix of wire was wound. The length of the helix was 34°3 centimetres, and the total number of coils 196. A current passed through the helix magnetised the wire longitudinally. At the lower end of the wire was fixed a short copper wire, which dipped into a pool of mercury. By this means a current could be passed along the wire so as to magnetise it circularly. The twist produced under the joint influence of the longitudinal and circular magnetisations was measured by the deflection of a spot of light focussed upon a millimetre scale after reflection from a mirror attached to the lower end of the wire.. Both the magnetising currents were measured on a Helmholtz tangent galvanometer. The method of experimenting was as follows :—One of the currents was kept steady, while the other was varied through a considerable range. When both currents were flowing the free end of the wire came to rest in a definite position, which was registered by the reading on the seale. -One of the currents was then reversed, and a second reading obtained. The difference between these readings was approximately four times the angle.of twist. By successive * See Maxwewt’s Electricity and Magnetism (2nd edition, vol. ii. § 448). The first edition comesto a wrong conclusion, in-consequence of a misprint in WIEDEMANN’s Galvanismus (1st edition, Bd. ii. § 491). See also Curystat’s article on “‘ Magnetism” in the Encyclopedia Britannica (vol. xv. pp. 269, 271). + Srurceon’s Annals of Electricity, vol. viii. p. 219; and Phil, Mag., 1847. { Wrepemann’s Galvanismus, 1st edition, Bd. ii. § 491. VOU. XXXII. PARTI. Ail 194 PROFESSOR C. G. KNOTT ON THE reversings and re-reversings of the current, a series of readings was obtained whose differences gave a good mean. From the numbers so deduced the true twist expressed in radians was easily calculated. The first experiments were made with an iron wire, ‘00435 square centi- metres in cross section. The most important are those in which the current along the wire (the linear current) was kept constant, while the helical current was made to vary from under half an ampere to nearly six amperes. Five different series were taken with different values of the steady current. In the following tables the upper row gives the successive values of the helical cur- rents in amperes, and the lower the corresponding twists in radians x 10°. Group A. Experiment J. Linear Current = 575 Amp. Helical Current, 0377 Oval PF 1889 2-045 2°573 5019 Experiment II. Linear Current = “723. Helical Current, | 0°368 | 0°758 | 1:289 | 1676 | 2°025 | 2°436 | 2902 | 3:°375 | 5-019 SS ee Oe ee eee Twist, ‘ 4 307 597 816 877 907 900 881 832 703 Experiment III. Linear Current = 1891. Helical Current, 0°393 | 0-741 |1:254 | 1566 |1:987 | 2-488 | 2°925 | 3-527 | 4-068 | 5°781 : pees ‘ ; 372 | 762 | 1179 | 1335 | 1389 | 1389 | 1387 | 1345 | 1279 | 1077 Experiment IV. Linear Current = 3°157. Helical Current, | 0:460 0-700 1:254 1991 2488 | DB Lo7 4:592 Rf | a | | Twist ; 342 775 | 1251 1567 1680 | 1710 1682 SUPERPOSED MAGNETISMS IN IRON AND NICKEL. 195 Experiment V. Linear Current = 4-068. Helical Current, 0-410 0-700 1:254 1:891 2°385 3039 4:214 Twist, é 5 | 390 810 1303 1678 1802 1886 1884 Three series were taken with steady helical current and varying . linear current. They are as follows :— Group B. Experiment I. Helical Current = ‘611 Amp. Linear Current, 0-410 0-716 1:272 | . 1943 2°395 3051 3°899 Twist, : p 126 357 ‘TAQ 1030 1125 1197 1225 Experiment II. Helical Current = 1:987 Amp. Linear Current, 0:418 0-750 1:276 1-948 2°364 2:970 3°803 Twist, ; : | 127 312 | 767 1190 1358 1576 1754 Experiment. III. Helical Current = 3:229, Linear Current, 0:505 | 0:893 1:320 1°703 2-724 Twist, : ; 152 | 387 718 877 1367 In both these series the wire was under a tension of 1950 grammes’ weight. The representative curves are shown on Plate XXIX., iron groups A. and B. The current strengths of the varied current are laid down horizontally, and the corresponding twists vertically. The two series differ markedly, the A group showing a maximum twist for an intermediate current strength, the B group giving no such indication. That such a difference between the two cases should exist is not to be wondered at, since the magnetisation due to a 196 PROFESSOR C. G. KNOTT ON THE linear current follows a different law from that due to a helical current. Indeed, it is impossible to magnetically saturate an iron wire by means of a linear current. Further than this, experiments of the B type need no discussion. The maximum point in the curves of group A is a constant characteristic of all similar cases, as will be seen by reference to the curves of groups C and D. These represent further experiments with iron wires, in which is studied | more particularly the effect of tension upon the amount of twist. In the fol- lowing tables there are three distinct series under each experiment correspond- ing to three different tensions. The last column contains the tensions expressed in grammes’ weight. i Group C.—Cross Section of Iron Wire = ‘00276 sq. cc. Experiment I. Linear Current = 033 Amp. Helical Current, 0:952 1657 2-489 3'°039 a v3) 5'198 || Tension, 561 632 632 607 523 413 1360 Twist, . : 1013 1148 1161 1097 1013 875 712 1123 1284 1258 1265 1097 923 388 Experiment II. Linear Current = 1:476 Amp. Helical Current, 0°533 |0°952 | 1657 | 2 489 | 3:039 | 3°723 | 5:198 |) Tension. 484 | 1213 | 1471 | 1484 | 1406 | 1299 | 1097 1360 Twist, . 5 458 | 1077 | 1452 | 1594 | 1529 | 1426 | 1187 712 439 | 1045 | 1503 | 1658 | 1684 | 1561 | 1323 388 Experiment III. Linear Current = 2°412 Amp. | Helical Current, | 0°533 | 0-952 | 1-657 2°489 | 3-039 | 3°723 | 5:198 || Tension. | 0484 | 03677 | 1332 | 1445°| 1510 | 1555 | 1394 1360 Twist, - ‘O< | 0490 | 1187 | 1742 | 1974 | 1974 | 2019 | 1800 712 | | 0394 | 0923 | 1394 | 1723 | 1820 | 1800 | 1645 388 SUPERPOSED MAGNETISMS IN IRON AND NICKEL. Group D.—Cross Section of Iron Wire = ‘000714 sq. cc. Helical Current, Twist, 0508 103 142 129 Experiment I. Linear Current = 0°65 Amp. 197 Helical Current, |0°508 | 0°995 1598 Twist, ae 252 The direction of twist was as. found by WIEDEMANN. passed down the wire from the fixed to the free end, and the wire is mag- netised with north pole downwards, the free end, as looked at from above, twists in the direction of the hands of a watch. As pointed out by MAxweE.Li and CuRyYSTAL, this agrees with JouLe’s discovery mentioned above. 0995 |1:593 | 2262 | 2°615 |3:157 | 4-068 || Tension. 290 | 368] 348 | 336] 329 | 265 388 400 | 613°} 619 | 613] 574] 484] 258 484} 697 | 761) 787} 761 | 723 |) 129 Experiment II. Linear Current = 0:973 Amp. 2:262 |2°615 | 3157 |4:068 || Tension. 794 | 839 | 865 | 807] 774 | 388 o 923°} 1090 | 1077 | 1013 | 884] 208 613 | 916 | 1045 | 1123.| 1084 | 1045 | 129 If the current is For the circular magnetisation due to the down current is right handed with reference to the current. Hence the resultant magnetisation lies in a direction inter- mediate to the circular and longitudinal magnetisations at any point; and as the iron extends in the direction of magnetisation, and contracts at right angles thereto, there will be a lengthening of the wire in a direction oblique to the axis, such as to cause a twist in the direction specified. The amount of twist depends not only on the magnetising force in this oblique direction, but also upon the obliquity, so that a maximum twist for an intermediate value of the helical current is quite in accordance with JouLe’s result that the extension Suppose, for example, that the circular and longitudinal magnetisations at a point on the wire are a and £, and that these give a resultant magnetisation ,/a?+ 6? in a direction making an angle, whose tangent is a/8, with the vertical line through the point. along this direction be represented by » (a? +"), an assumption approximately ‘increases with the magnetisation. Let the extension 198 PROFESSOR C. G. KNOTT ON THE true according to Jounr’s researches. Then the amount of twist per unit length of the wire will be r=p(a? + f?)a/B=(a*/B+ a8). If a is constant, 7 has a maximum value when p=a: If B is constant, there is no such maximum value of 7. A comparison of curves A and B (Plate X XIX.) bear this out fully. Hence, in the case of constant circular magnetisation and varying longi- tudinal magnetisation, the twist will first mcrease and then diminish as the latter is increased to its saturation point. For a stronger circular magnetisa- tion the maximum point is pushed further on, until, when the circular magnetisation has reached the saturation point, there will be no subsequent fall off in the twist, z.e., no true maximum point. These remarks apply strictly to a thin iron cylinder. In the case of a wire the effects are complicated. Still the curves on Plate I. bear out in a remarkable way these conclusions. Thus in fig. A the maximum point obviously occurs further to the right in the higher curve. In the following table a direct comparison between the linear current strength and the helical current strength, which corresponds to the maximum twist, is established :— Linear Current, ; : : : ‘ 0575 | 0°723 | 1°891 | 3:157:| 4-068 Helical Current for Maximum Twist, ; 2 Die, 2°4 3:1 3°5 + The highest curve has no distinctly marked maximum, a result in close agree- ment with the foregoing deductions. The other series of curves bear out the same conclusion. JOULE also found that the extension for a given magnetisation was smaller when the wire was subjected to a greater tension. Hence, in general, we should expect the twist in a wire due to superposed circular and longitudinal magnetisations to be less for the greater tension, since the longitudinal exten- sion will be diminished. This conclusion is quite borne out by curves C and D. ,With only one exception (namely, C III.) an increase in tension is accompanied by a decrease in twist. This result is not in accordance with WIEDEMANN’S, who found the twist to be nearly independent of the tension. Possibly, however, he worked with a thickness of wire which for the special combination of current strengths and tensions was not sufficiently sensitive to the change of tension. A glance at the curves C and D shows how much greater is the sensitiveness to tension change for certain combinations than for others. SUPERPOSED MAGNETISMS IN IRON AND NICKEL. 199 JOULE further discovered that when the tension exceeded a certain value, there was contraction instead of extension in the direction of magnetisation. This ought to give in these experiments a reversed twist under tensions higher than this critical value. Of this, however, there was no indication, although the thicker iron wire broke under a tension of 2600 grammes’ weight, and was, therefore, subjected in experiments A to a comparatively high tension. It remains now to consider nickel. The experiments were conducted in precisely the same manner as in the case of iron. The following are the tabulated results for a nickel wire of cross section, ‘0056 sq. cc., length 36 cc., and tension 1950 grammes’ weight ; first, for a steady linear current and varied helical current, and second, for a steady helical current and varied linear cur- -rent. As before, the currents are in amperes, and the twists in radians x 10°, Group A. (Linear Current Steady.) Experiment I. Linear Current — 0°674 Amp. Helical Current, | 0°368 |0°700 | 1-210 |1:891 | 2°303 | 2°616 |3:016 | 3:997 Twist, ; | 109} 200; 429} 765 952 | 1077 | 1206 | 1458 Experiment II. Jinear Current = 0°995 Amp. Helical Current, | 0°307 | 0-410 | 0-741 |1:276 | 1-680 2084 2°594 3s Twist, , ‘ Doe LOSa) 281s oO}. 8704 L052.) 1303 | 1897 Experiment III. Linear Current = 2'510 Amp. Helical Current, | 0°268 | 0°700 | 1:210 |1:891 | 2:303 | 2-616 | 3-016 | 3-997 Twist, , : 152 268 596 | 1119 | 1410 | 1923 | 2145 | 2552 Experiment IV. Linear Current = 3:039 Amp. Helical Current, | 0°205 | 0°393 | 0°741 | 1:°313 |1°726 | 2°084 | 2594 | 3-591 | 5-384 948 | 1310 | 1553 Twist, . ; | 20 | 74 | 436 1894 | 2345 | 2819 200 PROFESSOR C. G. KNOTT ON THE Experiment V, Linear Current = 4441 Amp. | Helical Current, | 0205 | 0°451 ors 1:298 | 1°750 | 2°084 | 2°594 | 3565 | 5-479 Twist, : ; 123 |. 219 | 584 | 1145 }~1535 | 1797 |. 2126 | 2626 | 31o2 Experiment VI. Linear Current = 5-578 Amp. Helical Current, 0:368 0-576 0:952 1521 1:938 2°784 4:519 Twist, 5 5 171 345 855 1442 7, Group B. (Helical Current Steady.) ‘Experiment I. -Helical Current = 0°658 Amp. Linear Current, | 0°368 | 0°578 007 1:815 | 2°368 | 2°724 | 3:277 | 3°815 | 4°796 Twist, . ; 39 v4 132 204 383 | 505 | 702} 897 | 1019 Experiment II. Helical Current = 1:891 Amp. Linear Current, | 0°327 | 0°582 | 1:141 |1:891 | 2°891 | 3-463 | 3-927 | 5-019 | | FE | | | Twist, . ; 57 89 | 180]; 420} 954 | 1871 | 1700 | 1991 ExperimentIII. Helical Current = 2°702 Amp. Linear Current, 0°327 | 0582 |1:141 |1°891 | 2°891 | 3-463 |3:927 | 5-019 ee ee ee ee Twist, .. : | 29 89 | 216] 457 | 1126 | 1545 | 1948 | 2322 SUPERPOSED MAGNETISMS IN IRON AND NICKEL. 201 Experiment IV. Helical Current = 2:405 Amp. Linear Current, 0:893 1:520 Wigs Vas 2°812 4334 4-680 ee Twist, . : 368 819 1355 1561 1865 1890 Experiment V. Helical Current = 3°338 Amp. Linear Current, 0:867 1:494 1-797 2°298 2°702 3°277 4519 Twist, . : | 439 929 1226 1639 1909 2168 2374 The representative curves are shown on Plate XXIX., nickel groups Aand B. The chief points of difference between the behaviour of iron and nickel are these: first, the direction of twist in the nickel is the reverse of that in the iron; and second, there is no maximum in the nickel A group of curves. The free end of the nickel wire twists.in the direction opposite to the hands of a watch, as looked at from above, when the wire is traversed by a down current, and is magnetised with north pole downwards. This agrees with BarRETT’s discovery,* that nickel contracts when magnetised. The possibility of a maximum, again, depends upon how the amount of contraction varies with the magnetisation, and also, since the abscisse represent currents and not magnetisations, upon the relation which holds between these last, The B curves are very similar in form to the B curves of the iron. It will be noticed that curve IV. of this series lies for the most part higher than curve III., although the steady helical current is smaller in the former ; also that L., IL, and III. seem to fall together, as belonging to the same set, while IV. and Y. form a system by themselves. The reason of this would seem to be that between the dates, June 2nd and 4th, namely, on which these sets were taken, the nickel wire underwent some physical change. Probably this was of the nature of a change in temper, since on the latter date the nickel wire was for an instant traversed by a current of sufficient strength to make it glow red hot. |Taking this consideration into account, and neglecting curve A, III., which is \obviously a bad experiment, we conclude that the twist due to the superposi- jtion of circular and longitudinal magnetisations in nickel wire increases with * See Mature, vol. xxvi. 1882, VOL. XXXII. PART I. 2K 7 Tels AL ‘THMOIN & NOU] NI SWSILUNSVW GHSOduaaNg UPA AL] ‘PUNSIT Y SUES SIL | sazeduy iy 2 | soasdury sueipeg AVON MSC LN vi0- £0- +b z | seredury Q 9 S & 2 | seaedury bole bs et = i oe i + : 900- I 900. 0 =! 10- = at vill 10° Hit i Pca +10+ - +0 alia : V [Pua aio. + 7 at 810: A fy sqaed Gi sedaduy f e Oi, 1 | ag a a e = I = "I f | | L j 3 ile Wi ry a | rai Vi ; 1 900- - < Tr 900: eT Y, a Aly i{" | ng 0 : 21 | om Le } at H e'T em. | / ‘ er ep iG A j ‘asta Fi < P 10- foe! == a 810- [ ‘OD |sta ale all t 20: i ee Lal | juIpy ‘90g ‘AOV ‘suBAT ( 205 ) XIT.—On the Relative Electro-Chemical Positions of Wrought Iron, Steels, Cast Metal, &c., in Sea-Water and other Solutions. By THomas ANDREWS, Assoc. M. Inst. C.E., F.C.S. (Plates XXX. to XXXIV.) (Read 15th January 1883.) The experiments contained in this memoir were made by the author with the galvanometer on wrought iron, steel, cast metal, &c., bars and plates, arranged in galvanic circuit in sea-water and various other waters and solutions, to determine the relative electro-chemical position of these metals under such circumstances. These varieties of the same metal iron are of such vast and universal utility that accurate information respecting any of the properties possessed by them cannot fail to be of interest. A knowledge of the relative electro-chemical positions assumed by wrought iron, steels, and cast metal when in galvanic connection in sea-water is of importance as determining their respective liability to electrolytic disintegration when combined in marine works and structures, and a research of this kind presents features of interest capable of practical application In many ways. When plates or bars of wrought iron, steel, &c., are connected in circuit and immersed in sea-water or other solution, and attached to a delicate galva- nometer, an electric current is set up of varying power according to the difference of chemical composition or mechanical or physical properties, &c., of the wrought iron and steels employed. The following experiments were undertaken by the author to measure, if practicable, the extent of this action, and to endeavour to determine the relative electro position of the various steels, wrought iron, and cast metal, with some degree of exactness. TABLE A. Analyses of Steel, Wrought and Cast-Iron Bars. Percentage Composition. Descripiion. ore Combines Silicon. Sulphur. |Phosphorus.| Manganese. Tungsten. (by eee ce). Soft Siemens-Martin steel, aa bai de des a sg ae i Wrought iron, A ; ot Trace | ‘224 None ‘239 ‘071 ess 99-466 Soft steel (Firth’s), . alla Miata: 570 032 Trace 066 147 side 99°185 Bessemer steel, P : Ree 550 None 032 175 216 ae 99-027 Puddled steel, 5 : ate "440, 144 048 149 Trace av 99-219 Puddled steel (chilled), . Peete 490 140 004 ‘073 ‘215 a 99-078 Hard steel (Firth’s), : ihe 1600* | +145 002 025 183 one 98-045 Cast metal, . ; ‘ 2:400 | 1:000* | ‘570 ‘140 580 860 ahs 94-450 Tungsten steel, . 6 ous 1°750* | +135 069 139 “720 9-270 87°917 * By combustion. VOL. XXXII. PART I. 21 206 MR THOMAS ANDREWS ON THE RELATIVE One interesting fact observed in the course of these experiments is that wrought iron and steels, &c., are not static in their relative electro-chemical posi- tions, and when immersed in sea-water, or other solutions in connection with each other, cannot exactly be regarded as constant elements. The relative electro- chemical position is also varied, according to the nature of the solutions employed. The chemical composition of the iron and steel bars and plates employed in the following experiments is shown by the accompanying analyses. TABLE B. . Analyses of Steel, Wrought and Cast-Iron Plates. Percentage Composition. Description. Grarhile Compings ilicon, | Sulphur. | Phosphorus. | Manganese. (by atone Soft Siemens-Martin steel, . ie 170 ‘071 ‘117 ‘077 "627 98'938 Soft steel (Firth’s),. Relies oo “460 074 025 210 184 99:047 Wrought iron, : : F 500 Trace. 206 024 454 396 98-920 Soft’ Bessemer, é : : ane 150 015 ‘lll 064 ‘540 99°120 Hard Bessemer, . . ; het 510 068 113 ‘087 1153 98:069 Hard Siemens-Martin steel, . ong 720 ‘080 102 143 1:239 97°716 Hard steel (Firth’s), . .| ... | 1-407*| -121 | -036 080 360 97-976 Cast metal, . . . . 1500 2:010* “410 ‘250 450 *650 94-730 * By combustion. Some of the physical properties of the bars employed are indicated by the following tests to which they were submitted :— TABLE C. Original, Ultimate Stress. Fractured. iabanenes Stress i per Square a Appearance Description Difference, Inch of ole Fractured i re. Size.| Area Total, | Per Square Inch Size.) Area. [= a)pom "Area, Inch Per = ‘ * | of Original Area. . ne Por neh. ! Cent. Area Cent. Inch.} Sq. in. Ibs. Lbs. Tons.|Inch.| Sq. in. Ibs. Tungsten steel, |-30 | -0 = 8011: : ; eC S : 10 ¥ silky 8 ’ 70 |12,561 179,443 =80°1)'27 | -057 013 {18-6 | 220,368 [0°73 | 7:3 90 % granular Hard steel, —. |-298 | 0697 |10,967 |157,346 = 70-2)-289 | -0656 | 0041 | 5°8| 167,179 | -12| 1:2] 100 % granular Bessemer steel, |-297 | -0693 | 9,851 |142,150 =63'4|-275 | 0594 | -0099 |14-2| 165,841 | -16| 16] 100 % granular Puddled steel, |-296 | 0688 7,180 |104,361 = 46°6)-257 | 0518 | ‘0170 |24°7 | 138,610 | -27| 2°7) 100 % silky Puddled steel (chilled), 298 | 0697 | 6,322| 90,703 = 40°5/-295 | 0683 | -0014 | 2°0| 92,562 | -07| 0-7 (i? ee Wrought iron, |-296 | 0688 6,028 | 87,618 = 39°1)-284 | 0633 | 0055 | 7°9| 95,229 | 11] 11} 100 % fibrous Soft Siemens- Martin steel, I 28 ‘113 | 8,328 | 73,699 =32'9|-25 |:049 |:064 [56:6] 169,959 |1°97 |19°7| 100 % silky 100 % granular | (mottled) Cast metal, —. |-293) 0674 | 1,436] 21,305= 9-6|-293] 0674 |-0000 | 0:0] 21,305 | 00] 0-0 A ELECTRO-CHEMICAL POSITIONS OF WROUGHT IRON, ETC. 207 GALVANOMETER EXPERIMENTS. The bars of wrought iron and steels, &e., used in the experiments were exactly 297jths of an inch (7°5 millimetres) in diameter, and were cut as test pieces from near the centre of bars of wrought iron and steel, manipulated as near alike as possible for purposes of comparison. All the wrought iron and steel, &c., plates employed in the following experiments, except where otherwise de- scribed, were exactly three inches square (representing a total surface area of exposure of eighteen square inches for each plate, exclusive of the edges which were alike in each case), and were of uniform thickness, and in shape as shown in fig. No. 1. The bars and plates were of the chemical composition and possessed of the general physical properties, as shown in the preceding tables, and with the exception of those covered with scale (magnetic oxide), were all smoothly polished bright. The experiments on the various samples were conducted in each case in precisely the same manner for purposes of exact comparison, and very many times repeated, but in the same manner for corroboration, the results being derived from exactly corresponding experiments in each case, the bars and plates in the solutions being kept exactly the same distance apart, &c., in fact, every precaution was adopted to insure accuracy. The records in the following tables of galvanometer experiments are the result of some 3000 carefully made observations by the author, some of which were thirty or forty times repeated to insure accuracy. It should be understood that the following experiments do not represent fixed or permanent deflections ; but they are the results of a number of observa- tions made in precisely the same manner in each case for purposes of exact comparison between the various steels employed. In cases where necessary the author has recorded the highest and lowest deflection noticed, in addition to the averages to illustrate the variations better. In the galvanometer experiments the bars and plates were all immersed, one pair at a time, in an equal measured quantity of sea-water, or other solutions, and placed in galvanic connection at equal distances apart. The wrought iron, &c., bar or plate, was connected with one terminal of a delicate galvanometer, to the other terminal of which was attached the bar or plate of steel, &c. The connections were made with insulated copper wires properly secured to the ends of the bars or plates with screw clips. The measurement of the galvanic action is recorded in the tables. [Inserted April 5, 1883.—The galvanometer selected for these experiments 208 MR THOMAS ANDREWS ON THE RELATIVE was a low resistance galvanometcr, with jewelled centre, accurately graduated throughout the circle. To observe the fractional parts of degrees with accuracy, the author took the observations through a powerful lens fixed above the galvanometer, by means of which arrangement and from the author’s experience in using it in this manner, and from repeated check experiments, it was found that variations. of the needle could be taken to about the ;th of a degree of deflection. The galvanometer was examined by the Wheatstone Bridge arrangement with standard resistance coils, and the resistance was found to be 220 ohms. A Daniells cell through a resistance of 9180 ohms (including the resistance of the galvanometer) gave a deflection of one degree, or 5;gpth of an ampére produces a deflection of one degree (taking the electromotive tone of the Daniells cell as unity). From these observations, therefore, the strength of the electric current represénted by the deflections recorded in this paper may be calculated ; and as the resistance in the cells containing the sea-water would not exceed 3 ohms, an indication of the E.M.F. can be obtained. In taking all readings the galvanometer was very carefully adjusted before each observation, and all deviations from vibration, tremor, or other causes,. carefully guarded against; the greatest care was exercised in the experiments, the point of the needle being under constant observation, and the slightest variations were carefully watched as the differences to be dealt with in course of these experiments were sometimes small. The author is satisfied that the observations recorded represent accurately differences arising from the nature of the metals and solutions employed. | The experiments on bars, recorded in tables D, E, F, represent the average of the deflections observed on first immersion of the steel and iron bars in the sea-water, the bars on each repetition of the experiment being carefully washed and wiped dry before re-immersion. A very marked feature in the other galvanometer experiments, recorded in table and diagram G, J, Plate XXXII. (these observations extending over longer periods of time), is the steadily changing deflections noticed from the — commencement; this appears to indicate a tendency in the various steels and irons to polarise each other’s electric action, so that in course of time, as. submerged iron and steel becomes coated with oxides, galvanic activity is con- siderably reduced from its first force; but it does not wholly subside. When plates of iron and steel, &¢., in galvanic connection were taken out of the sea-— water (the oxides being washed off) and were re-immersed, the deflections of — the galvanometer arose for a time, afterwards reducing again. The experiments in this memoir indicate that the galvanic relationships 0 the various steels and wrought iron do not remain the same, in sea-water or other solutions, but they appear capable of an interchange of electro-chemic ELECTRO-CHEMICAL POSITIONS OF WROUGHT IRON, ETC. 209 position; for instance, in the experiment with the plates, some of the steel plates took a negative position compared with the wrought iron ; but afterwards the position was reversed. This change of electro-chemical position is a fact of considerable interest, and the author has therefore given as typical some of the full records of the deflections observed in some of the experiments between steels, wrought iron, cast metal, &c. These diagrams, &c., illustrate this tendency in detail. A reference to some of the tables will also show that in many instances the interchange is greatly varied and influenced by the nature of the solutions in which the steels, &c., were immersed. When the steels, &c., were immersed in an acid solution instead of one containing neutral salts, such as sea-water, a noticeable result was, in some instances, an almost complete reversal of electro-chemical position. (See table and diagram G, I, Plate XX XII.) Although the soft steel and Bessemer steel bars in table D are recorded thereon as in the negative position compared with wrought iron, this is not contradictory to the results of similar soft steels in table G, because the results in table D are the first deflections, whereas those in table G indicate the same negative position at the commencement of the experiment; but the electro- chemical position afterwards changes by prolonged exposure. An explanation of this change in the electro-chemical position of the soft steels may be that, as the solution gradually penetrates and acts on the metal, it meets with crystalline networks of higher carbides, &c., and other consti- tuents of varying composition, which would pr ppabh offer varying resistance to the action of the solution, This view of the case would appear to derive support from the observations made “ On the Microscopical Structure of Iron and Steel,” by HENry CLirron Sorsy, Esq., LL.D., F.R.S., from which it would appear that iron or steel of the finest manufacture cannot be regarded as of purely homogeneous composition. The experiments recorded in the following tables were made not only with the object of endeavouring to ascertain the relative electro-chemical position of wrought iron, steels, and cast metal, but also to throw light, if possible, on the amount of galvanic action which takes place practically where these metals are combined in marine or other structures. It will be seen, therefore, that the observations are roughly arranged with this object. Amongst other experiments, measurements were not only taken using zinc, copper, and wrought iron as standards in combination with iron and steel and cast metal, &c., but it will be also observed that bars and plates covered with magnetic oxide were employed, as practically the action of this oxide upon wrought iron, steels, and cast metal in sea-water, &c., is frequently a source of electrolytic disintegration, to ascertain the extent of which forms one object of the following experiments :— MR THOMAS ANDREWS ON THE RELATIVE 210 i — ; “= a -“GLST ‘TE ysnSny ‘soustog RorMaYD “g_ ToNoag ‘uoNTIOOSsY YSyLIG oyy a10Joq par ,“19yV\\ ATETJOO Be ULI, PAATIap ST[V WOLOoIOUO_D SNOLMd oUIOG,, po}qUe ‘1oyyne ayy Aq soded v ur poureyuoo st rayea AreT[[OD plow sty Jo A1osty pue uoTpIsoduroo Teorey eT, “UosTIVdUMIOd YORXS IOF IOUULT SUTLS JY} UL asLd TOL UL apVUL SUOIYLALESGO YT JO 9SVIOAV OT} ST J[MSEL YOuy ‘jooLIOd ore sy[NseT oy} Wosteduuod Jo sosodimd «oy yey} os ‘syuotutredxe saoge oy} [TB ut poXopdura seam ynq { soerd padvys-aepnFeai we se oTVOS WOIL OY, ‘SI [20}S PUL WOIT OI} SB OJOUILIP IUTeS BY} SVL POI OUTZ BT, ‘LaJOULOUVAVS 94} JO WOTJePYep Jo saaisap UL passerdxa WoO OTMATLS VALET 9} MOUS S}[NSeT OY, ee oe LOVE NT GG-0 \ wo} d LI-0 d 81-0 N 00-1 d FG-0 N. 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Die > Hxperiments on the Gulvanic Action set up by a series of Burs of Wrought Iron and various Steels immersed in Sea-Water. The sample bars were portions cut from the same rods whose composition and general properties have been previously described. The deflections of the needle of the galvanometer are shown in the accom- panying tables K and L. TABLE K, Deflection of the Galvanometer Needle, produced when Bars of Wrought Ivon and Hard Cast Steel (all of the same size and polished bright) were immersed in Sea-Water forming the elements of Galvanie Action. Average of eight Experiments in each case., Deflection of Needle. | 3 Bars of wrought iron connected with 3 Bars of hard cast steel, 1:28 degrees ee +3 ; 4, 5 138i, an; : ; ony 3 2s 15 Owls fs 5 Onges +5 ETON, hs ates > » ieee ‘i PA 55 Se 3 55 Ole ies . ZEAOF « . 55 The wrought iron was the electro-positive metal. TABLE L. Deflections of the Galvanometer Needle produced wien Polished Bars of the Wrought Tron ail the Sott Steel, the same size, were immersed in Sea-Water forming the elements of Galvanic Action. Average of six Experiments in each case. Deflection of Needle. 3 Bars of the wrought iron connected with 3 Bars of the soft 1:00 degrees + » ”» ” 4 » » 1:50 » 5 5 =e ” ”» » Pe) oh) cast steel, The wrought iron was the electro-positive metal. The whole of the preceding galvanometer experiments afford some compari- | son of the galvanic action set up by the exposure of combinations of wrought iron, steel, &c., to sea-water, colliery mineral waters, or river waters, &c., of known composition, and are so far interesting, because in actual practice wrought and cast iron and steel bars, plates, &c., are frequently exposed to similar destructive influences. 218 RELATIVE ELECTRO-CHEMICAL POSITIONS OF WROUGHT IRON, ETC. In experiments made by the author to ascertain the galvanic action taking place between wrought iron and steels, &c., over more extended periods of time, it was found that galvanic action between these metals had a tendency to be reduced from various causes during prolonged exposure to sea-water and other solutions. The general deductions from the foregoing observations are that— 1st, The electro-chemical position of wrought-iron, steels, and cast metal appears capable of changing according to the nature of the solution in which they are immersed, an acid solution producing frequently different results from ‘one containing only neutral salts, This interchange of electro-chemical position between the metals being also frequently observable both when immersed in an acid and neutral solution, as indicated by the preceding tables. 2nd, A measurable difference is noticeable in the behaviour of the various. steels, &c. employed under the conditions recorded in the experiments. This. would lead to the conclusion that the danger from the greatly increased corrosion in sea-water, &c, through galvanic action, is a factor not to be disregarded in compound structures of the preceding metals. The tendency to polarise each other’s action, and the consequent interchange of electro-chemical position, would appear to exert a considerable influence in retarding and reducing this source of danger. Galvanic action between wrought iron and steels, &c., appears (from experiments on hand by the author) also to be - materially reduced in course of extended periods of time, otherwise the liability to destructive corrosion through such action, though never inconsiderable, would be a more formidable matter to encounter than in engineering practice it really is. At the same time, it need scarce be remarked, this source of dis- integration should not be overlooked in constructive works of wrought and cast iron and steel. It is not now necessary for the author to attempt to enter into the further practical application of the results deducible from the experiments contained in this memoir; he has, however, great pleasure in being permitted the honour to present the results herein recorded as a contribution to the chemistry of iron and steel. Soc. Enin® PLATE XXX. DIAG RA M..-D. /Ilustrating some of the Comparative Results in Table D. WATERS 1N WHICH THE BARS WERE IMMERSED. Sea WaTER. An Acip CoLLiERY WATER. [PTION POSITIONS OF THE STEELS, &c. POSITIONS OF THE STEELS, &C. Positive Positive position Negative position of Metals. position Negative position of Metals. of Metals. of Metals. Degrees of Deflection of Galvanometer. Curves SHOWING THE COMPARATIVE ELECTRO-CHEMICAL CURVES SHOWING THE COMPARATIVE ELECTRO-CHEMICAL i] Degrees of Deflection of Galvanometer. | 123 465 67 8 910 Zr. 1 23 45 6 T 8 9 10 21 4. fs ah =NS-MARTIN 5 7 \- v4 if 4 IT-IRON he 7 bs ~ in NS Tron Scale in connection with Wrought-Iron in connection with Zinc in connection with ' Wrought-Iron in connection with Zinc in connection with Tron Scale in connection with A. RITCHIE & SON, EOIN® a te eee Soc. Epin® D I A G R ix M G. RATE; eXOXONal: lustrating the change of Electro-Chemical position between some Steel and Wrought-I/ron Plates, see Table G. WATERS IN WHICH THE PLATES REMAINED CONSTANTLY IMMERSED DURING THE EXPERIMENT. CURVE SHOWING THE VARYING ELECTRO-CHEMICAL POSITION OF THE STEELS IN GALVANIC CONNECTION WITH WROUGHT-IRON. Sea WATER. Plate (bright) forming one Wrought-Iron Plate (bright) forming one Positive position Negative position of dard Cast Steel Plate (bright). } element with a Soft Bessemer Plate (bright). Time of Steels. Steels. from . . n ralvano- | Fyectro-Chemical | Deflection of Galvano- | Blectro-Chemical eee G 2 3 a o a grees SetOeS Ie meter in Degrees “ih f Py ais Py o : position of the - : position o of 6 | a Hard Cast Steel. at interes gf time | the Soft Bessemer QA é 3 A A ; uring three hours. Steel. 1 0= 1 9 Z w —— 5 lar | SBP ; ® fi yg Caen vee : ' ! i “A o : ' [ | agae aes = Qo pacha cS) a n Se © ® =>) & @ z Ss HES 7 3 5 n re} .) ; 3 n fa 4 i a : Rd cn 7 < 4 Ph ee : o wn fm ° rp OR Ay 2 o } 2 © rs lq hemi 2 ow HAGEUENOENBERMME) & far Bena das i Q a Jaa eae eee re ry Ee TASOE AO ESE BE : 2 (2) i= eee ea 3g h Q- @ o. Pe | owoues TTT TTT TL a : ture | Pee ee Rees ae A 0-10 p e Se ST ee ° ee SS RRR Re ae: mm | zene . € 4 =a ea oe | a : ____._ ee Ss | SS FERRER EE Se nRR Hs A @ Me, | : ___. | a es Rs th ® aes. | ECd Sanne ee Se ene nets aa | ee ae re ae WR Soc. Epin® PrAG RA M —-G, I. lustrating the change of Electro-Chemical position between Cast Metal and Wrought-/ron Plates, see Table G I. SOLUTIONS IN WHICH THE PLATES REMAINED CONSTANTLY IMMERSED DURING THE EXPERIMENT. PLATE XXXII. CurRVE SHOWING THE VARYING ELECTRO-CHEMICAL POSITION OF THE Cast METAL IN GALVANIC CONNECTION WITH WrovuGHT-IRON, Sea WATER. 4th Norma STaNpARp SutrHuric Aci. n Plate (bright) forming one Wrought-Iron Plate (bright) forming one Positive position of Negative position of ha Cast Metal Plate (bright). element with a Cast Metal Plate (bright). Time Cast Metal. Cast Metal. 7 he z from 4 é onl § 3 2 on o Q eflection o ‘ F Commencement & ‘S18 5 5 5 in Degrees eueo eo Chemical Galvanometer in Degrees | Electro-Chemical a Bb ) 2 | o fy ios} als of BORO ® at intervals of position of Z Q (a) bol A Ss : Toareinteyrres the Cast Metal. time during three hours. the Cast Metal. Experiment. 2 1 202 1 g—~— ae ye e 1-00 ae /| | | : hy - 0-25 2 _| AS a ees) O25 eL | aa | | | | | | |e fe |= 0:25 Pp ¥ LY SEBERBEEMIE 8 een f2 0-10 (a , & 0:00 ZERO = Ea > OB F E 0:10 mM | = aS ne O:-10 N | 4 [i] ° 0:10 | NV | : i a 0:10 M + ri : : 0:25 NV. i £ 7°50 1 He ees 0:50 0:50 N He ff p 0-50 Nv. [i es fee [PN TE ewe 5 0-60 NV. i: ela alaiabaes rf 2. ze : SeEeele ; 0.75 ae ' = 2 0-75 NV | pa w : | + PEC: W. me I @ 7 Poe GG A [5 es =) N_ Bee Bbww | ee 3s 7 A ca Z i pg | 3 5 casas aaa] ze }+—t4_} t+ +t o = = arrestee ae DG eNea =: i. “< Boa _ \ : £ S rs) \ 2 | FERRO . S a | re = : JCC. HEN SRRRESGE INGE oe : 2 ) < r) ERT REAR ER a ) : ° Oe EEE GE g } 5 s 3 } | | ; LJ S ° | 5 y Jd : = \ 5 Fe = 5 m PAELLA : ] Pe 0-90 N wa * 5 ) p AS ig ees p oe = : | sf ) i dal ee - D p ae =] BL E ss) ) L Lo) tf || 2 d) P = oc 5 72) | 5 ! He 5 P 1 > ; a, Zi a I L. oi | 3 HOURS { esl Soc. Iprn® DIAGRAM H. WATER IN WHICH THE PLATES REMAINED CONSTANTLY IMMERSED DURING THE EXPERIMENT. ; CURVE SHOWING THE VARYING ELECTRO-CHEMICAL STEELS IN GALVANIC CONNECTION WITH COPPER PLATES. PLATE XXXIII. trating the change of Electro-Chemical position between Steel, Wrought-/ron, and Copper Plates, see Table H. | POSITION OF THE SEA WATER. bright) forming one element | Copper Plate (bright) forming one element Positive position of the Steels. iemens-Martin Steel Plate. with a Wrought Iron Plate (bright). Time = from By g 8 4 g rs S zalvano-| Electro-Chemical | Deflection of Galvano-| Electro-Chemical Commencement, 5 5, 2 E, 5 2 5, s s egrees position of meter in Degrees position of oe o o a oy o oO By o oy By ef of time | the Soft Siemens- at intervals of time the Wrought A A A A A A A Qa A SUS hours. | Martin Steel. | during three hours. hark Eperimet.gg 9 § 7 6 5 4 3 2 1 20% f Hii a 4-50 P | a bo | ? S la 2 | 9 00 IL P {L PUG 7] oe oS 2 a (2) g Cao Ee Jar ee Viet) je 4 a im ie | | a 2 f 9:50 | Ja : : Sf 8 : oO n = ——_ $73 ___j_ Pp 1H ~ 2B H Qu © = % o Ss = D 9-50 P | Hour o 5 n re) p 2 i= o +— P. 9:50 P. ell A - isp = < 2 | ® BaP —— GE2Z5: fz Ss an Se ° =o sf Bie pp 9-00 Pp eee : = © A = Pp 8-75 P zie ° i on : o Hu (as : p 8-50 p = VB i : B | Ss rS) ER 2 Hours ie) . ‘ ° . ‘ le} ‘ 5 S| o e a ot S : p 175 P 2 2 os ) oO ted = a PL. VIS. /2 i a hae p aoe. Pl Ie = alent @ P. p 3 Hours Sel PLATE XXXIV. Le DIAGRAM ‘lustrating the change of Electro-Chemical position between some Steel and Wrought-/ron Plates, see Table I. Soc. Eprn® The Black Line ______ indicates the deflections caused by the Soft Siemens-Martin Steel in Galvanic connection with Wrought-Iron in #th Normal Standard Sulphuric Acid. » . Soft Bessemer ” ” ” oe ” ” ” ” ” ” o S) or o a. 9 Serre rrr! ” ”? %? 9? ” 99 2? ssais9q GN *20159q ey] oS neauneney i=) o1j9Use TN Negative position of Steels. it i it Ht Positive position of Steels Pec GN aneoe pSeaa maa ssn | ‘saois9q oD ee Te Ee LU Ht Ht eeee eae BEG tHE aes AEA SE Sie ee ee f\ f\ f\ A f\ STEELS IN GALVANIC CONNECTION WITH WROUGHT-IRON. CURVE SHOWING THE VARYING ELECTRO-CHEMICAL POSITION OF THE Time from Experiment. commencement of osition of ft Bessemer. Electro-Chemical (c} the g 0-00 0-00 0 meter in Degrees Wrought-Iron Plate (bright) forming one at intervals of time during three hours. element witha Soft Bessemer Plate (bright). Deflection of Galvano- IMMERSED DURING THE EXPERIMENT. @ 4 Be Bia ESE? o 2 elon O.B0 ¢ one's HOo8 Gy ei ae ic) ~ O45 0-25 0-25 0-25 ae 0-25 0:25 O25 _ aaa 0:25 O25 ee... O25 ie O25 4th Normat STanparpD SutpHuric Acip. SOLUTION IN WHICH THE PLATES REMAINED CONSTANTLY Mv Md cA | M f\ es ' i a Plate (bright) forming one Soft Siemens-Martin Steel Plate H A, RITCHIE & SON, LOIN® ar XIIL.— Report upon the Tunicata dredged during the Cruises of H.M.SS. “Porcupine” and “Lightning,” in the Summers of 1868, 1869, and 1870. By W. A. Herpmay, D.Sc., Professor of Natural History in University College, Liverpool. (Plates XXXV. and XXXVL) (Read 7th January 1884.) A few years ago the late Sir C. WyviLLe THOMSON gave me for examination . some specimens of Ascidians which had been obtained during the cruises of the “Porcupine” and “ Lightning,” and last summer I received from Mr Jonn -Morray the remainder of the Ascidiz Simplices and two species of the Ascidize Composite from the same deep-sea dredging expeditions.* Some additional specimens of the “ Porcupine ” Ascidize Composite have been placed in my hands during the last few days (January 1, 1884). The present paper contains a detailed account of the Simple Ascidians alone; the Compounc. forms will be worked up along with the “Challenger” Ascidize Composite, and will be described and figured in the second part of my Report upon the Tunicata of the ‘Challenger” Expedition. It may, however, be useful to state here that the “ Porcupine” Compound Ascidians include :— Distaplia rosea, Della Valle. One colony from Tangier Bay ; 35 fathoms. Aplidium Jallax, Johnston. Two small colonies from Loch Foyle; 10 fathoms. Leptochinum, sp. One colony from Station 12 (“‘ Lightning,” 1868, Feerde channel) ;. 530 fathoms. Leptoclinum, sp. Several colonies ; locality unknown. _Leptoclinum albidum. Several colonies from Tangier Bay ; 35 fathoms. * In the summer of 1868 H.M.S. ‘‘ Lightning” explored the region of the North Atlantic lying between the Hebrides and the Feriées. In 1869 H.M.S. ‘‘ Porcupine” made three cruises, the first off the north-west and west coasts of Ireland, the second off the south and south-west of Ireland, and the third off the north of Scotland as far as the Ferées. In 1870 the “Porcupine” dredged down the west coasts of France and Spain and in the neighbourhood of Gibraltar Strait, and explored the African coast of the Mediterranean as far east as Sicily. VOL. XXXII. PART II. 2N 220 DR W. A. HERDMAN ON Leptoclinum, n. sp. . One colony from Tangier Bay ; 35 fathoms. Didemnum, sp. One colony from Station 54 (Ferée channel, “cold area”); 363 — fathoms. Botryllus, sp. One colony from Tangier Bay; 35 fathoms. Botryllus, sp. . One colony from Station 54 (Ferée channel, “cold area”); 363 fathoms. Some of these possess an interest, apart from their morphological pecu- liarities, on account of the considerable depths from which they were obtained. ASCIDLZ SIMPLICES. Family AscipmIp&. This family is represented in the collection by three species of Ascidia, The common Ciona intestinalis was apparently not dredged at any ae the localities visited. Ascidia scabra, O. F. Miiller. ; About thirty specimens of this well-known species, most of them attached — to Lamellibranch valves, were dredged in Lough Foyle, Ireland, from a depth of 10 fathoms, during the first cruise of the ‘‘ Porcupine” in 1869. Most of them are small. They range from 5 mm. to 25 mm. in greatest length. The shape — varies considerably. The small individuals are ovate and much flattened; the larger ones are usually irregularly orbicular, but a few are oblong, and resemble the typical form of Ascidia virginea. The mantle is strong, and the muscle bands run very irregularly. In some remarks upon this species published in 1880, I showed how vari- able the branchial sac might be in the arrangement of the stigmata.* The “Porcupine” specimens exhibit this irregularity, and, in addition, show in some places an imperfect development of the internal longitudinal bars, which is frequently observed in Corella parallelogramma, and which I have figured in Ascidia triangularis.t In 1880 I described the meshes in Ascidia scabra * “Notes on British Tunicata,” Journ. Linn. Soc. Zool., vol. xv. No. 85, p. 274. + Loc. cit., pl. xvi. fig. 6. THE “ PORCUPINE”. AND “ LIGHTNING ” TUNICATA. DA as being usually transversely elongated, and as containing each about twelve stigmata; but in some of the “Porcupine” specimens the meshes are occa- sionally square, and have only 6-7 stigmata. Here and there at the angles of the meshes very short hemispherical papille may be found on the internal longitudinal bars, otherwise the ‘“ Porcupine” specimens agree with the description and figure in the Journal of the Linnean Society. The large tentacles are rather stouter than those in my former figure,* but the arrangement is the same. The dorsal tubercle is somewhat variable -in this species, but is always very simple. Two of the “‘ Porcupine” specimens have it intermediate in shape between those figured by myself in 1880T and by JuLin{ in 1881. In several of the specimens large masses of ova are present in the peri- branchial chamber. Ascidia plebeia, Alder, var. nov. (?) (Plate XX XV. figs. 1-8). External Appearance.—The body is irregularly ovate or pyriform, greatly compressed laterally, and attached by the posterior half, or more, of the left side. The anterior end is narrow and produced, the posterior considerably wider. The dorsal and ventral edges are irregular, but nearly equally curved; both sides are flattened. The branchial aperture is terminal and prominent; the lobes are well marked. The atrial aperture is from one-third to half way down the dorsal edge, prominent, projects laterally, and has well-marked lobes. The surface is somewhat irregular, but not rough. There are adhering sand and shell fragments at the posterior end and over part of the left side. The colour is yellowish-grey. Length of the body, 4:2 cm.; breadth, 1°9 cm. The test is moderately thick and strong, of a firm gelatinous consistency, translucent, smooth, and glistening on the inner surface, and richly supplied with blood-vessels. The left side and posterior end are thickened and made stiff by the presence of many imbedded sand grains and fragments of shells. The mantle is moderately strong. The musculature is well developed on the right side and the anterior end of the left, but is very slight over’the visceral part of the body. The sphincters are fairly strong. The branchial sac is slightly plicated longitudinally. The transverse vessels are all of the same size. The internal longitudinal bars are strong, and bear large curved and sometimes forked papille at the angles of the meshes, and smaller simple ones between. The meshes are slightly elongated vertically, and * Loe. ctt., pl. xvii. fig, 2. + Loe. cit., pl. xvii. fig. 1. t ‘Recherches sur l’organisation des Ascidies Simples, &c.,” Archives de Biologie, t. ii. fase. 1, pl. iv. fig. 2. 222 DR W. A. HERDMAN ON contain each four to six stigmata. The horizontal membranes are slight; there are none between the smaller papillee. The dorsal lamina is slightly ribbed transversely, and has small denticula- tions on the free margin. The tentacles are numerous, and so closely placed that their bases touch. There are 80 or 82 large, with about the same number of intermediate smaller ones. The dorsal tubercle is small and simple, ovate in outline, and with the narrower end anterior. The aperture is anterior, with the right horn rather longer than the left, but neither of them curved. No peritubereular area is present. Locality.—Two specimens, one large and one small, were obtained, during the second cruise of the “ Porcupine,” at Station 33, 20th July 1869, lat. 50° 38’ N., long. 9° 27’ W.; depth, 75 fathoms; bot. temp., 9°°8 C. These specimens are exceedingly like the common Ascidia plebeia, Alder, but differ from it in some details. They have no trace of the greenish tinge so characteristic of Ascidia plebeia even after preservation in alcohol, and the test is firmer and stiffer. The general shape, however, and the positions of the aper- tures (see Pl. XXXV. fig. 1) recall the characters of Ascidia plebeia. The measurements in the above description are those of the larger specimen ; the smaller one is 2°6 cm. in length and 1:4 cm. in breadth. In the smaller specimen the atrial aperture is not distant from the branchial, and is turned forwards. The body, when the test is removed, is long and narrow, and the branchial sac extends slightly beyond the viscera posteriorly (see Pl. XX XV. fig. 2). The stomach is large and the intestine rather wide. It is covered with renal vesicles and the reproductive ceca. The ovary forms thick swollen masses, and the spermary small dendritic tubules scattered chiefly over the anterior part of the intestine. The oviduct and the vas deferens are both greatly distended in the larger specimen, and form conspicuous curved tubes on the left side of the body (see Pl. XXXYV. fig. 2). Large quantities of ova were found in the peribranchial chamber. The branchial sac resembles that of Ascidia plebeta in every particular.* The primary papille are large (Pl. XX XV. fig. 3), and in some cases bear pinne or small tubercles on the sides. Smaller transverse vessels connecting the intermediate or secondary papille appear never to be present. The tentacles are numerous and closely placed, more closely than I have found before in Ascidia plebeia, and I can only distinguish two sizes, with an occasional very much smaller one here and there. The dorsal lamina is very - slightly ridged and denticulated. The prebranchial zone is papillated all over, * Compare description in Journ. Linn. Soe. Zool., vol. xv. No. 85, p. 288. THE “PORCUPINE” AND “LIGHTNING” TUNICATA. 208 and rather wide. There is no peritubercular area, and the dorsal tubercle is small and simple, just as in Ascidia plebeia. It only occupies about one-fourth of the breadth of the prebranchial zone. After taking all the characters into consideration, I am inclined to refer the specimens to Ascidia plebera, Alder, of which they may be considered as a variety until more is known about the range of variation in the species. Ascidia, sp. A torn test of a single individual of the genus Ascidia was found adhering to some fragments of Annelide tubes dredged at Station 45, lat. 35° 36’, long. 2° 29’; “ Porcupine” 1870; depth, 207 fathoms ; bot. temp., 12°°4 C. As the test only is present, it is, of course, impossible to identify the species, but there can be no doubt as to the genus. I consider it worthy of record simply on account of the depth from which it was obtained. Family CynTHuDs. No members of the sub-families CyntHIN& and BoLTENIN« are in the collec- tion, but the STYELIN# are represented by the common Styela grossularia, van Beneden, and four species of Polycarpa, three of which appear to be unde- scribed. One of these is from the Mediterranean, one from the Ferée channel, and the other from the North Atlantic 8.W. of Ireland, and from outside the _ Strait of Gibraltar, in rather deep water. Siyela grossularia, van Beneden. A large number of small individuals of this species were found attached to specimens of Polycarpa pomaria, dredged near Belfast on 4th August 1869, at a depth of 70 fathoms. | They vary from 2 mm. to 3 mm. in greatest length. Although they are so small, all of those I have examined are sexually mature and contain ripe | Ova, and in some cases tailed larve, in the peribranchial cavity. Also half a dozen small specimens of this species were found on a fragment of shell from Station 54, lat. 59° 56’ N., long. 6° 27’ W., during the third cruise of the “ Porcupine” in 1869; depth, 363 fathoms ; bot. temp. —0°'3 C. They are of the blister-like form, flattened ‘antero-posteriorly, and with | expanded margins. So faras I am aware, this is the greatest depth at which Siyela grossularia has been obtained. It is usually regarded as a shallow water species, and in some localities extends up between tide marks further than any other species of Tunicate. There are also in the collection one large and six small specimens, labelled “* Lightning,’ off Valentia.” 224 DR W. A. HERDMAN ON Polycarpa pusilla, n. sp. (Plate XXXV., figs. 4-6). External Appearance.—The body is spherical, ellipsoidal, ovate, or pyriform, - is not compressed, and is unattached. The anterior end is narrower if not the same as the posterior, which is wide and rounded. When the shape is ellipsoidal, the long axis is dorso-ventral. The apertures are not distant, on the anterior end; in some cases prominent, in others sessile and inconspicuous; no lobes are visible. The surface is even, but completely covered by an incrusting ie of fine sand. MHair-like processes are present on the posterior half or so of ‘the body, and bear sand grains. The colour is ight brown. Length of body (in an average sized specimen), 5 mm.; breadth, 6 mm.; thickness, 4 mm. | The test is moderately thick and tough, completely concealed externally by the sand, and smooth internally, it is continued posteriorly into the hair-like — processes bearing sand grains. The manile is rather strong. The muscle bands are numerous, though fine, and form a close network. Most of them compose a strong longitudinal layer internally, and a weaker circular layer externally. The sphincters are well developed. The branchial sac has four folds upon each side. The internal longitudinal bars are very broad, ribbon-like membranes; there are four or five on each fold, and one or two in the interspace. The meshes are rather large and square, and contain each five or six stigmata. In the mature sac the stigmata are long and narrow, and each mesh is divided transversely by a narrow horizontal membrane. The tentacles are of two sizes, with occasional smaller ones between. There are usually upwards of fifty altogether in the circle. The dorsal lamina is a narrow membrane with slight transverse ribs, which — begin a short way from the anterior end. The edge is thickened, but has no denticulations. The dorsal tubercle is simple, and ovate in outline; the aperture is directed anteriorly and to the left. The horns are not coiled, but almost touch ; the long axis is vertical. Locality.—Thirty-five specimens of this species were obtained 40 miles off Valentia, at a depth of 110 fathoms in the North Atlantic ; and one specimen was obtained at Station 31,‘ Porcupine.” 1870, lat. 35° 56’ N., long. 7° 6 WH at a depth of 477 fathoms; bot. temp., 10°3 C. This is a curious little species, in external appearance bearing considerable resemblance to Polycarpa pilella, a species discovered during the “Challenger” Expedition at Bahia, in shallow water. The present species is usually spherical, THE “ PORCUPINE” AND “ LIGHTNING” TUNICATA. 225 and most of the specimens look like little rough bullets covered with sand (see Plate XXXV. fig. 4, e. and f.). They feel quite hard, the test being rather firm. The specimens collected vary from 2 mm. to 9 mm. in ‘greatest diameter. Most of them are small. In the majority, the apertures are not visible externally, and it is impossible to distinguish the ends and sides without dissec- tion. Ina few, however (see Plate XX XV. fig.4, a and b.), the apertures are pro- minent, terminating short conical projections from the anterior end of the body. No lobes are visible, but when the test is removed in apertures are seen to be distinctly cross-slit. The mantle does not adhere to the test, and BehskGaenely the body can be readily shelled out. The musculature is well developed all over, and consists of two distinct layers, the internal longitudinal, starting anteriorly in bundles of fibres radiating from the apertures, and the external circular. Besides these, there are also a few oblique and irregularly running bundles. | The branchial sac appears variable. In small (young) specimens (see Plate XX XV. fig. 6), the stigmata are short and rounded, and the transverse _ vessels very wide; while in the larger specimen examined, the stigmata are long (see Plate XX XV. fig. 5) and closely placed, and the transverse vessels all very narrow. The internal longitudinal bars are wide and ribbon-like. In the part of the sac of the large specimen examined (see Plate XX XV. fig. 5) there were five bars on each of two folds next the endostyle, and only a single bar in the interspace, while the two rows of meshes formed by this bar with the adjacent folds had from five to six stigmata in each mesh. The series next to the endo- style was wider, each mesh containing nine or ten stigmata. In the young speci- men examined and figured (Pl. XX XV. fig. 6) the first or dorsal fold (67. f I) has seven bars, and is separated by a single row of meshes from the dorsal lamina; and by four rows of meshes from the second fold—hence this interspace has three bars. The second fold (b7. f J.) has three bars, and is separated from the third by three rows of meshes, hence this, the second interspace, has two bars only. The third fold (d7. f. ZZZ) has five bars, and is separated from the fourth by three rows of meshes, hence this third interspace has also two bars. The fourth fold (07. 7 ZV.) has also five bars, and is separated from the endostyle by two rows of stigmata, or an interspace with one bar. The stigmata in this sac are all short and rounded, and placed far apart. There are usually three or four in a mesh. The tentacles (Plate XX XV. fig. 6) are rather irregular, Three sizes are pre- sent, but members of the third order are often absent, as seen near the endostyle at the left hand end of the figure. The polycarps are fairly numerous. Some are male, others female, and others hermaphrodite. The endocarps are rare. The stomach is globular, and deeply sulcated. 226 | DR W. A. HERDMAN ON Polycarpa curta, n. sp. (Pl. XXXVI. figs. 7-11). External Appearance.—The body is ovate, ellipsoidal, or elongated trans- versely; not compressed laterally, and unattached. The anterior end is wide and convex, the posterior is usually still wider, and flat or irregular; the dorsal and ventral edges are short and similar. The apertures are rather far apart, being placed at the opposite extremities of the anterior end. They are equally : anterior, and are sessile and inconspicuous. There are ‘no apparent lobes. The surface is smooth, and fairly regular, but is slightly incrusted with small sand grains. The colour varies from yellowish- grey to light brown. Greatest length of the body, dorso-ventrally (in an average specimen), 9 mm.; breadth (antero-posteriorly), 7 mm.; thickness, (laterally), 5 mm. The test is thin, but very tough and leathery. It is quite opaque. The outer surface is slightly sandy, and the posterior end has a few hair-like pro- longations, to which sand grains are attached. The mantle does not adhere to the test. The apertures are slightly cross- slit, and the sphincters surrounding them are strong. The musculature else- where on the mantle is well developed, the muscle bands forming a close net- work not clearly divided into longitudinal and circular layers. The branchial sac has four well-marked folds on each side. The most dor- | sally placed is larger than the others, and has about twelve internal longitudinal bars. The rest of the folds have about six bars each, and there are two bars in each interspace. All the internal longitudinal bars are flat, ribbon-like membranes of considerable width. The transverse vessels are all of the same size. ‘The meshes are about square, and contain each four or five stigmata. The dorsal laminais a narrow membrane, with no ribs and no denticulations. The tentacles are not very numerous. There are eighteen or twenty larg tentacles, and the same number of smaller intermediate ones. The dorsal tubercle is simple. It is fusiform in outline, with the long axis vertical, There is an irregular slit down the middle, but there is no curva hence no horns are present. Locality.—Sixteen specimens of this species were dredged at Station 12; ‘« Lightning,” 1868; lat. 59° 36’ N., long. 7° 20’ W.; depth, 530 fathoms ; bos temp., 6°°4 C. This species is allied to Polyeaa ‘pa pusilla, but differs both in external appear- ance and in internal structure. It is not so much incrusted with sand, and the shape, though variable in both species, is here more decidedly elongated dorso- ventrally (Plate XX XVL. figs. 7 and 8), the result being the apertures come to b placed far apart at the opposite extremities of the wide anterior end (see Plat XXXVL. fig. 7). The greatest length is always dorso-ventrally, and this ranges i the specimens collected from 5 mm. to 13 mm. THE “PORCUPINE” AND “LIGHTNING” TUNICATA. 227 The branchial sac has the folds (Plate XX XVI. fig. 9) better developed than in Polycarpa pusilla. In one sac examined the arrangement, starting from the dorsal lamina along the right hand side, was—one row of wide meshes con- taining 8 to 10 stigmata, then the 1st fold with 12 bars, then the 1st interspace with 2 bars, then the 2nd fold with 7 bars, then the 2nd interspace with 2 bars, then the 3rd fold with 7 bars, then the 3rd interspace with 3 bars, then the 4th fold with 6 bars, and then a row of wide meshes separating the ventral fold from the endostyle. Figure 10 on Plate XXXVI. shows the narrow dorsal lamina and the wide row of meshes separating it from the commencement of the first fold on the left side of the sac. A large number of fine muscle fibres are | present in the branchial sac, chiefly in the transverse vessels. The peritubercular area (Plate XXXVI. fig. 2) is large and triangular in | shape. It is almost perfectly symmetrical. The tubercle is very different | from that of Polycarpa pusilla. It is comparatively simple, since the slit, | though irregular in shape, is not curved to form horns or spirals (see Plate | XXXVI. fig. 11, d.7.). The polycarps are irregularly rounded; they are herma- phrodite. Endocarps are not numerous. Polycarpa pomaria, Savigny. Twelve moderately large specimens of this common species were dredged | on August 4, 1869, near Belfast, at a depth of 70 fathoms. The largest indi- | vidual measures 3 cm. in length and 2 em. in breadth. Three or four of the specimens differ somewhat in appearance from the rest ; their tests are thinner and smoother, but otherwise they appear to be exactly the same. _ A single individual of this species was also obtained in 1870 in Tangier Bay | from a depth of 35 fathoms. The test is stiff, giving a solid appearance and | feel to the specimen, and the exterior is somewhat incrusted with sand. The | difference in external appearance between this individual and those with smooth thin tests from near Belfast is very considerable, but the species is a variable | one, and intermediate forms are common. Polycarpa formosa, nu. sp. (Plate XX XVI. figs. 1-6). External Appearance.—The body is elongated antero-posteriorly, and varies from pyriform to oblong in shape. There is almost no lateral compression, and } attachment is by the posterior extremity. The anterior end is moderately wide, but narrower than the middle of the body. The posterior end is narrower | than the anterior. The widest region is usually a little behind the middle of | the body. ‘The apertures are both anterior, and not distant. They form slight papillze, and are each distinctly four-lobed. The surface is even, but considerably incrusted with sand grains, especially VOL. XXXII. PART II. 20 228 DR W. A. HERDMAN ON at the posterior end, where there are also root-like prolongations of the test, to which sand is attached. The colour is light grey where the test is exposed; reddish-brown from the sand elsewhere. Length of the body (average specimen), 1°5 cm.; breadth, ‘7 cm. ; length of the root-like appendages, 1 cm. to 2 cm. The test is thin, but moderately tough. It is translucent where free from sand. The posterior end from which the sandy prolongations spring is some- what thickened. The mantle is rather slight. The muscle bands are feeble, and not very numerous; they form an open irregular network. The branchial sac has four folds upon each side. Each fold is formed by the aggregation of from six to twelve internal longitudinal bars. There are two to four bars in each interspace. The transverse vessels are of two sizes, alternating regularly. The meshes are much elongated vertically, and contain about three or four stigmata each. The stigmata are long and narrow, and the meshes are divided transversely by a narrow horizontal membrane. The dorsal lamina is rather wide, and has irregular and partial transverse ribs ; the margin is smooth. The tentacles are numerous, and closely placed. They are large, and all of much the same size. The dorsal tubercle is a simple, slightly-curved band, with the extremities directed posteriorly. Locality. Six specimens were dredged in Tangier Bay, on the 5th August 1870, from a depth of 35 fathoms. There is a characteristic appearance about the specimens of this species, although they all differ somewhat in shape (see Plate XX XVI. figs. 1-3). In all, the apertures are closely placed at the anterior end, the body is elongated antero-posteriorly, and the posterior end is prolonged into a mass of branched projections covered with sand. The dimensions of the six specimens are as follows :— A. B. C. D. E. F, Length of body alone, . .| 20cm. | 150m. | 15cm. | 16cm. | 10cm. | 14cm. Length of posterior projections, | 1‘lem. | 07cm. | 22cm. | 10cm. | 14cm. | 25 cm. Breadth of body, . ; » | lcm. | 0:9em. | 0°7 cm. | 0°7 cm. | 060m, | 05iomm The folds in the branchial sac (Pl. XX XVI. fig. 5), although they have a con- THE ‘“ PORCUPINE” AND “LIGHTNING” TUNICATA. 229 siderable number of internal longitudinal bars, do not project much into the cavity. The sac, as a whole, is very similar in structure to those of Styela oblonga, S. flava and S. glans.* The dorsal tubercle is very simple, the prebranchial zone is narrow (Plate XXXVI. fig. 6), and the peritubercular area small, and not occupied by the tubercle. The tentacles are of considerable size, and have large bases. Polycarps are not very numerous. They are scattered over the inner surface of the mantle (Plate XX XVI. fig. 4, g.). They are unisexual. The male poly- carps are deeply cleft into lobes. The alimentary canal lies on the dorsal part of the left side of the body. The stomach is pyriform, and is strongly ribbed externally ; the intestinal loop is moderately open, and the rectum is long and narrow (see Plate XXXVI. ne 4. 7): Family Mo.euip.. This family is represented in the collection by two species of Molgula and the common ELugyra glutinans. Molgula, sp. A single small specimen of a Molgula, slightly torn, was found adhering to one of the specimens of Polycarpa pomaria from near Belfast ; 70 fathoms. The shape is nearly globular; 8 mm. in diameter, and slightly compressed laterally. Short hair-like processes project all over, and have a few grains of sand and other foreign bodies attached to them, but there is no incrusting coat. The test is moderately thin, soft, and nearly transparent. The colour is light yellowish-grey. Possibly this may be Molgula nana, Kupffer. Molgula ampulloides, van Beneden. One specimen of this rather widely-diffused species was dredged in Lough Foyle, during the first cruise of the “ Porcupine” in 1869, from a depth of 10 fathoms. It measures 1‘7 cm. in length, and 1:4 cm. in greatest breadth. Hugyra glutinans, Moller (Plate XXXVI. figs. 12-14). Eighteen specimens of this common and apparently gregarious species were dredged in Donegal Bay, Ireland. None of the specimens are large. They range from 4 mm. to 12 mm. in greatest diameter. The incrusting sand is very fine and comes off readily, the result being that most of the specimens have very little left, and in some the delicate test is almost completely exposed. * See Report upon the Tunicata dredged during the voyage of H.M.S. “Challenger,” Part I. Plate XX. figs. 4, 8, and 11. 230 DR W. A. HERDMAN ON In the branchial sacs of several of these specimens, the vessels forming the apices of the spiral infundibula are considerably swollen, attaining as much as twice their normal calibre (Plate XXX VL. figs. 12 and 13); and the epithelium on the edges of the corresponding stigmata is greatly thickened (see Plate XXXVI. fig. 14). Postscript, May 30, 1884.—Since the above paper was written and the plates finished, I have received, through the kindness of Dr P. HeErpert CARPENTER, three specimens of an interesting and apparently undescribed Molegulid, which was dredged from a depth of 440 fathoms in the Ferée channel during the third cruise of the ‘ Porcupine” in 1869. This species will © be described and figured in the Report on the “ Challenger ” Tunicata, Part IL. — EXPLANATION OF THE PLATES. The following system of lettering has been adhered to in all the figures :— at. Atrial aperture. br. Branchial aperture. br. f. Fold in the branchial sac. d.l, Dorsal lamina. d.t. Dorsal tubercle. en. Endostyle. g. Genital organ. h. m. Horizontal membrane of the branchial sac. 7. l, Internal longitudinal bar of the branchial sac. m. The mantle, p., p'. Papille of the branchial sac. p. p. The peripharyngeal bands. vy, The rectum. sg. The stigmata of the branchial sac. st. The stomach. tn., tn’. The tentacles. tr., tr’., tr”. The transverse vessels of the branchial sac. z. The prebranchial zone. PLATE XXXV. Figs. 1-3, Ascidia plebeia, Alder, var. nov. Figs. 4-6, Polycarpa pusilla, n. sp. Fig. 1. Ascidia plebeia, var., seen from right side; natural size. ‘i Fig. 2. Ascidia plebeia, var., the test removed, body seen from the left side ; natural size, THE “ PORCUPINE” AND “ LIGHTNING” TUNICATA. 231 Fig. 3. Small part of the branchial sac of Ascidia plebeia, var., seen from the inside ; magnified 50 diameters. Fig. 4, a.-—f. Six specimens of Polycarpa pusilla, n. sp.; natural size. Fig. 5. Small part of the branchial sac of Polycarpa pusilla, seen from the inside; magnified 50 diameters, } Fig. 6. Right half of the anterior part of the branchial sac, showing also the tentacles, the endostyle, the dorsal tubercle, the prebranchial zone, &c.; magnified 50 dia- meters. PLATE XXXVI. Figs. 1-6. Polycarpa formosa, n. sp. Figs. 7-11. Polycarpa curta, nu. sp. Figs. 12-14. Zugyra glutinans, Moller. Fig. 1. Polycarpa formosa, from the right side ; natural size. Fig. 2. Another specimen of the same species. Fig. 3. Group of one small and two large specimens of the same species; natural size. Fig. 4. Specimen of Polycarpa formosa, dissected from the left side to show the alimentary canal, &c.; slightly enlarged. Fig. 5. Small part of the branchial sac of Polycarpa formosa, seen from the inside ; magnified 50 diameters. Fig. 6. Dorsal tubercle, &c., of Polycarpa formosa ; magnified 50 diameters. Fig. 7. Specimen of Polycarpa curta; natural size. The arrows indicate the branchial (inhalent) and atrial (exhalent) apertures. Fig. 8. Two other specimens of the same species. Fig. 9. Small part of the branchial sac of Polycarpa cwrta, seen from the inside ; magnified 50 diameters. Fig. 10. Small part of the dorsal lamina and branchial sac of Polycarpa cwrta, from inside ; magnified 50 diameters. Fig. 11. Dorsal tubercle and peritubercular area of Polycarpa cwrta ; magnified 50 diameters. Fig. 12. Centre of a spiral from branchial sac of Lugyra glutinans ; magnified 50 diameters. Fig. 13. Centre of another spiral from the branchial sac of Hugyra glutinans ; magnified 50 diameters. Fig. 14. Another similar spiral from Lugyra glutinans ; magnified 300 diameters. iS) ru VOL. XXXII. PART II. | Roy. Bece sain Vol XAAI. Plate XXXV. dman del. figs, /-3, ASCIDIA PLEBEIA, A/der var nov FIGS. 4-6. POLYCARPA PUSILLA, 7, 5. T.Dobb & C° Luth® Lpool. Plate XXXYJ OY, Soc. Edin't Vol XXXIL 2 6, POLYCARPA FORMOSA» sp Figs, 7-//, POLYCAKPA CURTA 17.52. | T.Dobb & C? Lith’ L'sool Hman del, Figs, /2-/4, EUCYRA GLUTINANS, Mo//er XIV.—WNote on Sir David Brewster's Line Y, in the infra-Red of the Solar Spectrum. By C. Piazzt Smytu, Astronomer Royal for Scotland. (Plate XXXVIT). (Read 17th December 1883. ) Of all known examples in physical science, of simplifying, and at the same time “ precisionising” some of its fundamental data, which might otherwise fall to be entangled in high numbers, none has been happier than FRAUNHOFER’S application of the letters of the alphabet to certain chief lines in the solar spectrum. Happy both in its conception by the inventor, and its universal acceptance since then by the world. Whence it comes to pass now, that in every country, whoever observes the solar spectrum at all, with whatever instrument, large or small, diffracting or refracting, and whether he holds tothe undulatory, or any other theory of light, and catalogues spectral lines either in Wave-lengths or Wave-numbers, or merely in terms of the brass scale screwed to his instru- ment by a maker,—yet whenever he speaks of the line A, or B, or C, or any other so named by FRAuNHoFER, he singles out thereby from among thousands, exactly the same identical line which any and every other spectro- scopist alludes to under the same simple letter. Hardly less happy was the extension of the system made by our great specialist in optical physics, Sir Davin Brewster, when, having discovered several lines in the infra-red of the solar spectrum, beyond or before Fraun- HOFER’ commencing line “ great A”’—he named them with the later letters of the alphabet, whose stock of symbols had not been more than half used up by FRAUNHOFER in reaching toward the further violet end of the spectrum. Hence, without disturbing any one of FRAUNHOFER’S lettered lines from red through green, to blue and violet, Brewster called his new line next beyond, or before great A in the “infra red,” by the letter Z; the next before and outside that, Y; and the next before that again, X. In so far, BREwsTER’s proceeding was quite as happy as FRAUNHOFER’s ; and if his assigned letters have been lately misused or omitted in certain high quarters, that is not his fault, and perhaps not intentional on the part of those who have done so, but has arisen jirst/y from the difficulty that many observers _ have in seeing his lines in the ultra-red, on account of their exceeding faint- ness; and secondly,from some of them being Solar, and others Telluric, to a degree that even he himself had not fully anticipated. It would seem, therefore, to be high time, in BrewsTER’s own Society and Country, to come to a clearer under- standing on the facts of his nomenclature, touching at least those three chief VOL. XXXII. PART II. 2Q 234 C. PIAZZI SMYTH ON NOTE ON SIR DAVID BREWSTER’S lines X, Y, Z; and the case is all the more claimant just now, seeing that a very grand chemical identification has just been made out in France for one of them; but one, unhappily of late called after one letter by some persons, and another letter by others, a fruitful source of future trouble unless corrected speedily. I propose, therefore, to inquire here, by help of a few recent obser- vations, and reference to many old ones, which is the right letter to employ for each of those three lines. Sir Davin BrewstTer’s activities in Solar-spectrum observation were in full force at his favourite Border seat of Allerly, in 1833, as evidenced by three spectroscopic papers in our volume of 77-ansactions for that year ; but the fullest and most authoritative publication on his new lines in the infra-red is that con- tained in his joint paper with Dr GLApsToNE in the Philosophical Transactions of the Royal Society, London, in 1860. Of the longest spectrum-view contained in a plate accompanying that paper, I submit a portion copied by myself, as Strip No. 1 of my own plate now pre- sented, with very little alteration, except slightly expanding it to suit my scale ; and freely crossmg and recrossing the lines representing both shade and the inevitable darkness at and about the very origin of spectrum light, which, beginning on the left-hand side of the picture, rapidly increases in intensity towards the right—FRAUNHOFER lines and bands therein always excepted. As an observer, I like Sir Davin’s drawing much, for its truthful representa- tion of the real and necessary degree of darkness, in midst of, or antagonistically to, which the new lines had to be detected; a feature of Nature, this darkness at either end of the spectrum, so rarely introduced in modern spectrum draw- ings. And though the shade bands are rather too sharply defined on either edge, I recognise, in spite of the depreciatory comments of M. Kircuorr, that it is exceedingly like what appears at that end of the spectrum, when a spec- troscope is under-prismed and over-telescoped. So too it must most eminently have been in Sir Davin’s case, when he seems to have employed but one simple prism of not very heavy glass, and no less than a 5-foot achromatic telescope to look into it. But then it was Brewsrer’s eye that looked; so no wonder that he saw with it more than any of his predecessors, and most of his suc- cessors as well. “The light less refrangible than A,” say the conjoint authors at their page 150, “is red, but extremely faint, so faint indeed, that few observers of the spec- trum have perhaps ever seen it; and the only drawing hitherto published of lines in it appears to be in a map of the solar spectrum by M. MarrutEsen of Altona. He represents a few lines which, on comparison with fig. 1, may be identified as the band anterior to Y, Y itself, and the band Y'. In order to map" the lines and bands in this portion of the prismatic image, Sir Davin BrewsTER was obliged to take extraordinary precautions. The telescope was lined with LINE Y, IN THE INFRA-RED OF THE SOLAR SPECTRUM. 235 black velvet, in order to exclude any reflected light ; a low power was em- ployed; the slit was made about the eighth, or tenth, of an inch wide,* and the eye of the observer was washed with water to cleanse the fluid that lubri- cates the cornea. The most prominent line in this space is that marked Y.” That last remark is quite to our purpose, and I trust the drawing-strip, No. 1, of the Plate now given, illustrates it perfectly, remembering that “ great A” and “‘little a” are introduced merely to give milestone references to known parts of the spectrum, and a measuring test universally understood for scale. Strip No. 2 represents some rude efforts of mine in 1871, with very unequal apparatus, to see something of this rare region of the ultra-red. The drawing is slightly altered from that in Vol. XIII. of the Edinburgh Astronomical Obser- vations, inasmuch as the mere general appearances of many close, thin lines unmeasured, and of shading, improperly represented there by vertical lines, are here crossed diagonally and horizontally in such a manner that they cannot be understood to imply true, resolved spectral lines, or anything but shade only, symbolically expressed. And the chief result is thereby plainer than ever, v7z., that the Y line was better seen ina high summer, than a low winter, sun; a ~ feature indicating it to be of Solar origin, and not of Earth’s atmosphere, or “Telluric ” intervention. Strip No. 3 gives the two views of high and low sun, contained in the Royal Societys Himalaya spectrum, in their Philosophical Transactions for 1875. This drawing is on a smaller scale than their’s ; and their questionable shadings With vertical lines have been changed by me into diagonal lines ; but otherwise it represents in exactly the same manner their very surprising negation of the visibility of Y in a high sun, but its abundant visibility, and that of BREwsTER’s Z also, in a low sun. Strip No. 4 represents on a reduced scale my own observations (from Vol. XIV. of £d. Ast. Obs.) made in Portugal in 1877, with a far more powerful spectroscope than I had ever possessed before, and which I had had constructed specially to look into this particular question of the visibility, or non-visibility, of the Y line in a very high, indeed almost Zenithal, sun. The result, as will be seen in the drawing, was to confirm the previous Edinburgh observation, and to show that Y was, with the sun near the zenith, most notably visible; Brew- stER’s X appearing next in strength ; but Z only in the faintest manner possible, if at all. Strip No. 5 is a very reduced copy of part of a magnificent work derived from photography by Captain Apnry and Colonel Festinc, forming the Bakerian Lecture at the Royal Society for 1880. * The distance of this slit is unfortunately not stated. It may have been at the other end of a long room, and was apparently unfurnished with any kind of collimator lens, in the improved manner introduced by Professor Swan. 2356 C. PIAZZI SMYTH ON NOTE ON SIR DAVID BREWSTER’S By dint of Captain ABNeEy’s really wonderful processes of changing the colour of silver for transmitted light, he was enabled to photograph not only all that: part of the infra-red end of the solar spectrum discovered with so much pain and labour by Brewster, but to procure records of other lines, some of them very grand ones too, extending nearly three times as far away, and into what is, to the human eye, absolute, unmitigated darkness. There is, therefore, not the slightest intention here to compete with him in spectral range ; and I have purposely left his spectrum strip bright and of full height up to the extreme left hand end of my paper, to indicate that his view extends very much further still in that same direction. The only point of difference in fact which I have with him and his distinguished fellow-labourer, or the Central Metropolitan Society which publishes their work, is,—that the very strong line, which from its place in the spectrum can be no other whatever than Y, he calls Z; and the letter Y he gives no place to. Apparently Captain ABNey and Colonel Festive had not seen the real Z line at all; and with little doubt because they worked in a too high Sun for #, though excellent for their other, and chief, objects. For Strip 6 shows the result of three observations which I had the fortune to make during an unusually long, bright sun-shiny afternoon on the 30th of May last at the house No. 15 Royal Terrace, Edinburgh. The apparatus was moderate in power; there was no attempt to resolve bands into their very thin component lines; but only mile-stone. At 5" 50™ p.m. then, of distinct lines, Y alone was visible outside Great A. But At 8" 0™ p.m., with a very much lower Sun, there, besides Y nearly as before, stood out Z as quite a strong line, accompanied too with bands, and proving itself to be Telluric without a doubt. Finally, Strip 7 represents what the ancient Greeks might have called th apotheosis of line Y, in its glorious identification at last by M. HENRI BECQUEREL with a bright emission line of the same Solar Sodium (Na), which produces that grand turning-key to all the modern developments of Spectrum analysis, viz. the Solar lines D’ and D’. a The fullest account of this final confirmation of the Solar character of Y that I have yet seen is that contained in the Compies Rendus for July 9, 1883 pp. 71-74, by M. Henrr Becqurret himself. He had been researching the infra-red spectrum of chemistry by his celebrated Father’s method of the pheno: mena of Phosphorescence, and found two new distinct and widely separatec salt lines to exist therein. He next proved the correspondence of both of them with?two extra strong and equally widely separated lines at the same points of LINE Y, IN THE INFRA-RED OF THE SOLAR SPECTRUM. 3H the Solar spectrum. One, and the fainter of these two lines, was an immense distance further into visual darkness than any of the lines in my plate. It was even beyond Captain ABNEy’s and Colonel Festine’s furthest photographic, being at 23 130 Wave Number. But the other, at 31 010 W.N.—to be freely taken as equivalent to our 30 860—is no less than BrewstTErR’s Y, and is honourably mentioned by M. BecquEreEt as being such. It is indeed so instructive, as well as encouraging, to find the line thus alluded to in Paris as “ BrewstTer’s Y line,” three years after that letter was expunged in London from the Solar spectrum, that I beg to conclude with M. Henri BECQUEREL’S own words thus :— “La vapeur de sodium, qui est principalement caracté¢risée dans le spectre lumineux par la double raie D, présente dans l’infra-rouge deux tres fortes raies caractéristiques dont les longeurs d’onde sont 819 (=W.N.Br. 31 010) et 1098 (=W.N.Br. 23 130). Ces raies sont les mémes lorsqu’on volatilise dans larc, du sodium métallique ou du chlorure de sodium; elles coincide avec deux fortes raies du spectre solaire. “Ta raie \ 819 (W.N. 31 010) que l’on peut voir a l’ceil nu avec un spectro- scope ordinaire, coincide avec une des plus fortes raies du spectre infra-rouge du Soleil que BREWSTER avait vue, et désignée par la lettre Y. “Dans les conditions ou lon dédouble les raies D, je n’ai pu dédoubler distinctement la raie Y.” POSTSCRIPT. The above concluding remark of M. H. BEcQUEREL is instructive to those who would desire to see for themselves this salt representative of BREWSTER’s Y line; for it shows that even in his “Arc” light, notwithstanding its necessary brilliance, that particular line must have been too faint for neat physical notation; and, indeed, unless an arc light can be prepared as bright as, or possibly still brighter intrinsically than, a high summer sun, such almost must be the result. With the most powerful Bunsen gas burners, consuming any amount of Chloride of Sodium, the trial is quite hopeless; and even with 1-inch induction Sparks, condensed by a half-gallon jar between platinum points, of which one Tises through moistened salt, with the effect of making the D lines painfully bright, I have not succeeded in causing the same salt’s Y line, or lines, to certainly appear. I bave, however, in the search found three air lines much further towards the infra-red than any of the standard list of air lines entered in Dr Wart’s invaluable Index of Spectra, as compiled by him from the observations of the greater spectroscopists. VOL. XXXII. PART IL. 2R 238 c. PIAZZI SMYTH ON NOTE ON SIR DAVID BREWSTER’S LINE Y. Though not quite so far to that end of the spectrum as certain two lines of Rubidium, yet being much more constant and more easily procured, these new lines may be useful to other researchers as references for spectrum place in that rather barren region. I give their approximate Wave-number readings therefore here, and have depicted their appearance in the last or “appended ” spectrum strip of our table, desiring to remark only, in addition, that the middle line of the three is triple, the distance between its first and second components being rather greater, and between its second and third rather less, than the potassium a’**’ pair, whose Wave-number places are 32988 and 33 128, respectively ; while all the three air lines appear fairly sharp, with a narrow slit, and under a dispersion of 12° A to H, combined with a magnifying power on the inspecting telescope of 15. Air Line 1, Rel. Intensity=5, Wave-number place in Brit. Inch=32 693 Its “a” component, Intens.=5, W.N.PI. if =33 944 Air Line 2, eb: = so =a) ps cs — 34 071 a? a c (i oP) 9) = 2, 9 9 = 34 157 Continuous spectrum begins soon after this, and goes on increasing towards the violet. Air Line 3, Rel. Intensity=6, W.N.PI1. in Brit. Inch, =35 404 First Air Line in Dr Warts’ Index of Spectra, Intens=6, W.N.Pl.=38 470 NOTE ADDED ON May 30, 1884. In the course of sundry spectroscopic experiments on vacuum tubes through the winter of 1883-4, and now communicated to Royal Society, Edinburgh, I have had abundant testimony that the first of the lmes noted above, viz., at 32 693 Wave-number place, is an oxygen line ; a very remarkable one too, for though like all other “tube,” or simple-spark, oxygen lines, it is very faint,—yet it is well-defined, and is further towards the ultra red than any — line or band I have yet come across in any of the other gases. The triple line which follows I have equally proved to belong to nitrogen. But to what gas, air line 3, at 35 404 Wave-number place belongs, I have obtained no indication as yet from vacuum tubes. C.: Pass Rv. Soc. EDINE. : PLATE XXXVII. APPROXIMATE SPECTRUM DRAWINGS BOR tle IST ORY (OF MEMS AviD BREWSTERS LINE Y IN THE INFRA-RED oF THE SOLAR SPECTRUM. ~ SCALE “Wave Numeper IN BaritisH INCH. yooo 30) 000 32| 000 33000 29,500 30,500 J2\Se0 33)Se0 ' ‘ 4 ‘ 4 __ Bre yenstersX "Bre wert BrevstersZ Great A arid Brewster ‘Dr ‘Cladstine 4 Plate LV o; _Philosop hical Wipe neers RB Sooiety J aS a a Gr tT ye Whe YVline betler seen tw high than low, Stam: mere Inere approx Sketch tn Vol. X/M/ of Ldinturgh A ston! Obs 1872. IEE SeBooooe SoCo J SEBS SE5bSse8he5sn0 @ tnvischle. g 5 Z Z reat A Veg ation o a as a ee line . Tellurec. Philosophical Transactions. /87 5. n aa | a ley TTY 2Eia BP ss Ly well seew. [=] aang eeiey Little @ not filled cr, Gecause n0E Tegucred SJ” thes Gap —& ih a a ar stn BS — S Ditla, delle; ant with no TLE, aw reseZvre the Bande of ALY, Y CGEEE A ‘6! Ladinburgh obs: 304 Nay 1883, Show Y as Brewster Aiscovered, placed, andl rammed, ct atrue Solar line; Z also ; ty ets old i place but asa DZellurce bees on’ Low Cl Za Senn na [| i | [ff fs ae fc PPP afc om [mJ ea J in f P fi [f [ tfn[oePe fe PC | o [a Gin Y week Solar Sodcum (Na). ae Rendus July, (883. OAL ALLNE NDip. New AIR LINES descovered en Edinburgh i SWVevernvber , 7883. avi PHOTO-LITHO. BY A. RITCHIE & SON, EDIN. Thomas Heath el, ( 239 ) XV.—On the Formation of Small Clear Spaces in Dusty Air. By Mr Joun AlTKen. (Plate XX XVIII.) (Received December 27, 1883 ; read January 21, 1884.) The dust particles floating in our atmosphere are every day demanding more and more attention. As our knowledge of these unseen particles in- creases, our interest deepens, and I might almost say gives place to anxiety, when we realise the vast importance these dust particles have on life, whether it be those inorganic ones so small as to be beyond the powers of the microscope, or those larger organic ones which float unseen through our atmosphere, and which, though invisible, are yet the messengers of sickness and of death to many—messengers far more real and certain than poet or painter has ever conceived. As the great importance of these dust particles is gradually being realised, we are from time to time increasing our efforts to protect ourselves from these invisible enemies. Professor, now Sir JosePH, Lister has shown us how to contend successfully with those organic germs, which, falling on our wounds, there find a suitable resting-place, and, if not killed, germinate and grow to our destruction. Sanitary societies are every day being formed, one of whose objects is to combat these floating particles by better appliances directed towards the prevention of the conditions suitable for the germination, growth, and increase of these germs, and against their spread from infected centres, while other societies are directing their energies against the artificial produc- tion of those inorganic forms of dust which pollute our atmosphere. The immense importance of everything connected with dust must be my excuse for bringing before this Society observations on phenomena which I fear must appear to many as trivial and uninteresting; as the clear spaces to which I shall direct attention are on almost a microscopic scale, and require to be magnified to enable us to see them clearly. Professor TyNDALL has made many experiments on the light-reflecting par- ticles floating in our atmosphere. He found these particles were destroyed by heat, and that by placing a flame under a brilliant beam of light, which revealed by illuminating the dust in the air, there was seen rising from the flame wreaths of darkness resembling intensely black smoke. He then found it was not necessary to burn the particles to produce this stream of darkness. This was observed when a hot metal ball was placed under the beam of light, and per- mitted to remain till its temperature had fallen below that of boiling water. It VOL. XXXII. PART II. 28 240 MR JOHN AITKEN ON THE was then found that, though the dark current was much enfeebled, it was still produced. To study this effect, Professor TyNpALL stretched a platinum wire transversely under the beam, the two ends of the wire being connected with the poles of a voltaic battery, and the necessary appliances for regulating the strength of the current. “ Beginning with a feeble current, the temperature of the wire was gradually augmented; but long before it reached the heat of ignition a flat stream of air rose from it, which, when looked at edgeways, appeared darker and sharper than one of the blackest lines of FRAUNHOFER in a purified spectrum” (see fig. 5). He goes on to say—“ Right and left of this dark vertical band the floating matter rose upwards, bounding definitely the non-luminous stream of air. What is the explanation? Simply this: The hot wire rarefied the air in contact with it, but it did not equally lighten the float- ing matter. The convection current of pure air therefore passed upwards among the inert particles, dragging them after it right and left, but forming between them an impassable black partition.” * This explanation of Professor TyNDALL’s has been received by most of us without question ; yet I think that if we try to form a mental picture of the process which is here supposed to go on, we shall have some difficulty in doing so. Professor TYNDALL supposes the distribution of the floating matter is due to the heat, which lightens the air, but does not in the same degree lighten the floating dust ; the tendency, therefore, he says, is to start a current of clear air through the mote-filled air. No doubt the lightening of the air will slightly increase the tendency of the motes to fall, but the increased freedom to fall from this cause will be extremely slight and inappreciable, and will be entirely negatived and overruled by the upward movement of the hotter air, and the result will be simply to cause the particles to lag a little behind the air in their movements. Our confidence in Professor TYNDALL’s explanation was not, however, shaken till Lord Rayerau, in going over Professor TYNDALL’s experiments and extend- ing them, discovered that the explanation given of the formation of the dark plane was not correct, and showed that it could not be due to heat lightening the air, and so enabling it to shake itself free from the dust motes, because he discovered that cooling the air produced a precisely similar result (see fig. 2). Lord Raytercu introduced a cold glass rod into smoky air, and then found that “a dark plane extending downwards from the rod, clearly developed itself, and persisted for a long while.” + He says—“ This result not merely shows that the dark plane is not due to evaporation, but also excludes any explanation — depending upon an augmentation in the difference of densities of fluid and * Proc. Roy. Inst., vol. vi. p. 3, 1870; also Essays on the Floating Matter in the Air, p. 9. Loigmans, Green, & Co., 1881. + Paper read before Royal Society, December 21, 1882; also Natwre, vol. xxviii. p. 139, FORMATION OF SMALL CLEAR SPACES IN DUSTY AIR. 241 foreign matter.” Lord Ray eicH also offers as a suggestion that the particles may be thrown out by the centrifugal force, as the mixture flows in curved lines round the obstacle. In a letter to Nature of July 26, 1883, Dr LonGe gives an account of some experiments he made on the dark plane and on dusty air. Dr Lopcr says— “We are now pretty well convinced that differences of temperature have nothing to do with the real nature of the phenomenon ; we jind that solid bodies have sharply defined dust-free coats or films of uniform thickness always surround- ing them, and that these coats can be continually taken off them, and as con- tinually renewed, by any current of air.” Dr Lopcer also describes a number of interesting electrical experiments on the dust, and makes many very valuable suggestions, but comes to no definite conclusion. He says—‘‘ Why,the air near a solid is free from dust we are. not prepared to say.” From these quotations it will be seen that the whole matter is involved in considerable obscurity; and as the subject already had considerable attractions for me, I determined to undertake an investigation in this particular direction. My experiments were begun in summer, but it was not till November that the greater part of the work was done. I have considerable difficulty in determining how it will be best for me to place the result of this investigation on record. Asa rule, it is best to take the reader over the road traversed by the investigator, as the probability is the difficulties of the one will be the same as those of the other, and the results generally unfold themselves best when treated in this way. In the present occasion this method is not suitable. The subject, though apparently simple enough, was found to be much more intricate and complicated than was expected. The result was, many a false scent was followed only to be given up, so that I would be taking the reader to my conclusions by a long, winding, and uninteresting path. It will therefore be better for me simply to describe the result of the investigation from my present point of view. Apparatus used. The apparatus used was all of the simplest and least expensive kind. The dust-box in which the experiments were made was a cigar-box, the lid of which was removed and a piece of glass put in its place. When in use the box was placed on its end, with the glass to the front. A window was cut out of the left side of the box, extending from close to the bottom to near the top, and coming close to the front of the box. The box was then painted black inside. Holes were cut in the back of the box, or wherever required for the introduction of the different pieces of apparatus, which shall be afterwards described. Asa source of illumination, two gas jets, placed close to each 242 MR JOHN AITKEN ON THE other, were used ; these jets were enclosed in a dark lantern, having an opening towards the dust-box. To concentrate the light, two double convex lenses were fitted into a short tube. This tube was loosely attached to the front of the dark lantern, and could be directed to, and focused on, any part in the interior of the dust-box. For observing the phenomena two magnifying glasses were employed —one a simple double convex lens, which was used for getting a general view of the phenomena; the other a more powerful compound glass, strong enough to enable me to see and follow the movements of the individual dust particles. For observations on the effects of slight differences of temperature, metal or glass tubes in some form or other were generally used. Straight tubes closed at one end were found most convenient; these tubes were introduced through the back of the box, and the closed end projected inwards to within a short dis- tance of the glass front, so as to admit of observation under the strong magni- fying glass. The tubes were heated or cooled by means of water or steam introduced into them through a small tube which passed down their interior. This small tube was connected by an india-rubber tube to a glass filler, into which the water was poured, and from which it flowed down the small tube to the front end of the experimental one, and returned to the outside of the box by the space between the tubes. In this way the experimental tube could be easily heated or cooled, and the space all round it left free for observation. For higher temperatures, a fine platinum wire, heated by means of a small bichromate of potash battery, was employed. Different kinds of dust were used in the experiments, such as dust made in the usual manner with hydrochloric acid and ammonia, and by burning sulphur in the presence of ammonia; this last was used when very dense fogging was required ; smoke of paper and other substances were experimented with; also dusts made by burning sodium or magnesium; and for experiments with dust which would not change with heat, calcined magnesia and lime were employed. Charcoal powder was also used in some experiments. The powders of these last three substances were stirred up by means of a jet of air. These dusts were also varied by the addition of water vapour. Suppose now that the gas is lit in the lantern, and the dust-box in its place Let us introduce into the box through the opening in the back one of the glass or metal tubes, closed at the front end, and introduce into this tube from the back the smaller one, and connect this latter with the filler, so as to enable us to pour hot or cold water through the tube, to heat or cool it. If we are going to use smoke, a piece of smouldering brown paper is introduced into the box, by removing the glass front, which is kept easily removable for this and other purposes ; or, if we are going to use sal-ammoniac dust, the ammonia and hydrochloric acid can be introduced on glass or wooden rods through small openings in the box, or the acid and ammonia may be placed in small open vessels inside the box. If the dense sulphate dust is required, the sulphur FORMATION OF SMALL CLEAR SPACES IN DUSTY ATR. 243 may be placed on a match and introduced into the box after being lighted. When the dust is thick enough, and uniformly distributed through the box, bring the light to a focus on the tube. For the present the tube must be neither heated nor cooled.. Using the magnifying glass ; it will in all proba- bility be found that there is a clear space all round the tube or on some part of it, and that the air currents are carrying off the clear space in an irregular manner, or there may be seen rising over the tube a regular dark plane, depend- ing on the relative temperatures of the air and the tube. Now remove the beam of light from the dust-box and leave it for some time. If left long enough, and the box kept free from changes of temperature, it will be found that all air currents have ceased, and a close examination of the experimental tube will show that the dust is now in contact with it at the sides and on the top. But if we look on the under side of the tube we shall there see a clear space, like that shown in fig. 1, which represents the tube seen endways.* It will be observed that this does not agree with Dr Lopar’s observations ; but I think I have taken every precaution, and the conclusion which I have come to is, that bodies have not sharply defined dust-free coats, and that when the bodies and the air have the same temperature, the dust comes into contact with the sides and top of the bodies.t Now what is the cause of this clear space under the tube? Clearly Gravitation, which brings me to the first of the causes of the dark plane. When the air comes to rest, the temperature of the air and the tube being the same, there is nothing to keep the dust from coming into contact with the tube. But gravita- tion is at work on the particles, and while the air is still the particles are all falling, and as the upper surface of the tube stops those falling on it, there are no particles to supply the place of those falling from the space under the tube, and the result is that a dustless space is here formed. If now we pour into the tube some cold water we can study the Kifects of Cold. At once a downward current is started, and this downward current carries with it the clear air under the tube; the two currents of dustless air from the sides * In the figs. the white surface represents the light-reflecting dusty air, while the black represents the transparent air, free from reflecting particles. + The only reason I can imagine for this difference between Dr Lopen’s results and mine is that he worked with more powerful sources of illumination than I did. He used either the sun’s light, an oxyhydrogen lamp, or a Serrin arce-lamp, while I only used gas. Now one result of this difference would evidently be that the illuminating beam used by him would have a much greater heating effect than the one used in my experiments, and would therefore heat the surfaces under examination. I found this effect even with gas. If the body had a small capacity for heat, it was only necessary to keep the light focused on it for a short time to heat it sufficiently to cause a clear space to form over the part where the light acted. 244 MR JOHN AITKEN ON THE of the tube meet underneath it, and forma dark plane in the centre of the descending current, as represented in fig. 2. It might be thought that gravitation would not act quickly enough to keep up a supply of dustless air sufficient for this purpose. This however does not seem to be the case, and gravitation appears to be the only cause of the distribution of the dust, causing this dark plane in the descending current. One reason for supposing this is, that if we only cool the tube very slightly, the dark plane is very thick and well marked; but the more we cool the tube the thinner does the dark plane become, intead of thicker, which would be the result if it was due to difference of temperature. The effect of the increased cold is to increase the velocity of the descending current, and draw out and thin down the dark plane. Further, if we closely examine the air round the tube with the strong magnifying glass, we shall see the particles of dust descending and settling on the horizontal part on the top of the tube, while the particles which fall a little to each side of the centre line are carried on by the current, and continue to clasp the tube closely till the current begins to turn under the tube, where the particles being free to fall, drop away from the tube, and leave a clear space (see fig. 2). This clear space only begins to be perceptible when the current begins to turn underneath the tube, and gradually becomes thicker as it travels underneath towards the centre where the two currents join, and form the descending dark plane. The rate at which dust settles out of air by gravitation is much quicker than we might imagine. Dust is kept in suspension by ascending currents, and when these are removed it settles remarkably quickly. There was an oppor- tunity for seeing this in these experiments. If the experimental tube was cooled, then the cold gave rise to currents descending on the side of the box where the tube was, and rising on the other side; but the rising current only came up to the height of the tube, and all the air above the tube was still and currentless, because its temperature increased towards the top of the box, and then was produced a condition of stable equilibrium. Under these circum- stances, I have frequently seen the whole of the upper part of the box above the cold tube become quite clear, and with a sharp line of demarcation between the clear still air above, and the dusty currents underneath. It is, of course, the vertical component of the currents that keeps the dust in suspension, the horizontal component having no such action. This may be seen when we cause a current of dusty air to flow along the under side of a horizontal flat surface. At the point where the current starts, the dust is in contact with the under surface of the body, but falls further and further from it as it flows — along. | In order to study the effect of temperature alone, it was necessary to arrange the experiment so as to get rid of this gravitation effect. For this purpose I prepared another piece of apparatus. The ideal shape of body for FORMATION OF SMALL CLEAR SPACES IN DUSTY AIR. 245 this purpose would be one having some length and breadth, but infinitely thin and flat, so that when placed vertically, the air in passing over it would never have to move in a horizontal direction. ‘The nearest approach I could make to this was made with a piece of copper foil folded on itself, soldered all round its edges, and fixed to the end of a brass tube. It was heated and cooled by passing into it hot or cold water. This instrument presented at the front edge extremely little thickness, and was found to answer well, but was rather delicate and easily put out of shape. As it is only necessary to examine one side of the test plane or surface, a different form of apparatus was afterwards adopted. It _ was made of a piece of brass tube the same as used in the previous experi- ments, and a flat plate of copper was soldered to one side of it at the front end. This plate was filed perfectly flat and smooth, and sharpened at the top and bottom edges, all the bevel being on the tube side of the plate. The side of the plate presented towards the source of illumination was thus a perfectly flat surface, and when placed vertically, the air passing over the front surface could not have its dust separated from it by gravitation, as a// the horizontal movement went to the back of the plate. Placing either of these test surfaces in the dust-box with the plate vertical, cold was applied. At once a downward current was produced, but no dark space was formed on the vertical test surface ; and if the copper foil apparatus, which is flat on both sides, is used, no dark plane whatever is formed, as shown in fig. 3. More intense cold was tried, and a temperature of —10° C. in air of a temperature of 15° C. was found to produce no effect save an increased rate of current, and an increased brightness in the particles near the plate, due to water vapour being deposited on them by the lowering of the tem- perature, an effect observed by Lord RAy1eicH on the dust bounding his cold dark plane. Different dusts were tried, and the experiment varied in many ways, ‘but when the gravitation effect was removed, not the slightest tendency to the formation of a dark plane by cold could be detected. The tendency seemed to be the other way. The dust particles in all cases tended to keep close to the cold body. This indicates that Lord Ray.eren’s dark plane formed in the descending current from a cold body is not an effect of the cold, but is due to the separating action of gravitation. What I am about to state may at first seem a contradiction of this conclusion. When varying the conditions of the experiment, and altering the amount of water vapour present, I was much surprised to find that under certain conditions the dark plane had a decided tendency to make its appearance in the descending current even from a thin vertical surface. On repeating t he experiment and varying it, it was found that the conditions best suited for getting this dark plane were when there was nothing but ordinary atmospheric dust in the box, and the air was saturated with water vapour. Under these conditions, there was generally all through the box a haziness, but in the space in front of the cold test 246 MR JOHN AITKEN ON THE surface the cold thickened this haziness into a dense cloudiness, which extended — for some distance from the plate and showered down from it. But between the fog and the test surface there was a well-marked dark space. To what was this due? I had already satisfied myself that cold did not tend to drive away the particles. Then why did these particles conduct themselves differently from the others? While the test surface was vertical, the motion of the particles was too quick to be followed with the magnifying glass. The surface was, therefore, placed nearly horizontal, with a slight slope towards the light (see fig. 4). Still the dark space remained, and the current flowed on, but the — particles did not come close up to the plate, though gravitation was acting on them. The cold could surely not be repelling the particles and keeping them off the plate. A short examination with the strong magnifying glass, which it was now possible to use as the particles were moving slowly enough, showed that this was not the case. The particles were seen flowing along in the current, but at the same time they were seen falling into the dark space and disappearing when they came within a certain distance of the surface. The explanation was evident. The surface, by its very low temperature, had robbed the air close to it of its moisture, which it deposited on itself in ice crystals. Into this cold but drier air the particles evaporated as they fell, and in this case the dark plane would contain the dust of the atmosphere, which, however, is black, compared with the brilliancy of the surrounding fog. In this case the dark plane was produced by Evaporation, and this explains why it is not visible when artificial dusts are present, the larger particles of the artificial dusts not being sufficiently reduced by evaporation to make them comparatively invisible. We shall now pass on to consider the Effects of Heat. For this purpose let us remove the flat test surface from the smoke-box, and put in its place a round tube of metal or glass. A glass one is preferable, as it permits the illuminating beam to pass through it, and we are thus enabled to see what is taking place all round. After the box is filled with dust, leave it for some time, till the tube has acquired the same temperature as the air. On examination we shall find, as before, the particles evenly distributed, and coming close up to the surface of the tube on the top and at the sides, while underneath we shall see the clear space produced by gravitation. We shall first examine what the effect is of a slight difference of temperature. For this purpose we shall pour some slightly heated water through the tube, so as to raise its temperature a very little—a degree or two. When this is done the equilibrium is destroyed, and currents begin to form. The clear space formed by gravita- tion under the tube rises up, closely clasping and encircling the tube m aa FORMATION OF SMALL CLEAR SPACES IN DUSTY AIR. 247 a dustless envelope. The two currents of clear air which started from the under side of the tube, reunite at the top after passing round the sides, and ascending in the centre of the upward current, form a well-marked dark plane (see fig. 5). Here again gravitation seems to be the principal cause of the distribution of the particles. This certainly is the case when the difference or temperature is very slight, but we shall see that, as the temperature rises, the gravitation effect bears a less and less proportion to the heat effects, which we shall presently consider. It will be as well to note here the difference in the clear space surrounding the tube in this case and when cold was applied, as shown in figs. 2and 5. When cold was applied (fig. 2), the dark space was only on the under side of the tube ; but with heat it is all round the tube, because it has its origin in the air under thé tube. | When making these experiments a somewhat peculiar effect was often noticed, which seems worth recording, as it forms a good illustration of the influences at work here. If, after the tube had been warmed and a well- marked dark plane formed over it, no more hot water was added, and the tube allowed to cool, the upward current became sluggish after a time, and the dark space presented the appearance shown in fig.6. The two sides of the tube now differed. The left side was bounded by a clear space, which ascended as before, but on the other side, the dark space did not continue to the top of the tube. As shown, the particles here came into the dark space and obliterated it. The explanation of this peculiar effect, which so often repeated itself, is this. The falling temperature had allowed the current on the right side to become so slow that gravitation had time to act on the particles after the current turned to the upper side of the tube, and the particles had time to fall through the clear space before they were carried into the ascending current over the tube. In other words, gravitation undid on the upper part over the tube what it did at the under. The left side of the tube continued to keep its clear space, because the light used for illuminating it was focused on this side; it, therefore, was slightly warmer than the other. Gravitation, while it explains the formation of the dark plane in such cases as above described, where the difference of temperature is slight, is evidently not the whole explanation. Gravitation can obviously have little to do with the formation of the dark plane formed over a thin wire, as the time occupied in horizontal movement when going round so small a body is not enough for it | to have any appreciable effect. In order to study the effects of heat apart from those of gravitation, the tube with the flat surface fixed on it, employed in the experiment with cold, was used, as it eliminates the gravitation effect and shows the heat effect alone. Fixing this piece of apparatus in the smoke-box with the test surface carefully adjusted in a vertical plane, heat was slowly applied to it. An upward current at once started, and it was noticed that at VOL, XXXII. PART II. aT 248 MR JOHN AITKEN ON THE the same time a clear space was formed on the hot surface, and rose up from it, producing a dark plane in the ascending current (fig. 7). This clear space was evidently entirely due to the heat in some way driving the particles away from the hot surface. When working with this flat test surface it is necessary to be careful about the adjustment of it ina vertical plane. Ifthe surface leans either to the one side or to the other, a clear space is, of course, formed on the side to which it inclines by the separating action of gravitation, and gravitation also acts on the particles on the other side, and tends to counteract the effect of the heat. Further, if the surface is inclined enough, the gravitation effect overcomes the heat effect, and destroys the dark space by causing the particles to fall towards the hot surface. At the same time, the gravitation dark space on the under side becomes thicker and thicker the more the plane of the test surface approaches the horizontal. This instrument may be made capable of measuring the relative effects of different temperatures, &c., by providing it with a scale to indicate its angle with the vertical. The greater the angle at which the dark space is visible the greater will be the repelling force. By the construction of the instrument, when placed vertically, the gravita- tion effect is entirely removed. The dust particles can be seen coming straight up, and no purified current coming from the under side (compare figs. 5 and 7). The clear space begins to show itself with a very slight rise of temperature. Indeed, it would appear that it is formed by the slightest rise of temperature, — as it always begins to be visible just when the temperature is high enough to cause an ascending current. With a slight difference of temperature it is extremely thin, and requires careful observation to detect it, but as the tem- perature rises it becomes thicker and thicker. For the present I shall not enter into the question as to why the dust particles move away from a hot body, but shall leave the consideration of this subject till after describing some experi- ments which seem to throw some light on the mechanism of these movements. — For the present I shall simply speak of it as repulsion due to heat. The following experiments will help us to understand the action of this repulsion. Fix a piece of glass in front of, and parallel to, our flat test surface, and ata distance from it of two or three millimetres. Glass is used because it is transparent, and allows the illuminating beam to penetrate and show us what is taking place at the different surfaces. If we now warm the test surface, the dust particles all move away from it towards the glass plate, and many of them attach themselves to the glass. After a short time the glass gets warmed by radiation, &c., from the hot test surface. If we now cool the test surface a change takes place, the dust particles move away from the glass, and crowd up towards the colder test surface. A better form of the experiment is shown at figs. 8 and 9. A glass plate FORMATION OF SMALL CLEAR SPACES IN DUSTY AIR. 249 A, 12 cm. long and about 4 cm. broad is attached by means of cement, near its upper end, toa metal tube, to enable us to heat it while in the dust-box. Another plate of glass B, of the same size as A, is placed opposite and parallel to it, at a distance of about 5mm. The plate attached to the tube is first put in its place in the box, and after it has acquired the temperature of the air, the other plate B is warmed and put in its place, opposite to A, as shown in sketch. The box is now filled with dust. If we now carefully examine the air between the two glass plates, we shall find that the warm plate B (fig. 8) is bounded on each side by a clear space, its high temperature having driven all the dust particles to a distance, while the other plate has no clear space round it. Now let us put a little warm water into the tube to heat the upper part of the cold glass plate A, and note the change in the distribution of the dust. As before, the lower part of B is bounded by a clear space (see fig. 9), but the upper part of A being now warmer than B, the dust is driven from A towards B, and a clear space opened in front of the hot part of A, while the clear space formerly in front of the upper part of B is closed. The heat has thus caused the dust particles to move across the direction of motion of the air. These experiments have been made with different dusts, and always with the same result. For the purpose of studying the effects of higher temperatures than that of boiling water, a fine platinum wire was fitted up inside the dust-box and heated by means of a small bichromate battery. The arrangement of wire which I prefer for this purpose is made by bending it into a U-shape and bringing the two legs close together, say one or two millimetres apart. The wire is placed horizontally in the dust-box, with the bend to the front, and the legs at the same level, the two copper wires to which it is attached being carried backward and out of the box. By this arrangement a clear end-view is obtained all round the wire, and the effect of the heat conveniently observed, and further, the wire doubled in this manner, tells us more than a single wire can. . In experimenting with this arrangement of apparatus, the results are as varied as the dusts employed. Each dust gives a different size of dark plane for the same temperature. The previous experiments with less intense heat seemed to point to repulsion as the cause of the clearing away of the particles. If this were the case, it seemed very unlikely that some dusts would be repelled further away than others, at least to the extent that actually took place. To see if repulsion was the explanation in this case also, instead of a single wire, which I used in my first experiments, I doubled the wire into a U-shape, as already explained, and placed the length horizontally, with the legs at the same level. When this wire was heated in the sal-ammoniac or in sulphate dust, it was at once evident that repulsion was not the cause of the dark plane in these dusts. With either of them, when the temperature of the wire was not 250 MR JOHN AITKEN ON THE very high, the dark plane rising over each leg was very thin (see fig. 10), but as the temperature rose, the planes extended on each side till the two planes met and formed one large one (see fig. 11). An examination by means of a magnifying glass showed that this broad dark plane was due to the evaporation, or to the disintegration of the particles, as they could be seen streaming upwards and disappearing into the dark space under the wires. They there arrived at a space the temperature of which was sufficient to convert them into gases or vapours. The dark plane in this case was thus due to a change of the particles from the solid to the gaseous state. Hence the great differences in the size of the dark planes of different dusts, each kind of dust having a different temperature at which it evaporates or becomes disintegrated. The sulphate dust, for instance, gives a smaller dark plane than the chloride, because the sulphate requires a higher temperature to drive it into the gaseous state than the chloride. This result is quite different from that got with temperatures which were not sufficient to vaporise the particles and make them invisible. It was there- fore now desirable to make experiments with some substance which a high temperature could not destroy. For this purpose I selected calcined magnesia and calcined lime, also soda and magnesia dusts, produced by burning the metals. With these dusts a different result was obtained. A high temperature had no other effect than forming a thin dark plane over each wire (see fig. 10). But even these stable forms of dust were subjected to a repulsion, the particles passing near the wire being driven to a small distance from it on each side. It may be possible that some of the particles of these dusts are vaporised, but if so, the amount must be very small, and can have but little influence on the formation of the dark plane. Another effect noticed in these, and in the experiments at lower tempera- tures, was that whenever there was much water vapour present, there was a faintly indicated dark plane formed by the evaporation of the water from the particles. If nothing but the dust of the air was present in a fog formed with steam, then the wires were surrounded by a very thick dark plane, due to the evaporation of the fog particles ; and if any artificial dust was present, then the thick dark plane was still visible, but not black, as the particles were only reduced in size by the evaporation of the water from them. All these different effects of the hot wire can be illustrated at one time, if we put into the dust- box some indestructible dust, also some sal-ammoniac and sulphate dusts, in proper proportion, and then add some water vapour. When the wire is heated in such a mixture, we get a result like that shown in fig. 12. In the centre we have the true dark plane, in the wider space there is only the indestructible powder present. The next boundary shows the vaporising zone of the sulphate, the next the vaporising zone of the sal-ammoniac dust, and the last that of water. In fig. 12, @ is the true dark plane, in which there is nothing but gases and FORMATION OF SMALL CLEAR SPACES IN DUSTY AIR. 2351 vapours ; in the wider space b, both the chloride and sulphate dusts are vaporised, and we have nothing visible save the indestructible dust ; in the next space ¢ the chloride is vaporised, and there are present the sulphate and indestructible dusts; while in the space d all the dusts are present, but dry, the condensed water being evaporated. Conclusion. The conclusion we have arrived at from these experiments is, that for the formation of the dark plane in dusty air, there are various causes which may be classed under the following heads :—With cold, producing the downward dark plane, we have—1st, the distributing effect of gravitation; and 2nd, the dis- appearance of the particles by evaporation, when falling into a space rendered dry by condensation produced by cold. With heat, producing the upward dark plane, we have—lIst, the distributing action of gravitation; 2nd, the distributing action of repulsion due to heat ; 3rd, evaporation of the particles; and 4th, dis- integration of the dust. In the last two cases the dust is rendered invisible by the heat changing it from the solid light-reflecting condition to the transparent gaseous state. Effect of Centrifugal Force. We may here ask ourselves, Are these the only ways in which the dark plane may be produced? It is, of course, impossible to give a definite answer to such a question. There are, no doubt, other ways in which it seems possible that this phenomenon might be produced, and it seemed worth while to consider | Lord Ray eicu’s suggestion as to the effect of centrifugal force. On consider- | ing the action of this force in the experiments described, it is evident that it can have but little to do with the distribution of the particles, because the air, in rising and passing round the wires and tubes, is curved first in one direction, and before it again takes up its original direction of motion, it is curved to an equal amount in the opposite way. So that whatever sifting action the centri- fugal force may have at the one part of its course, will be undone at the other. | 1, however, thought it worth while to arrange an experiment, to see if the par- | ticles really were thrown out by centrifugal force at any part of their passage. || With this object, I fixed inside the dust-box a piece of thin sheet metal, with its plane vertical. Arrangements were made so that a current of dusty air was \caused to flow down the one side of the plate, round the lower edge, and up the other side. In this way the air was caused to curve through an angle of /180°, and no curving in the opposite direction took place. When this was \done, it was seen to be possible to give an appearance very like as if the cen- rifugal force did throw the particles away from the centre of motion. In front, nd just above the lower edge of the plate, there was formed a clear space, —————E—E————— oo . iw) 52 MR JOHN AITKEN ON THE very near the centre of rotation of the air. On examination, however, it was seen that this was caused by an eddy, due to the upward channel in which the air was confined being wider than the space under the plate. In the eddy so formed the particles were soon sifted out by gravitation, and a clear space formed. On contracting the breadth of the upward channel, and making it equal to the passage under the plate, this eddy disappeared, and the clear space was no longer formed. In this experiment, though the air was caused to curve through a considerable angle, yet there was no satisfactory evidence of any — distributing action due to centrifugal force. It seems probable that, even under these conditions, a certain amount of sifting action does take place, though not enough to make it observable; and though there are reasons for supposing that if the particles were heavy enough, and the velocity of the current great enough, there would be a visible effect, yet it is evident that centrifugal force plays no part in the formation of the dark plane, in the experiments with heat and cold. The fact that the dark plane has a sharply defined boundary is proof that centrifugal force is not the cause of the distri- bution, as this force would not give such a result. Its tendency would be to throw the heaviest particles furthest out, and thus give rise to a shaded outline. Effect of Electricity. Electricity is another force which might be supposed to play some part in the formation of the dark plane. It was difficult to believe that the attraction of the particles was a thermal effect when making the experiments with the hot and cold surfaces placed opposite each other, and observing the way in which the particles were repelled by the one plate and attracted to the other; and on making other experiments, which will be presently described, in which the dust rising in the current from the heated platinum wires was attracted to, and deposited itself on, the surfaces of bodies placed in its path. The dust particles conducted themselves in a waystrongly suggestive of electricaldisturbance. They seemed to be attracted by the cold surfaces in exactly the same way as if they had become electrified at the hot surface. It was, therefore, thought advisable to make experiments to ascertain whether electricity had anything to do with the formation of the dark plane. Experiments were first made to see if the hot sur- face became electrified in the dust-box by the passage of the air over it, or from other causes. For this purpose I used a small cylindrical conductor of solid metal, about 1 cm. in diameter, and with rounded ends. This conductor was fixed to the end of a glass tube, and a conducting wire connected to it and carried through the tube. The conductor was then introduced into the dust- box through an opening in the back, after which its connecting wire was jomed to a gold-leaf electroscope. Before the conductor was put in its place it was FORMATION OF SMALL CLEAR SPACES IN DUSTY ATR. 253 heated, and the box was filled with dust. Examined with the magnifying glass in the usual way, the dark plane was found to be well marked and the repulsion going on as usual, but not the slightest sign of electrification showed itself at the electroscope. No signs of electricity having shown themselves at the hot surface, it was sought for in the ascending current. This was done by first removing the insulated heater and putting in its place the platinum wire, to get a more intense effect from the high temperature. Over the wire was placed a large insulated flat-shaped conductor for the dust to deposit itself upon. The conductor was then connected to the electroscope, the box filled with dust, and the electric current turned on to heat the wire. The leaves of the electroscope, however, remained close together, so that the dust deposited on the conductor could not have been charged with electricity. It may be objected to these experiments that the electroscope used was not sensitive enough for the purpose, and that if a more sensitive instrument had been employed, signs of electricity might have been obtained. It is quite possible that another instrument might have shown signs of electrical disturb- ance, but I think that if electricity was the cause of these phenomena, and was sufficiently strong to repel the particles and to cause them to adhere to bodies, it would be quite powerful enough to separate the leaves of the electroscope. Any electrification less than would affect the leaves would only be a secondary matter, and could not be the cause of the phenomena. Another reason for supposing that electricity has little to do with these effects is that the dust tends to settle only on cold surfaces. Experiments were now made to see what the effect is of electrifying the hot surface. The small cylindrical conductor was heated, placed in the box, and connected with the electroscope. A Leyden jar charged very slightly, but enough to cause the full divergence of the leaves of the electroscope, was then connected with the apparatus, and the effect on the dust surrounding the electri- fied conductor noted. While the body was hot enough to cause a well-marked dark plane, there was not the slightest effect produced by the electricity, though the leaves of the electroscope were wide apart, and showed that the hot surface had a decided charge. The electroscope was then removed, and a much higher charge given to the conductor. This time an effect was evident, but it was difficult to say what was taking place. The general appearance of the air round the hot conductor had quite changed. The sharp outline of the clear space round it was destroyed, and the dark plane over it had lost its clear and sharp outline, and had become much thicker, though not so dark, as before. All round the conductor there seemed to rage miniature storms, and the particles had much the appearance as if they were seen all out of focus. This effect was produced by either positive or negative charge. To find out what was taking place in the air round the electrified body, I 954 MR JOHN AITKEN ON THE had recourse to large-sized particles of dust to enable me to follow the move- ment of each particle. Calcined magnesia was selected for this purpose. When the air in the dust-box was filled with this powder, the reason of the change in the dark space at once became evident. The particles in the ascend- ing current could be seen rushing towards the electrified surface and adhering to it. The dark space was thus broken in upon, and its outline destroyed by the attracted particles ; the air round the body was at the same time deprived of a great quantity of its dust ; and over the conductor there rose a thick and ill-defined band of clearer air, the particles which formerly were in it having attached themselves to the electrified body. All the particles did not seem to be equally attracted, but some much more than others. This gave rise to the irregular movements seen all round the body. The dust particles frequently deposited themselves on the conductor in small needle-like radial columns, which grew by the addition of the particles till they got to a certain size, when they were shot off and flew through the air with surprising velo- city. If, after the conductor had been electrified a short time, the supply of electricity was cut off and the conductor connected with the electroscope, the charge given to the air and the dust in the box was given back. The leaves of the electroscope expanded quickly, and if discharged, rapidly became charged again, the dust at the same time being attracted to and deposited on the con- ductor in needle-like columns. After looking at this last experiment, and seeing the tendency which particles in electrified air have to deposit themselves on bodies, we cannot help asking — the question, Does this experiment throw any light on the well-known tendency to the development of certain forms of bacteria resulting in the putrefaction of our foods, and in the appearance of increased quantities of certain ferments during thundery weather? Can it be that the germs of these forms of life floating in our atmosphere have a far greater tendency to settle upon the — surface of bodies from electrified air than when there is no electrical disturb- ance? No doubt this electrical attraction must have some effect in this direction, but whether it is the principal cause or not I shall not venture to say. If we use still higher degrees of electrification than those used in the above experiments, other effects are produced, but they have no relation whatever to the formation of the dark plane. From the experiments described it will be seen that the effects of electricity are of quite a different kind from those of — heat. The electrified body, instead of repelling the particles like a hot one, attracts them, and clears the air in a partial way by attracting some of the par- ticles to itself, while heat acts by repelling all of them to a distance. This anta- gonism between the two forces may be illustrated by heating the conductor and electrifying it slightly. At first no effect is produced by the electricity ; the FORMATION OF SMALL CLEAR SPACES IN DUSTY AIR. 255 dark plane remains quite clear, but as the temperature falls, a stage is arrived at when the electrical effect overcomes the heat effect, and the particles break in on the dark space and destroy it. In making electrical experiments, most of us have noticed the tendency which dust in the room has to settle on the different parts of the electrical apparatus, and to destroy the insulation, and many have noticed the excited and rapid movements of electrified dust. Dr Lopae, in the letter already referred to, remarks on the rapidity with which the dust-box, in his experiments, was cleared of its dust by means of electrified bodies placed inside it. I have made some experiments on this subject, to determine the conditions most favourable for the clearing of air by means of electricity. For these experiments I preferred to use a large glass flask about 30 cm. in diameter. Placing this flask with its mouth downwards, I introduced into it an insulated metal rod, fixed vertically, and passing through the open neck of the flask. Ifa dense cloudiness was made in the flask with any dust, by preference it was generally made by burn- ing sulphur and adding a little ammonia. After a dense whiteness had been produced, the conductor was electrified. Seen from a distance, no change seemed to have taken place, but on examination it was found that all the dust was deposited on the inside of the flask ina nearly uniform white coating. To enable me to see what was taking place, the inside of the flask was wetted. When. the electrification began, the dust could now be seen driven about as by a violent wind, and, after a few turns of the machine, it had disap- peared from the flask. The conditions found most suitable for producing this result quickly were a rapid discharge of the electricity into the dusty air by means of a point or points. If the conductor terminates in a ball inside the flask, the electrification has but little effect. In addition to the conductor terminating in a point, it is also necessary to have near the electrified point surfaces to aid in the rapid electrification of the dust. When the point is surrounded by surfaces the air currents are violent, but if we remove the sur- faces the currents are not nearly so strong. This may be seen by allowing a cloud of dust to rise round a conductor placed in an open space, when but little effect will be observed on electrification. After the dust has been electrified, it ought to be brought near some surface, towards which it may be attracted, otherwise it may lose its charge before meeting a place to deposit itself. Experiments have also been made to determine whether the very fine and invisible dust of the atmosphere is also caused to deposit itself when electrified. With this object the large glass flask had an india-rubber stopper fitte] to it, through which passed a tube to connect the interior of the flask with an air- pump, to test the condition of the air in the flask by reducing its pressure, while it was kept moist by the presence of water, and to observe whether any cloudy condensation took place after electrification. A conductor insulated in VOL, XXXII. PART IL 2U 256 MR JOHN AITKEN ON THE a glass tube passed through the stopper, and terminated in a point inside the flask. Means were taken to insure the insulation of this conductor inside the flask. This was done by surrounding the insulating tube with another tube, and causing the entering dry air to pass into the flask through the space between the tubes. The insulation was thereby kept good, and the glow of the dis- charge at the point was quite visible in the midst of the moist air. On experimenting with this apparatus, it was found that electrification for a short time by means of an ordinary cylindrical electrical machine was sufficient to deposit almost all the dust, only the very slightest signs of condensation being visible after electrification. What formed the nuclei of the very few cloud par- ticles which appeared it is difficult to say. Whether they were undeposited dust particles, or particles thrown off the conductor, or some product of the electric discharge, this experiment does not determine. That they may be some pro- — duct formed from the air by the electric discharge is suggested by the following experiment. First purify the air in the flask, either by passing it through a cotton-wool filter, or by electrification, then reduce the pressure to super- saturate it, and now electrify. At once a cloud forms all round the conductor, and extends to near the sides of the vessel. This cloud is evidently not formed by anything thrown off the conductor, forming nuclei, as it appears at the same moment all round the point. It is more probable that the nuclei of these cloud particles are formed by the discharge of the electricity producing in the air nitric acid, or ozone, on which the supersaturated vapour condenses. That the nuclei so formed are not solid particles there seems to be but little doubt, because if we allow filtered air to enter so as to increase the pressure and evaporate the particles, cloudiness does not reappear on again reducing the pressure, which it certainly would do if the nuclei had been solid particles, The number of nuclei that remain after electrification is very small, if the air is not supersaturated with vapour; and practically we may say that electrifica tion deposits all the very fine dust, and I may remark here that it does it in a very rapid manner. The air in the flask can be purified much quicker by means of electricity than by the air-pump and cotton-wool filter. It may be noted here that the dust of the atmosphere has but little effect on the brilliancy of the glow of the point discharge. With a large amount of dust, with the ordinary dust, with no dust, and with the electrification used, no difference of importance in the brightness of the glow was detected. The Lungs and Dust. When we see a beam of sunlight shining into a darkened room through a small opening, and revealing, by illuminating, the suspended dust, making the beam look like a solid body, we have great difficulty in realising that our atmo- FORMATION OF SMALL CLEAR SPACES IN DUSTY AIR. Vi sphere can be so full cf dust, as this experiment shows it to be, as it escapes our observation under ordinary conditions of lighting, and it gives us a feeling of discomfort to realise that we are breathing that dust-laden air. This uneasiness was by no means decreased when my experiments on cloudy condensation revealed the fact that, in addition to that mass of visible dust, there are enormous multitudes of particles so small that even the concentrated light of the sun does not revealthem. These minute particles are so numerous that hundreds of them are crowded into every cubic centimetre of air. On realising these facts our feelings are those of wonder that our lungs can keep so clean as they do, while such vast quantities of impurities are constantly ebbing and flowing through them. Atthat time I was not aware that there is an influence ever at work tend- ing to protect the lungs by preventing, to a certain extent, the particles of dust coming into contact with their surfaces,—that nature had provided a subtle form of mechanism possessing some of the advantages of a filter without any of its disadvantages. The experiments here described show that a hot surface repels the dust particles in the air. The heat of our bodies will, therefore, exert a protective influence on the lungs, and tend to keep them free from dust. Our lungs, however, are not only hot, they are also wet. What influence will the constant evaporation which takes place at the surface of the tubes and passages have on the dust? To answer this question, I fitted the flat test surface in the dust-box, and through an opening in the top introduced a brush dipped in water, with which one-half of the surface was kept wet, the other half being dry, to compare the effects under the two conditions. When the surface was heated a few degrees, to even less than the temperature of our bodies, the result was most decided, the dust being driven more than twice as far from the plate in front of the wet part as it was from the dry. The evaporation, there- fore, of the water from the surface of the bronchial tubes tends strongly to ward off the dust, and keep it from coming into contact with their surfaces. We must not, however, imagine that the heat, or the heat and the evaporation, are sufficient entirely to prevent the dust coming into contact with the surfaces of our bronchial tubes and passages, because dust really does come into contact with them, but it does not do so nearly to the extent to which we have been in the habit of supposing. The necessary conditions for this repulsive effect to be active are, that the air is acquiring heat and moisture. If the air has the same temperature as our bodies, and is saturated with vapour, this force no longer exists, and gravi- tation and other forces are free to act. Although the repulsion due to heat and evaporation are not powerful enough to form a perfect protection to the lung surfaces against the contami- nation of dust, yet it is very evident that their protective influence will have a 258 MR JOHN AITKEN ON THE most important effect on the condition of our Jungs, and one towards which I wish to direct the attention of those who make this organ a special study. There seems to be but little doubt that we have here an explanation of some of the effects of different climates. For instance, what a difference there must be in the amount of dust deposited on the lungs from air breathed at, say, St Moritz or Davos Platz, and at such places as Madeira or other similar health resorts! These remarks are altogether apart from the question of the amount of dust in the air at the different places, and refer only to the action of the lungs on the dust which may be present.* In the Alpine resorts the air is cold and dry, and the tidal air, which flows backwards and forwards through the bronchial tubes, is in the very best condition for preventing the dust coming into contact with their surfaces, as the difference in temperature between the air and the body is great, and the air is also capable of causing a rapid evaporation. Whereas, at such places as Madeira, where the air is hot and moist, the repelling forces are both at a minimum. The effects of these different conditions on the lungs seems well worth study. : In illustration of the protective influence of heat and moisture many experi- ments may be made, but the following is perhaps the easiest. Take an ordinary — paraffin lamp, raise the flame till a very dense cloud of smoke rises from it. Over the lamp place a very tall metal chimney, to produce a quick current of air and also to cool it. Have ready two porous cylindrical jars (porous © jars are used because they keep up a supply of water for evaporation), one jar filled with water slightiy heated, and the other with cold water. Cover both jars with wet white paper. Now introduce the hot one into the top of the chimney, and leave the black wreaths of smoke to stream over it for say half a minute, then take it out and put in its place the cold one, and leave it for the same length of time. The result will be, the hot one will be quite clean, not a speck of soot on it, while the cold one is covered with soot. It is not, however, so black as a cold dry surface would be, as the slight evaporation from its surface tends to protect it. We must not, however, suppose that the lung surfaces are so well protected as the paper in this experiment. In the lungs the currents are quicker, they do not flow over such uniform surfaces, and further, they pass round curves, so that in the lungs dust tends to deposit where the currents flow quickly where they strike on the concave side of curved passages and on pro- jecting edges. Further, all dust which penetrates beyond the tidal air and gets into the residual air will ultimately fall on the surfaces of the tubes and air * The amount of dust breathed by invalids at the two places will not be greatly different, as most of their time is spent in the house, and the air in the rooms at the two places will be nearly ejually dusty. The higher temperature inside will slightly reduce the thermal effect, but will no diminish tlie rate of evaporation. FORMATION OF SMALL CLEAR SPACES IN DUSTY AIR. 259 cells. This tendency of the dust in the residual air to settle is increased by the load of water deposited on it by the moist air. The amount to which our lungs are protected by heat and evaporation can scarcely be solved in a physical laboratory, and will be best determined by anatomical examinations of lungs which have lived under different conditions of temperature and moisture. A Thermic Filter. Having observed that the dust particles tended to move away from hot bodies and to attach themselves to cold ones, I made some experiments on the subject to study the movements of dust particles when placed between hot and cold surfaces. Most interesting results were obtained by placing near the hot platinum wires, already referred to, a piece of glass or a plate of metal, and getting the dust deposited upon it. One arrangement of the experiment is to place the glass with its plane vertical and transversely over the wires, at such a height that its lower edge almost touches the wires, and fill the box with dust by blowing up some calcined magnesia or other fine powder. After all the currents have settled, and while the air is still full of dust, the electric current is turned on and the wire heated. A well-marked dark plane at once rises over the wire, and in its upward passage it is cut transversely by the glass plate. After the plate has been left for some time with the air current streaming over its surface, it is found to have a very beautiful impres- sion of the dark plane imprinted on it. The warm air, in streaming upwards over the surface of the glass, deposited its dust on it, and the fact of there being no dust in the dark plane is recorded by a well-defined line of clear glass, the deposit of dust on each side of the clean line being thickest just along the edge, and thinning away on each side. These impressions of the dark plane may be made permanent by causing the dust to be deposited on a plate newly coated with black varnish, and used while the varnish is still soft. It is not necessary to put anything on the surface of the glass to cause the dust to adhere, as it attaches itself to a clean surface of glass with considerable firmness, but some adhesive substance on the plate enables the impression to stand rougher treatment. Impressions of the dark plane have also been made with charcoal dust deposited on opal glass. These black impressions are, of course, “negatives” of the magnesia ones, the plane in the former case being white, surrounded by black dust. The charcoal dust was securely fixed by first coating the glass with a thin solution of gum, which was dried before the dust was deposited on it, and the dust fixed by breathing on the surface. If in place of putting a plate vertically over the wires, we place two plates vertically—one at each side of the wire—we then get the dust deposited on the plates, thickest opposite to the wires and thinner higher up. Arrangements 260 MR JOHN AITKEN ON THE were made for studying the action of surfaces placed on both sides of the wires. Fixing the plates parallel to each other, and at a distance of 2 or 3 mm. apart, — with the platinum wire between them, I carefully watched the motions of the particles carried up in the air current. As the particles approached the wires they gradually changed the direction of their motion, and instead of coming straight up they curved towards the sides, some of the particles striking and adhering to the side plates at a point below the wire. Some rose higher and stuck opposite to it, others went higher still, while others passed on to the top and escaped. I had for some time been trying to arrange an experiment in which I should be able to watch the movements of the individual particles of dust, so as to see them moving away from the hot surface. My intention was to examine the movements of the particles with a microscope of low power, or with a powerful magnifying glass. My great difficulty, however, was to get the movements due to the convection currents sufficiently slow to enable me to follow the moving particles when much magnified. After making the experiment last described, I saw it was possible to arrange for this much-desired observa- tion. The use of the large particles of magnesia enabled me to dispense with the microscope, and use only a magnifying glass of moderate power; and by — bringing the plates on each side of the wire close together, the velocity of the upward convection current could be greatly reduced by the friction of these surfaces, and by their cooling effect on the gases. The two side plates of glass were accordingly brought closer together, to a distance of about 1 millimetre. Fig. 13 represents the arrangement magnified five times, the U-shaped wire being shown in section between the plates. The ascending current was now very slow, and no difficulty was experienced in following the movements of the individual particles, so I had at last the satisfaction of seeing the particles being repelled by the hot wire. When the wire, heated to a red heat in air filled with magnesia dust, was examined by means of a magnifying glass, the spectacle which presented itself was most curious and interesting. At a distance below the wires, the particles — could be seen coming straight up between the glass plates, but as they approached — the wires they seemed to get uneasy, and as if wishing to avoid the heat, some of them attached themselves quickly to the glass, others went further up, but soon curved towards the sides and adhered to them; while others boldly — advanced straight up, almost to the wires, when their motion was suddenly arrested and they were driven downwards and sideways, and attached themselves to the glass. If the wires were hot enough, not a single particle got past them, and the glass plates had each a patch of magnesian powder adhering to its surface below the level of the wires. The direction of movement of the par- ticles is roughly indicated by the lines in fig. 13. FORMATION OF SMALL CLEAR SPACES IN DUSTY AIR. 261 These experiments naturally suggested the possibility of constructing an air filter on thermic principles. They showed that the visible particles of dust could be thrown out of the air, as the particles tended to move from the hot parts, and to attach themselves to cold surfaces. But the question which naturally suggested itself was, Are the very small invisible particles also arrested ? If the thermic filter turned out to be a success, it appeared to me it would also be the best way to get an answer to this question. In order to filter air on thermic principles, all that appeared necessary was to pass the air through a space or channel, the two sides of which were kept at different temperatures. In this way I hoped the dust would be driven from the hot side and attach itself to the cold one. Practically to carry out this idea, the simplest method that suggested itself was to pass the air through the space between two concentric tubes, the one tube being kept hot, and the other cold. In the preliminary instruments which have been made, the distance between the tubes forming the space through which the air passes, is in one instrument less than 1 mm., but in other instruments this space is nearly as much as 3mm. The length of the passage in the different instruments is about 35 cm. One of these instruments has the outer tube jacketed by means of a larger pipe for the purpose of heating it with steam. The other instruments were heated simply by means of a gas flame. The filter is shown in section, fig. 14. A is a tube about 13 mm. diameter. B is another tube slightly larger, and allowing a space C, between the two for the passage of the air to be filtered, which enters and leaves by the tubes D,D. The outer tube E forms a steam jacket round B. F, F are pipes for steam entering, and for condensed water leaving the jacket. The pipe A is kept cold by means of a stream of water. In working the instru- ment it is not, however, necessary to keep to this arrangement ; steam may be admitted to the centre tube A, and cold water to the outside jacket; both arrangements do equally well. For the purpose of cleaning and examining the surfaces of the air channel, the centre tube was not permanently fixed in its place, but was so arranged that it could be easily taken out, and the joints were made tight by means of the short pieces of india-rubber tube H,H. The air, after passing through the space C, was conveyed by means of a tube to a glass flask, in which there was a little water. The flask in turn was connected by means of another tube to an air-pump, in order to test the condition of the air after passing through the instrument. If cloudy condensation is produced when the pressure is reduced in the flask, we know that the air is not filtered; and, on the other hand, if the air remains perfectly clear on exhausting, we know that no dust, not even the invisible particles, have passed into it. The apparatus was fitted up for trial, all the connections being made and tested. Using the instrument heated with flame, the first effect of the heat, as expected, was a great increase in the fogging. The temperature was raised 262 MR JOHN AITKEN ON THE as high as it safely could be, to cleanse the instrument thoroughly ; after which, as we know, it will cease to give off nuclei at a lower temperature. When the tube was thoroughly cleansed by means of heat, and all the impurities swept out of it by a current of air, the temperature was lowered slightly, and the air allowed to pass slowly through the tube on its way to the test-flask. After this, the fogging in the flask gradually diminished, and after passing through the rainy stage, it ceased entirely, proving that the filter was doing its work thoroughly, not a single particle— not even one of the very minute and invisible ones—escaping it. On equalising the temperature, either making both tubes hot or both cold, the filtering action of course ceased. It does seem somewhat strange that air should be freed from all its dust in passing through a channel large enough for a fly to pass, if it has sufficient intelligence to keep always on the cold side. All who have experimented on this subject know that dust can get through any opening, however small. On testing this filter for the first time, I failed to get a satis- factory result. I however felt convinced that it ought to work, and the failure was attributed to some imperfection in the tubing or joints. Arrange- ments were therefore made for testing the tightness of the whole apparatus. The one end of the filter being connected, as described, to the glass flask in which the air was tested, I now connected a cotton-wool filter to the other end of the thermic filter, and proceeded to test ifall was tight, by drawing in air — from the cotton-wool filter through the apparatus, while it was cold. At first, I could not succeed in getting air free from dust; fogging always took place on reducing the pressure in the flask, showing that dusty air was leaking in some- where, and mixing with the filtered air. After much time spent in remaking all the joints, it was discovered that the air-pump valve was not quite tight ; by allowing the leakage to bubble through the water in the flask, it was found to be very slight, only about 2 or 3 c.cm. per minute. After this was put right, fogeing still appeared, showing that there was still leakage. This time it was traced to the stop-cock between the filter and the test-flask. This leakage was smaller than the other, yet it let in dust. After all leakages had been stopped, the cotton-wool filter was removed, and the thermic filter being heated, was now found to do its work satisfactorily, though more slowly than a cotton-wool filter. The ease with which dust passes through small openings is surprising ; indeed, I have found that any opening which admits air, also allows these less than microscopic particles to pass, and yet the air in its passage through the wide channel of this filter had every particle of dust. taken out of it by the thermal conditions to which it was subjected. If we cause the filter to purify air into which we have intentionally put a good deal of dust, such as dust of calcined magnesia, we find all the dust collected on the surface of the cold tube, near the end where the air entered, FORMATION OF SMALL CLEAR SPACES IN DUSTY AIR. 263 while the hot tube is quite clean. If we send the smoke of a cigar through the filter, nothing but perfectly transparent gases come out at the other end. The effect of coating the cold surface with glycerine has been tried, as it seemed pos- sible that the dust deposited on the clean surface might be carried on by the air current. The dust, however, seems to be firmly held on a cold clean surface, and no decided improvement was got by the addition of the glycerine. No accurate experiments have been made to determine the best size of the filtering channel. The filters with very narrow passages and those with much wider ones all work well, but no quautitative experiments have been made as to their relative values. It is not easy to determine what influence difference of temperature has on the action of a cotton-wool filter. Heating the cotton-wool has little effect in reducing its filtering powers. We might expect this, as the cotton and the air passing through it rapidly acquire the same temperature ; and it is extremely difficult to say how much of the action of this filter depends on the slight differences of temperature produced by the air in passing through the cotton. Diffusion Effects. I shall now describe two experiments on diffusion, which were made in the hope they would throw some light on this repelling action of hot bodies. For this purpose a tube similar to those used in the previous experiments was taken, and an opening made in the side of it, at the front end. Into this opening was fitted a thin plug of plaster of paris. The surface of the plug was made flat, and when put in the dust-box was placed vertically, as in the experiments on the heat effect, to get rid of the distribution due to gravitation. This diffusion diaphragm was blackened, to enable the effect to be better observed, as a white surface reflects so much light, it makes it difficult to see what is taking place. After the diffusion apparatus was fitted in its place, the dust-box was filled with sulphate dust, and left till everything had acquired the same temperature. Carbonic acid gas was then introduced into the tube. At once a downward current was produced in front of the diaphragm, the dust particles kept close up to its surface, and if there was any tendency to the formation of a clear space the carbonic acid at once closed it. The apparatus for supplying the carbonic acid gas was then removed, and a small pipe connected with the gas pipes was then led into the diffusion tube, so as to get the effect due to the diffusion of gases lighter than air. The effect in this case was the opposite of that given by the carbonic acid. An upward current at once started, and a thin clear space formed in front of the diffusion diaphragm. These experiments prove that the dust particles move in the direction in which the greatest rate of diffusion takes place. This at first sight looks very self-evident; but we must remember that in front of the diffusion diaphragm, when hydrogen is coming VOL. XXXII. PART II, 2x 264 MR JOHN AITKEN ON THE through it, that the ascending clear space is not composed entirely of the lighter gas which has come through the diaphragm. In that clear space the larger proportion of the molecules are air molecules; and while the air molecules advance up to and pass through the diaphragm, the dust particles are driven away from it. I shall presently have to refer to this. When speaking of the action of heat and moisture in protecting the lung surfaces from contact with the suspended dust in our atmosphere, no mention was made of this diffusion effect, as it can be better considered here. In our © lungs the small quantity of tidal air, which flows backwards and forwards, carrying in the oxygen, and out the carbonic acid, never gets further than the main bronchial tubes, and does not penetrate to the air-cells; the carbonic acid, set free into the residual air in these cells, is carried outwards to the tidal air by diffusion, and at the same time oxygen is diffused from the tidal air towards the residual air. Now, what is the effect of this diffusion on the distribution of the dust? We have seen that in diffusion through a porous diaphragm the dust moved towards the carbonic acid. If this was the case in our lungs, then the dust would tend to penetrate towards the air-cells and come into contact with their surfaces. In our lungs the exchange between the carbonic acid and the oxygen does not, however, follow the law of diffusion through a porous diaphragm, but those of osmose; and the rate of passage of these gases through the lung surfaces does not depend upon their relative densities, but on much more complicated conditions, of which solubility is in this case one of the principal. The result is, that in our lungs for every volume of oxygen that passes inwards, exactly or almost exactly one volume of carbonic acid passes outwards. These diffusion effects balance each other, and the result is that diffusion has no tendency to cause dust to penetrate towards the air-cells, or to adhere to the surfaces of our lungs. Repulsion due to Heat. We shall now consider the cause of the repulsion of the dust particles by hot bodies, and see if we can make out the mechanism by which the particles are driven away. This is a subject of considerable difficulty, and one on which I fear there will be much difference of opinion, and I shall simply state here what appears to me at present to be the cause of the particles moving away from a hot and towards a cold surface. The simplest explanation, and the one which offered itself first, was that possibly it might be a radiation effect, and that the particles are repelled in the same way as the vanes of a Crookes’ radiometer by the reaction of the heated gas molecules in the way explained by Professors Tarr and Dewar. We might suppose the side of the particles next the hot surface to be warmed by radiation, and the gaseous molecules on that FORMATION OF SMALL CLEAR SPACES IN DUSTY AIR. 265 side getting heated by contact, would rebound from it with greater velocity than those on the other side, the dust particles being thus driven away in a sort of rocket fashion. On examination, however, this explanation does not appear satisfactory ; because the particles are so very near the hot surface that they will not be heated principally by radiation, but by contact with the hot gases near the heating surface, radiation having but a slight effect. So far as I have been able to form a mental picture of the mechanism of this repulsion, it seems to be produced in the following way :—First, let us go back to the diffusion experiments. We saw that when hydrogen was diffused into air, a clear space was formed over the diffusing surface. Now why was this? The air molecules were moving towards the diaphragm and passing through it, yet they did not carry any dust particles with them. The reason seems to be this. In the air in front of the diaphragm there are two currents of molecules—one of hydrogen, moving outwards from the diaphragm, and one of air, moving inwards ; but as the hydrogen current is the stronger, it carries the dust particles along with it, and the difference in the strength of these two currents in this case gives rise to a thin clear space over the diffusing surface. Let us now apply the same reasoning to the heat effect. When we re- member that hot and cold gases tend to diffuse into each other, the explanation given does not require to be greatly altered. The molecules of air on the surface of the hot body get heated by contact, and these molecules tend to diffuse themselves outwards into the colder molecules. In imagination, let us look at a section of the air close to the hot body. The air there is no longer homogeneous. Some of the particles have more kinetic energy than others. Those molecules with the greatest kinetic energy have the greatest amount of their motion in a direc- tion away from the hot surface, while the cold ones have the greater amount of their motion in a direction towards the hot surface. Now what will happen to any particle of matter hung among these heterogeneous molecules? ‘The side of the particle next the hot body will be bombarded by a larger proportion of hot molecules than the other side, and the result will be to drive the particle away from the hot body. It may be objected that, as the air pressure is the same on the front and back of the particles, therefore the total energy of the molecules on the front and on the back must be the same, and therefore there will be no tendency to cause the particles to move. I think, however, this does not cor- rectly represent the case. Near the heating surface the hot molecules are moving outwards and the cold ones inwards. If there were more cold ones moving inwards than hot ones outwards, so that the total energy of the inward moving ones was equal to the total energy of the outward moving ones, which would be necessary in order that the pressures might be equal, then no motion would be produced in the dust particles. We must, however, remember that there are exactly the same number of molecules moving each way. One effect 266 MR JOHN AITKEN ON. THE of the hot surface seems to be to differentiate the movements of the molecules, causing the greater amount of the movement of the hot ones to be outward and of the cold ones inward, and the outward moving molecules, having the greater kinetic energy, exert a greater pressure on the dust particles and drive them outwards. In the hydrogen diffusion effect the particles of dust were driven away, because a greater number of hydrogen molecules were moving one way than air ones the other. In the heat effect they are driven away, because the molecules moving from the hot surface have a greater kinetic energy than those moving towards it, and the particles are bombarded on the one side by a greater number of hot molecules than on the other. We have the same effect intensified when the hot surface is wet. When this is the case, the vapour molecules diffusing outwards carry with them the dust particles to a much greater distance than the heat alone, as there is no inward current of vapour molecules to contend with the outward one, and tending to drive the dust particles inward; the result is, we get a dark plane at least twice as thick with heat and vapour as with heat alone. Of the two, the vapour seems to be the more powerful, as very little heat with moisture gives a thicker dark plane than double the heat would do. If we carefully fix the experimental test surface in a vertical position and simply wet it, the effect is to cool it by evaporation, and a downward current is produced ; but, at the same time, a clear space is formed, showing that in this case the outward effect of the vapour is greater than the inward effect of the cold. There seemed to be a possibility of getting an answer by experiment as to whether the radiation or the diffusion theory is the correct one. If radiation is the cause of the repulsion, then we should expect that a good radiator would cause the particles to be driven further away, and thus cause a thicker dark plane than a bad radiator. For the purpose of testing this, another experi- — mental flat test-surface was prepared. ‘This test-surface was made of silver and highly polished. One-half of it was then covered with lamp-black. After the test-surface was fixed in the dust-box heat was applied to it, and the thickness of the clear space over the two halves of the test-surface carefully noted. To do this, the dust-box was so arranged that I could look down the test-surface— not across it as usual—and could thus see down the boundary line between the dark plane over the polished surface and over the lamp-black. The result was, not the slightest difference could be detected between the two. The boundary line of the dark space in front of the plate was a straight line parallel to the surface of the plate. This experiment, while it gives no support to the diffusion theory, shows us that radiation is not the principal cause of the dark plane. If the explanation here given of the repulsion of the dust by a hot surface is correct, then this effect is not produced in the same way as the repulsion of the discs of a Crookes’ radiometer when heat is falling on them, but is similar to FORMATION OF SMALL CLEAR SPACES IN DUSTY AIR. 267 the repulsion of the discs by a hot surface placed inside the radiometer bulb, as in the apparatus described by Mr Crookes in Nuture, vol. xv. p. 301. In this radiometer the vanes were made of very clear mica, and they did not rotate when light fell on them. Inside the bulb, and just clear of the discs, was fixed in a vertical plane a blackened plate of mica. When the light was allowed to fall on this fixed and black plate, the vanes instantly rotated as if a wind were issuing from this surface. The energy which causes the repulsion of the dust and of the discs of this radiometer is transferred in both cases from the hot surface to the repelled surface by the kinetic energy of the gas molecules, and not by radiation. , Another consideration which indicates that the force causing the movement of the dust is not transferred by radiation is the well-known fact that radiant heat is not much intercepted by dust. When we concentrate a strong beam of light and heat in dusty air by means of a lens, perhaps one of the things which strikes us most is the very slight heating effect which is developed at the focus. The dust is not destroyed, and no rapid upward current is formed. But if we place a piece of paper at the same focus it is at once charred, and a rapid current of air rises from its heated surface. The rate at which vapour molecules diffuse under the conditions existing in the experiments is very great, and seems to be quite sufficient to account for the results. Take, for instance, the water molecules when they pass into vapour. Vapour molecules are selected because we can follow their move- ments. Ina small fraction of a second they diffuse to a distance of nearly lem. This can be seen in the experiment described with the flat test-surface when moistened. With a slight rise of temperature, fog particles are seen forming in the current, rising in front of the wet surface. Even at the lower edge of the plate these particles are seen at some distance from the plate, and separated from it by a dark space, showing that even at that point the vapour molecules have already diffused outwards to a distance and far beyond the dark space, while probably other molecules have gone further than the fog ‘boundary, but are under conditions which keep them in the state of vapour. Or take the reverse of this diffusion process, seen in the evaporation of fog particles. Let us blow some steam into the dust-box, so as to form a regular fog, but without adding any dust. Into this fog introduce a piece of very dry wood; if it is charred so much the better, as its blackness enables us to see more easily what is taking place. It will be observed that there is formed all round the wood a clear space, in which not a particle of fog can be seen. If Wwe watch the air currents we shall see the particles approaching, but vanishing at some distance from the wood, and over the wood the particles will be seen falling into the clear space and disappearing. This clear space is caused by the wood absorbing the vapour in the air near it, thus surrounding itself with 268 MR JOHN AITKEN ON THE a space of dry air, into which the fog particles evaporate as they approach, and so rapid is the diffusion towards the wood that the air is kept dry enough to evaporate the particles as quickly as they approach. Attraction Due to Cold. To explain the attraction of the dust particles by cold surfaces, we have only to reverse the explanation given of the repulsion due to heat. At the cold sur- face the outward moving molecules of air have less kinetic energy than the warmer inward moving ones, and the dust is thus driven towards the cold surface by the greater energy of the hot molecules. This explanation of the action of hot and cold surfaces may not at first sight seem satisfactorily to account for the peculiar movements of the dust particles as they approached the hot wire, in the experiment shown in fig. 13. We might here ask ourselves, for instance, Why were some of the particles carried close to the wire, and then driven away from it? The inertia of the particles is clearly not sufficient to cause them to advance against the force which produced their rapid repulsion. Then why did they approach so close to the wire, and then appear driven away with such violence? It looks as if the particles had become heated to a temperature sufficient to drive off their occluded gases and condensed vapours, and that the repulsion in this case was due to the rapid escape of these gases and vapours. No doubt, something will be due to their escape, but I do not think it is the principal cause of the — repulsion, because the particles are so small, the gases and vapours will escape from their surfaces all round them, and their effects will therefore nearly balance. Further, the escape of these gases will not explain why the particles were always driven towards cold surfaces. The following seems to be the principal reason why the particles are always driven sideways and not downwards. The rate at which a particle of dust will be repelled from the surface of a body is not necessarily the same in all directions round the body, but will depend on the closeness of the isothermal lines at the different places; and as in the experi- ment the temperature varies very much more rapidly towards the cold glass at the sides than it does downwards, the result is, a more powerful impulse is given sideways than downwards; and further, the cold glass surfaces diffe- rentiate the molecular movements near them, and cause an attraction. Let me illustrate this point further, and show by a parallel case in the action of gravitation, why it is that the particles of dust when repelled move towards. the side, and not downwards. Suppose there is a very long, but narrow and regularly shaped mountain, with its highest point near the middle, and the sides sloping regularly and quickly to the summit, while the ridge descends slowly. In ascending such a mountain, we can either go up the long easy slope of th ; FORMATION OF SMALL CLEAR SPACFS IN DUSTY ATR. 269 ridge, or up the steep sides. Now, suppose a stone to be rolled up the ridge of this mountain, by a force acting in a direction along the ridge, it is evident that if the stone gets off the ridge, that it will fall down the quicker slope towards the side; and if the stone keeps the ridge, and we succeed in rolling it nearly to the summit, but there meet a slope too steep for us to push the stone up, then the stone will obviously be in a position of unstable equilibrium, and the slightest fall will cause it to leave the easy slope of the ridge, and, once started on the quick descent of the sides, its motion will be rapidly accelerated in a direction at right angles to that in which we are pushing ; thus the stone will descend the quick slope of the side with great velocity, even while the force which pushed it up the ridge is still acting on it. The direction in which the force now acts on the stone is such that it no longer tends to prevent it falling; and further, supposing it was directly opposed to its motion, it would have but little effect against the steep slope of the side. Now draw the contour lines of this mountain. It will be found that they exactly correspond to the isothermal lines round the hot wire placed between the cold plates. The dust and the stone each fall towards the side, because that is the direction of steepest slope. General Remarks. This tendency which the dust in our atmosphere has to move away from hot bodies, and attach itself to cold ones, will, I have no doubt, help to explain many phenomena which are not at present well understood. No doubt, many things will suggest themselves to different minds as receiving their explanation im this somewhat curious liking of dust for lodging in cold places. Among other things, it explains the reason why stove and hot-air heated rooms are always so much dirtier than those warmed by open fires. Ina stove-heated room the air is warmer than the walls and than the objects in the room, the dust there- fore tends to leave the air, and to deposit itself on every object colder than itself in the room ; whereas, in a room warmed with an open fire, the heating being principally done by radiation, the walls and furniture are hotter than the air, they therefore tend to throw off the dust, and even when it does fall on them, it does not adhere with that firmness with which it does to a cold surface, and any breath of air easily removes it. Diffusion also, no doubt, plays some part in determining whether dust shall or shall not adhere to the walls and ceilings of rooms. Again, a knowledge of this tendency of dust to settle on cold surfaces is necessary to enable us fully to explain why so much soot adheres to the inside surfaces of chimneys. If the smoke were cold, so much soot would not settle in the chimneys, nor would it adhere so firmly. A simple experiment to illustrate this tendency of dust to leave warm, and 270 MR JOHN AITKEN ON THE to settle on cold surfaces, is made in the following way :—Take two narrow strips of glass mirror, any substance will do, but the mirror surface shows the result best. Arrange so as to hold these strips of glass face to face, and with their surfaces at a distance of a few millimetres, but before putting them in their places, heat one of them to a temperature of say 100°C. Have ready a tall glass vessel, large enough for the glass strips to enter freely. Now fill this vessel with some dust, by burning sodium or magnesium, or by shaking up some calcined magnesia or other powder. By the time the air in the vessel is settled and cooled, but before the dust settles, have ready the glass strips, one of them hot as directed, and placed in front of the other, face to face, with an air space between. Now put the mirrors into the vessel among the dust. After a minute or so examine them. The following will be the result. The hot one will be quite clean, while the cold one will be white with dust. That the dust has no tendency to settle on the cold one, may be proved by putting at the same time in the vessel another cold strip some distance from the hot one, when it will be seen that this one is almost entirely free from dust, depending upon whether it was a little hotter or colder than the dusty air. When one looks at the enormous amount of dust deposited on the cold mirror in this experiment, we cannot help associating the result in some way with the condensation of vapours, and it takes some time before we can arrange our ideas and realise that the thick white deposit was truly thrown out of suspension and settled on the mirror in the solid state, and was not in the state of vapour before coming into contact with the cold glass. A somewhat curious experiment may be made with light calcined magnesia powder, which shows the action of this force in a marked way. The magnesia is heated to a good red heat in an iron vessel. If we now take a metal rod 5 or 10 mm. diameter and heat it as hot as the powder. We may then dip in into the powder, and stir it as much as we please, but on taking the rod out, it will be found to be quite clean. But if the rod is cold, it comes out of the powder with a club-shaped mass of magnesia adhering to it, so thick that the magnesia-coated end is twice as thick as the rod itself. If the rod is kept in the hot powder for a short time, and then taken out, with its coating of powder adhering to it, whenever the powder gets outside the hot vessel, and exposed to the cold, it falls away, as the inside of the powder is now hotter than the outside. Most of us have noticed when heating powders, particularly if they are light, that while they are heating they take on a peculiar semi-fluid appear- ance if stirred, or if the vessel is tilted back and forwards. This I have always supposed was due to the escape of occluded gases from the powder, keeping it in a state of semi-suspension. Now, however, I think this peculiar effect is a result of the repulsion due to heating. My reason for supposing this FORMATION OF SMALL CLEAR SPACES IN DUSTY ATR. 271 is, that if after the powder is heated it is cooled quickly, and again heated before there is time for it to absorb gases, the same semi-fluid appearance is again produced while heating. Further, if the powder, instead of being heated in a closed vessel, is placed in a cup, so that the under side of the powder is kept hot, while the top is cooled by radiation, so long as these conditions are kept up the powder retains its fluid-like properties, moving about on the slightest tilting of the cup, and conducting itself in a way very suggestive of the spheroidal condition, but without any generation of vapour to give rise to the irregular movements seen in liquids. It seems possible that something of the spheroidal condition may receive its explanation in this repulsion between hot and cold surfaces. This repulsion may be illus- trated by placing a hot and a cold surface together. A piece of cold glass, for instance, slides about in a remarkably easy way on a hot surface of glass. Many practical applications of this attraction and repulsion will no doubt be found. It might be easily applied to the condensation of those fumes from chemical works which at present are allowed to pollute the air. But perhaps the application of most general interest would be towards the prevention of smoke, or rather the prevention of the escape of smoke into the atmosphere. Whatever interest, however, it may have in this way, it is clear it can never meet with general adoption, save under compulsion, as it will effect no saving in fuel, such as would result from more perfect forms of combustion. I have, however, made some experiments in this direction, and find that by placing a tall metal chimney over a very smoky paraffin lamp, surrounding this chimney with another tube slightly larger, and causing the products of combustion to rise up the centre tube, and descend through the annular space between the two tubes, the soot is all taken out, and nothing but a white Vapour is seen escaping. On examining the tubes after they have been in use “some time, the inside surface of the inner one is found to be slightly coated with soot, while its outer surface is perfectly clean and bright, not a speck of dust on it, and the inside of the outer tube, which is only a short distance from it, is thickly coated with soot. This arrangement, however, is too complicated, Save for special purposes. It has been already stated that the reason why so much soot collects in chimneys is that the gases are hotter than the sides of the chimney. In cases where the gases are allowed to escape at a high temperature advantage might be taken of this tendency. If we simply cooled the smoke in the presence of plenty of depositing surface, much of its soot would be trapped out, and the escaping smoke made less dense. The amount that might be trapped in this way will depend on the extent to which the gases could be cooled. For works with large chimneys this plan evidently could not be adopted, and in their case the purification would require to be down at the bottom of the VOL. XXXII. PART II. 2Y 272 MR JOHN AITKEN ON CLEAR SPACES IN DUSTY AIR. chimney. The evident objection to this is, that as the gases are cooled in the depositer, the draught in the chimney will be destroyed. This, however, ca be avoided by the use of “regenerators.” The impure air would be led toa — cold regenerator, where it would be cooled and its impurities deposited; and when purified it would be led through another chamber, where it would be heated before being sent up the chimney. This arrangement would not require heat to be spent in working it, as the process would be reversed, and by simply revers- ing the direction of currents from time to time the heat stored up in cooling would be used for heating the purified gases before being sent up the chimney, This purifying process by heating and cooling would require to be done a number of times, and the air sent through a succession of regenerators before it could be made perfectly pure. oy. Soc. Edn® ] LYLUVLY yt / j / Hy \\ rt OES 1 NY \ L/THINN\NAN \\ JPW \ ad SON x WV 7/ Wa 7, nh pte Wa ea le Paget led ya Fig.6 =-== Archibald & Peck Edn? XVI.—On Stichocotyle Nephropis, a new Trematode. By J. T. CUNNINGHAM, B.A., Fellow of University College, Oxford, and Naturalist in charge of the Marine Station, Granton, Edinburgh. (Plate XX XIX.) ‘J, (Read 5th May 1884.) The Norway lobster, Nephrops norvegicus, on account of its abundance in the Firth of Forth, and the consequent ease with which it can be obtained from the Newhaven market, is given to the practical classes in the Natural History Laboratory of Edinburgh University for dissection, as an example of the de- capodous Crustacea. One day in December last, while I was superintending the work of a class engaged in the study of this animal, one of the students, whose name I have unfortunately forgotten, called my attention to some glob- ular protuberances on the intestine of the specimen he was dissecting. At the time I was unable to answer his questions any further than to say that the _ protuberances were the cysts of a parasite, and I put the specimen by for sub- sequent examination. On opening the cysts afterwards I found in them a small white worm, which proved to be a Trematode possessing novel charac- teristics. In the following paper I shall describe this parasite, and show that ‘it is so distinct from all Trematodes hitherto known as to constitute a new genus. On several occasions I had the pleasure of examining the animal in the company of my friend and former colleague, Mr DuncAN MatTTHEws, and some of the points in its structure were first noticed by him. I will first describe the animal as completely as possible, and then deal with the manner of its occurrence and its relation to other Trematodes. The worms when taken out of the cysts are elongated and cylindrical in shape, one surface, the ventral, being slightly flattened; they vary in length from ‘75mm. to 80mm. They are white in colour and somewhat opaque, so that there is considerable difficulty in making out their internal anatomy under the microscope. The body tapers towards each end, the thickest part being | near to the oral or anterior extremity. The arrangement of the organs is bi- laterally symmetrical. The mouth is a small simple circular aperture, situated on the ventral surface, close to the anterior end of the body. Behind it, along the median line of the ventral surface, is a single row of large muscular | suckers, which diminish gradually in size towards the posterior end. The |margins of the mouth are muscular, and its cavity can be dilated and con- tracted, so as to act as an additional sucker. When the animal is viewed with | its ventral surface upwards, slightly compressed by a cover-glass, and under a VOL. XXXII. PART II. | OM: 274 MR J. T. CUNNINGHAM ON low power, it presents the appearance shown in Plate XX XIX. fig. 1. The ventral series of suckers is seen along the median line; each of them has a central depression varying in size according to the state of contraction, and round this is the projecting rim, in which can be seen the radiating muscles by which the sucker is dilated. The number of suckers present varies in different individuals according to their age and size,—the smallest specimens, such as the one shown in fig. 4, may have as few as 7, the larger usually have 15 or 16, while in the largest I have counted as many as 22. No doubt specimens might be found the totals of whose suckers would supply all the intermediate numbers between these. The suckers are always more difficult to distinguish at the posterior end of the series, where they are very small, and they evidently increase in number at this end, just as the segments of a Chaltopod. It is this approach to meta- merism which renders the creature specially interesting. The metamerism, however, does not extend to any of the other organ systems, and consequently the animal cannot claim among the Trematodes so isolated a position as the Gunda segmentata, described by LANG, among the Turbellarians. From the disposition of the system of suckers, I have named the animal Stichocotyle, adding Nephropis for the specific name, from the name of its host. The surface of the body is marked by closely set transverse folds, which are indicated in fig. 1, between the suckers. These folds, seen in optical section, give the body a crenated outline, which is also indicated in the figure. When the body is much extended, either by compression or by the muscular move ments of the animal, the folds disappear; they are probably due to the pre- sence of an inelastic cuticle, although neither in the opticle nor actual section of the integument can a separation between cuticle and epidermis be dis- tinguished. The external layer of the body wall, as seen in optical section in the living animal, is homogeneous and transparent, and of considerable thickness. The most conspicuous of the internal organs are the main canals of the water-vessel, or excretory, system. These are two in number, one running down each side of the body through its whole length. Their size, in compari- son with that of the whole animal, is extremely large; their walls are throwt into transverse folds. The interior of the canals is crowded with large spherical concretions similar to those found in the excretory system of other Trematodes and of Cestodes. These concretions, during the examination of the living animal, are continually moving with considerable rapidity, the contractions of the body forcing them suddenly from one part of the canal to another. In the middle line, between the main excretory canals, is the intestine. From the mouth can be traced a narrow cesophagus, dilating into a muscular pharynx, with thick walls, and this leads into an intestine which diminishes slightly it + STICHOCOTYLE. NEPHROPIS, A NEW TREMATODE. 2795 diameter towards the posterior end, where it ends blindly. The intestine is quite simple, and has no branches or diverticula. When a specimen is examined with its dorsal side upwards, and consider- ably compressed, the intestine and lateral excretory canals are seen with great distinctness, as there are no muscular thickenings dorsally to form suckers. Fig. 2 shows somewhat diagrammatically the view thus obtained. At the pos- terior end the two lateral canals terminate in muscular portions, which pass in- wards behind the intestine, and unite to form a single median chamber with thick muscular walls. This chamber opens in the usual way by a pore on the dorsal surface, close to the end of the body. The rhythmical dilatation and contrac- tion of the terminal chamber is very pronounced, and it commonly happens, when the animal is under compression, that one of the spherical bodies con- tained in the lateral canals passes into the terminal chamber, and is expelled from the dorsal pore with some force. The appearance of the terminal part of the excretory system under a high power is shown in fig. 3. When the living animal is very attentively examined with an objective of high power, by careful focussing fine ciliated canals can be made out be- tween the large lateral canals and the dorsal surface. It is probable that, like the corresponding fine canals in other Trematodes, these open into the main lateral canals, and are, on the other hand, in communication with the inter- cellular spaces of the body-parenchyma; but owing to the opacity of the tissues, I have not yet succeeded in tracing out these relations. The cilia, whose motion alone enables one to trace the tubules in question, are of great length, and are situated on the walls of the tubules at intervals. I have not been able to discover any “ éntonnoirs ciliés” at the ends of the branches of the system of tubules, like those described by Fraivont.* I have followed the ciliated tubules sometimes for considerable distances. Their course is somewhat irre- gular, but maintains a longitudinal direction. They branch occasionally, but the branches never extend into the median region of the body above the intes- |time. I have not found any tubules on the ventral side of the body, but they | extend forwards beyond the anterior limit of the main lateral canals. Ihave now described the general disposition of the digestive, excretory, and integumentary systems of the animal, and have hitherto mentioned nothing | which cannot be made out in living specimens. No reference has been made \to the generative or nervous systems. In the stage of the animal’s history’ | which is passed within the body of Nephrops neither of these systems is jdeveloped. I shall refer to structures which may be their rudiments. Special Sense organs are altogether absent. In order to examine the histological structure of the tissues, I have pre- * “ Rech, sur l'appareil excréteur des Trém. et Cestoides,” Junin Fratpont, Are. de Biologie, Tom. i. 1880, 276 MR J. T. CUNNINGHAM ON : pared transverse sections in continuous series from specimens preserved with picro-sulphuric acid, and stained with borax-carmine. The specimens chosen for this purpose were of the medium size, carrying about 16 suckers. The sections are all very similar to one another, differing chiefly in the relation which they bear to the series of suckers. In one taken from the middle of the series, the intestine is seen in the centre, elliptical in outline, the long axis of the ellipse being dorso-ventral. The epithelium of the intestine is thick, and composed of large nucleated cells, which form sometimes more than one layer, and are not quite regular in arrangement. Both in the living animal and the prepared section it can be seen that the cells of the intestinal epithelium are rapidly proliferating ; the free ends of the cells project into the lumen in various degrees, and a number of detached cells are seen lying free in the interior, | In the living animal these cells float about under the influence of the move- ments of the body, and are occasionally expelled from the mouth. Some of them contain minute round granules. On each side of the intestine is the section of one of the main lateral excretory canals, in which there is no distinct epithelium to be seen. There are nuclei in the walls, and the cavity may be lined by an epithelium of ex- tremely thin cells, to which these nuclei belong. The walls of the canal are extremely thin. The parenchyma of the body, or mesenchyma, appears in the sections as a fine reticulum with deeply stained nuclei at the nodes. The actual structure of the mesenchyma in Trematodes has been much disputed,* some observers maintaining that the intercellular spaces are globular and the cells stellate; others, vice versa, that the cells are globular, and the intercellular spaces reticu- late. In the living Stichocotyle the mesenchyma is seen to be crowded with minute bright refringent granules, which seem to be contained in intercellular spaces, as they move through considerable distances in parts of the animal which are in active contraction. They are shown in fig. 3. The muscular layers of the body wall are imperfectly differentiated; they are represented by a zone of closely crowded nuclei at the periphery of the mesenchyma, and, external to this, a zone of small dots, which are probably. the sections of longitudinal fibrils. The account of the muscular layers of the integument in the young of Amphilina, given by SALENsky,t agrees pretty there are no nuclei. The sucker is composed chiefly of elongated cells, whose long axis is per- pendicular to the epidermis. These are simple muscular cells which dilate the * Vide Fratpont, loc. cit., p. 428. { Zeit. f. wis. Zool., Bd, xxiv., 1874. STICHOCOTYLE NEPHROPIS, A NEW TREMATODE. 2G cavity of the sucker. Nuclei are scattered through the tissue, each cell pro- bably possessing one. The muscles which contract the cavity of the sucker are not so conspicuous. The tissue of the sucker is separated from the tissues of the body by a thin limiting membrane, which is continuous at its periphery with the limiting membrane of the epidermis. This is an arrangement which is not easily explained, as, the muscles of the sucker being probably a special- isation of the ordinary muscles of the body wall, it would be expected that the continuity between the two would be maintained. Beneath the lateral excretory canal of the right side, in the anterior sec- tions, is an area occupied by very closely crowded nuclei. This can be traced through successive sections of the series as far as the end of the fifth sucker. It passes from its first position, under the right main canal, to the left side of the same canal, at the same time becoming thicker, and towards its termination becomes so broad as to extend beneath the intestine from the right canal to the left. There is thus an irregular cord of small unmodified cells extending through a considerable part of the length of the body, and it is possible that the generative organs of the adult are derived from this. The most external layer of the body representing the epidermis and cuticle, is in sections, as in the living animal, quite homogeneous. I have not yet been able to distinguish in it either nuclei or cell boundaries, or a separation between epidermis and cuticle. The layer becomes thinner where it lines the cavity of the sucker. In the living animal small funnel-shaped openings are seen in the epidermis, which may be the apertures of glands, but as they are not visible in the sections it is possible that they are only fractures produced by com- pression. The only trace of tissue which may belong to the nervous system is a tract composed of very fine fibrils in some of the sections anterior to the mouth. This tract forms a band extending horizontally across the body near to the dorsal side. ‘The fibrils of which it is composed are extremely minute, and the whole tract is destitute of nuclei. It is shown in fig. 6, and may represent the cerebral ganglion. ?). This Q, will in general have one or more concurrences due to the flaps sub- stituted for subsolids removed. All these are to be cleared away (art. 13), whereby Q, becomes Q;, an unsolid without a concurrence; and Q) is to be — treated as we treated (’ in art. 14. We shall finally arrive by these reductions either at an unsolid of two portions, neither of which is least, which is to be reduced by a final section to two subsolids each of ¢ crossings ; or at a ring of flaps which is reducible to the fundamental ,A ; or to a nucleus subsolid or solid knot. We have now to set about the reduction of subsolids. 19. Reduction of a Subsolid of n Crossings by its Leading Flap.—The rule is—Remove both edges of a leading flap, or of a leading flap when there are_ co-leaders. By this removal, the two meshes covertical with the deleted flaps lose each a crossing; and if one or both coverticals are triangles, that one or both become flaps. The result obtained is a subsolid of m— 2 crossings. 20. Every flap can be written AB,CD, where A and B (ASB) are col- laterals, and C and D (CSD) are coverticals, of the flap. | We compare first the collaterals of the flaps whose leader is to be found, CONSTRUCTION OF KNOTS OF FEWER THAN TEN CROSSINGS. 287 If A,B,, A,B, &c., are the pairs of collaterals, the leader has the greatest A, no matter what be the coverticals. If several flaps have the greatest A, the leader has the greatest B. If several have both A and B greatest, we compare co- verticals. If one has the greatest C, it leads; if more than one, the greatest D gives the lead. If no leader can thus be determined, we have to examine the collaterals of the A’s. The leader has more than any other of the greatest of these collaterals; and so on we go over the collaterals of the B’s, the C’s, and the D’s. The leader, if there is only one, is certain to be found. I have never had occasion to examine the collaterals of AB,CD. If two competitors have these all equal, it is almost a certainty that there is symmetry, and no leader, but a set of co-leaders. Where there is no symmetry, no two edges or flaps on a knot are alike. It suffices, after writing two or more flaps as equally claiming by their AB, CD to lead, to place a note of interrogation, and to examine the symmetry, which readily betrays itself. The deletion of any one of the co-leaders com- pletes the reduction. A flap can neither be removed from a knot nor added to it without cutting of threads and reunion of ends. But this does not trouble us here, as by art. 2 we know that every projection making tessaraces only is a true knot, that its circles can be read by the rule of under and over, and that the threads of all the circles can be drawn in double lines as narrow untwisted tapes visibly passing under and over at alternate crossings. 21. In the converse problem of construction, the question is, in how many | ways to add, on a knot P’ of n—2 crossings, a leading flap, so as to construct without risk of repetition a subsolid of m crossings. The note of interrogation written after the comparison of two flaps that can be drawn across two meshes of P’ is a presumption of symmetry, which is pretty certain to be verified when we come to draw in turn our new flaps on P’, and to examine the constructed P of n crossings as to the leadership of the doubted flap which turns P’ into P. 22. Two things are to be noted here, both in reduction and construction. Ifa flap f on any subsolid is covertical at its crossing @ with a triangular mesh abe, which carries a flap /’ on the edge dc, since abe cannot lose a crossing by the deletion of /, it thereby becomes itself a flap f” collateral with the flap /”. Now a pair of collateral flaps is excluded from all our constructions, because it is a circle of two crossings, whose projection represents nothing in space but a | movable ring through which one thread once passes. Wherefore the flap /is indelible or a jived flap. It cannot be removed, nor be a competitor for the lead, either in reduction or construction. When two flaps are collateral with the same triangular mesh, both are jized ; for the deletion of either leaves the other hanging by a nugatory crossing which admits a forbidden punctual section. The reader can easily verify this. 288 REV. T. P. KIRKMAN ON THE ENUMERATION, DESCRIPTION, AND By continuing this reduction of a subsolid by removal of the leading flip, we must at last arrive either at a solid knot, or at one of the two irreducibles ,A and ,A, of three and of four crossings. 23. Construction of Knots of n Crossings—The rules for this are the exact converse of those above given for reduction. First, to construct the subsolids of n crossings, all inferior knots being given with their symmetry, we have in the first place to take in turn every subsolid P’ of n—2 crossings, and to determine before we draw them the different lead- ing flaps that can be added on P’. Knowing its symmetry, we can write down and mark on its edges every different pair of points on flap or edge that can be joined as the crossings of a new flap, and also the collaterals and coverticals which this will have. We make a table of the possible leading flaps, with the — notes of interrogation that presume symmetry in the P of m crossings to be built on P’. Next we draw the leading flaps, thus constructing and registering the resulting subsolids P. A caution is required here, for the examination of the claim of a new flap, ab=8M, to leadership ; a and 0 being the crossings of the flap, when one of its - collaterals is a triangle abc. If ¢ in this triangle is the crossing of a flap cd, ed becomes fixed (art. 22), for it is covertical with a trianglegsab, which carries a flap on its edge ab. Care must be taken to exclude this flap cd from claim to — leadership over ab. I was caught in this trap in the art. 41, for I had entered the flap (dd) as led by (56), and thus missed the unifilar ,G. Professor Tarr found this knot, — adding one to my first list of 8-fold knots, He first found also the unifilars »Al, Ak, and ,Bg, omitted by a like error in arts. 51 and 56. He also first found ,Dm, which I ought to have constructed along with ,D/ in art. 61. 24. In the second place, we take in turn every unsolid P” of n—2 crossings on which a leading flap or flaps can be drawn so as to abolish all concurrences, and to block linear section. Such leading flaps will be few. Next we draw them all, and thus complete without omission or repetition our list of subsolids” P of a crossings. This. list is. the only difficulty of our work ; what follows is for every value of m all easy routine, as we shall see; but it soon becomes toe tedious. by the enormous number of results to be registered and figured. 25. Next, to construct the wnsolids of n crossings which have no concurrence, we impose in the first place on the solids and subsolids, and in the second on — the unsolids, of »—7 crossings, each taken in turn as the subject Q’ to be pleting an unsolid Q of 2 crossings. without a concurrence. The ¢ charges may be all or none alike, or all but one alike, &. ; and from our list of subsolids of & crossings must be selected with or without repetition CONSTRUCTION OF KNOTS OF FEWER THAN TEN CROSSINGS. 289 every possible set of e charges. These, as well as their reflected images when required (although such images are neither registered or figured by us), have to be imposed in every different posture, by every kind of possible section, jc, 7 &c., on every different set of ¢ flaps or edges that can be selected on the subject knot, and in every different order that symmetry permits without repetition of results (art. 4), so that when the work is done not one of the unsolids Q of n crossings shall have a least marginal subsolid besides the e that we have just imposed, nor have a concurrence upon it. 26. The linear sections by which the charges are imposed may be any of the five of art. 15. But, observe, when we use the section /f¢, we are to select the charge from our list of subsolids of /+2 crossings ; because (art. 16) two will be lost. For other sections our selection of the charges will be from those of k crossings. 27. The number of different postures in which a charge can be imposed on Q’ depends on the symmetry of the united portions of the Q completed by the union. Let « denote the edge or flap of the subject and ¢’ that of the charge in all the five sections fc, 77, fe, ef, ee. The rules are three— (1) If one or both of « and & be zoned polar, only one configuration is pos- sible by the union; no second and different (art. 4) can be formed by turning the charge C through two right angles about ¢’, nor by using C’, the reflected image of C, when C is not C’.. Every knot on which is a zone is its own mirrored image. (2) If neither e nor < be zoned polar, and if they are not both asymmetric, two and two only different configurations can be made by the above variation of posture of the charge. (3) If both « and ¢ are asymmetric, four different configurations can and | must be made and registered, due to such variation. No more results can be obtained by putting for Q’ the reflected image of Q’: nothing is so attainable but repetitions or reflected images of knots already Tegistered. On almost every subject Q’ and charge C, though having any symmetry, may be found asymmetric, 7.¢., zoneless and non-polar, flaps and edges, which are to be dealt with by the above rules. 28. The subject Q’ to be charged with a set of least marginal subsolids may have or not have concurrences. All that is required in order that the com- pleted Q shall have no concurrence, is that our number e of charges of & crossings shall be large enough to spoil all concurrences on Q’, as well as to cover at least once every marginal subsolid on Q’ which has fewer than +1 crossings. In the constructions of this paper, Q and C are one or both symmetric. When asymmetrics come to be handled both as subject and charge, the number VOL. XXXII. PART. II. 3B 290 REV. T. P. KIRKMAN ON THE ENUMERATION, DESCRIPTION, AND of results becomes unmanageably vast long before m the number of crossings is out of its teens. 29. The jinal operation, after construction of all knots of » crossings with- out concurrences, is to take every subsolid and unsolid R in our lists which has m—c crossings and no concurrence, and to add to it in every possible different way ¢ flaps making with one or more on R concurrences of every possible number of two or more flaps, thereby adding ¢ crossings, and completing the number 2. This last operation soon becomes impracticable from the number of results. 30. Nothing can be here added that will give so much insight into our subject as the actual construction of knots, to which we now proceed, first to that of subsolids, and next to that of unsolids of the number 7 in hand of — crossings. : _ Two Fundamental Subsolid Knots.—The only subsolids that cannot be reduced by deletion of a leading flap (art. 19), are those of three and of four crossings. These, ,A and ,A( vide Plate XL.), are irreducible and fundamental. 3A is a 3-zoned monarchaxine, whose principal poles are triangles not plane, which have three common summits and no common edge. The unsolid ,B is formed on ;A by art. 29, and has a symmetry of like description. The secondary 2-zoned poles on either are alternately flaps and — erossings, being heteroid poles in ;A and janal in ,B. 31. Subsolid and Unsolids of Five Crossings.—The subsolid must be built on 3A. The only points that can be here joined by a flap, are either on one flap of — 3A or on two. We cannot obtain a subsolid by joining the former pair, because the constructed knot would be an unsolid having a concurrence of two (art 13). We join the latter pair, and it matters not whether we draw our flap in the upper or in the lower of the two triangles whose summits are the same three crossings, and whose edges are different halves of the three flaps of ;A. Drawing the flap 54, the two flaps of ;A connected by it become triangles, and sA is constructed, a 2-zoned monarchaxine heteroid, whose zoned poles are a tessarace and an opposite tetragon. ‘This is the only subsolid of five crossings. The unsolid ;B is by (29) formed on ,A, and ,C is made on ,A. 32. Knots of Six Crossings.—The subsolids ,A, &c., must be formed on ,A and ,B. This ,A has a janal 2-zoned axis through thie z centres of the flaps, and two like 2-ple janal zoneless axes through two pairs of opposite mid-edges. It has only one mesh, the monozone triangle 342, and the only pair of point that can be joined are 5a and 56. Drawing 5a, or rather conceiving it drawn, we write » to determine the leading flap, (5a)=43,43 ; (12)=43,43; (5a)>(12)? CONSTRUCTION OF KNOTS OF FEWER THAN TEN CROSSINGS. 291 This is read thus—the flap on 5a has for collaterals 3 and 4, and for coverticals 3 and 4; so has the flap on 12: which leads ? Next, conceiving 56 drawn, we write, (56)=43,44; (12)=44,43; (43)=43,44. Here by art. 19 (12) appears to be leader, until we observe that it is fixed by art. 22, and cannot be a competitor. We therefore write more correctly, (56) =43,44>(43)=43,44 ? (12) is fixed ; which inquires, Does (56), which is 43,44, lead (48), which is also 43,44? We consider this second as well as the preceding note of interrogation a pre- sumption of symmetry (art. 21). Drawing the flap (5a) we obtain ,A, and the flap (56) gives us ,B, on both of which the leading flap so drawn is marked 56. Observe that in our figured subsolids of m crossings, the leading flap is always marked n(n—1). Our pre- sumptions of symmetry are verified in the two results ,A and .B. The polar edges of the heteroid zoneless axis of ,A are evident in the figure. The two-zoned axis of ,B has for faces a flap and an opposite 4-gon. The other two flaps of ,B are like epizonals. It was possible to connect by a flap the two edges of the flap 43in,A. But this could have completed an unsolid having a linear section through 3 and 4; and completed it wrong, because no unsolid is ever made by so adding a flap. 33. We next take the unsolid ,B, considering whether or no a flap can be drawn on it to make it a subsolid of six crossmgs. Readily we perceive that by joining two opposite flaps we can both spoil the concurrence and block the linear section. This gives us ,C, which has all the symmetry of the wedge which it becomes when an edge is removed from every flap. The three, ,A ,B and .C, are all the subsolids of six crossings. 34. We seek now the unsolids of six crossings. To obtain them by least marginal charge or charges (art. 25), we have to lay 2 upon 4 and 3 upon 3. There is but one charge that can add two crossings only, ,Afc, which means 4A imposed (art. 15), by the section fv. Imposing this on ,A we get ,.D, a zoned triaxine, whose three janal 2-zoned axes have for poles, one two tessaraces, a second two flaps, and the third two 4-gons symmetrical but not plane, which have two common summits and no common edge. Laying next on ;A the charge ,A/ (art. 15), we obtain ,E, another zoned triaxine, whose janal poles are two edges, two tessaraces, and two hexagons alike and non-planar. There is in truth no least marginal subsolid in either sD or .E, the two halves of the knot being identical in each. But it is instruc- 292 REV.T. P. KIRKMAN ON THE ENUMERATION, DESCRIPTION, AND tive, and involves no error, here to consider them as cases of the linear sections fe and ff. 35. We have constructed all the knots of six crossings that are without a concurrence, viz., «A, «B, «C, ~D, .—E. Those having concurrences are obtained, sF on ;A, ,G and ,H on ,A, and ,I on ;A. These nine, ,A...,I, along with the solid knot ,J, are the ten possible knots of six crossings. Four of them, as Tait has found and drawn them, are unifilar, viz., ,A, sH, «F, «G4; and this is read on the figures. The number 12 on each shows that there are 12 steps in the circle of the knot, which passes twice through every crossing, once over — and once under. ,B, ,D, and ,H are bifilars; ,C and ,J are trifilars. 36. Knots of Seven Crossings.—The subsolids ,A, &c., must be built on ;A, : ‘&c. The only lines that can be drawn on ,;A here © NRE given are jf and aa, each 44; and af, ae’, ee’ be, bh, iaripgres each 34. 2 By 7, which has no rival, we get ,A ; whose 2-zoned VW ; poles are the flap and the tessarace 3333, 4 (aa) =44> (12), or (34) =48 ; (af) =53, 43 >(12)=53, 43 ? (bh) =48, 43>(12)=48, 43 ? For the:rest, ae’, be, and ee’, (43) =53 > (ae) =43 ; (43) =44> (be) =43 and >(ce')=43. We ‘have to draw, besides ff, the flaps (aa) (af) and (bh), expecting symmetry with the two last, which we soon find, By (aa) we get »B, whose 2-zoned poles are this flap and a tessarace. By (af) comes ,C, monozone ; By (0h) , ,D, whose zoneless 2-ple poles are a 4-gon and a 4-ace. Thus there are four sub- solids, ;A, ;B, ;C, ;D, reducible by the leading flap to ,A. 37. On ;B, annexed, as we cannot allow a concurrence, we can draw only ' (if) and (b/), (af)=53>(12)=43, and (45) is fixed (art. 22). (2f)=44, 43 > (45) =44, 43 2 ((12)=34), for (45) is not fixed when (Lf) is drawn. 3 % 5 We have to draw (af) and (2/) looking for symmetry in the latter. CONSTRUCTION OF KNOTS OF FEWER THAN TEN CROSSINGS. 293 (af) gives us ,H, asymmetric ; (of) ” /F, monozone. Thus there are six subsolids, ,A ;B...-F, of which we read on their figures that ,C, ,D, and ,E are unifilar. f 38. To obtain the unsolids ,G, &c., without concurrences, we have to lay 2 upon 5, 3 upon 4, and 2.2 upon 3, sAfe on ;A gives ,G, monozone, This is 2 upon 5. We cannot lay the same charge on ;B destroying the con- currence, without completing an unsolid having two marginal charges of which we have just imposed only one; which is forbidden (art. 25). For 3 upon 4, ; 34f on ,A gives ;H: 3Afe on ,A gives ,I; vide the figures. Observe that we can impose ;A only by the sections fand fe; for it has no edge to lose at a section ef or ee; and if we attempt to lay it on a flap h by fc, we merely turn / into a concurrence of two, which is not permitted as a result of any charging operation. In ;H and ,I the 2-zoned and the zoneless 2-ple axes of ,A, after being loaded symmetrically by ;A, retain their repeating polarity, but from being janal have become heteroid, not janal. For 2.2 upon 3, we lay on;A the two charges ,A?fc, which stands for twice ,Afe. The result is ,J, in which one flap is zoned polar, and two are epizonal. Thus there are four unsolids, ;G, ;H, ;I, J, without concurrence. 39. For unsolids, ,K, &c., having concurrences, we obtain on ,A, ;K; on al.and ;M; on .C,,N; on,D,,P; on,H, ,Q; on;A,Rand,S; on,A, ;r and ,U; on,A,,V; eleven of them. Thus we have 21 knots of seven crossings, of which 6 are subsolids and 15 are unsolids. ‘Their symmetry and circles are to be read on their figures. Twelve of them, ,C, ,D, ,E, ,G, 7H, -I, -L, ;P, S, ;T, ,;U, ,V, are unifilar, of which all but ,I have been found and figured by Tair. See Plate XV., Trans. L.S.#., 1876-77, for his eleven figured unifilars, and his reduction of them to eight. 40. The meaning of the symbols jv, 7; and fe is clear from the figures 7G, ;H, ;I. In reduction of ,G, after making the linear section, two flaps have | to be restored. Also after section of the two parallels in ,H, the cut portions have to be united to make two flaps on the severed knots; and after section in ;I they have to be united to restore the flap on the charge ;A and the edge on ,A. We shall see an example of the section ef in ,Dg, and of ee in ,A/ and ,Di; vide the figures. 294 REV. T. P. KIRKMAN ON THE ENUMERATION, DESCRIPTION , AND 41. Construction of Knots of Eight Crossings—For the subsolids ,A, &¢., we have to draw leading flaps on ,A, &c. In A, which is nae figured here, the 2-ple zoneless heteroid axis passes sf through @ and e. The only faces are 5641, 634, and 4 563, and there is one flap which is asymmetric, hay- ing different edges marked f and f’. The only different lines that can be drawn are fa, fb, ca, cb, each 35; fc and ab, each 44; and fd, fe, be, bd, de, de, each 34, The two d’s are the same point repeated in the repeated triangles 563 and 124. (fa) =53, 53 >(12)=58, 53 ? (fb) = 58>(12)=43; (ca) =53, 54>(56)=53, 53; (12) is fixed (art. 22) ; (cb) =53, 44>(56)=53, 44 ? (fe) =44, 43 >(12)=—44, 43 ? (fd) —43, 43> (12) =43, 43 ? (bd) =43, 54>(12)=43, 53; (56) is fixed (art. 23), For the rest, (12) leads (ab); and (56) leads (fc) (be), (de) and (dc). We have to draw seven flaps, expecting symmetry in four cases— (fa) gives us A; (ca) gives us .H; (fc) ” 3B; (cb) » alths (7) 5 (0d) yg (fd) gD; whose symmetry and circles are read on their figures, where the zoneless poles on ,A, ,B, and sD are 55 and =) 44 and 33, 44 and 44, and the leading flaps are marked 78. 42. We take next ,B, whose only faces are the 2-zoned polar 1256, and the monozone faces 4253 and 124. The only lines drawable are, Ja, ba, hb, each 35, ff, aa, bb, ha, each=44, and Jb, bb, each=43. 3 Here (43) is fixed for every flap that we can draw, {The 6 should be at the base corner.] except (7) and (6b), each = 44. (ba) = 53, 54>(56)=53, 54? (12) and (43) are fixed (arts, 22, 23). (hb) = 53>(12)=—44 and >(56)=—43, (bb) =44, 44>(12) or (56) or (43)? each=44, 44, (ff) =44, 33 > (43) =44, 33 ? (aa)=44 >(12)=48 and >(56)=43. CONSTRUCTION OF KNOTS OF FEWER THAN TEN CROSSINGS. 295 For the rest, (56) leads (fa) and (7b) from the flap (12), and (12) leads (bb) =43, We have to draw five flaps, presuming symmetry with (ba), (6b), and (7). (f) gives us .H, whose three 2-zoned janal axes terminate in the centres of the zoned polar flaps and of two pairs of edges 44, 44; and 33, 33. (ib) gives us ,J, asymmetric, (db) gives us ,J, whose two janal zoned poles are 4-gons, the four like janal zoneless 2-ple poles being edges 44. We often mean by pole the polar face summit or edge in which an axis ends. (aa) gives us .K, having two different zoned polar flaps : (ba) gives us ob, whose zoneless poles are 44 and 55. 43. Our next base is ,C, which has one flap, one triangle, and one 4-gon. The only different lines that can be drawn are jf and aa, : f each 44, and fa and aa, each 43. The two /’s are alike. | Gre bitn Bea | (ff) =44, 33> (23) =43, 33 2 (aa)=44 >(382) or (56) or (14)? each =44; not (fa)=53 >(14)=54; a OS, Meemor (a0)=—43 >(14)=—54. 3 4 We have two flaps only to draw. (7) gives .M, | whose zoned poles are the flaps, the four like zoneless 2-ple poles being tessaraces. (aa)=44 gives ,N, whose eight janal secondary 2-zoned poles are alternately flaps and 4-gons. 44. We have no more subsolids of six crossings. Of the unsolids, we . find only four, ,D, ,E, .F, and ,G, on which a flap can be drawn to block linear section. We have on ,D, in laa, and 14aa, 3 (aa)=53>(34) and >(56), each=43., (aa) =44> (34) or (56) each=43. 2 By (aa)=53 we get ,P. By (aa) =44 we get ,Q, wide the figures, ) 6 296 REV. T. P. KIRKMAN ON THE ENUMERATION, DESCRIPTION, AND We have on ,E, (aa) =64 >(23) or (45)—63. (aa)=55>(12) or (45)=—53. By (aa)=64 we get ,R, and by (aa)=55 we get ,S. Upon ,I we see that (ab), (ad), (ac), are the only flaps that ean block linear section and exclude concurrence, J 74 7 (ab) =54, 33>(43)—54, 33 ? SS (ac)=54 >(43)=44, 2s a A not (ad)=63 >(43)=64. 4 3 Drawing the flaps (ab) and (ac) we get ,T and ,U. Upon .G only (a) can exclude concurrence. Here (84) is fixed (art. 22). (ab)=54>(56)=54? (12)—34, Drawing (ab) we obtain ,V symmetric as we expected, having three different flaps, one zonal, one epizonal, and AS, one asymmetric. One more subsolid, ,W, is built on J, which has only one edge and one angle. We have constructed twenty-two subsolids of eight crossings, Ae ~3We whose symmetry and circles are seen on their figures. Seven of har are unifilar. : In naming these knots I use an alphabet of 25 letters, omitting the letter O. Thus . A, B,...%: Aa, Ab... Mow Be Bh Bee are each a set of 25. 45. For the unsolids ,X, &c., of eight crossings which have no concurrence, we have to lay 2 upon 6, 3 upon 5, 4 and 2:2 upon 4. For 2 upon 6 we can impose ,Af% on ,A once, on ,B twice, on ,C once, on , once, and on ,F once, but on no other of six crossings, without violating the rules in arts. 25, 28. sAfe on ,A gives ,.X ; yp eek A ic ” ae » sAa ; 4 Que stg ” ae ” gAc > whose descriptions are read on their figures. The monozone ,Aé has four different flaps, one epizonal upon the marginal charge, and three zonals, in the zonal plane. CONSTRUCTION OF KNOTS OF FEWER THAN TEN CROSSINGS. 297 For 3 upon 5, sAf on ,A gives ,Ad; 3Afeon ;A gives ,Af and Ae; 3Afe on ;B attempted gives ,Z erroneously, or leaves a concurrence. ;Afe on ;A gives ,Ag, by arts. 16, 17, and ,AA, art. 27. For 4 upon 4, sAff on ,A gives ,Az; AVON. AL 54 SAYS zAeeon,A ,,* Ak and ,Al. The janal zoned poles on ,A7 are two flaps, two edges of the 4-gon, and two opposite not plane 6-gons. The two poles of ,A/ are a flap and an edge 33: on ,A& the janal zoneless poles are edges 33: on ,A/ are two pairs (66) and (33) of janal zoneless 2-ple poles; and a third pair are two 6-gons not plane. There are two constructions by the charge ,Ace, because neither e nor ¢ (art. 27) is zoned polar. For 2-2 on 4 (art. 38), 6 : ,A’fc on ,A gives ,Am, which has all the symmetry of ,A ; the four 2-ple zoneless janal poles are where they were, and the zoned janal poles are the two flaps of the imposed charges. Finally, i ; ,A’ffc on ,B gives ,An, ee a janal zoned pole in each flap, and another pair in opposite non-plane 6-gons. sAp is the only solid knot of eight crossings, a 4-zoned monarchaxine homozone, whose eight identical janal 2-ple zoneless poles bisect eight polar edges 33. Thus we have constructed seventeen unsolids without concurrence, eX -¥..., An, of which nine are unifilar. 46. We complete our list of unsolids by art. 29— 7A gives Aq; J gives .By, .Bh ; 7B ae Ce or way ey, 2 See _Br a.) ABE, .BL..Baan Bn: 7D , Au; 66 gbp, .Ba; AB yy «= gAv; thw Aw; (Dee sbi abs aly evel Baevs ae ADM a lb lees BG, gb, gb03 pa. «6g, g BU; pte abe, bd ; Jee Be gis DY, abe: Pla. | abe, .b/5 Ve IE ee Oli Of these 36 we have figured only half, the 18 of them which are unifilar ; VOL, XXXII, PART II. 3 298 REV. T. P. KIRKMAN ON THE ENUMERATION, DESCRIPTION, AND as in the unifilars appears to lie mainly the interest of these knots. The 18 plurifils (if ever they deserve a name) can easily be drawn by the student with — the aid of the above list ; and they must be figured by him who constructs the — 10-fold knots, for on many of them flaps can be drawn to make subsolids of ten crossings. We have found of eight crossings, 1 solid knot, unifilar, 22 subsolids, A... .W, 17 unsolids without concurrences 36 unsolids with concurrences ; in all 76 8-fold knots, of which 35 are unifilar. 47. Construction of Knots of Nine Crossings.—The subsolids ,A, &c., are to be formed by drawing leading flaps on ;A, &c. 5 4 ee The only lines that differ on ,A here figured are, Jb and dd, each=44; b df, dd, db, dq, ge, ee, eb, each=34 : 2376, 347, 123, and 134 are the only faces. The d’s Sp . . 5 6 7 are alike, all on the same asymmetric edge 34, which has two different sides. (fb) = 44, (fd) =43, and (dd)=438, have no competitors ; for this (dd) fixes (67) (art. 23), (ddl) =44, 44>(67)=44, 44? All the lines =34, except fd and dd, are led by (67). We have four flaps to draw, expecting symmetry with (dd)=44. By (dd)=44 we get ,A; by (dd)=43 we get ,D; 7 (fb) =44 ” gb 5 ” (fd) ? oC. The symmetry and circles of these four knots are read on their figures, 48. We consider next ;B, here drawn. This has the faces 1473, 6745, an Z 541, with one zoned polar and one epizonal flap. oe different lines that can be drawn are, “ : ab, aa, fb, bb, and cb, each=53, ~ ab, fc, and bb, each=44, EZ es aa and ae, each=43. In 07 (bb) =53, 55>(23) or (54) each 53 54; (67) is fixed (art. 23) (aa)=53 >(23, 67 or 54) each=44; (fe) =44 >(23)=43; In 67b (bb) = 44, 55>(67)=44, 55? (45) =(23) = 43. oe 9a — CONSTRUCTION OF KNOTS OF FEWER THAN TEN CROSSINGS, 299 For the rest, (54) leads (fb), (aw) =44 and (ab) =44, (67) leads (ab)=38, (ea) and (cd), We have to draw (0b) =53, (aa), (fc) and (bb)=44, expecting symmetry with the last, (bb) =583 gives ,E; (bb) =44 gives ,G; (fo) » oF; (aa) » oH; _ whose symmetry and circles are on their figures. 49. ,C annexed has monozone faces 1357, 12467, 354, and asymmetric faces 456, 567, and the flap. The different lines on it are, ab, ac, cc, each 36; ad, ac, be, each 45 ; bd, ec, each 44; ed, eb, each 35 ; besides lines 34 that can be drawn in triangles. (aa) has no rival : in lab, (ab) =63, 53 >(67) =63, 53 ? in 2ac, (ac) =63, 43 > (67)=—63, 43 ? in 24ca (ac)= 54>(67)=53; in 12cbd (bc) = 54>(67)=53 or (12)=43; (cc) =63, 44>(12) or (67) each=63, 44 ? For the rest, (12) or (67) leads them all, as well as all flaps on lines 34. We have to draw six flaps, looking for symmetry with three, (aa) gives us gl ; (ab) gives us oJ ; In 2ace (ac) bolt sul I (ac) » gl in 24ea. in 21be (bc) ap as (ce) Pe ON The symmetry and circles of these are on the figures. 50. Next comes ;D here drawn. The polar 4-gon is 5217, and the asym- metric faces are 5234, 123, 143. The only different lines to be drawn are, fa, fh, ch, ed, dg, in 1dg, and dg, in 7dg, all 53 ; fe, dd, dh, gg, all 44 ; g 7 eg, et, gt, he, hi, ci, all 43 ; 16 lines. y) (fd) =53>(67) =43; (fh) =53>(67)=43; (ed) =53, 54>(82)=58, 53; (67) =48 ; (dg,)=53, 54>(67)=53, 53, or (82) =44 ; (dgy)=53 >(82)=43; and (67) is fixed (art. 23); 300 REV. T. P. KIRKMAN ON THE ENUMERATION, DESCRIPTION, AND inc4h, (ch) =53, 44>(32)=53, 44? (67) is 43 ; (fc) =44 >(76)=43; (dh) =44 >(76 or 32)=43; (gg) =44, 44>(76 or 32) =44, 43 (eg) =43, 53>(76)=43, 53 ? (ei) =43, 43>(76)—438, 43 2 (hi) =48, 54>48, 43; (23) is fixed (art. 23). For the rest, (32) leads dd, gi, ct, and he=43. We have twelve flaps to draw, expecting with three at least symmetry : (fd) gives oP; (je) gives ,V; (fh) » Q; (dh) » W; (cd) 4 oR; (99) » 9&3 (94,) » 993 (9) oo» 9X; (ch) 4» of; (c?) » 94} (49_) » 9U; (Mm), gAa. The poles of ,X are a tessarace and the leading flap. The symmetry and circles of all are read on figures. 51. Our next subsolid base is E, appended, on which no two edges are alike. Thirty-one different flap-lmes can be drawn on it, namely, bd, bf, ed, ec, fe, all 63; be, be, ef, fd, de, all 54; ae, ah, lm, Yj, hm, hy, hi, te, all 53 ; ai, hl, eh, jm, all 44; Sm, nf, nm, gk, gt, ik, jd, jk, kd, all 48 ; % the lines /m, &c., in the base being supposed dotted. (bf) =63, 43>(67)=63, 432? 54=44; (ed) =63 =>(54)=43,; (ce) =63 >(54)=53; (bc) =54 = >(54)=43; (be) =54 >(54 or 67)=53; (cf) =54, 48 >(23)=54, 482? (54)=44; (fd)=54 >(23 or 54)=44 and >(67)=53; (de) =54 >(54)=53, or (67)=43; (23) is fixed ; (lm) =53, 43>(67)=53, 43? (67)=44; (dk) =43, 64>(54)=43, 64? (67) and (23) are fixed (ie) =538, 64>(54)=53, 64? 5 ” For the rest, (23) leads nf, ah, ae, ai, mh, ef, mj, mn; (67) ,, Al, he, hi, bd, Yj, jd, my; (54) ,, gt, gk, tk, jk, jh. CONSTRUCTION OF KNOTS OF FEWER THAN TEN CROSSINGS. 301 We have eleven flaps to draw, with five queries about symmetry, which speedily reveals itself, (of) gives ,Ab; (fd) gives ,Ah; (ed). gAes (dae i, +g Awe (ae). gad; my 4 GA; (00) oy) ge (die .,, gAhs (UE) OP 2) Ur ris; Ade (Ff) » Ag; The symmetry and circles of all are written on their figures. The poles of »Aj are the tessarace common to the two 5-gons, and the flap which connects them: those of ,A‘ are a 6-gon and a 4-ace. 52. The sixth and last subsolid is ;F, which has only one asymmetric face (1567), and one asymmetric flap (67). The flap (25) is epizonal, Eighteen different flap-lines can be drawn: ae, bd, W’e, 07, be, ef, ec, fd, all 53 (bj and be dotted below) ; ac, bb, U’f, ee, ed, cj, all 44 ; f af, dd, dj, all 43. (bb) =44>(25)=43; ('d) in Vd7 =53>(23)=43 and (34) =44, For the rest, (25) leads b’e, Of, cj, ed ; (34) leads ae, ce, ec, ac, af, dd, and dj in 7dy ; (67) leads fd, be in 3be, ff, fe, and by in 40). We have two flaps to draw, (bb) giving ,Am and (0d), giving ,An, whose circles and symmetry are read on the figures. 53. We betake ourselves next to the unsolids of seven crossings, which, by a leading flap, can become subsolids. These are WG, 7H, 7, wd, 7K, 7L, >M, iN, 7, 7R, a) On ,G annexed can be drawn to block the linear section only three lines, which are (ab) =54> (12) =43; in @b7, (cb) =63,44>(54) = 63,43 and >(12)=43; in cb17, (cb) =54>(54)=53 and >(12)=43. We draw three flaps, (ab) giving ,Ap, (cb) giving ,Ag, and (cb) giving ,Ar; whose description is seen on their figures. 302 REV. T, P. KIRKMAN ON THE ENUMERATION, DESCRIPTION, AND 54. On ,H, here seen, we can draw two flaps only, = (ab) = 64 (in 56ba)>(43)=63 or (21)=43. (ab) =55 (in 562ba) >(43)=53 or (21)=43. One (ab) gives ,As, the other gives ,Az. Zoe Four flaps can be drawn on ;I annexed, (ab) = 64 >(56)=63 or (13)=53; eee (db) = 55 >(57)=53 or (13)=53; (ac) =55>(24 or 56)—53 and >(13)=54; (de) =64>(57 or 24)=68 and >(13)=54. / wea — Here (ab) gives ,Aw ; (ac) gives ,Aw; s (GO) O53. ghd (dc) , Am. Professor Tart does not allow ,H and ,I to be different knots, giving a reason at p. 158, Trans. RSE. 1876-7, which appears to me sufficient wherever it can be verified without twisting the tape, or breaking the law of alternate over and _ under. It is true that on the knot in space whose projection is ;H, the three crossings 543 which are found on the thread 67 between 6 and 7, can by slipping of the thread be made to appear on the thread 71; so that the order of the crossings shall be changed from 165435437 .., the thread passing over at 15347, to 167543543 .., the thread passing over at 17534, 7.e., making two consecutive overs at 7 and 5. The resultant figure in space, although it would have ,I for its projection, would, if I am in the right, be no knot. If I had not drawn both ,H and ,I, I should have missed some unifilar 9-fold knots, both here and in art. 63. 55. On ,J, annexed, can be drawn only two lines to make a subsolid, (ab) =54,44(67) =54,44% (54=12)=43. (ac) = 54,44>(12 or 54)=43; (67) is fixed. (ab) gives Ay, and (ac) gives ,Az. 2 both concurrence and linear section, (fa) =54, 43 >(54) =54, 33; (12) =44; (fo)=54 >(54)=44; (12)=43; (ga) =54, 43>(57)>54, 43? (12)=44; : (gc)=54 >(57)=44, or (12) =53. A flap (fy) can be drawn, but the linear section 74 would remain. For t] rest, (45) leads fe, he, hd; (75) leads bg, ic, id, CONSTRUCTION OF KNOTS OF FEWER THAN TEN CROSSINGS. 303 Here (fa) gives ,Ba ; (ga) gives .Be ; CO) 33 ob ; (ge) oBd. The circles and symmetry are on the figures. 56. On ;L, here given, no line can be drawn to spoil the concurrence and the linear section but from « or 8, (ae)=54 >(23)=44 and >(67)=53; (54) is fixed (art. 22). not (ac)=63 >(23)=64; not (ad) =54, 33>(23) =54, 43; not (6g)=53, 53>(67) =53, 54; 2 not (bf)=44 >(67)=53. Here (ae) gives us Be. mae (ad)=63 >(12)=44, or (34)=43; \ ape fer (ab)=54 >(12 or 34)=53; (56) is fixed (art. 22). a lie On ;M, here seen, the leading flap must be drawn from a. (ac) = 54, 43 >(56) =54, 43? (34)=44, Here { 4 (ad) gives ,B/, (ab) ,Bg, and (ac) ,BA, the latter symmetrical. 57. On ,N, annexed, (ad) =54>(42, 26, 17)=54? (26) leads (ab), and (45) leads (ae). = Ww x M ae + The only leader (ad) gives us ,Bi, symmetric. On ;P no flap can spoil both concurrence and linear section. On ,Q there can be drawn only one leading flap— IN (ab)=56, giving .By. \ 7 On ;R, here given, (ac) =55 >(32 or 17)=55 ? (ab) is led by (17). ~ to Be Here (ac) gives us ,Bk, symmetric. On ;S, annexed, s Q (ac)=55>(76 or 34)—54. (ab) =64>(56 or 34)=64 2 Here (ac) gives ,B/, and (ab) ,Bm, the latter symmetric. 1 > We have constructed by their leading flaps sixty-three subsolids of nine crossings, of which thirty are unifilars, bearing on their figures the number 18. . 304 REY. T. P. KIRKMAN ON THE ENUMERATION, DESCRIPTION, AND 58. We demand next the number of the unsolid 9-fold knots, and first, of those which have no concurrence. To construct these we are to lay 2 upon 7, 3 upon 6, 4 and 2°2 upon 5, and 32 upon 3. For 2 upon 7 (art. 34) imposing ,Ajfc, we get On ,A , ,Bn; Ony,I,.,00., cco; » 7>, bp and.ba; » ye pe sees ye ptelee Renee el og DS's yy op pone 3 pls gbb), pbs .bUs 5 UN Oks peg! sigh a; PA pacts » 72 5 By; » 7B, GJ. Dateh iprinen Cael, On ,J we do nothing, because we cannot cover both its least marginal charges ; and nothing on ,P, because we cannot both spoil the concurrence and cover the least marginal charge. 59. For 3 upon 6, the charge must be ;A/e (art. 26) or ;Af;, or Age sAffe on ,A gives ,Ck and ,C/; te). Bay One Cr | cep » Ae) ” 9 . On ,D we cannot cover both marginals ,Aj. On ,E we cannot cover both. On ,F, ;Age imposed to spoil the concurrence would be ;A?fc on A wrongly constructed by one charge ,A/¢ only. On .G we cannot both spoil the concurrence and cover the least marginal. On .H it requires two charges to spoil the two concurrences. Next, for 3 upon 6 again, 3Af on ,A gives ,Cr; gAjeon pA 5° BCs ener, (ev. .cls ews for the e charged on ,A (art. 41) is in turn every different edge, a,,c,d,e. 3Af on _B gives ,Ca , ,Cy; sAfeon ,.B 4 »C2,,Da; sAf on .C .» D8; sAve on C °,,' (Des pAf on GF» 5, 5D; sAfeon WJ 4, De. CONSTRUCTION OF KNOTS OF FEWER THAN TEN CROSSINGS. 305 60. We have next to lay 4 and 2:2 upon 5, sAf on ,A gives ,D/; sAgfon A ,, Dg; jAjeon A, Dh; gAceon A ;, Dz. sA’ffc on .A gives ,D7 (art. 38). ,A-feon ~B 3. Wis 5B was made (art. 31) by adding a concurrence to ,A ; but it is also ,Afe on ;A, though improperly made (art. 38); and as we have two charges to im- pose, we can both spoil the concurrence and cover the least marginal of ;B, thus making ,D/. 61. Finally, we have to lay 2:3 and 3:2 upon.3, ;A7fc on A gives ,D/ and ,Dm. 3A2f on ,A gives ,Dn. These lay 2°3 on 3. sA%fe on A gives yDp. This lays 3:2 on 3. In ,D/, ,Dm, and ,Dz the symmetry is maintained about one of the 2-zoned axes of ,A, though not a 2-zoned symmetry. We have constructed 115 9-fold knots without concurrences, of which 63 are subsolids, and 52 are unsolids without concurrences. Among the 63 are 30 unifilars, and among the 52 are 25, making 55 unifilars without concurrences. 62. There remain only the 9-fold unsolids which have concurrences. The number of ways in which a knot K’ of x-c crossings can be made by add- ing ¢ concurrences of flaps into K of m crossings is easily seen when the symmetry of K’ is given, K’ having no concurrence— gA gives Dg; gV gives oFc , 9Fd , ,Fe; 3B 5 9D7; oh ” bE gC nS 9Dt 2g g& » gk , ohh ; BON Bf) Dus Yew Mobos dip gees abe 3. 2Do, Dw, Dz; 32 on gl, gm; a 5 Dy ; De; Re Ga ge Ds SG) gay ,Ed , Hes pAb ,, oF ,oFr, oFs; BED 4G, Vola: phe 5 oF¥, 9Fus glu; ple as lle poEy oligs sAd ,, okw, Fa; Sy gh; ple 5, volYi, oft pieiee oa, oly, ok; Say a gad , 6G .gac, tines, oll, Ban: GAO sz, gO 5 a 6 (ok; sAh , Ge; aN » oiip ; gAt » AC yi 3 gh ” og ? gH ? Ay ” Gg ? oGh ; BO oS gH; gAk ,,° ,Gt; Blu; oli, sw; pA ow odin RSM pte 5g ha 5 sAm , Gk; st ky; wAn ,, ,Gl,,Gm. Us, Be 2 Ha ,ghOs VOL. XXXII. PART II. 306 REV. T. P. KIRKMAN ON THE ENUMERATION, DESCRIPTION, AND 63. We have next to add two concurrences of flaps to all of ,A, &., on which is no concurrence— yA gives Gn ;, vB 3, GGP sigG@ s gots Gs; ; WO 5, gGt), gas yD page ows Ea, ca e ey np oo Gy o1 bg gules EF 3, god. lei. be Go 5, wl, Ghd ey pil ays gles gtlly, pian. 1 rr 8 emer shay ale lobar 872 0 © 5. legis gigi’, Surtees The number of results in any of the above cases of this article is that of the different flaps which can be made a concurrence of three plus the number of different pairs of flaps that can be made each a concurrence of two. 64. We have next to place three concurrences of flaps on ,A, &c., foun on 5A, five on ,A, and six on ,A— gA gives Hw , Hx; goo Sgt ciple gta, glo ghes la gC » gle ) olf ? lg 3 pit Grrglts oles get Pau Viewlen 5A gives oI/ , Im, oIn; yA ” olp ? olg ? gl; fee Bost Balls: Finally, there is one solid knot, ,I¢. The number of 9-fold knots that have concurrences is 128, of which y have figured only the 70 of them which are unifilars. The rest will have to” drawn if the census of unifilars is carried to higher values. This can easily done. We have found 244 knots of nine crossings, viz. :— 1 solid knot, 63 subsolids, 52 unsolids without concurrences, 128 unsolids with concurrences. Of these 244— 30+25+70+1=126 are unifilar. CONSTRUCTION OF KNOTS OF FEWER THAN TEN CROSSINGS. 307 I think that no difficulty will present itself in the construction of higher n-fold knots, which has not been met in the preceding pages. Here follow the abbreviations used in the descriptions of symmetry :— Monch. for Monarchaxine. . Mox. for Monaxine. Triax. or Tri. for Triaxine. Moz. for Monozone. Triarch. for Triarchaxine. Hom. for Homozone, Zo. for Zoned. Het. for Heteroid, not janal. Az. for Azonal, or Zoneless. 2p. for 2-ple, repetition about an axis. POSTSCRIPT, SepremBer 1, 1884. 65. As it is a brief matter, it may be worth the while to show how all solid knots can be constructed without omission or repetition. Solid Knots, Prime and Non-prime.—aA solid knot Q of crossings is prime or non-prime according as it has or has not a crossing or summit A3B3, A and B being any meshes. Lowest Triangle of a Solid Knot Q.—It is easily proved that no solid knot has fewer than eight triangles. The triangle L of Q is ABC, DEF, where ABC are the three covertical faces and DEF the collaterals of L, the lesser being written before the greater in both triplets. If L’ be another triangle of Q, the lower of LL’ has the least A, whatever be the other five faces. If A= >) N NN 9Bec Vol. XXXII, Pl. XLII. 4.6.8|9Be ypN 4.14 4.10 a / L _2 iia 9 asym. Moz asym. asym. 9Bi 4.4.10 | 9 Bj 4.6.8/9Bk ig |9 Bl 3 |9Bm 6.12 eS a: = 9Bf 4.14 | 9B$ 18 AW asym asym 9Bn 4.14 |9Bp 4.14 ry 2 zo. Mox. Het 3 zc. Mox. Het. 2 p. Mox. Het. |. 3 zo. Mox. Het. Moz Moz ;.i2|}9Br 8.10|sBs 8.10} 9Bt 6.12 |}9Bu is | 9 By 8.10 |} 9Bw ig |9 Bx 4.14 | asym. asym asym asym. asym. asym. Moz 9Bz ig|o9Ca 6.12} 9Cb 18 9Cd ig |9Ce ae i Moz asym ae sa SO | asym. asym. asym. a 1 9Ci is | 9 Cj ig See oe acl ig|9Cm 8.10|/9Cn 6.12 Moz Moz asym. asym. Moz | Moz 9Cr is|}9Cs ig | 9Ct is|9Cu is | 9CV ig|9Cw 18 Moz 2p. Mox. Het. 2 p. Mox. Het. asym. asym. asym. ae Cy a. 14 oDa 4.14|9Db aDe 4.4.10} 9Dd ig |9De 4.4.10 2z0. Mox. Het. asym Moz. asym. 2 zo. Mox. Het. 9Di 6.12 he 2Dm aot © 1s] x ® st o o n=) ie id o teil a asym. asym 2 zo. Mox. els asym. Moz 2 p. Mox. Het. 9Ds 18 ice is|9Dv is|}9Dw 18 ——— a SS Re —— oN WS 5 | ESS | ee ee ee a am | Cg ema = 3 zo. Monch. asym asym. asym. asym. asym. F. Huth, Lith? Edin* Soc. Edin* Vol. XXXU, Pl. XLII. sEl ig | 3Em 1g |3Eq ig asym. asym. asym. gEz 18 18 re 8 2 p. Mox. Het. asym. asym asym. asym 18 18 3Fw 18 asym. Moz aS ES 2 z0. Mox. Het. 2 zo. Mox. Het. i: = ae asym. asym. asym. 9HI 18 . Mox. Het. 2 zo. Mox. Het. ———I| Sek DIDI AA 2 zo. Mox. Het. | a za. Mox. Het. 2 zo. Mox. Het. 2 zo. Mox. Het. glb 18 a Mox. Het. = Al 2 zo. Mox. Het O 3 zo. Monch. ¥. Huth lith® Edin” ( 311 ) XVIII.—On the Approximation to the Roots of Cubic Equations by help of Recurring Chain-Fractions. By Epwarp SAnc. (Read 7th January 1884.) In the twenty-ninth volume of the Society’s Transactions, at page 59, Lord BrounckEr’s process for finding the ratio of two quantities (commonly known as the method of continued fractions) is extended to the comparison of three or more magnitudes. It is there shown that recurrence, which was believed to belong exclusively to equations of the second degree, extends to those of higher orders, and examples of this extension are given in determining the proportions of the heptagon and enneagon. In the present paper it is proposed to show the application of this extended method to equations of the third degree. | If there be a progression of numbers A, B,C,D,E,.... formed by means of the multipliers p, g, 7, according to the scheme :— rA+qB+pC=D 7rB+qC+pD=E rC+qD+pE=F, and if the number p be greater than either g or 7, the terms will approach to be in continued proportion, and their ultimate ratio will be the positive root of the equation a —px?—qu—r=0, : : A ; : (1) — independently of the values assumed for the initial A, B, C. The actual pro- | gression may be regarded as the sum of three series having the initials A, 0, 0; 0,B, 0; and 0, 0, C respectively. On developing the term, we find that the | coefficient of A in the mth term is 7 times that of C in the preceding or n—1st term; while the coefficient of B is compounded of g times the n—1st, and r times the n — 2d coefficients of C. Hence we need only to compute the series | beginning with 0, 0, 1, in order to have the means of compounding any term of a progression formed with the same multipliers. VOL. XXXII. PART II. 3F 312 EDWARD SANG ON THE APPROXIMATION TO THE ROOTS OF The successive terms of the elementary progression are easily found to be [0]=1 ie [2]=p" +9 [3J=p* +2pq +7 [4]=p* +3p’¢ +2pr +9” [5]=p° +4p°¢ +3p"r +3pq? +2qr [6] =p° Popty Papin pep? -H6pgr NP pr [7T]=p" +6p°¢ +5p'r +10p%¢? +12p’or +4 pg? +3pr? +3927 [8]=p® + 7p°¢ +6p’r +15ptg? + 20p%97r +10p7q? 4+ 6p?7? +12p9?r +94 +397? and the general form of the mth term of the progression having the initials A, B,C, is, C being regarded as the zero term, [v—1]rA+ {[r—1]g+[n—2]7}B+[n]C or [n—2]rB+[n—1]{rA+qB}+[n]C. But the elementary progression alone suffices to determine the value of the ultimate ratio 1:2. This process is applicable directly only to equations having suitable coeffi- cients. In the case of pure equations, those whose queesitum is the cube root of some number, the coefficients p and q are both zeroes, and the progression becomes 02-01 OR OF 0 Us On ae euioces which contains the truism that the ratio 1:7; 7:7"; is triplicate of that of which we are in search. ! In order so to change the form of an equation as to fit it for the application of this method, we modify LAGRANGE’S process in a manner which may be best explained by examples. Let it be proposed to extract the cube root of the number 2. In the equation w—Oz?—0x—-2=0, we may write - in place of x, so as to give to it the form a? — 0a*b—Oab?— 20? =0, in which, if 6 represent the side of a cube, a@ stands for the side of the double q cube. CUBIC EQUATIONS BY HELP OF RECURRING CHAIN-FRACTIONS. 313 Here, in order to find the ratio of a to b, we, following BrouncKEr’s plan, try how often } is contained in a. Clearly it is only once, with something over. We therefore write a=1b+c, and get, by substitution, 108 — 3b%e— 30e?—cF =0 , an equation easily managed. The ratio of ¢ to 6 is now obtained from a progression regulated by the multipliers 7=1, ¢g=3, p=3; thus 0, 0, 1, 3, 12, 46, 177, 681, 2620,°10080, &e.; so that if any one term—say 177—be assumed for c, the succeeding term, 681, is approximately the corresponding value of 6; but ~a=1b+c¢, wherefore 858 is the corresponding value of a. In this way we form the series— oO ©@ @® & ® 6) (6) (7) (8) (9) eo ot 0 OU 1K CB 223858 8 B01 HE TROD | 44861 ioe 68” CD” ECT” Ss GBL* «2 620" 10080" 38781’ (10) (11) (12) (13) (14) (15) 187984 723235 2782518 10705243 41186518 158 457 801 ee 149203’ 571032’ 2208486” 8496757’ ' 32689761’ 125768040’ ~’ approaching very rapidly to the cube root of 2. Among these we notice that each member of the terms (3), (6), (9), (12), (15) is divisible by 3, On simplification, these terms, with the prefixes ae 2 form a series progressing according to the scheme r=1, g=—3 p=57; thus (0) @) (2) (3 (4) (5) +1 0 5 286 16287 927506 52819 267 St 0 A 227 go27,” ‘s6i62 47922680’ converging still more rapidly to the required root. The term (2) is true to within the accuracy of five-place logarithms, the defect being ‘000 0032. The next term (3) passes beyond the exactitude of seven-place tables, its loga- rithm being in excess by 00000 00157. The excess in the case of (4) is 00000 00000 31409, which could not be detected with the ten-place tables; while (5) gives a defect of 00000 00000 00053, as tested by my manuscript tables to fifteen places. The errors are two in defect, two in excess, and so on. The roots of numbers immediately above or below a cube are very readily found. Thus for the cube root of 9 the equation becomes a@—9?=0; whence a=2b+c, and b3— 126%e— 66c?++1e=—0. 314 EDWARD SANG ON THE APPROXIMATION TO THE ROOTS OF Hence for a progression converging to the ratio 6: ¢ we have the multi-- pliers r=1, g=6, p=12, giving the series 0,.0, 1, 12, 190, 1 8¥s:, 23'388.,- &e. ; and hence, converging to the ratio of a: b, we have the progression (0) ()erae@) (3) (4) (5) (6) (7) (8) 1 0 2 25 312 3896 48649 607476 7855502 941719529 0’. 0’ 1’ +18 150’: 1873” 23°388° °292 044° 31646°729" 455aqnueee (9) (10) (11) (12) 1182754836 14768960708 184418777041 2302 821 843 576 568 609 218’ 7100175745’ 88659 300 648’ 1107 081 271 464’ a Here the terms (3), (6), (9), (12) are reducible by the common divisor 6, and form the progression (0) (@) (2) (3) (4) 2 0 52 101246 197125806 383 803 640596 —1’ 0’ 25’ 48674’ 94768203’ 184513 545 244’ which proceeds according to the multipliers 7=1, g=-—3, p=1947. This convergence is so rapid that the error of the term (2) cannot be detected by help of the ten-place logarithms; that of (3) is beyond the precision of the fifteen-place tables. In the case of the number 7, which is less by unit than the cube of 2, the convergence is somewhat slower. For the equation a—Te—0 it is convenient to take the first measure in excess, and to write a=2b—¢ which gives b§— 126%e+ 6bc?—?’=—0; so that the progression, by help of the multipliers r=1, g=—6, p=12, becomes (0) a) (5) (6) (7) -1 0 2 23 264 3032 34823 399948 4593470 0’ 0’ I” 12’ 188’ 1585’ 18204’ 209076" 2401276" (8) (9) (10) (11) Oo 52756775 605920428 6959097956 79926409679 917 968 248 840 4. 27579 024’ 316749726’ 3637923 841’ 41782166760’ 479 875 207 800° CUBIC EQUATIONS BY HELP OF RECURRING CHAIN-FRACTIONS. 315 of which the terms (3), (6), (9), (12) give, on being simplified, the pro- gression (0) (1) (2) (3) (4) 0 44 66 658 100 986 '738 152994 '708 140 ad’ «00 o23”)-84846” 52791621" - 79 979 201 300’ for which the multipliers are r=1, g=—3, and p=1515. In order to get a clear view of the general principles here involved, we shall propose to extract the cube root of n’+1. The equation a°—(n?+1)b?=0, gives, for the first approximation, a=nb+c, whence b8 — 3nb?c— 3nbe?—c =0, so that the multipliers are r=1, g=3n, p=3n’, which give, converging to the ratio of 6: c, the progression 0,0, 1, 3n?, 9nt+3n, 27n°+18n3+1, &c., and consequently, converging to ./(7?+1), the series of fractions One () (2) (3) (4) eo 0 n 3n? +1 9n> + 6n? 27n7 +27 nt +4n 0.” 0’ atte 3n? 7 = Ont+3n’ 27n8+18n3+1 ’ (5) (6) 81n9+ 108° + 33n2+1 243nU+ 4058+ 189n°> + 21 n? 81n8+ 81nd +1522 ’ 243n10 4+. 324n7+108nt+6n ” (7) 729n!8 +1 458n29+ 918774 189nt+7n 729n +1 215n9+594n8+81n?+1 ’ (8) 2187n%+5 103n'!? +4 050n9+1 2428+ 117n3 +1 2 187n4#+44 374n" + 2 835n?+648n°436n? =” (9) | 6 561n 417 496n*+16 767m" +6 885n8+1 107254 45n? | 6 561n ©+15 309n% +412 393n%+4 050? +459nt+9n * Here we observe that the numerators of the terms (3), (6), (9) are divisible 316 EDWARD SANG ON THE APPROXIMATION TO THE ROOTS OF 3 3 by 37, the denominators by 32, and hence, for the value of a there comes out the progression +1 0 Sau Or 81n9+ 13575 + 63n3+7 81n®+ 108% + 36n3 +2’ bn? +2 3n8+17 2 187n4 +5 832n124+5 589n9+ 2 295843693 +15 2 1875+ 5 103n!+ 4 131n?+ 1 350n5+1538n4+3 ’ the multipliers for which are r=1, g=—38, p=2in+27n +3, w/ (nm? —1) N and similarly we find for , the multipliers to be r=1, q=—3, p=272' —27nF +3 , with the initial terms ieee 3n3 —1’ ea a +1 0’ these results agreeing with what has been found in the cases of 9 and of 7. It may also be observed that each third term of these second series is reducible by 3, and that they form a progression converging still more rapidly. When the proposed number differs from a complete cube by more than unit the extraction of the root is more complicated. As an example, we shall take the number 3. In the equation a?—3?=0, on putting a=1b+¢ we get — 23+ 367+ 3b? +1c=0, or 3 3 rt (eS / 0.) IE el 5 ee eae b 7 be 3 OC 7° =(() . whence the multipliers or, more conveniently ws OVS gi WS goed ae hare ap 8 from which the progression 3 1b. 67... B05. 1371) 6189) 28 035 9+, 05 te go a2. BM teilby? bebe? + aed Semel ' 4 ; ‘ ; ) CUBIC EQUATIONS BY HELP OF RECURRING CHAIN-FRACTIONS. 317 the numerators being got from the multipliers 4, 6, 3, while the denominators are powers of 2. From this, since a=0)+<¢, we have the approximations to ./3 Cy (3) (4)- ..(5) (6) (7) (8) (9) ee Ob OF. 437 OTT sO4t AN 439 189.853 is ~6 CG oe eal 90". 28085” TIE783 ” (10) (11) (12) 826921 3739613 16911777 573355 2592903’ 1725071 ** Here, as in the preceding cases, each third term may be simplified,,the pro- gression being 7 659 60951 5637259 =) GP doa’ sgogeer & i0.7 457’ 42261’ 3908657’ _ for which the multipliers are 7=64, g= — 48, p=98. Here the approximation is comparatively slow, the less accurate terms being _ largely combined with the more accurate ones. _ To carry BRouNCKER’s process one step farther, let us try how often 6 con- tains c; for b=1c, the above equation gives + 5c? instead of zero; for b=2c, the result is + 3c? ; but for b=3c, we get —17c*?, wherefore 6 contains c twice with something over ; we therefore write b=2c+d. The substitution gives +3 —9c?d —9ed?— 2d? =0, or —3e'd— Bed?— +d =(0. The multipliers hence resulting are giving the progression for d:c 2 4 O70) 135 12. 45-5 175, 670, 2565-5 &e., but a=3c+d, b=2c+d, wherefore the ratio of a:b is given by the pro- gression 318 (OF, Moti (2) fC) wae (5) Ons Bro h0 ol B8rAt dd9.5 4 ae OAcweawa 272 sre Bons” (8) (9) (10) (11) 320344 122659 4696572 11798306 92 211g’ 85047’ 32562218 1246806 converging much more rapidly. LAGRANGE’S application of BRouNCKER’s meth tinued, as in the following scheme :— 0= a— 0ab— Oab?— 38°; 0O=— 269+ 30%+ 36c?+ 10; 0O=+ 38— 9e?%d— 9ed?— 23 ; 0 = —29d°+18d?e+18de?+ 32°; 0= + 10e—33e?f — 69 ef2— 297% ; &e. —e=4f4g EDWARD SANG ON THE APPROXIMATION TO THE ‘ROOTS OF (6) (7) 2185 83662 1515’ 5 8008’ (12) 26 6 885 6678 Hh? 2774955 ° > od may be still farther con- a=1b+e ; b=2c+d; c =3d+e ; d=le +f ; &e. until we arrive at some equation promising greater facility or greater rapidity. The last of the above gives r=2.9; q=6.9; p=3.3; with the condition a=13¢+10/; b=9e+7/7 For the cube root of the next number, 4, we have a— O0a>— O0ab?—40> =0, — 30+ 30%+ 3bc?+ 1e°=—0; + 438— 0cd— b6ed?—"3d2=0 ; — 5d?+ 6d’e+ 12de?+ 4c? =0; + 12e— 24e?f— 24ef2— 5f3=0; — 5373+ 24f%9+ 48f9?+1293 =0 ; + 319 — 639°h—135gh?—53h7=0 ; —188h3 + 324h77 + 216/27 +318 —0 ; &e. The equation in e and f put in the form SG YON NL Gy toy 5 ys eo — 26?f— ef i af Ss 0 5 a1? G—2. 4.) —25 8 gives the multiplications 7= ditions a=3e+3f; b=5e+2f a=1b+c; b=1ce+d; c=ld+e ; d=2e +f ; e=aftg; fHlgth; g=sh+t ; A=2+hk; &e. nd these, along with the cor > CUBIC EQUATIONS BY HELP OF RECURRING CHAIN-FRACTIONS. 319 produce the progression g “19 “54 140 414 11508 ee ot 9 94 ogee? 74a converging rapidly to the value of 4/4. For the cube root of 5 the equations are e@— 0ab— Oab?— 50°=0; a=1b-+e ; — 48+ 30%+ 3027+ 1°=0; b=1ce+4+d; + 32— 3d— Y9ced?— 40°=0; c=2d+e ; —10d?+ 15d?e+ 15de?+ 32 =0; d=2e4+f ; +13¢ — 45f— 45ef?-10f7=0; e =4ft+y; —78f? +219729 + 111/72 +137=0; f=39+h; &e. &e, The equation in d and e gives the multipliers f= =the pal D5 while a=5d+2e; b=3d+1e; hence for %/5, we have the progression 1D Sa 21.75 48.375 108.0375 241.14575 538 . 284375 ee eee §6©6- 12275" 28.275’ Gauls7> ” .-141.01875 - 314.'791875 ’ ; Here the error is reduced about 5 times at each successive step. The equation in ¢ and / gives wetegon 585 45 me siae st ae BES igh while a=12¢e¢+5/; b=7e+3/. The progression thence resulting is 12 605 34245 1915230 107 241125 en De soe 20025) e045.” 627714910: *, converging more rapidly than the former. From these instances it is clear that the cube root of any number, or the root of any cubic equation with integer coefficients, may be represented by a series of chain-fractions of the third order; and not by one only, but by many of such series. Since the successive steps of the Brounckerian process neces- sarily depends on the peculiarities of the case, it would be difficult to make a general analysis beyond the first step; but a symbolical investigation that far may lead to important results. VOL. XXXII. PART Il. 3G 320 EDWARD SANG ON THE APPROXIMATION TO THE ROOTS OF Let us take the general case of a number exceeding a perfect cube by, say, a; that is a number of the form v’+a. We have here a=nb+c, and the equation a—(n8+a)8=0 F becomes —ob + 3n%e+3nde+e=0 ; - which gives the multipliers 1 37 3n? r=— ) GS ? = ? a a a or more conveniently Nae 3an, Sn? Te ra ge te from which we have the elementary progression Owe Ie 2. Ont+8an Bint + Bani +a* ge, a a a® and thence the progression of fractions as 0 3+a 9n' + ban? 27n§ + 27an?+ 4a? 0 O- 3n2 *? =9Ont4+B8an ? 27 n®+18an?+a2 ’ convergence to the cube root of the ratio v’—a : n’, is aheaeed from a oral sion of which the multipliers are v=a°; g=—3at; p=27n® + 27an*?+ 3a", the initials being‘ +a” , 0, 3n3+2a a? 0’ 3n3+1a° This formula may be generalised by substituting for 2° any number K. pe = “ is obtained with the multipliers a®; —3at; 27K2+27aK + 3a? from the initial terms +a-*?, 0. 8K+2a —q"*’ 0’ 3K+1la’ CUBIC EQUATIONS BY HELP OF RECURRING CHAIN-FRACTIONS. o21 sae a ; 8/7 L : And again, if we write K+a=L or a=L—K, NA K results, with the multipliers, (L—K)*; 3(L—K#; 3L24+21KL+3K?2; from the initials +(L-K=. 0. K+2L. 2K3430K®L+42K12+71L! =k s” OI e ROL sOKie IF These inquiries have been confined to the components of two terms only of the elementary progression, whereas in chain-fractions of the third order three terms are admissible. For the purpose then of giving the utmost generality to our research we shall suppose the three initial terms of a progres- sion to be the multipliers being, as before, 7, 7, p. Then, according to what has been already shown, the xth subsequent terms is \ | | [n—2rB+[n—1]{rA+qB}+[n]C _ | [n+2]r6+[n—-1]{ra+o8}+[rly | | If then z be the asymptote of the elementary progression, while S is that of the series of fractions, we must have 7B+(rA+qB)0+Co? _« 7B+(ratgByot ye RM a ee BO) -}and we wish now to express S directly in terms of the nine data, A, B, C; a, By: p,9,7. For this purpose we must eliminate x from the two equations | (1) and (2). Equation (2) may be written im the form (C—yS8)x2+{7(A —aS8)+9(B—8)}a+-7(B—B8)=0 . . . . . (2) from which and 2 — Or age m—iO" ue! fo ig rk en Ue) ae ne eee GO) we have to eliminate z, The elimination gives 322 EDWARD SANG ON THE APPROXIMATION TO THE ROOTS OF S8{7°a8 + 2gra°B+ pra*y + (pr+¢q’)aB + (py—sr)aBy—gay*+ (py +7) 6° +(p?— 9) By — 2pBy* + y°} —S*{A[87°a? + 4qraB+ 2pray + (pr+9°)B? + (pq—sr)By—ay’] + Bl2gra’+ (2pr+29")aB + (v9 —8r)ay + (Bp9 + 37)B? + (2p? — 29) By —2py?] +C[ pra’ + (pq—87)aB — 2gay +(p*—9)8°—4pBy + 3y"]} +S{a[37r?A?+ 4qrAB + 2prAC + (¢?+p7)B? + (pg —37)BC—qC?] + B[2qrA?+ (2pr+ 2¢°)AB+ (pq —38r)AC + (3p¢ + 37) B? + (2p? — 2¢) BC — 2pC?] + y[prA?+(pq—3r)AB—2qAC + (p?—q)B*—4pBC + 8C?]} —S°{r? AS + 2qrA?B + prA2C + (pr+q7)AB? + (pq— Seals —9AC?+( hae -- (p?—q)B?C —2pBC?+C33}=0 . . .. . A; came : ee Thus it appears that, while the root of every cubic equation may be reached by help of a recurring chain-fraction of the third order, every such fraction has for.its asymptote the root of a cubic. The above equation (3) gives us directly the form of the cubic when the initials and the scheme of progression are known ; and, inversely, it contains the means for discovering the progression suiting a proposed cubic. Thus for such an equation as GS*— HS?+KS—L=0, we must equate the above coefficients to G, H, K, L respectively. Here, among the nine unknowns, p, 7g, 7; A, B, C; a, 8B, y, we have only four conditions, so that we are at liberty to make five arbitrary assumptions. Now of the six, A, B, C; a, 8, y, the third power of each occurs; hence the ultimate equation must contain at least one cube. Thus we are again thrown back on the solution of a cubic; but in this case we know that it is always possible so to make the assumptions as that the root may be integer, providec the coefficients of the given equation be so. The preceding very involved expressions may be replaced by others con- siderably simpler. The xth term of the progression may be written D[v]+ E[n—1]+F[n—2] d[n|+e[n—1]+F[n—2] ’ where D takes the place of rB, E that of (rA+qB), and F that of C; an similarly for the denominator. ‘The asymptote then is Da? +Ezr+F da* + ea +f i whence (D--dS)a?+(E eS)e—(F—/f)ce=0. CUBIC EQUATIONS BY HELP OF RECURRING CHAIN-FRACTIONS. 323 The elimination now gives S*{77a? —qrd’e+ (q?— 2pr) dif + prde’ — (pg + 3r)def+ (p* + 29)df?+ re —geft pef? +f} — $?{373Dad? — qr(2Dde + Ed?) + (q?— 2pr)(2Ddf + Fad?) + pr(De? + 2Ede) — (pq +37) (Def+ Edf + Fde) + (p?+ 29)(Df? + 2Fdf ) + 37He?— q(2Hef + Fe”) + p(Ef? + 2Fef) +3Ef%} +81{3r3D?d — gr(D?e + 2D Ed) + (9? — 2pr)(D?f+ 2DFd) + pr(2DEe + Ed) — ( pg +37) (DE/+ DFe+ EFd) + (p?+ 2¢)(2DF/+ Fd) + 37 Ee — q(E2f+ 2EFe) +p (2EFf+ Fe) +3F7/ } —§$°{ 72D — grD?E + (q? — 2pr)D?F + pr DE? — (pg + 387) DEF + (p?+ 2q)DF?+7E? —qE°F ee 0) ts NO Gwe Susss, “ent ge gact @acsrt ts we * oe nt AAD It may be interesting to apply this method to some problems in geometry ; and we may take the construction of the heptagon as a first example. The ratio of the diagonal to the side of a regular pentagon is given by the well-known series0,1,1,1,2, 3, 5, 8, 18, 21, &c, in which each term is the sum of the two preceding, this being a progression of the second order having the multipliers g=1, p=1 The relation between the long diagonal, a, and the side, b, of a heptagon is easily shown to be a3 — 2a7b — ab? +03=0, which gives at once the multipliers r=1, g=+1, p=2, whence tbe pro- gression (re Opetiie2 oe il 825). OO), 120, 289, O50... &E.., each new term being the double of the last found together with the difference between the preceding terms. The convergence here is slow; to make it more rapid we may write a=2b+c, and so get the equation ~ a adieeelionenes —034+-3b%e+ 4b7+=0. This gives the multipliers =1, g=4, p=3; whence the progression 324 EDWARD SANG ON THE APPROXIMATION TO THE ROOTS OF and a still more rapid convergence is obtained by putting b=4c+d; we then find b&—20ced—9e?—- B=0, while a=9e+2d, b=4e+4+1d. Here r=1, g=9, p=20, and the rapidly converging series is 0 182 3721 76067 185805 9 > O° 4 BL’ Te56’ 33853’ e2eg1? &* Enneagon. If we contract an isosceles triangle, having each angle at the base quadruple of the angle at the vertex, and if we lay off along the side two parts, each equal to the base, and from the vertex one part, the three measures overlap by a distance easily shown to be the fourth term of a continued proportion, of which the side and the base are the first and second terms. Hence, if @ be the long diagonal of an enneagon, and 0 the side, a:b? ::b: 38b-—a, or “—8ab+b?=0. This equation gives at once a series having r=—1, g=0, p=8 for the multipliers, viz.— F 0,0, 1, 3, 9, 26, 75, 216: 622, 1791, S157 padeee which converges pretty rapidly to the ratio of the base to the long diagonal. Here, from thrice the term last found, we subtract the ante-penult, in order to get a new term; that is, from thrice AB we subtract PN to obtain AF. From thrice AF we should subtract KB to get the long diagonal of an enneagon having FA for its side, and so on, the distances PN, KB, BA, AF being continued proportion. The figures FMNP and FABK are evidently similar; so if in the continued direction FB we measure from K, twice FB, to M’, we shall obtain an enlarged edition of th figure FM NP. The convergence becomes more rapid if we put a=3 —c, so as to get the equation b—9b2c+6bce—c2=0. CUBIC EQUATIONS BY HELP OF RECURRING CHAIN-FRACTIONS. 325 The multipliers 7=1, g=—6, p=9 thus found give the progression ele 0 3 26 216 1-791 14849 en ee i Oe? Oe > Ley &e., which contains each alternate term of the preceding. | The construction of a regular polygon of eleven sides involves an equation _ of the fifth order, and would introduce chain-fractions also of that order. The extension of the present method to that case offers no difficulty, but would pass beyond the scope of this paper. In the preceding examples we have several times examined the progression formed by each third term of the series; and in the last example we have noticed the progression of the alternate terms. This brings us to the general law, that the terms taken at equal intervals along a series of recurring chain- fractions form a series of the same kind. Thus [0], [2], [4], [6], &c., are connected by the law | [~—4] {07} x [w—2]{2pr—9?} + [a] ip? + 2g} =[n—2], | the multipliers being | R=7?, Q=29r—-¢@, P=p? +2¢. And, similarly each third term forms a progression according to the law [n—6]{r3} +[n—3] fg? — 3pqr—3r°} —[n]{p + 3p9 +37} =[n+3], where R=; Q=@—d8pgr —37°; P=p?+3pq+3r. In the same way, for the terms four steps apart, we have R=—1*; Q= — 2p'r? + 4pq?r— 9 + 497° ; P=p'+4p7q+4pr+2¢’. This law of recurrence extends to chain-fractions of all orders, and even to periodic continued fractions. Thus, in seeking the square root of 7 by the usual \process, we get the successive quotients 2;1,1,1,4;1,1,1, 4; &, occurring in groups of four, and giving the converging fractions, 4 1 il + 1 it i Se 3m 6 45 C82 aT 00. ih, SO 0 3 ae 7? SY AR? 208” 6 OF “AO rer 326 EDWARD SANG ON THE APPROXIMATION TO THE ROOTS, ETC. If we select here the last term of each group as = = hs a , &., or the 2 37 590 first term as [> 77° 593° &c., we form a progression with the multipliers g=1, p=16. Similarly, for the square root of 20, we get the quotients 4; 2, 8; 2,8; &c., occurring in groups of two, the successive approximations being A 2° 962 8 2 1.4 = 76 161.1364 2889 é ° 1 9. Lely 2.883 0° LT’ ; T7’ 36 ) 305 > 46’ &C., nN which the terms 0 ’ Dp} ’ 36 5) 646 ) &e ) progress with the multipliers g=—1, p=18. This circumstance greatly facilitates our investigations in quadratics; thus if the indeterminate equation e=Ty? +1 were proposed, we have at once the solution by seeking ,/7, and taking the last term of each group; thus ¥ Mellel Wal) =e (= 7 Y= 48 > xv=2024, y=1765, and so on, are the solutions. “ When the group of quotients consists of two terms a, 8, the order of recurrence is given by g=—1, p=a8+2. For a period with the three quotients a, 8, y, we have g= Sek p= aBy +a+Bt+y. } For one with the four, a, B, y, 8, we have q=—1, p=aByd+(a+y) (B+8)+2. The subject, however, is too extensive to be treated as an syecnds to the present paper. q (327%) XIX.—On Knots. Part I. By Professor Tarr. (Plate XLIV.) (Read 2nd June 1884. ) One main object of the present brief paper is to take advantage of the results obtained by Kirkm4n,* and thus to extend my census of distinct forms to knottiness of the 8th and 9th orders; for the carrying out of which, by my own methods, I could not find time. But I employ the opportunity to give, in a more extended form than that in the short abstract in the Proceedings, some results connected with the general subject of knots, which were communi- cated to the Society on January 6, 1879, as well as others communicated at a later date, but not yet printed even in abstract. L Census of 8-Fold and of 9-Fold Knottiness. 1. The method devised and employed by Kirkman is undoubtedly much less laborious than the thoroughly exhaustive process (depending on the Scheme) which was fully described and illustrated in my former papert; but it shares, with the Partition method, which I described in § 21 of that paper and to which it has some resemblance, the disadvantage of being to a greater or less extent tentative. Not that the rules laid down, either in KirkmAn’s method or in my partition method, leave any room for mere guessing, but that they are too complex to be always completely kept in view. Thus we cannot be absolutely certain that by means of such processes we have obtained all the essentially different forms which the definition we employ comprehends. This is proved by the fact that, by the partition method, I detected certain omissions in Kirkman’s list, which in their turn enabled him to discover others, all of which have now been corrected. And, on this ground, the present census may still err in defect, though such an error is now perhaps not very probable. On the other hand, the treatment to which I have subjected K1rkman’s col- lection of forms, in order to group together all mere varieties or transformations of one special form, is undoubtedly still more tentative in its nature; and thus, though I have grouped together many widely different but equivalent forms, I cannot be absolutely certain that all those groups are essentially different one from another. : Unfortunately these sources of possible error, though they tend (numeri- cally) in opposite directions, and might thus by chance compensate one another * Ante, p. 281. + On Knots, Trans. R.S E., 1876-7. VOL. XXXII. PART II. 3 H 328 PROFESSOR TAIT ON KNOTS. so far as to make the assigned numbers of essentially different forms accurate, cannot in any other sense compensate. In other words, there may still be some fundamental forms omitted, while others may be retained in more than one group of their possible transformations. Both difficulties grow at a fear- fully rapid rate as we pass from one order of knottiness to the next above ; and thus I have thought it well to make the most I could of the valuable materials placed before me ; for the full study of 10-fold and 11-fold knottiness seems to be relegated to the somewhat distant future. 2. The problem which Krrxman has attacked may, from the point of view which I adopt, be thus stated :—“ Form all the essentially distinct polyehdra* (whether solids, quasi-solids, or unsolids) which have three, four, &e., eight, or nine, four-edged solid angles.” Thus, in his results, there is no fear of © encountering two different projections of the same polyhedron; or, in the language of my former paper, no two of his results will give the same scheme. — Thus there is no one which can be formed from another by the processes of §5 — of my former paper. 3. But, when a projection of a knot is viewed as a polyhedron, we necessarily lose sight of the changes which may be produced, by twisting, in the knot itself — when formed of cord or wire; a process which (without introducing nugatory | crossings) may alter, often in many ways, the character of the corresponding polyhedron. This subject was treated in §§ 4, 11, 14, &c., of my former paper. — But it is so essential in the present application that it is necessary to say some- thing more about it here. It would lead to great detail were I to discuss each example which has presented itself, especially in the 9-folds ; but they can all be seen in PI. XLIV., by comparing together two and two the various members of each of the groups. The following example, however, though one only of several possible trans- formations is given, is sufficiently general to show the whole bearing of the remark, so far at least as we at present require it. ] It is obvious that either figure may be converted into the other, by merely rotating through two right angles the part drawn in full lines, the dotted part of the cord being held fixed. Also, the numbers of corners or edges in the right and left handed meshes in these two figures are respectively as below :— * This word is objectionable, on many grounds, in the present connection. But a more suitable one (loes not oceur to me; and the qualification (given in brackets) will prevent any misconception. Of course no projection of a ¢rue polyhedron can be cut by a straight line in two points only. PROFESSOR TAIT ON KNOTS. 329 55332 nq 04882 443322 ® 433332, These numbers would necessarily be zdentical if the forms could be repre- sented by the same scheme. As will be seen by the list below, § 6, these are respectively the second, and the sixth, of the group of equivalent forms of number vit of the ninefold knots. (See Plate XLIV.) The characters of the various faces of the representative polyhedra (so far at least as the number of their’sides is concerned) are widely different in the two cases. [Mr KirKxman objects to this process that it introduces twisting of the cord or tape ztse/f, No doubt it does, or at least seems to do so, but the algebraic sum of all the twists thus introduced is always zero; 2.¢., by “ iron- ing out” the tape in its new form, all this twist will be removed. I have often used a comparison very analogous to this, to give to students a notion of the nature of the kinematical explanation of the equal quantities of + and — elec- tricity, which are always produced by electrification. If the two ends of a stretched rope, along whose cylindrical surface a generating line is drawn, be fixed, and torsion be applied to the middle by means of a marlinspike passed through it at right angles, one-half of the generating line becomes a right- handed, the other an equal left-handed cork-screw. Thus the algebraic sum of the distortions is zero. And, in consequence, if the rope be untwistable (the Universal Flexure Joint of § 109 of Thomson and Tait’s Natural Philosophy) and endless, the turning of the spike merely gives it rotation like that of a vortex-ring. Such considerations are of weighty import in many modern physical theories. | As will be seen, by an examination of the latter part of Plate XLIV., even among the forms of 9-fold knottiness there are several which are capable of more than one different changes of this kind. Some of these I may have failed to notice. But it is worthy of remark that the 8-folds seem, with two excep- tions, to resemble the 7-folds in having at most two distinct polyhedral forms for any one knot. 4. KirkMAn’s results for knottiness 3, 4, 5, 6,7, when bifilars and composites are excluded, agree exactly with those given in my former paper. I have figured these afresh in Plate XLIV., in the forms suggested by KirKman’s drawings, omitting only the single 6-fold, and the single 7-fold, which are com- posite knots. As will be seen in the Plate, where they are figured in groups, there are but 18 simple forms of 8-fold knottiness. Besides these there are 3 not properly 8-fold, being composite (¢.¢., made up of two separate knots on the same string) ; either two of the unique 4-fold, or a trefoil with one or other of the two 5-folds. These it was not thought necessary to figure, especially as they may present. themselves in a variety of forms. 330 PROFESSOR TAIT ON KNOTS. And the Plate also shows that there are 41 simple forms of 9-fold knotti- ness. Besides these, and not figured, there are 5 made up of two mere separate knots of lower orders, and one which is made up of three separate trefoils. 5. Thus the distinct forms of each order, from the 8rd to the 9th inclusive, are in number AL hie ok 2h nase or, if we exclude combinations of separate knots, 1 Ae oe dk Oe AL. The later and larger of the numbers in these series, however, would be con- siderably increased if we were to take account of arrangements of sign at the crossings, other than the alternate over and under which has been tacitly assumed; and which are, in certain cases, compatible with non-degradation of the order of knottiness. This raises a question of considerable difficulty, upon which I do not enter at present. Applications to one of the 8-folds and to one of the 9-folds will be found in my former paper, § 42 (1). Another interesting fact which appears from Plate XLIV. is, that there are six distinct amphicheiral forms of 8-fold knottiness: at least if we include one, not figured, which consists of two separate 4-folds; in which case we must consider that there are two six-fold amphicheirals, the second being the com- bination of right and left handed trefoils, described in § 13 of my former paper. Thus the number of amphicheirals is, in the 4-fold, 6-fold, and 8-fold knots respectively, either 1, 2, 6, or (if we exclude composites), 1, 1, 5. All but two of these 8-fold amphicheirals were treated in my former paper, two having been separately figured, and the other being a mere common case of the general forms of § 47. | Finally, as a curious addition to the paragraphs on the genesis of amphicheiral knots, given in my first paper, I mention the following, which is at once suggested by the amphicheiral 6-fold :—Keeping one end of a string fixed, make a loop on the other; pass the free end through it and across the fixed end; pass the free end again through the external loop last made, then across the fixed end, and so on indefinitely. The second time the fixed end is reached we have the trefoil (if the alternate over and under be adhered to), the third time we have the amphicheiral 6-fold; and, generally, the mth time, a knot of 3(m-1) fold knottiness, which is amphicheiral if » is odd. Three of these were, inci- dentally, given in my former paper. But, reverting to the main object of my former paper, we now see that the distinctive forms of less than 10-fold knottiness are together more than sufficient (with their perversions, &c.) for the known elements, as on the: Vortex Atom Theory. 6. From the point of view of theory, as suggested in §§ 12, 21, of my PROFESSOR TAIT ON KNOTS. 331 former paper, it may be well to give here the partitions of 2n which correspond to true knots—for the values of m from 3 to 9 inclusive. The various parti- tions, subject to the proper conditions, are all given, in the order of the number of separate parts in each; those which have a share in one or more of the true knots, as given in the Plate, are printed in larger type. co N= 6 (contd.) N =8 (contd.) n=9 N =9 (contd.) 33 42999 772 99 66222 22:2 33222 763 972 65322 222222 754 963 64422 664 954 64332 N=4 a 655 882 63333 ——- = 8429 873 55422. 44 77 8332 864 55332 422 752 7522 855 54432 332 743 7432 774 54333 2222 662, 7333 765 44442 653 6622 666 44433 644 6532 9522 822222 N=5 554 6442 9432 732292 7322 6433 9333 642222 55 6422 5542 8622 633222 532 6332 5533 8532 552222 442 5522 5443 8442 543222 433 5432 4444 8433 533322 4229 5333 82229 7722 444929 3322 4442 73229 7632 443322 22222, 4433 64222 7542 433332 62222 63322 « 7533 333333 53222 55222. 7443 6222229 nN=6 442922, 54322 6642 5322229 ae 43322 53332 6633 442922292 66 33332 44422 6552 4332222 642 422222 44332 6543 3333222 633 332222 43333 6444 42222999 552 22929299 622229 5553 33222222 543 532222 5544 222222222, 444 nN=8 442229 93222 6222 — 433222 84222 5322 88 333322 83322 4499 862 4229229 75229 4332 853 3322222, 74322 3333 844 22222222 73332 The whole numbers of available partitions are thus in order :— 2, 4, 7, 14, 23, 40, 66. Of these there are employed for knots proper only Ie. 4 A We 17. 36. respectively. The remainder give links, or composite knots, or combinations of these. (See Appendiz.) To enable the reader to identify, at a glance, any knot of less than 10-fold knottiness, I subjoin the partitions corresponding to each figure in Plate XLIV. It is to be remembered that (as in § 15 of my former paper) deformations which are compatible with the same scheme, however they may change the appearance ¢ 332 PROFESSOR TAIT ON KNOTS. of a knot, do not alter the partitions. But it is also to be remembered that identity of partitions, alone, does not necessarily secure identity of form. The 3, 4, 5, and 6-folds may be disposed of in a single line. n=3 n=4 n=) n=6 33 sen 442 55 543 552 222 332 3322 , 22222 4332 , 3838222. ., .33222 Here the bar indicates not only that the right and left-handed partitions are alike in number and value, but also that they are similarly connected, 7.¢., that the knot is amphicheiral. For the Sevenfolds, we have if II, - UL 5333, 4433 5482 5432 5432 4433 45322 43322 43322 33332 44992 44229 IV. Vv. VL VIL. 644. 5522 662 77 332222 44222 ga0202° 9222999 For the Eightfolds, L re Til. 54322 | 54322 | 54322 53332 | 44332 44332 53332 44332 43333 44499 44499 IV. Vv. Wal: Vile 5443 54322 m 6532, 6532 333322 44332 54322 44332 333322 433222 43333 VIII. TX: ae s Vs =D - Thus, if 7 denote the column, and s the row, of the table in which py! occurs, all numbers in the row following p' are equal to it. Thus the values of p{ enable us to fill up half the table. In the remain- ing half 7 is less than s; and by a dissection of this class of partitions, similar to that which was given « above, we see that Pi =Di-e FPiregr ts ee FP ot Pit ps; where the two last terms obviously vanish ; and the first term is obviously 1 in the case of r=s, unles r<2, when it vanishes. PROFESSOR TAIT ON KNOTS. 341 Hence, if the following be a portion of the table, the crosses being placed for the various values of pi, mil or not, Values of 7. Sw 16 1708 — Values of s. = ii iat a a cae © ttt ee + + ADO FR WD H OS Pett+tt+t+t+ tio Uy 02M at i ceo ps meer a © Ce a) H+tt+tt H++4 +4 +K it will be seen at a glance that the above equation tells us to add the numbers A, B, C, D, E together, to find the number at K. This is quite general, so that L, in the second last column, is the sum of A, B,...., H; and all the numbers beyond it, in the same row, are equal to it. In the table on next page, each number corresponding to the jirst L is printed in heavier type, and its repetitions are taken for granted. Thus it is clear that simple addition will enable us to construct the table, row by row, provided we know the numbers in the first row and those in the first column. Those in the first and second columns are all obviously zero, as above. The rest of the first row consists of units. These are the values of p:, %.¢., the first term of the expression above for p?. Hence we have the table on the following page, which is completed only to 7=17, with the corresponding sub-groups. From the table we see that p}=8. Hence the partitions of 18, subject to the conditions, are in number 84+114+114+14+104+8+34+1=66, _ which agrees with the detailed list in § 7 above. [The rule is to look out the number p”, and add it to all those which lie in the diagonal line drawn form it downwards towards the left. But the construction of the table shows us that this is the same as to look out pz, at once. | Similarly we verify the other numbers of partitions given in the text. And it is to be remembered that p” is the number of required partitions in which m occurs, and that every one of the class p>" has for its largest constituent »—7. Thus, looking in the table for p/ and the numbers in the corresponding downward left-handed diagonal, we find the series 4 6 5 5 2 i which will be seen at once to represent the dissection of the partitions of 14 given above. The investigation above was limited by the restriction, imposed by the theory of knots, that no par- tition should be less than 2. But it is obvious that the method of this note is applicable to partitions, whether unrestricted, or with other restrictions than that above. The only difficulty lies in the border- ing of the table of double-entry. Thus, if we wish to include unit partitions, all we have to do is to put unit instead of zero at the place »=1, s=0, and develop as before. Or, what will come to the same thing, sum all the columns of the above table downwards from the top, and write each partial sum instead of the last quantity added, putting unit at every place in the second column. Similarly, we may easily form the corresponding tables when it is zequired that the partitions shall be all even, or all odd. 342 Table of the values of »{; the number of partitions of s in which no one is PROFESSOR TAIT ON KNOTS. less than 2, nor greater than 7, (The values of r are in the first row, those of s in the first column.) 0 2 ae 0 1 1 2 3 Te 4 1 2 5 1 4 6 De 7 1 2 8 om 9 of) 10 2 5 11 Q 4 12 7 13 5 8 7 10 — for) So © 9S 6496707080 OC (OZOcS OFCnO (ORO So Ono OVO OLORron OOo ao oO 1S AA nKWInar or Fr PP WOR WW DH Wb & — bo (RSIS SSS SS) SS OS) CS SS SS) SS) OOS Se OS] OS SS Se ea Ss SD SS SS) KH OrorcororortorortorororcorororororF: From what has been stated in the previous pages, it is easy to see how to extend this table ; forming the successive terms of each row by adding step by step upwards to the right along a diagonal, thence upwards to the top, zig-zag along the row of heavier type as soon as it is reached. 5 22 42 6 7 8 113 126 155 2 0) al 95 110 134 155 189 171 215 207 107 123 154 eG 220 115 135 168 197 12:73 14. to 16 my 21 23 33 39 52 61 81 94 122 143 180 24 33 40 53 63 83 98 100 102 34 40 54 64 85 126 130 150 ' 3 aa 54 55. 65 65 66 86 87 Amphich! Amphich? o forms Il Two forms mG. WW ve Il, IV Unique Sie i Unique aE aes iA aes a fie: ae orms Ill Two fee IV ae mS , a os eed a , ie VII at ree Vill te forms X pe forms sf — mene plo SERS Dat 8 Bb 8 Ax sy XII be XLV id XV Unique XVI_ Unique oor ie wit: ( Il Six forms sBj sBz oJ 9K 2P 9Q IL Two ieee IV Four ae a4 Unique VI_Three forms 9 Ab ] 9Aq rm: a Six areas IX hea X Unique Xl Unique 3Au o AV 2Bec XIII Three forms a Four forms eAz 2Bw 2Dw ee Three forms XVII Four forms XVII1 Three forms 9Fj ] XX_ Three ea aoe a oe cae Four ioeg 9D1 3D si a Aan pe Four ee can Three a: ” 35 Two forms 9Fa 9Fc 9Fn 9 Fi 9 Fk 9Gk 9Em 9 Gl 9Hz oHt 9Gp 2Gq | forms XXIX Two forms XXX Two forms XXXI Two forms XXXII Two forms XXXII Two forms 9Gv 9 Hi 9Gz 9Hh 9Ha a 9Hs oHy XXXIV Two forms XXXV Unique XXXVI Unique XXXVII Unique soe ne XXXIX Unique re ey XLI Unique gIt gle oll F. Huth, Lath® Bdin® — ©o i (Sy) — XX.—Philosophy of Language. By Emeritus Professor J. S. BLAckteE. (Read 7th April 1884.) The UNIVERSE, as we have it, is an organised system of rational or reasonable forces and forms; of which the former are the product of the plastic, self- energising, productive power within, the latter the external presentation or manifestation of that power. I. Language is a form of the fluid element, the air, moulded into shape by the vital forces of any living creature acting under the constraint of a determined organism, and significant of the sensations, emotions, sentiments, or thoughts of the creature; transmitted to and made appreciable to other similarly consti- tuted creatures by the instrumentality of the ear, an organ nicely sensitive to all the affections of the fluid element, and thus faturally fitted to be the medium of intelligible communication between creature and creature in a system of social interdependence. II. The simplest elements of language which we have in common with the lower animals are of the nature of cries ejaculated or instinctively sent forth from the vocal organs of the creature, under the stimulus of some sensations of pain or pleasure, either arising altogether from within, or called into action by some external agency, as the pricking of a pin,—such cries as the cawing of rooks, the purring of cats, the grunting of pigs, the braying of asses, the cackling of geese, the shrieking of women, and the roaring of men,—cries which arise necessarily from the nervous constitution and vocal organism of the creature, and which are naturally intelligible to all creatures of a kindred nature, and endowed with a responsive susceptibility. These cries in human language are, in the language of grammar, interjections: such as ha, ha! ho,ho! 4 po, BaBot. But they are in fact verbs, or at least the soul of a certain class of verbs, performing, as a means of communication between creature and creature, the complete function of verbs, and becoming perfect verbs in grammatical ‘form directly they are tied down by certain modifications to definite relations of personality and time ; of which anon. III. Were a human being only a bundle of sensibilities, human language would consist merely of such ejaculatory words; but this sensibility is only the starting point of his existence, the point which he has in common with a mouse, a midge, or a monkey ; he soon becomes a perceptive animal, and after that a mimetic or imitative animal; being moved by an unfailing instinct to reproduce, in some form or other, whatever striking forms or energising forces from without may VOL. XXXII. PART II. 3K 344 EMERITUS PROFESSOR J. 8S. BLACKIE ON have strongly affected his nature. Hence, the whole family of words, in grammars stupidly called onomato-poetic, in which we recognise the germ of the dramatic element in literature, as in the ejaculatory element we may recognise the germ of the lyrical element. This whole class of words, representing originally all sorts of natural sounds, is manifestly the product of the native dramatic instinct of the human creature, and, though starting originally from im- pressions of sound, readily adapts itself by analogy to cognate impressions of the other senses, and even to emotions of the mind, and in this way claims a much larger domain in the field of every cultivated speech than would at first sight seem to belong to it. IV. Our next proposition brings us to a higher and a characteristically human platform. When I call an ox, bo—bov—baa, as in Greek, Latin, and Gaelic, this, as a mere echo of an animal sound, might be repeated by a parrot, or any other animal with imitative instinct and apt vocal organisation. But the moment I use this imitative sound to express the name, not only of the indi- vidual animal which I just heard utter the sound, but the notion, idea, or type of a whole class of animals uttering the sound, I plant myself on a platform of in- tellect of which no animal, not even the cleverest monkey, is capable. The genesis of the idea in the human soul is a matter of which neither sensation nor sensibility can give any account; sensation is always the occasion, never the cause, of the idea. Four eggs, for instance, are no doubt felt to be four by a dog, or bull, or by a man; but the leap from that to the mathematical proposition, 2+2=4, is infinite, and cannot be overbridged by any ingenuity. In forming the idea of an ox or a cow, the vovs or Adyos, which differentiates a man from a brute, acts plastically from its own dominant centre, and uses sensuous impressions merely as a multiform material on which the unity of an intelligent type is impressed; here we have the birth of human, that is intellec- — tual language, a language expressive, not of sensations or of feelings, but of — thoughts and ideas, which are as general as mathematical definitions, and are the pure creations of thinking. In forming them man acts as a god creating an | organism ; and this truth, so habitually ignored by a certain narrow school of physical scientists in these latter days, is not the least striking manifestation of the philosophic depth which lies at the bottom of that text—Gen. i. 27, “God made man in his own image.” Here we see distinctly the reason why brutes have no language in the sense that we talk of human language. The vital forces which belong to them, being purely of sensational and emotional origin, are satisfied by the lowest form of vocal expression which we call cries ; their . language is in the main ejaculatory, and in some part also imitative. But there being no Adyos or vods in them that craves for expressing in intelligible form, the words significant of types and general ideas, of course no such form appears ; and man stands emphatically differentiated from them as the only THE PHILOSOPHY OF LANGUAGE. 345 speaking, because the alone thinking animal ; the Adyos of speech being in part only the outside of the Adyos of thought, and both expressed significantly in Greek by the same word. We say, therefore, distinctly that the mass of human language consists of an array of articulated sounds elevated by the power of self-acting imperial mind—Bacwkkds vovs, as Plato calls it—from their original sensous significance into the region of thought, and made thus to serve as an organ of thinking in the communications of a specifically thinking animal. V. That the vows in the formation of language acts in its own imperial style, and not at all in the manner of Locke’s unhappy simile of the sheet of blank paper, will appear plainly on considering the nature of that class of words which, in all languages, is found to express purely mental operations. They are, of course, formed by a secondary application of originally sensuous terms; but the point lies not in their origin, but in the selection made from a host of words of the same origin. Thus, in Greek—xaradapBavo, cvvinnn, ovddoyilw; in Latin—comprehendo, concipio, intelliyo; in German—/assen, beyreifen, plainly imply a very distinctly energetic forthputting of the internal moulding faculty to lay hold of the material presented by the senses, as a potter lays hold of the clay. And in this regard it is not without interest to remark that, whereas verbs of sensation generally in Greek govern the genitive case, verbs of seeing, which is pre-eminently the intellectual sense, always govern the accusative ; for the same reason evidently that active verbs generally govern that case, viz., because the accusative is a case of motion towards a point; that is the appropriate case to mark the invasion, so to speak, of the external material world, by the internal vital force of the observer in the act of cognition. VI. The steps by which language grows from the original simple elements into the luxuriant expanse of significant sounds found in our dictionaries is not difficult to trace. The original stock, either in its single nakedness or with some modifications and slight additions, is adapted to new and very diverse uses by the law of similitude acting along with the law of parsimony. The law of parsimony, or a Wise economy and a wise laziness, forbids to invent absolutely new words when old ones can serve the purpose; and the law of similitude, which the mind constantly follows in the classifications of science, as in the inspirations of poetry, by easy steps of transference, leads to an unlimited variety of uses of the same root, just as in the world of colour dark green may pass into light yellow. The changes of meaning which the root undergoes in this process of adaptation to new objects and new circumstances are always instructive and often amusing. We shall content ourselves with two familiar examples. The word prick, for instance, whether as a noun or a verb, is, I have no doubt, derived from the slight sharp sound made by a pin or a drop of rain 346 EMERITUS PROFESSOR J. S. BLACKIE ON falling on a dry surface. The various forms which it has assumed in its passage through the millions of millions of human mouths during long centuries, from Sanscrit, through all the Teutonic languages, will be found in Skeat. They all signify a dot or spot, or the point that makes it, or the act of making it ; and the last of the large progeny of small dots or points is one which is said to be produced either by native virtue of the academic soil at Oxford, or, as Lord Reay had it, by a peculiar metamorphosis which the rude unkempt Scot some- times undergoes when he is transplanted to that atmosphere compounded curiously of the four elements of Greek, Episcopacy, Aristocracy, and Plutocracy ; so that, to use the language of geologists, a prig is a metamorphic Scot, having in West End estimation the same relation to a normal Scot that a dainty Alderney cow has to a shaggy Highland stirk. This is the bright side of the creature, and the side of course from which he habitually contemplates himself. The dark side is revealed by the etymology which plainly sets him forth as a creature of small points and proprieties—a creature mighty in small matters— a sort of dainty drawing-room pedant—in whom the 76 ceuvdv of true manhood has been altogether swallowed by the 76 zpérov of smooth convention, and the To Kopabov of petty elegance and superficial polish. Opposed to him is the sumph, a creature with neither points nor polish, from the German swmpf, a bog, coudos, porose, a boggy-brained animal, whose depth, when he has any, is only a profundity of soft and sinking stupidity. Take now the word bu//—not the animal which is kin to Bo, but the Pope’s bull, which has nothing to do with the bovine cousinship in which the model Englishman glories. The Latin bulla, as every schoolboy knows, was a sort of boss or knob hung round the neck of patrician boys, and pet lambs sometimes, by fond Romish mamas ; its original meaning was a bubble of water, from bullio, English bod. This round boss or knob, in a leaden avatar, came in the Middle Ages to be attached, as a sort of seal or stamp, to the thundering ordinances which his Holiness of the seven hills used to thunder over Europe largely, in order to crush kings and frighten fools ; hence transferred to the document itself; and as the good old gentleman, with all his infallibility, sometimes blundered, a bull came to signify a blunder; and as Irishmen are famous for blunders, the little gilded ornament on the baby patrician’s neck became metamorphosed into a blunder very closely akin to the bubble out of which the word arose. VII. The modifications, in verbal form, which the root underwent, in order to adapt itself to new applications and to acquire new shades of meaning form — two classes—those of which the origin and significance are either perfectly plain or can reasonably be presumed, and those of which the significance is altogether unknown, and in all probability not to be recovered. The general rule is, in the words of Horne Tooke: “ Nothing in language is arbitrary or conven-— tional.” Language, like political constitutions and national character, is a growth, THE PHILOSOPHY OF LANGUAGE. 347 not a convention or an institution. The most superficial dissection of the familiar forms of words, as we have them in our grammars, distinctly shows this. Amo amas means merely love I, love thou; the Sancrit asmz, the Latin swum, and the Greek «iui, being merely the two interflowing elements which are presented separately in the Gaelic tha mi and the English Jam. So the case terminations in Greek and Latin are merely significant attachments expressive of local relationship which have grown into the root in these terminational languages, but of which the meaning stands clear in that detached form which these agglutinated postpositives present as independent propositions ; the sign of the genitive in English of being manifestly = 07, Greek amd, Latin abd, away from, It matters nothing that we cannot in all cases, or in the majority of cases, distinctly put our fingers on the original significant form of the abbre- viated or polished case termination ; enough that man is a reasonable animal, and that from his reasonable proceeding in known cases we can certainly divine it in where the formative action is hidden from our view. Words as we have them, especially terminations, conjunctions, and other such frequently used and much abused elements of the vocal currency of a country, are like old shillings from which the image and superscription has been defaced, but which certainly was there, as it lies in the very nature of a coinage to bear some stamp and authoritative signature on its face. VIII. That some modifications made in the root are without separate signi- ficance, and may without impropriety be called arbitrary and conventional, I think we must admit ; and so Horne Tooxe’s rule, like other rules, will have its exceptions, and must not be pressed urgently in all cases. Any child could tell how rubefacio signifies to make red ; it is merely two words run into one, in the same way that the Greek use movea in dpromows, a baker; but no man can tell me how fell came to signify to cause to fall, or how the plural of man should be men. No doubt in this latter case you may say that the a of the singular was changed into the e of the plural by the reflex contagion of the ¢ in the plural termination Manner ; but this is merely the description of a process of contagion or infection taking place between two contiguous emissions of articulated breath, not the laying bare of any natural significance in the change which has taken place. There is nothing in the word /e// that should cause it to mean to cause to fall; it is a pure matter of convention—an ingenious device, let us say, to make one word serve two purposes, as faces have been made by ingenious draughtsmen representing two different persons, according as you look at them from this side or from that. In the same way no conceivable reason can be given why wre in German, were in English, should be the subjunctive mood of was ; or, what is similar, why the a of the indicative of the Sanscrit or Greek should be softened into y in the subjunctive. It is for the sake of variety and distinction alone that such changes are made ; and they are in this view perfectly 348 EMERITUS PROFESSOR J. 8 BLACKIE ON analogous to the change of accent which takes place in English when a verb and a substantive are in all other respects identical, as in prétest and protést, or in the case of proper names in Greek— A toyernjs, born of Jove ; Avoyévys, a man’s name; deEdpevos, having received; Aecéapevds, Mr Receiver. A phenomenon somewhat different from these cases presents itself in the case of diminutives, which are made in most languages by the addition of terminations, which, though possessing no separate meaning in themselves, do really suggest the idea of littleness by the character of the differentiating syllables. Thus the terminal /, being a pleasant soft letter, and easy to dwell on prettily with a kindly tongue, seems to have been used in various languages to express diminutives—as in Latin puer, puella, puerulus; German Magd, médl; Italian donna, donzella, dama, damigella. The same explanation may apply to the vowel p in the Greek taddépu, from avd. It is impossible, however, to see the same propriety in the termination foxos used to diminish substantives in Greek, as ish is to diminish adjectives in English, and zke in Scotch, as in lass, lassie, lassikie. It is probable that all thése terminations, as also the Greek ixdés adjectival termination, are only varieties of the verb éuxew, to be like, in which case they belong not here, but to our previous section. IX. Before proceeding further, it may be well to make two remarks about roots. (1) However remote the single Sanscrit monosyllabic roots in dha, tha, ma, &c., may appear from any ejaculatory or mimetic origin, I most firmly believe that they are merely the curtailed forms of words which had such an — origin, starting from the impressions made on the senses or from external sensations; as, for instance, when Max MULLER says that pater, a father, comes from the root pa, to nourish—even if that be true—I am not at all sure that the root pa, to nourish, did not first come from the kindly babble of infantile lips which produced papa, mama, Amme, pata, and py. (2) All roots are, and must have been verbs originally, for the simple reason that substantives could not receive names except from certain qualities residing in them; but qualities, so long as they are quiescent, do not strike the senses sufficiently to stir the soul to that vocal utterance which is the word ; therefore adjectives, being quiescent qualities, could not be the first words, but verbs, which are energising qualities or functions. But the first word, though a verb, while the language-forming instinct is yet in its infancy, would answer all the three purposes of verb, sub- stantive, and adjective; as happens in our bald and unterminational English every day—jire, to fire, fireman—which, had the Englishman spoken Greek, would infallibly have assumed the triple form of zip, tupéve, and supeurys. X. Hitherto we have spoken of language only as a useful machinery for the purpose of communication among social creatures; but language is also a fine’ art, and that in a double sense: a fine art fashioned by Nature under the influence of that striving towards the Beautiful which is apparent in all the THE PHILOSOPHY OF LANGUAGE. 349 Divine workmanship, and again cultured and improved by man in virtue of his divine origin and divine mission on earth, so beautifully expressed by the Stoics— Contemplari atque imitari mundum. Now, in this view, the perfection of a language will depend in the first place, as in a musical instrument, on the number and variety and completeness of the notes which it contains, and again on the quality of these tones, and lastly on the skill with which they are used by a natural genius and a practised player. With this high ideal before us, we shall certainly find no human language perfect ; for, besides that the organs of utterance in some cases may be of less perfect construction and of inferior capacity, the most highly gifted peoples in the use of language are apt to have pet tendencies and to fall into mannerisms, which are not only bad in them- selves, but do an additional harm by excluding other less-favoured elements of a perfect vocal gamut from fair exercise. Thus the language becomes lopsided, and, as in the case of a body palsied in one limb, presents an appearance of completeness which its power of action does not warrant. It appears to have two arms, but can strike only with the right or with the left. Any vital function rarely used is used with difficulty, which gradually hardens itself into an impossibility ; and so we find whole nations of the highest organic accom- plishment unable to pronounce certain letters; as the Germans cannot pro- nounce 7h at all, and the English regularly change the y of the Greeks and the Scotch ch into &. Some nations cannot even distinguish 7 and /, both liquids, no doubt, and so akin, but considerably different, both in the movement of the tongue by which they are pronounced, and in their musical effect on the ear. On the otber hand, the aspirate which the German cannot enunciate is so familiar to the Celt that he introduces it regularly where it does not belong, and not rarely allows it, as in the Gaelic ha for ta, to override and delete the consonant which it modifies. There is hardly a nation that does not get into a bad habit of using one part of the machinery by which vocal breath is emitted with such preference as to impart a mannerism so strong as to become a distinctive mark of nationality ; thus the Englishman, by the preferential use of the back of his mouth, gets into what is called the ha-ha style, and the curtailing of the 7 of its fair proportions, so that I saw A beautiful sta-aw = star, is a perfectly good rhyme to a London, but not to an Edinburgh ear. The | Greek, on the other hand, gave a preference to the front of the mouth, which produced the vjrcv and the ov=o0, which the Englishman in his ignorant | insular fashion refuses to recognise. The Yankee nasalism is another familiar ‘instance of the same kind; and the vocalisation even of the liquid J, as in Versailles, of the modern French, is the most recent instance of the 350 EMERITUS PROFESSOR J. 8. BLACKIE ON polished feebleness in which that emasculated offspring of the Latin language delights. XI. The quality of the vowels, and the choice and combination of consonants by which the music of language is specially affected, must depend partly on the delicacy of the original senses and organic tissue ; and that this is influenced in a considerable degree by the climate, that is, by the atmosphere which the speaker breathes from his cradle, can scarcely be doubted. Hence the greater fulness and sweetness of the English vocalisation compared with the Scotch ; hence, perhaps, the less musical character of the Teutonic languages generally as compared with the Greek and Latin. But, though climate no doubt asserts its sway here, as in a matter as much physical as moral, national character, at the same time, as the moral element which affects enunciation, cannot fail to make itself felt; so the Germans and the Scotch, being a more emotional people than the English, put more soul into their syllables, and draw out their words with a more kindly moral emphasis ; and it seems impossible not to deduce the nos tamen sumus fortiores of Quinctilian, spoken in contrasting Latin with Greek, from the radically different character of the two peoples. But here we must remark, that the ideal of harmony in a language consists not merely in rich- ness and sweetness, but in that grand and curiously varied combination of strength and sweetness by which the great compositions of a BEETHOVEN ora — HANDEL distinguish themselves from a pleasant or a plaintive popular ditty. Now the strength or the bones of a language are in the consonants ; and the trunk, so to speak, of the word lies in the root ; so that the typical language is that which has always at hand a strong combination of consonants to express strong feelings, and a rich flow of vowels to express the more delicate emotions. Now, as we have already said, it is extremely difficult for a language to possess all excellences ; as the French avez for habetis, pére for the Italian padre, peut for potest, not to mention the systematic deletion of the mz in the final syllable of the present indicative of verbs, are a strong proof of how apt polish in this region is to degenerate into feebleness. Nay, it seems absolutely impossible, even in the best constituted languages, to combine sweetness with strength in the degree which an ideal type would demand ; for, as the most significant and dramatically most effective part of a word lies in the root, it follows that when-— ever a strong utterance is to be fairly given, then the root which dramatically expresses the strong word ought to be made prominent. On the other hand, as the music of a language depends very much upon the cadence of the termina- tions, which in fact have only their vocalic element to recommend them, itt follows that, whenever sweetness is to be expressed, these terminations ought not to be cheated of their natural emphasis. But, as a matter of fact, these terminations being affixed without distinction to all kind of roots, either, being accented, will swamp the root, or, being unaccented, will be apt to lose THE PHILOSOPHY OF LANGUAGE. 351 part of their full musical value, or; at all events, prevent the root from standing so emphatically on its own legs, and producing its full dramatic effect. One line from Homer will show this— 4 AS 4 > A tA te) > Sovmnoe O€ Tec av apabyae Se TEVXE ET AUTH, and this may stand to verify the general proposition that the English language, besides being superior generally to either Greek or Latin in the dramatic truth and vigour of its roots, by virtue of its very lack of terminations, has a dramatic power in its daily use, which it is as impossible for Greek to emulate as it is impossible for English to emulate Greek in the volume of sentences and the cadence of periods. XII. In the music of language, as the vowels are more sonant than the conso- nants, so the long vowels and the broad vowels, as a@ and o and w, are more musical than the short vowels and the slender vowels. Next to the quantity or volume of sound, the pitch of sound, accompanied as it naturally is with an emphatic dominance of the accented syllable, has a notable effect on the music of spoken address, and cannot be transposed or neglected without doing violence to the genius of the language. In respect of accent, the Greek, as noted by the ancient rhetoricians, has a decided advantage over the Latin, in allowing the accent to ride freely, according to certain laws, over the three last syllables ; while the Latin, like the Gaelic, altogether excluded the accent from the last syllable of the word, where it is most musical. As the accent is one of the most character- istic, so it is one of the most persistent elements of the vocal life of a people ; and in the case of Greek is, accordingly, prominent alike in the books of the ancient grammarian and in the mouths of the modern people ; a fact which renders inexcusable the practice of English Hellenists in transferring wholesale the Roman system of accentuation to the Greek. We have no more right to tamper with the music of any language than with the colouring of a great painter or the diction of a great poet. XIII. A written alphabet, or a body of visible signs significant of sounds, is | no doubt a grand invention, and a great convenience, but belongs to the philo- | sophy of language only in a very indirect fashion. A written, graven, or printed language is for record primarily, not for expression ; like a photograph, it is an exact likeness, but without the expression which is the soul of the living image. An OrpPHEUS, therefore, and a Homer, the highest form of lyrical and epic poetry, was possible to Greece, if not before a written alphabet was known, certainly before it was used for purposes of writing and reading. Neverthe- less, it seems certain that without the habit of writing and reading books, certain forms of literature which appeal to calm introspection, rather than to present excitement, could not have existed; without a written alphabet, Homer VOL. XXXII. PART II. a0 352 EMERITUS PROFESSOR J. S. BLACKIE ON and Hestop could never have been followed in due season by the large range of historical survey in Heroportus, and the condensed summation of political wisdom in THucypipEs. oor Papa Stour Sheet 389 B. Intrusive Igneous Rocks, . : 368 5. Dykes— ; A cialis Rocks. 383 1. Intrusive Sheet of Binary Granites Binary Granites ; : 383 in Northmavine, . : 368 and Quartz-fel- 2. Intrusive Sheet of Granite in Send sites, ’ : + ges sting, . 370 Rhyolites, ® wiht l 384 3. Intrusive Sheet of shiveatinge Fel- Summary of Results, . F ‘ : _ 386 sitein Papa Stour, . : Sasa 4, Dykes— ; ‘ ‘ snore APPENDIX.—Table of Chemical Analyses of a. Binary Comics : : OS: eight Specimens of Shetland Old Red b. Quartz-felsites, : : one Voleanic Rocks, by R. R. Tatnock, c. Rhyolites, : : : . 374 F.R.S.E., . : ; - : . 387 d. Diabase Rocks, : ‘ = ext) Perhaps the most interesting feature connected with the Old Red Sandstone formation in Shetland is the evidence of prolonged volcanic activity in those northern isles. The great development of contemporaneous and intrusive igneous rocks, which gives rise to some of the most striking scenery in Shet- land, is all the more important when compared with the meagre records in the Lower Old Red Sandstone of Orkney and the Moray Firth basin. Not till we pass to the south of the Grampians do we find evidence of a far grander display of volcanic action during this period, in the sheets of lava and tuff in the Sidlaws and Ochils and in the great belt stretching from the Pentlands south-westwards into Ayrshire. The relations of the Shetland igneous rocks are admirably displayed in the various coast sections, especially in the mural cliffs of Northmavine and some of the Western Islands. From these records, though they have been subjected to much denudation, it is possible to con- struct a tolerably complete sketch of the volcanic history of this formation, as developed in that region. VOL. XXXII. PART IL. 3M 360 B. N. PEACH AND J. HORNE ON THE No previous attempt has been made to furnish a chronological account of the Old Red volcanic phenomena of those northern isles. In H1BBERT’s admirable volume * there are various references to the granite masses of the Mainland and the amygdaloidal claystones in the south-west of Northmaviue. He also refers to the porphyritic and amygdaloidal rocks in Papa Stour, which were likewise described by Dr FLemine.t In various papers published in the Mineralogical Magazine,{ Dr HeppLe notes the existence of interbedded and intrusive igneous rocks of this age in Shetland, with descriptions of the minerals obtained from them. The first attempt, however, to connect these Old Red volcanic rocks with their representatives south of the Grampians, was made by Dr ArcuiBaLp GEIKIE, the present Director-General of the Geological Surveys. In 1876 the geological structure of Papa Stour, which is almost wholly com- posed of volcanic rocks, was solved by him in company with Mr Bb. N. Peacu; and, as the result of that traverse, an account of the geology of that interesting island was given in his celebrated paper on “The Old Red Sandstone of Western Europe,” published in the Zransactions of this Society.§ Though unable to visit the voleanic rocks on the north side of St Magnus Bay, he ventured to suggest that,the amygdaloidal claystones referred to by H1BBERT would turn out to be merely a repetition of those in Papa Stour,—a suggestion which has been amply verified by subsequent investigations. During our successive visits to Shetland, which were undertaken mainly with the view of examining the glacial phenomena of the group, we were induced to pay close attention to the distribution and geological structure of the Old Red Sandstone rocks, on account of the important bearing which they have on the ice-carry during the glacial period. A brief sketch of the develop- ment of the contemporaneous and intrusive igneous rocks was given in the paper which we communicated to the Geological Society in 1879.|| But since that paper was read we have twice visited the islands in the course of our holiday rambles, in order to work out in greater detail the volcanic history of that period. Our last visit was specially devoted to the investigation of an interesting series of rhyolites, which have not hitherto been described, though at certain localities they have a remarkable development. A large number of microscopic sections have been prepared and examined, while detailed chemical analyses of the typical volcanic rocks have been made for us by our friend Mr RR. R. Tatrock, F.R.S.E., one of the public analysts for Glasgow. We now propose to lay the results of these investigations before the Society. * Hispert’s Shetland Isles, pp. 341, 474, 484, 491. Tt Mem. Wernerian Soc., vol i. p. 162. t Mineralog. Mag., vol. ii. pp. 160, 170 et seg., 253 ; vol. iii. p. 32. § Trans. Edin. Roy. Soc., vol. xxvii. p. 345. || Quart, Jour. Geol. Soc., vol. xxxv. p. 786. OLD RED SANDSTONE VOLCANIC ROCKS OF SHETLAND. 361 I. GEOLOGICAL STRUCTURE OF THE VOLCANIC Rocks. The records of volcanic activity are mainly confined to the west and north- west portions of the Mainland and the islands adjoining the western seaboard. They may be grouped in two divisions,—first, the contemporaneous igneous rocks, comprising the lavas and tuffs which were erupted and spread over the sea-floor during the accumulation of the sedimentary deposits ; second, the in- trusive igneous rocks, which were injected at a later date, probably towards the close of the Old Red Sandstone period in Shetland. The result of the chemical analysis of typical examples of these divisions clearly proves that the former belongs wholly to the basic series, while the latter includes both acidic and basic rocks. A. Contemporaneous Lavas and Tuffs. Beginning first with the interbedded volcanic rocks, the best development of them is to be found in the south-west part of Northmavine, between Stenness: and the mouth of Rooeness Voe. No finer sections could be desired than those exposed along the storm-swept cliffs of the Grind of the Navir. Here and there the observer sees narrow “gios” which have been excavated in the tough lavas and ashes and occasionally a subterranean passage or tunnel, com- municating with the surface by a funnel-shaped aperture, from which, during storms, a column of spray issues with the advancing tide. The best examples of this latter phenomenon are to be seen at the “ Holes of Scraada.” The tract of ground occupied with this series of ancient lavas and tuffs measures about six miles in length from Stenness to Ockren Head. It is evi- dent, however, that they must originally have covered a larger area, from the isolated fragments which have escaped denudation, in the islet of Doorholm, and Esha Ness Skerry. In the southern part of this tract, between Stenness and Hamna Voe, the terrace-shaped features which are characteristic of vol- canic areas are so apparent, that the eye can easily follow the successive out- crops of the lavas and tuffs. This area is almost entirely occupied with contemporaneous volcanic rocks, there being but few intercalations of sedimen- tary deposits. Along the east side, between Rooeness Voe and Brei Wick, the lavas and tuffs are bounded by a great sheet of granite and quartz-felsite, which will be described in a subsequent page. On the south bank of Rooeness Voe, rather more than a mile from Ockren Head, the relation between the two is admirably exposed in a steep grassy “gyo.” At this locality the slagey por- phyrites, which form a cliff about 300 feet high, with a beautifully slicken-sided | surface, are brought into conjunction with the pink granitoid rock by a fault. Owing to the covering of peat, we were unable to trace this fault across the 362 B. N. PEACH AND J. HORNE ON THE peninsular tract. On the shores of St Magnus Bay at Brei Wick, the inter- bedded and intrusive igneous rocks are not found in such close proximity ; the junction between the two being concealed by a sandy beach. From the admirable coast sections there is little difficulty in determining the geological structure of the volcanic masses. They form a great syncline, the centre of which is occupied by a coarse volcanic breccia or tuff and from underneath this breccia there crops out a series of slaggy diabase-porphyrites, with occasional beds of red ashy sandstones and flags. Such is the general arrangement of the strata, though the succession is occasionally disturbed by faults of greater or less magnitude. The order of succession is best displayed in the cliffs bounding St Magnus Bay, and we shall therefore describe first of all the section between Brei Wick and Stenness. On the west side of Brei Wick Bay, which is the eastern limit of the interbedded volcanic rocks, the following section is visible. Fic. 1.—Section in Brei Wick Bay, Northmavine. At the east end of this section occurs a bed of coarse tuff (2), with bombs of porphyrite, averaging 6 inches across, which is succeeded by finer tuff (1); the strata forming a small synclinal fold. Towards the west they are under- laid by red sandstones (3), which are pierced by a mass of pink quartz-felsite (4), like the intrusive igneous rock to the east of Brei Wick. Fragments of the sandstones are seen adhering to the felsite, which have been slightly indurated — by the intrusive mass. On the west side of the felsitic intrusion, the sand- stones are repeated with a westerly dip, and they are succeeded by the beds of coarse and fine tuff already described. These are overlaid in turn by coarse ashy sandstones, in which masses of tuff are curiously intermingled with layers of sand in the same bed. Grey sandy flags rest on these ashy sandstones, which are abruptly truncated by a fault bringing in the porphyrites. For a short distance the order of succession is disturbed by intrusive dykes; but near Tang Wick Ness the lavas are seen dipping in a north-west direction. In the little bay beyond Tang Wick Ness a bed of dark purple diabase-por- phyrite passes underneath coarse volcanic breccia, containing blocks of schist and porphyrites ; the latter being most numerous. These included fragments of schist were doubtless derived from the sides of the old vents, and though we ~ cannot now point to the sites of the volcanic orifices, still the existence of these blocks of schist in the tuffs clearly indicates that they must have pierced the metamorphic rocks of the district. Not far to the west of this locality, pale slaggy porphyrites rest on dark purple lavas; the latter being overlaid near Stenness by coarse volcanic breccia, OLD RED SANDSTONE VOLCANIC ROCKS OF SHETLAND. 063 occupying the centre of the syncline. From Stenness northwards towards Hamna Voe this volcanic breccia is traceable, being inclined at a gentle angle to the south of east and on the west side of the synclinal fold the porphyrites reappear, with a gentle easterly dip. They occupy the strip of rising ground bordering the sea at the Grind of the Navir, and in this neighbourhood the terrace-shaped features are most characteristically developed. Along the coast- line, from Stenness to the Grind of the Navir, there is an excellent exposure of the successive lava flows with few intercalations of tuff. The numerous isolated stacks and the more distant islet of Doorholm, which are formed of the same materials, plainly indicate the great denudation which the contemporaneous volcanic rocks have undergone. A traverse along the south bank of Rooeness Voe confirms the general arrangement of the strata just described. The fault bounding the interbedded | Fic. 2.—Four successive lava flows overlaid by tuff. Ovkren Head, Rooeness Voe, Rooeness Hill cliff in the distance. series in Rooeness Voe, which has already been referred to, has not produced much effect on the inclination of the bedded masses. Fic, 5.—Generalised section across the Old Red Sandstone on the east side of Shetland, showing the position of the voleanic rocks in Bressay. 1, Schists of the Cliff Hills; 3, Brenista flags; 4, Rovey Head con- glomerates; 5, Lerwick sandstones: 6, flaggy series of Bressay and Noss; 7, volcanic rocks; J, faults. of volcanic activity are not confined to those materials which were accumu- lated simultaneously with the sediment on the sea floor. The phenomena con- nected with the intrusive igneous rocks furnish even more striking proofs of the display of volcanic energy which characterised that period. q B. Intrusive Igneous Rocks. These may be grouped in three divisions—(1) Sheets, (2) Dykes, (3) Necks. Of these divisions the first is the most important, as the sheets cover extensive areas in Northmavine and Sandsting on the Mainland, nearly the whole of Papa Stour, the greater portion of Meikle Rooe and a portion of the island of Vementry. An interesting feature connected with these intrusive sheets is the evidence which they furnish of the vast amount of denudation which has taken place since Old Red times. It is only by working out the physical relations of these intrusive masses that we can form an approximate idea of the extent of this denudation. By far the largest area occupied by these intrusive rocks is in Northmavine, where they extend from the northern headlands of the Mainland opposite Uya Island to Rooeness Voe and onwards to the Heads of Grocken, near Hills- wick. The isolated columns of the Drongs are composed of the same intrusive rocks and likewise the eastern part of Meikle Rooe and the northern portion of Vementry. It is highly probable that the masses just indicated, though now isolated from each other, once formed parts of the same intrusive sheet. Lithologically, as well as microscopically, the rocks bear a close resemblance to each other. The length of this sheet, when measured from its northern limits to Vementry, is about twenty miles, and its breadth in Northmavine varies from three to four miles. This mass is brought into conjunction with the OLD RED SANDSTONE VOLCANIC ROCKS OF SHETLAND. 369 metamorphic series at the Heads of Grocken by a fault, which is admirably seen on the shore. In Meikle Rooe the granite mass is also faulted against the older rocks, which consist mainly of diorite with occasional patches of mica schists. In all likelihood, the fault at the Heads of Grocken and in Meikle Rooe is merely the northern prolongation of the great north and south dislocation bounding the altered Old Red strata west of Weisdale. On the shores of Rooeness Voe, however, and northwards by the Biurgs, on the eastern seaboard of North- mavine, the granite spreads over the ancient crystalline rocks in the form of a great sheet, without deflecting the strike of the metamorphic series, and termin- ates along the eastern margin in a great escarpment 200 feet high. The North- Fic. 6.—Binary granite faulted against the ancient crystalline schists, Heads of Grocken, Northmavine. The Headlands of Stenness, and the Islet of Doorholm in the distance, formed of bedded lavas and tufts. Mavine mass consists mainly of a binary granite or aplite, composed of quartz and pink orthoclase felspar, shading occasionally into salmon-coloured quartz- felsite. Generally the rock is coarsely crystalline and highly siliceous, and there can be no doubt that the mass must have consolidated under great pressure, though the materials under which it lay buried have been wholly removed by denudation. The presence of so much silica has no doubt retarded the general denudation of the Rooeness plateau, but it has been ineffectual in preventing the waste caused by the sea. But apart from the coarsely crystalline character of the rock, the marked columnar structure suggests the idea that it is a great intrusive sheet which has consolidated underneath the surface. Those who wish to study this feature would do well to sail down Rooeness Voe or along the shores of St Magnus Bay from the Heads of Grocken to Brei Wick (see Sketch of Heads of Grocken, fig. 6). Along the cliffs the observer is confronted by symmetrical columns rising from the sea-level, which are tra- 370 B. N. PEACH AND J. HORNE ON THE versed by a series of vertical joints. Hence it follows that the vertical face of the cliff is preserved, though constantly assailed by the sea and subjected to continual recession by the removal of huge slices of rock. Frequently the columns are isolated and left to battle with the denuding agencies as_ best they may. The columns of the Drongs are beautiful relics of the Rooeness Hill sheet which have hitherto been able to resist complete demolition. We have already referred to the fact that the only place where this intru- sive mass is seen in contact with the interbedded volcanic rocks of North- mavine is on the south bank of Rooeness Voe, where the latter are thrown down by a fault against the former. We have therefore no indication of the thickness of strata which originally covered the plateau. But, from the columnar structure, the coarsely crystalline texture, from the manner in which it spreads over the metamorphic series like a great cake, we have come to the © conclusion that the Rooeness mass is an intrusive sheet which forced its way — Ww ; , Ockren Head Rooeness alee RooenessHit The Biurgs Skeal | " arate ZS ’ H NAVAN im ZLIEE 2 ay in j Y \ \ ZZ LZR DD B ea | Soe aces pe TT LT - Lie py, WV RGE ce oD Fic. 7.—Section across Northmavine from Ockren Head to Skea Ness. 1, Metamorphic rocks; 2, serpentine ; 3, granite and quartz-felsite ; 4, breccia of serpentine fragments ; 5, bedded porphyrite and tuff ; /, faults. upwards and laterally between the metamorphic strata on the one hand, and the members of the Old Red Sandstone on the other, at the time when the Main- land lay buried under tke deposits which accumulated during that period. It is right to state, however, that, so far as our observations went, there are no , beds underlying this igneous mass which could be referred to the Old Red Sandstone. At one locality, to the north of Colafirth Voe, a curious brecciated serpentinous mass occurs, which might, on further examination, prove to be a basal breccia of this age. Be this as it may, it is evident that the underlying platform consists mainly of diorite and various metamorphic rocks. The fore- — going conclusion is confirmed, as we shall presently point out, by an examina- tion of the relations which the Sandsting granite mass and the Papa Stour felsite bear to the Old Red strata. | The age of the granite mass of Sandsting is placed beyond doubt by a study of its relations to the altered Old Red strata of that district. It covers a triangular area, extending from Selie Voe to Gruting Voe. A\ a \ Direction of dip of strata. Hardened sandstone Rhyolite. Shingle, and flagstone. Fic. 12.—Ground Plan of rhyolite dykes intruded among Lower Old Red Sandstone strata, south-west shore of Papa Little, Shetland. of the beds; but we shall now point out that the same feature is observable in the dykes near Loch Skeld, about 3 miles from the bounding fault. In the Laxa Burn, to the south-west of Bixetter Voe, a dyke of rhyolite was observed, which, on the roadside near the cottage as well as in the burn below the road, merges into a crystalline granitoid rock with quartz, felspar and mica. Again, in the neighbourhood of Loch Skeld, near the granite boundary, we found typical examples where the dykes display fluxion structure as perfect as in Papa Little. The three preceding types of intrusive veins belong to the acidic series, and closely resemble each other in chemical composition, as may be seen at a glance VOL. XXXII. PART II. 30 376 B. N. PEACH AND J HORNE ON THE by referring to the table of chemical analyses appended to this paper. Nay further, it may be noted that the rhyolites are, so far as their chemical com- position is concerned, closely allied to the great intrusive sheets. Taking this important point into consideration, as well as their behaviour in the field, it is evident that the former are merely offshoots from the latter. We are inclined to believe that the rhyolites formed ducts leading in all probability to the sur- face, and that in these subterranean fissures the banded structure was originally developed. Had the molten matter reached the surface, it would have been ejected as highly acidic and glassy lava. When we come to describe the microscopic characters of these rocks, it will be seen that they have undergone considerable devitrification. But there is another series of dykes of a highly basic type, which have been injected through the great sheets of granite and quartz-felsite, and are therefore of a later date. This material is also met with in the form of bosses Fic. 13,—Diabase dykes traversing pink granite, north shore of Rooeness Voe, Northmavine, piercing the granitoid masses, as in the case of Skeld Hill in Sandsting. These rocks consist of diabase of a fine-grained character when occurring in the form of dykes, but very granular and coarsely crystalline when developed in bosses. The dykes are prominently developed on the Rooeness plateau, where they have been noted by Hispert and Dr HEDDLE, on the shores of Rooeness Voe, and on the cliffs of Meikle Rooe. At these localities they have a north and south trend ; and, owing to their dark colour, they form a striking contrast to the pink granite in which they occur. Sometimes, owing to rapid decay, they leave great clefts, indicating their course; sometimes they project abov: the general level of the acidic rock on either side. In the Sandsting granite mass we likewise noted several dykes of the same rock. In the burn neat Garder House, close to Selie Voe, several examples occur. The granite an OLD RED SANDSTONE VOLCANIC ROCKS OF SHETLAND. 377 felsite through which these diabase rocks are injected are occasionally very hornblendic, but not always so. Notwithstanding this feature, the boundary is clearly defined. On the Skeld Hill the boss of diabase has a well-marked boundary separating it from the granite which surrounds it. In this instance the granite is micaceous, with pink orthoclase felspar and quartz, the mica being very dark-coloured and abundant close to the basic rock. The diabase, on the other hand, hardly contains any quartz, and the felspar is only sparingly developed ; while the green mineral is very abundant. In a subse- quent paragraph we shall point out the resemblance in chemical composition, and, to a certain extent, in microscopic characters, between these basic intrusions and some of the diabase lavas. From the manner in which they traverse the intrusive sheets, there can be no doubt that they mark a later phase of volcanic activity, if, indeed, they do not mark the close of volcanic action in the Old Red Sandstone of Shetland. 3. Necks.—The occurrence of volcanic pipes of Old Red age in Shetland is another proof of the manifestation of volcanic activity which characterised that 5 « NIE I Tp UU — A) — SSS ro & Z | © 10 20 30 40 50 100 , ee ae P Wu, LANL SS eS ee a ighly incline 0. ; Sandstone Volcanic Porphyrite i+ peri calietnate: and ahales agglomerate. dyke. big. 14.—Plan of Volcanic Pipes or Necks on East Shore of Bressay. | . | period. Strange to say, they occur on the eastern seaboard of Shetland, where the interbedded volcanic materials hardly exist. So far as our observations a gone, no trace of these volcanic orifices is to be found in the western districts of the Mainland or the adjoining islands, where the igneous rocks are best developed. At the entrance to Noss Sound, on the south-east shore of Bressay, and also in the island of Noss, a series of necks is exposed. The vent in the island of Noss was noted by Dr HEpDLE in 1848,* though, so far as we are aware, no previous description of it has been given. The necks are arranged in a linear manner, and have evidently come to the surface along a line of fissure. * Mineralog. Mag., vol. ii. p. 253, oyrites LM 378 B. N. PEACH AND J. HORNE ON THE The beds surrounding the necks consist of red sandstones, which are much shattered and baked along the lines of junction with the agglomerate. They dip seawards (towards the east) at angles varying from 20° to 25°; but towards the edge of the fissure they are highly inclined. When the sandstones are followed inland, the alteration which is so apparent at the line of junction gradually disappears. As may -be seen from the accompanying ground plan (fig. 14), the outline of the vents is very irregular. The materials filling the vents consist of a coarse agglomerate, made up of angular fragments of sandstones, flags and shales, imbedded in a finely- comminuted paste. Occasionally large masses of the surrounding sandstones are enclosed in the agglomerate, which are highly crystalline. Besides these, there are masses of red calcareous and highly-baked mudstones, which have been torn from the sides of the vent. No bombs of porphyrite occur in the agoelomerate,—at least, none was observed by us. A vein of porphyrite a few inches thick is traceable along the margin of the orifice for a short distance, and coatings of a diabasic lava occur on the surfaces of the indurated sandstones. We also noticed a thin vein of copper pyrites traversing the agglomerate and the altered sandstones. Crossing the Noss Sound, another neck is visible, which resembles that just described in the nature of the material filling the vent and in its mode of — occurrence. Round the neck the gradual folding inwards of the flags near the edge of the agglomerate is worthy of note, as it forms a characteristic feature of the stratified rocks in immediate contact with the Carboniferous volcanic vents in central Scotland. From the nature of this volcanic agglomerate it is highly probable that no lavas were ejected from these orifices. It is more likely that they served mainly as blow-holes, discharging occasionally showers — of triturated materials derived from the sides of the vents. We shall now briefly summarise the succession of events as indicated by the volcanic phenomena described in the foregoing pages. ‘The earliest ejections — consisted of basic lavas and tuffs, which were spread over the sea-floor, and in — several instances were: intercalated with the ordinary sediment. In North- mavine the volcanic accumulations were nearly continuous, save towards the horizon of the lowest beds, where flagstones and ashy sandstones alternate with the lavas. In the Aithsting and Sandness district the ejections were limited to a few sheets of diabase and some bands of tuff, which are interbedded with a great succession of altered sandstones, flags and shales. The sheet of porphyrite in Melby Holm indicates a recurrence of volcanic activity, which became more pronounced as the conglomerates, sandstones and flags of Papa Stour were deposited. In the latter case the discharge of volcanic materials must have been intermittent. The band of tuff and the necks in Bressay OLD RED SANDSTONE VOLCANIC ROCKS OF SHETLAND. 379 indicate a sporadic outburst during the deposition of the flaggy series of Bressay and Noss. The discharge of these highly basic lavas and tuffs and the deposition of the associated sediment, were followed by the injection of three great sheets of highly acidic rocks. The relations of the sheet in Papa Stour to the basic rocks plainly show that the eruption of that mass was later than the ejection of the lavas. Similar evidence is supplied by the granite mass in Sandsting, and there is every probability that the great Rooeness plateau was erupted at a later date than the basic lavas of Northmavine. Numerous veins of granite, of quartz-felsite, and of rhyolite radiate from these intrusive sheets, which doubtless belong to the same period of intrusion. The last phase was characterised by the eruption of a series of highly basic rocks, consisting of diabase, which traverse alike the ancient crystalline rocks, the Old Red strata and the great intrusive sheets. II. Microscopic CHARACTERS. The microscopic examination of the bedded lavas proves that there is a con- siderable difference between the so-called porphyrites and the diabase rocks, which both occur in the series. A typical example of the former group, taken from the neighbourhood of Ockren Head in Rooeness Voe, shows that it is composed mainly of very minute columnar crystals of plagioclase felspar, which, as a rule, are much altered, and only occasionally show traces of the twin striation. Between these closely aggregated crystals there is a fine ground mass, and some of the minute interspaces are also occupied with a bright green decomposition product, which may be green earth. After the felspar, however, magnetite is the most abundant mineral,—so much so, indeed, that it might be grouped with the class of felspar-magnetite rocks described by Dr ArcuiBaLp GEIKIE in his paper on the “ Carboniferous Volcanic Rocks of the Basin of the Forth.” * The sections prepared from the lavas in the altered Old Red area, between Clouster and Aith Voes, show that plagioclase felspar is the chief constituent. Augite, however, is also present, though it is only occasionally recognisabie, by far the larger portion having been converted into chlorite. In one instance | where this alteration has been considerably developed the augite has a granular appearance ; but in other sections a few larger crystals of augite remain which are quite distinguishable. The magnetite, which is also largely distributed, has been converted to a great extent into limonite. This type is a true diabase, and were it not for the great alteration which has taken place in the pyroxenic mineral, it might be compared with some basaltic lavas of later paleeozoic age. * Trans. Roy. Soc. Edin., vol. xxix. p. 508. 380 B. N. PEACH AND J. HORNE ON THE There is one noteworthy feature connected with the sections prepared by us from the Shetland lavas, and that is the absence of olivine in recognisable forms. In this respect they differ from the diabase lava of the same age in Shapinshay, Orkney, which we detected in 1879. One of the sections from this locality shows that, in addition to the plagioclase felspar, there is much olivine distributed in crystals and crystalline grains, which, for the most part, has been converted into serpentine. Chlorite is also present, but the augite is hardly represented at all. The magnetite, which is very abundant, frequently envelopes the crystals of olivine either wholly or in part only. This type is very different from any we have met with in Shetland. It might be termed a felspar-diabase, rich in olivine and poor in augite. On referring to the table of analyses appended to this paper, it will be seen that of the two types—the one taken from the porphyrites in Northmavine, and the other from the diabase lava in Clouster Voe—the latter is the more basic. The proportion of silica in the porphyrite lava from Rooeness Voe is 51°82, while in the diabase from Clouster it is 48°36 per cent. The alumina in the former is 14:14, while in the latter it is 19°73 per cent. Another difference of some importance is in the relative quantities of magnesia: in the porphyrite lava it is 1°76, while in the diabase lava it amounts to 5:97 per cent. It would seem, therefore, that the diabase lavas from the altered Old Red area west of Weisdale were not only more basic originally, but the greater proportion of magnesia points to considerable alteration at a subsequent date. A section of volcanic ash from Dales Voe, Sandness, when examined micro- scopically is found to consist of angular and subangular quartz grains, with a few fragments of orthoclase and plagioclase felspar. It also contains fragments of felsite, and a rock exhibiting an ill-defined micro-crystalline structure re- sembling that of some of the devitrified rhyolites. A fine dusty felspathic substance separates the individual grains. It may be more convenient to describe here the microscopic characters of the intrusive diabase rocks, as they have close affinities both chemically and — microscopically with the interbedded lava just referred to. These affinities are all the more interesting when we remember that the respective eruptions of the two groups were separated by a considerable interval of time, during which highly acidic rocks were ejected. The microscopic characters of the diabase from the boss in Sandsting resemble those of the dykes in North- mavine, with this exception, that the former are more coarsely crystalline. The sections from the Skeld Hill show that the felspar crystals are much decomposed, but in some cases it is possible to determine that they are plagio- clase. Instead of presenting the usual clear faces, they have a dusty brown — appearance, which has almost obliterated their twin structure. It is observable that the triclinie felspars, though larger than in the interbedded lavas, do not OLD RED SANDSTONE VOLCANIC ROCKS OF SHETLAND. 381 form the main constituent. They are associated with a green fibrous mineral, which is largely represented, and has apparently replaced the augite. In one of the sections, the augite occupying the interspaces still occurs in forms which are recognisable; parts of the original crystals being quite fresh, while the remainder has been converted into chlorite and a yellowish green mineral which may be epidote. The unaltered portions show the characteristic play of colours with polarised light. A little magnetite is diffused through the sections, but to a much more limited extent than in the diabase lavas. It occupies quite a subordinate position compared with the felspar and the green chlorite mineral. We have already called attention to the fact that the boundary line between the diabase and the granite is well defined. A section of the granite from the junction contains triclinic felspars, clear quartz with fluid inclusions, and mica partially converted into a green decomposition product. Numerous specks of limonite occur, resulting from the hydration of the iron oxide. The rock associated with this in the same microscopic section is a diabase similar to those described. It contains no quartz, and the augite is faintly recognisable. The sections taken from the stream near Garder House, on the west bank of Selie Voe, are coarsely crystalline like those from Skeld Hill. The plagio- clase felspars are much kaolinised, and the pyroxenic mineral has undergone intense alteration. Compared with these, the sections taken from the dykes in Northmavine traversing the binary granite and felsite are exceedingly fine-grained. In one instance, the crystals of plagioclase are very fresh, and the interspaces between the crystals are filled with a bright green mineral, probably chlorite, there being no fresh traces of the original augitic constituent. Magnetite is not abundant, and small needles of apatite are disseminated through the mass. Another example taken from Rooeness Voe exhibits much granular augite along with the triclinic felspar, which has only undergone slight alteration. Magnetite is also present in very small grains. The chemical analysis of a typical example of the Skeld Hill rock proves that it is closely allied to the basic lavas; the proportion of silica being 50°58 per cent. The percentage of magnesia is even larger than in the two examples of the interbedded lavas, amounting to 8°90 per cent. This feature plainly indicates the great alteration which the pyroxenic mineral has undergone, and the consequent development of magnesian silicates. It is worthy of note that while the specific gravity of the bedded lavas is 2°7, that of the Skeld Hill rock is 2°9 per cent. The microscopic characters of the great intrusive sheets in Northmavine and Sandsting have many points in common. A section from the Heads of Grocken shows that the rock is coarsely crystalline, consisting essentially of red orthoclase and quartz. The felspar is much kaolinised; but in one instance 382 B. N. PEACH AND J. HORNE ON THE a crystal of orthoclase displays the Carlsbad type of twinning, polarising with different colours on different sides of the median line. The quartz occurs in erains and in crystals, clear and colourless, with numerous fluid inclusions. A small quantity of apatite is present in the section. There is no trace of any felsitic ground mass, and it is therefore evident that the rock most nearly approaches the character of a binary granite or aplite. Another section from the north bank of Rooeness Voe exhibits the same coarsely crystalline charac- ter as the preceding example; the felspar predominating over the quartz. Besides the orthoclase, which is also kaolinised, there is some microcline which, with polarised light, displays that peculiar rectangular arrangement of the striations traversing the mineral. Magnetite is also present, merging in some instances by hydration into limonite. The microscopic examination of sections taken from various localities throughout this mass only confirms the conclusion previously arrived at by Hispert and Dr Heppie. The rock is essentially granitic, but owing to the singular absence of mica over the greater portion of the sheet, it is different from the older granites in Shetland, represented by the masses at Dunrossness and Bixetter Voe. A section taken from near the margin of the Sandsting sheet in Gruting Voe contains much orthoclase which has been considerably kaolinised, large grains of quartz, and a little black mica. In short, it is a typical granite. Another specimen from the hills west of Skeld closely resembles the foregoing, with the addition of a small quantity of microcline. At Laxa Burn the rock consists of an admixture of red orthoclase and quartz. The rock occurring near the diabase on Skeld Hill shows, under the micro- scope, prisms of orthoclase and plagioclase ; the latter predominating, and less altered than the former. With these are associated clear quartz and dark mica, which are strongly dichroic. Needles and prisms of apatite occur abun- dantly in the section, while magnetite is also present along with some crystals | of sphene. A specimen, not far removed from the foregoing, exhibits a fair proportion of green hornblende, which is dichroic, along with biotite, the other constituents being the same. In the sections prepared from the Sandsting sheet no trace of a felsitic ground mass has been observed. The only note- worthy microscopic difference between the Sandsting and Rooeness sheets is in the development of mica and hornblende in the former mass. Far more interesting and exceptional are the microscopic characters of the Papa Stour sheet of pink or salmon-coloured felsite. Instead of presenting a marked crystalline aspect, it shows a felsitic ground mass of a reddish-brown colour, in which few felspar crystals are discernible. This ground mass is highly decomposed, and hence, even with a high power, it is impossible to define the fine granular constituent, as the base has little action on polarised light. The characteristic feature of the rock is the well-marked spherulitic OLD RED SANDSTONE VOLCANIC ROCKS OF SHETLAND, 383 structure which it presents under the microscope. A section prepared from the knobs of this rock, near the church, on the east side of the island, displays this spherular arrangement with singular beauty. The spherulites do not traverse the section in regular bands, but in wavy lines and in groups. No nucleus is observable in the centre of the spherules, nor are they enclosed by a periphery, as in the spherulitic glassy lavas of younger date. When magnified 120 diameters, some of these spherular developments exhibit very clearly the fine radial fibres diverging from a common centre, while others have lost all traces of these fibres. In the latter case they are supplanted by an exceedingly fine-grained ground mass, but the rude outlines of the original spherules are still visible. The ground mass is stained by minute ferruginous particles, resulting from the decomposition of iron pyrites. There are numerous small nests or cavities in the ground mass, filled chiefly with quartz of secondary origin and small crystals of orthoclase. Another section, taken from the cliff at the Horn of Papa, exhibits a similar spherular structure, though of a less perfect type. The divergent fibres are not so characteristically developed, and in the parts of the section where they are absent, the ground mass is more granular. The nests filled with secondary quartz do not form such a striking feature in this section ; but one large crystal of clear quartz, with fluid inclusions, occurs in the mass. Attention has been previously directed to the microscopic characters of this felsite by Dr ARcHIBALD GeErxKIE, who has pointed out the spherular group- ings of the constituents and the absence of any crystalline structure in the rock. From the evidence now adduced, we are inclined to believe that the felsite originally possessed a vitreous character, which has to a large extent disappeared through devitrification. In all likelihood the great alteration which the rock has experienced may have been partly coincident with, and partly subsequent to, this molecular change. If the vitreous material had reached the surface originally, it would have been ejected in the form of a glassy lava. The dykes radiating from the intrusive sheets present microscopic characters of a varied type. The coarse-grained aplites or binary granites are identical with the Northmavine and Sandsting sheets. A typical example occurs at Mavis Grind, in which the felspar is mainly orthoclase with some Carlsbad twins. Some microcline is also present, but the felspars have undergone con- siderable alteration. The quartz occurs in isolated crystals and in groups enclosed in the felspars. A number of sections of the quartz-felsites have been prepared, displaying very uniform characters. A typical example from Aith Ness, in Aithsting, shows a micro-crystalline ground mass of felsitic matter, with small crystals of orthoclase porphyritically developed. Quartz occurs in small | grains and nests, and magnetite is also present in minute grains. Another sec- . VOL. XXXII. PART II. 3 P 4 J84 B. N. PEACH AND J. HORNE ON THE tion from a dyke close by the former locality exhibits a similar ground mass, but more coarsely crystalline, which is traversed by veins of secondary quartz and lamin of chlorite, with magnetite grains more abundantly developed. All the’specimens have been much kaolinised. The rhyolites possess certain microscopic characters which readily distin- euish them from the preceding group. They exhibit fluxion structure of a more or less perfect type and possess a micro-crystalline base. In this base, erystals and grains of quartz and felspar are arranged in parallel but wavy lines, round which the felsitic matter curves in continuous streams. The parallel and wavy bands of felsitic matter vary considerably in density. Some of them are extremely fine-grained, parts of them remaining dark under crossed nicols. The coarser bands do not remain dark with crossed nicols, and with polarised light many of the particles exhibit the play of colours characteristic of quartz. It is evident, therefore, that much of the base of the coarser bands consists of minute grains of quartz. The felspar and quartz fre- quently exhibit rounded edges in the midst of the streams of devitrified mat- ter. Another feature of these ancient rhyolites is the absence of microlites in the ground mass, which are so characteristic of the younger vitreous rocks. A section (59 ¢) from the north-east corner of Papa Little exhibits most of the foregoing characters. The wavy bands of micro-felsitic matter are ad- mirably shown, along which are arranged lines of quartz and felspar, but not — continuously. Plagioclase is of less frequent occurrence than the orthoclase, and many of the quartz and felspar crystals have distinct rounded edges. A few crystals of iron pyrites occur in the section, which decompose into fine grains of limonite. A green dichroic mineral, probably hornblende, occurs in — one of the denser bands. There are also minute grains of viridite, which are evidently decomposition products. No microlites are observable in this section. In one section (2 e), taken from a dyke close by the foregoing instance, the bands of fine micro-felsitic matter enclose small oval-shaped masses of a — coarse-grained material otherwise similar in character to the surrounding base. The quartz is frequently elongated in the direction of the flow of the molten matter. Throughout the base there are abundant dark grains, probably opacite. The section (3 ¢) from the same neighbourhood possesses a very fine- grained and dense band of micro-felsitic matter, in which a prism of orthoclase lies obliquely across the direction of the flow, round which the stream of devitrified matter curves in continuous lines. With crossed nicols, this dense band exhibits patches which remain dark when the stage is rotated. The section from near Skeld,in Sandsting, close to the edge of the granite — mass, exhibits very distinct fluxion structure, but the micro-felsitic base con- OLD RED SANDSTONE VOLCANIC ROCKS OF SHETLAND. 385 tains hardly any crystals of quartz and felspar. The sections from Laxa Burn, near Sand Church, in Sandsting, display similar characters. From the foregoing descriptions it cannot be doubted that this well-marked fluxion structure is due to movement of the molten magma which originated in the fissures radiating from the intrusive sheets. The evidence seems to point to the conclusion that the materials originally existed in a glassy form, and that the rock when it consolidated was a rhyolite. Since that period a process of devitrification has been in operation, which has converted the glassy matrix into the micro-felsitic matter. The fact that only portions of the denser bands remain persistently dark under crossed nicols, while the coarser bands transmit the light, would seem to indicate that the devitrification has advanced so far as nearly to destroy all traces of the original glass. Nay more, in one instance (65 ¢), from near Aith Ness, in Aithsting, the fluxion structure is hardly traceable, save with polarised light. This section shows a crystalline felsitic ground mass, with occasional crystals of orthoclase and quartz; the iatter being minutely distributed in the ground mass, though much of it appears to be of secondary origin, filling cracks in the section. The whole mass has been much kaolinised, and is darkened by the presence of minute specks of ferrite. Indications of fluxion structure are observable in the neighbourhood of the isolated felspar crystals, but the rest of the ground mass has lost all trace of this structure. It seems reasonable to infer, there- fore, that this example displays an extreme type of devitrification, and that possibly many of the quartz-felsites belonging to the Old Red Sandstone forma- tion of Shetland may represent what originally were rhyolitic rocks, though all traces of the original structure have disappeared. We have been favoured with the following note from Professor RENARD, who has kindly examined the typical sections showing fluxion structure from Shetland :—‘‘ L’examen que jen ai fait a porté sur deux points: 1. Je crois qu il n’y a pas lieu de douter que les echantillons, spécialement les sections typifiques 2, 3, 5, 59, montrent avec beaucoup d’evidence une structure fluidale. 2. Je ne vois pas dinconvenient a’nommer cette roche rhyolite ancienne, et je crois en effet comme vous, que c’est une rhyolite dont la base s’est devitrifiée, et que ne contient guere d’elément vitreux apres les modifications auxquelles elle fut soumise. Sion admet cette maniere de voir, d’apres la classification que nous suivons sur le continent on la grouperait peut-étre parmi les /eszt pechsteine, mais cest la un terme de nomenclature sur laquelle il y a beaucoup a distinguer. Vous savez, mieux que je ne puis vous le dire, que les /elsit ’ pechsteine représente les rhyolites anciennes et apres tout lun nom vaut Yautre.” On referring to the table of chemical analyses, it will be seen that the members of the acidic series—both the intrusive sheets and the branching 386 B. N. PEACH AND J. HORNE ON THE veins—are closely allied to each other in chemical composition. The granites of Rooeness and Sandsting, the spherulitic felsite of Papa Stour, and the rhyolites of Papa Little, yield similar results. The percentage of silica in the Sandsting granite is 70°96, in the Papa Stour felsite 69:12, in the grey and pink varieties of rhyolite 73°70 and 72°32 respectively. There is no appreci- able difference in the other ingredients, save in the quantity of potash in the Papa Stour felsite, which amounts to 10°17 per cent. The specific gravity of the granites and rhyolites is 2°6, while that of the Papa Stour felsite is 2°5. In conclusion, we might thus briefly summarise the results of these inves- tigations. 1. The porphyrite and diabase lavas of Shetland belong to a basic series, and present microscopic characters akin to the great volcanic series of Lower Old Red Sandstone age in central Scotland. 2. The intrusive diabase dykes and bosses resemble the foregoing in chemi- cal composition and microscopic characters, though they are separated from each other by a considerable interval of time. . 3. The great intrusive sheets of Rooeness Hill and Sandsting consist of binary granite and ordinary micaceous granite respectively, while the Papa Stour sheet is composed of pink spherulitic felsite. The dykes of devitrified rhyolite, associated with the binary granites, closely resemble the granites and felsites in chemical composition, and hence the divergence in lithological and microscopic characters is due to the different conditions under which they con-— solidated. 4. The well-marked fluxion structure displayed by the rhyolites seems to indicate that they originally possessed a glassy ground mass, which has to a large extent disappeared through devitrification. 5. The mere presence of fluxion structure in igneous rocks does not by itself prove that the lavas were ejected at the surface, as the physical relations of the Shetland rhyolites clearly show that they are intrusive. Norr.—Our best thanks are due to Professor Renarp and Mr T. Davies for the assistance they kindly rendered in the microscopic examination of these rocks. OLD RED SANDSTONE VOLCANIC ROCKS OF SHETLAND. 387 City Awnatyst’s LABORATORY, 138 Bato Srrezt, Guascow, 22nd June 1881. ANALYSES of eight Specimens of Shetland Igneous Rocks received from J. Horne, on the 4th February 1881. 3a. : aby 2c, 3b, 3c. . : : pe Vari bun te eee ecu e eer: | oss | We. | Re ese | 28ss | ace Spewheces | 2@b | £25. | sae per cent. | per cent. | per cent. | per cent. | per cent. | per cent. | per cent. | per cent. Silica, . : : : ‘ 51°82 48-36 50°58 71°66 70°96 69°12 73°70 72°32 Alumina, . . : . 14:14 19°73 15°51 13°28 15:18 14°55 13°34 14-02 Peroxide of iron, . : ; 5°50 7-71 5°74 1:24 1:69 1:70 1:06 1-11 Protoxide of iron, : F 5°76 4:68 3°06 "10 | absent 14 14 ‘47 Bisulphide of iron, . . | absent | absent ‘45 | absent | absent | absent | absent | absent Oxide of manganese, . : ‘25 | trace 29 | absent | absent | absent ‘10 | trace Lime, . - : : ; 6°10 6°63 9°52 2°24 1°52 1:57 2°33 114 Magnesia, . : : 5 1°76 5:97 8:90 64 “70 52 1:24 48 Potash, : z ; : 7°81 2°57 85 4°84 4°68 10°17 5°05 7°44 Soda, . : : ; : 1:09 3°47 2°89 5°37 4:32 1:27 2°43 2°53 Phosphoric acid (Anhydride) ‘56 05 13 18 | trace 05 | trace trace Sulphuric acid, <5 : 05 | absent ‘08 | absent ‘ll 12 22 | absent Titanic acid, S . | absent | absent | absent | absent | absent | absent | absent | absent Carbonic acid, 55 F 4:05 ‘10 1-28 | absent | absent | absent | absent | absent Water of combination, : “91 53 “51 “30 66 67 27 “40 Moisture, . : - “20 20 21 15 18 “12 12 ‘09 100: 100° 100: 100° 100° 100° 100° 100° SPECIFIC GRAVITY, . : 2°743| 2°788*| 92-911* 2-609 2618 2540 2°652 2°621 * Mean specific gravity of three pieces. Ropert R. TATLocK. VOL. XXXII. PART II. 3Q 388 Fig. Fig. Fig. Fig. . Porphyrite, Rooeness Voe, Northmavine, showing minute columnar crystals of plagioclase fel- — . Diabase, Clouster Voe, Aithsting. A contemporaneous volcanic rock seen with polarised light, . Diabase, Skeld Hill, Sandsting. An intrusive rock seen with polarised light. This section . Rhyolite, Papa Little. An intrusive rock showing dense bands of micro-felsitic matter, with a . Rhyolite, Papa Little. An intrusive rock seen between crossed Nicol prisms, showing wavy . Spherulitic felsite, Papa Stour. An intrusive rock seen with polarised light, composed of reddish- . Felsite, Dales Voe, Sandness. An intrusive rock seen with polarised light, showing a fine . Binary granite or aplite, Heads of Grocken, Northmavine, seen with polarised light, consisting THE OLD RED SANDSTONE VOLCANIC ROCKS OF SHETLAND. EXPLANATION OF PLATES XLV. AND XLVI. spar, abundant magnetite, with a green decomposition product. A fine ground mass is interposed between the felspar crystals. This is a typical example of the porphyrite lavas of Old Red Sandstone age in Shetland (30 diameters). The crystals of plagioclase felspar are well preserved and abundant, the augite has been con- — verted to a large extent into chlorite. Magnetite is very abundant throughout the section (70 diameters). shows the marked distinction between the interbedded and intrusive diabase rocks. The plagioclase felspar crystals are larger than in the preceding section, but much decomposed. The augite has been largely replaced by a green fibrous mineral, but fresh crystals are recog- nisable in the section. Magnetite is also present (20 diameters). prism of orthoclase lying obliquely across the direction of the flow. This section exhibits” very perfect fluxion structure, the movement being from right to left (20 diameters). bands of micro-felsitic matter, which partly remain dark and partly transmit a faint light. Lines of quartz and felspar are arranged more or less parallel with the wavy bands of vitreous matter. The quartz is elongated in the direction of the flow (20 diameters). brown felsitic matter, arranged in well-marked spherules, in which the fine radial fibres are prominently developed. In some parts of the section the diverging fibres have been sup-. planted by a fine grained ground mass. Nests or cavities filled with a secondary quartz are visible. The ground mass is stained with minute ferruginous particles (70 diameters). felsitic ground mass, with large irregular grains of quartz containing fluid inclusions. Strings of quartz also traverse the section. A well-marked prism of orthoclase forms a prominent feature near the centre of the drawing, and minute grains of magnetite are evenly distributed through the mass (30 diameters). of-reddish-brown orthoclase, which is much kaolinised, and quartz with fluid inclusions ( y diameters). . Roy. Soc. Edin’ Vol. XXXII, Pl. ALV achle] F Huth, Lith” Edin® oy.Soc. Kdin* . Vol. XXX1i PL. XI F Huth, Lith’ din" ( 389 ) XXII.—Observations on a Green Sun and Associated Phenomena. By Professor C. Micuiz SmiruH. (Plate XLVILI.) (Read July 7, 1884.) The appearance of a green or blue sun, though not unknown, is of sufficiently rare occurrence to make a full investigation of all the phenomena connected with it highly desirable. I have therefore tried to obtain as accurate and complete information as possible concerning the appearance of a green sun in India during several days in September 1883.. The general features of the phenomena were well seen in Madras, and will probably be best described by my notes taken at the time. On September 9th the sun before setting assumed a peculiar silvery appearance, and its brightness was so much decreased that for about half an hour before sunset it could be observed with the naked eye. This was observed, I believe, though to a less extent, on the two days preceding, but I did not myself see it on these days. On September 10th, from 5.0 to 5.30 p.m., the sun could easily be looked at with the naked eye, yet the limbs were sharply defined. At 5.30 the sun entered a low bank of clouds, and did not fully reappear again, but a narrow strip seen through a rift in the cloud at 5.43 was coloured a bright pea green. Round Madras this colour had been seen in the morning, but in Madras itself _ clouds concealed the sun till it had risen to a considerable altitude. Of the | morning of the 11th I have no record, but in the evening the green colour was _ very brilliant, and was visible for more than half an hour, being preceded, as on the former night, by the silvery white appearance of the sun’s disc. On this _ evening a large sunspot about one foot long was so conspicuous an object that | it attracted the attention of even the most casual observers. | September 12th, at 12.35 a.m., the moon, which was near the horizon, appeared | apale green. Bright stars near the horizon showed the same tint. From 5.15 to 5.30 the clouds to the east were coloured reddish-brown. At 5.55 the sun rose with a yellowish-green colour, but was almost instantly lost in clouds. | It reappeared at 6.4, and was then of a bright green colour ; this colour rapidly got fainter, but was quite perceptible till 7 o'clock. In the afternoon, the phenomena of the previous nights were repeated, and the horizon being free from clouds, the actual sunset was observed. The entry in my notes is—‘‘6.3, the sunset as a greenish-yellow ball, cumulus, stratus, and nimbus clouds near the horizon, but moon fairly clear. Some blue sky, but hazy.” The change from green to greenish-yellow was evidently due to the great increase in the strength of the VOL. XXXII, PART IL. ve ae 390 PROFESSOR C. MICHIE SMITH ON OBSERVATIONS ON low-sun band close to the horizon, which left the strip of yellow between that — band and the rain-band by far the most prominent feature in the spectrum. September 13th.—In the early morning there was a good deal of distant light- ning. The sun rose of a bright golden yellow colour; no green was seen. In the afternoon there were slight showers. A most remarkable observation made this morning by Mr Pocson seems very difficult to explain, except by some form of auroral display. I give his notes in full :— “ September 12, 1883, 17" 0", Madras mean time.—The sky a most remarkably intense reddish-yellow, so unusually bright that I called up my ~ daughter Isis to witness it. A dark cloud bank from about east to south, and — the vivid light above uncommonly auroral in appearance; more so than anything I have seen here before. “At 17" 10", the red hue considerably diminished, and bright orange yellow the prevailing tint. The light quite bright enough to make notes by. “ At 17" 20", the dark blue-black stratum now from about north to east, and very near the horizon. Sky tolerably clear to about 20° altitude, but of a rich red tint, with bright yellow clouds above, beginning at about 30° and covering the east of the sky. “At 17" 30", all changed within the last four or five minutes, and writing now difficult without a lamp. A thick dark red stratum over the sunrise point, and everywhere else a very greenish-yellow. “At 17° 40", the low cloud stratum now sea-green. Light only enough © to write by with difficulty. “ At 17" 50", sun rising a bright yellowish-white, and otherwise nothing extraordinary, all unusual tints having disappeared with the sunrise.” September 14th.—Before sunrise the clouds were blue and grey, with patches of red. Clouds of all sorts,—cirrus, nimbus, stratus, cumulus, and mare’s tails. Two bright flashes of lightning about 5.30 a.m. In the evening there was a slight green tinge, and after sunset the sky was golden red till 6.50, while mercury seen through the red haze was twinkling strongly. September 15th.—The sun rose golden. In the evening the sunset was very fine ; in the west the colour was golden to orange yellow, in the east it was greenish; red clouds remained till 7.5; there were very brilliant red “ rayons de- crépuscule.” From September 15th to September 20th the sunrises and sunsets were very fine, with red and gold for more than half an hour before sunrise and after us September 21st.—Sunset normal. ; September 22nd.—The sun rose as a yellow ball, and showed distinct — yellow afterwards, From ten minutes before till sunset, the sun was greenish- yellow, but the sun was much brighter than on the 10th and 11th. ‘ September 23rd.—The sun rose very green. At 5.37 p.m. the sun appeared A GREEN SUN AND ASSOCIATED PHENOMENA. 391 from under clouds very green. Strong absorption in the red end of the spectrum to C, low-sun bands weak. 5.45, clouds greyish-purple. There was only one bank of clouds which was near the horizon; above this was a peculiar greyish haze. At 6.0 the clouds were of a marked purple colour; breaks near the horizon were reddish-brown. During the night there was a great deal of sheet lightning in the south. September 24th.—The sun rose bright yellow. The spectrum showed complete absorption up to B; the rain-band, a and 8 were very thick, and the low-sun bands less marked than usual. There was lightning all night, beginning in the south and working round tothe south-east. It consisted chiefly of sheet lightning, with occasional zigzag flashes, but no thunder; the stars were fairly clear except near the horizon. Saturn and the moon, when near the horizon, were both very dim. September 25th.—Sunrise golden green. In the afternoou the shadows cast on white paper were still quite pink, but the sunset was bright yellow. September 26th.—Much the same as yesterday. September 27th.—Before sunrise C, B, a, the rain-band and the dry-air band were very strong, but the dry-air band was less than half as dark as the rain- band. The sun rose golden red. The-spectrum showed signs of clearing up; glimpses of A could now be obtained. After dark there was very bright light- ning in the west—sheet lightning, with a good deal of zigzag, and at least one _ very fine specimen of a flash such as is obtained a | by discharging a Leyden jar through a spangled BOR ay ig | tube, the flash being broken upintoa number of : ee os ei _ detached pieces. During the day there were “ ! | slight local showers in parts of the town. | September 28th.—Spectrum still showed great absorption. Lightning at _ night. September 29th.—Absorption still very strong. After dark there was a | display of luminous clouds, specially towards the east. After 11 p.m. there | was very heavy rain, with much lightning and some thunder. | September 30th._Sunrise golden. The spectrum on the sun showed A | clearly, and was very thick. October 2nd.—In the morning from about seven to nine, there was a thunder- storm, in which the thunder was almost continuous for above an hour and a half; but though the storm was almost vertically overhead, hardly any lightning | was visible. Apparently the discharges were chiefly from cloud to cloud, and the thick layers of heavy clouds overhead shut out the flashes. The thunder was followed by heavy rain. The official Meteorological Report contains the following reference to this storm—‘The weather on the 2nd instant was decidedly remarkable; thunder in the morning; heavy rain at noon, exactly 392 PROFESSOR C. MICHIE SMITH ON OBSERVATIONS ON three inches being recorded by 1 p.M., and continuing less heavily, but stor till 10 p.m. The total rainfall for ie day was 4°88 inches.” To complete the description of the phenomena, I will now quote from the accounts of some reliable observers in other parts of the Presidency. The following is from the diary of the superintendent of the lighthouse at Muttum, in the south of Madras, for September 1883 :— “6th, 7th, 8th.—After sundown on these days there was a very peculiar saffron glare, which faded as it became dark. On 8th it was very marked. “9th (Sunday).—This day, from about 4 p.m., the sun became perfectly green, and could be looked at without any inconvenience. The saffron glare after sunset seen. The green appearance of the sun continued several days, both in the morning and the evening. “13th, 6.30 p.M.—A large meteor [? a fire-ball] passed from west to north- east. It burst three times and faded away. “15th.—There were observed on this day five clusters of spots on the sun ; the green tint has been lost, and the sun is of a natural colour. “22nd.—Sun again appeared of a very green colour, which continued every day up to the 28th.” The next account is from Bellary :— “ Sunday, 9th September.—Sun set as usual, but after sunset a lurid glare spread over the sky, the colour being red with mauve in it. [Another corre- spondent writes that.he thought the infantry lines were on fire. ] “ Monday, 10th. —Sun, both at rising and setting, emerald green. « Tuesday, 11th. —Again the same appearance both at rising and setting. “12th, 13th, 14th.—Emerald green at sunset. After this week no record.” From Coonoor, on the Nilgiris, more than 6000 feet above sea-level, I have the following notes from Mr J. F. Gri :— “Sunday week (9th) was remarkable chiefly for a persistent red glow, likened by many to the reflection of some great fire. Our sunsets have been — gorgeous for several days, always abounding in the peculiar pea-green tints. Last evening (20th) the eastern sky and the whole landscape showed a most lovely and unusual greenish glow. After sunset a few clouds in the east were tinted lilac. The more distant mountains stood out very distinct against the green—clear but somewhat deep—of the sky. All near trees and other objects at hand had a ‘scene-painty’ (chromium oxide suggested) green tint. Red predominated in the western sky on the many clouds; but there was an intensely luminous area of hardly yellowish light near where the sun had set, which must have continued an hour. The ‘shimmery’ appearance of the sum, and the ease with which it could be looked at during Monday to Thursday, were remarked everywhere. There has been a good deal of bright lightning seen at some distance over the plains on many days.” if A GREEN SUN AND ASSOCIATED PHENOMENA. 393 This is particularly interesting on account of its close resemblance to the description so often given of scenes in hill countries just before heavy rain. Mr MAntey’s observations at Ongole, which is the farthest north point at which satisfactory observations seem to have been made, have already been published in Nature, and need not be repeated here. The Spectrum. _ The observations on the spectrum were made partly with a direct vision spectroscope, with a lens in front of the slit (HILGER’s rain-band spectroscope), but chiefly with my zodiacal light spectroscope, which has a single large dense glass prism and a collimator three feet long. The great length of the collimator permits the use of a very wide slit, which was found to be a great advantage in this case. The only means of recording the positions of the lines is by reference to a reflected scale; and since all the lenses of the instrument are quartz, the focus of the observing telescope, and consequently of the scale also, has to be changed for different parts of the spectrum. This was found very inconvenient when it was necessary to take a number of readings in different parts of the _ spectrum in rapid succession. The positions of the bands cannot be considered as strictly accurate, but they cannot be far wrong, as they were fixed by refer- ence to known lines near them, and the scale values for the different parts of _ the spectrum were obtained by plotting the scale readings for known lines in terms of wave-lengths, and smoothing the curve. The main features of the _ spectrum taken on the sun when green were— (1) A very strong general absorption in the red end. (2) A great development of the “ rain-band” and of all other lines which are ascribed to the presence of water vapour in the atmosphere, more especially of the group C, of a, and of the band at W.L. 504. The absorption in the red end was of very varying intensity; but when the phenomenon was at its maximum phase it gradually crept up from about B till past C, as the sun sank towards the horizon. On the 12th, when the sun was within a few degrees of the horizon, the absorption was well marked up to | W.L. 621—i.¢., to beyond a, while at the violet end the visible spectrum ended at W.L. 428, or just beyond G. The lines A and a were never visible, even on the sun, when it was green, and even B could be made out with difficulty from half an hour before sunset | onwards ; and before it vanished it grew intensely prominent, with enormously | thick bands on the less refrangible side. The band C, on the more refrangible | side of C, became very broad and black, while the fine line between this and C remained thin and sharp, and C itself thickened out on the less refrangible side. The rain-band was stronger than I have ever before observed it on the plains ; 394 PROFESSOR C. MICHIE SMITH ON OBSERVATIONS ON and even with the dispersion produced by a single prism, at least eight lines could be measured in it, while many more were visible. The low-sun band was not very conspicuous; but this was partly due to contrast with the very strong rain-band. The line W.L. 568 at the more refrangible side of the low-sun band was very well marked, and the band itself seemed to consist of a series of equidistant lines. The apparently much ~ stronger absorption in the red than in the blue end was a very marked feature, which became still more conspicuous when a photograph of the blue end was examined. A photograph was taken on the evening of the 23rd September, when the sun was very green, and the visible spectrum extended between W.L. 645 and W.L. 410. Half of the slit was exposed for twenty seconds, and the other half for thirty-three seconds. Both gave good photographs, extending from about F to a distance beyond H, twice as great as the distance between F and H. This is very nearly the same length as I obtain under similar circumstances in ordinary weather, though not nearly so long as I obtained last summer at an altitude of 6000 feet. The lines were sharp and well defined, and contained no bands that were specially prominent, though some seemed darker than usual. I have, unfortunately, no means at present of making an accurate determination of these lines. The atmospheric band C was very strongly marked, and was decidedly more conspicuous than C itself. It was thick and dark even at an altitude of 60° or 70° in the middle of the day, and formed then, next to the — general absorption, the most characteristic feature of the spectrum. The contrast of the thin line between C and C’ with these lines was most interesting. Since the passing away of the abnormal conditions, I have made careful observations of the sunset spectrum with the same apparatus, and I find that ordinarily A and @ are clearly visible, as well as B, though at times they are strongly marked, and a good deal of shading is observable between them. C is much thinner, and the rain-band is less prominent than the low-sun band, which, however, does not now have the appearance of a number of fine lines. The nearest approach to the green sun spectrum was observed recently during © a severe thunderstorm, which was accompanied by a fall of about 14 inch of rain. A very similar though less intense spectrum can be observed almost any evening by taking advantage of the passage of a small thin cloud over the sun’s disc. Ifa lens is used in front of the slit of the spectroscope, the absorption due to the cloud will be seen as a band in the middle of the bright spectrum from the unclouded part of the sun; and, owing to the strong contrast, the details of the absorption will be well seen, just as in the case of a spectrum of a sunset. A GREEN SUN AND ASSOCIATED PHENOMENA. 395 Meteorological. My attention was first called to the peculiar state of the atmosphere on September 3rd, when making observations on atmospheric electricity. Observa- tions made at 10 a.m. on August 31st showed a normal but rather low electrification ; no observations were made on the 1st or 2nd September, the electrometer being out of order. On the 3rd, after the instrument had been carefully dried, observations were begun at 1.10 P.m., when the air potential was found to be negative, the electrometer readings varying from —28 to —17 divisions. By 2.45 it had become positive, amounting, however, to only +6, which was also the reading at 4.45. During the succeeding days numerous readings were taken, and these show a remarkable state of electrification (see Appendix A). The general results of the observations may be summed up thus :—In the early morning the potential of the air was positive ; it continued positive, but gradually decreased in strength till some time between 9 and 10 A.m., when it fell to zero, and then became negative. The strength of the negative charge varied greatly and with remarkable rapidity, and the maximum readings were obtained either just before or during strong gusts of wind. The negative charge continued till the sea breeze set in in the afternoon, when it became positive, and continued so all night, and in all cases, I believe, the change of sign coincided with a change in the direction of the wind. Very high readings were at times obtained; in one case the reading was —459 divisions of the scale (=about 1900 Daniell cells or 2100 volts) at about 5 feet above the ground, in bright sunshine with a clear sky, but with a gusty wind, which raised clouds of dust. At other times there would be scarcely a trace of electricity perceptible. In all cases in which the potential was negative it decreased with height, but when it was positive it increased with height. Another point worth noticing is that, when negative, the potential might vary very much, but with two exceptions (and these are a little doubtful) it did not change sign, as one finds so often in a thunderstorm. This state of affairs continued from September 3rd to September 6th. On the 7th the potential was positive all day, the day being cool and cloudy throughout. On the 8th it was negative for a short time; on the 9th it was again positive all day; jon the 10th, 11th, and 12th, it was as from the 8rd to the 6th; from the 13th |to the 19th it was normal, though on the last of these days it fell to zero jat 11 a.m. From the 20th to the 27th it was again abnormal,—positive till jabout 9.30 a.m., then negative and then positive again,—except on the 23rd, -\when the lowest reading obtained was zero. After the 27th the readings were jall positive. It will be observed that all the negative readings were obtained when the 396 PROFESSOR (C. MICHIE SMITH ON OBSERVATIONS ON wind was westerly, and after the day had so far advanced that the ground had begun to grow hot. This westerly wind is a hot land-wind, and on a previous” occasion I obtained negative readings during its prevalence (Proc. Roy. Soc. Edin., vol. ix. p. 615), but then there were local showers a few hours afterwards. Thinking at the time that this was probably a similar case, I wrote a note to the local papers on the 6th, asking particulars of the weather within a radius of © 100 miles of Madras, especially with reference to rain, thunder, and lightning, and wind direction between the Ist and 6th of the month. In reply to this I got information from various stations which was of considerable interest, but apparently no rain fell within 100 miles of Madras up to the 6th, but on that day there were a few showers in and around Madras (0°03 inches at Madras Observatory). On the same day there was a storm at Tindivanum, about 75 miles south of Madras, which is thus described by a correspondent :—* At about 3 p.m. on the 6th a severe storm passed over this place, direction west by a little south to east by a little north. Wind preceded rain by a quarter of an hour, and blew steadily (not in gusts) for an hour ; velocity not known, but must — have been very great..... Rain fell in torrents from 3.15 to 3.45, and from this time till 6 p.m. it continued to drizzle. There was only one clap of thunder, which lasted some two or three minutes, and seemed to roll on eastward; it took place about 3.30. This seemed to break the violence of the storm. .... a Of this storm, which seems to have been very violent and local, I received another account from a gentleman who passed through it in the train, and who stated that the storm was such as he had seldom, if ever, experienced before. From Canajore in Mysore I received the following :—“..... Here, 6 miles” from the Western Ghauts, altitude 3100 feet, the weather during the first week of this month was abnormally wet. The average rainfall for September is about 12 inches, but between the Ist and the 9th I gauged 18-04 inches, the aggregate on the 6th, 7th, and 8th being 10°85 inches. No thunder.” From the Koondahs, near Coonoor on the Nilgiris, another correspondent reports that he was awakened about 4 a.m. on the 9th by a terrific gale, which lasted for only about half an hour, and passed off as suddenly as it began. The reports show an abnormal state of the atmosphere, which tended to give rise to — local disturbances. This abnormal condition is also shown in a report from — Kodaikanal, on the Pulney Hills, kindly sent me by Mr Levinas, who has kept a rainfall register since 1873. He writes—“There was the same peculiar colour of the sun at rising and setting here which was noticed in other places, and on the same dates as recorded in the newspapers. The atmosphere here all the time was very hazy. The only other remarkable events were that we had frosts in the beginning of September, which I never observed before at that time of the year. The rainfall for September was also the lowest I have any record of; it was as follows :—1st to 13th, none; 14th, 0°40; 15th, 135, A GREEN SUN AND ASSOCIATED PHENOMENA. 397 19th, 0-40 ;—total, 2°15 inches. [Average for September, 6°65 inches on thirteen days.| During the month we had no thunder or lightning. Early in the month the wind was from the north, which was unusual.” An examination of the daily weather reports for the month shows that in the earlier. part the “eneral weather” to the north was threatening or overcast, in the central parts of the Presidency it was fine with passing clouds, and in the south sultry. From about the 7th onwards for some days there are frequent reports of “ dust haze,” “sultry,” and “dark gloomy weather ” in the reports ; while, on the other hand, at two stations the report is, “atmosphere unusually clear.” The rainfall for September over the whole Presidency was much less than ‘usual. The average for fifteen stations for which reliable data are available is | 3°24 inches, instead of 6°90, the average for preceding years. The monsoon | rainfall, on the other hand, was much above the average for the same fifteen | stations. The rain at some stations continued into January, but taking only ‘the months of October, November, and December, the average rainfall was | 21°75 inches, while the average due for the same time is 17°36. This includes | Bellary, at which the fall was 11-90 inches below the average. | The barometric variations during the month also seem worth a careful study. Except for Madras, I have only the 10 a.m. readings, but these may | generally be taken as yielding a fairly accurate, though rather less smooth, barometric curve than that which would be obtained from the mean of the | corrected three daily observations. The accompanying diagram shows the / curves for Colombo, Madras, Belgaum, Allahabad, and Calcutta (Alipore). | The first point that strikes one on examining the curves is their strong general resemblance, showing the same causes at work in producing change of pressure over the whole area of India. We have first a minimum, which was on the | 6th at Colombo, Madras, and Allahabad, and on the 7th at Belgaum and Cal- | cutta, The delay at these two last places was exceptional, for out of ninety- three stations sending in reports only thirteen show a falling barometer on the 7th, and these are connected with small local areas of depression. The rise to a maximum is rather irregular, but it is reached for most stations on the 18th, and the report for the 19th shows a fall at every station except Sholapur and Moulmein. The fall continued till the 21st, when a rise took place at the great majority of stations. A third minimum falls on the 27th. Observations made with the black bulb solar radiation thermometer in vacuo and the grass mini- mum thermometer will be referred to further on, In any attempt to discover the cause of the phenomena observed it is of importance to determine exactly the dates at which they were first seen at different places. This, however, is a very difficult thing to do, inasmuch as most of those who have reported on the subject have been untrained in exact VOL. XXXII. PART II. 38 398 PROFESSOR C. MICHIE SMITH ON OBSERVATIONS ON observations, and in many cases have made more definite statements than their observations warranted. Thus, for example, I watched the sunset on the 9th, and certainly there was no trace of green in the silvery colour of the sun’s dise; yet several people in Madras told me that they had seen the sun set green on — that night ; but this was after they had seen the green sunsets on the following nights. I believe this is only an illustration of what happened in many cases, the peculiar sunset on the evening of the 9th was observed casually, then when people began to talk about the green sunsets of the 10th and 11th, the casual — observer recollected that he had seen something peculiar, and his imagination gave the silvery whiteness a green tinge. This has made me careful to sift as far as possible the various statements which I have received, and, though I cannot claim that the dates which I have accepted are im all cases absolutely accurate, I think that they come very near the truth. The general result of my investigation into the dates of occurrence of the — phenomenon is, that in Ceylon, in the south part of the Madras Presidency, and at Ongole, in the north, the sun first appeared green on the evening of the 9th, and that over the rest of the Presidency, where seen at all, it was first seen on the morning of the 10th. At Belgaum it is reported to have appeared on the 8th, and if this is accurate it isthe earliest date on which it was seen anywhere in India, and would at once negative the idea of a gradual propagation either from south to north or from east to west. I have no good reason to doubt the accuracy of my Belgaum correspondent, but as no notes seem to have been taken at the time, it is possible that he is not strictly correct. Beyond India I have two reports from ships at sea—one from the captain of the “ Cleomene,” who reports that there was a green sun and moon on the 9th, 10th, and 11th, when his position was from lat. 8° N. to lat. 16° N., and from long. 83° 30’ E. to long. 88° 40° E. In the same letter he reports that his ship was struck with lightning on the Ist. The other report is from the chief officer of the ss. “Pelican,” who has given me the following extract from his log :—‘‘ September 10th—The sun rose this morning looking quite green; never saw the like before. Last evening the sky had a greenish haze, making the moon lock sickly pale green, and a few peculiar black clouds like wisps or mare’s tails. Light breeze from S. to S.W. with high S.E. swell. Position at noon, lat. 10° 4° N., long. 64° 12° E. It was preceded by squally weather, with strong 8.W. wind and very damp weather ;—heavy dews at night.” Thus at two places—Madras and the position of the “ Pelican”—more than 1000 miles apart, the phenomenon appeared simultaneously, while to the south and east it appeared on the previous day. At Ongole, lat. 15° 30° N., long. 80° 8’ E., Mr Manpey saw the green sun on the 10th, and was informed that it had been seen on the 9th by one whose evidence he thinks entirely satisfactory. I have no information to show that the green sun was seen at A GREEN SUN AND ASSOCIATED PHENOMENA. 399 any stations farther north except Vizagapatam, Rajamundry, and Simla, and unfortunately I cannot obtain the dates at which it was seen at these places. At Bombay it cannot have been at all conspicuous, for though noticed by some persons it was not seen at the Observatory, and so I cannot obtain any accurate details as to the date of first appearance, &c. Beyond India we have several dates which seem to be fixed with considerable certainty. In Honolulu, on September 5th, the sun’s disc before setting was seen to be green (Nature, vol. xxix. p. 549). On September 4th, at 5 p.m., the master of the “Jennie Walker” “noticed the strange appearance of the sun, which was greenish.” The ship’s position then was long. 155° 28’ W., lat. 8° 20’ N. A passenger travelling from San Francisco to Sydney, three days out from Honolulu, writes: —“On Wednesday, September 5th, we witnessed a most curious phenomenon. The sun set perfectly blue, and next morning it rose a flaming ball of blue” (Nature, vol. xxix. p. 181). From Barinas, in Venezuela, we have a report that “on September 2nd, from daylight until noon, and from 3 p.m. to sundown, the sun appeared like a globe of burnished silver ; between noon and 38 o’clock it was of a bluish-green colour” (Nature, vol. xxix. p. 77). At Trinidad, on | September 2nd, the sun was observed as a blue globe at 5 o'clock (Nature, vol. xxviii. p. 577). It was seen at Panama on the 2nd and 3rd, and at Cape Coast Castle, apparently, on the Ist. All these dates refer to the first appear- ance, but we have a series referring to the second. Of these the earliest that I can find is in an extract from the log of the P. and O. s.s. “ Nizam,” with which Captain Harvey has favoured me :—‘“‘September 20th, in lat. 12° 50° N., long. 48° 26’ E., and the sun at the time being about 15° high, a greenish haze was noticed gathering over it and the sky generally in the west. As the sun decreased in altitude the green became more distinct, until a bank of green cloud, of various shades, formed on each side of the sun, and as the sun disappeared below the horizon so the cloud closed over the point of its setting. This peculiar sky lasted nearly an hour after sunset, and made a greenish twi- light most wonderful to look at. The light air blowing at the time was from the eastward, and the weather fine and clear.” On the 21st the same pheno- mena were observed, but not so clearly, owing to the ship’s proximity to Socotra, “the wind at this time was 8.S.W. and the air moist.” The entry for the following day is also of interest. “September 22nd, in lat. 12° 00’ N., long. 58° 00’ E., the S.W. monsoon blowing fresh in this position and the sky cloudy, but there was unmistakably a greenish tinge in the west at sunset, From this date until September 25th the weather was overcast and cloudy, so that no observations were made; but in lat. 8° 50’ N., long. 71° E., the sun was again observed to set with a green tinge over it. The weather at this time was fine and clear, with a light northerly wind.” At almost all stations in South India the greenness reappeared on the 22nd. Finally, we have the letter from 400 PROFESSOR C. MICHIE SMITH ON OBSERVATIONS ON Hicks Pasna, dated Duem, September 24th-—“ To-day, when it [the sun] rose it was of a pale green colour.” There is no proof, of course, that this is the date of its first appearance in the Soudan, but if the green was nearly as brilliant there as it was here, it could not have escaped observation. Before discussing the causes of the phenomena that have been described, © it will be well to point out that we must distinctly separate the green sun and the sunsets that appeared along with it from the remarkable sunsets which occurred nearly all over the world some time later, and which were visible here till at least the end of April. My reasons for making this separation are —1. The general appearance was quite different in the two cases. The sunsets accompanying the green sun were peculiarly lurid, and were, so far as I could judge, simply an exaggerated form of what we usually have some time before the bursting of the monsoon, and round the horizon we had then a most decided fog, in which stars were lost some time before setting. The main features of the subsequent sunsets, on the other hand, were the delicacy of the colours, and the beautiful rosy afterglow reflected apparently from very light — cirrus clouds high up. The horizon at this time was remarkably clear, as is shown by the circumstance that Mr Pocson was able to make accurate measure- ments of the faint comet “Ross” within less than 5° of the horizon. 2. The spectrum was totally different in the two cases, for in the latter case the red end was very free from general absorption A, @, and B standing out clear and sharp, while the rain-band was slight, or altogether wanting, and the low-sur bands were strong-—a complete contrast to what I have described as being visible in the former case. I may add, that any increase in the strength of the rain-band has been accompanied by a decrease in the brilliance of the after. glow. : To account for the green sun, three hypotheses have been put for- ward— 1. That it was due to vapours or dust from the volcanic eruption at Krakatao. First suggested by Mr Pogson. ( 2. That the cause was the presence of an abnormal amount of aqueous vapour. An explanation which I offered at the time of the occurrence. 3. That it was caused by a cloud of meteoric dust. Mr Lockyer has taken up the first of these theories, and starting with the assumption that the sunset effects were due to the same cause as the green sun, has attempted to trace the general propagation of the dust round the earth. His first line passes through Mauritius, the Sechelles, Cape Coast Castle, Brazil, Trinidad, Panama, and Honolulu. His second is a line passing from south to north through India. Taking the dates of the appearance of the phenomena which can be relied on, we find that they would require approxi mately the following velocities of propagation— A GREEN SUN AND ASSOCIATED PHENOMENA. 401 Krakatao to Mauritius, é ; ; . 161 miles per hour. a Cape Coast Castle, . E : ; a! “ " Trinidad, . ; : ' : . 74 ix a Near Honolulu, lat. 8° 21’ N., long. 155° 28’ E., 85 is These are the velocities if we assume that the column of dust was sent up by the great explosion which took place between 8 A.M. and 9 A.M. on the 27th; and even the plutonists seem to hesitate to affirm that the violence of the | previous explosions was sufficient to send the dust up to the required height, though the first great shower of dust must have been ejected some time | previous to that hour. When we consider that, from the nature of the case, the deduced velocities can only be very rough approximations, being in each case the minimum value, it must be admitted that the more distant ones agree fairly | well with each other. Here, however, we are met by two difficulties, viz., is _ there any reason to believe in the existence of an upper current moving with _ anything like the requisite velocity? and, if it moved so fast along the one | track, how was it so long of reaching Southern India? Regarding the first of | these difficulties, it seems absolutely certain that no such uniformly strong currents exist, at least at any altitude to which the dust could possibly have been projected. Mr Locxyrr attempts to overcome the second difficulty by | assuming an upper current from east to west, nearly along the equator. It | crossed to the north however to reach Cape Coast Castle and Trinidad—and | an under current from south to north. If, however, Mr MANLEY’s observations | are accurate, as there seems every reason to believe they are, it appeared at | Ongole as soon as in Colombo, and at least twelve hours sooner than in Madras; and, if the Belgaum observations are accurate, it appeared there a day | before it was seen in Colombo. Taking, however, only those observations about | which there can be no doubt we get the following velocities, taking the shortest lines between Krakatao and the various stations :— To Colombo, : . 2000 miles, 6-7 miles per hour. ee vindiras. . ' Be een mere oF 3, Bellary, ». : ‘ eZ. once oO 0s Lat. 10° 4’ N., long. 64° 12’, 3100 ,, 98 Ps velocities increasing with the distance from the source. Taking these along with the Japan observations, which require a velocity of over 40 miles per hour, it seems very difficult to believe that dust would have travelled in these different directions with such very different velocities. Finally, we have the negative evidence, which in this case seems to have some weight, that the first rain which fell after the appearance of the green sun contained no volcanic dust. I collected several gallons of the rain which fell on the night of the 29th, and had the sediment which it contained carefully 402 PROFESSOR C. MICHIE SMITH ON OBSERVATIONS ON examined under the microscope by Dr T. K. Rocrrs, a skilled chemist, but no — trace of volcanic matter could be detected in it. Ido not suppose that the — asserted discovery of volcanic ejecta in rain and snow in Europe will be allowed to have much weight in the decision of the question, since, even if the volcanic nature of the materials found is proved, it still remains an open question where they came from. With regard to the water vapour theory, there is at least some definite evidence upon which to found an argument. The spectroscopic evidence detailed above shows that all the prominent lines in the spectrum which are due to the presence of aqueous vapour were stronger than usual, and that there was, in addition, a strong general absorption in the red. This general absorp- tion might doubtless be produced by the presence of dust of a suitable fineness suspended in the air, but that it may also be produced by water vapour, or at least by clouds, is amply proved by observations which I have since made on several occasions. In a recent thunderstorm, to which I have referred above, and which was predicted spectroscopically forty hours before it developed, I found almost exactly the same spectrum as in the case of the green sun, but — the absorption in this case was produced by the passage of the sunlight through — a comparatively thin stratum of dense cloud, instead of through a fairly trans- parent atmosphere. We know, too, that the absorption produced by aqueous — vapour in certain conditions is capable of producing the observed appearance. On this point we have the observations made by Mr Lockyer, confirmed by — other observers, of the sun being seen green through the steam escaping from the funnel of a steamboat, and his further observation of a green sun seen through a mist on the Simplon. We have also an observation made by Professor Prazzt Smyta (Edinburgh Astronomical Observations, vol. xiv. Appendix, p. 29), represented in a plate of which the following description is” given :—‘“ Two eye views of varieties of daylight, whereof the first represents a remarkable case of the sun looking blue rather than yellow, red, or the colours usually given to it by extra thickness of atmosphere; and the second shows a peculiarly green sunset sky—both of them proving to be forerunners of the sirocco’s stifling wind and its concluding warm rain.” The spectrum of the cloud light on this occasion shows a strong similarity to the spectrum observed here, only the absorption in the red end is less, and in the blue end rather more strongly marked. For my own part, I do not believe that a more or less green sunset is so rare an occurrence as has been supposed, and since my attention has been called to it, I have seen it several times and very markedly on the 13th and 14th of May, when it was perhaps the earliest symptom of the coming monsoon. The abundance of water vapour present is also shown by the very heavy monsoon which followed the appearance under discussion, when in Madras A GREEN SUN AND ASSOCIATED PHENOMENA. 403 itself the rainfall was 19°17 inches, and in Masulipatam 15°71 inches above the average. We see then that aqueous vapour was present in large quantities, and that the presence of aqueous vapour is sufficient to account for the phenomena, so that it seems unscientific to call in the aid of any other agents, such as dust or sulphurous vapours, unless their actual presence can be proved, which, I submit, has not yet been done. Assuming then that the cause was aqueous vapour, the farther question arises, Why the phenomena should not be ' more frequently observed? This question cannot perhaps be fully answered at _ present, but some light can, I think, be thrown upon it by the following con- _ siderations:—In most cases, where we have an excessive amount of vapour present in the atmosphere, part at least is condensed into clouds, and these _ even when light, form a screen near the horizon which shuts out the sun at the | time when the greenness would be observed. In the present case, on the other _ hand, the vapour was almost entirely uncondensed, only a very light haze being _ observed, and a few clouds low down on the horizon. The vapour was also at _ a greater height than usual, and was probably diffused through a great depth of | the air; while in India, at least, the meteorological conditions near the surface _ of the ground prevented the formation of low clouds. An interesting question arises as to whether electrical action may not have had something to do with this distribution of moisture. The observations _ already described, both those made with the electrometer and those made on | lightning, show that the air was very highly charged with electricity. I am ' not prepared to lay much stress on the electrometer observations, however, until I have had an opportunity of investigating more fully the ordinary state _ of the atmosphere during the prevalence of west and south-west winds. The | circumstance that the potential of the air was negative only when the wind was | westerly, and even then only when the surface of the ground was hot, seems | to indicate that the chief cause of the peculiar electrical state lay in the lower | parts of the atmosphere. At the same time, it seems well to record these electrical observations along with the other meteorological ones. Even neglecting the electrometer observations, we have still various indications of | an abnormal electrical state, for all the clouds that were formed about this time were evidently highly electrified, and the abundant displays of sheet lightning— which I ventured to say were not due to the reflection from distant storms— accompanied by occasional flashes of forked lightning, were indications of the great storm which burst on October 2nd, when the vapour had at length con- | densed into clouds. In this connection, it ought to be noticed that the storm of October 2nd was one in which the discharges took place almost entirely between cloud and cloud. Ido not know that there is sufficient experimental data to show whether or not highly electrified vapour would be less ready to condense into clouds than non-electrified vapour, but it seems probable that 404 PROFESSOR C. MICHIE SMITH ON OBSERVATIONS ON this would be the case. The experiments made by Dr OLIvEer Lopce (Nature, vol. xxix. p. 612) seem quite insufficient to found any theory upon, inasmuch as they deal simply with the effect produced on a mass of very fine particles of water in an enclosed space by a highly electrified point. The presence of abundance of vapour seems to be explained, naturally enough, by the setting in of the moist monsoon currents in the upper parts of the atmosphere; or at least by the conflict between the north-east and south- west monsoons, which was apparently begun by that time.* It is by no means impossible that the Krakatao eruption may have had some influence on the direction of these currents, for we have proof of the immense displacement of the air caused by the eruption in the barometric waves which were traced three times round the earth. Further, the ascent of a heated column of air and vapour over the volcano would tend to produce an area of low pressure round it, and thus to set up a cyclonic influx of air from other places, and it is quite possible that this influx is indicated in the oscillations of the barometer shown in the accompanying diagram, the sudden cessation of the cause of inflow after the eruptions ceased, causing a series of decreasing waves—direct and reflected. The eruption may also have had something to do with the electrical state of the air, for we know from observations made on the spot, that much electricity was generated by the eruption, and Professor PALMIERI’s observations show that the material ejected from Vesuvius is negatively electrified. A hypothesis connecting the phenomena with the eruption at Krakatao in this way would not be liable to the same difficulties regarding the velocity of propagation as one which involves the actual transport of dust, for the delay at one place relatively to another might be caused by the absence of a sufficient quantity of vapour. The theory which I have suggested would also account naturally for the second appearance of the green sun, the interval being due to one of the familiar lulls in the contest between the two monsoons. On the dust theory, it seems very difficult to account for this second appearance. At one time I was inclined to think that the theory which made the phenomena depend on cosmic dust was an extremely probable one, and that the dust formed nuclei, about which the vapour condensed in the manner shown by Mr Airxen. Various observations, however, seem to negative this. It seems hardly possible that vapour was condensed in any quantity, else the absorption of solar heat would have been considerable. Observations made with the black bulb thermometer im vacuum are not very satisfactory, yet when carefully made with the same instrument under similar circumstances, they have some value. The Madras observations show that the readings were above the average for the month, and that on the 28rd, one of the days of * See Mr Levine's remarks, ante, p. 396, and the extract from the log of the “ Nizam,” p. 399. ; A GREEN SUN AND ASSOCIATED PHENOMENA. 405 maximum greenness, 160°°7 was reached. ‘The mean for the month was 147°°3, against an average of 136°°5. The presence of either dust or condensed moisture in quantities sufficient to have produced the observed effect would, it seems certain, have intercepted the solar heat to a great extent, but vapour, on the other hand, probably would not. Admittedly the question of the absorption of radiant heat by aqueous vapour is still a moot one, but the recent experiments made by Professor M‘Grecor, by Professor Tarr’s new method, show conclusively that the absorption cannot be nearly so great as many people have supposed; and we find such an experienced meteorologist as Mr BLANForRD stating, as the most probable conclusion from meteorological observations, that “both air and vapour, as compared with other gaseous bodies, are moderately good absorbers of heat, and in nearly equal degree.”* The minimum temperatures, which are perhaps a safer guide to the transparency of the air, yield results similar to those of the black bulb thermometer ; and observations of double stars showed that the atmosphere was clearer and steadier than usual. We must therefore, I think, give up any theory involving the presence of sufficient dust to render the sun green. Whether or not the following sunset glows were due to the presence of dust I cannot discuss here, but I would point out that an amount of dust sufficient to produce these effects would probably not materially affect the transparency of the atmosphere. * Indian Meteorologist's Vade Mecum, part ii. p. 24. | APPENDIX. VOL. XXXII. PART It. oT 406 Date. Hour. Sept. 3 1.10 P. 5 2.45 Sept. 4 10.5 a | 10.10 ” to 10.17 i Noon i 1.10 Pp i 3.0 as 6.30 Sept. 5 5.50 a bs 9.0 x 10.0 ” 53 11.5 i 15 P. s Du) ‘ 2.10 os 3.15 5.0 ‘ 6.20 e 10.10 Sept. 6 6.0 a. bs 8.0 8 9.0 Fp 9.45 a. 10.5 3 10.10 : 1.10 P ( 9.5 ts to {210 3 2.20 + 4.20 ¥ | 6.15 Lt. S.W. Do. Fr. Sx E. it! We As: Very light. 10 31 PROFESSOR C. MICHIE SMITH ON OBSERVATIONS ON APPENDIX A. Electrometer. Remarks. Positive.| Neg. 28 ad | to VG 6 sie 136 to On roof. ih a Ground—wind in gusts with much dust flying; | 495 bright sun, ila e When wind light, R. B, 2. : 67 Very fine and bright. ue 11 Ground. 35 re Do. 5 bas Do. 5 a Roof—clear. on 2 Ground—bright. ~+-+ || onaee.|| oor. tL 72 Do. 86 - to Ground—dust flying. 122 325 Me } to Wind gusty. 368 2 40 Calm. 3 20 Bee 35 Cloudy. sve 1 Roof—wind going round to S.E. 12 Ate Ground. 10 03 Cloudy. 29 12 feet above ground—thin arts 2 Do.—starry, with light clouds. 5 Le spe |» o.—cloudy. a Le + 74 Ground—cloudy. 188 to Do.—just before slight dust-cloud. 432 ec 18 Steady. Sr 24 ie From window about 40 feet high—dust-storm, | 6< | 105 and a few drops of rain, followed by heavy] 1 06 J rain, 560 hate eeie ceased. This was followed by o one clap of thunder. R. B. 8. i Roof—followed almost immediately by a shower. Steady—dry. Date. Sept. 7 — : A GREEN SUN AND ASSOCIATED PHENOMENA. - 407 APPENDIX A.—continued. Electrometer. Hour. Wind. i ee | Remarks. Positive.) Neg. 6.0 a. Mod. W. | 25 ine Steady—cloudy and cool. Very light 9.0 { ae \ a Pe. Do. da 10.0 Lt. do, 16 aie Do. do. 11.30 Do. 15 aCe Do. do. 1.35 Bb Trace. ; 2.45 S.W. 15 Bs 6 A. Lt. W. 14 wis Roof—steady. 9.0 Do. i aie ey ic aia | Some clouds, but sun pretty bright. R. B. 5 to 6. 2.0 P. 5 $n |) 4,20 nee 146 ae Cloudy, apparent thunder cloud overhead. 6.15 S. fresh. 38 ies Rain at 7 P.M. 6.35 a. Lt. W. 32 dae Cool and cloudy. 8.10 Fresh. 16 Ste Steady. 9,0 Do. 14 fed R. B. 3 to 4. 0.0 Do. 16 ashe Thin clouds. For the rest of the day maximum 16, minimum 13. 5.40 a. | Lt. W. 16 sh Cloudy. 9.0 Do. 8 a3 10.0 Very light.| ... 21 Very little dust. 46 11.30 Light. si f to Do. 10 2.10 P, Calm. Grace}; «6. Cloudy. 5.10 Do. as 31 Do. a he 7 Ey \ hin clouds—very close and still. ; 6.104. | Light W. | 27 ag Steady. 9.0 Ss 8 Cee Roof. 9.10 ads 2 oF Ground. 9.30 one No | trace. 10.15 5 to oF ae to Cloudy, but hot. 10.22 23 1020 | | a | | p Bight clouds 12.354. | Lt. W.S.W.| 10 He Light haze. 5.30 Lt. W. 18 cbs 6.30 ag 23 ap R. B. 4 to 5. 10.15 to 10.45 3.507, | Lt SE. | 42 5.30 Lt. E. 56 143 i as to Ground—thin haze, and plenty of dust. 4 Roof. at 1.5 Pp. Do. Max. 60 at 5.45 a.m; min. 11 at 9.40 a. Do. Max. 60 at6p.m.; min. 47 at1.10P. No { observations in forenoon. Do. Max. 74 at 11.50 a.m.; min, 37 at 9 a.m. \ Cloudy. | Positive all day. Max. 66 at 2.30 p.; min. 8 408 PROFESSOR C. MICHIE SMITH ON OBSERVATIONS ON APPENDIX A.—continued. Electrometer. Date. Hour. Wind. ae Se Remarks. Positive.| Neg. Positive all day. Max. 78 at 310P.mM.; min. Pep 1 33 { trace at 11 a.m, Bright. | Sept. 20 6 A. Light W. | 63 38 + 9.0 sis 18 a Light clouds. R. B. 5. 5 9.55 at se 34 Cloudy. 53 11.55 Very Lt. E) 44 ae Clear. Sept. 21 6 A. Lt. W'ly. 29 sar Do. 35 OA: see Trace. 10.10 i 7 to Very Lt. W. 9to} 19 10.15 a 11.0 Ane No | trace. Hazy. 19 A 11.50 Light E. {i 34 +» 4.30 P. ots 49 Sept. 22 8 a. Light W. No | trace. ae 9.0 Ss ... | Trace. | Cloudy. 5 10.0 ae pak 4 5 11.0 ses No | trace. Ground. # wh siete 6 Vi Roof. “y ao at 4 Sus At 12 feet above ground. Positive all day, Max. 11 at 3.30 P., min. 0 at} Sept. 23 . 50 oe 3: { 10.20 a. Sept. 24 5.45 Light W. | 35 oe Fine—slight mist. a 9.0 .. 15 ce Hazy. os 9.50 axe oak 25 Ground—bright. ” aes bor 8 Roof. J 11.30 | LightE&. | 25 | ... | Lightning all night to S. and SE. Sept. 25}. 7.15 Light W. | 18 ie Cloudy and hazy. bs 9 Very Lt. 8 5a Hazy. 33 oF 9.55 Light W. ob to Cloudy. 27 a 11.45 Light E. to ar Sun very hot. Slightly negative between 9 and 10, but positive Sept. 26 at all other times. Thereafter no negative read- ; o is ih a ings were got except in storms ; but the read- ings have been low, except in stormy weather. A GREEN SUN AND ASSOCIATED PHENOMENA. 409 APPENDIX B. Rainfall for October, Difference fom November, and 3 Station. December. Average. Actual. | Average. | Above. Below. Vizagapatam, : : : 19°40 20°13 ae 0:73 Masulipatam, ; , ; 28°12 12°41 ere das Bellary, . : : : : 5°47 17:37 moe 11:90 Madras, . : : 48°21 29:04 Ilia ace Salem, : ; : ; 19°48 10°17 9°31 Wellington, : : : : 25°11 18-98 6:13 Coimbatore, ’ : ; : 15°73 9:92 581 Bs Trichinopoly, é : ! : 14°25 16:07 a 1:82 Negapatam, ‘ ; ; 32°48 31:27 1:21 Madura, . 5 : : p 22°57 16:01 6°56 Cochin, . 5 : 22°44 17:94 4:50 ao Mangalore, : : : 8-47 10°50 50 2°03 Mercara, . : ‘ : ‘ V2 10°58 6°63 Bangalore, : : : : 17°43 8°58 8°85 A Colombo, . : : ‘ : 29°82 31:43 aS 1-61 Average, . : : : F 21°75 17°36 4°39 APPENDIX C. Abstract of the Mean Meteorological Condition of Madras in September 1883, compared with the Average of past Years. Mean Value of 1883. Difference from Average. Reduced atmospheric pressure, . 29°791 0-017 above. 29:°774 Temperature of air, : : : 84°7 16 do. 83:1 Do. of evaporation, : : 76°6 0-6 do. 76:0 Percentage of humidity, : 68 | 5 below. 73 Greatest solar heat in vacuo, : : 147°3 10:8 above. 136°5 Maximum in shade, é : : 95°9 3°8 do. 92-1 Minimum in shade, : : : TS) 0-6 clo. 103 Do. on grass, ‘ : : 76:1 i) do: 74:4 Rainfall in inches on six days, . : 0°56 4:24 below. 4°80 Do. since January Ist on fifty-two days, 12°54 (AE) Glo 19°73 General direction of wind, : ; S. by W. | 2 points South. | S.W. by S. Daily velocity in miles, . ? 5 190 30 above. i. 160 Percentage of clear sky, . : F 40 4 do. 36 N. R. POGSON, Government Astronomer. MOL, XXXII, PART IT, 3 U Vol. XXXII. Pl. XLVIL September 1883. 18 COUR NOESS= je} 7X Jak (0) Wl SF 1gy Ie Roy. Soc. Edin* 20 al 19 17 16 IZ ASE aS ll Z tt | | T aie lay { | | t a Zz a2 @3 24 25 26 27 28 29 30 - Calentta, (blipore) = Seal ———— Colombo. — 8 Fi] al Ma fia PS eee AMM. ee Scale) (é. Allahabad 0-002. 22 23 24 25 26 27 18 19 20 21 Vertical Scale 1 div 34 5 30 28 29 em i ie 12 45 16 17 : F-Huth, Lith® Edin® GREEN SSP EG le RoUaVi ee Olk SieHGe @ ate) XXIII.—An Example of the Method of Deducing a Surface from a Plane Figure. By L. Cremona, LL.D. Edin., Hon. F.R.SS. Lond. and Edin., Professor of Mathematics in the University of Rome. (Read 21st April 1884.) Let there be given, in a plane z, six (fundamental) points 1, 2, 3, 4, 5, 6, of which neither any three lie in a right line, nor all in a conic ; and consider the six conics [1] = 23456, [2] = 13456, [3] = 12456, [4] = 12356, [5] = 12346, [6] = 12345, and the fifteen right lines 12, 18,.., 16, 28,.., 56. There is a pencil of cubics 1°23456 (curves of the third order, having a node at 1 and passing through the other fundamental points) ; their tangents at the common node form an involution, viz., they are harmonically conjugate with regard to two fixed rays. Five pairs of conjugate rays of this involution are already known; for instance, the line 12 and the conic [2] have conjugate | directions at the point 1, for, they make up a cubic 1723456. | Each other fundamental point is the centre of a like involution. And also on each conic [1], [2],..., and each line 12, 13,... points are coupled har- monically with regard to two fixed points. The involution on the conic /1] is cut by the pencil of rays through 1; for instance, the point 2 is conjugate to the second intersection of [1] with 12, &c. The involution on the line 12 is cut by the pencil of conics 3456; for instance, the points 12.34, 12.56 are conjugate, as 34 and 56 make up a conic through 3456; and the point 1 is con- jugate to the second meeting of 12 with the conic [2]; &c. The Jacobian of a linear twofold system (réseau) of cubics 123456 is a sextic K = (123456) having six nodes at the fundamental points. Since any réseau of cubics 123456 contains 1° a cubic 4== 1723456; 2° a cubic breaking up into a ray 7 through 1 and the conic [1]; 3° a cubic made up by the line 12 and a conic ¢ through 3456, &c.; we see immediately that the (sextic K) Jacobian of the réseau 1° has the same tangents as the cubic /£ at the common node 1; 2° and 3° passes through the intersections of 7 with [1], and the inter- sections of c with 12, &c. The Jacobians K form a linear threefold system of sextics (123456)’ MCN EN KY WK = 0, | therefore we have the following theorem : If six points 1, 2, 3, 4, 5, 6 are given in a plane 7z, as said above, we may VOL. XXXII. PART Il. 3X 412 DR L. CREMONA ON AN EXAMPLE OF THE construct a threefold linear system of sextics K = (123456), whose tangents at each of the six common nodes are coupled in involution, and which cut, also in involution, each of the six conics [1], [2],..and of the fifteen right lines 12,18,... Any sextic of this system is the Jacobian of a réseau of cubics 123456. Among these o’ cubics, there are o' curves possessing a cusp (stationary point), and the locus of the cusps is a curve 6 = (123456)‘ of the twelfth order, which touches each conic [1], [2],... and each line 12, 13, ... in two distinct points, and has (only) two distinct tangents at each quadruple point 1, 2,... : those points and these tangents being the double elements of the twenty-seven involutions mentioned above. Let us start now from the foregoing plane diagram, without any further — reference to its origin; and consider 7 as representative of a surface ® whose plane sections shall have the sextics K as their images.* We see at once that the order of ® is 12, for, two sextics K meet in (6.6—6.4=) 12 more points. Thus we get a (1, 1) correspondence between the points of 7 and those of ®; any point M on zw being common to ow?’ sextics K, it is the image of a point M’ on ®, in which the co? corresponding planes meet. But if M lies on one of the six conics [1], [2], .. or of the fifteen lines 12, 18, .. or infinitely near to one of the six points 1, 2,..., then all the o? sextics K passing through M contain also another common point M, , which is conjugate to M in one of the twenty- seven involutions. Therefore, in such case, M’ isa double point on ®: this surface has an infinite range of double points, whose locus, as easy to see, is constituted by twenty-seven right lines, having as their images on z the six fundamental points and the six conics and fifteen lines connecting them. If M falls at the intersection of 12, 34 viz., if it belongs to two involutions, it will have two conjugate points M, = (12) (56), M, = (84) (56); and the three points M M, M, will be common to ow’ sextics K corresponding to planes, whose point of intersection M’ (where the nodal lines of ® meet, which answer to 12, 34, 56) is consequently a treble point on ®. Thus, cur surface possesses forty-five treble points, in each of which three nodal lines meet. Let a cubic 123456 have a cusp M; then, every sextic (123456)’, which is the Jacobian of a réseau including that cubic, shall pass through M and touch there the tangent at the cusp. Hence the ’ sextics K through M will have the same tangent at this point. Accordingly the corresponding point M’ will be a double point on ® with coinciding tangent planes, viz., a cuspidal or stationary point. Thus we see that ® has a cuspidal curve, whose image on 7 is the locus of cusps of cubics 123456, viz., the curve © = (123456)* of the twelfth order. The order of the cuspidal curve on ® is (6.12—6.2.4=) 24. © * See Caroraui’s paper in Collectanea Math. in memoriam D. Chelini. METHOD OF DEDUCING A SURFACE FROM A PLANE FIGURE. 413 The class of ®, that is to say, the number of the tangent planes drawn through two arbitrary points in space, is equal to that of the intersections of the Jacobians of two linear twofold systems of sextics K. The Jacobian of such a system is of the order 3(6—1)=15, and passes 3.2—1=5 times through each fundamental point ; but the curve © is clearly included in the Jacobian, therefore, this latter will break up into a fixed curve, 9, and a variable one, being of the order 15-—12=3, and possessing the multiplicity 5-4=1 at the fundamental points. So the residual Jacobian is a cubic curve 123456. Two such curves meet in 9—6=3 more points ; hence the class of ® is 3. The surface ®, being of the twelfth order and third class, and having twenty-seven nodal right lines and a cuspidal curve of the twenty-fourth degree, is the reciprocal of the general cubic surface. It was very easy to foresee this conclusion, in accordance with the (1, 1) correspondence between any surface and its reciprocal. But I wished to give an instance of the method of deducing -a (unicursal) surface from a plane figure assumed as its representative. 3 ; Art. XX.—On the Philosophy of Language. By Emeritus Professor Buackig, E.R.S.E, XXI.—The Old Red Sandstone Volcanic Rocks of Shetland. By B. N. Peaon, Esq., ni F.R.S.E., and Jonn Horne, Esq., F.R.S.E. Read March 17, 1884. (Plates XXII. — Observations on a Green Sun and Associated Phenomena. By Professor C. Micute Smira, F.R.S.E. Read July 7, 1884. d XXIUL—An Example of the Method of Deducing a Surface from a Plane Figure. ‘Professor L, Cremona, LL.D. Edin., Hon. F.R.SS. Lond. and Edin., . The TRANSACTIONS of the Royau Sociery or EDINBURGH will in future Vol. | Bl yl GN Ue Read April 7, 1884, . XLV. and XLVI), Price to the Public. £029 Et we we OOoOocCc Co KrF OCOoOcorocococ]Se or (Plate XLVIL.), at the following reduced Prices :-— OOOO fC CCC aanqoodocoaco O'S. CO. Sto S519 So Out of Print. ct fo} lar) iy 2 Price to Fellows. t ooo oC KK Coco ocoodc ood ©. ©: OSGi “Oo FOS Aa AAaAnDD OOO FS Baonoe ao coooococoocooaco]o Vol. XXI. Part 3. 5). Parts’: XXII. Part 1. >) amt sj. baRbro, XXII. Part 1. 57 abn ey arbre: XXIV. Part 1. peak 2 Part 3. . Part 1. » Fart 2. XXVI. Part 1. yh ARAL: Dre Ay a erot a. », Part 4. XXVIII. Part 1. si eecines i aries Part 4.

PAGE XXIV.—Micrometrical Measures of Gaseous Spectra under High Dispersion. By C. Prazzt Suytu, F.R.S.E., and Astronomer-Royal for Scotland. Read June 16, 1884, (Plates XLVIII.-LXXVIIZ.), : F : . 415 XXV.—On Bipartite Functions. By Tuomas Muir, LL.D, Read February 16,1885, 461 —The 364 Unifilar Knots of Ten Crossings, Enumerated and Described. By __ Rev. Tuomas P. Kingman, M.A., F.R.S. Read July 20,1885, . . 483 Knots. Part Ill. By Professor Tarr. Read June 1 and July 20, 1885, (Plates LKXIX.-LX XXL), 493 A New Graphic Analysis of the Kinematics of Mechanisms. By Professor Rosert H. Smits, Mason College, Birmingham. Read January 19, 1885. (Plate LXXXIL), . : 4 ; : : P we BOT -The Visual, Grating and Glass-lens, Solar Spectrum (in 1884). By C. Prazzi _ Smyru, F.R.S.E., and Astronomer-Royal for Scotland. Read June 1, 1885. (Plates LXXXITI.-CXLIIL.), ? 3 : ‘ 3 og — Observations on the Recent Calcareous Formations of the Solomon Group made during 1882-84. By H. B. Guppy, M.B., F.G.S., Surgeon H.M.S. “ Lark.” Communicated by Jonny Murray, Esq. Read June 15, 1885. (Plates CXLIV., CXLV.), . an 2 : ; , : . 545 — Observations on Atmospheric Hlectricity. By Professor C. Micuin Smiru. Read June 1, 1885. (PlateCXLVIL), . : . 583 -Note on Ectocarpus. By Joun Ratrray, M.A., B.Sc., Scottish Marine Station, Granton, Edinburgh, . Communicated by Jonn Murray, Esq., Ph.D. Read February 2, 1885. (Plates CXLVII., CXLVIIL), i ; REY — Anatomy and Physiology of Patella vulgata, Part I, Anatomy. By R. J. Harvey Gipson, M.A. Communicated by Professor Hurpman, D.Sc. Read January 5 and July 20, 1885. (Plates CXLIX.-CLIIL), . cy OO XX! 'V.—Detached Theorems on Circulants. By Tuomas Muir, LL.D. Read May 4, rt, 1885, : : : : rie : , ; . > 639 .—On the Hessian. By Professor Curystat, Redd May 18, 1885, : . 645 - ee XXIV.—Micrometrical Measures of Gaseous Spectra under High Dispersion. APPENDICES. ~I for) Ord Go bo By C. Prazzt Smytu, F.R.S.E., and Astronomer-Royal for Scotland. (Plates XLVIII. to LX XVIII.) (Read 16th June 1884.) CONTENTS. PAGE INTRODUCTION, : 416 Part I.—The first Gas to 8 astednneay ia ade what Gpanttons? : : 4 ; + PAIS The Candle-Spectrum, or CH gas in Blow-pipe Flame, : : : ; . 419 The Spectrum plates employed here, .« : : é ; : . 420 Principles of Spectrum representation, ; : ; : ; : pel Maps of the CH Spectrum in Flame, . : : : ; : . 422 Advantages of Electric-lighted Gas- Vacuuin Tubes, ‘ ; E ‘ : . 424 A London objection to my testimony therein, : : ¢ ; ; . 425 Part IJ.—Citron and Green bands of CH in Vacuum Tubes, ‘ : ‘ : eA 7, Orange band of CH and effects of Pressure, . : : : ; : . 428 Blue and Violet bands of CH, . ; : ‘ : ; : : J 86431 Marsh Violet band of CH, : ‘ ; : : s = 432 Chemical Interpretation of the CH Spectrom, : ‘ : - ‘ . 432 Part II[].—The CO Spectrum, : ? : : : ‘ ; : : . 435 Statical differences, ! 2 F : ; ‘ : : : . 485 Green band of CO, : : d : . 5 ' : : » 4386 Its numerical explication, : : : ; ; ‘ : : . 488 Remaining bands of CO,. , : ; ‘ F : : : . 439 Part IV.—Elementary Gases, Subject 1,or H, . : : : : : : . 440 Elementary Gases, Subject 2, or O, . : : ; ; . : . 444 Elementary Gases, Subject 3,or N, . ; : ‘ ‘ ‘ : . 446 Part V.—Conceluding Noteson H,O,andN, . - : ‘ F : ‘ . 450 Appmnpix I. Professor Alexander 8. Herschel’s letter on the Green Band of CO and its explications (eventually condensed into Plate 31), . 454 Aprrenpix II. Professor Alexander 8. Herschel’s letter, on a theoretical point in Plate 31, a) 4D Apprmnpix ITI. Mr Charles F. Casella’s letters on the f aeae and Purification of some of his Vacuum Tubes, . F : ‘ : ; c : . 458 Apprnpix IV. Plates 1 to 31, as follows:— PLATES. XLVIII. 1 ; CH in Blow-pipe Flame, Orange band thereof, and Citron band, adapted to a 40-foot Spectrum length. " " Citron band continued and Green band. " " Green band continued and Blue band. " Violet band thereof. Sreessive methods of Incandescence tested by the D! and D? Sodium lines, on an enlarged scale. CH in Vacuum tubes, Citron band thereof, and Green band, adapted to a 40-foot Spec- trum length. " " Gren pang continued, Blue band, Violet band, and Marsh Violet and. VOL. XXXII. PART Ill. ai one 416 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF AprenpDIx IV. Plates—continued. PLATES. LV. 8 | CO in Vacuum tubes, Red band thereof, and Scarlet band, on a 40-foot Spectrum length. LVI. 9 " " Orange band and Yellow band, LVIL. 10 " " Yellow band and Citron band. LVIILI. 11 " " Green band thereof and Blue band. LIX. 12 " Indigo band and Violet band. LX. Uys |p Bl abet Vaouum tubes, Early Red, Red to Scarlet, region ; on a 40-foot Spectrum length. LXI. 14 " " Orange, Yellow, and Citron. LXII. 15 " " Citron to Green. LXIII. 16 " " Green, Glaucous, and Blue. LXIV. 17 " " Blue, Indigo, and Violet. LXV. 18 " " Violet continued. LXVI. 19 | O in Vacuum tubes, Ultra-Red, Red, and Scarlet, regions on a 40-foot Spectrum length. LXVII. 20 " " Orange and Yellow. LXVIII. 21 " " Citron to Green. LXIX. 22 " Glaucous to Violets LXX. 23 | N in Veouum tubes, Ultra-Red regions thereof, adapted to a 40-foot Spectrum length. LXXI. 24 " " Ultra Red, Red, and Scarlet. LXXIL. 25 " " Yellow and Citron. LXXIII. 26 " " Citron and Green. LXXIV. 27 " " Glaucous and Blue. LXXV. 28 " " Blue and Indigo. LXXVI. 29 " " Violet ; all the above Plates have scales in terms of Wave-number per British Inch. LXXVII. 30 | Folding Index Map of all the above, and some other, gases, at both high and low tempera- ; 5 tures, and throughout the visible Spectrum, but greatly reduced in scale. LXXVIII. 31 | Folding plate of Green CO's extra-green-CH portion ; full size of original record, viz., for a 120-foot Spectrum length, with explication of its double arithmetical series. AprEnDiIx V. On the numerical Wave-number Spectrum Scale adopted here. INTRODUCTION. After the Royal Society, Edinburgh, had been pleased in 1880 to accept and print my paper on the general appearance of Gaseous spectra as seen on a very small scale, but complete on that scale from one end to the other of the visible spectrum, I was desirous to present them with some very highly Dispersed and much magnified views of the more interesting and probably crucial por- tions of the most important of those spectra. 4 An example of acting on that principle had already been set in the admir- able essay of MM. Ancsrrom and THALEN, published in the Upsala Trans- actions for 1875, For there, both in the Plates and letterpress, the final portions entitled “Mesures Micométriques” are very largely magnified representations of certain small parts of what went before. _ But just as occurred in the earlier division of that great work, so also this later portion of it, there appeared to me to be too few gases, and too few portions of their spectra treated of, to supply a sufficiently comprehensive basis for this branch of science. GASEOUS SPECTRA UNDER HIGH DISPERSION. 417 or definition to bring out many of the exquisite and close-set details which spectroscopy is beginning to demand in the present day for any and every gas that is now observed. And this, too, although those Upsala results did most honourably transcend all others at the time they were published, and for many years afterwards, indeed almost, if not quite, up to the present time. Hence I have felt it incumbent on myself, before venturing to trouble this Society with new versions of any old phenomena, not only to increase the range of subjects treated of, but to improve the instrumental apparatus employed on all of them, until it was capable of some very remarkable performances in the way at least of differential mensurations in the field of view or near it. Of such differences, however, only. For temperature changes in the fluid prisms, although greatly reduced by a variety of contrivances, were yet continu- ally at work, altering to so sensible an extent the value of the Dispersion scale from its distant zero, as to prevent the absolute places given by this very lately put-together apparatus being anything better than extremely rough when over long ranges.” But condoning that one weakness, for the sake of other advantages, the strength of the instrument for micrometrical detection and record of small differences may be indicated thus— (A) The one-prism spectroscope employed in my collective and rudimentary paper of 1880, possessed a little more than 3° of Dispersion from A to H, with a magnifying power on the telescope of 10 diameters; virtually broadening those 3° to 30°. (B) The apparatus employed by MM. Ancstrom and Tuaten for their Mesures Micrométriques, as nearly as I can gather in a general way, must have had at the utmost a Dispersion A to H of 24°, with a magnifying power of nearly the same number of diameters; or equivalent virtually to a spectrum 600° long. (C) While my present arrangement has 60° of Dispersion A to H, with magnifying powers on the telescope of inspection rising from 12 to 36, and a further mechanical magnifying in the recording apparatus of 5 times; equivalent to 9000 of the same degrees altogether; or to the action of 1800 simple prisms of 60° refracting angle in white flint-glass, viewed with the naked eye.+ * By observations on Green CO on November 3, 4, and 5,it was ascertained that, after every- thing had been done at the place that could well be done to secure constancy of temperature in the bisulphide of carbon prisms employed, a slow fall of 1° Fahr. increased the Dispersive power of the collective train of prisms by 0°727 of a Revolution of the very coarse screw motion ; or by close upon 10 inches on the surface of the recording barrel. The interval of time therefore between any two Mutually dependent observations was, after that, made as short as possible. + The diameter of the objectives was the same as in my.earlier apparatus, viz., 2°25 inches, and the refracting faces of the prisms presented nearly the same breadth to the entering ray. 418 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF To which qualities were added, when assisted however by certain more intense illuminations, a transparency nearly as great, and a definition in certain parts of the spectrum considerably better, than I have seen in almost any smaller instrument. For this latter excellence I have chiefly to thank Mr Apam Hui1cer, and to laud the extreme skill and perfection wherewith he constructed both the glass cores of the bisulphide prisms, and their all-important anti-prisms out of admirably hard, white, and uniform crown glass. The Micrometrical recording apparatus was exquisitely constructed by Messrs T. Cooke & Sons of York, to whom I am therefore much obliged; while I am further quite unspeakably indebted to the progress of Chemical Science, which has, in recent years entirely freed bisulphide of carbon from the horrors of its ancient smell, and has given us a fluid perfectly colourless, nearly inodorous, exceedingly trans- parent, and endued with less refraction but more concomitant Dispersion, than anything else under the Sun. ta In discussing therefore the results obtained with all these advantages, I shall not only refer to MM. Anesrrom and THALEN’s now nine year old, yet still most excellent, essay, but shall consider it a duty to seek out later and more advanced works, if they exist, elsewhere. Paying particular attention to the recent Reports of the British Association’s very powerfully constituted Committee * for reporting on our present knowledge of Spectrum Analysis in 1880, 1881, 1882, and 1883. For their admirable digests of all that has gone before, and all that has come up to their own time, in the now voluminous bibliography of the spectrum, enables every one to locate the place, and assign the value of any new observation both with high certainty and the least loss of time. 4 PART I. THE First GAS TO BE EXAMINED, AND UNDER WHAT CONDITIONS. As my object has been to a large extent to pass over superficial variations, and arrive, if possible, at the great constants of Nature in this department,— * The Members of the Committee are given thus— Professor Drwar. Professor A. K. Huntineton. Dr WiiAMson. Professor Emerson REYNOLDS. Dr Marssaatyt Warts. Professor Reinoup. Capt. W. pp W. Asney, R.E. Professor Livni. Mr Sroney. Lord Ray.eieu. Professor HartLey. Dr Scuuster, and Professor M‘Lrop. Mr W. CHanvier Roserts, Secretary. Professor Carny Fosrmr. , GASEOUS SPECTRA UNDER HIGH DISPERSION. 419 it would seem that I ought to begin with the simple, elementary gases; and afterwards touch on their compounds if desired. But the practical methods of inductive inquiry into Nature, cblige me to proceed in exactly the opposite manner, and begin, as did also the great Upsala leaders, with the manufactured compound gas most immediately at hand in any and every situation in life, viz., illuminating gas, whether of coal, oil, wax, or tallow. There may be, as we shall see presently, some difficulty in deciding on the chemical interpretation to be put on the spectrum thence obtained, but there is none in procuring a view of it; for whether we observe the blue flame of a blow-pipe of coal-gas and air, or the blue base of an upright flame of either those or any other of the ordinary illuminants of night employed by man, | burning in the open air,—there appears to be always the same identical | spectrum present, differing in no one case from another, except in ‘degree of brilliancy. Were we to burn the illuminant in a current of pure oxygen, something additional might be seen. But I have purposely refrained from doing that, and | confined myself, in this part of the inquiry, to the grand aerial constant for all | men, compound though it be, of the earth’s atmosphere, for the sole elementary aid to combustion, as a mode of obtaining incandescent temperature. To make the effects of that, however, more visible than usual, I have em- | ployed a blow-pipe nearly a foot long; with coal-gas in quantity from the | service pipes of the house, but urged in intensity by air from a bag under pressure equivalent to 6 or 8 inches of water: and have further always | placed the flame thence procured “end-on” to the spectroscope’s slit, in the | manner described to, and approved by, the Royal Scottish Society of Arts _ several years ago. Thence results what the Brittish Association calls, THE CANDLE-SPECTRUM, IN AIR, or, as named here, for reasons presently to appear, CH, 7.e., CARBO-HYDROGEN, IN Biow-Pire FLAME. Having been introduced to this Society nearly thirty years ago, by our respected Fellow, Professor Swan, this particular spectrum will doubtless be well known to every one present, as offering a charmingly simple arrangement of five bands, most aptly to be compared to the human hand. For the first of | them, orange coloured, and therefore in the orange region of the spectrum, is comparatively thin and weak, say like the little finger. The second, citron coloured, much stronger like the next finger. The third in the green, the | brightest and strongest of the whole, like the middle finger. The fourth, in | the blue, intermediate for strength between the first and second, like the index 420 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF finger; while the fifth, in the violet, is not of the build of any of the other bands; you may say not a finger at all, but shorter, broader, sturdier, like the thumb. Viewed in any ordinary single-prism spectroscope, each of the first four of these bands begins on the red side with a strong line, followed by two, three or more similar lines, but in decreasing brightness and lessening distance, interspersed with haze; while the fifth band seems to be composed of nothing but haze. . ; This luminous hazy mist has, however, been occasionally seen by some individuals with powerful spectroscopes to be more or less resolvable into faint and exceedingly close lines or linelets. And now, with my new ~ spectroscope, I have not only seen it all so resolved, but have been able to measure almost every linelet by micrometer, until at last they became too faint to be distinguished in any manner whatever. The record thus procured, proving so neatly that there is no waste, neglected, unordered or accidental material in the spectrum of this cheapest of all the gases, was obtained on the instrument in so very magnified a condition, that the whole visible spectrum, or from red to violet on the same scale, would — extend to 120 feet in length. But this being supposed a rather longer scale than the world is as yet quite - ready for, though demanding far more for certain parts of the Solar Spectrum, the original record has been reduced on subsequent working sheets to a 40— foot spectrum length. And as only the portions with very visible lines and linelets for the five bands of CH in air, are given,—this particular subject will yet be found in larger and fuller representation than it has probably ever enjoyed before, though packed away in four only of our plates. - THE SPECTRUM PLATES EMPLOYED HERE, THEIR METHODS AND SYMBOLISM. For the original observations and records on both the long 120 foot scale, and the first reduction to the forty-foot, I am answerable myself. But the drawing out of the final and finished plates, thirty-one in number for the whole paper, and all save three on the same exact 40 foot Wave-number per British inch scale, has been confided to Mr Tuomas Hearn, First Assistant in the Observatory ; because his handling of the pen and pencil is finer than mine; and, under photo-lithographic treatment will give something like the perfection of copper-plate engraving, without its superior expense. The said plates are intended moreover to serve more than the usual purpose of such data. For though it is customary, and was actually done by Messrs Ancstrom and THALEN in their classical case, to give both a printed list of the numbers representing their micrometrical measures, and also an engraved, and GASEOUS SPECTRA UNDER HIGH DISPERSION. 421 most beautifully engraved, map, or picture of the same—yet I have invariably found a mere list of printed numerical spectrum places, by whomsoever issued, to be but very little instructive,—without spending a lamentable amount of time over its interpretation, application and meaning on every occasion of using it; while it is also not a little expensive to print. Hence I have tried on this occasion to save the cost of figure printing, by throwing the whole burden of what is needed for final results, on the Plates alone. Spectroscopic plates of some kind, on account of peculiar virtues of their own for such subjects, must be introduced in some shape, or to some degree. The following characteristic sentence occurs in a British Association Report for 1883, p. 123 :—“ Three such spectra have been photographed, but without the aid of maps their peculiarities are not capable of description.” Wherefore now, by keeping our plates sufficiently large, and with very clear and distinct scales, we may hope that they will not only preserve their own peculiar attri- bute of showing at a single glance the groupings and general bearings of multitudes of lines far better than any other known method,—but they will allow, on close examination and longer inquiry, the numerical places of any particular lines to be read off to nearly as minute a degree of exactitude, as the original observations were capable of giving. This good quality would have been absolutely so with the 120 foot records ; and if not quite so with the 40 foot size, that is why I specially request that Mr Hearn’s drawings shall not be reduced any further, as no smaller scale can pretend either to do justice to the originals, see especially Plates LX XII. and LX XIII., or impart confidence to those who may use them. To which apology I have only now to add, that the following principles of representation have been strictly followed throughout all the plates of this series. PRINCIPLES OF SPECTRUM REPRESENTATION. Rule 1. The representation is negative, in so far as it shows light by black ; and darkness by white. Rule 2. A vertical black line, whether thick or thin, tall or short, on the plate, represents, and is devoted to representing, nothing else than a true spectral line of light, seen and measured as such in the spectroscope, and is considered as precious a result of observation or discovery to the spectroscopist, as a real star is to the Astronomer. | Rule 3. Different degrees of brightness in the real lines of light in these gaseous spectra, where all lines are necessarily of an equal height,—are represented in the drawings, approawimately by different thicknesses of the black lines employed there; and more exactly, by adding thereto the further method of different heights or depths of the lines so drawn. 422 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF Rule 4. When lines of light in the spectrum are so faint or ill-defined that — they no longer give the appearance of solid or liquid light, and are no longer sharp and smooth-edged like knife blades, or stretched silver wires, but look more like faint, uncertain, granular, worsted threads,—the lines representing them on the plates are not drawn in full ink or with parallel sides, but of a conical shape, or in dots, or in wavy lines, and in extreme cases with cross lines. . ; Rule 5. Faint broad bands in the spectrum, and its occasional portions of continuous spectrum light, are never indicated in these drawings by any kind or arrangement or succession of vertical lines, but by either horizontal, or oblique lines; and these may be crossed over and over again to produce the required degree of intensity in any case. For the lines of such shadings can evidently be never confounded with true spectral lines; which, being images of the slit of the spectroscope, must all be vertical and parallel, when the spectrum range is horizontal. Rule 6. Shading by either inclined or horizontal lines being symbolic and abstract only; such lines may, for facility of execution, be of almost any degree of coarseness or width apart; provided only that the amount of ink contained in them shall, if symbolically supposed to be smeared up and down within the upper and lower limits of the horizontal spectrum strip,—indicate only a grey shade, not a full degree of blackness. And exceeding refinements of such shade or faint-light surfaces in the spectrum itself, may be indicated on the drawings by making the shading lines there cover more or less of height or — depth in the spectrum strip, as already adopted for the easier representation of — different degrees of brightness in the spectral lines alluded to under Rule 3. DRAWINGS OF THE CH Spectrum IN BLOW-PIPE FLAME. Now all the latter of these rules came into play at once with our first subject, or the blue-grey blow-pipe flame of coal-gas and air; for there is not light enough in it to give off any lines of real, liquid light, only haze of different degrees of rarefaction. Considering indeed the proverbial faintness of the blue base of flame, as when a candle burns low and blue, it is rather surprising to find that so very small a portion of it as enters between the almost closed jaws of the spectroscope’s slit, can yet be distinguished as made up into upwards of 400 parcels, separated one from the other always by different and definite spectrum place ; and sometimes also by instantly recognisable features of physiognomy or gradated intensity. | : Yet such is the case, for the plates now exhibited of the coal-gas and air blow-pipe spectrum (Plates XLVIII. to LI.), show 81 separate existences in th GASEOUS SPECTRA UNDER HIGH DISPERSION. 423 Orange band, 94 in the Citron, 97 in the Green, 107 in the Blue, and 71 in the Violet. Their distribution in each band appearing thus— Orange band—1st leader consists of lines 2, followed by linelets 27 2nd n is . 14 3rd A 2 o 11 | 4th Ss De ie 5th : my 4 5 6th a. iy i 62 Citron band—1st - 2 Pe aS. 2nd 4 2 - UP 3rd ‘. 2, 6 9 Ath . 2, ie 7 5th i 2; Hs 31? Green band—1st leader, “Green giant” 2, a Al 2nd lines consists of 2, id sf 3rd 4 in ' fb 4th A We F 7 5th . 22, - 4 6th 12, : 17 Blue band—H1st eo DE 4 Zl 2nd Dy. é 14 3rd " ae ' 12 ’ Ath es PAP i, 5 5th ad 22, . 55 Violet band—Preliminary band has linelets 20 Subsequent and chief band contains iheaee and linelets of various kinds, certainly . hae | and probably many more; each being fainter and faimter in every successive repetition beyond. This is also probably the case with the linelets of the more refrangible ends of each of the earlier bands, for they are all vanishing series to that side. Hence to record more, or fewer of them, tells nothing new in the theory, but speaks only to the brightness of the optical images ; and as I usually stopped, not when a definite end was arrived at, but when the linelets had become so ‘| faint and diffuse that it did not seem worth while to go on any longer,—other persons may succeed with better apparatus in chronicling more lines and linelets than I have done ;—-such gatherings however being always fainter than those now tabulated. But even with them, the strain on the eye to measure their places micro- | metrically was often so great, that I was not unfrequently afraid I might be deceiving myself, and undoubtedly must have made many mistakes, particularly in setting the pointer between the close linelets, instead of upon one or other jof them. Yet after completing the measurement of any band, there was found jon the whole such a decided order, or law of increasing distance from linelet to @eyVvOL. XXXII, PART Itt. 3 Z 424 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF linelet, in proceeding from the red to the violet end, and of decreasing distance at the same time between the leading lines, or rather pairs of lines in each band,—as could not have arisen from mere accidental error, or blind fancy ; and did seem to testify to a considerable portion of the interesting arrangements — of Nature, in this branch of her handiworks, having been secured on this occasion in linear record. If the leading lines too in each band, notwithstanding their faintness and haziness, have been represented by me as double, though single to all former observers, we may find strong confirmations thereof in our next subject, viz., ADVANTAGES OF ELEcTRIC-LIGHTED GAS Vacuum TUBES. These tubes are usually illumined for observation by that variety of electri- city contained in the spark from an Induction coil, actuated by a Bichromate Galvanic battery. Such was the kind employed here, and was capable of giving sparks from 2 to 4 inches long in the open air: the size of the immersed portions of the plates being 4”°2 by 46 ; and the number of cells 12, but only 6 of them having fresh exciting fluid each observing night. The coil was by Mr Apps, said to be a6 inch spark coil if used with five quart-sized Bunsen, or Grove, cells. It was also furnished with a quantity, as well as an intensity, primary ; one or other to be employed alternatively ; but*after many trials with — little or no difference on spectra, I settled down to the intensity arrangement alone, and to carefully attending to the state of the spring brake ; its freedom from oxidation ; or from becoming self-soldered, and being in the best state of strain for illuminating sparks, without stopping dead. Employing these sparks then on vacuum tubes, they may of course be expected to show higher temperature effects than mere blow-pipe flame. But they have other advantages over both that method of incandescence, and induction electric sparks in the open air, whether taken direct from the coil or with the interposition of a condenser, in the shape of “the jar dis- charge.” To illustrate the nature of these advantages for our particular purpose of Micrometrical measures of precision, I submit on Plate LII. four views of the salt lines (D! and D? of the Solar spectrum) rendered incandescent in as many different modes, and viewed under high dispersion. No. 1 is the effect of burning a solution of Na (chloride of Sodium) ona small spiral of iron wire in the flame of a Bunsen burner of coal-gas and air, the usual manner of all ordinary Spectroscopists. The effect will be seen to be broad, dull and hazy in the extreme; there is much continuous spectrum paling the lines, and the outer envelopes of vapour of the flame produce on each line an inversion of the direct action; or cause a black line to run do wn GASEOUS SPECTRA UNDER HIGH DISPERSION. 425 the middle of each big bright line,—represented here by a white line on a broad black band, splitting it into two, but foggily and uncertainly. This whole result is of course most unsatisfactory and untoward to sharp, micrometric bisection. No. 2 exhibits the spark drawn from a solution of Na forming one of the poles, the other being a platinum wire. There is here no continuous spectrum, there is also something sharper and more intense than before in the picture which it gives of the D lines; but the abnormal central line down the middle of each standard line is repeated; and the whole is in a peculiar, crackly, continually exploding, condition, also opposed to very nice bisection. No. 3 shows the same identical spark, but altered in quality by the intro- duction of a half gallon Leyden jar. The change is immense, the whole field being now filled with fervid light of the general air glow, also with certain hazy air-bands palpitating in their heated atmosphere, and which I have not attempted to show, while the D lines are still split through the middle and are hazy both inside and out. Finally, No. 4 shows the D lines in an end-on vacuum tube. The field here is absolutely black about them; the D lines absolutely bright, sharp, compact, steady, well defined, and everything-that a micrometrical observer could desire. In a second tube with the D lines still as above, there were a few faint, low temperature, Hydrogen lines. These were just as sharp and steady as the Na lines, but being vastly fainter were exceedingly thin; so that, over- looking linear, in place of disc-point, figures, the whole field of view gave one the impression of gazing upward into illimitable stellar space, where one star differeth from another in glory, but all of them exist in the quietude of heaven, the calm of eternal peace and distance ineffable. A Lonpon OBJECTION TO MY TESTIMONY WHEN USING THAT METHOD. The tube incandescence then is pre-eminently favourable for accurate micro- metrical observations. But before I can expect to have my descriptions of what it has revealed to me listened to elsewhere, it will be necessary to meet Openly an accusation lately printed against me by that very same British Association Committee whom I have already on other points alluded to most honourably for their ability, and presumed sense of justice. Yet the following is what appears at p. 12 of their Report for 1880, published in London, when speaking of certain of my observations at that date in vacuum tubes :— “ Professor Prazzi SMYTH has however not filled his own tubes, and we must be careful not to attach too much value to the labels put on vacuum tubes by the glass-blower who has filled them.” 426 ©. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF Of course this a delicate insinuation that I have been trusting to such labels : if it is not also intended to indicate that he who fills his own tubes, as the actual writer of that sentence for behoof of the Committee of fifteen had done for himself, may take a very high place among the philosophers of the land. While any one who falls short of that particular tubular operation by the smallest item, no matter in what company, or under what system of friendly or scientific co-operation with others,—instantly pitches headlong down a social precipice, and may only bring up afterwards among glass-blowers. Now it is perfectly true that I did not either make or fill my own tubes ; and there has never been any secret about it; for I have from the first joyfully proclaimed who did that for me; and did it at last so well, that I could conscientiously recommend them elsewhere. For as to the persons concerned, I have been very fortunate in interesting in this matter intellectually, several gentlemen of education, ability, and experience in both chemistry, scientific instrumentation, and business, viz., first, M. SALLERON, and then his successor M. DEMICcHEL in Paris; next Mr Louis P. Casetia, and then Mr Cuarues F. Casetua in London; and finally I believe I may add, to name one deficient to none in persevering enthusiasm to conquer every chemical difficulty that arose in his path, though with little leisure and less of laboratory appointments, Mr W. H. Suarp of Messrs Kemp & Co. in this city. With one or other of these gentlemen I have been in nearly continued correspondence for the last six years, discussing and trying experiments for the quality of the glass, size and shape of the tubes, materials of the electrodes, strength of sparks, arrangement and bore of capillary, as well as the methods of preparing the several gases, purifying them when made, removing occluded gases from the electrodes both before and during the filling, and then finally sealing. Sealing too not a single tube only, but a series at several stated and pre-determined steps of pressure. But did I even then trust to either the necessary labels of some kind put on these tubes, or to the long descriptive letters also sent to me ? Certainly not, after the first few days of experience. For my plan ever since then has invariably been, on receiving a batch of fresh tubes from any maker, to put them one by one into a testing apparatus; — find out there what is in them by their stronger lines compared with the — general literature of the subject, put my own labels on them, and perhaps send i of the batch back to the maker for faults that had escaped him; and then would begin a correspondence to try and find out where, either in the making — of the gas, or the steps of its purification, the fault originated, and how it — might be avoided in a new set. | Again, even with tubes that have passed this examination, I have usually GASEOUS SPECTRA UNDER HIGH DISPERSION. 497 reviewed a number of them before any night of final observation for the present paper, in order to find out if any changes with time and use were going on amongst them, and to ascertain more particularly for the service of the great spectroscope, which tube of them all, whatever its original label, was just then capable of showing a particular part of the spectrum of some specially required gas, with the greatest purity and the utmost vigour. If this is still to be held up to public reprobation by London central and immovable scientific authority, as my “trusting to a label put on by a glass- blower,’—and because I did not fill my own tubes,—there is nothing left for me but to request the Royal Society, Edinburgh, to judge between us,—if I shall yenture to set forth, before the close of this paper, how much more of the undoubted phenomena, of at least one particular gas I have succeeded in discovering, identifying, and micrometrically recording on an extended scale, than have any of those London and British Association gentlemen ever been able to observe in their tubes, although they filled them for themselves. Resuming then, by this Society’s leave, we come next to PART II. CITRON, AND GREEN, Banps or CH, 1n Vacuum TUuBEs. After preliminary experiments with Alcohol, Marsh gas, Turpentine, Coal gas and Olefiant gas—I settled down to working chiefly the two last of these Carbo-hydrogen vapours or gases. Of these gases much desired, pure CH spectrum, by electric light, but under atmospheric pressure,—MM. Anesrrom and THALEN have given the two brightest bands, viz., the Citron and the Green, in their Mesures Micrometriques. Those well-known bands make therein a very brilliant picture, especially as they are engraved in ne plus ultra style of both refinement and force ; in the positive manner too, or with the lights white, on a field of black for darkness, and with an effect that RemBpranpT might have envied. The Swedish scientists do also there give a considerable indication of hazy, fluted linelets, continually getting closer, and brighter as they approach the least refrangible side of each band. But, strange to say, they have wholly omitted the vastly superior brilliancy of the leading /ives in each band! These strong Jeading lines are the first exact features which a beginner in spectroscopy makes out, to his great delight, when studying each CH Blow- pipe band; though at first sight, and with a too broad slit, said bands had probably appeared to him as only composed of smooth haze. And I can now further vouch, that those CH bands’ leading lines, whether in blow-pipe or vacuum tube, remain equally conspicuous over the linelets, in all my subsequent 428 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF magnifyings up to a size fully 12 times larger than that of the Swedish Philosophers. These lines moreover in the vacuum tubes, are very distinctly double, and get wider and wider in their duplicities, though they decrease their whole distances of double from double, with every succeeding line. There must therefore, in their omission, be an error in the work of those otherwise unexceptionable authorities; and it is pretty certainly owing in large part to the bad definition, or broad slit of the spectroscope there employed, as well as the greater practical difficulties in the positive mode of representing bright-line spectra. For the Upsala linelets are ultra hazy things, running one into the other and making only a confused and slightly undulating surface of luminous fog; culminating too soon, on the red-ward side, into the perfect light, or whiteness, of white paper. Whereas in my Vacuum tubes, far beyond the Blow-pipe’s hazy separations already alluded to, the linelets, however faint, are thin and linear; and in some new tubes are capable of exquisite sharpness of definition, on an almost absolutely black field of view. ‘That however is not all that has to be noted with a very high Dispersion power ; for after further working these tubes, the linelets became double, and ~ after that even treble! Such a change however being always the beginning of a tube failing, or going altogether wrong: and was first testified to, as will be seen in Plate No. LIII., by the very superior optical power of a fine Grating which I had the honour of receiving from Professor RowLanp, of Johns Hopkins University, Baltimore, U.S. ; but corroborated afterwards only too abundantly — by the older prismatic apparatus. Hence some advantage will be found, when comparing my different views of any of these CH bands, to note the name of the tube employed on the occasion, and the date of observation ; a single day, — of hard work, often showing great progress in the work of deterioration. ORANGE Banp or CH; anp Errects oF PRESSURE, IN VACUUM TUBES SO-CALLED. For testing my own views of any other than the Citron and Green bands — just disposed of,—we must fall back on the general map of the Upsala scientists, small though it be. But it is beautifully engraved ; in the negative manner fortunately as to representing light by black; and professes to give the Orange, Citron, Green, Blue and Violet bands. Shading them, however, into striking relief by adding to others closely ruled vertical lines, which are a mere engraver’s easy method of producing shade, and mean nothing, while they mislead much, in spectroscopy. Comparing it, however, first of all with my own Index Map of CH im vacuum tubes (Plate LX X VII.)—what is the meaning of the immense force ol the Orange band, and at the same time the dwindling down to a mere trace of GASEOUS SPECTRA UNDER HIGH DISPERSION. 429 the Violet band in the Upsala Memoir,—so very differently to what occurs in that grand constant, viz., the Blow-pipe flame’s spectrum of coal-gas and air. In this last material nothing is easier on any occasion, and for any length of time, than to get all 5 bands to show; but the Orange band is always weak; and did therefore altogether escape some of the earlier ' observers. | In the tubes also, by electric light, the Orange band is far weaker than | either the Citron, or the Green; but it has another difficulty to contend against there, of this nature,— | When the pressure of the CH gas is small, it is so very easily decomposed | by the electric spark, that Hydrogen low-temperature lines are set free; and _ being nowhere stronger and more multitudinous than over the Orange region, | they completely mask any residual traces that may remain of Orange CH, and | much of the Citron CH, band, as well. But, as I have been finding with tubes | specially prepared to that end, the decomposition becomes less and less with increasing density of the filling, until at several whole inches, instead of | hundredths of an inch as with the old tubes,—Hydrogen lines nearly disappear, and CH bands like the blow-pipe’s bands, so far as their range extends, are | almost the only existences visible. To get the CH Orange band, however, quite clear of those obstructions, is particularly difficult. Thus with coal-gas at 5 inches pressure, last year, every _ blow-pipe band was well seen, except the unfortunate Orange one; and so it | was also this year with a fine tube of Olefiant gas prepared by Mr CasELLa at | 2 inches pressure. But with another tube he had prepared at the same making, | at 4 inches pressure,—such is the superiority of Olefiant, to Coal, gas for | this purpose,—the long desired cynosure was reached at last.. For in that | tube’s spectrum, while not a single low-temperature H line appeared, there was “the Orange CH band as perfect in its symmetry of lines and linelets as any- | thing could well be imagined, and as I have never seen it written yet. There were to be counted in it 5 leading lines very bright and distinct and perhaps a sixth, all at successively smaller intervals in proceeding towards the violet : while between every pair of them, and in the interval beyond of greater refrangibility, were the linelets, in infinite thinness, sharpness, and definition ; | at first, or towards the red side, very close set, but continually increasing their | distances apart, and preserving their inimitable Liliputian visibility, right up to | the very beginning of the Citron band. This being a glorious extension of the | vanishing side of the Orange band, far beyond anything ever seen with the blow-pipe, or even with tubes, when coal-gas is the filling medium. Next, turning to the Citron band of CH (in the same 4 inch pressure Olefiant gas tube) its leading lines were vividly bright; its linelets also un- precedentedly clear, and never ceasing for a moment until, although continually 430 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF widening their distances from each other, and paling and thinning their light, but not losing their definition, they at last came right up to the Green band. The Green band as a matter of course began with its “‘Green-giant ” line in magnificent cue ; then came closely packed, but well separated, sharply defined linelets ; then the second leading line, and wider linelets, then the third leading line and after that the long expanding series of sharp linelets, which continued on, and on, and on, until the beginning of the distant Blue band was reached. But shortly before that point was arrived at, a broad, faint, grey haze-cloud was passed. I had never seen anything like it, in that spectrum place before. What could it possibly be ? It turned out to be Glaucous Hydrogen. Not in the shape of the sharp and vividly bright line that it always shows in tubes at smaller pressures, but a mere amorphous bundle of Nebular haze. Turning back then to the Red end of the spectrum, there, in the place of the usual Red Hydrogen line, was another broad cloud of faint haze, but of course red in colour. This therefore was the reason why even the Orange band of CH, with its ultra thin and sharp linelets, was, for once, not sensibly interfered with by low- temperature H lines. For at that grand pressure of four mercurial inches on the Olefiant gas,—mere nascent Hydrogen could only exist, even with its strongest lines, as a sort of faint vapour, floating like a ghost over certain 7 spectrum places ; and all low temperature H lines being vastly fainter than its — two just mentioned high temperature lines (Red, and Glaucous)—their resolu- tion into similarly broad clouds, depressed their intensity of light to beneath — the minimum visibile of any eye. I spent perhaps half an hour noting these circumstances in the testing spectroscope which has 12° Dispersion A to H, and was planning how I would — _ arrange the great spectroscope of 60° Dispersion, to take advantage of such an unprecedented view of the Orange band of CH,—when I fancied I saw a double line where lately there were only linelets; then a stronger line appeared — between two of that band’s leading lines: then another, and another. To my horror they began to look amazingly like low-temperature Hydrogen lines. Turning therefore to the places of the late nebulous clouds of Red H and Glaucous H,I actually saw them slowly gathering themselves together, and settling down as lines into their ancient places. While in half an hour more, ted H and Glaucous H were narrow and vivid exceedingly ; while the whole band of lines and linelets of this poor, persecuted Orange CH was now hidden. in a positive jungle of intrusive low-temperature H lines, of a most provoking degree of strength, brilliancy and number. . My hope then of presenting the Society with a large map of Orange CH, out of that tube, was gone for ever. Because, when decomposition, by spark GASEOUS SPECTRA UNDER HIGH DISPERSION. 431 illumination, once begins in a CH. tube, it never stops until all the H has freed itself from the trammels of connection with C (Carbon); and that element either falls inert, or if it can find any O, combines with that, and appears as CO, to the still further confusion of all CH bands. At the same making where these two Olefiant gas tubes at 2’°0 and 4”:0 pressure were prepared, Mr CasELLA made for me another tube at only 0"1 pressure. There was no O nor CO visible there, nor any CH either ; nothing but the most brilliant set of lines of pure and simple H that were ever beheld, I should suppose, by mortal eye. In fact, at that low pressure, the first spark had decomposed the whole of that faint charge of Olefiant gas; its C was nowhere visible, but its H atoms were vibrating everywhere: and the only consolation I had for seeing nothing of the expected CH was, the apposite illustration that the whole case offered of a favourite idea of the late excellent Sir WILLIAM SIEMENS, whose loss we all deplore. His idea being, that the gases which, by combining under 800 inches pressure on the surface of the Sun, give out light and heat,—may, when excessively rarefied by removal into outer space, become decomposed or separated from each other under even the weakest physical influences ; but are made ready in that way, on their return to the Sun, to give out light and heat by renewed combination under pressure, over again. BLUE AND VIOLET CH Banps, Of the Blue band of CH, I have little to say beyond what my readers will find out for themselves, on referring to Plate LIV., to my Index Map (Plate LXXVII.), and also to MM. Ancsrrom and THALEN’s Index Map, which mutatis mutandis is fairly enough compatible therewith. But in the case of the Violet band, so large and bulky with me, so thin, small, and vanishing with them, there is a huge difference to be ex- plained. : _ Now TI should have already indicated that an exactly opposite difference in the case of the Orange band, seemed to be attributable there to the Swedish observations being made on gases at far greater pressure (probably the full atmospheric) than the densest fillings of any of my tubes; and the same reason, though with opposite effects, is apparently the acting cause at the opposite, or violet, end of the spectrum, of what we may note there. For with my own | tubes, the denser the filling, the nearer did the Orange band come to the | larger Swedish development of it,—yet the nearer also did the Violet band come to the Swedish depreciation of 2. In fact in my densest tubes I have not only found the Violet band (the furthest visible one of the Coal-gas | Blow-pipe series) an almost vanishing quantity,—but have proved an entire | absence of a still more beautiful and powerful band beyond it—and which VOL. XXXII. PART III. 4A 432 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF ought otherwise (as well as another band between the blue and the violet) to be always seen at electric temperature, viz., THE MArRSH-VIOLET CH BAnp. This band was so-called, from Professor ALEXANDER HERSCHEL first finding it during some of these experiments in one of my tubes of Marsh gas; but it was already known to older spectroscopists who have used pure Oxygen, in place of atmospheric air, in their blow-pipes. With stronger sparks too than my earlier ones, I have latterly found the band developed to more or less extent in every kind of CH gas ;—and capable of coming out with far more force and picturesque luminosity that the previous Violet, or the ante-previous Indigo, band. In short with its very pronounced leading lines, and then the expanding linelets after each of them, in such regular series,—this last and latest “ Marsh Violet” CH band may be considered a most typical example of a CH band. It would also probably make a still more magnificent appearance in photography ;—for, it is so far within the ultra violet of the spectrum range, as not to exhibit its full glories to the human eye, but is by just so much within the sphere of the impressibility of bromo-iodide of silver, focussed on by quartz lenses and prisms. My own plate of it therefore (No. LIV.) must be looked on | as its ¢nterim presentation only. OF THE CHEMICAL INTERPRETATION OF THIS CH Spectrum. Through all the variations I have been describing of this CH spectrum, © however much more or less may have been visible at its one end, or the other, by reason of accompanying circumstances just explained,—no one known and recognised band in it, when tested by its sharp leading lines has been moved out of its spectrum place by the smallest, recognisable quantity. Hence it is one and the same spectrum throughout all the above intensity variations, and one so continually met with in this world, and in astronomy is so characteristic of the self-luminosity of comets, that it is most important to know what chemical science says as to its origination and nature. I have been, thus far in the present paper, calling it the CH, or Carbo- Hydrogen, spectrum; but in London among the magnates of Chemistry and Spectroscopy, it has been declared to be the spectrum of C, or pure Carbon alone. So, too, it was evidently very firmly held to be by them, a few years ago. For when I sent a paper on Auroral Spectroscopy to the Royal Astronomic Society in 1871 making use of the Candle-spectrum as a reference, and attri buting it to CH in general, and Acetylene, or C,H, in particular,—I have bee GASEOUS SPECTRA UNDER HIGH DISPERSION. 433 told, informally of course, where a secret meeting is concerned,—that a Royal Society Fellow on the Council of the R. A. S. informed that body that my chemistry was entirely wrong, and my paper was consequently rejected. Now Carbon has long been known to be one of the most refractory substances under the Sun; though when exposed to the most terrible temperatures of Condensed Induction Electric sparks, it is forced at last, in the unanimous consent of all men, into incandescent vapour, and then gives out a totally different spectrum, to anything we have been describing, viz., one of a few isolated lines merely, see No. 3, Part I. of my Index Map (Plate LXXVII.). This therefore was termed by the London men, “ Carbon spectrum No. 1;” while the spectrum we have been discussing, and which may be seen in the base of the weak flame of any little candle whose temperature is low indeed by comparison, was, with them, Carbon spectrum No. 2, or 3, or 4; on the then new presumption that a Chemical Element, instead of being confined to cone spectrum alone, may have several. The history of the origin, and metropolitan establishment, of this very contradictory conclusion for Carbon, is, that Dr AtTrrreLp of London in 1862, presented a paper to the Royal Society there, which that body accepted and printed ;—wherein he claimed to have seen the banded spectrum of the Blow- pipe flame of Coal-gas and air in every possible compound of Carbon with either H or any other gas; whence he decided, that the spectrum must be that of pure Carbon alone ; however different it might be from the English Carbon spec- trum No.1. This decision therefore having been given forth under the auspices of the Royal Society, London, has remained the rule ever since in that region, however violently it conflicts with the Natural Philosophy of the case, and the Chemistry of Carbon in general. Outside the London circle some very different ideas prevailed; but were ignored by the grand central authority there, until at last the progress of knowledge raised an earthquake in their midst, with effects which would have been far less disastrous, had the London magnates been previously only a little less exclusive. For thus, with a charming naiveté of confession, explains the British Association’s Report of 1880,— “ On the whole it may be said that, from the publication of ATTFIELD’s paper (1862) until the year 1875, every spectroscopist, whether he was a chemist o1 physicist, who’had set to work to decide the question, came to the conclusion that the Candle-spectrum was a true spectrum of Carbon (2.¢., of C., not CH), and the question appeared to be settled.” Now I was not original in having, on the other hand, during that interval, upheld the Candie-spectrum to be one of CH, not of C; for I had learned it previously from my friend Professor Swan, who, with his paper on the subject to this Society in 1856, is an older authority by many years on the Candle- 434 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF spectrum than any of the London gentlemen,—and yet, with myself, was pushed — out of the pale of recognition through all that long period from 1862 to 1875 But, what occurred in that latter year ? In 1875 was published the grand Memoir of MM. Anestrom and THALEN, wherein a very polite denial is given to the correctness of one of the most important of Dr ATTFIELD’s assertions, viz., that the candle-spectrum was an invariable accompaniment of a CO flame burning in the open air.* Imperfect niethods of preparing CO (Carbonic Oxide), argued M. THatEn, may easily allow CH gas to be present and give its spectrum ;—but pure CO does not give it. So also I have found with my tube experiments,—for while some of M. D&miIcHEL’s very carefully prepared tubes of CO did not reveal a particle of any of the bands of the CH Blow-pipe flame,—certain other examples of CO by a London maker exhibited so much of the said bands, not too as a mere residual accidental impurity in the tubes, but as a something introduced part passu by an erroneous chemistry in making the gas, for it increased always with the pressure, that I wrote at last for the particulars of the manufacture; and then discovered that the maker had been using a very weak and watery example of mere commercial Sulphuric Acid, instead of the most pure and anhydrous example that could be obtained. The outcome therefore in 1875 of the opinions of such men as ANGSTROM and THALEN, could not be altogether repressed and repudiated even by the Royal Society, London. But that Society has since then had a severer trial to bear ; for almost in the e¢ tw Brute manner of the stricken Ceesar, they have had to — read the later essays of Professors Liveinc and DeEwar, from the Cavendish — Laboratory at Cambridge; and find therefrom, that those distinguished — scientists have come to precisely MM. ANnestrom and THALEN’s conclusion; viz., that the Candle-spectrum is a CH, not a C, spectrum; and that its uniformity through all varieties of CH chemicals, depends upon the formation of Acetylene, C,H,, in the course of the combustion or incandescence. In short, the mental confusion that has now overtaken those who have ruled the London world of spectroscopy in this matter, so long,—is illustrated _ at the end of the British Association’s Report upon it ;—for it terminates with a disjointed, unnecessary and primitively simple statement of the spectrum places of the mere general beginning of the Orange, the Citron, and the Green bands” of what may now be firmly called by every one, the CH spectrum. Unnecessary was that proceeding of the Committee, because all men have * From p. 14 of Messrs Anesrrom and Twaten’s Memoir. “Quant & Vobservation de M. ArtrieLp que l’oxyde de carbone donne le spectre ordinaire des carbures d’hydrogéne, nous devons remarquer que cela ne s’accorde pas bien avec nos propres expériences. “Dans un tube de Geissler, contenant de l’oxyde de carbone ou de V’acide carbonique, on p certainement trouver des traces des spectres des carbures d’hydrogéne, puisque le gas n’est jam i parfaitement sec.” GASEOUS SPECTRA UNDER HIGH DISPERSION, 435 been long since agreed on the said places, quite closely enough for identifying the phenomenon; and the Bezonian query of “C or CH” has never yet been attempted to be answered by referring to any doubt about exact Spectrum place. PART III. THE CO SpEcTRUM. This CO spectrum should symmetrically arise in a combination of Oxygen with Carbon; just as CH represents Hydrogen joined to the same element ; and accordingly vacuum tubes with a trace of Carbonic Oxide (CO) give the spectrum we have now to discuss, in a most marked manner and easily recognisable character. In my former paper to this Society, I regret to say that I did, though with expressions of considerable reserve, allow for the time, with the English spectroscopists, that this spectrum might be one of pure Carbon, at a temperature between lamp-flame and that of the Condensed Induction spark. But I beg now to apologise for that error, to withdraw the name of “Tube Carbon spectrum,”—and to follow the teaching of Messrs ANcsTRoM and THALEN, who consider it to be the spectrum of the compound gas CO, (Carbonic Oxide) and of that alone; for even if CO, (Carbonic Acid) be also in the tube, or even occupy it entirely, one charge of its Oxygen remains ineffective, and exactly the same visible spectrum, as that of CO alone, appears. Now this CO spectrum, from the materials of its origination, is one of almost as extensive presence on the earth as CH; and has at first sight ‘something of its appearance. Yet they are two opposing and antagonising principles at every step. STATICAL DIFFERENCES. In small spectroscopes the CO spectrum is so far like the CH, in that it isa spectrum of bands; but it has many more; so that while MM. Anesrrom and THALEN have shown in their Mesures Micrometriques two only for CH, they show three for CO; and in their general Index Map they have represented 8 principal, 5 secondary, and some 16 very faint indications of tertiary bands, for CO; but 5 only for CH. The 8 principal bands of CO reinforced by 2 bright ones of the secondary, are, from their spectrum places, of the following notable grades of colour— (1) Red, (6) Green, (2) Scarlet, (7) Blue, (3) Orange, (8) Indigo, (4) Yellow, (9) Violet, and (5) Citron, (10) Ultra violet. 436 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF All these have their brightest, hardest edges toward the red end of the spectrum, in so far agreeably with all the CH bands; while the Citron and Green of the CO bands, fall so nearly on the spectrum places of the similarly coloured Citron and Green CH bands, that beginners may sometimes confound them; or even imagine a physical connection and community between them. A very little increase however of Dispersive power with Definition, will show that the CO bands have no leading lines in them, like those which are so prominent in CH bands. The CO bands in fact are made up of nothing but very uniform linelets, and therefore present a smoother, more enamelled looking, surface ; and they are narrower than those of the other compound. A far more certain difference however comes out on very highly increasing the spectroscope’s powers; for then it will be found that every band of CO has its every linelet of a different construction, or we might almost say material, to any linelet of CH; and every arrangement of them is different also. This will appear perhaps most strikingly on comparing the Green band of either; but as we have already given that band of CH, we have only here to picture, describe and discuss the GREEN BAND oF CO. In the Upsala micrometrical view this band is very short, and the linelets — of which it is dimly indicated to be composed are coarser and wider apart than those of CH. The shortness of the band, as given, merely arises from the circumstance, that at the point where it is cut off towards the violet side-—Green CH (when that is simultaneously present, owing to faulty chemical preparation of CO, or otherwise) comes in, and one band, after that, overlying the other produces confusion. The Upsala philosophers therefore did well, in picturing for green CO by itself, only that little bit of its Green band by whose small breadth it comes out from behind the bright beginning of Green CH ; forming in that way a tiny peninsula of perfectly pure Green CO illumination, which is already somewhat celebrated in spectroscopic story. A few years ago this peninsula was thought so. very narrow, or minute, a quantity, that it was proposed as a test, much better than the Micrometer measures of that day, to settle whether the carbonaceous spectra of Comets belonged to CH. or CO. In MM. Anestrom and THaten’s Index Map, the said little bit measures 0-23 of an inch broad, and the shading expended upon it does not claim to Db anything more than engraver’s ornament. In the larger plate of their Mesures Micrometriques the CO peninsula 0: Green measures 1°4 inches across, and shows 14 indistinct or roundet corrugations, or “ flutings ”” of surface. GASEOUS SPECTRA UNDER HIGH DISPERSION. 437 In my own finally reduced plates it measures 4°3 inches across, and shows no less than 44 distinct and positive lines. But in the original records of my spectroscope, and which alone I would desire to refer to now (see Plate LX XVIII.), the breadth of the peninsula is upwards of 26:4 inches; and though it shows only the same 44 lines just alluded to,—yet it gives them with a force, a character and an effect that can be attained on no smaller scale ; and was the practical mean by which many of them were first discovered to exist. Though speaking of these 44 luminous existences as lines, yet it is to be remembered that they are nothing but the linelets composing what appears in smaller instruments a smooth shaded band ; and with my largest spectroscope, it was the most extraordinary thing to contemplate the broad fields of absolute blackness that separated each one of these vivid, hard, sharp-edged, well-defined lines from its nearest neighbour on either side. Nor was it less instructive to use a tube containing both CH and CO; and then compare in the same field of view these two opposing principles, as it were, of the Physical world. The unoxidised against the oxidised; the fuel still to burn, against the refuse of fuel long since burnt; this latter the condition of the whole surface of our planet, rocks and water alike, excepting only its coal beds and a little amount of gold and other unoxidisable metals. The green CH band comes in (as will be very clearly seen in Plate LVIIL) just on the right of the green peninsula of pure CO; and with its doubled Green-Giant line of CH, shines gloriously enough, but yet with a suspicion of haziness along its edges; while its closely packed following CH linelets, though sometimes exquisitely defined, have something of a gossamer weakness and transparency of look. ‘They are like mere filaments of silk, or spider lines at the best ; and if doubles are seen amongst them occasionally, it arises probably from a process of decomposition having set in, or Hydrogen freeing itself from all earthly contamination; a liliputian curiosity in a vacuum tube, but the chief acting agent in the mighty red prominences of our Sun, and in the terrific conflagrations of so called new, or temporary, stars. With CO on the other hand, and its CO linelets, which are the best defined and hardest of diamond-like lines in structure,—if you see them once, you see them always; fixed like the rocks; or even growing in their places; for when once Oxygen has got hold of any Carbon, all the further actions of the illuminating spark seem only to enable it to go on taking an equally firm hold of all the rest of the carbon that may be within its reach. In fact, while the usual mode of failing for any CH tube by powerful Sparking is to end in its showing nothing but H lines, so for tubes containing | any compound of Oxygen, it is to finish by showing nothing but the CO spectrum. And if it has been said, that in the event of a solar conflagration 458 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF of this world, nothing of its solid material would be left, except atoms and molecules vibrating in the intense light and heat, we may be pretty sure that while Hydrogen would be dancing like the fire-fiend above tbe scene of destruction, the more stolid CO would dominate beneath. Its NuMERICAL EXPLANATION. But would such a reproduction of Nebular haze bring back the chaos, the confusion, of the Greeks; or would it be an entrance into a superior realm of law and order, in number, weight, and measure ? Let the 44 lines in this Green peninsula of CO, now first rescued from the very bad definition, uniform haze, and contracted views of the old observers,— answer for themselves. There are evidently amongst them, on the grand 26: inch scale, lines thick, and lines thin; lines single, and double, and triple; some expanding their distances apart in the direction of the violet, and others towards the red; there are places of unseemly crowding together of many lines, and other spaces which are comparatively bare,—in short, a careless viewer would pronounce at once for confusion. But having fortunately sent one of the ori- ginal, and raw, but large sized instrumental records to my friend Professor ALEXANDER S. HERSCHEL,—he was enabled by his experienced study of such phenomena to return in three days a demonstration, that each of those 44 lines was a necessary step in a remarkable system of physical numeration, proceeding in two rows of simple arithmetical progression, one over, but slightly - advanced upon, the other; not accidently or discordantly,—but so as to set forth the unit, the quinary, the decimal, and even the quinquagesimal standard of what may be now termed the CO system of linear construction. __ The success of this numerical demonstration, this extraction of scientifically ordered simplicity out of at first sight extreme complexity, may be quickly — judged of by reference to the large Plate No. LX XVIIL. prepared especially to show it; but more completely still, by reading Prof. A. S. Herscuer’s letters in Appendices Nos. I. and II. Their account is happily so complete, and so: independent, as to leave nothing further for me to remark upon here, except: observationally ; for theory in this case has given pretty certain indications that 8 lines out of the 44 which I have set down as single, are really doubles; but far closer than anything which I have yet been able to resolve. These cases must therefore be left to future observers, a test for their instrument to come; and a still further proof we may expect, when it does come, of the exact geometrical foundations of the very smallest components of the ultimate materials of Nature. GASEOUS SPECTRA UNDER HIGH DISPERSION. 439 REMAINING BAnbs oF CO. Of the Red, the Scarlet, the Orange, the Yellow, and the Citron bands of CO below that Green band which we have just been discussing; and of the Blue, the Indigo, and the Violet bands above the Green,—and which are all pictured in the Plates Nos. LVIII. and LIX.,—their linelets seem to have somewhat similar characteristics on the whole to those of the Green band,— but with compound variations,—not yet fully made out by observation. Nor | perhaps very soon likely to be much further elucidated, because (1) The dispersion of my present Prisms below the Green is too small; (2) Above the Green the definition is not sufficiently good ; (3) Towards either end of the Spectrum the illumination of my existing _ sparking apparatus is not sufficiently bright; and | (4) It is very difficult to get those bands perfectly free from impurities of | CH, H, and other gases. I will therefore at present proceed to a provisional termination of the CO subject, by means of a few words on some general characteristics of that | compound gas in vacuum tubes. | A small pressure of the gas, say 0°25 inch, seems to be most suitable for | securing a maximum of brilliancy conjoined to stability. For higher pressures, ) say 1 inch, 2°5, 5:0, or 125 inches, simply show the same spectrum, but fainter and fainter as the pressure is greater; while lower pressures, say 0°1 inch or under that, though exceedingly brilliant for a time, are very apt to get their tubes overheated and loosened at their electrodes with loss of illuminating | power altogether. To prevent this catastrophe, the electrode ends of the | tubes, whether with platinum wires as usual passing through them, or coated only with a film of silver outside, have been made to dip into vulcanite | insulated basins of water, and receive their electric charge from thence ; but | the illumination was never at its best in that manner, the whole apparatus | sometimes became inconveniently charged ; and with the silver coated tubes, | the glass was actually perforated sooner or later. Some of the best exhibi- tions, however, of the CO spectrum, have been the unintended ones; as of tubes prepared with Oxygen alone; and showing at first the Oxygen spectrum, but that changing during use into CO; and always more and more quickly or inevitably, the weaker the pressure at which the Oxygen had been sealed in. Whence comes the C for this transformation of O into CO? Some persons have suggested, from the use of a coal-gas, in place of a | hydrogen, blow-pipe in working the glass ; and an extraordinary hypothesis has been recently started in Germany, of Si being convertible into C in vacuum tubes.* * The following note has been furnished to me:—‘‘Herr WrssenpDonx«K prepared Siliceous gas with most scrupulous care and purity, without being able to obtain a trace of Silica lines, only CO bands over and over again, and more and more brilliant the purer the gas he used. Silica could never be found, VOL. XXXII. PART IIL. 4:18 440 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF But my own idea is still, that it may be owing to the electric spark’s power of convecting C along its wires; and then, not merely because such wires are usually coated along their whole length with an easily melted material so rich in C as Gutta Percha,—but because the Induction coil itself is, throughout its chief bulk, little but a huge mass of soft C; and the rolled up insulated wires inside it, make it a perfect ganglion for accumulating all possible transportable atoms of that element. Some small spectroscopic evidence in this direction too, is already in print; as thus, plate i. of M. Lecocg DE BorsspAupRAn’s admirable book Spectres Lumineux gives two pictures of the electric spark in open air; one near the positive, and the other near the negative, Pole. They both of them exhibit chiefly the well-known low-temperature Nitrogen bands; but the latter, or Negative Pole’s end, has a glorious distinction from the Positive’s, in this, that it has also a very strong violet line, the a, or chief of the whole — display, which does not belong to the simple Nitrogen’s or to the Air’s low- temperature spectrum at all; nor to their high-temperature spectrum either. To what then does it belong ? According to my earlier and perfectly mdependent “gaseous Spence paper to this Society in 1880, it is the characteristic line of Cyanogen, or Carbon combined with Nitrogen, the chief constituent of our atmospheric air. Carbon vapour then added to the spark which is producing the Nitrogen — spectrum in the open air, can hardly but produce this Cyanogen leading line; and such Carbon can be obtained by the electric current from nothing so readily as the gutta-percha, vulcanite, and waxed, or resined-paper interstitions, which form so notable a portion of every Induction coil. But as I had an opportunity of setting forth something of this view in - Nature journal last year, assisted by a woodcut of the spectra,—I here close this part of the present paper on the two compound and opposed gases, CH and CO; in order to proceed to the next part treating of the three elemental gases H, O, and N. PARTLY, THE THREE ELEMENTAL GASES, H, O, anp N. SuBJECT 1.—H or HyYpDROGEN. There is little trouble in procuring good H tubes; and they are such excellent illuminators as to get the better of all ordinary impurities, espe- in any quantity to speak of ; so it could not have come out of the glass. SiH, and Sif, were used (very easily prepared pure) CO was the only result he could possibly obtain. That, always that.” GASEOUS SPECTRA UNDER HIGH DISPERSION. 441 cially with time and use; and show at last nothing but the Hydrogen tube- spectrum with brilliancy and certainty at any pressures between 01 and 0°5 inch. One particular impurity, however, has to be guarded against; for its lines though few, are strong, viz., Mercury,—whose vapour always has a chance of entering, in connection with the Sprengel air-pumps now so generally used in the exhausting operations. To this end therefore some tubes specially contain- ing Mercury have been made for me in Edinburgh by Mr W. H. Suarp (of Kemp & Co.), and have furnished the Mercury low-temperature spectrum which appears as No. 13 in the second division of my Index Map; and will enable any one with great ease to eliminate Mercury, from the H, lines ; espe- cially if they try it at various lamp temperatures. But not a great deal has yet been written on the tube, or “low electric temperature,” H spectrum, though every one knows about the 4 grand lines in its high-temperature spectrum, and which reappear in the tubes, together with all their low-temperature lines. MM. Ancstrom and THALEN, for instance, are silent on the subject in 1875; and still more remarkably Hydrogen does not figure in the otherwise very comprehensive list of gaseous spectra treated of by the British Association’s Committee’s Report of 1880. Fortunately these low-temperature Hydrogen lines attracted the attention several years ago of the savants of the Imperial Central Observatory of Russia at Pulkowa; and Dr HassevzereG, their chief spectroscopist (a former pupil too of M. Anesrrom), entered into the subject with intense enthusiasm. He had begun with other gases, but soon alighted, as I had done in my paper of 1880, on the existence of low-temperature lines, as an addition to the well-known high temperature spectrum of 4 lines only for Hydrogen. He found them too so invariably in any and every mode of preparing Hydrogen gas, that he concluded they must belong to it alone, and under such impression prepared a map of them about 18 inches long, with three of the four great lines intro- duced amongst them. But that size of map he afterwards considered did by no means do justice to the richness of this H spectrum, wherefore he laboured again with new prisms; and in the course of last year, published with the Imperial Academy of St Petersburg, a new map of Hydrogen “tube” lines by simple electric spark, or the many low-temperature + the few high-temperature lines ; the map having a length altogether of nearly 90 inches from the Red to near the Violet line. This last map of Dr HassELBerc’s is a very grand work as compared to anything yet published, either on the H, or indeed any other, gaseous Spectrum; and it will doubtless be long regarded as a high authority for the absolute spectrum place of the lines which it contains. 442 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF Hardly so, however, for either the number or minute physiognomy of most of its lines; for whereas the Doctor begins the low-temperature H lines far within, or above, the great Red Hydrogen or C line of the Sun,—I have found them commence far without, or below, Red Hydrogen ; continually increasing too in brightness as they pass that line, and at length join on to Dr HasseEz- BERG'S earliest lines, which are with me very bright. And then again, his scale of 90 inches must necessarily fall lamentably short of a 480 inch spectrum, when it is a question of detecting a close, double, or triple, hitherto recorded as single only. This indeed by itself might have been got over, or apologised for; but unhappily the laborious author has allowed his engraver to exert his own taste in doubling and frebling the chief part of his principal lines, and even making a banded group out of the grandly single line Red H, in a manner, and to a degree which must entirely mislead the spectroscopic searcher after micro- metrical truth. Now my own original measures of this spectrum, though they cannot pretend to compete with his for accuracy of absolute-spectrum place, are on such a scale that from the earliest Red to the Hydrogen, Violet occupies as I have already mentioned, a continued length of 120 feet. So that if, in this grand hall, you imagine the spectrum strip to begin over the President’s Chair, and extend thence continually towards the right, the red and scarlet would reach the end of that wall, the orange would cross that end of the room, the yellow, the citron, the green and the glaucous would occupy all the other long — side of the room, the blue would cross its further end, and the indigo, the violet, and the ultra violet would come back and overlap very nearly the beginning of the spectrum’s scroll right over the President’s head. Along with that immense length, truly immense considering it is merely a magnification of a slit about 3,5 of an inch wide,—you would see nothing of bands of CO with their orderly, closely set regiments of linelets, nothing of the leading lines and fainter linelets of CH,—but only lines and lines and lines again, free, easy and distinct of H. There are some 1625 of them absolutely recorded at the instrument; generally they are brilliant, well-defined, showy lines; nowhere very closely packed, but forming all the way along an- independent kind of open groups, which have perhaps a certain kind of family resemblance among themselves, but with never any precise repetition between one group and another, either of its strongest single lines, or the occasionally exquisite doubles or trebles which try all the powers of the best spectroscopes yet made to resolve them. In short Hydrogen, in between the positions of its four grand high temperature lines, shows in these almost endless low temperature lines of the tubes, nothing but a saltatory sort 0 movement, such as an ariel sprite might indulge in, and such as does typify the GASEOUS SPECTRA UNDER HIGH DISPERSION. 445 taste or the instinct of Hydrogen to shake itself loose from all terrestrial matter, and rise above all the other elements the lightest and most ethereal of them all. But my apparatus is still so far from describing all that Hydrogen has to show, and which future observers may discover,—one does not know how soon,—that I make no attempt in the present state of the question to try to develop the kind of order on which its arrangements are founded ;—but would beg leave to call attention; by its means, to a general feature touching definition in all bright-lines pectra, viz., excepting some of the fainter lines in the ultra Red, the definition of Hydrogen lines is inimitably fine and sharp through the red, scarlet, orange, yellow, citron, and green until we come near the blue, where a little falling off sensibly occurs. In the further Blue and the Indigo the defalcation increases ; and in the Violet becomes unbearably offensive ; so that what should be a sharp line of light, becomes more like a dull, broadened, or diffuse woollen cord or hazy band. Is this change which thus supervenes on approaching the Violet end of the spectrum, a fault of the instrument ; or a quality of Nature ; or a failure of the human eye ? Not a fault of the particular instrument built up by me in rather rough and economical fashion, because I have met the same principle of effect in every spectroscope I have looked through,—even including that charming instrument, the Cooke-Monckhoven spectroscope of Professor Tart’s Natural Philosophy Laboratory,—a spectroscope whose every adjustment is carried out to perfec- tion, and where nothing seems to have been omitted or neglected. Nor is it a necessary, and innate quality of Nature; for exquisitely defined spectrum lines in both the Violet and ultra Violet regions are said to be obtainable, and have I believe often been obtained, though not by me, in the medium of Photography. Then the failure must arise in the eye. Yes, in.the human eye and its total inability to distinguish between Violet as it is in the spectrum, and every Other so-called Violet colour under the Sun. For these, so far as I have yet ‘examined, whether in chemical solids, or fluids, flowers or stained glass, are jnothing but a mixture of blue and red; and are allocated to a totally | different mean spectrum place than that of violet, by the more than man’s dis- criminating power of either the prism, or a diffraction grating. In fact, except for the purpose of establishing a sort of border neutral , territory, where eye-results may be compared with the blackened imprints on | bromo-iodide of silver, so extra sensitive to violet light,—no eye observations |should be trusted for minute features and full effects, much beyond Glaucous | Hydrogen,—for there Photography can be brought in with advantage, and probably will be, before long for everything, by those eminent scientists who 444 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF have of late employed that method in their own special researches, but usually on a far too miniature scale to satisfy present requirements. SuBJECT 2.—O oR OXGYEN. With this gas comes in a change; a relief perhaps to many persons after the growing complexities of other spectra. So far at least as the O spectrum has yet been seen and published in vacuum tubes, it is simplicity itself; and though called “the compound-line” Spectrum of Oxygen, that name was given to it merely in deference to a theoretrical idea, in accordance with which the lines owght to have been compound; or at all events totally dissimilar to what has been termed, by way — of pre-eminence, ‘the line” spectrum of Oxygen ;—because that is what results from the high temperature of the jar, or condensed discharge of induction sparks,—in contradistinction to the low temperature, or direct discharge, of the simple spark, which we are now dealing with. Of this low temperature, “called” compound-line, Spectrum of Oxygen then it is, that the British Association’s Report speaks, when it declares it to consist of four lines only; one in the Red (or Orange rather), two in the Green (or rather one in the Citron and one in the Green), and one in the Blue (or rather — between the Indigo and the Violet); but the spectrum places of all four have been accurately measured in Wave-lengths, so that they can be easily identified by any one. | A. gaseous emission spectrum then, consisting of four widely apart lines only, must surely be as simple as any one could desire;. and the statement is founded on very high authority, viz.,.a paper by one of the British Association’s Committee, printed by the Royal Society, London, in 1879. The author of it too, —being one who not only “ fills his own gas-vacuum tubes,” but who launched the depreciating accusation against me that I did not perform that operation for myself (pp. 11 and 12),—I shall hardly be allowed, by either of those two great English Associations to put forth any accounts of more lines than their four; and yet, if my mode of arriving at more than four had been dependent on my filling my own tubes,—would there not have been a chance of my being com- pared to that publie lecturer who, about half a century ago, in London, under- took, in defiance of the doctors, to drink off half an ounce of Prussic Acid, ot deadly strength according to the Pharmacopeia, but stipulated that he must prepare the fluid himself! | : Before relating however what I have found, and how ; viz., by open methods which should bring out the same result in whatever part of the world they are performed, and have brought out the same in the hands of both French and English workers ;—there is something more to be precisionised in the Royal GASEOUS SPECTRA UNDER HIGH DISPERSION. 445 Society’s printed paper alluded to. The letterpress thereof certainly speaks of four lines only, and gives the places only of 4, in figures; but in the map accompanying them they are made into 8; viz., each line of the four is made a double line; two, much more distinctly so than the other two. It is not for me to pronounce on the accomplished fact of the Society’s thus doubling the number of lines in a very scantily furnished spectrum; and making the original single lines of observation conform more nearly to the theory they publish, by representing them ‘‘ compound” to the extent of doubling each one,—but it is absolutely necessary for truth’s sake to warn all into whose hands the Philo- sophical Transactions may come, of the absolute falsity of the (London) Royal Society's Oxygen spectrum plate, in that respect. The talented author of the paper, moreover, has never claimed to have seen more than four single lines, placed as described; has made an immense number of most admirable experiments to assure himself that they belong to pure Oxygen, and not to any accompanying impurity,—and that there is nothing else in the O spectrum of equal visibility. That degree of visibility however, being something very small; for Oxygen gas is what is generally known, as a bad illuminator, in all vacuum tubes. There then, with only jour truly observed lines, the tube spectrum of Oxygen might have remained, had I not in 1879, independently of the late energetic Dr VAN MonckHoveEN, both struck, and worked out, the idea of using vacuum tubes end-on, in place of transversely to their capillary part, as others seem to have done universally before that time; some of those earlier observers even using the tube’s upright line of light, in place of the slit of a spectroscope proper. But with the new end-on vacuum tubes, and equally when they were made for me in Paris, or in London, I immediately, through the greater bright- ness of their light, saw the presence of many fainter features constant in, or evidently belonging to, the O Spectrum of the four lines. First, for instance, I found that three, out of the four, primitive lines were, each of them, a triple. Each triple a long way from its nearest neighbour, but of precisely similar build; and I have since then discovered three other such | triples, one of them further away towards the Red, than the longer known ee ae > Orange one; and two others further towards the Blue, than the older Green one. They make moreover a remarkably connected, though wide apart, and only faintly luminous system altogether, extending through so great a range of the Spectrum as from Red to Glaucous; for the six triples are arranged in three pairs, whereof the mean place of the third pair is from the mean place of the second pair, close on half the distance that the mean place of the second | is from the mean place of the first; while at the same time the much smaller distance apart of the sixth triple from the fifth is just about half that of the 446 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF fourth triple from the third; and that is again about half that of the second triple from the first. And finally, to carry the principle still further into details, but these details supposed to be more nearly eternal than worlds, — and suns, and stars,—in each of the six triples the third line is about half the brightness of the second, and at half the distance from it, that the second line is from the first line. Indeed the characteristics of an Oxygen triplet are so peculiar, and so closely adhered to in every instance, that I have been able in some tubes swarming with lines of impurities to pick out an Oxygen triplet, as easily as one would distinguish in a crowd of civilians, a soldier with cross-belts and — scarlet coat. Although then there is so little show of general light in a pure Oxygen tube, geometrical order is preserved there amongst such lines as it does show, most rigidly. So that while Hydrogen, with its multitudinous, brilliant, varied lines dancing or vibrating through the whole length of the spectrum, may be likened to a big, curly-haired, Newfoundland dog, bounding about and barking at its own free will,—Oxygen is a Bull dog which, without any show, runs straight to his quarry and holds him fast with an iron grip. This view, moreover, trifling as it may appear, comes out more notably still, when we attend to the many single lines which there are, after all, in the Oxygen spectrum, and are shown both in my Index Map, and the larger plates, Nos. LXVI., LX VIL, LX VIII, and LXIX. For, in spite of its faintness of light, Oxygen in the spectrum actually outflanks every other gas. That is to say, it begins with a very well marked and sharply defined line, further away into the ultra-red than any line, band, or haze of any known elemental gas. This same lowest line too of the O tubes appears to be identical with the most red-ward line in the jar-discharge in the open air, as described in my recent paper to this Society on BrewstTEr’s Solar line Y. SuBsecT 3.—N or NITROGEN. This is the last gas I have observed on the present occasion, and its spectrum is in many respects the most mysterious, and most multitudinously lined of all, when seen with great dispersive power; for otherwise, it is an affair of hazy bands alone. Just as it was with O, so here, mutatis mutandis is it with N, that a condensed induction spark, or jar-discharge, discloses the high-temperature, line, spectrum of the gas; and if the two gases be mixed together as they are in the atmosphere, the same discharge shows the line spectra of both gases overlying or multiplying each other; as may be seen in the upper portions ol of the Index Map; forming hazy lines when in a dense, sharper lines im 4 = B.- F GASEOUS SPECTRA UNDER HIGH DISPERSION. 447 rarefied, medium; but evidently the same linear spectrum in each case, and of but a few, say a score or two, lines even at brightest.* With the simple or direct spark on the contrary in the open air, those two spectra vanish, and are replaced by other two, perfectly different; whereof, as just described, that of O is barely visible to moderate power, even in its isolated compound triples or the stronger of its single lines lately discovered; while N is heavily conspicuous all along the spectrum in the shape of a closely packed arrangement of numerous, narrow bands. In a vacuum tube of N alone this arrangement is still more brilliant, is generally known as “the band spectrum of N,” and “is one of the most beautiful,” says the British Association Report, “which can be observed.” The best map of it I have yet seen is that in ANGsTROm and THALEN’s paper of 1875; a map about 27 inches long, and exquisitely engraved; i.¢., so far as engraver’s work alone is concerned, for the vertical limes wherewith the bands are shaded are engraver’s ornament only, and have no pretension to represent- ing lines seen by the observer. But with this reservation accepted, the map effectively reproduces all that was known of the spectrum until 1880; when Prof. Avex. 8S. HerscHEL communicated to this Society some notable exten- sions of the spectrum into the ultra red, which he had just then made with my Spectroscope as it then was, or merely in a pretty good condition. His whole conclusion I believe was, that he could identify many more of the narrow bands of N, in that lower region, far beyond or outside the place where the first of THALEN’s pictured bands begin. And he could even trace them up to a place where a triplet.of sharp lines shot up, and seemed to form a sort of fountain head, whence had flowed down the continued stream of Nitrogen cross-bands all through the Red, the Orange, the Yellow; and the Green of that spectrum. . With my present improved instrument, and several new and exquisitely pure tubes of N prepared for me by both M. Demicuet in Paris, and Mr CaseLLa in London, at various pressures between 1:0” and 2°5”,—I have been enabled somewhat to modify the above view, as thus,— (1) The band spectrum of Nitrogen, even in those brilliant colour regions Just cited, is by no means one uninterrupted series of similar bands,—but is a succession of four large groups of bands; each group bringing in with it slight variations on the preceding one, and separated from its neighbour group on | either side, by a tolerably distinct breadth of 2 or 3 bands of weaker action. (2) THALEN’s first band, though no longer to ‘be regarded as the first band or beginning of the N spectrum, is yet the first band of its own, or the Red, p group; which we may therefore worthily denominate THALEN’S group. * The manner in which the Red Hydrogen line comes into that Spectrum, is very striking, and I have not yet seen a good reason given for it. VOL. XXXII. PART III. 4c 448 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF (3) Outside and far away into the ultra-red, more N bands do extend, as Prof. HERSCHEL saw; but they form a group of their own, beginning in faintness far beyond Prof. HERScHEL’s triplet of lines, or anything that he saw; rismg in — intensity of light and markedness of physiognomy as they pass that triple of — his, and finally subsiding again very materially before they join, but unsymmetrically, the first band of the THALEN group; for which features please to examine, first the Index Map, and afterwards Plates Nos. LXX. and LXXL (4) Prof. Herscuet’s triplet of lines is however a very interesting existency, with nothing else like it through all the rest of the N spectrum, and with these two following features in addition,— (a) It is shown only, so far as I can make out, in N tubes at very small pressures, say under 0°1”; for brighter tubes as to the bands but at greater pressures, say 0°5” to 2°5” show nothing of it. (b) This triplet of lines, so anamolous in the tube, and unsymmetrically placed as to the bands of the ultra-red group which pass in front of it,—is nevertheless owing to the N gas; for it appears to be identical with the triplet of lines which I discovered last summer in the jar discharge in the open air. The one line seen on that occasion outside the triple, has since then been — identified with Oxygen; but the triple having no resemblance to anything in that spectrum, can hardly be of any other than N material, and may be deservedly noted as HerscueE’s N triple. If the large Plates of the N spectrum, Nos. LX XI., LX XII, and LX XIII, as observed by myself be now examined, it will be seen that THaLen’s Red series of bands opens a more brilliant portion of this spectrum; and one which, in and after its third band, effloresces into almost an infinity of the closest and most exquisitely defined lines and linelets that were ever packed into a telescopic field of view. Nor were they all revealed even then, for amongst them seemed to be doubles, or other multiples so exceedingly close that they passed the power of my spectroscope, even at the best, to resolve with certainty; and how many degrees further their intricate refinements of structure extend through the residual haze, of which a little still appears,—it is dangerous to speculate. Had it not been for the method I elaborated of recording any number of micrometrical places of lines consecutively, and without taking the eye away from the eye-piece,—the attempt to note the exact place of each and every one of such legions of lines in the usual micrometrical manner, would have been hopeless ; for at the average rate of closeness of those which I could separate, there are probably 4000 in the first half of the N spectrum alone. The brightest example of the N tubes, viz., one at 0:1” pressure, brok down, I regret to say, early in the work, or when I was using it near the - GASEOUS SPECTRA UNDER HIGH DISPERSION. 449 region; the rest was therefore recorded by means of a 0°5” pressure tube, compared occasionally with 1:0” and 2:5” pressure tubes. Of the gradual swellings and subsidences of brightness in each of the four long groups of bands (the red, the orange, the yellow, and the green), and the minute variations introduced into the composition and settings of the linelets forming all the several bands of one group, compared with all those of another group,—the Plates Nos. LX XI. to LX XIV. will give a better and quicker idea than verbal description. And they will also indicate well the immense change which comes on in the Glaucous region, making the rest of the Nitrogen spectrum, through the Blue and Violet an utter contrast to its earlier appear- ance from ultra Red to Green. This difference is marked strongly in ANGSTROM and THALEN’S map, in so far as those classic authors represent the Blue and Violet bands much broader than the Red and Yellow. But they have wholly missed the club-like, or fascicular, groups of lines with which each such Blue or Violet band com- mences. I have had therefore to alter my Index Map considerably from theirs, in order to represent this most innate and valuable distinction, as it appears to me, of blue N, from blue CO, bands when in close neighbourhood. And the minuter construction of these clubs of lines may be made out pretty well in the larger plates of N, as Plates LXXV. and LXXVL., notwithstanding the characteristic bad definition of any and all spectral lines in the Blue and Violet. There is another peculiarity, however, well worthy of note in these more refrangible and very broad bands; viz., that there is another class of bands with sharper beginnings mixed up with them; and these additional, or smaller featured bands (unnoticed I believe as yet by other spectroscopists), are more constantly and certainly seen in tubes prepared for N, than those prepared for N,O, or Nitrous Oxide. Or, in other words, the N,O Spectrum is simpler than that of N; though the chemical notation as it stands now, is more complicated. But I have no maps of the Nitrous Oxide spectrum to show, on account of all the N,O tubes, after a preliminary eye survey had been taken, having gone wrong spontaneously, while I was observing those of N; and I had no more funds for further tube making. My present task therefore is finished, save a few words, or perhaps mere conjectures respecting the possible chemical origin of the spectra just described for THe THREE ELEMENTAL Gases, H, O, anv N. 450 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF PART V. ConcLupInc Notes ON THE ELEMENTAL Gases, H, O, ann N. If in the earlier part of this paper, we found it expedient to admit that the — two separate spectra there described were the spectra in each case of a compound Gas, viz.; the one of CH and the other of CO; and to some degree because the high-temperature or jar discharge gave a totally different spectrum to C alone; is there not something rather similar to be said touching the spectra we have just been describing for H, O, and N, though they are simple and elementary gases according to the Chemists ? . There is at least in so far, that if we try said reputed simple gases, not with the weak direct spark which we have been using all along, but with the intensified or jar discharge, there is introduced for each of them a totally different spectrum from that which we have been describing. But why, in that case, are our tube spectra of those gases not ascribed to compounds of each of them with some other, in place of being confined to the one gas alone ? Partly, I imagine, because no one knows at present what the other component may be. And partly because there is a very conveniently classifying theory for use in the meantime, which sets forth how one, simple, elemental gas may have two or more different spectra under different temperature circumstances; granting always that it exists as a gas at those temperatures, and is not, like Carbon, inert and solid at all but one of them. M. THALEN has controverted the multiple view for gases in general, not only on the grounds that his deceased, revered, and loved friend M. Anastrom held that each chemica] element cowld have only one spectrum under any, or all, circumstances (though how proved is not stated)—but considers he has demonstrated that the low temperature or “ Band-spectrum” of Nitrogen, is the spectrum of the bi-oxide of that gas, and not of that gas by itself. In 1872 (Proc. R. Soc., xx. p. 482) Dr Scuusrer, the able writer of the Report for the British Association Committee in 1880, held a similar view. But in 1880 he repudiates the idea, and states that no emission, or bright, spectrum has yet been found that can with certainty be referred to a compound of Nitrogen and Oxygen; so that he restores the “ gorgeous Band-spectrum” to Nitrogen alone ; its /ine spectrum at higher temperature notwithstanding. Dr ScuustTer is also the hero for claiming the particular Oxygen spectrum we have been describing, viz., the spectrum of minute triplets and a few thin lines, for Oxygen alone; calling it the compound-line, or low-temperature, or simple-spark, spectrum of that gas; but without invalidating in any degree its claim to the strong Line-spectrum which it shows at high electric temperature, GASEOUS SPECTRA UNDER HIGH DISPERSION. 451 And Dr HAssELBerG seems to perform a somewhat similar part for Hydrogen, excepting that there, the high-temperature lines are seen simultane- ously, or together, with those of the low-temperature spectrum. Of these three elemental gases, all of them equally and similarly disputed upon, the case of Oxygen is perhaps the most advanced and instructive. _ With simple, direct, uncondensed induction sparks, passing through an Oxygen vacuum tube, every one allows, or will allow I hope after reading this paper, and severely experimenting, that he does, as he should, get that spectrum of minute triplets which I have been describing here at length. And every one also allows, and has allowed it for many years past, that if you send a suffi- ciently condensed, intensified, jar discharge of induction electricity through the same tube, the spectrum immediately changes to something perfectly different, viz., the high-temperature, or line-spectrum of Oxygen, as set forth on strips Nos. 7 and 8 of our Index Map, Plate LX X VII. The facts therefore are allowed, and it is only the interpretation of them which is different with different parties. One side insisting on a different vibration of the same particles of Oxygen, under the two kinds of electric sparks, being the only reason of the two totally different spectra; and the other declaring that with the milder spark, the Oxygen must have entered into momentary chemical combination with something else that was already in the tube, but unperceived by, and totally unknown to, its owner. There is little doubt too that there may be many more infinitesimally small things in a tube, or extractible out of its sides by electric discharge, than chemical philosophy is at present aware of. While even with so gross a matter, as CH in sufficient quantity to give strong spectral bands,—we have seen London scientists going on for years preparing CO, and quite unconscious that they were at the same time manufacturing CH with it, even pari passu. Some particular kinds of gaseous impurity that may be in a tube, adhering to its sides or otherwise,—I have shown in this paper may be easily submerged by | greater density of another gas thrown into it. But if that gas be contaminated at its birth with some other, either not yet recognised by Chemistry, or in too small proportions to be detected by any existing chemical method,—who shall help! There may have to be a new chemistry elaborated, dealing with infinite- simally small combining quantities. But that is something so hazardous to count upon, that we may well in the meantime accept the varying temperature vibration theory, as a mere method of classification; and then we shall find that there is an immense deal yet to be done, in order to collect even the plain and practical facts of the spectra of the best known gases, in such degree of purity as they can be prepared in, at present. For with every elemental and permanent gas, 7.¢., gaseous at all known temperatures and moderate pressures,—there seem to be three different temperatures under which its spectrum in some 452 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF shape may appear, viz., the temperature of the condensed spark, the simple spark and the atmospheric or auroral. With compound gases, there are only the two latter temperature stages, viz., the simple spark and the cold auroral; for the high-temperature condensed spark resolves them instantly into their known chemical components, which then give out their own elemental spectra. While with Carbon, and every other similar solid, there is only one temperature stage; viz., that highest one at which alone it can be volatilized. To return then to the elemental and permanent gases, as the commplente system, how little do we know yet of all three varieties of spectra belonging to any one of them;—not to say anything of each variety, in order to be fully understood, requiring to be made to appear /i7'st as an emission spectrum with bright lines in a dark field, and second, as an absorption spectrum, with the same set of lines but dark in a bright field. Suppose we take Oxygen again as an example. 1. Its emission spectrum of bright lines in the condensed spark, or jar discharge has been grandly studied by Kircuorr, THALEN, Plucker, and Hucerns in long past years, with a most satisfactory cataloguing of Wave- length places again and again,—and yet it was left for me to discover the earliest of its ultra red lines last summer. But no one has yet seen either that line, or I suppose most of the others, as dark, or absorption, lines; though Professors Liveinc and DEwAR are now working at that subject, and towards that end very magnificently in the Cavendish Laboratory at Cambridge. 2. Oxygen’s emission spectrum in the simple spark, viz., the spectrum of minute triplets and a few thin lines, has been set forth in this paper at some length, though elsewhere, and particularly in London, only 4 lines of it have been recognised ; but none of them have yet been seen by any one as a dark absorption spectrum, so far as I am aware.* 3. At the atmospheric, the cold, or auroral, temperature no one has ever yet seen any bright, or emission, spectrum of Oxygen. But two persons are said to have recently seen its dark, or absorption lines connected with that very low, or non-fiery, temperature; and it came about in this manner. After I had for years and years besought, but in vain, the rich London Societies, or the Government to make the enormous experiments which are necessary for the purpose,—these have recently been made in St Petersburg! There, in connection with the University of that city, M. Ecororr, with his. friend M. KHAMANTOFF,—so far as we can trust the rather too scanty informa- tion yet given out,—established a horizontal tube 66 feet long with glaze *T thought, on the first discovery of 3 of these triplets, that they could be recognised i Anestrom’s Normal Solar Map as dark Fraunhofer lines, but I delay now either affirming or refuti that idea, until I have made more satisfactory and exact observations on the Solar Spectrum itself. GASEOUS SPECTRA UNDER HIGH DISPERSION. 453 ends; filled the tube with pure Oxygen gas at several atmospheres pressure, looked into it at the near end with a powerful spectroscope, while an incandes- cent lime-light was placed outside the other end ;—and then, pictured on the bright continuous spectrum of that light,—they inform us they saw and measured certain most distinctive bands and groups of dark absorption lines. These were totally different in both arrangement and spectrum place from any of the bright lines of either the high-temperature, or low-temperature, spark- ings already described for Oxygen,—but they were held, nevertheless, to be Oxygen lines, because they were only seen when that one particular gas, in 'immense excess, was introduced into the tube ; while there was quite lowering enough of temperature between the simple induction-spark and atmospheric temperatures, to permit of another kind of gaseous vibration being set up, if that was already allowed to be possible, between the simple, and the compound, spark, by reason of the latter’s superiority therein. The special interest, however, of the St Petersburg experiment, if confirmed, | depends still further, and more pointedly, on this other observational fact; viz., that the dark absorption groups which MM. Ecororr and KHAMANTOFF saw in their Oxygen tube they declare to be identical in build, and spectrum place, | with the powerful groups of similar dark absorption lines, telluric chiefly, but perhaps partly Solar, or extra-Solar,—seen by all the world constantly in the |} spectrum of the Sun’s light, and so well known there as FRAUNHOFER’s great | A and great B. While still more recently M. Cornu in Paris, by an exceedingly elegant method of his own, having lately succeeded in eliminating from the a (Alpha) band of the same Solar spectrum, both the Solar metallic and the terrestrial water-vapour lines, found the residual markings so exactly the | counterparts of the now thoroughly understood geometrical construction of the preliminary bands of great A and great B,—that he can pronounce with the utmost certainty for their being all three born of one and the same kind of | gas ; though whether, after all, that gas be really Oxygen, the world will be better instructed when other physicists have repeated the bizarre experiments of the Russian capital, and vouched for the purity of the gas introduced there into the long tube. Even concerning Oxygen then, our knowledge is but rudimentary, and in fragments; while of Hydrogen, and Nitrogen, how very little have we yet seen of one, possibly two, of the three double phases which the temperature theory | indicates must belong to every one of such permanent gases ; and all of whose phases too, our observations in this paper promise will be found replete with the most exact Natural writing, whenever they be efficiently and sufficiently interrogated by man. 454 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF > He eg agp gt 8 a aaa PROF, ALEX. 8. HERSCHEL’S LETTER ON THE GREEN BAND OF CO, AND ITS EXPLICATIONS (EVENTUALLY CONDENSED INTO PLATE LXXVIIL). Dated November 20th, 1883 ; College of Science, Newcastle-on- Tyne. The chart of the green band’s lines* is beautiful; it is quite a page of the spectrum itself much more clearly laid down, I am sure, than I have ever seen the tribe of linelets, and I’m astonished how you can have both discovered and plotted so many perfectly ! You have far surpassed the sight you gave me last, I find, of the CO band, by dividing “broad” and plenty of the fine lines too, into pairs and triplets. This is a real triumph, that I couldn’t well believe possible, when i discovered it by trying to recognise your new map in the drawing and measures that I took of SALLERON’s CO tube’s green band (with five Sulphide of Carbon prisms) in December Jast; and couldn’t make them fit immediately, until I found that you had duplicated and triplicated numbers of the lines that I recorded “ broad,” “ winged,” “united pair,” &c., only, so that there is a profusion of new dissections of the band that you have managed now to supply for its anatomy! And then Ilo TrIUMPHE! in searching over the spaces of my “readings” to identify your lines with, I lighted luckily on the key of the construction, which is simplicity itself, and couldn’t well be exceeded in the exactness with which your new map reveals it! Lux in tenebris, what a happy and glorious release you have disclosed to all our uncertainties ! a_i a a a I grounded first on this palpable feature of themeasures [| * | ise | [ile | [\ |, that while the “leaders,” and twin-cub followers open out regularly all down the range, it is. not so between the twin-cubs and the leader neat following them, so that the distances a remal n constant, varying from 0159 revns. to 0172 revns. in my readings without any symptoms of expanding, as far as my list went; so that these “leaders” are simply accompanied on the pre- ceding side by a companion pair that is at an invariable distance from them! In other words, the “leaders” form a scale-in-chief by themselves, and a little distance preceding it is just such another scale of fainter twins, overlying the former scale. How will this relationship, I asked myself, be borne out 7m the thronged part of the band between its front edge and the “ crossing ” point, beyond which point as far as the “ green giant,” it is as plain as the alphabet ?—The answer was to take up the constant distance a between any * This was merely the raw record-slip taken at the Instrument, in the manner which I specially arranged for all the Spectra described in this paper.—C. P. S. ; GASEOUS SPECTRA UNDER HIGH DISPERSION. 455 leader-line and its precursor shadow-pair from any good specimen conjunction of them on your rap, and to apply it successively to all the leader lines from near the “green giant” backwards across the crossing-point and on into the thick of the mélée that precedes it, right up to the first edge of the band. The result was, to my joyful surprise that it accownts instantly, and in toto for every single line of the band laid down on your map! The band is simply two exactly similar single-rank line progressions laid over each other displacing one of them slightly on the other; and while one consists of single strong lines, the other is formed of fainter, closely double ones. You will see this by the enclosed card strips* along the top edge of one of which your map of the band is exactly copied, while under it the members that compose the close double, or fainter series are prolonged so as to produce a linelet progression by themselves. On another card the rest of the band’s linelets are figured, also in a single-ray progression of (in red ink) strong single lines ; by applying this card with its left hand leader at No. 5 line of the natural delineation, you will see that it includes all the lines not prolonged downwards or abstracted from that stripe to form the partial stripe of duplex lines; and by then shifting it leftwards till its beginning coincides with No. 1 line of the natural band, you will see too that it then exactly covers all the duplex line series of the natural band. Besides the two constituent bands’ precise resemblance to each other, there is also this link of connection between them, that the ruler of the following band is not placed anywhere, | but on Wo. 5 line of the foremost one. And again there is this simplicity about the single- | rank or partial bands themselves, that their intervals are quite distinctly an arithmetical | progression of spaces denoted by the series of natural numbers 1, 2, 3,4, &. I have plotted | in, under each (singular and duplex) portion of the band a ¢rue simple progression of this kind, | so that the eye can judge how nearly each of the two tributary bands satisfies it, and there is no question, I think that it is, with some very slight disturbances here and there, the simple tule of formation of them both? Instead of being, therefore, a linelet band of the most curiously involved compleaity, as it at first sight looks by its “ crossing” lines and close pack of crowded lines near the front edge, the ruled CO green band is really the very simplest in its | mode of construction that I think has yet been met with in Spectroscopy! The way in which | your sharp resolution of the two “crossings” lines themselves into a minute triplet and a _ minute doublet respectively agrees with the conjunction is by itself a wonderful corroboration of the structure. But without the clear and precise resolution of all ats lines throughout with the most accurate autographic measurement that you have effected, it would evidently have been quite impossible to recognise and establish it in its microscopic mixture! A good example of the powerful discrimination that you have used upon the band occurs in its very first line, which I had noted “ BROAD,” only, in my little sketch of measurement, but which you | have mapped as a pair Nos. 1 and 2 of the band, just as accurately placed as the other equi- vocal looking linelets of the band are all clearly and exactly broken up and divided into their proper places in the dual band. The displacement between the band’s two parts is 10 (1+2+3+4), unit spaces of the structure, which is neither an indifferent interval nor an indifferent number of unit-intervals of its structure; so that the two parts can’t be described as two independent overlying bands belonging possibly to two different gases. But yet the duality is singular, as if either sever- * These very ingenious card strips of Prof. HnrscHEL’s, being unsuited to beok-illustration, —it occurred to me, to prepare Plate ‘LXXVIIL, including them both and the manner of working them, but in one statical view. This Plate afterwards had his rapoovel. though with a proviso touching ideal accuracy, which he has touched on in Appendix II. page 43.—C. P. S. VOL. XXXII. PART III. 4D 456 C, PIAZZI SMYTH ON MICROMETRICAL MEASURES OF ance into constituents physical, or constituents chemical, of the CO, was accomplished by the spark ; and the tetravalence of Carbon wnsatiated by the bivalence of Oxygen, or in other words the propriety that chemists admit (our chemical Professor, Dr Bepson, just now suggests to me) of regarding Carbon as sometimes divalent like Oxygen in forming neutral combinations such as CO, may be the origin of ( y O- =e ¢O- =-O° \ the double structure Tetravalent Carbon, Divalent Carbon. of this CO linelet band. At any rate it will interest me very much to see if I can make better sense now, and trace some similar evidence, of duality perhaps in other “ Carbon ” records of the CO citron, and Blow-pipe-green Band-lines that I have, distinctly enough measured I~ daresay to tell the same tale if they are carefully interrogated. A. S. H. GASEOUS SPECTRA UNDER HIGH DISPERSION. 457 ee NX PROF. ALEX. 8S. HERSCHEL’S LATER REMARKS ON PLATE LXXVIII, AND AN IMPROVABLE POINT IN ITS SCALE OF REPRESENTATION.—May, 1884. | Two distinct “spectra closely resembling each other, together form the Green band of | Carbonic oxide figured in the Plate LXXVIII.; one of which consists of single linelets, and | the other of slowly opening double ones, or of linelets coupled together in close pairs. If the | whole unilinear spectrum is shifted together to the left until its first line coincides with the | leading one at the band’s least refrangible edge, all its lines fall nearly into coincidence either | with the middle place, or else with one or other side-line of the several linelet pairs of which the remaining bilinear portion of the spectrum is composed. An ideal spectrum is placed for comparison above and below the two component spectra | of the band, forming an arithmetical series of micrometer-revolution, or of sensible dispersion | intervals, representing with a suitable scale-unit of measurement, the series of natural numbers 11, 2,3,4,&c. The necessary data for replacing this array of gradually increasing micrometrical intervals by a similar, more scientific arithmetrical progression having a wave-number unit | instead of a micrometrical dispersion one for prime measure of its successive terms or intervals, | was not exactly procurable in the state of the instrument’s adjustment; but the small regular | differences which are noticeable in the Plate between the two observed spectra and the | arithmetical comparison series of micrometrical line intervals, are, it may be remarked, of | exactly the description in direction and in varying magnitude which the provisional substitution in the Plate of a micrometrical for a wave-number series of successive intervals would | correspond to, and serves sufficiently to account for. Were such a replacement of the provisional array by a corresponding wave-number one made with perfect certainty and | correctness, it would seem to bea safely legitimate assumption to conclude, that the small visible departures of the ideal from the observed spectra which their comparison together exhibits on the Plate, would all, then, be quite satisfactorily obliterated and removed. AQIS. ae To which I, as the Observer, may probably be allowed to add,—not “ quite removed.” For wherever there is numerical observation aiming at exactness, there will always be errors of the observer to some extent. But I must confess I have been well pleased to see the smaller amount of the apparent errors of observation, when one Natural System of spectral lines is compared with another, as in the lowest compartment of Plate ;—than when either one of them is contrasted with the artificial screw-unit scale, as shown /irst at the top of the plate, and then near the bottom of it; viz., Plate LXXVIII.—C. P. S. 458 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES OF APPENDIX ITI. MR CHARLES F. CASELLA’S LETTERS ON THE PREPARATION AND PURIFICATION OF SOME OF HIS LATER VACUUM TUBES: 147 Hoizorn, Lonpon, E.C., 31st August 1883. To Professor C, Piazzi Smyth, F.R.S.E, 15 Royal Terrace, Edinburgh. DeEaR Sir,—I am in due receipt of your favour of the 30th inst., and I must thank you for the kind expressions that you make use of with regard to my Father, as well as for your kindness in communicating with me on the subject of the Tubes. By train to-day I have great pleasure in sending you three tubes, viz., the 4th CO+C02 Tube at 0:2” pressure, and the CO+CO? Tube at 0:3’ pressure, also the N tube at 12:5” pressure—all of which I trust will be entirely to your satisfaction. This now completes all the Tubes I have had to do for you, and I now beg to give you a formal note of how the gases in the above tubes have been made, the various processes being as follows. Hydrogen, by electrolysis of water. Oxygen I tried as above, but the manufacture of the gas was so dreadfully slow, that I had to resort to a chemical process, viz., by heating chlorate of Potass, which I think is the most satisfactory way of obtaining Oxygen. Nitrogen, by boiling Ammonium Nitrate; of course the preliminary bubblings yielding impure Nitrogen, were allowed to escape, and only the subsequent bubbles of gas collected. Carbonic Acid, by heating ferro-cyanide of Potassium with eight times its weight of sulphuric acid. Coal-gas simply by connecting the gas jet with the gas receiver connected to the Pump. CO+CO? prepared by heating crystallised oxalic acid with concentrated sulphuric acid. All the above gases were prepared in glass retorts, then passed through water into glass receiver, which latter was connected with the Pump by glass tubes, and a very delicate small steel tap; the various drying tubes used were—next to the end-on tube a Caustic Potass tube; immediately next to which was an Anhydrous Phosphoric acid tube: then came a four-foot pummice-stone tube saturated with concentrated sulphuric acid; next to which was a small chloride of Calcium tube, and then came the small steel tap separating the Pump from the gas receiver. Before making each gas the trough, receiver, and everything were thoroughly cleaned, and fresh water and new drying tubes used each time; a new Phosphoric Acid tube being used for each tube. I trust I have made myself clear in all the above details, but if I have not, pray do not hesitate to ask me for further particulars. Assuring you of best attention at all times, and hoping that at some time I may have the honour of being specially mentioned in connection with the preparation of these tubes, which , | GASEOUS SPECTRA UNDER HIGH DISPERSION. 459 I confess require the greatest personal thought and attention—lI am, dear Sir, yours very truly, CHARLES F, CASELLA. P.S.—Your note of the 31st just to hand. I will carry out your suggestion by using naked copper wires instead of gutta-percha covered ones, which already are suspended across my laboratory with a pair of leads coming down to each Pump. Before doing so, however, may I have your opinion on the following suggestion in opposition to yours, namely, the various strong and damp fumes the naked wires would be subjected to, would create a strong oxidation on them, and would not therefore the current, instead of conveying one gas into the tubes, which gas we already are acquainted with, carry a variety of “gaseous” all sorts into our tubes. This is a mere hypothesis of mine, and therefore please take it for what it is worth. Crag. Lonbovn, E.C., 13th Nov. 1883. Dear Sir,—Your favour of the 9th inst. has duly reached me, and I have now much pleasure in telling you that I am back again in office, having returned last week. Before being able to say that I am ready to commence vacuum tube work again, I must tell you that my pump room or laboratory-is without pumps, they having all become spoilt and broken by wear and tear. To make fresh ones will take about two or three weeks, they being very elaborate but exquisite instruments, Please state how many olefiant and acetylene tubes and at what pressure you would like. I will note all my chemical proceedings, and also let you have an account of those last sent, which is as follows, viz.:—Action of Nitric Acid on pure copper filings (turnings), gas collected in a receiver in water, and communication from receiver to pump, the gas first passing through four drying tubes as follows, viz.—(1) Chloride Calcium, (2) Anhydride Phosphoric Acid, (3) Anhydride Phosphoric Acid, (4) Caustic Potash. Minor details, &c., were conducted as before, but with the same care in every respect.—Yours truly, CHARLES F, CaSELLA. Previous to these chemical operations of Mr C. F. CaseLa, his father, Mr Louis P. CASELLA, had had some curious experiences with the wires forming the electrodes of his vacuum tubes. Platinum wires usually blacked the inside of the bulbs; wherefore he then tried gold,— the following recommendation of that metal in the Proceedings of the Royal Society, London (and subsequently reprinted in the Philosophical Transactions, Part I, for 1884, page 51), having been brought to his notice :— “Of all metals affording materials for electrodes, gold appears to be the best; its spectrum is a weak one, containing comparatively few lines; it is an excellent conductor of electricity, and it is not attacked by solutions of metallic chlorides.” No sooner, however, did he try this highly commended material than the insides of his tubes were brilliantly, opakely, and utterly gilt by 7¢, combined with the six-inch induction sparks employed. He had, therefore, to fall back on aluminium wire and to use that very thick, or between ;1, and +1, inch in diameter. CaP. 8. VOL. XXXII. PART III. 45 “7 460 C. PIAZZI SMYTH ON MICROMETRICAL MEASURES. APPENDIX IV. SEE THE THIRTY-ONE PLATES, FOLLOWING AFTER THE PRINTED MATTER. Viz. 29 Plates, each opening to 18x11 inches, and showing what they contain on a 40 foot spectrum length from A to H; 1 Plate, folding out to 42x11 inches, giving approximate and contracted views only, of whole spectra, 26 inches long from A to H ; And 1 Plate, folding out also to 42x11 inches; but showing what it contains on a spectrum length of 220 feet from A to H; a length erroneously printed in earlier pages herein as 120 feet only. APPENDIX \V. ON THE NUMERICAL “ WAVE-NUMBER” SPECTRUM SCALE OF ALL THE PLATES. The regularly altering number of theoretical Waves of Light at each part of the spectrum, contained ina certain constant unit of length, and called for shortness “ Wave-number,” has been adopted here, rather than the successive lengths of each of such waves, or “ Wave-length,” as a practical scale for each of our spectrum pictures—because it gives a most desirable mean between the oppositely exaggerated views of Prisms on one side, and Gratings on the other. And the Inch was at the same time employed as the unit of absolute length referred to, because it is not only British, but nearly Earth-commensurable in the best way; viz., as the 500 millionth of the length of the Earth’s Axis of Rotation ; and it furnishes also a convenient series of numbers for the memory. The method is, moreover, in the direction of its increase of figures, combined with the universal European mode of writing from left to right,—exactly suitable to Fraunhofer’s now nexpugnable order of lettering the chief lines of the Solar spectrum from Red A as the beginning, to Violet H as the end; or from lowest to highest, or Earthly ordinary, to Solar transcendental, temperatures. Hence “ Wave-number” always goes conformably from Fraunhofer’s A to his B, C, &e., and from his so-called b* to his 0%, b3, &. While the “Wave-length” method, with its reversed numbers, leads the Spectroscopists who adopt it—whether in terms of . French or English measures of length-——to do despite to the memory of their great predecessor by going backwards with his letters, while forwards with their own numbers; or by beginning the visible spectrum with H and ending it with A, in a manner so confusing to the rest of the world, accustomed loug since to invariable procedure from A to H; and also from b! to b4, in place of the opposite arrangement so recently introduced by the French metricalists. C. Bas ERRAT A, P. 416, line 29; p. 420, line 19 ; p. 420, line 12 ab imo; p. 421, line 20; p. 442, line 19; and back of Plate Ixxvi. line 4 ab imo, for 120, read 220, foot spectrum length passim. P, 442, line 12, for frebling vead trebling. P. 443, line 9, for bright-lines pectra, read bright-line spectra. P. 443, line 21, for spectrescope read spectroscope. P, 447, footnote, erase the latter half, asa @ WiTGe AGE TO THE PLATES OF MICROMETRICAL MEASURES OF GASEOUS SPECTRA GENERAL RULES FOR THE METHOD OF REPRESENTATION ADOPTED IN THESE PLATES. (1) The Method is Negative, in that Light is represented by Black, and Darkness by White. i. (2) Every straight Vertical Line, whether thick or thin, and whether close to another or not, within the limits of eaeh horizontal Spectrum Strip, always stands for a veritable and measured Spectroscopic Line, or monochro- matic image of the Slit; and nothing else. 3) Lines in any other direction than Vertical, i.e, whether a worizonial or slanting, and from either side, or both sides at once as in crossed lines, also wavy /lines,—are to be interpreted as Nebulous Shade only, in vertical bars or bands of corresponding width at the place. 4 (4) Greater or less Height or Depth, either of Lines or Bands,— is intended, in connection with the amount of ink bye pended upon them, to typify greater or less intensity and visibility of such Lines or Bands. (5) Cones of shade arranged on a vertical central axis, indicate nebulous bands of pale light, shaded off towards either side very gradually and delicately. CoP a 8: F del T_ A. Ritchie ¢ Son, Photo-lith. 1884 Trans. Roy. Soc. Edin. | er) x ia & PE RE BE IY AOD) | PS || 17 | | |e pee -- Nat fic ; - | 7 Ht be RA: fd ol 2 S P27 et record o 2, » RSE Fre Lets e VO SRL C J883. AL more 7 = #) July 3/ (Cont 2 Dor Solar and Terrestrial Gall: Chloride of Sodtunr or Na.) deal BAND v ee BOC ORANGE BAND, « SaR008 ORANGE ORANGE BAND i BB OI RORY ROOT BAND. ‘< CITRON y2 Suty 28/889. Prismatic Disperstow < 4 *f J CPS. obs. ¢ del Tin eben Vol XXXII PI.XLVII MOA + orate Anaxy and Slrong 27 than ri Orange. Cand, x N / fer breadth and conf lee xt feertness of faze. i i Sete, hat LOD : Ee Xe | PoeSeSSosos es Kl ae SOK Cw very Vt The and lnelets fer clearer H.. Ways tnerensing ow 1% Trans. Roy. Soc. Edin. “a o CITRON. BAND, Cone2y eee eM GREEN BAND,(Gut, “eneledts , Gut falls o f Very Fe CPS. obs. ¢ del. / Vol. XXX 4: -PE. XLIX eee UE MUMS HLL THUL HES LDR Trans. Roy. Soc. Edin. ON CH IN Be OOY SX O5 50505 oO » SSA) (Cott) Desferseonm = B78 BAND, BLUE BAND, @entyy Cut they are-all very fated «a CPS. obs. del] lene es Ci Haely Vol. XXXII ae rot ttr x PS L es: jealeafa esha} Lré ap the Gre Beae Low oO 5) S N SS H echt llog ether beyond the reg mao Ee BAND rd 4 Ml 2 if Trans. Roy. Soc. Edin. 2 82 } ease OPon | eae Se a oo o + s oo j = + th fy i a 1a cect behets VIOLET BAND. August 2 , /883. —_ oT SL S25 VIOLET BAND, (Cows Ver notable band La fee tlm c age. Em a Seteeh as ves LL \ Flees Vol. XXXII atin, Wore uneerlea flere es w LT he: dele { . 0 9, XK \ OX) SK FI ¥ » RX ‘ Uh x) YOOO SONOS yA of arte form ol 950 % xS RS SRC Orese SRR SS 5 SOR OR Qo GYR HAE OD) D and D oF Sopium. or Na..VAPoUR AS THEY APPEAR IN DIFFERENT SUCCESSIVE METHODS OF INCANDESCENSE. Pe eee ee _preponder ates CVS

platés in Battery, oh Sharks trecreased from 2% 3 long. Definition distressinyubad CO ips CHEN so: Trans. Roy. Soc. Edin. BSRGESRERe h 0b. 20° 78835 POUR Wana. 150 ° © Banas BD R PE obs 4 del. / CPS >< a) a > “ 3< rr) > AEH. 60° —_ — Ay dro JL. swmatu QD espers tory $1700 le 2" Red We ty tree ee = = 1853 . Ohiber 164 o NISCARLET ro ORANGE. TH. del. 2. Trans. Roy. Soc. Edin. 4/\100 050 tebe . ° > ‘a F / fe) 13) = 4 Le} S x ar x al Fa WwW N : < :| > or hc hh - ° J s O 3 L S ‘1 Oo ache | YELLOW ro CIT 42/300 mite Lisperstow 250 Z) (Cont). Les (Cond be es a Me ); ah ORANGE Press, ry 2. 1 (Cont | PI. LXI, Vol. XXXII one gacenaade lercuyy |. “V Mlow CO begins hore. is ORANGE at (OWL. Pressure. Casellas H tite or 2S, 1883 . SMR LALA Trans. Roy. Soc. Edin. wi hy E SSERRERERSESRSERRSSROGEs ‘To © Octiber 29, 7883. Za 000 0 r CITRON To GREEN,(GntZy. CPS. obs. $¢ del] TIN ALEL, 2, Vol. XXXII] PI. LXIL a \ Iss } x 5 S x teeth Ate = 66 Des per score jj : B e Le a TO btrh 350 f Lt tt & SRRSSRRRRERERoe oO 2 Nu OO oO Oo i Beal eels) 50/300 Casellas H tube a ; GLAUCOUS 250 JOE. 20, 200 (Cont é ) ooh J oo oe Lt | l °o i etek L | CITRON to GREEN, (Coxrtz). SERRE S Nov, 150 To GLAUCOUS IGR EE Nto GLAUC$ (Gned) 7 / GLAU CO.Us & del TO 7 |000 GREEN obs Trans. Roy. Soc. Edin. ofS. ee a | LXIll, Vol. XXXII PI. ay, power Me A a oF, 48 Ie = (ILI SLO Dis LEM ALEL en Casetla's OL Bessure tnbe. Prismatic Dispersion = 48 "At Ff. matic Dish 12) 3 e s ro) - H : eo) LT] 2 Sate ee ey a Peedi. | (3 - a crete & : =, : tHe - ~N | = = —_— > a | oak | ca PY fe) ah ree ‘ 2 es | S | a S = at =) c : re) ‘ 2 5 2 a li ey b o /~ < sa 2 : ei | & QO z Ba: Zz = a i Ree 2 Ps E . he ES 4 = S : w Sy = : y a < e Vol. XXXII PI.LXIV, fe) <3) a + a) n eo ae BORE SSEReaa ei S cot NI a a Ea o iss o aS T = 2/ ~ ing poovver Magn} Cusolla's H 3 on : | = 9 on er g <4 8 aug? 1 \ 7 060 ss : ~|) ono | ot ig lA “N ozol-+4 a. ool H | N“\ salt IX oso ~ wit 2 Be an |} 2 i. S N ais vol SN tA KS |} cH Q SS NS eeikie NS | oeor— fon fy 3 ool od iS 10-4 el i i i A 2 oS i ae © Trans. Roy. Soc. Edin. 0 58 O 7 d 3. wn del obs CLS LXIX, Rie TM akere, DD Vol. XXXII GOO UCR: Power = 2/. yong - Mea a Val ek Bad LS ee Trans. Roy. Soc. Edin. isla any 2130 (=) oo;o | oo = oo oo oo 2] un oO t on ey Ti 2 on = nu nxn NN Om m eae Ve che aaa ae eee Saas 18 84. Casetha's N tube at Re i“ ae , i50 33)20: pe ~~ 33/300 ag eis 2 egeg|eeee | ed N N Tee ss a ase Stet tree etch WLLL: a na Villdiidii me YY ULTRA- RED, (Gnxez) ae °o 2 ea¢ ULTRA-RED, (Gree, LE his trople of lines (4. 45 Horschake °o o oe SS Y hot Lil B aeeee RD ULT R A- R ED Ps te) Ths iwltra-Re2 Group CPS. obs. & del er Vol. XXXII Pl. LXX, . ee x Eartiest VY band or light Jercecevadble. era Spectro scope. ULTRA-RE D. a “331700 5) 800 850 9 oOo i=) sgz| 3 Fai ha ae eee Lt tt ae Bit i i ee Bae OSRBARARES BHRABEREBa VLE Sotto y ee (a= | a yy — META LAG IE, Sees eae Pressure, ea at Ov ORANGE. A new Casetla’s tube at O band N lute la’s This ultra Ret Goup of band s | be Cas eZ #) 78S. (Cont SJ. s RED Saneary 18 X This Nlube at OT Press. sudclenty fasts . RED Ss ULTRA 4 = Trans. Roy. Soc. Edin. =a oe PS MEV, (LOA SS \, WS Vol. XXXII Pl. LXXL RED Group begins. ’ ay SSS SSS COLOUR. x , ' Ni y S 3 S Q N S y Ne : . |S perston= 60° A tH. Q W . x | = a . i? : 7 df bane. del January 22, /98Ly, (Cont 2) YELLOW. WG J PS. obs # OF Jan! 22, cont 4. x Trans. Roy. Soc. Edin. | Vol.xt] Py. LXXIIL, oc6 SS } f Beer =eeec=u ate ly Ouse Press. O2Z i ’ 014: RSS | jepduptepdonsentn Casetla's Cand 57 ie femrter eivck More re eal engby Asfined egy LL7V, 22, /88L. F. eM -TUBES or. hegins Prrore St ———saae Hl [ t i f | | CiITRORS Q it ‘ S iw - S 4 . \ é bah de Samuary 22, (98h, (Cont 2) O Zand Lie; Comt © 7) obs. € Trans. Roy. Soc. Edin. Vol! XXXII Pl. LXXII, Ro : mates et Of6} +S — | | |} 086 —-EEEESEEe R-----= A SSS aE een LI or a 7 sr i O1Z Tatoos ozz LOSS a Casetle's se e= ongly AcpinedL Ky LLY, or. b CYtpag Fi07Te Sé =—=a=e= fe UBS a2, /98h. 7] J Cana aa Ves Cand. H del 2. / ad defenilion o the Corestilicest Unas trveomnendvctble. C Lapepiers a Trans. Roy. Soc. Edin. =6. (@ Le February, 7884. (Corti Prismatic Disp.= t Intinsel =3. = e ————— | S } m a : : x a = a N - oo S i — ed E SS 8 SSS SSS ———__: | ea a O-S Press. oginnitng WaA stro Cas etla's COLOUR. 78354. COLO UA CITRON GREEN Fee ery Txrte nsity = he. ¢ Be february 18 84-, (Continucd .) obs. & del GREEN COLOUR CITRON GREEN ands 6b C72 CPS LXXIII, Bi Vol. XXXII 950 the bands Cost. cs Lo del, 2: Trans. Roy. Soc. Edin. © 4 Fab . 1884, (Conte. COLOUR: GREEN Peter ae ° oO =] oO 250 cht bth 150 - GLAUCOUEEE yy and finally observed; butler it are. the fant 23 L feell v This Portion wo SS = Dakhalal Es LA LA 080 020 0) 010 B\ AAAS \" eee Lanne = Hite loirt.. Very _ hazy and hereabouts mee A C March 10 (Gnt4) COLOUR. BLUE GLAUCOUS weneun oo on wo © (ae fa Ss aa Stro , | = s = re ae ee x at mis ose} | Ns . a a oastt4 ie : N ue ae “4 : = uae 046 H $ Be ae : Zags A RY 3 oT A a | 4 eee > Ov6 : Orb} His . . ore oes a a : oze}+ oz6'+ 8 S o16 Z 5 ott Sd ) a H ay Z r N oss 3 one} x 2S oss} oes} S || O88 ttt CO CSdCL:SCtsé < = ove X ‘ a i a al ‘ 3 2 ° H 2 ra $ ie : oe LH x Sis LH oee + : < Hs oze} 1 aa y] < CI] a < 4 io Ole - : SP oe Se . oszt $ Bee 02a ‘ a u oz} s > o Me A es Caan x \\ N Cc] | : Cs) his "Ss 7 a SN one $ ps NS ie ais LE . aa Soest 2) i] 8 ns .. Trans. Roy. Soc. Edin. to] + oy | Se et ee AVE ES See Ofe oze BERee j -@eu o om iB Z z ASR SS AVRAAAY 53/300 WALLA oO 2 N F] o ~~ N losé ASt rt lines bands Yhe broad Blac - TIxtenstly and rrr ose: fen 95|300 A Narrow begin Pristcate Dispersiow = 48° ‘ ; ee y Sle ‘ ‘ é S) iS Hee f R Aa) . : ie ‘ N ees eer | 8) in ws 8 ; co) & k : alk i fa] S ° ‘ : “ Trt i | ~ a $ }O} 8 o | oso $ de SS 5 oly * | i | Z| ~ ‘ | {Gs ri l= —— : bale B eee aH i iagaa ae CCF a: —— i FE. AS TH. del. 2. A Marrow eee ae 7 CAN INos BW tmneng . 4 Feb. sh, (88h. QMS Oru (lt defined characteritie Violet band. Os Press. N tribe, | PSSSiensus— = : | PSS i Broad ozs 6 COLOUR. nh : ‘ SECS Hi | Bip \ Petpet rH = ECE 029| | NSWWSSOSESE fea 7 SE EE\\\ os a i BZA. 5 operons SRST aR . “7 BS. ————_- i EN —— SS aa = | Uinues siaietalsiaeisiaisis 18384-. Casetia’s Be UE cesta : ; 06s FN fet ruary 2/, SSS ose Loo Broad club begin. Prismatic DisAers /8 54 . Vio Cet 4 Letruary ery The broad ae — e EW Risse 040} 0€0}- + WS 020 ZS 010 4A Febr. 2/ , 188hy, (Cont 2) too bad. WwW ati aA. tet 18844. (Cont #) 18 Sh- , (Cont #). e broad Veolet ae: 4. Lebr 2F- | | bs. & del. 7 | @ \Febn. 274i Zh An | CPS. ee M Boos 0&2 ; LEX WES 089 — ie 099 TZ. del. 2. = LIST OF ALL THE PLATES CONTAINED HEREIN, — ViZ, 29 DOUBLE-PAGE PLATES, AND 2 LONG FOLDING PLATES, AS BELOW. — RK Sums THIS VOLUME PAPER’S GENERAL SUBJECT. PARTICULAR DETAILS. a NUMBER. |. NUMBMBY asi ee Eee 26S eee eee XLVIII. 1 C i Orange band, and Citron band. XLIX. 2 IN BLOW-PIPE FL AME; Citron band continued, and Green band. Li. 3 on a 40 foot Green band continued, and Blue band. Li. 4 Spectrum lensth. Violet band at the end thereof. Characteristics of several methods of Gaseous-Incandescence. A single- page Representation. CH again, but in Vacuum Tubes, and by Electric Spark. Citron band and Green hard Green, Blue, Violet and Marsh Vi. bands. LV. 8 CO Red band and Scarlet band. — LVI. 9 a ee hues Orange band and Yellow band. LVI. 10 ID GHC Yellow band and Citron band. LVIII. a 40 foot Spectrum Green band and Blue band. LIX. ‘2 length. Indigo band and Violet band. x Early Red, Red, and Scarlet, regions. LXl. ar Orange, Yellow and Citron regions. LXIl. J Citron to Green, region, : LXIII in Vacuum Tubes, Green, Glaucous, and Blue regions. LXIV on same Scale. Blue and Indigo regions. LXV. Violet region. LXVI. Ultra Red, Red and Scarlet regions, LXVII. O Orange and Yellow regions. LXVIII. ] Citron to Green, region. ~: LXIX Pa Vines ne Glaucous to Violet, region. WN.B.—The Glawcou coloured Oxygen triplets at 50,630 and 5. on same Seale. W.N. Pl. respectively, should be decreased a what in intensity and size. 4 LXX. Ultra Red region. LXXI. N Red and Scarlet, regions. LXXII. 5 Yellow and Citron, regions. LXXIIh. in Vacuum Tubes, Citron and Green, regions. LXIV. Glaucous and Blue, regions, LXV. on same Scale. Blue and Indigo, regions. LXVI. Violet regions. Long, folding, Index Map, on a very small Spectrum scale, of all the LXXVII above, and some other, Gases, at both high, and low, Electric ; temperatures; intended to serve as a Frontispiece and useful Key, to the whole. Long, folding Plate of Green CO’s extra CH’s green, portion. Full size 0 original instrumental record, viz. on a 120 foot Spectrum length (cl b LXXVII. 31 H of Fraunhofer) ; with explication of its remarkable double Art metical Series of construction, by Professor Alex. S. Herschel, « d. College of Science, Newcastle-on-Tyne. PLATE LXXVII. or 30 TRANSACTIONS R.S.E. rom Angstroms CoH LHR ERS AdUinS by co Silex Hep, RED. Stlooo PTET Li reedel VOL XXXII. ae =Dpee 0 BS Bee ee ee ee ee eee eee eee eee eee eee eee ees { rn =e < <= we 5 er) > o = ez 5 8 © . ae s SZ DROGEN; from [-4 o OO o = a Of Angstrom, Thaler, o. ” 8 fo So yy, = TS i ERCURY, from 5 > = z4 a A, Thaten, Plucheor, te. ‘a 2S f= Zz o Jer AC Wetts. Ary B S: ITROGEN from > IP S33 ee 25 Thaten , Plucher, ¥. 5 ° a Sor IL por MM. batts F =n) as Ww, =% = Y Oxy cen from Avpr ia © Thaler . Cae e (a, (b z o omvicen from set ed Schucstér . Zo a a w wo ne 2 w SoLAR GuiDe. Citron. Cir-@ ae 2 i < = F 3 F 4 CaARBO-HYDROGEN, | ca 2 fe or CH. re a > fe) | © Son Gee B Pen -Omeas | 3 = 2 cwa I. on CO. a, Sameer (7 aoe) kr Y @ CYANO GEN, Oe S af Sea. = one on CN, fa) z Wi z 72 4 zo 5 YDROGEN, x ese 52 H z i, OR - >) 7 | W oe Ow IB faa) = 2 Mercury, Zz > on Hg. _ =) Bk pve BORER os N, Our Si ie posscl t+ 5 Bio xIDE or een « 1 ° OXYGEN, ; on O, Sovar Guioe. 12 SCARLET i YeLLow —CiTRON i} _ j i : 3 ¥ BLUISH- KY=6 coe ee a) PP Viouer. os] Lavences. zy [vou 62|oe om S| 63/00 6/| G00 BuiuisH, Skv-Bive, DCE } iH L $8|o0e Splece a 62Jooo | 63)00 # fie rem Angstroms Setar Map, OLAR GUIDE. Z Air, AIR, fom as . per Df. Watts. CARBON, prom Thaler . HyDROGEN, AX Angstrom, Thaten, Ke: MERCURY, fom Thaten, Plucker, %. Ber I. Watts . NITROGEN, mac Thalen, Plucker, MN. Wate . oueen » from XQ Thalon. SW jtbe) 2) alts (a2-uvuHosita Oxyeen, prom Schuster . Guibe. SOLAR uve) a35N44N09 wo fsguntvuadw3at H!IH HAuvwds ~ “T 9 CARBO -HyYDROGEN} or CH. O CarBo-OxyceEn, on CO. CYANOGEN, on CN. CTPTTT TTT 7] Hyprocen, on H. ° 6zlace 6s|oc0 Cor Soar Mercury, 7] On Hg. NITROGEN, on NN& possibly Biox10E or NITROGEN, OXxVGEN, &| on O "“S3E94NL NANIVA Ni VulId3ads SorarR GuIDe. 31dwis vo Mo “yYuwds ‘JUNLVYSI WIL —-——— 4] PLATE LXXVIL. oR 30 TRANSACTIONS R.S.E. VOL. XXXII. za ° io) oO Mm br x = E> te) 58 =. oN Sy 2 © zm 2 oe 4 > i) =< ow C) m = a = at Sy ae ia = aS S Dp m x2, 9 vir- ame D> m ay @ = (nl ™o iv} Ae) Pay zm e> ih ae zp Les) a ™ d ro) = 4 = Da > “— SS af > THe Green CO | Bano’s Becinnince, on tHe Scate-ror Size emp! coven py M.M. Anestrom anv THALEN, IN PLATE LXXVIIL ss : anal THEIR Mesures Micrometriques” 7 &753 But TRANSLATED HERE FROM THE TRANSACT! ace yo. XXXII. PosiTive, To THe NEGATIVE, MANNER, AS REGARDS LIGHT AND Snape. eC ee | THE SAme | GREEN Band's BEGINNING , RESOLVED IN EDINBURGH BY C) EXPLICATED AS TIWO SERIES IN ARITHMETICAL PROGR LE | Sums. — = q TweoRETICAL ARITHM., PROGRESSION, | mxe-l]2| >] t rr === a me 35 5- ae Se SPLIT-LINE OPECTRUM PRODUCED UPWARDS. OBSERVATIONAL, | YZ NERY Na IN NEGATIVE REPRESENTATION EXACTLY AS MEASURED, Fut Size OF THE INSTRUMENTAL RECorRD. | MAIN-LINE SPECTRUM PRODUCED DOWNWARDS. = ¥ | ‘ice THEORETICAL ARITHM. PROGRESSION AGAIN, [| 5 6 BEGINNING on 5” Line of First SERIES. ‘ 2 PUTT) TU EEE SPECTRUM-PLACE iw WaAVE-NUMBER een BR.INCH, ‘18 il | £8,950 44,000 APPROXIMATELY ONLY: | 1 Serit— Se uM ITH COMPARISON OF it— Line ECTR Ww | | ERS. obs adel. Main-Line -Speotrum Set /O units’ sack. — : a, aeameii | ia ti “Tl See “Recherches sur l (es Spectres des Métalloides, par A.J. Angstrim et ( Ext rait des Wova Acta Reg. Soc. Upsal. ,Ser. Ill, Vol. IX.) Up sal, Fd. Berling, Imprimeur de l'Université. 1875. f4goo goo hy,0e0 | Meg Joe Ufjtoe WAVE N2 SPECTRUM-PLACE , APPROX. W. N24” Bret. Inch - PLATE LXXVIII, or 31 TRANSACTIONS R.S.E. VOL. XXXII. T.R.Thalen, eT CT NE OS A WO A ROR ET: STS AZZ | SMYTH INTO nS COMPO NENT LINES, JNIND) Wee SIE ESSION BY PROFESSOR ALEXANDER S.H ERSCHEL , Morr 7883. 16 Z EET 10 /20 49,/00 ETT 90 Oo POO 130 14.0 49,050 | THEORETICAL THEORETICAL ARITH. PROGRESSION. SH LZABSAGA SHERI +I H9H/IOFM +12 +13 +14 + 1S +16 +17 + BH, SPLIT-LINE SPECTRUM PRODUCED UPWARDS. ea VA VON, <= Every LINE, REPRESEN TATION, IN NEGATIVE IMG WIE WANS WIE AS WIR TE, 1D), Fury Size oF THE INSTRUMENTAL REcorD. MAIN-LINE SPECTRUM PRODUCED DOWNWARDS. ARITHM. PROGRESSION AGAIN, BecinNING on 5@ Line of First SERIES: MAOH SpecTRUM-PLACE in Wave-NumBeR eer BR.INGH, APPROXIMATELY ONLY. i Spuit- Line Si 2 © wh Wi » C OM PARED WITH Main-Line Spectrum Set /0 units sack TH. det. 2 XXV.—On Bipartite Functions. By THomas Muir, LL.D. (Read 16th February 1885.) 1. If a row of elements be taken, and closely following this array, but separated by a bar from it, we write nm rows of n elements each; and closely ing either outside column of this square array, but separated by a bar it, we write » columns of n elements each; and closely following an de row of this second square array, but separated by a bar from it, we n rows of n elements each; and so on, passing from the rows or columns me array to the columns or rows of the next, and ending not with a square wy, but, as we began, with a single line of elements, we have the matrix sentation of a bipartite function. For example, when n»=3 and the number of square arrays is 4, the repre- 2. The ordinary algebraical expression of the function is obtained from the ata ix representation by forming every possible term containing as a factor , and only one, element from each array, subject to the condition that element to be taken from any one array must be in the same row or column with the element taken from the preceding array, and in the same column or row with the element taken from the following array; and then connecting, by means of plus signs, the terms thus formed. - VOL. XXXII. PART III. 4¥ 462 THOMAS MUIR ON BIPARTITE FUNCTIONS. For example, b - d\g i = acgk +acil + achk + aejl + bdgk + bdil + bfhk + bff ; k and ab. (Cdd gti e pat ben oF hl Se H(abedtefgh). 3. If the number of elements in a row or column be x, the bipartite is said to be of the n™ order: if the number of arrays, square or not, be m, it is evidently of the m'™ degree; and combining these we may speak of such a bipartite as being of the deg-order (m, 7). 4. The number of terms in the final expansion of a bipartite of deg-order (jm, 7) is n™™. For the deg-order (2, x) the number is evidently , 7.¢.,n°~*: for the deg- order (3, 2) there must be one term, and one only, for every element in the square array, and therefore in all n? terms, 7.¢, n°’; and if the number of terms in a bipartite of deg-order (p, 7) be n’~', it is readily made evident that the number in the bipartite of deg-order (p+1, 7) is n”: hence the statement is established. 5. Each element of any one of the square arrays of a bipartite of deg-order (m, n) occurs n”™~'+ n?, 7.2. n”~* times in the final expansion; and each element — of either of the other arrays occurs n”~'+n, 7.e., n”~* times. For, one of the former, and only one, must occur in each term, and there are nw” of them; and one of the latter, and only one, must occur in each term, and there are 2 of them. 6. The elements of the square arrays may therefore be called secondary elements, and the others primary. 7. The two lines of primary elements may be distinguished as initial and Jinal. Strictly speaking, however, either is at the beginning, and the other at the end; for the definition shows that the order of writing the arrays may be reversed without affecting the final expansion. Thus ab phat io 2 CO Gs C= Th Pe eflh 7 4g\d¢ kl Bite a THOMAS MUIR ON BIPARTITE FUNCTIONS. 468 8. Also, it may be remarked, the law of formation of the terms would give the same result if the initial row of any bipartite were made into a column, and at the same time all the other rows and columns altered accordingly. Thus the bipartite of § 7 may also be written ale e agit bid f aa ghi\k gh\k alc e a Jl bld f if on any occasion there be convenience in so doing. 9. If any two rows or two columns of a square array be interchanged, and, at the same time, the two collinear rows or columns in one of the adjacent arrays, the bipartite is in substance unaltered. Thus m nq m n\q a bik Cp 2a b\k 1 |p Coes ee @ EL, gl Cay Ge a @ aig 4 k L |p ia bm n\ ¢ Mia tal gue 2 Ce feet yg 10. A bipartite is multiplied by any quantity if each of the elements of any one of its arrays be multiplied by that quantity. 11. A bipartite having every element of one of its square arrays a sum of p terms may be expressed as the sum of p bipartites, the first of which is got from the original by deleting all the terms of each of the p-termed elements except the first term, the second by deleting all the terms of each of the p-termed elements except the second term, and so on. 12. The cofactor of any one of the principal elements of a bipartite of deg-order (m, 2) is expressible as a bipartite of deg-order (m—1, m), which is obtained from the original bipartite by deleting, first, the line to which the said principal element belongs, and then the elements of the adjacent square array which are not collinear with the said principal element. 464 THOMAS MUIR ON BIPARTITE FUNCTIONS. Thus in aS Ms a/hy hy Cy |e & e d\f, te Ss cs ds|\% Jo Js So oO so we the cofactor of a, is and the cofactor of h, is Gy lig de b, & ad, | 4, bp tp delhi bs ¢s Ag}. 13. A bipartite of deg-order (mm, 2) is thus expressible as a sum of » products of two factors each, the first factors being elements taken either all from the initial line or all from the final line, and the second factors being bipartites of deg-order (m—1, 7). Thus hy, he, 0, hh | hy, ky ky 7 he, ene ie Gee a Ue. dy |e, ee, be Sf Io Ss Gg ji ty Is dy A So Ss bs! Yo Ys (3191 Go Is 43191 Go Ys This recurrent law of formation of a bipartite might of course have been adopted as the definition. 14. The cofactor of any one of the secondary elements belonging to the p™ array of a bipartite of deg-order (m, m) is expressible as the product of two bipartites, one of deg-order (p—1, m) and the other of deg-order (n—p, n), the first being got from the first p—1 arrays by deleting from the (p—1)" array all the elements not collinear with the element in question, and the second being got from the last »—yp arrays in the same way. THOMAS MUIR ON BIPARTITE FUNCTIONS. 465 Thus in hs ky 15| Py Po Ps hig olen, “Uy| My Ma Me a, a, M,| hy hk, 1,| m, m, m, b CY ay Q 6 Og) Ty Sy UW] bo Cy del|fi So Ja|%2 82 Wel bz C3 d3\91 92 9s\T3 $3 Us! % the cofactor of /, is a, M, Ms M1 My Ms by Cy d, Cy Ty Sy Uy, | @, by Co dy h Up) Sq Uy | Yy bs Cy ds | Jo 73 Sz Ug | % , and the cofactor of f, is or A, o 4, le Is |a, yy 2 6G, ay My Mh, Py % Te. Tr; My Ne Po|S, S_ $3 Ms Nz Pz|Uy Uz Us 15. A bipartite of deg-order (m, 2) is thus expressible as a sum of n’ products of three factors each, the first factors being elements all taken from any one of the square arrays, the p™ say, the second factors being minor bipartites of deg- order (p—1, m), and the third factors being minors of deg-order (n—p, n). Thus So In| hy Fe | van | hy 5 ee A hy [Pr bh a4 jd, a, | Gye Hf | My, Me bp Oy | 0, lg yg | ye _ if we decide on taking the elements of its fourth array, is equal to oS CE aha) ee a a eral Te fe | Bt Ws Cae raluct. em eid ae 0s by Cy | ty Jo | = Me by Cp | & ty Ja |M Me (a) of. ‘s a» hy ky Oi Gh Pg a hy key hh 1 4/4 CT se HE al aig LS) by | de Bey Sa i erty by Cy | % fg |My Me by Cg | @ tz Jo | My 466 THOMAS MUIR ON BIPARTITE FUNCTIONS. or, if we decide on taking the elements of its 3rd array, is equal to S| k ky Bes eee Aj! : Pine as ey a ee ho| Py b ty Gy Fe | Wa te Caos re ei ee re ps Mae Rs tg Jog |M% Me B I2 ky Key | I2 ky ky a pre hy hy Py by gees Cy Ti Sel eo A, hel Py h . 6G, 4, jy |™m m, US eGo 4 Jy | my ™M, 1% Jo |My My tq Jo |My My 16. Since a bipartite function is linear with respect to the elements of any one of its arrays, the cofactor of any of the elements (which has been shown above to be expressible as a minor bipartite or as a product of minors) is expressible also as the first differential coefficient of the function with respect to the element in question. Hence, B denoting the bipartite whose initial line is a@,, a, a3, ...., Qs the theorem of § 18 may be alternatively stated in symbols thus— oB B=2a,5- (r=1, 2, ..., m) and the elements of any square array of B being the elements of the deter- minant |q@,,,|, the theorem of § 15 is B=2an5,- Ce ant ot) 17. A bipartite of deg-order (m, 2) is expressible as the sum of » products of two factors each, viz., a minor bipartite of any degree less than m, say of the degree p, and a minor of the degree m—vp, the former being obtained from the first p arrays by deleting all the lines of the p” array except one, and the latter being obtained from the last »—~p arrays by deleting all the lines of the (x—p)™ array except the line collinear with that formerly undeleted in the p™ array from the beginning. This theorem is deduced from the theorem of § 15 by combining those terms of the development there obtained which have a common factor. Thus, taking the first development of Jn Ga \ hy he a, a\f er ge te hy he Giles hte bn oe da, d,\t jf, |m, m, Ba Cy dey lg ty ie, WE eS THOMAS MUIR ON BIPARTITE FUNCTIONS. 467 en as an example in § 15, viz.— a a ' hy he Pit We Oy sy ; Ay him HM "by Gd fy} mm mM, ms b 4 fd, 4 fy | Im mM, b, Cy fal ty Ja |My Me by Cy | ly tg fg | MMe Pie 8s ky keg | Py G Lie it ee? kK kelp om Der G, Pay, — ty. gy lay mn, J2* Be ld tie fu ey, aig 2 by Cy |@ ty Jo |™ Me b, Ca |} % Jo | Me f Gr es re G, a, a +100 1 bh Gg | dy bh 864 |] a, Boitasatgel €; Gy) Ott. ee qh al nH 5, 6 | dy dy De. Og | Op Oy | rly, the cofactor of the factor common to the last two terms is seen Gy O2\ fo Go 4 bh 4) ad, a, Don lelen beg Yeo hy A,| Pr % ae EG TED An byl, Bh G2 | helm Y (a) do\% fy jm mM, & G |a, dg | fj mm & & |d dy % J, | Mm Mm, | % Jo | M My dy Ole Cy ty fg |My My dy Cp |e by tg Jn | 1 My Jo Ga|\ hy hy ori kp go) ky ky lh, | hy hol Pr GH _ % Si\ ty he| Pi He, % Ge K| My he) Pr % me al am. B Fe a a a b pe —— | — = . GA Ay(% Jy | Mm My 1% | % y Jy | Mm M, 1 % | % WH fi | mM, My, 72 10 ly} % Jo | Mg dg 6} e [4 Jy | Mg dy Cy | tg Jo |My Ne ‘ 468 THOMAS MUIR ON BIPARTITE FUNCTIONS. Again, by combining the first and third terms of the second development in § 15, we should have the case where the one factor is of the second degree, and the other of the sixth, viz.— Sr g2| hy to Go| By Ie | So Go| hy he dy Ms I Ni | hy hel Pr Hh 2 ty % A K\ Ay ho| Pr H era % AN hy hg Po b, & | dy dal gf) |p mm, b,c, a, dy By an my bh eee ieee Dy Cy} Cy) %_ Jo | Me (Uy Jo | Ny Ny ty Jo |M My The case where the one factor is of the Ist degree and the other of the 7th falls under the theorem of § 13, which may thus be looked on as a particular case of the present theorem. 18. Two minors such as those of each term of the development in the preceding paragraph—that is to say, minors which, when multiplied, give terms that are all terms of the parent bipartite—may be called complementary minors. 19. A bipartite of deg-order (m, n) is expressible as a sum of x” products of three factors each, the first being an element of the initial line, the second an element of the final line, and the third the minor bipartite of deg-order (m— 2, m), which is obtained from the original by deleting the initial and final lines, and — those lines of the first and last square arrays which are not collinear with one of the said pair of elements. Thus a ay Sas 9 Bee Sty ilad, a5 Oy Mes Me, ie, 2 bi, 205 Oe, . C, + gy rey + afi d, & & D SiG. Dip} Bo Bey iM Ba GD bGe Ga Ckc 4 and, proceeding on the same lines as in the foregoing case, we have (§ 13) By=4,A,+ a,A,+4;A; , (§ 13) Be=hH,+4,K,4+41, . Also, by an extension of the same theorem (§ 17), = dh, M% a ih ih | op Ue a, Hii by abe Bs an ci Be adie aids 7h % a & & bs bo Op dg fi te Ss b, cs dy 9, Jo Js Multiplying together the three dexter members of these equations we obtain an expression of twenty-seven terms which are exactly the twenty-seven terms of B,. Hence B, = Bt The same mode of demonstration is evidently applicable when the bipartites are of any higher degree. 30. If the bipartite adjugate to a given bipartite be formed, any minor of it of the 7» degree is equal to the product obtained by multiplying the cofactor of the corresponding minor in the original bipartite by the (*—1)™ power of the latter. For example, in the third case of the preceding paragraph, the minor ee ae ae at as a, —————- » a, =—> —> >> A=. — DD; Dee Boy ee Si te ts 91 Go Ys EB, BG, y, 1m 7 Go 4» % Ge % pacman we oon a" Be a, Gy, d, dy|hy bh | ; = hy Bi Wey ey. € es bp Cy d, i Dae by ¢; d3!f, Go Ys = Ash: (a)r 3 and a;h, is the cofactor of that minor of 8, which corresponds with the minor DI iD, Be or B;. ‘= F, G 1 474 THOMAS MUIR ON BIPARTITE FUNCTIONS. 31. To every general theorem which takes the form of an identical relation between a number of the minors of a bipartite or between the bipartite itself and a number of its minors, there corresponds another theorem derivable from the former by merely substituting for every minor its cofactor in the bipartite, and then multiplying any term by such a power of the bipartite as will make all the terms of the same degree. This is the important Law of Complementaries already known to hold good in regard to Determinants and Pfaffians. Any class, indeed, of algebraical com binatory functions, concerning which we can assert the truth of two theorems - like those of §§ 29, 30, is ruled by the Law of Complementaries. The mode of establishing the law is literally the same for all. (See my Theory of Deter- minants, pp. 141, 142.) 32. If all the rows or all the columns of any square array of a bipartite be identical the bipartite is resolvable into two factors. For by the theorem of § 17 the bipartite is expressible as a sum of products of pairs of factors, and all these products by the datum have one factor in common. Thus Gi, ‘whi =) % 4% % , % My ty a, ad, a: re Er — Mtb ee ad, b, G; dy 110, Mere by 6, Gy| Gj. 6, 96 ‘ b, ¢, d,|€; € ¢s x 212% ; An bth Ain | hy Jo 92 hg} l, Jo Gn Ne] Jz 93 hm, Ss 93 hg! my 33. Any power of a bipartite of the second degree may be expressed as a bipartite. For example— (OLN NE a> 'b) Ye =( a) ax ay aZ\ «x ZY 2) ax Coe me ee 28) sted bu by bz\y ae) | by CL CY One GY — vn and Ge by Oy 2 bY tae Oy by ners eg The ax ay az\ax bu ce 2 | ae abe ace * z Z x be by bz ay by cy x ce Cy Cz az bz @ it THOMAS MUIR ON BIPARTITE FUNCTIONS. 475 34, The product of two bipartites of the third degree may be expressed as a bipartite of the third degree. For example— ’ a a 4s GQ, Ay G3 Be). Why 97 ah Nn 4A Hn b dale > 5 meet. 81 | By 8} 4 He ats ave a, A, as 161 LE) 36) b, 6, de|f, By 2 82} dy Br 8 mee, d,\ 9; B 6, | ¥ Gy Gy. @ fr Bs me 8! Xs ry ag gp e Yo A a. NX eX) AsX, |——_2— 5 B, Y3 8s The law of formation of the product is the same for all orders. 35. The product of a bipartite of deg-order (3, m) by the (1 —2)™ power of the determinant of its square array is expressible as a determinant of the (n+ 1)” order. Thus denoting the determinant |), c,d;e@| by A, and its adjugate by |B, C, D, E,|, we have Wy Wy A, & a a, a a Beds «| nity, b, a d, @ _ A dA a aA wt i\%, % dy N\A A dA eA h,\ bs; ¢3 ds ¢, POL Meg Vd, K eA Kyi by Cy dy % kibA «4A GA &A ay a, he hy ~ Fi) \C.D Bal o—|.BD.E,| |B,C;E,| —|B,C;D,| 9, |—|C,D3E,| |B,D,E,| —| B,C,E,| | ByC.D 5 A,| |C,D.E,| —| B,D,E, | B,C, E, | —|B,C,D, k |\—|C,D,E,; | |B,D,E,| —| B,C,E, | | B,C,D, _ _|9 @ mW a a Fi Bie DE, mn B GQ dD, E, hy Be (Cy Ds EB, Ey Bb, Cyr,” E, 36. § 22 makes it evident that the foregoing theorem is quite generally true —that is to say, is true when the bipartite is of deg-order (m, 2) (m being of ‘course greater than 3), and when the determinant she is the determinant of any one of the square arrays of the bipartite. 37. A very much wider definition of a bipartite may be given than that with which we started. The arrays lying between the initial and final lines, -F 476 THOMAS MUIR ON BIPARTITE FUNCTIONS. instead of being squares, may be merely rectangles, the length of the first rectangle being the same as that of the initial line, the length of the second the same as the breadth of the first, the length of the third the same as the breadth of the second, and so on. ‘Thus, starting with a line of m elements, we draw the separating bar and write » rows of m elements each, then 7 columns of n elements each, then s rows of 7 elements each, and end with a line of s elements. The case of this where m=2, n=3, r=4, s=1 is represented by My, A, b, 4 |d, dy ad, a, Da Gs | Bi Ne Gok ea bs Cs | fi _h debude mn & & | | m, 38. A little consideration serves to show that almost every theorem we have given can be extended so as to hold true of bipartites with rectangular arrays whose length and breadth are different. Indeed, this extended defini- tion was not adopted from the first, only because it was seen that by doing so the difficulties of exposition would have been considerably increased. 39. Of course any bipartite with arrays that are merely rectangular may be expressed as a bipartite with square arrays by the introduction of a sufficient number of zero elements; and in this way what we have called the more ' general form of bipartite may also be looked upon as a degeneration of the particular form. Thus the square-arrayed bipartite 8 S\8 Oia, as sd, “a, Oia) ey) 1B. € 0 0 aS i) Q wo Se Is Ss he Go Gein 1G i. te, 14 S r) SS re) (Si Mes y tak (iit | oO So 1 m 1 is evidently equal to the merely rectangular bipartite Aye b ¢ |d, dg dy Bs "Oy iy “ey te Os Cy. Ju. Ja TR ve h 1 my 1 and has only 2'3:4 terms instead of 4:4°4. Fewer zeros than twelve, be it also remarked, would make it assume the latter form; for, in a square-arrayed bipartite, if any line of any square array be a line of zeros, the line collinear with it in one of the adjacent squares may be made a line of zeros also. THOMAS MUIR ON BIPARTITE FUNCTIONS. 477 40. A few examples will now be given of the occurrence of bipartite func- sin mathematical investigations. These will partially indicate the bearing . The elements of the determinant which is the product of m determinants 1e 2" order are bipartites of the degree-order (m, 7). | hus { | 3 | | fai MOR el Bin Wis Mel a &, ay tly as a, a, a, 1 2 3 . 1 2 3 ' 2 3 ge Bn a Bo 2 a, Bs Ys b b b af |b, b, 7b, b, by b5 6; b,8 65) | 1 Bee Cael | Pe see Pal = eee B : B | | | er B, Wil 2. Po Y2 3, P3 V3 ; Oe Oca 6 (hy ol a ae ees Cn" | : 1. Wo: Ss ee oop 1 % 1¢ ¢ Cc % Yo Y Sea eS Se 1 2 8 1 2 3 , D | a By wal a Po Qe B, Ys | @ GM, a, .G, 4a, ity Ly Me dh, Wy Os hy Oy Ms @, A, as a By y% a, a By y1 |2, a, By V1 ie dp Bo ¥2i~i ta Ba Yo [Yo ta Bo Yo \Ys ‘ay Bs Ys % az By Ys |% ay Bs Ys 23 b, by bg by 0, D, bbs 0, HB n1% UB a Bi |% ay By YoY; dy Bo Yo Yo tn Ba ‘V2 |Ys az By y3 as Ps Y3 % az Bs Ye |% ‘a CeeGo G5 O15 So hs Cyto es HA m|% UB |e% 1, |e, ay By ¥2|%1 ae By Yo /Yo 42 Bo Y2 |¥s Gg Bz Ys }%4 az Bs V3 |% ag By Ys *31> [@y by es} > [4 Bo %g| > [@1 Yo %| * [My ho 4s has for its first element &, Ge A|h, k, lL, a By y1 | & Ly We ay Bo Y2 ‘Yn Yo Ys a Bx Ys % & %. 478 THOMAS MUIR ON BIPARTITE FUNCTIONS. _ The truth of any individual case of this follows at once from the preceding case by use of § 13. 42. The existence of a notation for the elements of a determinantal product and a knowledge of the properties of the elements facilitate very much the in- vestigation of the laws of repeated determinantal multiplication. Some results of an investigation of this kind are intended to form the subject of a future paper: the matter is therefore not now entered on. Suffice it merely to draw attention to the fact that, when using the notation of bipartites, the jirst — element of a determinantal product is all that need be given. For example, the last instance of § 41 is quite fully stated when we write | @, by ¢,| + | a, Bo ¥s oP Yy 2g) |My ep le a, G, 4 hy ky ly a; By Yi | % % Ly” dy By 2/41 Yo Ys a, Bs Ys % % % The element given on the right hand side is the element of the place (1, 1), and the element of the place (7, s) is got by substituting for the Ist row a, dg, a, the 7 row of the same determinant, and for the 1st column /,, 4,, 1, the s™ column of the same determinant. 43. This relation between bipartites and determinants is of considerable importance to the bipartite theory itself. Thus, we have seen (§ 23) that Ue We My N, 7; LM @, % d3/a,8,y, P, Py P,|s, b, b, 05 | a2 Bo Yo Q, Q2 Qs | s, C, Cy Cz | as Bs Ye R, R, R, | s @, By By | Sy My Yo Ys | S2 Ac ap Meg Reg where = iy. Bot Dy Bae Bg __ & Ly 2s ¥ Ay 3 ay By ¥1 |e” by ay By Yo [os Cy az Bs 3 5 8 Pe a By y, | a Bi Ys ay By yo 2, ay By Yo as Bs Y_!% as Bs Ys Py y. = My Y2 8 &e. Ta By ¥1 | % 7) Bo Y2 b As Bs ¥3 % But these bipartites are in order the elements of the determinant which is the THOMAS MUIR ON BIPARTITE FUNCTIONS. 479 product of |, Yo %| » [41 Bo ¥g| > [4 5g | 5 hence, putting |@, 65 3] =Ay, |¢; Bo ¥3|=Ao» |%1 Yo %3| =As» we may write the above identity in the form mM, Ny ry EG Ny r, A, | Dy a | $1 eee TA AA. 3, 8p | | 53 83 and the like holds when there 1s ay number of square arrays A,, Az, Az, Z As another instance, the theorem of § 27 may be taken, which may now stand thus— ly As AG | Ae | 4 9, 2, 4. By A, | Ag A, | A, | Ay __ & My Mg | BY, % Al but in the case of every theorem we have given regarding the condensation of bipartites a like simplification of expression is possible. The only points requiring attention are—(1) that, in forming the determinant of any square array, we must take for the first row that line of the square array which is contiguous with the bar separating it from the previous square array; (2) the initial and final lines of a bipartite are to be looked on as lines of a determinant whose other elements are all zeros. 44, @uantics are expressible as bipartites. Thus the binary cubic (abcde vy) is and the ternary quadric ax + by? + cz + Qday + Zen + 2fyz is 45. A notable characteristic of the bipartite expression for a quadric is that it brings into evidence the discriminant of the quadric—the discriminant, in fact, being the determinant of the square array of the bipartite. This suggests 480 THOMAS MUIR ON BIPARTITE FUNCTIONS. for examination how the matter of the invariance of the discriminant will look from the new point of view. ; Instead of the special symmetric form which represents a quadric, let us rather take the quite general bipartite of the third degree calling the determinant of it its square array A, and perform the two sets of substitutions & | Bié at Poy + Bog z= nF + yon t+ yh NS ll == Ba + Ba + a Y = ME + Ngy! +246 “= M,€ +My + “| z# =7& +7 +726 calling the determinant of the first substitution A, and of the second A,. The mere substitution changes the bipartite into ai dG a Bu Bz Bs OAR OE IES Seek te which > oe sae Faery oS es ass THOMAS MUIR ON BIPARTITE FUNCTIONS. 481 If, now, in this generalisation we make A axisymmetric, put & », C=&’, 1’, (, and consequently put A,= Ax, we have the theorem that the discriminant of the quadric resulting from a linear substitution performed on a given quadric is equal to the discriminant of the original multiplied by the square of the modulus of substitution.* * After the theory of this new class of functions had been worked out under a temporary designa- tion of my own, I got the Philosophical Transactions for 1858, in consequence of a communication on another matter from Professor Tait, in order to read Professor CayLny’s Memoir on Matrices ; and there found, immediately following the said memoir, another, “On the Automorphic Linear Transformation of a Bipartite Quadric Function.” This quadric function I saw at the first glance was a member of the class I had been dealing with—viz., that of the third degree. This led me to discard the name I had been employing, and to adopt bipartite instead. Professor Cayuny gives the above extension of the theorem regarding the invariance of the discriminant of a quadric, but without proof, and not as if looking at it from that point of view. I think, however, I am correct in saying that this is the only point in which my paper has been anticipated. Professor CayLey’s notation for the bipartite we have used above is (ad, % a, §eyeta yz ) Dt ibaa ibe | Cy Co Cg |} which does not, I think, bear on the face of it the exact nature of the two-sidedness of a bipartite of the third degree ; that is to say, it does not imply, as Si Oe dy, Gy | does, that the function is equal to (aye' + by’ + ez/)e (yx + Any + gz) a0’ either < +(agx’ + byy’ + cg2’)y or < + (0+ bay + bg2)y' + (ager' + Bgy’ + C52')e + (6% + Coy + Cg2)2’ . It may be of interest, as another evidence of the usefulness of bipartites, to remark here that the “ Memoir on Matrices” came opportunely for another reason. The new instrument I had got hold of seemed as if specially devised for dealing with matrices, and I immediately succeeded in proving Car.zy’s great theorem that, if m be a matrix, the equation— a-M b é d e-M if =) g h k-™ is satisfied by @ @ @)) M= id e # - Gy te AN. This proof, with its accessories, has been communicated to the Mathematical Society of London. VOL. XXXII. PART III. 41 - 482 THOMAS MUIR ON BIPARTITE FUNCTIONS. 46. A continuant is expressible as a bipartite. Thus Peres sp? 1 aoe 7 POE ae Maslin SR eet 1 —1 gi oil =—L- |, i Phe inn alt ama a bis ie hc Meat ari oi) a = a i MS ie and more generally pl a Pole toe ete 1 , SLE Gin “Gh aaa le eg —-1l is This mode of expression seems more natural than the determinant form, a continuant consisting essentially of positive terms, if the elements be positive. — All the known theorems regarding continuants- flow with the utmost readiness from the properties of bipartites. (i4s8°4) > XXVI.—The 364 Unifilar Knots of Ten Crossings, Enumerated and Described. By Rev. THomas P. Krrxman, M.A., F.R.S. (Read July 20, 1885.) 1. The 119 subsolids (marked ss) and the 244 unsolids (marked ws), of these unifilars are here arranged in lists according to their flaps. F, is the num- ber of flaps of ¢ loops upon a knot; and the headings of the lists, as, e.g. I, F,=1, F,=8, describe so far all the knots in the lists. Thus in ,,I each has one 2-ple flap and three single ones. After the number in the list comes always the base on which the knot is constructed by the rules of my paper, XVII. in vol. xxxii. part ul. of the Trans. R. S. EF. ; and the reader who has that paper before him will find it easy to draw any knot on its base, nearly always there figured, by the first given flap, which is the leading one of the knot described ; thus in ,,J the first written flap is the double one, and in ,,P, F,;=1, F, =2, it is the triple one. ‘The leading flap of a subsolid is always followed by a colon. It will be seen that no two subsolids nor unsolids have the same description. A flap AB, CD is generally given by its collaterals AB only ; but the coverticals CD are added when required for distinguishing the knots from each other. To me it appears that this tabulation of these knots will be more useful than the engraving of the figures; for the student who draws a 10-fold unifilar will hereby more readily satisfy himself that it-is found or not found in my census, than if he had 364 knots projected before him, in the manner of the plates of my former paper. One solid knot makes up 364 unifilars. 2. I am indebted to Professor Tarr for the detection of several bifilars which Thad passed as unifilars, and for the addition of four to my list of unifilars, — namely, ,,B.21 ; ,.D,17; 1,30; and ,,I4,8; and I may obtain from him farther contributions before he has performed on the figures all his surprising feats of twisting, which add a charm of conjuring to this curious and difficult inquiry. The abbreviations which mark the symmetry are those used and explained in my paper above mentioned. My linear drawings of these unifilars of ten, as well as the more numerous figures of the unifilars of eleven crossings, will be found in the archives of the Royal Society of Edinburgh. I have to acknowledge two omissions in my census of the knots of nine crossings. One is that of the bifilar ,Az? referred to as a base under ,,J. This ought to have been formed in art. 55 by drawing from the point ¢ the flap 63,44. The other knot omitted is a unifilar (,Av?) which should have been formed VOL. XXXII. PART III. AK 484 REV. T. P. KIRKMAN ON by drawing in art. 53, in the base under 7, the flap 35,44. But no unifilar of ten crossings can be made on this ,A7”. 3. As Professor Tair excludes all compound knots, 2.¢., all that can be cut by a closed curve in two mid-edges only, the name of a fixed flap ought to be given to every flap whose deletion lays bare such a compound, @¢., such a section through two edges only. As the deletion of such a flap is forbidden, so must be the drawing of it; and it cannot compete for the leadership with a flap drawn or about to be drawn. A correction is to be made also in (2) of art. 27, which ought to stand thus :— (2) If neither e nor ¢ be zoned polar, but be () one zoneless polar and the other epizonal, or (b) one zoneless polar and the other zonal, or (c) one epizonal and the other zonal, only one resulting configuration is possible: in all other cases, When neither « nor é’ is zoned polar, and not both are asymmetric, two and only two configurations can and must be made by the above variation of - posture of the charge. In my plates in volume xxxii. part i. a few errors require correction. In Pl. XLI, for ,H; 8,10; read ,H; 4,4,10: im Pl. XLIL, for ,By, 18; read oBy ; 8,10: for Db; 4, 14; read ,Db, 4,4,10: for ,Ch, 18; read ,Ch; 4,14: for »Dk, asym. ; read Ds, Moz: after ,D/ and after ,Dm write 18. In Pl. XLIIL under ,G/, for asym. write 2z0. Mox. Het. Postscript, July 13, 1885.—This day I see for the first time that when the problem is to construct, not all the knots of ” crossings, but only the non- compound unifilars, in which the tape passes over and under itself alternately at successive crossings, there is no need to discuss at all marginal dissections, nor marginal charges, nor any use of bifilar bases. This is shown as follows :— Let K,, be any non-compound unifilar of 2 crossings alternately under and over all through the circuit. Going round the circle, plant at every mid-edge between two crossings a (lot on the right of the thread. Every flap will have two dots, both inside, or both outside, or one inside and the other outside of it. In the last case call the flap odd; in the others, even, The following theorems are easily proved :— Theorem A.—If K,, above defined has an even single flap (of one loop only), it can be reduced to an unifilar, solid or unsolid, of 7-1 crossings by shrinking up that flap to a point. Theorem B.—If K,, has an odd single flap, it can be reduced to an unifilar, solid or unsolid, of n-2 crossings by effacing the two edges and the two summits of that flap. Theorem C.—If K has a double flap, of two loops, the two terminal con- UNIFILAR KNOTS OF TEN CROSSINGS. 485 tiguous loops of a (2+7)-ple flap (¢>0), the knot can be reduced to an unifilar, solid or unsolid, of 2-2 crossings by shrinking up those two loops to a point. It is evident that, if any clear definition of a leading flap and of a fixed flap be made and stuck to, the constructing converses (easily defined) of these three theorems must completely solve the fcllowing problem :— The non-compound unifilars of 2-1 and of n-2 crossings, alternately over and under, being given, to construct all the unifilars K, above defined of m crossings, without risk of repeating a result in any posture, or of making a plurifil knot. All that we have to do in reducing K, is to do that at a leading or co-leading “flap. All that we have to do in constructing K,, on a base, is to see that we do it by drawing or completing a flap which shall be the leader, or a co-leader on K,. And we shall of course define that a plural flap leads any single one. Thus, by theorem A, ,A (vide Pl. XL. vol. xxxii. Trans. R. S. EH.) reduces to ;A, on which it is regularly built by its even flap. By theorem B, ,A reduces to ,A, on which ,A is properly constructed by its odd flap. By theorem C, ,F and ,G reduce to ,A, on which by a double flap either is correctly formed. By these little examples the constructing converses are plainly suggested. This appears to make an end of the puzzle of unifilar knots whose crossings are all through alternately under and over, so far as their construction upon lower non-compound unifilars is desired, as a preparation for the curious transformations and reductions by twisting of Listine and Tair. I fear that my distinction of subsolids and unsolids is of little value, as a subsolid can often be twisted into an unsolid, and vice versd. I have had theorems B and C for nearly a year. Had I obtained theorem A earlier, my tasks on the unifilars of 8, 9, 10, and 11 crossings would have been much easier, and under less risk of error. The simplicity of the three theorems is provoking enough, as usual, after the labour spent with clumsier tools, which looked so much more learned. ioe 3. ss. .C; 63,43: 43; asym. p= 4 03,88: p ; J. » ” 54,438: 3 ” ee: ses 6, , 5843: 2p. Mox. Het. 2. ss. gAg; 55,33 2z0. Mox. Het. 7 43.53: 3. ss. ,Ap; 43,54: asym. goes ADE 53,53: 43; asym. sin One <5 OA Oo 55 ae 10 ele Gta ch: A a 11. , , 4348: 2p. Mox. Het. He ss. A; 63,63 : 2p. Mox. Het. ley ps, Os OES - 2 Bees, 60,04: 53%; asym. 13. ,, ,M; 4448: 2zo. Mox. Het. 486 REV. T. P. KIRKMAN ON 14. ss. QU; 54,33: 44; asym. 20, ss. .G; 54,43: 44; 43; asym. 15. ,, gW; 43,54: 43; ns Bhoce to yyip, GODpO Le, Doenoe 16.0 34 3. aado see ade . 22: 5° gl gb4: 545,53. LT cbgiiced St ieee 2p. Mox. Het. 23: ies Lp DOL eon EA orion é IS. 45 3" oa esbees Moz. 24, ,, P; 54,53: 44; 43; 1D; ew pe ae 2p. Mox. Het. 25. 5, g@; 53: 53; 43,54; 20% og” ere i! 26. ,, gh; 55,43: 64,43); 53.44; | DY Oreipe haa Moz. Zi? yo ype ODsUOR MOO Oe Moz. aoe 14, gates6ae Moz. 28)", 11495408 HGR E Bae - 23. us. ,A; 53,63; 33; asym. 29. , 4 5453: 535 535.) sya 24: 5, eB; AL; 33; s 30... > 5, 68,40); 63:5 55 ee ee QDs iN ag Geo. os © 31. -,, V5, 63,582 :63.5 Aas Moz. 2G. Se Rotor oor ys BQ. 5) — a» Oastog bon aan Zils 4, 6D, 405 p05 i 2p. Mox. Het. 20-5 gl; 10s oo; \ Bas, 55) yy Os Oona asym. Zo: 74, gk oes oor i 34, ,, X: 53,54: 538 Aa oee es OU 5 (eA Wog ous Moz. 30. , 4 63,44: 48; 435 _ S15) 4h AS. OBE 13385 r. S620qur ing 638,047 Sais D2. 4), CsG3>) Das asym. a7. 4, 4 63,44: 48; 43; 5 Dos he teenth IO aL Ps 38. , ,, 5444: 44; 43; , Oki” 36% DEbo 433 ne 39. 5, Aa; 541-545 43°obeeee DD ei eNO ata = 40. ,, Ae; 64,435.65; 4am = 36. 5, aA; 585 53; 2p. Mox. Het: Al. ,, jAd; 64437635 4355 = AO. 4! ly) 44S 1S i ee be! 43, ,, gAe: 74335) 733 He E t 44. ,, gAd; 65,33: 63 53a ae AB. hy) yg BBA 5S 4Seuee ss. ,A; 63,64: 64; 63; asym. 46. 3/0 gAjf;00;83:; 53 5-435 ee ia poy OS,04-0055 boc 4 47: 4, Af; 6438: 635 438; -: pie ent OO peo ie gh AS... SAG: 73 t tose oe Moz. ie od, DDO. oe oe + 49; ape, DOA? Domoer 3 6p OSU: oasou: uae 2p. Mox. Het. » » 40,64: 64; 43; 3 50.- ,, Ah; 68,54: 63; 58; asymn 5 VDE Bajb0 25353" if DIF 4 4 Ad Seetoor a yy yy JOB DA RSS IoS:: F 52.) a8, (Ei; Tos eeu roas asym. » - ») wets sb4: AB; 4 53. ss. gAt; 55,43: 54,33; 53,44 ,, 9 Oaspet DOs Adda 9 54, ,, gAw; 54 54; 48.44; , » 43,54: e 55. , gAv; 6433: 65; 465 » gl; 60,400-ba5 Dos < 56. , Ba; 64: 64; 43; 5 , 68: 54; 53; 3 57. us, ,E; 63,53; 54; 335 aay » ». eiot 00. pos ; 58. , gi; Gog at4 37: F ; 63,58: 53; 43; a DO, 4, ~O: bade 456 Ba5 Fe » » OOm aes 3 60. 4, gh; Daiaos 30. 6 3: 64; 43; bs 61, |, ., Soh verses: 4 8. , , 58: 44; 43; 3 62. 05, 9 35385 435 Sa ” (9. 4 44: bo 43. z 63. , .Q;-445 43; 33; . ONO oR oN eo oR AN ESS —— OU oo Se a Sar ot gts fo5, Fos ool; Moz. Pa) As ok ook asym. 3 (go; 69; 53; 335 , Ds (035 635339 2p. Mox: Het. » gU; 63,43 54; 33; asym. Py a sO OB. Soars ¥ ee PGACHOD = be $30.5 x Py; 025.63 5°43 ; ¥ Pape o4 3°50. 5a: x Pee, 64;°535'43: ¥ aia (83 te, 43; , mee “Op O04 5°53: F Peete pies ae, » gh; 68; 44; 43; f Bee 100; a0. dos 220, Mox. Het. Sia; Goe G4 54. 53: UNIFILAR KNOTS OF TEN CROSSINGS. 487 gA; 53; 44; 43; ”» 10D. F=4. asym. » D4: 54; 54; 54: 2p. Mox. Het. s 5a Oo" 3 mp os 00ero4, abo 53k, gl; 638: 63; 54; 54; ¥ f +Go:Ge" 55; 53: x » 04542545553: 53; 2p. Mox. Het. gb; 63: 64; 55; 53; asym. pe oae- Oe bo AAs mp u0e. Gay of: 45: 3s; 53: 53; 44; 44; 2p, Mox. Het. , 03: 54; 44; 43; asym. EV bo 5 60 Ode 5S 5 - ;, 63: 655 04; 43; : » Ode 05:43; 33; , . gb; 5d: 54; 53; 48; g¥ ; 54:54; 53; 48; Z gAb; 65: 64; 53; 43; . 74: 74; 73; 43; : PAC OO? Lon 4e - He 00 200 * 0a Ads F sAe; 64: 64; 63; 63; 2p. Mox, Bet. bo bo bo OU oom b> bo bo 2 C V0. 42, st bo oN) bo 4, an Ss. us. us. sAf; 64: 63; 55; 53; gAls 64:64:63; 63; 2,, gAv; 63: 66; 63; 44; 2p. Mox. Het. e thectocl ton 445 SNioz. » Joos 00% 533. asym. xOGGor, 45 :-) a, gAws bbs OF: 54 43.5 15 ie (4s 535 TF wae Oo +555 55% 53 : 2p. Mox. Het. » 04:54;48;43; Moz. sBf; 65: 64; 53; 53; asym. 387; 55:55;55;44; Moz. 3B; 55: 54; 54; 44; 2p. Mox. Het. . gsAw; 75,43; 74; 43; 33; asym. eae: Wey 40 38 | a gAz; 65,33; 64; 43; 33; », 00,384; 64; 43; 33; ,, 3By; 76; 76; 43; 33; plmlGGr Oar 0o 5 44. f Sek hoa Log 44.5 3 go ; 66; 66; 33; 33; 2zo0. Mox. Het. guyoo; DO donee: Lay, gAj; 64: 63; 54; 43; asym. » . 00,44: 54553543; ,, 1 An; 55:65 68; 43; 48; 2p. Mox. Het. eRe: bo? 6D “6b; 55; 58> Moz, Ri gb! 62 i160 3445 Sor, REV. T. P. KIRKMAN ON us. Ac; 54; 54,33; asym. 33. us. Bk; 66; 65; 65; Moz. » gAp; 54; 54,35; 5 on, . 9bl; Go: 65° 54. asym, i gbF 3 lage: b 55 30, 4, poms 75; Yes 7de © sao » 44;63; 3. 36, 3; GBP; Gos oe oon 7 iP pbs; Baas £ OT: 4) tl” Rote aoe oak >i op Abeaoe 3 38. 5 gbgs 166: bo oe ¥ x gy Aas 35 Moz. 30. 5)) Gbes O&= as ape asym, 5 /GbRS5y 5 40: 5 tp Se bose ™ 9Ck; 64; 43; asym. Aly gts 16. ao gae pls Was as : is 42, , gbv; 44; 54: 53: See saree ee Se eS et pe Le ae) Aa. 3; Gee GOs) Ga so. . oH. Ae MS? Seated Sas e 45. 5 bw; 44: 54: 43- i Py=1; F=2. 46, ,, -) 8528 ee us. .M;54;55;53; asym, 47. ,, Bue; 55; 54; 33; - » » 65;63; 53; ss 48. Cd; 44; 65; 43; ; gNG (2; Woo Moz. 49. 3, » (6A8: 43-233) y glvs De noo. OOF asym. DO. 5) ay) eee rOoe eae s y » O04. 63543; f Ol. 4 9Ces 10335 40" Bor s » 99; 64; 53; 44; . 52. , , 44; 65; 48; : ol ; 64,44; 63; 43; - De: yee ih" Dee Gor aepe P Fie seit Seesyoito pp Moz. " 54 ,,. 9Cm; TA; 7833-44" Moz, » oV; 64; 54; 43; asyn). DOL / T4; 78,Ad ee DO. SO ee eor ip 06. ,, On; 64,44; 53; 44; f 11. |, 4 Wsobsbas 43: - 57. yo yt vbaghe be, ame is 12. , 4. 54,64;5454;43: , 58. ,, jCps b4e6S- 53: asym. 13. ,, 9X;55; 44; 44; ‘ D9, |) Wb; 44.7555 .50- 5 aaa 14. ,, ,Aa; 54,54; 54,44; 43; ,, 60. 38 Gye (66255o-"33 2. ae 1D. 9 | ago ba aBe aw G1" 5 SDR SEreoe sae asym. 16, ,, Ac; 54;64; 63; = 02905) gDms T4276 bas a ie 3) Spe ee As eM 18. 4, gid $747 742750, (4s n mf TOS OS: “ly, © 64364 (65 es ; 543 » ,. Pe «Cf; 74; 75; 44; 33; _,, ‘ : emi sees > 2, , JK; 65; 64; oe : Pome, » 95; 65; 63; 33; _,, epee gs 27. ,, Ch; 15; 76; 65; 93; , NS i al ee ceme, (07, 425 76; 765° 735) | ,, A ieeet ce beakes- rj ‘ Pome, »,. 91;.87; 835 33; ,, Pak Ia ile Eas Pate 30, Ave; 54; 65;°63; 43; , epee Hee, » g¥ 365; 54; 55; 65; asym. Se hos tasoo7 45: gAn; 77; 44; 77; 33; Moz. gl; 73; 74; 54; 53; asym. 1. us. J; 55; 55; 54; 54; - o i oS eX us. ,A; 64; 64; 2p. Mox. Het. a é . MI. » gC; 64; 54; asym. » gD; 54; 54; 2p. Mox. Het. Kop) EO, 4. ,, X; 54; 44; asym. ho 1, us. ,E; 75; 74; 54; asym. » 7; 65; 65; 54; Moz. bo F,=2; Fy=1. oN. us. .E; 74; 74; 44; asym, F3=1; F,=1. me! Oo: 64: 65.65; ,, Pee, 005, 6463.63 _,, Peg! 7 O45. a0 5 Od, : sG; 65; 54; 43,63; __,, meow Op wos: 43655. ,, Pe Ot; 545 54; i » gl; 65; 64; 53; : » of; 54; 54; 58; Moz or: » gM; 95; 54; 43; asym. eee GE 8 aR; 85; 84; 83; ; Se ae Poe Bo (Ost; Go; . io, ,U; 64; 55; 65; z re 00.’ GO 63; Peek (Als OF: i us. .B; 66; 44; asym. ge LOSE | g gh 095 935" ,, gO CFs | 5, eAm ; 55; 33; 2z0. Mox. Het. eae ibe = = Cota AR oN ol Se ee SS us, gE; 75; 73,45; 54; asym. Be iy ch Loon OA es DT LMG Das be 4 3 tee eiOGH oor sor Moz. po i POON RE — oo 490 REV. T. P. KIRKMAN ON 5. us. ,.F; 755 73; 44; asym. gel 6. , gG; 76; 43; 438; - Te 5% ot OOD bas DAM Aa ye 8. | (65,085 54543; 1. us. ,A; 65; 65; 2p. Mox. Het. 9. 4, —Q; 66; 43; 43; 2p. Mox. Het. 10.~,, 2! Goeads4se asym. 1, gp Gb osneos Moz to We 12. 4,“ ODS wor aa * Rynig \aeesis P= 2) 1S. 4 - gets ae 33 - 14. 5 gf@3Sbn Shee asym, 1. us. ,C; 86; 83; asym. Ld. 3, (ee aes Oe : Zc, AAO ore. O° UG. oy se DOOD s 6h 7G ; 66; 53; Moz. 0Q- 10 W. Kylee RyS32 =i) B= TS. alg Orga sone too « asym. a ges Oe is us. ,E; 87; 83; 43; asym. ya, TOS DAS G eae es Tiles de Aa se “J ; 66; 55; 33; Moz. oe hob : ” oR. ioe ie (0, 3 2 1 1.8 1. us. ,C; 85; 84; asym. , ; 2 » »D ; 65; 54; ” ; el Est By a5 Gg TOG AA Fit, 1. us. ,A;'76; 54; asym. ws: ie'¢ F;=1; F,=1; F=1. dye B=: shea 1, us, ,E; 76; 54; 73; asym. 1. us. ,B; 77; 54; 53; Moz, % » mo; 8b5aay me OPE thes) te capa 2 ay EE, Bi on gly Oa OpoUee ue A 5. nh ODEO EEOSr= 7. 5Y rT yes 7637 o2A35% »” 6. .od8 oy SBS URRb4ia PG Tey 5 T7144 38) Moz, : B.. i gy 00 Aeon e. 2) Fy=1; Fj=1. 1, us. A; 96; 95; Moz. ol: Fo=Ls) dese =O 0A 1. us. .B; 75; 74; 55; Moz, Fy=1; F,=1. 2. , C377; 76; 76; 220, Mox. Het, 1, us. ,A; 87; 43;asym, UNIFILAR KNOTS OF TEN CROSSINGS. 491 109: oe F,=1; F,=1. ora Bai; Fei. us. ,A; 97; 94°; Moz. . ius. ,A; 98; 93; Moz: 0 ®- Bt; Fo). jes 61a 1. us. ,A; 77; 55; 2z0. Mox. Het. T. ys. ,A; 99; 33; 220, Mox. Het. Finally, there is one solid unifilar knot, the ,B described in art. 68 of my ir above referred to. In that article the quadrifilar (4466) ,,A is ly designated a zoned triaxine; that ,A is a 4-zoned monarchaxine XXVII.—On Knots. Part III. By Professor Tair. (Plates LXXIX., LXXX., and LXXXT.) (Chapter I. read June Ist, Chapter II. July 20th, 1885. One change, small but important, was made during printing. It is described at the end of the paper.) The following additional remarks are the outcome of my study of the polyhedral data for tenfold knottiness, which I received from Mr Kirkman on the 26th of last January. My main object was, as in the first chapter of Part II., to determine the number of different types; as well as the number of essentially different forms which each type can assume, as distinguished from mere deformations due to the mode of projection. This study has been a somewhat protracted one, in consequence (1) of the great number of tenfold knots; (2) of the very considerable number of dis- tortions of several of the types, many of which are essentially distinct while others present themselves in pairs differing by mere reversion; and especially (3) of the fact that the polyhedral method often presents some of the distinct forms of one and the same type projected from essentially different points of view (of which, in the present case, there are sometimes twelve in all). Reason (3) depends on the fact that Kirkman’s method occasionally builds up various forms of one type on different bases of a lower order, and it really involves additional labour only ; but great care is requisite to avoid confusion as regards (2), and in consequence I may not have fully reduced the final number of distinct types. [At the end of this paper I shall give a simple illustration of the nature of this special difficulty. | The fact that I was dealing with knottiness of an even order induced me to commence the testing of the materials at my command by picking out the Amphicheirals. This led to some new considerations of a very singular nature, which are treated in the first of the following chapters. The second deals with the tenfolds as a whole. I. Various Orders and Classes of Amphicheirals. 1. As one form of check on Kirkman’s results, I sought for an independent method of forming all the amphicheirals of a given order. But, as will be seen below, we must be careful in this matter, which is not so simple as I first thought. I therefore commence by recalling the original definition of an amphicheiral. VOL. XXXII. PART III. 4M 494 PROFESSOR TAIT ON KNOTS. In § 17 of my first paper I introduced it thus :— An amphicheiral knot is one which can be deformed into its own perversion. The word ‘“‘ deformed” was here used in the sense of alteration of form by mere change of point of view, or mode of projection; a process which leaves the number of corners in each mesh, and the relative positions of the various meshes, unchanged. This definition implies that the right and left handed meshes are similar in pairs and similarly situated in congruent groups; and it will be adhered to for the present, though we shall afterwards find that there are at least three other senses in which a knot may be called amphicheiral, and shall thus be led to speak of different orders and classes of amphicheirals. The above definition will then be considered to belong to amphicheirals of the First Order and First Class. 2. Suppose an amphicheiral knot to be constructed in cord, and extended over the surface of a sphere which swells out when necessary so as to keep the cord tight like the netting on a gazogene. Let its various laps be displaced until the several corresponding pairs of right and left handed meshes are made equal as well as similar. Trace its position on the sphere. Now suppose it to become rigid, and move it about on the surface of the sphere. We can again bring it to coincide with its former trace, but in such a way that each left-handed compartment now stands where the corresponding right-handed one was, and each right-handed where its corresponding left-handed was. Now such a displacement, as we know, can always be effected by a finite rotation about a diameter of the sphere as axis. This axis, of course, cannot terminate (at either end) inside a mesh, else that compartment could not be shifted by the rotation to the original position of the corresponding one of the other kind. Hence either end of the axis must be at a crossing, or midway on the lap of cord passing through two adjoining crossings. A little consideration shows that if one end be at a crossing the other also must be at a crossing, and the whole must be a link. This is easily seen from the fact that, if one end of the axis be at a crossing, the four meshes which meet there must each exactly fit that next it when the whole is turned through a right angle; and the series which immediately surrounds these must possess a similar property, &c., &c. Thus the whole spherical surface must be covered with a pattern which consists of four equal and similar parts, each of which takes the place of the preceding one at every quarter of a rotation about the axis. And four laps of the string must there- fore proceed all in the same way from one end of the axis to the other; since, if we can trace one lap of the string continuously from one crossing to the other, exactly the same must be true of the other three. [Of course, if the string cannot be traced from one crossing to the other, there must be two separate strings at least. | PROFESSOR TAIT ON KNOTS. 495 Hence, for a true knot, both ends of the axis must be the middle points of laps ; and therefore— There must be two laps, at least, in every amphicheiral knot, each of which as common to a pair of corresponding right and left handed meshes; and when the whole is symmetrically stretched over a sphere the middle points of these laps are at opposite ends of a diameter. 3. With regard to the middle point of either of these laps, the various pairs of corresponding right and left handed meshes are situated at equal arcual distances measured in opposite directions on the same great circle. Hence if the whole be opened up at the middle point of either of these laps and projected on a plane symmetrically about the middle point of the other, the halves into which the plane figure is divided by any straight line passing through the latter point are congruent figures applied on opposite sides of that line as base; the point being, as it were, a centie. There are, thus, at least two ways of opening up any amphicheiral knot so as to exhibit this species of quasi-symmetry. What precedes is on the supposition that the system of right, or of left, handed meshes can be applied to itself zm one way only. If there be, as happens in some specially symmetrical cases, more than one way of doing this, there is a corresponding increase in the number of pairs of common laps, as defined in the preceding section. It has also been assumed above that, on the sphere, the systems of right and left handed meshes are not only similar but congruent. The question of the possible existence of knots in which the system of right hand meshes shall be the reversion of the left hand system will be considered later. 4. Wenow obtain a perfectly general, though of course in one sense tentative, method of constructing amphicheirals of any order. Think of the result of § 3 as to the congruency of the halves of the knot when opened at either of the pair of corresponding laps. Asa continuous line necessarily cuts the projection of a complete knot in an even number of points, the half figure which is to be drawn on one side of the common base must meet it in an odd number of points because one lap has been opened. Let these be called, in order, A, B, C, &c. Then, to form the half figure, these points must be joined in pairs, the odd one forming one end of the line whose other terminal is at the broken lap. These joining lines, and that with the free end, must be made to inter- sect one another in a number of points equal to ha/f the knottiness of the amphicheirals sought. Every mode of doing this gives a figure which, when its congruent has been applied on the other side of the base, possesses the amphicheiral quasi-symmetry above described. 5. To ensure that the figure shall be a knot, and not a link ora set of detached figures, the following precautions are necessary. If A’, B’, C’, &., 496 PROFESSOR TAIT ON KNOTS. in the congruent figure correspond to A, B, C, &c., in the original, they will be adjusted to one another as follows. (The case of five is taken as being suft- cient to show the general principle.) ABCDE E/ D’ C’B A’ Now if B be joined with D, however the joining line be linked with the others, B’ will be joined to D’; and these parts will form, together, one closed circuit, so that the figure is not a knot. Similarly if A and E be joined. Similarly if A be joined to B, and also D to E. If C be the terminal of the free lap, so will C’; and again we have a figure consisting of more than one string. It will be observed that the common characteristic of these excepted cases is that each possesses at least partial symmetry in the mode in which points to be joined are selected from the group. Hence the rule for selection is simply to avoid every trace of symmetry. Even when this is done the final result may be a composite knot, 2.e., two or more separate knots on the same string. These can be detected and removed at once, so that it is not necessary to lay down rules for preventing their occurrence. Repetitions of the same form from different points of view form the only really troublesome part of this process. These are inevitable, as we see at once from the fact that there may be several essentially different ways of cutting the complete quasi-symmétrical figure into congruent halves by lines meeting it in the same odd number of points. But it may also often be cut by one such line in one odd number of points and by another in a different odd number. Still, with all these inherent drawbacks, the method is applicable without much labour to the tenfold amphicheirals ; and it fully answered my purpose, 6. I had proceeded but a short way with the application of this method when I found that there may be more than one distinct amphicheiral belonging to the same type. One example of this had been already given in § 48 of Part I. while I was dealing with amphicheirals, and again in Part II. in my census of eightfolds (Type V.), but I had carelessly passed it over as a special peculiarity probably due to the fact that the knot in question, though not composite, was constructed of portions each of which possessed, all but complete, the outline of the four- fold amphicheiral. From the point of view taken in § 4 above, however, the reason of the property is evident. For if the half knot, when the extremities of the strings are all held fixed, be capable of a distortion which shall change the relative positions of some of its meshes or the numbers of their corners, PROFESSOR TAIT ON KNOTS. 497 the same can of course be done with the congruent half. ‘The whole pre- serves its type, and is still amphicheiral, but it becomes an essentially distinct form. 7 It will be seen that there is one type of tenfolds which has four different amphicheiral forms ; another contains three ; while there are four types each with two forms. The remaining seven amphicheiral types are either unique forms or have no amphicheiral distortion. 7. We are now prepared for one extension of the definition of an amphi- cheiral given in § 1 above. But we prefer to establish a new and independent definition :—thus An amphicheiral knot of the First Order and Second Class is one which can be distorted into its own perversion. Under this definition every distortion of an amphicheiral knot is included, even although it be such that its right and left handed meshes do not corre- spond to one another in pairs. For, whatever be the distortion, and whatever parts of the knot be affected by it, an exactly similar distortion might have been applied to the congruent parts of the original amphicheiral. These two distorted forms are, of course, capable of being distorted one into the other :— and that other is its perversion. Every amphicheiral knot of the first order and second class corresponds to, and can be distorted into, at least one of the first class :—but the converse is not necessarily true. 8. Whether there are other classes of amphicheirals of the first order besides these I do not yet know. I have made attempts to construct a specimen of a supposed Third Class which should have the property of being changed into its own perversion by the twisting of a s¢ng/e, limited, portion, while the result could not be obtained by any simpler method. Such forms, if they exist, must in general be incapable of distortion into amphicheirals of either the first or the second class. This search has been fruitless. Among the requirements which it introduces, is the necessity for an ordinary amphicheiral in which two pairs of corresponding right and left hand meshes shall have one common corner ; a condition which does not seem to be satisfied except by the simplest (amphi- cheiral) link, in which indeed it must be satisfied, as there are but four com- partments in all. But this gives no satisfactory solution. 9. We may now take up the curious question raised in the last paragraph of § 3 above. A simple method of producing arrangements in which the group of left- handed meshes is similar to, but not congruent with, that of the right-handed follows at once from the fact that, if one end of a diameter of a sphere trace a figure of any kind, the other end traces a similar and equal but (except in Special cases of symmetry) non-congruent figure. These figures can, if we 498 PROFESSOR TAIT ON KNOTS. choose, be taken so as together to form one closed curve; and this, along with a great circle of the sphere, forms a link of two cords possessing the required — property. On the plane we can carry out this construction by describing any - figure within a circle, along with its inverse as regards the circle but on the opposite side of the centre; and arranging so that these may join into a con- tinuous curve linked with the circle. But this arrangement vemains a link when we unite the new curve with the circle by so introducing new meshes as to leave the whole possessed of the required property. Or, we may trace any curve on a hemisphere, and its image (in the common base) on the other hemisphere. These, together with the great circle separat- ing the hemispheres, give another link solution. It is clear, from the essentially limited nature of the spherical surface, that — these two methods give the only possible solutions of the problem :—.e., when the corresponding right and left handed meshes required by the conditions are made equal in pairs, the lines joining similarly situated points in them must either meet in one point (which, of course, must be the centre of the sphere), or they must be parallel. 10. As I did not at once see how to obtain solutions corresponding to unijilar knots by means of either of these methods, I asked Mr Kirkman whether he knew of a polyhedron which possessed the requisite property. The first he suggested to me corresponded, as I easily found, to a trifilar which belongs to the results of the first method above :—z.e¢., one of its cords being taken as the circle, the other two were inverses of one another with regard to it. But, as soon as he mentioned to me that the polyhedron, corresponding to a composite knot consisting of two separate once-beknotted 5-folds on the same string, satisfies the special conditions of the present question (though inadmissible on other grounds), I saw why I had failed in obtaining unifilars by the first of the two methods above. For the purpose of avoiding trifilars from the first I had always made the curve traced by either end of the moving diameter (in the process of § 9 above) cross the great circle wherever it met it, so as to join that traced by the other end. No insertions of new meshes could then reduce the whole to a unifilar without depriving it of the property for which it was sought. 11. But if we make the closed curve traced by one end of the moving diameter touch the great circle in one point, the point of contact must of course be regarded as a crossing, while the circle and the closed curve necessarily fuse into one continuous line. The same happens with the curve traced by the opposite end of the diameter. Thus we may obtain with the greatest ease any number of unifilars satisfying the conditions. And it is clear that, by a slight extension of the definition above, all such knots will be brought under the general term amphicheiral. To make them true knots, 7.¢., not composites, th PROFESSOR TAIT ON KNOTS. 499 curves traced by the ends of the diameter must intersect one another, which implies that they must each cut the great circle in two points at least besides touching it at one or more. Hence the lowest knottiness in which they can possibly occur is 10-fold; 7@¢., 2 points of contact with the great circle, 4 intersections with it, and 4 intersections of the two branches. This process fails when applied in connection with the second method of § 9, for it brings in triple points which cannot be opened up into three double ones without depriving the whole figure of the desired property. 12. The 10-fold, whose genesis is described in last section, has the form shown in Plate LX XIX. fig. D, where the great circle is made prominent. It is easily recognised as the ordinary amphicheiral, fig. 31, of Plate LX XX. The reason why it figures in both categories is that the arrangement of the right or left handed meshes, being symmetrical, is not changed by reversion. Thus every ordinary amphicheiral, which is in this sense symmetrical, belongs also to the new kind of amphicheirals with which we are now dealing. Plate LX XIX. fig. A shows a 12-fold knot, which is its own inverse with regard to the part drawn as nearly circular, and which is not amphicheiral in the ordinary sense. Equal distortions of two corresponding parts give it the new form fig. B, which is also its own inverse with regard to the circular part. But if, as in fig. C, we perform one of these distortions alone, the form is no longer its own inverse. But it is certainly amphicheiral, in the sense that it can be distorted into its own perversion. ‘Thisis effected, of course, by undoing the single distortion which produced C from A, and inflicting the other of the pair of distortions which, together, produced B from A. 13. Thus there are at least four different senses in which a knot may be amphicheiral. A(a) Those in which the systems of right and left hand meshes are similar and congruent. A(f) Unsymmetrical distortions of any of the preceding, when such exist. | When the distortion is symmetrical the knot remains one of A(c). | B(a) Those in which the systems of right and left hand meshes are similar but not congruent. B(@) Unsymmetrical distortions of any of the preceding. [When the distortion is symmetrical the knot remains one of B(c). | A and B may be spoken of as different Orders, the First and Second; a and B as Classes, First and Second. As already stated, the knot of fig. D belongs to both orders. But no knot can belong either to both classes of one order, or to the first of one order and the second of the other. 14. In fig. (D) the 10-fold (fig. 31) of § 11 is drawn so as to exhibit its symmetry. And we thus see at a glance that there are at least two ways 500 PROFESSOR TAIT ON KNOTS. (indicated by heavier lines, one continuous, the other dotted) in which we can choose the laps which are to form the circle with regard to which it is its own inverse. Fig. 38 of the 10-folds, which by reason of its symmetry belongs to both orders of amphicheirals, can have its circles shown as in figs. (E) and (F). 15. But if we take a non-symmetrical knot of the kind B(a), such as fig. A above treated, we obtain some still more striking results as to the number of ways in which we can choose the laps which form the circular portion. In this figure corresponding right and left handed meshes are marked with the same letter. Thus, if we throw out the right hand mesh, d, from the contents of the circle and take in the left hand d instead, the figure (drawn to show the new circle) becomes fig. G. If we throw out 7 and take the amplexum instead, we obtain fig. H. ' But, if we throw out from the circle g, c, and e, and take instead of them the corresponding external meshes, the figure takes the curious form K. Here the full line is the new boundary between the two halves of the figure. This new boundary, as well as the entire figure, is easily seen to be its own inverse with regard to the part bounded by the heavier portion of the full line. This, however, is only one of four ways in which it might be selected from the full line alone. Such modifications are very curious as well as numerous, but we cannot pursue them here. 16. In the upper rows of Plate LX XIX. I have given the amphicheirals of the first class, up to the tenfolds inclusive. They are drawn on the principle of § 4 above, and the first form in which each presented itself has been preserved. A comparison of these, with the corresponding figures as drawn in Plate LX XX. directly from Kirxmay’s results, is very instructive. [ Added, Oct. 19, 1885.—Though the general statement in § 11 above is true from the point of view there taken, there is a possibility of evading it. Thus, if we draw a figure like E, Plate LX XIX., but with a four-pointed star inside, we get vil. of the 8-folds; which is thus shown to be an amphicheiral of the Second, as well as of the First, Order. But, if we try a three-pointed star, we get the simp'est trifilar locking ; as in Part I. § 42 (1), and Part II. § 8.] PROFESSOR TAIT ON KNOTS. 501 II. Census of Tenfold Knottiness. 17. Omitting composites, the number of separate types of 10 fold knottiness is, as shown in Plates LXXX., LXXXI., 123. Of these 48 are unique, while the remaining 74 give 315 distinct forms, 364 individuals in all. The largest number of distinct forms for one type is 12; and there are two such groups. One type which furnishes a group of 10, has 4 of them amphicheirals of the first order and first class, the remainder of the second class. Each of the figures is drawn in the special deformation in which it is presented by the polyhedral method; and, for reference, the corresponding designation of the knot in KirxMan’s list is appended to it. 18. Of the 107 partitions of 20, under the limits imposed by the nature of a knot, 52 only are utilised; the rest belonging to links, composites, &c. These are as below; each being followed by a distinctive letter, which will presently be employed (for brevity) in place of it. ; For knots with 6 right-handed and 6 left-handed meshes :— ErratumM.—Page 501, par. 17, line 2, for 48, read 49. a 1B ‘y ne) (4452 € 55532 q 4433222 ¢ 74333 f 50442 r 4333322 € 66422 g 55433 s 3333332 y 66332 h 54443 ¢ 65522 k 44444 yw For 4 of one and 8 of the other :— 8732 a 7652 f 43322222 0 8633 b 7643 ¢ 33332222 k 8552 ¢ 7544 h 8543 d 6653 k 7742 e 6554 1 And for 3 of one and 9 of the other :-— 992 p 965 5 332222222 Xr 983 q 875 t 974 r 776 u 19. In Part II. of this series I arranged the types of each degree of knotti- ness in the order in which their respective deformations first appeared in Mr VOL. XXXII. PART III. 4N 502 PROFESSOR TAIT ON KNOTS. KirkMan’s lists. This had the disadvantage of mixing up together types with very different relative numbers of right and left handed meshes. On the — present occasion I have taken in the first rank the knots which have an equal number of meshes (six) of each kind, next those which have respectively 5 and 7,4 and 8, &c. This will considerably simplify the process of seeking for any particular ten-fold in so long a list. The arrangement of the various types in each rank, however, follows somewhat closely the order of their earliest — appearance in the first list which I got from Mr Kirkman, that upon which I- commenced the present work. To identify any 10 fold, all that is necessary is to count the numbers of corners in the respective right and left handed meshes, look out the contracted expressions for the corresponding partitions of 20 in § 18, and then search below — for the symbol, or pair of letters so obtained. Their order, of course, is imma- terial, as it can be altered by a mere change of mode of projection. If the symbol occur more than once, a closer examination must be made, account — being now taken of the way in which the right, ov the left handed, meshes are coupled together. This is easily done as in § 20 of my first paper. 20. The number of distinct forms which I detected as not contained in Mr — KirkMan’s first list of 10 folds bears a far smaller ratio to the whole than was the case with the ninefolds. I consider that this is due not to my remissness, but to Mr KirkMman’s improvements in his methods, ¢@.¢., rather to the non- existence than to the non-detection of omissions ; and I think it is improbable that any distinct variety of a recognised type has escaped detection. Thus in the present census some types may be omitted (this is more likely to be true of unique types than of others); and I may have, as already indicated, grouped in two or more smaller detachments the varieties of one and the same type. But the possibility of either defect is due to the somewhat tentative nature of the methods employed. The guarded way in which I spoke (Part II., § 1) of the completeness of the Census has been justified by a recent observation made by Mr Kirxmavy, viz., a9 fold not included either in his list or in mine. Fortunately this knot, figured as fig. L, Pl. LX XIX., is not a new type but a distinct form of type VI. of the 9 folds as shown in the Plate attached to Part II. My methods ought to have supplied this additional member of a group, of which some forms had been furnished by Kirkman; but I had not, at the time, much readiness in applying them. The labour of the 10 folds has made me much ~ more skilful than before in this matter, 21. In the following list, the order is the same as in the plates. The symbols for each knot are so written that the second, in all cases, corresponds to the group of meshes to which (as the figure happens to be drawn) the amplex belongs. PROFESSOR TAIT ON KNOTS. 5038 The various Types of Tenfolds with their distinct Forms. Six right and six left hand meshes ; 24 non-unique types, 14 unique; 133 individual distinct forms in all. Amphicheirals of the first order and first class are marked by a bar over the symbol instead of a repetition. BeaCeCO,.GGlI0G, KC KG, GiGK, K .., 2. HC, GF, GF, GF. . HB, LB, BC, GB, BG, KB, HF, FC, FG, LF, GF, FK. hGH, KE GE, GE, BK, GB, GB, KB, BG, GB, EK, EG. / EF KB, FB, BF, FF,FK. 6. GE, LE, KE. Sib bC PB BB, EG, BE FE FG, FB. 8. EK,KF 9. F.FF.F. 10. GF KF. weene Ke, BB, Gr, KG, GB, EF, KB, BE. 12 L¥,LF,FH. 13. KG,K, G. i]s §.G, EB, BG,EG. 15. A,EA,E, 16. BB, FB, KB, KF, FB, FF. a Gt Gr 18. FD;DB,KD. 19. FA, KA, FA. GA, GA, EA. worBA, KA, KA, AF 2 GA,GA,AF,BA. 22. FB,B,F 23. DB, FD. iW A Ady 25. KG. .26:.G. Drab ae Celine 292K | 30s LG. 2 EE 633. WE 34, BE 35..D. ~ 86. AD. . 37.A, .38. 0, STIo Ff © Five meshes of one kind, seven of the other. Forty-three non-unique types, twenty-one unique—200 distinct forms in all. 39. €5, €S, EP, YP, SY, SY- 40. em, em, ef. Al. el, ec, yl, ye, ne, nl, Sl, Se, ef, If. 42. &, yl, el, ya, €g, &. 43. ef, em, ep, €s, yf, ym, ys, yp, PS s& Em, Ef. 44, se, te. 45. &d, th, ch, ch, ed, ed, hf, dé. 46. &, &, ml. AT. kr, ek, nk, &. 48. eh, ed, em, h3, mB, dB. A9. &, &, ne, ye, &, ec. 50. gy, eg, &9, Sg. DI. 66, 6b, fb, be, yb. 52. Bb, cb, HB, ch, eh, ed. 53. er, Br, el, el, Bl, 1B. 54. ve, fe. 55. sB, (8, mB, sB, pP, sB. 56. Of, dp, os. 57. my, yn, en, en. 58. Gr, ry, €¢, ye, &, er. 59. Ol, 89. 60. ee, ey, ly, el, &, &. 61. ee, el, et, 8, eB, IP. 62. ¢8, pB, IB, él, ep, ee. 63. ek, ky, Ch. 64. Bl, Ba, 8. 65. rf, ec, er, Be. 66. &b, Bb, eb. 67. dB, mB, Bl. 68. dB, Bl, sf. 69. eg, gy. 70. dd, 06. TL. Br, g8, eB: 72. (Bor 8. 73. pa, ta, la, ra. 74. ec, 7B, re, cf. 75. ek, Bk. 76. Be, ec. 77. ea, ea, a8. 78. dB, LG. wo: Be; ec. 80. ra, ac. 81. ha, ab. 82. fu. 83. se. 84. et. 85. & 86. &. 87. 78. 88. pF. 89. er. 90. fn. 91. eg. 92. re. oc meme 95.¢e. 96.d Mile 98 cl 99. ch, 100.6% 101.46. 102. aa, _ Four meshes of one kind, eight of the other. Seven non-unique types and eight unique—twenty-five distinct forms in all. 103. «f, Of. 104. «a, «a, Oa. 105. «d, «ge, dd, gé. 106. «ce, Oc. 107. 6d, 10. 108. Ob, g@. 109. 61, Oh. 110. «k. jE iat M3 112, xh. 113. xg. 114, 6k. 1 GeO 116. Oe. ag) Three meshes of one kind, nine of the other. Six unique types. Meme) 119) xg, 128) Ap, 104, re.. 122 rr 128, at. 504 PROFESSOR TAIT ON KNOTS. 22. The nature of the special difficulty hinted at in the beginning of the paper will be easily seen from the simple case illustrated by the four figures M, Plate LX XIX. They denote various forms of the type 40 of Plate LX XX. It will be noticed that the crossings A, B, C may, one, two, or all, be changed from one lap of the string to the other, as shown in the second figure. Also D may be transferred to a position between A and B, or between A and C. There are thus two positions for each of A, B, and C; and three positions for D; giving 24 combinations in all. But it is clear that we need not shift D at all, so far as the outline of the figure is concerned; for a mere rotation of the whole in its own plane (as A, B, and C are similar to one another) will effect this. Then a change of B will merely give the reverse of the figure obtained by changing C. Again, by inverting the first figure about a point in the inner mesh, we get the second. If we had changed C, and then inverted, we should have got the same figure as by changing simultaneously A and B. By changing C alone in the first, we get the third; but by shifting D in the first we get the fourth ; and these two are obviously each the reverse of the other. Thus the 24 figures reduce to the three shown in Plate LX XX. As another example, take the third form of the third type of 10 folds as given in Plate LXXX., — Two of thecrossings on its external boundary can be shifted, but each to one other place only. The form itself, and the same with one or both of these crossings shifted, give a set of four; each of which can take five new forms by the shifting of other crossings. But it will be found that the 24 forms thus obtained are identical in pairs ;—thus reducing to the 12 given in the Plate. 23. Mr Kirxman informs me that he has nearly completed the enumeration and description of the polyhedra corresponding to the unifilar 11 folds. I hope, therefore, at some future time to lay before the Society the census of 11 fold knottiness. This was the limit to which I ventured to aspire nearly two years ago, in a paper* which, I am happy to think, directed Mr Kirxman’s attention to the subject. 24. It must be remembered that, so far as these instalments of the census have gone, we have proceeded on the supposition that in each form the crossings — have been taken over and under alternately. But, as was shown in § 13 of — Part I., as soon as we come to 8 folds we have some knots which may preserve their knottiness even when this condition is not fulfilled. These ought, there- fore, to be regarded as proper knots and to be included in the census as new and distinct types. This is a difficulty of a very formidable order. It depends upon the property which I have called Knotfulness (Part I. § 35; IL. § 6), for whose treatment I have not yet managed to devise any but tentative methods. To show, by a single case (even though not thoroughly worked out) of how * Listing’s Topologie, § 22, Phil. Mag., Jan. 1884, PROFESSOR TAIT ON KNOTS. 505 great importance is this consideration, I have appended to Plate LX XIX. the five figures N ; with the nature of each crossing indicated. The numbers affixed show the positions they occupied in the census of 8 folds, when the crossings were alternately over and under. Then they were all unique knots, incapable of any change of form. Now they are capable of being changed into one another. The linked trefoils in N, xiv. are perversions of one another. But we may have them of the same kind, and the link such that there shall be continuations of sign. This was briefly treated in Part I. § 42,1. How many new types may by this process be added to the census, I have not yet made out with certainty even for the 8 folds. P.S.—I may introduce here, as a note on Part I. of this series of papers, a remark or two with reference to the three-ply plaits treated there; in § 27 as fully knotted, and in § 42, 1 as fully beknotted. First, it is obvious that the 4 fold, as first drawn in § 17, should have been repeated in Plate XV., at the head of the series of figures 15, 16,17, &c. Itis the case of 3n+1 of § 27, with n=1. Secondly, with its crossings arranged as in fig. P, Plate LX XIX. of the present paper, it should have come in before figs. 24 and 25 of Plate XVI Part I., in a form reducible to the ordinary trefoil. Fig. 25 of that Plate puzzled me much at the time when I drew it, for I could not account for the production of a 3 fold and a 5 fold (linked) from a figure possessing a peculiar kind of (cyclonic ?) symmetry round an axis. The figure is accurate, but I now see that it gives an erroneous impression of the true nature of the knotfulness. The correct idea is at once obtained from Plate LX XIX., fig. Q, of the present paper. The knot is an irreducible trefoil, with a second of the same character tied twice through one of its three-cornered meshes. (Added, September 3, 1885.) Three days ago I received from Mr Lockyer a copy of a most interesting pamphlet ‘“ On Knots, with a Census for Order Ten,” a reprint from the Trans Connecticut Acad., vol. vii., 1885. The author, Prof. Lirrte of the State Uni- versity, Nebraska, has made an independent census of 10 fold knots ; employ- ing the partition method, with some new special rules analogous to those in Mr Kirxman’s recent paper. So far as I can judge from a first hasty compari- son of the mere number of types and forms in each class, there are important discrepancies between this census and my own. One of these, at least, is due to a slip on my part; and, as my paper was not printed off when I detected it, I have taken the opportunity of correcting it both in the text and in the corresponding Plate. I had failed to notice that the two forms which now appear under No. 109 really belong to one type. Hence I have had to VOL. XXXII. PART III. 40 506 PROFESSOR TAIT ON KNOTS. reduce by one the number of the distinct 10 fold types which was originally given in my paper. I hope in time to make a full comparison of the two versions of the census. Meanwhile I may note that there is one omission, and also one duplicate, in Class VI. of Mr Lirrte’s version. This duplicate has led him to insert one type too many. More than a month ago I received from Mr Kirkman the full polyhedral data for the census of 11 folds, which I hope soon to undertake. The number of forms is so great, and the time I can spare for the work so limited, that I cannot promise it at an early date. 5 a D I IV VII 1x XIV 8 3.Tait del F.Huth, Lith* Edin™ BE GSSESES| FSS BSE COS FBOaseS BaS@eoeseseneels VOSS QS sieegee be (S| © @ |G Eb 3 fe BS JBEBEOVGER Jers) O28), On| Sers IGCISSe SEaTRA - Hse oe | FSSS BSOO8 IBC EOE @e Da haba © OS 0 15 3 m € m € Fe € l = = c7m — ceo - pw —- ; ps = D2 = cés 43 WOLStAs FO0 a6 F Huth Jath® Edin? y. Soc. Edin Meee Ore Dr SKNO'T Tt NE SS. Vol. XXXII, Pl. LXXXI. CEE EREERISD Ion Ese fee BiVE ages By ee JE Oe ORT: Bud sunossace le SOx H8\O9 268 OCS GS Li SSSaire O22 GSgiaVeuges ie) S (SS Sees eS HSCs ES SHws Ke G8) ele} @ @) eh EXO PHL OUE oe Enice Beoes ia AURBA Ge SSeS spo ggaagooacg F Huth Litht Edin? 6 10 ( 507 ) XXVIIIL—A New Graphic Analysis of the Kinematics of Mechanisms. By Professor Roserr H. Smiru, Mason College, Birmingham. (Plate LXXXII) (Read 19th January 1885.) A mechanism may be defined as a combination of plates, bars, or flexible - members jointed together, so that, while the parts may move relatively to each other, the relative positions of all the different parts are determinate for each given possible relative position of any two parts. It follows immediately that the simultaneous relative displacements, velocities, and accelerations of velocity of all parts are also strictly determinate. This determination, by accurate graphic means, forms the subject of this paper. In it those mechanisms alone are considered that are composed of rigid members, the motions of whose parts are all continually parallel to one plane, the constancy of the plane being defined relatively to one of the members of the mechanism itself. The different rigid members of mechanisms will be termed “bars.” That bar relatively to which the displacements, velocities, and velocity-accelerations are measured, will be termed the base-plate or bed-plate. The displacement, velocity, and velocity-acceleration of the base-plate remain, of course, always zero. To avoid repetition of the cumbersome phrase “ relatively to,” this phrase is discarded for the shorter expressions ‘‘ through,” “past,” “ over,” or ‘“ round.” Every possible motion or other vector is through some field in which positions and directions may be defined in a determinate manner. It is improper to speak of the motion of one point past another, without mention of the parti- cular field through which the motion is measured, because two points alone are inadequate to define a field in which vectors may be measured. In what follows, when the field of reference is not mentioned, it is to be understood that the vectors are taken through the “ field of the base-plate,” 2.¢., through the space surrounding and defined with reference to the base-plate. On the other hand, it is perfectly definite to speak of the motion of a point or of a bar over, past, or round another bar, the motion being understood, without further mention, to be measured through the field of the bar round which it takes place. The graphic determination of the simultaneous positions of the various bars of most commonly used mechanisms is easy and well understood. When difficulties occur, as in various engine reversing link-motions, the special methods here explained enable them to be readily overcome. The /oci of the successive positions of the various parts may be called the “motion curves” or VOL. XXXII. PART III, 4P 508 PROFESSOR R. H. SMITH ON A NEW GRAPHIC more simply the “paths” of these parts. These paths are drawn in on the ~ “mechanism diagram.” From these “paths” the displacements from any assumed initial configuiaai” can be directly measured. It may, however, be often advantageous to have a separate “displacement diagram,” consisting of a series of curves, showing the successive simultaneous displacements of all important points of the mechanism as vector-radii from one and the same pole. These curves in the “ displace- — ment diagram” are, of course, exact copies of the “paths” in the “mechanism — diagram.” Let ABC and BDE be two bars linked together at the joint B. Let P’ be the pole of the displacement diagram, and let the curves A’A’, B’B’, D’D’ be | the displacement curves of the three points ABD. All these curves, of course, pass through the pole P’. P’A;, P’B;, and P’D), being simultaneous displace-. ments of AB and D, draw on A;B; and B,D; as bases, the triangles A,B,C; and B,D,E; similar to the triangles ABC and BDE in the mechanism. It can easily be shown that P’C; and P’E; are the simultaneous displacements of C and H, By joining all the points C’ and E’ found by such constructions, the displacement curves of C and E can be drawn in. Numerous simultaneous points on the various displacement curves should be marked, and numbered 1, 2,3, 4, &e. The advantage of such a displacement diagram over the set of “paths” dispersed over the mechanism diagram, consists in the greater facility of com- parison between the displacements of the various parts of the mechanism that it affords. Thus, comparing simultaneous points A’ and C’ belonging to the same bar, the vector A’C’ is the displacement of C’ past (or relatively to) A in the base-plate field. The same holds for points in different bars; thus, D’C’ is the displacement of C past D in the base-plate field. As a useful fact of - assistance in drawing these diagrams, it may be noted that any line, such as A’C’ belonging to one bar, is perpendicular to the line bisecting the angle between the simultaneous and “initial” positions of the line AC in the- mechanism. This does not, however, apply to a line, such as E’C’, joining points belonging to different bars. The method of obtaining the velocities by taking the small differences of the displacements, which method is the basis of kinematic analysis developed by means of the differential calculus, has often been adopted as a graphic process for the solution of specially complicated problems. After constructing the velocity hodographs, the same method may be followed to find the velocity accelerations. As a graphic process, however, this method is capable of no accuracy ; it is, in fact, practically useless. Professor RevLeavx’s method of centroids, more properly called axoids, has now become famous; but, although the writer has constructed the axoids of ANALYSIS OF THE KINEMATICS OF MECHANISMS. 509 many mechanisms, he has so far failed to discover any practical use to which these axoids can be applied. They are very tedious of construction, and when constructed furnish no direct means of measurement of any useful quantities. The method now proposed furnishes velocity and acceleration diagrams, somewhat similar im appearance to stress diagrams, which show the true directions and magnitudes to scale of the velocities and velocity accelerations of all points in the mechanism; there being one pole only for each diagram from which all vectors radiate, so that the velocities or accelerations of all parts and at all times of the complete cyclic period can be compared with maximum facility. Fig. 1.—Let ABCD be a rigid bar. Suppose the velocity of A over the base-plate P to be known. Choose any pole p, and draw pa parallel to the velocity of A, and of a length to represent its magnitude to any scale considered convenient for the velocity diagram. If now the angular velocity w of the bar be also known, ab may be plotted perpendicular to AB, and equal in length to «AB to the above velocity scale. Then, pb is the velocity of B over the base- plate. If, instead of w being known, we know the velocity of B as well as that of A, then pb may be plotted directly, and joining ab the angular velocity may, if desired, be calculated by dividing ab by AB. Since the (relative) velocity of C round A is perpendicular to AC, and its relative velocity round B is perpen- dicular to BC; if ac and be are drawn perpendicular to AC and BC, their intersection c gives pc the velocity of C through the base-plate field. Similarly, pd is found to measure the velocity of D. The diagram gives not only the velocities over the base-plate P, but also all the velocities of pairs of points relative to each other. For instance, bd is that of D round B, and db is that of B round D, these relative velocities being through the field of the base- plate P. It is clear that the figure abcd forms a diagram of the bar ABCD to a diminished scale and turned through a right angle in the direction of .* Further, on this new diagram of the bar, altered in scale and rotated through 90°, the pole p represents the position of the instantaneous axis of rotation, Theoretically, the original diagram ABCD, with the position P of the instan- taneous axis added, would serve equally well as a diagram of velocities, the scale being chosen suitably, so that PA would represent the velocity of A. But for practical graphic construction it cannot be so used, for several reasons. Firstly, the usual variation of the position of the instantaneous axis is extremely inconvenient, and in almost all mechanisms this axis periodically recedes to an infinite distance. Secondly, the scale to which it could represent the velocities *Tn an abstract of this paper written for the engineering journals, the late Professor Fiemmine JENKIN very expressively called abed the “image” of ABCD. In the acceleration diagram another “image” a'b’c'd’ appears. 510 PROFESSOR R. H. SMITH ON_A NEW GRAPHIC is always varying throughout the periodic motion of the mechanism; it is always necessarily an awkward scale to measure to, and it periodically becomes in most cases an impossible scale by becoming infinitely large. Thirdly, the various bars of a mechanism have all different instantaneous axes, and the scales of the velocities would be entirely different for the different bars. As will be shown presently, in the method explained in this paper, the velocity diagrams of all the bars of even the most complicated mechanisms are all grouped together so as allto radiate from one pole, and so as to be to the same scale for all the bars and at all times throughout the periodic motion of the mechanism. A similar construction is applicable to accelerations of velocity. In fig. 2 — let ABCD be one rigid bar. Let the acceleration of velocity of point A through the field of the base-plate be known, and represented in direction and magni- tude by p’a’ drawn from any convenient pole p’ to any convenient accelera- tion scale. The acceleration of B can be obtained by adding to the vector p’d’ the vector acceleration of B in its relative motion round A. If be the angular velocity of the bar in the base-plate field, and if ’ be the acceleration of angular velocity, the radial or centripetal component of velocity acceleration is w AB and the tangential component is »*AB. The whole acceleration of — relative velocity is therefore, AB:,/o'+”, and its direction is inclined to BA by the angle tan™! a This angle is the same for every pair of points in the same rigid bar ; and, since the magnitude of the acceleration of one point round any other is proportionate to the distance between them, therefore, if w’b’ be drawn inclined to BA at the angle tan“! # and of length AB,/o*+@”, and if a 2 the figure a’b’c'd’ be made similar to that of the bar ABCD, then p’'0’, pc’, pd, will be the accelerations of the points BCD in the base-plate field. Further a’c’, for instance, is the acceleration of C round A. In the graphic construction it is simplest to plot aB’=AB‘o’, and parallel to BA (not AB), and Bb’ = AB-o’ perpendicular to AB and in the direction given by the sign of o’. The radial component is usually obtainable from the already constructed velocity diagram, where the velocity of B round A is called ad, and the radial acceleration is therefore oe Fig. 3 gives the two most ready graphic con- structions for calculating oe In figs. (1) and (2) the velocity ab is plotted — along BA from B to 8 towards A in (1); and away from A in (2). From Bas centre with B@ as radius, a circular arc is struck intersecting in 8, any other radius from A. From £ is drawn Bf’ parallel to that other radius, and intersecting BB, in B’. Then Bf’ is the radial acceleration fae In (8) (ab) is plotted from B as B£ perpendicular to AB, and a circular are with centre in ANALYSIS OF THE KINEMATICS OF MECHANISMS. 511 BA is struck through A and 8. This arc cuts the diameter AB in f’ giving B£’ the desired radial acceleration. If the bar be plotted to the scale m’=1”, m being a fraction ; and if the velocity be plotted to the scale m’=1 inch/second ; then such constructions give the acceleration to the scale (") inch =1 inch/second.? It is evident that the figure a’b’c'd’ of the acceleration diagram is simply a reproduction of the figure ABCD of the bar altered in scale and rotated through an angle | 180°—tan™ “| in the direction of » where in tan“ Ws the sign of we w is to be taken positive or negative according as it is in the same or the opposite direction to that of w. In this altered diagram p’ is the point of the bar if the bar extends so far, or of its field if it does not extend so far, which suffers no acceleration or is moving uniformly in a straight line. This point does not in general coincide with the instantaneous axis of rotation. If the velocity diagram were rotated and altered in scale, and placed on top of the acceleration diagram so that ab’c'd’ coincided with abcd, then p’p would represent in direction and magnitude the acceleration of that line in the bar or in the field of the bar which is at any time the instantaneous axis.* If G be the centre of inertia of the bar and the similar points g and g’ be plotted in the velocity and acceleration diagrams, then the products of the bar-mass by pg and p’g’ are respectively the integral momentum and the integral acceleration of momentum of the whole bar. In what follows the capital P will denote the base-plate through whose field the velocities, &c., are reckoned. The pole of the velocity diagram will be called p. The pole of the accelera- tion diagram will be called p’. Points in the mechanism will be named by capital letters ABC, &c. The corresponding points in the velocity diagram will be named by the same letters in small type, abc, &c.; so that pe will denote the velocity of C over the base-plate and bc the velocity of C round B, and cb that of B round C. The corresponding points in the acceleration diagram will be named by accented small letters ; this being in accordance with the common mathematical convention, whereby x’ represents 2 a In finding, for instance, the point 0, it is sometimes necessary to find other points which are not afterwards required in the completed diagram. When such construction points require to be named, they will be called A,, B., &c., * The acceleration “image” of a bar moving without rotation reduces to a point. The velocity “image” of a bar moving without rotation reduces to a point. 512 PROFESSOR R. H. SMITH ON A NEW GRAPHIC if used to find b in the velocity diagram, and @; 83, &c., if used to find 0’ in the acceleration diagram. In the displacement diagrams described above, the accented capitals A’BC’ &c., are suitable. The simplest mechanism is that with four bars and with two joints, P,P, in the base-plate, and two joints AB coupling the other three bars together. An example is shown in fig. 4, the calculations being made for five different phases of the periodic motion. The velocity of the crank-pin A is supposed known at each phase. From any pole p, and to any convenient scale this velocity pa is plotted perpendicularly to P,A. From p a line is drawn perpendicularly to P,B. Evidently the — extremity b of bp, the velocity of B, must lie in this line. But also pb pa plus a velocity perpendicular to AB. Therefore from @ a line is drawn perpendicular to AB to meet the above line in 4. Thus pb is determined. In the example pa is taken of the same magnitude at all the five phases. To obtain the acceleration diagram we assume the acceleration of A. This 2 . e . . is constant in magnitude he on the supposition that pa is also constant in 1 magnitude and is wholly radial, since pa is taken as constant. From any pole p’ this acceleration oars pa is plotted parallel to AP, 1 (not to P,A). The calculation of the magnitude is performed by the graphic construction previously explained. By the same construction the magnitudes oF and _ of the radial components of the accelerations of B round P, and round A are found and plotted off from p’ (as p’B’) and from a’ (a’f’) parallel to BP, and to BA. From these two points 6’ thus obtained, lines are drawn perpendicular — to BP, and to BA. The point 0’ sought for must lie on both of these last lines, and is, therefore, at their intersection. The acceleration p’b’ of the joint B through the field of P is thus obtained for the five different phases of the © motion. The method of procedure is plain. Each joint of the mechanism is a point in two different bars, and therefore the calculation for that joint may be approached, as it were, from two different sides. In each of the two calcula- tions there is one element missing, and the last stage of the calculation cannot be completed directly ; for example, approaching the calculation of the accelera- tion of B through A, we can calculate the radial component (parallel to BA) of the acceleration that has to be added to that of A, but of the tangential com- ponent the direction only is known, but this gives a line in which the desired point — must lie.* Another conditioning line being similarly found by approaching the cal- culation in another way, the point is found at the intersection of these two lines. ANALYSIS OF THE KINEMATICS OF MECHANISMS. 513 In the ordinary steam-engine with guide bars, the radius bar BP, swinging in the base-plate-bearing at P, is replaced by the cross-head sliding in straight guides which form part of the base-plate. The effect is the same as if BP, were infinitely long. On account of the cross-head joint being guided in a straight line, passing through the crank journal centre, a symmetry is given to the motion which materially lightens the labour of drawing complete velocity and acceleration diagrams. Fig. 5 illustrates this. Here the four positions 1, 2, 3, and 4 of the crankpin A are taken equi- distant from the dead-points O and O’. Therefore the two cross-head positions B, and B, coincide, as doalso B, and B;. Therefore also the four velocities pa, po, pds, and pa, are equally inclined to the velocity line pb, and the four points Mh, Ge, M3, d, are equidistant from the line pb. Also at 1 and 2 the connecting rod has the same inclination to the centre line, which inclination is equal and opposite to that at 3 and 4. Thus the lines a,b, and a,b,, and a,b, and aszbs, are equally inclined to pb; and, therefore, the velocities pb, and pb, have equal magnitudes, as also have pb; and pb,. Therefore also the radial accelerations Mi, 85, 383, 048; have equal magnitudes, and are equally inclined to pv’; while also the tangential accelerations, 6,b;, &c., are equally inclined to the same line, and are of the same length, because ai, a3, a3, and a, are equidistant from pb. Therefore, finally, b{ coincides with b;, and 6; with b;. The four accelerations a’b’ have equal magnitudes, but p’b;=’b; differs in magnitude as well as direction from p’bi=p' bi. This symmetry is, of course, destroyed by want of uniformity in the rotation of the crank. The joint lines of the bars of a mechanism, the velocity lines, and the acceleration lines need be drawn in full for one position only. The results for the other positions are indicated by numbered points on the three set of curves, which are the loci of the corresponding points or extremities of lines. The first " set of curves are the paths of motion of the joints. The second series of curves are the hodographs of the velocities of these same joints. The third series are the /oci of the extremities of the lines representing the velocity accelerations. Six-bar motion is nearly equally easy to deal with by this method. The first example given in fig. 6 is quite simple, because the velocity pa of the joint A is assumed as known, the bar P,A being one of the quadrilateral P,ABP,. The determination of the velocity pb is, therefore, the same as that given already. Thus, pb and ab are drawn perpendicular to P,B and AB, and their intersection gives b. Then the triangle abc is made similar to ABC. pd is then drawn perpendicular to P;D, and cd to CD, the intersection giving pd the velocity of D. To find the velocity of E, there are drawn pe and de per- pendicular to P;E and DE. The construction of the acceleration diagram here offers no special difficulty. 514 PROFESSOR R. H. SMITH ON A NEW GRAPHIC The solution of the next example in fig. 7 is not quite so direct, because here the velocity assumed as known, namely, pa that of A, is that of a joint in the pentagon P,ABCP,. First, pa is drawn of the known magnitude and perpendicular to P,A ; and then a8 of indefinite length perpendicular to AB. Then, pd and pe are drawn of indefinite length perpendicular to P;D and P,C, that is, in the directions of the velocities of D and C. The points b and d now sought for are known to lie on the lines a8 and 6, and also it is known that the line joining 6 and d is perpendicular to BD. Any point 8 on @@ is chosen, and from it 8d drawn perpendicular to BD; and then the triangle @dy is con- structed similar to BDC, corresponding sides being perpendicular. The triangle bde that is sought for must evidently be similarly placed to Bdy between the the lines pd and af. Therefore, y is joined with the intersection of pd and af, and this line is produced to intersect pc, drawn from p perpendicular to P,C. This gives the true position of c, and the triangle dcb is then completed by — drawing cd and cb perpendicular to CD and CB to meet pd and af. The point e is obtained by drawing pe and de perpendicular to P,E and DE. The acceleration diagram has, in this case, to be constructed according to a similar indirect method, The acceleration of A being supposed known can be — plotted at once. Then the radial components of the accelerations of B round A, of C round P,, and of D round P;, are calculated and plotted off in their * 1 7 4 4 7 7 1 b ? (pe)? (p Ss roper directions from a’ and P; their magnitudes being ay) —— So 8 BA’ P Ca PD From the three points so obtained, three lines, which we may call £, y, and 8, are drawn of indefinite length perpendicular to BA, P,C, and P,;D. The tangential components of the above three accelerations lie along these lines, which, therefore, contain the three points b’, c’, and d’ sought for. On the line 6, any two points, 8, and 6,, are chosen, and from each the centripetal acceleration Lee of C round D is plotted parallel to CD; and from the two points thus obtained are drawn two lines perpendicular to CD, to meet the line y in two points, say y, andy On the two bases, Sy, and 8:7, are con- structed two triangles similar to DCB, whose two vertices may be called 6, and B,. Neither of these points, 8,, 6, will be found to lie on the line 8, and their distances from this line may be taken as measures of the errors involved in the two guesses, 6,, 6, at the position of d. The error thus found in the resulting position of £, is a linear function of the error in the guessed position of 6; and, therefore, the interpolation between these two errors in order to reduce them j to zero is to be performed by simple proportion. This linear interpolation is at — once effected graphically by drawing a line through A, and £,, and producing it until it meets the line 8. The intersection thus found will be the true position of b.. Or, otherwise, the two error-distances of 8, and £, from the line 8 may be plotted off from the points 8, and 8, perpendicularly to the line 6 (or both in ANALYSIS OF THE KINEMATICS OF MECHANISMS. 515 any one direction inclined to 8), and through the two points thus obtained a straight line is drawn to cut the line 6 in the true position of d’, From a’ or b’ thus determined, the other points are constructed as usual. This indirect method of ‘two trials and two errors,” and linear interpolation between them, is adopted in drawing the velocity and acceleration diagrams for the ordinary steam-engine reversing link motion. These diagrams could not be obtained except by this method. It may be mentioned that this is frequently the only practicable method by which stress-diagrams of immovable linkworks can be completed. In the common steam-engine mechanism we have already had a case of one bar sliding on another, namely, the cross-head sliding in the guide-bars of the bed-plate. A circular slot in which sliding takes place may, of course, be looked upon as simply an incomplete pin joint of large size, the radius of the pin becoming infinite when the slot is straight. But when the radius of the slot is large, this manner of regarding the joint is not practically useful. A more direct application of the present graphic method to sliding joints is effected thus: If B be a bar sliding over the bar. A, the difference of the velocities of any two touching points in B and A is a velocity parallel to the slide-surface, or “ guide-surface.” Thus, the velocity of the bar A being known, the velocity of any point in B can be obtained by adding to the velocity of any touching point in A a velocity parallel to the guide-surface, and further adding a velocity perpendicular to the line joining this touching point with the point in B whose velocity is to be found. This last added component is that due to the rotation of B in the field of the base-plate. If the touching surface of B has the same shape as that of A, so that B always “fits” on to all parts of A into contact with which it comes, and if during the sliding these fitting surfaces are forced always to le close together, then the angular velocity of B is always the same as that of A. In this case, if the velocity of A be completely known, the linear velocity of any point in B can be calculated by adding to the velocity, which the point would have if B were rigidly attached to A, a velocity parallel to the guide-surface. In the illustration (fig. 8), the velocity of point A round P, is supposed to be known, and it is plotted as pa. Then p@ and af are drawn perpendicular to P,Band AB. This gives p@ the velocity that point B would have if the cross- head were rigidly attached to the guide-bars, and if 8b be drawn parallel to the slot, the point 6 must lie in this last line. But B is guided by the radius rod P,B. Therefore pbis drawn perpendicular to P,B to meet 8b in b; then pb is the velocity of B in the P fieid, and 8b is the velocity of sliding in the slot. If a block C (see fig. 9) slide in two slotted bars A and B, the first of which has a translatory velocity pa, and the second a translatory velocity pb, VOL. XXXII. PART III. 4Q 516 PROFESSOR’ R. H. SMITH ON A NEW GRAPHIC evidently the method of finding the velocity pe of the block is to draw from a and b two lines parallel to the two slots in A and B. If these lines meet in «, then pe is the velocity required. : If the slotted bars have rotational instead of purely translatory velocities, then precisely the same construction is to be followed, making pa and pb the linear velocities of the touching points of the guide-surfaces in A and B. Now, however, it is evident that one and the same block cannot constantly fit close to both slotted guide-surfaces. But if two fitting blocks, one fitting the one slot and the other the other, be pinned together, then the above construction may be applied to find the velocity of the centre of the joing pin, and from the velocity of this centre it is easy to deduce by methods already explained — the velocities of all other points in the two sliding blocks. These last graphic methods have been applied to the calculation of velocity and acceleration diagrams for Player’s pneumatic forging hammer, in which a combination of oscillating sleeves, through which slide levers, makes the com- plexity of the mechanism such as to be incapable of algebraic treatment in a manner that is at once accurate and yet not impracticably cumbersome. The following application (see fig. 10) of the construction for sliding motion to toothed wheel gear well illustrates the complete generality of the method, and owes its interest not chiefly to its technical character. The sketch represents four wheels, P,A, P;B,, P;B, and P.C, pinned to the base-plate at P,, Py, and Pe. The point A of the first touches the point B, in the second, the two surfaces having here a common tangent to which the line (AB,)T,, is drawn normal. The third wheel being mounted on the same shaft as the second, these two are to be looked upon as forming, along with the shaft, one bar of the mechanism. The third and fourth wheels touch at the common point (B,C), and the line (B,C)Tx¢ is drawn normal to the common touching surface. The points T,, and Ty, are in the centre lines P,Ps and Treo The velocity of the wheel A, and therefore of its touching point A, is supposed known, and this velocity is marked off as pa from any pole p, the the line pa being drawn perpendicular to P,A. Then ph, and ab, intersecting in 6, are drawn perpendicular to P,B, and to B,T,,. This gives pd, the velocity of B, and ad, the velocity of sliding of one tooth over the other. Then ph, and 6,b, intersecting in b, are drawn perpendicular to P,B, and to B,B,; pb, is the velocity of the point B,. Finally, pe and 0,c intersecting in ¢ are drawn perpendicular to P.C and to the normal CTyc. This gives pe the velocity of C, and b,c the sliding velocity of this second pair of teeth over each other. The process may be carried on indefinitely through a whole train of wheel work, however complicated, As a method of finding the velocities throughout such a train, however, it is not a practically useful one, because the ANALYSIS OF THE KINEMATICS OF MECHANISMS. 517 directions of the normals to the touching surfaces cannot be very accurately obtained on the drawing unless the “ pitch points” T,;, Tc, &c., are known, and if these are known to start with, the various velocities can most simply be determined from them directly without reference to the touching points. The point T,, may be looked on as indicating two points, one in the first wheel, which may be called T,, and the other in the second, which will be called T;. To obtain the velocity of T, the triangle pat, is constructed similar to the triangle P,AT,. In this triangle az, coincides with the line ab,, and pt, is perpendicular to P,P3;. Making a similar construction for the velocity of the point T;, we find that the point 7, coincides with the point @. Thus the points T, and T, in the two wheels have the same velocity pt», and the point T,, is therefore called the “pitch point.” The angular velocities of the two wheels are therefore inversely as the distances P,T, and P,Ts, this being a familiar theorem proved in the ordinary treatment of toothed gearing. Similarly, if pt,, be drawn perpendicular to the centre line P,P, to its inter- section with b,c, this pt,, is the velocity of the pitch point Ty, of the pair of wheels (BC). If the teeth be so shaped as to give constant angular velocity ratios between the wheels, the points Ty;, Tc, &c., in the diagram of the mechanism and the points t., ¢,,, &c., in the velocity diagram remain fixed throughout the periodic motion of the train. It may also be noticed that since bt, _ B,Ts : tab ANI 12 qt P Ab ee and —— = 1-8 th Ma pli & = Joe Big es 9 , — pyr Mere ae te, ~ Pals’ Bs ~ Pal,’ Ata 3 : so that ; = also measures the ratio of the angular velocity of wheel A to that it of wheel B. The condition that the angular velocity ratio should remain constant may thus also be expressed by the condition that the line ab in the velocity diagram, representing the velocity of sliding of tooth over tooth, should be divided in a constant ratio by the fixed-point ¢,. [This point ¢,, is only fixed if the angular velocities themselves, as well as their ratio remain constant, the magnitudes of these angular velocities being proportional to pt,.| Whether this proposition can be utilised in simplifying the practical drawing out of the teeth-profiles, so as to secure a constant velocity ratio, the author has not yet had time to investigate. Velocity and acceleration diagrams have been completely worked out for the Joy’s valve gears used by Mr F. W. Wess on his compound locomotive engines, the gear being differently arranged for the high and low pressure cylinders. These mechanisms are too complicated to be treated without very inaccurate approximation by any other graphic or algebraic process known to the author. Velocity Diagram Acceleration Diegram en Vol. XXXI. Plate 12 Mechanism Diafram Velocity Diagram Acceleration Diagram GRAPHIC ANALYSIS OF THE KINEMATICS = UN CARTALIOS, or MECHANISMS Tivariane berskine Ine ( 519 ) XXIX.—The Visual, Grating and Glass-lens, Solar Spectrum (in 1884). By C. Prazzi Smyrtu, F.R.S.E., and Astronomer-Royal for Scotland. (Plates LX X XIII.-CXLITIL.) CONTENTS. PAGES Part I. The Observations ; their objects, and the mode of pee nase them, F : 519-524 Meteorological Appendix to the Same, c . c : 524-526 Part II. Reduction of the Instrumental, to a Wave- Reber pcale) 5 x : 526-528 Part III. Graphical representation, in place of printed numbers alone, * . a, 3 529-531 Part IV. Indexing by Colour, ; : 531-532 Parr V. Variations of Temaperaniize and giier Crane sources of Mesa Distutbaries, 3 532-537 Parr VI. Appearancesand Disappearances of Terrestrial Water-Gas lines in the Solar Spectrum, 537-539 Part VII. Some of the results arrived at touching true Solar lines in the year 1884, Q 539-541 Parr VIII. Testimony of Successive Gaseous Groups as to the most practical of Natural Spectrum Seales, . : : 541-543 Part IX. The Map in 60 Plates and with an index Plate, LXXXIIL _OXLIIL Part ].—THE OBSERVATIONS ; THEIR OBJECTS, AND THE MODE OF COMPASSING THEM. Throughout the year 1884 the sun was seen over most countries under peculiar atmospheric circumstances; and these, instead of being confined to low altitudes, were never more conspicuous than during the summer of the year, and noon-tide of each day, and in the clear air on mountain heights of every country, whenever the sky was more or less free of actual clouds. On such occasions then, the usual phenomenon to be noticed by the eye, was, that nothing like blue sky could be witnessed near the sun. But in place of that, there was a broad glare of whitish light extending for several degrees around the luminary; and beyond that range, or over 20 degrees distant from him, there spread a wide reddish haze, passing into purple, and at greater distances into blue, but nowhere a very decided and deep blue sky. That the medium producing this appearance was terrestrial rather than Solar, was indicated by similar effects being seen about the full moon. But that its locality must have been far higher than the ordinary clouds was still more conspicuously proved by the said clouds always appearing in front of, or backed by, the peculiar reddish glare; and then showing their own cloud- tints, greenish-white on their illuminated edges, and blue-gray on their shaded sides, in most pronounced chromatic relief. The upper air, to produce any such effect, must at the very least have been filled with far more than the average amount of those minute dust particles, which are always floating about there in greater or less quantity far above the level of all ordinary massive clouds of watery vapour. And though some of the extra amount of this higher dust may have been derived from several other sources, yet the general opinion of most men of science in VOL. XXXII. PART III. 4k 520 . CG. PIAZZI SMYTH ON. THE most nations appears now to be, that by far the greater part of it must have been supplied by the widely extended volcanic eruptions of 1883, in Australia, in Alaska, but chiefly at Krakatao in the Indian seas. In each of those three cases, clouds of matter went up, and mud, stones, and coarse dust came down, both speedily and within such immediate proximity of each volcanic vent as to testify unmistakably to their parentage, But in the Krakatao case, if not in the others also, a far finer kind of dust went up very much higher; so high indeed as to be left behind by the earth — in its axial rotation; and thus to be seen successively by every terrestrial meridian in the course of 24 to 35 hours; and was recognised to be spread- ing out sideways widely and rapidly at the height attained. One of these resultant cases, I believe that I saw from the Calton Hill in December 1883 when, after sunset, a brilliantly illuminated display of broad, thin, and nearly uniform cirrus cloud, stretching at one moment apparently through the whole heavens from south, through the zenith to north,—went — down with remarkable speed, and in one piece, towards the west, as though it — had been a curved shutter of the outer sky, pivoting in the south and north points of the horizon, turning rapidly upon them as an axis, and leaving ordinary clouds hanging about in the lower air, amenable only to petty winds — blowing this way and that, near the low-down surface of the solid earth. That any great portion of a volcanic eruption is ever got rid of by being reduced to impalpable powder, projected upwards far above the clouds, and eventually sprinkled in homceopathic dust-rain over all the surface of the globe, seas and continents alike, and found in rain-gauges—was evidently beyond the ideas of geologists in 1850. For then after a valuable paper read before the Royal Society, Edinburgh, by one of its most respected Fellows, on the volcanic features of the Alban Hills near Rome,—wherein the learned author enlarged on the terrific intensity of the ancient explosions which had blown out the once stupendous rock-contents of their now deep, hollow craters, a gray-headed geologist present inquired with painful care, what had become of that mass of © ejected rock? Was it to be found close outside the craters, or at what distance therefrom, and in what sizes and shapes of blocks? Whereupon the really able author of the paper became confused, admitted he had made a mistake, and ought to have said that the supposed blown-out rock-masses had really fallen in; and that was the reason why they were not to be found lying about in big, recognisable portions outside. But with the ultimate Krakatao volcanic ejection which went up, it is said, | as a mighty dust cloud, formed of half the mountain’s bulk, to a height of forty _ miles, and under such compelling force as to carry its electrical charge, as due — to the interior of the earth with it, and thereby became endued in its every atom with a power of floating perhaps for years above the terrestrial planet,—did VISUAL, GRATING AND GLASS-LENS, SOLAR SPECTRUM. 521 any gaseous matter, and if so, of what kind and in what quantity—accompany the ultra triturated dust of material shot up from earth’s furnaces far beneath the sea?. In the red prominence explosions of the sun, which are far more like the gigantic Krakatao upshoot, than are any of the cannon-ball experiments at Wool- wich, gaseous matter is conspicuous enough. But in the case of any earthly voleanoe, such a conjectured material has never yet been proved for its superior manifestations. For though many persons may—like the elder Pliny when he ventured too near Mount Vesuvius at its classic eruption in A.D. 79,—may, I repeat, have perished from noxious gases exuding out of the lower flanks of the mountain,—those cases do not seem to have excited much curiosity as to whether such volcanic gases are chemically different from those already known to exist in the atmosphere, and are ever ejected in such quantity and with such force as to form a notable part of the explosion in the higher regions of the air. The spectroscope however is, with the assistance of transmitted light, an infallible test as to whether any particular medium in the upper air, dense enough to colour the rays of the sun when shining through it,—is formed of solid insoluble particles only, or is composed of a true but strange gas, unnatural to our atmosphere. For in the former case the solar spectrum will be merely, but continuously dulled from one end to the other,—while in the latter some remarkable localised spaces or transverse lines of absorption, in addition to all those already known as Fraunhofer lines, whether of solar or terrestrial origination, may be expected to be met with. Hence a solar spectroscoping in 1884, besides its own proper uses for cosmical knowledge, might be expected to have some further special interest connected with our own earth, 7.¢., if conducted with sufficient dispersive and magnifying power; and unprecedented power of the former kind has been lately given to many scientists by the magnificent diffraction gratings prepared by Professor Rowianp of Johns Hopkins University, Baltimore, on his novel and admirable ruling engine. I was among the happy number to receive one of those gratings, with a surface ruled at the rate of 14,438 lines to the inch, over an area of 3°5 x 5:0 inches ; but had intended to confine its use to vacuum tube spectra,—until I learned that the mysterious attractions of the invisible, over the visible, especially when brought out by the hasty, labour-saving method of photography, —were leading most of the other donated observers to neglect the visual portion of the solar spectrum, in spite of its beauty, its central character, and the wonderful organs by which the Creator has enabled man to enjoy it. Without giving up therefore my own eventual hopes and intentions on artificial spectra, or interfering in the slightest degree with the recondite proceedings of the greater physicists on the invisible extensions at either end of the solar visible spectrum,—I proceeded through the autumn, winter, and 522 C. PIAZZI SMYTH ON THE spring of 1883-4, with the valuable aid of Messrs T. Cooxe & Sons, of York, to adapt my example of a Rowland’s grating for use in a large wood and metal apparatus. This was of somewhat unusual form, carried object glasses 4 inches in diameter, employed a magnifying power of 67 times linear on the inspecting telescope, and was specially adapted for securing differentially, but with remarkable rapidity, a highly magnified record of the whole visual solar spectrum, whatever that might prove to be at the epoch. Something however still more than one single record of such a spectrum appeared due to the science of our time ; for such science has established most profoundly, that there is no scientific subject of numerical mensuration whatever, wherein any man, or any number of men, can do more, when they aim at exactitude, than arrive within certain limits of probable error as to what the truth may be. As these limits too may be very various for the different lines of the spectrum, of which there are several thousands,—I determined, if I could observe one spectrum well, to follow it up by a second, and even third time of going through the whole of it; with the view of eventually bringing the three records together in such a manner as to facilitate their comparison, and rather provoke, than silence, criticism on every line. But could three such extensive spectra be successively, as well as com- pletely, observed micrometrically by the eye and hand of one observer in the course of two months only of an ordinary North-British summer season ? Not unhappily in Edinburgh ; where, over and above the general cloudiness of the summers, the fearful increase of coal smoke in the air, during these latter years of unexampled growth of its happy population in numbers, wealth, and abundant burning of coal without consuming the smoke thereof,—has vitiated the city’s atmosphere to a degree quite prohibitive at last of any of the nicer observations of Astronomical Physics. Could, however, the desired end be obtained by visiting the South of England, profiting by itsusually sunnier summers, the absence of coal fields, and avoiding the larger cities ? That was what I proposed to try; and after some deliberation pitched on Winchester. Once indeed the ancient metropolis of England under her Saxon Kings; but now is it so shrunk within its former magnificent bounds, and so lowly withal, that with the exception of its Cathedral, St Mary’s College, and a new town-hall by GitBert Scort—the rest of its generally diminutive, flint-walled houses might almost all be packed away, even hid, within our George Street. Eminently neat and decorous however is modern Winchester ; with no manu- factories to speak of, save a few small ones for brewing beer, or preparing Hampshire bacon and flower honey. A useful country town evidently for farmer's supplies, and yet grandly historic. Surrounded by healthy, open, undulating chalk downs, with umbrageous trees and charming gardens in their hollows; VISUAL, GRATING AND GLASS-LENS, SOLAR SPECTRUM. 523 sky-larks and wood-peckers the principal birds. Noble landscapes of English kind on every side, teeming with well preserved objects of even higher than Saxon antiquity. Roman roads shooting straight over hill and dale. and tumuli of aboriginal Britons far older still, While the primeval soil itself, wherever opened, shows virgin white ; and nothing gets smirched in that fair champaign with either smut, or soot, or any appreciable coal smoke. In the largest upper chamber therefore, of a new country house, by name “Kurn Hattin” (for every house there, even in the town streets seems to have a name) and about two miles North of Winchester, which my Wife and I engaged for the time, the rather unwieldy spectroscope was set up, with its heliostat looking out of a window towards the South-east ; and where, when clouds permitted, the sun could be conveniently commanded at the summer solstice from 10 a.m. to 1 P.M, at an average altitude say of 45°. Suitable therefore for both solar originated lines, and those produced by the higher telluric atmosphere whether natural or adventitious. Seldom however, through the two months of observation, June and July, did the far too frequent clouds permit of anything being seen except themselves ; and little would have been accomplished unless by utilising every moment of occasional or even partial break ; and sometimes even by observing through the thinner clouds, though that was very untoward for securing the fainter lines. At the same time the heliostat, employed for bringing the solar rays whenever they were visible, to the grating, being only the same rude, hand-worked affair I had taken before to Lisbon and Madeira, required the services of an assistant in rapid observation. Well too had I been assisted therein at both those foreign stations, by my Wife’s patient enthusiasm, and enduring skill. But through almost the whole of our stay at Kurn Hattin she was unfortunately laid up with severe, even dangerous illness ; and the observing conditions would have gone too heavily against me, but for a circumstance as unexpected, as it proved appropriate, grateful, and effective. This was,—that the country-house next to us, was occupied by Colonel Kyicut, an officer recently retired after a long and honourable period of active service in tropical climates. But now he was prosecuting to his heart’s content Meteorology of the most careful and conscientious kind,—while he rejoiced also in the possession of an Astronomical Observatory built by himself, furnished with both Transit Instrument and magnificent Equatorial by Cooke, and was both F.R.A.S. and F.R.MLS. This gentleman then most obligingly gave me the utmost aid in working the heliostat. For whenever there was the slightest chance of seeing the sun, he would come over to Kurn Hattin, sit out the most perverse clouds until sun- shine broke at length ; and then he would keep any solar image visible at all,— and more particularly the same colour region in the preliminary spectrum 524 C. PIAZZI SMYTH ON THE which he knew I was working at in the subsequent spectrum,—steadily on the.. collimator’s slit, for as long as I could make effective use of it. This important assistance so greatly increased my powers for work, as to enable me after all just to accomplish the three spectra, pack up the instrument, and return to Edinburgh within a day of the date required. METEOROLOGICAL APPENDIX TO PART I. The originals of the following Meteorological observations, so important as a guide to water-gas lines, and their varying manifestations from day to day, though telluric, in the Solar Spectrum, have been kindly handed to me by Col. KNIGHT; and were taken by himself at his Observatory, within a few yards of Kurn Hattin, Harestock, Winchester,—in Latitude =51° 4’ 434 N. Longitude = 0" 5™ 21°53 W. Height of cistern of barometer above mean sea-level==316 feet 7 inches. The daily time of observation being 9" a.M., and the means referring always to that hour except in the case of self-registering instruments; whence, in June, Mean Barometric Pressure, reduced to sea-level and Temperature 68°, = 307145 inches 1884, Mean Temperature of Air in shade, , ; , A : . =08 anes Mean of Self-registering Maximum Thermometer, . ; ; - - =Ope ORE: Mean of Self-registering Minimum Thermometer, . : : . =—43™ia Mean Semi-daily Range of Temperature in shade, . : ; < = Fe ome Mean Depression of Wet-bulb temperature in shade, .. : . SS" Water-gas in a cubic foot of Air, computed, . : ; : . = 40 grains Mean Relative Humidity (Saturation =100), computed, . ; . S7o0 Water-gas still required to saturate a cubic foot of Air, computed, . =1°5 grains Total Sunshine, by Recorder, in A.M. hours, . : 2 . =80 hours 45 minutes Total Sunshine, by Recorder, in P.M. hours, . : . . =92 hours 14 minutes Wind, Measured mean miles per hour, . ; , . =6°74 Wind, Direction E. to W. as 3 to 6; and S. to N. as a to 16, . =N. by W. nearly and in July, Mean Barometric Pressure, reduced to sea-leveland Temperature 68° F., = 30-064 inches 1884, Mean Temperature of Air in shade, . ; ; é ; . “= '62°25RF Mean of Self-registering Maximum Thermometer, t . = 68°-60R, Mean of Self-registering Minimum Thermometer, 5 ‘ . =62°>E: Mean Semi-daily range of Temperature in shade, , ‘ . = 8:0, Mean Depression of Wet-bulb Temperature in shade, . : . = £3 Water-gas in a cubic foot of Air, computed, 5 , . = 46 grains Mean Relative Humidity (Saturation=100), ae ay : . =760 Water-gas still required to saturate a cubic foot of Air, computed, = 1°6 grains Total Sunshine, by Recorder, in A.M. hours, ; 4 . =60 hours 38 minutes Total Sunshine, by Recorder, in P.M. hours, ( - . =84 hours 37 minutes — Wind, Mean measured miles per hour, : : . =8:24 Wind, Direction, E. to W. as 2 to10; andS. to N. as 14 to 3,=S.58.W. nearly.* * From observations taken by my friend, Mr Ranp Caproy, F.R.A.S., at Guildoun, Guildford, VISUAL, GRATING AND GLASS-LENS, SOLAR SPECTRUM. 525 THE DAILY OBSERVATIONS ARE AS FOLLOWS :— Sofia 4 geile eR eee esl = o | & Festi eased. | a Date. oe ro Fe | Sz @o |s8 = Re Sun-shine Recorder. Wind. ss. 2 © ‘og e< 2) Se) Ee Ree Er se Wee 8 nbs |s B28 Se | 98 | 22. | Sa ees | as 25s £o iy || Gh) Rett || celal) Sie ES aa | £6 | Se | ee | 822) 37 niles ee 1884. Hour. ge & Sa | 3 Za | s3 | g AM. P.M. Hoe, Direction. an & A 2 = A.M. Inches. Grains, Grains. H. MIN. H. MIN June 1. © 9 30103 54-2 6°7 2°8 60° 1-9 (On 2 45 584 |S.S ne 2. se 29-736 573 5°8 3°4 65° 1°8 See 2 34 3 38 8°87 S ng 3. 6 29625 55°8 5°0 3°5 70° ic) 0°03 0 00 0 00 9°63 N.E a 4, % 29-870 50°2 iY oD 87° 0°6 20 0 00 0 38 7°58 N. sty Den aL 29°931 53°4 2°4 3°8 83° 0°8 06 0 00 Lt 24. 6:72. N.W. ae Gs >2 29°872 55°0 46 3°5 72° 14 95 1 14 2 29 7°59 | W.N.W. ay ie Dp 29°632 46°7 13 3°4 92° 0°83 03 0 00 2! 10°51 | N.N.E. ag 8. © 29:908 52°4 3°2 3°5 79° 0:9 20 0 44 0 05 11:05 | N.N. W. An os te 29°9938 50°3 3°77 3'0 15" 11 0 08 0 32 7°85 | N.N.W. 36 10. 6 30°199 54-2 4°8 353 69° 14 if bl 1 09 7°69 | N.N.W. ey Mes 30°296 54°3 0 4°4 93° 0°3 0 00 0 00 4:26 Ss. W. pin 12. 4 30°413 62°0 orf 4°6 79° 14 4 57 6 49 6°64 N. eels. 9S 30°399 66°6 6°7 4°8 65° 2°5 6 04 4 59 2°58 S.W oF 14. h 30°347 58°9 3°8 4°3 76° 1°3 2 46 6 42 8°22 N. x6 15. © 30°414 55°3 4-7 3°5 72 14 2 26 38 10°09 N. 15 16. ¢ 30°321 52°4 27 3°5 81° 0'9 WPA 2 59 7°84 |N.N.W. ae WG Ws 30°279 54°6 3°3 3°9 80° 1:0 00 0 20 7°96 N.W. an ih) 30°293 59°3 4°8 4°0 fats 16 1 52 0 09 4.93 N.W. AB OL = 2) 30°341 60°1 56 4:0 68° 1°9 3 09 4 00 3°66 | N.N.W an 20. @ 30°299 62°6 4-9 4°6 2 1°8 sit 5 34 A bil 3°80 | N.N.E An 21. h 30°306 60°0 4:2 4°4 76° 14 02 3 59 WBS} 5°06 N.E 59 22. © 30°262 63-4 Ue 4:0 63° 2°4 ‘Ol 5 25 1 05 5:07 N. W. AS 23. ¢ 30°171 60°7 5-6 4:2 70° Uh) e 5 108 6 08 7°59 N.E “9 24. 6 30°105 62°2 8:2 3°6 58° 2°6 4 15 0 18 4°69 | N.N.W Ap 25. 9% 30124 61°1 2:2 52 88° 0°8 1 952 6 43 7°89 N.W. » 26. 1 30:283 || 65:8 | 9:8 | 8:7 | 52° | 3:3 6 56 6 39 4-76 | S.W. > 2. 9 30°236 68°4 WB) 5'0 63° 225) 6 12 6 41 4°64 S.S.E. » 28 kh SOA || BEI O87 |) Ze) |) ase 7B || 1 Bi) 6 38 | 4:59 | S.E. An 29. © 30°105 56°9 0°8 4:9 94° 03 ‘ 1 24 6 13 7°29 E. os 30. ¢ 30°209 61°8 4°8 4-4 (PX 1°8 4 23 4 38 1°22, W. Surrey,—projected in graphical curves on compendious table-forms, and then photographed by himself,— it would appear that these two months, June and July of 1884, were peculiarly unfortunate for sunshine. For not only was the preceding month of May bright with frequent sun, but the following month of August was the brightest and sunniest month of that, or any name which had occurred in the South of England for years. And yet it would have proved dangerous to trust to that precedent for another campaign, as in the very next year (1885), it was the month of July that proved to be the most admirably sunny ; and to a degree far beyond both May and June on one side of it, and August and September on the other. —Subsequent Note. C.P.S. 526 C. PIAZZI SMYTH ON THE AND FOR JULY— on : ; = SE B/E Se Bibel eens Date. oe mee | eget mer (lesa ates Sun-shine Recorder. Wind. Bee | 82 | 28 | £2 | os |gas| 12 522 ea aH Be £5 | hee) ad 23° 5a Zo ma) SE | ag € ES a= za gs g3 225 a= Miles per 1884. Hour, E 3 5 z2 iS 24 |S22| 2 AM. P.M, suk. | Direction. fo) A.M. Inches. Grains. Grains, H. MIN. H. MIN July 1. ¢ 9 30°310 62°1 4:0 4°7 HOP 15 1 44 6 21 6°81 | S.W. Pr 2.3 ; 30°280 64:7 6°4 4°5 66° 2.3 4 58 6 48 4°72 | S.E. 9 3. 1 80°115 70°7 7:0 5:4 Gor 2°9 6 45 4 21 2°33 | S.S.E 55 ce 29°998 70°3 7:0 5-2 65° 2°8 a 8 40 6 08 2°96 NS) s be Th 30°021 65°9 6°0 4°8 68° 2°2 07 0 00 2 04 5°96 iS) re 6. © 30°054 61°6 3°4 4°9 ie 1°3 03 3 06 2 08 511] SW 5 Une 30080 64°2 55 4°6 67° 2°0 01 3) 14 6 47 10°88 s. < 8. 6 30°005 63°9 4°5 5:0 74° 1°6 oe 3 02 5 04 6°62 | N.E. 33 9. 8 29935 65°6 37 56 79° 1°4 02 0 18 3 32 5°94 S oy LOL Ml 29°737 62°9 3°4 5:0 79° 1°4 13 0 36 0 Ol 4°72 | S.S.W. Be valle GO 29°856 62°'4 67 3°9 62° 2°3 87 3 450 0 28 10:36 | S.W. a 2. 29°956 60°4 1°4 5°3 91° | 05 19 0 45 iy ae 10°06 | S.S.W. a les FO 29962 721 8:2 5:3 61° 32 ‘01 4 58 5a 8:09 8.E. yp ea? WG 30063 61°3 2°5 5°0 84° 1:0 =al7/ 1 27 By aly/ 13°54 | S.W. a LD. as 30°034 60°5 0°6 58 96° 0:2 24 0 00 0 41 14°35 | S.W. ae) 29°797 59°4 sy 50 90° 0°6 0 02 6 34 14°40 | S.W. Sete altima! 29°858 62'2 3°8 4-7 we 1°5 01 27, 4 47 14°33 | S.W. 5p aq 8: RO 30°155 60°5 67 3°8 64° 2°2 3) hl 0 00 11°61 W. 55 te lO a 80'245 58°9 7:0 3°5 61° 21 4 02 5 36 7°94 | "N.W. 2058S 30°214 58°7 3°3 4°5 80° Wal 1 52 iL 57} 4°49 S.E. ay add. RG 30°055 60°3 |% 3°3 4°6 80° 12 0 00 2 32 3°43 | S.W. A EP eS 30°135 62°9 4:0 4:9 Tift 15 04 0 45 Oo 14 10°73 | W.S. W. Hy Bs 19) 29°996 59°6 0:9 54 94° 0°4 05 0 12 0 02 12°14 | S.W. a3 ek 29°862 LOA I ayes} 3°8 68° 1°8 ‘13 2 35 2 O1 10°12 W. rae 7a Ak: 80°042 58°3 4-9 3°8 (le 1°6 08 Bf 3 59 9°38 NE 5p) eos. ip 30°254 53°4 3°8 34 ow ila 15 0 15 0 12 5:87 | W. oo he 1S 29°925 58°4 32 4°5 81° 11 1 58 2129 13°82 | W.S.W. Pn eae aC 30°245 59°0 7°8 3°2 57° 2°4 07 Lt 50 0 O1 7:97 N. aay eee: ae 30°164 64°6 37 5°4 80°} | 14 £ 0 Ws 0 03 7°22 |W.N.W. eg CLUES 8, 30°302 65°9 4:2 bya) 78° 15 0 10 0 47 3°71) S.W. i wo 30°318 57°6 01 one 99° 00 1h yy 2 38 3°81 | S.S.E. Part IJ.—REDUCTION oF THE INSTRUMENTAL, TO A WAVE-NuMBER, SCALE. The shape in which the Winchester Spectrum work was brought to Edin- burgh on July 30th, consisted in three packets of seven lengths of paper each ; every such length containing 19 to 20 parallel, but consecutive revolution strips, and each strip, 14 inches long, holding on an average the recording marks for about 50 Fraunhofer lines. So that each of the three spectra might be formed into a continued length of nearly 160 feet of paper, holding something between — 6 and 7,000 symbolic notings in its course, to indicate various characteristics besides the very important one of angular place, by micrometric screw measure, of as many solar, spectral, “fixed” lines. VISUAL, GRATING AND GLASS-LENS, SOLAR SPECTRUM. 527 The first step in reduction consisted in transferring with ruling pen and square all these fiducial markings at their several distances apart, to large engraved sheets, furnished with scales of nearly equal length to that of the Micrometric apparatus, but with much more space above and below whereon to develop the condensed symbology of the original pencillings, and introduce dates and notes for every day’s work. Each of the three spectra was thus treated in perfect independence of the others, and the third one had further still been observed in a very different manner to the first and second. For while they had the benefit of a collimator 70 inches long, the collimator used for the third, though with the same diameter of objective, was only 35 inches long ; while the cone of rays from the preliminary condensing lens of the heliostat was now still further condensed and shortened by a supplementary lens. Greater brightness of spectrum was hoped for by this concentration of Sun- light on the slit, but was not obtained ; and in place of it only a third spectrum very like the first and second ;—no one of them being perfect ; and the mean of the three, probably better than any one taken by itself alone. The amounts of such residual failings in each set of measures, though very small in themselves and hardly to be perceived in most spectrum work, was nevertheless, on the grand scale here attempted, quite sufficient to prevent the records, though derived from a Diffraction Grating, bemg always read off implicitly as a continuous scale of wave-lengths. 1 determined therefore to look upon them as varying differential measures, to be trusted only for short micro- metric runs ; while an absolute scale was prepared for them all, by referring the places of their chief lines to Ancsrrom’s celebrated Normal Solar Spectrum Map,—assisted where necessary by the numbers recorded in the much later works of MM. VoGEL, Cornu, Fievrez, THOLLON, and Professor Younc, U.S. Am. Their scales however being for Wave-lengths in terms of the French Metre,—I had to reduce their figures to Wave-number per British Inch, for the reasons stated in my paper lately printed by the Royal Society, Edinburgh, entitled “Micrometrical measures of Gaseous Spectra.” While finally I entered tlie leading divisions of such a scale, to the number of 600 for each spectrum, upon the sheets of pen and ink work,—after having obtained the rates of variation by the usual method of projecting the places of known lines on paper ruled transversely with the Micrometer scale, and drawing curves, through the points of intersection. The insertion of nine marks of nearly equal subdivision between every pair of the original 600 then followed, and gave each spectrum by itself a Wave-number scale with as many as 6000 fiducial steps marked and numbered; but on a continually contracting, or conical, scale in passing from Red to Violet: as well as totally different when, for some parts of the spectrum,—as the very earliest of the Red,—the first order of the Grating was substituted for the second order, or that usually observed upon. VOL. XXXII. PART III. 4S 528 C. PIAZZI SMYTH ON THE These 6000 fiducial steps had, of course, next to be transferred to sheets representing a Wave Number Scale of equal parts; and in order that the ultimate comparison of different authorities might be as instant as possible, these latter sheets must be of a collective character and contain all the authorities, at each point, one under the other. To this end, 60 plate forms of a long or double quarto size were prepared, each carrying 500 units of Wave-number scale, as adapted to a spectrum now of only 80 feet in length, and in strips one under the other five times repeated. In the three lower strips the three Winchester spectra were entered by measure ; and in the two upper, the standard tests and critical references. The topmost of these two reference strips, excepting for the three first sheets of the series, wherein Kircnorr’s celebrated spectrum was followed, could not but be devoted to ANcstrom’s Normal solar Spectrum ; not only on account of the accuracy of his absolute places, and his long priority—but for his, and his friend M. THALEN’s invaluable chemical equivalents of solar lines; and as they were now stretched out on these new sheets to about ten times the length they occupied in the original Upsala Atlas,—I was much pleased to find that a certain amount of microscopic confusion which has been complained of by some persons there, was completely corrected. The second however of the reference strips was confined both to solar lines and to the most advanced maps of them by any of the later observers, as Professor VoceL, M. Firvez, M. Cornu, M. THoiion, Professor Youne of Princeton, and Professor Row .anp, Baltimore, U.S.,—duly naming each of those great authorities whenever cited. But it is now time that I should render due thanks, and give proper praise to Mr Tuomas Hearn, First Assist. Astron. R. Obs. Edin., for the very great help he has afforded me in this section of the work. For not only has he, in the long conical sheets of the three Winchester spectra, inserted the nine sub- dividing lines and their numbers between each pair of my 600 preliminary points thrice repeated; but he has had the whole responsibility of copying, introducing, and greatly enlarging at the same time ANcstTRom’s celebrated Normal Solar Spectrum with all its chemical references in clearer guise, into the topmost horizontal strip of each of the final and collective plates ;—besides doing the same for all the consecutive selections of various spectra introduced into the second reference strip,—where too the various depths of lithographic tints employed by some of the authorities, could not have been reproduced certainly and satisfactorily in printable form, except by such admirable and clear-lined penmanship as Mr HEAtu’s. VISUAL, GRATING AND GLASS-LENS, SOLAR SPECTRUM. 529 Part IJI.—GRAPHICAL REPRESENTATION IN PLACE OF PRINTED NUMBERS ALONE. The final step, that of transferring into the three lower strips of each of the 60 plate forms above alluded to, every line of each of the Winchester Spectra from the long sheets with the conical scales—had of course to be carried out rigidly by myself; and as it has also been done on a partly symbolic plan of my own, intended to secure greater trustworthiness in spectrum drawings for the future,—I may as well say a few words upon it at this point. For the middle of the Spectrum, the ordinary method of representing all the stronger Fraunhofer lines, as vertical and parallel black lines ruled of more or less thickness, but of equal height on a horizontal strip of white paper,— such a method, I say, is just about as good a one as can be desired; for excepting colour, which has been hitherto tabooed in all high class Solar Spectrum Maps, the white paper stands expressively enough for the brilliant continuous part of the Spectrum of the Sun, and black ink lines also well represent the darkness of sharply-defined Fraunhofer lines seen thereon. But when exactly the same method is carried out to each end of the Spectrum, where of course the continuous spectral lhght of the hitherto lumimous back-ground in Nature at last vanishes in darkness, and no black lines can be seen clearly, in a quite, or even an almost, dark field,—such method I would beg to point out, misleads these who use such maps, grievously. For they are led to believe that there is just as much continuous spectrum light between, or as it almost looks behind, the lines of the pre- liminary band of Great A, as there is between those of Great B, or of the Alpha band ; and such reading students may form very erroneous estimates of the probable error attending on the observations of place for the first named lines, or on the distribution of lines, their thickness and the degrees of definition prevailing among them. To meet this imperfection in previous maps, I have introduced into mine, towards each end of the spectrum, a black shade running along the lower side of the otherwise white horizontal strip, and gradually rising in it as the spectral light fails ; until, when that ceases any longer to be visible, the black shade has risen to the top of the horizontal white strip, and eclipses it from that place onwards. Hence at any intervening point between the full height of the white strip near the middle of the spectrum, and its final extinction at either end, readers may judge of the degradation of the light, by the com- parative heights of the black shade below and the white paper above it; or they may imagine the sort of gray that would be produced over the full height of the strip, by smearing upwards, though but approximately, the amount of black contained in that part which is so coloured by the shade below. 530 . PIAZZI SMYTH ON THE So much then for the strength of the illumination of the back-ground of continuous spectrum light, whereby alone any Fraunhofer lines can be distinguished at all. But amongst Fraunhofer lines themselves, there are very ereat differences ; and while there is nothing so easily imitated or represented by merely drawing a sharp, simple line with a ruling pen and black ink on white paper, as a strong, well-defined, Fraunhofer line,—there are all sorts of deviations from such an ideal in the course of the Solar Spectrum. For there, every experienced observer knows so abundantly, that besides lines thick and lines thin, there are lines of various degrees of paleness, and of various degrees of sharpness, as welias sometimes of even extravagant haziness ; and all these are physical facts which should be expressed to some extent,— though minute accuracy does not stand with them on the same high level of importance as with accuracy of place in the horizontal scale. _ Hence with those two great ‘“ Dioscuri” leaders of modern Spectroscopy, KircHorF and ANGSTROM, the former’s map is not so popular now as it once was, —and partly because the method he adopted of indicating both paleness and thinness of some lines, by printing them in from pale tint stones amongst black lines previously printed from another stone, both sacrificed accuracy of place, and produced very ultra ideas of colour as well as paleness. While Angstrom’s map, which printed every line from one stone, with one inking, and sought to give thinness and paleness by exquisitely fine engraving only,—still holds its own among Spectroscopists with remarkable power and tenacity. Yet his is not a perfect method, for it cannot show such an undoubted existence as is occasionally met with, in the shape of a broad Fraunhofer line of pale material. While partly to make up for that graphical weakness as well as some others, the plan of pure engraving has been made the parent of a most: widely followed, yet distinctly vicious, system of representing shade, especially pale shade, in the spectrum by thin, close, vertical and parallel lines. Now some shady, nebulous bands to inferior spectroscopes, do undoubtedly resolve themselves into thin lines in a better instrument, but some of them do not, and ought not, in any spectroscope whatever; and even with those that do, the question of importance is to determine, into how many lines, and at what distances apart? Wherefore for an observer who has seen nothing whatever but a hazy, nebulous shade, to represent that in his map by clean, distinct lines of his own invention, drawn just as they would, or ought to, have been drawn, if he had seen veritable Fraunhofer lines in that place, is a species of wilful, scientific misleading which should be tolerated no longer. I have had no scruple therefore in my own maps, and also in my copies of anything really important from other men’s maps, in adopting as a governing principle for representing both paleness, and degrees of haziness in the spectrum, a symbolic method, not only easy of execution but perfectly impossible to be VISUAL, GRATING AND GLASS-LENS, SOLAR SPECTRUM. 531 confounded with any genuine Fraunhofer, or spectroscopic line proper,—and have called attention to the fact, and the principles on which it is based, at the foot of every one of the 60 plates now presented. These plates are further, though only half the size * of the original records, yet still on so very large a scale, that the places of any lines thereon, despite much roughness in the drawing, may yet be read off to such an accuracy, as not to require any columns of printed numbers to follow. There only remains therefore the propriety, when the plates are so numerous, to devise some easy and effective Index to them and their chief contents. Part ITV.—INDEXING BY COLOUR. The want of something of that kind becomes most evident, when some one line has to be looked for among actual thousands of others, without its exact Wave-Number place being perhaps known beforehand ; and not known most prebably on account of the Scientist or Student having been accustomed to use some other Spectrum scale, as either French Wave Lengths, or Kircuorr’s private Prism numbers, or the devices of some optician. But no matter what strange, artificial and human devised spectrum scale any one may have been using,—he must also, if an observer, bave had Nature’s inimitably beautiful, and effective general indexing of spectrum place by Colour, before his eyes again and again; till those colours must, if he has a soul, have been impressed involuntarily and indelibly, on the tablets of his heart in thankful admiration of God’s glorious Creation. Wherefore such a person’s search for any particular lines, guided otherwise by merely the one remaining, self- evident feature, viz., their configuration in black and white,—a configuration which may repeat itself very nearly, and therefore deceptively, many times in the course of the whole spectrum,—will be enormously aided, expedited and rendered more agreeable too, if, knowing beforehand that the group he wants is in the Gireen,—he finds 6 out of the 60 sheets coloured Green, and the rest of them steeped in colours as easily distinguishable from Green as they can well be. The manner however of introducing this colour into the Winchester work, is again partly symbolic ; in so far as, instead of one colour blending insensibly into another, each is inserted in a flat tint, perfectly uniform from beginning to end; but for that very reason, by so much the more easy to be separated by the eye, from either the preceding or the following colour. Nor need this be considered much of a violation of the more important laws of the Natural Spectrum ; because, as I have shown several years ago in the Transactions of * This note of size refers to the drawings for the plates. The actual prints, for economy’s sake, are only one-third the size. 532 C. PIAZZI SMYTH ON THE the R. Soc. Edin. (vol. xxviii.)—the spectrum colours, unlike the Fraunhofer, or “fixed” lines in the solar spectrum, are not fixed and unalterable in spectrum — place; but are positively locomotive therein through certain limits, according to the colour and the strength of the light. Hence Colour, though gloriously powerful, can only be, under any method of representation, an approximate indicator of exact spectrum position ; and will be most useful, when we employ it on that clear understanding alone. Dependent then in part on what the chromo-lithographer can accomplish, and what I shall be able to pay for—as the Society is not to be put to the expense of colour,——I have turned to the chromatic plate in my book “‘ Madeira Spectroscopic,” and have extracted thence ten well separated and easily dis- tinguishable colours,—extending by equal spaces of 3000 W.N. Units on 6 plates each, through all the visual spectrum depicted as here from 33,000 to 63,000 W. Number place. And I have also described, as well as exhibited, each of those 10 colours, together with an ultra-region at the beginning and end of them in a single collective plate, which I trust will be found all the title- page and index, which the whole mass of the following plates requires. These plates are numbered, not 1 to 60, but 2 to 61; for the reason, that the No. 1 plate after being finished in MS., was found to contain only one line, and that of no very pronounced character. In the spectrum itself too, it is exceedingly difficult to see, and therefore not capable of much accuracy of measure, so the plate carrying it has been omitted for economy’s sake. While finally, at the suggestion of the Secretary R. 8. Ed., I have added throughout, to the two upper strips, the scale points of ‘“‘ Wave lengths” in modern French metric terms, adopted by ANcstrrom in the latter years of his life, vice the “inches” of his renowned and heroic Scandinavian forefathers. Part V.—OF VARIATIONS OF TEMPERATURE AND OTHER PROBABLE Sources oF MINUTE DISTURBANCE. On comparing the three Winchester Spectra carefully together, after they were entered, reduced to Wave-number scale, on the final 60 sheets,—I was rather disappointed to find that they did not agree more closely and minutely at every point—whether as regarded (a) the exact places and appearances of strong and well-known lines; or (/) the existence or non-existence, as well as the exact places, of very thin lines not hitherto generally known of, or recognised amongst most observers. In matter (a) the anomalies were found, not only in the absolute Wave- number places of the sheets of reduction, but in the original instrumental records ; so that the simple intervening distances there, in three several cases of certain well-identified lines between great A and great C,—measured, in VISUAL, GRATING AND GLASS-LENS, SOLAR SPECTRUM. 533 mere inches of the paper micrometric record, with these decidedly too broad limits of variation :— 5°90 5°95 6.16 88°24 89-02 88°34 56°76 56°37 56:27 Still, however, being facts of observation, unexplained and unexpected,—I have never scrupled to give the anomalies in place thence resulting to any of the spectral lines, exactly as they came out, through all the finished Plates. But in the inferior matter of intensities of lines, and where my method of recording was confessedly weak,—I have often used considerable licence in making each of the three records, if certainly of the same line, approximate from their individual, to their mean, value as to strength. This proceeding will enable every reader to identify the same lines much more easily, in spite of not exactly coinciding places. And though this latter kind of discordance is undoubtedly a blemish, yet its full and intrepid insertion may perhaps prove in the end a valuable aid in deducing the limits of probable error for the place of any line, as given in either a single spectrum representation or in the mean of the three. But in matter (5) the immense variations that appear both for place and even existence among the thinnest and faintest orders of Fraunhofer lines are truly surprising and need inquiry before going further. Some portions of the uncertainties of place, generally, and for all kinds of lines, thick and thin together, are due to the effects of varying temperature on the grating. Not indeed of the absolute temperature, when settled down to something like permanence ;—for that should have been eliminated by the method of reduction and its appeal to M. Awnastrom’s standard places. But quick changes of temperature, and sudden springings of the apparatus during a rise or fall of temperature are much more difficult to guard against, and are only too likely to occur from the very nature of the case. That is to say, from the direct heating influence of the Sun, condensed by the heliostat on the slit, and thence passed on to the Grating itself ;—but acting there, as dependent on the clouds from minute to minute, sometimes for an hour together, sometimes for only five seconds during several hours. Some of the errors of place in special localities of the spectrum were Owing to the want of correctly fixed standards of reference in regions where, until lately, nothing was known to exist. And some again are due to the fragmentary character of the observation opportunities afforded by the too frequent clouds, whereby the time interval between noting two successive and neighbouring lines, may have been prolonged from a second, to an hour, or a day, or even a week; and a spectrum run which should have been con- 534 ©. PIAZZI SMYTH ON THE tinuously as well as speedily obtained at one temperature, may have been a slowly accumulated piece of patchwork at several temperatures. Other portions again have been suggested to be owing to the natural dis- placement of lines by the rotation of the Sun, when taken from either East or West limb, instead of from the centre of the visible disc. But these effects could only have been exceedingly small; for I had much difficulty in realising anything of that kind to be measurable, when I actually tried the experiment with the apparatus arranged as employed through the whole of these observa- — tions ; ¢7z., with an anterior separating prism to confine the grating’s view to one colour region, or nearly so, of the spectrum at a time. And that again reduced to a minimum the chance of occasionally mistaking intruding lines — from an overlapping order of spectrum, for those of the order intentionally in the field of view,—-a source of error to which Gratings are peculiarly liable. A ruder but more powerful source of occasionally possible error, existed in. an imperfect action of the inspecting telescope, combined with the peculiarities of vision through a narrow vertical slit. For though when the focal position of the eye-piece was too far out, that fact was easily shown, and as it should be by a haziness in the image of a line, yet when it was too far 77, every line in the field of view split immediately and sharply into two: and these separated further and further from each other, as the error of the focus increased. Wherefore the appearance of close and similar double lines had to be jealously watched whenever the observer’s telescope, by passing from green to violet of the spectrum, was innately growing in focal length. On the other hand, when the definition of the atmosphere was bad, the members of a really double line would throw out fringes of haze towards each other, and conceal thereby their real duplicity, if very close. While all the time alteration of focus had to be very sparingly employed, as it was only too apt to spoil the nicety of bisection. Something also of the highest accuracy may have been lost, in exchange for the greater speed at which the observations both were, and imperatively required to be, secured whenever the sunshine was continuous. In _his authoritative little work, Studies in Spectrum Analysis, Mr Norman Lockyer has rightfully stigmatised the slowness of the ordinary hand and eye micro- meter observation, as only enabling a careful observer “to lay down ten lines an hour.” But with the peculiar method,—utilising both hands and the eye,— which I arranged for this spectroscope, I was enabled on Thursday, June 26, 1884, to lay down permanently 1865 lines in three hours. Yet where so many opposing difficulties are concerned, I cannot perhaps d better than conform at once to the General Secretary’s suggestion to give further details as to the chief apparatus, and the daily circumstances unde which the three several spectra were measured. Now these latter were thus :—— First WINCHESTER SOLAR SPECTRUM, 1884. VISUAL, GRATING AND GLASS-LENS, SOLAR SPECTRUM. 535 VOL, XXXII. PART III. Hours of . Order of L - Max.Shade| Water-gas| Forenoon Portions of Ain Nes Coloured Glass ~ é a _ = : x Day of Grating’s . | Temp. in | in Cubic | Sun-shine : Spectrum in . Ss loyed ee rig ‘ Notes at the time. WN. Place, | OPeYation, Spectrum | UW tront oF Si | Ou Fe ats Pe Recorder. °F. Grains. H. M. 33,000-35,000| 8% June 25 1st two blue 70°0 5-2 a2: Between openings of clouds only. 35,000-36,500| S$ June 24 1st 1 blue + 1 red 67:0 3°6 4 15 Violet lines of 2nd order intrude. 36,000-39,700 | ¢ June 23 and 1 red 68°3 4:2 i) Xs) Blue lines of 8rd order intrude. 39,700-43,050| 3 June 24 2nd None 67:0 36 4 15 Definition exquisite, no coloured glasses. 43,050-46,830| &% June 12 2nd 68°0 46 4 57 46,830-48,150| h June 14 2nd 69°7 4:3 2 46 48,150-49,630| @ June 16 2nd 62°5 3°5 i Pal 49,630-50,000| % June 18 2nd 64°5 4:0 iy 50,000-55,850 | Y% June 19 and 66°4 40 3) 19 Focus of Collimator thus far untouched. 55,850-58,950} ?@ June 20 2nd 1 blue 67:0 4°6 5 84 Afterwards moved simi- larly to telescope’s focal adjustment, but to half the amount only, and 58,950-60,600] h June 21 2nd 1 blue 66:0 4°4 8 59 at frequent intervals. 60,600-62,950| @¢ June 23 2nd 1 blue 683 4°2 bf SECOND WINCHESTER SOLAR SPECTRUM, 1884. ‘, é = eens of Portions of rder of Coloured Glass ES bade VEMOIEEES) guenoon os Day of Grating’s an: Temp. in | in Cubic | Sun-shine : Spect é s loyed Ds ‘ Notes at the time. Bm Pisce. | Observation: | Spectrum | “font of Slit. | Observing [Footof Ain) by Col. ee ee Recorder. 2355 Grains. H. M. 33,000-34,400| 2 June 27 Ist 2 blue+1 red 73°4 5-0 6 12 34,400-43,050| h June 28’ and 1 blue+1 red 76:0 4°9 yi) The last part of the way, 43,050-47,700| 9 June 13 2nd None 73°0 4°8 6 4 1 red-glass only. 47,700-58,900| 4% June 26 2nd None 72:0 on 6 56 A marvellous three days for nearly continuous sun-shine, viz., W, ¢ and kh. Says Col. 58,900-62,900| ¢ June 27 2nd 1 blue 73°4 5:0 6 12 Knicut, “It cannot last !” And it did not.. THIRD WINCHESTER SOLAR SPECTRUM, 1884. Hours of 7 Order of Max. Shade} Water-gas| Forenoon Portions of eer Coloured Glass 5 : " oe 4 . Day of Grating’s A P Temp. in | in Cubic | Sun-shine Notes at the time. Spect : , Sereens employed in : . Bieice, | Oberration, | Ses | front of Sit, | Bom SF omatde. | “Kalght's Recorder. eyitts Grains. H. M. ; ita 33,000-36,500| 4 July 3 Ist 2 blue + 1 red 73:0 54 6 45 ee ‘¢a” in immense orce. 36,000-41,750| 4% July 3 2nd 1 red 73:0 54 6 45 41,750-44,650| 9 July 4 2nd 1 orange 73°5 5:2 3 40 All between clouds. 44,650-50,000| « July 7 2nd 1 green 68°5 4°6 3 14 50,000-55,320| 3 July 8 2nd 1 blue 71°8 50 8 55,320-56,000| % July 9 2nd 1 blue 70°5 56 0 18 Through clouds. 56,000-58,100} 2% July 17 2nd 1 blue 66°8 4°7 1 27 euuen clouds more or ess. 58,100-60,700} @ July 18 2nd 1 blue 66°4 3°8 3 31 Den clouds more or ess, 60,700-,63000| h July 19 2nd 1 blue 66:0 3°5 4 2 Between clouds, and with lower eye-piece. 4T 536 C. PIAZZI SMYTH ON THE To the above numerical particulars, the following details of focus, taken on — h June 21 may be usefully added. _ The Collimator being kept at a fixed focus, the telescope’s focus tried on the Solar lines of the Grating’s spectrum with an eye-piece magnifying 67 times, was found to be at the following successive distances in inches from its objective :— At Solar Lines. Ist Order of Spectrum. 2nd Order of Spectrum. 3rd Order of Spectrum. Great A (68°55) ? Mixture of Spectra. | Mixture of Spectra, Little “a” 68:43 shown by red and B 68°39 B= 6357 blue lines inter- C 68°36 C'= "68°50 mingled. D 68°31 D = 68°43 D = 6846 E 68°34 E = 68-43 E = 68:46 F 68°39 F = 68°46 F = 68:52 F to G 68°47 F to G = 68°55 Mixture of Spectra G 68°59 G = 68-702" again, red and blue H (68°72) ? Mixture of Spectra. lines intermingled. These numbers show that Messrs Cooxke’s form of achromaticity of objectives, gives a more nearly uniform focus throughout the spectrum than is generally met with. Yet that very excellence rather conduces sometimes to the mistaking of intermingled lines of two adjacent orders of the Grating’s spectra. Such intermingling was probably less on this occasion than it often is, by reason of the employment of a large anterior prism, which never allowed a white image of the.Sun to fall on the Slit, from the Heliostat’s condenser lens (6 inches in diameter and 90 inches focus); but spread it out sideways as a short spectrum-coloured smear. Of very “impure” spectrum-character 10 doubt, yet enabling the greater mass of each individual colour to be thrown separately on the slit at will. The Prism was of moderately good Flint glass, of 38° Refracting Angle, and with the faces enclosing that angle, measuring 5 by 5 inches. It was inserted transversely into the cone of Solar rays coming from the Heliostat lens, 65 inches before they arrived at a focus; and the large spectroscope table, carrying collimator, grating and telescope on its surface, rotated horizontally round a vertical axis under the centre of the prism; and could afterwards be adjusted slowly or definitely fixed by a grand screw motion in tangential direction at the outer end of the whole and on the floor level,—when the colli- mator had been placed by trial in the line of minimum deviation for the prism at the part of the Spectrum under observation with the Grating. In the third Winchester Spectrum, more use was made of coloured glasse VISUAL, GRATING AND GLASS-LENS, SOLAR SPECTRUM. 537 than in the first two; with the effect of spoiling the purity and beauty of spectrum colour, but of blackening the lines, without I hope disturbing their position for differential measures such as mine. } Part VI.—APPEARANCES AND DISAPPEARANCES OF TERRESTRIAL WATER- GAS LINES IN THE SOLAR SPECTRUM. But the most powerful cause of all, for altering the very physiognomy of some districts of the spectrum, is due to the invisible vapour, or gas, of water dissolved in the lower strata of the atmosphere; and thickening or thinning certain lines, or making new ones, according to its varying amount from day to day, from season to season, and from one country to another. In the dry climate of Portugal in June, and near Noon-day, I could only see a few mediocre lines occupying the spectrum place of “little a” and its preliminary band—hboth of them due to water-gas. So likewise was it in Edinburgh during the early days of May, in the present year 1885, when the air was both cold and dry; or with a temperature of 46°, and grains of water-gas in a cubic foot of air=2°6 only. But in Madeira, that “ Ocean-flower” fed by perpetual exhalations from the warm currents around it, with a July temperature of 72°°9, and grains of water-gas=6'49,—both those constellations of spectral water-vapour lines, even in a high Sun, were rich exceedingly in thick, black groups inimitably defined on brilliant red light, so as to form quite an inspirit- ing sight to have beheld once in one’s life. And at Winchester, in both June and J uly, Iam bound to confess that the said constellations put on a most respectable appearance, under the usual impregnation of the air in that locality and at that season to the extent of 4°5 and even 5°0 grains of water-gas to the cubic foot; chiefly thickening lines already known both to exist, and to represent water vapour. The puzzling manner however in which the thinnest class of Fraunhofer lines, if of water-gas, may either appear, or entirely disappear in the spectrum, in places where they might have been entirely unexpected by the observer,— was first and well described by Professor Jostan P. Cooke, of Cambridge, Mass., U.S., in a contribution to the American Journal of Science in November 1865. For, confining himself there, to the narrow space between the two Solar and therefore permanent and steady D lines in the Yellow,--he showed how the number of thin interstitial lines increased, just as the weight of water-gas in the cubic foot of air gradually enlarged from 0°81 to 6°57 grains. Professor Cooke further reasoned well on the Annual Maximum of such lines occurring in the American autumn, when the weight of such transparent water-gas dissolved in the air, but not forming clouds, or interfering with the brightness of the Sun, comes also to its maximum. Now this weight of water-gas in the air, is quite a different matter to the 538 C. PIAZZI SMYTH ON THE usual term of “Humidity” among Meteorologists, but which is in reality “ Relative Humidity” only; and means nothing for spectroscopic purposes, nor for absolute chemical composition either, unless accompanied by a statement of the temperature at the time. This may be well illustrated by the exceilent annual account of New York Meteorology published by Dr DAnteL DRaAPrr, at the Central Park New York Observatory for 1884. For, while his annual list of monthly means of “ Elastic force of Vapour” numbers (which are but another form of “Grains of water-gas in a cubic foot of air”) shows a grand — curve through the year, having its mmimum in January, and Maximum in August or September,—agreeably with Professor Cooxe’s observed growth of “ Aqueous lines between D* and D?”—yet the New York “Relative Humidity,” runs up to its terrible maximum of 96, not in August or September, but in January! On referring however to the Doctor's Tempera- ture return for the same month, and same hour, it is found to be only 21°42° F. Wherefore the amount of water-gas in each cubic foot of air at that time could only have been 1°3 grains ; under which scarcity, all thin water-gas lines would have been practically imvisible. Even at Edinburgh, in the present month of May, looking with the identical Winchester grating spectroscope—it was almost startling to find hardly anything except the one Nickel line, by contrast most pronounced in the middle of an apparently waste, empty space between the two D’s ; the water-gas amount- ing in this case to 2°6 grains per cubic foot of air. While at Winchester, when assisted by double that weight, I seldom looked at the D lines without seeing eleven or more finer, and evidently water-gas lines between them, besides the solar Nickel line ; and some of the former were almost as strong as that. Although therefore definite and constant lines of water-gas have only hitherto been much noticed towards the red end of the Spectrum, where they are undoubtedly strongest, and most easy to see, yet in warm, moist weather we may expect to find them elsewhere also. And there is a narrow, but positive band of them, noticed by ANGsTRoM as “ strong in summer,” so far away as in the further Green, or beyond little b. This band too, from the interesting manner in which it has lately been independently rediscovered, and even utilised in Jamaica as a Rain indicator, has been proposed to be named “ Maxwell Hall’s Jamaica Rain-band.” Besides which, Spectroscopists should be warned, that as the whole violet end of the spectrum is sensibly dulled by water-vapour when in abundance, there is most probably a formation over the whole of that region of infinitely — fine linelets. And though these have not yet been distinctly resolved to view by any one,—still with every increase in the power of new spectroscopes we may expect to fall across some cases of them made visible; especially if we look under the most powerful of the appropriate Meteorological conditions. VISUAL, GRATING AND GLASS-LENS, SOLAR SPECTRUM. 539 Such for instance would be those, if true, recently described in the Newspapers, as being much complained of by our army at Suakin on the Red Sea; viz., a temperature in the shade of 110°, and a depression of the Wet bulb of 4° or 5° only; which implies no less than 20 grains of water-gas to every cubic foot of air; and would present a subject of observation to any earnest spectroscopist of perfectly phenomenal attraction,—if Government would only condescend to make it possible to him, by granting commissariat facilities of transit to, and lodging at, the place. Part VII.—RESULTS ARRIVED AT TOUCHING TRUE SOLAR LINES IN THE YEAR 1884. It is now time, however, to return to our own more immediate subject ; viz., the hard and fast lines of Solar origin in the Solar spectrum. Lines which every one, in every country and in all varieties of climate sees, or should see, as constant as the Sun itself. And yet some anomalies occasionally will, and do, occur, when even such lines have to be observed and tabulated by human agency. ‘So that an important business before us now, is to ascertain by fact, whether the method here adopted, of publishing three successive and indepen- dent spectra in final juxta-position with each other, and with two previous authorities, has any real advantage in clearing up some of those otherwise doubtful, perhaps inscrutable cases, which will now and then happen among even the latest and most carefully taken observations. Thus at 44,620 W. N. Place, or on Plate 25, a strong line, far outside any water-gas variation effect, and represented both by M. Frevez’s, and the 2nd and 3rd Winchester, Spectra, is not contained in the Ist Winchester Spectrum. So that had that view alone been published by me, it might have led to time- Wasting discussions on a supposed lost line of the Solar Spectrum, vanished between 1882 and 1884; when the simpler, and I believe the true, explanation is, that the omission was merely an accidental slip on my part of one line in 6000, occurring at the first, but not on the two succeeding occasions. On Plate 43, however, we find in M. Fievez’s spectrum no symptom whatever of a very strong line, also far above water-gas variation limits in that part of the spectrum (viz., 53,673 W. N. Place), although it is conspicuously and solidly recorded on each of the three Winchester spectra. Wherefore, if the Belgian Astronomer maintains the truth of his negation of that strong line’s existence when he observed in 1882; and if neither he, nor any one else can disprove that there must have been such a line there when I observed in 1884; and, without any prepossession in favour of such a thing did on three independent occasions, separated from each other by two or three weeks,——always record a nearly first class line, whose position was subsequently 540 C. PIAZZI SMYTH-ON THE ascertained to be in the very middle of a blank region of M. Firvez’s Solar Spectrum map,—-why this is, in so far, just the kind of result that would be given either by the Krakatao volcanic explosion having caused a transmis- sion of some new and strange gas to the upper regions of the atmosphere,— or by something still more extraordinary having happened in the Sun, And yet I do hope M. Fievez will forgive me, if I am more inclined at present to attribute the ominous-looking blank in his work to the imperfections necessarily inherent in any single-drawn spectrum map (which is by its nature positive on everything, but may be mistaken on anything likewise), than to any new gas having appeared within the last two years in either the Earth’s atmosphere or the Sun’s surrounding. But when we come to the question of a possible recent increase in opaque dust effects, or a general dulling of the whole Solar and Telluric spectrum,— such indications in the Winchester work, and equally in all three of its spectra, are vast and undeniable. These dust effects, however, are more easily recognised towards each end of the Spectrum; for there, the “continuous” light, elsewhere in blinding excess, fades away into utter darkness, and increases thereby the sensitiveness of the photometric scale. Compared then with what I was enabled to observe of the Solar Spectrum in Portugal in the years 1877—78,—-each Winchester spectrum is deficient at the Red-end by the whole of what precedes great A; and deficient at the Violet-end by all that follows little “h,” including therefore those notable spectrum mile- stones—so grand when the air is pure and clear, viz., great H, and great K. But the Winchester Spectrum was observed on a grating, while prisms were used at Lisbon; and some gratings are very limited in the length of spectrum they are capable of reflecting at any time. I proceeded therefore, on returning to Edinburgh last July, to arrange a prismatic Solar spectroscope very like that employed in Portugal, though furnished with a stronger preliminary condenser for the Solar rays, and armed with very transparent simple glass prisms, in place of rather dark compound ones,—so as to make up, in Edinburgh, for the want of the clearer air, and brighter Sun, of Lisbon. With the Edinburgh arrangement then in 1884, and during many trials there in August of that year,—I could not only see the middle of the spectrum, but also as far towards the Red as great B, rather better than I used to do at Lisbon in 1877-78. But great A, further towards the Red-end, not so well; Brewster's Z still further that way and always faint in the middle of the day, not at all; his great Y line and accompanying bands, by no means so well; and his great X line, with its distant companions, not in the least degree,—though they were abundantly clear at the southern station in 1877. Heuce an extra-dulling of the Red end of the spectrum in 1884 is established with much certainty. VISUAL, GRATING AND GLASS-LENS, SOLAR SPECTRUM. 541 Again, on trying in a similar manner with the Violet end—great G, and some distance beyond it, were, with the better. apparatus, seen better in Edin- burgh in 1884, than at Lisbon in 1878. But every trace of light died out in the Edinburgh spectrum long before arriving at great H or great K, though they were grandiose spectral existences on the earlier occasion in Lisbon. Wherefore the whole result of this prismatic appendix to the Winchester grating observations evidently is, that the Violet end, joined testimony with the Red, in illustrating that there actually must have been just such a dulling of the Solar Spectrum in 1884, as should arise from the upper air being at that time over-charged with opaque, dusty particles—whether from the Krakatao explosion, or any other source. Leaving that matter, however, of location of the dust’s origin, to geologists to pursue further,—I will beg leave to terminate this paper with a few words on the subject of Spectrum Scales. Part VIII.—TESTIMONY OF SUCCESSIVE GASEOUS GROUPS TO THE MOST PRACTICAL OF NATURAL SPECTRUM SCALES. _ In 1878 the British Association for the Advancement of Science, published in their Dublin volume, an admirably extensive exhibition (in 52 printed pages) of the numbers for a Solar Spectrum, compiled from both M. Anestrom and Professor Krrcuorr, with the chemical origin of the chief lines, and the places of all, given throughout in terms of “ Oscillation ereeency: ” This being, 4 _ however, in practice, only “Inverse Wave Lengths;” or the “ Wave-number” here employed, though in terms of a French, instead of a British, standard of _ of linear measure. In their volume for 1881 (at York) the Association ale further “strongly recommended” their method of “Oscillation-frequency,” as against “ Wave- Lengths”; and led its Members to expect a speedy publication of lists also of the lines in Chemical elemental spectra, expressed in the terms they so much ‘approved of. They had also in 1878 promised to distribute to the Members, at the Sheffield meeting in 1879, a map of the Solar Spectrum in terms of the ‘same “Oscillation Frequencies.” This promise, however, I have just ascer- tained from the Secretary, they never fulfilled ; and now in their volume for 1884, where the lists of metallic elemental lines are given at last, and to the noble extent of 95 pages,—the Members, and the outside world too, will be much amazed to find, that without a word of explanation or apology, the places are all expressed in terms of Wave-Lengths. Such a breaking of its previous promises, inferences, and example, on the part of a great Association, supposed by many to have necessarily more continuity, and less vacillation in its opinions from year to year, than any 542 C. PIAZZI SMYTH ON THE single human being—is rather disturbing to private workers in science. And I cannot but think the change to be a mistake, wherever at least Spectrum — maps are concerned, for this amongst other reasons derived from the Winchester records. Viz., there are divers practical cases known, where the same chemical element repeats a certain constellation group of lines of its own, at several successive places in the length of the Spectrum. And evidently, if only for recognition purposes by means of measure, it would be of advantage to every one researching these matters, that the scale of a spectrum map should be such, that each of these repetitions of a recondite natural phenomenon should be presented of the same size,—in whatever successive colour of the spectrum it may reappear. Now the grandest example throughout the whole Solar Spectrum, of such a_repetition-form, is without doubt set forth in those three most striking linear constellations of great A, great B, and the Alpha band; all of them now considered to be due to absorption by cold Oxygen in telluric, and super-— telluric, position. Much of the peculiar arrangement of the lines in great B and its pre- liminary band, has been known for a long time past, from ANGsTROM and_ THALEN* downwards. But that the arrangement in great A is exactly similar, even down to the doubling of every line but one, in its preliminary band,—was only discovered with the powerful assistance of one of Mr RuTHERForD’s best gratings so lately as 1878, by Professor LANGLEY of the Allegheny Observatory, _U.S.; and that a similar arrangement prevails in the Alpha band, was the very recent and neat discovery of M. Cornu in Paris, in 1883. Whoever too has had the privilege of repeating these observations with sufficient diffraction, or dispersion, power—must have been struck with the extraordinary perfection of the series. In the preliminary bands for at least ten couples and one single line, the emplacement is exact; and in the subse- quent line groups very nearly, though not quite, or simply so; for they are * Tt seems by a recent publication from Upsala, that M. TaaLen with prisms, saw the clear duplicity of the linelets of Great B’s preliminary band much better than did M. Anestrom with a small grating, mounted on a theodolite stand. In fact the latter did not see them to complete identi- fication ; and in his extreme anxiety not to pass beyond the modesty of observation and the truth of nature, disputed long before he would allow his friend M. THatEn to draw these linelets double, as he — saw them without any doubt, on the manuscript for the immortal “ Normal Solar Spectrum.” They — were however so drawn at last by M. Tarun, and were so engraved by the lithographer; but on his sending a proof of his work for correction to M. Anesrrom, then on his death-bed, the dying philosopher, in his over conscientious desire not to exaggerate what he had really seen, took a pencil and filled in therewith the narrow spaces between the double members of each linelet; the engraver imitated the granular pencil markings ; and that is the origin of the shading by dots, quite anomalous in spectroscopy, to be seen now on the finally engraved and published Atlas of the Normal Solar Spectrum, in its particular plate representing that preliminary band of the great B line. F VISUAL, GRATING AND GLASS-LENS, SOLAR SPECTRUM. 543 fraught with a further degree of close set lines and linelets; following, apparently, in each of the three cases, certain harmonic variations of one fundamental idea; and that not of the uniformity of an iron railing and its mere equal spaces, but with a delicate rise and fall of proportions most intensely admired by those of artistic mind. Wherefore every good observer, can hardly but regard with almost solemn awe, this surpassing and esthetic symmetry of elemental matter, which is obeyed so perfectly by every vibrating atom of a given element, but remains at present beyond all human mathematical theory to equal or explain. Now if we measure these groups on a Wave-length scale they give, as on my original instrumental records,— Great A = 23°86 inches, Great B = 18-40 inches, and Alpha band= 14°98 inches ; or with most violent variations of size and a converging tendency, threatening compression amounting to practical extinction and invisibility in the much further blue, and violet, regions of the Spectrum. Regions too where every observer knows so well, that more map space than what the “ Wave-length ” can give, is so imperatively required to do simple justice to the increased number of lines that appear there, as compared with the Orange and Yellow domains. But if we now measure the three Oxygen repetitions on a Wave-number scale (or practically the same as the Oscillation frequencies, so long advo- cated, but now at the last moment rejected, by the British Association), they come out thus, on the final plates herewith presented to the Royal Society, Edinburgh, viz. :— Great A = 9-24 inches, Great B = 9-00 inches, Alpha band = 9:20 inches. So that, as a natural representation, and in accord with the latest dis- coveries of both Solar and chemical spectra, there is not at present known any better scale than that which has been employed, for already published good physical reasons, throughout the 60 plates of this paper on “The Solar (grating and glass-lens) visual Spectrum in 1884.” And these plates themselves now follow,—with their naturally expanded room for Blue, Violet and Ultra-violet, lines,—to aid quick and easy examination of their multitudinous natural features, which consist as often in the grouping of many close lines, as in the absolute place of one standing solitary by itself. Part [X.—TuHe Map In 60 PLATES, AND WITH AN INDEX PLATE. VOL. XXXII. PART III. 4U VoU. XXX. Pl. LXXXH. ce. Edin. ZX TO THE WINCHESTER VISUAL SOLAR SPECTRUM IN 1884. TRUM COLOUR AT PLACE. JOURS NAME. 3ERS OF THE PLaTEs Sa 10,000...33,000. 33,000....., 36,000. 36,000...... 39,000. 39,000 ..... 2,000. IOLUDED THEREIN. Great X = 29,680. para Toms camury mann | Suu ATS tg] game B=389H8 | sta tnd soe Great Z = 31, 900. § INCLUDED THEREIN. ee Pisces | 2,5400...7697. WOO Acces 7056. 7056......6513, 6518...... a. | [LARLY INCLUDED. Great Y = 8231. Lille Go85. ees Alpha band = 6278. Great Z= 7962. a ss | 26 to 31. 32 to 37. 38 to 43. fees. f 45,000......48,000. 48,000......51,000. 51,000......54,000. AURORA’S Great E = 48,205. Inttle c=51,242. ee Inne = 45,550. Iittle 6=49,005. Great F = 52, 255. ee. ; , eee | = ae > jaeo. 97 4704. Aurora’s Great E= 5269. Little c= 4957. Chief Line = 5576. Tittle b = 5183. Great F= {86/. SPECTRUM COLOUR AT PLACE. La DEEP BLUE. VIOLET. ULTRA-VIOLET. | COLOUR’S NAME. P — 50 wo 6 56 1 61, ee eee Wave NuMBER PLACES bese 57,000. 57,000...... 60,000. 60,000...... 63,000. 63,000...100,000. ein Naot D6 509 To REE Little g= 60,100. | Gnear H=64,012. Sranparp Lines : : ; Great bie 58, 967. Tittle h= 61, 933. Great K = 64, "582. ALSO INCLUDED THEREIN. 7, 4 AOE Bi WavE Sao. PLACES 0. Be cad 4456. VHA Omapoce 4233, PES racoece 4082, KOSS gorcon 2540. CLARE INGE: latile e= 4404. Little g = 4226. Great H = 3968. SranparD Lines IN W. A.: Inttle h = 4101. Great K = 3933. Anastrom’s Norm. Sot. Sp. Little f= 4383. W. & AK Johnston, Edinburfh, t& London Great G = 4307. 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Roy. Soc. Edin? . XXXII, Plate CXLVIII. { 1 oGa HA |b SS PSs a !) i t oo 99.6900 WO 206 0 we M'Farlane & Erskine, Lith®? Edin®™ (60h) XXXITI.—Anatomy and Physiology of Patella vulgata. Part I. Anatomy. By R. J. Harvey Gipson, M.A. Communicated by Professor HErp- MAN, D.Sc. (Plates CXLIX.-CLIIL) (Read 5th January and 20th July 1885.) CONTENTS. PAGE PAGE INTRODUCTION, . ; : : é . 601 3. Circulatory System, . ‘ ; 2) Gls Historican Account, . ‘ : é =) 60 4, Purificatory Systems, : 614 MorpHo.oey : 5. Muscular, Connective reese and 1. External Form—General Arrangement Epidermal Systems, . . 620 of Viscera, . : : : . 603 6. Nervous System and Sense Gone . 626 2. Alimentary System, . : : - 605 7. Reproductive System, ‘ P . 633 INTRODUCTION. The following research was undertaken chiefly with the object of furnishing a complete memoir on the morphology and physiology of Patella vulgata. A number of isolated observations on various organs are recorded, but no systematic account has as yet been written, so far as the writer is aware. He has endeavoured to incorporate these observations in such a general account, having first convinced himself of their accuracy so far as lay in his power. The paper is divided into two sections. Part I. deals solely with Anatomy and Histology; Part II. will contain an account of the Physiology of the systems described in Part I. An attempt will be made to give a description of the as yet uninvestigated development of Patella. These observations will doubtless afford material for certain conclusions bearing on the phylogeny of the Patellide. All the observations described in Part I. were made on specimens obtained from Granton, the Gareloch, Loch Goil, and Firth of Clyde, fresh or preserved in spirit, or a saturated solution of picric acid. The research was conducted in the Zoological Laboratory of University College, Liverpool ; and the author is indebted to his friend Professor HErp- MAN, D.Sc., not only for permission to make these observations in his labora- tory, but also for constant advice during the prosecution of the work. His best thanks are also due to Dr Murit, F.L.S., for the great assistance rendered by him in the bibliography of the subject. HIsToRICAL ACCOUNT. As indicated above, the investigations into the minute anatomy of the limpet are not numerous, and with few exceptions exceedingly fragmentary and contradictory. Dat, in a recent paper, afterwards to be referred to, ~ VOL. XXXII. PART III. oH 602 R. J. HARVEY GIBSON ON THE expresses a hope that the anatomy and development of this form may be taken up by some one; and although it is to be regretted that the task had not fallen into more competent hands than the present writer’s, yet he hopes that he has, — in the following research, done something towards dispelling the prevailing uncertainty in regard to many questions, which have too long demanded inves- tigation. The desideratum at present in the natural history, more especially of the Mollusca, is a series of complete accounts of all the more common types ; and it seems to the author that much more might be made with regard to interesting problems of Phylogeny, if, instead of elaborating a number of small detached papers on special points, some naturalists were, for a few years at least, to devote themselves to the working out of complete monographs of the most important forms belonging to each group. A considerable amount of work has been done in the way of naming and identifying the numerous species of the Patellide; although, owing to their identification being based on unimportant external features, e.g., the form and colour of the shell and exposed parts, many forms have received several — synonyms, and have consequently been described several times. : In this summary of research, the author desires rather to indicate the leading papers on which our knowledge of Patella is based, than to give any detailed account of these papers themselves, which he prefers to postpone until the different organs with which they deal come to be discussed. The limpet is mentioned first, of course, by the all-observant ARISTOTLE, who gives a brief account of some of its more obvious characters and habits,— referring especially to its moving from place to place and returning after each forage to its old roosting place. General descriptions have been given by Linnaus, Born, ADANSON, and various other naturalists of the last century; and we are generally able to identify the species described by them with those now inhabiting our coasts. Similar accounts are given by later conchologists, more especially by REEVE, HANLEY, GwyN JEFFREYS, GRAY, and WooDWARD. The first attempt at giving a complete account of the anatomy of Patella is that of Cuvier in his Memoires, where the species is described with tolerable fulness. Gray, and later Datt, have described and figured the radula, the mechanism of which has been lately fully investigated by GEppxEs. The renal organs have come in for a good deal of attention from LANKESTER, DALL, and CUNNINGHAM, and are perhaps the most thoroughly investigated portions of the whole animal. The respiratory organs have not been so fortunate, having bee examined, in allied forms only, by WiLL1AMs (whose paper the writer has not been able to see). Some remarks on the respiratory organs by BLAINVILLE ali ADANSON are mainly contradictory of each other. The nervous system has been investigated by Branpt and by SPENGEL; and their admirable work leaves little to be done in that system, save to make a few remarks on histology. SPENGEL ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 603 also gives an account of the olfactory organ; and Fraisse describes and figures the eye of an allied species, Lacaze Duruigrs has investigated the auditory organs. With regard to the reproductive system there is great uncertainty, the existence of oviducts and of vasa differentia being asserted and denied repeatedly. Cuvier asserts the presence of an oviduct ; DALt in one research thinks that he has seen it, and in another he denies that it exists. LANKESTER describes two so-called “ capitopedal orifices,” which he took to be the openings of oviducts, but which he now believes are the rudiments of true gills; DAL denies their existence altogether. Gray mentions the presence of reproductive glands, but gives no details. Many authors have made observations on the habits of the limpet, and some few notes on its development have been published by FiscuEer; these researches, however, do not fall to be discussed in this part, since they are rather physiological than anatomical in their nature. MorpPHOLOGY. 1. External Form.—In size, Patella vulgata varies from 4 inch to 23 inches in maximum antero-posterior diameter. The maximum transverse diameter is about 2 to ¢ of the maximum antero-posterior diameter. In a typical moderately large specimen, say 2 inches long, the short diameter is about 13 inch, the height of the dome about ,% inch; but in no case are the relations of the measurements perfectly constant. Before removal of the shell, such a specimen is seen to be dome-shaped, the apex being rounded. The marginal outline of the shell is oval, the narrow end corresponding to the head end of the animal; the apex of the dome is nearer the anterior end. The rim of the shell is sharp and irregularly notched; it is also bevelled, the bevelled side being inner. Two series of markings are visible, one series running from the apex to the edge of the shell, 2.¢., radial, the other concentric with the edge. Internally, bands of colour of varying tint replace the radiating lines. The radial lines, externally, are usually tuberculate. The body is surrounded by the mantie skirt, which in specimens preserved in spirit extends beyond the ventral surface of the foot, owing to contraction of the muscle of that organ, but which naturally reaches a point midway down the side of the body. The mantle skirt is notched or wrinkled and pigmented. It usually retreats ‘somewhat from the shell, its extreme edge forming a thickened rim. From the inner surface of the skirt, throughout its entire circumference, _ there depends a series of lamellee, the functional gills. These occupy a grove, or _ valley formed by the mantle on one side, and the concave side of the muscular 604 R. J. HARVEY GIBSON ON THE foot and of the circular muscle which attaches the foot to the shell on the other. This band of muscle is discontinued at the anterior end for a space equal to about ith of the circumference ; which space is occupied by the head. The mantle and gill processes are, however, continued round the anterior end, and depend in front of the head. The head is distinct, and a slight narrowing indicates a rudimentary neck region. The oral disc (Pl. CXLIX. fig. 1), in the centre of which is the oral — aperture, is corrugated and kidney-shaped in outline, the hilus being ventral. On either side of the head there is situated a epee more or less pigmented tentacle (the ‘‘nuchal” tentacle), usually from 4 to 4 of an inch long in its con- tracted condition, but, when extended, in large fienplots as much as # to an inch in length. On either side of the neck there may be seen an oval yellowish body, the rudimentary gills or ctenidia. They are usually about twice their own length from the circular muscle. They vary in length according to the size of the animal, from 7; to 24 of an inch (Pl, CXLIX. fig. 3).* Over the right — shoulder may be seen the anal papilla, and the right and left renal papilla, one on either side of it. Ventrally the muscular foot is seen widening as it passes downward, and having a thin rim as its ventral edge. On removal of the shell, the visceral dome is exposed, and found to be covered by a deeply pigmented membrane. The colours are deep indigo, streaked with dull yellow. The yellow tinge being due mainly to the subjacent viscera shining through the visceral integument. The superficial dark pigment layer is easily scraped off (Pl. CX LIX. fig. 2). 7 The muscle connecting the foot and the shell is now visible, on surface view, as a ring, incomplete in front, of uniform width, save at its anterior extremities, which are rather wider and rounded off. The superficial pigment is most abundant near the muscle band. ' The eyes may be made out as minute black specks, one on either nuchal tentacle, on a slight prominence on their outer aspect, near the base. General Arrangement of the Viscera.—The general arrangement of the viscera may be made out on remoyal of the shell, and after the superficial pigment layer of the visceral integument has been scraped off. If the imtegu- ment itself be removed, the relation of the viscera may be still better defined (Pl. CXLIX. fig. 3). The integument must be removed with care, as it is intimately related in some parts to the subjacent tissues. The free edge of the mantle over the cephalic region being also removed, the visceral mass is seen to be bounded anteriorly by a ridge, from which project forwards on the right hand side the anal and renal papille. From the anal papilla, the rectum passes _ backwards transversely for a certain distance, and then passes circularly round * In the figure they are represented as too near the middle line and too near the base of the tentacle. ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 605 the visceral mass. Posteriorly to the rectum, and supporting it, lies the genital organ (male or female), which at certain seasons is very large, and forms a erescentic mass, on surface view, enclosing and supporting the other organs. It is wedge-shaped, and extends along the floor of the visceral cavity, its thick edge forming the crescent above mentioned. Between the rectum and the genital gland, and spreading round the former and sending projections over the latter so as to enclose it, is the posterior portion of the right nephridium. It may be traced as a dark brown mass pass- ing up the right side. It is very variable in form, sometimes scarcely apparent on surface view, at other times ramifying extensively over the dorsal surface. It varies in colour from a brown yellow toa deep burnt umber. On the extreme right may occasionally be seen-a portion of the lingual ribbon inits sheath. The right nephridium usually extends for 4 of the circumference of the visceral mass. The centre of the visceral dome is occupied by the liver, a granular villous mass of yellowish-green colour. It is enclosed by a coil of intestine, which springs from and ends at the right side, and which separates it from the right nephridium. Between the anterior bend of this coil and the rectum lies a branch of the right nephridium. Anterior to the rectum, and between it and the anterior boundary ridge, there is a quadrilateral region, which is divided into two by a fibrous septum. That part, usually more or less triangular in outline, lying nearer to the anal end of the intestine, is entirely occupied by a light brown body, the left nephridium. The rest of the space is white and fibrous in appearance, and forms the dorsal wall of the pericardium. The visceral integument is free from the viscera, save where it lies upon the nephridia and pericardium, with both of _ which it is intimately connected. Born and REeEve, among the older naturalists, give the fullest accounts of the external features, the former in his Testacea Mus. Ces. Vind., the latter in his Conchologica Iconica. CuviER gives a short description of the soft parts visible without dissection (Mémoires pour servier a UVhistorie et Canatomie des Mollusques). Gwyn Jerrreys (British Conchology) gives the most complete recent account, but errs in saying that the shell is opaque. None of the shells examined by the writer were altogether opaque ; the majority were translucent, though some were less so at the apex than elsewhere. 2. Alimentary System.—The alimentary system is very complicated, and has not hitherto been investigated in any detail. The following account does not profess to be perfectly complete, either macroscopically or microscopically ; and the difficulties in the way of a thorough and accurate examination of all the parts are such that it cannot profess to be final either. Many points yet require a more detailed investigation, which the writer means to undertake in 606 R. J. HARVEY GIBSON ON THE connection with the physiological section of this research. With that intention he has omitted certain histological details, more especially into the minute structure of the crop, the openings of the bile ducts, &c., with regard to which it may be possible to obtain some information when the physiology of these parts comes to be investigated. Considering the alimentary canal first of all macroscopically. The buccal — cavity is entered by an oval or kidney-shaped opening on the oval dise. Immediately within the circular puckered outer lip which guards the opening — is a shallow cavity, which is closed posteriorly by a pair of inner lips. These inner lips are two stout flaps of muscle which rise vertically from the floor of the buccal cavity, and project almost to the roof. They leave between them a narrow vertical slit, through which the odontophore may be seen (Pl CLIL. fig. 54, a). Within these lips a large irregular chamber is found, which may be termed the pharyngeal chamber. Its form may best be understood by following the reflections and foldings of the pharyngeal mucous membrane (Pl. CLI. fig. 62). Ventrally the mucous membrane, starting from the inner aspect of the inner lips, runs along the floor of the chamber for a short distance until it has reached the middle of the odontophore. There it bends anteriorly, and is reflected up over the anterior part of the odontophore. Laterally the mucous — membrane follows a similar course, being there reflected over the sides of the odontophore. The mucous membrane then passes beneath the radula, forming the subradular membrane. Ata short distance from the centre of the dorsa surface of the odontophore the membrane unites above the radula,—forms in this way a bag for its reception. Indeed, the radula is an epidermic modifica- tion of the pharyngeal mucous membrane. The radula lies folded in this bag, from the wall of which it is developed. The bag is suspended among the viscera, usually to the left side, sometimes, however, on the right, more rarely still in a spiral coil on the floor of the visceral cavity. Returning to the pharyngeal mucous membrane, dorsally it springs from the palate, and when it has become free from the body or neckwall, and uniting with the lateral portions of itself, passes backwards over the dorsal surface of the odontophore. After passing the origin of the radular sheath, it unites with the ventral portion, and becomes the pharynx proper. On the palate and on the floor of the pharyngeal chamber, there are two structures which require mention. These are two plates which protect the subjacent tissues from injury from the teeth of the radula. The palatal plate (Pl. CL. fig. 17, and Pl. CLIII. figs. 63 and 64) is sunk in the tissue of the palate, and like the radula and the ventral plate, is a development of the pharyngeal mucous membrane. Looked at from below, it presents a central triangular area, which is of a brown colour, and from which posteriorly (apex) — project two large almost colourless flaps; from the (base) anterior end also_ ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 607 project two smaller wings. These wings are sunk in the tissue, the triangular central piece being that against which the radula works. The anterior smaller wings are seen to be flaps of a collar which is formed by the turning back of the plate. In other words, the anterior flaps are on a higher plane than the posterior flaps. The palate is slightly depressed where the anterior margin appears ; and the plate itself is curved, the concavity being ventral, and being the groove in which the radula slides. Since the radula passes over the anterior end of the odontophore, the teeth are therefore brought into contact with the floor of the buccal cavity. There accordingly is found another plate (Pl. CLII. figs. 55, 56), which has not hitherto attracted the attention of de- scribers of the hard parts of the limpet. It is not so large nor so distinct as the other, but that it affords protection to the tissues at that point, is shown by the fact that the surface of the plate is furrowed by the radular teeth. The entire plate (as described below) is simply a thickened cuticle. The pharynx, behind the palatal plate, becomes distinct above. It has very thin and delicate walls. It may be seen to be 3-chambered, or rather to have two very evident folds running down one on either side (Pl. CLIIT. figs. 61, 62). The wall of either lateral division has a very manifest thickening of a yellowish colour, where the salivary ducts enter. The roof also of the pharynx has posteriorly a large number of mucous glands in it, which give it a white appearance, as contrasted with the more transparent anterior portion. The buccal mass now falls to be described. And, first of all, having theo- retically stripped off the pharyngeal mucous membrane, the radula must be noticed as distinct from the odontophore and its muscles. The radula is a narrow belt usually about (in a moderately-sized limpet) ;4,th of an inch broad, and about twice the length of the animal in length. Anteriorly it widens out into a flat plate, in the centre of which is the radula proper. The plate and radula is merely a modified cuticle. The plate is bent over the front end of the buccal mass. It is fastened to the mass beneath, whilst, superficially and pos- teriorly, it sinks beneath the level of the muscles of the buccal mass, and runs into its sheath as already described. ‘Towards the posterior end the teeth gradually disappear, and ultimately it ends in a soft hammer-shaped knob. Its minute structure will be described under the histology of the alimentary system. The odontophore itself is composed of muscles and cartilages. The buccal mass (Pl. CLIII. fig. 65), deprived of its covering and radula, is ovoid, and divided almost into two hemispheres by a furrow, which runs vertically from before backward. Anteriorly the furrow widens and becomes shallow, and has a prominence in its centre, over which the radula was bent. Either hemisphere is composed, therefore, superficially of a mass of muscle whose fibres run out- wards and from before backwards, and are the muscles of the radular mem- brane. Beneath these muscles lie the cartilages. The cartilages are six in 608 R. J. HARVEY GIBSON ON THE number—two anterior, two posterior, and two lateral. The anterior cartilages are the largest ; they are pointed and slightly curved upwards in front, and are arranged like the legs of the letter V, with the apex pointing towards the mouth (Pl. CLIIL. fig. 66). At the bases of the legs lie the posterior cartilages, and closely attached to them. The posterior cartilages are square blocks with corners rounded off. The lateral cartilages lie alongside the anterior cartilages, and towards their anterior ends. They are triangular in shape, having the base of the triangle anterior. These various cartilages are bound to one another (a) by connnective tissue, and (b) by muscles. (a) Distinct bands of connective tissue bind the posterior cartilages to the anterior, and also the lateral to the anterior. (b) There are also a number of muscles which connect the various cartilages to each other; a band uniting the anterior and lateral cartilages on either side, dorsally ; two bands or sheets uniting the two anterior cartilages, ventrally ; the upper of these being the broader and larger, and being separated from the under narrower band by two bands of muscle passing from the infra- radular membrane to the base of the posterior cartilage on either side ; and, lastly, a band uniting the anterior and lateral cartilages on either side, ventrally. All these muscles may be termed intrinsic. There are, however, in addition several extrinsic muscles connecting the buccal mass with the neck wall. Firstly, two broad plates attached posteriorly, one on either side to the posterior cartilage, anteriorly to the floor of the neck cavity. These may be termed the ventral protractor fibres (Pl. CL. fig. 17, v.pr.). Also attached to the posterior cartilage on either side is a lateral protractor, which is attached anteriorly to the roof of the neck cavity. Finally, attached laterally to the anterior cartilage, on either side, is a vertical band of muscle, attached at its upper end to the roof of the neck cavity. Many delicate muscular fibres also pass from the pharynx to the walls of the neck cavity. Returning now to the pharynx, it is found, as already stated, to be more or less divided externally by two longitudinal furrows into three parts, a central and two lateral. These several parts are in complete communication with each other, the division being rather apparent than real. Anteriorly the wall of the pharynx is thickened by the development of two oval yellowish-brown masses, one on either of the lateral divisions. Into these masses the four very evident salivary ducts open, two into either mass (Pl. CLIII. fig. 61). The ducts are long ~ isolated, slightly twisted, yellowish-brown tubes which run from thence back- wards, the two inner lying in the furrows of the pharynx, but easily detachable therefrom, the two outer running alongside the odontophore. The two inner enter the salivary glands about the middle; the two outer are attached to the glands at their extreme edges (Pl. CLIIL fig. 61). The glands themselves vary somewhat in size and colour. They are usually large orange-coloured masses closely united together, lying over the shoulders, beneath the pericardium on one ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 609 side, and the renal and anal papillee on the other. The pharynx widens consider- ably after becoming free from the buccal mass, and two deep pouches, the continuations of the lateral divisions of the pharynx, lie on either side of the neck in front of the salivary glands. The so-called “crop” (the name is very inappropriate) is a long thick-walled sac continuous on the one side with the pharynx, on the other with the cesophagus. The folds in the pharynx are con- tinued to the crop, which has other transverse folds of its own. The interior has been justly likened to the maniplies of a sheep’s stomach. Round the “crop” and the true stomach, which lies above it, is the liver, an irregular yellowish mass which fills up all the intervening space between the “crop,” stomach, and coils of intestine soon to be mentioned. It is a compound tubular gland, supported by a framework of connective tissue. The biliary secretions appear to be poured into the crop at many points; more accurate information must be obtained, however, with reference to that point. The cesophagus is of small and uniform diameter; it makes one short coil on the floor of the visceral cavity and then widens into a long stomach, which is doubled on itself, and lies across the centre of the body (when not displaced by the greater size than usual of the genital gland), the blunt or folded end lying behind the peri- cardium, but usually separated from that by one or two folds of intestine. The two halves of the stomach are closely applied. From the pyloric end of the stomach the intestine springs, and maintains throughout its entire length a constant diameter, viz., about equal to that of the cesophagus. The intestine immediately after leaving the stomach bends sharply back and runs beneath the folded end of the stomach round to the head, passes in front of the cardiac portion of the stomach, over the buccal mass, and, on reaching the extreme edge of the visceral sac on the left side, bends sharply upwards, and coils over a subsequent loop of intestine. It then forms a superficial loop on the dorsal surface, over the top of the stomach, passes again back to the point at which it bends upwards, and there bends downwards. The ascending and descending portions touch one another at that point. The intestine then travels along the floor of the visceral sac, and, after making a complete circuit of the sac, passes forward, and, curving backward once more, forms that portion of the intestine which is looped over by the ascending and descending parts above mentioned. It makes one more complete circuit of the visceral sac, and then ends at the anal papilla on the right shoulder. The columnar epithelium of the exterior epiderm is continued into the interior of the alimentary canal. The pharynx is lined with columnar epi- | thelium resting on a layer of connective tissue and muscle. Over the roof of | the pharynx, both in the central and in the lateral divisions, there are many | convoluted compound tubular mucous glands. The secretion of these glands, | which is poured into the buccal cavity, is thick and viscous, and contains many | VOL. XXXII. PART IIL. bE 610 R. J. HARVEY GIBSON ON THE ~ cast-off epithelial cells. At the palatal plate, and also at the ventral plate, the epithelium becomes many layers deep (elsewhere it is in a single layer, save in the glands), and the superficial cells secrete a very thick cuticle which becomes modified into the distinct and separable palatal plate in the one case, but in the other remains attached to the cells (Pl. CLIT. fig. 56). Beneath the edges of the ventral plate the connective tissue forms two soft pads. The radula, which lies in a long sac formed by an out-pushing of the pharynx, from the wall of which it is developed, is a ribbon, expanded at the anterior end into a flat plate, which is wrapped round the anterior cartilages, and is continuous with the pharyngeal mucous membrane, viz., with that — reflection of it which covers the under surface of the buccal mass. Posteriorly the ribbon is bent on itself in its sac and ends in a soft clubbed end. The teeth are not developed in the latter part of the ribbon, though their general position is mapped out on the membrane. The various ridges are then strengthened and developed by deposition of particles of chitinous matter with which the sac is plentifully supplied. When completely formed (Pl. CLII. fig. 60) the radula is seen to be composed of a tough chitinous band, from which spring a number of teeth. The teeth are arranged in curved rows, the concavity of the row being anterior. The radula tends to tear in that way. Each row consists of ten teeth. The four central teeth (4, 5, 5, 4) are similar in shape, although — the middle two are slightly smaller than the exterior two. Each is composed of a yellowish root and neck, succeeded by a brown band or collar, and terminated by a black crown, which is in shape like a bird’s claw, the claw having its convexity directed: towards the mouth. Next to the four central teeth, and placed a little in advance of them, is, on either side, a tooth slightly larger than any of the central teeth, but similar to them in structure, save that it has three claws instead of one (3.3). Most external of all, there is a pair of teeth on either side which are flat, faintly yellow in colour, without claws; the ends are, however, slightly curved upwards and backwards. ‘These teeth are also slightly in advance of the last mentioned, and the outer of the two is slightly beneath and in advance of the inner. The form and relationships of the teeth will be much better understood by reference to the figure (Pl. CLI. fig. 60). The cartilages of the odontophore are composed of the usual elements. The cells are large, and the matrix (cell walls) small in amount, so that the cartilage is spongy in texture. The cells are smaller as they approach the perichondrium. The muscle fibres of the odontophore are nucleated, and are similar to tho fibres found in the heart (q.7.). The salivary glands are compound tubular glands. The walls of the tubule are composed of cubical epithelium with yellow granules in the cells. The outlines of the cells are difficult to make out. The salivary ducts likewise are ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA, 611 lined by cubical epithelium. Both tubules and ducts are supported by a base- ment layer of connective tissue. The ducts enter the pharynx towards its anterior end, and where they do so there is a large mucous gland, the cells of which, however, are largely supplied with the yellow granules found in the salivary glands. The pharynx is a very complicated structure, and its fuller investigation is left to the physiological part of this research. In the anterior part there are two distinct folds from the dorsal wall; the lateral chambers are continued into a pouch over either shoulder. These folds, along with others on the ventral wall, are continued into the crop. The entire pharynx is lined with columnar epithelium. The crop is thick-walled, but in reality the thickness is due to the presence of an enormous number of long compound tubular follicles, much resembling those found in the large intestine of a mammal. There are two very distinct longitudinal folds running from one end of the crop to the other on the ventral wall, and also one pretty definite fold on the dorsal surface. Each of these folds has secondary longitudinal folds on itself. Further, the wall generally is thrown into transverse folds, which are arranged like a series of leaflets across the intervening spaces. On these folds are developed the follicles above- mentioned. The follicles are lined by elongated cubical or columnar cells, two or three layers deep. The superficial layer is composed of pear-shaped cells, which are filled with granular protoplasm. The larger cells contain rounded granular masses of a highly refractile nature. These masses are often placed in a vacuole, and are apparently shed into the lumen of the follicle. The cells spring from a basement membrane of connective tissue cells, and there is a lymph space between every two follicles. These spaces communicate with the spaces in the connective tissue surrounding the glandular stomach, and con- sequently with the circulatory system. The liver, as already stated, is a compound saccular gland, irregular in form, and filling up generally the spaces between the glandular stomach, the true stomach, and the various coils of intestine. It consists of a framework of connective tissue, covered by secreting epithelium. The epithelium is one layer deep, and is extremely difficult to make out, so full is the whole tissue of biliary secretion. When the débris is washed away, usually the epithelium is also removed. When found, it is seen to be composed of delicate columnar or cubical cells, without evident cel] wall, and filled with the minute droplets or granules of which the biliary secretion is composed. The cells are not unlike goblet cells in form. There are usually to be seen some minute cells between the bases of these larger cells, which probably replace the larger cells when destroyed. The bile is apparently poured into the glandular stomach by a number of ducts. A fortunate section may show the opening of one of these ducts (Pl. CLIIL. fig. 71). The ducts open between the bases of the two 612 R. J. HARVEY GIBSON ON THE follicles, and is lined by nucleated squames. Apparently the liver tubules open into a single lobular duct, which passes between the irregular lobes into which the liver is divided. There does not appear to be a common bile duct. The stomach proper is a large sac, with a very thin non-glandular wall. The epithelium is often ridged, but the arrangement of the ridges is not constant. The epithelium is very beautiful columnar, ciliated two or three layers deep, The wall is composed of the usual muscle (non-striated) and connective tissue. There are abundant blood spaces in the gastric wall. The entire alimentary canal is lined throughout by columnar ciliated epithelium one layer deep, but with young cells inserted between the bases of the superficial large cells. The alimentary canal has, in various parts, the power of secreting in its interior a whitish rod. The nature of that structure will be discussed in the physiological section, with the subject of secretion generally. Tlie rectum is often ridged and papillose, in a manner similar to the rectal — papilla. The muscle is circularly arranged, and the faeces escape in masses more or less like strings of beads. The cilia of the alimentary canal must be eminently useful in preventing obstruction in the course of a canal of such length. The rectal papilla, which projects a variable distance from the anterior edge of the visceral mass on the right shoulder, is composed of a thick layer of circularly-arranged muscle fibres, thrown internally into ridges and papilla, the whole interior being covered by columnar ciliated epithelium. The cilia are very long, and the cells very distinct and perfect. They are arranged ina single layer. The papillae are in most cases compound, and they, assisted by the cilia, no doubt prevent the entrance of infusoria and other small creatures into the rectum. The alimentary canal and its connected glands have received less attention than any other part of the animal. With the exception of Cuvier (/oc. cit.) no one has done anything towards unravelling the apparently endless coils in which the intestine lies. The dissection is attended with great difficulty, not only on account of the extreme tenderness of the intestinal walls, but also on account of the intricate way in which the coils are intertwined, and the inti- mate connection subsisting between them and the liver, right kidney, and con- nective tissue supporting these organs. Out of over a score of limpets, which the author dissected with a view to the untwining of the alimentary canal, he was successful in only one case ; and it measured over 14 inches in length, the antero-posterior diameter of the animal itself being 21 inches. Cuvier’s figure errs in showing far fewer coils than there really are; he excuses himself by saying that the directions in which it twists are “assez inutiles & décrire!” The stomach also is inaccurately drawn. The buccal mass, its cartilages and ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 613 muscles, are described and figured by Geppss (7rans. Zool. Soc., x. 485). TLaAn- KESTER (Ann. and Mag. Nat. Hist., 1867) confirms Cuvier’s discovery of a crop of salivary glands, and says they (the salivary glands) open into the buccal cavity by four ducts. Datu (Amer. Jour. Conch., 1871) figures and describes the radula ; as does also Gray (Sys. Distrib. of Mollusca in Brit. Mus.). 3. Circulatory System.—The circulatory system consists of a branchial vein and veinlets, a heart, and two efferent vessels. The branchial vein is easily seen in fresh specimen as a large clear belt beneath (ventral) the circle of gill lamelle, when examined in section. It cannot be distinguished from a large lacuna. No special lining of epithelium is visible; its walls are composed of connective tissue. Crossing it at reeular intervals can be seen clear veinlets, which however do not open into the branchial vein. These veinlets spring from the mantle skirt beyond the bran- chial vein,—.¢., nearer its edge,—and open into lacune at the origin of the gill lamelle. From the gills again arise veinlets (Pl. CLI. fig. 38, ¢), which open into the branchial vein (Pl. CL. fig. 28). The branchial vein sur- rounds the entire mantle skirt, and the ends unite to form one vessel, which passes over the left shoulder to enter the pericardium at its extreme left corner. The vessel, as it passes--round the pillar-like termination of the circular muscle, becomes surrounded by fibres of muscular tissue, which are continuous with the fibres of the auricle into which the vessel immediately opens (Pl. CLI. figs. 41 and 43). The pericardium, which is continuous with the visceral integument, but thicker, is composed of very tough connective tissue, to which muscle fibres are attached on its inner aspect for the support of the heart. It is lined internally with squamous epithelium, often scarcely visible owing to its thinness. The heart consists of two chambers, an auricle and a ventricle. The | auricle is large, and very thin-walled. It is attached to the pericardium at _ some points, especially in front. The attachment at that point is extensive, _ and the writer has not been able to convince himself that no communication _ exists between the auricle and the very vascular cephalic portion of the mantle. | He has not been able to force any injection into the auricle from the lacune, | nor has any injection passed into the lacunz from the heart, so far as he can _ make out. It is possible, however, that further injection experiments, which he | purposes trying, may lead to different results. [These experiments the author has since made, with the result that he feels convinced that the mantle in the | head region acts as an accessory respiratory organ, and that the blood from | that area enters the auricle by openings in the “attachment” referred to. ] |The auricle is very distendible. It opens into the ventricle, which lies be- i neath it, by a slit which is guarded by muscle fibres rather curiously placed. |The fibres are continuous with others which form a network inside the 614 R. J. HARVEY GIBSON ON THE ventricle, rendering it more or less of a sponge. From the arrangement of the muscle fibres round the auriculo-ventricular opening, contraction of the — ventricle must bring about contraction of these muscle fibres, and cause — occlusion of the opening, thus preventing regurgitation (Pl. CLI. fig. 44). The ventricle is practically a sponge of muscle fibres. It is oval, and more or less pointed in shape at the ends, where it opens into two aorte. The long axis of the ventricle runs transversely,—that is, from right to left. The left aorta, or efferent vessel, passes into and supplies the circular muscle. The right, after passing out of the pericardium at the posterior right-hand corner, breaks up and opens into a very perfect system of lacune. Although the writer has made many injections with carmine gelatine in fresh specimens, — he has never been able to trace the vessels beyond a very short distance, The right efferent vessel runs beneath the rectum. ; The wall of the auricle is composed of diagonally arranged belts of musclé which are held together by single nucleated muscle and connective tissue cells. The fibres seem embedded or covered by a connecting mem- brane with small nuclei scattered in it, which may represent squamous epithelium (Pl. CLI. fig. 39). The ventricle has a similar structure, but— the muscle fibres cross and recross in the interior of the ventricle. The muscle fibre of both auricle and ventricle is composed—the auricle partly, the ventricle wholly—of a species of striped fibre common enough in invertebrate hearts. The transverse striation is not very distinct, and it gives the individual fibres rather a granular appearance. Bundles of fibres are enclosed or wrapped round by nucleated connective tissue cells (Pl. CLI. figs. 39 and 45. The blood corpuscles (Pl. CLI. fig. 42) are colourless and ameeboid. — They appear something like spiny balls; though here and there flatter, more irregular corpuscles are visible. Each contains one or more nuclei, and is composed of granular protoplasm. When a coagulum is formed, the pseudo- podial processes anastomose, and the clot under the microscope resembles a plasmodium of Monobia. With the exception of Cuvirr’s (loc. cit.) brief remarks on, and rather meagre drawing of, the heart, and WiLLIAms’ reference to the structure of the blood corpuscles (quoted by Datu in his paper on “ Limpets” in the Amer. Jour. of Conchology, 1871), the writer has been unable to find any observation of importance on the circulatory system. LAnKeEstTEr (art. ‘“ Mollusca,” ney. Brit., 9th ed.) makes a brief reference to it, but does not enter into any detail. — 4, Purificatory System.—(a) Respiratory System.—The functional gills are in the form of lamella, arranged round the inside of the skirt of the mantle. They are morphologically processes of the mantle. They are attached to the mantle in an oblique manner, so that a transverse (7.¢., vertical) section may cut through ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 615 two or more lamellz. Under the low power they appear as flattened pockets more or less triangular in form, with a base attached to the mantle, and with the apices projecting into the valley between the mantle and the foot (Pl. CLI. fig. 38). The structure of the mantle and of the gills is so similar, and since, as shall be afterwards shown, the mantle is also respiratory in function, it may be best to describe them together. Under the low power (Pl. CL. fig. 24) a vertical section shows the mantle to be attached to the circular muscle just where it springs from the shell, and to extend as a plate thickened in its outer third, and having certain processes springing from its ventral surface, which are vertical sections of gill lamelle. The entire surface of the mantle is covered by epithelium, which is in many places greatly wrinkled. The mass or body of the mantle consists of connective tissue and muscle, with large and small lacunar spaces. The lamelle are also hollow, and their opposite walls are connected by transverse bands of tissue. When the epithelium is examined under a high power, it is found to be columnar, but presenting variations in structure at different parts. The epithelium over the dorsal surface of the mantle is low columnar, with large nuclei. Towards the attachment of the circular muscle it becomes squamous, which again becomes continuous with the dense epithelium covering the surface of the circular muscle. Outwards, the cells become longer and more tapering. They are arranged in fan-shaped masses owing to the corruga- tion of the surface. The tapering ends (Pl. CL. fig. 25) are individually attached to the fine ends of transverse muscular fibres, while the free ends, which are more granular than the bodies of the cells, are covered with a continuous homogeneous cuticle. Just beneath the epithelium, and separat- ing the fine tapering extremities of the cells from one another, lies a layer of muscle which runs in a circular manner round the mantle edge, 2.¢., in vertical section the ends of these fibres are cut across. These fibres are extremely close to the epithelium, and are not separated from it by any base- ment membrane or connective tissue. Beneath this layer, and closely applied to it, is another layer, which is arranged vertically, ¢.¢., parallel with the long axis of the section, in which they are seen as strands. The transverse fibres run between these fibres, crossing them at right angles, to be attached to the tapering ends of the epithelial cells. Beneath that layer there is a quantity of connective tissue of loose texture, which is succeeded by another but much thicker layer of vertical muscle fibres, which is prolonged downwards to the very edge of the mantle skirt. At the edge of the mantle the epithelium becomes low and cubical, and is frequently pigmented, the pigment being deposited chiefly as a band in the centre of the cells. There are frequent indentations on the dorsal surface of the edge of the mantle, the cells lining which are pigmented. 616 R. J. HARVEY GIBSON ON THE . The under surface of the mantle differs in many respects from the upper surface, and resembles the structure of the gills so markedly that no doubt it is to be looked upon as functionally a respiratory organ, just as the gill lamellee are to be considered as morphologically processes of the mantle. The epithelium covering the under surface of the mantle and the lamelle is also columnar ; at the tip it is regular and low; over the thicker part of the mantle the cells are very small and crushed, and the columnar structure is not always evident. Their outlines on surface view are ragged, and their free ends are embedded in a homogeneous membrane. Their inner ends are also ragged, the processes being sunk in the subepithelial connective tissue (PI. CL. fig. 26). Where the mantle again thins, and where the gills rise, the cells become regular columnar, as on the dorsal surface, and spring from a muscular layer similar to but thicker than the most superficial layer mentioned, as underlying the epithelium ofthe dorsal surface. The fibres are, however, frequently oblique. Above the origin of the gill lamelle the epithelium is also columnar, and is covered by a very distinct cuticle. The muscle in this part of the mantle is arranged in a thin radial layer separated by connective tissue from the epithelium — (Pl, CL fig./27); The body of the mantle in its upper half is divided by transverse muscular bands into a series of quadrilateral‘compartments, which are lacunar blood spaces. The thicker ventral or outer part of the mantle is composed in the main of connective tissue and muscle with scattered nerves, forming a dense network in which, however, there are lacunze—one large one, which is the branchial vein, and several of smaller size. The whole mantle is well supplied with nerves, There are usually five or six branches, which run at uniform distances round the mantle skirt. Each is enclosed in a connective tissue sheath, and each divides up into fibres and fibrillz, which are distributed to the muscular fibres. Occasionally a specimen is found in-which the branchial vein is enormously swollen. In such cases, the tissue of which the mantle is composed can be studied to much better advantage (Pl. CL. fig. 28). The connective tissue corpuscles are specially well developed (Pl. CL. fig. 29). The free part of the mantle skirt over the head is similar in structure to that just described. The membranous portion has a structure like that of the visceral integument. It is composed of three layers—a superficial pigmented layer composed of cubical cells, a middle layer of connective tissue and a few muscle fibres, and a deep layer of cubical cells similar to those of the visceral integument (q.v.). The middle layer contains many lacunar blood spaces (Pl. CL. fig. 20). Each gill lamella is composed of two flattened plates of connective tissue, with a few muscular fibres connected by transverse bands of connective tissue ‘Pl. CL. fig. 30). A single layer of columnar epithelium covers over each - ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 617 side of the lamella. These cells have large nuclei, and a comparatively thick cuticle. The cells are relatively far apart, the spaces between the cells being filled probably with intercellular substance, possibly with sea water. The pro- toplasm of the cells is clearer, but with larger granules in the superficial than in the basal portion. The nucleus lies in the basal portion. Towards the free extremity of the lamella the cells are more flattened and more vacuolated, and the cuticle is not so distinct. All parts of the lamella and the ventral face of the mantle not occupied by the muscle and connective tissue frame- work above indicated are filled by a network of delicate fibres and films, the cavities in which are lacunar blood spaces, and are filled with blood corpuscles, &c. In the basal portion of the lamella the muscle which underlies the epithelium may be seen to be continuous with the muscle of the mantle. At intervals along the mantle edge there are to be found papille, probable tactile in function, sunk beneath the surface. The papille are on an average about °35 mm. long, and about half that in breadth. They are conical in shape (Pl. CLI. fig. 31), and spring from a broadened base. They lie in pits, which are sunk beneath the surface about half a mm. The pits are slightly broader than the papillz, and have a narrow outlet to the exterior. In some sections the papillee can be seen cut tangentially when it is seen to be completely surrounded by the mantle tissue. The walls of the pit and of the papille itself are covered with epithelium, which is continuous with the epithelium lining the dorsal and ventral surface of the mantle. In Patella vulgata they are about 100 in number, arranged apparently in a single row. The epithelium of the dorsal wall of the mantle, just before it bends in- wards to form the pit, is very regularly columnar. The cells are widely separated by cement substance (Pl. CLI. fig. 32), which spreads out over the surface to form a cuticle, with which the free ends of the epithelial cells are fused. The nuclei are oblong. The epithelium covering the pit walls and the papilla is very irregular. The cells are widely separate and irregularly columnar. The surface of the papilla is much corrugated, and the epithelium is thus thrown into folds which run circularly round the papilla. The epithelial cells are attached by fine processes to the subjacent tissue (Pl. CLI. fig. 33). The centre of the papilla is composed of muscular fibres running longitudinally in the papilla, and spreading in a fan-like manner, so as to unite with the epithelium with their ultimate fibrille. The muscle fibres are continuous with those of the mantle. The very centre is occupied by a large nerve. There is a nerve plexus, more or less distinct at the root of the papilla. The papilla lies nearer the ventral side of the mantle, and the inside wall of the pit on that side is lined by squamous epithelium. (6) Renal System.—The kidneys (nephridia) are two in number, right and left. Their position and relationship have been more fully worked out than VOL, XXXII. PART III. aK 618 R. J. HARVEY GIBSON ON THE most other parts. There are, however, points in their anatomy and histology which do not appear to have received sufficient attention. x The left nephridium is by far the smialler of the two, and occupies the triangular space between the pericardium and the terminal portion of the rectum. It is bounded above by the visceral integument, and beneath by the dorsal wall of the subanal portion of the left nephridium; to the right it is bounded by the wall of the rectum. ( The left nephridium communicates with the pericardium by a minute canal. On laying open the pericardium, the opening of this canal may, in specially large limpets, be seen (Pl. CLI. fig. 36). The one from which the figure is taken was about 24 inches long with the shell removed. A split bristle was inserted into the aperture, and on dissection was found to have penetrated into the cavity of the left nephridium. The pericardial opening was situated just beneath the attachment of the auricle, and very near the front wall of the pericardium. It lay almost in front of the much larger opening of the right nephridium. The left nephridium communicates also with the exterior by a papilla which lies to the left of the anal papilla. The left nephridium itself consists of a sac whose walls are folded and ridged to an enormous extent, , $0 that the central cavity is broken up into a series of diverticula. The central cavity remains continuous with the duct into the pericardium on one side and to the exterior on the other. The canal leading from the pericardium to left kidney is lined by squamous epithelium continuous with the epithelium lining the pericardium. ‘Towards the cavity of the kidney itself the squamous epithelium becomes cubical and then ciliated, and contains granular concretions. The cilia are exceedingly difficult to preserve, and only a cell here and there showed the cilia at all satisfactorily. | The author has not been able to see the “triangular piece of tissue,” de- scribed by CUNNINGHAM as functioning as a valve at the opening into the kidney but his sections may not have been in this respect so favourable. The canal is surrounded by a quantity of connective tissue and nonstriped muscle, by the contraction of which it may be possible to occlude the canal altogether. The valve under such circumstances seems to be rather superfluous, though the writer is not prepared to say it does not exist. The folded wall of the ki is composed of connective tissue containing a large quantity of nonstriped muscular fibre. In the connective tissue there are a large number of lacunar blood spaces; in short, as well put by Lanxesster, “the sac is practically a series of blood-vessels covered by renal epithelium.” The renal epithelium is in some points difficult to make out in its structure. It has been described as consisting of ciliated nucleated columnar cells containing small dark-coloured concretions. So far as the author has been able to make out from a study of the ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 619 epithelium in the fresh condition and in section, the connective tissue of the folds is covered by epithelium which is in several layers (Pl. CLI. fig. 35). The lower cells are rounded or polygonal, and present a homogeneous protoplasm crowded with granules of a light green or brownish tinge. A nucleus may here and there be distinguished, but, as a rule, the density of the protoplasm, and the manner in which it is filled with concretions, prevents it being possible todo so. The upper cells of the epithelium are much larger (Pl. CLI. fig. 37), and present a large number of vacuoles. These cells are ciliated; and it has been possible in some sections to make out distinctly the cilia, although in by far the most cases they could not be made out. They are, however, visible in the fresh condition by teasmg. As stated by Von JHERING to occur in Tethys, and as suggested by CunnINGHAM in Patella, probably the process of secretion is the absorption from the blood in the lacunar spaces in the walls of the diverticula of the urinary matters, the presence of which in the cells causes them to be vacuolated. Probably, as the lower cells become so filled, they come to the surface, aud burst into the lumen of the gland, where they appear as granular débris, composed partly of the remains of the epithelial cells themselves, partly of the concretions which they contained. The writer thinks he has been able to make out the successive stages in this process in sections which were found to show best mounted in balsam (Pl. CLI. fig. 37). (The subject will be referred to in detail in its proper place in Part II.) The epithelial layer varies in thickness at different points. On surface view the polygonal outlines of the cells could be distinctly seen, and in sections mounted unstained in balsam the separate cells were perfectly distinguishable. The right nephridium is of far larger size than the left nephridium. It forms a large sac much darker in colour than the left kidney, and extending round the viscera from almost the median line above quite to the median line below, where it ends abruptly in a straight edge. It encircles the posterior part of the genital gland, and rises over the coils of the alimentary canal behind. It ends at the posterior part of the superficial coil of the intestine. In front it is bounded by the anterior body wall, but passes in the form of a long tongue behind the rectum, being bounded in that region behind by the anterior part of the superficial intestinal coil. On dissection it is found to send a corresponding tongue beneath the rectum (the “subanal tract” of LANKESTER and Bourne), which is like the superficial tongue irregular in outline. Like the left kidney, the right has two outlets—one to the exterior and one.to the pericardium. The canal opening to the exterior opens at the right renal papilla situated to the right of the anal papilla. The opening into the pericardium can be easily made out in a large specimen from the pericardial aspect. It lies beneath and slightly behind the opening of the left kidney, and appears when viewed from the interior of the pericardium as a longish pear-shaped slit lying 620 R. J. HARVEY GIBSON ON THE horizontally, the broader end being anterior. The duct connecting it with the cavity of the kidney is comparatively short and wide, and like that of the left kidney is lined by squamous epithelium, and surrounded by connective tissue and muscle. The duct soon opens into the subanal tract of the right nephridium, and then becomes lined by granular ciliated epithelium similar to that found in~ the left kidney. The histological structure of the right kidney is similar in all respects to that of the left, but the cells are filled with granules which are much darker in colour, though they can scarcely be said to be more numerous. While the left nephridium partakes more of the nature of a sponge, the right is rather a sac with plaited walls (Pl. CL. fig. 34). With regard to the comparative structure of the two kidneys, the author is inclined to think that the substances which the right kidney secretes from the blood are chemically different from those secreted by the left. The degree of solubility in certain reagents of the granular matter of the two kidneys is different, and the granules are much darker, in addition to being more numerous in the right than in the left. This subject will, however, be gone into in detail in the physiological part of the work. Cuvier (loc. cit.) asserts that the laminze dependent from the mantle are gills. BLAINVILLE denies this, and thinks the mantle over the neck is respira- tory in function, owing to the number of vessels found there. ADAMSON, Mitne-Epwarps, and Gray support Cuvier’s view. As above shown, both views are to be accepted as true. Dawn (Amer. Jour. of Conch., 1871, 268) strangely enough, says that the cordon of gills is uninterrupted; an undoubted interruption does take place at the point of entrance of the branchial vein over the left shoulder (PI. CLI. fig. 38). Lanxesrer (Ann. and Mag. Nat. Hist., iii. p. 20, 1867), showed that Patella had two distinct kidneys, one of which, he was at that time able to show, opened into the pericardium. The opening into the right kidney was subsequently discovered by LaNKESTER and Bourne, and the existence of the subanal tract pointed out (Ann. and Mag. Nat. Hist., vii. 188. ). Doubt being thrown by various observers upon certain points in LANKESTER'S description, more especially on the connection between the left kidney and the pericardium, the subject was reinvestigated by CunnincHAm (Quart. Jour. Mic. Science, xxii. 369), who further described the form and structure of the renal organs, and confirmed LANKESTER’s account. WILLIAMS’ account of the structure of the branchie (as quoted by Dat in Amer. Jour, Conch., 1871) the author is able to confirm and extend; the author found, however, no indi- cation of the cilia mentioned by WitLIAMs as covering the branchiz ; nor are they, indeed, to be expected there, since the laminz are really outpushings of the mantle wall, and not morphologically true gills, as in the cited case of the gill plate of Anodon. 5. Connective Tissue System.—The connective tissue of Patella does not ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 621 for special mention. It consists of the usual elements, viz., connective tissue fibres, connective tissue cells, and elastic fibres. These last are few in number, ‘and are never so distinctly definable as in the Vertebrata. Many amceboid cells are also found among the connective tissue fibres. These are usually larger than the blood corpuscles, and have long branched processes. The presence of connective tissue has been indicated, and its general features have been pointed out under the different organs in which it occurs. Muscular System.—The general muscular system, comprising the muscular fibres entering into the structure of the various organs, is described under the different sections where these organs are described. The special muscular system includes (a) the muscle of the head and neck, (b) the circular muscle connecting the foot and the shell, &c., and (c) the muscle of the foot proper. (a) The muscle of the head and neck is arranged in three layers over the dorsal surface, from tentacle to tentacle, a superficial transverse, or circular, layer, a middle longitudinal with numerous oblique fibres, and a deep transverse layer. These layers are continuous with the muscle bands composing the foot and circular muscle, and fibres from them pass up into the tentacle. On the ventral aspect the middle layer is usually wanting, though a few strands of oblique fibres are occasionally present. The outer and inner layers also are much thicker. | (6) The circular muscle at its origin from the shell is composed of a number of plates arranged vertically, and having their long axes parallel with the surface of the body. Their free ends where they spring from the shell are covered with a very dense layer of epithelium, which is in direct contact with the shell. The epithelium is cubical, and so closely packed that the general appearance is such as to suggest that the ends of the muscle fibres are them- selves in contact with the shell, and that the epithelium is really only the denser terminations of the muscle fibres (Pl. CX LIX. fig. 6). If the epithelium covering the free part of the mantle in the head region be examined, the cubical nature of the epithelium is there clearly to be made out. The inner ends of the cells are serrated in a manner similar to the epithelium in many other parts (Pl. CL. fig. 18). The free ends are covered by a thin cuticle. The cells are continuous on the one hand with the epithelium covering the dorsal surface of the visceral integument, and on the other with that of the dorsal surface of the mantle skirt (Pl. CL. fig. 20). The muscle plates descend vertically, branching and spreading in a fan- shaped manner, so as to cause the circular muscle to be twice the breadth at its union with the foot as it is at its origin from the shell. The outer lamelle | pass directly downwards, the inner lamellz curve round, and are continuous | with the muscle of the foot proper. These bands of vertical muscle are separated 622 R. J. HARVEY GIBSON ON THE by thin plates of oblique or circularly arranged muscle, which almost entirely take the place of the vertical muscle towards the exterior of the foot (Pl. CL. fig. 19). The fibres there are fine, and are enclosed in bundles by strands of connective tissue. (c) In the foot proper, towards the margin there is an open connective tissue network, with variously arranged branching muscle fibres scattered through it, many of which are in connection with the inner ends of epithelial cells by fine processes. The upper portion of the foot, which forms the floor of the visceral _ sack, is composed of the horizontal or oblique plates of muscle continued from the circular muscle. The ventral portion is composed of a network of con- nective tissue fibres, amongst which are found a large number of horizontal, vertical, and oblique muscle fibres. u The connective tissue is dense on the ventral surface, especially just beneath the layer of epithelium. The cells of the epithelium are continuous with those of the side of the foot, but are much crushed, and often wanting in section. There are no glands of any kind in the foot. | In the head region, where there is no circular muscle, the muscle fibres which sprung from the shell are continued into the free skirt of the mantle (Pl. CL. fig. 20). _ The individual muscular fibres of which the bands of muscle are made up, are of the nonstriped variety. ach cell is a very long fibre, often as much as 4 of an inch in length, while the breadth is about z455 of an inch. The fibres do not branch, but are collected in fasciculi with a small amount of cement substance between. ach fasciculus is surrounded by a small quantity connective tissue. The fibres themselves are perfectly homogeneous or faintly fibrillated (Pl. CL. fig. 21). Epidermal System.—The visceral dome is entirely covered by an integuiitlll which is easily detachable, and which is composed of two or three layers according to the position. . Externally (Pl. CXLIX. fig. 4) is a layer of dark pigment cells, then a layer of connective tissue, and internally (in those parts where it covers the nephridia) a layer of light pigment cells. : The external pigmented cell layer consists of a single layer of tabular ot cubical cells, each containing a round or elliptical nucleus, with one or two nucleoli. On vertical section, the outlines of the cells can be distinctly made out, but they are not so easily seen on surface view. In such a surface view as that represented in Pl. CXLIX. fig. 5, the nucleus is seen to be surrounded by a quantity of pigment in the form of rounded black granules. In other situations — the granules do not surround the clear nucleus, but lie between it and the upper part of the cell, which is hyaline in appearance, but possesses no cuticle. As the edge of the dome is reached, the pigment is wanting, and there appears ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 623 over the cells a delicate homogeneous highly refractile cuticle. Just before the circular muscle, the cells for a short distance become spindle-shaped, and lie on their sides (Pl. CX LIX. fig. 6). The fine processes of these cells fuse with the cuticle on one side, and with the subjacent connective tissue on the other. Over the circular muscle the cells are cubical and densely packed, and set directly on the ends of the muscle fibres. Over them there is a tolerably distinct cuticle. These cells are continuous with the epithelium of the dorsal surface of the mantle. Where the pigmented epithelium is absent, as at the top of the dome, there is a layer of squamous epithelium forming a superficial covering to the middle layer of connective tissue. The second and main layer of the visceral integument consists of a feltwork of connective tissue fibres and branched connective tissue corpuscles. A few fibres of a more highly refractile nature may be seen which are probably elastic in their nature. The middle layer is divisible into two chief layers, one of which allies itself to the superficial pigmented epithelium, the other to the deep pigmented epithelium when that layer exists. Hach layer is composed of several finer layers separable by pressure or teasing. The fibrils of which each layer is made up are extremely fine, and are united by a gelatinous and in some places eranular matter into thin films. Connective tissue cells and nuclei are scattered irregularly among the fibres. The third layer consists of a single layer of large cubical cells which are polygonal in outline on surface view (Pl. CX LIX. fig. 7), and contain nucleus and nucleolus, and a large number of greenish-yellow granules. These cells really form the superficial layer of the right nephridium, but are usually found adherent to the visceral integument when that is removed. The author has not been able to make out any squamous epithelium on those parts of the inner surface of the integument not covered by this pigment layer. The integument of the side of the foot (Pl. CXLIX. fig. 8) is composed of cells similar to those found on the tentacle. Near the origin of the mantle the cells are low columnar ; they increase in size as the lower edge is approached, and on the lower half they are thrown into ridges as in the tentacle. The cells are there very long, with nuclei near their centres, and with a cuticle externally. The upper part of the side of the foot sometimes bears permanent ridges, composed of outpushings of subepithelial tissue, covered by columnar cells, much longer than those covering the side of the foot in that region. The dense layer of connective tissue found beneath the epithelium in the tentacle is in this situation very scanty; and beneath it is a series of vacuoles, or lacunar spaces, between the trabecule which pass from the general muscle of the foot to be connected with the ends of the epithelial cells. The epithelium is continued round the edge of the foot for a short distance, in the form of long columnar cells, which soon, however, become modified into 624 R. J. HARVEY GIBSON ON THE a granular crushed layer, very irregular, and resting on a dense layer of con- nective tissue. The epithelium, at least in sections, most commonly falls off, and leaves the subjacent connective tissue exposed. ~ Over the head and neck the columnar epithelium is composed of large cells which have distinct nuclei. The subepithelial connective tissue layer is very evident, and fibres are seen passing through it to the epithelial cells (Pl. CXLIX. fig. 9). On surface view the cells present a granular mosaic. Protective System.— Under the head of protective system may be classed the mantle, whose function in this relation is to afford protection to the functional gills and the shell. The mantle has already been described under the respinteeias system. The shell, as has been already stated, is dome-shaped, and has ventrally an oval outline (Pl. CL. fig. 22), the narrow end being anterior. The apex of — the dome is blunted, and the outline of the sides is curved. The apex of the dome is nearer the anterior end (Pl. CL. fig. 23). Externally two series of lines are visible on the earns a radiating series from the dorsal apex to the edge; () a series concentric with the ventral edge. The lines are of various degrees of coarseness, and some are nodulated and tuberculate. | Internally, the radiating lines are represented by bands of blue and yellow — of variable shade and width. These bands are crossed at intervals by con- centric bands of dark colour more or less distinct in different individuals. The rim of the shell is chisel-shaped, the bevelled side being inwards. The — shell rapidly thickens from the edge, and then maintains a tolerably constant thickness throughout. The edge is sharp and notched. The pallial line is visible as a pale belt of variable width (usually } inch) running in a sinuous manner along the shell about 4 inch from its edge (Pl. CL. fig. 22). Inside the mantle line at a short distance is the impression of the attach- — ment of the circular muscle connecting the foot and the shell. The impression is divided, as is the muscle itself, into more or less distinct areas. The breadth — of the belt is tolerably constant (usually about + inch.) The most anterior muscle impression, one each side, is larger, and rounded anteriorly. The inner border of the belt is more irregular than the outer. id Within the impression of the circular muscle there is a belt of irregular breadth and outline, generally broadest posteriorly. The belt marks the attachment of the integument of the visceral dome. The impression expands in front, and fills up the space left vacant by the absence of the circular muscle impression. That space is about one-sixth the entire circumference of the shell at that level. The remainder of the concavity of the shell is not touched by the derm of the visceral dome. It is usually white, and lacks the lustre of the ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 625 other parts of the inside of the shell. The entire shell is translucent, though the portion round the apex tends to become opaque. ~The microscopic structure of the shell is extremely difficult to determine accurately. If it be soaked in strong nitric acid for some time, a series of lamine may be peeled off, each lamina being apparently made up of a net- work, or meshwork, of very fine fibres. The superficial lamine have much wider meshes than the deeper lamine. A vertical section through the entire shell presents three layers, the middle layer above extending from edge to edge (Pl. CLII. fig. 46). The inner layer is found only beneath the dome, and, under the low power, presents itself as a granular, more or less structureless film, occupying mainly that portion of the shell not touched by the derm of the visceral mass. The outer layer, which also appears granular, carious, and pigmented, extends over the entire surface, save the extreme borders. This layer, when examined under a higher power, is found to be perforated in every direction by minute canals (Pl. CLII. fig. 49). These canals are not more than 79, of an inch in diameter, and branch and anasto- mose to such an extent as to give that part of the shell the appearance of yellow elastic cartilage, or the framework of a sponge. The canals are much more abundant towards the surface. The canals break into one another, and thus form larger canals varying in size according to the number of small canals which have gone to form the larger. The small canals are long, unbranched, and straight, and much fewer in number as the middle layer is approached. Indeed, there can scarcely be said to exist three distinct layers; the inner and outer layers being simply the middle layer under different conditions of growth or decay. The middle layer itselfis composed of long, branching, polygonal “ cells” or rods, whose long axes lie at right angles to the outer surface of the shell. Each rod is made up of a large number of febrils, lying parallel to the long axis of the rod, and the rod has in consequence a striated appearance. In section the rods are polygonal, round, oval, or irregular ; they are separated from each other by a cement substance, which forms the reticulum left after the removal of the mineral matter by the nitric acid. This substance, which is fibrillated, is stained yellow by the acid, and is therefore probably animal in its nature. These rods are crossed, especially towards the border of the shell, by lines indicating _ the successive laminz of deposition. The arrangement of the various elements will be best understood by reference to the figures (Pl. CLII. figs. 46-49). q The inner and middle layers are perfectly colourless ; the outer layer has yellowish-green and brown pigment granules deposited in the canals by which it is perforated. The bands of bluish-grey, usually seen on the inner surface of the shell, are therefore not due to pigment, but probably to the peculiar arrangement of the rods, and the effect of light upon them. On the inner VOL. XXXII. PART III. OL 626 R. J. HARVEY GIBSON ON THE surface of the dome, however, at the very apex, the inner layer becomes im- pregnated to a slight extent by pigment granules. It is very doubtful whether the caries on the surface layer of the shell be a natural condition ; the author is inclined to think that it is due to a parasitic growth, and that the pigment is foreign matter, either belonging to the parasite or introduced from the surrounding water into the canals formed by it. This view is supported by the fact that in some places the shell is much more decayed than elsewhere, and that some shells, though younger, are more carious than others which are obviously of older growth. The shells examined were of course not fresh, and so any possible inhabitant of these tubes could not be detected. In the physiological section of this research, the subject will be reinvestigated. Irrespective of the possible truth of the explanation above suggested, it will be interesting to know what conditions are necessary for the — formation of this caries, and what are the agents and modus operandi employed. The general appearance of the shell has been described very frequently ; indeed, in the older accounts of Patella the shell was the only part which was described with anything like completeness. CARPENTER, who, so far as the © writer is aware, alone has studied the shell microscopically, says that it consists of three layers, inner and outer layers less compact, and a middle layer of polygonal or prismatic cells. " Dau. (doc. cit.) quotes WILLIAMS as saying that “the lining membrane of the branchiz is continuous, and therefore that it is highly improbable that water penetrates into the circulatory system, as in some other molluscs.” With reference to that statement, it may be well to remember the nature of the epithelium lining the branchiz, as indicated above (vid. “ Respiratory system ”). REAUMUR mentions the existence of glands in the foot, and Born (oc. cit.) — says there are tubercles in the same organ; and these authors affirm that from these glands, or tubercles, there exudes a glue, by which the animal fixes itself _ to the rocks. ADANSoN also speaks of suckers on the pedal surface; and ADAMS (Recent Mollusca, i. 465) asserts that the cavities which the limpet not infrequently makes in some kinds of rock are made by spicula with which the ~ foot is provided. The writer has not been able to find the slightest indication of glands, either beneath the surface or in tubercles; nor has he been able to see anything that could be mistaken for a sucker or a spicule of any kind — whatever, although he made a very thorough examination of the foot, not only by superficial search, but also by many microscopical sections. 6. Nervous System.—The nervous system is exceedingly complicated, but, with moderate care, it may be dissected out in its entirety. There are altogether no less than eight pairs of ganglia; only three of these, however, are of primary importance, viz., the cerebral, visceral, and pedal (Pl. CLIT. fig. 50). ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 627 The cerebral ganglia are large irregular nervous masses, situated deep down, just at the base of the tentacles; the visceral and pedal ganglia lie close together just at the anterior edge of the floor of the visceral cavity. The cerebral ganglia are found to give off (a) nerves and (2) commissures. The nerves are four in number, on either side. (The nerves of the left cerebral ganglia only are here described, those of the right being precisely similar.) First, the tentacular nerve, which arises from the anterior left corner, and passes directly into the nuchal tentacle. This nerve very soon divides, giving off numerous branches to the muscles and skin of the tentacle. Just at its base anteriorly arises a small nerve, the cutaneous, supplying the skin of the neck and snout. Immediately behind the origin of the tentacular nerve is the optic nerve, which is not a branch (as might be supposed) of the tentacular, but is an entirely distinct nerve, going directly to the eye. The nerve divides repeatedly ere reaching the eye, and loses itself in a nervous plexus, immediately behind the retina. All these nerves spring from the outer aspect of the cerebral ganglion. On its inner aspect, immediately opposite to the origin of the optic nerve, is a small nerve supplying the muscles of the pharynx, and which may be termed therefore the posterior lateral pharyngeal nerve. In addition to these nerves there are a number of commissures uniting the cerebral ganglia to the rest of the system. The anterior end of either ganglion gives off two com- missures, one passing in front of the buccal mass, and easy to find, the other passing vertically up the side of the same, and more or less involved in muscle and connective tissue. The former is a large thick white commissure which runs in front of the csophagus, far forward. It unites the two cerebral ganglia. After leaving either ganglion the commissure is slightly swollen, | and at that point it gives off a nerve, which, since it supplies the anterior | - muscle of the pharynx, may be termed the anterior lateral pharyngeal nerve. In front the commissure gives off many small nerves which supply the lips. At the point where the anterior pharyngeal is given off a nerve loop encloses the commissure, coming from below upwards and passing backwards. It is not connected in any way with the commissure. Following now the second commissure, which springs from the cerebral ganglion, we find it mounts the side of buccal mass, and becomes united to a small ganglion lying at the side of the pharynx and on the top of the muscles of the infraradular sheet. This ganglion is one of four which lie at the angles of a square formed by the commissures which unite them, 7.¢., along either side of the pharynx. On the top of the muscles of the infraradular sheet there are two ganglia united to each other and to their fellows on the opposite side. These ganglia are the superior, anterior, and superior posterior buccal ganglia respectively. To the anterior ganglion on either side is united the end of the loop spoken of above as enclosing the cerebral commissure. The commissures uniting the 628 R. J. HARVEY GIBSON ON THE two anterior and the two posterior ganglia to each other lie between the pharynx and the muscles of the infraradular sheet. Tracing the loop above mentioned round the cerebral commissure, it is found to bend suddenly back- ward, and to unite itself with a small ganglion on a second cerebral commissure which lies beneath the buccal mass. These two small ganglia on this second commissure have been considered as inferior buccal ganglia; and, since the nerves from them supply the ventral protractors of the odontophore, they may be so named. From the posterior part of either cerebral ganglion two slender white commissures pass backwards along the sides of the neck—the exterior to join the visceral ganglion, the interior to join the pedal ganglion. The pedal and — visceral ganglia form one thick hoop of nerve matter rather than four ganglia unitedly commissures. The visceral ganglia are, as already stated, united to the cerebral ganglia by slender commissures, to the pedal by a thick short band. They give off two important nerves on either side of the body,—first, externally, the musculo-pallial nerve (which soon splits into two branches, which go to supply the branchie and mantle and the circular muscle respectively) ; and, internally, the splanchnic nerve. This splanchnic, soon after it leaves the ganglion, gives off a delicate nerve which travels back along the pharynx, and may be termed the recurrent nerve. The left splanchnic itself mounts the left shoulder, passes beneath the salivary glands, and, cross- ing the right splanchnic, gives off a minute branch to the right ctenidium; 22., — the right ctenidium is supplied by the left splanchnic. The nerve then crosses back and unites on the way with the right splanchnic. The combined — nerve gives off a number of branches to the viscera as it goes; and finally, crossing over to the left side once more, it supplies the left ctenidium. (We are indebted to SPENGEL for this discovery, and for the important suggestion that accompanies it, viz., that these ctenidia are really the rudiments of the lost true gills.) SPENGEL describes a minute ganglion, the olfactory ganglion lying near — the ctenidia ; that the writer has not been able, however, to see. ; The pedal ganglia lie between the two visceral ganglia, close together and — united by a very thick and short commisssure. They are united, as already stated, to the cerebral ganglia by long slender commissures, one for either ganglion. They give off into a slit in the muscle of the foot two large nerves | each, one of which supplies the deep muscles of the foot, the other the super- ficial muscles. Both the pedal and musculo-pallial nerves divide ultimately into a large number of secondary branches. The histological structure of the nervous system is extremely simple. The nerves are composed of fibres, each of which is a very elongated, nucleated, cell. The cell itself is band-shaped and fibrillated, nucleus oblong, taking on a deep ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 629 stain, and exhibiting a nucleolus in its interior. These fibres are collected in bundles, and among them, 7.¢., between the individual fibres, are a number of bipolar spindle-shaped cells. These cells are provided with nucleus, nucleolus, and a small quantity of granular protoplasm prolonged at either end of the spindle into long and delicate threads (CLII. fig. 51). Both cells and fibres are enclosed in a sheath of ordinary connective tissue, usually one cell thick. The nuclei of the connective tissue corpuscles and fibres are very evident, and quite distinguishable from the nuclei belonging to the nervous elements. The ganglia are composed of a framework of neuroglia of the ordinary nature (a very delicate connective tissue), with a very large number of nerve cells. The great majority of these cells are small triangular or irregular masses of protoplasm, with short branching or unbranched processes. The cells con- tain nuclei and nucleoli, and take on a deep stain. The cells are usually much more abundant towards the surface of the ganglia, and this is more especially the case with the cerebral ganglia. The cells (round) also run up the sides of the principal nerves for a short distance as a distinct layer beneath the sheath. In some places, more especially in the pedal and visceral ganglia, there is an abundant admixture of long bipolar cells. This may be owing to the almost undifferentiated nature of the ganglia and commissures in that situation. The author has not been able to ascertain definitely the connection between the cells of the ganglion and fibres of the nerve. In some positions, notably in some parts of the pedal and visceral ganglia, and also in the buccal ganglia and their longitudinal commissures, there are present a number of yellow or orange granules, which appear to be immediately within the connective tissue sheath. These give to the parts where they are present a yellowish-orange hue. Touch.—The special organs of touch are the tentacles—two in number— situated on the right and left sides of the neck. Each in its contracted condi- tion is about } inch in length, but it may be extended to from four to eight times that length. At the base they are about +4; inch in diameter, and taper to a bluntish point. When examined with a hand lens, they appear corrugated and pigmented, especially towards the tip. About 5 inch from the base, a small pit can be made out, on the outer aspect of either tentacle. The pit is filled with pigment, and has its open mouth pointing towards the tip of the tentacle. Itis ocular in function, and is described below. The tentacle consists essentially of a mass of connective tissue in which are embedded longitudinal and transverse muscular bundles. In the centre are one or more nerves. The outer surface of the tentacle is covered by epithelium, consisting of a single layer of columnar cells (Pl. CXLIX. figs. 10 and 11). 630 R. J. HARVEY GIBSON ON THE The cells are narrow and tapering. The nuclei are long, and usually contain two nucleoli and granular protoplasm (Pl. CXLIX. fig. 12). The cells are slightly swollen in the position of the neuclei. They spring from a more or less homogeneous layer of dense connective tissue, which acts as a basement membrane. The epithelial cells are connected to this layer by fine processes, which give their inner ends a serrated appearance. The connection can, however, be easily made out in their sections under a high power. The cells are not closely arranged, but leave spaces between, filled probably with cement substance, so that a greater degree of contraction and extension is thus attainable in the tentacle. The outer ends of the cells are widened some- what, and become continuous with a homogeneous and relatively thick (in the contracted condition) cuticle, which is highly refractile, stain bright yellow with picric acid, and is therefore probably elastic in its nature. The cuticle on its under aspect is lined by a layer of granular protoplasm formed apparently by the fusion of the ends of the epithelial cells. The epithelial cells become more cubical nearer the base of the tentacle. The subepithelial connective tissue layer is not so apparent at the tip of the tentacles, where the distinctly tapering epithelial cells are seen to be continuous with fibres in the mass of the tentacle. In the thicker part of the tentacle the subepithelial layer may be seen to give off fine processes, similar to those which connect the subepithelial layer to the — epithelial cells, to join the feltwork of connective tissue of the body of the tentacle (Pl. CX LIX. fig. 14). At the tip of the tentacle the connective tissue layer sehen subjacent to the epithelial layer is pigmented, the pigment being in the form of minute rounded granules. No pigment is found in the epithelial cells in that position. The muscle of the tentacle is disposed in a longitudinal manner, running from the base to the tip (Pl. CXLIX. fig. 11). The muscle fibres are arranged in — loose irregular strands, which may be seen to branch and unite again at intervals. There is a tolerably distinct layer of longitudinal fibres beneath the epithelial cells, especially on the outer aspect of the tentacle, the larger fibres being ventrally placed. There are many transverse fibres, not arranged in any definite bundles ; also a few oblique fibres. There are no circular fibres, nor are they required. The muscle fibres are of the type described under the muscular system. Connective tissue, and a reticulum of connective tissue corpuscles, fill up the rest of the body of the tentacle. ‘The connective tissue is of the ordinary type, a dense feltwork of homogeneous and fibrillated fibres against and among which lie many nucleated connective tissue corpuscles. One or more nerve branches are found occupying the centre of the tentacle. Each is made up of a bundle of very fine wavy fibres, amidst which may be seen minute red-stained nuclei. The nerves branch and give off fibrils to the bands of muscle. ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 651 On transverse section (Pl. CXLIX. fig. 12) the relation of the muscle to the connective tissue can be more distinctly seen. ‘The bands of muscle underlying the epithelium are observed as rounded areas, each surrounded and clasped by a number of connective tissue cells. Sometimes one area only is so enclosed occasionally many such are clasped by one cell, whose neucleus is seen as a bulging at one point. There are a large number of trabeculee composed of connective tissue fibres and cells which spring from the homogeneous sub- epithelial connective tissue, and passing inwards lose themselves in the general feltwork of the body of the tentacle. The transverse bands of muscle are specially numerous in the distal portion of the tentacle. The wrinkles are for the most part temporary, but there are some where the epithelium lining the valleys differs from that covering the ridges. Numerous very fine fibrils are seen among the connective tissue and muscle. As they are highly refractile, they are probably elastic in their nature. A fortunate transverse section may show the epithelial cells in surface view (Pl. CXLIX. fig. 13). They form in such an aspect a mosaic. The outlines of the individual cells are roughly hexagonal or polygonal. ‘Their ends are granular, and seem embedded in a clear membrane. Probably the cuticle is a secretion of the cells, and is therefore made up by a fusion of a number of distinct areas, each corresponding to the end of one epithelial cell. The epithelial cells them- selves are not close together. They do not touch, hence the spreading appearance presented by their outer ends on longitudinal section, and their isolated appearance on end view. The tactile papille of the mantle are described under the respiratory system. Sight.—The eye lies at the base of each tentacle, and consists of a small indentation or pouch which resembles the scar of a fallen leaf. The centre of the pouch is apparently filled with a black pigment. On longitudinal section of the tentacle, a distinct bulge is visible in the position of the eye, with a secondary bulge of lesser size below the large one (Pl. CXLIX. fig. 15). The large bulge forms the thick roof of a cave which is lined on its upper (roof) surface by pigmented epithelium. The cave is perfectly open to the exterior, and its mouth points forward. The swelling or bulge is very vacuolated, there being large oval and irregular spaces amongst the connective tissue (PI. CXLIX. fig. 15). The epithelium covering the bulge is continuous with the epithelium covering the general tentacular surface. The cells are, however, slightly longer, and are separate from each other, save near the edge of the cave, where they are more crowded together. As they enter the cave they increase in length, and again become wider apart. Among the long epithelial cells of the outer surface of the ocular swelling are to be found a few cells which spring by many processes from the basement layer, and after swelling out and containing at that point a large round nucleus, terminate among the 632 R. J. HARVEY GIBSON ON THE epithelial cells in a fine-pointed end (Pl. CXLIX. fig. 14). The epithelium of the surface is continuous with the epithelium lining the ocular pit. Just after turning the edge of the pit the cuticle becomes thicker, and then becomes split into two layers, which are farthest apart at the bottom of the pit, but which are connected throughout by a series of columnar fibres which pass directly from upper to the lower layers (Pl. CL. fig. 16). The cuticle is therefore replaced by a latticework bounded on either side by a cuticle. The fibres are straight and homogeneous. They vary in thickness from the finest threads searce visible to columns about half as thick as a columnar cell. From the outer layer of the cuticle and projecting into the cavity of the pit, are a number of very fine fibrils of variable length. They are extremely delicate, and are | often destroyed in the section-cutting. The inner layer of the cuticle, which is much thinner than the outer and not so hyaline in appearance, is continuous with the ends of long, narrow columnar cells, which are longer than those of — the surface of the ocular swelling. Their basal extremities taper to fine fibres, and become lost in a dense feltwork (often so dense as to appear homogeneous) which underlies the epithelium. The upper half of these cells is pigmented, the dark granules of pigment being arranged round the cell, not generally in — the protoplasm (Pl. CL. fig. 16a). The nucleus occupies the lower half of the cell, and is long and contains many granules. The general protoplasm of the cell also is very granular. Continuous with the subepithelial layer is a dense network of fibres and of cells, which are probably nervous. A secondary pit in the floor of the eye pit is usually to be seen, but it contains no pigment, and the cuticle has here regained its single nature and uniform thickness. Beneath the ocular swelling, — a secondary swelling is situated; a pit similar in form to that just described is present, but neither the cuticle nor the epithelium show the differentiation mentioned as occurring in the true ocular pit. The connective tissue of the ocular pit and of the secondary pit is loose, and — presents large vacuoles. (The relation of the eye to the nervous system is dis- cussed under the Nervous system.) : The most important researches on the nervous system are those of BRANDT, | SPENGEL, FRAtssh, and LAcazE DuTHIERS. Branpt (Bull. Acad. St Petersburg, 1869) gives a very full account of the nervous system, describing in detail the system of buccal ganglia. His account does not differ in many respects from that given above. He has, however, fallen into error more especially with regard to the arrangement of the visceral nerves. The recurrent nerve, also, he makes to spring from the musculo- pallial, whereas it springs from the splanchnic. SPENGEL (Zeit. f. wissen. Zool., xxxy. 382) has an important statement in reference to the arrangement of the visceral nerves, and to their relation to the ctenidia, which has already been ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 633 noted. He has also described the olfactory organs, which lie in close relation to the ctenidia. FRratssn’s account of the eye of Patella cerulea (Zeit. f. w. Zool., xxxv. 461) agrees generally with that given above for P. vulgata; the chief difference seems to be that, in Patella vulgata, the “cuticularsaum” is double. In both species the outer surface of the cuticle is provided with a number of cilia—the ‘‘ Faserchen” of Fraisst. Lacaze DuTHIERS’ investiga- tions into the nature of the auditory organ (Arch. Zool. Exper. i.) will be referred to subsequently. With reference to the sense of touch, CLARK (oc. cit.) mentions but does not describe the minute tentacles (or “ cirrhi,” as he terms them) on the mantle edge. 7. Reproductive System.—The male and female reproductive elements are developed in separate individuals. The glands are single, and pour their con- tents, when ripe, into the cavity of the right kidney, from which they escape by the right renal papilla, together with the urinary excretions. Male.—The male generative gland is a wedge-shaped, yellowish mass, lying on the floor of the visceral cavity, and having its thicker side towards the back and left side of the visceral mass. It is covered by a delicate membrane com- posed of fibres of connective tissue, covered by squamous epithelium. The gland itself is a spongy mass, less dense towards the centre. Peripherally, it is composed of a framework of connective tissue, which sends processes inwards, between which trabecule, therefore, are formed a large number of “nests” in which sperms are developed. The trabecule are covered by cubical epithelium, many layers deep, the superficial layers of which become the future sperms. The manner of their development and their general appearance is extremely like that of mammalian sperms, as described by KLEIN (Adlas of Histology). The cubical epithelium is composed of rounded or polygonal cells, variable as to size, but usually considerably smaller than a human blood corpuscle. The superficial cells are slightly pear-shaped, and are arranged in | tufts or mounds. Each cell contains a nucleus and many granules, but a cell | wall is not visible (Pl. CLIII. fig. 77). The process of development seems to be the gradual formation of a slender _ filament at the attached end of the cell (Pl. CLIIL figs. 78, 79) when superficial and in its pear-shaped condition ; probably at the expense of the protoplasm of _ the cell, the nucleus becoming the head. The appearance of the cellular tuft at | what may be termed the second stage is that of a raspberry, with the individual _ drupes separated slightly from each other. In the next stage the tuft assumes | the appearance of a sheaf of barley, the “heads” of the grain corresponding to | the heads of the sperms. The entire tuft meanwhile has been growing, so | that ultimately any portion of the gland examined shows a series of long strands | of fibre fringed and tufted with delicate plumes. If a single plume be next examined, under a higher power, it is discovered VOL. XXXII. PART IIL. oM 634 R. J. HARVEY GIBSON ON THE to be composed of a central stalk, evidently formed by the union of the several filaments of a number of heads, which are arranged around the stalk in an extremely graceful manner. Very careful focussing, under a power of 800 — diameters (after long staining), is necessary before the separate filaments can be seen (Pl. CLIII. fig. 79). Isolated sperms show themselves to be composed, as in the case of mam- malian and other sperms, of a head and tail. ‘The head is oblong, about gzg of an inch in length, and about a third of that in breadth, and apparently structureless. It takes on a deep stain with picro-carmine. The tail is very slender, being not more than 35.455 Of an inch in breadth by about zoo of an inch long. It takes on scarcely any stain after an hour’s immersion in picro- carmine ; the head, meanwhile, as already stated, becoming deeply stained of a crimson colour (PI. CLIII. fig. 80). Female.—In principle, the structure of the female generative organ is some- what similar to that of the male. Like the male organ, it is more or less wedge-shaped, and usually larger in size. It is covered by a very delicate — membrane composed of connective tissue, and covered with squames, of which latter the nuclei are the most evident parts. The gland itself is merely a bag, with a fibrous wall puckered externally and covered by a cubical epithelium many layers deep; the superficial layers of which become free, and fill the cavity of the gland as ova. The ova are of all sizes, from that of the cubical epithelial cells to spheres which can be perfectly easily seen with the naked eye. The cubical epithelium is more abundant in certain spots, which, as in the case of the testis, may be termed “ nests.” An ovum (Pl. CLIII. fig. 76) fully developed is polygonal, or, when free, rounded mass, about from ;3, to gg of an inch in diameter. It is covered — externally by a stout capsule, structureless, or vertically striated and punctured. The protoplasm is made very opaque by the presence of a very large quantity — of yolk spherules. A nucleus containing nucleolus and endo-nucleoli is always visible after staining or crushing. In the younger ova, however, it is easily seen. Historically, with the exception of FiscHer’s researches on development, very little indeed has been done towards the elucidation of the structure of the reproductive organs. In fact, any observations made on the system have been mainly as to whether ducts are present or not, and if so, whether or not the “capito-pedal orifices” are the openings of these ducts. Cuvier (loc. cit.) de- scribes and figures an oviduct, which no one since his time has been able to find, Dat thinks he has seen a duct “from the extreme left of the gland, and open- ing into the dendritic renal sac” (Amer. Jour. of Conch., 1871, vi. 271). In. another later paper, however (Proc. Acad. Philad., 1876, 239), he denies all knowledge of an oviduct ; he denies the very existence of LANKESTER’S “ capito- pedal orifices” in the first-quoted paper, but admits in the second that they are ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 635 present in some Patelliide, but denies that they occur in P. vulgata; he more- over thinks they are “ aquiferous pores.” The author’s experience is that they are present, and can be seen with the greatest of ease in all limpets; that they are, as described by SPENGEL (doc. cit.), uot “ orifices” at all (and how they could be called or thought so is to him a mystery), but rudiments of the lost true gills. Gray, in his British Museum Catalogue, says that the milt or roe lies on the right side ; the author’s experience is that in the vast majority of cases it lies on the left, although the point is of no great importance. Rosin and Lepert (Anal. de Sc. Nat., 1846) say that the generative gland was wanting in more than half of the specimens they examined. Without going so far as to contradict that statement, the writer must state that, in the examination of over 100 specimens, he never found the generative glands entirely wanting, although in some cases they were smaller in size. The animals examined were collected in April, July, October, and December. The writer found no indication whatever of any duct either from the testis or ovary, and therefore is disposed to believe that the reproductive glands must open at certain seasons into the right renal sac, and that they do not possess special ducts of their own. EXPLANATION OF PLATES. PLATE CXLIX. Fig. 1. Patella vulgata, face view (x2). v.h., visceral hump; l7.p. and 7.r.p., left and right renal papille ; a.p., anal papilla; c.m., circular muscle; ¢., tentacle; m., mouth; f, foot. Fig. 2. Dorsal view, shell removed (n.s.). m.s., mantle skirt. Fig. 3. Dorsal view, visceral integument removed (n.s.). 7., rectum ; pr., pericardium ; ct., ctenidium ; l., liver; Z.n., left nephridium ; 7.n., right nephridium ; ¢.m., circular muscle; ra., radula ; s.t., superficial coil of the intestine; g., genital gland. Fig. 4. Visceral integument (x 250), a, superficial pigmented epithelium ; 6, median connective tissue layer ; c, deep pigment layer (renal epithelium). Fig. 5. Superficial pigment layer of visceral integument ( x 500), surface view. Fig. 6. Epithelium over the circular muscle-band (x 250). a, ordinary cells; 0, transitional spindle- shaped cells; d, dense epithelium over the muscle, with cuticle ; c, muscle. Fig. 7. Deep epithelium of visceral integument, surface view ( x 500). Fig, 8. Epithelium covering the surface of the foot ( x 350). Fig. 9. Epithelium covering the head and neck ( x 500). Fig. 10. Transverse section of nuchal tentacle (x 500). a, epithelium; 0, nerve fibres; c, ventral muscle band ; d, eye. Fig. 11. Longitudinal section of nuchal tentacle (x50). d, eye; e, pigment in subepithelial connective tissue of tip of tentacle. Fig. 12. Epithelium of tentacle (x 500). a, columnar cells; 6, subcuticular layer of granular proptoplasm ; c, cuticle; d, trabecule of connective tissue passing inward from g, the subepithelial layer of connective tissue; jf, muscle fasciculi enclosed by connective tissue cells, e, Fig. 13, Epithelium of tentacle on surface view (x 500). 636 R. J. HARVEY GIBSON ON THE Fig. 14. Epithelium from the outer aspect of the ocular swelling (x 500). a, cuticle; b, columnar cells ; c, pointed short cells ; d, subepithelial connective tissue ; e, trabecule. Fig. 15. Longitudinal section of eye (x 250). a, ocular pit and retina, PLATE CL. Fig. 16. Retina (x 800). a, cuticle with two layers. 6, prisms separating them ; c, pigmented epithe- lium; d, nerve plexus. (This figure was drawn from a preparation in which the cilia were aaa ) Fig. 16a. Arrangement of pigment granules in the columnar cells ( x 800). Fig. 17. fecayane section through neck behind the origin of the tentacles. ph., pharynx; s., salivary gland; p., palate; 7., radula; m.s., muscle of infraradular sheet ; /.c., lateral cartilage ; a.c., anterior cartilage; U.p., lateral protractor; v.pr., ventral protractor; w.p., under plate; — v.tr. and v’.tr’., ventral transverse muscles ; Z.m., longitudinal muscle. Fig. 18. Epithelium covering the attachment of the mantle to the shell in the head region ( x 250). a, epithelium ; 0, subepithelial layer ; c, muscle. 3 Fig. 19. Vertical section of circular muscle (x50). a, epithelium; 0, blood vessel; ¢, vertical — muscle; d, epithelium of side of foot; e, circular muscle (deep); h, circular muscle ; (superficial); f, nerves ; g, dense connective tissue beneath the epithelium of foot. Fig. 20. Section of the mantle (x50), (see fig. 18). a, epithelium; 0, lacunar blood spaces; ¢, mantle muscle, “ Fig. 21. Muscular fibres of foot ( x 500). ; Fig. 22. Shell, with muscle, &c. impressions (interior), (n.s.). m.a., mantle attachment; c.m., circular muscle attachment ; v., visceral attachment; d., dorsum, not touched by viscera. . Fig. 23. Shell (exterior) (n.s.). Fig. 24. Radial section, mantle and gill processes (x 50). a, papilla; 0, nerve; c, efferent branchial vein; d, gill lamella; e, muscle; f, afferent branchial veins. Fig. 25. Epithelium of the dorsum of the mantle (x 500). a, epithelium; 0, circular muscle fibres; ¢, radial muscle fibres; d, connective tissue; ¢, muscle fibres connected with epithelial cells; Ff, deep radial muscle. Fig. 26. Epithelium covering the under surface of the mantle (x 250). a, surface ; 2, side view. Fig. 27. Epithelium of the mantle at the origin of gill lamelle (x 500). Fig. 28. Mantle, radial section, with Salen branchial vein (x30). a, cavity of papilla; 0, nerve | ganglion; c, lacune; d, efferent branchial vein; e, transverse trabecule; /, radial muscle ; g, afferent poeta vein. Fig. 29. Connective tissue cells of same ( x 500). Fig. 30. Part of gill lamella ( x 100). PLATE CLL Fig. 31. Mantle papilla, longitudinal section (x 100). a, ganglion and nerves; 0, nerve fibres ; c, vascular lacunz ; d, blood corpuscles. Fig. 32. Epithelium of the dorsal wall above the pit of papilla ( x 250). Fig. 33. Epithelium of papilla ( x 250). - Fig. 34. Nephridia, A, left; B, right (x50). ¢, fibrous septum; a.a’, blood vessels in the walls of the nephridia ; 2, left roel epithelium ; e, right renal epithelium ; d, cavity of right a ridium ; f, cavity of left nephridium ; g, epithelium of nephridia on surface view. Fig. 35. Renal epithelium, right nephridium ( x 250). i Fig. 36. Pericardium interior, looking towards the right shoulder (x20). a, right renal papilla; }, anus ; c, left renal papilla; d, pericardium ; e, pericardial opening of the left kidney; f, pericardial opening of right kidney; g, right aorta; h, rectum. (This figure is semi- diagramatic, and compounded from several preparations. ) Fig. 37. Renal epithelium, left nephridium. Fig. 38. Branchial vein and veinlets (x50). a, gill lamella; 6, circular muscle; c, common branchial vein ; d, afferent branchial veinlets from the mantle skirt; e, efferent branchial veinlets from the gills to branchial vein proper; f, branchial vein of right side. Fig. Fig. Fig. Fig. Fig. Fig. Fig. Fig. Fig. Fig. 60. Fig. 61. Fig. 62. . 39. . 40, . Al. . 42, . 43. . 44, . 45, . 46. . 47. . 48. . 49, ig. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA. 637 Muscular fibres of the auricle ( x 250). Pericardium (x 250). a, superficial clear membrane; 0, subcutaneous connective tissue; ¢, muscular fibres attaching auricle to the pericardium. Diagramatic representation of heart and its vessels. 0.vm., branchial vein; p., circular muscle ; b., pericardium ; 7, left renal papilla; g., anal papilla; a., auricle; v., ventricle ; d.d'., right and left aorte ; ¢., left nephridium ; ¢., aur, vent. valve. Blood corpuscles. Heart and vessels, pericardium removed. (Letters as in fig. 41.) Auriculo-ventricular valve. Muscular fibres of ventricle. PLATE CLII. Diagramatic section of shell, showing the arrangement of the lamine. Section of shell, showing the three layers and lamin. Do. do., magnified (x 50). a, upper; b,"middle; c, lower layers. Superficial layer of shell. Nervous system, semidiagramatic. ct., ctenidium; p.s.b., posterior superior buccal ganglion ; a.s.b., anterior superior buccal ganglion; 7.0., inferior buccal ganglion; ¢.g., cerebral ganglion ; ¢., eye; c.c., cerebral commissure ; ¢.p., cerebro-pedal commissure ; ¢.v., cerebro- visceral commissure; v.g., visceral ganglion; p.g., pedal ganglion; p.n., pedal nerve ; p., pallial nerve ; m., muscle nerve ; /.s., left splanchnic ; 7.s., right splanchnic ; 7., recurrent nerve; I, tentacular; II., cutaneous; III., ocular; IV., posterior pharyngeal; V., anterior pharyngeal ; VI., labial nerves. The outer dotted and inner dotted lines represent the outlines of the buccal mass and the pharynx respectively. Nerve elements. (1) nerve—c, isolated fibre; (2) cells of a ganglion—a, rounded, 6, bipolar. Vertical section through the nuchal tentacle, showing separate origins of tentacular and ocular nerves, and of the cerebral and visceral commissures from the cerebral ganglion. a, super- ficial layer of ganglion cells; 0, visceral commissure ; c, ocular nerve; d, tentacular nerve ; J, epithelium of tentacle ; e, the ocular mound ; g, cerebral commissure. Semidiagramatic representation of intestinal coils. ph., pharynx; ¢r., crop; a, anus; r., rectum ; s, and s’., stomach. Face view of mouth. a, radula; 0, palate ; c, inner lips; d, outer lips. Section of the lower plate. a, cuticle; 6, stratified columnar epithelium; c, connective tissue ( x 50). Same, magnified ( x 250). Section of liver ( x 150), showing hepatic tubes cut in transverse section. Liver cells, connective tissue ( x 450). Liver cells, isolated ( x 500). Radula, two rows of teeth. 1 and 2, lateral teeth; 3, median tridenticulate ; 5 and 4, central unidenticulate. PLATE CLIII. Pharynx and salivary glands, dorsal neck wall removed. a.b, ducts of salivary gland of right side, d ; c, pharynx ; e, buccal mass; f, lobe of pharynx ; g, intestine. Vertical section through neck. a, inner lip; 0, upper (palatal) plate ; c, lower (ventral) plate ; d, pharyngeal wall; e, anterior cartilage; jf, radula; g, ventral protractor muscle ; h, superficial transverse muscle; #, longitudinal muscle; /, deep transverse muscle; m, posterior cartilage ; m, muscles of the subradular membrane ; 9, nuchal body cavity. Figs. 63. and 64, Dorsal and ventral views of the upper (palatal) plate. Fig. 65. Ventral view of buccal mass. a, ventral protractor reflected; 6, terminal radular plate reflected ; 0’, radula; c, longitudinal muscles; d and e, superficial and deep transverse muscles. ~ VOL. XXXII. PART III. oN 638 Fig. Fig. Fig. Fig. Fig. Fig. . Cartilages of odontophore, horizontal section, dorsal view. a.c., anterior cartilage ; pity . Stomach wall. The section is taken transversely through a part where the adjacent walls of. . Transverse section of intestine near rectum, . Glandular stomach and liver. a, follicles ; 5, liver sacs; c, bile duct. . Cells of the intestine isolated and more highly magnified. . One of papillze of rectal papilla wall. . Transverse section of rectal papilla. . Membrane covering the genital organ. . Ova, in different stages of development. . Development of spermatozoa. Figs. 78 and 79. Two stages in the development of a tuft of spermatozoa. Fig. 80. Spermatozoa isolated. GIBSON ON ANATOMY AND PHYSIOLOGY OF PATELLA VULGATA, posterior cartilage ; /.c., lateral cartilage ; v.t7., deep ventral transverse muscle; ., con- nective tissue and pemeneniinces the two divisions of the stomach touch. ’ Vertical section through the visceral dome. a, pericardium; 8, in the stomach; c.c, sections of intestine; d, in the ee nephridium ; ¢, section of rectum; f, left nephntdiaael n glandular Saenas, “crop”; h, genital organ ; k, liver ; l, foot. Cells of a follicle in glandular stomach. mis. Roy. Soc. Edin® VoPAXAW, Plate CXL ~ aes Za : = } AY mB ! a IY ae { VA / ALIA Bora CAI ub wy Nt ays a A) gifts: WE a <7 7 OMT pox = ARO a Wh LON & : = ef y : ae . : CLE) Fig. 15. 2 Ng xy = ad nat. del. Marlene & Exskine, Lith™? Edin? Vow Place (CL. ans. Roy. Soc. Fdin® 8 Vx MSFarlane é& Erskine, Lith?S Edin® G. ad. nat. del. ans. Rey Soc. Edin™ b Vol XXXIT “Pilate CLE ' , Cra —S, 7 6 ' SS Dry Var TI HY Bor TOYS 2 as —— ABCDE. Let us denote by p one of the zmaginary fifth roots of unity, the other roots being p’, p’, p*, 1, and we have from § 2 ’ C(a, b, ¢, d, e)=(at+w b4+o0%+o%d+o'c) (Ato E+w2D+o°C +B), =(4+0*%)+o'¢+o d+w°%c) (A+e’E+o4D+o C+o°B), =(4+0%)+o c+o1d+o%) (A+0°E+oD+o'C+o°B), =(4+0'b+o%¢+ wd+wo e) (A+o1E + w*D+o?C +o B), =(a+ b+ c+ d+ e)(A+ E+ D+ C+ B). From these by division there result A+wo E+o?D+o°C+o'!B= 6yde A+o°E+o'D+o C+o°B=ydea A+o*E+o!D+o'C+o*B =deaB A+oE+o°D +@°C+o'!B=caBy A+ E+ D+ C+ B=ays). Calling the right-hand members here @, U’, c’, d’, e’, we see readily that a+ + + H+ =5A w a +b’ +o%c’ +d’ +e’ =5B wd’ +b! +oc+w%d' +e’ =5C wt +b’ +1 +02 +e =5D wd +o°b’ +02 +o dU +¢=57/, THOMAS MUIR ON DETACHED THEOREMS ON CIRCULANTS. 641 and therefore by multiplication C@, U, ¢, d’, ¢)=5°A BCDE, as was to be proved. 4. If the elements of the first row of a circulant of the nth order be multiplied by w, ow", ...., w respectively, the elements of the second row by #~', w', . w, wo" respectively, the elements of the third row by °~*, wo °,...,@, @, ow" respectively, and so on, where w is any nth root of unity, the circulant is unaltered in value. If we take the circulant as thus changed outwardly, and multiply all the elements of the second row by », all the elements of the third row by ”, and so forth, the elements of the first column will have »” for a common factor, the elements of the second column will have w"~', the elements of the third column w"?,and so on. We thus can strike out of the columns the very factors we introduced into the rows (with the immaterial addition of ©", z.¢., 1), and leave the circulant as it originally stood free of »:—which proves the theorem. 5. If we take two skew circulants, of the 5th order say, C’(ay,..-,@;), C’(d,,...,05) and write the first in the form ay ay tls @, Gs =| — Oh. ty hy Gd, a, | Ce ay hy Ag =Uy Sly =O; ay a, —& —U, —-A, =—A, | ; and the other with its rows in reversed order, then the determinant whose every element is the sum of the corresponding elements in these two determinants, that is to say, the determinant a, —b, ty — bz a,—b, az—b, a,—b, —t,—b, a, — 04 ly — b, ag+b, ay+b, —a,—b, —a,—b; a+, A,+b, d3+; | —t3—b, —ay+b, —a3;+b, a+b; a+b, | —dy+b, —d3+b, —a+b, —a,+b, a,4+0, |, has for a factor (a, +o lg +o 23+ w+ 0~*A5) (A, + @4,+ 073+ w+ w'A;) —(- w'ba+ wb, + w*by + w-*bs) (b,+ wb, + wb, + wd, + w'b;) where w is an imaginary fifth root of —1, the linear factor which remains being a, —M,+a,—a,+4,+0, —b,+),—b,+6,. 642 THOMAS MUIR ON DETACHED THEOREMS ON CIRCULANTS. This is equivalent to saying that the determinant is equal to [2a,? +2 003 36° (ayy + Agtlg + Ugh, + Uys — Ug) + 2 COS 72° (44+ Mgty + gs — A401 — Ag, — 3,2 —2 cos 36° (by), + Dgby +0), +04), —Dsp,) —2 008 72° (byb,-+ 0,0, +05b,—b,b —B,),) | x [ 2a,? —2 C08 72° (yg + Ugg + Ag, + Myls — M30ly) — 2 COs 36° (4,05 + Ay + Ag, — Ug — Agi — Zby2+2 cos 72° (b,), + 0ybg-+0,b, +040, —b;b,) +2 cos 36° (by), +b.b, +0, —0,b, — 0,1) | x [a.— Ay +,—A,+d;+6,—b,+ b,—b, +b; , where the law of signs in Ay Ay + Ugly + Ag+ Agh;— A, ANd AyMg+ M.A, + Ags — Ay — Ugly is made clear by noting that each expression is got from two rows of C’ (ay, Ag, 3, Uy, Az), the former being (a, cg, dg, Ay Us, 8— Ap, Uy, Up, Ug, Uy) and the latter (— a2, —d3, —Gy, — Ag, y8— Cg, — My Ug, — Cy, Ue). This theorem is established exactly as its analogue in ordinary circulants. (See Messenger of Math., xi. pp. 105-108.) 6. One of the hardest problems connected with circulants is the finding of the final expansion of the circulant of the nth order. Anything that has been done towards a solution will be found in the following papers: GLAISHER, Quart. Journ. of Math., xv. p. 354, xvi. p. 33; Murr, Quart. Journ. of Math., xviii. pp. 176, 177; Forsytu, Mess. of Math., xiv. pp. 43-46.; Muir, Mess. of Math., Xlv. pp. 169-1735. One plan which occurred to me of determining the law of the coefficients was to try to hit upon a determinant of some more general form than the circulant and having an easier law of formation for its final expansion, and then to specialise. The determinant which seemed to offer fairest promise is exemplified by | @a BB cy do ce 7A eB ay 6 ce da dy « ade ba cB co de 6a a by be ca dB ey ad.-|. It evidently degenerates into the circulant C(q, b, ¢, d, e) whena=B=y=d0=e=1, and, what is of importance, the letters a, B, y,4,¢ are themselves introduced in cyclical fashion, the determinant, in fact, degenerating into the circulant C(a, B, y, 8, «) when a=b=c=d=e=1. This determinant I find equal to (O40 +02°+d°+e)aByde —(asbe+bica+cdb+d%ec+ ead) (a®yd+ B'de+ y*cat+ Sab +eBy) —(aced+b3de+ cca+d*ab+e%be) (a®Bet+ Byat y*dB + Hey + ead) + (abd + b+ d*a + deh + ea°c) (a? By’ + B?y0? + y*de? + 8ea? + €a3”) + (a*he? + bcd? + cde? + dea? + ab?) (a®B°d + Bye + ya + 0°e"6 + €a"y) — 10abedeaByde, THOMAS MUIR ON DETACHED THEOREMS ON CIRCULANTS. 645 which, using > for cyclic swum, we may write in the form Da’. aByde— SarheDaryd - Yared Da2Be+ Sard Ye2By? + Sa°be2D0282S — 10 abcdeaByde. Putting a=B=y=d=c=1, we obtain C@ b, ¢ d,; e)= Ya? —5Sa%be —5 Sared 4+5502bd +5 Dae? \ —10 abcdeaByce , and it is seen how the coefficients, —5, —5, 5,5 originate. Unfortunately the general determinant still contains a set of unsifted terms, viz., 10 abcdeaByde, which are got, curiously enough, from the elements by a series of knight’s moves. Though therefore the discussion of the problem may be advanced in this way, the full solution is not yet in sight. VOL. XXXII., PART III. 5P ( 645 ) XXXV.—On the Hessian. By Professor CurystTat. (Read 18th May 1885.) 12) Ket US + +42 7+....=0 be the equation to an algebraical curve of the mth degree, the co-ordinates of any point on which in a system of linear co-ordinates are (a, y, Z), Uo, Ui; U2-+-- being homogeneous functions of « and y of degrees indicated by the attached suffixes ; then H=wyU,U.+2U,.U.0.,—U,,U,2—U,,U.29—U.Ue=0 is the equation to its Hessian, which is a curve of the 3(m —2)th degree. Every one of the 3n(m—2) points of intersection of H and U is a point of inflexion on U if it be not a multiple point on U. In this last case the inter- section may or may not be a point of inflexion on some one of the branches of U; but in any case where H passes through a multiple point the total number 3n(n—2) of inflexions suffers a reduction. It is therefore a problem of great geometrical interest to calculate the number of the intersections of H and U which are absorbed at a multiple point on the latter. This problem has never been solved directly in any but a few simple cases. It has been shown, for example, that at an ordinary double point on U, H has also a double point the tangents at which are the same as the tangents at the double point on U, and that such a point absorbs 2x2+2=6 of the intersections HU ; also that a multiple point of order &, all of whose tangents are distinct, is a multiple point of order 34—4 on H, & of whose tangents are tangents to U, and that such a point absorbs 4(3k — 4) +4=6 x 44(4—1) intersections,—in other words, has the same effect as the 44(4—1) ordinary double points to which it may be regarded as equivalent. It has also been shown that a point which is a cusp of the ordinary kind on U is a triple point on H, two of whose tangents coincide with the cuspidal tangent of U; this cusp counting for 2x3+2=8 among HU. Finally, Cay.ey has laid down that every singularity of an algebraical curve can be regarded, for our present purpose, as equivalent to a certain number 6 of ordinary double points, and a certain number « of ordinary cusps. But the proofs which have been given of this theory by N6rHER, ZEUTHEN, STOLZ, Henry Sirs, and the methods given for ascertaining the indices d and «, are of an indirect nature, and it has been doubted whether any proof of this theory can be given by methods appropriate to co-ordinate geometry. VOL. XXXII. PART III. 5Q 646 PROFESSOR CHRYSTAL ON THE HESSIAN. The direct calculation of the reduction is therefore a general problem, whose interest is quite equal to its difficulty. With a view to clear the way for a general solution (if such be attainable) I have worked out a number of cases, _ some quite special, others of a more general character, and propose to com- municate the solutions to the Society in the following paper. 2. In its ultimate stage the problem reduces to the following :— To determine the number UV of the intersections of two algebraical curves U=0, V=0, which coincide with a common point which is multiple on one or both. | Let us suppose that the common point is a multiple point of order 4 on U and of order « on V. ’ So long as no one of the & tangents of U coincides with any one of the x tangents of V, there is no difficulty; the number of intersections absorbed at the common point is kr. But let us suppose that / of the & tangents and A of the « tangents coincide with «=0, then we have U=thip +i. Veo yp FU sae ee. or, what is still worse, that z=0 is a multiple inflexional or undulatory tangent, so that US vig FO ptembOUeen os w s o VSO ig Oe EO Yetens Hn and the problem becomes one of some difficulty. In many cases the solution may be obtained by the following process :— Ex. 1. Let us suppose Uj U, + U9 VEe'v, +0. Let K=a0,U — u, VE=ary tty) — U0, Up » say, where w,, does not contain # as a factor. Then, since K passes through all the intersections of U and V, taking VU to denote the number of those inter- sections which coincide with 2=0 y=0 we have, since oe \ gives u,.V=0 and .. nV}? UK =0V +z, .0., Uthg=UV +U0u,, — a a, whence UV =Uu,, —Uu;. PROFESSOR CHRYSTAL ON THE HESSIAN. 647 Now, provided none of the linear factors of u,, occur in vu,, and none of those of wu, in u,, we have Uu,,=8 x 12 Gui; =wygts=10 x 5 whence finally UV =96 —50=46. We may consider the more general case. Ex. 2. UO wg A+ te, M> lh VESOUp—p +VUetp Tp; of which Ex. 1 is a particular case; it may be shown by the above method that OV =kxe+ru, This obviously agrees with the result of Ex. 1, «nd also with the following. Ex. 3. U=x2- UV =2x1+1x1 V=az -¥ =o. which may be looked fs upon as the limiting case of Fig 2 The figure corespond- ing to this case is Ifin Ex. 2r>p the application of the above method is not so simple, and the result is not in all cases the same as will be shown directly. For the sake of comparison with the results of another process shortly to be indicated, I work out two more examples by the present method. Ex. 4. US13 5 +2, + U49 Vay, +230, +,, we have K=20,U — 4, V=3(0,u,— U,V5) + BV U9 — UV, =u, +4». say L=a,K —u,0=u, +, say 7 8xi7=0L— UK + Uz, =UV+4 0u,+ Ou, = iy, + 2 (x?u,)U, 648 PROFESSOR CHRYSTAL ON THE HESSIAN. Ez. 5. U=8u, +aug +49 =xtv, +270, +0, K=a0,U —u,V =2%ly+ rhyp L= au, K—u,U Say, + Uy M=zu,L — uy K=u9, 11x29=MK=KL42K +u,K = KL 4 ot + tgthy = KU+Ku, HF atiag + Ugly =kU FBiyg t Bigg _ =UV+u,U + &e. =UV +20, Ugly + Qiigtlyg + Bilyy UV =319—5 —40—216—-12=46. redundant steps, for in the three examples (1) (4) (5) the same final result, viz., UV =46, is obtained by extremely different developments. Yet it is obvio s, a priori, that the same final result ought to be arrived at in all these a since the additional terms which appear in U and V in examples (4) and (5) are such that they do not affect the forms of U and V at the point z=0 y=0, which alone can be supposed to affect CV. It is at once suggested, therefore, that the problem will be simplified by substituting for U and V the approximations to their branches at the origin determined by the rule of Newron and Cramer. In this way we can in general reduce the problem to a series of others, of which the following is a type. To determine the number of intersections of US2"—y"=0....(1) and V=0'=—y'=0.... (2) at the point z=0 y=0. Since imaginary branches must be considered as well as real branches, it may be well to give a rigorous proof of the solution in this simple case. If aja,....a, be the m roots of +1, the m values of y given by y"=a” are a,c” 5 ae” eynuers ant” c The eliminant of the two equations (1) and (2) with respect to y is therefore { +a" y} pee C: vee | eae yi =0, utis SLSR EH PPh tee Now, if g be the G.C.M. of » and », and n=gn’, v=g’, then the series ai, a,....a%, simply consists of the roots of a” —1=Orepeated g times. Hence the equation last written reduces to pv (apin' mv _ 19 = 0), that is (w’—a™o=0.... (3), PROFESSOR CHRYSTAL ON THE HESSIAN. 649 where from the nature of the process employed we are sure that there is no redundant factor. Now 2" or 2” is a factor in (3) according as wr< or >my, w.e., the number of zero roots of (3) is the least of the two numbers yun mv. Hence denoting for shortness the least of the two yn mv by U(un, mv), we have the following simple theorem. The number of intersections of #”—y"=0 and w*—y’=0 at the point c=0 y=0, is (un, my). 4, By means of the NEwron-CrAMER rule we can, as far as points near x=0 y=0 are concerned, replace U and V by U'= (aA, y") («@ —A,y”).... VG Bg Ge By 8) a aan where the factors in U’ will in general be all different, those in V’ all different, and no factor common to U’ and V’. In this case we can at once find the number UV. We have, in fact, LEE VS UV=UV=l(m, vy, % my) +E (Mm, ve, M Mg) ..-- +1 (Mg vy, My My) HU (MM, Vy, Ng My). --- et ee This result still holds when factors are repeated in U’ or in V’; but when there are factors common to U’ and V’ there is a modification, as will be shown presently. 5. Before proceeding farther, let us apply the above principles to one or two examples. Ex. 1. U= au, + 0%, +U,)=0 ] Vxtu,+a%vgtv, =0. The NeEwrTon-CraMErR diagrams for U and V show at once that (omitting constant coefficients as irrelevant to the issue) we may write U = u,(a?+y°) V=v (a+) ; —~ “ UV=5x1+5x44+3x1+4+3x6=46, the same result as before. Ex. 2. U = au, +2ugt uo V = atv, +20, +0,. Here it is easily shown that we may write US uty’) (@+y’) V = v, (x+y); LS ~ UV=5x1+5x4+42x14+2x6+1x1+1x6=46. Ex. BY U == a” Un—m + Ur—r Nie oF 6 Ug: VOL. XXXII. PART III. 5R 650 PROFESSOR CHRYSTAL ON THE HESSIAN. The diagrams here are both of the same character that for U, for example, is figure 3, where AB and CD are parallel and each full of terms ; the co- -ordina es of D are (m, k—m); and OA=k+7, OC=kh. The two lines CD and BD give approxmations at <=0 y=0. We may therefore write ) C A U= w_m(e™+y"*"), VEX +yr™). Hence Fig.3. OV =(b—m)c + m(e—w) +U(p-+ um, (r+-m)u} =kk-—ma+mp +1(pm, ru) =kk+U(pm, 7) =kk+pm or =kk+7u, according as pm Tp. This result includes that of Ex. 2 in § 2 as a particular case. Ex. 4. To illustrate the particular case of Ex. 3, where mp< 7, consider CI U=e—-y1. V=22—7 Here m=2, k=2, r=2, — 2 k=2, p=1; mp=2, ur=4. UV. = 225-9 6. The corresponding figure is Fig.4. which may, in fact, be considered as the limiting case of (Lo be continued in another Communication.) y The Transactions of the Roya Society or Epinsure# will in fature be Sold Vol. Tre ae IV. at the following reduced Prices :— Price the Public. £0 9 11 11 18 17 0 19 14 14 18 5 11 mm NESCOSOSO SO HH OSOOrFSCOSOS ° FR a") Out of Print. St Price to Fellows. Vol. XXI, Part 4. £0 7 0 XXII. Part 1. 09 O rari 2. Crees .i6 ae eabb re: 015 O XXIII. Part 1. 014 0 » Part 2. OF 20 59. wEarb os 016 =O XXIV. Part 1. |. OPI 2 0 ay earbi2s OL arto: 015 O XXV. Part 1. Nae! Lae) pee Gk arbi. 1 6 0 || XXVI. Part 1. a rath. a » Part 3. 014 O » Part 4. @. 7 36 XXVIII. Part 1. 0 4 0 igo ert 2; 0 5 6 iy Eatin, » Part 4. T= 0 XXVIII. Part 1. Ae EP Harn) 111 0 » Part 3. 015 0 XXIX. Part 1. yo Earth 2, Wet ere XXX, Part 1. 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A : : : O93 List or Puruic Institutions AND INDIVIDUALS ENTITLED TO RECEIVE COPIES OF THE PROCEEDINGS AND TRANSACTIONS OF THE Roya SOcrEry, : ; . ; : aol INDEX, ; ; : ; i : i ; ; a eOT [Issued July 9, 1887.) APPENDIX. TRANSACTIONS OF THE ROYAL SOCIETY OF EDINBURGH. 1884-8 5. VOL, XXXII. PART IV. 58 CONTENTS. THE COUNCIL OF THE SOCIETY, ALPHABETICAL LIST OF THE ORDINARY FELLOWS, LIST OF HONORARY FELLOWS, LIST OF ORDINARY FELLOWS ELECTED DURING SESSIONS 1883-85, . LAWS OF THE SOCIETY, THE KEITH, BRISBANE, AND NEILL PRIZES, AWARDS OF THE KEITH, MACDOUGAL-BRISBANE, AND NEILL PRIZES, FROM 1827 TO 1879, ; : i : : : PROCEEDINGS OF THE STATUTORY GENERAL MEETINGS, LIST OF PUBLIC INSTITUTIONS AND INDIVIDUALS ENTITLED TO RECEIVE COPIES OF THE PROCEEDINGS AND TRANSACTIONS OF THE ROYAL SOCIETY, INDEX, 701 707 LIST OF MEMBERS. COUNCIL, ALPHABETICAL LIST OF ORDINARY FELLOWS, AND LIST OF HONORARY FELLOWS. At November 1886, THE COUNCIL OF THE ROYAL SOCIETY: OF EDINBURG NOVEMBER 1886. Str WILLIAM THOMSON, LL.D., F.R.S., Foreign Associate of the Institute of France, Regius Professor of Natural Philosophy in the University of Glasgow. HONORARY VICE-PRESIDENTS, HAVING FILLED THE OFFICE OF PRESIDENT. His Grace.tHE DUKE or ARGYLL, K.T., D.C.L. Oxon, F.R.S. Tue Ricut Hon. Lorp MONCREIFF, LL.D., Lorp Justice-Cimrx. THOMAS STEVENSON, Esq., M. Inst., C.E. VICE-PRESIDENTS. ALEXANDER FORBES IRVINE, of Drum, Sheriff of Argyll. JOHN MURRAY, Ph.D., Director of the Challenger Expedition Commission. D. MILNE HOME of Milne-Graden, LL.D. Sir DOUGLAS MACLAGAN, M.D., President of the Royal College of Physicians, Edin., F.R.C.S.E., and Professor of Medical Jurisprudence in the University of Edinburgh. Tue Hon. Lorp MACLAREN, LL.D. Edin. and Glas., F.R.A.S., one of the Senators of the College of Justice. Tue Rey. Proressor FLINT, D.D., Corresponding Member of the Institute of France. GENERAL SECRETARY. P. GUTHRIE TAIT, M.A., Professor of Natural Philosophy in the University of Edinburgh. SECRETARIES TO ORDINARY MEETINGS. Sir WILLIAM TURNER, M.B., F.R.C.S.E., F.R.S., Professor of Anatomy in the University of Edinburgh. ALEXANDER CRUM BROWN, M.D., D.Sc, F.R.C.P.E., F.R.S., Professor of Chemistry in the University of Edinburgh. TREASURER. ADAM GILLIES SMITH, C.A. CURATOR OF LIBRARY AND MUSEUM. ALEXANDER BUCHAN, M.A, Secretary to the Scottish Meteorological Society. COUNCILLORS. GEORGE CHRYSTAL, M.A., Professor of | WILLIAM CARMICHAEL M‘INTOSH, M.D., Mathematics in the University of Edinburgh. ALEXANDER DICKSON, M.D., Professor of Botany in the University of Edinburgh. J. SHIELD NICHOLSON, Professor of Political Economy in the University of Edinburgh. T. B. SPRAGUE, M.A. S. H. BUTCHER, M.A., LL.D., Professor of Greek in the University of Edinburgh. JOHN G. M‘KENDRICK, M.D., F.R.C.P.E., F.R.S., Professor of the Institutes of Medicine in the University of Glasgow. THOMAS MUIR, M.A., LL.D., Mathematical Master in the High School of Glasgow. LL.D., F.R.S., F.L.8., Professor of Natural History in the University of St Andrews. ROBERT GRAY, Secretary to the Royal Physical Society of Edinburgh, Member of the British Ornithologists’ Union, Corresponding Member of the Academy of Natural Sciences of Philadelphia. ARTHUR MITCHELL,C.B., M.A., M.D., LL.D., Commissioner in Lunacy. STAIR A. AGNEW, Esq., C.B., M.A., Advocate, Registrar-General. ROBERT M. FERGUSON, Ph.D. Date of Election, 1879 1871 1881 1878 1875 1878 1856 1886 1874 1883 1883 1881 1867 1883 1886 1849 1885 1879 1875 1843 1879 1877 ALPHABETICAL LIST OF THE ORDINARY FELLOWS OF THE SOCIETY, B. K. N. 12, HP. BP, CORRECTED TO NOVEMBER 1886, N.B.—Those marked * are Annual Contributors. prefixed to a name indicates that the Fellow has received a Makdougall-Brisbane Medal. Keith Medal. ” »”? ” Neill Medal. cf a », contributed one or more Papers to the TRANSACTIONS. Abernethy, Jas., Memb. Inst. C.E., Prince of Wales Terrace, Kensington * Aonew, Stair A., C.B., M.A., Advocate, Registrar-General, 22 Buckingham Terrace Aitchison, James Edward Tierney, C.ILE, M.D., F.RS., F.LS., Brigade-Surgeon, Secretary to the Surgeon-General, H.M.F. Bengal, and Naturalist with the Afghan Delimitation Commission, H.M. Bengal Army, North Bank, Simla, Punjab, India * Aitken, Andrew Peebles, M.A., Sc.D., F.I.C., 18 Dublin Street * Aitken, John, Darroch, Falkirk 5 Allchin, W. H., M.B. (Lond.), F.R.C.P., Physician to the Westminster Hospital, 5 Chandos Street, Cavendish Square, London, W. Allman, George J., M.D., F.R.S., M.R.LA., F.L.S., Emeritus Professor of Natural History, Univ. of Edinburgh, Ardmore, Parkstone, Dorset * Anderson, Arthur, M.D., C.b., Ex-Inspector-General of Hospitals, Pitlochry Anderson, John, M.D., LL.D., F.R.S., Superintendent of the Indian Museum, and Professor of Comparative Anatomy in the Medical College, Calcutta, 71 Harrington Gardens, London, S.W. * Anderson, Robert Rowand, LL.D., 19 St Andrew Square 10 Andrews, Thomas, F.C.S., Mem. Inst. C.E., Ravencrag, Wortley, near Sheffield Anglin, A. Hallam, M.A., LL.B., M.R.I.A., Medmenham, Great Marlow, Buckinghamshire * Annandale, Thomas, M.D., F.R.C.S.E.., Professor of Clinical Surgery in the University of Edinburgh, 34 Charlotte Square Archibald, John, M.B., C.M., Lynton House, Brixton Rise, London, 8.W. '|* Armstrong, George Frederick, Professor of Engineering in the University of Edinburgh 15 Argyll, His Grace the Duke of, K.T., D.C.L., F.R.S. (Hon. Vicz-Prus.), Inveraray Castle * Baildon, H. Bellyse, B.A., 73 Princes Street * Bailey, James Lambert, Royal Bank of Scotland, Ardrossan * Bain, Sir James, 3 Park Terrace, Glasgow Balfour, Colonel David, of Balfour and Trenabie, Balfour Castle, Kirkwall 20 * Balfour, George W., M.D., LL.D., F.R.C.P.E., 7 Walker Street * Balfour, I. Bayley, Sc.D., M.D., C.M., F.R.S., Sherardian Professor of Botany in the University of Oxford VOL. XXXII. PART IV. 5 T 656 ALPHABETICAL LIST OF THE ORDINARY FELLOWS OF THE SOCIETY. Date of Election. 1870 1886 1872 1883 | 1882 1874 1878 * Balfour, Thomas A. G., M.D., F.R.C.P.E., 51 George Square * Barclay, A. J. G., M.A., 5 Ethel Terrace * Barclay, George, M.A., 17 Coates Crescent 25 * Barclay, G. W. W., M.A., 40 Princes Street Barnes, Henry, M.D., M.R.C.S., 6 Portland Square, Carlisle Barrett, William F., M.R.I.A., Professor of Physics, Royal College of Science, Dublin Bateman, John Frederic La Trobe, Memb. Inst. C.E., F.R.S., F.G.S., F.R.G.S., 16 Great George Street, Westminster Batten, Edmund Chisholm, of Aigas, M.A., 16 Pelham Crescent, South Kensington, London 30 * Bayly, General John, C.B., R.E., Ardincaple Castle, Helensburgh, Dumbartonshire Beddard, Frank E., M.A. Oxon, Prosector to the Zoological Society of London, 9 Cleve- land Terrace, Hyde Park, London, W. * Bell, A. Beatson, Chairman of Prison Commissioners, 130 George Street * Bell, Joseph, M.D., F.R.C.S.E., 2 Melville Crescent * Belcombe, Rev. F. E., 14 Merchiston Avenue 35 Bernstein, Ludwik, M.D., Lismore, New South Wales * Berry, Walter, Danish Consul General, 11 Atholl Crescent * Birch, De Burgh, M.D., Professor of Physiology, University College, Leeds, 16 De Grey Terrace, Leeds * Black, James Tait, Gogar Park, Corstorphine * Black, Rev. John S., 6 Oxford Terrace 40 Blackburn, Hugh, M.A., LL.D., Emeritus Professor of Mathematics in the University of Glasgow, Roshven, Ardgour * Blackie, John S., Emeritus Prof. of Greek in the Univer. of Edin., 9 Douglas Crescent Blaikie, The Rev. W. Garden, M.A., D.D., LL.D., Protessor of Apologetics and Pastoral Theology, New College, Edinburgh, 9 Palmerston Road * Blyth, James, M.A., Professor of Natural Philosophy in Anderson’s College, Glasgow Bond, Francis T., M.D., B.A., M.R.C.S., 1 Beaufort Buildings, Spa, Gloucester 45 * Bottomley, J. Thomson, M.A., Lecturer on Natural Philosophy in the University of Glasgow * Bow, Robert Henry, C.E., 7 South Gray Street * Bower, Frederick O., Regius Professor of Botany in the University of Glasgow, 45 Kerrs- land Terrace, Hillhead, Glasgow : Bowman, Frederick Hungerford, D.8c., F.R.A.S., F.C.S., F.G.S., F.L.S., West Mount, Halifax, Yorkshire * Boyd, Sir Thomas J., Chairman of the Scottish Fishery Board, 41 Moray Place 50 * Boyd, William, M.A., Peterhead * Bramwell, Byrom, M.D., F.R.C.P.E., 23 Drumsheugh Gardens Brittle, John Richard, Memb. Inst. C.E., Vanbrugh Hill, Blackheath, Kent Broadrick, George, Memb. Inst. C.E., Elmfield Lodge, Doncaster .|* Brown, Alex. Crum, M.D., D.Sc., F.R.C.P.E., F.R.S. (Srorerary), Professor of Chemistry in the University of Edinburgh, 8 Belgrave Crescent 55 * Brown, J. A. Harvie, of Quarter, Dunipace House, Larbert, Stirlingshire * Brown, J. Graham, M.D, C.M., F.R.C.P.E., 16 Ainslie Place * Brown, J. Macdonald, M.B., F.R.C.S.E., 6 Atholl Place Brown, Rev. Thomas, 16 Carlton Street Brown, William, F'.R.C.S.E., 25 Dublin Street 60 Browne, Sir Jas. Crichton, M.D., LL.D,,7 Cumberland Terrace, Regent’s Park, London, N. W. ALPHABETICAL LIST OF THE ORDINARY FELLOWS OF THE SOCIETY. 657 Date of Election. 1883 1878 1867 1869 1870 1882 1883 1869 1879 1878 1874 1882 1876 1885 1866 1874 1875 1872 1880 1875 1886 1863 1875 1882 1886 1872 1863 1879 1875 1886 1873 1878 1886 1877 1884 1871 1841 1878 1885 1867 BeP: 1. P; * Bruce, Alexander, M.A., M.B., M.R.C.P.E., 16 Alva Street Brunlees, Sir James, Memb. Inst. C.E., 5 Victoria Street, Westminster * Bryce, A. H., D.C.L., LL.D., 42 Moray Place * Buchan, Alexander, M.A., Secretary to the Scottish Meteorological Society (CURATOR oF Lrprary), 72 Northumberland Street 65 * Buchanan, John Young, M.A., 10 Moray Place * Buchanan, T. Ryburn, M.A., M.P. for the City of Edinburgh, 10 Moray Place * Butcher, S. H., M.A., LL.D., Professor of Greek in the University of Edinburgh, 27 Palmerston Place * Calderwood, Rev. H., LL.D., Professor of Moral Philosophy in the University of Edin- burgh, Napier Road, Merchiston * Calderwood, John, F.I.C., Belmont Works, Battersea, London 70 Campbell, John Archibald, M.D., Garland’s Asylum, Carlisle Carrington, Benjamin, M.D., Eccles, Lancashire * Cay, W. Dyce, Memb. Inst. C.E., 107a Princes Street Cazenove, The Rey. John Gibson, M.A., D.D., 22 Alva Street, Chancellor of St Mary’s Cathedral * Chambers, Robert, 10 Claremont Crescent 15 * Chalmers, David, Redhall, Slateford * Chiene, John, M.D., F.R.C.S.E., Professor of Surgery in the University of Edinburgh, 26 Charlotte Square * Christie, John, 19 Buckingham Terrace Christie, Thomas B., M.D., F.R.C.P.E., Royal India Asylum, Ealing, London * Chrystal, George, M.A., Professor of Mathematics in the University of Edinburgh, 5 Bel- grave Crescent 80 * Clark, Robert, 7 Learmonth Terrace * Clark, The Right Hon. Sir Thomas, Bart., Lord Provost of Edinburgh, 11 Melville Crescent Cleghorn, Hugh F. C., of Stravithie, M.D., LL.D., F.L.S., St Andrews, United Service Club, 13 Queen Street * Clouston, T. S., M.D., F.R.C.P.E., Tipperlin House, Morningside * Coats, Sir Peter, of Auchendrane, President of the Glasgow and West of Scotland Horti- cultural Society, Auchendrane, Ayr 85 Connan, Daniel M., M.A., Education Department, Cape of Good Hope * Constable, Archibald, 11 Thistle Street Cowan, Charles, of Westerlea, Murrayfield * Cox, Robert, of Gorgie, M.A., 34 Drumsheugh Gardens * Craig, William, M.D., F.R.C.S.E., 7 Bruntsfield Place 90 * Croom, John Halliday, M.D., 25 Charlotte Square * Crawford, Donald, M.A., Advocate, M.P., 18 Melville Street * Cunningham, Daniel John, M.D., Professor of Anatomy in Trinity College, Dublin * Cunningham, David, Memb. Inst. C.E., Dundee * Cunningham, George Miller, 2 Ainslic Place 95 * Cunningham, J. T., B.A., 1 Walker Street * Cunynghame, R. J. Blair, M.D., 6 Walker Street Dalmahoy, James, 9 Forres Street * Dalziel, John Grahame, 2 Melville Terrace, Pollokshields, Glasgow * Daniell, Alfred, M.A., LL.B., D.Sc., Advocate, 3 Great King Street 100 '* Davidson, David, Somerset Lodge, Wimbledon Common, Wimbledon 658 Date of Election. 1848 1884 1870 1876 1879 1869 1869 1884 1876 1869 1863 1885 1881 1867 1882 1866 1878 1880 1860 1863 1870 1876 1878 1859 1874 1869 1885 1875 1880 1855 1884 1863 1879 1878 1875 1866 | ALPHABETICAL LIST OF THE ORDINARY FELLOWS OF THE SOCIETY. Davidson, Henry, Muirhouse, Davidson’s Mains Davy, Richard, M.B., F.R.C.S., Surgeon to the Westminster Hospital, 33 Welbeck Street, Cavendish Square, London, W. * Day, St John Vincent, C.E., 115 St Vincent Street, Glasgow, and 12 Rothesay Place, Edinburgh * Denny, Peter, Memb. Inst. C.E., Dumbarton 105 * Denny, William, Memb. Inst. C.E., Bellfield, Dumbarton * Dewar, James, M.A., F.R.S., Jacksonian Professor of Natural and Experimental Philosophy in the University of Cambridge, and Fullerian Professor of Chemistry at the Royal Institution of Great Britain, London * Dickson, Alexander, M.D., Professor of Botany in the University of Edinburgh, 11 Royal Cireus * Dickson, Charles Scott, Advocate, 59 Northumberland Street é * Dickson, J. D. Hamilton, M.A., Fellow and Tutor, St Peter’s College, Cambridge 110° * Dickson, William, 38 York Place * Dittmar, W., F.R.S., Professor of Chemistry, Anderson’s College, Glasgow Dixon, J. M., Professor of English Literature in the University of Tokio, Japan * Dobbin, Leonard, Ph.D., 4 Oxford Street * Donaldson, J., M.A., LL.D., Principal of the United College of St Salvador and St Leonard, St Andrews 115 * Dott, D. B., Memb. Pharm. Soc., 24 Castle Street * Douglas, David, 22 Drummond Place Drew, Samuel, M.D., D.Sc.. Chapelton, near Sheffield * Drummond, Henry, F.G.S., Prof. of Natural History in the Free Church College, Glasgow Dudgeon, Patrick, of Cargen, Dumfries, 27 Glencairn Crescent 120 Duncan, J. Matthews, M.A., M.D., F.R.C.P.E., LL.D., F.R.S., 71 Brook Street, London | * Duncan, John, M.D., F.R.C.P.E., F.R.C.S.E., 8 Ainslie Place * Duncan, James, of Benmore, Kilmun, 9 Mincing Lane, London, E. * Duncanson, J. J. Kirk, M.D., F.R.C.P.E., 22 Drumsheugh Gardens Duns, Rev. Professor, D.D., New College, Edinburgh, 14 Greenhill Place 125 * Durham, William, Seaforth House, Portobello * Hider, George, Knock Castle, Wemyss Bay, Greenock * Elgar, Francis, LL.D., The Admiralty, London Elliot, Daniel G., New York * Elliot, T. Armstrong, M.A., Fettes College 1 Etheridge, Robert, F.R.S., Assistant-Keeper of the Geological Department at the Briti Museum of Natural History, 14 Carlyle Square, Chelsea, London * Evans, William, F.F.A., 184 Morningside Park, Edinburgh Everett, J. D., M.A., D.C.L., F.R.S., Professor of Natural Philosophy, Queen’s College, Be * Ewart, James Cossar, M.D., F.R.C.S.E., Professor of Nat. Hist., University of Edinburgh, 3 Great Stuart Street * Ewing, James Alfred, B.Sc., Professor of Engineering and Drawing in University Co Dundee 135 Fairley, Thomas, Lecturer on Chemistry, 8 Newton Grove, Leeds * Falshaw, Sir James, Bart., Assoc. Inst. C.E., 14 Belgrave Crescent ALPHABETICAL LIST OF THE ORDINARY FELLOWS OF THE SOCIETY. 659 “Date of Election. 1859 Fayrer, Sir Joseph, K.C.S.I1., M.D., F.R.C.P.L., F.R.C.S.L. and E., LL.D., F.R.S., Honorary Physician to the Queen, 53 Wimpole Street, London, W. 1883 * Felkin, Robert W., M.D., F.R.G.S., Fellow of the Anthropological Society of Berlin, 20 Alva Street, Edinburgh 1868 * Ferguson, Robert M., Ph.D., 12 Moray Place 140 1874 * Ferouson, William, of Kinmundy, F.L.S., F.G.S., Deputy-Lieutenant of Aberdeenshire, 21 Manor Place, Edinburgh, and Kinmundy House, near Mintlaw 1886 Field, C. Leopold, F.C.S., Upper Marsh, Lambeth, London 1852 Fleming, Andrew, M.D., Deputy Surgeon-General, 3 Napier Road 1876 * Fleming, J. S., 16 Grosvenor Crescent 1880 * Flint, Robert, D.D., Corresponding Member of the Institute of France, Professor of Divinity in the University of Edinburgh, Johnstone Lodge (Vicr-PresipEnt), 54 Craigmillar Park 145 1872 *'Forbes, G., Professor, M.A., F.R.A.S., M.S.T.E. and E., 34 Great George Street, West- minster 1859 Forlong, Major-Gen. J. G., F.R.G.S., R.A.S., Assoc. C.E., &., 11 Douglas Crescent 1828 Foster, John, Liverpool 1858 Fraser, A. Campbell, M.A., D.C.L., LL.D., Professor of Logic and Metaphysics in the University of Edinburgh, 20 Chester Street 1867 |B. P. | * Fraser, Thomas R., M.D., F.R.C.P.E., F.R.S., Professor of Materia Medica in the University of Edinburgh, 37 Melville Street 150 1885 * Fraser, A. Y., M.A., Secretary to the Mathematical Society of Edinb., 8 Chalmers Street 1867 Gayner, Charles, M.D., Oxford 1880 | P. |* Geddes, Patrick, Assistant to the Professor of Botany in the University of Edinburgh, and Lecturer on Zoology at Minto House, 814 Princes Street 1861 |B. P.| Geikie, Archibald, LL.D., F.R.S., F.G.S., Director of the Geological Surveys of Great Britain, and Head of the Geological Museum, 28 Jermyn Street, London 1871 |B. P.| * Geikie, James, LL.D., F.R.S., F.G.S., Professor of Geology in the University of Edinburgh, 10 Bright Crescent, Newington 155 1886 * Gibson, Alexander, Advocate, 12 Great King Street 1881 * Gibson, G. A., D.Sc, M.B., F.R.C.P.E., F.G.S., 1 Randolph Cliff 1877 * Gibson, John, Ph.D., 20 Warrender Park Crescent 1885 | P. |* Gibson, R. J. Harvey, M.A., Demonstrator of Zoology in University College, Liverpool 1870 * Gifford, Hon. Lord, late one of the Senators of the College of Justice, Granton House 160 1879 * Gilray, Thomas, M.A.. Professor of English Language and Literature and Modern History in University College, Dundee 1880 * Gilruth, George Ritchie, Surgeon, 67 York Place 1850 Gosset, Major-General W. D., R.E., 70 Edith Road, West Kensington, London 1867 * Graham, Andrew, M.D., R.N., Army and Navy Club, 36 Pall Mall, London, S.W. 1880 * Graham, James, 195 Bath Street, Glasgow 165 1851 Grant, The Rev. James, D.D., D.C.L., 15 Palmerston Place 1883 * Gray, Andrew, M.A., Professor of Physics in University College, Bangor, North Wales 1875 * Gray, Robert, Secretary to the Royal Physical Society, Bank of Scotland House SSO! | Ps Gray, Thomas, B.Sc., 17 Hayburn Crescent, Partick Hill, Glasgow 1886 * Greenfield, W. S., M.D., Professor of General Pathology in the University of Edinburgh, 7 Heriot Row 170 1872 * Grieve, David, Lockharton Gardens, Colinton Road, Slateford 660 ALPHABETICAL LIST OF THE ORDINARY FELLOWS OF THE SOCIETY. Date of Klection. 1884 1886 1883 1886 1867 1867 1881 1876 1886 1869 1877 1870 1880 1875 1870 1862 1876 1884 1881 1871 1859 1879 1885 1828 1879 1881 1883 1886 1872 1864 1855 1882 1874 1886 IN. 22: * Grieve, John, M.A., M.D., F.L.S., 212 St Vincent Street, Glasgow * Griffiths, Arthur Bower, Ph.D., Principal and Lecturer on Chemistry in the School of Science of the City and County of Leicester, 15 Broadgate, Lincoln Gunning, R. H., M.D., 30 Hazlitt Road, West Kensington Park, London * Haddington, The Right Hon. the Earl of, Tyninghame House, Haddington 175 * Haldane, D. R., M.D., F.R.C.P.E., 22 Charlotte Square * Hallen, James H. B., F.R.C.S.E., F.R.P.S.E., Inspecting Veterinary Surgeon in H.M. Indian Army, 1 Lauriston Gardens * Hamilton, D. J., M.B., F.R.C.S.E., Professor of Pathological Anatomy in the University of Aberdeen, 1a Albyn Place, Aberdeen * Hannay, J. Ballantyne, Cove Castle, Loch Long, N.B. * Hare, Arthur W., M.B., C.M., 21 Ainslie Place 180 Hartley, Sir Chaves A., K.C.M.G., Memb. Inst. C.E., 26 Pall Mall, London Hartley, Walter Noel, Fr R.S., Lhe: of Coe Royal College of Science for Irelenil Dublin * Harvey, Thomas, M.A., LL.D., Rector of the Edinburgh Academy, 32 George Square * Haycraft, J. Berry, M.B., B.Sc., Professor of Physiology in Sir Josiah Mason’s Science College, Birmingham Hawkshaw, Sir John, Memb. Inst. C.E., FERS, F.G.S., 33 Great George Street, Westminster Te Heathfield, W. E., F.C.S., 1 Powis Grove, Brighton Hector, James, C.M.G., M.D., F.R.S., Director of the Geological Survey, Wellington, New Zealand .|* Heddle, M. Forster, M.D., Emeritus Professor of Chemistry in the University of St Andrews * Henderson, John, jun., 4 Crown Terrace, Dowanhill, Glasgow * Herdman, W. A., D.Sc., Professor of Natural History in University College, Liverpool 190 Higgins, Charles Hayes, LL.D., Alfred House, Birkenhead Hills, John, Lieut.-Colonel, Bombay Engineers, C.B., United Service Club, London Hislop, John, Secretary to the Department of Education, Wellington, New Zealand Hodgkinson, W. R., Ph.D., Professor of Chemistry, South Kensington Museum, 29 Pem= broke Square, London Home, David Milne, of Milne Graden, LL.D., F.G.S. (Vicu-PrusipEent), 10 York Place 195 * Hood, Thomas H. Cockburn, F.G.S., Walton Hall, Kelso * Horne, John, F.G.8., Geological Survey of Scotland, 41 Southside Road, Inverness * Hoyle, William Evans, M.A., M.R.C.S., Office of Challenger Commission, 32 Queen Street Hunt, Rev. H. G. Bonavia, Mus. B. Oxon., F.R.A.S., F.L.S., La Belle Sauvage, London * Hunter, Major Charles, Plis Céch, Llanfair, Anglesea, and 17 St George’s Square, London, S.W. 200 * Hutchison, Robert (Carlowrie Castle), and 29 Chester Street Inglis, Right Hon. John, LL.D., D.C.L., Lord Justice-General of Scotland, and Chancellor of the University of Edinburgh, 30 Abercromby Place * Inglis, J. W., Memb. Inst. C.E., Myrtle Bank, Trinity * Irvine, Alex. Forbes, of Drum, Advocate, Sheriff of Argyll (Vicu-PrusipEnt), 25 Castle — | Terrace - ‘* Irvine, Robert, Granton, Edinburgh 205 Date of Election, 1875 1882 | 1860 1880 1865 1869 1867 1874 1877 1866 1886 1877 1880 1883 1878 1875 1880 1875 1886 1878 1885 1870 1881 1872 1872 1882 | 1883 1863 1858 1874 1870 1882 1861 1884 1849 1886 1855 1885 1883 ALPHABETICAL LIST OF THE ORDINARY FELLOWS OF THE SOCIETY. 661 i. P. Jack, William, M,A., Professor of Mathematics in the University of Glasgow * Jamieson, A., Assoc. Memb. Inst. C.E., Principal of College of Science and Arts, Glasgow Jamieson, George A., 24 St Andrew Square Japp, A. H., LL.D., The Limes, Elmstead, near Colchester * Jenner, Charles, Easter Duddingston Lodge 210 Johnston, John Wilson, M.D., Surgeon-Major, 11 Windsor Street * Johnston, T. B., F.R.G.S., Geographer to the Queen, 9 Claremont Crescent Jones, Francis, Lecturer on Chemistry, Monton Place, Manchester * Jolly, William, H.M. Inspector of Schools, F.G.S., Ardgowan, Pollokshields * Keiller, Alexander, M.D., F.R.C.P.E., LL.D., 21 Queen Street 215 * Kidston, Robert, F.G.S., 24 Victoria Place, Stirling * King, James, of Campsie, LL.D., 12 Claremont Terrace, Glasgow * King, W. F., Lonend, Trinity * Kinnear, The Hon. Lord, one of the Senators of the College of Justice, 2 Moray Place * Kintore, The Right Hon. the Earl of, M.A. Cantab., Keith Hall, Inglismaldie Castle, Laurencekirk, N.B. 220 * Kirkwood, Anderson, LL.D., 7 Melville Terrace, Stirling * Knott, C. G., D.Se., Prof. of Natural Philosophy in the Imperial University of Tokio, Japan * L’Amy, John Ramsay, of Dunkenny, Forfarshire, 107 Cromwell Road, London, 8, W. * Laing, Rev. George, 17 Buckingham Terrace | * Lang, P. R. Scott, M.A., B.Sc., Professor of Mathematics in the University of St Andrews 225 * Laurie, A. P., B.A., B.Sc., Nairn Lodge, Duddingston, Edinburgh * Laurie, Simon §., M.A., Professor of Education in the University of Edinburgh, Nairn Lodge, Duddingston * Lawson, Robert, M.D., Deputy-Commissioner in Lunacy, 24 Mayfield Terrace * Lee, Alexander H., C.E., Blairhoyle, Stirling * Lee, The Hon. Lord, one of the Senators of the College of Justice, Duddingstone House, Edinburgh 230 * Leslie, Alexander, Memb. Inst. C.E., 12 Greenhill Terrace * Leslie George, M.B., C.M., Old Manse, Falkirk * Leslie, Hon. G. Waldegrave, Leslie House, Leslie Leslie, James, Memb. Inst. C.E., 2 Charlotte Square * Letts, EK. A., Ph.D., F.LC., F.C.S., Professor of Chemistry, Queen’s College, Belfast 235 * Lister, Sir Joseph, Bart., M.D., F.R.C.S.L., F.R.C.S.E., LL.D., D.C.L., F.R.S., Professor of Clinical Surgery, King’s College, Surgeon Extraordinary to the Queen, 12 Park Crescent, Portland Place, London, N.W. * Livingston, Josiah, 4 Minto Street Lorimer, James, M.A., Advocate, Professor of Public Law in the University of Edinburgh, 1 Bruntsfield Crescent * Low, George M., Actuary, 19 Learmonth Terrace Lowe, W. H., M.D., F.R.C.P.E., Woodcote, Inner Park, Wimbledon 240 Lyster, George Fosbery, Memb. Inst. C.E., Gisburn House, Liverpool Macadam, Stevenson, Ph.D., Lecturer on Chemistry, Surgeons’ Hall, Edinburgh, 11 East Brighton Crescent, Portobello * M‘Bride, Charles, M.D., Wigtown * M‘Bride, P., M.D., F.R.C.P.E., 16 Chester Street 662 ALPHABETICAL LIST OF THE ORDINARY FELLOWS OF THE SOCIETY. Date of | Election. 1867 1886 1886 1847 1878 1878 1885 1877 1878 1886 1880 1879 1869 1882 1873 1840 1843 1853 1869 1864 1869 1870 1876 1883 1872 1876 1884 1883 | 1858 1880 1882 1869 1864 1866 1885 1883 pe £ * M‘Candlish, John M., W.S., 27 Drumsheugh Gardens 245 * Macdonald, The Right Hon. J. H. A., CB, Q.C., M.P., LL.D.,.M.S,T.E, and E., Lord Advocate of Scotland, 15 Abercromby Place * Macdonald, William J., M.A., 4 Polwarth Gardens Macdonald, W. Macdonald, of St Martin’s, Perth * MacDougall, Alan, M.1.C.E., Mail Building, 52 King Street West, Toronto,’Canada Macfarlane, Alex., M.A., D.Sc., Professor of Physics in the University of the State of Texas, Austin, Texas 250 * Macfarlane, J. M., D.Se., 15 Scotland Street * Macfie, Robert A., Dreghorn Castle, Colinton * M‘Gowan, George, F.I.C., Ph.D., University College of North Wales, Bangor * MacGregor, Rev. J., D.D., 11 Cumin Place, Grange MacGregor, J. Gordon, M.A., D.Sc., Professor of Physics in Dalhousie College, Halifax, Nova Scotia 255 * M‘Grigor, Alexander Bennett, LL.D., 19 Woodside Terrace, Glasgow * M‘Intosh, William Carmichael, M.D., LL.D., F.R.S., F.L.S., Professor of Natural History in the University of St Andrews, 2 Abbotsford Crescent, St Andrews * Mackay, John Sturgeon, M.A., Mathematical Master in the Edinburgh Academy, 69 Northumberland Street * M‘Kendrick, John G., M.D., F.R.C.P.E., F.R.S., Professor of the Institutes of Medicine in the University of Glasgow Mackenzie, John, New Club, Princes Street 260 Maclagan, Sir Douglas, M.D., President of the Royal College of Physicians, Edinburgh, and F.R.C.S.E., Professor of Medical Jurisprudence in the University of Edinburgh (Vicz-PresipEnT), 28 Heriot Row Maclagan, General R., Royal Engineers, 86 Lexham Gardens, London, W. * Maclagan, R. Craig, M.D., 5 Coates Crescent * M‘Lagan, Peter, of Pumpherston, M.P., Clifton Hall, Ratho * M‘Laren, The Hon. Lord, LL.D. Edin. and Glase., F.R.A.S., one of the Senators of the College of Justice (VicE-PREsIDENT), 46 Moray Place 265 * Macleod, Geo. H. B., M.D., F.R.C.S.E., Regius Prof. of Surgery in the University of Glas- gow, and Surgeon in Ordinary to the Queen in Scotland, 10 Woodside Crescent, Glasgow * Macleod, Rev. Norman, D.D., 7 Royal Circus * Macleod, W. Bowman, L.D.S., 16 George Square * Macmillan, Rev. Hugh, D.D., LL.D., Seafield, Greenock **« Macmillan, John, M.A., B.Se., Mathematical Master, Perth Academy 270 * Macpherson, Rey. J. Gordon, M.A., D.Sc., Ruthven Manse, Meigle * M‘Roberts, George, F.C.S., Ardeer, Stevenston, Ayrshire Malcolm, R. B., M.D., F.R.C.P.E., 126 George Street Marsden, R. Sydney, M.B., C.M., D.Sc. F.L.C., F.C.S., Rillington, near York. Marshall, D. H., M.A., Professor of Physics in Queen’s University and College, Kingston, Ontario, Canada 275 Marshall, Henry, M.D., Clifton, Bristol * Marwick, James David, LL.D., Town-Clerk, Glasgow * Masson, David, LL.D,, Professor of Rhetoric and English Literature in the University of Edinburgh, 58 Great King Street * Masson, Orme, D Sc., Professor of Chemistry in the University of Melbourne * Matthews, James Duncan, Springhill, Aberdeen 280 ALPHABETICAL LIST OF THE ORDINARY FELLOWS OF THE SOCIETY. 663 Date of Election. 1885 * Mill, Hugh Robt., D.Se., F.C.8., Scottish Marine Station, Granton, 3 Glenorchy Terrace, Edinburgh 1886 * Miller, Hugh, H.M. Geological Survey, 51 Lauriston Place 1852 Miller, Thomas, M.A., LL.D., Emeritus Rector of Perth Academy, Inchbank House, Perth 1885 * Miller, William, 8.S.C., 59 George Square 1833 Milne, Admiral Sir Alexander, Bart., G.C.B., Inveresk 285 1886 * Milne, William, M.A., B.Sc., Mathematical and Science Teacher, High School, Glasgow 1866 * Mitchell, Arthur, C.B., M.A., M.D., LL.D., Commissioner in Lunacy, 34 Drummond Place 1865 * Moir, John J. A., M.D., F.R.C.P.E., 52 Castle Street 1870 * Moncreiff, The Right Hon. Lord, of Tullibole, Lord Justice-Clerk, LL.D. (Honorary Vics- PRESIDENT), 15 Great Stuart Street 1871 * Moncrieff, Rev. Canon William Scott, of Fossaway, Christ’s Church Vicarage, Bishop-Wear- mouth, Sunderland 290 1868 * Montgomery, Very Rev. Dean, M.A., D.D., 17 Atholl Crescent 1879 * Morrison, J. B. Brown, of Finderlie and Murie, The Old House, Harrow-on-the-Hill 1877 | P. |* Morrison, Robert Milner, D.Sc., F.1.C., Nether Liberton House 1873 * Muir, M. M. Pattison, Preelector on Chemistry, Caius College, Cambridge 1874 | K.P.|* Muir, Thomas, M.A., LL.D., Mathematical Master, High School, Glasgow, Beechcroft, Bishopton, Glasgow 295 1870 * Munn, David, M.A., Mathematical Master, Royal High School 1857 Murray, John Ivor, M.D., F.R.C.S.E., M.R.C.P.E., 24 Huntriss Row, Scarborough 1877 | N.P.| * Murray, John, Ph.D., Director of the Challenger Expedition Commission, 32 Queen Street, and United Service Club (Vice-PRESIDENT) 1884 Mylne, R. W., C.E., F.R.S., 7 Whitehall Place, London, S.W. 1877 * Napier, John, 23 Portman Square, London 300° 1866 * Nelson, Thomas, St Leonard’s, Dalkeith Road 1883 * Newcombe, Henry, F.R.C.S.E., 5 Dalrymple Crescent, Edinburgh 1884 * Nicholson, J. Shield, Professor of Political Economy in the University of Edinburgh ; Eden Lodge, Eden Lane, Newbattle Terrace 1880 | p, |* Nicol, W. W. J., M.A., B.Sc, Lecturer on Chemistry, Sir Josiah Mason’s College, Birmingham 1878 Norris, Richard, M.D., Professor of Physiology, Queen’s College, Birmingham 305 1886 Oliver, James, M.B. Edin., M.R.C.P. Lond., Montague Street, Russell Square, London 1884 * Omond, Robert Traill, Superintendent of Ben Nevis Observatory, Fort-William, Inverness 1877 Panton, George A., 95 Colmore Row, Birmingham 1886 * Paton, D. Noel, M.D., B.Sc., 4 Walker Street 1881 | N.P.|* Peach, B. N., F.G.S., Acting Paleontologist of the Geological Survey of Scotland, 8 Annandale Street 310 1863 * Peddie, Alexander, M.D., F.R.C.P.E., 15 Rutland Street 1886 * Peebles, D. Bruce, Tay House, Bonnington, Edinburgh 1869 Pender, John, 18 Arlington Street, Piccadilly, London 1883 Phillips, Charles D. F., M.D., 10 Henrietta Street, Cavendish Square, London, W. 1859 | P. Playfair, The Right Hon. Sir Lyon, C.B., LL.D., F.R.S., M.P., 68 Onslow Gardens, London 315 1877 Pole, William, Memb. Inst. C.E., F.R.S., Mus. Doc., 31 Parliament Street, Westminster, S.W. VOL. XXXII. PART IV. dU 664 ALPHABETICAL LIST OF THE ORDINARY FELLOWS OF THE SOCIETY. Date of Etection. 1886 1874 1852 1880 1875 1849 1885 1882 1885 1880 1884 1882 1885 1869 1883 1875 1872 1883 1877 1880 1872 1859 1886 1877 1881 1862 1881 1880 1852 1880 1869 1863 1864 1849 1846 | 1885 1880 1875 |B. P. * Pollock, Charles Frederick, M.D., F.R.C.S.E., 1 Buckingham Terrace, Hillhead, Glasgow Powell, Baden Henry Baden-, Forest Department, India Powell, Eyre B., C.S.L, M.A., 28 Park Road, Haverstock Hill, Hampstead, London * Prentice, Charles, C.A., Actuary, 8 St Bernard’s Crescent 320 Prevost, E. W., Ph.D., Ellesmere, Salop Primrose, Hon. B. F., C.B., 22 Moray Place * Pringle, James, Provost of Leith, 7 Claremont Park, Leith * Pryde, David, M.A., LL.D., Head Master of the Ladies’ College, 19 Fettes Row, Edinburgh * Pullar, J. F., Rosebank, Perth 325 © * Pullar, Robert, Tayside, Perth Ramsay, E. Peirson, F.LS., F.R.G.S., F.G.S., Curator of Australian Museum, Sydney, New South Wales * Rattray, James Clerk, M.D., 61 Grange Loan * Rattray, John, M.A., B.Sc., 15 Scotland Street Raven, Rev. Thomas Milville, M.A., The Vicarage, Crakehall, Bedale 330 * Readman, J. B., 9 Moray Place * Richardson, Ralph, W.S., 10 Magdala Place Ricarde-Seaver, Major F. Ignacio, Conservative Club, St James’ Street, London, S.W., and 2 Rue Lafitte, Boulevard des Italiens, Paris * Ritchie, R. Peel, M.D., F.R.C.P.E., 1 Melville Crescent * Roberton, James, LL.D., Professor of Conveyancing in the University of Glasgow, 1 Park Terrace East, Glasgow 335 Roberts, D. Lloyd, M.D., F.R.C.P.L., 23 St John Street, Manchester * Robertson D. M. C. L. Argyll, M.D., F.R.C.8.E., Surgeon Oculist to the Queen for Scot- land, and President of the Royal College of Surgeons, 18 Charlotte Square Robertson, George, Memb. Inst. C.E., Atheneum Club, Pall Mall, London * Robertson, J. P. B., Q.C., M.P., 19 Drumsheugh Gardens * Robinson, George Carr, F.1I.C., Lecturer on Chemistry in the Royal Institution, Hull 340 * Rogerson, John Johnston, B.A., LL.B., Merchiston Castle Academy Ronalds, Edmund, LL.D., Bonnington House, Bonnington Road Rosebery, The Right Hon. the Earl of, LL.D., Dalmeny Rowland, L. L., M.A., M.D., President of the Oregon State Medical Society, and Professor of Physiology and Microscopy in Williamette University, Salem, Oregon Russell, Alexander James, C.S., 9 Shandwick Place 345 * Russell, J. A., M.A., B.Sc,, M.B., F.R.C.P.E., Woodville, Canaan Lane * Rutherford, Wm., M.D., F.R.C.P.E., F.R.S., Professor of the Institutes of Medicine in the University of Edinburgh, 14 Douglas Crescent * Sanderson, James, Deputy Inspector-General of Hospitals, F.R.C.S.E., 8 Manor Place Sandford, The Right Rev. D. F., LL.D., Bishop of Tasmania Sang, Edward, C.E., LL.D., Secretary to the Royal Scottish Society of Arts, 31 Mayfield Road 350 Schmitz, Leonard, LL.D., 81 Linden Gardens, London, W. Scott, Alexander, M.A., D.Sc., 4 North Bailey, Durham Scott, J. H., M.B., C.M., M.R.C.S., Professor of Anatomy in the University of Otago, New Zealand | Scott, Michael, Memb. Inst. C.E., 22 Mount Ephraim, Tunbridge Wells 7 ALPHABETICAL LIST OF THE ORDINARY FELLOWS OF THE SOCIETY. 665 Date of Election. 1864 1872 1872 1870 1871 1859 1876 1868 1882 1885 1883 1871 1855 1886 1871 - 1880 1846 1880 1882 1874 1850 1885 1886 1884 1877 1868 1848 1868 1878 1866 1873 1848 1877 1823 1870 1848 1844 1875 1885 * Sellar, W. Y., M.A., LL.D., Professor of Humanity in the University of Edinburgh, 15 Buckingham Terrace 355 * Seton, George, M.A., Advocate, 42 Greenhill Gardens * Sibbald, John, M.D., Commissioner in Lunacy, 3 St Margaret’s Road, Whitehouse Loan * Sime, James, M.A., South Park, Fountainhall Road * Simpson, A. R., M.D., F.R.C.P.E., Professor of Midwifery in the University of Edinburgh, 52 Queen Street Skene, Wm. F., W.S., LL.D., D.C.L., Historiographer-Royal for Scotland, 27 Inver- leith Row 360 * Skinner, William, W.S., Town-Clerk of Edinburgh, 35 George Square * Smith, Adam Gillies, C.A. (TREASURER), 64 Princes Street Smith, C. Michie, B.Se., Professor of Physical Science, Christian College, Madras, India * Smith, George, F.C.8., Polmont Station, N.B. Smith, James Greig, M.A., M.B., 16 Victoria Square, Clifton 365 * Smith, John, M.D., LL.D., F.R.C.S.E., 11 Wemyss Place Smith, Robert Mackay, 4 Bellevue Crescent * Smith, Colonel R. Murdoch, R.E., Director of Museum of Science and Art, Edinburgh * Smith, Rev. W. Robertson, M.A., LL.D., Librarian to the University of Cambridge Smith, W. Robert, M.D., 74 Great Russell Street, Bloomsbury Square, London 370 Smyth, Piazzi, Professor of Practical Astronomy in the University of Edinburgh, and Astronomer-Royal for Scotland, 15 Royal Terrace Sollas, W. J., M.A., D.Se., late Fellow of St John’s College, Cambridge, and Professor of Geology and Mineralogy in the University of Dublin, 4 Clyde Road, Dublin * Sorley, James, F.F.A., C.A., 2 Dean Park Crescent * Sprague, T. B., M.A., 29 Buckingham Terrace Stark, James, M.D., F.R.C.P.E., of Huntfield, Underwood, Bridge of Allan 375 * Steggall, J. E. A., Prof. of Mathematics and Natural Philosophy in University Coll., Dundee * Stevenson, C. A., B.Sc., C.E., 45 Melville Street * Stevenson, David Alan, B.Sc., C.E., 45 Melville Street * Stevenson, James, F.R.G.S., 4 Woodside Crescent, Glasgow Stevenson, John J., Red House, Bayswater Hill, London, W. 380 Stevenson, Thomas, Memb. Inst. C.E., F.G.S. (Honorary Vice-PRESIDENT), 84 George Street Stewart, Colonel J. H. M. Shaw, Royal Engineers, Madras * Stewart, James R., M.A., 10 Salisbury Road * Stewart, T. Grainger, M.D., F.R.C.P.E., Professor of the Practice of Physic in the University of Edinburgh, 19 Charlotte Square * Stewart, Walter, 22 Torphichen Street 385 Stirling, Patrick J., LL.D., Kippendavie House, Dunblane * Stirling, William, Sc.D., M.D., Brackenbury Professor of Physiology and Histology in Owens College and Victoria University, Manchester Stuart, Captain T. D., H.M.LS. * Swan, Patrick Don, Provost of Kirkcaldy Swan, Wm., LL.D., Emeritus Professor of Natural Philosophy in the University of St Andrews, President of the Royal Scottish Society of Arts, Ardchapel, Helensburgh 390 Swinton, A. Campbell, of Kimmerghame, LL.D., Duns Syme, James, 9 Drumsheugh Gardens * Symington, Johnson, M.B., F.R.C.S.E., 2 Greenhill Park 666 ALPHABETICAL LIST OF THE ORDINARY FELLOWS OF THE SOCIETY. Date of Election. 1872 1861 1870 1872 1873 1885 1884 1870 1875 1880 1863 1870 1847 1882 1870 1876 1878 1874 1874 1879 1861 1877 1875 1867 1873 1886 1864 1883 1870 1866 1866 1862 1873 1840 1882 1876 1881 | ROE K.P. NEE. Die Tait, the Rev. A., D.D., LL.D.,Canon of Tuam, Moylough Rectory, Ballinasloe, Ireland Tait, P. Guthrie, M.A., Professor of Natural Philosophy in the University of Edinburgh — (GENERAL SECRETARY), 38 George Square 395 * Tatlock, Robert R., City Analyst's Office, 138 Bath Street, Glasgow * Teape, Rev. Charles R., M.A., Ph.D., 15 Findhorn Place * Tennent, Robert, 23 Buckingham Terrace * Thompson, D’Arcy W., Professor of Natural History in University College, Dundee * Thoms, George Hunter, of Aberlemno, Advocate, Sheriff of the Counties of Orkney and Zetland, 13 Charlotte Square 400 * Thomson, Rev. Andrew, D.D., 63 Northumberland Street * Thomson, James, LL.D., F.R.S., Professor of Engineering in the University of Glasgow, 2 Florentine Gardens, Hillhead, Glasgow Thomson, John Millar, King’s College, London : * Thomson, Murray, M.D., Professor of Chemistry, Thomason College, Ltoorkee, India ; * Thomson, Spencer C., Actuary, 10 Chester Street 405 Thomson, Sir William, LL.D., D.C.L., F.R.S. (Presipnnt), Regius Professor of Natural Philosophy in the University of Glasgow, Foreign Associate of Institute of Franee, and Member of the Prussian Order Pour le Mérite : Thomson, William, M.A., B.Sc., Professor of Mathematics in University College, Stellen- bosch, Cape Colony * Thomson, Wm. Burns, F.R.C.P.E., F.R.C.S.E., 110 Newington Green Road, London, N. Thomson, William, Royal Institution, Manchester Thorburn, Robert Macfie, Uddevalla, Sweden 410 * Traquair, R. H., M.D., F.R.S., F.GS., Keeper of the Natural History Collections in the Museum of Science and Art, Edinburgh, 8 Dean Park Crescent * Tuke, J. Batty, M.D., F.R.C.P.E., 20 Charlotte Square * Turnbull, John, of Abbey St Bathans, W.S., 49 George Square Turner, Sir William, M.B., F.R.C.S.E., F.R.S., Professor of Anatomy in the University of Edinburgh, and President of the Royal Physical Society (SzcrErary), 6 Eton Terrace * Underhill, Charles E., B.A., M.B., F.R.C.P.E., F.R.C.S.E., 8 Coates Crescent 415 Vincent, Charles Wilson, Royal Institution, Albemarle Street, London * Waddell, Peter, 5 Claremont Park, Leith * Walker, Robert, M.A., University, Aberdeen * Wallace, Robert, Professor of Agriculture and Rural Economy in the University of Edin. * Wallace, William, Ph.D., City Analyst’s Office, 138 Bath Street, Glasgow 420 * Watson, Charles, Redhall, Slateford ; * Watson, James, C.A., 45 Charlotte Square * Watson, John K., 14 Blackford Road * Watson, Patrick Heron, M.D., F.R.C.P.E., F.R.C.S.E., LL.D., 16 Charlotte Square Watson, Rev. Robert Boog, B.A., Free Church Manse, Cardross, Dumbartonshire 425 Welsh, David, Major-General (Retired), R.A., 1 Barton Terrace, Dawlish Welwood, Allan A. Maconochie, LL.D., of Meadowbank and Garvoch, Kirknewton * Wenley, James A., Treasurer of the Bank of Scotland, 5 Drumsheugh Gardens White, Rev. Francis Le Grix, M.A., F.G.S., Leaming-on-Ulleswater, Penrith Whitehead, Walter, F.R.C.S.E., 202 Oxford Road, Manchester 430 ALPHABETICAL LIST OF THE ORDINARY FELLOWS OF THE SOCIETY. 667 Date of Election. 1883 Wickham, R. H. B., F.R.C.S.E., Borough Lunatic Asylum, Newcastle-on-Tyne 1879 * Will, John Charles Ogilvie, M.D., 305 Union Street, Aberdeen 1868 * Williams, W., Principal and Professor of Veterinary Medicine and Surgery, New Veterinary College, Leith Walk 1879 * Wilson, Andrew, Ph.D., Lecturer on Zoology and Comparative Anatomy in the Edinburgh Medical School, 118 Gilmore Place : 1877 * Wilson, Charles E., M.A., LL.D., H.M. Senior Inspector of Schools for Scotland, 19 Palmerston Place 435 1878 * Wilson, Rev. John, M.A., Bannockburn Academy 1875 Wilson, Daniel, LL.D., President of the University of Toronto, and Professor of English Literature in that University 1882 Wilson, George, M.A., M.D., 23 Claremont Road, Leamington 1834 Wilson, Isaac, M.D. 1847 Wilson, John, LL.D., Emeritus Professor of Agriculture in the University of Edinburgh 440 1870 Winzer, John, Chief Surveyor, Civil Service, Ceylon, 7 Dryden Place, Newington 1880 * Wise, Thos. Alex., M.D., F.R.C.P.E., F.R.A.S., Thornton, the Beulah, Upper Norwood 1886 * Woodhead, German Sims, M.D., 6 Marchhall Crescent 1884 Woods, G. A., M.R.C.S., Carlton House, 57 Houghton Street, Southport 1864 * Wyld, Robert S., LL.D , 19 Inverleith Row 445 1882 * Young, Andrew, 22 Elm Row 1882 * Young, Frank W., F.C.S., Lecturer on Natural Science, High School, Dundee, Woodmuir Park, West Newport, Fife 1882 * Young, Thomas Graham, Durris, Aberdeenshire 448 668 APPENDIX—LIST OF HONORARY FELLOWS. LIST OF HONORARY CEE LORS AT NOVEMBER 1884. His Royal Highness The PRINCE OF WEES. FOREIGNERS (LIMITED TO THIRTY-SIX BY LAW X.). Elected. 1884 Pierre J. van Beneden, 1864 Robert Wilhelm Bunsen, 1867 Michel Eugéne Chevreul, 1858 James D. Dana, 1877 Alphonse de Candolle, 1883 Luigi Cremona, 1879 Franz Cornelius Donders, 1877 Carl Gegenbaur, 1879 Asa Gray, 1883 Julius Hann, 1884 Charles Hermite, Louvain. Heidelberg. Paris. New Haven, Conn. Geneva. Rome. Utrecht. Heidelberg. Harvard University. Vienna. Paris. 1864 Hermann Ludwig Ferdinand von Helmholtz, Berlin. 1879 Jules Janssen, 1875 August Kekulé, 1868 Gustav Robert Kirchhoff, 1875 Hermann Kolbe, 1864 Albert Kolliker, 1875 Ernst Eduard Kummer, 1876 Ferdinand de Lesseps, 1864 Rudolph Leuckart, 1881 Seven Lovén, 1876 Carl Ludwig, 1878 J. N. Madvig, 1855 Henry Milne-Edwards, 1864 Theodore Mommsen, 1881 Simon Newcomb, 1874 Louis Pasteur, | 1864 Carl Theodor von Siebold, 1881 Johannes Japetus Smith Steenstrup, 1878 Otto Wilhelm Struve, 1855 Bernard Studer, 1874 Otto Torell, 1868 Rudolph Virchow, 1874 Wilhelm Eduard Weber, Total, 34. Paris. Bonn. Berlin. Leipzig. Wurzburg. Berlin. Paris. Leipzig. Stockholm. Leipzug. Copenhagen. Paris. Berlin. Washington. Paris. Munich. Copenhagen. Pulkowa. Bern. Lund, Berlin. Gottingen. APPENDIX——-LIST OF HONORARY FELLOWS. 669 BRITISH SUBJECTS (LIMITED TO TWENTY BY LAW Xa): Elected. 1849 John Couch Adams, LL.D., F.R.S., Corresp. Mem. Inst. France, Cambridge. 1835 Sir George Biddell Airy, K.C.B., M.A., LL.D., D.C.L., F.R.S., Foreign Associate Inst, France, Greenwich. 1870 Thomas Andrews, M.D., LL.D., F.R.S., Belfast. 1865 Arthur Cayley, LL.D., D.C.L., F.R.S., Corresp. Mem. Inst. France, Cambridge. 1884 Edward Frankland, D.C.L., LL.D., F.R.S., London. 1874 John Anthony Froude, LL.D., London. 1881 The Hon. Justice Sir William Robert Grove, M.A., LL.D., DCs EERSS:, London. 1883 Sir Joseph Dalton Hooker, K.C.S.I., C.B., M.D., D.C.L., LL.D., F.R.S., F.G.S., Corresp. Mem. Inst. France, Director of the Royal Gardens, Kew, London. 1884 William Huggins, LL.D., D.C.L., F.R.S., London. 1876 Thomas Henry Huxley, LL.D., D.C.L., P.R.S., F.LS., F.LS., F.G.S., Corresp. Mem. Inst. France, London. 1867 James Prescott Joule, LL.D., D.C.L., F.R.S., Corresp. Mem. Inst. France, Manchester. 1845 Sir Richard Owen, K.C.B., M.D., LL.D., D.C.L., F.R.S., Foreign Associate Inst, France, London. 1881 The Rev. George Salmon, D.D., LL.D., D.C.L., F.R.S., Foreign Associate of the Institute of France, Dublin. 1884 J. S. Burdon Sanderson, M.D., LL.D., F.R.S., Oxford. 1878 Balfour Stewart, M.A., LL.D., F.R.S., Manchester. 1864 George Gabriel Stokes, M.A., LL.D., D:C.L., Sec. R.S., Corresp. Mem. Inst. France, Cambridge. 1874 James Joseph Sylvester, M.A., LL.D., F.R.S., Corresp. Mem. Inst. France, Oxford. 1864 The Right Hon. Lord Tennyson, D.C.L., LL.D., F.R.S., Poet Laureate, Isle of Wight. 1883 Alexander William Williamson, LL.D., F.R.S., V.P.C.S., Corresp. Mem. Inst. France, London. 1883 Colonel Henry Yule, C.B., LL.D., Member of the Council of India, London. Total, 20. 670 APPENDIX—LIST OF HONORARY FELLOWS. LIST OF HONORARY FELLOWS AT NOVEMBER 1885. His Royal Highness The PrINcE oF WALES. FOREIGNERS (LIMITED TO THIRTY-SIX BY LAW X,), Elected. 1884 Pierre J. van Beneden, 1864 Robert Wilhelm Bunsen, 1867 Michel Eugéne Chevreul, 1858 James D. Dana, 1877 Alphonse De Candolle, 1883 Luigi Cremona, 1879 Franz Cornelius Donders, 1877 Carl Gegenbaur, 1879 Asa Gray, 1883 Julius Hann, 1884 Charles Hermite, 1864 Hermann Ludwig Ferdinand von Helmholtz, 1879 Jules Janssen, 1875 August Kekulé, 1868 Gustav Robert Kirchhoff, 1875 Hermann Kolbe, 1864 Albert Kolliker, 1875 Ernst Eduard Kummer, 1876 Ferdinand de Lesseps, 1864 Rudolph Leuckart, 1881 Sven Lovén, 1876 Carl Ludwig, 1878 J. N. Madvig, 1864 Theodore Mommsen, 1881 Simon Newcomb, 1874 Louis Pasteur, 1881 Johannes Iapetus Smith Steenstrup, 1878 Otto Wilhelm Struve, 1855 Bernard Studer, 1874 Otto Torell, 1868 Rudolph Virchow, 1873 Wilhelm Eduard Weber, Total, 32. Louvain. Heidelberg. Paris. New Haven, Conn. Geneva. Rome. Utrecht. Heidelberg. Harvard University. Vienna. Paris. Berlin. Paris. Bonn. ‘Berlin. Leipzig. Wurzburg. Berlin. Paris. Leipxg. Stockholm. Leipzig. Copenhagen. Berlin. Washington. Paris. Copenhagen. Pulkowa. Bern. Lund. Berlin. Gottingen. APPENDIX—LIST OF HONORARY FELLOWS. BRITISH SUBJECTS (LIMITED TO TWENTY BY LAW X.). Elected. 1849 John Couch Adams, LL.D., F.R.S., Corresp. Mem. Inst. France, 1835 Sir George Biddell Airy, K.C.B., M.A., LL.D., D.C.L., F.B.S., Foreign Associate Inst. France, 1870 Thomas Andrews, M.D., LL.D., F.B.S., 1865 Arthur Cayley, LL.D., D.C.L., F.R.S., Corresp. Mem. Inst. France, 1884 Edward Frankland, D.C.L., LL.D., F.R.S., 1874 John Anthony Froude, LL.D., 1881 The Hon. Justice Sir William Robert Grove, M.A., LL.D., mC; HRS. 1883 Sir Joseph Dalton Hooker, K.C.S.1., C.B., M.D., D.C.L., LL.D., F.R.S., F.G.8., Corresp. Mem. Inst. France, Director of the Royal Gardens, Kew, 1884 William Huggins, LL.D., D.C.L., F.R.S., 1876 Thomas Henry Huxley, LL.D., D.C.L, F.RS., F.LS., F.Z.S., F.G.S., Corresp. Mem. Inst. France, 1867 James Prescott Joule, LL.D., D.C.L, F.R.S., Corresp. Mem. Inst. France, 1845 Sir Richard Owen, K.C.B., M.D., LL.D., D.C.L, F.R.S., Foreign Associate Inst. France, 1881 The Rev. George Salmon, D.D., LL.D., D.C.L, F.R.S., Foreign Associate of the Institute of France, 1884 J. S. Burdon Sanderson, M.D., LL.D., F.B.S., 1878 Balfour Stewart, M.A., LL.D., F.R.S., 1864 George Gabriel Stokes, M.A., LL.D., D.C.L., Sec. R.S., Corresp. Mem. Inst. France, 1874 James Joseph Sylvester, M.A., LL.D., F.R.S., Corresp. Mem. Inst. France, 1864 The Right Hon. Lord Tennyson, D.C.L., LL.D., F.R.S., Poet Laureate, 1883 Alexander William Williamson, LL.D., F.R.S., V.P.C.S., Corresp. Mem. Inst. France, 1883 Colonel Henry Yule, C.B., LL.D., Member of the Council of India, Total, 20. VOL, XXXII. PART IV. Cambridge. Greenwich, Belfast. Cambridge. London. London. London. London. London. London. Manchester. London. Dublin. Oxford. Manchester. Cambridge. Oxford. Isle of Wight. London. London. 671 672 APPENDIX.—LIST OF HONORARY FELLOWS. LIST OF HONORARY FELLOWS AT NOVEMBER 1886. His Royal Highness The PRINCE oF WALES, FOREIGNERS (LIMITED TO THIRTY-SIX BY LAW x) Elected. 1884 Pierre J. van Beneden, Louvain. 1864 Robert Wilhelm Bunsen, Heidelberg. 1867 Michel Eugéne Chevreul, Paris. 1858 James D. Dana, New Haven, Conn. 1877 Alphonse De Candolle, Geneva. 1883 Luigi Cremona, Rome. 1879 Franz Cornelius Donders, Utrecht. 1877 Carl Gegenbaur, Heidelberg 1879 Asa Gray, Harvard University. 1883 Julius Hann, Vienna. 1884 Charles Hermite Paris. 1864 1879 Jules Janssen, Paris. 1875 August Kekulé, Bonn. 1868 Gustav Robert Kirchhoff Berlin. 1875 Hermann Kolbe, Leipzig. 1864 Albert Kolliker, Wiirzburg. 1875 Ernst Eduard Kummer, Berlin. 1876 Ferdinand de Lesseps, Paris. 1864 Rudolph Leuckart, Leipzig. 1881 Sven Lovén, Stockholm. 1876 Carl Ludwig, Leipzig. 1878 J. N. Madvig, Copenhagen. 1886 Alphonse Milne-Edwards, Paris. 1864 Theodore Mommsen, Berlin. 1881 Simon Newcomb, Washington. 1886 H. A. Newton, Yale College. 1874 Louis Pasteur, Paris. 1886 L’Abbé Renard, Louvain. 1881 Johannes Iapetus Smith Steenstrup, Copenhagen. 1878 Otto Wilhelm Struve, Pulkowa. 1855 Bernard Studer, Bern. 1886 Tobias Robert Thalen, Upsala. 1874 Otto Torell, Lund, 1868 Rudolph Virchow, Berlin. 1874 Wilhelm Eduard Weber, Gottingen. Hermann Ludwig Ferdinand von Helmholtz, Berlin. Total, 36. APPENDIX.—LIST OF HONORARY FELLOWS. BRITISH SUBJECTS (LIMITED TO TWENTY BY LAW X.). Elected. 1849 John Couch Adams, LL.D., F.R.S., Corresp. Mem. Inst. France, 1835 Sir George Biddell Airy, K.C.B., M.A., LL.D., D.C.L., F.RB.S., Foreign Associate Inst., France, 1865 Arthur Cayley, LL.D., D.C.L., F.R.S., Corresp. Mem. Inst. France, 1884 Edward Frankland, D.C.L., LL.D., F.B.S., 1874 John Anthony Froude, LL.D., 1881 The Hon. Justice Sir William Robert Grove, M.A., LL.D., DC. L., E.B.S., 1883 Sir Joseph Dalton Hooker, K.C.S.I., C.B., M.D., D.C.L., LL.D., F.R.S., F.G.S., Corresp. Mem. Inst. France, 1884 William Huggins, LL.D., D.C.L., F.RB.S., 1876 Thomas Henry Huxley, LL.D., D.C.L., F.RS., F.LS., F.Z.S., F.G.S., Corresp. Mem. Inst. France, 1867 James Prescott Joule, LL.D., D.C.L., F.R.S., Corresp. Mem. Inst. France, 1845 Sir Richard Owen, K.C.B., M.D., LL.D., D.C.L., F.R.S., Foreign Associate Inst. France, 1886 The Lord Rayleigh, D.C.L., LL.D., Sec. R.S., 1881 The Rev. George Salmon, D.D., LL.D., D.C.L., F.R.S., Foreign Associate of the Institute of France, 1884 J. S. Burdon Sanderson, M.D., LL.D., F.R.S., 1878 Balfour Stewart, M.A., LL.D., F.R.S., 1864 George Gabriel Stokes, M.A., LL.D., D.C.L., Pres. R.S., Corresp. Mem. Inst. France, 1874 James Joseph Sylvester, M.A., LL.D., F.R.S., Corresp. Mem. Inst. France, 1864 The Right Hon. Lord Tennyson, D.C.L., LL.D., F.R.S., Poet Laureate, 1883 Alexander William Williamson, LL.D., F.R.S., V.P.C.S., Corresp. Mem. Inst. France, 1883 Colonel Henry Yule, C.B., LL.D., Member of the Council of India, Total, 20. Cambridge. Greenwich. Cambridge. London. London, London. London. London. London. Manchester. London. London. Dublin. Oxford. Manchester. Cambridge. Oxford. Isle of Wight. London. London. 673 674 APPENDIX.—LIST OF MEMBERS ELECTED. ORDINARY FELLOWS ELECTED Durina SEssion 1883-84, ARRANGED ACCORDING TO THE Dare or THEIR ELxcrion. 7th January 1884. Francis T. Bonp, M.D., B.A. 4th February 1884. Gzorcr M. Low, Actuary. Rev. J. Gorpon Macruersoy, M.A., D.Sc. Dr Freperick HunGERFORD BowMaAN, Cuartes Scorr Dickson, Advocate. F.R.A.S. Rosert TRAIL Omonp. 3rd March 1884. G. A. Woops, M.R.C.S. Ricuarp Davy, M.D. Joun Grirve, M.A., M.D. 7th April 1884. James Tart Buack. FE. Perrson Ramsay, F.L.8. bth May 1884. Professor JospPH SHIELD NICHOLSON. Rey. J. S. Buack. Joun Hernperson, Jun. ond June 1884. J. T. Cunnineuay, B.A. 7th July 1884. Davin ALAN StEvENSON, B.Sc., C.F. Guorce Hunter MacTuomas Tuoms, of R. W. Myint, C.E., F.R.S. Aberlemno, Sheriff of Caithness, Orkney, W. Evans, F.F.A. and Zetland. APPENDIX.—LIST OF MEMBERS ‘DECEASED, ETC. 675 FELLOWS DECEASED, RESIGNED, OR CANCELLED, Durine Session 1883-84. DECEASED. Professor Joun Hutron BaLrour. C. H. Mituar of Blaircastle. The DuKe or Bucctevucn. JOSEPH MITCHELL. Isaac ANDERSON HeEnry. Dr Attan THOMSON. Ex-Provost Linpsay of Leith. Dr ALEXANDER Woop. RESIGNED. ALEXANDER Howe, W.S. CANCELLED. Francis W. Mornet, M.D. ELECTION OF HONORARY FELLOWS. FOREIGN HONORARY FELLOWS. 16th June 1884. M. Cuartes HERMITE, Paris. M. Pisrre J. vaN BENEDEN, Louvain. BRITISH HONORARY FELLOWS. 7th July 1884. Professor E. FRanKLAND, D.C.L., LL.D., F.R.S. Wuti1am Hueerns, D.C.L., LL.D., F.R.S. Professor Burpon Sanperson, M.D., LL.D., F.R.S. FOREIGN HONORARY FELLOWS DECEASED. Session 1883-84. JEAN Baptiste Dumas. RicHarp Lepsius. CHARLES ADOLPHE WURTZ. 676 APPENDIX.—LIST OF MEMBERS ELECTED. ORDINARY FELLOWS ELECTED Durine Session 1884-85, ARRANGED ACCORDING TO THE DATE OF THEIR ELECTION. lst December 1884. H. Brttyse Barnpon, B.A. RoBeRT CHAMBERS. Cuarues M‘Bripg, M.D. 2nd February 1885. Professor W. R. Hopexrnson. JoHN Ratrray, M.A., B.Se. Hueu Rosert Mitt, B.Sc. Witiram Miter, 8.8.C. ALFRED DanieuL, M.A., LL.B., D.Sc. 2nd March 1885. Professor EuGar. Orme Masson, D.Sc. J. M. Macraruang, D.Se. 6th April 1885. Professor J. E. A. STEGGALL. Rk. J. Harvey Grpson, M.A. James Prince, Provost of Leith. Professor Dycr Davipson, M.D. A. P. Lauri, B.Sc. Georce SmitH, F.C.S. 4th May 1885. Jounson Symineton, M.B., F.R.C.S.E. Professor J. M. Drxon. J. F. Punwar. J. Macponatp Brown, M.B., F.R.C.S. lst June 1885. Professor D’Arcy W, THompson. A. Y. Fraser, M.A. ALEXANDER Scott, M.A., D.Se. APPENDIX.—LIST OF MEMBERS DECEASED, ETC. 677 FELLOWS DECEASED OR RESIGNED DurinG Session 1884-85. DECEASED. Sir James Anexanper, K.C.B. J. W. Larpuay of Seacliffe. _W. Linpsay Atexanner, D.D. Joun Macnair. T. C. ArcHER, Museum of Science and Art. James Napier of Partick. Aveustus J. D. Cameron, M. Inst. C.E. Rev. Francis Reprorp, M.A. Francis Brown Doveuas, Advocate. Major-General A. CunNINGHAM ROBERTSON. FREDERICK Fieup, F.R.S. Professor Morrison Watson, M.D. Principal Sir ALEXANDER Grant, Bart. Water Wetpoy, F.R.S. Professor H. C. Fizeminc Jenxy, F.R.S. Tuomas Wricuat, M.D. RESIGNED. R. K. Gattoway, Esq., B.A. Joun Dick Peppiz, Esq. FOREIGN HONORARY FELLOWS DECEASED. Session 1884-85. Heyry Mitve-Epowarps. Karu THEODOR VON SIEBOLD. 678 APPENDIX.—LIST OF MEMBERS ELECTED. ORDINARY FELLOWS ELECTED Durine Session 1885-86, ARRANGED ACCORDING TO THE DATE OF THEIR ELECTION. 7th December 1885. Dr A. B. Grirritus, F.C.S., School of Davip Cunnineuay, M. Inst. C.K, Science of the City and County of Danie, M. Connan, M.A., Education Leicester. Department, Cape Town. 4th January 1886. A. J. G, Barctay, M.A. lst February 1886. The Right Hon. J. H. A. Macponatp. Artuur W. Hare, M.B., C.M. Professor Freprrick O. Bower. GzorcE Fossery Lystur, M. Inst. C,E. Rosert Irvine. D. Nort Paton, M.D., B.Sc. GERMAN Sims Woopueap, M.D. Rey. Grorcr Laine. Wituiam J. Macponatp, M.A. lst March 1886. Hucu Mitime, H.M. Geological Survey. Professor GrorcE FREDERICK ARMSTRONG, Joun Ricuarp Brirties, M. Inst. C.E. M.A., F.G.S. The Right Hon. Sir Tuomas Cxark, Bart., ArtTuur ANDERSON, C.B., M.D. Lord Provost. ALEXANDER Gipson, Advocate. Professor Ropert WALLACE. Colonel R. Murpoca Smiru. The Right Hon. the Hart or Happrineton. 5th April 1886. A. Beatson Bett, Chairman of Prison Joun Hatuipay Croom, M.D. Commissioners. D. Bruce Prrsies. J. P. B. Ropertson, Q.C., M.P. C. Leopotp Frsxp, F.C.S. Rev. J. MacGrecor, D.D. 3rd May 1886. — Cuartes Freperick Pottock, M.D., Byrom Bramwe tt, M.D. F.R.C.S.E. C. A. Stnvenson, B.Sc., F.R.C.P.E. Professor GREENFIELD. Wittram Mitnp, M.A., B.Se. 7th June 1886. James Ouiver, M.B., M.R.C.P. Lond. 5th July 1886. Rogzert Kinston, F.G.S. Rev. H. G. Bonavia Hunt, Mus. B, Oxon., ERAS. FL. APPENDIX.—LIST OF MEMBERS DECEASED, ETC. FELLOWS DECEASED OR RESIGNED DurinG SEsston 1885-86. DECEASED. Sir Jonn Anverson, LL.D. * ALEXANDER Hamitton, LL.B., W.S. The Right Rev. Bishop Corrrrit1, D.D., Cosmo Gorpon Loain, M.D. LL.D. Aneus Macponatp, M.D., F.R.C.P.E. James ‘I’. Grpson-Craic, W.S. GrarEmMe Rem Mercer of Gorthie. Professor A. Dyce Davipson, M.A., M.D. JouN MILnr. James Dunsmury, M.D., F.R.C.S.E. JouN Mitroy of Torsonce. W. Mitcuett Extis, Advocate. Davin Stevenson, M. Inst. C.E. J. SAMPSON GAMGEE. Witiam TURNBULL. Freperick Guturin, M.A., F.R.S. Tuomas Wiiamson, M.D., F.R.C.S.E. * Died 1st January 1884. Death only intimated on 17th June 1886. RESIGNED. Grorce F. Barsour of Bonskeid, BRITISH HONORARY FELLOW DECEASED. Susston 1885-86, Tuomas AnpREws, M.D., LL.D., F.R.S. VOL XXXII. PART IV. 5 Y 679 LAWS OF THE ROYAL SOCIETY OF EDINBURGH, AS REVISED 20TH FEBRUARY 1882. ( 683 ) bck W 5. [ By the Charter of the Society (printed in the Transactions, Vol. VI. p. 5), the Laws cannot be altered, except at a Meeting held one month after that at which the Motion for alteration shall have been proposed. | i: THE ROYAL SOCIETY OF EDINBURGH shall consist of Ordinary and Honorary Fellows. 7 ie Every Ordinary Fellow, within three months after his election, shall pay Two Guineas as the fee of admission, and Three Guineas as his contribution for the Session in which he has been elected ; and annually at the commencement of every Session, Three Guineas into the hands of the Treasurer. This annual contribution shall continue for ten years after his admission, and it shall be limited to Two Guineas for fifteen years thereafter.* III. All Fellows who shall have paid Twenty-five years’ annual contribution shall be exempted from farther payment. IV. The fees of admission of an Ordinary Non-Resident Fellow shall be £26, 5s., payable on his admission ; and in case of any Non-Resident Fellow coming to reside at any time in Scotland, he shall, during each year of his residence, pay the usual annual contribution of £3, 3s., payable by each Resident Fellow ; but after payment of such annual contribution for eight years, he shall be exempt * A modification of this rule, in certain cases, was agreed to at a Meeting of the Society held on the 8rd January 1831. At the Meeting of the Society, on the 5th January 1857, when the reduction of the Contribu- tions from £3, 3s. to £2, 2s., from the 11th to the 25th year of membership, was adopted, it was resolved that the existing Members shall share in this reduction, so far as regards their future annual Contributions. Title. The fees of Ordi- nary Fellows resid- ing in Scotland. Payment to cease after 25 years. Fees of Non-Resi- dent Ordinary Fellows. se of Fellows oming Non- sident. faulters. vileges of linary Fellows. mbers Un- ited. lows entitled l'ransactions. le of Recom- iding Ordinary lows. ‘ 684 LAWS OF THE SOCIETY. from any farther payment. In the case of any Resident Fellow ceasing to reside in Scotland, and wishing to continue a Fellow of the Society, it shall be in the power of the Council to determine on what terms, in the circumstances of each case, the privilege of remaining a Fellow of the Society shall be continued to such Fellow while out of Scotland. V; Members failing to pay their contributions for three successive years (due application having been made to them by the Treasurer) shall be reported to the Council, and, if they see fit, shall be declared from that period to be no longer Fellows, and the legal means for recovering such arrears shall be employed. VI. None but Ordinary Fellows shall bear any office in the Society, or vote in the choice of Fellows or Office-Bearers, or interfere in the patrimonial interests of the Society. Al al The number of Ordinary Fellows shall be unlimited. VIII. The Ordinary Fellows, upon producing an order from the TREASURER, shall be entitled to receive from the Publisher, gratis, the Parts of the Society’s Transactions which shall be published subsequent to their admission. Lx Candidates for admission as Ordinary Fellows shall make an application in writing, and shall produce along with it a certificate of recommendation to the purport below,* signed by at least /owr Ordinary Fellows, two of whom shall certify their recommendation from personal knowledge. This recommendation shall be delivered to the Secretary, and by him laid before the Council, and shall afterwards be printed in the circulars for three Ordinary Meetings of the Society, previous to the day of election, and shall lie upon the table during that time. * “A. B., a gentleman well versed in Science (or Polite Literature, as the case may be), being “to our knowledge desirous of becoming a Fellow of the Royal Society of Edinburgh, we hereby “recommend him as deserving of that honour, and as likely to prove a useful and valuable Member. © LAWS OF THE SOCIETY. 685 X. Honorary Fellows shall not be subject to any contribution. This class shall consist of persons eminently distinguished for science or literature. Its number shall not exceed Fifty-six, of whom Twenty may be British subjects, and Thirty- six may be subjects of foreign states. XI. Personages of Royal Blood may be elected Honorary Fellows, without regard to the limitation of numbers specified in Law X. XII. Honorary Fellows may be proposed by the Council, or by a recommenda- tion (in the form given below*) subscribed by three Ordinary Fellows ; and in case the Council shall decline to bring this recommendation before the Society, it shall be competent for the proposers to bring the same before a General Meeting. The election shall be by ballot, after the proposal has been commu- nicated viva voce from the Chair at one meeting, and printed in the circulars for two ordinary meetings of the Society, previous to the day of election. XT. The election of Ordinary Fellows shall only take place at the first Ordinary Meeting of each month during the Session. The election shall be by ballot, and shall be determined by a majority of at least two-thirds of the votes, pro- vided Twenty-four Fellows be present and vote. XIV. The Ordinary Meetings shall be held on the first and third Mondays of every month from December to July inclusively ; excepting when there are five Mondays in January, in which case the Meetings for that month shall be held on its third and fifth Mondays. Regular Minutes shall be kept of the proceedings, and the Secretaries shall do the duty alternately, or according to such agreement as they may find it convenient to make. * We hereby recommend ted eh Ea) dist) 2 Bom: for the distinction of being made an Honorary Fellow of this Society, declaring that each of us from our own knowledge of his services to (Literature or Science, as the case may be) believe him to be worthy of that honour. (To be signed by three Ordinary Fellows.) To the President and Council of the Royal Society of Edinburgh. Honorary Fellows, British and Foreign. Royal Personages. Recommendation of Honorary Fel- lows. Mode of Election, Election of Ordi- nary Fellows. Ordinary Meet- ings. . Transactions. vy Published. > Council. iring Council- be ction of Office- wrers. cial Meetings ; vy called, easurer’s Duties. 686 LAWS OF THE SOCIETY. XV. The Society shall from time to time publish its Transactions and Proceed- ings. For this purpose the Council shall select and arrange the papers which they shall deem it expedient to publish in the Z’ransactions of the Society, and shall superintend the printing of the same. The Council shall have power to regulate the private business of the Society. At any Meeting of the Council the Chairman shall have a casting as well as a deliberative vote. XVI. The Transactions shall be published in parts or Fasciculi at the close of each Session, and the expense shall be defrayed by the Society. XVII. That there shall be formed a Council, consisting—First, of such gentlemen as may have filled the office of President ; and Secondly, of the following to be annually elected, viz. :—a President, Six Vice-Presidents (two at least of whom shall be resident), Twelve Ordinary Fellows as Councillors, a General Secretary, Two Secretaries to the Ordinary Meetings, a Treasurer, and a Curator of the Museum and Library. | ) XVIII. Four Councillors shall go out annually, to be taken according to the order in which they stand on the list of the Council. XX: An Extraordinary Meeting for the Election of Office-Bearers shall be held on the fourth Monday of November annually. 2. Special Meetings of the Society may be called by the Secretary, by direction of the Council; or on a requisition signed by six or more Ordinary Fellows. Notice of not less than two days must be given of such Meetings. XXI. The Treasurer shall receive and disburse the money belonging to the Society, granting the necessary receipts, and collecting the money when due. He shall keep regular accounts of all the cash received and expended, which shall be made up and balanced annually ; and at the Extraordinary Meeting in November, he shall present the accounts for the preceding year, duly audited. i LAWS OF THE SOCIETY. 687 At this Meeting, the Treasurer shall also lay before the Council a list of all arrears due above two years, and the Council shall thereupon give such direc- tions as they may deem necessary for recovery thereof. ) ONE, At the Extraordinary Meeting in November, a professional accountant shall Auditor. be chosen to audit the Treasurer’s accounts for that year, and to give the neces- sary discharge of his intromissions. XXIII. The General Secretary shall keep Minutes of the Extraordinary Meetings of General Secretary’s the Society, and of the Meetings of the Council, in two distinct books. He ee shall, under the direction of the Council, conduct the correspondence of the Society, and superintend its publications. For these purposes he shall, when necessary, employ a clerk, to be paid by the Society. XXIV. The Secretaries to the Ordinary Meetings shall keep a regular Minute-book, secretaries to in which a full account of the proceedings of these Meetings shall be entered ; ON ee they shall specify all the Donations received, and furnish a list of them, and of the Donors’ names, to the Curator of the Library and Museum ; they shall like- wise furnish the Treasurer with notes of all admissions of Ordinary Fellows. They shall assist the General Secretary in superintending the publications, and in his absence shall take his duty. XXYV. The Curator of the Museum and Library shall have the custody and charge curator of Museum of all the Books, Manuscripts, objects of Natural History, Scientific Produc- “*'""* tions, and other articles of a similar description belonging to the Society ; he shall take an account of these when received, and keep a regular catalogue of the whole, which shall lie in the Hall, for the inspection of the Fellows. XXVI. All Articles of the above description shall be open to the inspection of the Use of Museum Fellows at the Hall of the Society, at such times and under such regulations, ““* “”"™"™ as the Council from time to time shall appoint. XXVII. A Register shall be kept, in which the names of the Fellows shall be Register Book. enrolled at their admission, with the date. VOL. XXXII. PART IV. 5 Z ( 688 ) THE KEITH, BRISBANE, AND NEILL PRIZES. The above Prizes will be awarded by the Council in the following manner :— I. KEITH PRIZE. The Kerrn Prize, consisting of a Gold Medal and from £40 to £50 in Money, will be awarded in the Session 1887-88 for the “best communication on a scientific subject, communicated, in the first instance, to the Royal Society during the Sessions 1885-86 and 1886-87.” Preference will be given to a paper containing a discovery. Il. MAKDOUGALL-BRISBANE PRIZE. This Prize is to be awarded biennially by the Council of the Royal Society of Edinburgh to such person, for such purposes, for such objects, and in such manner as shall appear to them the most conducive to the promotion of the interests of science; with the proviso that the Council shall not be compelled to award the Prize unless there shall be some individual engaged in scientific pursuit, or some paper written on a scientific subject, or some discovery in science made during the biennial period, of sufficient merit or importance in the opinion of the Council to be entitled to the Prize. 1. The Prize, consisting of a Gold Medal and a sum of Money, will be awarded at the commencement of the Session 1887-88, for an Essay or Paper having reference to any branch of scientific inquiry, whether Material or Mental. 2. Competing Essays to be addressed to the Secretary of the Society, and transmitted not later than 1st June 1888. 3. The Competition is open to all men of science. APPENDIX.—KEITH, MAKDOUGALL-BRISBANE, AND NEILL PRIZES. 689 4, The Essays may be either anonymous or otherwise. In the former case, they must be distinguished by mottoes, with corresponding sealed billets, super- scribed with the same motto, and containing the name of the Author. 5. The Council impose no restriction as to the length of the Essays, which may be, at the discretion of the Council, read at the Ordinary Meetings of the Society. They wish also to leave the property and free disposal of the manu- scripts to the Authors; a copy, however, being deposited in the Archives of the Society, unless the paper shall be published in the Transactions. 6. In awarding the Prize, the Council will also take into consideration any scientific papers presented to the Society during the Sessions 1887-88 and 1883-84, whether they may have been given in with a view to the prize or not. III. NEILL PRIZE. _ The Council of the Royal Society of Edinburgh having received the bequest of the late Dr Patrick Nem. of the sum of £500, for the purpose of “the interest thereof being applied in furnishing a Medal or other reward every second or third year to any distinguished Scottish Naturalist, according as such Medal or reward shall be voted by the Council of the said Society,” hereby intimate, 1. The Nett Prize, consisting of a Gold Medal and a sum of Money, will be awarded during the Session 1888-89. 2. The Prize will be given for a Paper of distinguished merit, on a subject of Natural History, by a Scottish Naturalist, which shall have been presented to the Society during the three years preceding the 1st May 1888,—or failing presentation of a paper sufficiently meritorious, it will be awarded for a work or publication by some distinguished Scottish Naturalist, on some branch of Natural History, bearing date within five years of the time of award. ( 690 ) AWARDS OF THE KEITH, MAKDOUGALL-BRISBANE, AND NEILL PRIZES, FROM 1827 TO 1879. I. KEITH PRIZE. lst Brennrat Pertop, 1827-29.—Dr Brewster, for his papers “on his Discovery of Two New Immis- cible Fluids in the Cavities of certain Minerals,” published in the Transactions of the Society. 2np Biennrau Periop, 1829-31.—Dr Brewster, for his paper ‘fon a New Analysis of Solar Light,” published in the Transactions of the Society. 3RD BieNNIAL PeRiop, 1831—33.—THomas Grauam, Esq., for his paper “ on the Law of the Diffusion of Gases,” published in the Transactions of the Society. 47H Biennial Pentop, 1833-35,—Professor J. D. Forsrs, for his paper “on the Refraction and Polari- zation of Heat,” published in the Transactions of the Society. 5TH Brenn1aL Periop, 1835-37.—Joun Scorr RussELL, Esq.,for his Researches “on Hydrodynamics,” published in the Transactions of the Society. 67H Brenniat Periop, 1837-39.—Mr Jonn Suaw, for his experiments “on the Development and Growth of the Salmon,” published in the Transactions of the Society. 77H BrenniAL Periop, 1839—41.—Not awarded. 8TH Brenntau Periop, 1841-43.—Professor James Davin Forses, for his Papers “on Glaciers,” ‘ published in the Proceedings of the Society. 97H BrenniaL Periop, 1843—45.—Not awarded. 107TH Brennrau Periop, 1845-47.—General Sir THomas Brispans, Bart., for the Makerstoun Observa- tions on Magnetic Phenomena, made at his expense, and published in the Transactions of the Society. llra Brennrat Perron, 1847—49.—Not awarded. 127H BrenniaL Periop, 1849-51.—Professor Ketuanp, for his papers “on General Differentiation, including his more recent communication on a process of the Differential Calculus, and its application to the solution of certain Differential Equations,” published in the Transactions of the Society. 137m Brenniat Periop, 1851—-53.—W. J. Macquorn Rankine, Esq., for his series of papers “on the Mechanical Action of Heat,’ published in the Transactions of the Society. 1478 Brennrau Periop, ]853-55.—Dr Tuomas Anperson, for his papers “on the Crystalline Con- stituents of Opium, and on the Products of the Destructive Distillation of Animal Substances,” published in the Trans- actions of the Society. 157H Brenniat Periop, 1855-57.—Professor Booun, for his Memoir “on the Application of the Theory of Probabilities to Questions of the Combination of Testimonies and Judgments,” published in the Transactions of the Society, 167TH BrenniAu Pertop, 1857—59.—Not awarded. 177H Brenniau Peron, 1859-61.—Joun Auian Broun, Esq., F.R.S., Director of the Trevandrum. Observatory, for his papers “on the Horizontal Force of the Earth’s Magnetism, on the Correction of the Bitilar Magnet- ometer, and on Terrestrial Magnetism generally,” published in the Transactions of the Society. 181m Brienniat Pertop, 1861—63.—Professor Wiit1am THomson, of the University of Glasgow, for his Communication ‘on some Kinematical and Dynamical Theorems.” 19rx Brenniat Periop, 1863-65.—Principal Forses, St Andrews, for his “Experimental Inquiry into the Laws of Conduction of Heat in Iron Bars,” published in the Transactions of the Society, APPENDIX.—KEITH, MAKDOUGALL-BRISBANE, AND NEILL PRIZES. 691 20TH Brennian Periop, 1865—67.—Professor C. Prazzi Smyvg, for his paper “on Recent Measures at the Great Pyramid,” published in the Transactions of the Society. 21st Brenniau Periop, 1867—69.—Professor P. G. Tarr, for his paper “on the Rotation of a Rigid Body about a Fixed Point,” published in the Transactions of the Society. 22np Brenntau Periop, 1869—71.—Professor CrerkK Maxwet., for his paper “on Figures, Frames, and Diagrams of Forces,” published in the Transactions of the Society. 23rp Brenniau Periop, 1871—73.—Professor P. G. Tarr for his paper entitled “ First Approximation to a Thermo-electric Diagram,” published in the Transactions of the Society. 247H BisnniaL Periop, 1873—75.—Professor Crum Brown, for his Researches “ on the sense of Rota- tion, and on the Anatomical Relations of the Semicircular Canals of the Internal Ear.” 257 BrenniaL PeRioD, 1875—77.—Professor M. Forster Heppix, for his papers “on the Rhom- bohedral Carbonates,” and “on the Felspars of Scotland,” published in the Transactions of the Society. 26TH Brennrat Psriop, 1877—79.—Professor H. C. Firemine Jenkin, for his paper “on the Appli- cation of Graphic Methods to the Determination of the Effi- ciency of Machinery,” published in the Transactions of the Society; Part IT. having appeared in the volume for 1877-78. 277H Brenntat Periop, 1879—81.—Professor Groree Curystat, for his paper “on the Differential Telephone,” published in the Transactions of the Society. 287H Brenntat Periop, 1881—83.—Txomas Murr, Esq., LL.D., for his “ Researches into the Theory of Determinants and Continued Fractions,” published in the Proceedings of the Society. 297TH Biexntau Periop, 1883—-85.—Joum ArrKeEn, Esq., for his paper “on the Formation of Small Clear Spaces in Dusty Air,” and for previous papers on Atmospheric Phenomena, published in the Transactions of the Society. II. MAKDOUGALL-BRISBANE PRIZE. Ist BrewniaL Perriop, 1859.—Sir Roprrick Impry Murcuison, on account of his Contributions to the Geology of Scotland. 2np Brenniat Periop, 1860—62.—Wiiiam Sevier, M.D., F.R.C.P.E., for his ‘‘ Memoir of the Life and Writings of Dr Robert Whytt,” published in the Trans- actions of the Society. 3RD Brenniau Periop, 1862-—64.—Joun Denis Macponatp, Esq., R.N., F.R.S., Surgeon of H.M.S. “Tearus,” for his paper “on the ‘Representative Relationships of the Fixed and Free Tunicata, regarded as Two Sub-classes of equivalent value; with some General Remarks on their Morphology,” published in the Transactions of the Society. 47H BrenntaL Periop, 1864—66.—Not awarded. 57H Brennrat Periop, 1866-68.—Dr Atnxanper Crum Brown and Dr Tuomas RicHarp Fraser, for their conjoint paper “on the Connection between Chemical Constitution and Physiological Action,” published in the Transactions of the Society. 67H Bienniat Periop, 1868—70.—Not awarded. 77H BreNNIAL Pertop, 1870—72.—Grorce James Auiman, M.D., F.R.S., Emeritus Professor of Natural History, for his paper “ on the Homological Relations of the Coelenterata,” published in the Transactions, which forms a leading chapter of his Monograph of Gymnoblastic or Tubu- larian Hydroids—since published. 87H Brenna Periop, 1872—74.—Professor Lister, for his paper “on the Germ Theory of Putre- faction and the Fermentive Changes,” communicated to the Society, 7th April 1873. 692 APPENDIX.—KEITH, MAKDOUGALL-BRISBANE, AND NEILL PRIZES, 9raH Brenniat Periop,1874—76.— Atexanper Bucuan, A.M., for his paper “on the Diurnal Oscillation of the Barometer,” published in the Transactions of the Society. 10rH Brannrat Periop, 1876—78.—Professor ArcarBaLD Geikin, for his paper “on the Old Red Sandstone of Western Europe,” published in the Transactions of the Society. llra Brenniat Periop, 1878—80.—Professor Piazz1 Smytu, Astronomer-Royal for Scotland, for his paper ‘fon the Solar Spectrum in 1877-78, with some Practical Idea of its probable Temperature of Origination,” published in the Transactions of the Society. 127TH Brennrat Pertop, 1880—82.—Professor James Gurxie, for his “ Contributions to the Geology of the North-West of Europe,” including his paper “on the Geology of the Farées,” published in the Transactions of the Society. 13rH Brenniat Pertop, 1882—84.—Epwarp Sane, Esq., LL.D., for his paper “on the Need of Decimal Subdivisions in Astronomy and Navigation, and on Tables requisite therefor,” and generally for his Recalculation of Logarithms both of Numbers and Trigonometrical Ratios, —the former communication being published in the Pro- ceedings of the Society. III. THE NEILL PRIZE. 1st Trimnn1aL Periop, 1856-59.—Dr W. Lauper Linpsay, for his paper “ on the Spermogones and Pycnides of Filamentous, Fruticulose, and Foliaceous Lichens,” published in the Transactions of the Society. 2npD TRIENNIAL Pertiop, 1859-—62.—Rosert Kayz Grevitiy, LL.D., for his Contributions to Scottish Natural History, more especially in the department of Cryp- ; togamic Botany, including his recent papers on Diatomacee. 3rD TRIENNIAL Periop, 1862—-65.—Anprew Crompie Ramsay, F.R.S., Professor of Geology in the Government School of Mines, and Local Director of the Geological Survey of Great Britain, for his various works and Memoirs published during the last five years, in which he has applied the large experience acquired by him in the Direction of the arduous work of the Geographical Survey of Great Britain to the elucidation of important questions bear- ing on Geological Science. 47a TRIENNIAL Pertop, 1865-68.—Dr Witt1am Carmicuart M‘Intosu, for his paper “on the Strue- ture of the British Nemerteans, and on some New British Annelids,” published in the Transactions of the Society. 57H TRIENNIAL Pertop, 1868—71.—Professor Witi1am Turner, for his papers “on the great Finner Whale ; and on the Gravid Uterus, and the Arrangement of the Foetal Membranes in the Cetacea,” published in the Transactions of the Society. 67H TRImNNIAL Periop, 1871—74.—Cuartes Witiiam Pracg, for his Contributions to Scottish Zoology and Geology, and for his recent contributions to Fossil Botany. 7TH TRIENNIAL Periop, 1874—-77.—Dr Ramsay H. Traquair, for his paper “on the Structure and Affinities of T'ristichopterus alatus (Egerton), published in the Transactions of the Society, and also for his contributions to the Knowledge of the Structure of Recent and Fossil Fishes. 8TH TrienntAL Periop, 1877—80.—Joun Murray, for his paper “on the Structure and Origin of Coral Reefs and Islands,” published (in abstract) in the Proceedings of the Society. 97H TaimnNnIAL Puriop, 1880—-83.—Professor Herpman, for his papers “on the Tunicata,” published in the Proceedings and Transactions of the Society. 107TH TrienntAL Periop, 1883-86.—B. N. Prac, Esq., for his Contributions to the Geology and Palaeontology of Scotland, published in the Transactions of the Society. PROCEEDINGS OF THE STATUTORY GENERAL MEETINGS, AND LIST OF MEMBERS ELECTED AT THE ORDINARY MEETINGS FROM NOVEMBER 1881 TO NOVEMBER 1885, ( 695 ) STATUTORY MEETINGS. NINETY-NINTH SESSION. Monday, 28th November 1881. At a Statutory Meeting, Professor MacLacan, Vice-President, in the Chair, the Minutes of last General Statutory Meeting of 22nd November 1880 were read, approved, and signed. The Ballot for the new Council was then taken, Messrs TENNANT and MaccuLLocH being requested to act as Scrutineers. The following Council was elected :— The Right Hon. Lorp Moncretrr, President. Davip Mitnz Home, LL.D. Sir C. Wyvittze THomson, LL.D. Professor Dovetas Macuacan, M.D. Professor H. C. Firemine JenKiy, F.R.S. Rev. W. Linpsay Atexanver, D.D. J. H. Batrour, M.D., F.R.S. Professor Tart, General Secretary. Professor Turnmr, F.R.S. Professor Crum Brown, F.R.S8. Apam Giuures Suitu, C.A., Treasurer. ALEXANDER Bucuan, M.A., Curator of Library and Museum. Vice-Presidents. \ Scoretaries to Ordinary Meetings. COUNCILLORS. Professor CAMPBELL FRASER. Professor A. Dickson. Professor Grrxin, F.R.S. The Right Rev. Bisnop Correrixt. Rev. Dr CazEnove, The Rey. Professor Duns. Davin STEVENSON. Dr Ramsay Traquair, F.R.S. Professor CHRYSTAL. JoHN Murray. Sheriff Forsrs Irvinz, of Drum. WittraM Ferevuson, of Kinmundy. The TREASURER’S Accounts were submitted and approved. On the motion of Professor Tarr, seconded by Mr Maccuttocu, the Auditor was re- appointed. Professor CruM Brown gave notice of the following motion for alteration of a part of the Laws, viz., To change in Law XIV. the words “ November to June” into “ December to July.” VOL, XXXII. PART IV. 6A 696 APPENDIX.—PROCEEDINGS OF STATUTORY MEETINGS. HUNDREDTH SESSION. Monday, 27th November 1882. At a Statutory Meeting, Professor MACLAGAN, Vice-President, in the Chair, the Minutes of last General Statutory Meeting of 28th November 1881 were read, approved, and signed. The Ballot for the new Council was then taken, Professor SWAN and Professor Dickson being requested to act as Scrutineers. The following Council was elected :— The Right Hon. Lorp Moncrerr, President. Professor Dovetas Mactacan, M.D. Professor H. C. Fiuemine JENKIN, F.R.S. The Rev. W. Linpsay ALExanpeER, D.D. = . Ton Bierore: Wa. Vice-Presidents. Tuomas Stevenson, M. Inst. C.E. Ropert Gray, Sec. Roy. Phys. Soc. Professor Tart, M.A., General Secretary. Professor Turner, F.R.S. Professor Crum Brown, F.R.S., Apam Giuuies Situ, C.A., Treasurer. ALEXANDER Bucuay, M.A., Curator of Library and Museum. | Secretaries to Ordinary Meetings. COUNCILLORS. Professor GzorcE CurystaL, M.A. Wi1aM Fercuson, of Kinmundy. ALEXANDER Forses Irvine, of Drum. Professor James Cossar Ewart, M.D. Professor ALEXANDER Dickson, M.D. Professor James Grrxre, F.R.S. The Right Rev. Bisnorp Correritt, D.D. Professor WILLIAM RoBERTSON SMITH, The Rev. Professor Duns. LL.D. Ramsay H. Traquair, M.D., F.R.S. Starr A. Acnew, M.A. JouN Murray, Director of “Challenger” Comniission. Read Letter from the Treasurer apologising for absence on account of illness, and explain- ing the apparent surplus shown by the Financial Statement, The Auditor’s Report on the Treasurer’s Accounts was read and approved. On the motion of Dr Crum Brown, the Auditor was reappointed. APPENDIX—PROCEEDINGS OF STATUTORY MEETINGS. 697 HUNDRED AND FIRST SESSION. Monday, 26th November 1883. At a General Statutory Meeting, THomas STEVENSON, Esq., Vice-President, in the Chair, the Minutes of last General Statutory Meeting of 27th November 1882 were read, approved, and signed. The Ballot for the new Council was then taken, Professors SwaAN and Duns bemg requested to act as Scrutineers. The following Council was unanimously elected :— The Right Hon. Lorp Moncreirr, President. Professor H. C. Furemine JENKIN, F.R.S. The Rey. W. Linpsay ALExanpeErR, D.D. THomas Stevenson, Esq., M.Inst. C.E. Ropert Gray, Esq., Sec. Roy. Phys. Soc. A. Forpss Irvine, Esq. of Drum. Epwarp Sane, LL.D. Professor Tait, M.A., General Secretary. Professor TuRNER, F.R.S. Professor Crum Brown, F.R.S. ApvaM GiLuies SmitTH, Esq., C.A., Treasurer. ALEXANDER Bucuan, Esq., M.A., Curator of Library and Museum. Vice-Presidents. \ Secretaries to Ordinary Meetings. COUNCILLORS. The Rev. Professor Duns. The Rev. Dr W. Ropertson Situ. Dr Ramsay Traquair. Starr AGNeEw, Esq. Joun Murray, Esq., Director of “ Challenger ” Professor Douaetas Mactacan, M.D. Commission. The Hon. Lorp Mactaren. WiuiiaM Fereuson, Esq. of Kinmundy, The Rev. Professor Fiint, D.D. Professor Cossar Ewart, M.D. Professor T. R. Fraser, M.D. Professor JAMES GEIKIE, F.R,S. The Treasurer’s Accounts, duly vouched, were laid on the Table. The Auditor’s Report was read and approved. On the motion of Professor CRuM Brown, the Auditor was reappointed. The General Secretary presented an Agreement by the Scottish Meteorological Society, binding that body to relieve the Royal Society from all pecuniary and other claims connected with the Observatory Site on Ben Nevis. It was moved by Mr FeErcuson, seconded by Sheriff Irvine, and carried unanimously, That the Secretary be empowered to sign the Agreement on behalf of the Society. On the motion of Mr YounG, a vote of thanks was passed to the Chairman. 698 APPENDIX—PROCEEDINGS OF STATUTORY MEETINGS. HUNDRED AND SECOND SESSION. Monday, 24th November 1884. At a General Statutory Meeting, RoperT Gray, Esq., Vice-President, in the Chair, the Minutes of last General Statutory Meeting of 26th November 1883 were read, approved, and signed, The Ballot for the new Council was then taken, Professors SwAN and Duns having been nominated Scrutineers. The following Council was duly elected :— Tuomas STEVENSON, Esq., M.Inst. C.E., President. Rev. W. Linpsay Auexanper, D.D. Rosert Gray, Esq. * A. Forzes Irvine, Esq. of Drum. Epwarp Sane, LL.D. Daviv Mitye Homs, Esq. Joun Murray, Esq. | Professor Tarr, M.A., General Secretary. Professor Turner, F.R.8. Professor Crum Brown, F.R.S. Apa Gixiies Situ, Esq., C.A., Treasurer. ALEXANDER Bucuan, Esq., M.A., Curator of Library and Museum. Vice-Presidents. \ Secretaries to Ordinary Meetings. COUNCILLORS. Professor Cossar Ewart. Rev. Professor Frnt, D.D. Professor JAMES GEIKIE. Professor T. R. Fraser, M.D. Rey. Dr W. Ropertson Smiru. Professor CHIENE. Srair Acnew, Esq. J. Y. Bucnanan, Esq. Professor Doueitas Mactagan, M.D. Professor CHRYSTAL. The Hon. Lorp Macraren. Professor Dickson. The Treasurer’s Accounts, duly vouched, were laid on the Table. The Auditor's Report was read, and, on the motion of Sheriff Forses IRVINE, was unanimously approved. On the motion of Professor Crum Brown, the Auditor was reappointed. The Secretary and Treasurer were empowered to sign a Discharge by the Society m favour of CHARLES THOMAS BRISBANE, Esq. of Brisbane. Sheriff THoMs was admitted a Fellow. A vote of thanks was, on the motion of Lord MACLAREN, given to the Chairman. APPENDIX—PROCEEDINGS OF STATUTORY MEETINGS. 699 Monday, 5th October 1885. At a Special General Meeting called by the Secretary, under Law XX., for the purpose of electing a Member of the New Governing Body of George Heriot’s Hospital—THomas STEVENSON, Esq., President, in the Chair,— The Secretary read Letter from the Lord Provost; also some Excerpts from the Order in Council as to Heriot’s Hospital; and explained that the Society's Council had determined that the Election should be conducted in the same manner as that of Office-Bearers. On the motion of the President, the Rev. Dr Grant and J. Livineston, Esq., were requested to act as Scrutineers. The Scrutineers having examined the Balloting Papers, announced that Dr Jonn Murray had been unanimously elected. HUNDRED AND THIRD SESSION. Monday, 23rd November 1885. At a General Statutory Meeting, JoHN Murray, Esq., Vice-President, in the Chair, the Minutes of the last General Statutory Meeting, of 24th November 1884, also those of the Special Meeting of 5th October 1885, were read, approved, and signed. The Chairman requested Professor DuNS and Mr A. YounG to act as Scrutineers. The Ballot for the New Council was then taken, and the Scrutineers reported that the following were unanimously elected :— THomas STEVENSON, Esq., M.Inst. C.E., President. Ropert Gray, Esq. A. Forses irvine, Esq., of Drum. Davip Minne Homg, Esq. Joun Murray, Esq. Professor Doveitas Mactaaan. The Hon. Lorp Mactaren. Professor Tarr, General Secretary. Professor Turner, F.R.S. Professor Crum Brown, F.R.S. Apam Gites Smiru, Esq., C.A., Treasurer. ALEXANDER Bucuay, Esq., M.A., Curator of Library and Museum. Vice-Presidents. \ Secretaries to Ordinary Meetings. 700 APPENDIX—PROCEEDINGS OF STATUTORY MEETINGS, COUNCILLORS, Rey. Professor Fiint, D.D. Professor SHIELD NicHoLson. Professor T. R. Fraser, M.D., F.R.S. T. B. Spracus, Esq. Professor CHIENE. Professor BurcueEr. J. Y. Bucnanan, Esq., M.A, Professor M‘Kernprick, F.R.S8. Professor CHRYSTAL. Tuomas Murr, Esq., LL.D. Professor Dickson. Professor M‘Inrosu. The Secretary laid on the Table the Treasurer’s Accounts for the past year, duly vouched. These were approved. On the motion of Professor CRuM Brown, seconded by Professor MacLaGAN, the Auditor was re-elected. The Secretary laid on the Table proofs of the Fasciculi of Proceedings and Transactions shortly to be issued. A vote of thanks was, on the motion of Professor DUNS, unanimously given to the Chairman. Ov n0t A) The following Public Institutions and Individuals are entitled to receive Copies of the Transactions and Proceedings of the Royal Society of Edinburgh :— London, British Museum. Royal London. Anthropological Institute of Great Bri- tain and Ireland, 3 Hanover Square, London. ... British Association for the Advancement of Science, 22 Albemarle Street, London. Society, Burlington House, .. Society of Antiquaries, Burlington House. Royal Astronomical Society, Burlington House. -.. Royal Asiatic Society, 22 Albemarle Street. ... Society of Arts, John Street, Adelphi. ... Atheneum Club. Chemical Society, Burlington House. Institution of Civil Engineers, 25 Great George Street. ..- Rvyal Geographical Society, Burlington Gardens. ... Geological Society, Burlington House. ... Royal Horticultural Society, South Ken- sington. ... Hydrographic Office, Admiralty. Royal Institution, Albemarle Street, W. ... Linnean Society, Burlington House. -.. Royal Society of Literature, 4 St Mar- tin’s Place. Medical and Chirurgical Society, 53 Berners Street, Oxford Street. Royal Microscopical Society, King’s College. Museum of Economic Geology, Jermyn Street. Royal Observatory, Greenwich. Pathological Society, 53 Berners Street. Statistical Society, 9 Adelphi Terrace, Strand, London. Royal College of Surgeons of England, 40 Lincoln’s Inn Fields. London, United Service Institution, Whitehall Yard. University College, London. Zoological Society, 11 Hanover Square. The Editor of Nature, 29 Bedford Street, Covent Garden. The Editor of the Electrician, 396 Strand. Cambridge Philosophical Society. University Library. Historic Society of Lancashire and Cheshire. Leeds Philosophical and Literary Society. Manchester Literary and Philosophical Society. Oxford, Bodleian Library. Yorkshire Philosophical Society. Gower Street, SCOTLAND. Edinburgh, Advocates Library. University Library. College of Physicians. Highland and Agricultural Society, 3 George IV. Bridge. Royal Medical Society, 7 Melbourne Place, Edinburgh. Royal Physical Society, 40 Castle Street. Royal Scottish Society of Arts, 117 George Street. Royal Botanic Row. Aberdeen, University Library. Dundee, University College Library. Glasgow, University Library. Philosophical Society, 207 Bath Street. St Andrews, University Library. Garden, Inverleith IRELAND. Royal Dublin Society. Royal Irish Academy, 19 Dawson Street, Dublin. Library of Trinity College, Dublin. =". 702 APPENDIX. COLONIES, DEPENDENCIES, &e, Bombay, Royal Asiatic Society. ... Elphinstone College. Calcutta, Asiatic Society of Bengal. Madras, Literary Society. Canada, Library of Geological Survey. Queen’s University, Kingston. Montreal, Royal Society of Canada. Quebec, Literary and Philosophical Society. Toronto, Literary and Historical Society. +E The Canadian Institute. Cape of Good Hope, The Observatory. Melbourne, University Library. Sydney, University Library. Linnean Society of New South Wales. Royal Society of New South Wales. Wellington, New Zealand. Institute. CONTINENT OF EUROPE. Amsterdam, Koninklijke Akademie van We- tenschappen ; Koninklijk Zoologisch Genootschap. Athens, University Library. Basle, Die Schweizerische Naturforschende Gesell- schaft. Bergen, Museum. Berlin, Kénigliche Akademie der Wissenschaften. Physicalische Gessellschaft. Bern, Allgemeine Schweizerische Gesellschaft fiir die gesammten Naturwissenschaften. Bologna, Accademia delle Scienze dell’ Istituto. Bordeaux, Société des Sciences Physiques et Naturelles. Brussels, Académie Royale des Sciences, des Let- tres et des Beaux-arts. Musée Royal d'Histoire Naturelle de Belgique. L’Observatoire Royal. La Société Scientifique. Bucharest, Academia Romana. Buda, A Magyar Tudés Tarsasag—Die Ungarische Akademie der Wissenschaften. Konigliche Ungarische Naturwissenschaft- lische Gesellschaft. Catania, Accademia Gioenia di Scienze Naturali. Christiania, University Library. Meteorological Institute. Coimbra, University Library. Copenhagen, Royal Academy of Sciences, Danzig, Naturforschende Gesellschaft. Dorpat, University Library. Ekatherinebourg, La Société Ouralienne d’Ama- teurs des Sciences Naturelles. Erlangen, University Library. Frankfurt-am-Main, Senckenbergische Naturfor- schende Gesellschaft. Gand (Ghent), University Library. Geneva, Société de Physique et d’ Histoire Naturelle, Genoa, Museo Civico di Storia Naturale. Giessen, University Library. Gottingen, Konigliche Gesellschaft der Wissen- schaften. Graz, Naturwissenschaftlicher Verein fiir Steier- mark. Haarlem, Société Hollandaise des Sciences Exactes et Naturelles. Musée Teyler. Halle, Kaiserliche Leopoldino - Carolinische deutsche Akademie der Naturforscher. Halle, Naturforschende Gesellschaft. Hamburg, Naturwissenschaftlicher y Verein, 6 Domstrasse. Helsingfors, Siallskapet pro Fauna et Flora Fennica, Societas Scientiarum Fennica (Société des Sciences de Finlande). Jena, Medicinisch-Naturwissenschaftliche Gesell- schaft. Kasan, University Library. Kiel, University Library. Ministerial-Kommission zur Untersuchung der Deutschen Meere. Kiev, University of St Vladimir. Konigsberg, University Library. Leyden, Neerlandsche Dierkundige Vereenig- ing. The University Library. Leipzig, Prof. Wiedemann, KGnigliche Sichsische Akademie. Lille, Société des Sciences, Lisbon, Academia Real das Sciencias de Lisboa. Sociedade de Geographia, 5 Rua Capello. Louvain, University Library. Lucca, M. Michelotti. APPENDIX. 703 Lund, University Library. Lyons, Académie des Sciences, Belles Lettres et Arts. Société d’Agriculture. Madrid, Real Academia de Ciencias. Comision del Mapa Geologico de Espaiia. Milan, Reale Istituto Lombardo di Scienze, Lettere, ed Arti. Modena, Regia Accademia di Scienze, Lettere, ed Arti. Montpellier, Académie des Sciences et Lettres. Moscow, Société Impériale des Naturalistes de Moscou. Société Impériale des Amis d’ Histoire Naturelle, d’ Anthropologie et d’Ethno- graphie. Musée Politechnique. L’ Observatoire Impérial. Munich, Koniglich-Bayerische Wissenschaften (2 copies). Naples, Zoological Station, Dr Anton Dohrn. Societa Reale di Napoli—Accademia delle Scienze Fisiche e Matematiche. Neufchatel, Société des Sciences Naturelles. Akademie der Palermo, Signor Agostino Todaro, Giardino Botanico. Societa di Scienze Naturali ed Econo- miche. Paris, Académie des Sciences de ]’Institut. Académie des Inscriptions et Belles Lettres de l'Institut. ... Association Scientifique de France. Société d’ Agriculture, 18 Rue de Bellechasse. Société Nationale des Antiquaires de France. Société de Biologie. Société de Géographie, 184 Boulevard St Germain: Société Géologique de France, 7 Rue des Grands Augustins. Société d’Encouragement pour l’Industrie Nationale. Bureau des Longitudes. Dépdt de la Marine. Société Mathématique, 7 Rue des Grands Augustins. Ecole des Mines. Mimistére de I’Instruction Publique. VOL. XXXII. PART IV. Paris, Musée Guimet, 30 Avenue du Trocadero. Muséum d’ Histoire Naturelle, Jardin des Plantes. L’Observatoire. Kcole Normale Supérieure, Rue d’Ulm. Société Frangaise de Physique, 44 Rue de Rennes. Ecole Polytechnique. Société Zoologique de France, 7 Rue des Grands Augustins. Revue Scientifique, et Revue Littéraire et Politique. Prague, Konigliche Sternwarte. Koniglich-Béhmische Gesellschaft der Wissenschaften. Rome, Accademia dei Lincei. Societa Italiana delle Scienze detta dei XL. Societa degli Spettroscopisti Italiani. Comitato Geologico. Rotterdam, Bataafsch Genootschap der Proefon- dervindelijke Wijsbegeerte. St Petersburg, Académie Impériale des Sciences. Commission Impérial Archéolo- gique. Comité Géologique. L’Observatoire Impérial de Pul_ kowa. . Physikalisches Central - Observa- torium. Physico-Chemical Society of the University of St Petersburg. Stockholm, Kongliga Svenska Vetenskaps-Acade- mien. Strasbourg, University Library. Stuttgart, Verein fiir Vaterlindische Naturkunde zu Wiirtemberg. Thronddjem, Videnskabernes Selskab. Tiibingen, University Library. Turin, Reale Accademia delle Scienze. Upsala, Kongliga Vetenskaps-Societeten. Venice, Reale Istituto Veneto di Scienze, Lettere ed Arti. Vienna, Kaiserliche Akademie der Wissenschaften. Novara Commission. Oesterreichische Gesellschaft fiir Mete- orologie, Hohe Warte, Wien. Geologische Reichsanstalt. Zoologisch-Botanische Gesellschaft. 6B 704 APPENDIX. Zurich, University Library. Commission Géologique Suisse, ASIA. Java, Bataviaasch Genootschap van Kunsten en Wetenschappen. ... The Observatory. Japan, The Imperial University of Tokio (Teikoku-Daigaku). UNITED STATES OF AMERICA. | American Association for the Advancement of Science. Baltimore, Johns Hopkins University. Boston, the Bowditch Library. American Academy of Arts and Sciences, Beacon Street, Boston. Society of Natural History. Cambridge, Mass., Harvard University. Harvard College Observatory. Chicago Observatory. Clinton, Litchfield Observatory, Hamilton Col- lege, Concord, Editor of Journal of Speculative Philo- sophy. New York, State Library. Philadelphia, American Philosophical Society. Academy of Natural Sciences, Logan Square. Philadelphia, Geological Survey of Pennsylvania. Salem, The Peabody Academy of Science. St Louis, Academy of Sciences. Washington, United States Coast Survey. United States Fishery Commission. United States Naval Observatory. United States Geological Survey of the Territories. United States Signal Office. The Smithsonian Institution, Surgeon-General’s Office, United States Army. Wisconsin, University (Washborn Observatory), Madison. Yale College, Newhaven, Connecticut. MEXICO. Mexico, Observatorio Meteorologico Central. SOUTH AMERICA. Buenos Ayres, Public Museum, per Dr Bur- meister. Corduba, Argentine Republic, Academia Nacional de Ciencias. The Observatory. Rio de Janeiro, The Astronomical Observatory. All the Honorary and Ordinary Fellows of the Society are entitled to the Transactions and Proceedings. See Notice at foot of page 706. The following Institutions and Individuals receive the Proceedings only :— SCOTLAND. Edinburgh, Botanical Society 5 St Andrew Square. Geological Society, 5 St Andrew Square. Scottish Geographical Society. é Mathematical Society, 8 Queen Street. Edinburgh, Scottish Meteorological Society, 122 George Street. Pharmaceutical Society, 36 York Place. Geological Society of Glasgow, 207 Bath Street. The Glasgow University Observatory. Berwickshire Naturalists’ Club, Old Cambus Cockburnspath. APPENDIX. 705 ENGLAND. London, Geologists’ Association, University College. Mathematical Society, 22 Albemarle Street, London, W. Institution of Mechanical Engineers, 10 Victoria Chambers, Victoria Street, Westminster. Meteorological Office, 116 Victoria Street. The Meteorological Society, 25 Great George Street, Westminster. Nautical Almanac Office, 3 Verulam Buildings, Gray’s Inn. Pharmaceutical Society, 17 Bloomsbury Square, London. The Editor of the Illustrated Science Monthly, 3 St Martin’s Place, Trafal- gar Square, London, Birmingham Philosophical Society, King Edward’s Grammar School. Cornwall, Geological Society. Epping Forest and County of Essex Naturalists’ Field Club. Halifax, Geological and Polytechnic Society of Yorkshire. Liverpool, Literary and Philosophical Society. Manchester, Geological Society, 36 George Street. Newcastle, Philosophical Society. North of England Institute of Mining and Mechanical Engineers. Norfolk and Norwich Naturalists’ Society, The Museum, Norwich. Oxford, Ashmolean Society. Radcliffe Observatory. Scarborough, Philosophical Society. Whitby, Philosophical Society. IRELAND, Dublin, Royal Geological Society. Dunsink Observatory. Belfast, Natural History and Philosophical Society. COLONIES, DEPENDENCIES, ETC. Adelaide, South Australia, University Library. Royal Society. Bombay, Natural History Society. Brisbane, Royal Society of Queensland. Canada, Natural History Society of Montreal. Melbourne, Royal Society of Victoria. Sydney, The Australian Museum, Halifax, Nova Scotian Institute of Natural Science. China Branch of the Asiatic Society. The Observatory. Madras, Superintendent of Government Farms of Hong Kong, Madras Presidency. Queensland, Branch of the Geographical Society. Tasmania, Royal Society. CONTINENT OF EUROPE. Amsterdam, Genootschap der Mathematische Wetenschappen. Berlin, Deutsche Meteorologische Gesellschaft. K. Technische Hochschule. Bonn, Naturhistorischer Verein der Preussischen Rheinlande und Westfalens. Bern, Naturforschende Gesellschaft. Bordeaux, Société de la Géographie Commer- ciale. Brunswick, Verein fiir Naturwissenschaft. Bucharest, Academia Romana. Cassel, Verein fiir Naturkunde. Chemnitz, Naturwissenschaftliche Gesellschaft. Cherbourg, Société Nationale des Sciences Natu- relles. Copenhagen, Naturhistoriske Forening. Delft, Ecole Polytechnique. Dijon, Académie des Sciences. Erlangen, Physico-Medical Society. Gratz, Chemisches Institut der K. K. Universitit. Halle, Verein fiir Erdkunde. Hamburg, Verein fiir Naturwissenschaftliche Unterhaltung, 29 Steindamm, St Georg. Lausanne, Société Vaudoise des Sciences Natu- relles. Leipzig, Naturforschende Gesellschaft. Lille, Société Géologique du Nord. Luxembourg, Société des Sciences Naturelles, Lyons, Société Botanique. Société Linnéenne, Place Sathonay. Marseilles, Société Scientifique Industrielle, 61 Rue Paradis. Milan, Societa Crittogamologica Italiana. Modena, Societa dei Naturalisti. 706 APPENDIX. Nijmegen, Nederlandsche Botanische Vereeniging. Oberpfalz und Regensburg, Historischer Verein. Odessa, New Natural History Society. Offenbach, Verein fiir Naturkunde. Paris, Société d’Anthropologie (4 Rue Antoine Dubois). Société Philomathique. Ecole Libre des Sciences Politiques. Bureau des Ponts et Chaussées. Pisa, Nuovo Cimento. St Petersburg, Imperatorskoe Russkoe Geogra- phicheskoe Obtshéstvo. Stockholm, Svenska Siillekapet for Anthropo- logi och Geografi. Tiflis, Physical Observatory. Toulouse, Académie des Sciences. Trieste, Societa Adriatica di Scienze Naturali. Museo Civiso di Storia Naturale. Tromso, The Museum. Utrecht, Provinciaal Genootschap van Kunsten en Wetenschappen. Vienna, K.K. Naturhistorisches Museum. Zurich, Naturforschende Gesellschaft. ASIA. China, Shanghai, North China Branch of the Royal Asiatic Society. Japan, Tokio, The Seismological Society. Yokohama, Deutsche Gesellschaft fiir Natur- und Volkerkunde Ostasiens. Java, Batavia, Koninklijke Natuurkundije Vereeniging, UNITED STATES, Annapolis, Maryland, St John’s College. Chicago Observatory. California, State Mining Bureau, Sacramento, Cincinnati, Observatory. ... Society of Natural History. Cincinnati, Ohio Mechanics’ Institute. Colorado, Scientific Society. Connecticut, Academy of Arts and Sciences. Davenport, Academy of Natural Sciences. New York, The American Museum of Natural History. The American Geographical and Sta- tistical Society. Salem, The Essex Institute. Peabody Academy of Science. San Francisco, The Lick Observatory. Trenton, Natural History Society. Washington, Philosophical Society. American Museum of Natural His- tory, Central Park. : United States National Museum. Wisconsin, Academy of Sciences, Arts, and Letters, SOUTH AMERICA. Rio de Janeiro, Museu Nacional. MEXICO. Mexico, Observatorio Meteorologico-Magnetico Central. Tacubaya, Observatorio Astronomico, NOTICE TO MEMBERS. All Fellows of the Society who are not in Arrear in their Annual Contributions, are entitled to receive Copies of the Transactions and Proceedings of the Socicty, provided they apply for them within Five Years of Publication. Fellows not resident in Edinburgh must apply for their Copies either personally, or by an authorised Agent, at the Hal of the Society, within Five Years after Publication. my r< TO VOL. XXXL. A Amphicheiral Knots. See Knots. AiTKen (JouN), F.R.S.E. On the Formation of Small Clear Spaces in Dusty Air, 239. AnprEws (Tuomas), Assoc.M.Inst.C.E., F.R.S.E. On the Relative Electro-Chemical Positions of Wrought Iron, Steels, Cast Metal, &., in Sea Water and other Solutions, 204. Asteroidea dredged in the Faroe Channel during the Cruise of H.M.S. “ Triton” in 1882. By W. Percy Stapen, F.L.S., 153. B Bipartite Functions, By Tuomas Murr, LL.D., F.R.S.E., 461. Bracke (Professor Jonn Stuart), F.R.S.E. On the Philosophy of Language, 343. Brewster (Sir Davin). Note on Sir David Brewster’s Line Y in the Infra-Red of the Solar Spectrum. By Professor C. Piazzi Smytu, F.R.S.E., 233. Bright Clouds on a Dark Night Sky. By Professor C. Prazzi Smytu, F.R.S.E., 11. C Calcareous Formation of the Solomon Group. By H. B. Guppy, M.B., F.G.S., 545. CasetLA (Mr Cuartzs F.). On the Preparation and Purification of Vacuum Tubes, 458. Chain-Fractions. On the Approximation to the Roots of Cubic Equations by help of Recurring Chain-Fractions. By Epwarp Sane, LL.D., E.R.S.E., 311. Curistison (Dr Davin). Rosert), 45. —— (Sir Rosert), Bart., F.R.S.E., and Dr Davin Curistison. The Annual and Monthly Growth of Wood in Deciduous and Evergreen Trees, 45, See Curistison (Sir CrysraL (Professor), F.R.S.E. On the Hessian, 645. Circulants. Detached Theorems in Circulants. Tuomas Muir, LL.D., F.R.S.E., 639. Clear Spaces in Dusty Air. By Mr Joun AITKEN, F.R.S.E., 239. Clouds (Bright) on a Dark Night Sky. By C. Prazzi Smytu, F.R.S.E., Astronomer-Royal for Scotland, 11. Cremona (Professor L.) Hon., F.R.S.E. An Ex- ample of the Method of Deducing a Surface from a Plane Figure, 411. Cubic Equations. On the Approximation to the Roots of Cubic Equations by help of Recurring Chain-Fractions. By Epwarp Sane, LL.D., F.R.S.E., 311. CunnincHaM (J. T.), B.A., F.RS.E. On Sticho- cotyle Nephropis, a new Trematode, 273. By D Dusty Air. On the Formation of Small Clear Spaces in Dusty Air. By Mr Jounn ArrTKen, FE.R.S.E., 239. Effects of Gravitation, 243; of Cold, 243; of Evaporation, 246; of Heat, 246; of Centrifugal Force, 251; of Electricity, 252 ; the Lungs and Dust, 256. E Ectocarpus, Note on. By Joun Rattray, M.A., F.R.S.E., 589. Electricity. Effect of Electricity on the Formation of the Dark Plane in Dusty Air. See Dusty Air. Observations on Atmospheric Electricity. By Professor C. Micutz Smitu, F.R.S.E., 583. —— HElectro-Lighted Gas-Vacuum Tubes, 424. Electro-Chemical Positions of Wrought Iron, Steels, Cast Metal, &c., in Sea Water and other Solu- tions. By THomas AnpREws, F.R.S.E., 204. 708 F Faroe Channel. Pycnogonida of, 1; Tunicata of, 93; Pennatulida of, 119; Asteroidea of, 153. G Gaseous Spectra. See under Spectrum Analysis. Geological Structure of the Volcanic Rocks of Shet- land. See Shetland. Gipson (R. J. Harvey), F.R.S.E. Anatomy of Patella vulgata, 601; Historical Account, 601; Morphology, 603; Viscera, 604; Alimentary System, 605; Respiratory System, 614; Renal System, 617; Connective Tissue System, 620 ; Muscular System, 621; Epidermal System, 622; Protective System, 624; Reproductive System, 633. Grating and Glass-Lens Solar Spectrum im 1884. See under’Spectrum Analysis. Green Sun. See under Sun. Guppy (H. B.), F.G.S. Observations on the Recent Caleareous Formations of the Solomon Group made during 1882-84, 545. H Hay (Matruew), M.D. A Contribution to the Chemistry of Nitroglycerine, 67. and Orme Masson, M.A., B.Sc., F.R.S.E. The Elementary Composition of Nitroglycerine, 87. Herpman (W.A.), D.Sc. F.R.S.E., Professor of Natural History in University College, Liver- pool. Report on the Tunicata collected during the Cruise of H.M.S. “Triton” in the summer of 1882, 93. Report on the Tunicata dredged during the Cruises of H.M.SS. “ Porcupine” and “ Light- ning” in 1868, 1869, 1870, 219. Herscuet (Professor ALEXANDER §.). Green Band of CO, 454. Hessian, On the. By Professor Curystat, F.R.S.E., 645. Horx (Dr P. P. C.). On the The Pycnogonida dredged in the Faroe Channel during the Cruise of H.M.S. | “Triton” in August 1882, 1. Horne (Jonny), F.R.S.E., and Pracn (B. N.), F.R.S.E. The Old Red Sandstone Volcanic Rocks of Shetland, 359. Hoyts (W. E.), M.A., F.R.S.E.. On a New Species of Pentastomum (P. protelis) from the Mesen- tery of Proteles cristatus, with an Account of its Anatomy, 165. INDEX. K Kinematics of Mechanisms, a New Graphic Analysis of, 507. Kirkman (Rev. T. P.), F.R.S. The Enumeration, Description, and Construction of Knots of fewer than Ten Crossings, 281. —— The 364 Unifilar Knots of Ten Crossings, enumerated and described, 483. Knots. Knots of fewer than Ten Crossings, 281. The 364 Unifilar Knots of Ten Crossings, enumerated and described. By Rev. THomas P. Kirxmayn, F.R.S., 483. —— By Professor Tait, Sec. R.S.E., Part II. Census of Eightfold and Ninefold Knottiness, 327. Beknottedness, 335. —— Part III. Various Orders and Classes of Amphicheirals, 493. Census of Tenfold Knottiness, 501. The various Types of Tenfolds, with their distinct Forms, 503. Kworr (Professor C. G.), D.Sc, F.R.S.E. On Superposed Magnetisms in Tron and Nickel, 193. L Language. On the Philosophy of Language. By Professor JoHn Stuart Buackin, F.R.S.E., 343, Little b Group of Lines in Solar Spectrum. See Spectrum Analysis. M Magnetism. On Superposed Magnetisms in Iron and Nickel. By Professor C. G. Kvyort, F.R.S.E., 193. Marsuauti (A. Miryzs), M.D., D.Sc., Professor of Zoology in Owens College. Report on the — Pennatulida dredged by H.M.S. ‘“ Triton,” 19. Mechanisms. A new Graphic Analysis of the Kine- matics of Mechanisms. By Professor Rosprrt H. Sirs, 507. Murr (Tomas), LL.D., F.R.S.E. On Bipartite Functions, 461. Detached Theorems on Circulants, 639. N Nitroglycerine. A Contribution to the Chemistry of Nitroglycerine. By Marruew Hay, M.D., 67. —— Action of Potash, Ammonia, Alkaline Car- bonates, Phosphate of Soda, Chloride of Sodium Acids and Sulphides, and Water on Nitro- INDEX. glycerine, 75-82. Preparation and Characters of Nitroglycerine, 83. Nitroglycerine. The Elementary Composition of Nitroglycerine. By Marraew Hay, M.D., and Orme Masson, M.A., B.Sc., F.R.S.E., 87. O Old Red Sandstone. See under Sandstone. Pp Partitions. Note on a Problem in Partitions. Professor Tait, R.S.E., 340. Patella vulgata, Anatomy and Physiology of Patella vulgata. Part I.—Anatomy of. By R. J. Harvey Gipson, F.R.S.E., 601. Psaco (B. N.), F.R.S.E., and Horne (Jonn), F.R.S.E. The Old Red Sandstone Volcanic Rocks of Shetland, 359. Pennatulida. Report on the Pennatulida dredged by H.M.S. “Triton.” By A. Minwes MarsHatt, M.D., Professor of Zoology in Owens College, w1g. Pentastomum, A New Species of, from the Mesen- tery of Proteles cristatus, with an account of its Anatomy. By W. E. Horus, M.A., FE.R.S.E., 165. Body-Wall, 167. Muscular System, 169. Digestive Tract, 174. Secretory Organs, 177. Nervous System, 180. tive Organs, 181. Proteles cristatus. See Pentastomum. Pyenogonida dredged in the Faroe Channel during the Cruise of H.M.S. “Triton” in August £s82- By Dr P: P..C. Hox, 1. By Genera- R Ratrray (Joun), M.A., F.R.S.E.. Note on Ecto- carpus, 589. S Sandstone (Old Red) Volcanic Rocks of Shetland. By B. N. Peacu, F.R.S.E., and Jonn Horns, E.R.S.E., 359. Sane (Epwarp), LL.D., F.R.S.E. On the Approxi- mation to the Roots of Cubic Equations by help of Recurring Chain-Fractions, 311. Shetland. On the Old Red Sandstone Volcanic Rocks of Shetland. By B. N. Psacu, F.R.S.E., and Joun Horne, F.R.S.E., 359. Contem- poraneous Lavas and Tufis, 361. Intrusive Igneous Rocks, 368. Microscopic Characters, 379. Chemical Analysis of Eight Specimens of Shetland Volcanic Rocks, 359. 709 Snapen (W. Percy), F.LS., F.G.S. Asteroidea dredged in the Faroe Channel during the Cruise of M.H.S. “Triton” in August 1882, 153. Smite (Professor C. Mrcuiz), F.R.S.E. Observations on a Green Sun and associated Phenomena, 389. —— Observations 583. SmitH (Professor Rogperr H.). A New Graphic Analysis of the Kinematics of Mechanisms, 507. SmyrH (C. Prazzi), F.R.S.E., Astronomer-Royal for Scotland. Bright Clouds on a Dark Night Sky, 11. —— Note on the Little b Group of Lines in the Solar Spectrum and.the new College Spectro- scope, 37. —— Note on Sir David Brewster’s Line in the Infra-Red of the Solar Spectrum, 233. —— Micrometrical Measures of Gaseous Spectrum under High Dispersion, 415. —— The Visual, Grating and Glass-Lens, Solar Spectrum in 1884, 519. Solomon Group. Observations on the Recent Cal- careous Formations of the Solomon Group, made during 1882-84. By H. B. Guppy, M.B., F.G.S., 545. Spectroscope. The new (Edinburgh) College Spec- troscope. By C. Prazzi Smytu, F.R.S.E., Astronomer-Royal for Scotland, 37. Spectrum of Green Sun. By Professor C. MicH1E SmitH, 393. Spectrum Analysis. Note on the Little b Group of Lines in the Solar Spectrum and the new College Spectro- scope. By C. Piazzt Smyru, F.R.S.E., Astronomer-Royal for Scotland, 37. —— Note on Sir David Brewster’s Line Y in the Infra-Red of the Solar Spectrum. By C. Prazat SuytH, F.R.S.E., 233. — Micrometrical Measures of Gaseous Spectra under High Dispersion, 416 ; Candle Spectrum, or HC Gas in Blowpipe Flame, 418; the CO Spectrum, 435; Elementary Gases, H, 440; O, 444; N, 446. By C. Piazzt Smyru, E.R.S.E., 415. —— The Visual, Grating and Glass-Lens, Solar Spectrum in 1884. By C. Prazzi Smyru, FE.R.S.E., 519. Stichocotyle Nephropis, a new Trematode. T. CunnincHam, F.R.S.E., 273. Observations on a Green Sun and associated on Atmospheric Electricity, By J. Sun. 710 Phenomena. By Professor C. Mion1e Sirs, F.R.S.E., 389. Surfaces. Example of the Method of deducing a Surface from a Plane Figure. By Professor L. Cremona, Hon. F.R.S.E., 411. Tr Tair (Professor), Sec. R.S.E. On Knots. Part 1G EV a —— (Appendix). Note on a Problem of Parti- tions, 340. —— On Knots. Part IIL, 493. Trees. Annual and Monthly Growth of Wood in Deciduous and Evergreen Trees. By Sir Rosert Caristison, Bart., and Dr Davin Curistison, 45. Annual Increase in Girth of Deciduous Trees, 47. Annual Increase in Girth of Evergeeen Trees, 48. Monthly Increase in Girth of Trees, 51-59. Influence of Weather on the Growth of Wood, 59. INDEX. Tunicata collected during Cruise of H.M.S. “ Triton” in 1882, 93. Report on the Tunicata dredged during the Cruise of H.M.SS. “Porcupine” and “Lightning” in 1868, 1869, 1870. By Professor W. A. Hmrpman, 219. U Unifilar Knots of Ten Crossings, 364 enumerated and described. By Rev. THomas P. Kirkman, F.R.S., 483. v Visual Solar Spectrum in 1884. See under Spectrum Analysis. Ww Wood. Observations on the Annnal and Monthly Growth of Wood in Deciduous and Evergreen Trees, By Sir Ropert Curistison, Bart., and Dr CarIstTIson, 45. 29 JUL. 1887 PRINTED BY NEILL AND COMPANY, EDINBURGH. 7 . ~ ig ’ ‘ ‘ ~- «! o a i a 6 a ‘ . é -. x : B . t 4 i ‘ : ‘ ‘ ' The TRANSACTIONS of the Royau Sociery or EpinsurGs will in future be Sold at the following reduced Prices :— Vol. L 11. If. | Out of Print. FY: L£ VI. 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