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ALBERT R. MANN
LIBRARY

NEW YorK STATE COLLEGES
OF
AGRICULTURE AND HOME ECONOMICS

CORNELL UNIVERSITY

;
_

eee

The tural TexrteBook Series
Evitep sy L. H. BAILEY

SOILS

THEIR PROPERTIES AND MANAGEMENT

Qhe Mural Cert-Book Series

Evirep sy L. H. BAILEY

B. M. Duggar, Puant Prysio.oer.
J. F. Duggar, Souturrn Frevp Crops.
Gay, Tue Princienes AND Practice OF
Jupeine Live-Srock.
Harper, ANIMAL Huspanpry FOR ScHOOLS.
Hitchcock, A. TExT-BooK or GRASSES.
Livingston, Firup Crop Propuction.
Lyon, Fippin and Buckman, Sorts: THEIR
PROPERTIES AND MANAGEMENT.
Mann, Bucinnines in AGRICULTURE.
‘Montgomery, Tue Corn Crops.
Piper, Forage PLaANtTs AND THEIR CULTURE.
Warren, ExpmMents of AGRICULTURE.
Warren, Farm ManaGEemMent.
Wheeler, Manurus anp FERTILIZERS.
White, PriIncipLes oF FLORICULTURE.
Widtsoe, Principtes or I[RRricarion
TICE,

Others in Preparation.

SOILS

THEIR PROPERTIES AND MANAGEMENT

T. LYTTLETON LYON, Ps.D.

PROFESSOR OF SOIL TECHNOLOGY, CORNELL UNIVERSITY

ELMER O. FIPPIN, B.S.A.

EXTENSION PROFESSOR OF SOIL TECHNOLOGY
CORNELL UNIVERSITY

HARRY 0. BUCKMAN, Ps.D.

ASSISTANT PROFESSOR OF SOIL TECHNOLOGY
CORNELL UNIVERSITY

Nef Work
THE MACMILLAN COMPANY
1916

Coprrigat, 1909 anp 1915,
Br THE MACMILLAN COMPANY.

Set up and electrotyped Published September, x91z5. Reprintec
September, 1915; January, 1916

Norwood JBress
J.§. Cushing Co, — Berwick & Smith Co.
Norwood, Mass., U.§.A.

ACKNOWLEDGMENTS

THE authors wish to acknowledge the originals of
the two colored maps as occuring in Bulletins 60 and
96 of the Bureau of Soils, U. S. Department of Agricul-
ture. The remaining illustrations were drawn es-
pecially for this text. Some few are copies in part, or
in whole, from other authors. Acknowledgments not
made in text are due the Bureau of Soils, U. S. De-
partment of Agriculture; T. C. Chamberlin; E. W.
Hilgard; F. H. King; G. P. Merrill, and H. W. Wiley.
The authors wish also to express their appreciation to
Messrs. A. B. Beaumont and J. H. Bromley for their
careful work in the preparation of the original drawings
and to Miss Lela G. Gross for aid on the manuscript.
Thanks are also due Professor W. D. Bancroft for sug-
gestions as to the theoretical phases of soil colloids
and to Professor J. L. Stone for a like favor regarding
the soundness of the chapter on fertilizer practice.

TABLE OF CONTENTS

CHAPTER I

Some GENERAL CONSIDERATIONS .

Composition of the soil, 1— Factors for plant growth,
2— Plant food elements, 3— Abundance of plant food
elements, 4—-Soil-forming rocks, 5— Soil-forming min-
erals, 6— Relative abundance of minerals, 7 — Organic
matter, 8-— The soil and the plant, 9.

CHAPTER II
SorL-FORMING PROCESSES

Water, 10— Wind, 11—Ice, 12— Heat and cola, 1B
— Frost, 14—- Plants and animals, 15— Oxidation and
carbonation, 16-—~ Deoxidation, 17-— Hydration, 18 —
Solution, 19 — A general statement of weathering, 20 —
Factors affecting weathering, 21—-Law of mineral and
rock decay, 22 — Special cases of weathering, 23 — Prac-
tical relationships of weathering, 24.

CHAPTER III

Toe GEoLogicaL CLASssIFICATION OF Sorts . .
Residual soils, 25 — Distribution of residual soils, 26
— Cumulose soils, 27—Colluvial soils, 28— Alluvial
soils, 29— Distribution of alluvial soils, 80— Marine
soils, 831— Characteristics of marine soils, 32 —~ Distri-
bution of marine soils, 83.

CHAPTER IV

GzoLocican Cuassrrication or Sos (Continued)

The ice sheet, 84— The American ice sheet, 35—
Cause of the ice age, 36 — The extension of the ice sheet,
37— The ice as a soil builder, 838 — Glacial till soils, 39

vii

PAGES

1-12

13-30

31-45

46-64

Vill TABLE OF CONTENTS

PAGES
— Composition of glacial soils, 40— Humus of glacial

soils, 41 -— Glacial lakes, 42-— Lacustrine soils — glacial
lake, 43— Lacustrine soils—recent lake, 44— olian
soils. 45— Loess soils, 46— Distribution of loess, 47 —
Adobe soils, 48-— Sand dunes, 49— Volcanic dust, 50.

CHAPTER V

CLIMATIC AND GEOCHEMICAL RELATIONSHIPS OF SOILS . 65-82

Climatic relationships, 51-— Geochemical relationships
of residual and marine soils, 52 — Residual and glacial
soils, 53 — Effect of glaciation on agriculture, 54—- Hu-
mid and arid soils, 55—Soil color, 56— White and
black soils, 57— Red and yellow soils, 58 — Agricul-
tural significance of color, 59—Soil and subsoil, 60 —
Soil and subsoil of humid regions, 61— Soil and subsoil
of arid regions, 62.

CHAPTER VI

Tue Sort Particle. . . . . . . 88-107

Soil separates and mechanical: analysis, 63 — Princi-
ples of mechanical analysis, 64— Mechanical analysis
by water in motion. Schone elutriator, 65 — Hilgard’s
churn elutriator, 66 — Yoder’s centrifugal elutriator, 67
— Mechanical analysis by water at rest — Osborne’s
beaker method, 68 — Atterberg’s modified Appiani silt
cylinder, 69-—~ Centrifugal soil analysis, 70 — Classifica-
tion of soil particles, 71 — Bureau of Soils classification,
72 — Physical character of the separates, 73 — Mineral-
ogical characteristics of the separates, 74— The chem-
ical constitution of soil particles, 75— Value of a
mechanical analysis, 76—Soil class, 77 — Determination
of class, 78 — The significance of texture and class, 79.

CHAPTER VII

Some Puysicat PROPERTIES OF THE SOIL . . . . 108-125

Arrangement of soil particles, 80 The absolute spe-
cific gravity of the soil, 81 Apparent specific gravity,

TABLE OF CONTENTS ix

PAGES
82 — Actual weight of a soil, 83 — Pore space in soil, 84

— The number of soil particles, 85 Surface exposed
by soil particles, 86—-The effective mean diameter of
soil particles, 87.

CHAPTER VIII

Tur OreGanic Matrer or tHe Sor, . . . . . 126-152

The source and distribution of organic matter, 88~—~
Composition of plants, 89—~ Decay of organic matter in
soils, 90 —Composition of soil humus, 91— The work of
Oswald Schreiner, 92— Toxic material in the soil, 983 —
End products of humus decay, 94—Carbonized mate-
rials of soil, 95 — The estimation of soil organic matter,
96 — The estimation of soil humus, 97 — The organic
content of representative soils, 98 —~- The humus content
of soil, 99—- The influence of the original material on
the resultant humus, 100 — Effects of organic matter on
soil, 101 — Maintenance of soil organic matter, 102.

CHAPTER IX

Tus CottoraL Marrer or Sorts . . 158-169

The colloidal state, 108 — The properties « of colloids,
104 — Colloidal phases, 105 -—~ Flocculation, 106 -—Com-
mon soil colloids and their generation, 107 — Prepara-
tion of colloids, 108 — Colloids and soil properties, 109
— Factors affecting colloids, 110-—Estimation of col-
loidal content, 111.

CHAPTER X

Sort STRUCTURE . . . . 170~197

Plasticity, 112-— The cause of plasticity, 118 — The
importance of plasticity, 114—- Cohesion, 115 — Methods
of determining cohesion, 116— Factors affecting cohe-
sion, 117 — Moisture limits for successful tillage, 118 —
Control of cohesion and plasticity, 119— Soil tilth, 120
—— Granulation, 121— Forces facilitating granulation,
122 — Wetting and drying, 128 —- Freezing and thawing,

x TABLE OF CONTENTS

PAGES
124— Addition of organic matter, 125 — Action of plant
roots and animals, 126-—~ Addition of lime, 127 — Til-
lage, 128-— The action of the plow, 129 — Résumé, 180.
CHAPTER XI
Tue Forms or Sorn WatTER AND THEIR MOVEMENT . . 198-242

Methods of expressing soil moisture, 181 — Kinds of
water in the soil, 182 — Hygroscopic water, 133 — Effects
of texture and humus on hygroscopicity, 184-—~ Nature
of the film, 185— Effect of humidity and temperature
on hygroscopic water, 186— Determination of hygro-
scopicity, 137 -— Heat of condensation, 1388 — Capillary
water, 139-— Surface tension and the torce developed
thereby, 140 — The form of water surfaces between soil
particles, 141— Factors affecting capillary water, 142 —
Surface tension and the amount of capillary water, 143
—~ Texture and the amount of capillary water, 144 —
Effect of structure on the amount of capillary moisture,
145 — Organic matter and the amount of capillary mois-
ture, 146 — Determination of capillary water, 147 — The
moisture equivalent of soils, 148-— The maximum re-
tentive power of soils, 149-— Capillary movement, 150
—— Factors affecting rate and height of capillary move-
ment, 151-—-Effect of thickness of film on capillary
movement, 152-—Surface tension and capillary move-
ment, 1538 — Effect of texture on capillary movement,
154—- Texture and capillary pull of soils, 155 — Effect
of structure on capillary movement, 156 — Gravitational
water, 157— Pressure and the movement of gravity
water, 158 — Effect of temperature on the flow of grav-
ity water, 159-—- Effect of texture and structure on the
flow of gravity water, 160-—- Determination of the quan-
tity of free water that a soil will hold, 161— The caleu-
lation of the free water of a soil, 162 — Value of studying
flow and composition of gravitational water, 163 — The
study of gravity water by means of tile drains, 164—
The lysimeter method of studying gravitational water,
165 — Thermal movement of water, 166.

Tan Controy or Sor Moisture

TABLE OF CONTENTS

CHAPTER XII

THe WatTEeR oF THE SoIL IN ITs RELatTion TO Pranrs

Functions of water to the plant, 167—The water
requirement of plants, 168 — Factors affecting trans-
piration, 169— Effect of crop and climate on transpira~
tion, 170 — Effect of soil moisture on transpiration, 171
-—— Influence of fertility on transpiration, 172 — Effect of
texture on transpiration, 1738 — Actual amounts of water
necessary to mature a crop, 174— Réle of capillarity in
the supplying of the plant with water, 175 — Influence
of water on the plant, 176 — Availability of the water in
the soil, 177 — Unavailable soil water, 178 — The wilting
coefficient of plants, 179 — Determination of the wilting
point, 180 — Calculation of the wilting point, 181 — Re-
lation of texture to the wilting point, 182— Available
and superavailable water, 183-—- Optimum moisture for
plant growth, 184.

CHAPTER XII

Run-off losses, 185 —- Percolation losses, 186 — Methods
of checking loss by run-off and leaching, 187 — Evapo-
ration losses, 188 — Methods of checking evaporation
losses, 189—~ Mulches for moisture control, 190 — Kinds
of mulches, 191— The functions of a mulch, 192-— The
soil mulch versus the dust mulch, 193 —~ Formation of a
mulch, 194 — Depth of a mulch, 195 — Résumé of mulch
control, 196 — Water saved by a mulch, 197 — Effect of
mulches other than on moisture, 198-— General useful-
ness of a mulch, 199-— Other practices affecting evapo-
ration losses, 200 — Fall and early spring plowing, 201—
Rolling, 202 — Shelters, 203-— Level cultivation, 204—
Plants, 205 — Summary of moisture control, 206,

CHAPTER XIV

Som Hmar . °°. . .

Relation of heat to germination and gro wth, 207 —
Chemical and physical changes due to heat, 208 —

PAGES

243-263

264-288

289-326

TABLE OF CONTENTS

Sources of soil heat, 209-—— Factors affecting soil tem-
perature, 210 —Specific heat, 211— Vaziations of spe-
cific heat, 212— Specific heat based on volume of soil,
218 — Eftect of water on specific heat, 214 -— Absorptive
power of soils for heat, 215 — Effect of color on absorp-
tion of heat, 216-—~ Effects of texture and structure on
heat absorption, 217 — Radiation of heat by soil, 218 —
Conductivity and convection of heat in soils, 219—
Measurement of conductivity, 220— Effect of texture
on conductivity of heat, 221—~ Effects of humus and
structure on conductivity, 222 — Influence of moisture
on heat conductivity in soil, 223— Effect of evaporation
of water on soil temperature, 224— Effect of organic
decay on soil temperature, 225—~ Relation of slope to
soil temperature, 226 — Heat supply and its effects, 227
~—— Control of soil temperature, 228.

CHAPTER XV

AVAILABILITY OF Prant Nutrients aS DETERMINED BY

CHemMicaAL ANALYSIS

Solubility of the soil in various solvents, 229 — Com-
plete solution of the soil, 230— Partial solution with
strong acids, 231 — Significance of a strong hydrochloric
acid analysis, 282-- Relation of texture to solubility,
233 — Nature of the subsoil, 234-——Calcium carbonate,
235 — Deficiency of ingredients and manurial needs, 236
— Partial solution with weak acids, 287 — Advantages
in the use of dilute acids, 288 — The one-per-cent citric
acid method, 239 —- Usefulness of the citric acid method,
240 —- Dilute mineral acids, 241 — Extraction with an
aqueous solution of carbon dioxide, 242 — Extraction
with pure water, 243-~— Influence of absorption, 244 —
Other factors influencing extraction, 245 —— The soil solu-
tion in situ, 246 — Devices for obtaining a soil solution,
247 —-Composition and concentration of the soil solu-
tion, 248 — Variability in composition and concentration
of the soil solution, 249— Discussion of the theories
regarding soil solutions, 250.

PAGES

827-348

TABLE OF CONTENTS Xl

CHAPTER XVI

PAGTS
Tas ABSORPTIVE PROPERTIES OF SOILS . . . . 849-874

Substitution of bases, 251-—— Time required for absorp-
tion, 252 — Insolubility of certain absorbed substances,
2583 — Influence of size of particle, 254 — Causes of ab-
sorption, 255— Zeolites, 256—Chabazite, 257 —~ Pres-
ence of zeolites questioned, 258-—- Absorption of phos-
phoric acid, 259-—— Formation of insoluble phosphates,
260—- Absorption, 261-——- Absorption by colloids, 262 —
Absorptive properties of colloidal matter, 263 — Selective
absorption, 264-— Absorptive power of colloidal silicates,
265 — Absorption by colloids versus absorption by zeo-
lites, 266-—~ Absorption by organic matter, 267 — Ab-
sorption of water vapor and of gases by soils, 268 —
Absorption of ammonia, 269-—— Absorption of carbon
dioxide, 270 —- Absorption of nitrogen and oxygen, 271
— Relation of temperature to gas absorption, 272-—
Relation of absorptive capacity to productiveness, 278
— Absorption as related to drainage, 274 — Substances
usually carried in drainage water, 275— Drainage rec-
ords at Rothamsted, 276-— Drainage records at Brom-
berg, 277 -— Losses of nitrogen and calcium, 278 —
Composition of surface water, 279.

CHAPTER XVII

Acrip or Sour Sorts . . . . . . . 375-890

Nature of soil acidity, 280 — Positive acidity, 281 —
Negative acidity, 282— Production of sour soils, 283 —
Removal of bases by drainage as a cause for acidity, 284
— Removal of bases by plants, 285— Effect of green
manures on acidity, 286—Effect of fertilizers on soil
acidity, 287-— Acidity in relation to climate and to for-
mation of soil, 288— Weeds that flourish on sour soils,
289 — Crops adapted to sour soils, 290-— Crops that are
injured by acid soils, 291 — Qualitative tests for acidity,
292 — Litmus paper test, 298 — Ammonia test, 294 —
Zine sulfide test, 205 — Litmus paper and potassium
nitrate, 296-— Acid test for carbonates, 297 —~ Plants as

X1V TABLE OF CONTENTS

PAGES
indicators of acidity, 298 — Quantitative determinations

of acidity, 209 — Potassium nitrate method, 300 — Lime-
water inethod, 801—- Résumé, 302.

CHAPTER XVIII

ALK ivr SOILS . . . . 391-408

Composition of alkali salts, 303— White and black
alkali, 304 — Effect of alkali on crops, 305 — Effect on
different plants, 806— Other conditions that influence
the action of alkali, 307 — Accumulation of alkali, 308 —
Irrigation and alkali, 309 — Handling of alkali lands, 310
~~ Eradication of alkali, 311—- Leaching with under-
drainage, 312 — Correction with gypsum, 3138 — Scraping,
314 — Flushing, 315 — Control of alkali, 316 — Cropping
with tolerant plants, 817 — Alkali spots, 318.

CHAPTER XIX

ABSORPTION OF NcuTRITIVE SALTS BY AGRICULTURAL Pruants 404-420

How plants absorb nutrients, 319 — Relation between
root-hairs and soil particles, 320— Liebig and Sachs on
solvent action of plant-roots, 821 —- Czapek’s experiment,
322 — Secretion of an oxidizing enzyme by plant-roots,
323-—- Importance of carbon dioxide as a solvent, 824 —
Insufficiency of carbon dioxide, 8325 -— The present status
of the question, 326-— Possible root action on colloidal
complexes, 327-—- Why crops vary in their absorptive
powers, 328-—Extent of absorbing systems, 329— Os-
motic activity, 380 — The absorptive power of cereals,
831—The feeding of grass crops, 882 —Leguminous
crops, 333 — Root crops, 884 — Vegetables, 385 — Fruits,
336 — Mineral substances absorbed by plants, 837 — Re-
lation of plant growth to concentration of nutrient solu-
tion, 888 — Quantities of plant food materials removed
by crops, 339-— Quantities of plant food materials con-
tained in soils, 340— Possible exhaustion of mineral
nutrients, 341,

TABLE OF CONTENTS XV

CHAPTER XX

PAGES
ORGANISMS IN THE SOIL . . . . . . 421-442

Macroorganisms.
Rodents, 842—-Worms, 343 — Insects, 344 — Large
fungi, 345 — Plant root, 346.

Microorganisms.

Plant microdrganisms, 847-—Plant microdreanisms
injurious to higher plants, 348 — Plant microorganisms
not injurious to higher plants, 3849— Bacteria, 350 —
Distribution of bacteria, 851-— Numbers of bacteria, 352
— Numbers as influenced by season, 3538 — Conditions
affecting growth, 354 Oxygen, 355 — Moisture, 356 —
Temperature, 357 — Organic matter, 358 — Soil acidity,
359 — Functions of soil bacteria, 360 — Decomposition
of mineral matter, 361—JInfluence of certain bacteria
and molds on the solubility of phosphates, 362 — Decom-
position of non-nitrogenous organic matter, 363 — De-
composition of nitrogenous organic matter, 364.

CHAPTER XXT

Tue NirroGen CYCLE . . . . . . ; . 443-474
Decay and putreiaction, 365 — Ammonification, 366 —
Bacteria and substances concerned in ammonification,
367 — Nitrification, 368— Effect of organic matter on
nitrification, 369 —~ Effect of soil aération on nitrification,
370 —- Effect of sod on nitrification, 371— Depths at
which nitrification takes place, 372—-Loss of nitrates
from the soil, 373— Nitrate reduction, 874 — Nitrate
assimilating organisms, 875 — Denitrification, 376 — Ni-
trogen fixation through symbiosis with higher plants,
377 — Relation of bacteria to nodules on roots, 378 —
Transfer of nitrogen to the plant, 379 — Soil inoculation
for legumes, 380 — Nitrogen fixation without symbiosis
with higher plants, 381 — Nitrogen-fixing organisms, 382
— Mixed cultures of nitrogen-fixing organisms, 888 —
Nitrogen fixation and denitrification antagonistic, 384.

XVl

TABLE OF CONTENTS

Treatment of Suils with Volatile Antiseptics and Heat.

Effects of carbon bisulfide and heat on properties of
soils, 885 — Hypotheses to account for effects of carbon
bisulfide and of heat, 386 — Koch’s theory, 887 — Hiltner
and Stormer’s theory, 888 — Russell and Hutchinson’s
theory, 389~—~ Greig-Smith’s theory, 390.

CHAPTER XXII

Tae Sor Arr

Factors that Determine Vulume.

Texture, 391 — Structure, 392—~ Organic matter, 393
— Moisture content, 394.

Composition of Soil Air.

Analyses of soil air, 395— Sources of carbon dioxide
in soil air, 8396 — Production of carbon dioxide as affect-
ing composition, 597.

Functions of Svtl Air.

Oxygen, 398 — Carbon dioxide, 399.
Movement of Soil Air.

Diffusion of gases, 400-—- Movement of water, 401 —
Changes in atmospheric pressure, 402 — Changes of tem-
perature in atmosphere or in soil, 403 — Suction produced
by wind, 404.

Methods for Modifying the Volume and Movement of
Soil Air.

Tillage, 405 -— Manures, 406 -~ Underdrainage, 407 —

Irrigation, 408 —- Cropping, 409.

CHAPTER XXIII

ComMERCIAL FERTILIZERS . . . : . .

Early ideas of the function of manures, 410 — Devel-
opment of the idea of the nutrient function of manures,
411 — Classes of manures, 412 — Commercial fertilizers,
413 — Fertilizer constituents, 414.

Fertilizers Used for their Nitrogen.

Forms in which nitrogen exists in soils, 415 — Forms
in which nitrogen is absorbed by plants, 416— Use of
nitrates by plants, 417 Ammonia as a plant food, 418

PAGES

475-488

489-533

TABLE OF CONTENTS XVil

— Utilization of humus compounds by plants, 419— vases

Sodium nitrate, 4£20-— Ammonium sulfate, 421 — Ferti-
lizers containing atmospheric nitrogen, 422 — Cyanamid,
423 — Composition of cyanamid, 424— Changes of cal-
cium cyanamid in the soil, 425—~-The use of cyanamid,
496 — Calcium nitrate, 427— Organic nitrogen in ferti-
lizers, 428-—- Availability of organic nitrogenous ferti-
lizers, 429.

Fertilizers Used for their Phosphorus.

Bone phosphate, 430— Mineral phosphates, 431 —
Superphosphate fertilizers, 482—-Reverted phosphoric
acid, 488 — Relative availability of phosphate fertilizers,
434 — Changes that occur when superphosphate is added
to soils, 485 — Other factors influencing the availability
of tricalcium phosphate, 486 — Effect of plants on the
availability of tricalcium phosphate, 487— Effect of
basicity on tricalcium phosphate, 438 — Influence of fer-
menting organic matter, 489 — Influence of other salts,
440.

Fertilizers Used for their Potassium.

Stassfurt salts, 441-—-Wood ashes, 442— Insoluble
potassium fertilizers, 4438.

Sulfur and Sulfates as Fertilizers.

The use of free sulfur, 444— Sulfur as sulfate, 445.
Catalytic Fertilizers.

Nature of catalytic action, 446— Catalytic action of
soils, 447 —- Substances used as catalytic fertilizers, 448
— Manganese, 449— Physiological réle of manganese,
450 — Action of manganese as a fertilizer, 451— Forms
of manganese and response of soils, 452.

CHAPTER XXIV

Sor, AMENDMENTS . . .

Salts of calcium, 453— Effect on tilth and bacterial
action, 454 — Liberation of plant food materials, 455 —
Influence of lime on the formation of nitrates in soil, 456
-— Effect on toxic substances and plant diseases, 457 —

§34-545

XVill TABLE OF CONTENTS

PAGES
The lime-magnesia ratio, 458 — Forms of calcium, 459 —

Caustic limes, 460 — Carbonate of lime, 461 — Relative
effectiveness of caustic lime and carbonate, 462 — Sul-
fate of calcium, 468 — Common salt, 464-— Muck, 465.

CHAPTER XXV

FeRvILizER PRACTICE . . . . . . . . 546-576

Effects of nitrogen on plant growth, 466 — Effects of
phosphorus on plant growth, 467 — Effects of potassium
on plant growth, 468 — Law of the minimum, 469 — Fer-
tilizer brands, £70 -— Fertilizer inspection and control,
471 -— Trade values of fertilizers, 472-— The buying of
mixed goods, 473 — Home-mixing fertilizers, 474 — Fer-
tilizers not to be mixed, 475— How to mix fertilizers,
476 — Factors affecting the efficiency of fertilizers, 477 —
Method and time of applying fertilizers, 478 — Fertiliz-
ing crops, 479 — Systems of fertilization, 480.

CHAPTER XXVI

Farm MANURES . . . . . . . . . 577-618

General character and function of farm manures, 481
— Variable composition of manures, 482 — Litter, 483 —
Class of animal, 484 -— Individuality, condition, and age
of animal, 485 — Food of animal, 486— Handling of the
manure, 487 — Composition and character of farm ma-
nures, 488 — Actual plant-food in liquid and solid excre-
ment, 489— Production of manure, 490 — Heiden’s
formula, 491— Poultry manure, 492-—-Commercial and
agricultural evaluation of manures, 498 — The fermenta-
tion of manure, 494 — Aérobic action, 495 — Anaerobic
action, 496 —- Fermentation in general, 497 — Gases from
manures, 498— Change of bulk and composition of rot-
ting manure, 499—Fire-fanging of manure, 500—
Waste of farm manures, 501— Losses due to digestion,
502-— Losses due to leaching and fermentation, 5038 —
Increased value of protected manure, 504-—The money
waste of manure, 505— Handling of manures, 506—
Care of manure in the stalls, 507 — Hauling directly to

TABLE OF CONTENTS xix

the field, 508 —Cemient pit, 509—— Covered barnyard, a

510 —~ Piles outside, 511 — Distribution of manure in the
field, 512—Reimiorcement of manure, 515— Genefiis
from reinforcing, 514— Lime and manure, 515 —Com-
posting, 516— Manure and muck, 617 — Miects of ma-
nure on the soil, 618 — Residual eiect of manure, 519 —
Piace 0i Manure in the rotation, 620-— Resume, 521,

CHAPIER XXVII
GREEN MANUEES . : : ; : : : . 619-626

fects Of gréen-manurins, 522-— Quantities of plant
constimments added by green-manuring, 523—— Decay of
sreen Manure, 6524 — Crops suitable for ereen manures,
52o— When 10 use green manures, 526 — When to turn
under Sreen crops, 527 — How to turn under green mate-
rial, 526 — Green manures and lims, 529-— Green manure
and the rotation, 550,

CHAPTER XXVIII

LAND DRAINAGE -; : : a : . 627-662

Hixtent of drainage needed in humid regions, 631 —
History of drainage, 552— Eifects oi land drainage on
the soil, 568 —= Methods of drainage, 534— Construction
Of small open ditches, 535 ——Construction of larse open
ditches, 586— Construction of early types of under-
drains, 50/ stone drains, 653— Tile drains, 539 —
Quality of tile, 540— Shapes of tile, 541 — Protection of
joints, 542 — Enirance of roots into tile, 645 -— Protection
Of joints On Curves, 544-—Poundation for tile, 545 —
Arrangement Of drainage systems, 540-——Grade of tile
Grains, 647——Depth of drains, 545-—— Distance between
drains, 649-—— Construction of dramage trenches for tile,
550— Laying tile, 551-——Size of tile, 502-— Amount of
Water to be removed trom land, 552 —- Carrying capacity
of @& tile-drain system, 554——Cost of drainage, 555—
Storm channels, 556 — Silt basins, 567 —— Suriace intakes,
558 —— Outlets, 569-— Muck and peat soil, 560— Drain-

TABLE OF CONTENTS

age of irrigated and alkali lands, 561— Vertical drainage,
562 — Drainage by means of explosives, 563 — Résumé,
564.

CHAPTER XXIX

TILLAGE

Objects of tillage, 565 -—- Implements of tillage, 566 —
Effects on the soil, 567 — Classes of tillage implements,
568 — Plows, 569 — Pulverizing action of the plow, 570
— Types of plows, 571— Shapes of moldboard plows,
572-—— Position of the furrow slice, 573— Depth and
width of furrow, 574—— Plow sole, 575—~ Hillside plow,
576 —- Covering rubbish, 577 — Subsoil plow, 578 —
Cultivators, 579—~ Cultivators proper, 580 — Leveler
and harrow types of cultivator, 581—- Seed cultivators,
582-—~ Packers and crushers, 588—~ Rollers, 584-—— Clod
crushers, 585 — Efficient tillage, 586.

CHAPTER XXX

IRRIGATION AND Dry Farmrne

Relation of irrigation to rainfall, 587—~ Extent of irri-
gated land, 588—- History of irrigation, 589 — Develop-
ment of irrigation practice in the United States, 590 —
Irrigation in humid regions, 591—-The Reclamation
Service, 592-— Legal, economic, and social effects of
irrigation, 593 — Divisions of irrigation, 594 — Source of
water for irrigation, 595—- Canals, 596 — Preparation of
land for irrigation, 597-—~- Methods of applying water,
598 — Overhead sprays, 599 — Subirrigation, 600—
Methods most used in arid regions, 601 — Flooding, 602
— Furrows, 603 — Size and form of furrows, 604— Unit
of measurement, 605-- Amount of water to apply, 606
— Time to apply water, 607 — Conservation of moisture
after irrigation, 608 —Sewage irrigation, 609.

Dry Farming.

Practices in dry farming, 610 — Storage of water in
the soil, 611 —- Conservation of moisture, 612 — Alternate
cropping, 6138 — Drought-resistant crops, 614 — Soils

PAGES

663-681

682~717

TABLE OF CONTENTS XX]

PAGES
associated with dry farming, 615 — Extent of dry farm-

ing, 616.

CHAPTER XXXI

Tun Sor, SURVEY . . . . . . . 118-740

The classification of soils by survey, 617 — Factors
employed in classification, 618 — Texture, the soil class,
619 — Special properties, the soil series, .620 — Source of ,
material, the soil group, 621— Agency of formation, the
soil province, 622 — Climate, 623 — The practical classi-
fication of soils in the United States, 624 — The soil type
and soil series, 625—The equipment for survey work,
626 -— Procedure in the field, 627 — Collection of soil
samples, 628-— The accuracy and detail of the soil sur-
vey, 629— The soil survey report, 630 — The soil map,
631— The extent of soil surveys in the United States,
632— Surveys by state institutions, 688— Surveys in
other countries, 634 — Use of the soil survey, 635.

SOILS: THEIR PROPERTIES
AND MANAGEMENT

CHAPTER I

SOME GENERAL CONSIDERATIONS

Tue broken and weathered fragments of rock that
cover in a thin layer the solid part of the earth and that
furnish the foothold and, in part, the sustenance for plant
life, are termed soil. Soil comes from rock and returns
to rock. It is merely a transitory stage in the change
from one form of rock to another. It is never still. From
the time when the particle leaves the disintegrating rock
until it is again cemented in the skeleton of the earth,
it is subjected to almost constant movement and to the
action of numerous forces that change it chemically and
physically. It is the movement, the strain and the
stress, the hard treatment at the hands of disintegrating
agencies, that make the soil useful to plant life.

It was only the simpler forms of plants, however, that
first throve on the pulverized rock. Tribe after tribe of
plants has invaded the soil. Each has wrested from it
the mineral matter necessary for its growth and develop-
ment. Each has, in the end, left not only the mineral
matter that it obtained from the disintegrated rock, but
also the carbon and the oxygen that had been won from the

B 1

2 SOILS: PROPERTIES AND MANAGEMENT

air in the struggle for life. Primitive plants have been
followed by more highly organized ones as the incursions
have gone on, and always to the profit of the soil, until
the soil has accumulated a great store of organic matter
and a teeming population of microscopic life.

This débris of rock and plant residue that has accumu-
lated through the centuries of struggle is the arable soil
from which man obtains his bread. The study of this
soil is a history of strife and struggle, and as the light of
investigation is turned on it, new contestants, new opera-
tions, new results, and new principles are brought to view
and the story must be retold.

1. Composition of the soil.— Broadly speaking, the
soil is composed of two general classes of materials, rock
and organic matter. The former usually makes up the
bulk of the soil, while the latter occurs under normal
conditions in relatively small amounts. In spite of this
low proportion, however, its presence is of vital impor-
tance to productivity. The soil has also three general
phases — the physical, the chemical, and the biological.
In the physical phase, the size and shape of particle, the
movement of air and water, and other physical proper-
ties are dealt with; in the chemical phase, the composi-
tion of the particle, of the organic matter, and of the soil
solution isof dominant importance; in thebiological phase,
the soil is seen to be not an inert material, but teeming
with life — minute forms of life, to be sure, but of great
importance in the manufacture of food for plants. Under
these three general phases, then, the changes going on in
a, soil may be studied, and they are found to be directed
primarily toward the production and maintenance of con-
ditions favorable for plant growth. The soil is not a
simple medium to study, but is extremely complicated

SOME GENERAL CONSIDERATIONS 8

for two reasons: first, because of the complicated nature
of its two general constituents; and secondly, because of
the action and interaction of these constituents with each
other.

2. Factors for plant growth. — The growth and devel-
opment of a plant are largely the result of two sets of
factors, the internal and the external. The former de-
pends on the nature of the plant itself, the latter on its
environment. The external factors of plant growth under
normal conditions may be classified as follows: (1) me
chanical support, (2) air, (3) heat, (4) light, (5) water, and
(6) food. With the exception of light, the soil supplies,
either wholly or in part, all the conditions named. As
a mere mass of ground-up rock with which are mixed
varying quantities of decayed organic matter, the soil
acts as a medium for root development and thereby pro-
vides a foothold for the plant. Aur, heat, and water are
supplied as a consequence of the inherent physical condi-
tion of a soil. The circulation of water serves to bring
food into solution for absorption by the rootlets. Thus
the two prime functions of the soil are realized — the
supplying of plant-food and of a foothold for plant life.

3. Plant-food elements.1— While the physical condition
of the soil has tremendous influence on plant growth, the
food elements must first be considered, since their avail-
ability is so closely related to the factors that function
in soil formation. Ten elements are usually considered
as absolutely necessary for plant growth. They may be
classified as follows :—

1¥For a complete discussion of the plant-food elements as re-
lated to the plant, see Russell, E. J. Soil Conditions and Plant
Growth, Chapter II, pp. 30-46, New York City. 2d edition,
1915.

4 SOILS: PROPERTIES AND MANAGEMENT

Elements obiained from Elements coming directly from!
air or water the soil itself
Carbon Nitrogen Magnesium
Oxygen Phosphorus Iron
Hydrogen Potassium Sulfur
Nitrogen Calcium

Carbon is obtained very largely by the plant directly
from the air as carbon dioxide (CO,); while oxygen
comes directly from the atmosphere or from water, which
is also the source of at least a part of the hydrogen utilized
in vegetative growth. The other elements, except in
the case of leguminous crops, are taken wholly from the
soil solution itself.

While all these elements found in the soil must be
available in order that plants may grow normally, only
a very few ever become limiting factors. The three
elements most likely to be lacking im a soil from a food
standpoint are nitrogen, phosphorus, and potassium.
They may be designated as the primary elements for
plant growth. The other elements are usually present
in amounts many times greater than will ever be needed
by crops. Calcium, while necessary in large quantities
in a soll, is largely an amendment, and very seldom may
limit plant growth because of being in too minute quantity
to supply the food needs of a crop. The liming of a soil
is for other purposes than the supplying of calcium for
plant nutrition. Sulfur is supposed, in certain soils,
to limit plant growth because of its insufficiency, but
ordinarily it is never found in a minimum quantity.

Nitrogen exists in the soil largely as a portion of the

1 Sodium, silicon, and aluminium are found in plants, but are
not essential to proper growth.

SOME GENERAL CONSIDERATIONS 5

partially or wholly decayed organic matter present therein.
It is utilized by the plant ordinarily in the form of nitrate.
The atmosphere, composed of four-fifths nitrogen by
volume, has been the original source of this element;
and through natural processes which are continually
at, work the nitrogen has been transferred to the soil.
The encouragement of this natural fixation, thus draw-
ing upon the great body of gas surrounding the earth,
has become of great practical importance in agricultural
operations.

Phosphorus has its origin in the mineral apatite and
exists in most soils largely as a tricalcium phosphate
(Cas(PO,)2). In case of a lack of lime or of the presence
of considerable quantities of humus, phosphorus may be
present as ferric or aluminium phosphates or as organic
phosphoric acid. Phosphorus is probably taken up by
the plant as the mono-or di-calcic phosphate (CaH4(PO,).
or CasH> (PO,4)2).

The potassium of the soil exists largely in feldspar
(K20 . Al,O3 . 6 SiOz), in mica, or in hydrated aluminium
silicates, which, while rather insoluble, supply potash
to the soil solution in the bicarbonate, chloride, nitrate,
or sulfate forms. It is from such compounds that the
plant draws upon the soil for this element.

4. Abundance of plant-food elements. — Having con-
sidered the plant-food elements, especially those of primary
importance, it is of interest to note their distribution in
the earth’s -crust. Clarke! estimates the composition
of the lithosphere, which makes up 93 per cent of the
known terrestrial matter, as follows :—

1 Clarke, F. W. Data of Geochemistry. U.S. Geol. Survey,
Bul. 491, p. 38. 1911.

t) SOILS: PROPERTIES AND MANAGEMENT

Oxygen... . 47.17 Sodium ... . 2.48
Silicon . . . . 28.00 Potassium . . . 2.49
Aluminium . . . 784 Hydrogen... .28
Tron . ww. COE = CO Carbon: 7 ww. OY
Calaum . . . . 342 Sulfur... . Jil
Magnesium . . . 2.27 Phosphorus... 11

The briefest scrutiny of this table reveals the fact that
the lighter elements are the more abundant in the earth’s
crust. The first four elements make up eighty-seven per
cent, while the primary elements of plant growth either
are lacking or are present only in very small quantities.

5. Soil-forming rocks. — As has been stated, ordinary
soil is made up largely of Inorganic matter which is derived
from ground-up rock material. Therefore, in any study
of soil origin or formation, however cursory, the atten-
tion must be directed toward geological conditions, not
because of their mere geological interest but because of
their ultimate bearing on soil fertility and crop growth.
In the soil we expect to find, and do find, fragments of
the commonest rocks, because those most exposed and
those present to the largest extent at the earth’s surface
must be the ones to break down into soil. Therefore
the commonest soil-forming rocks are the rocks that
are met so commonly in the field. They may be classified
broadly under three heads — igneous, sedimentary, and
metamorphic. Some of the common types are as follows:

Igneous Sedimentary Metamorphic
Granite Limestone Schist
Syenite Sandstone Gneiss
Diorite Shale Marble
Diabase Dolomite Slate
Gabbro Quartzite

Peridotite

SOME GENERAL CONSIDERATIONS 7

The igneous rocks furnish material for the formation
of the types constituting the other groups. They may
be divided in a general way into two classes — one con-
taining a high percentage of silica and some free quartz,
the other having a medium or low silica content and no
quartz. ‘The former is designated as acid, and the latter
as basic since it contains a high percentage of the alkalies
and the alkaline earth minerals. Granite and gabbro
are excellent examples, respectively, of these general
groups of rock.

The sedimentary rocks, formed from material derived
from the igneous rocks, have been deposited usually
under fresh- or salt-water conditions. The development
of pressure has In many cases been instrumental in the
consolidation of this material. The limestone and the
dolomite deposited by precipitation may be expected
to be comparatively soluble rocks. Shale is merely a
more or less hardened clay, while sandstone varies ac-
cording to the cementing material which serves to hold
its sand grains together. This cement may be iron
(Fe.O3), calcium carbonate (CaCQs), or silica (SiO).

The action of heat, usually with pressure, on either
igneous or sedimentary rocks, results in the third group,
the metamorphic. Thus, granite on metamorphosis
may form either a gneiss or a schist ; limestone or dolomite
may form marble; shale may form slate; and sandstone
may form quartzite.

On examination, ordinary rock is found to be composed
of one or more minerals. In other words, it is a mineral
aggregate. The mineral, in turn, is a natural compound
of approximately a constant chemical composition, usually
displaying a crystalline form and other well-defined
physical properties. In order to illustrate the com-

8 SOILS: PROPERTIES AND MANAGEMENT

plication that may arise, the mineral composition of some
common rocks is given below : —

Granite — Quartz, orthoclase, and plagioclase with mica
and hornblende.

Syenite — Orthoclase and mica with hornblende and
augite.

Basalt — Plagioclase and hornblende or augite with
apatite, pyrite, and mica.

Peridotite — Olivine with augite, pyrite, mica, and horn-
blende.

Limestone — Calcium or magnesium carbonate with traces
of silica. and iron.

Sandstone — Sand cemented with iron, silica, or calcium
carbonate.

This complex character of rocks has an important
bearing on the question of soil formation, since the presence
or absence of certain minerals may have considerable in-
fluence on the physical or chemical characteristics of the
resultant soil. It is the minerals, therefore, rather than
the rocks themselves, that must be looked to in a study
of the great mass of inorganic matter, some active and
some inactive, which makes up the bulk of ordinary
soils. The question of the composition of a soil thus
becomes more intensely geologic as we proceed.

6. Soil-forming minerals.—A great many minerals
have been discovered, studied, and classified, but only a
comparatively few occur in any abundance in the normal
soil. Nevertheless, it may be said that practically all
soils contain all the common rock-forming minerals.
This is to be expected, as fragments of practically all the
common rocks go to make up an ordinary soil. The

SOME GENERAL CONSIDERATIONS 9

following list will give some idea of the minerals normally
present in soils : —

COMMON SOIL-FORMING MINERALS

1. Quartz.
2.
3. Plagioclase

Orthoclase

. Hornblende

. Augite .

. Muscovite

. Biotite.

. Olivine

. Serpentine
. Epidote

. Apatite

. Zircon .

. Chlorite

. Calcite

. Dolomite .
. Gypsum
. Tale

. Hematite .
. Siderite

. Limonite .
. Kaolinite .
. Zeolites

S10.

K,0 . AlbOs . 6 SiO,

Na2O . Al,O3 . 6 S102, CaO . ALLO. 2 SiO>
or combinations

Chiefly Ca(MgFe)3Si,O1e with
NacAlsigOre and (MegFe), . (AlFe)> .
S1gOie

Chiefly CaMgSi0O, with (MgFe)
(AlFe) 2120 6

2 H.O. 1:0. 3 AlOs . 6 SiO.

(HIN)» (MgFe), (AlFe): (S104)3

2 (MgFe)O . SiO,

3 MgO .2Si0,. 2 H,0

HO .4 CaO. 3 (AlFe).03 . 6 Si02

3 CasP203 + (CaFl,) or (CaCl) or
combinations

ZrO, . SiOg

Hyo(FeMg)o3AhSirgOo0

CaCOx3

CaCO; . MgCO;

CaSO, 2 HO

FeO:

FeCQO3

2 FeO; . 3 HO

2 H.0 . Al,O3 . 2 SiO»

Complex hydrated aluminium silicates of
Ca, K, and Na as Philolite (Cak,Ne)
Al.Si1p0 24 5 H,O

10 SOILS: PROPERTIES AND MANAGEMENT

There are certain of these minerals that merit especial
attention because of particular attributes which they may
impart to a soil. Quartz, for example, is very common
in all soils, making up usually from 85 to 99 per cent of
their composition. It is a makeweight material, how-
ever, as it is used to a very slight extent by most plants;
but it adds a stability to the soil that perhaps the soil
would not otherwise have, and this function is of con-
siderable significance. Of greater importance from the
plant-food standpoint are the feldspars, of which orthoclase
is probably primary because it is the source and store-
house of the soil potash. Acted upon by physical and
chemical agencies, it slowly supplies the soil solution with
potassium, which in turn nourishes the plant. The micas
also may furnish considerable potash for crop growth.
The plagioclase, instead of being rich in potassium, as
the formula indicates, contain the more basic elements,
calcium and magnesium, as also do the pyroxenes and
amphiboles represented by augite and hornblende. Olivine
and serpentine, also silicates, are particularly rich in
magnesium. Practically all the phosphorus in the soil,
either organic or inorganic, has had its origin in the
mineral apatite; yet this mineral is present in rocks and
soil usually in very small quantities, making up not more
than 0.6 per cent of the bulk of igneous rocks. More-
over it is a rather insoluble material. This fact, together
with the small quantities occurring in soil-forming rocks,
may account for the need of phosphorus in many otherwise
fertile soils.

Calcium, so important as a basic material in soil, may
be supplied to a certain extent by other minerals besides
those already named — calcite, dolomite, and gypsum
being perhaps the most important, especially the calcium

SOME GENERAL CONSIDERATIONS 11

carbonate in either the crystalline or the amor-
phous forms. Plenty of calcium in a soil tends not only
to better physical conditions, but also to improve chemical
reactions and biological activity. The iron of the soil
minerals is of importance in its color relationships, for
when oxidized to the hematite form a bright red may be
imparted, while a yellow may result if limonite is pro-
duced. Color has great significance in a general estimate
of soil productivity and is always an important factor in
soil identification and survey. The tendency of most
iron compounds in the soil is toward the hematite or the
limonite form when subjected to oxidation and hydration.

Kaolinite is a product of rock decomposition and is
considered to be of considerable importance in most clays
or clay loams. It is almost always impure and in this
form is designated as kaolin. Jaolin and the soil zeolites,
which are hydrated aluminium silicates carrying chiefly
calcium, sodium, and potassium, are really the end prod-
ucts of rock decay and therefore are secondary minerals.
Consequently they must always be considered in any
study of soil formation or of soil utilization, particularly
as they may serve to enrich the soil solution in plant-food
held by them in physical and chemical combinations.

7. Relative abundance of minerals. — D’Orbigny * pre-
sents the following table as a result of his calculation on
the distribution of certain minerals in the earth’s crust : —

Percentage Percentage
Feldspars. . . . . 48 Carbonates . ... tL
Quartz. . . . . . 385 Hornblende, augite, ete. 1
Miean . .. . . . 8 Allother minerals . . 2
Tale ...... 9

1Hall, A. D. The Soil, p. 16. New York City. 1907.

12 SOILS: PROPERTIES AND MANAGEMENT

This agrees in general with the distribution of these
minerals in the earth’s surface and accounts for their
universal presence in all soils.

8. Organic matter.— The minerals as listed account
for all the elements of plant-food obtained from the
soil except nitrogen, which, as already indicated, is found
very largely locked up in proteid and other nitrogenous
material. The incorporation of organic matter in any
soil, either by natural or by artificial means, besides
tending to better its physical condition also enriches
it in its total, or gross, nitrogen content. Though this or-
ganic matter is so necessary in a fertile soil, its addition
and thorough incorporation occurs late in the process of
soil formation. Through the agency of bacteria and
other organisms the organic compounds are slowly sim-
plified, new compounds are split off, and nitrogen is in-
troduced into the soil solution mainly as nitrate, which
is one of the principal forms in which it may be used by
plants growing on the soil.

9. The soil and the plant. — Observed from the agri-
cultural standpoint, then, the soil becomes purely a
medium for crop production. Its composition, both
mineral and organic, is of vital importance in the further-
ance of such a use. All the physical, chemical, and
biological agencies become directed toward this end.
The study of the soil and a better understanding of its
function will allow the great class of landowners not
only to merease their crops, and consequently their
profits, but at the same time to maintain as far as possible
the fertility of our greatest national resource. A rational
study of the soil should ultimately lead to a study of
conservation in its bearing both to present prosperity
and to the welfare of posterity.

CHAPTER II

SOIL-FORMING PROCESSES

AFTER the first proper estimate of the relations hetween
the crop and the soil, the next step is toward the mode of
soil formation and the agencies concerned. As might be
expected, this 1s a complicated problem from the fact
that most rocks are so heterogeneous in their composition.
The question becomes still further involved because of
the many factors that are continually functioning in rock
decay. This process of the breaking down of rock masses
and their gradual evolution into soil is called weathering.
Rock weathering may be defined specifically as the changes
that rock masses undergo due to the physical and chemical
activities of atmospheric agents. Everything on the
earth’s surface is seeking a more stable condition, and
therefore, from a geological standpoint, is continually
changing. If a soil represents a more stable condition
than the exposed rock, the rock slowly evolves toward
the soil. Again, if a soil presents constituents not wholly
stable, that soil will change by an elimination or an
alteration of these components. The soil, then, is a
geologic unit. It is a transition product from one con-
dition to another.

This weathering, which brings about such changes and
is such a factor in the modifications of our topography, is

1 For a complete discussion of weathering, see Merrill, G. P.
Rocks, Rock Weathering, and Soils. New York. 1906.
18

14 SOILS: PROPERTIES AND MANAGEMENT

very superficial and affects the earth to but relatively
shallow depths However, from the fact that it provides
a medium for crup growth and at the same time is largely
instrumental in maintaining the fertility of this medium,
its agencies and processes become of great significance.

The forces of weathering, while very diverse not only
as to action but also as to product, permit of an outline
so clear that the true relationships at once become ap-
parent. This classification may be made under two
heads, mechanical and chemical, as follows :—

Forces of weathering

I. Mechanical changes, or disintegration
A. Erosion and denudation
Water, wind, ice
B. Temperature
Heat and cold, and frost
C. Plants and animals

II. Chemical changes, or decomposition
A. Oxidation and carbonation
B. Deoxidation
C. Hydration
D. Solution

10. Water. — The three great agencies of erosion and
denudation are water, wind, and ice. They are instru-
mental not only in the breaking up of rocks, but also in
transporting the resultant materials. Water is especially
of importance, as its denuding effects are very rapid when
viewed over geological periods. It is estimated that
the United States is being planed down at the rate of
one ich in seven hundred and sixty years. This is rapid
enough to dig the Panama Canal in seventy-three days.

SOIL-FORMING PROCESSES 15

The water, in order to be a successful cutting agent, must
be laden with sediment, so that its carrying power largely
determines its power of erosion. In other words, it must
be armed.

From the time when the raindrops beat down on a
surface until they have been gathered into rivulets and
streams and finally discharged into the ocean, they are
engaged in moving the detrital matter already produced.
The Mississippi River is working fast enough at the
present time to reduce the continent of North America
to sea level in four million years. The Appalachian
Mountains, born in Paleozoic times, have lost vastly
more material than now remains for us to view. Our
river and lake soils are due to the cutting and carrying
power of the streams. The deltas, and the marine soils
of the Atlantic and Gulf coasts, afford other examples
of such effects. The continual pounding and grinding
of waves are no mean factor in rock disintegration. The
rounding of the sands is a mute evidence of this great
force.

11. Wind.— The wind as a soil-forming agent has,
like water, two phases of action — erosive and transpor-
tive. Sweeping over the land in dry weather, it has the
power of picking up innumerable fine particles which
may abrade rocks very noticeably over a term of years.
The fluting of exposed rocks, especially in arid regions,
the undermining of cliffs, and the polishing of stones
to a smoothness equal to that of glass, are frequent occur-
rences. The roughening of wmdowpanes in houses near
the seashore during severe storms, and the illegibility
of old tombstones, are of common record. Great areas
of soil have been deposited by winds, especially in the
United States. The loess of the Mississippi Valley and

16 SOILS: PROPERTIES AND MANAGEMENT

the adobe of the Southwest owe their origin, at least
partially, to the carrying power of wind at a time when
aridity existed over all this area.

12. Ice. — When in large bodies, as in glaciers, ice
exerts a tremendous grinding power. Glacial ice, by its
mobility and motility, adapts itself to all topography,
and as it moves slowly forward it grinds and scours and
abrades even the hardest rocks. The great masses of
pebbles and rocks which are picked up and imbedded
by glaciers, especially in their lower surfaces, increase
their cutting power many fold. The effect of glaciers
is of particular interest because of the fact that all of
the northern part of the United States was covered at
one time with a great ice sheet, and our northern soils
are due either directly or indirectly to the advances and
retreats of this ice sheet. Formed im northern latitudes
due to a change in climatic conditions, the ice sheet
slowly covered many thousands of square miles of terri-
tory, and as the ice was usually several thousand feet
thick, hills, and often mountains, were overridden. Their
tremendous weight made the grinding action almost
irresistible. In the retreat, or melting back, of the ice,
a mantle of this ground-up and well-mixed material was
deposited as soil; while the streams flowing from its
front, or into glacial lakes, were furnished with heavy
sediments for distribution in other regions.

13. Heat and cold. — The changes in temperature of
the air, and the soils and rocks, tend vastly to augment
the effect of the denuding agents. Constant expansion
and contraction is productive of weakness and ultimate
physical breakdown. Heat is conducted slowly through
rocks, thus leading to differential heating and unequal
expansion or contraction. Rocks, as already noted, are

SOIL-FORMING PROCESSES 17

usually mineral aggregates, and these minerals vary
in their coefficients of expansion. With everv change
of temperature, differential stresses are set up which
ultimately must produce a considerable effect. When
the separate minerals expand they expand differently,
and when they contract they never again assume quite
their former relationships to one another. Thus crevices,
cracks, and rifts are created in rocks, especially those of
heterogeneous mineral composition. The expansion coef-
ficient of granite is .0000048 of an inch to a foot for every
degree Fahrenheit, while that of marble is about .0000056
of an inch. This seems to be very slight, but it must be
remembered that under natural conditions large surface
areas of rock are concerned. A sheet of granite 100 feet
Jong will expand one-half an inch with a change of 75°
Fahrenheit, which is not an uncommon variation of
temperature in arid regions or high altitudes. This
leads to chipping, flaking, and exfoliation. The rock
fragments may range from microscopic sizes to large
blocks, which are often split off with great violence.

14. Frost. — Great as is the action of a simple change
of temperature, its effects become many fold more ap-
parent when water is present. We then have the action
of frost. The cracks and crevices made by heat and cold
will in a humid region become filled with water. This
moisture, on freezing, exerts a very great force. The
expansive power of water passing from the liquid to the
solid state is equal to about 150 tons to a square foot,
which is equivalent to the weight of a column of rock
about a third of a mile in height. Moreover, most rocks
contain a certain amount of water in themselves. This
water is recognized in excavation operations as quarry
water. The passage of the quarry water to a solid state

18 SOILS: PROPERTIES AND MANAGEMENT

must result most disastrously to the physical condition
of the rock. This action of frost is by no means com-
plete when the rock is fined mechanically to a soil, but is
continued on the soil itself. Such further fining is of
the greatest importance in bettering the physical condi-
tion of the soil, and is usually designated as a wetting and
drying and freezing and thawing process. It is to such
forces, more than to any other action, that the farmer
owes the good tilth of his soil.

15. Plants and animals.— Plants and animals unite
their forces with those already mentioned to bring about
further physical change. Unlike the modifications due to
erosion, denudation, and temperature, these agencies affect
the soil to a greater extent than they affect the parent rock.
In other words, they begin their work after the minerals
have been reduced, at least partially, to the form of a
soil. Simple plants, as mosses and lichens, will develop
readily on rock ledges and coarse rock fragments. They
send their rootlets into the crevices and exert a prying
and loosening effect. They also catch dust, provide
humus, and gradually accumulate a soil in which higher
and still higher species of plants may grow. Their
chemical effects, especially regarding solution and oxida-
tion, aid in this disintegration. The distribution of
organic matter through the soil by the extension and
death of plant roots is of no mean importance in soil
fertility. Bacteria also may be a factor in rock decay,
not only through their action on the humus material
but also through a direct attack on the rocks themselves.
Their influence, however, is probably mostly chemical.

Animals also effect the fining of rock fragments and
souls, from their burrowing and mixing tendencies. Such
rodents as gophers and squirrels open up the soil, thus

SOIL-FORMING PROCESSES 19

providing better circulation of air and water. This
brings about a deeper and more effective action of the
other physical agencies of weathering. Earthworms
produce similar effects. Their holes provide channels
for ready drainage, and large quantities of soil are brought
to the surface yearly by them. Darwin estimates that
this amounts to as much as one or two inches in a
decade.

16. Oxidation and carbonation. — The physical and
chemical forces do not act alone, but, as a general thing,
combine in their effects. Thus one set of factors aids
and accelerates the other. Scarcely has the disintegration
of a rock begun, then, before its decomposition is also
apparent. Of the chemical forces oxidation is usually,
especially near the surface of the earth, the first to be
noticed. It is perceptibly manifested in rocks carrying
iron, and consists in such a change that the added oxygen
may be accommodated. Sulfides readily succumb and
become oxides, while these same oxides are prone to take
up oxygen to their fullest extent. This oxidation is dis-
closed by a discoloration of the rock, which is first streaked
and stained with iron oxide but at last changed to a
uniform ochre. The change may be exemplified by the
following reactions : —

2 FeS, + 7 Os + 4 HO = 2 FeO | 4 HoSO,4
4 FeO + O. = 2 Fe.O3 (red)

While not all the minerals contain iron, enough of them
do to impart a fatal weakness to most rocks. The ferrous
oxide (FeO), being soluble, is washed out and the rock is
ereviced and crumbled. A way is now open for more
energetic physical and chemical decay.

With the oxidizing action there is also the influence of

20) SOILS: PROPERTIES AND MANAGEMENT

carbon dioxide (CO;), which is universally a constituent
of air and is a product of the decaying vegetable matter
present in most soils. This means that the water cir-
culating among rock fragments, especially those of a soil,
is heavily charged with this compound. The carbona-
tion may be illustrated as follows: —

2 FeS, + 7 O. + 4 H.O +- 2 CO. = 2 FeCOs; + 4 H.SO, or
2 NaQH + CO. = NasCOxz + H.O

17. Deoxidation. — Deoxidation is an opposite re-
action to oxidation, being a loss of oxygen either to the
air or to some other compound. With hematite it might
take place as follows :—

2 Fe.Os _ Oz = 4 FeO

Under normal conditions, however, it is not a very im-
portant factor, since most rock fragments and soil are
fairly well aérated, at least too well aérated to allow this
reverse process to occur. In poorly drained soil or in
soil very rich in humus arid carrying organic acids it
may occur, and is usually manifested by the development
of blue and gray colors, indicating that a reduction has
taken place. The bleaching of sands, sandstones, and
clays may be due partially to this, and also to a removal
of the ferriferous salts in solution. Some subsoils dis-
play this phenomenon. The average farmer, however,
need not concern himself with the juries that may re-
sult from deoxidation.

18. Hydration. — Hydration usually accompanies oxi-
dation, but when occurring at great depths it may be
practically the only change the minerals have undergone.
Minerals, especially feldspars, become clouded and lose
their luster on this assumption of chemically combined

SOIL-FORMING PROCESSES 21
water. There is also a considerable increase in bulk, this
being often as much as 88 per cent during the transition
of a rock to a soil. Hydrated minerals, while apparently
sound, quickly succumb when exposed to forces of weather-
ing which are more superficial in their effects. Car-
bonation and oxidation usually take place as correla-
tive actions with hydration. A simple example of
hydration is shown in the change of hematite to limo-
nite, which occurs in practically every case when iron
is allowed to oxidize from pyrite or a simpler oxide to
the higher forms : —

2 Fe.O; (red) + 3 H.O = 2 FeoO; . 3 H20 (yellow)

19. Solution. — As it is now quite evident that weather-
ing, especially the chemical manifestations, is largely a
simplification of compounds, and that water is almost
universally present, some solution must occur. These
simple materials are particularly prone to enter solution
because of the presence of carbon dioxide, which, by
acidifying the soil water, intensifies its solvent action to
a considerable extent and consequently increases its power
as a weathering agent. The atmosphere contains amounts
of this gas ranging from 3.87 to 4.48 parts in 10,000,
while considerable amounts are brought down on the
rocks and the soil in snow and rain. The carbon dioxide
evolved directly into the soil water from decaying organic
matter also aids in keeping the soil charged with this gas.
This means, then, that solution is largely a process of
‘carbonation, especially after the soluble constituents have
been thrown out into the soil solution. It is evident
that oxidation, carbonation, hydration, and solution act
in unison to bring about the chemical decay of the rock
and the soil. This combined action may be represented

22 SOILS: PROPERTIES AND MANAGEMENT

by showing the various stages that orthoclase may undergo
in producing a residual clay :—

KAISi;30, + HOH = HAISi;03 + KOH
2 KOH — CO. — kk.COs + H.O
HAISiz0g — 2 SiO. = HAISiO, (kaolinite)

The silica in this case may become quartz or colloidal
silica, or, what is more probable, may unite with certain
elements to produce complex hydrated silicates.

20. A general statement of weathering. — The question
of rock weathering is complicated because no one action
can be considered alone. All forces are acting together,
tending to produce a great complex of reaction and inter-
action. No amount of explanation or speculation can
ever fully clarify the question as to the formation of a
soil from a parent rock. Nevertheless, knowing in general
the separate forces and reactions produced, we may formu-
late the phenomenon in a general and superficial way.
The change that a rock undergoes in the formation of a
residual clay is first a physical breaking-down accom-
panied by chemical changes, which consist in the hydra-
tion of the feldspars, the oxidation of the iron, and the
solution and carbonation of the soluble bases.

21. Factors affecting weathering. — It is readily to be
seen that the activity of the various agencies of weather-
ing will be modified by certain factors which determine
not only the kind of rock decay but also its rate. Of
these, climate is probably of the greatest importance.
The difference in the weathering in an arid region as
compared to that in a humid region will illustrate this
point. Under arid conditions the physical forces will
dominate and the resulting soil will be coarse. Freezing
and thawing, heat and cold, the action of the wind, and

SOIL-FORMING PROCESSES 23

the effect of animals, will be almost the sole agents.
In humid regions, however, the forces are more varied
and practically the full quota will be at work. Chemical
decay will accompany the disintegration, and the resultant
product will be finer and more minutely divided. The
separate minerals will show also the change of color and
loss of luster due to the decomposition of some of their
essential elements. The same rocks, then, will behave
differently under different climatic conditions. A granite,
for instance, is a very insoluble rock as compared with a
limestone, and in a humid region where chemical agencies
are dominant 1t would be markedly more resistant. If,
however, these two rocks are placed under arid conditions
where the physical forces are potent, particularly as re-
gards change of temperature, the comparison is different.
The limestone, bemg homogeneous, is not affected by
atmospheric changes; but the stresses set up in granite
due to differential contraction and expansion must ulti-
mately reduce it to fragments.

As weathering is confined to the very surface of the
earth, the exposure or position of a rock will determine
the kind and the rate of decay. If the rock is very deep
below the surface, only hydration may occur; while if
it exists as an exposed ledge, the full force of the weather-
ing agents will be sustained. If the débris of the decayed
rocks is not removed, this serves as a blanket for the
protection of the rocks below. The transportive powers
of weathering are important in maintaining a clean sur-
face for action.

The texture of the rock is also a factor. Other things
being equal, a coarsely crystalline rock will disintegrate
and decompose more rapidly than one of finer grain.
The coarser the grain, the larger the amount of interstitial

24 SOILS: PROPERTIES AND MANAGEMENT

space and the greater the encouragement to physical
agencies. As physical changes open the way for chemical
decay, coarse texture will ultimately encourage decomposi-
tion as well as disintegration.

Lastly, the disruptive forces of the rock will be in-
fluenced by the chemical composition of the minerals
and the mineral composition of the rock. A rock made
up of minerals that offer but little resistance to decay
will naturally succumb readily and quickly to a soil.
Rocks that very largely bear minerals which are re-
fractory in their nature, however, may never decompose
far enough or rapidly enough to give a soil of any agri-
cultural significance. The next step, then, m the study
of soil formation is a consideration of the relative resistance
of the minerals and the rocks.

92. The law of mineral and rock decay. — Considerable
work has been done on the comparative solubility of
minerals both in pure and carbonated water, but in most
cases it has proved somewhat inconclusive. Neverthe-
less we are able, by consulting the work of Miiller,! Clark,”
Daubree,® and others, to arrange some of the commoner
minerals in the order of their solubility, the most resistant
minerals heading the list : —

1. Quartz 6. Epidote 11. Apatite
2. Muscovite 7. Serpentine 12. Olivine
3. Biolite 8. Tale 13. Calcite

4, Orthoclase 9. Hornblende
5. Plagioclase 10, Augite

1 Miller, R. Solution of Rocks in Carbonated Water. Jahrb.
k-k Geol. Reichsanstalt, Vol. X XVII, p. 25. 1877.

*Clark, F.W. Data of Geochemistry. U.S. Geol. Survey,
Bul. 330, p. 401. 1908.

8’ Daubree, A. Solubility of Orthoclase. Htudes de Géol.
Expérimentale, pp. 27 and 252. Paris, 1847.

SOIL-FORMING PROCESSES 25

The next step is to deduct some general law which can
be shown to govern the resistance of these minerals.
Such a statement would aid considerably in the making of
general deductions regarding weathering. The siliceous
content of some of these minerals, taken in the order as
above, throws considerable light on this phase: —

Per cent of SiO; Per cent of SiOz2
Quartz . . . . . 100 UHormblende. . .. 45
Orthoclase . . . . 65 Olivine ..... 41
Plagioclase . . . . 55 Calcite . . . . . trace

Another case might be cited in a comparison of the
chemical composition of anorthite, hornblende, and
olivine : —

Anorthite . CaAlSieOs
Hornblende . Ca(MgFe)2(Si03) with
Olivine . . (MgFe).Si0O,

It is to be noted that immediately as the resistance of a
mineral declines, its content of silica decreases and the
percentage of the basic constituents imecreases. Silica
and aluminium, then, mark resistance to decay; while
calcium, magnesium, sodium, potassium, and iron func-
tion in increasing susceptibility to decay. The law of
mineral resistance may be formulated as: “The more
basic a rock becomes, the more rapid is its decomposi-
tion; and the more acid, the less marked is its decay.” *

This general law certainly should apply to rocks that
are made up of the minerals listed above. One example
will show this clearly. The igneous rocks, as already
stated, may be divided into two groups, acid and basic.

NaeAle (SiO3) 4 and
(MgFe) (AlFe)2Si05

1Buckman, H. O. The Formation of Residual Clay. Trans.
Amer. Ceramic Soc., Vol. XIII, p. 362. February, 1911.

26 SOILS: PROPERTIES AND MANAGEMENT

This acidity and basicity 1s determined by the presence
of silica and the alkalies, respectively, as carried by
certain essential minerals. Suppose we name some
representative igneous rocks in the order of their acidity,
and list some of the minerals carried by them :—

1. Granite . . Quartz, orthoclase, and mica
2. Diabase . . Plagioclase, mica, hornblende, or augite
3. Peridotite . Principally olivine

It is to be seen that the minerals contained by granite
are more resistant than those carried by either the diabase
or peridotite, while the olivine of the last group is near
the foot of the list when the minerals are arranged in the
order of their resistance.

The following data! bear out the argument presented
above as to the relative resistance of rocks : —

PrRoportionaL AMOUNTS OF Frese Rocks SotusuEe in Bor
inc Hyprocuioric Acip AND SopiumM CARBONATE SOLUTIONS

PHONOLITE DisBASE GRANITE
S10, . 2. . 6 we ee 21.64 10.85 9.49
AlO;Fe2O03 . 8 8 © we ee 12.60 15.65 $.36
CaO. . . 2. 1 ew ee 1.07 3.09 .60
MgO. ...... 2. . 40 2.20 Jl
K.0 . 2. 1 ew ee ee 28 1.21 1.68
NasQ . ... 2. «ee 5.45 .00 1.23

4.1.44 33.00 22.07

It is evident, then, that the law of mineral resistance
applies to rocks as well as to the separate minerals, al-
though its application thereto is much more complex
and difficult to interpret.

1 Merrill, G. P. Roeks, Rock Weathering, and Soils, p. 366,
New York. 1906.

SOIL-FORMING PROCESSES 27

23. Special cases of weathering. —'The weathering of
granite and limestone under different climatic conditions
has already been compared. The changes that take
place in these rocks as they are evolved to residual clays
may now be considered. The following analyses serve
to show on what elements the losses are likely to be most
serious during the process :—

Freso GRANITE AND ITs ResuurTant Cray }

Rock Chay PERCENTAGE
Si0. . . 1. ee we 60.69 45.31 52.45
AlO3;. 2. 2. 6 6 2 eee 16.89 26.55 00.00
FeOz;. . . 2. 2. 2. 2 a 9.06 12.18 14.35
CaO... . . ee ee 4.44 00.00 100.00
MgO. ........ 1.06 40 74.70
K20 . 2. 1. ee ew es 4.25 1.10 $3.52
Nad. . . ..... 2.82 22 95.03
PoOs. .- 6. 6. 1 ew eee 25 AZ 00.00
Ignition . . . ...., .62 13.75 Gain

VIRGINIA LimesSTONE AND Its Resipuat Ciay?

Rock CLAY PERCENTAGE
Si0, . . 2. ee ew ee 7.41 57.57 27.30
Al,Os. . . 2. 2. . ew ee 1.91 20.44. 00.00
FeoO3. . 2. 1 ee eel .98 7.93 24.89
CaO... . ee eee 28.29 Jl 99.83
MgO... .. ...-. 18.17 1.21 99.38
K.0 . 1. 1 kw ee es 1.08 4.91 57.49
NaoO. . . . 2. 0. eel .09 23 76.04
PoOs . 2. 2 1 ee ee 03 10 68.78
CO. .- . 1. we ew eee 41.57 238 99.15

HO... eh eee 57 6.69 Gain

1 Merrill, G. P. Bul. Geol. Soc. Amer., Vol. 8, p. 160. 1879.
2Diller, J.S. U.S. Geol. Survey, Bul. 150, p. 385. 1898.

28 SOILS: PROPERTIES AND MANAGEMENT

Soils have resulted in both cases from the decay of
these rocks. In the case of the granite the resulting soil
was a deep red clay, with quartz grains present. ‘The
soil from the limestone was a plastic clay, high in silica
and aluminium. Leaching has probably gone on to a
very great extent in both soils. It is noticeable also
that the basic constituents have suffered the greatest
losses, especially calcium, magnesium, sodium, and
potassium. The carbonate has almost wholly disap-
peared from the limestone clay, showing that a limestone
soil may not necessarily be rich in lime. As a matter of
fact, the chances are that if it is residual it will be lacking
in that compound. When shown diagrammatically (See
Figs. 1 and 2), the changes that the parent rocks have
undergone chemically in forming a clay will become
apparent.

pt At} tt pt
Be NZAnee
Brie PHN |

Fig. 1.— Diagrammatic representation of the chemical composition o
fresh granite and its residual clay. See analyses above.

SOIL-FORMING PROCESSES 29

As shown by the diagrams, the soil from the granite does
not differ greatly from the original rock, except in loss
of bases, assumption of water, and increase of organic

a
Lit ALT | TAT

CHEER ECE
\
a Oe

@lresh rock | y
bresitata/ clay area

Fig. 2.— Diagram showing the chemical composition of Virginia lime-
stone and its residual clay. See analyses above.

matter. The residual clay from the limestone presents
greater differences, due to the almost entire disappear-
ance of calcium carbonate. The diagrams for the two
clays resemble each other fairly closely in spite of their
widely differing sources. Because weathering causes
the persistence and accumulation of silica, aluminium,
and iron, and a loss of the basic materials, all soils as
they weather tend to approach a similar composition.
Yet, owing to a difference in the adjustment of the forces
at work and in the time element, no two soils will ever
be exactly alike. Soils will differ, then, from the original
rock and from one another according to the intensity

30 SOILS: PROPERTIES AND MANAGEMENT

and character of the weathering and the constitution of
the parent minerals.

24. Practical relationships of weathering. — Weather-
ing processes result in a general simplification of com-
pounds. Their action first affects the rock, with the
result that a soil is produced; but they still remain ac-
tive in the soil after it isin a condition to support plants.
The physical agencies especially tend to loosen and fine
the soil, contributing largely to its tilth. The farmer
encourages such influences by plowing his land and by
other operations. Were it not for such weathering
action, the soil would become physically unable to afford
foothold for plants. The continued chemical changes
resulting in solution and carbonation provide a soil water
rich in plant-food nutriment. Weathering, then, by a
slow process over geologic periods has provided us with
soil, and by the same slow process is maintaining the
fertility of this creation. The encouragement and control
of such an agency is of no small importance in agricultural
practice.

CHAPTER II

THE GEOLOGICAL CLASSIFICATION OF SOILS

WEATHERING must be considered as affecting soils both
in situ and in motion. This gives two general classes of
materials — those that have not been shifted far from
their place of origin, and those in the formation of which
the transporting agencies have been instrumental. These
two general groups, designated as sedentary and trans-
ported,! are subject to considerable subdivision, as
follows :—

Residual
Sedentary Cumulose

Gravity — Colluvial

Alluvial
Water | Marine

Lacustrine
Ice — Glacial
Wind — olian

Transported

25. Residual soils. —'This group of soils covers wide
areas of our arable regions and comes from many kinds of
rocks. Residual soils are old soils, the oldest with which
we have to deal in agricultural operations. Since a

1See Trowbridge, A. C. A Classification of Common Sedi-
ments. Jour. of Geol., Vol. 22, No. 4, pp. 420-436. 1911.
31

32 SOILS: PROPERTIES AND MANAGEMENT

residual soil is formed in sztu, the rocks that underlie it,
if sound, show the character and composition of the rocks
from which the soil was actually a product. In such
soils the changes that a rock undergoes in forming a
residual clay are to be studied to the best advantage.
An examination of the various grades of material that are
found overlying the country rock (Fig. 3) in an area where

"at
tak it ee

*
4 at S
’ ae %,
stele. Pas ke
? . * tae
zi

.
Bas
a
wa,
Rta

Fro. 38. — The gradual transition of country rock into residual soil by
weathering in situ.

this residual mantle exists, reveals more or less accurately
the gradations from rock to soil. Residual soils, besides
being old soils, are usually nonstratified and present a
heterogeneous mass of material. Since they have been
subjected to leaching over vast periods, a very large
amount of the soluble materials have been washed out,
tending to leave high percentages of the persistent ma-
terials, such as silica, iron, and aluminium. An analysis
of an Arkansas limestone, its residual clay and the cal-
culated percentage loss of the various constituents pres-
ent in the fresh rock, illustrates this point :—

GEOLOGICAL CLASSIFICATION OF SOILS 33

ARKANSAS LIMESTONE AND ITS Ruesipvat Cray}

Freso Rocx Cuay PERCENTAGE
ost
Side . - 2 se ee ee 4.13 33.69 .00
AlO3s. 2. - s+ 6 se 8 ee 4.19 30.30 11.35
FeOs. - 6 + © 8 «© « « 2.35 1.99 89.56
MnO... . + ee ee 4.33 14.98 57.59
CaO... ee ee 44..79 3.91 98.93
MgO... + + + + «+ : .o0 26 89.38
Ko0O . 1 1 ee es R33) .96 66.36
NasQ. 2. 6 8 ee ees 16 61 538.26
CO... 6 6 © ee ee 34.10 -00 100.00

The vast age of such soils tends to bring about great
oxidation, so that most of the iron has changed to hematite
and limonite. Since almost all soils contain considerable
iron, the prevailing colors of residual soils are reds and
yellows, depending on the degree of oxidation and hydra-
tion. Grays and browns may exist, however, where iron
has been lacking or oxidation has been feeble. In texture
such soils usually present very fine conditions. Having
been attacked by both the physical and the chemical
agencies, the particles have been reduced to a very fine
state of division. Over residual areas the heavier soils
predominate, as silts, silt loams, clays, and clay loams.
Very often sand or chert may be present, having been a
constituent of the original rock mass.

An examination of the particles of a residual soil usually
shows them to be in an advanced stage of decay. The
feldspars have lost their luster and have become opaque.
The iron bas become oxidized, and the soluble bases have

1 Penrose, R. A. F. Ann. Rept. Geol. Survey Arkansas,
Vol. I, p. 179. 1890.

34 SOILS: PROPERTIES AND MANAGEMENT

either disappeared or changed their combinations to more
stable forms. The tendency of all soils is toward a con-
dition of equilibrium, and consequently they approach,
but never reach, a common composition. This does not
apply to their productivity, because many other factors
besides chemical composition go to determine cropping
power. Residual limestone soils, therefore, become poorer
and poorer in lime as their age increases. The organic
matter of residual soils largely depends, in amount and
condition, on climatic factors. If rainfall and tempera-
ture, for instance, are favorable for the rapid and con-
tinued development of a natural vegetation, the soil
will be rich in humus, so rich at times as to mask to a
certain extent the red color so characteristic of such soils.
If plants do not grow well on this soil, however, it will be
low in organic matter and probably in poor physical con-
dition, so vital is humus to a proper foothold for plant
life. Two residual soils coming from the same kind of
rocks may vary rather widely in their general character-
istics, especially as to crop productivity.

26. Distribution of residual soils. — Residual soils are of
wide distribution in the United States,! particularly in the
eastern and central parts. A glance at the soil map of this
country (See Fig. 4) shows four great provinces— the Pied-
mont Plateau, the Appalachian Mountains and Plateaus,
the Limestone Valleys and Uplands, and the Great Plains
Region. The age of these soils varies in the order named,
showing that while they are very old as compared with
other soils yet to be discussed, there may be vast periods
of geologic time between their beginnings. As a matter

1 For a full discussion of the origin and characteristics of the
soils of the United States, see Marbot, C. F., and others. U.S.
D. A., Bur. Soils, Bul. 96. 1913.

GHOLOGICAL CLASSIFICATION OF SOILS 30

of fact, there is probably a greater difference in age be-
tween the soils of the Piedmont Plateau and those of
the Great Plains Region than has elapsed since the latter
were formed. ‘The soils of the Piedmont Plateau have
been formed mostly from gneiss and schist. In fact,
the Piedmont Plateau is the remnant of the old continent,
Appalachia, which was in existence in early Cambrian
times. The rocks of the Appalachian Mountains and
Plateaus are limestone, sandstone, and shales. The Great
Plains Region presents limestone, sandstone, and shale
of the Cretaceous, Permian, and Carboniferous ages, be-
sides much unconsolidated material. The soils of these
provinces, extending as they do over great areas, vary
within wide limits due to rock formation, climatic con-
ditions, and age; yet certain common characteristics,
as already pointed out, are exhibited by all.

27. Cumulose soils. — This type of soil is of a very
different character from the one just under discussion,
being made up largely of organic matter with the mineral
constituents of secondary importance. At relatively
recent periods shallow lakes, ponds, and basins were
formed, partly by stream action, partly by marsh con-
ditions along sea or lake coasts, or, what is commoner in
the northern part of the United States, by glaciation.
Any basin that contains water throughout the year serves
as a place for the formation of cumulose soil. The highly
favorable moisture relations along the banks and shores
of such standing water encourage the growth of many
plants such as alge, moss, reeds, flags, grass, and the like.
These plants thrive, die, and fall down only to be covered
by the water in which they were growing. The water
shuts out the air to a large extent, prohibits rapid oxida-
tion, and thus acts as a preservative for the rapidly collect-

36 SOILS: PROPERTIES AND MANAGEMENT

ing organic matter. Year after year this process goes
on, and year after vear the bed of cumulose material
becomes deeper and deeper. Large shrubs, and even
forests, often grow on such land. Time and the lack of
water are the factors that may limit the depth of such
beds. Accumulations of this nature are found dotted
over the entire country. Their size may vary from a
few acres to several thousand. Along streams the old
abandoned beds offer a common opportunity for the
beginning of such accumulations. Along large bodies
of water, marshes, either salt or fresh, may allow the
process to go on. Shallow basins scraped and gouged
out by advancing glaciers are frequently occupied by
such material. In the last-named case the beds are
more or less independent of topography, and may be
found on hillsides, or even on hilltops, as well as im the
lower lands.

Cumulose materials may be grouped under two heads,
peat and muck. The only difference is in their stage of
decay. In peat the stem and leaf structure of the original
plants can still be detected, and identification is quite
possible. In muck, however, the putrefaction and decay
have gone so far that the plant tissue has lost its
identity as such and is merged into that complicated
and indefinite material called humus. The composition
of peat and muck may be much altered by the wash-
ing-in of mineral matter from above. In some cases
the beds may be from 80 to 85 per cent organic, while
in other cases, due to this foreign material, the percent-
age may drop to as low as 15, giving a black or swamp
marsh mud.

The following analyses illustrate the composition of
representative cumulose soils ; —

GEOLOGICAL CLASSIFICATION OF SOILS 37

1 | 2 3
jp
Mineral matter . . . . . 31.60 24.79 80.40
Organic matter . . . . .| 68.40 67.63 15.77
Nitrogen . . tee 2.63 2.03 —
P.O;. - . - + ee ee 20 19 15
K.O ..... .. 2... 17 15 65
Moisture ...... . — 7.58 3.83

1. Muck — Pickel, G. M. Muck: Composition and Utili-
gation. Fla. Exp. Sta., Bul. 18. 1891.

2. Muck — Rept. Can. Exp. Farms, 1910. Rept. of chem-
ist, p. 160.

3. Marsh mud — Rept. Can. Exp. Farms, 1910. Rept. of
chemist, p. 137.

Muck soils, while usually not of large extent, become of
extreme value when drained, especially if they are near
a good market. They are of particular value in trucking
operations, being adapted to such crops as onions, celery,
lettuce, and the like. Usually they must not only be
provided with drainage, but also be treated with fertili-
gers carrying phosphorus and, especially, potash. It is
also a good practice to start vigorous decay by the appli-
cation of barnyard manure, as the nitrogen carried by
muck soils is usually not very readily available to plants.
In many cases muck and peat may be underlaid at vary-
ing depths by marl, which is a soft, impure calcium
carbonate. Before and at the beginning of the organic
accumulation these basins were inhabited by Mollusca,
which at death deposited their shells on the bed of the
inclosure. These shells are now found in a more or less
fragmentary condition, usually mixed with sand and
clay and covered to a varying depth with peat or muck.
Such material, because of its richness in lime, is valuable

88 SOILS: PROPERTIES AND MANAGEMENT

as a soil amendment, and often where it is found pure
enough in quality and in sufficiently large quantities it
is handled commercially. When it contains large amounts
of phosphorus, as it does in some cases, it may be used
as a fertilizer. The following analyses! show the general
character of this soil: —

i 2
SiO, . . . . ee eee 25.28 5.65
Al.O3 . Fe,03 oe . . . . : 3.02 3.30
CaO .......~. . 37.52 48.51
MgO ......... . 12 1.96
KeO .. ww we eee 22 23
P05 2. 2. 2 ee ew ew ee 40 Trace
CO, . 2. 6. ee ee es 29.02 39.80

Ignition . . . . . ee ee | 4.17 25

se theese re

28. Colluvial soils. — This class of soil is not of great
importance, first because of its small area and its inac-
eessibility, and secondly because it is usually a coarse,
loose soil, rather unfavorable for plant growth. It is
formed, as its name indicates, in regions of precipitous
topography, and is made up of fragments of rocks de-
tached from the heights above and carried down the
slopes by gravity. Talus slopes, cliff débris, and other
heterogeneous rock detritus are examples of colluvial
soll. Avalanches are made up largely of such material.
As the physical forces of weathering are most active in
the formation of these soils, the amount of solution and
oxidation is small. The upper part of the accumulation

» Kerr, W. C. Geology of North Carolina, Vol. I, p. 195.
1875.

GEOLOGICAL CLASSIFICATION OF SOILS 39

exhibits this isolated physical action to the greatest extent,
the particles being angular, coarse, and comparatively
fresh; farther down the slope the material may merge
by degrees into ordimary soil. Such soils are usually
shallow and stony, and approach the original rock in
color unless large amounts of organic matter have ac-
cumulated (Fig. 5).

Fig. 5. — Diagram showing the formation of a colluvial soil. (a), bed
rock; (b), dismantled cliff; (d), coarse unproductive talus; (p), soil
capable of bearing plants.

29. Alluvial soils. —In considering the importance of
water as a weathering agent, it was found that it had
both cutting and transporting powers. The alluvial

40 SOILS: PROPERTIES AND MANAGEMENT

soil is a direct result of both these activities. The carry-
ing power of water varies directly as the sixth power of
its velocity ; so that a doubling of the velocity increases
the transportive ability sixty-four times. It 1s estimated !
that water flowing at the rate of three inches a second
will carry only fine clay, but if this rate is mcreased to
twenty-four inches a second, pebbles the size of an egg
will be moved along the stream bed. Any checking of
the velocity of a stream will cause it to deposit the ma-
terial carried in suspension, the larger particles first and
the finest when the current becomes very sluggish. This
brings about one of the important characteristics of an
alluvial soil, its stratification. Wherever material is
being laid down by water this phenomenon is exhibited,
due to the rapid changes in velocity. As a stream ap-
proaches nearer and nearer to its outlet, its bed becomes
less and less inclined and the current more and more
sluggish. This tends toward an aggrading of the stream
bottom from the deposited material. Such a condition
naturally mcreases the probability of overflow in high
water. Overflow at a time when the stream is carrying
its maximum of sediment causes the deposition of a thin
layer of soil over the areas covered by the water. This
soil is stratified according to the conditions under which
it was laid down, the finer particles usually being carried
farther and often deposited in slack water or lagoons.
Also, a stream on a gently inclined bed may begin to
swing from side to side in long, gentle curves, due to the
deposition of alluvial material on the inside of the curve
and the cutting by the current on the opposite bank.
This results in oxbows, lagoons, and similar inclosures,

1Geikie, A. Text Book of Geology, p. 380. New York. 1893.

GHOLOGICAL CLASSIFICATION OF SOILS 41

ideal for the deposition of alluvial matter. Deltas are
another good example of alluvial deposits, whether oc-
curring in ocean, gulf, or lake. Due to a change in grade,
a stream may cut down through its already well-formed
alluvial deposit, leaving terraces on one or both sides.
Often two, or even three, terraces may be detected along a
valley, marking a time when the stream bed was at
these elevations. On the lower slopes of hills border-
ing valleys, the colluvial deposits may touch or even
mingle with the alluvial, and furnish a stream with some
of its detritus.

Alluvial soils, then, are found as narrow ribbons along
streams. They are always young soils, and are still in
process of formation. Smce in most cases they are de-
posited by slowly moving water, the texture of such soils
is fine, the soils being mostly clays, silts, and fine sandy
loams. Found im low lands, alluvial soils need drainage
to a large extent. Because of the favorable moisture con-
ditions these soils usually have a very large amount of
organic material, as vegetation grows readily under such
conditions. Considerable humus is also washed into
alluvial materials at the time of their deposition. The
soil is usually deep, and, because of the high organic con-
tent, universally of good physical condition, although
very heavy stiff clays may be found in certain cases.
The character of the soils and the rocks from which the
detritus has been obtained exerts considerable influence
on its character. For example, a red soil will often
give rise to a reddish alluvial soil, while a soil or a rock
poor in lime will certainly not be parent to a soil very
much richer in that constituent.

30. Distribution of alluvial soils. — The distribution
of alluvial soils in the United States is not wide, although

42 SOILS: PROPERTIES AND MANAGEMENT

these soils exist along almost every stream east of the
Great Plains Region. Their best and widest develop-
ment is found, as the map indicates (See Fig. 4) along
the lower Mississippi river, where they may often show
a lateral extension of one hundred miles. Extensions of
this band are noted along the Missouri, Ohio, and Upper
Mississippi rivers. All streams flowing east exhibit
areas of such soils, these areas varying with the size and
velocity of the stream.

The soils of the alluvial province may be divided under
two heads because of topographic differences — (1) the
first bottoms, or present flood plains; and (2) the terraces,
or old flood plains. These soils differ in their elevation,
drainage, and age, but their general characteristics are
similar; the surface features in both cases vary from a flat
to a gently rolling topography (Fig. 6). Erosion, especially
in the terraces, may have obliterated some of the out-

ate
Saemiasesnmeeiabieanl cs “the ‘S
aN SS ZS
eee 3g ge = SS
EN en. as, <= ss ee ,
fs SS
a /~—™

Fig. 6.-— Cross-section of typical alluvial soils. (a), bed rock;
(r), stream; (b), present flood plain, a recent alluvial soil; (c), flood
plain terrace; (d), very old stream terrace, an old alluvial soil.

standing features. Alluvial soils, being very rich, are
particularly adapted to trucking crops, although in most
cases they are utilized for more extensive farming. When
well drained and protected from overflow, they are the
richest and most valuable of soils.

GEOLOGICAL CLASSIFICATION OF SOILS 43

31. Marine soils.— The sediments which are con-
tinually being carried away by rivers are eventually
deposited in the sea, the coarser fragments near the
shore, the finer particles at considerable distances. This
layer of material, varying in thickness, consists of stratified
gravels, sands, and clays, and is of a rather recent age
compared with the residual soils. It has not become
consolidated as yet, because of insufficient pressure and
time. When such material becomes raised above the
sea, due to a change in land elevation, it is classified as a
marine soil. It has been worn and triturated by a num-
ber of agencies. First, the forces necessary to throw it
into stream suspension were active, and next it was
swept into the ocean to be deposited and stratified,
possibly after being pounded and eroded by the waves
for years. At last came the emergence above the sea
and the action of the forces of weathering in situ. The
latter effects are not of great moment, since with our
most important marine soils they have been at work
for but a comparatively short time, speaking geologically.

32. Characteristics of marine soils. — Marine soils,
while much younger than residual soils, are usually more
worn and ordinarily show a less amount of the important
food elements. This is because of their almost con-
tinuous contact with water from the time when they are
swept into the streams until they rise above the sea level
as a soil. They are generally characterized as sandy
soils, because the forces to which they have been sub-
jected have worn out and dissolved most of the minerals
except quartz. This gives them a coarse texture and
fits them particularly for trucking soils. Sands, sandy
loams, and loams predominate usually in such soil prov-
inces, although clays and silts may occasionally be

t4 SOILS: PROPERTIES AND MANAGEMENT

found. These soils are usually low in humus, and con-
sequently must be handled with reference to the possi-
bilities of increasing their organic content. Lack of
humus makes the predominating color of the soil light,
ranging from light gray to brown and dark brown. The
character of these soils is governed to some extent by the
origin of the sediments; different rocks, particularly if
weathered under different climatic conditions, may give
rise to widely different marine soils. The climatic con-
ditions to which marine materials are subjected after
being raised above the sea may also be a considerable
diversifying agency.

33. Distribution of marine soils. — Marine soils are
found very widely distributed in the eastern United States,
and make up one of our most important soil provinces.
Beginning at Long Island at the north (See Fig. 4),
they extend southward along the coast in a band ranging
from one hundred to two hundred miles in width. The
western edge of the Atlantic coastal plain is marked by
the great “ Fall’”’ Line, or the edge of the old continent
Appalachia. It is from this area that most of the sedi-
ments of the Atlantic marine soils were derived. Proceed-
ing southward, we find that Florida is practically all of
marine origin, together with a great area of the Gulf
coast extending westward to central Texas and having
an average width of two hundred fifty miles. This
gulf marine soil is considerably younger than that of
the Atlantic coast. It is cut to two parts by the allu-
vial soils of the Mississippi, and is covered by a narrow
band of alluvial soil on the eastern bank of that stream.
The sediments of the Gulf coastal plain were derived
from the erosion and denudation of the old lands to the
northward.

GEOLOGICAL CLASSIFICATION OF SOILS 45

The soils of the Atlantic and Gulf coastal provinces,
formed as vast outwash plains, are very diversified, due
to source of material, age, and climatic conditions. They
comprise a sufficient range in texture and climate to
support a highly varied agriculture. There are great
tracts of general farming land, besides wide areas of
special-purpose soils adapted to highly specialized in-
dustries. The latter soils require refined and intensive
methods of cultivation. Predominantly sandy, these
soils are easy to cultivate, and they are well drained
except in the lower coastal plain belt. Good aération is
usually found because of their open structural condition.
Severe leaching occurs in times of heavy rainfall, for the
same reason. When sufficiently supplied with organic
matter, carefully fertilized, and cultivated properly,
these soils support a great variety of crops, such as cotton,
corn, oats, forage crops, and peanuts, besides vegetables
and fruits of many varieties.

CHAPTER IV

GEOLOGICAL CLASSIFICATION OF SOILS
(CON TINUED)

Ice in the form of glaciers has been, as already stated,
a very great factor in soil formation, especially in the
north temperate zones of North America, Europe, and
Asia. Not only was the old mantle of material swept
from the land by the advance of the ice, but a new soil
was laid down as drift material. This drift was some-
times merely ground-up rock, sometimes rock flour
mixed with the original residual soil, and sometimes
glacial material wholly reworked and considerably strati-
fied by water. Besides this, the streams of water that
issued from under the glaciers were instrumental in
many cases in distributing sediments a considerable
number of miles southward of the ice front. Glacial
lakes, also, when in existence for sufficiently long periods,
furnished basins for the distribution and deposition of
voaterials derived from the erosive and grinding power
of the ice. The ice also furnished a large amount of
very fine detritus, which was susceptible to wind move-
ment. This material, reworked and deposited as bars
in stream beds, was carried many miles by the prevailing
westerly winds during a period of aridity following the
glacial epoch. It now exists over wide areas, especially
in the Middle West of the United States and in northern

China, in which places it reaches its best development.
46

GEOLOGICAL CLASSIFICATION OF SOILS 47

It is the important soil of these regions. Glaciation was
instrumental, then, either directly or indirectly, in the
formation of three general classes of materials — glacial
drift soils, glacial lake soils, and a certain class of Holian
materials designated as loess and adobe.

34. The ice sheet.'— If in any region, but more likely
one of some elevation, the temperature and the snowfall
stand in such relationship that the heat of summer does
not offset the winter accumulation of snow, great snow
fields form. As this condition persists year after year,
and the snow becomes deeper and more widely spread,
the temperature is reduced to such an extent as to in-
crease the proportion of the precipitation which persists
through the summer’s heat. The pressure of the over-
lying snow, and the water from the melting surface, bring
about a change of the snow into ice. Often a recrystalli-
zation appears to occur without a melting and refreezing.
As the depth of ice mcreases, the phenomenon of move-
ment is inaugurated as the thickness of the ice at the
center develops strong lateral pressure. Ice, when under
great stress, exhibits a plasticity which it does not or-
dinarily possess. As it moves slowly forward under
this tremendous pressure, and with a thickness of develop-
ment almost incredible, it conforms itself to every un-
evenness of the surface it may be invading. It rises over
hills, or shapes itself to valleys and even small depressions,
with surprising ease. The rate of advance or retreat of
a glacier is determined by the rate at which its edges
are wasting or melting away. If the melting is slow, the
ice front advances; if it just balances the advance, the

1For a complete discussion of glaciers and glaciation, see
Salisbury, R. D. The Glacial Geology of New Jersey. Geol.
Survey of New Jersey, Vol. 5. 1902.

48 SOILS: PROPERTIES AND MAN.LGEMENT

ice front is at a standstill; but if the wasting is rapid,
and the advance of the glacier is not fast enough to re-
place this waste, the ice is said to be retreating. A great
ice sheet may exhibit all three of these conditions many
times in its history.

<p
AO),

Woe we
~
~~, pt J

et
MAES iar 1)

Ase

sg
v

gas
: £73 wai
FTG

tm
cy
Non taal
apes
amet?

Fie. 7 — Map of North America, showing the area covered by the
great ice sheets, the three centers of accumulation, and the approxi-
mate southward extension.

35. The American ice sheet.— The northern part of
the American continent was at one time covered by a

GEOLOGICAL CLASSIFICATION OF SOILS 49

great sheet of ice possessing all the properties described
above. Accumulation seems to have occurred in three
well-defined centers, from which, over long geologic
periods, the ice slowly moved southward, encroaching
upon and covering thousands of square miles. The
ice cap of Greenland is a very good example of the con-
ditions then existing in the northern part of the United
States. The area covered by glaciers in North America
at the time of the greatest extension of the ice is estimated
as 4,000,000 square miles. The thickness of the sheet
was probably very great, ranging from a few feet at the
margin to probably a mile or more toward the centers;
at least it was thick enough to override some of the
highest mountains of the New England ranges. Local
glaciation also occurred on the hill and mountain tops,
which tended to increase the apparent thickness of the
ice mantle.

36. Cause of the ice age. — The ice age was not one
unbroken invasion and retreat of the ice cap, but was,
as is conceded by ‘all authorities on glaciation, really
divided into epochs. Five great invasions appear to
affect at least the central part of the United States,
possibly without bringing about a disappearance of the
ice across the Canadian border. These interglacial
periods are shown by forest beds, accumulations of
organic matter, and evidences of erosion between the
drift deposited by the successive ice sheets. Some of
the interglacial periods evidently were times of warm,
and even semitropical, climate. Just exactly what was
the cause of the ice age is still under dispute. The most
probable theory, both as to its occurrence and as to Its
disappearance, is that a change in the carbon dioxide
content of the atmosphere took place. It is believed

50 SOILS: PROPERTIES AND MANAGEMENT

that doubling the amount now present would bring about
tropical climate in the temperate zones, while halving
it would cause frigid conditions and a probable return
of the great ice fields.

37. The extension of the ice sheet.— While the
advancing ice in general exhibited well-defined viscosity,
certain parts were more or less rigid. This was especially
true of the parts near the edges of the sheet. These
parts had become filled in their advance, particularly
near the bottom, with earthy and stony material, which
aided the erosive processes to a very great degree. The
eroding and denuding power of the glaciers is shown
everywhere by the gouged-out valleys and by the scratches,
or strize, on exposed rocks. As this sheet of ice slowly
advanced a few inches or a few feet a day, the mantle of
residual soil was carried away or mixed with the rock flour
constantly formed by the moving ice. The original soil
was really an instrument for more effective ice action.
The scouring effect is observed now to the best advantage
in valleys which lay longitudinally to the ice movement,
as did the valleys of the Finger Lakes of central New
York. Valleys lying at right angles to the ice were very
often partially or wholly filled with débris, and the en-
tire topography was altered. Rivers flowing under the
ice often left large amounts of materials designated now
as eskers and kames. The mixing, grinding, trans-
porting, and stratification that went on emphasizes
again the great influence of glaciation on general topog-
raphy and soils.

The greatest southward extension of the ice in the United
States is marked by a great terminal moraine (Fig. 8).
It is supposed that the margin of the sheet was stationary
at this point for a sufficiently long period to allow this

GHOLOGICAL CLASSIFICATION OF SOILS

Fig. 8.— Areaof the United States covered by glacial ice and the approximate location of the great terminal

On
fod.

moraine.

52 SOILS: PROPERTIES AND MANAGEMENT

narrow band of material to collect by the continual
melting of the ice and a consequent dumping of its load
of débris. This moraine is by no means continuous,
and for miles across the continent no trace of it can be
found. It extends, roughly, eastward from the Canadian
border in Washington to the upper sources of the Missouri
River, then down that river to St. Louis, up the Ohio
River, northeastward until the southwest border of
New York is reached, and then southeast to New York
City and Long Island. Many other moraines are found
to the northward, marking points where the ice became
stationary for a time during its retreat.

38. The ice as a soil builder. — It was during these
retreats that the ice acted as a soil-forming agent. Ma-
terial gathered and ground by the ice as it pushed to the
southward was finely pulverized and it is only natural
to suppose that this débris was deposited as the ice slowly
retreated by the melting back of its margins. The
material laid down as a great mantle over the glaciated
areas is called drift. Some of this has been reworked
and stratified by water, but a very large proportion has
remained untouched since it was laid down by the melt-
ing ice. It presents In most cases — except at the very
surface, where weathermg may have occurred or organic
matter accumulated — exactly the same condition as
when deposited. This mass of unstratified material is
heterogeneous, both as to size of the particles that make
it up and as to its rock composition. It may be coarse
and bowldery, especially in mountains or where there
are gneisses or schists, or it may be very fine where the
rocks are soft. Bowlder clay is a term sometimes used
in describing the matrix of this glacial deposit. In some
cases foliation occurs, and often coarse and fine layers

GEOLOGICAL CLASSIFICATION OF SOILS 53

of till may alternate. This great mantle of material,
varying in thickness and constitution according to the
underlying rocks and the strength of glaciation, gives a
great soil province in northern United States which
may be designated as glacial till soil.

39. Glacial till soils.—-The glacial till soils may be
characterized physically as heavy or relatively heavy
soils. The tremendous force of the grinding has pro-
duced fine particles, and as a consequence clay loams
and silt loams predominate. Such soils usually have a
subsoil which is finer than the surface material and may
be so impervious to water as to produce bad drainage
conditions. The individual particles of a glacial soil
are found to be unweathered to a great degree unless the
soil is mixed with some of the old mantle of residual
material which once overspread all our glaciated areas.
The particles are jagged and unrounded; the feldspars
retain all of their luster, and the iron stains so common
in residual soils are almost absent. As the glacial soils
are young soils, their colors are seldom made up of reds
and yellows, but grays and browns prevail. Red may
occur, however, where red sandstones have been glaciated
or where red residual soil has become incorporated in
the till. Where considerable organic matter has accu-
mulated the soil is usually very black. The subsoils
in the glaciated areas usually present colors ranging
from light grays to light browns. Blue or mottled clay
or clay loam is often found, due to a lack of aération in
the soil; to the soil expert such a condition near the sur-
face indicates a need of drainage.

40. Composition of glacial soils. ——- The chemical com-
position of glacial soil approaches more nearly than that
of any other soil the composition of the original rock.

D4 SOILS: PROPERTIES AND MANAGEMENT

This close resemblance to the parent rock is not sur-
prising, since glacial soil is ground-up rock material of
recent formation on which the weathering agencies have
as yet had little time for action. Therefore the amounts
of the important constituents in such soil are governed
largely by the composition of the original rock. The
lime content is due to such a relationship, and the agri-
cultural value of the soil is greatly influenced thereby,
since large amounts of calcium are of great importance
to soil fertility. The hill soils of central New York
(Volusia series) come from shales poor in lime, and the
soil owes its properties very largely to this lack, which
is traceable to the parent rock. On the other hand, cer-
tain glacial soils of the Mississippi Valley (Miami series)
formed from sandstones and limestone, contain plenty
of lime due to the nature of their rock origin. Glacial
soils from limestone always contain plenty of lime, a
condition that is far from true with residual soils.

41. Humus of glacial soils. — The humus content of
glacial soils depends to a large extent on the climatic
conditions under which the soil has existed since its
formation. If environmental factors have been such
as to encourage the accumulation of organic matter,
these soils will exhibit the deep black color that arises
from the presence of such material. If, however, con-
ditions do not encourage the natural growth of a heavy
vegetation, the amount of organic matter in such virgin
soil will be low. Lime may be a very great factor in
such soils, not only in the encouragement of plant growth,
but also in the proper decay of the plant tissue after
it has become incorporated with the soil.

Glacial till soils are found distributed over all the area
north of the great terminal moraine, and stretch, roughly,

GEOLOGICAL CLASSIFICATION OF SOILS 55

from New England to the Pacific coast (see Fig. 4).
They comprise a great variety of soils, not only as to their
physical character, but also as to fertility. They are
adapted to many crops, but general farming is practiced
on them to the greatest degree. This means extensive,
rather than intensive, operations. In some localities
dairying has been developed to a large extent, and has
proved to be not only a means of obtaining paying re-
turns from such soils, but at the same time a method of
keeping up their fertility.

42. Glacial lakes. Such great masses of ice could
not advance and retreat, again and again, on such an
extensive scale, without causing the formation of great
torrents of water. It is more than probable that at all
times great streams gushed from the ice front, laden
with much sediment. Often these streams were under
pressure, which when released caused an immediate
deposition of material. As long as the ice front stood
south of the east and west divide, this water found ready
egress and flowed rapidly away to deposit its load as
gravelly outwash, river terraces, valley trains, and allu-
vial fans. These formed alluvial soils of varied character,
depending on the size of the materials carried. There
came a time, however, in the retreat of the ice, when the
front stood north of the divide and only a small pro-
portion of the water found itself free to flow over the divide
and away to the southward. The remaining water was
ponded between the ice front and the old divide. Thus
glacial lakes were produced, of large or small extent,
according to the position of the ice. The location of
such lakes is shown on the soil map of the United States.
The ponded water remained in this condition for many
years, subject, of course, to changes concordant with

56 SOILS: PROPERTIES AND MANAGEMENT

the oscillation of the ice front. With the ice melting
rapidly on the hilltops, these lakes were constantly fed
by torrents from above which were laden with sediment
derived not only from under the ice, but also from the
unconsolidated till sheet over which it flowed. As a
consequence, there were in the glacial lakes deposits rang-
ing from coarse delta materials near the shore to fine silts
and clay in the deeper and stiller water. Such materials
now cover large areas (see Fig. 4), not on]y in New York
State and along the Great Lakes, but also in the Red
River Valley and in the northerly inclined valleys of the
Rocky Mountains and the Cascade and Sierra Nevadas.
They make up by far the most important lacustrine
soils.

43. Lacustrine soils — glacial lake. — Glacial lake soils
probably present as wide a variation in physical char-
acteristics as any of our great soil provinces. Being
deposited by water, they have been subject to much
sorting and stratification, and range from coarse gravels
on the one hand to fine clays on the other. They are
generally found as the lowland soils in any region, al-
though they may occur well up on the hillsides if the
shores of the old lakes encroached thus far. The color
of such soils varies from gray to black, according to
the degree of organic matter present. The humus con-
tent of such soils, as with the glacial till, varies with
climate, and may be high, low, or medium according
to conditions. The thickness of glacial lake deposits is
variable, ranging from a few feet to many feet. In
chemical composition they closely approximate the soil
from which they are derived. This is particularly true
as regards the presence of lime. The Dunkirk soil
of southern New York, a wash from the lime-poor

GEOLOGICAL CLASSIFICATION OF SOILS 57

Volusia series of the highlands, is low in lime; while
the same soil just south of Lake Ontario, obtaining its
wash from a limestone till (Ontario series), is rich in
lime. As may be inferred from the above comparison,
the glacial lake soils of the United States are variable
in their fertility.

The distribution of the glacial lake deposits, as seen
from the soil map of the United States, is fairly wide.
Such soils are found in areas large enough to be of great
agricultural influence, extending from New England
westward along the Great Lakes until their greatest
expanse is reached in the Red River Valley. These de-
posits make up some of the most important soils of the
northern states. They are valuable not only for ex-
tensive cropping with grain and hay, but also for fruit
and trucking crops. The Ice Age was certainly not
in vain as far as the production of fertile soils is con-
cerned.

44. Lacustrine soils— recent lake.— There is yet
another lacustrine soil to be considered besides the one
just discussed — recent lake soil. While the glacial lake
deposits were formed many thousands of years ago, the
lake soils of the second group are in process of construc-
tion. It is a well-known fact in physical geography
that lakes are only enlarged stream beds, and are doomed
ultimately to be filled by river sediments. Such soils
have been reclaimed to a certain extent, but their acreage
is not large enough to give them the importance of
the glacial lake soils. The lake soil is usually of a fine
character, rich in humus, of good tilth. If properly
drained, it is almost invariably highly productive, and
is adapted to a variety of crops depending on climatic
conditions.

58 SOILS: PROPERTIES AND MANAGEMENT

45. Molian soils. — During glaciation much fine ma-
terial was carried miles below the front of the glaciers
by streams that found their sources therein. ‘This fine
sediment was deposited over wide areas by the over-
loaded rivers. The accumulations occurred below the
ice front at all points, but seem to have reached their
greatest development in what is now the Missouri Valley.
There, too, the sediment seemed finest, and, coming
mainly from glaciated limestones, was very rich in cal-
cium. It is generally agreed by glacialists that a period
of aridity, at least as far as this particular region is con-
cerned, immediately followed the retreat of the ice.
The low rainfall of this period was accompanied by
strong westerly winds. These winds, active perhaps
through centuries, were instrumental in the picking-up
and distributing of this fine material over wide areas
of the Mississippi, Ohio, and Missouri valleys. One
strong argument for this Aolian origin is that the soil is
found in its deepest and most characteristic development
along the eastern banks of the large streams. Especially
noticeable is the extension down the eastern side of the
Mississippi River almost to the Gulf of Mexico. This
wind-blown material, called loess, is found over wide
areas in the United States, in most cases covering the
original till mantle. It covers eastern Nebraska and
Kansas, southern and central Iowa and Illinois, northern
Missouri, and parts of Ohio and Indiana, besides a wide
band, as already noted, extending southward along the
eastern border of the Mississippi River. Due to its
mode of origin, its depth is always greatest near the
streams and gradually becomes less farther inland. In
places, notably along the Missouri and Mississippi rivers,
its accumulation has given rise to great bluffs which

GEOLOGICAL CLASSIFICATION OF SOILS 59

bestow a characteristic topography to that region. The
loess soil is found also covering the great areas of China
and Siberia, and thus it is one of the important soils of
the world. Another soil, made up, at least partially, of
wind-blown material and found in Arizona and New
Mexico, is called adobe. Volcanic soils of the western
United States and elsewhere are to some extent of wind
origin. Sand dunes are of Aolian origin, but these sink
into insignificance as to agricultural value when com-
pared with the soils named above, especially loess.

46. Loess soils. — Loess is usually a fine calcareous
silt or clay, of a yellowish or yellowish buff color. While
it may be readily pulverized when subjected to cultiva-
tion, it possesses remarkable tenacity in resisting ordinary
weathering. The vertical walls and escarpments formed
by this soil show one of its striking physical character-
istics. In China! caves that house thousands of persons
are dug in the defiles and cafions existing in this deposit.
Another feature of loess is the presence of minute vertical
canals lined with a deposit of calcium carbonate. These
canals are supposed to give the soil its vertical cleavage
and its tenacity. The particles of loess are usually un-
weathered and angular. Quartz seems to predominate,
but large quantities of feldspar, mica, hornblende, augite,
calcite, and other substances are found.

A few typical analyses” are given below:

1 Richthofen, F. Chinese Loess. Geol. Mag., May, 1882,
p. 293.

2 Clark, F. W. The Data of Geochemistry. U.S. Geol. Sur-
vey, Bul. 491, p. 486. 1911.

A. From near Dubuque, Iowa.

B. From Vicksburg, Mississippi.

C. From Kansas City, Missouri.

D. From Cheyenne, Wyoming.

60 SOILS: PROPERTIES AND MANAGEMENT

A B Cc D
Sid... ... . .| 72.68 | 60.69 | 74.46 | 67.10
ALO, . . . . . .| 12.03 7.95 | 12.26 | 10.26
FeO; . ... . .| 3.58 2.61 3.25 2.52
MgO - i... ef LL 4.56 1.12 1.24
CaO . 1.59 8.96 1.69 5.88
NaO ..... .;| 168 1.17 1.43 1.42
KO... .. . et 218 1.08 1.83 2.68
PO;.... 2... 23 13 09 Al
CO... ... 39 9.64 A9 3.67
HO... ... .| 2.50 1.14 2.70 5.09

It is immediately noticeable that the lime content of
these soils is high, as is also the phosphoric acid. In
fact, all the more soluble constituents are present in
relatively large quantities, as would naturally be ex-
pected from the mode of origin of such soils — they having
been subjected to aridity and then deposited by the wind
at a relatively recent period. It is maintained by some
geologists * that the deposition of loess is still going on
in certain parts of the world, but that the rate of accumu-
lation is so exceedingly slow that it escapes the notice
of all but trained observers. The lack of fossils, par-
ticularly those of plants, is accounted for by this slow
rate of formation, which allows sufficient time for all
organic matter to become fully oxidized before being
covered by the drifting material. Snail shells are often
found, but as they are of land species they argue against
a water origin of loess.

1 Merzbacher, G. The Question of the Origin of Loess. Mitt.
Justus Perthes’ Geogr. Anst., 59, pp. 16-18, 69-74, and 126-130.
1913.

GEOLOGICAL CLASSIFICATION OF SOILS 61

47. Distribution of loess. — Not only is loess found
over thousands of square miles in the central part of the
United States, but it occurs elsewhere in large areas.
It is greatly developed in northern France and Belgium,
and along the Rhine in Germany, where it is an important
soil in all the valleys that are tributary to that river.
Silesia, Poland, southern Russia, Bohemia, Hungary,
and Roumania, all have deposits of this highly fertile
material. In Europe it extends from sea level to eleva-
tions of 5000 feet, showing its independence of water
as a formative agent. In China it is found over a very
large part of the valley of the Hoangho, a region prob-
ably larger in area than France and Germany combined.
The thickness of the deposit is variable, ranging from a
few feet to several thousand feet in certain places. The
depth is practically always sufficient for any form of
agricultural operations.

Wherever moisture relations are favorable loess is an
exceedingly fertile soil, due to its rich stores of potash,
phosphorus, and lime. Its organic content is usually
medium to high, depending on conditions. In general
it may be classified as the richest soil in the world,
considering its wide extension and the great variety
of climate and of crops to which it is subjected. In
the United States it occurs in the Corn Belt region,
and might be called the great corn soil of the Mississippi
Valley.

48. Adobe soils. — The term adobe is a name applied
to a fine calcareous clay or silt formed in a manner some-
what like that in which loess is formed. It is supposed
that, while part of the deposit came from the waste of
talus slopes as mountains were weathered under conditions
of aridity, the remainder had an origin similar to that of

62 SOILS: PROPERTIES AND MANAGEMENT

loess. Certain characteristics also seem to indicate that
the valley adobe might have been deposited by water.*
It appears, therefore, that, while the physical characters
of all adobe are somewhat similar, its mode of origin and
chemical composition may be variable. Below are the
analyses® to two typical adobe soils: —

A B
SiO, 66.69 44,64.
AlOs 14.16 13.19
FesOs3 4.38 5.12
CaQ 2.49 13.91
MgO 1.28 2.96
KO 1.21 1.71
Na,Q . .67 59
CO, 77 8.55
POs . . « 2 «8 # ew we 29 94.
Organic matter. . . . . . 2.00 3.43

Like the loess, adobe is an exceedingly rich soil, but
it occurs in an arid or a semiarid region. When irrigated,
its fertility seems inexhaustible. It is found in Colorado,
Utah, southern California, Arizona, New Mexico, and
Texas. It has an especially wide distribution in New
Mexico. Like loess its elevation is variable, ranging
from sea level in California and Arizona to 6000 feet
along the eastern border of the Rocky Mountains. Its
maximum thickness cannot be estimated, as it is very

+ Russell, I. C. Subaérial Deposits of the Arid Regions
of North America. Geol. Mag., August, 1889, pp. 342-350.

* Hileard, E. W. Relations of Soil to Climate. U.S. Weather
Bur. Bul. 3. 1892.

* Merrill, G. P. Rocks, Rock Weathering, and Soils, p. 321.
New York. 1896.

GEOLOGICAL CLASSIFICATION OF SOILS 63

little eroded and is supposed to be still accumulating,
Some valleys are known to be filled to a depth of 3000
feet with this material. Its characteristics are its fine
texture, its great depth, its wide distribution, and its
great fertility when moisture conditions are suitable for
crop growth.

49. Sand dunes.— Sand dunes are the outgrowth
of two conditions—a large quantity of sand and a
wind that blows in a more or less prevailing direction.
Under such conditions the sand and other fine material
not only is blown into heaps, but also tends to move in
the direction of the prevailing wind. Such heaps or
mounds of sand may travel several feet a day by the
continual movement of the sand grains up the windward
side of the dune, only to be deposited again on the lee-
ward side. Sand dunes may often assume gigantic
proportions, being sometimes ‘several hundred feet high
and twenty or thirty miles long. In such proportions
they become a grave menace to agriculture, not only
because they are an absolutely valueless medium for plant
growth, but also because they cover fertile lands and
entirely blot out all plant growth. The particles of this
wind-blown sand are usually round, from the continual
abrasion that they receive. A great many minerals
may be represented, but quartz 1s the commonest, es-
pecially if the dune originally had its origin on a lake or
a seashore.

50. Volcanic dust.— From early geologic times de-
posits of the very fine material that is continually bemg
ejected from volcanoes have been distributed over the
earth’s surface. These deposits are usually flour-like,
and while at one time they probably covered many
square miles of territory, they have succumbed very

64 SOILS: PROPERTIES AND MANAGEMENT

largely to erosion and denudation, and only remnants
are found at the present time. Such material may be
found in Montana, Nebraska, and Kansas. X®olian
deposits of this character are usually rather porous and
light, and are likely to be highly siliceous. They are
not of great agricultural importance.

CHAPTER V

CLIMATIC AND GEOCHEMICAL RELATION-
SHIPS OF SOILS

AuruouGsH during the process of weathering the tendency
of all soil is toward a common composition, such a con-
dition is never reached, due to different kinds and varying
intensities of decay and disintegration. Soils lend them-
selves readily to a geological classification because of this
difference in mode of formation. Such a classification
really signifies a variation in composition. A difference
in age, a preponderance of physical agencies over chemi-
cal or vice versa, a difference in the transportive agencies,
or a variation in climatic conditions after a soil is once
formed, will assuredly give a different product, not only
chemically, but physically and biologically as well.

51. Climatic relationships. — It is evident that climate
is a factor in all geochemical relationships of soils. Not
only does climate determine the kind of weathering and
its intensity, but in many ways it influences very largely
the characteristics of the soils of different provinces and
sections. Climate must be considered also im the geo-
logical classification of soils, since it plays such an im-
portant réle in determining the kind and intensity of the
formative agents. In any scheme of grouping for the
systematic survey ahd mapping of soils, climate is the
very first factor to be considered. It gives three great
groups — tropical, subtropical, and temperate. These
may in turn be subdivided into arid, semiarid, and humid,

F 65

66 SOILS: PROPERTIES AND MANAGEMENT

In the utilization of soil, climate, particularly as regards
rainfall and temperature, plays an important part. Crop
adaptation is really more of an adaptation to climate than
to soil, although the latter also should be very carefully
studied. The climatic relationships in soil formation,
in soil chemistry, and in geochemistry in general, cannot
be too strongly emphasized, whether the viewpoint be
technical, practical, or merely educational.

52. Geochemical relationships of residual and marine
soils. —It is evident from the above that coastal plain,
residual, and glacial soils should exhibit certam well-
defined general differences due to their mode of formation.
The following analyses, which are representative of the
provinces in question, illustrate the chemical differences
of coastal plain and residual soils :—

ANALYSES oF TrptcaAL CoastaL Puain anp ResrpuaL SOILs

Licut SANDY | CoRN AND
Loam rrom |WHEAT CLAY
MARYLAND Loam Sorin
AVERAGE OF | AVERAGE oF
5 Sampies!| 3 Sampues!

RESIDUAL RESIDUAL

Soil FROM SoIt FROM

VIRGINIA VIRGINIA
GNEIss 2 LIMusTONE 3

Si0Q, .... =. 92.30 80.55 45.31 57.57
AlOzs. . . . . 3.20 8.82 26.55 20.44
FeO, . .. . 91 2.67 12.18 7.93
P20;. .. . . 05 A2 47 10
CaO... ... Al AT trace 51
COs... . . . 08 .05 trace 238
MgO. .... 235 29 .40 1.20
Nad. . . . 50 49 22 23

KO... . .70 1.22 1.10 4.91

1 Veitch, F. P. The Chemical Composition of Maryland
Soils. Maryland Agr. Exp. Sta., Bul. 70, pp. 71 and 73. 1901.

2 Merrill, G.P. Weathering of Micaceous Gneiss in Albemarle
County, Virginia. Bul. Geol. Soc. Amer., Vol. 8, p. 160. 1879.

’ Diller, G. 8. The Educational Series of Rock Specimens.
U.S. Geol. Survey, Bul. 150, p. 385. 1898.

CLIMATIC AND GEOCHEMICAL RELATIONSHIPS 67

It is to be noted, in the first place, that silica exists in
large quantities in the coastal plain soils, due to the fact
that quartz is such a resistant mineral. The constant
washing that this soil has undergone has very largely
decomposed the silicates. The aluminium and iron are
rather low on the average in such soils, even in those of
the richer type. It is to be noted also that the amounts
of phosphoric acid, calcium, potash, magnesia, and sodium
are much less in the marine soils, due to the excessive
washing that they have received. These figures would
lead to the belief that in general the marine soils are
lower in the mineral plant-food constituents than soils
formed in situ. The amount of organic matter that they
may contain depends entirely on their location and
climatic conditions. They may or may not be rich in
humus, according to circumstances. It is generally con-
sidered, however, that they are not so well supplied with
the organic elements as are other soils.

53. Residual and glacial soils.— A comparison of
residual and glacial provinces cannot be made with such
assurance, because of the many kinds éf rocks that may
have been parent to the soils and because of the great
variety of climatic conditions under which the soil-form-
ing processes may have gone on. Such a comparison 1s
best made in a region where both residual and glacial soils
are found, as nearly as it is possible to judge, coming
from the same rocks. Analyses of soils under such con-
ditions are available, from the driftless and glaciated
parts of Wisconsin. The original rock was limestone.
The analyses! are as follows :—

1 Chamberlin, T. C., and Salisbury, R. D. The Drift-

less Area of the Upper Mississippi. Sixth Ann. Rept., U. S.
Geol. Survey, pp. 249-250. 1885.

68 SOILS: PROPERTIES AND MANAGEMENT

ANALYSES or Rosipt1L AND GLACIAL CLAYS FROM THE DrRirt-
LESS AND Guactatep ARTAS OF WISCONSIN

RESIDUAL GLACIAL
i 2 3 4
SiQ, . . . 6. 71.13 49.13 40.22 48.81
AlO;. . . . =. 12.50 20 08 8.47 7.04
FeeO3;. . . . . 5.52 11.04 2.83 2.53
MgO... .. 38 1.92 7.80 7.95
CaO... .. 85 1.22 15.65 11.838
NaoO. . .. . 2.19 1.33 84 92
KO... 1.61 1.61 2.36 2.60
P.O; . . 0. 0. =. .Q2 04 .O5 13
CO, . . . . . 43 09 18.76 15.47

H20.... =. 4.63 11.72 1.95 2.02

These analyses illustrate to very good advantage the
beliefs entertained by Chamberlain and Salisbury regard-
ing the differences between residual and glacial clays.
Residual clay is designated by them as “ rock rot,” and
glacial clay as “rock flour.” The latter, being less
weathered, retains a larger proportion of its easily soluble
materials. It is #0 be noted here, as in the comparison
of marine and residual soils, that silica, aluminium, and
iron are lower in the soil subjected to the less amount of
leaching, which in this case is the glacial clay. This in
itself would serve to indicate that the important plant-
food constituents are generally present in larger quanti-
ties in the glacial clay. In fact, it would be expected
that the glacial soils would approximate very closely the
rock or rocks from which they came. The phosphoric
acid, lime, sodium, magnesium, and potash of the residual
soils in this case amount on the average to 5.73 per cent,
while that of the glacial clays reaches the high figure of
24.61 per cent. Tis is due largely to the great amount

CLIMATIC AND GEOCHEMICAL RELATIONSHIPS 69

of lime present, and again emphasizes the point that,
while a glacial soil from a limestone is rich in lime, a
residual soil from the same rock is usually poor in that
constituent. Even loess, which has been subjected to
some washing before being deposited, is a considerably
richer soil than those of residual origin.

It must be remembered, however, that these comparisons
are of a general character and do not apply to all cases,
since many glacial soils may be very much poorer in the
plant-food constituents than some of the representative
residual soils. Moreover, the physical condition of a
soul is a great factor in productivity. As a matter of
fact, the mere presence of plant-food is but one of a
considerable number of factors that determine the crop-
producing power of a soil. Also, the humus content of
the soils of various provinces may be variable, due to
climatic conditions. Neither are all glacial soils rich in
lime, as that constituent is determined largely by the
amount in the parent minerals. A rock poor in lime,
therefore, must from necessity give rise, when glaciated,
to a soil deficient in lime. This is well illustrated by the
average analyses! of the loam soils of Ashtabula County,
Ohio, originating from the glaciation of the lime-poor
shales of that region : —

CaO . . www we ew ew D5
MgO.......... 61
PoO, . . 1... ee eee OA
KO . .... 2... . . 1.87
NN... ee ee ee LB
Humus .......... 1.70

1 Ames, J. W., and Gaither, E.W. Soil Investigations. Ohio
Agr. Exp. Sta., Bul. 261. 1918.

70 SOILS: PROPERTIES AND MANAGEMENT

However, our major premise does seem to stand in a
general way —that a glacial soil, other things being
equal, contains a larger amount of the mineral plant-food
constituents, and ordinarily a smaller amount of such
materials as silica, iron, and aluminium, than does a
corresponding soil of residual origin.

The following data! bring out the poimts already dealt
with in their fullest significance : —

Percontace or P,0;,Ca0, McO, ano K.O in Sorts or Dir-
FERENT PROVINCES

Sorns P2Os CaO | MgO K20 Toran
7 Coastal plain. . . .| .07 14] .16 70 | 1.07
3 Residual (orysteliine) ~| oO 67 | .75 | 2.08 | 3.75
10 Glacial . . | 22 1.86 | .79 | 2.08 | 4.45

54. Effect of glaciation on agriculture. — These differ-
ences between residual and glacial soils reflect on the
general fertility of the soils. In a comparison of the
driftless area of Wisconsin with the glaciated parts,-
only 43 per cent of the former is improved as against
61 per cent of the latter, while the value of the farms
on the glaciated soil averages 50 per cent higher. The
same general differences appear between the glacial and
residual soils of Indiana*® and Ohio.‘

1Failyer, G H., and others. The Mineral Composition
of Soil Particles. U.S. D. A., Bur. Soils, Bul. 54. 1908.

*Whitbeck, R. H. The Glaciated and Driftless Portions of
Wisconsin. Bul. Geog. Soc. Phil., Vol IX,No 3, pp. 10-20. 1911.

?Von Engeln, O. D. Effects of Continental Glaciation on
Agriculture. Bul. Amer. Geog. Soc , Vol. XLVI, p. 246. 1914.

4 Ames, J. W., and Gaither, E. W. Soil Investigations.
Ohio Agr. Exp. Sta., Bul. 261. 1918.

CLIMATIC AND GEOCHEMICAL RELATIONSHIPS ‘T1

Von Engeln,! in a comparison of glaciated soils with
corresponding residual areas, was able to point out cer-
tain general differences. The agricultural condition
within the zone of glaciation was always consistently
higher than that beyond the regions of drift accumulation.
The extensive leveling due to glacial erosion and dep-
osition had almost always resulted favorably for agri-
cultural operations. Even the thickness of the dni‘t
was found to conserve the ground water supply. Not
only did this author conclude that glacial soils were
richer in soluble plant-food constituents than residual
soils, but he also showed that glacial soils had a greater
crop-producing power and a higher agricultural value.
The dominant textural quality of glacial soils seems
adapted to certain staple food crops, and, due to their
intermingling, a considerable opportunity for diversified
and intensified farming is offered. It is therefore evident
that in any study of soils, particularly those of the United
States, a careful consideration of the effects of glaciation
is necessary. The great ice sheet has been responsible
in some cases for the rejuvenation of our soils, i others
for the production of an entirely new soil mantle. Even
the alterations in topography are factors not to be ignored.

55. Arid and humid soils.2 — This distinction between
soils due to differences in the formative process is always
evident, but is particularly striking in a comparison of arid
and humid regions. In areas of light rainfall the physical
agents are dominant, and disintegration goes on very
largely without decomposition. Under humid conditions,

1 Von Engeln, O.D. Effects of Continental Glaciation on Agri-
culture. Bul. Amer. Geog. Soc., Vol. XLVI, pp. 353-355. 1914.

2 For a more complete discussion of this subject, see Hilgard,
E. W. Soils, Chapters XX and XXI, New York. 1911.

72 SOILS: PROPERTIES AND MANAGEMENT

however, the chemical forces are the determining factor
as to the character of the soil. Arid soils are therefore
usually coarser soils and their color is very likely to be
light. Such soils are deep and uniform, there being
but little difference between the surface and the subsoil.
The soils of the humid regions are usually of fine texture,
particularly in residual regions, since the chemical agencies
have been so active. Various colors may develop because
of oxidation, hydration, and the presence of organic matter.
Such soils usually are not excessively deep, and are likely
to be underlaid by subsoils heavier than the surface.
The general physical condition and tilth of arid soil is
uniformly better than that of regions of plentiful rainfall.

Chemically, because of less leaching the arid soils con-
tain more of the important mineral plant-food elements.
The following analyses bring out the differences in a
striking manner : —

Arp Soius | Homrp Sorts AVERAGE
AVERAGE oF | AVERAGE or {COMPOSITION O1
573 Sampies!|696 Sampugs!| LirdospHURE?

Sid... . . . . . .| 75.87 88.21 | 59.36 (SiQs2)
Al,O; . . . . es eee 7.21 3.66 14.81
FesO3 ee 5.48 3.88 6.34
P205 16 12 29
CaO 1.43 13 4.78
MgO 1.27 29 3.74
Na.O Coe ee 25 14 3.35
KoO . .. . ee .67 21 2.98
Water andignition . . . 5.15 4,40 —
Humus ....... 1.13 1.22 —

i Hilgard, EH. W. The Relation of Soil to Climate. U. S.
Weather Bur., Bul. 3. 1892.

*Clarke, F. W. Data of Geochemistry. U. 8. Geol.
Survey, Bul. 491, p. 338. 1911.

CLIMATIC AND GEOCHEMICAL RELATIONSHIPS 1783

It is immediately apparent that the arid soil is poorer
in silica than the humid soil, but richer in iron and alumin-
ium, indicating a less weathered condition of the feldspars.
Due to a greater amount of leaching, the humid soil is
much lower in phosphoric acid, lime, magnesium, sodium,
and potassium. The humus in arid soils is somewhat
lower than in the soils under better conditions of rainfall,
as one would naturally expect. The amount of easily
soluble material is higher in arid regions, due to the lack
of heavy rain and the tendency for soluble salts to accumu-
late. A comparison of the analyses above with Clarke’s
estimate regarding the composition of the earth shows
that the humid-region soil has moved farther away from
the average soil-forming rock than the soil produced
under conditions of aridity.

Biologically, organisms are found active at greater
depths! in arid regions than in humid regions, because
of the loose structure of arid soils and because of their
good aération. Such soils are seldom water-logged. In
humid regions bacterial action is limited very largely
to the surface foot of soil, since only there.are the aération
and the food conditions adequate. The intensity of
biological activity in arid soils is very largely governed
by moisture, and when moisture conditions are satisfied
bacterial changes may be expected to take place rapidly.
Cases are on record in which the soluble salts due to
bacterial action have become of such concentration as
to be toxic to plants.

56. Soil color.— Another characteristic of soil is its
color, which has originated during the processes of soil

1Lipman, C. B. The Distribution and Activities of Bacteria
in Soils of the Arid Region. Univ. of Calif., Pub. in Agr. Sei,
Vol. I, No. 1, pp. 1-20. 1912.

74, SOILS: PROPERTIES AND MANAGEMENT

formation, largely through natural weathering agencies.
This is really a phase of geochemistry, particularly as
regards those tints that originate from the oxidation of
the iron. Color has long occupied the attention of
geologists and agriculturists, m the first place because
it gives a clew to the mode of soil formation, and in the
second place because it is to a certain extent an index to
agricultural value. At the outset it must be understood
that soil colors are not pure colors, although spoken of
as such, but tints and shades. In soils it is possible to
find almost any conceivable color, ranging from white
sands to black swamp muds or the blood-red clays of the
Piedmont region. The three coloring matters of soil
may be classified as (1) the color arising from the mineral,
(2) the color given by the humus present in the soil and
around the particles, and (3) the reds or the yellows due
to oxidization of the iron. These three primary, or
basal, colors may be represented for convenience as
follows : —

WHITE

LLAGK RED

BROWMSH

Fig. 9.—A triangular representation of the three primary soil colors
and their mixtures,

CLIMATIC AND GHOCHEMICAL RELATIONSHIPS Td

A soil low m humus, and with the iron either absent or
unoxidized, will be of 4 light color. Sea sands are good
iiustrations of this condition. A well-drained soil con-
taining large Quantities Of Organic matter will present a
deep black color im spite of the oxidized iron, as the latter
will be masked to a larce extent. Ji humus is low or
Jacking and the iron is Oxidized, a red or a yellow color
may characterize the soil) As might be expected, there
are blendings of these three primary colors, and grays,
browns, and yellows of Varying intensities are Common.

57. White and black soils. — The lisht colors in soils
are not due to the agencies of weatherins, but rather to
a lack ot such action. The cause o: such coloration 1s
therefore not hard to explam. The development of the
black or dark colors and tints, being due to the accumula-
tion Of Ofganic Matter, mdicates the operation of two
favoring conditions: first, climatic agencies that stimu-
late the luxuriant development o7 plants; and, secondly,
Sufiicient aeration to promote a favorable decay of such
tissue. It is @ well-recognized fact that in order to
develop a black color from decaying vegetable matter,
fairly good aeration must be provided. [i such a con-
dition does not prevail, the decayed material has a hghter
hue and may exhibit toxic properties which will check
Or inhibit plant growth. ‘The development of the black
color, therefore, in @ normal well-drained soil; is an in-
dication of good soil sanitation.

58. Red and yellow soils. — The presence of iron, as
already noted, is a very important factor im rock weather-
ing, and the discoloration due to its preserice is an untailing
indication of chemical decay. The iron im minerals
occurs usually as ferrous oxide, which is soluble, especially
if the water circulating among the rock fragments carries

76 SOILS: PROPERTIES AND MANAGEMENT

carbon dioxide. As this water comes in contact with the
air, its excess of carbon dioxide is discharged and the
oxides and carbonates of iron are deposited. Under
this condition oxidation goes on rapidly, and the iron
passes to the ferric state and becomes insoluble. Thus
it may be seen that iron imparts a fatal weakness to rocks
and minerals in which it may exist, due to its solubility ;
yet from the oxidation that it undergoes, it tends to
persist and accumulate in soils. A corollary might be
added to the law of mineral resistance, to the effect that
“the more iron a mineral contains, the more susceptible
it is to the weathering agencies.”

Therefore, from the geochemical standpoint, the de-
velopment of the red and yellow colors in soils has been
the subject of considerable dispute from time to time.
The red and yellow soils of the Cotton States frequently
excite comment, especially as a difference in fertility is
popularly recognized; the red surface soil with a red
subsoil being considered more fertile than a similar soil
with a yellow subsoil. Crosby! believes that the differ-
ence in color is due to a difference in hydration of the
iron oxides. The soil temperatures, particularly in
tropical and subtropical regions, have first tended to
fully oxidize and hydrate the iron, and then to dehydrate
the soil at the surface into the deep red color, leaving the
subsoil yellow and causing the contrasts so miarkedly
evident. The ultimate product of both oxidation and
hydration would be limnite, a yellow mineral; while
if only oxidation were active, hematite, which imparts
a red color, would result as a final product. A dehydra-
tion of the limnite would cause the formation of hematite

1 Crosby, W.O. Colors of Soils. Proc. Boston Soc. Nat. Hist.,
Vol. 23, pp. 219-222. 1875.

CLIMATIC AND GEOCHEMICAL RELATIONSHIPS TT

or some intermediate product. The composition of the
common iron oxides found in soils tends to support
Crosby’s explanation : —

Hematite. . . . FeO, Red
Turgite . . . . 2 Fe,Q;. HO

Goethite . . . . FeO;,.H.O

Limonite . . . . 2 F,0,.3 H.O
Xanthosiderite . . Fe0O;.2 H.O

Limnite ... Fe.0;.3 H.O Yellow

Merrill? holds the same idea, but thinks that the sur-
face soil may contain relatively more iron than the sub-
soil. He considers that the ferric iron oxides, because
of their imsoluble nature, tend to accumulate at the
surface, and because of their large quantities and because
they are there subjected to more vigorous weathering
action the vivid red colors tend to develop.

The iron coloring matter usually exists as a coating’
on the soil particles, although it may sometimes occur
as concretions. It is found also that in general, but not
always, the intensity of the color varies with the amount
of iron present. From a large number of analyses com-
piled by Robinson and McCaughey,® the following figures
may be obtained showing the authority for such a state-
ment :—

AVERAGE [Ron CONTENT OF PERCENT OF
Ferric [Ron

Deep reds to lightreds. . . . . . . 1440

Ochre yellow to yellow. . .- . . . . 885

1 Merrill, G. P. Rocks, Rock Weathering, and Soils, p. 375.
New York. 1906.

2Van Bemmelen, J. M. Beitrage zur Kenntnis der Ver-
witterungsprodukte der Silicate in Ton-, Vulkanischen-, und Lat-
erite-Boden. Zeit. Anorg. Chem., Bd. 42, Seite. 290-298. 1904.

3’ Robinson, W. O., and McCaughey, W. J. The Color of
Soils. U. 8S. D. A., Bur. Soils, Bul. 79, p. 21. 1911.

(8 SOILS: PROPERTIES AND MANAGEMENT

This being true, the thicker the film, the greater is the
intensity of the color. The same quantity of iron, there-
fore, would make a greater showing in a sandy soil than
in clay, as the amount of internal surface of the former is
comparatively low and the film of iron oxide would there-
fore be thicker.

It is evident from the data already presented that
the intensity of color arising from iron in the soil is due
to several conditions. Without a doubt the oxidation
that occurs is of primary importance, but the hydration
that very often takes place is a powerful modifying agent.
The thickness of the film, as determined by the amount
of iron present or by the texture of the soil, is probably
a factor having to do particularly with the intensity of
the coloration, although the color or tint itself may be
modified to a certain extent thereby.

59. Agricultural significance of color. — The white or
the black color of a soil indicates the lack or the presence
of an important constituent, namely, organic matter.
This matter not only tends to keep the soil in good
physical condition, but also acts both as a plant-food
and as a source of energy for bacteria and other soil
organisms. A dark soil, provided its drainage and
climatic conditions are favorable, is usually a rich soil.
The dark color is no mean factor in temperature relation-
ships, since not only does a dark soil absorb heat faster
than a light soil, but the tendency of the former toward
reflection and radiation is much restricted. This is
important with crops which must go into the soil early
in the season, or which need to be pushed rapidly to
maturity. A dark color, with virgin soils especially, is
an excellent guide to fertility and general agricultural
value.

CLIMATIU AND GEOCHEMICAL RELATIONSHIPS T9

Red colors in soil often show low or medium organic
content. Besides this, the presence of oxidized iron is
always an indication of age. The residual soils of the
Piedmont Plateau are especially characterized in this
way. Age gives opportunities for leaching, and conse-
quently a lack of the soluble bases may be expected in
such soils. The reds and the vellows are characteristic
of residual soils, or of soils that have arisen from them
by erosion or glaciation. A red color is almost as efficient
in the absorption of heat as is black; so that the early-
growth and quick-maturing tendencies of crops on a
red soil, other things being equal, are about the same as
on a dark soil. Hilgard,) who lays great stress on the
agricultural significance of color, considers the mottled
yellows and reds as indications of poor drainage, since
such a condition shows that oxidation has been both
unequal and insufficient. A soil that has a heavy blue
or mottled blue clay as a subsoil will in most cases be
greatly benefited by some form of drainage.

60. Soil and subsoil. — A common distinction is made
between the surface soil and that which is some distance
below the surface. This is natural, as the forces of soil
formation have served to bring about certain distinctions,
especially in humid regions, which are of importance in
any consideration of soil fertility and crop growth. Cli-
matic agencies acting on soil after it has been formed have
served to intensify these distinctions. The term soil
is used to designate the top layer of earth, which usually
extends to the plow line or even deeper. The soil below
is spoken of as the subsoil, and may be rather variable in its
depth (Fig.10). Often the subsoil is divided into the upper

1Ehlgard, E. W. Soils, pp. 283-285 New York. 1906.

80 SOILS: PROPERTIES AND MANAGEMENT
and the lower subsoil, the upper subsoil being considered

to extend to about the depth of three feet below the sur-
face. Usually, especially in humid regions, there is a

ls 62, s/f leo ; ke
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10 tae grAay sf At cz .*
a aS Iny « ay . os - / ‘
‘ "itis .? / +43 . XU ese a Ot >
SHEN IS vin elt | SNe a, a

Fre. 10. — Soil and subsoil. (a), Surface soil with many plant roots;
(6), subsoil; (c), country rock.

sharp line of demarcation between the soil and the sub-
soil, due to differences in the humus content. As organic
matter accumulates faster at the surface, the soil there
tends to assume a darker color. Whether the land has
been tilled or not, this line of separation is fairly marked
and can usually be located with little difficulty. On
tilled land, where the surface soil extends to about the
depth of plowing, the plow line marks the separation of
surface and subsoil. Where soil samples are being taken
for soil survey or soil analysis, some arbitrary depth,
depending on circumstances, is usually established for
the surface soil. This depth varies from six to twelve
inches.

61. Soil and subsoil of humid regions. — In humid cli-

CLIMATIC AND GEOCHEMICAL RELATIONSHIPS 8]

mates there are usually certain well-defined differences be-
tween the surface soil and the subsoil, besides the organic
content already spoken of. The subsoil is usually of a finer
and heavier character than the surface soil, due to the
downward movement of the small particles. This tends
to give the subsoil high retentive power, and may make
it rather Impervious to water. Poor drainage conditions
may result. <A certain amount of retentive power in a
subsoil is of considerable advantage, in that it aids in
the storage of water and prevents the excessive leaching
away of soluble plant-food. Moreover, almost all the
bacterial activities so important in the simplification of
compounds carrying food constituents are restricted
to the surface soil. The subsoil, being protected by the
layers above, has not been subjected to such vigorous
weathering, and as a consequence its mineral constituents
are not so available for the use of the crop. The deepen-
ing of the plow line and a consequent turning-up of the
subsoil must be carried out very cautiously for the above
reason. The cropping power of a soil may be markedly
reduced by the presence of too much of such material on
the surface at one time.

The root distribution is restricted largely to the surface
soil, and this condition determines to some extent the
larger accumulation of humus therein and also its better
aération and drainage. Experiments conducted in Utah?
show that with barley, corn, and clover, from 90 to 96
per cent of the roots grow in the upper seven inches of
soil. From experiments made in Kansas” and in North

1Sanborn, J. W. Roots of Farm Crops. Utah Agr. Exp.
Sta., Bul. 32. 1894.
2Ten Eyck, A.M. The Roots of Plants. Kansas Agr. Exp.
Sta., Bul. 127. 1904.
G

82 SOILS: PROPERTIES AND MANAGEMENT

Dakota,! the roots of such crops as alfalfa were found
to penetrate to a depth of ten feet, while the small grains
often showed an extension of their roots to four feet
below the surface. It must be borne in mind, however,
that, while some plant roots may penetrate far into the
subsoil, the main feeding rootlets are restricted largely
to the surface soil. This is natural, as there they find
the aération and drainage essential to normal growth.
Hilgard? has shown that plants in arid regions have a
root extension far beyond that of the same crops under
humid conditions. The physical conditions of the arid
subsoil, the larger amount of plant-food, and the better
aération, account for such differences.

62. Soil and subsoil of arid regions. — The subsoils
in arid or semiarid regions do not exhibit such marked
contrast to the surface soil as are observed in humid
climates. In arid soils there is generally no sharp line
of demarcation between soil and subsoil, the latter being
as high in humus and in agricultural value as the former.
Nor is any great textural variation to be observed. The
latter condition is due to the fact that physical weather-
ing is dominant in such a region. As a consequence, arid
soils may be leveled, often excessively, in establishing
an even surface for the application of irrigation water,
without any danger of lowering the fertility thereby.
Such a practice in humid regions would be fatal to the
further growing of successful crops, at least for a con-
siderable period of years.

1Sheppard, J. H. Root Systems of Field Crops. N. Dak.
Agr. Exp. Sta., Bul. 64. 1905.

2 Hilgard, E. W. Soils, Chapter X, pp. 161-187. New York.
1911.

CHAPTER VI

THE SOIL PARTICLE

Tue soil formed by the grinding-up of rocks and the
intermixing therewith of small quantities of organic
matter must be studied physically from the standpoint
of its particles. These particles, varying in size from
coarse gravel easily discernible by the naked eye to
particles so fine as to be invisible under the ultramicro-
scope, determine very largely the different relationships
of the soil to the plant. The movement of air in the soil,
the circulation of water, the rate of oxidation and hydra-
tion, and the presence and virility of various organisms,
are determined very largely by the size of the particles
making up the soil. Teature is the term used to express
this size of particle. Thus a soil texture may be coarse,
medium, or fine, indicating that the particles making up
that soil conform in general to such description. Tex-
ture is of great importance in soil study and utilization.

There is hardly any condition exhibited by the soil
that is not influenced, if not directly determined, by the
size of the soil particles. A study of plant conditions,
whether physical or chemical, ultimately leads either
directly or indirectly to a consideration of soil texture.
Texture, however, is an element which can be but little
modified under normal conditions. We have seen how
a rock can be disintegrated and decomposed into a soil.
A change in texture has been wrought, but such a process
demands geologic ages for its fulfillment. In the time

84 SOILS: PROPERTIES AND MANAGEMENT

covered by the life of man the necessary forces are not
active enough to have this effect; consequently, as far
as the farmer is concerned the texture of the soil in his
field is subject to but slight alteration. A sand remains
a sand and a clay remains a clay, as far as practical con-
siderations are concerned. Changes in texture may be
made on a small scale by mixing two soils, but this is not
practicable in the field.

63. Soil separates and mechanical analysis. —'The
soil particles, varying in size as they do, may be separated
into arbitrary divisions, according to their diameters.
The various groups are designated as soil separates, and
the process of making the separation and determining
the percentage of each group present is called mechanical
analysis. There are a large number of classifications, or
groupings, of the soil particles, as well as several methods
of bringing about the actual separation. The grouping
and method of mechanical analysis most generally used
in this country is that devised by the United States Bureau
of Soils. Other methods? are more nearly accurate,
but speed as well as precision is necessary in this work.
A Swedish classification 3 of soil particles has been adopted
by the Committee on Mechanical Soil Analysis,* appointed

1 Briggs, L. J., and others. The Centrifugal Method of Soil
Analysis. U.8. D. A., Bur. Soils, Bul. 24. 1904.

2Hor a detailed discussion of all methods of mechanical
analysis, see Wiley, H. W. Agricultural Analysis, Vol. I,
pp. 195-276. Easton, Pa. 1906.

3 Atterberg, A. Die Mechanische Bodenanalyse und die
Klassifikation der Mineralbéden Schwedens. Internat. Mitt.
f. Bodenkunde, Band II, Heft 4, Seite 312-342. 1912.

4Schucht, F. Uber die Sitzung der Internationalen Kom-
mission fiir die Mechanische und Physikalische Bodenunter-
suchung in Berlin am 31, October 1913. Internat. Mitt. f.
Bodenkunde, Band IV, Heft I, Seite 1~31. 1914.

THE SOIL PARTICLE 85

by the Second International Agro-Geological Congress,
which met in Stockholm in 1910. In simplicity and
facility of interpretation the last-named grouping seems
at least equal to that of the Bureau of Soils. Since a
number of methods of mechanical analysis have been
devised during the evolution and study of soil separation,
it is necessary to be conversant with the principles in-
volved and with at least two or three of the most successful
modes of procedure.

64. Principles of mechanical analysis.— The various
methods of mechanical analysis may be grouped according
to the agents employed in the separation. The outline is
as follows : —

Outhne of systems of mechanical analysis

Wet

1. Sieve { or (Used to separate sands in practically all
Dry methods)

2. Air (Cushman’s air elutriator)

Gravity (Schone’s elutriator and
Hilgard’s churn elutriator)

tn motion Centrifugal (Yoder’s centrifugal
elutriator)
3. Water Gravity (Osborne’s beaker method
and Atterberg’s modified silt
At rest cylinder)
Centrifugal (Bureau of Soils
method) |

In the consideration of such an outline, certain of the
general methods proposed may be dismissed without
further parley since they are inadequate for the separation

86 SOILS: PROPERTIES AND MANAGEMENT

in question. Sieves of all kinds have the one great dis-
advantage that their meshes cannot be made small enough
to separate the finer grades of soil. When one considers
that many soil particles are less than .005 millimeter in
diameter, the inadequacy of sieve separation becomes
apparent. However, sleves may be used in connection
with other methods as an easy way of dealing with the
larger soil particles. Air in motion! is inadequate, as
it can be used only for very fine particles. Even with
these the separation is slow and inaccurate, because of
the tendency of the dry particles to cohere. These two
methods have therefore been largely abandoned as dis-
tinct methods, and water is used as the medium of separa-
tion in all the modern systems of mechanical analysis.
The principle involved in the subsidence of soil particles
in water, whether the force of gravity or centrifugal
force is utilized, is recognized by every one. When
fragments of rock or soil are suspended in water, they
tend to sink slowly, and it is a well-recognized fact that
other things being equal, the rate of settling depends
on the size of the particle. As the particle is decreased
in size, its weight decreases faster than the surface ex-
posed to the buoyant force of the water. As a conse-
quence, the rapidity with which the soil particles settle
is proportional to their size. The suspension of a sample
of soil would therefore be the first step in mechanical
separation by water; the second step would be subsidence
and the withdrawal of each successive grade of particles
as it slowly settled; the third step would be determina-
tion of the percentage of each grade, or group, of particles

1Cushman, A. 8., and Hubbard, P. Air Elutriation of
Fine Powders. Jour. Amer. Chem. Soc., Vol. 29. No. 4, pp.
589-597. 1907.

THE SOIL PARTICLE

as based on the original sample. This is precisely what
every method of mechanical analysis in which water is
utilized aims to do, although often the apparatus and

technique are excessively complicated.
65. Mechanical analysis by water in
motion. Schone’s elutriator. — Any ap-
pliance that is designed to separate
particles of different sizes by water in
motion may be designated as an elutria-
tor. One of these, commonly used in
Europe, is called Schéne’s elutriator.'
This utilizes hydraulic force. In it the
upward current of water ascends a coni-
cal glass tube (see Fig. 11) from a
narrow curved inlet tube below. The
soil sample present in the inlet tube is
kept agitated by the current. It is evi-
dent that by regulating the rate of flow
of the water, different sizes of particles
will be carried away over the top of
this conical glass tube. Thus by a gentle
flow only fine grades will be separated,
while by increasing the current larger
and still larger particles will be carried
upward against the force of gravity.
There are three objections to this
method: first, the entrance tube may
become clogged, and, unless a very small

ax GS
*
eee SS ae

SENT

Se
SSS SSS SS SESE Ee
a

5 SS ee

LY LS

hak Tad

Fig. 11. —Schéne’s
elutriator for me-
chanical soil
analysis with
water in motion.

1Schéne, BE. Ueber Schlammanalyse. Bul. Soc. imperiale
des Naturalistes de Moscow, 40, Part 1, p. 324. 1867. Uber
Schlammanalyse und einen neuer Schlammapparat. Berlin,
1867. Also see Wiley, H. W. Agricultural Analysis, Vol. I,

pp. 231-241. Easton, Pa. 1906.

88 SOILS: PROPERTIES AND MANAGEMENT

quantity of soil is used, the mass is not kept properly
agitated ; secondly, convex currents are set up in the
conical glass tube, which vitiates the results; and, thirdly,
the separate particles tend to coalesce into granules. It
is evident that in any separation of soil particles all
granulation must be avoided. This is usually accom-

Fic. 12. — Hilgard’s churn
elutriator for mechanical
soil analysis of particles
above .01 mm.in diameter,
(e), Intake; (p), stirrer:
(c), sereen; (a), separating
chamber; (0), outlet tube.

plished by shaking or boiling the
sample previous to the determi-
nation. The tendency toward
granulation during the process
of separation itself is fatal to
accuracy, aS compound particles
carrying a large number of small
grains would fail to pass over
at water-current velocities cor-
responding to their component
parts.

66. Hilgard’s churn elutriator.
— The errors of the Schéne ap-
paratus are obviated to some
extent by Hilgard’s,' the prin-
ciple of operation remaining ex-
actly the same. In Hilgard’s
elutriator the deflocculated soil
sample is introduced into the
base of a cylindrical tube (see
Fig. 12) m which is placed a
rapidly revolving stirrer. This
is designed to counteract convex
currents and to prevent the

1 Hilgard, E. W. Methods of Physical and Chemical Soil
Analysis. Ann. Rept. California Agr. Exp. Sta., pp. 241-257.

1891-1892.

THE SOIL PARTICLE 89

formation of compound particles. A screen placed just
above the stirrer serves to prevent the whirling motion
from being communicated to the ascending column of
water in which the separation occurs. The various grades
in the separation are regulated by the rate of water flow.
With this apparatus it is necessary to remove the finer
particles below .01 mm. in diameter by subsidence
previous to the determination.

While this method is very nearly accurate and will
give a separation of the various grades such as is impossible
with most other methods, it is impracticable in ordinary
soil work. The large quantity of water which is used
in carrying over each grade, and which of course must
be evaporated before the sample can be weighed, is the
first objection. The length of time necessary for the
separation, and the cost of the apparatus, are two addi-
tional objections urged against it. As mechanical analysis
is used largely in determining soil texture, rapidity and
ease of operation are of more importance than the ex-
tremely accurate separation of the particles.

67. Yoder’s centrifugal elutriator.— One of the ob-
jections to the methods already described is the length
of time necessary for a determination. This is due to
the fact that very fine particles subside in water very
slowly. In order to hasten the separation, Yoder!
devised a machine in which hydraulic force may be
supplemented by a centrifugal pull. This imgenious
apparatus consists of an elutriator bottle (see Fig. 13)
mounted in a centrifuge. The muddy water is introduced
into the bottle at the center of the centrifuge. It then
passes to the bottom of the bottle and back again to the

1Yoder, P. A. A New Centrifugal Soil Elutriator. Utah
Agr. Exp. Sta., Bul. 89. 1904.

90 SOILS: PROPERTIES AND MANAGEMENT

outlet, carrying with it a sediment the size of which
depends on the rate of water flow and the strength of
the centrifugal force. The bottle is so designed that
particles in all parts of the separating chamber are sub-
jected to the same force, no matter what their distance

YEN im

CURNNARANSRAANSANNARRERN UCN

LLL US Nd,
Ww

Fic. 18. — Separatory bottle of Yoder’s centrifugal elutriator. (8B), Bottle ,
(e), intake; (a), tube for conducting liquid to bottom of separatory
bottle; (0), outlet; (C), centrifuge; (w), counterpoise.

from the center of the centrifuge may be. The apparatus
can be used only for separating particles less than .03
millimeter in diameter. It is open to the same objections
that apply to Hilgard’s machine, besides being very much
more complicated and delicately adjusted. It is too
costly an apparatus for ordinary work.

68. Mechanical analysis by water at rest. Osborne’s
beaker method. — One of the earliest and most nearly
accurate methods to be perfected was the separation of
the various grades of soil by simple subsidence in a column
of still water. This is commonly spoken of as the Os-
borne béaker method! The determination is very
simple. The soil sample is first fully deflocculated and
thrown into suspension, each particle functioning sepa-
rately. Beakers are commonly used as containers, but

1 Osborne, T.B. Methods of Mechanical Soil Analysis. Ann.
Rept. Connecticut Agr. Exp. Sta., 1886, pp. 141-158; 1887, pp.
144-162; 1888, pp. 154~-157.

THE SOIL PARTICLE 91

any vessel that is relatively deep will do for the deter-
mination. The larger particles, or sand grains, will of
course settle first, and the finer silts and clays may be
decanted off. As the sands carry finer particles down
with them, the suspension and subsidence must be re-
peated a number of times. The finer particles, separated
thus and decanted, may be further subdivided in the
same manner. ‘The time necessary for such decantation
as will leave in suspension only particles below a given
size is determined by the examination of a drop of the
suspension under a microscope fitted with an eyepiece
micrometer. In this way the size of the particles decanted
may be accurately measured.

The three steps in this method of separation are:
deflocculation of the sample; separation by successive
subsidence and decantation; and evaporation to dryness
of the separates and their calculation to a percentage
based on the original sample. The method, however, is
slow, as the time necessary for each subsidence of the
finer particles is very great and the number of individual
subsidences is large. Neither is the method capable of
the refinement of separation which is possible with cer-
tain of the elutriators. As a consequence it has been
superseded by methods that utilize centrifugal force for
the finer separations while retaining gravity for removing
the various grades of sand.

69. Atterberg’s modified Appiani’ silt cylinder (Fig.
14).— This method “is similar to the beaker method in

1 Appiani, G. Ueber einen Schliammapparat fiir die Analyse
der Boden- und Thonarten. Forsch. a. d. Gebiete d. Agri-
Physik, Band 17, Seite 291-297. 1894.

2 Atterberg, A. Die Mechanische Bodenanalyse und die
Klassifikation der Mineralbéden Schwedens. Internat. Mitt.
f. Bodenkunde, Band II, Heft 4, Seite 812-342. 1912.

92 SOILS: PROPERTIES AND MANAGEMENT

general principle, but a special apparatus is employed by
means of which the various grades obtained by sedimenta-
tion are siphoned off instead of decanted. The cylinder is
really a modified Wahnschaffe cylinder,’ such as was
used in early soil analyses for drawing off the various
suspensions except that the siphon is placed outside the
cylinder instead of inside.

The cylinder (die Schlammapparat)
as used by Atterberg is about 25 cen-
timeters high, with a glass pedestal
and a ground glass stopper. It is
graduated at 5, 10, 15, and 20 cen-
timeters upward from the bottom.
The same distance is divided also
into 16 divisions at the left of the
first graduation. The latter gradua-
tion is used in the separation of the
clay (Schlamm), so that the height
of the sedimenting column may be
regulated according to the time
available for the settling process.
An outside siphon, 4 to 5 milli
meters wide, is attached to the cylin-
der at the bottom for the drawing
Kia 14, — Atterbere’s of the liquid when the sedimenta-

silt cylinder for the tion is complete. The top of this

ot cod he wabslee siphon is opposite the 5-centimeter
mark on the cylinder. Cylinders

of this size are used only for the separation of particles
below .2 millimeter in diameter; for larger particles a
somewhat taller cylinder is used, with a siphon of the

1 Wiley, H.W. Agricultural Analysis, pp. 205-207. Easton,
Pa. 1906.

fyi

nuff

;

{

TUE SOIL PARTICLE 93

same width as for the finer particles. The graduation of
the cylinder and its diameter are the same as described
above.

A 20-gram sample of soil is used with this apparatus,
and deflocculation is brought about by means of a stiff
brush. The sample is reduced to a paste in a porcelain
dish, and then, by alternate working with the brush
and decanting, all the particles are thrown into separate
suspension. A deflocculating chemical is used in humus
soils, in order to hasten the process and counteract the
effect of the organic matter. As in the beaker method,
the size of the various grades of separation may be varied
according to the will of the operator.

70. Centrifugal soil analysis. —Of the centrifugal
methods used in mechanical analysis, that emploved by
the United States Bureau of Soils? is the most successful.
A 5-gram sample of well-pulverized soil is put into a
shaker bottle of about 250 cubic centimeters capacity
(see Fig. 15). This bottle is filled about two-thirds
full of water, so that in shaking the disintegrating force
of the liquid may be utilized. A few drops of ammonia
are added, to dissolve the organic matter and to make
deflocculation easier. The sample is then agitated in
the bottle until disintegration is complete. This period
ranges from five to twenty hours, depending on the
sample.

The separation of the silt and the clay from the sands
is made in the shaker bottle by simple subsidence, the
time for decantation being determined by a microscopic
examination of a drop of the suspension. The silt and

1Fletcher, C. C., and Bryan, H. Modifications of the
Method of Soil Analysis. U.S. D. A., Bur. Soils, Bul. 84.
1912.

94. SOILS: PROPERTIES AND MANAGEMENT

the clay are decanted directly into a test tube fitted into
a centrifuge (see Fig. 15). Whirling at the rate of 800 to
1000 revolutions a minute will cause the subsidence of
the silt to the bottom of the test tube in a few minutes.
The clay is then decanted. The microscope is necessary
here, in order to determine when the settling of the silt
is complete. As small particles tend to cling to the
larger particles, the entire operation must be repeated

ener Py) penta tland ed crete meek A
PILZ =e F 7 perpen
Vaden, CETTE ULL Ee a a a aa ae Se
CUeeee: enmamiapin

Pn eke Linck el eed chen Ld deed oN

Fig. 15.— Apparatus for centrifugal mechanical analysis of soil, show-
ing shaker bottle, shaker, centrifuge, and test tube.

several times; therefore the processes of gravity sub-
sidence and centrifugal subsidence are carried on side by
side, material being constantly poured from the shaker
bottle into the centrifuge tubes and from the test tubes
into the receptacles for the clay.

The centrifuge is usually large enough to allow the
separation of several duplicate samples at once. The
various separates made by this method are dried and

THE SOIL PARTICLE 8)

weighed. ‘The sands, which are obtained in bulk, are
further separated by sieves into the grades desired.
Where a large quantity of organic matter is present, it
must be determmed and included in the final report on
the sample.

This method of mechanical analysis as perfected by
the Bureau of Soils has been very generally adopted by
soil workers. It has many advantages over other methods.
In the first place, It is rapid, often requiring only hours
where other methods take days for completion; secondly,
it is simple, and the technique of the separation is easily
acquired; thirdly, m the decantations no very large
amount of water is accumulated with the separates,
except for the clay, and thus the time and cost of evapora-
tion is elimmated. The clay, moreover, may be as ac-
curately determined by difference as by direct methods,
thus allowing a further saving of time. The cost of the
equipment for this method is low. The apparatus itself
is simple, and is carried by all standard chemical com-
panies. The same cannot be said of the various elutriator
mechanisms. While the method is accurate only within
one per cent, it is sufficiently precise for practical pur-
poses, especially in class determination, for which me-
chanical analysis is generally utilized.

71. Classification of soil particles. — With the large
number of different methods of mechanical soil analyses
there has arisen a large variation in textural groupings
expressed in diameter of particles. This would naturally
occur because of the differences in degree of refinement
which the various methods of separation allow, and also
because of the uses which the investigators wished to
make of such analyses. Some of the best-known group-
ings are given below :—

96 SOILS: PROPEPTIES AND MANAGEMENT

Various TroxtTuRaAL CLASSIFICATIONS USED IN THO MumcHANtI-
caL ANALYSES OF Sorus. EXpRoSSED IN DIAMETER OF
Parricues In MILLIMETERS

Separato |; Ossporne! | Hineirp? BUREAU OF EneuisH! | Arrerpure 5
1 3.000 3.000 2.000 1.000 20.000
2 1.000 1.000 1.000 200 2.000
3 500 000 .000 040 200
4. 290 300 250 010 020
5 050 .160 .100 002 002
6 010 .120 .050
7 072 005
8 .047
) .036

10 025
11 .016
12 .010

Of these classifications only three need claim our atten-
tion — that of the Bureau of Soils, that of Hall and
Russell (the English classification), and that devised by
Atterberg. These represent the groupings used in ex-
pressing mechanical soil analyses in the United States,

1Qsborne, T. B. Methods of Mechanical Soil Analysis.
Ann. Rept. Connecticut Agr. Exp. Sta., 1886, pp. 141-158;
1887, pp. 144-162; 1888, pp. 154-157.

* Hilgard, E. W. Methods of Physical and Chemical Soil
Analysis. Ann. Rept. California Agr. Exp. Sta., 1891-1892,
pp. 241-257.

’ Briggs, L. J., and others. The Centrifugal Method of
Soil Analysis. U.S. D. A., Bur. Soils, Bul. 24. 1904.

4Hall, A. D., and Russell, E. J. Soil Surveys and Soil
Analyses. Jour. Agr. Science, Vol. IV, part 2, pp. 182~223.
1911.

5 Atterberg, A. Die Mechanische Bodenanalyse und die
Klassifikation der Mineralboden Schwedens. Internat. Mitt.
f. Bodenkunde, Band II, Heft 4, Seite 312-342. 1912.

THE SOIL PARTICLE 97

in England, and in Continental Europe, respectively.
As to which is the best for an interpretation and ex-
pression of textural qualities it is difficult to say. They
are all arbitrary, yet they are all extremely useful.
It therefore seems immaterial which one is employed.
It would be better, of course, if the classification were
uniform for all countries; correlation of soil properties
would then be easier.

72. Bureau of Soils classification. — As the grouping
established by the United States Bureau of Soils is met
with in all of our soil literature, and as it is really the
standard classification for this country, a closer considera-
tion of it may be profitable. The discussion of the
properties exhibited by the various separates, and of the
interpretation and value of a mechanical analysis, will
therefore be made with this classification as a basis. By
way of illustrating the grouping and the mode of ex-
pressing a mechanical analysis the results obtained from
two distinctly different soils are given below :—

MecuHanican ANALYSES! or A Dunkirk Fine Sanpy Loam
AND A DunxirK Cuay

SEPARATE Vee a as PINE BANDE Cay

% %

Fine gravel . 2. . 1. 2-1 1 1
Coarse sand. .... . 1-.5 2 2
Medium sand .... . 5-25 3 2
Fine sand .... . ./| .25-.10 22 6
Very finesand . . . . .|[ .10-.05 35 7
Silt wee ww ew we |) LQ5—.005 27 39
Clay . .. . . . . .| below .005 10 43

1 Soil Survey Field Book, pp. 152,154. U.S. D. A., Bur.
Soils. 1906.
H

98 SOILS: PROPERTIES AND MANAGEMENT

73. Physical character of the separates. —It is im-
mediately apparent that as these groups vary in size they
must exhibit properties, especially physical ones, which
are widely different. These properties should in turn
be imparted to the soil of which the separates form a
part. If we are conversant with these various values, a
mechanical analysis should reveal to us at a glance cer-
tain soil conditions which may or may not be conducive
to the best plant growth.

The clay particles are very minute; many of them are
so small as to be invisible under the ultramicroscope.
They are really shreds and fragments of minerals, and
are jagged and angular in outline. They are highly
plastic, and when rubbed together they become sticky
and impervious. They shrink much on drying, with the
absorption of considerable heat. On being wet again
they swell with the evolution of the heat already taken
up. Many of the particles exhibit the Brownian move-
ment and will remain in suspension for an indefinite
period. The finer part of the clay makes up a portion of
that indefinite group of material in the soil called colloids,
which because of their fineness of division (molecular
complexes) exhibit certain well-defined properties, of
which adsorption of moisture and salts in solution, and
high plasticity and cohesion, are the most important
from a soil standpoint. Silt exhibits the same qualities
as clay, but to a much less marked extent. The presence
of clay in a soil imparts to it a heavy texture, with a
tendency to slow water and air movement. Such a soil
is highly plastic, but becomes sticky when too wet and
hard and cloddy when too dry. The expansion and the
contraction on wetting and drying are very great. The
water-holding capacity of a clay soil is high.

THE SOIL PARTICLE 99

The sands and the gravel, because of their sizes, func-
tion as separate particles. They are irregular and rounded,
the continual rubbing that they have received being
sufficient to have effaced their angular character. They
exhibit very low plasticity and cohesion, and as a con-
sequence are little influenced by changes in water content.
Their water-holding capacity is low, and because of the
large size of the spaces between each separate particle
the passage of water is rapid. They therefore facilitate
drainage and encourage good air movement. In all
the grades of sand the separate particles are visible to
the naked eye, a condition impossible with the silt and
clay groups. Soil containing much sand or gravel,
therefore, is of an open character, possessing good
drainage and aération, and is usually in a loose friable
condition.

74. Mineralogical characteristics of the separates. —
From the mineralogical standpoint there are usually
considerable differences in the soil separates. These
differences would naturally be expected to occur par-
ticularly in residual soils, because of the differentiating
tendencies of weathering. Quartz would naturally per-
sist, and because of its slow solubility would very soon
make up most of the larger soil grains. Other minerals,
such as the feldspars, hornblende, augite, and the like,
being less persistent as the law of mineral resistance
has already taught us, would be worn to fine shreds
and be found as the main constituents of the silts
and the clays. The following data sustain this as-
sumption regarding the mineralogical characteristics of
some of the soil groups as designated by the Bureau of
Soils as well as furnish some interesting comparisons of
some important soil provinces :—

100 SOILS: PROPERTIES AND MANAGEMENT

GENERAL MINERALOGICAL COMPOSITION OF THE SANDS AND
Siuts oF Various Sort. Provinces or THe UNitEep Sratss }

pert sceerent etherresntymeinr rnin ANNhAI RE eis TTT sti Neetf Oneal eer pret errhp Set

MINERALS OTHDIR THAN

UARTZ IN
Sor snes °
Sands Silts
Residual. . . . . . 12 15% 21%
Glacial and loessial . 6 12% 15%
Marine ...... 4. 5% 8%
Arid . ee 3 37 % 42%

saeeimmmeeaaneeerecieataal apechaagmmeneen ona amma tasmmmenr animes mee amaairimmenn 2 acaueaameeeeananimanannameees

It is to be seen immediately that in every case the
silt carries a larger quantity of the important soil-forming
minerals and a smaller quantity of quartz than does the
sand. This reveals at least one of the reasons for the
greater fertility and lasting qualities of fine-textured soils
as far as agricultural operations are concerned. It is
important to note, however, that, although quartz is
the predominating mineral in sands, all the common
soil-forming minerals are usually accessory. This merely
serves to again emphasize the fact that all soils contain
all the common minerals found im soil-forming rocks.

It 1s also interesting to note the general differences
exhibited by the various soil provinces. The residual,
glacial, and coastal plain soils possess minerals other
than quartz in the order named. In the marine soils,
in particular, this difference has largely come about by
the disintegration and leaching that these soils have
undergone during their formation. The arid soils, due
to the suppression of chemical weathering and the activity

1 McCaughey, W. G., and William, H. F. The Microscopic
Determination of Soil-Forming Minerals. U. 8. D. A., Bur.
of Soils, Bul. 91. 1913.

THE SOIL PARTICLE 101

of the physical agents, exhibit smaller quantities of free
quartz. ‘The silica in such soils is held as complex sili-
cates, which very largely carry the elements that are so
important in plant development.

Although these data are based on but a few samples,
they are so concordant with what would naturally be
expected that these general conclusions cannot be avoided.

75. The chemical constitution of soil particles. — The
mineralogical examination of soils has revealed a larger
percentage of such minerals as feldspars, mica, horn-
blende, and the like, in the finer separates. A larger
percentage of the important plant-food elements would
therefore be expected in those groups. The following
data, compiled from work performed by the United
States Bureau of Soils, substantiate this assumption :—

CHEMICAL COMPOSITION OF Various Sor SEPARATES

Num-| PERCENTAGE or]; PERcDONTAGE OF |} PLRCENTAGE OF

a I
Soins N

PLUS |Sand/} Silt | Clay|/Sand! Silt | Clay||Sand| Silt | Clay

Crystalline residual 82 94
Limestone residual 12.26 |10.96| 9.92
Coastal plain 9} 655

1.281 1.30] 2.69
4.09] 9.221 8.03

Glacial and loessial
Arid soils

It is seen that on the average the soils with finer particles
are richer in phosphoric acid, potash, and lime, than
those of coarser texture, the only exception in this case
being in the lime of the residual limestone soils. The
arid soils present a less marked difference in the sands,

1Failyer, G. H., and others. The Mineral Composition
of Soil Particles. U.S. D. A., Bur. Soils, Bul. 54. 1908.

102 SOILS: PROPERTIES AND MANAGEMENT

silts, and clays than the representatives of the other
soil provinces; this is true also of the glacial soils, but
to a less degree. Under such conditions of weathering
the sands have not as yet been depleted of their stores
of essential elements. Average data compiled from a
number of soil analyses by Hall,! presented below, tend
to corroborate the data already noted and that obtained
by Loughridge? of California : —
Composition or Sor, SEPARATES

einem enacts | ceittiratemementnenene | inn, | Ena | ree | mgue eR

Coarse sand (1-.2 mm.) ./} 98.

9/16/12) 4] 6! 8 | .05
Fine sand (.2-.04 mm.) ./ 94.0) 2.0) 1.2] .5| .1 | 1.5) 1
Silt (04-01 mm.) . . ./ 89.4) 5.1/1.5] .8) 28) 2.3 | 1
Fine silt (.01-.002 mm.) . | 74.2 |18.2) 5.1/1.6 | 314.2] 2
Clay (Below .002 mm.) . | 58.2 (21.5 |18.2 {1.6 | 1.0 | 4.9 | .4

76. Value of a mechanical analysis. — It is now evi-
dent that the proper interpretation of a mechanical
analysis throws considerable light on the probable physical
and chemical properties of a soil. To the trained ob-
server the preponderance of sand or clay signifies certain
physical properties which may affect the plant not only
mechanically, but physiologically as well, through varia-

1Hali, A. D., and Russell, E. J. Soil Surveys and Soil
Analyses. Jour. Agr. Science, Vol. IV, Part 2, p. 199. 1911.
Also a Report of the Agriculture and Soils of Kent, Surrey, and
Sussex. Board of Agriculture and Fisheries. 1911.

* Loughridge, R. H. On the Distribution of Soil Ingredi-
ents among Sediments Obtained in Silt Analyses. Amer.
Jour. Sci., Vol. VII, p. 17. 1874.

In this connection see also Puchner, Dr. Uber die Ver-
tielung von Nabrstoffen in den Verschieden Feinen Bestandteilen
des Boden. Landw. Ver. Stat., Band 66, Seite 4638-470. 1907.

THE SOIL PARTICLE 103

tions in air and water movements. The chemical phases
of such an interpretation are also worthy of considera-
tion, as the proportion of the various separates determines
whether the essential plant-food elements will be present
in sufficient quantities to permit normal crop growth.
Thus in a general way the mechanical analysis of a soil
not only enlightens us as to the general properties of a
given soil, but is to some extent a criterion of agricultural
value and crop adaptation. Some authors! maintain
that in the investigation of any soil a mechanical analysis
should first be made, as such an analysis throws so much
light on the general qualities of a soil.

77. Soil class. — Class is a term used in relation to
the texture, or size of particles, of a soil. Class differs
from texture, however, in that it has reference rather to
the particular properties exhibited by a soil than to any
absolute grain size. As soils are not made up of particles
of the same size, a blanket term is needed which will not
only give an idea of the texture of the soil, but also name
it in such a manner as to reveal general peculiarities and
properties. We may have any number of classes, de-
pending on the sizes of the soil grains carried.

These class names have originated through long cen-
turies of agricultural operations, but of late they have
been more or less standardized because of the necessity
of a definite nomenclature. In general the names used
for the soil classes are the same as are used in mechanical
analyses to designate the soil separates. This is rather
unfortunate, but it obviates the increase of technical terms
and a little care will prevent confusion in this regard.

Another word introduced by common usage is loam.

1 Hall, A. D., and Russell, E. J. Soil Surveys and Soil
Analyses. Jour. Agr. Science, Vol. IV, Part 2, p. 199. 1911.

104 SOILS: PROPERTIES AND MANAGEMENT

Loam, from the technical standpoint, refers to a soil
possessing in about equal amounts the properties im-
parted by the various separates. If, however, we have
practically the same condition but with one size of particle
predominating, the name of that particular separate is
prefixed, giving still more data regarding the soil in
question. Thus a loam in which clay is dominant will
be classified as a clay loam. In the same way we may
have a sandy loam, a sandy clay loam, a gravelly sandy
clayey loam, and so on. The number of soil classes that
may occur is therefore rather large, ranging from coarse
eravel, through the various grades of sands, to silts and
clays.

A few of the common classes, with their mechanical
analyses, are listed below :—

MECHANICAL CoMmPosition or Various Sor. Cruasszs !

e a p

es 12) s/|28) 21 eels | 3

beaié|8is\2 8s alé
Coarse sands. . .| 185; 12 | 31 | 19 | 20 6; 7] §
Sands ... . .| 401) 2 {| 15 | 23 | 87 j 1il 7| 65
Fine sands . . .| 511] 1 4; 10 | 57 | 17 7 | 4
Sandy loams . . ./1141| 4) 18/ 12 | 25 | 18 | 21 | 12
Fine sandy loams .| 9384/ 1 3 4 | 32 | 24 | 24 | 12
Loams ... . .| 659} 2) 6§ 5 | 15 | 17 | 40; 16
Siltloams . . . .| 1268} 11 2 1 5 | 11) 65) 15
Sandy clays . . .| 162) 2 8 8 | 30 | 12 | 18 | 27
Clay loams . . ./ 718) 1 4} 4); 14} 13 |) 88 | 26
Silty clay loams . .| 765! Oj} 2 1 4) 71} 61) 25
Clays . . . . .{|4970) 1 3/ 2) 8!| 8 | 36) 42

' Whitney, M. The Use of Soils Hast of the Great Plains
Region. U.S. D. A., Bur. Soils, Bul. 78, p. 12. 1911.

THE SOIL PARTICLE 105

It is evident that a mechanical analysis of a soil is
nothing more or less than an expression of class, and
the inferences that may be derived from either are
the same. This leads to a consideration of class deter-
mination.

78. Determination of class.— The common method
of class determination is that employed in the field. It
consists In examination of the soil as to color, an estima-
tion of its humus content, and, especially, a testing of
the “feel” of the soil. Probably as much can be judged
as to the texture and class of a soil by merely rubbing it
between the thumb and the fingers as by any other
superficial method. This is a method used in all field
operations, especially in soil survey work. The accuracy
of the determination depends largely on experience.
Inaccuracies are likely to occur in distinguishing between
the various finer grades of soil; for this reason more
nearly exact methods are necessary at times, especially
in checking soil survey work or in carrying out investiga-
tions in which absolute accuracy is required.

As a mechanical analysis of a soil is really a percentage
expression of texture, it presents an exact method for
class determination. For detailed work somewhat com-
plicated tables! have been arranged; but the following
diagram (Fig. 16), devised by Whitney,” presents a simple
method for the identification of a soil from a mechanical
analysis. The convenience of this triangular representa-
tion may be tested by the use of the average analyses,
already presented on a previous page.

1Bur. of Soils, Soil Survey Field Book, p. 17, U.S. D. A,
Bur. Soils. 1906. Also, Bur. Soils, Bul. 78, p.12. 1911.

2Whitney, M. The Use of Soils Hast of the Great Plains
Region. U.S. D. A., Bur. Soils, Bul. 78, p.13. 1911.

106 SOILS: PROPERTIES AND MANAGEMENT

CLAY
JOT

SL7"
100 Ya

Fic. 16.— Diagram for the determination of soil class from a mechani-
eal analysis.

79. The significance of texture and class. — Soil
texture and class are the basis for all soil consideration,
whether regarding some specific property or a general
condition such as crop adaptation. No matter what the
phase of soil study may be, texture and class are sure
to have some important influence and must be included
in the investigation. From observations in practice,
certain crops have been found to be adapted to certain
kinds of soil—as clay loam for wheat, silt loam for
corn, loam or sandy loam for potatoes, clay or clay loam
for timothy, and so on. Two authors! have determined
the mechanical qualities of soils well adapted to certain
crops. An average of their analyses is given below: —

1Hall, A. D., and Russell, E. J. Soil Surveys and Soil
Analyses. Jour. Agr. Science, Vol. IV, Part 2, p. 207. 1911.

THE SOIL PARTICLE 107

Tar Mercuanicat ANALYSIS oF Sprciric Crop Soins

War BARLEY Por ato | Hop FRur
(9 samples) (9 samples) {8 samples) |(7 samples) (6 samples)
Fine gravel 1.4 1.2 BY) 1.2 1.0
Coarse sand 3.7 18.3 20.1 4.8 6.8
Fine sand . .| 24.5 32.0 43.5 33.8 42.0
Silt . . . .| 23.0 18.2, 11.0 28.8 23.3
Fine silt 12.8 8.0 6.4 8.7 7.3
Clay 20.0 11.9 9.7 12.1 10.9

The soil particle can thus be seen to function in no
insignificant manner regarding plant conditions. Its
size, its physical relationships, its chemical composition,
and the conditions imposed by a preponderance or a
limitation in its various grades, are of vital importance.
Soil texture and soil class, therefore, are terms of constant
usage in soil discussion and study, whether the viewpoint
is practical or purely theoretical.

CHAPTER VII
SOME PHYSICAL PROPERTIES OF THE SOIL

WHILE texture is of great importance in the determina-
tion of the physical and chemical nature of a soil, it is
evident that the arrangement of the particles also exerts
considerable influence. The term texture refers to the
size of the soil particles; the term structure is used in
reference to their arrangement, or grouping. It is at
once apparent that certain conditions — such, for ex-
ample, as air and water movement, heat transference,
and the like — will be as much affected by structure
as by texture. As a matter of fact, the great changes
wrought by the farmer in making his soil better suited
as a foothold for plants are structural changes rather
than changes in texture. The compacting of a light
soil or the loosening of a heavy soil is merely a change
in arrangement. of the soil grains. It is of interest, there-
fore, to ascertain the probable arrangement of the particles
in any soil.

80. Arrangement of soil particles (Fig. 17).— In any
consideration it is the easier way to advance from the
simple to the complex. Therefore in the explanation of
structural relationships a theoretical condition will be dealt
with first, after which the discussion will proceed to the
intricate condition existing in the soil. Assuming that
this theoretical condition consists in spherical particles
all of the same size, we find these particles susceptible

108

SOME PHYSICAL PROPERTIES OF THE SOIL 109

to two different arrangements: (1) in columnar order,
with each particle touched in four points by its neighbors ;
and (2) the oblique, in which each particle is in contact
with six of its neighbors. The possible pore space in
the first case is 47.64 per cent, while that in the second
case is 25.95 per cent. The amount of this pore space
is uninfluenced by the size of the particles, provided they
are round and all of the same volume.

Fig 17 —Ideal arrangements of spherical particles, showing, from left
to nght, columnar, oblique, compact, and granular orders.

To any one of practical experience it is a well-known
fact that the soil particles are not homogeneous as to
size, and neither do all the particles function as simple
grains, being gathered together in groups called granules,
or crumbs. A small particle of soil may be made up of
a number of very small grains. This will modify the
ideal condition as described above, giving two additional
conditions — first, a mixture of spherical grains of differ-
ent sizes, and, secondly, a condition in which the large
grains are complexes made up of numerous small particles.
A mixture such as is presented by the first of these con-
ditions, in which the small grains fit in between the
larger ones, will result in a reduction of pore space. The
pore space will fall below 25.95 per cent and approach
zero. A real soil having such restricted pore space is

110 SOILS. PROPERTIES AND MANAGEMENT

designated as being in a puddled condition. This con-
dition is detrimental to plant growth, for it not only
impedes root development and extension, but also pre-
vents the circulation of air and water, a function necessary
for proper soil sanitation. In the second condition an
increase in pore space must occur, as each large grain
presents considerable internal air space. If the granules
as well as their component particles were arranged in
columnar order, the pore space would reach the high
percentage of 72.58. Under natural conditions, then,
the pore space might range from zero plus to about 72
per cent.

However, not only are the particles of a normal soil
not of the same size, but they are far from round. A
soil, as already demonstrated, ordinarily presents varying
amounts of particles, ranging in size from stone and
coarse gravel to the very finest clay. These particles
may also differ in shape, varying from almost perfect
spheres to flakes, chips, and fragments of every con-
ceivable form. Therefore the laws that apply to the
ideal condition will hold only in a general way in a normal
soul. It is evident, first, that the more compact the
soul, the less is the pore space; secondly, that it is possible
to so manipulate a soil as to work the small particles in
between the larger ones and create an impervious or
puddled condition; and, thirdly, that by the forming
of granules the pore space of a soil may be increased to
a high percentage.

From the standpoint of size and arrangement of particles
there are really two classes of soils, those of single grain
structure and those that are granular. In the former
each particle functions separately. In order to do this
the particles must be large. This condition is found in

SOME PHYSICAL PROPERTIES OF THE sort 111

sand. In such soil would naturally be found also a
medium to low pore space, just as has been exemplified
in the ideal condition described above. In granular
soils, the granules, being made up of small particles,
present much internal pore space. This condition occurs
only in fine soils, such as loams, silts, and clays, since
large particles will not cohere firmly enough to produce
a crumb structure. A fine-textured soil, which will
puddle more readily than a coarser one, is thus saved
from a semi-impervious condition by this tendency toward
granulation.

The ideal soil condition might be considered to be most
likely to occur in a loam (Fig. 18) In loamy soil some
of the particles are large and
function separately; others are
medium in size and tend to form
the nuclei around which smaller
particles may cluster to form
granules, or crumbs. ‘There are
thus a few large pore spaces
which facilitate drainage, and ws ,
numberless small openings in Fig 18 — The arrange-
which water is retained. Air ™entofparticlesinloamy

soul of good structural
therefore finds easy movement condition (a) Large
and sanitation is promoted. In stanule, (6), small sand
ie . particle, (c), large pore
such a condition the organic mat- _gpace, (d), small granules
ter plays an important part. wth sma elgaier
This exists usually as dark, par- grain
tially decayed material. It pushes
apart the grains and lightens the soil, and contributes
much in bringing about the loamy condition so favorable
to plant development. Because of its water-holding
capacity also it proves a valuable addition. Thus with

112 SOILS: PROPERTIES AND MANAGEMENT

particles of varying sizes, of a structure partly single-
grain and partly granular, to which has been added by
natural means sufficient organic matter in an advanced
stage of decomposition, we have the ideal soil conditions
for plant development. Yet the same laws govern here
in a general way as were found to function with homo-
geneous grains of spherical shape.

81. The absolute specific gravity of the soil. — The
structural condition of any soil, be it single-grain, granular,
or a favorable combination of the two, has considerable
influence on certain other physical conditions. One of
those most affected is the weight. The weight of a soil
is determined by two factors: the weight of the individ-
ual particles, or the absolute specific gravity; and the
amount of actual space taken up by such particles in any
given volume. The latter is really a structural condition
and is independent to some extent of the size of particles.
The absolute specific gravity, or weight compared with
an equal volume of water, of some of the common minerals
is as follows: —

Quartz . . . . 2.7 Apatite . . . 3.2
Orthoclase . . 2.6 Gypsum . . . 2.3
Plagioclase . . 2.7 Hematite . . 5.2
Mica ... . 80 #£Limonite. . . 4.0
Olivine . . . . 34 Serpentine . . 2.6
Calcite . . . . 2.7 Chilorite . . . 22
Dolomite . . . 2.9 Tale . . . . 2.7

Although a great range is observed in the absolute
specific gravities of these common soil-forming minerals,
it must be remembered that such minerals as quartz
and feldspar usually make up the bulk of a soil. As a
consequence it has been found that the absolute specific

SOME PHYSICAL PROPERTIES OF THE sorz 118

gravity of a purely mineral soil varies only between
narrow limits, these being from 2.6 to 2.8. Nor has
fineness any appreciable effect, as shown below by Whit-
ney’s determinations on the various separates : —

SPerociric GRAVITY

Fine gravel (2-1 mm.). . . . . . . 2.647
Coarse sand (l—5mm.) . .. . . . 2.655
Medium sand (.5-.25mm.) . . . . . 2.648
Fine sand (.25-.10mm.) . . . . . .) 2.659
Very fine sand (.10-.05 mm. ) . . . . 2.680
Silt (.05-.005 mm.). . . . . . « 2,698
Clay (below 005mm.) . . . . . . 2.887

The only marked variation here observed is in the clay
separate, and this may be due to the concentration of the
iron-bearing silicates in this grade. However, for all
practical purposes the average absolute specific gravity
of a mineral soil may be placed at about 2.70. One
condition that may vary this is the quantity of organic
matter present. As the specific gravity of the soil humus
usually ranges from 1.2 to 1.7, the more humus there is
present, the lower will be the absolute figure for a given
soil. A purely organic soil, such as muck or peat, pre-
sents a variable absolute specific gravity ranging from
1.5 to 2.0, according to the amount of wash it has received
from external sources. Some humus-loam soils may
drop as low as 2.1. Nevertheless for general calculations
the average arable soil may be considered to have an
absolute specific gravity of about 2.70.

82. Apparent specific gravity. — Since all soils contain
more or less pore space, depending on textural and struc-

1 Whitney, M. Some Physical Properties of Soils. U. 8,
D. A., Weather Bur., Bul. 4, p. 34. 1892

114 SOILS: PROPERTIES AND MANAGEMENT

tural conditions, the actual weight of the absolutely dry
soil in any volume is of great importance. This is ex-
pressed as is the absolute specific gravity of any material,
the weight of an equal volume of water being used as a
unit. Because of their tendency to granulate, fine soils
have a very large amount of pore space, as has been shown
in the discussion of structure; it is to be expected, there-
fore, that they will weigh less in any particular volume
than will soils made up of large particles. Coarse soils
are heavy soils, as far as weight is concerned. Mineral
soils may range in apparent specific gravity’ from 1.10
to 1.20 for clay to 1.65 to 1.75 for sand. Humous loams
may drop as low as 1.00, and muck often reaches the
low figure of .40. The appar-
ent specific gravity is always
expressed on the basis of abso-
lutely dry soil.

In the field the absolute
specific gravity of a soil may
be determined by driving a
cylinder of known volume into
the ground and_ obtaining
thereby a core of natural soil
(see Fig. 19). By weighing
the soil and then determining
Fie. 19. Cylinder for deter- the amount of water that it

mining the apparent specific holds, the amount of absolutely

The cutting edge at (@) is GY Soil may be ascertained.

drawn in somewhat to pre- Dividing this by the weight

vent excessive friction be- of an equal volume of water

tween the sides of the ecylin- . op
der and the entering soil core. gives the apparent specific

1See Whitney, M. Some Physical Properties of Soils.
U. 8. D. A., Weather Bur., Bul. 4. 1892.

SOME PHYSICAL PROPERTIES OF THE SoIt 115

gravity for that soil. A laboratory determination may be
made by putting the soil into a receptacle of known volume
and weighing it. From the weight of the absolutely
dry soil and the weight of an equal volume of water, the ap-
parent specific gravity may be calculated. This method
will give only approximate results, however, as the struc-
tural relationships are more or less artificial. The only
reliable method is the one first described.

83. Actual weight of a soil.— With the apparent
specific gravity of a soil known, its weight in pounds to
the cubic foot may be found by multiplying by 62.42.
Soils may vary in weight from 68 to 80 pounds for clays
and silts to 100 to 110 pounds for sand. The greater the
humus content, the less is this weight to the cubic foot.
A muck soil often weighs as little as 25 or 30 pounds.
This weight, of course, is for absolutely dry soil and does
not include the water present, which may be much or
little, according to circumstances. The actual weight
of a soil is often expressed in acre-feet. An acre-foot of
soil refers to a volume of soil one acre in extent and one
foot deep. In the same way we may have an acre-eight-
inches or an acre-six-inches. The weight of an acre-foot
of soil usually varies from 3,500,000 to 4,000,000 pounds ;
granulation and organic matter may modify this con-
siderably. The value of knowing the actual weight of
a soil lies in the possibility of calculating thereby the
amount of water, the amount of humus, or the actual
number of pounds of the mineral constituents present in
the soil. Such information affords a ready means of
comparing two soils as to their crop-producing capabilities.

84. Pore space in soil. — The pore space in soil is
due largely to structural conditions. As already em-
phasized, the coarser the soil, the smaller is the aggregate

116 SOILS: PROPERTIES AND MANAGEMENT

amount of internal space. Each individual space is
larger under such conditions, and this accounts for the
ready movement of water and air through such soils.
A clay soil, while containing a very large amount of pore
space, has the disadvantage of very minute individual
pores. The large amount of space occurs because of
the lightness of the particles and the tendency toward
granulation. The small size of the individual spaces
is a direct function of size of particle, or texture.

A very simple formula may be used for a determination
of the percentage of pore space in any soil, provided the
absolute and the apparent specific gravity is known :—

Ap. Sp. Gr, a

Percentage of pore space = 100 ~ Ab. Sp.Gr. 1

Thus a soil having an apparent specific gravity of 1.60
and an absolute specific gravity of 2.60 has 38.5 per cent
of pore space; while in a soil in which the above figures
are 1.10 and 2.50, respectively, the percentage of pore
space is 56. The following figures, taken from King,
illustrate the relation that texture holds to total pore
space in soils : — PERCENTAGE OF

Pore Space

Sandy sol . . . 2... . . . 82.49
Loam. ....... . . . 8449
Heavy loam ....... . 4415
Loamy clay sol . .... . . 45.32
Clayey loam ....... . 47.10
Clay . 2... 2... 648.00
Very fneclay . . . . .. . . 52.94

1King, ¥. H. Physies of Agriculture, p. 124. Published
by the author, Madison, Wisconsin. 1910,

SOME PHYSICAL PROPERTIES OF THE SOIL 117

The pore space in any of these soils is, of course, subject
to considerable fluctuation, especially in the surface
soil, due to tillage and the incorporation of organic matter ;
hence a sandy loam might under certain conditions present
more pore space than a silt or a clay loam. When soils
are in the physical condition for the best plant growth,
however, the rule holds that, the finer the soil, the greater
is the pore space. The differences in pore space between
the surface soil and the subsoil in Wisconsin are shown
by King?! as follows: —

WHIGHT PER PERCENTAGE OF

Cusic Foor Pore Space
First foot . .... 79.0 52.2
Second foot . . .. . 92.6 44.0
Third foot ..... 104.6 36.8
Fourth foot . . . . . 106.2 35.8
Fifth foot . . .. . 111.0 32.9

Sixth foot . . .. . 111.1 32.8

The pore space in a normal soil is occupied by water
and air. If the water content is low, the air space is
large, and vice versa. Thus the relationships of the total
pore space and the size of the individual spaces to the
amount of air and water contained, to their movement
through the soil, to soil sanitation, to root extension, to
bacterial action, and to cropping conditions in general,
become apparent. It is the regulation of this pore space
that is really studied in any structural consideration.
The effect on plant growth of a change in pore space 1s
the final test of its advisability.

1 King, F. H. Physics of Agriculture, p. 111. Published
by the author, Madison, Wisconsin. 1910.

118 SOILS: PROPERTIES AND MANAGEMENT

85. The number of soil particles. — The number of
particles in any given volume of soil is really determined
by texture, and, as this number determines very largely
the probable arrangement of the soil grains, structure
becomes in turn dependent on the size of grain. Since
soil particles run to very small diameters, the number
in any given volume is very large, especially when we
are dealing with fine-textured soils or with soils of com-
pact structural condition. Any calculation of the number
of particles present in a soil is open to considerable in-
accuracy, first, because it is impossible to get a correct
figure for the average diameter of the particles of any
soil or of the various groups of separates that go to make
it up, and, secondly, because it must be assumed in the
calculation that the particles are spherical. This assump-
tion is of course incorrect, as has already been demon-
strated; but it must be entertained in order to obtain
approximate ideas as to the number of grains in any soil.

The number of particles in any soil sample may be
arrived at from a mechanical analysis and the diameters
that limit each group. Using the average diameter of
each group together with the percentage of the groups
in a given sample, the number of particles may be cal-
culated by the following formula : —

Number of particles ina Weight of sample in grams

sample of soil 1/6 a D® X 2.70

The formula 1/6 7 D® is that used for determining the
volume of a sphere, the diameter in this case being ex-
pressed in centimeters. The volume of the sphere, then,
is obtained in cubic centimeters, which must be multiplied
by the absolute specific gravity of soil minerals, or 2.70,

SOME PHYSICAL PROPERTIES OF THE SOIL 119

in order that the weight in grams of a single soil grain
may be obtained. A calculation by this method of the
number of particles in a sandy loam is given below : —

zs i b “ APPROXIMATE
SEPARATES Limits NUMBER wie FARTI- 5s n Z Pantiouns IN ONE
or Hack SnpaRats ann Gram or Sanpy
ee (
Fine grav-
el . .| 2-1 mm. 209 I 2
Coarse
sand .|1~-.5 mm. 1,670 4 67
Medium
sand . | .56-.25 mm. 13,410} 25 3,092
Fine
sand ./ .25-.10 mm. 131,900) 35 46,165
Very fine
sand .10-.05 mim. 1,676,500; 20 335,300
Silt . .| 05-.005 mm. 30,934,000) 10 3,993,400
Clay . below .005 mm | 45,632,000,000 5 2,291,600,000
2,285,018,290

A very great error is introduced by this method, es-
pecially in assuming that the average size of particles
for the clay separate is .0025 millimeter. As the clay
particles may become molecular complexes and conse-
quently are very, very small, it stands to reason that
such an assumption is far"from correct. Nevertheless,
it gives a very good idea as to the immense number of
grains that we have to deal with, even in the coarsest of
soils. A few figures as to the approximate number of
particles in various average soil classes of the United
States! as reported by the Bureau of Soils, are given
below : —

1 For mechanical analysis of the classes, see Chapter VI, p. 104.

120 SOILS: PROPERTIES AND MANAGEMENT

APPROXIMATE NUMBER OF PARTICLES TO THE GRAM IN
Various Crasses oF Soin IN THE Unitep SIATES

APPROXIMATE NUMBER oF

Cass PARTICLES
Coarse sands. . . te ee 2,299,145,360
Sands . . . . 0.0. ee ee 2,287,251 ,842
Fine sands ... . .. .. .. 1,826,176,893
Sandy loams we ee ee ke 5,483,797,920
Fine sandy loams ....... . 5,485,069,147
Loams . . . . . 0. eee es 7 ,332,679,042
Silt loams. . . . 0.0. ee ele 6,868,546,664
Sandy clays . . . . . . . . =. . 12,324,914,033
Clay loams . ....... 2... 11,877,875,092
Silty clay loams ........ 11,430,037,544
ClayS . 2.0. 6 ee ee ee 19,177,571,994

tnt

86. Surface exposed by soil particles. — Besides giving
an actual numerical figure and an insight into the prob-
able structural relationships of a soil, the approximate
number of particles may serve still another purpose —
that of enabling us to calculate the aggregate internal
surface exposed by the soil grains. The surfaces of the
grains hold more or less water according to their area,
and they increase the amount of chemical and biological
activities — functions so necessary to a continuous re-
placement in the soil solution of the elements withdrawn
by the plant. The minerals in the soil are all very re-
sistant to solution; if they were not, they would long
ago have been leached away. Such materials, while
almost insoluble, allow the amount of material going
into solution to be notably increased by fineness of tex-
ture, although their solubility remains the same. The
fineness of the particles, then, presents another significant
feature besides those already pointed out.

SOME PHYSICAL PROPERTIES OF THE SOIL 121

Another important property of the surface of the
grains is the tendency toward the retention of soluble
material in a partially or wholly available condition for
plant use. This power, designated as adsorption, is
one exhibited to a high degree by fine soils, in which
the individual pore spaces are small and the amount of
surface exposed is large. It is an important factor to
be observed in the addition to the soil of soluble fertilizing
constituents. Adsorption may also, by bringing materials
into closer contact, hasten or retard certain chemical
actions. Reactions may thus be expected to go on in the
soil that would not take place in the laboratory beaker.
The relation of this adsorption to bacterial activity also
cannot be overlooked.

The aggregate area presented by soil particles is very
large, even for the coarser soils. With the finer soils,
because of the immense number of particles, a figure is
reached that is almost beyond comprehension. When
the approximate number of particles and their sizes
in any given weight of soil are known, the internal surface
may be calculated by the following formula : —

Surface = 7D? X number of particles

As the estimation of the number of particles in a soil is
so inaccurate, it is evident that a calculation of the
surface exposed based on such a figure must be more in
error.

However, to give some idea of the internal surface ex-
posed by ordinary soils, the calculations made on a few of
the average soil classes of the United States, already
presented,! are given in the table on the following page.

1See Chapter VI, p. 104.

122 SOILS: PROPERTIES AND MANAGEMENT

APPROXIMATE INTERNAL AREA EXPOSED BY AVERAGE CLASSES
or Unitrp Starrs SoILs

Seuarn INcHES SQuane Fort AGGRES PE ae
PER GRAM PER FOUND 13,500,000 Pounps

Coarse sands... . 91 286 23,055

Sands ..... . 89 280 22,549
Fine sands ... . 79 248 20,014
Sandy loams . .. . 213 671 53,965
Fine sandy loams . . 222 699 56,180
Loams . .... . 294 926 74,410
Silt loams. . .. . 307 967 77,700
Sandy clays ... . A17 1313 105,540
Clay loams ... . 430 1354 108,830
Silty clay loams . . . 458 1442 115,910
Clays ..... . 653 2057 165,270

It is at once apparent that the amount of surface
exposed by the soil grains of even a sand is tremendous.
It is not to be wondered at that the slowly soluble minerals
are able to supply sufficient food to the crop growing on
the soil, when such a large amount of surface is continually
available for chemical action. The figures presented for
an acre-foot of soil are almost too large for adequate com-
prehension. It is quite evident that the finer the soil,
the greater is the amount of internal surface. For ex-
ample, a sandy loam weighing 90 pounds to the cubic
foot would present 60,390 square feet of surface, while
a clay weighing 75 pounds to the cubic foot would expose
about 154,275 square feet. This is equivalent to 1.39
and 3.54 acres, respectively.

87. The effective mean diameter of soil particles. —
It is very evident that the calculations presented above,
both as to the number of particles and as to the internal

SOME PHYSICAL PROPERTIES OF THE SOIL 128

surface exposed, are far from correct, as we can arrive
at no definite figure as to the average size of grain. Neither
do we know the actual structural conditions. In con-
sidering these maccuracies King! decided that we were
in need of a single term which not only would give an
indication regarding the size of grain, but also would
carry with it definite ideas as to the arrangement of the
particles, particularly as to the rate at which they would
allow air and water to pass through. This would bring
the considerations nearer to the plant, as permeability
very largely determines the conditions for plant develop-
ment. King, while he could obtain neither the mean
diameter of particle nor the actual internal surface, found
that he could determine with considerable accuracy,
particularly in sands, the diameter of grain which if sub-
stituted for the actual one would permit under like con-
ditions the same rate of air and water movement. This
size of grain he designated as the effective mean diameter
of particle for that particular soil.

The theory of the method is presented by Schlicter,?
and is based on the flow of fluids through capillary tubes.
From the observed rate of the flow of air through a soil
column under controlled conditions, it is possible to
calculate the effective diameter of the interstitial spaces.
From these data the size of the spherical grains which
would be necessary to form such pore spaces, or capillary
tubes, is computed by appropriate formule. Such a
figure represents the effective mean diameter of the soil,

1King, F. H. Physics of Agriculture, pp. 119-120. Pub-
lished by the author, Madison, Wisconsin 1910.

2Schlicter, C. 8. Theoretical Investigation of the Move-
ment of Ground Waters. U.S. Geol. Survey, 19th Ann. Rept.,
Part II, pp. 301-384. 1899.

124 SOILS: PROPERTIES AND MANAGEMENT

from which the effective surface exposed can be deter-
mined. Thus, designating a soil as having an effective
mean diameter of particle of .0052 millimeter merely
indicates that this particular soil shows an air and
water movement the same as would be shown by a
homogeneous soil with spherical particles of that diameter.

The apparatus! for the de-
termination consists of a cylin-
der in which is placed a sample
of air-dry soil, the pore space
being carefully determined by
weighing. The rate of air
movement is then determined
by connecting with an aspi-
rator, the temperature and
the pressure being constantly
under control. The reading is
usually calculated to a tem-
perature of 20°C. The fact
that the structural condition
of the soil is likely to be dis-
turbed in placing the sample
in the aspirator tube detracts
from the accuracy, especially
in fine soils. Nevertheless,
Fig 20 Kings suitor for King found his results fairly

of air movement through accurate, and showed that

soils. (@), Pressure gauge; the calculated and the ob-

(S), soil column; (Z), water ;
(A), aspirator; (W), weight. Served flow of water through

1 King, F. H. Principles and Conditions of the Movements
of Ground Water. U.S. Geol. Survey, 19th Ann. Rept., Part
II, pp. 222-224. 1899. A complete discussion is given of
King’s ideas in this article, pp. 67-294.

SOME PHYSICAL PROPERTIES OF THE SOIL 125

sands ! agreed rather closely (see Fig. 20). The effective
diameter of the particles of some of our common soils, to-
gether with the effective surface exposed, is given
below : 7 —

ErFEectivE Sur-

So Bymmemive op bom | [AcE EXPOSED Ts
oF Soru

Coarse sandy soil . .| .1432 mm. 34.9 8,318 sq. ft.
Sandy soil. . . . .| .0755 mm. 34.4 15,870 sq. ft.
Sandy loam . . . .| .0303 mm. 38.8 36,880 sq. ft.
Loam ... . . .| 0219 mm. 44.1 46,510 sq. ft.
Loamy clay soil . . .j| -0140 mm. 45.3 71,316 sq. ft.
Fine clay soil. . . .| .0086 mm. 48.0 110,500 sq. ft.
Very fine clay . . .| .0049 mm. 52.9 173,700 sq. ft.

The method of King has certain advantages, besides
giving an idea as to the number of particles, their internal
surface, and the relation of this internal surface to soil
conditions. In the first place, a single figure is used
to express the size of particle; secondly, from this effec-
tive size of particle the probable rate of air and water
movement may be calculated; and, thirdly, the number
of particles and the internal surface calculated therefrom
have a fairly definite relationship to the plant, as such
figures are so closely correlated to the circulation of air
and water.

1 King, F. H. Physics of Agriculture, p. 123. Published
by the author, Madison, Wisconsin. 1910.
2Tbid., p. 124.

CHAPTER VIII
THE ORGANIC MATTER OF THE SOIL

One of the essential differences between a soil and a
mass of rock fragments lies in the organic content of the
former. Organic matter is a necessary constituent in
order that finely ground mineral material may be desig-
nated as a soil and that it may grow crops successfully.
Physical condition depends largely on the presence,
and chemical reaction is greatly accelerated by the de-
cay, of organic matter. In the process of soil formation
its addition is more or less a secondary step. In residual
débris the amount of organic matter held by the growing
soil increases as the process of weathering goes on; in
glacial soils, however, the matrix, or skeleton of the soil,
is already formed before there is an opportunity for humus
to become incorporated therein. The final result from
the mixing of the minerals carrying numerous weathered
and altered products with the decayed or partially de-
cayed organic matter that is sure to accumulate, must
be a mass much more complicated than either of the
original constituents. It is hardly necessary to further
emphasize the complexity of the average soil, the reasons
therefor, and the difficulties in studying the question.

88. The source and distribution of organic matter. —
The source of practically all soil organic matter is plant
tissue. Some of this matter accumulates from the above-

ground parts of plants that have died and fallen down
126

THE ORGANIC MATTER OF THE SOIL 127

to become mixed with the surface soil; the remainder
is a result of root extension and subsequent decay. The
organic matter of the surface soil is derived from the
tops and the roots of plants growing on it, while that of
the subsoil is very largely a result of root extension and
subsequent decomposition. The relationship between the
humus content of three soils and the roots developed is
shown by the following data presented by Kostytscheff !
and quoted by Hilgard ? and Wollny *:—

Root Content aNd PgerRcentTaapn or Humus In THREE
Ruvusstan SOIns

1 2 3
(rekon) Roots Humvus Roors Honus Roors Humus

6 100 5.4 100 8.1 100 96
12 89 4.8 64. 5.2 80 7.7
18 67 3.6 48 3.9 70 6.7
24. 47 2.5 35 2.8 58 5.6
30 47 2.5 26 2.1 38 3.6
36 35 1.8 18 1.5 33 3.1
42 24. 1.3 6 5 16 1.5
48 14 8
54. 7 3

Saad

89. Composition of plants. — It is usual, in classifying
the materials composing plant tissue, to group them under
three heads — carbohydrates, fats and oils, and proteins.

1 Kostytscheff, M.P. Les Terres Noires de Russie. Annales
de la Sci. Agron., Tome II, pp. 165-191. 1887.

2 Hilgard, EH. W. Soils, p. 180. New York 1906.

’Wollny, E. Die Zersetzung der Organischen Stoffe, p. 194.
Heidelberg. 1897.

128 SOILS: PROPERTIES AND MANAGEMENT

The carbohydrates, having the general formula of
C,(H.0),, include such compounds as glucose, starch,
cellulose, dextrose, cane sugar, and the like. The fats
and oils may be represented in plants by such glycerides
as butyrin, stearin, olein, palmitin, and the like. The
proteins are by far the most complicated of the three
principal compounds, as they may carry not only carbon,
hydrogen, oxygen, and nitrogen, but also mineral elements
such as sulfur, phosphorus, lime, iron, and other elements.
They are compounds of high molecular weight and are
mostly of unknown constitution. Simple proteins, such
as albumin, globulin, protamins, and others, are found
in plants, besides certain derived proteins such as
proteosis and peptones. In addition to all these, there
is a host of other compounds that have no small influence
on the composition of the soil organic matter. Among
these are the alkaloids, waxes, tannins, phenols and their
derivatives, hydrocarbons, resins, acids, aldehydes, and
others.

The original plant tissue, therefore, while fairly well
known, as to chemical constitution, is far from simple.
The degradation of such material, especially in the pres-
ence of complex mineral products, will evidently give rise
at first to compounds no simpler; in fact, the chances
are that the resulting compounds will be much more com-
plicated. It is only later in the processes of decay that
simple products result.

90. Decay of organic matter in soils. — From the fact
that weathering in general is a process of simplification,
and since it is evident that the plant tissue as it enters
the soil is so very complex, the general change that the
organic matter undergoes must be one of simplification.
This simplification, however, is very slow, and many of

THE ORGANIC MATTER OF THE SOIL 129

the products built up are more complex than the original
tissue. Most of this decay and simplification is due to
that great group of organisms so universally present in
soil, called bacteria. Some of these are putrefactive in
their action, while others deal to a large extent with the
products of the decomposition. All, however, exert a
general simplifying influence. The action of such or-
ganisms may be direct, but is more likely to be enzymotic
in its nature, and may take place either within or outside
of the cell. A cycle is therefore set up, in which the higher
plants and animals are occupied in building up, while
bacteria are tearing down and reducing the residue of
plant action to simple forms, such as can be ultimately
utilized again in plant nutrition. The great importance
of bacteria is thus evident, and the encouragement of
their growth and function is clearly a part of good soil
management.

‘When the complex molecules that make up plant
tissue break down, they split along definite lines of cleav-
age, depending on the structure of the original molecule.
These bodies, which are usually stmpler in nature than
those from which they have sprung, are called cleavage
products, and without a doubt they are the primary
products of the first step in organic decay. These com-
pounds are subject to still further change, and because
of the great number of agencies at work the secondary
products that result may be simpler or more complex,
according to conditions. Bacteria have a tendency,
while tearing down organic matter, to construct certain
built-up products which present a very complicated
molecule until they are in turn degraded. The secondary
products therefore vary widely because of differences in
temperature, moisture, aération, and other conditions,

130 SOILS: PROPERTIES AND MANAGEMENT

The character of the secondary products probably ex-
hibits a greater variation than does that of the original
plant tissue. In the process of decay these products
become black or brown in color, and are usually designated
as humous materials in the soil. Organic matter, then,
covers all the material of organic origin in the soil, and
may refer not only to the original plant tissue, but also
to that which has lost its identity in the secondary prod-
ucts. Humus refers specifically to the primary and the
secondary products of decay, and may be simple or com-
plex, according to conditions.

As the process of decay goes on, certain end products
result. These are partially solid and partially gaseous.
Carbon dioxide is a universal product of bacterial activity
of all kinds, as is also water. Besides these, urea, am-
monia, nitrites, and nitrates may result from nitrogenous
decay. The three general classes of organic matter found
in soil may be illustrated by the following diagram : —

PLANT TISSUE HUMUS END PRODUCTS

UNDECOMPOSED MATTER § SICONDARY AND INTERMEDIATE SIMPLE MATDRIAL

Fig. 21.— Diagram illustrating the three general classes of organic
matter found in soils.

It is therefore possible to have present, besides the
original organic constituents which are mostly of plant
origin, not only their primary and secondary degradation
products, but also compounds either torn down or built
up from these. An attempt to enumerate even the
original compounds in the plant tissue, or even the simple
end products of complete decay, would result in a long
list of materials representing almost every known class
of organic compound. Such a procedure is possible,
but is unnecessary as the important ones have already

THE ORGANIC MATTER OF THE SOIL 131

been mentioned. It is to be kept in mind that the simpler
products of decay are the ones utilized by crops, although
it 1s a well-established fact that some of the secondary
and intermediate compounds may be taken up by certain
plants and probably are of some importance from the
standpoint of use as plant-food.

91. Composition of the soil humus. —It is evident
that the most complicated parts of the organic matter
in the soil are the primary and the secondary products
of decay, or the so-called soil humus. The study of this
matter is difficult and calls for the very highest knowledge
of organic chemistry. This is true for two reasons:
first, because of the complexity of these compounds;
and, secondly, because they are continually changing.
A certain compound present in the soil one week may
disappear the next week. Moreover, while some of the
soil humus is soluble in water and may circulate in the
soil solution, the bulk of it is insoluble. This in itself
presents difficulties. When the soil humus is treated
with the various extractive agents, reactions may be
induced which would not take place in a normal soil.
Compounds are then formed which not only would be
abnormal, but would probably not exist under natural
conditions. .

A great many chemists have worked on the problem of
the constitution of the organic matter of the soil and
have published their results. The ideas of the early
workers are really embodied in the conclusions advanced
by Mulder,! who was in many ways far in advance of his

1Mulder, T. J. Die Organischen Bestandtheile im Boden.
Chemie der Ackerkrume, I, pp. 308-360. Berlin, 1863. Also,
Wiley, H. W. Agricultural Analysis, Vol. I, p. 53. Haston,
Pa. 1906.

132 SOILS: PROPERTIES AND MANAGEMENT

time. Mulder contended that the organic matter con-
sisted of seven distinct compounds, as follows : —

1 and 2. Ulmic acid and ulmin 5. Geic acid
3 and 4. Humic acid and humin 6. Apocrenic acid
7. Crenic acid

These bodies he considered as arising from one another
by oxidation; thus, ulmic acid (CaHivOw) gave humic
acid (C4yoHiOw), which in turn yielded geic acid
(C4oH2O14), followed by apocrenic acid (C4sHieOe4),
and finally by crenic acid (CogHieOxs). Such a classi-
fication seems very simple, but certain flaws are at once
noticeable. In the first place, nitrogen does not find a
place in any of these formule; secondly, the compounds
are simpler than most plant tissue, which is not what
would be expected, especially with some of the degrada-
tion compounds; thirdly, none of these products have
united with the bases in the soil, a reaction that would
be very likely to take place especially with acid compounds.
Even the investigators’ of Mulder’s time obtained dis-
cordant results, but these were explained for the time
being by assuming that the discrepancies occurred because
of added molecules of water.

Later investigators, while progressing only slightly
toward definite results, did accomplish one thing of im-
portance, and that was throwing considerable doubt
on the old ideas of the Mulder school of chemists. This
again opened up the question as to the composition of
the soil organic matter, especially the humous constituents.
Thus, while it is evident that no such compounds as geic

18ee Schreiner, O., and Shorey, E. C. The Isolation of
Harmful Organic Substances from Soils. U. 8. D. A., Bur.
Soils, Bul. 53, pp. 15-16. 1909.

THE ORGANIC MATTER OF THE SOIL 133

acid, humic acid, or crenic acid exist in the soil, one name
has persisted in soil literature—that of humus and
humic acid. The word humus, as already indicated,
does not relate to any definite compound, but to the
great mass of primary and secondary products of bio-
logical and chemical organic decay taking place in the
soil. One of the men whose work established beyond
a doubt the fact that humus was not a definite compound
was Van Bemmelen.t His investigations still further
showed that the soil humus was largely in a colloidal
condition, and therefore exhibited properties quite dis-
tinct from those shown by crystalloids.

In recent years investigation has again been directed
toward the immense field opened by the overthrow of
the Mulderian school. Baumann,’ by his researches,
has shown freshly precipitated humus to possess properties
which are largely colloidal in nature. Among these char-
acteristics are high water capacity, great adsorptive power
for certain salts, ready mixture with other colloids, power
to decompose salts, great shrinkage on drying, and coagula-
tion in the presence of electrolytes. Jodidi* has studied
the composition of the acid-soluble organic nitrogen in
peat and in mineral soils. The nitrogenous compounds
thus obtained can be divided into the following
groups : ——

1Van Bemmelen, J. M. Die Absorptions Verbindungen
und das Absorptionsvermogen der Ackererde. Landw. Ver-
suchs. Stat., Band 35, Seite 67-136. 1888.

2Baumann, A. Untersuchungen uber die Humussauren.

Mitt. d. K. bayr. Moorkulturanstalt, Heft 3, Seite 53-123.
1909.

3 Jodidi, S. L. Organie Nitrogenous Compounds in Peat
Soils I. Mich. Agri. Exp. Sta., Tech. Bul. 4, November, 1909.
Also, The Chemical Nature of the Organie Nitrogen in Soul.
Iowa Agr. Exp Sta., Research Bul. I, June, 1911.

184 SOILS: PROPERTIES AND MANAGEMENT

1. Nitric nitrogen 3. Diamino acids
2. Ammoniacal nitrogen 4, Acid amides
5. Monamino acids

The two latter constituents were found to make up the
bulk of the organic nitrogen, but quantitative determina-
tions proved uncertain. These compounds produced
ammonia readily, the rate depending on their chemical
structure.

92. The work of Oswald Schreiner. — Of the chemists
who have been most active and most successful, Schreiner 1
deserves especial mention. Our present knowledge of the
chemical constitution of the organic matter of the soil is
very largely due to his efforts. While he realized that
the isolation of specific compounds from the soil was likely
to present insurmountable problems, and that the iden-
tification of such compounds after they were obtained
might be very difficult, he undertook a systematic ex-
traction of the soil. As a result of several years of work
he was able to isolate and identify a number of com-
pounds. The complexity and varied character of these
compounds is revealed by the following list of the more
important bodies isolated : —

List oF COMPOUNDS ISOLATED FROM Sort ORGANIC
MATTER BY SCHREINER, SHOREY, SKINNER, ReEeEp,
AND OTHERS, OF THE U. S. Bureau or Sorts

Hentriacontane, Ca;H¢4 Picolme carboxylic acid,
Dihydroxystearic acid, C,H,O.N
CrisH 04 Histidine, CsH,OoN3

1 Schreiner, O., and Shorey, E. C. The Isolation of Harm-
ful Organic Substances from Soils. U. S. D. A., Bur. Soils,
Bul. 58, 1909; also, Buls. 47, 70, 74, 77, 80, 83, 87, 88, and 90.

THE ORGANIC MATTER OF THE SOIL 135

Monohydroxystearic acid, Arginine, CgsHisO2N,4
Cighl3¢03 Cytosine, C4H;ON3. HO
Agroceric acid, CoH 4:03 Xanthine, CsH,O.N4
Agrosteral, Co2He2.O.H,O Hypoxanthine, C;sH,ON,
Paraffinic acid, CogH4,O. Tysine, CgH;,O.No
Lignoceric acid, Co4H4sOr2 Adenine, C;H;N;
Phytosterol, CogH4O0.H,O Choline, C;H,;O.N

Pentosan, C;H;O,4 Trimethvlamine, CsH N

Oxalic acid, C.H2O, Quanine, CH;N3

Suceinic acid, C4H,O, Creatinine, C4H;ON3

Sacharaic acid, CsHsQio Creatine, CsgH O.N3

Acrylic acid, CsH,Ov» Nucleic acid (constitution

Mannite, CgHi 40, unknown)

Rhamnose, CgHi4Ox0 Trithiobenzaldehyde,

Salicylic aldehyde, (CsH;CSH)3
C,-H,OHCOH

From a chemical standpoint these compounds may be
classified under four heads: (1) those containing carbon
and hydrogen; (2) those containing carbon, hydrogen,
and oxygen; (8) those containing carbon, hydrogen, and
nitrogen, or carbon, hydrogen, oxygen, and nitrogen;
(4) those containing sulfur in combination with the
elements listed above. With the possible presence in
soils of compounds containing five elements, it is of
little wonder that the subject is a complicated one. It
is evident, moreover, that the list given above is only a
partial one, and many other compounds of an even more
intricate composition will later be isolated.

So far as the plant is concerned, the compounds may
be divided into three groups — those that are beneficial,
those that are neutral, and those that are toxic, or harm-
ful, in their effects. As an example of the first group,

186 SOILS: PROPERTIES AND MANAGEMENT

histidine and creatinme! may be mentioned. Here is
a case in which the compounds found in the soil humus
may exert a stimulating effect on plant growth, and
may also be a source of plant-food, supplementing the
nitrates? to a certain extent. That the nitrogen of the
soil organic matter may be utilized by plants is well sum-
marized by the publications of Hutchinson and Miller.
As an example of a harmful compound arising from the
decomposition of the organic matter, dihydroxystearic
acid * may be mentioned as one of the best known. This
compound was the first to be isolated and identified by
Schreiner, and is very toxic.

93. Toxic material in the soil.— The discovery of
such compounds in the soil has revived the old theory
of toxicity,> by which the infertility of certain soils is
accounted for. Root excretions are also held to be
detrimental to succeeding crops of the same kind. The

1Skinner, J. J. Effect of Histidine and Arginine as Soil
Constituents. Eighth Internat. Cong. App. Chem., Vol. XV,
pp. 2538-264. 1912. Also, Beneficial Effects of Creatinine
and Creatine on Growth. Bot. Gaz., Vol. 54, No. 2, pp. 152~
163. 1912.

2 Schreiner, O., and Skinner, J. J. Nitrogenous Soil Con-
stituents and Their Bearing upon Soil Fertility. U.S. D. A,
Bur. Soils, Bul. 87, p. 68. 1912. Also, Schreiner, O., and others.
A Beneficial Organic Constituent of Soils; Creatinine. U. S.
D. A., Bur. Soils, Bul. 83, p. 44. 1911.

’ Hutchinson, H. B., and Miller, N. H. J. The Direct
Assimilation of Inorganic and Organic Forms of Nitrogen by
Toa Plants. Jour. Agr. Sci., Vol. 4, Part 3, pp. 282-302.

12.

4 Schreiner, O., and Skinner, J.J. Some Effects of a Harm-
mu oem Soil Constituent. U.S. D. A., Bur. Soils, Bul. 70.

>See Schreiner, O., and Reed, H. S. Some Factors Infiu-
ayeng Boll Fertility. U.S. D. A., Bur. Soils, Bul. 40, pp. 36~

THE ORGANIC MATTER OF THE SOIL 137

toxic materials of the soil humus largely originate under
conditions of poor drainage and aération, and conse-
quently are biological in their genesis. The toxicity of
such compounds as dihydroxystearie acid, picoline car-
boxylic acid,’ and aldehydes * may therefore be overcome
by oxidation,? so that good soil aération is a factor in
dealing with such conditions. Insufficient sanitation
of the soil seems to account very largely for the presence
of soil toxines. Fertilizers, according to Schreiner and
Skinner,* seem to decrease the harmful effects of such
compounds; nitrogenous fertilizers overcoming some
toxic materials, and phosphorus or potash neutralizing
others. For example, in water solution and sand culture,
nitrogen seems especially efficacious in correcting such
toxic substances as dihydroxystearic acid and vanillin,
phosphorus is particularly powerful in counteracting
cumarine, and potash has considerable influence on
quinone.

While the real importance of the toxic material generated
in the soil cannot be fully discussed at this point, it is
quite evident that such constituents do tend to develop
under insanitary conditions and must be considered in

1§chreiner, O., and Skinner, J. J. The Isolation of Harm-
ful Organic Substances from Soils. U. 8. D. A., Bur. Soils,
Bul. 53, pp. 46-49. 1909.

2 Schreiner, O., and Skinner, J. J. Harmful Effects of
Aldehydes in Soils. U.S. D.A., Bul. 108 (Professional Paper).
1914.

$ Schreiner, O., and others. Certain Organic Constituents
of Soils in Relation to Soil Fertility. U.S. D. A., Bur. Soils,
Bul. 47, p. 52. 1907. Also, Schreiner, O., and Reed, H. 8.
The Réle of Oxidation in Soil Fertility. U.S. D. A., Bur.
Soils, Bul. 56, p. 52. 1906.

4 Schreiner, O., and Skinner, J.J. Organie Compounds and
Fertilizer Action. U.S. D. A., Bur. Soils, Bul. 77. 1911.

188 SOILS: PROPERTIES AND MANAGEMENT

the discussion of the composition of that great group of
intermediate compounds, called humus, arising from the
decay of the organic matter of the soil. While Schreiner
found twenty soils, out of a group of sixty taken in eleven
States of this country, to contain dihydroxystearic acid,
this does not necessarily mean that this compound in
itself is a serious detrimental factor. It is very likely
that such compounds are merely products of improper
soil conditions, and are to be considered as concomitant -
with depressed crop yields. When such conditions are
righted, the so-called toxic matter will disappear. Good
drainage, lime, tillage, a balanced food ration, promoted
aération and oxidation, are so efficacious in this regard
that permanent soil toxicity need never be feared by the
farmer.

94. End products of humus decay. — As the processes
of chemical and biological decay of the soil organic matter
proceed, the simple compounds already noted begin to
appear. This change is of course codrdinate with a
certain amount of synthetic action, but compounds thus
built up must ultimately succumb to the agencies at
work and suffer a splitting-up and reduction to simple
bodies. Carbon dioxide is one of the most important of
these compounds, being always a product of bacterial
activity. Its importance has already been noted in the
discussion of weathering. Here it heightens the solvent
power of water and tends to increase the amount of plant-
food carried in the soil solution. Carbonation is a direct
result of its presence. Carbon dioxide may also tend to
flocculate colloidal matter in soils, and thus benefit the
physical conditions. With increased organic matter in
any soil, there greater bacterial action and an increase
in the carbon dioxide evolved may well be expected. In

THE ORGANIC MATTER OF THE SOIL 189

fact, the carbon dioxide production of a soil is considered
by some authors* to be a measure of bacterial activity.
With this increase in carbon dioxide the soil air becomes
more heavily charged and an alteration in bacterial and
plant relationships may thereby be induced. The fol-
lowing figures, by Wollny,? show the composition of the
soil atmosphere and the effects of additional humous
material on the carbon dioxide content :—

PERCENTAGE BY

YOLUME OF
C02 | O
Soil air (average of 19 analyees) ae 2.54. 18.33
Atmospheric air .... oe oe .04 20.96
A sandy soil Le woe eee 1.06 19.72

A sandy soil plus manure re 9.74 10.35

eenenamanneenend

While carbon dioxide may be evolved by the splitting-up
of both carbohydrate and nitrogenous bodies, ammonia
results only from the latter. It is really the first ex-
tremely simple nitrogenous body produced. It can be
utilized by some plants as a source of nitrogen, as is also
true with certain simple humic bodies, but ordinarily
it must undergo oxidation. This oxidation results in
nitrites (NO,) and ultimately in nitrates (NO), the
latter being usually considered as the chief source of
the nitrogen utilized by plants.

1 Stoklasa, J., and Ernest, A. Ueber den Ursprung, die
Menge, und die Bedeutung des Kohlendioxyds im Boden.
Centrlb. Bakt., II, 14, Seite 723-736. 1905.

2 Wollny, E. Die Zersetzung der Organischen Stoffe,
Seite 2. Heidelberg, 1897.

140 SOILS: PROPERTIES AND MANAGEMENT

Other end products, such as methane (CH), hydrogen
disulfide (H,S), free nitrogen (N), sulfur dioxide (SO,),
carbon disulfide (CS,), and the like, may also result.
They are relatively unimportant, however, as regards
the plant, in comparison to the réle played by carbon
dioxide, ammonia, the nitrites, and the nitrates. The
production of the nitrates from ammonia particularly
is very clearly correlated with good soil conditions, es-
pecially optimum moisture and adequate aération. The
proper handling of the soil, then, not only will tend to
eliminate toxic matter and prevent its further formation,
but will encourage the proper decay of the soil humus and
the production of end products which will function directly
or indirectly as plant foods.

Snyder 1 found that when humus was extracted with an
alkali and then precipitated with an acid, it yielded from
five to twenty-five per cent of a reddish brown ash. This
ash contained silica, iron, and alumina, as well as mag-
nesia, potash, phosphorus, sulfur, sodium, and calcium.
While part of these mineral constituents may be chemically
combined with humus, it is probable that some may be
present because of the adsorptive capacity of the organic
colloids which are always present in humus generated
under normal conditions. Snyder has estimated that
in an ordinary soil containing a fair amount of organic
matter, one-sixth of the phosphorus and one-twelfth of
the potash may be present in such a state. They are
then fairly available, and are yielded much more readily
to the plant than if of a strictly inorganic nature.

95. Carbonized materials of soil. After the extrac-
tion of the soil for the study of the ordinary humus com-

1Snyder, Harry. Production of Humus from Manures.
Minnesota Agr. Exp. Sta., Bul. 53, pp. 29-30. 1897.

THE ORGANIC MATTER OF THE SOIL 141

pounds, a considerable mass of material remains, which
is insoluble in water, alkali, and other ordinary solvents.
By the extraction of a large amount of soil, Schreiner !
was able to study this material. He found it susceptible
to division into six groups, as follows: (1) plant tissue,
(2) insect and other organized material, (3) charcoal
particles, (4) lignite, (5) coal particles, and (6) materials
resembling natural hydrocarbons, as bitumen, asphalt, and
the like. Such material was found not only near the sur-~
face of the soil, but at depths of fifteen or twenty feet be-
low. All the groups above listed were found by Schreiner
to be represented in the thirty-four soils collected from
all parts of the United States and subjected to rigid test.

The exact origin of such material is problematical.
Forest and prairie fires, infiltration, mild oxidation, and
lignification might be mentioned. Of a certainty, the
agencies of distribution are the natural forces engaged
in physical weathering. This carbonized material is
important, as it makes up no inconsiderable part of the
soil humus. It is very resistant, and consequently lends
stability to the soil organic matter. It can be divided
into two general groups, organized and unorganized ;
in the former the original structure remains intact, while
in the latter the original features have been obliterated.
The study of such material and the changes that it under-
goes not only increases the list of known organic com-
pounds existing in the soil, but throws considerable light
on the nature of the soil organic matter as a whole.

96. The estimation of the soil organic matter. —
Many methods have been proposed for the determination

1 Schreiner, O., and Brown, B. E. Occurrence and Nature
of Carbonized Material in Soils. U. S. D. A., Bur. Soils,
Bul. 90. 1912.

142 SOILS: PROPERTIES AND MANAGEMENT

of the organic matter in soils, but none have proved
entirely satisfactory, since the composition of this ma-
terial is so complicated and so likely to change while
under investigation. Other soil constituents also tend
to interfere with the determination. ‘Two general methods
seem worthy of mention, as they have been used very
widely in soil analyses and at least give comparative, if
not absolutely accurate, results.

Loss on ignition.|— This is a simple method which
designs to burn off the organic matter and determine
its loss by difference. Five grams of dry soil are
placed in a platinum dish and ignited at a low red
heat until the organic matter is all oxidized. The
cold mass is moistened with ammonium carbonate
and heated to a temperature of 150°C. in order to
expel the excess of ammonia. The loss is rated as or-
ganic matter.

This method is open to the objection that, besides the
loss of organic matter, a certain small amount of water
of combination, together with all ammoniacal compounds,
nitrates, all carbon dioxide, and some alkali chlorides if
the temperature is carried too high, is driven off. The
method therefore gives high results, especially in the
presence of large amounts of hydrated silicates. An
attempt to replace the carbon dioxide is made in the
treatment of the cold mass with ammonium carbonate.
Notwithstanding these objections, this method is one of
the best and is very generally used all over the world
in estimating the organic matter of the soil. Very often

1 Houston, H. A., and McBride, F. W. A Modification of
Grandeau’s Method for the Determination of Humus. U. S.
os” Div. Chem., Bul. 38 (edited by H. W. Wiley), pp. 84-92.
1893.

THE ORGANIC MATTER OF THE SOIL 143

the combustion is carried on in a current of oxygen over
hot copper oxide. The organic carbon may thus be
determined very accurately, and the organic matter
calculated by multiplying the carbon found by the factor
1.724.

Chromic acid method.1— This method, proposed by
Wolff, has been modified and improved by various chem-
ists. Warington and Peake? have perhaps done more
with the method than any other investigators. In the
United States the modification of Cameron and Brea-
zgeale® has been very generally accepted. It consists
in the treatment of the soil sample with sulfuric acid
and chromic acid or potassium bichromate. The organic
matter, in the presence of the sulfuric acid and an oxidizing
agent, evolves carbon dioxide until, if the mixture is
boiled, practically all of the carbon is thus driven off.
This gas is drawn through a train of absorption bulbs,
caught in a solution of potassium hydrate, and thus
weighed. On the supposition that organic matter is
58 per cent carbon, it is very easy to make the calcula-
tion. The carbon found may be multiplied by 1.724,
or the carbon dioxide by .471. The product is considered
as soil organic matter. The results thus obtained are
usually lower than with combustion or ignition methods,

1For comparison of methods, see Wiley, H. W. Principles
and Practices of Agricultural Analysis, Vol. I, pp. 347-356.
Easton, Pa. 1906.

2Warington, R., and Peake, W. A. On the Determina-
tion of Carbon in Soils. Jour. Chem. Soc. (London) Trans.,
Vol. 37, pp. 617-625. 1880.

’ Briggs, L. J., and others. The Centrifugal Method of
Mechanical Soil Analysis. U.S. D. A., Bur. Soils, Bul. 24,
pp. 33-38. 1904. Also, Cameron, F. K., and Breazeale, J. F.
The Organic Matter in Soils and Subsoils. Jour. Amer.
Chem. Soc., Vol. 26, pp. 29-45. 1904.

144 SOILS: PROPERTIES AND MANAGEMENT

due to the resistance to oxidation’ by the carbonized
matter, already discussed. This material, while it suc-
cumbs to ignition, resists the action of the sulfuric and
chromic acids to a very large degree.

97. The estimation of soil humus.— The common
method of humus estimation is that proposed by Grand-
eau.” The sample of soil is first washed with acid in order
to remove all bases. It is next treated with ammonia,
which will then dissolve out the humous materials. By
catching this percolate, evaporating it to dryness, and
weighing it, the percentage of humus may be calculated.
The dark humous extract obtained with the ammonia
is called the Matiére Noire.

This method has undergone several modifications? of
which that of Hilgard * and that of Houston and McBride ®
seem the most promising. The method of the latter
chemists has been adopted by the Association of Official
Agricultural Chemists and is considered as the official
method. In the procedure an attempt is made to keep
the concentration of the ammonia in contact with the
soil constant during the extraction. Consequently the
sample, after treatment with the acid, is washed into a

1 Schreiner, O., and Brown, B. E. Occurrence and Nature
of Carbonized Material in Soils. U. S. D. A., Bur. Soils,
Bul. 90, pp. 19-21. 1912.

2Grandeau, L. Traiti d’Analyse de Matieres agricoles. I,
p.- 151. 1897.

3 A comparison of the various methods is found as follows:
Alway, F. J., and others. The Determination of Humus.
Nebr. Agr. Exp. Sta., Bul. 115. June, 1910.

* Hilgard, E. W. Humus Determination in Soils. U. S.
D. A., Div. Chem., Bul. 38 (edited by H. W. Wiley), p. 80.
1893.

* Wiley, H. W. Official and Provisional Methods of Analy-
sis. U.S. D. A., Bur. Chem., Bul. 107, p. 19. 1908.

THE ORGANIC MATTER OF THE SOIL 145

500 cubic centimeter flask, which is filled to the mark
with 4 per cent ammonia. Digestion is allowed to pro-
ceed for twenty-four hours, with frequent shakings, and
and an aliquot portion of the supernatent liquid is taken
for analysis. This method with its modifications is
practically the only one that we have for the estimation
of soil humus. It is based on the fact that when a
soil is lacking in active basic material, the humous
matter may be extracted with ammonia. A modification
of this method may be used as a test for soil acidity,
as any soil of humid regions allowing the extraction of
humus by ammonia alone must lack basic materials.

The composition of the ash constituents of the matiére
noire is given by Snyder? as follows, the data being the
average of eight analyses :—

Tus AsH FROM THE Houmvus or Minnesota Prarriz Soins

Percentage
Insoluble . ..... =... +. 61.97
Fe.Os a 3.12
AlOg . 2. 1 ee ew ew ee) 848
KO ..... . . 2. 2. . . 4¢.50
Na,.O . 8 13
CaO 09
MgO . 36
P.O; 12.37
SO; 98
CO, 1.64

The relatively high percentage of phosphoric acid is
immediately noticeable in this analysis. This indicates

1 Snyder, Harry. Soils. Minnesota Agr. Exp. Sta., Bul. 41,
p. 30. 1895.
L

146 SOILS: PROPERTIES AND MANAGEMENT

that no mean portion of the soil phosphates is held in
organic combination. The promotion of favorable hu-
mous decay must thus liberate a considerable amount of
phosphorus for plant utilization.

98. Organic content of representative soils. — The
organic content of soils varies widely according to climatic
conditions. The following average data show the limits
of variation as well as the comparative content of the
important soil sections of the United States : —

OrGaANiIc Content or Unirep Staris Sorus

Sanpy Sorus Cuay Loams AND LoAMSs
Soil Subsoil Soil Subsoil
North Central States . ] 84 76 3.06 1.07
Northeastern States . 1.66 .60 3.73 1.35
South Central States . 1.16 55 1.80 .65
Southeastern States . 93 Al 1.53 13
Semiarid States . . . 99 .§2 2.64 1.11

Arid States . . . . 89 64. 1.05 62

er ererrrrepenctasmty

It is at once apparent that the subsoil contains con-
siderably less organic matter than do the surface layers.
Also, the areas of the United States that have been
glaciated are noticeably richer in organic material than
the residual, coastal plain, and arid regions. This is
largely a climatic and geochemical relationship. Some
soils, particularly alluvial soils, very often run higher
than the average data given above. An organic content
of 5 or 6 per cent is not an uncommon figure with such
materials. Muck and peat soils are of course not to be
classified with the above, as their organic content may

THE ORGANIC MATTER OF THE SOIL 147

range from 35 to 85 per cent, according to the admixture
of mineral matter from extraneous sources.

99. The humus content of soils. — The humus content
of soils is of course lower than the organic matter therein
contained. It likewise varies according to climate and
region, not only in amount, but also in composition. The
following data, compiled from Hilgard,' illustrate this
point :—

Tac Humvus or ARtIp AND Homip Sorns

Humus 1n_ | NrvrRoGEN in | NITROGEN IN
Sor H Som

(Percentage) | (Percentage) | (Percentage)

41 Arid uplands soils . . . 91 135
15 Subirrigated arid soils . . 1.06 .099
24 Humid soils ..... 4.58 .166

It is evident that humid soils not only contain the
greatest amounts of organic matter, but also excel in
humus. The humus of the arid regions, however, is
richer in nitrogen, due to the peculiar decomposition going
on. As a consequence the nitrogen in the soil of humid
regions is not greatly in excess of that in the soils of drier
climates.

The percentage of humus not only decreases as the
lower depths of soil are examined, but also changes in
composition, becoming poorer in nitrogen the deeper
the soil is penetrated. The following data on a Russian
river soil, quoted by Hilgard,? may be cited as an in-
stance : ——

1 Hilgard, E. W. Soils, pp. 186-1387. New York. 1911.
2 Tbid., p. 139.

148 SOILS: PROPERTIES AND MANAGEMENT

Tun Hummus or A Russran ALLUVIAL SOIL

PrRCONTAGE OF

Derrs In Frer UMUS

WOON SH Hb O tor

PERCONTAGE OF
NITROGEN IN
Humus

5.30
4.32
3.87
3.76
2.16

2.66
2.04:
1.54
2.24
1.15
1.51
1.81

PORCENTAGE OF
Humovs NirrrocEen

IN porn

064
054,
044
44.
.O16
.016
O12
012
.012
.006
.008
008

Other depth relationships, especially regarding the
proportions of carbon, humus, and nitrogen, are brought
out in the following data, obtained by Alway and Vail!
in the study of Nebraska Soils : —

ComposiTION oF A Nance County, Nmpraska, SOIL NEAR
GENOA

Derr AGE OF AGE OF

PRRCENT-

ZAQ

Ratio or

a snimeemenmenmmeeemennemieiaittien’ Unssnitinenmimminciaiiaaaeeuneuitieanel Tonainnemeamninammnntteetiiesimanetl Ueaemmnniaanaammentmnnteieme carmen Konmmandieininerenmnaitienammnmmeenament Rapmaminiueniemenmsnnedme’l Tennamenemieanmenmemen sl Taniethienimmmmmmenmninemaiti’

255 . 247
102 . 1.00
056 ; 40
042 . 30
034 . 19

Oo mt Grr

HNO GS

2
3
5
7
0
2

1Alway, F. J., and Vail, C. E. The Relative Amounts
of Nitrogen, Carbon, and Humus in Some Nebraska Soils.
Nebraska Agr. Exp. Sta., 25th Ann. Rept., p. 155.

1912.

THH ORGANIC MATTER OF THE SOIL 149

100. Influence of the original material on the resultant
humus. — It is evident that the source from which any
humus material is derived will exert a profound influence
on its composition, especially its nitrogen content.
Snyder + has investigated this by mixing certain materials
with a soil poor in humus and allowing the process of
decay to proceed for a year under favorable conditions.
At the end of the period the humus was extracted by the
Grandeau method. The results are given below :—

Ter COMPOSITION OF Hummus PRODUCED FROM Various Or~
GANIC Matrnoriats

O N
Sugar 39.04 08
Sawdust 3.33 47.07 32
Oats straw 2.48 40.72 2.50
Wheat flour 3.82 40.14 5.02

Cow manure
Green clover
Meat scrap

Although the humification may not have reached
completion in this case, the great variation in nitrogen
is striking. Existing, as it probably does, mostly as
acid amides and monamino acids, it will change readily
to ammonia and exert a marked effect on plant growth.
Possibly the variation of the nitrogen in soil humus is
the most potent factor in the nutritive functionings of
this material. The variability of the carbon, hydrogen,
and oxygen of the soil humus is not such an important
factor, as these elements can easily be supplied to the

1Snyder, Harry. Production of Humus from Manures.
Minnesota Agr. Exp. Sta., Bul. 53,.p. 25. 1897.

150 SOILS: PROPERTIES AND MANAGEMENT

soil by the plowing-under of green materials or of barn-
yard manures. In general, the percentage content of
inorganic matter increases as the organic matter decays.

101. Effects of organic matter on soil.— The effects
of the organic matter on soil and plant conditions are as
numerous as they are complex. Some of the influences
are direct, others are indirect. As the specific gravity of
organic matter is low, the first effect of its addition would
be to lower the absolute and the apparent specific gravity
of the soil. As the water capacity of humus is very high,
a soil rich in organic constituents usually possesses a
high water-holding power. This makes possible greater
volume changes both on drying and in the presence of
excessive moisture. The granulating effects of wetting
and drying and freezing and thawing are therefore ac-
eelerated. The organic matter tends also to spread
the individual particles of soil farther apart, especially
in a clay. Its loosening effects are immediately ap-
parent in such soil. On the other hand, because organic
matter has a higher cohesive and adhesive power than
sand, it performs the function of a binding material
with, the latter soil, a condition much to be desired in a
material possessing such, textural characteristics.

The better tilth induced by the presence of organic
matter in any soil tends to facilitate ease in drainage
and to encourage good aération. These two conditions
are of course necessary for the promotion of soil sanita-
tion. Root extension and bacterial activity are thus
increased. It is of especial importance that the splitting-
up of the organic matter shall take place in the presence
of plenty of oxygen, in order that toxic compounds may
not be generated and that a humus highly favorable to
plant growth shall be produced. The increased water

THE ORGANIC MATTER OF THE SOIL 151

capacity of the soil resulting from the presence of organic
materials is of some importance in drought resistance,
while the black color imparted by the humus tends to
raise the absorptive power of the soil for heat.

The soil organic matter, however, functions in other
ways than those strictly physical. The humus or its
degradation products may serve as plant-food. Bacteria
and other soil organisms are also furnished a source
of energy thereby, and the production of carbon dioxide
is much increased. This carbon dioxide, as well as the
organic acids generated, tends to raise the capacity of
the soil water as a solvent agent, and thus the amount of
mineral plant food available to the crop is greatly in-
creased. The general effect of organic matter, then, is
to better the soil as a foothold for plants, and to increase
either directly or indirectly the available food supply for
the crop.

102. Maintenance of soil organic matter. — The main-
tenance of a proper supply of organic matter in a soil is
a question of great practical importance, as productivity
is governed very largely by the humus content of the soil.
This maintenance of the soil humus depends on two
factors — the source of supply and methods of addition,
and the promotion of proper soil conditions in order that
the organic matter may perform its legitimate functions.

The organic matter of the soil may be increased in a
natural way by the plowing-under of green crops. This
is called green-manuring and is a very satisfactory prac-
tice. Such crops as rye, buckwheat, clover, peas, beans,
and vetch lend themselves to this method of soil im-
provement. Not only do these crops increase the actual
carbohydrate content of a soil, but in the case of legumes
the nitrogen also is increased in amount, due to the

152. SOILS: PROPERTIES AND MANAGEMENT

symbiotic action of the nodule bacteria. Green-manure
crops may also protect the soil from loss of plant-food by
leaching. The addition of barnyard manure is a common
method of raising the organic content from external
sources, and on decaying this manure performs the same
function as natural soil humus. Muck, peat, straw, or
leaves may be used in a similar manner.

Improper soil conditions not only prevent the proper
decay of organic matter, but also tend to encourage the
production of products inimical to plant growth. There-
fore, in order that organic materials added to any soil
may produce the proper humous constituents and per-
form their normal functions, soil conditions in general
must be of the best. Tile drainage should be installed,
if necessary, in order to promote aération and granulation.
Lime should be added if basic materials are lacking, for
it promotes bacterial activity as well as plant growth.
The addition of fertilizers will often be a benefit, as will
also the establishment of a suitable rotation. The rota-
tion of crops not only prevents the accumulation of
toxic materials, but also, by increasing crop growth,
makes possible a larger addition of organic matter by
green-manuring.

Good soil management seeks to adjust the addition
of organic matter, the soil conditions, and the losses
through, cropping and leaching, in such a way that paying
crops may be harvested without impairing the humus
supply of the soil. Any system of agriculture that tends
to permanently lower the organic matter of the soil is
impractical, and improvident, as well as unscientific.

CHAPTER Ix
THE COLLOIDAL MATTER OF SOILS!

Ir has already been noted, in the discussion of the clay
separate of any soil, that in the presence of water
certain of the very finest particles, even though apparently
dissolved, assume particular and important properties,
such as high adsorption, nondiffusion through mem-
branes, and the Brownian movement. Such material
has been designated as colloidal in nature. It must
be understood from the beginning, however, that

1Some of the following general references may prove of in-
terest : —

Freundlich, H. Kapillarchemie. Leipzig, 1909.

Zsigmondy, R. Kolloidchemie. Leipzig, 1912.

Bancroft, W. D. The Theory of Colloid Chemistry.
Jour. Phys. Chem., Vol. 18, No. 7, pp. 549-558. 1914.

Niklas, H. Die Kolloidechemie und ihre Bedeutung fiir
Bodenkunde, Geologie, und Mineralogie. Internat. Mitt.
fur Bodenkunde, Band II, Heft 5, Seite 883-403. 1913.

Ramann, E. Kolloidstudien bei Bodenkundlichen Arbei-
ten. Kolloidchemische Beihefte, Band II, Heft 8/9, Seite 285—
303. 1911.

Konig, J., Hasenbaumer, J., und Hassler, C. Bestimmung
der Kolloide im Ackerboden. Landw. Ver. Stat., Band 76,
Heft 5/6, Seite 377-441. 1912.

Noyes, A. A. The Preparation and Properties of Colloidal
Mixtures. Jour. Amer. Chem. Soc., Vol. 27, pp. 85-104. 1905.

Thaer, W. Der Einfluss von Kalk und Humus auf die
Mechanische und Physikalische Beschaffenheit von Ton-,
Lehm-, und Sandboden. Jour. f. Landw., Band 59, Heft 1.
Seite 9-57. 1911. Also, Kolloidchemische Studien. Jour.
f. Landw., Band 60, Heft 1, Seite 1-18. 1912.

1538

154 SOILS: PROPERTIES AND MANAGEMENT

colloidal material does not differ from crystalloidal
in chemical composition, but the distinction is merely
one of size of particles. For example, if large particles
are suspended in water, they will immediately sink,
since their weight is so much greater than the sur-
face that is exposed for buoyance. When these particles
are decreased in size, their weight decreases much faster
than the surface exposed. It is therefore evident that
a point will at last be reached at which the particles,
because of their minute size, will form a homogeneous
solution. The upper limit of the colloidal state has then
been entered.

103. The colloidal state. — The colloidal state in which
these particles are now found is a peculiar one, and ex-
hibits much diversity, not only in properties, but also
in the size of particle in which the material exists. The
upper limit of the clay group as designated by the classi-
fication of the United States Bureau of Soils is .005 milli-
meter, while the upper limit of the particle existing in a
colloidal state is estimated to be below .005 of a micron,
or .000005 millimeter. Indeed, so small are the colloidal
particles that they become molecular complexes, that is,
a few molecules may go to make up a _ particle.
The various colloids, or the same colloid under different
conditions, may exhibit greatly differing sizes of particles.
Some colloidal particles are very large, approaching the
upper limit already set for material in such a state. Other
particles are finer. It is evident that a gradation must
exist until a particle is reached which consists of only one
molecule. The solution then ceases to be a molecular
complex and becomes a true solution. The colloidal
state thus grades into the true solution, just as an
ordinary suspension grades into a true, or colloidal,

THE COLLOIDAL MATTER OF SOILS 155

suspension. While this method of comparison fails to
recognize the various phases that colloidal materials
may exhibit and is therefore faulty in this regard, it
does lay emphasis on the differences as to size of par-
ticle that exist between colloidal bodies and materials
as they are ordinarily recognized. This relationship
is shown by the following diagram : —

ORDINARY SUSPENSION | COLLOIDAL STATE j TRUE SOLUTION

MOLECULAR COMPLE.

Fig. 22.— Diagram showing the relationship of the colloidal state
(molecular complex) to ordinary suspensions and true solutions.

Since colloidal particles vary in size from .005 of a
micron to a molecule, the range must be very great.
Just how great cannot be very accurately stated. It
is interesting to note, however, that this range is much
greater in proportion than is exhibited between the fine
gravel and the ordinary clay particles found in soil. With
this possible difference, it is no great wonder that the
various colloids exhibit with different intensities the
characteristics so peculiar to them and of such great im-
portance in everyday life. The particles in the upper
range of the colloidal field can be seen with the ordinary
microscope. As such particles become smaller they cease
to be visible under the ordinary microscope and can be
detected only by the ultramicroscope. It is probably
true that by far the greater proportion of the particles
of material in a colloidal state cannot be detected by
microscopic means. This gradation of colloidal materials
and the extreme fineness of the particles is well illus-
trated by the following diagram (Fig. 23), although it
fails to convey any idea regarding the various phases
that colloids may occupy,

156 SOILS: PROPERTIES AND MANAGEMENT

WUSPENMSION

NUMGCROSGOPE

YULTRAWPTICROSGOPE

eh aap 2 yet okt takemipom j= nasa i.
MET a
po REVERSIBLE CREVER S/(BL

;

-, =

|
|

Fia 23 — Diagram showing the possible range in the size of colloidal
particles.

104. The properties of colloids. — In general there are
certain properties which materials in a colloidal state
exhibit and by which they are distinguished from true
solutions. In the first place, since they are not in
true solution they exert little effect on the freezing
point, on vapor tension, and on vapor pressure. Some
colloids have absolutely no effect on these conditions,
while others, as they allow a certain small amount
of true solution to take place, do possess such

THE COLLOIDAL MATTER OF SOILS 157

influences to a slight degree. Secondly, colloids do not
pass readily through semipermeable membranes, as
parchment paper, while crystalloids do. This serves as
a very easy way of separating colloidal and crystalloidal
material. As a matter of fact, the membrane is itself a
colloid. Thirdly, heat and the addition of electrolytes
will serve to coagulate or precipitate certain colloids, a
property which again serves to distinguish them sharply
from a true solution. Fourthly, colloidal material has great
adsorptive power, not only for water, but also for materials
in solution, a quality of extreme importance in soil studies.

It has been shown that a colloid is a material in a
certain state of division, in which it exhibits properties
not possessed by an ordinary suspension or by a true
solution. It is therefore proper to speak of matter so di-
vided as being in the colloidal state, or colloidal condition.
It is not to be inferred, because the colloidal phase is
contrasted with the crystalloidal, that colloids are amor-
phous. They may or may not be in such a condition.
Moreover, the same material may exist without chemical
change either in the colloidal or non-colloidal state. For
example, silicic acid, ferric hydrate, gold, carbon black,
and other materials, may or may not be colloidal, ac-
cording to circumstances. The fineness of division is
the explanation of colloidal properties. In order to
place such a discussion on a more understandable basis,
a few illustrations of the colloidal state will not be amiss.
The following materials, which may exist as colloids, may
be for convenience grouped under two general heads,
organic and inorganic: —

Organic: Gelatin, agar, caramel, albumin, starch, jelly,
humus, carbon black, tannic acid, ete.

158 SsozLS: PROPERTIES AND MANAGEMENT

Inorganic: Gold, silver, iron, ferric hydrate, arsenious
oxide, zinc oxide, silver iodide, Prussian
blue, ete.

105. Colloidal phases. —In general, two conditions
are necessary for the colloidal state — a dispersive medium,
and a material that will disperse, the latter being usually
designated as the disperse phase. Three materials may
function as a dispersive medium — a liquid, a solid, or a
gas. In the same way, with each dispersive medium there
may be three disperse phases — a liquid, a solid, or a gas.
This gives nine general phases to be considered in colloidal
chemistry. From the soil standpoint, the liquid-solid
and the liquid-liquid phases are by far the most portant
and will be the only ones to receive detailed attention
here. In the liquid-solid phase, as with colloidal gold
or ferric hydrate, the particles are suspended in water
as the dispersive medium. In the case of gelatin, another
liquid-solid example, the jelly surrounds the dispersive
medium, or liquid. An emulsion may exhibit the liquid-
liquid phase, and possibly exists in soils rich in humus.

In these colloidal phases under discussion and of such
particular interest in soil study, two general classes of
materials are found, which seem to differ radically from
each other and yet are likely to lead to considerable con-
fusion unless special pains are taken to distinguish between
them. As types, gelatin and a colloidal suspension of
ferric hydrate may be cited. The gelatin is considerably
more viscous than water, while the ferric hydrate does
not differ from water in this respect. The former gelatin-
izes on cooling or on loss of moisture, but will become
dispersed again on the addition or presence of water. In
other words, it will pass again and again, back and forth,

THE COLLOIDAL MATTER OF SOILS 159

from asoltoagel. Itis what might be called a reversible
colloid. Moreover, it is not coagulated by ordinary addi-
tions of salt or by heating. The ferric hydrate colloid,
on the other hand, when precipitated or agglutinated by
any means may not easily be brought back again to the
sol state. It isa so-called irreversible colloid. Moreover,
it is thrown down by the addition of electrolytes. There
exist, then, the viscous, gelatinizing, reversible colloids, and
the non-viscous, non-gelatinizing, easily coagulable, and
non-reversible colloids, besides all gradations and variations
between the two. In the ordinary clay soil, both types
of these materials probably exist and play important parts
in the physical and chemical characteristics exhibited.

106. Flocculation. — While the gelatinous colloids of
the soil, such as some of the humic materials, are not
agglutinated by the addition of electrolytes, most of the
colloids of a nature similar to colloidal silicic acid and
ferric hydrate are thrown down by this treatment. This
phenomenon is often spoken of as flocculation. A very
good example is afforded by treating a clay suspension
with a little caustic lime. The tiny particles almost
immediately coalesce into floccules, and, because of their
combined weight, sink to the bottom of the con-
taining vessel, leaving the supernatant liquid clear.
The same action will take place in the soil itself, but of
course with less rapidity and under conditions less notice-
able to the eye. The colloids thus thrown down, being
largely irreversible, cannot again assume their former
attributes and thus lose their distinguishing character-
istics. In general, acids bring about flocculation while
alkalies do not, calcium oxide and calcium hydrate being
the best-known exceptions to the latter. Ammonia is
an intense deflocculator.

160 SOILS: PROPERTIES AND MANAGEMENT

Just how this phenomenon of flocculation or agglutina-
tion may be accounted for theoretically it is rather difficult
to state. The general theory is one of electrification. It
is found that certain colloids, when subjected to the
proper electric current, will migrate to either the positive
(anode) or the negative (cathode) pole. These particles
evidently carry a charge of electricity. Ferric hydrate,
aluminium hydrate, and basic dyes, for example, move
toward the cathode and carry a positive charge; while
arsenious sulfide, silicic acid, gold, silver, and acid dyes
move toward the anode and are negative. It is assumed
that as long as the colloidal particles remain charged
they repel each other and the colloidal state persists.
When an electrolyte is added the ionization is supposed
to cause a discharge of the repellent electricity carried
by the colloidal particles, and flocculation or agglutina-
tion immediately takes place.

Certain colloids may flocculate certain others, as the
gelatinization of silicic acid by ferric hydrate. At times
one colloid may protect another, probably by surrounding
it with a protective film. Such a case may be shown by
adding gelatin to a clay suspension. When a colloid such
as ferric hydrate is flocculated, it loses to a certain extent
its peculiar properties, and assumes the characteristics of
ordinary materials. It is evident, therefore, that if the
properties exhibited by colloidal materials become either
directly or indirectly detrimental to plants, their floccula-
tion would be beneficial. In field practice this is usually
accomplished by the addition of lime. The colloidal
material existing in a normal soil and possessing a gelat-
inous nature, similar in general to gelatin, is probably
not all flocculated by the addition of ordinary amounts
of electrolytes. This material may be influenced by

THE COLLOIDAL MATTER OF SOILS 161

drying, whereby it slowly gives of water, becomes more
and more Viscous, and at last may lose its se] qualities
and become hard and irreversible. it is evident, there-
fore, that wetting and drying, frost, and the like, become
factors in dealing with this form 06: colloidal matter,

107. Commion soil colloids and their generation.’ —
The common soil colloids may, for convenience, be dis-
cussed under two heads, organic and inorganic. Of the
former, the so-called humic acid stands as the example;
of the latter, silicic acid, ferric hydrate, and amorphous
Zeoutie silicates are the commonest.

Orgame colloids.— The humic colloids in a normal
fertile soil probably make up the bulk of the colloidal
matter. Such Material is very heterogeneous, very
complex, and constantly changing. As yet very little
study of the organic soil colloids has been made because
or the diticulties presented by the problem. Humic
colloids may be viscous or non-viscous, as the case may
be, and Inay or may not be thrown down by lime. The
adsorptive power of these colloids for water, gases, and
such materials as calcium, magnesium, and potash, 1s

1Van Bemmelen, J. M. Die Absorption. Seite 114-115.
Dresden, 1910. Also, Die Absorptionsverbindungen und das
Absorptionsvermogen der Ackererde. Landw. Ver. ‘Stat,
Band 35, Seite 69-136. 1858.

Way. J. T. On Deposits of Soluble or Gelatinons Silica
in the Lower Beds of the Chalk Formation. Jour. Chem, Soc.,
Vol. 6, pp. 102-106. 1354.

Warineton, R. On the Part Taken by Oxide of Iron and
Alumina in the Adsorptive Action of Soils. Jour. Chem. Soc.;
2d ser., Vol. 6, pp. 1-19. 1868.

Cushman, A. S. The Colloid Theory of Plasticity. Trans.
Amer. Cer. Soc., Vol. 6, pp. 65-73. ‘1904.

Ashley, H. H. ‘The Colloid Matter of Clay and its Meas~
Grements. U. s. Geol. Sur., Bul’ 333. 1909,

162 SOILS: PROPERTIES AND MANAGEMENT

very highly developed — more so, probably, than that
of the inorganic colloids. These organic colloids are
formed during the tearing-down and splitting-off processes
of bacterial activity. Some of the humic materials are
thrown off in a sufficiently fine state of division to assume
the condition that has been designated as colloidal. Of
course the chemical forces of weathering are also operative
in this process of organic colloidal production.

Mineral colloids. — The inorganic soil colloids, especially
ferric oxide and silicic acid, are less complex than the
organic and have been more thoroughly studied. Such
colloids are generated during the operation of the ordinary
forces of weathering, especially the chemical phase. For
example, when a feldspar undergoes decomposition, the
following reaction may be used to illustrate the possible
change that takes place: —

2 KAISI30g + 2 HO + CO, = HyAbSipO, + 45102 +
K,CO3

Kaolin practically always has its origin in this way,
together with an alkali carbonate and silica. The process
is essentially one of hydration and carbonation; the CO,
by reacting with the alkali permits the process to go on.
The silica may go in three directions, according to con-
ditions — to free quartz, to hydrated silicates, and to
colloidal silica. Similar reactions may be written for
iron and aluminium, but they can only show, as does
the above, the general trend of the change. In general it
can be concluded that most inorganic colloids arise from
ordinary chemical weathering, together with secondary
minerals of various kinds. Such colloids must be very
dilute and are difficult to study because, of their reaction
among themselves.

THE COLLOIDAL MATTER OF SOILS 163

108. Preparation of colloids. — There are a number of
methods that may be used in the preparation of artificial
colloidal solutions, but the description of only one will
suffice in the present discussion. This is the use of a
semipermeable membrane. It has already been men-
tioned that crystalloids pass with ease through a membrane
such as parchment paper, while colloids do not. It is
reasonable to expect, then, that these materials may be
thus separated by proper adjustments. As a matter of
fact, such a procedure is employed in many cases. The
operation is called dialysis, and the membrane, itself a
colloid, is designated as the dialyzing membrane.

For example, if a solution of ferric chloride to which
some ammonium carbonate has been added is placed in a
dialyzer with pure water on the outside, the hydrochloric
acid and other impurities gradually pass through the
membrane and a more or less pure colloidal solution of
ferric hydrate is left behind. The objection to this
method lies in its extreme slowness. Nevertheless, since
the cells of plants present a semipermeable membrane,
this method of preparation serves to explain many actions
that go on between soil and plant during the processes
of nutrition. In the soil the formation of colloidal ma-
terial is entirely a natural exertion of chemical and bio-
logical forces under such conditions that the particles
split off are in that state of division which has been desig-
nated as colloidal.

It may be inferred that the quantity of colloidal matter
in an average soil is large, but as a matter of fact this is
not the case. The proportion of the soil in a colloidal
state at any one time is very small. It must be remem-
bered, however, that material is continually being thrown
out of the colloidal condition and at the same time more

164 SOILS: PROPERTIES AND MANAGEMENT

is generated; thus the effects may be marked, although
the amount present at any one time is extremely minute.

109. Colloids and soil properties. As may naturally
be inferred, the influence of the colloidal matter on soil
conditions, especially as related to plants, are extremely
important. This influence is exerted in two ways. First,
on cohesion and plasticity; and, secondly, on the adsorp-
tive power of the soil. Both these qualities must be con-
sidered, not only in the physical, but also in the chemical
and the biological, study of the soil as a medium for crop
production.

In general it is found that, other conditions being equal,
an increase of colloidal matter increases plasticity; in
other words, the ease with which a soil may be worked
into a puddled condition becomes greater. This is a rather
undesirable quality when too pronounced, and in clays
in which it is most likely to be developed some means
of decreasing the colloidal influence is advisable. This
great plasticity is developed because the colloids, espe-
cially those of a gelatinous or viscous nature, facilitate
the ease with which the particles may move over one an-
other and yet cohere sufficiently to prevent disruption
of the mass. In general, also, the greater the plasticity
of a soil, the greater is the cohesion when dry. In soils,
then, in which the colloidal material is very high, clodding
may occur if the soil is tilled too dry because of the great
tendency of the particles to cohere. This cohesion and
plasticity, as factors in soil structure, soil granulation,
and tilth, will be discussed in the succeeding chapter.
It is sufficient at this point only to observe the relation-
ship of colloidal materials to the development of such
qualities.

The second important attribute imparted to soil by

THE COLLOIDAL MATTER OF SOILS 165

colloid development is high adsorptive power. This
power extends not only to condensation of gases, but also
to water and to materials in solution. The water of
condensation on dry soil particles when exposed to a
saturated atmosphere is largely determined by the col-
loidal content. In other words, the surface exposure of
colloidal matter is so preponderant in water condensation
as in a general way to allow the one to be a relative meas-
ure of the other. Again, colloids exert adsorptive power
for material existing in the soil water, and to a limited
extent compete with the plant for food. Until the col-
loids are satisfied the soil solution may not reach its
maximum concentration for crop growth. This adsorp-
tive power is exerted especially on the basic materials,
such as calcium, and unless the existing colloids are fully
satisfied the soil tends to become lacking in available
bases. This condition is generally termed soil acidity.
It may readily be seen that the concentration of the soil
solution is governed to a considerable extent by the col-
loidal content of the soil, and that the adjustments in
concentration are always toward an equilibrium between
thetwo. Colloidal matter does not exert the same adsorp-
tive power for all materials, but is capable of what might
be called selective adsorption. For example, if ammonium
sulfate is added to a soil, the ammonia is strongly taken
up, which tends to release the sulfate. The continuous
use of such a fertilizer on a soil poor in lime will ultimately
result in the presence of free sulfuric acid. This example
is sufficient to emphasize the relationship of adsorptive
powers to fertilizer practice.

110. Factors affecting colloids. — It must not be in-
ferred from the preceding discussion that the generation
of colloids is detrimental to soil conditions. In light

166 SOILS: PROPERTIES AND MANAGEMENT

soils the presence of such material is extremely necessary,
as it tends to bind the soil together, facilitates granula-
tion, and prevents loss of plant food by leaching. It is
only in heavy soils in which such material is excessive
that a detrimental condition is likely to exist. This occurs
because of a high cohesion and plasticity, because of the
competition for food that is likely to arise with the crop,
and because of the tendencies toward acidity. Where
lime is low or lacking, the situation has a tendency to
become still more aggravated by further colloidal devel-
opment.

In general, the practice of underdrainage by allowing
the wetting and drying of the soil to proceed, is the first
step not only for the curbing of excessive and improper
colloidal influence, but also for the encouragement of
just the right development thereof. The freezing of
winter, tillage at proper times, the addition of humus,
and the application of lime are all practices that aid
in the control of colloidal conditions. Since this control
and utilization of colloidal influences is only a phase of
soil structure as related to tilth and granulation, a further
discussion of the subject will be reserved for later consid-
eration.

111. Estimation of colloidal content.—- The colloids
in the soil are so complex, so numerous, so variable in
function, and so susceptible to change, that an exact
determination of their amount is impossible. The knowl-
edge of colloidal material in general is so meager that it
is not surprising that such slight advances have been
made in fully and clearly determining their character in
a complicated material, as the soil undoubtedly is. The
important methods of estimating the colloid content of
the soil depend for their expression on the intensity of

THE COLLOIDAL MATTER OF SOILS 167

certain qualities, supposed to be developed largely by
colloid content. This indicates that the methods are
largely comparative, rather than exact or strictly analyti-
cal in nature. These important methods! are three in
number: Van Bemmelen’s, Ashley’s, and Mitscherlich’s.

Van Bemmelen.— The first investigator to advance
a method for colloid estimation was Van Bemmelen,?
who considered that the amount of silica dissolved from
a soil by digestion with bydrochloric or sulfuric acids
was a measure of its colloidal content. It is now known
that some materials, such as crushed rock, may yield
as much silica with this treatment as a highly colloidal
clay. This method is not of great importance at the
present time, except as to the information that it gives
regarding the evolution of colloidal soil study.

Ashley. — A second method, and one of much more
value, has been evolved by Ashley. He found that the
adsorption of certain dyes by soils afforded a very good
index to colloidal content. The difficulty in this method,
however, lies in choosing the most effective dye and regu-
lating its concentration. Moreover, different colloids
vary so much in adsorptive capacity for the same dye,
that only roughly comparative results have thus far been
possible.

Mitscherlich. — The third, and as yet the most valu-

1A comparison of these methods is found as follows:
Stremme, H., and Aarnio, B. Die Bestimmung des Gehaltes
anorganischer Kolloide in Zersetzten Gesteinen und deren
tonigen Unlagerungsprodukten. Zeitsch. f. Prak. Geol.,
Band 19, Seite 329-349. 1911.

2Van Bemmelen, J. M. Die Adsorptionsverbindungen
und das Absorptionsvermégen der Ackererde. Landw. Ver.
Stat., Band 35, Seite 69-136. 1888.

3 Ashley, H. E. The Colloid Matter of Clay and Its
Measurement, U.S. Geol. Sur., Bul. 388. 1909.

168 SOILS: PROPERTIES AND MANAGEMENT

able, mode of colloidal estimation is that of Mitscherlich,?
in which the adsorptive capacity of the soil is again made
the comparative index. Water instead of dye is used as
the adsorbed material. In this method the air-dry soil
in a thin laver is brought to absolute dryness over phos-
phorus pentoxide. It is then placed in a desiccator over
a 10 per cent solution of sulfuric acid and the condensa-
tion is hastened by a partial vacuum. The sulfuric acid
is used in order to prevent the deposition of dew on the
soil. After exposure for about twenty-four hours the
soils are found to have taken up their maximum moisture
of condensation, which is called the hygroscopic water.
The soil is then weighed, and the increase, figured to a
percentage basis, is taken as a measure of colloidal con-
tent. The reverse process may also be followed, by
exposing air dry soil in a saturated atmosphere and
afterwards drying over phosphorus pentoxide. The
hygroscopicity of the soil, or its hygroscopic coefficient,
is thus the basis for colloidal comparison. It is now
clear why the term colloidal estimation is employed in
this discussion, rather than colloidal determination.

An objection to the Mitscherlich method is advanced
by Ehrenberg and Pick,? who claim that the drying over

1 Rodewald, H., und Mitscherlich, A. BE. Die Bestimmung
der Hygroskopizitit. Landw. Ver. Stat., Band 59, Seite
433-441. 1903. Also, Mitscherlich, E. A., und Floess, R.
Hin Beitrage zur Bestimmung der Hygroskopizitat und zur Bewer-
tung der physikolischen Bodenanalyse. Internat. Mitt. f. Boden-
kunde, Band I, Heft 5, Seite 463-480. 1912.

* Ehrenberg, P., und Pick, H. Beitrage zur physikalischen
Bodenuntersuchung. Zeit f. Forst- und Jagdwesen, Band
43, Seite 35-47. 1911. Also, Vageler, P. Die Rodewald-
Mitscherlichsche Theorie der Hygroskopizitat vom Standpunkte
der Colloidchemie und ihr Wert zur Beurteilung der Boden.
Fuhling’s Landw. Zeit., Band 61, Heft 3, Seite 78-83. 1912.

THE COLLOIDAL MATTER OF SOILS 169

phosphorus pentoxide will coagulate certain colloids and
lower their adsorptive power, thus causing the hygro-
scopic coefficient to become an unreliable comparative
figure. They suggest first the exposure of the field
soll over the water and sulfuric acid, and then the ex~
traction of the hygroscopic water over phosphorus pent-
oxide. Since this modification is very slow, the original
Mitscherlich method, in spite of its faults, remains the
most valuable up to the present time.

CHAPTER X

SOIL STRUCTURE

WHILE texture is the term used in reference to the size
of the particles in a soil mass, the word structure is em-
ployed in reference to the arrangement of the grains.
The structural condition of the soil 1s very important to
plant growth, since the circulation of air and water are
so necessary to normal development. The structural
condition may be loose or compact, hard or friable, granu-
lated or non-granulated, as the case may be. Of these
conditions, granulation, especially in heavy soils, is of
vital importance, since it is really a summation of all
favorable structural conditions. By granulation is meant
the drawing together of the small particles around a
suitable nucleus, so that a crumb structure is produced.
The grains thus cease to function singly. The impor-
tance of such a structural condition on a heavy soil is
very obvious. The soil becomes loose because of the
larger units, air moves more freely, and water not only
drains away readily when in excess, but responds with
celerity to the capillary pull of the plant. Before the
promotion of granulation and the factors that function
therein may be clearly discussed, however, two properties
of particular importance, especially in soils of fine tex-
ture, must be considered. These properties are plasticity
and cohesion.

112. Plasticity. — Any material which allows a change
of form without rupture, and which will retain this form

170

SOIL STRUCTURE 171

not only when the pressure is removed, but also when dry,
is said to be plastic. Putty with a proper admixture of
oil is a very good example of a plastic body. As is well
known, the various plastic materials differ in their plastic-
ity. Not only this, but such substances as clay or some
other soils vary in plasticity with their moisture content,
their granulation, and their texture. The great diffi-
culty in the study of plasticity has been in finding a
means of estimation allowing an exact numerical expres-
sion. The amount of hygroscopic water that a soil will
hold has been used as an expression of plastic qualities,
as well as shrinkage on drying, the ability to adsorb dyes,
tensity, and other characteristics. None of these has
proved satisfactory, since one quality of a clay or other
soil is used as a measure of another quality.

Atterberg+ has suggested that the difference in mois-
ture content of a clay at the point at which it ceases to
be plastic, as compared with the moisture content at
which it becomes viscous, might be used as an expres-
sion of plasticity. He has called this figure the plasticity
coefficient. Thus, a soil may cease to be plastic at 20
per cent of moisture and may flow at 40 per cent. The
plasticity coefficient would then be 20. While this is one
of the latest methods, it is open to the objection already
stated — that one quality of a soil is used as a measure
of another. Two soils showing the same plasticity coeffi-
cient by this method may exhibit undoubted differences
in actual plasticity. Kinnison,? in testing several methods
of expression, found Atterberg’s no better than others

1Atterberg, A. Die Plastizitat der Ton. Internat.
Mitt. f. Bodenkunde, Band I, Heft 1, Seite 10-43. 1911.

2Kinnison, C. S. A Study of the Atterberg Plasticity
Method. Trans. Amer. Cer. Soc., Vol. 16, pp. 472-484. 1914.

172 SOILS: PROPERTIES AND MANAGEMENT

already in use. For all practical purposes in soil dis-
cussions, general descriptive terms may be employed.

113. The cause of plasticity. — Exactly what may be
the cause of plasticity has long been under discussion.
The various theories advanced may be grouped under the
following heads : ! —

A. Structure of clay particles
1. Fineness of grains
2. Plate structure
3. Interlocking particles
4, Sponge structure

B. Presence of hydrous aluminium silicates
C. Molecular attraction between particles
D. Presence of colloidal matter

Of these theories accounting for the plasticity of cer-
tain bodies, that of colloid content seems the most rea~
sonable. The presence of gelatinous colloidal matter,
with a certain optimum amount of water, seems to facili-
tate the ready movement of the particles while at the
same time exerting sufficient force to prevent the body
from splitting apart at the time of movement, or when
the pressure is removed or the material dried. Thus,
in general, other conditions remaining equal, materials
become more plastic the greater the content of colloidal
matter. In general the colloids function as a measure
of plasticity. The consideration of shrinkage, hygro-

1 Davis, N. B., The Plasticity of Clay. Trans. Amer.
Cer. Soc., Vol. 16, pp. 65-79. 1914.

*Cushman, A. 8S. The Colloid Theory of Plasticity.
Trans. Amer. Cer. Soc., Vol. 6, pp. 65-78. 1904. Also, Ashley,
H. E. The Colloid Matter of Clay and Its Measurement.
U.S. Geol. Survey, Bul. 388. 1909.

SOIL STRUCTURE 173

scopic water, and dye adsorption as an expression of
plasticity become logical on this basis.

114. The importance of plasticity. — Plasticity assumes
considerable importance in a soil when it becomes highly
developed, since it promotes ease in puddling. The
more plastic a soil is, the more likely it is to become pud-
dled by tillage, especially if it has a high moisture con-
tent. Thus a clay cannot be plowed wet, since this
would allow its particles to be worked into that very intri-
cate condition so detrimental to plant growth. A sand,
on the contrary, may be stirred even when saturated,
and still its structural condition will not be impaired
since its plasticity is low or nihil. A very plastic soil
is also likely to become exceedingly hard when dry unless
it is well granulated, which shows the great care demanded
by soils having high plasticity coefficients.

The three factors that affect plasticity to the greatest
extent are texture, granulation, and moisture. In gen-
eral, the finer the texture of the soil, the higher is the
maximum plasticity thereof. The more granular a soil,
the lower is the plasticity or the tendency to puddle
when plowed. The amount of water is the third vital
factor. A soil will exhibit its maximum plasticity at a
definite moisture content. This point will lie somewhere
between the flowing, or viscous, condition and the point
at which a soil refuses to mold, or, in other words, to be-
come crumbly. With a soil such as a clay, in which the
plasticity is high, plowing should be done when the
moisture condition is such that there is no likelihood of
puddling, and yet the soil will turn over with a maximum
granulating effect.

115. Cohesion. — Very closely correlated with plas-
ticity, but not in exact similarity, is cohesion. By the

174 SOILS: PROPERTIES AND MANAGEMENT

cohesion of a soil is meant the tendency that its particles
exhibit in sticking together and in conserving the mass
intact. In general, the greater the plasticity of a soil,
the higher is its cohesion, especially when it is dry or
only slightly moist. For that reason, cohesion might
be made a rough measure of plasticity. Cohesion of a
soil occurs under two general conditions, the wet and the
dry. When a soil is moist its cohesion is developed by the
moisture films and the colloidal materials that may be
present. This form of cohesion is often spoken of as
tenacity. When a soil is dry its cohesion is developed to
some extent by the interlocking of its grains and the dep-
osition of cementing salts. The greatest force is devel-
oped, however, by the drying and shrinking of the
gelatinous colloidal matter. As a general rule, the greater
the amount of colloidal material, the more firmly the soil
is bound together when dry, or, in other words, the greater
is its cohesion.

Cohesion is important in tillage operations, in that
soils having a high coefficient of cohesion tend to become
cloddy when plowed and may thus be rendered poor in
physical condition. This may be avoided by timing the
operation so that the moisture content is somewhere
above the point at which excessive cohesion is exerted.
As cohesion is not greatly developed, except in a heavy
soul, it is only where fine texture is found that such a
danger exists. As already shown, the danger is a double
one, for, since high plasticity and high cohesion go to-
gether, a soil plowed too wet may puddle while one
plowed too dry may clod.

116. Methods of determining cohesion. — A number
of methods have been devised for determining the co-
hesion of clays and other soils. One of the earliest was

SOIL STRUCTURE 175

Schiibler’s,| in which was tested the resistance of rec-
tangular prisms of dry soils to penetration by a steel
blade. The apparatus consisted of a beam supported
on a fulcrum more than one third of the distance
from the end. A pan for holding the weights added
for causing the crushing was hung at the end of the
long arm, while a counterpoise on the short end of the
beam acted as a balance. The steel knife was placed
on the long end of the arm near the fulcrum. The dry
soil prism was placed under the knife and weights were
added to the pan until crushing occurred. The weight
necessary was designated as the cohesion coefficient of
that soil.

Haberlandt 2 measured cohesion by crushing soil
cylinders of a definite size. A glass vessel was placed
on the top of the column and water was added until the
column gave way. The weight necessary to bring this
about was designated as the absolute cohesion of the
sample. Haberlandt also measured cohesion of soil
cylinders of a definite size by determining the resistance
to breaking under a transverse load, the soil column being
placed across supports six centimeters apart. On the
column midway between the ends a scale pan was sup-
ported, into which weights were put until breaking oc-
eurred. The figure thus obtained was called the relative
cohesion.

1 A good description of Schubler’s apparatus is found on page
104 of Bodenkunde, by E. A. Mitscherlich, published by Paul
Parey, Berlin, in 1905.

2Haberlandt, H. Ueber die Koharescenz Verhaltnisse
verschiedener Bodenarten. Forsch. a. d. Gebiete d. Agri.-
Physik., Band I, Seite 148-157. 1878. Also, Wissenschaftlich
praktische Untersuchungen auf dem Gebiete des Pflanzenbaues,
Band I, Seite 22. 1875.

176 SOILS: PROPERTIES AND MANAGEMENT

Puchner! used a penetration apparatus, consisting
of a vertical shaft held by metal guides and counterpoised
by a weight hung over a pulley. The shaft was armed
at the lower end with a cutting blade, while the upper:
end carried a scale pan for holding the necessary weights
for penetration. The cohesion coefficient was the weight
necessary to force the blade a certain distance into the
soil. All important apparatus have been modeled after
either Puchner’s or Schiibler’s. That of Atterberg? (see
Fig. 24) follows the former, while that of the Bureau of
Soils ® (see Fig. 25) resembles the latter.

Fig. 24 —- Atterberg’s apparatus for determining the cohesion of soil
prisms. The soil prism is placed between the cutting edge (K) and
the sharp plunger (P). Weights are added at (W). (C) is a coun-
terpoise.

+Puchner, H. Untersuchungen tiber die Kohireszenz der
Bodenarten. Forsch. a. d. Gebiete d. Agri.-Physik., Band 12,
Seite 195-241. 1889.

* Atterberg, A. Die Konsistenz und die Bindigkeit der Boden.
Internat. Mitt. f. Bodenkunde, Band II, Heft 2~3, Seite 149-
189. 1912.

* Cameron, I’, K., and Gallagher, F. E. Moisture Content
and Physical Condition of Soils. U.S. D. A., Bureau of Soils,
Bul. 50. 1908.

SOIL STRUCTURE LT7

Recently Puchner! has found a machine for measuring
the crushing strength of dry soil cylinders to be of value
in determining the absolute, or maximum, cohesion of
soils. The results, as he has already demonstrated in
his previous work, are comparable, in relative value at
least, to those obtained by simpler methods.

The great difficulty encountered in measuring the
natural cohesion of a soil, either wet or dry, is not so

Fig. 25.— The apparatus used by the United States Bureau of Soils
for determining the penctration of soils. (C) is mechanically packed
soil; (A), steel point; (P), pail for receiving sand from funnel (F).
(W) is a counterpoise.

much in the accuracy of the determination as in controlling
physical conditions. The cohesion of a soil depends
very much on the handling it has received in the prepara-
tion, in the amount of water that is added, and in the
amount and length of time of drying. Natural granu-
lation cannot be secured. The Bureau of Soils attempted
to obviate these difficulties by mechanical sifting and
packing, but the results were abnormal, due to the sift-
ing process. As a consequence, most cohesion results

1Puchner, H. Vergleichende Untersuchungen iiber die
Kohareszenz verschiedener Bodenarten. Internat. Mitt. ftir
Bodenkunde, Band III, Heft 2-3, Seite 141-239. 1913,

178 SOILS: PROPERTIES AND MANAGEMENT

have been determined either on samples that have been
worked to a maximum plasticity and then brought to
the required moisture content, or on uniformly compacted
samples that have been allowed to take up water by capil-
larity. In general the curve that would occur with normal
granulation, while lower, will follow the direction of a
maximum plasticity curve.

117. Factors affecting cohesion. — It is obvious, from
what has already been said regarding the general char-
acteristics of soils, that texture must play an important
role in the determination of the cohesion factor. In
general, the finer the texture, the greater is the cohesion,
since, whether the soil is wet or dry, the forces that tend
to hold the particles together are stronger than in a coarser
soil. The drier the soil, however, the greater is the tex-
tural influence in this regard, due to the very great in-
crease in the binding capacity of the colloidal matter
on drying. In a coarse soil this binding effect is small or
entirely absent.

Another factor is the granular condition of the samples.
In general granulation may be said to be due to an exer-
tion of cohesion between a limited number of particles,
resulting in a crumb, or granular, structure. This granu-
lation, by loosening the soil mass, lowers not only plastic-
ity but cohesion also. The addition of organic matter
to a soil, by hastening and increasing granulation, will
tend to lower cohesion at every moisture content ranging
from a dry to a saturated condition. The following
data, taken from Puchner,! bring out the points just
discussed :—

1Puchner, H. Untersuchungen tiber die Kohireszenz der
Bodenarten. Forsch. a. d. Gebiete d. Agri.-Physik., Band 12,
Seite 195-241. 1889,

SOIL STRUCTURE

179

Errects or Texrure, GRANULATION, Humus, anp Moisturs
on CoHrSION or SoILs.

Sorin

Clay .

2 clay + 1 quartz

1 clay + 2 quartz
Quartz

2 clay + 1 humus

1 clay + 2 humus
Humus .

Pulverized loam .
loam
(granules .5—9 mm.

Granulated

diam. )

100
per
cent

114
30
85

167
44,
og

115
30

(PUCHNER.)

PENETRATION IN GRaws ar Vartous
MolIsturs Contents

80
per
cent

2,404
437
1,887
2,937
754
1,010
1,414
272

60
per
cent

9,537
6,304
3,903
4,237
4,704
1,704
1,904

775

40
per cent

11,870
12,370
10,003
5,137
7,204
4,204
1,804
1,408

20 0
per cent | per cent

15,037 | 20,037
13,204 ; 15,704

13,703 |

8,370
9,537
5,070

870
8,125

6,057
2,370
12,037
1,637
487
12,358

Fra.

26. — The effects of texture, humus, and moisture on the cohesion
of soil

180 SOILS: PROPERTIES AND MANAGEMENT

The relationships already spoken of are especially well
shown by the curves (see Fig. 26), particularly the effect
of the moisture content on cohesion. In a heavy soil the
cohesion increases steadily from a saturated condition until
dryness is reached, the increase becoming accelerated as
the percentage of moisture decreases. This is because

Fig. 27. ~~ The cohesion curves of clay and fine sandy loam at various
moisture contents. (C), point at which soil changes in color.

SOIL STRUCTURE 181

the binding power of the colloidal material is greatly
augmented by desiccation. In a coarse soil such as
quartz, in which there is very little colloidal matter, the
cohesion is developed principally by the water film. As
this thins, its pulling power increases and the curve
ascends; but when the soil dries this film disrupts and
the curve drops again, having no colloidal binding ma-
terial. The same relationships are shown by curves (see
Fig. 27) adopted from recent determinations by Atter-
berg.!

118. Moisture limits for successful tillage. — In heavy
soils, in which the colloidal content is usually high, plas-
ticity and cohesion also are high. This means that the
soil when too moist will be puddled by tillage implements,
especially such as the plow, and when too dry clodding
will occur because of very high cohesion. A moisture
limit must therefore exist on a heavy soil, within which
successful plowing may be done and maximum granu-
lation results may be secured. That this moisture limit
is narrow is obvious, since high cohesion and high plas-
ticity bound it so closely on either hand. Such a rela-
tionship must be kept In mind not only by the farmer
but by the technical man as well, since so much depends
in any work upon good soil tilth. The relationship is
clearly shown by the following curves (Fig. 28) partially
adopted from Atterberg.! The cohesion and plasticity
curves are seen to cross near the center of the diagram
and indicate the existence of a zone where neither are
exceedingly high or low.

In a clay soil a study of the optimum moisture condi-

1 Atterberg, A. Die Konsistenz Kurven der Mineralbéden.
Internat. Mitt. f. Bodenkunde, Band IV, Heft 4-5, Seite 418-
431. 1914.

182 SOILS: PROPERTIES AND MANAGEMENT

COME SIOLY PLASTICITY

Fig. 28 — Diagram showing the moisture limits for successful plowing
in soils of different class. cc’ and hh’ represent the moisture hmits
within which successful plowing may be accomplished on a clay and
humus clay respectively.

tions is necessary in order to determine what is just the
right moisture content for good plowing. That this
condition must be carefully gauged and immediate use
made of the advantages it offers is shown by its narrow
limit. A few days may suffice for the moisture to drop
through such a narrow area of fluctuation. A clay soil is
so difficult to handle at best that no opportunities such as
are offered by optimum moisture conditions should be lost.
Moreover, a heavy soil plowed too dry or too wet does not
regain its normal granular condition for several seasons.

In a sandy soil no such difficulties are encountered.

SOIL STRUCTURE 188

Since the soil has low cohesion, plowing when it is too
dry will not clod, while, because of low plasticity, little
puddling will occur if tillage is in progress when the soil
is wet. Being always rather loose, such a soil is often
benefited by plowing when it is slightly wet, the parti-
cles being brought into closer contact and excessive per-
colation being stopped while at the same time the water
capacity is raised.

119. Control of cohesion and plasticity. — It is evi-
dent not only that cohesion and plasticity control the
successful tillage of the land, especially where the soil
texture is fine, but also that these same factors vary with
the moisture and the granular structure of the soil. It
has been shown that there is a moisture zone in all soils —
this being narrower the finer the soil texture — at which
neither cohesion nor plasticity is excessive. In this zone
a heavy soil may be successfully plowed, with results
favorable to the structural condition of the soil. Since
the processes of granulation have already been shown to
lower cohesion and plasticity, itis evident that as a crumb
structure is developed the moisture zone for proper plow-
ing will be widened, especially in a heavy soil. This is a
very important point in the handling of clays and clay
loams, since it not only opens a way for the elimination
of the dangers of bad structural relationships, but also
provides for putting the soil in a condition for easier and
more convenient tillage. In a sandy soil, particularly
where humus is the granulating agent, a soil with
more cohesion, more plasticity, and a greater water-
holding power is developed, all of which tend toward a
better medium for plant growth. Methods of develop-
ing this granulation thus become the logical topic for
further discussion.

184 SOILS: PROPERTIES AND MANAGEMENT

120. Soil tilth.— The previous data and discussion
have clearly shown the very great importance of a crumb
structure in the working of the soil in the field. Since
good physical condition will reflect itself on crop yield,
it is evident that structure must ultimately be considered
in relation to all plant growth. This relationship is
usually expressed by the term wlth. While, structure
refers to the arrangement of the particles in general, and
granulation to a particular aggregate condition, tilth
goes one step further and includes the plant. ‘Tilth, then,
refers to the physical condition of the soil as related to
crop growth. It may be poor, medium, good, or excel-
lent, according to circumstances. Good tilth may de-
mand in some soils maximum granulation, in others
only a medium development. Maximum tilth always
implies the presence of water, since the best physical
relationships cannot be developed without optimum
moisture conditions.

From the curves already presented, it is evident that
an optimum moisture condition exists for the proper
tillage of a soil, especially one of a heavy character. Also,
an optimum moisture condition must exist for proper
tilth, and therefore for proper plant development, since
adequate tilth is the best physical condition for crop
growth. Practical experience and theoretical evidence !
have shown that these two optimum conditions are
identical in nearly all cases, a happy coincidence in the
practical management of a soil. The optimum moisture
condition for plant growth, then, is the proper moisture
condition for effective plowing. The optimum condition

1Cameron, F. K., and Gallagher, F. BE. Moisture Content
and Physical Condition of Soils. U. 8. D. A., Bur. Soils, Bul.
50, p. 8. 1908.

SOIL STRUCTURE 185

for developing a favorable crumb structure is obviously
the optimum moisture content for the development of
the highest tilth. In fact, it can be stated with certainty
that the optimum moisture condition for plant growth
is the optimum for all favorable soil activities, whether
physical, chemical, or biological. Granulation, then,
becomes the vital factor in placing the soil in a physical
condition such that the highest tilth, that physical criterion
which every farmer should strive for, may be developed
in any soil. Until proper granulation is reached, no soil
can be expected to yield maximum paying returns.

121. Granulation. — While it is possible to list the
factors that bring about granulation in a soil, it is diffi-
cult to state specifically just why this phenomenon takes
place. It has been suggested that much of the granule
formation in the soil is due to the contraction of the
moisture film around the particles when, for any reason,
the moisture content is reduced (see Fig. 29). It is known

Fig. 29. — A puddled and a well-granulated soul.

that the soil particles tend to be drawn together by this re-
duction in the soil moisture, due to the pulling power of the
thinned film. If to this condition is added a material which
tends to exert not only a drawing power on loss of mois-
ture, but also a binding and cementing power when dry, all

186 SOILS: PROPERTIES AND MANAGEMENT

the essentials for successful granulation are present. This
second force is found in the colloidal material present in
considerable quantities in heavy soils. These are the same
forces that have already been shown to determine the
cohesion and plasticity of the soil, except that in granu-
lating operations they are localized at numberless foci,
and clodding or puddling is thereby prevented. It is
evident that if cohesion and plasticity forces are to func-
tion for granulation — or, in other words, locally in the
soil instead of generally and uniformly as when clodding
or puddling occurs —a certain moisture content must
be maintained. From what has already been shown,
it is hardly necessary to restate that this moisture condi-
tion is near the optimum moisture content for plant
growth.

Warington! attributes granulation to unequal expan-
sion and contraction of the soil mass, due to the imbibi-
tion and loss of water. In a soil subject to such a condi-
tion, the cohesive forces being localized, the internal
strains and pressures are unequal and a tendency arises
for the mass to divide along lines of weakness into groups
of particles. The binding capacity of colloidal material,
as well as of salts deposited from the soil solution, tends
to make such a crumb structure more or less permanent.
Tillage operations, development of roots, burrowing
of animals and insects, the presence of humus, and the
formation of frost crystals, may assist in further develop-
ing these lines of weakness in the soil mass, on which the
tension of the moisture films around the soil particles is
brought to bear. The flocculation of soil particles may
also develop lines of cleavage by their aggregation around

1 Warrington, R. Physical Properties of Soils, pp. 36-41.
Oxford. 1900.

SOIL STRUCTURE 187

certain centers. This movement of the soil particles is
in every case facilitated by the presence of a moderate
amount of moisture.

122. Forces facilitating granulation. — Granulation is
nothing more or less than a condition brought about by
the force exerted by a variable water film and the pull-
ing and binding capacities of colloidal material, operating
at numberless localized foci. It is evident that any influ-
ence or change in the soil which will cause a greater locali-
zation of these operative forces will promote in¢reased
granulation. The addition of materials from extraneous
sources is also a practice that may tend to develop lines of
weakness and thus cause a more intense localization of
the forces at work.

The conditions, additions, and practices tending to
develop or facilitate a granular structure in soils may be
listed under six heads: (1) wetting and drying of the soil,
(2) freezing and thawing, (3) addition of organic matter,
(4) action of plant roots and animals, (5) addition of
lime, and (6) tillage.

123. Wetting and drying. — The drying of a soil has
been shown to result in a drawing together of the particles
into aggregates. When this process is repeated again
and. again by alternate wetting and drying, the influence
on granulation becomes marked.

In drying, the small particles are moved into the spaces
between the larger ones, thereby reducing the volume
as is shown by the checks produced. These checks that
result from shrinkage are due to the unequal contraction.
There comes a time when the general film around the
whole mass must rupture, and it breaks along the lines
of least resistance. If the soil mass is very uniform, there
will be few breaks and the shrinkage will be mainly around

188 SOILS: PROPERTIES AND MANAGEMENT

a relatively few centers. This process produces clods,
or “overgrown” granules. If there are numerous lines
of weakness, however, there will be many centers of con-
traction, and consequently a larger number of small
clods, or granules, will be formed. ‘This is the desirable
condition and constitutes good tilth — that is, the most
favorable physical condition for plant growth.

Just what may be the effects of wetting and drying on
the colloidal matter of soil is a question. In general,
desiccation tends to flocculate colloids and in many cases
their binding power becomes highly developed thereby.
If such colloids are irreversible, as many in the soil un-
doubtedly are, this binding becomes more or less per-
manent, which explains the tendency for a crumb struc-
ture to persist. Wetting, on the other hand, tends to
develop colloidal matter which will become binding mate-
rial on the next drying. The desiccation and throwing
down of colloids, as well as their generation, thus be-
comes a very important factor in the wetting and drying
as related to granulation.

The following figures! represent the relative force
necessary to penetrate puddled clay dried once, as com-
pared with the same puddled soil wet and dried twenty
times. The relative hardness may be taken as a rough

measure of granulation : —
Percentage of pene-
tration

1. Puddled clay dried once. . . . 100.0
2. Puddled clay dried twenty times . 31.4
3. Puddled clay dried twenty times. 30.6
4, Puddled clay dried twenty times . 32.0

1¥Wippin, E. O. Some Causes of Soil Granulation. Trans.
Amer. Soc. Agron,, Vol. 2, pp. 106-121. 1910.

SOIL STRUCTURE 189

The fact illustrated above has many practical appli-
cations. It should be observed that the change in struc-
ture is not associated with continual wetness, nor is it
identified with a continued dry state. In neither condi-
tion is any force brought to bear on the particles. The
force is exerted only during the drying process and the
wetting process. It is a well-known fact that soils which
are continually wet are usually in bad physical condition.
In the drainage of wet land, it is found that the soil is at
first very refractory; but when good drainage is estab-
lished there is a gradual amelioration of the physical
condition, which is primarily a change in structure. On
the other hand, in a soil continually in a dry state there
is no change in granulation. The improvement of soil
structure, as a result of changes in the moisture content,
is dependent largely on lines of weakness in the soil mass.
Some of these are produced in the process of drying, and
others in the ways already listed.

124. Freezing and thawing.— As will be seen in
the consideration of soil moisture, the water is distributed
in the fine pores of the soil. When it freezes it forms long,
needle-like crystals. This crystallizing force is very
great, amounting to about 150 tons when a cubic foot of
water changes to ice. In freezing, the crystals gradually
grow first in the larger spaces. During this process there
is a marked withdrawal of moisture from the smallest
spaces, so that the ice crystals in the large spaces may be
built up. The soil mass is separated by the crystals, and
as the result of even a single hard freeze a wet, puddled soil
is shattered into pieces. The repetition of this process by
subsequent freezing and thawing will further break up the
soil by creating new lines of weakness. The granulating
power of freezing and thawing is shown in the following

190 SOILS: PROPERTIES AND MANAGEMENT

figures,) expressed as the relative force necessary to
penetrate a puddled clay treated in various ways: —

Percentage
penetration
. Puddled clay dried once . . . . . . . . 100.0
. Puddled clay frozen once and dried once . . 30.3

. Puddled clay frozen three times and dried once 27.3
. Puddled clay frozen five times and dried once. 21.8

Hq G2 BRO et

Freezing probably affects the colloidal material in
the same general way as does drying. This has been
indicated by the work of certain investigators,” in which
it was found that lowering the temperature of a soil below
freezing lowered the hygroscopic coefficient.

125. Addition of organic matter. — Soils rich in humus
or decomposed organic matter are generally in better
physical condition than soils low in organic content.
The marked effect of the absence of this material in many
long-cultivated soils is well known. For example, in
much of the southern New York hill regions, the soils
are now recognized to have a very different relation to
crop growth from what they had for a few years after
they were cleared. Their color has become lighter, and
with the decay of the humus a decided physical change
has taken place in the soil, which is to some extent cor-
rected by the restoration of the organic content. In
certain prairie soils the effect of humus depletion on struc-

1Fippin, E. O. Some Causes of Soil Granulation. Trans.
Amer. Soc. Agron., Vol. IT, pp. 106-121. 1910.

*Czermak, W. Hin Beitrag zur Erkenntnis der Veran-
derungen der Sog. physikalischen Bodeneigenshaften durch
Frost, Hitze, und die Beigabe einiger Salze. Landw. Ver.
Stat., Band 76, Heft 1-2, Seite 73-116. 1912. Also, Ehrenberg,

P., und Romberg, G. F. von. Zur Frostwirkung auf den Erd-
boden. Jour. f. Landw., Band 61, Heft 1, Seite 73-86. 1913.

SOIL STRUCTURE 191

ture is even more marked. While the actions of humus
are many, as has already been shown, its relationship to
physical condition is always particularly emphasized.

Humus contains much colloidal material and in this
way possesses a certain degree of plasticity. It is, how-
ever, of a very loose structure and the large spaces con-
stitute lines of weakness. Another property of humus is
that it undergoes great change in volume when dried
out — a property akin to the fineness of the soil, producing
larger shrinkage cracks. This is noticeable in many
black clay soils, which check excessively. The great
capacity of humus for moisture permits a wide range in
moisture content, which produces corresponding physical
alteration. ‘This wide swing from one extreme to another
is a potent factor in granulative influences. The color
of the humus affects the color of the soil, and thereby
increases the rate of change from the wet to the dry state
by increased evaporation of moisture. The relative
effects of crude muck, and the ammonia.extract from the
same muck, on the cohesion of a puddled clay, as indi-
cated by the force required for a uniform penetration of
a knife-edge, is shown in the following table; the samples
were dried and rewetted twenty times : —

Puppuiep Cray PLus Muck!

Percentage
of penetration
1.Clay . 2... 1 eee 100
2. Clay plus 5percentofmuck ... . 8
3. Clay plus 15 per cent of muck . . . . 7%
4. Clay plus 25 per centofmuck ... . 58
5. Clay plus 50 per centofmuck . . . . 50

1Fippin, H. O. Some Causes of Soil Granulation. Trans.
Amer. Soc. Agron., Vol. 2, pp. 106-121. 1910.

192 SOILS: PROPERTIES AND MANAGEMENT

Puppitop Cray puus Muck Exrractr }

Percentage
of pene-~
tration

1 Clay 2. 2. 2 1. we eee ee ee 100
2. Clay plus 1 per cent of extract . . . . . 85
3. Clay plus 2 per cent of extract . . . . . 7%
4. Clay plus 4 per cent of extract . . . . . 69

126. Action of plant roots and animals. — The exten-
sion of plant roots changes the soil structure by forcing
the particles apart at each growing root point, and possibly
also by some action yet to be explained. Crops differ
greatly in their effect on soil structure. Grass, millet,
wheat, and other plants with fine roots are more beneficial
to tilth than coarse or tap-rooted plants such as corn,
oats, and beets. Grass affects structure also by protecting
the surface of the ground. It is advisable to establish
a rotation on clay soil, that plowing may be done at fre-
quent intervals and that plants with different root devel-
opments may be given an opportunity to exert their
influences. The organic matter left in the soil by
decaying roots is always in very intimate contact
with the soil grains and has much to do with accelerat-
ing granulation.

Animals also affect soil structure. Earthworms, by
carrying materials to the surface, exert a mixing effect,
while the lines of seepage and zones of weakness developed
through their burrowing proclivities are of no mean im-
portance. Insects, especially ants and other burrowing
creatures, aid in this and in other ways.

1Fippin, E. O. Some Causes of Soil Granulation. Trans.
Amer. Soc. Agron., Vol. 2, pp. 106-121. 1910.

SOIL STRUCTURE 193

127. Addition of lime. — One of the important effects
of lime is in its flocculating action. This agglomeration,
as already explained under colloids, is the drawing to-
gether of the finer particles of a soil mass into granules.
When caustic lime is mixed with water containing fine
particles in suspension, there is almost immediately a
change in the arrangement of the particles. They appear
first to draw together in light, fluffy groups, or floc-
cules, which then rapidly settle to the bottom so that
the supernatant liquid is left clear or nearly so. This
phenomenon is termed flocculation, because of the
groups of particles. It is not an action limited to
caustic lime alone, however, but because of the useful-
ness of this compound in other ways, and because of
its very strong action, it is ordinarily used on soils.
This flocculating tendency when caustic lime is added
goes on in the soil as well as with suspensions, although
more slowly. In general the lime serves to satisfy the
adsorptive capacity of the colloidal material, and by
throwing down these colloids develops lines of weakness.
The cohesive power of the soil is thus localized and
granulation must necessarily occur.

The various forms of lime differ in their granulating
capacities, calcium oxide and calcium hydrate being very
active while calcium carbonate is relatively inactive in
this regard. For this reason, if flocculation effects are
desired, the oxide or hydrate combinations are added.
The relative influences of lime on puddled clay as measured
by penetration is shown in the following table;? the soil
was dried once and the untreated soil was used as 100
per cent : —

1Fippin, E. O. Some Causes of Soil Granulation. Trans.
Amer. Soc. Agron., Vol. 2, pp. 106-121. 1910.

194 SOILS: PROPERTIES AND MANAGEMENT

Percentage

of pene-

tration
1. Puddled clay . . 2 e ss « 100
2. Clay plus 2 per cent CaO resi)
3. Clay plus 4 percentCaO ..... . 48
4. Clay plus 6 percentCaO . .... . 3883
5. Clay plus 5 percent CaCO; . . .. . 98
6. Clay plus 10 per cent CaCO; . . . . . (Lil
7. Clay plus 25 per cent CaCO; . . . . «95

In the soil the oxide and hydrate revert to the carbonate,
but before this change occurs the flocculating effects have
been exerted and the lines of weakness so essential to
granulative processes have been developed. Lime really
does not produce granulation in a normal soil through
its own action alone, but is aided by the other influences
already discussed.

Warington ! reports a statement of an English farmer
to the effect that by the use of large quantities of lime on
heavy clay soil he was enabled to plow with two horses
instead of three. It is generally true that soils rich in
lime are well granulated, and maintain a much better
physical condition than soils of the same texture that
are poor in lime.

128. Tillage. — The effect of tillage on soil structure
is to produce lines of cleavage, and these, when produced
by plowing, are multitudinous and fairly uniformly dis-
tributed. Plowing, when the moisture content is suit-
able, tends to break the soil into thin layers, which move
one over the other like the leaves of a book when the pages

1 Warington, R. Physical Properties of Soil, p. 33.
Oxford. 1900.

SOIL STRUCTURE 195

are bent. This disturbance of the existing arrangement
of particles puts in motion the two forces that have al-
ready been discussed, the pull of the water film and the
binding power of the colloidal matter. The strength
of cohesion between small particles, such as clay, can be
realized when one considers the tenacity with which these
particles are held together in dried puddled soil. This
cohesive attraction is inversely proportional to the square
of the distance between the centers of the attracting bodies.
Particles that can be brought as closely together as can
clay particles may be thus held with great firmness.
The effect of tillage when an excess of water is present
is to force the particles into large masses and bring about
a generalized exertion of the forces of plasticity. The
soil then becomes puddled. ‘Tillage when the soil is
too dry results either in clodding or in the soil’s becom-
ing so pulverized that it becomes puddled on wetting.
As already emphasized, proper pulverization by tillage,
especially by plowing, may occur only when the soil is
in optimum moisture condition.

129. The action of the plow. — The plow brings about its
effects because of the differential stresses set up in the fur-
row slice as it passes over the share and the moldboard.
The soil in immediate contact with the plow surface is re-
tarded by friction, and the layers above tend to slide over
one another much as the leaves of a book when they are
bent. If the soil is in just the right condition, maximum
granulation results; but if the moisture is too high or too
low, puddling or clodding may follow, especially on a
heavy soil. Not only does a shearing occur, but this
shearing is differential, due to the slope of the share and
especially to the curve of the moldboard. Where the
soil is to be turned over with the least expenditure of

196 SOILS: PROPERTIES AND MANAGEMENT

force, the share is sloping and is set to deliver a slanting
eut, and the moldboard is long and gently inclined. This
allows the furrow slice to be turned with little granulation
and a minimum expenditure of energy. When maximum
granulation and pulverization are desired, the moldboard
is short and sharply turned, and the share is less sloping
and the cutting edge is less slanting. Such conditions
make for the development of more friction and the genera-
tion of those internal twisting and shearing stresses neces-
sary for good granulation. The sharper the bending of
the furrow slice, the greater are the internal stresses set
up. While the plow is the very best pulverizing agent
when optimum soil moisture conditions prevail, it is also
a most effective puddling agent when the soil is wet.
Therefore care in the judging of optimum conditions for
plowing is a most important feature in the maintenance
and encouragement of soil granulation and tilth.

130. Résume.— The factors controlling the struc-
tural condition of any soil are found to be plasticity and
cohesion. As these increase, the tendencies of a soil to
puddle when wet and to clod when dry are augmented.
Therefore, in heavy soils a decrease in these factors is
advisable, through a careful control of moisture and a
bettering of the granular structure of the soil. Granu-
lation, while due to some extent to the localized influence
of the water film, is traceable largely to the colloidal
matter which acts as a binding agent. It is really a
concentration of the forces of cohesion and_ plasticity
around numberless localized foci. Granulation takes
place under the influence of wetting and drying, freezing,
plants and animals, addition of humus and lime, and
tillage operations, especially plowing. Due to the high
cohesion and plasticity of heavy soils, the moisture zone

SOIL STRUCTURE 197

for successful plowing is relatively narrow. The ability
to detect when this zone has been reached in a clay soil
is one of the essentials of successful soil management.
Another essential is the effective widening of such a
zone by granulation operations. The optimum mois-
ture condition for tillage is also the optimum condition
for plant growth —a happy coincident, since by regu-
lating the moisture content for plant development condi-
tions are rendered most favorable for all soil activities.
It is thus possible to realize that criterion in all soil physi-
cal operations, 2 maximum tilth.

CHAPTER XI

THE FORMS OF SOIL WATER AND THEIR
MOVEMENT

UNpER all normal conditions the soil bears a certain
amount of moisture, which must be reckoned with in
any study whether of a practical or of a theoretical na-
ture. Moreover, the amount of water varies in its char-
acteristics according to its position. It also has move-
ment, which goes far in determining its usefulness to plants.
Before a discussion of the different forms of water, their
movement, and their availability to plants, may be entered
into, however, some way of quantitatively stating the
amounts present must be determined upon.

131. Methods of expressing soil moisture. — During
the many years of soil investigation, especially where the
problems had to deal either directly or indirectly with
moisture, five methods of water expression have been
evolved, their use depending on the nature of the work
and on the points to be expressed. These may be listed
under two general heads : —

A. Percentage expression
1. Percentage on a wet basis
2. Percentage on a dry basis
B. Volume expression
1. Cubic inches to the cubic foot of soil
2. Percentage by volume

3. Surface inches
198

THE FORMS OF SOIL WATER 199

The simplest way of explaining the application of these
methods for the expression of the amount of water in a
soil is by a specific case. Suppose a certain soil in field
condition weighs 100 pounds to a cubic foot and carries
10 pounds of water. Obviously it would contain 10
per cent of water by the wet method of calculation, or
11.1 per cent of water, using the absolutely dry soil as
a basis. A pound of water contains 27.6 cubic inches;
therefore the amount of water carried by this soil expressed
by volume would be 276 cubic inches for every cubic
foot of soil. The percentage by volume would equal
(276 + 1728) 100, or 16 per cent. An inch of water
covering the top of a cubic foot weighs 5.2 pounds. Ob-
viously the number of surface inches which this 10 pounds
of water would occupy if placed on the top of the cubic
foot of soil would be 10 + 5.2 or 1.92 surface inches.

The first method of moisture expression, as percentage
on a wet basis, is open to two serious objections. In the
first place, two different percentages of water in different
samples of the same soil do not represent the same degrees
of wetness as are expressed by the percentages. For
example, 100 grams of wet soil containing 5 per cent of
water would consist of 5 grams of water and 95 grams of
soil, a ratio of 1 to 19. If the soil contained instead 25
per cent of water, the ratio would be 1-3 instead of 1-3.8,
as the ratio of the percentages would naturally lead one
to expect. The second objection is just as serious and
arises from the fact that soils have different apparent
weights. For example, 5 per cent of water on the wet
basis for a clay weighing when dry 70 pounds to the cubic
foot would equal 3.72 pounds, while 5 per cent on a sand
weighing 100 pounds would give 5.25 pounds of the same
volume. The error of such a method of expression is

200 SOILS: PROPERTIES AND MANAGEMENT

obvious, not only in comparing the water content of the
same soil, but in comparing different soils as well.

In using a percentage of moisture based on the dry
soil instead of on the wet, the first of the above objections
is eliminated. Consequently this method of expression
is perfectly legitimate as long as soils having about the
same apparent specific gravity are compared. As soon
as soils of different weights are considered, however, a
more nearly accurate method must be employed. Ob-
viously, then, the only really rational mode of moisture
statement is by the volume method. In ordinary calcu-
lations of water, however, the percentage by dry weight
is generally used because of its simplicity and the facility
of expression that it affords. It is also much easier to
establish than a percentage based on volume.

The first and second methods of volume expression are
of about equal value as far as direct comparison goes. For
the actual water present the number of cubic inches to a
cubic foot of soil is perhaps preferable, as it shows the exact
amount of water contained and may easily be converted
to pounds to a cubic foot or tons to an acre as the case
may be. The third volume statement is generally used in
field practice, especially in irrigated regions, where water
is measured in inches in depth to an acre of area. Such
a statement of the available water in a soil not only is
convenient, but also gives a direct comparison with the
probable rainfall of the growing season.

132. Kinds of water in the soil. — As has already been
demonstrated, a soil of a definite volume weight has a
definite pore space which may be occupied by air or by
water, or shared by both, as the case may be. Of course,
an ideal soil for plant growth is one in which there is
both air and water, the proportions depending on the

THE FORMS OF SOIL WATER 901

texture and the structure of the soil and the character
of the crop. Assuming for the time being, however, that
the pore space is entirely filled with water, or, in other
words, that the soil is saturated, three forms of water
are found to be present — hygroscopic, capillary, and
free, or gravitational. These forms differ, not in their
composition, but in the position that they occupy in rela-
tion to the soil particles.

The hygroscopic and capillary water are both film
forms; that is, they surround the soil particle, being held
partly by the attraction of the particle and partly by the
molecular attraction of the liquid for itself. The hygro-
scopic film is very thin, being water of condensation, or
adsorption. When this film is satisfied and moisture is
still present, the capillary water film begins to form. The
line of demarcation between hygroscopic and capillary
water is not sharp. The general difference between the
two forms may be considered as being not only one of
position, but also one of movement, this power being pos-
sessed only by the capillary film. With a change in any
controlling condition, such as temperature, hygroscopic
water may change to capillary, or capillary water to
hygroscopic, as the case may be. As the capillary water
continues to increase and the film becomes thicker and
thicker, a point is at last reached at which gravity over-
comes the surface tension of the liquid and drops of water
form which tend to move downward through the air
spaces, being now subject to movement by the attrac-
tion of gravity. Free, or gravitational, water then also
becomes present in the soil. If water is still added, the
gravitational water continues to increase until the air
is almost entirely displaced and a saturated condition
results. There may be a change of capillary to free water

202 SOILS: PROPERTIES AND MANAGEMENT

or of free water to capillary with a change of structure,
temperature, or pressure, as was seen to be the case be-
tween the hygroscopic and capillary moisture. The forms
of water present in a saturated soil may be conveniently
represented by the following diagram : —

Fie. 30.— Diagram representing the three forms of water that may
be present in a soil.

133. Hygroscopic water.— The hygroscopic water
in a soil has been spoken of as the water of condensation,
or adsorption. It is, however, quite distinct from water
condensed on a surface colder than the atmosphere in
which it is placed. All bodies possess the power, to
a greater or less degree, of adsorbing water even when
at the same temperature as the air with which they are
in contact, provided, of course, that the air contains water
vapor. The hygroscopic film may be continuous or only
partly continuous, depending on the condition of the
surface. In fact, the movement of water over surfaces
is often greatly facilitated by an already existing hygro-
scopic film. External conditions being constant, the
amount of hygroscopic water of various materials -is
determined by two factors: (1) the characteristics of the
material itself, and (2) the amount of surface it exposes.

It is a well-known fact that various materials differ
in the amount of hygroscopic water they will hold, due
to the attraction of the substances themselves for water.
The differences in the thickness of the film is so slightly
altered, however, by differences in materials, that, other
factors being constant, the hygroscopic water becomes
a function almost entirely of surface. Glass becomes

THE FORMS OF SOIL WATER 208

far more hygroscopic when pulverized. Porous bodies
are especially high in hygroscopic water, sometimes
holding as much as 20 to 380 per cent of moisture. The
following data, drawn from Ammon?! and von Dobeneck,’
although no doubt faulty, illustrate the differences in
hygroscopicity of materials commonly found in soils
and make plain the complexity of the question when
applied to soil phases : —

PERCENTAGE OF HyGroscoriciry or DiIrreREnt SUBSTANCES
at 20° C. wHen Exposep ror One Day to SaruRATED
AIR

AMMON Von DosENnecK
Humus .......-. 15.96 18.04
Ferric oxide . . . .... 19.76 20.41
Kaolin re AZ 3.55
Limestone . .... .. 29 .o2
Quartz . ....... .07 17

One of the characteristics peculiar to colloids in partic-
ular is a high adsorptive power for moisture, this giving
them properties not usually possessed by crystalloids.
Gelatinous precipitates of silica, ferric oxide, and alumin-
ium oxide are good examples. Colloidal humus, gela-
tin, and agar are noted for their adsorptive powers. The
water in such cases is not simply adsorbed on the external

1Ammon, Georg. Untersuchungen uber das Condensa-
tionsvermégen der SBodenconstituenten fur Gase. Forsch.
a. d. Gebiete d. Agri.-Physik, Band IT, Seite 1-46. 1879.

2 Dobeneck, A. F. von. Untersuchungen uber das Absorp-
tionsvermogen und die Hygroskopizitat der Bodenkonstitu-
enten. Forsch. a. d. Gebiete d. Agri-Physik, Band XV,
Seite 163-228. 1892.

904 SOILS: PROPERTIES AND MANAGEMENT

expanses, but is distributed over the great internal sur-
face exposure. Such water cannot be expelled by ordi-
nary drying, but the material must be subjected to a high
heat in order to drive off even a part of the water so held.
The question is greatly complicated also by the fact that
some bodies have a chemical affinity for water. This
results in the formation of hydrates and other salts. Such
water cannot be expelled without the breaking-up of the
compounds.

Ordinary soil possesses to an extraordinary degree
the three characteristics already cited: that is, it exposes
a very large amount of free surface; it tends to generate
continuously large amounts of colloidal material such as
ferric hydrate, aluminium hydrate, silicic acid, and espe-
cially humic materials in a colloidal state; and it always
has present compounds having an affinity for water.
However, since these compounds are easily satisfied, and
also since the adsorptive power of colloids is due to the
surface exposed, it may be considered that, other condi-
tions being equal, the hygroscopicity of the soil is essen-
tially a surface phenomenon. Although for all practical
purposes hygroscopicity may be considered as having
special relation to surface, exact correlation is not easy
partly because of the difficulty of accurately determining
the surface exposed by a normal soil.

134. Effect of texture and humus on hygroscopicity. —
The question being thus reduced to a surface consideration,
it is evident that the texture of the soil, external factors
being under control, is the determining factor. The fol-
lowing figures from Loughridge,! by whom the hygroscopic

1Loughridge, R. H. Investigations in Soil Physies.
California Agri. Exp. Sta., Rept. of Work of the Agri. Exp.
Stations of California for 1892-3-4, pp. 76~77.

THE FORMS OF SOIL WATER 205

moisture was determined by exposing the air-dry soil at
15° C. to a saturated atmosphere and then drying at 200°
C., illustrate this point : —

Hyacroscopic Capacity or Various Sorts

Par cont Cuar
Marrriin RoMAIn- Hyaroscopic
Sorts ING IN SUSPENSION |WatER EXPRESSED
APTFR STANDING IN PERCENTAGE
FoR 24 Hours

l5eclays . . . .. 31.97 10.45

7elayloams . .... . 17.15 6.06
Qloams ........ 12.06 5.18
4. sandy loams woe ee 7.39 2.50
4sands ..... ... 2.93 2.21

rat epee PABA ERT RY RIN rpstinnerNmNNRR insane neAIY AT HM Teter meme ene

Apparently, the finer the soil, the greater is the hygro-
scopicity. The finer the soil, the higher also is the per-
centage of clay, and consequently the greater is the amount
of material likely to be present in a colloidal state. Asa
matter of fact, the hygroscopic moisture as shown above
is roughly proportional to the clay; and as clay, espe-
cially the finer forms, is largely colloidal in nature; the
colloidal content of a soil practically determines the hygro-
scopic content. This fact is the basis for Mitscherlich’s !
method of colloid estimation, in which hygroscopic mois-
ture determined under certain controlled conditions is
used as a relative measure of colloidal content. The vari-
ous grades of particles constituting the textural make-up
of a soil, then, do not possess the same weight in the deter-
mination of hygroscopicity, the dominant grade being
clay, especially that part which has, by either physical

1 Mitscherlich, E. A. This text, paragraph 111.

206 SOILS: PROPERTIES AND MANAGEMENT

or chemical means or both, been thrown into a colloidal
condition. Especially do the humous colloids, as has
already been shown, function in this regard, so that the
organic matter must be of very great importance In deter-
mining the hygroscopic capacity of any soil. The finer
the soil, the greater is the amount of hygroscopic water
merely because of the large area of surface exposed.
Also, any practice that will increase the colloidal material
— the humous colloids being very susceptible to increase
by proper soil management — the higher will be the per-
centage of this hygroscopic moisture. Texture and humus,
then, govern the hygroscopicity of most soils.

135. Nature of the film. — The nature of this thin film
which is designated as hygroscopic water has not as yet
been determined. Held so strongly by a molecular force
averaging probably 10,000 atmospheres, generated by
adhesion and cohesion, it is not definitely known whether
the film exists as a liquid or a vapor. Consequently it
cannot be expected to conform to the laws that are gen-
erally found to apply to capillary films. In many cases
the film may not be continuous, and being so very, very
thin, it may even possess a negative surface tension. The
radius of influence of a particle in water has been shown
by Chamberlain! to be about 1.5107" centimeters.
Within this zone the molecules of water are much restricted
in their motions. The thickness of the hygroscopic film on
quartz particles as calculated by Briggs? is 2.66 x 107°
centimeters, showing that the outer edge of the hygroscopic

1 Chamberlain, C. W. The Radius of Molecular Attrac-
tion. Physical Review, Vol. 31, pp. 170-182. 1910.

* Briggs, L. J. On the Adsorption of Water Vapor and of
Certain Salts in Aqueous Solution by Quartz. Jour. Phys.
Chem., Vol. 9, pp. 617-641. 1905.

THE FORMS OF SOIL WATER 207

film, where the water to a large extent loses its movement,
is considerably without this zone of influence. In order
to give some idea of the extreme minuteness of the hygro-
scopic film, it may be said that its thickness is less than
the diameter of the smallest known soil bacteria. In
moving from the surface of a particle outward through
an ordinary water film, passage is first made through the
zone of influence. When the edge of this is reached, an
area 1s passed through which continues with constantly
increasing capacity for molecular motion until the outer
edge of the hygroscopic film is crossed, where molecular
activity reaches its maximum.

136. Effect of humidity and temperature on hygro-
scopic water. —~ T'wo external conditions seem to affect
the amounts of hygroscopic water that a soil may hold
under definite conditions ~ humidity and temperature.
As a general rule, the higher the humidity, the higher is
the hygroscopic moisture. The experiments of von Dobe-
neck? with quartz and humus illustrate this point : —

PERCENTAGE OF HyGroscopic WATER HELD AT Various Humip-
ITIES AFTER AN Exposure or, Twenry-rour Hours at
20° C.

30 50 70 90 100
Per cent Per cent Per cent Per cent Per cent
Quartz . .045 053 .076 .119 175
4.055 7.765 10.589 | 15.676 18.014

The results as to the effects of a rise in temperature
on the hygroscopic film are not so definite. Most in-

1 Dobeneck, A. F. von. Untersuchungen tiber das Absorp-
tionsvermégen und die Hygroskopizitét der Bodenkonstitu-
enten. Forsch. a. d. Gebiete d. Agri.-Physik, Band XV, Seite
163-228. 1892.

2908 SOILS: PROPERTIES AND MANAGEMENT

vestigators! find that as the temperature is increased
the hygroscopicity becomes lowered, thus following the
general laws of adsorption. Hilgard, however, obtained
opposite results when the air was saturated, although his
data agreed with previous results when hygroscopicity
was studied in an atmosphere unsatisfied as to its capac-
ity for water vapor. King? explains this discrepancy
as being due to the very high vapor pressure generated
by a saturated atmosphere at high temperatures, causing
a more rapid taking-up of water by the soil than was
lost from iis surface. The time necessary for a soil to
assume its maximum thickness of adsorbed water is un-
certain. Hilgard? used seven hours in his determina-
tions, while Mitscherlich* exposed his soil for several
days. A soil continues to increase in weight slowly as
its time of exposure to moist air is increased, so that a
sharp line of demarcation between capillary and hygro-
scopic water is difficult to establish. Capillary water
may even be present in the minute interstices before the
hygroscopic film is elsewhere satisfied.®

137. Determination of hygroscopicity.— The method
of the determination of the maximum hygroscopicity of a
soil, or, in other words, the hygroscopic coefficient, is
simple in outline. The soil, in a thin layer, is exposed

1 Patten, H. E., and Gallagher, F. H. Adsorption of Vapors
and Gases by Soils. U. S. D. A., Bur. Soils, Bul. 51, p. 33.
1908.

*King, F. H. Physics of Agriculture, pp. 179-180.
Published by the author, Madison, Wisconsin, 1910.

’ Hileard, EH. W. Soils, pp. 196-201. New York. 1911.

4 Mitscherlich, E. A. Bodenkunde, pp. 56-58. Paul
Parey, Berlin. 1905.

> Briggs, L. J. The Mechanics of Soil Moisture. U. S.
D. A., Bur. Soils, Bul. 10, p. 12. 1897.

THE FORMS OF SOIL WATER 209

to an atmosphere of definite humidity under conditions
of constant temperature and pressure. Complications
arise from the necessity of using a very thin layer of soil,
from the difficulty of controlling humidity, and from the
tendency of capillary water to form in the soil interstices
before the hygroscopic film is satisfied. The question of
how long the exposure should take place is a very serious
factor, as has already been pointed out. In the drying
of the soil after exposure a vexing condition also is en-
countered, in that as the temperature is raised, the giving-
off of water vapor continues. It is evident, therefore,
that not only must any method be more or less arbitrary,
but that its value can be only comparative. The method
of Mitscherlich, as already described,! is probably the
most nearly accurate. He exposes the dry soil under
partial vacuum over 10 per cent sulfuric acid and water.
The partial vacuum is to hasten adsorption, and the acid
to prevent a fully saturated air, thereby cutting down
chances of dew deposition.

138. Heat of condensation. — The amount of energy
necessary to expel the hygroscopic film from around a
soil particle is very great, since its only movement is
thermal. As a matter of fact, it is really impossible to
divest the soil grain entirely without causing the loss of
moisture other than that simply adsorbed. As so much
energy is expended in removing this film, it is reasonable
to expect that a certain amount of heat of condensation
when the film is resumed would become apparent. Pat-
ten? offers the following quantitative data concerning
this point : —

1Mitscherlich, A. EH. This text, paragraph 111.
2Patten, H. EB. Heat Transference in Soils. U. S. D. A,
Bur. Soils, Bul. 59, p. 34. 1909.

210 SOILS: PROPERTIES AND MANAGEMENT

Heat Evouvep BY Wettina Sors Drizep at 110° C.

CALORIES PER

Sor Kito or Dry Sor.
Coarse quartz . . Soe ee ke es 150
Podunk fine sandy loam rar 200
Norfolk sand Soe ee ke 347
Hagerstown loam 1108
Galveston clay . Coke 3785
Muck soil (25 per cent organic matter) Loe 6413

139. Capillary water. — It has been shown in the pre-
vious discussion that a large proportion of the hygroscopic
film is beyond the radius of influence of the particle and
is not held so rigidly as is the inner portion. In other
words, in this film a certain amount of molecular move-
ment is possible, this movement depending on the dis-

Fic. 31, —~ Diagram
showing the rela-
tionship of the
hygroscopic and
capillary water
films surrounding
a soil particle.
(s), particle;
(7), zone of influ-
ence of particle;
(w), outer edge of
hygroscopic zone;
(c), capillary film.

tance from the particle. As soon, how-
ever, as the boundary of the hygroscopic
film is crossed, a comparatively thick
film of moisture is reached in which
molecular movement, except for the
influence of viscosity, is perfectly free
and unimpeded. These two zones (see
Fig. 31) —one in which capillary move-
ment is more or less free, and a com-
paratively thin film in which molecular
movement becomes increasingly slug-
gish as the radius of influence of the
soil grain is approached —are there-

fore clearly differentiated. The capillary water differs
from the hygroscopic moisture (1) in that it is largely in
a liquid state and consequently is governed by the ordi-
nary laws of liquids; (2) in that it evaporates at ordinary

THE FORMS OF SOIL WATER 211

temperatures, being held with less tenacitv; and (3) in
that it has the power of movement from place to place
within the film, hence the name capillary water.

140. Surface tension and the force developed thereby.
— The power that tends to hold this capillary water in
place against the force of gravity, a constant, depends
on the surface tension of the liquid. This phenomenon
of surface tension is due to the existence of certain molec-
ular forces acting from within. In a drop of water, for
example, the particles are attracted equally in all direc-
tions and consequently are able to move with perfect
freedom. The molecules on the surface of the drop,
however, are not in such an equilibrium of attraction,
since the pull of the water particles within is greater than
that of the air particles without. The resultant attrac-
tion is therefore inward, and is directed along a line per-
pendicular to the surface at that point. The result is
the development of a more or less ideal membrane, the
effective force of which is not affected by the amount of
the surface, but by the curvature. In a sphere the force
or pressure developed by surface tension is equal to twice
the surface tension divided by the radius. This increase
of the effective force by curvature of film is very impor-
tant as regards soil water, since, as will be shown later, it
governs the movement of capillary water from one particle
to another, the direction of the movement being deter-
mined by a difference in pressure as developed by un-
equal curvatures of film surfaces.

As a result of this force developed by surface tension,
the water film around a soil particle tends to equalize
itself until this pressure is everywhere the same. On
this force depends also the thickness of the capillary film.
Under any given condition this capillary film will con-

Y12 SOILS: PROPERTIES AND MANAGEMENT

tinue to thicken until the mass of the water Is so great
as to allow gravity to come into play and pull enough
water away to again restore the equilibrium. The soil
particle would at this point be maintaining its maximum
thickness of capillary film. It is also quite evident that
as the capillary film is thinned —as, for example, by
evaporation — the force developed by surface tension
would be increased, due to increased curvature of the
film, and the difficulty of removing the external layers
of the film would naturally become greater.

141. The form of water surfaces between soil particles.
——JIn the case of a soil, however, the question of the
capillary film becomes more complex, since a great num-
ber of different-sized particles are present in more or less
close contact with one another. This means that under
normal soil conditions the capillary film 1s continuous
from one particle to another — a very different question
to consider from that of a film about a single isolated soil
grain more or less
spherical in shape.
Suppose, for example,
that two particles,
Fic, 32. — Diagram showing the coalescence each Carrying @ capil-

and readjustment to the capillary film of lary water film, be

two soil particles when brought in con- .

tact. At left is shown the condition be- brought into such

fore adjustment with a sharp angle at B; contact that the films

at right the films are shown in equi-

librium with a great thickening at B. coalesce. There are
now two distinct sur-

faces — that at A, A’ (see Fig. 32), with the curvature
of the original film, and that at B, which is very acute
and which naturally must exert a very great outward
pull. Under the stress of this pull developed by the
surface tension acting in this film of very great curvature,

THE FORMS OF SOIL WATER 213

the water is drawn into the space between the particles,
where it becomes thicker than the capillary film about
the particles. This readjustment continues until the
forces developed by the two films become equal. An
equilibrium is now established. It is evident, then, that
as the capillary water becomes less in a soil from any
cause, the moisture collected in the spaces between the
particles becomes less and less, but still remains thicker
than the films about the particles themselves. What
percentage of the capillary water is held in the thickened
waists of the soil grains cannot be calculated, but it is
probable that this moisture makes up the major part
of the capillary water of any soil. One of the errors
in the determination of the hygroscopic coefficient of a
soil, as already pointed out, arises from the tendency
toward the formation of capillary water in these angles
between the soil particles before the hygroscopic film on
the grains themselves becomes satisfied.

142. Factors affecting amount of capillary water. —
As might naturally be expected, the factors that tend to
vary the amount of capillary water in a soil are several,
and their study 1s more or less complex, due to the second-
ary influences that they may generate. These factors
may be discussed under four heads: (1) surface tension,
(2) texture, (38) structure, and (4) organic matter.

143. Surface tension and the amount of capillary
water. — Any condition that will influence surface ten-
sion will obviously influence the thickness of the capillary
film, because of a variation in the forces thereby de-
veloped. A rise in temperature, by lowering the surface
tension, would consequently lower the capillary capacity
of the soil, and if the soil were capillarily saturated would
allow some of the water to become gravitational in its

214 SOILS: PROPERTIES AND MANAGEMENT

nature. A lowering of the temperature would cause a
change in the opposite direction. This theory has been
verified by certain experiments by King,! in which he
found, other conditions being constant, a very decided
influence on capillary water through change of tempera-
ture. Wollny ? has shown that a depression of from .65
per cent in sand to as high as 3.7 per cent in kaolin may
occur from a rise in temperature of twenty degrees. The
surface tension of a liquid may also be greatly changed
by the addition of salts, and, since the soil always carries
some material in solution, the surface tension, and conse-
quently the capillary capacity, might be expected to
increase. As a matter of fact, the soil solution is very
dilute, and even if large amounts of fertilizer salts were
added the adsorptive power of the soil would tend to
maintain a very dilute soil water at the surface of the
films. Again, as humus decay is continuously going on,
oily materials are probably produced which would tend
to spread over the capillary films and greatly reduce their
surface tension. Therefore, as far as is now known of the
two varying influences, temperature change is by far the
most potent in its influence on capillary capacity.

144. Texture and the amount of capillary water. —
The finer the texture of a soil, the greater is the number
of angles between the particles in which a film of capillary
water may be held; also, the actual amount of surface
exposed by the particles is immensely larger than in a

1 King, F. H. Fluetuations in the Level and Rate of Move-
ment of Ground Water. U. 8. D. A., Weather Bur., Bul. 5,
pp. 59-61. 1892.

*Wollny, E. Untersuchungen tiber die Wasserkopacitat der
Bodenarten. Forsch. a. d. Gebiete der Agri.-Physik, Band 9,
Seite 361-378. 1886.

THE FORMS OF SOIL WATER 215
coarse soil. Due to these two conditions, a soil of fine
texture will contain considerably more capillary water
than one of which the texture is coarse. The maximum
capillary capacity of a soil is not directly proportional to
the surface, as was roughly proved to be the case with
the hygroscopic coefficient. This is probably because
the angle exposures between the grains increase in number
as the texture becomes finer much faster than the actual
surfaces developed by the‘particles are generated. The
capillary water in any soil varies with the height of the
column. This comes about from the gravity effects
on the liquid surrounding the particle. If the liquid had
no weight, gravity would not be a factor and the same
thickness of film would be found at
any point in a soil column. Such a
condition would greatly simplify the
study of soil moisture. If a number of
particles (see Fig. 38) carrying maxi-
mum capillary films are brought together
vertically, the weight of the whole con-
ducting film is thrown momentarily on
the capillary surfaces at the top. The
capillary spaces at this point immediately

Fre. 33. —- Diagram

lose water downward, so that they may
assume a greater curvature and thus
support this extra weight thrown on
them. This curvature must be sufficient
to balance the curvature pressure of the
particles below plus the weight of the
water in the connecting films. The par-
ticles beneath are at the same time un-

showing the ad-
justment of the
capillary film in a
long column and
the appearance of
free or gravita~
tional water if the
weight is too
great for the sup-
porting films.

dergoing a similar adjustment with a set of particles still
farther below, losing water in order to allow a change of

216 SOILS: PROPERTIES AND MANAGEMENT

curvature. <A thinning of these films results, but not to
such an extent as in the particles above. The action
continues in this manner through each capillary surface
until equilibrium is established, the change in thickness
of film being less and less in each case due to the cumu-
lative support of the films above. If the amount of
capillary water present is too great to be supported by
the films, enough is lost by gravity at the bottom to
bring about an equilibrium. *The film is at its maximum
at the bottom of the column, but decreases in thickness
as the column is ascended, not only on the particles
themselves, but in the angle interstices as well. This is
necessary, as each successive film must support an in-
creased weight of water. It is, therefore, evident that
it 1s impossible to assign any definite figure as to the
capillary water capacity of a soil. Only relative or
comparative data mav be quoted. The following diagram

Fre. 34.—- Diagram showing the distribution of moisture in capillary
columns of soil of different textures. The end of each soil column
rests in free water.

THE FORMS OF SOIL WATER 217

(see Hig. 34) irom Buckingham * makes clear not only
the mfluence ot texture on capillary water, but also the
distribution of water in a capillary column.

ihe final méan water content of these soils was 10,
15, and 20 per cent, respectively, for the fine sand, the
sandy loam, and the clay; showing that as the texture
becomes finer, the greater is the average capillary content
even aiter allowing jor the differences im hygroscopic
moisture.

145. Effect of sttucture on the amount of capillary
moisture. — [he structure of the soil, or, in other words,
the arrangement of the particles, will become a factor in
capillary Capacity in so far as it ailects the amount of
eflective capillary surface. Any arrangement of parti-
cles that will increase the number of angles of contact will
evidently increase the amount of capillary water. ‘The
compacting oi 4 loose soil will increase the possible capil-
lary moisture untii all the interstitial space becomes
capillary in its nature; further compactine will then
Cause @ marked decrease. “The pranuiation of a clay soil,
by producing a crumb structure and by actually increas-
ing the eflective surface exposure, tends to increase its
Water-holding capacity. At the same time the compacting
Or & sand, by increasing not only the actual efrective sur-
face, but aiso the number oi angles possible for capillary
concentration, will cause a rise in the capillary capacity
or that soil.

In @ study of this kind it is very evident that the aver-
age data of a long column should be considered, since
the percentage Of Moisture at any One point is not in-
dicative of the true capillary capacity of 2 sol. Such

1 Buckingham, EH. Studies on the Movement of Soil
Moisture. U.S. D. A., Bur. Soils, Bull 33, p. 32 «1907.

9183 SOILS: PROPERTINS AND MANAGEMENT

ficures have been obtained by Buckingham * in his study of
loose and compact soils. The following curves repre-
sent the general trend of his results: —

eg ao We Go WATER

WiGHE? FROM WATER LEVEL
%

Fic. 35.— Diagram showing the efiect of 2 compaction upon the distri-
bution of moisture in capillary columns (2), loose sandy loam;
(7), compact sandy loam; (C), compact clay; (C’), loose clay.

While it is evident that the mean water content of the
comipact sandy loam 1s greater than that of the less com-
pact, the latter showed a higher percentage of moisture
up to about the tenth mech. The clay shows a more
Marked effect from compacting, dropping in the compact
Sampie almost as low as the sand, on the average, and
showing at about ten inches from the end of the column
a percentage Of moisture considerably below that oi either
the loose or the compact sand. It is obvious that the
farmer May GO much in the contro! of capillary water by
promotme a proper physical condition of his soil.

146. Organic matter and the amount of capillary mois-
ture. — Organic matter, especially when it has been
rediiced to the form of humus, has great capillary capac-
ity, tar excelling in this rezard the mineral constituents of
the soil. dis porosity aliords an enormous interna! sur-

+ Buckingham, H. Studies on the Movement of Soil Mois-
ture. U.S. D. A., Bur. Soils, Bul. 38, pp. 34-35. 1907.

THE FORMS OF SOIL WATER 219

face, while its colloids exert an affinity for moisture which
raises its water capacity to a very high degree. Its ten-
dency to swell on wetting is but a change in condition
incident to an approach to its maximum moisture con-
tent. The following data, taken from a compilation by
Storer,! give an idea of the cxpillary capacity of the soil
organic matter : —

Percentage
of water
1. Humous extract from peat . . . . . . 1200
2.-Non-acid extract from peat . . . . . 645
3. Vegetablemold ........ . £809
4. Peat . ....... 2... . . «190
5. Garden loam, 7 percent humus ... . 96
6. Illinois prairie soil . =. 2. ww we 57
7. Field loam, 3.4 percent humus ... . 52
8. Mountain valley loam, 1.2 per cent humus. 47

Even after allowance has been made for the increased
hygroscopic coefficient incident to an increase in organic
matter, the effect of the latter -s very strongly evident
on the capillary capacity of a soil. Besides this direct
effect, organic matter exerts a stimulus toward better
granulation, a condition in itself favorable to increased
water-holding power.

147. Determination of capillary water. — The capillary
water in a sample of field soil may be determined by mak-
ing a moisture test in the ordinary way for the total water
contained. This represents the hygroscopic plus the
capillary water. A determination of the hygroscopic
coefficient on another sample yields a figure which when

1Storer, F. H. Agriculture, Vol. I, p. 106. New York.
1910.

220 SOILS: PROPERTIES AND MANAGEMENT

subtracted from the total water will give the capillary
water present in the sample. The capillary water at
various points in a soil column may be obtained by sub-
tracting the hygroscopic coefficient from the various
percentages of moisture present, since the thin hygroscopic
film is not influenced by height of column or ordinary
structural conditions. In ordinary soils, however, the
differences in hygroscopicity are not so great but that
the total water retained in a soil column against gravity
serves aS a very good measure of relative capillary
capacity.

148. The moisture equivalent of soils. — Briggs and
McLane? have perfected a method of comparing soils
on the basis of their capacity to hold water against a
definite and constant centrifugal force of one to three
thousand times the force of gravity. The soils, in thin
layer, are placed in perforated brass cups which fit into
a centrifugal machine capable of developing the above
force, and are whirled until equilibrium is reached. The
resultant moisture percentage is designated as the mois-
ture equivalent. It really represents the capillary
capacity of a soil of minimum column length when
subject to a constant and known force or pull. The
finer the soil, the greater of course is the moisture
equivalent. The authors also found that 1 per cent of
clay or organic matter represented a retentive power of
about .62 per cent, while 1 per cent of silt corresponded
to a retention of .18 per cent. Representative data
which show the correlation of the moisture equivalent
to the textural properties of the various types are given
in the table on the following page.

1 Briggs, L. J., and MeLane, J. W. The Moisture Equiv-
alents of Soils. U.S. D. A., Bur. Soils, Bul. 45. 1907.

> PER-
sow kenor| St | Pere | oovmaan | roa
OR- OF or SILT fe) HQuiva-

ganic Sanps Cray LENT

1. Norfolk coarse sand 9 | 87.9 7.3 4.8 4.6
2. Norfolk fine sandy loam) 1.3 | 73.4 | 18.1 8.5 6.8
3. Yazooloam . . . .| 1.3 |.25.8| 64.1 10.1 18.9
4. Waverly siltlaom . .| 2.0 | 14.9| 62.9 22.2 24.4
5. Houston clay loam 3.7 | 30.9 | 42.5 26.6 32.4
6. Houston clay 1.4 |; 10.0} 56.6 30.4 38.2

149. The maximum retentive power of a soil. — An-
other determination has been devised by Hilgard! and
used to considerable extent by other investigators.? It
is designated as the maximum retentive power of a soil.
A small pertorated brass cup is used, having a diameter
of about 5 centimeters and capable of containing a soil
column 1 centimeter in height. A short column is used,
since it is only under such conditions that a soil may re-
tain against gravity the greatest amount.of water. Also,
the soil is able to expand or contract, as the case may be,
on the assumption of water until an equilibrium is reached.
A filter-paper disk is placed in the metal cup, and the soil
is poured in, gently jarred down, and stroked off level
with the top of the cup. The cup is then set in water
and the soil is allowed to take up its maximum moisture.
After draining, the weight of the wet soil plus the cup,
together with the weights previously obtained, will allow
the calculation of the total water contained by the soil.

150. Capillary movement. — It has already been shown
how different thicknesses of films on two particles tend

1 Hilgard, E. H. Soils, p. 209. New York. 1911.
2 This text, paragraph 181.

992 SOILS: PROPERTIES AND MANAGEMENT

to become equal, due to the pulling force developed by
the angle of curvature between the particles. It is evi-
dent that differences in curvature must be the motive

— -—~ force in the capillary movement

’ of soil water. Let it be supposed,
for convenience, that three equal
A spheres when brought in contact

Fic. 36.— Diagram show. contain unequal amounts of water
ing the mechamics of the jn the angles of curvature (see
a soil, The wea Fig. 36). In this case the greater
justment takes place in pull would exist at A, since the
the direction of (A) due .
to the high tension devel. @ngle here is more acute. Conse-
oped by the sharp film quently water must move through
curvature at this point. the connecting film until the pull

at A and that at B become the same. Such an adjust-
ment might go on over a large number of films, and if
one end of the column was exposed to an evaporation
of just the right rate and the other end was in contact
with plenty of moisture, large quantities of water would
be pumped by capillarity.

This capillary movement may go on in any direction in
the soil, since it is largely independent of gravity; yet
under natural field conditions the adjustment tends to
take place very largely in a vertical direction. When
a soil is exposed to evaporation the surface films are
thinned and water moves upward to adjust the ten-
sion. This explains why such large quantities of soil
water may be lost so rapidly from an exposed soil.
Capillary adjustment may go on downward, also, as is
the case after a shower. Here the rapidity of the ad-
justment is aided by the weight and movement of the
water of percolation.

The capillary adjustment in a soil may go on under

THE FORMS OF SOIL WATER 223

two conditions: (1) if the soil column is in contact with
free water; and (2) if no gravity water is present, the
movement being merely from a moist soil to a drier one,
an inexhaustible supply of water not being present. In
the first case the lower portion of the soil is entirely
saturated for a short distance above the free water sur-
face, due to the functioning of the pore spaces as true
capillary tubes; above this the film movement becomes
dominant. The second condition of capillary adjustment
is the one most commonly found in a normal soil, since a
water table a short distance below the surface is not
usually conducive to the best crop growth. In studying
the rate and height of capillary rise in any soil, however,
the maintenance of a supply of free water at the lower end
of the column is usually provided for, since this allows a
near approach to the maximum capillary capacity for any
point in the column.

151. Factors affecting rate and height of capillary
movement. — To persons familiar with the habits of grow-
ing plants it is evident that capillary movement must
play an important part in their nutrition, since the root-
lets are unable to bring their absorptive surfaces in con-
tact with all the interstitial spaces where the bulk of the
available water is held. Consequently a consideration
of the movement of capillary moisture is necessary, not
only as to its mechanics, but also as to the factors influ-
encing its rate and height of movement. These factors
are four in number: (1) thickness of water film; (2) sur-
face tension; (8) texture; and (4) structure.

152. Effect of thickness of water film on capillary
movement.—It has been repeatedly noticed, in the
study of the capillary adjustment between two soils, that
the lower the percentage of water, the slower is the rate

924 SOILS: PROPERTIES AND MANAGEMENT

of movement. This indicates that the thickness of the
film covering the particles and connecting the interstices
containing the bulk of the capillary water 1s, within
eertain limits, a dominant factor in rate of movement at
least. Let it be supposed that a withdrawal of water
occurs at A (see Fig. 37), the interstitial space between
two particles, the water surface being represented by the
dotted line aa’. There is an immediate increase in the

eee Cee curvature of this surface, and

(pas ~~ o water tends to flow through
\ the capillary film spaces at ¢
| and ce’, toward this area of
/ greater tension. If water con-
Fig. 87.— Diagram for the ex- tinues to be withdrawn at A,

planation of the effect of this adjustment continues

thickness of water film about with considerable ease until
soil particles upon ease of ;
capillary movement. the film channel at e and ¢
becomes so thin as to cause
its surface (bb’) to approach the edge of the hygroscopic
film surrounding the particle. The viscosity of the
water gradually becomes a factor at this point, imped-
ing the capillary adjustment toward A. This point of
sluggish capillary movement has been designated by
Widtsoe+ as the point of lento-capillarity.

The amount of capillary water delivered at any one
point, therefore, will obviously be influenced by the
thickness of the film and may consequently be taken
as a measure of rate of rise. A short soil column
should deliver more water from a constant source
than a longer one, due to the thicker films at the sur-

1 Widtsoe, J. A., and McLaughlin, W. W. The Movement
of Water in Irrigated Soils. Utah Agr. Exp. Sta., Bul. 115,
pp. 2238-231. 1912.

THE FORMS OF SOIL WATER 225

face of the former column. King! shows this by the
following data :—

EVAPORATION FROM THE SURFACE OF Sanp Couumns or Dir-
FERENT LUNGTHS, THEIR BASE BEING IN CONTACT WITH
Free WaAtER

EVAPORATION at Surrace

FT I E
Lenere or Cotumn in IncHEs tn INcHES A Day

6 114
12 Lit
18 080
24. 034

30 O19

Briggs and Lapham? found, in comparing the evapo-
ration from tubes of different lengths (85 and 165 centi-
meters, respectively) of Sea Island soil, that the shorter
column showed over five times as much evaporation in a
period of forty-two days. This diminished flow with the
thinner films is a vital point in plant production, since
wilting must occur as soon as capillary movement becomes
too sluggish to supply moisture fast enough for normal
development.

The thickness of film is important also in a considera-
tion of the height of rise in dry and moist soil respectively.
It is evident that the rate would be much more rapid in
the latter, but what as to total rise? Stewart, in study-

1 King, F. H. Principles and Conditions of the Movements
of Ground Water. U.S. Geol. Sur., 19th Ann. Rept., Part II,
p. 92. 1897-1898.

2 Briggs, L. J., and Lapham, M. H. Capillary Studies.
U. 8. D. A., Bur. Soils, Bul. 19, pp. 24-25. 1902.

Reported by Briggs, L. J.,and Lapham, M.H. Capillary
Studies. U.S. D. A., Bur. Soils, Bul. 19, p. 26. 1902.

9296 SOILS: PROPERTIES AND MANAGEMENT

ing the capillary limits as to the height of rise in dry and
moist Michigan soils, found this limit much greater where
the soil was damp. This vertical rise from a water table
was almost three times greater, on the average, in the soil
in which the films were originally thicker. Briggs and
Lapham ! found this ratio in Sea Island soil to be as high
as four and one-half; while Wollny ? has shown sand with
9.5 per cent of moisture to raise moisture from a water
table one-half higher in six days than did the same sand
dry. It is evident, therefore, that a soil with a thick
capillary film will carry moisture faster than one with a
thinner film, and also will raise the moisture higher when
the final film adjustment has taken place.

In an air-dry soil it is obvious that before capillarity
may take place a thicker film than has already existed
must be established. ‘This is often difficult because of the
presence of oily materials deposited on the surface of the
particles during the process of drying out. Such a condi-
tion probably accounts, at least partially, for the differ-
ence in total rise of capillary water in a dry and in a moist
soil, since, theoretically, if time enough were given for
adjustment, the total height should be the same in both
columns. This resistance of dry soil to the resumption
of a capillary film is made use of in soil mulches, where a
dry surface layer of the soil checks evaporation by imped-
ing capillary rise. It is also obvious that in a study of the
rate and height of capillary movement and the factors
affecting it, moist columns should be used, as this is a

1 Briggs, L. J., and Lapham, M. H. Capillary Studies.
U.S. D. A., Bur. Soils, Bul. 19, p. 26. 1902.

2 Wollny, E. Untersuchungen uber die Kapillare Leitung
des Wassers im Boden. Forsch. a. d. Gebiete d. Agri.~Physik,
Band 7, Seite 269-308. 1884.

THE FORMS OF SOIL WATER 227

near approach to the conditions of a field soil. Since this
is rather a difficult study to carry out, most of the rate
and height data on capillary movement have been largely
obtained with dry columns in contact with free water at
the bottom. Such data are comparative, but are far
from quantitative as regards the performance of any soil
under normal conditions.

153. Surface tension and capillary movement. — As
has already been shown, the thickness of a maximum
capillary film is largely determined by surface tension ;
and as surface tension with any given curvature exerts a
definite pressure, it is evident that this pressure may be-
come greater or smaller with variations in the surface
tension. One of the most potent factors having to do
with this variation is temperature. If the temperature
of a soil column in capillary equilibrium and containing
its maximum capillary moisture should be raised, some
of the water would be lost as free water, since the pulling
power of the films would be decreased. In the same
way, the capillary capacity would be increased by a lower-
ing of the temperature, which of course would mean a
higher capillary rise in either a dry or a wet soil. The
rate of movement,! however, would be facilitated in the
first case, since the viscosity of the water would be much
reduced, allowing the movement in the film channels to
take place with less friction.

King? has verified these conclusions in his experiments

1Wollny, E. Untersuchungen tuber die Kapillare Leitung
des Wassers im Boden. Forsch. a. d. Gebiete d. Agri.-Physik,
Band 8, Seite 206-220. 1885.

2King, F. H. Fluctuations of the Level and Rate of Flow
of Ground Water. U.S. D. A., Weather Bur., Bul. 5, pp. 59-
61. 1892.

298 SOILS: PROPERTIES AND MANAGEMENT

with the fluctuations of the ground water of a soil held
in a large cylindrical tank. He found that with a lower-
ing of temperature the ground water was lowered, due
to the increased capillary capacity of the soil generated
by a higher surface tension. A consequent upward move-
ment of water took place. When the temperature was
raised, however, there was a reverse movement, due to a
change of capillary water to free water brought about by
a, lowered surface tension.

The surface tension may also be varied by materials in
solutions, most salts tending to cause increased tension.
The addition of soluble fertilizer salts to a soil would
therefore be expected to exert some influence. It must
be remembered in this connection that all soils contain a
certain amount of oily substances, produced during the
processes of organic decay. It is probable that the lower-
ing effect of such material would largely overbalance
any marked influence from fertilizer salts. Moreover,
as such salts are strongly adsorbed by the soil particles,
their effect on the concentration of the surface film would
probably be light even if undisturbed by the soil resins.
Wollny! has shown that adsorbed salts produce little
effect on capillarity, while non-adsorbed salts cause a
depression increasing with concentration.

Briggs and Lapham? found that with Sea Island soil
dissolved salts in dilute solution had no appreciable effect
except in the case of sodium carbonate. The increased
rise in this case they ascribe to the saponification of the

1;Wollny, H. Untersuchungen uber die Kapullare Leitung
des Wassers Forsch. a. d, Gebiete d. Agri~Physik, Band 7,
Seite 269-308. 1884

* Briggs, J. B., and Lapham, M. H. Capillary Studies.
U.S. D, A., Bur. Soils, Bul. 19, pp. 5-18. 1902,

THE FORMS OF SOIL WATER 229

oils on the particles, and a consequent exposure of clean
surfaces for capillary movement. These authors found
also that concentrated solutions reduced the rate of
capillary movement. Davis,' in working with a silt loam,
obtained variable results, some salts depressing and some
accelerating capillary rise. Potassium acid phosphate
caused the maximum retardation, while ammonium ni-
trate most markedly increased the rate. Since only one
soil was used and the greatest observed capillary rise was
less than twelve inches, additional data must be presented
before it is clear that the concentration of salts may be-
come a very important factor in humid soils. In alkali
soils, in which the concentration of the salts is very great,
there is no doubt that considerable retardation may occur.

154. Effect of texture on capillary movement. — In
sous of fine texture, not only is the amount of film surface
exposed greater than in coarse soils, but the curvature of
the films is also greater, due to the shorter radii. The
effective pressure exerted by the films is consequently
much higher in fine-grained soil. The greater exposure
of surface and the increased pressure both serve to raise
the friction coefficient and retard the rate of flow. The
finer the texture of the soil, other factors being equal, the
slower is the movement of capillary water. Water should
therefore rise less rapidly from a water table through a
column of clay than through a sand or a sandy loam.

The height to which water may be drawn by the effec-
tive capillary power of a soil, equilibrium being estab-
lished, depends on the number of interstitial angles. The
greater the number of angles, the greater is the total

1 Davis, R.O. E. The Effect of Soluble Salts on the Physi-
eal Properties of Soils. U.S. D. A., Bur. Soils, Bul. 82, pp.
23-31. 1911.

230 SOILS: PROPERTIES AND MANAGEMENT

supporting power of the films. As a silt soil contains a
larger number of such angles, its capillary pull is greater
than that of a sand, and consequently the ultimate move-
ment would be of greater scope. The finer the texture,
then, the slower is the rate of capillary movement but the
greater is the distance.’

The relation of texture to rate and height of capillary
movement in dry soil is shown by the following un-
published data, obtained in the laboratory of the Depart-
ment of Soil Technology, Cornell University : —

Errect or Texture on Rato anp Hercur or CAPprminuLARY
Risz= rrRom 4A Warer TaBLE THROUGH Dry SoIL

Inches Inches Inches Inches Inches Inches

Sand ...| 35 | 5.0!] 59 | 68] 68 | 69
Clay ...| 5 | 5.7] 89 | 109 | 12.2 | 13.3
Sit... .| 25 | 145 | 206 | 242 | 26.2 | 27.4

It is seen that the movement in sand is rapid, one-half
of the total rise being attained in one hour. The maxi-
mum height is reached in about three days. The silt in
this case seems to be of just about the right textural con-
dition for a fairly rapid rise, yet it exerts enough capil-
lary pull to attain a good distance above the water table.
The friction in the clay is greater, however, and this
results in a slower rate. Whether the clay would ever be
able to exhibit a rise comparable with its tremendous pull-

1Wollny, E. Untersuchungen uber die Kapillare Leitung
des Wassers im Boden. Forsch. a. d. Gebiete d. Agri.-Physik,
Band 7, Seite 269-308. 1884. Also, Forsch. a. d. Gebiete d.
Agri.-Physik, Band 8, Seite 206-220. 1885.

THE FORMS OF SOIL WATER 231

ing capacity is doubtful, because of the resistance offered
by the dry soil.

155. Texture and the capillary pull of soils. — An ingen-
ious method for measuring quantitatively the capillary
pull exerted by a moist soil has been devised by Lynde
and Dupré.! The apparatus consists of a glass funnel
jomed to a thick-walled capillary tube by means of a piece
of rubber tubing, a water seal being used at this point.
The lower end dips into mercury. The soil to be studied
is placed in the funnel, and after being saturated is con-
nected by means of a wick of cheesecloth or filter paper
to the water column previously established in the capil-
lary tube. If no break occurs between the soil and the
capillary water column, the apparatus is ready for use.

The excess water having drained away, there is a
thinning of the films on the soil surface due to evapora-
tion. Equilibrium adjustments now take place, which
result in the drawing upward of the water column. The
mercury follows, and the strength of the pull may be meas-
ured by the height of the mercury column. The old
method of measuring capillary power by the water move-
ment through a dry soil is vitiated by two conditions
—the length of time necessary, and the fact that the
maximum lift cannot be obtained due to excessive fric-
tion. This new method uses a wet soil, requires only
a short time, and gives a more nearly accurate idea of the
power of the capillary pull. It does not, however, yield
data regarding rate of movement,—a factor of vital
importance to plant growth, as will be shown later.

Lynde and Dupré, in their results, confirm the state-

‘Lynde, C. J., and Dupré, H. A. On a New Method of
Measuring the Capillary Lift in Soils. Jour. Amer. Soc. Agron.,
Vol. 5, No. 2, pp. 107~116. 1913.

232 SOILS: PROPERTIES AND MANAGEMENT
ments already made regarding the relation of texture
to capillary power : —

Tap Capituary Lirr or Sor Separates aS DETERMINED BY
LYNDE AND DUPRE

Sor, DIAMETDR OF GRAIN, Lirr or Watnr

IN MILLIMETERS CoLuMN, IN Fret
Medium sand ... . 6 —.25 .98
Fine sand . ... . 25 —.10 1.78
Very finesand . .. . 10 —.05 4.05
Silt re .05 -.005 9.99
Clay . . .. .. . .005- 26.80

The capillary pull may also be established, at least
comparatively, by the height of the wetted soil and the
amounts of water at various points in a soil column that
has reached a capillary equilibrium when its base is in
contact with a constant supply of water. The curves
from Buckingham ! (Fig. 34, p. 216) determined after the
soil had stood for sixty-eight days, illustrate this.

156. Effect of structure on capillary movement. —
Structure has already been shown to affect capillary
capacity by its influence on the angle interstices. Evi-
dently, therefore, it may alter both the rate and the height
of capillary rise. The loosening of a clay soil or the
compacting of a sandy soil will lessen the effective film
friction, while at the same time it will strengthen the
capillary pull resulting in a faster and a higher capillary
flow of water. The exact structural condition of any soil
in which this result is realized to its highest efficiency it
is impossible to judge exactly. In general, however, this

1 Buckingham, E. Studies on the Movement of Soil Mois-
ture. U.S. D.A., Bur. Soils, Bul. 38, p. 32. 1907.

THE FORMS OF SOIL WATER 233

point is approached when the soil is in the best physical
condition for crop growth. ‘Tillage operations in general,
tile drainage, and the addition of lime and organic matter,
operate toward this result by their granulating tend-
encies; while rolling, by compacting a too loose surface,
may accomplish the same effect but by an opposite process.

At certain seasons of the year capillarity must be
impeded near the surface, as it continually pumps val-
uable water upward to be lost by evaporation. This
movement may be checked by producing on the soil sur-
face, by appropriate tillage, a layer of dry, loose soil.
This layer, called a soil mulch, affords much resistance
to wetting because of its dryness, while at the same time
it affords but little surface and few angle interstices for
effective capillary pull. Thus it is that a farmer, in order
to meet his immediate or future needs, may alter and
control capillary movement by careful attention to phys-
ical conditions, especially those at the surface where
evaporation is always active.

157. Gravitational water.—-As soon as the capillary
capacity of a soil column is satisfied, further addition of
moisture will cause the appearance of free water in the air
spaces. By the attraction of gravity, this water moves
downward through the earth at a rate varying with soil
and climatic conditions. In general the flow is governed by
four factors — pressure, temperature, texture, and structure.
An understanding of the operation of these forces is im-
portant, since the rapid elimination of free water from the
soil is necessary for optimum plant growth. The actual
procedure, however, is considered under the head of ‘“ Land
Drainage,” a distinct phase of soil management in itself.

158. Pressure and the movement of gravity water. —
It is very evident that any pressure exerted on a water

934 SOILS: PROPERTIES AND MANAGEMENT

column will accelerate the rate of flow. Under normal
conditions pressure may arise from two sources, baro-
metric pressure and the weight of the water column.
Changes in barometric pressure are communicated to
gravitational water through a movement of the soil air.
As the mercury column rises, more air is forced into the
soil and the pressure on the soil water increases. Such
a change has been observed by King! to produce as high as
a 15 per cent increase in the flow of drains. King observed
also that the level of wells fluctuated from time to time for
the same cause. The expansion of the air of the soil due to
daily heatings was also observed to produce diurnal oscil-
lations in the level and the rate of flow of ground water.

Perhaps of greater import in the rate of percolation of
water is the pressure produced by the weight of the free-
water column. Working along this line, Welitschkowsky ”
has shown rather conclusively that with an ideal length of
column the flow varies directly with the pressure. His
ideal column with the sand with which he experimented
was 75 centimeters in length. With a longer column the
flow did not increase as fast as the pressure; while with
a, shorter column, doubling the pressure more than doubled
the flow. These results have been verified by Wollny °
and ably reviewed by King.‘

1King, F. H. The Soil, p. 180. New York. 1906.

2 Welitschkowsky, D. von. Experimentelle Untersuchun-
gen tiber die Permeabilitat des Bodens fur Wasser. Archiv f.
Hygiene, Band II, Seite 499-512. 1884.

’Wollny, E. Untersuchungen uber die Permeabilitét des
Bodens fir Wasser. Forsch. a. d. Gebiete d. Agri.-Physik,
Band 14, Seite 1-28. 1891.

‘King, F. H. Principles and Conditions of the Movements
of Ground Water. U.S. Geol. Survey, 19th Ann. Rept., Part
II, pp. 67-206. 1897—-98.

THE FORMS OF SOIL WATER 235

159. Effect of temperature on the flow of gravity water.
— A rise in temperature of the soil not only varies the
amount of capillary water and thus increases the possible
free water present, but at the same time it increases the
fluidity and thus facilitates percolation. The expansion
of the soil air also tends to increase such movement. This
can be noticed in the operation of a tile drain in early
spring as compared with summer conditions. Calculated
effects of temperature change have been verified by con-
trolled experimental results.

160. Effect of texture and structure on the flow of
gravity water.— Of much more practical importance
than temperature, in the flow of gravitational water,
are the size and the arrangement of the soil particles.
In working with sands of varying grades, Welitschkowsky,}
Wollny,? and others have shown that the flow of water
varies with the size of particle, or texture. King? has
demonstrated that in general with such materials the
rate of flow is directly proportional to the square of the
diameter of the particle. By the use of the effective
mean diameter ¢ of a sand sample, he was able to calculate
a theoretical flow which compared very closely to observed
percolations. In sandy soils this law holds in a very
general way, but in clays it fails entirely. For instance,

1 Welitschkowsky, D. von. Experimentelle Untersuchungen
tiber die Permeabilitit des Bodens ftir Wasser. Archiv f.
Hygiene, Band II, Seite 499-512. 1884.

2Wollny, E. Untersuchungen uber den Hinfluss der
Struktur des Bodens auf dessen Feuchtigkeits- und Tempera-
turverhaltnisse. Forsch. a. d. Gebiete d. Agri.~Physik, Band
5, Seite 167. 1882.

3 King, F. H. Principles and Conditions of the Movements
of Ground Water. U.S. Geol. Survey, 19th Ann. Rept., Part
II, pp. 222-224. 1897-98.

4 This text, paragraph 87.

236 SOILS: PROPERTIES AND MANAGEMENT

if such a law was in force a sand having a diameter of
5 woillimeter would exhibit a flow 10,000 times greater
than that through a clay loam with a diameter, say, of
005 millimeter; whereas the actual ratio, as observed
experimentally by King, was less than 200.

Evidently, therefore, while it can be stated as a general
thesis that the flow varies with the texture, no governing
law can be deduced for soils since structure exerts such a
modifving influence. The percolation in a heavy soil
takes place largely through lines of seepage, which are
really large channels developed by various agencies.
If in the drainage of average soil, the farmer depended
on the movement of water through the individual pore
spaces, the soil would never be in a condition for crop
growth. These lines of seepage are developed by the
ordinary forces that function in the production of soil
granulation, as freezing and thawing, wetting and drying,
lime, humus, plant roots, and tillage operations.

A clear understanding of the factors governing the
flow of gravitational water is of especial importance in
tile drainage operations, particularly regarding the depth
of and interval between tile drains. Since percolation
is so slow in a heavy soil, it is evident that the tile must
be near the surface in order to secure efficient drainage.
In a sand the depth may be increased, because of the
slight resistance offered to water movement. The depths
for laying tile in a heavy soil range from one and a half
to two and a half feet, while in a sand the tile may often
be placed as deep as four feet below the surface. It is
evident also that the less deep a tile drain is laid, the
less distance on either side it will be effective in removing
the water; consequently on a clay soil the laterals must
be relatively close, as compared to the interval generally

THE FORMS OF SOIL WATER 237

recommended for a sandy soil. A rational understanding
of the movements of gravitation water is clearly necessary
in the installation of tile drains, not only that the system
may be fully effective, but also that a minimum effective
cost may be realized.

161. Determination of the quantity of free water that
a soil will hold. — While there is no particular advantage
in finding the quantity of gravitational water that a soil
will hold, since a normal soil should never remain saturated
for any length of time, it is nevertheless of interest to
know by what methods such data may be obtained. One
method is to saturate a column of known weight, and
then, by exposing it to percolation, measure the amount
of water that is lost. The gravitational water can then
be expressed in terms of dry soil. The disadvantage in
this method lies in the fact that it is extremely difficult
to free a soil entirely of air, so that a determination made
in this way would yield low results. Again, a very long
time must elapse before a soil will give up all its gravita-
tional water. JXing! found that with even a sand the
draining-away of the free water continued over a space
of two and one half years. It must also be noted here
that because of the lessening of the capillary water as a
column of soil is ascended, the space for possible free
water increases, thus accounting for the ready entrance
of rain into a soil which on the average may contain a
relatively high water content.

162. The calculation of the free water of a soil.— A
more nearly accurate idea of the possible free-water
capacity of soil may be obtained by calculation. If the
absolute and the apparent specific gravity of a soil, and

1King, F. H. Physics of Agriculture, pp. 134-135. Pub-
lished by the author, Madison, Wisconsin. 1910.

238 SOILS: PROPERTIES AND MANAGEMENT

its percentage of moisture when capillarily satisfied, are
known, the following formula may be used : —

(percentage of pore space
Percentage of air space when | _ | — (percentage of H,0

capillarily saturated x ap. sp. gr.)
Percentage of free water pos~ _ (percentage of air space
sible ap. Sp. gr.

163. Value of studying flow and composition of gravita-
tional water. — While the determination of the possible
free water that a soil will hold is of little real value, a
knowledge of its movement and its composition is of
vital importance. It has already been shown how the
rate of movement of such water is a factor in efficient
drainage. The amount likely to be thus lost is of interest
in plant production from two standpoints: first, the
réle that water plays as a food and a regulator; and
secondly, the losses of nutritive elements that always
occur with drainage. It is quite evident that these
questions should be studied only on soil in a normal field
position. Consequently two methods of procedure are
open — the use of an efficient system of tile drains, and
the construction of lysimeters.

164. The study of gravity water by means of tile drains.
—— In the first method an area should be chosen where
the tile drain receives only the water from the area in
question and where the drainage is efficient. A study
of the amounts of flow throughout a term of years will
yield much valuable data concerning the factors already
discussed. An analysis of the drainage water will throw
light on the ordinary losses of plant-food from a normal
soil under a known cropping system. The advantage

THE FORMS OF SOIL WATER 239

of such a method of attack lies not only in the fact that
a large area of undisturbed soil is considered, but also
in the opportunity to study practical field treatments
in relation to the movement and composition of drainage
water.

165. The lysimeter method of studying gravitational
water. — The lysimeter method, however, has been the
usual mode of attacking these problems. In this method
a small block of soil is used, being entirely isolated by
appropriate means from the soil surrounding it. Effective
and thorough drainage is provided. The advantages of
this method are that the variations found in a large field
are avoided, the work of carrying on the study is not so
great as in a large field, and the experiment is more easily
controlled. One of the best-known sets of lysimeters
was that established at the Rothamsted Experiment

Grade
“Tagen
ack «

out ty” ne Dae “oe se
M es ne in ear SO ne me
CREON PLP he

Caen) .
me et ee

*. “4 * ** Cd
.
oF a a Fie Py e soe * 7 _ fe ai . *
> are pa ‘ 2 ete ts mee
hd ee t * * s “e ad s * +

. . ‘
He eee

Cs ER jer
‘
a ae a
+ Cocwmpumnall ©
cr) anes Ge
‘
Cn 6
=n a
pond
: ____]”
Se ¢
‘Tr’
Fae Miemeenionne (iP
Ss wane Wes
eT.
‘tld.
°C ompunmenl ”.
oo
*
_—
Cr
as
Lb a a
© orem
Co manne ie
as
a oe
sesame
*
Ps Saee SNR
© Rewunpernne
- J 1]
‘Td
ais SU Ce
5 real
Ps tan
ae
Pe ied
Po ea
een os
© Hagen
a
i mans eee
L) eae
bs Rem amin
Oo cnmerrenni
.
Salen
eee ervanad
.
.
*

* . .
. ”
ot ete

ar s
=»
.

Fig. 38.— Cross section of a lysimeter at the Rothamsted Experiment
Station, England. (n’), soil column under study; (p), outlet for
collected drainage water.

240 SOILS: PROPERTIES AND MANAGEMENT

Station? in England. (See Fig. 38.) Here blocks of
soil one one-thousandth of an acre in surface area were
isolated by means of trenches and tunnels, and, supported
in the meantime by perforated iron plates, were separated
from the surrounding soil by masonry. The blocks of soil
were twenty, forty, and sixty inches in depth, respectively.
Facilities for catching the drainage were provided under
each lysimeter. The advantage of such a method of
construction lies in the fact that the structutal condition
of the soil is undisturbed and consequently the data are
immediately trustworthy.

ween ge
*

*,
Sateen te

ive Ginter Puddle

wrtage

ie Rahat ae Nee she

ee Ae ite tegen PES... wy ete

UBS ae SE EH a i ats
: Cinder Podetle: = wat aw oe

Os é ‘Sewer Tie O

Fig. 39.—- Cross section of a soil tank at Cornell University, New
York. (a), soil under investigation; (p), outlet of drainage pipe.

1 Lawes, J. B., Gilbert, J. H., and Warington, R. On the
Amount and Composition of the Rain and Drainage Waters
Collected at Rothamsted. Jour. Roy. Agr. Soc., Ser. II, Vol.
17, pp. 269-271. 1881.

THE FORMS OF SOIL WATER 24-1

At Cornell University ! a system of cement tanks sunk
in the ground has been constructed. Each tank is about
four and a half feet square and four feet deep. A sloping
bottom is provided, with a drainage channel opening into
a tunnel beneath and at one side. As the tanks are ar-
ranged in two parallel rows, one tunnel suffices for both.
(See Fig. 39.) The sides of the tanks are treated with
asphaltum in order to prevent solution. The soil must
of course be placed in the tanks, this causing a disturb-
ance of its structural condition. As a consequence data
as to rate of flow and composition of the drainage water
are rather unreliable for the first few years. Such an
experiment must necessarily be one of long duration.

166. Thermal movement of water. — Little has been
said as yet regarding this third mode of water movement,
the vapor flow, which is not peculiar to one form of soil
water but affects all alike. It is at once apparent that
the movement of water vapor can be of little importance
within the soil itself, simce it depends so largely on the
diffusion and convection of the soil air. While the soil
air is no doubt practically always saturated with water
vapor, the loss of moisture by this means is slight. Buck-
ingham ? has shown that, while sand allows such a move-
ment to the greatest degree, the loss occurring in a soil
with any appreciable depth of layer is almost negligible.

The question of the thermal movement of water at the
soil surface, however, is vital in farming operations. At
this point the water films are exposed to sun and wind,
and drying goes on rapidly, the free, capillary, and a

tLyon, T. L. Tanks for Soil Investigation at Cornell Uni-
versity. Science, N. Ser., Vol. 29, No. 746, pp. 621-623. 1909.

2 Buckingham, E. Studies on the Movement of Soil
Moisture. U.S. D. A., Bur. Soils., Bul. 38, pp. 9-18. 1907.

249 SOILS: PROPERTIES AND MANAGEMENT

part of the hygroscopic water vaporizing in the order
named. If the loss of the surface moisture were the
only consideration, the problem would not be serious;
but the capillarity of the soil must be considered also.
As the films at the surface become thin a capillary move-
ment begins, and if the evaporation is not too rapid a
very great loss of water may occur in a short time.

The evaporation from a bare soil in the Rothamsted
lysimeters! averaged about seventeen inches a year,
with a rainfall ranging from twenty-two to forty-two
inches. This means that from one-third to one-half of
the effective rainfall was entirely lost as thermal water.
The necessity of checking such a loss becomes apparent,
especially in regions where rainfall is slight or drought
periods are likely to occur. As no country is free from
one or the other of such contingencies, the great promi-
nence that methods of moisture conservation hold in
systems of soil management is understandable. While
means of checking losses by leaching and run-off are
advocated, effective retardation of surface evaporation
is always particularly emphasized.

1 Warington, R. Physical Properties of the Soil, p. 109.
Clarendon Press, Oxford. 1900.

CHAPTER XII

THE WATER OF THE SOIL IN ITS RELA+
TION TO PLANTS

Water, as has already been shown, is one of the external
factors in plant growth in that it is necessary in the
processes of weathering, which results in the simplifica-
tion of compounds for plant utilization. It also func-
tions as an internal factor in plant development, inasmuch
as it maintains the turgidity of the plant cells, acts as a
carrier of food materials, functions as a regulator, and
can actually be utilized as a source of hydrogen and
oxygen. These direct or indirect functions of water in
relation to plant growth may be considered under three
heads, as follows : —

167. Functions of water to the plant. —

1. Water acts as a solvent and a carrier of plant-food
materials. It is therefore a medium of transfer
for the mineral and gaseous elements from the
soil to their proper places within the plant.

2. As a food water either becomes a part of the cell
without change, or is broken down and its ele-
ments are utilized in new compounds.

3. Water in maintaining turgidity, in equalizing the
temperature by evaporation from the leaves, and
in facilitating quick shifts of food from one part
of the plant to another, acts as a regulator during
assimilation and while synthetic and mevabolic

processes are going on.
243

944 SOILS: PROPERTIES AND MANAGEMENT

Soil moisture, therefore, in proper amounts, becomes
one of the controlling factors in crop growth and must
be looked to before the maximum utilization of the
primary elements can be expected. The amount of
water held within the plant is not large, however, in
comparison with the amount lost by transpiration, al-
though green plants contain from 60 to 90 per cent of
moisture. The main cause of the high transpiration of
most crops is traceable to the dilute condition of the
soil solution, although certain regulatory functions may
also come into play.

Since relatively few parts to a million of nitrogen,
phosphorus, and potash are carried by the soil solution,
large quantities of water must be taken up in order that
sufficient quantities of food may be supplied to the plant.
This excess water is largely lost or disposed of by trans-
piration, at the same time performing its regulatory
functions.

168. The water requirement of plants. — As might be
expected, the pounds of water transpired for every pound
of dry matter produced in the crop is very large. This
figure, called the transpiration ratio, or water require-
ment, ranges from 200 to 500 for crops in humid regions,
and almost twice as much for crops in arid climates.
An accurate determination of the transpiration ratio of
a crop is somewhat difficult, due to the methods of pro-
cedure necessary and also to the difficulty of controlling
the numerous factors that may vary the transpiration.
For really reliable figures the plants must be grown in
cans or pots, in order that the water lost may be deter-
mined accurately by weighing. If there is no percolation,
the water ordinarily lost from a cropped soil includes
both that evaporated from the soil surface and that

WATER OF SOIL IN ITS RELATION TO PLANTS 245

transpired from the leaves. The former loss may be
eliminated from calculations in two ways: (1) by covering
the soil in some way so that evaporation is absolutely
checked and the only loss is by transpiration; or (2) by
determining the evaporation from a bare pot and, by
subtracting this from the total water loss from a cropped
soil, finding the loss due to transpiratior alone.

An objection to the former method is that any covering
which interferes with evaporation interferes with proper
soil aération also and may render soil conditions abnormal.
In the second method, however, an even more serious
error enters, since the evaporation from a bare soil is
not the same as that from a soil covered by vegetation
because of the shading effects. Also, due to the action
of the roots, less water is likely to be allowed to move
to the surface by capillary attraction in the cropped soil.
Therefore, any data that may be quoted can be only
general in its application, not only because of the errors
of determination but also because of the great number of
factors that under normal conditions may vary the
transpiration ratio. The data on the following page,
drawn from various investigators working by the gen-
eral methods! already outlined, give some idea of the
water transpired by different crops, due allowance being
made for various disturbing factors. Below the data
regarding transpiration will be found the citations to
the work of the various authors as well as a few
notes regarding their experimental procedure.

1A brief discussion of the various methods is found as follows:
Montgomery, E. G. Methods of Determining the Water
Requirements of Crops. Proc. Amer. Soc. Agron., Vol. 3,
pp. 261-283. 1911. Also Briggs, L. J., and Shantz, H. L.,
The Water Requirement of Plants. U. 8. D. A., Bur. Plant
Ind., Bul. 285. 19138.

246 SOILS: PROPERTIES AND MANAGEMENT

Water REQUIREMENTS oF Puants BY DirFERENT

INVESTIGATORS

a a Zz |e A ce

ae Pate G8 alt S Bin | he <n 2286

4 ss ia A esl Mm on BO

K: 2 ee E E oO | ae | ao ct
Barley . . . . .|258| 774 | 310 | 464 | 468 534
Beans . . . . ./209| — | 282 | — — 736
Buckwheat . . .| — | 646 | 363 | — — 578
Clover . . . . ./269)| —- | 310 | 576 | — 797
Maize . . .. .| — | 238 — |271 | 337 368
Millet . . . . .| —| 447) — — — 310
Oats . . .| — | 665 | 376 | 503 | 469 597
Peas . o. . « . {259} 416 | 273 | 477 | 563 788
Potatoes . . ..j/—|— — | 385 — * 636
Rape .... .[/—j)]912); — | — — 441
Rye... . . | | om | 358 | — — 685
Wheat . . . . .|247;| — | 388 | — | 544 513

1 Lawes, J. B. Experimental Investigation into the Amount
of Water Given off by Plants during their Growth. Jour.
Hort. Soe. London, Vol. 5, pp. 38-63. 1850.

Pots holding 42 pounds of field soil were used. Evaporation
from soil was reduced to a very low degree by perforated glass
covers cemented on the pots. The figures quoted are from
unfertilized soil.

*Wollny, E. Der Einfluss der Pflanzendecke und Beschat-
lung auf die Physikalischen Higenschaften und die Frucht-
barkeit des Bodens, Seite 125. Berlin, 1877.

Wollny grew plants in humous sand in amounts ranging from
5 to 12 kilograms. Evaporation was reduced to a very low
degree by perforated covers. Actual evaporation from un-
cropped cans was observed, however.

* Hellriegel, H. Beitrige zur den Naturwissenschaftlichen
Grundlagen des Ackerbaus, Seite 663. Braunschweig, 1883.

Hellriegel grew plants in 4 kilograms of clean quartz sand
and. supplied them with nutrient solutions. The loss by evap-
oration from uncropped pots was used in determining losses

WATER OF SOIL IN ITS RELATION TO PLANTS 247

169. Factors affecting transpiration. — These figures
serve to indicate not only the variation between crops,
but also the great effect of climate and soil on transpira-
tion. The factors may be listed under three heads, as
follows :—

1A complete review of the literature concerning the climatic
and soil factors in their effect on transpiration may be found
as follows: Briggs, L. J., and Shantz, H. L. The Water
Requirement of Plants. U.S. D. A., Bur. Plant Ind., Bul.
285. 1913.

by transpiration. In later experiments covers were used in
order to cut down evaporation.

4King, F. H. Physics of Agriculture, p. 139. Published
by author, Madison, Wisconsin, 1910. Also, The Number of
Inches of Water Required for a Ton of Dry Matter in Wis-
consin. Wisconsin Agr. Exp. Sta., llth Ann. Rept., pp. 240-
248. 1894; and The Importance of the Right Amount and
Right Distribution of Water in Crop Production. Wisconsin
Agr. Exp. Sta., 14th Ann. Rept., pp. 217-231. 1897.

King used cans holding about 400 pounds of soil. Some were
set down into the earth while others were not. Part of the
work was carried on in the field; the remainder was run in
vegetative houses. Normal soils were used. Evaporation
from soil was very low, water being added from beneath. The
data quoted are the average of a large number of tests.

5 Leather, J. W. Water Requirements of Crops in India.
Memoirs, Dept. Agr., India, Chem. Series, Vol. I, No. 8, pp.
133-184, 1910, and No. 10, pp. 205-281. 1911.

Jars containing from 12 to 48 kilograms of soil were used.
Loss by evaporation was determined on bare pots. The plants
were grown in culture houses or in screened inclosures.

6 Briggs, L. J., and Shantz, H. L. Relative Water Require-
ment of Plants. U.S. D. A., Jour. Agr. Research, Vol. III,
No. 1, pp. 1-68. 1914. Also, The Water Requirements of
Plants. U.S. D. A., Bur. Plant Ind., Bul. 284. 1913.

Plants were grown in cans holding 250 pounds of soil. HEvap-
oration from soil was prevented by means of a paraffin covering.
Work was conducted in screened inclosures. The data are the
average of several years’ work.

248 SOILS: PROPERTIES AND MANAGEMENT

1. Crop. — Differences due to different crops and to
variations of the same crop.

2. Climate. — Rain, humidity, sunshine, temperature,
and wind.

3. Soil. — Moisture and general fertility.

170. Effect of crop and climate on transpiration. —
Not only do different crops show a variation of tran-
spiration in the same season, but the same crop may give
a totally different transpiration in different years. This
is due in part to inherent differences in the crop itself.
For example, leaf surface or root zone would totally
alter the transpiration relationship under any given
condition. However, a great deal of the variation ob-
served in the ratios already quoted arises from differences
in climatic conditions. As a general thing, the greater
the rainfall, the higher is the humidity and the lower is
the relative transpiration. This accounts for the high
figures obtained by Widtsoe? in arid Utah. Mont-
gomery * found, in studying the water requirements of
corn under greenhouse conditions, that an increase in
the percentage humidity from 42 to 65 lowered the tran-
spiration ratio from 340 to 191. In general, temperature,
sunshine, and wind vary together in their effect on tran-
spiration. That is, the more the sunshine, the higher is
the temperature, the lower is the humidity, and the

1Widtsoe, J. A. Production of Dry Matter with Differ-
ent Quantities of Irrigation Water. Utah Agr. Exp. Sta.,
Bul. 116. 1912. Also, Irrigation Investigations. Factors In-
fluencing Evaporation and Transpiration. Utah Agr. Exp.
Sta., Bul. 105. 1909.

2 Montgomery, E. G., and Kiesselbach, T. A. Studies in
Water Requirements of Corn. Nebraska Agr. Exp. Sta.,
Bul. 128, p. 4. 1912.

WATER OF SOIL IN ITS RELATION TO PLANTS 249

greater is likely to be the wind velocity. All this would
tend to raise the transpiration ratio.

171. Effect of soil moisture on transpiration. — From
the soil standpoint, however, the factors inherent in the
soil itself are of more vital importance as regards ‘tran-
spiration, since they can be controlled to a certain extent
under field conditions. An increase in the moisture con-
tent of a soil usually results in an increased transpiration
ratio. The work of Hellriegel! with barley grown in
quartz sand containing a nutrient solution may be cited
in this regard, together with the data obtained by Mont-
gomery? at Lincoln, Nebraska, with corn grown in a
loam soil: —

Errnoct or Sorin Moisture on TRANSPIRATION

BaRLey—-—— HYELuRIEGLL Corn — Monrcomury

Soul Moisture Per-
centage of Total
Capacity

Soil Moisture Per-
centage of Total

Transpiration
Capacity R

Transpiration
atio R

ato

80 277 100 290

60 240 80 262
40 216 60 239
30 223 45 229
20 168 35 252
10 1380

easement meer itr pe epee ieAt lina ipl nt sam enter ein A fea N eA POaI

These data show clearly that an excessive amount of
water in the soil is not a favorable condition for the

1 Hellriegel, H. Beitrage zu den Naturwissenschaftlichen
Grundlagen des Ackerbaus, Seite 639. Braunschweig. 1883.

2 Montgomery, E. G. Methods of Determining the Water
Requirements of Crops. Proc. Amer. Soc. Agron., Vol. 3,
p. 276. 1911.

950 SOILS: PROPERTIES AND MANAGEMENT

economic use of water, as the plant, in order to supply
itself properly with food, must transpire excessive amounts
of water. As soil moisture may be controlled, this waste
may to a certain extent be eliminated.

172. The influence of fertility on transpiration. — The
amount of available plant-food is also concerned in the
economic utilization of water. In general the data along
these lines show that the richer the soil, the lower is the
transpiration ratio. Therefore a farmer, in raising the
general fertility of his soil by drainage, lime, good tillage,
green manures, barnyard manures, and fertilizers, provides
at the same time for a greater amount of plant production
for every unit of water utilized. Again, quoting from
Hellriegel and Montgomery, the following figures are
available : —

Errect or tan Suppity oF Puant-Foop MarfrRiaLs ON THE
TRANSPIRATION Ratio oF BARLEY GROWN IN QuaRTzZ SAND
with A Nurripnt Souutrion; Caxicrum NITRATE BEING IN
tan Minimum. HE.uRIEGEL !

Units? or Ca(NQs)e Dry Marrer PRopucep

APPLIED per Por (GRAMS) TRANSPIRATION Rario

0 1,111 724
4 8,479 399
8 13,936 347
12 18,288 345
16 23,026 302
20 29,004 292

1 Hellriegel, H. Beitrage zu den Naturwissenschaftlichen
Grundlage des Ackerbaus, p. 629. Braunschweig. 1883.

7A unit of Ca(NOs3). equals 1 mg.-equivalent. A mg.-
equivalent of Ca(NOs)2 equals 82.1 mg.

WATER OF SOIL IN ITS RELATION TO PLANTS 251

RELATIVD Water REQUIREMENTs OF CoRN ON DIFFERENT
Types or NEBRASKA Sorts, 1911. Monreomery !

Drr WEIGHT or PLANTS

IN Grams por Por TRANSPIRATION Ratio

Son
Manured |Unmanured} Manured | Unmanured
Poor (15 bushels) . . 376 113 390 549
Medium (30 bushels) . 413 184. 341 479
Fertile (50 bushels). . 472 270 346 392

173. Effect of texture on transpiration. — The effects
of texture have been investigated by a number of men,
the work of Von Seelhorst? and of Widtsoe’ being per-
haps the most reliable. While these investigators found
in general that crops on heavy soils exhibited a lower
transpiration ratio, hasty conclusions must not be drawn.
Since the fine-textured soils contain more plant-food
materials, it is probable that this is the balancing factor
rather than texture alone.

174. Actual amounts of water necessary to mature a
crop. — Although it can be seen from the transpiration
ratio that the amount of water necessary to bring an
average crop to maturity is very large, a concrete example
may be cited to advantage. A fair estimate of the dry
matter produced in raising a forty-bushel crop of wheat
would be about two tons. Assuming the transpiration

1Montgomery, E. G. Water Requirements of Corn.
Nebraska Agr. Exp. Sta., 25th Ann. Rept., p. xi. 1912.

2Seelhorst, C. von. Uber den Wasserverbrauch von
Roggen, Gerste, Weizen, und Kartoffeln. Jour. f. Land-
wirtschaft, Band 54, Heft 4, Seite 316-342. 1906.

3’ Widtsoe, J. A. Irrigation Investigations. Factors Influ-
encing Evaporation and Transpiration. Utah Agr. Exp. Sta.,
Bul. 105. 1909.

952 SOILS: PROPERTIES AND MANAGEMENT

ratio to be 300, the amount of water actually used by
the plant would amount to 600 tons to the acre, or about
5.2 inches of rainfall. This does not include the evapora-
tion that is continually going on from the soil surface,
which might very easily amount to as much more. More-
over, this draft on the soil water is not a uniform one, but
increases gradually as the crop develops, until at heading
time great quantities must be supplied in a short period.
The necessity of moisture conservation in order to meet
the plant requirements and preserve its normal develop-
ment, even in humid regions, becomes obvious.

175. Réle of capillarity in the supplying of the plant
with water. — A query arises at this point regarding the
mode by which this immense quantity of water is supplied
to the plant. The plant rootlets, especially their absorb-
ing surfaces, are few in number as compared with the
interstitial angles that contain most of the water retained
in the soil. How, then, does the plant avail itself of
water not in immediate contact with its rootlets? This
question has been anticipated in the discussion concern-
ing the capillary equilibrium which tends to occur in all
soils. As soon as the rootlet begins to absorb at one
point, the film in that interstitial angle (see Fig. 36) is
thinned. A considerable convexity of the water surface
occurs at that point, resulting in a great outward pull
which causes the water to move in all directions toward
that point. Thus, a feeding rootlet, by absorbing some
of the soil solution with which it is in contact, creates a
condition of imstability which results in considerable
film movement. It can therefore be said that capillarity
is the important factor in any soil in supplying the plant
with proper quantities of moisture.

Many of our early investigators have overestimated

WATER OF SOIL IN ITS RELATION TO PLANTS 258

the distances through which this movement may be
effective in properly supplying the plant It must be
understood, however, that the rate of water supply is
the controlling factor in plant nutrition. It has been
shown also that the longer the capillary column, the less
is the amount of water delivered from a water table to
any given point. Therefore capillarity, although it
may act through a distance of ten feet, may be important
for only three feet as far as plant nutrition is concerned,
since water beyond that point is moved too slowly to be
of any great value in time of need. No reliable data are
available as to this particular phase, but the knowledge
of the factors governing capillary movement clearly
indicates that capillarity of the soil is of greatest 1m-
portance in a restricted zone immediately around each
absorbing root surface.

176. Influence of water on the plant? — In general,
as the amount of water available to a crop is increased,
the vegetative growth also is increased, the plant be-
coming more succulent. The percentage of moisture in
the crop, even at harvest time, is usually high. Quality
practically always suffers with such a stimulation of
vegetative activity. This is especially noticeable with
such crops as barley and peaches. Shipping qualities
also are depressed with increased water, especially i
the water available is excessive. With an enlargement
of the plant cell a change probably occurs in the cell
contents, tending toward a greater susceptibility to
disease. Ripening is delayed, tillering is diminished,

1 Warington, R. Physical Properties of Soil, p. 105. Ox-
ford. 1900.

2 Mitscherlich, E. A. Das Wasser als Vegetationsfaktor.
Landw. Jahr., Band 42, Seite 701-717. 1912.

254 SOILS: PROPERTIES AND MANAGEMENT

and the percentage of protein content of the crop is de-
creased. It is a curious fact, as will be shown later, that
many of the general and morphological effects of large
quantities of available water on plant growth are the
same as those from the presence of too much soluble
nitrogen. In cereals the stimulation of increased water
is shown especially in the ratio of grain to straw. Widt-
soe’s! results in this regard are representative of the
data? available on this point : —

DisrRiBguTion oF Dry MarreR BETWEEN GRAIN AND STRAW
with Varying AMOUNTS oF WATER

GRAIN IN PERCENTAGE OF

Incuzes oF WATER Toran Dry Marror

5) 44.4

73 43.2
10 42.8
15 40.8
25 38.6
35 37.5
50 32.9

etree gm

As a general rule this depression of the ratio of grain
to straw is not due to an actual decrease in the grain, but
to a correspondingly greater production of dry matter in

1Widtsoe, J. A. The Production of Dry Matter with
Different Quantities of Irrigation Water. Utah Agr. Exp.
Sta., Bul. 116, p. 49. 1912.

*Bunger, H. Uber den Einfluss Verschieden Hohen Was-
sergehalts des Bodens in den Hinzelhen Vegetationsstadien
bei Verschiedenem Nahrstoffreichtum auf die Entwicklung
des Haferpflanzen. Landw. Jahrb., Band 35, Seite 941-1051.
1906. Also, Seelhorst, C. von, und Freckmann, W. Der
Kinfluss des Wassergehaltes des Bodens auf die Ernten und
die Ausbilding Verschiedener Getriedevarietaten. Jour. f.
Landw., Band 51, Seite 2538-269. 1903.

WATER OF SOIL IN ITS RELATION TO PLANTS 255

the vegetative parts. As available water increases this
dry matter ascends until a maximum is reached. The
general relationships are well exemplified by data from

~
&

THOUSANDS POUNDS ORY ITATTER
&

oO 70 ao Ja ao vo 60/74 "oO

Fie. 40.—- The effect of increased water supply on the production of
dry matter by various crops.

Widtsoe,! tabulated on the following page, although
other equally valuable figures may be obtained from Von
Seelhorst? and Atterberg.2 The curves above (Fig. 40)
illustrate Widtsoe’s data and the general trend in the
dry matter produced as the moisture is increased.

1Widtsoe, J. A. The Production of Dry Matter with Dif-
ferent Quantities of Irrigation Water. Utah Agr. Exp. Sta.,
Bul. 116, pp. 19-25. 1912.

2 Seelhorst, C. von, und Krzymowski, Dr. Versuch uber
den Einfluss, welchen das Wasser in dem Verschiedenem Vegeta-
tionsstadien des Hafers auf sein Wachstum ausubt. Jour. f.
Landw., Band 53, Seite 357-370. 1905. Also, Atterberg, A.
Die Variationen der Nahrstoffgehalte bei dem Hafer. Jour. f.
Landw., Band 49, Seite 97-113. 1901.

256 SOILS: PROPERTIES AND MANAGEMENT

Crop Yicnup in Pounps to tHe Acre AS INFLUENCED BY
Dirrprent Amounts or WateR. WIDTSOE

INcHrs eed INCHES wee INCHES Mee on
op Waren | Mammen | or | MS | Shen | MAE
18.74 4,969 13.04 10,757 11.17 2310
21.24 5,045 15.54 12,762 13.67 2730
23.74 5,684 20.54 13,092 16.17 2925
28.74 6,279 25.54. 13,856 21.17 3405
38.74 6,672 30.54 14,606 26.17 4005
48.74 7,229 30.54 15,294 36.17 3660
63.74 7,999 60.54 12,637 51.17 3797

177. Availability of the water in the soil.— From the
discussion already presented regarding the forms of water
in the soil, the ways in which they are held, and their
movements, it is evident that all the moisture present
in a soll is not available for plant growth. ‘Three divisions
of the soil water may be made on this basis: unavailable,
available, and super-available.

178. Unavailable soil water.— As has been shown in
a previous paragraph, free or capillary water may become
of little use to a plant through distance, since capillarity
is unable to pump the water fast enough to supply ordinary
crop needs. Water near at hand or in the immediate
zone of the rootlet may also become unavailable through
the obstruction of capillarity, friction instead of distance
being the cause in this case. As the rootlet thins the
interstitial film at any point, capillarity occurs and
water moves toward the absorbing surface. This move-
ment is rapid enough for plant needs until the film chan-
nels on the particles become thin. (See Fig. 37.) As the
zone of hygroscopic influence of the particle is approached

WATER OF SOIL IN ITS RELATION TO PLANTS 257

the viscosity increases very rapidly and cuts down the
capillarity to such a point that the needs of the plant
are unsatisfied. Wilting therefore occurs simply be-
cause the soil is unable to move the water rapidly
enough for crop needs. As the viscosity of the water
increases very rapidly after the point of lento-capillarity
is reached, the wilting coefficient is a figure somewhat
less than the percentage representing the lento-capillarity ;
also, it is greater than the hygroscopic coefficient, since
wilting due to viscosity occurs before it is possible
for the film to become thinned to the zone of hygro-
scopicity. Not only all the hygroscopic water is unavail-
able, then, but also a certain small quantity of the
capillary water lying between the point of wilting and
the hygroscopic film. This relationship is shown by
data from the work of Heinrich and of Briggs and Shantz;
men working at widely different times and under entirely
different conditions.

RELATION OF THE Witting Pornt to tat HyGroscoric Co-~
EFFICIENT. HEINRICH!

eerriibineareyermeen

PERCENTAGE OF

Sor Witting Point Hyoroscoric WatTER

Coarse sandy soil . 1.5 1.15
Sandy garden soil . 4.6 3.00
Fine humous sand . 6.2 3.98
Sandy loam . ... . 7.8 5.74
Caleareous soil . 9.8 5.20

9.7 42.30

Peat . .... . . 49,

1 Heinrich, R. Ueber das Vermogen der Pflanzen den Boden
an Wasser zu erschdpfen. Jahresbericht der Agri.-chem.,
Band 18, Seite 368-372. 1875,

258 SOILS: PROPERTIES AND MANAGEMENT

RELATION OF THE WiiTING Point to THE Hyaroscopic Co-
EFFICIENT. Briaccs AND SHANTZ }

Sor HyGRoscorie Wiurine Pornr
Coarse sand . 5 me)
Fine sand 1.5 2.6
Fine sand 2.9 3.3
Sandy loam . 3.5 4.8
Sandy loam 4.4. 6.3
Fine sandy loam 6.5 9.7
Loam . Lo 7.8 10.3
Loam . 9.8 13.9
Clay loam 11.4 16.3

179. The wilting coefficient of plants. — It has been
known for many years that the common plants possess
different capacities for resisting drought. This has
usually been ascribed to one or more of three causes:
(1) difference in root extensions; (2) difference in ability
to become adjusted to a slow intake of water; and (8) dif-
ference in pulling power against the viscosity of the water
film. The last two capabilities would argue for different
wilting coefficients for different crops on the same soil.
The most extended work on this subject has been by
Briggs and Shantz,” who found that the permanent wilting
point in a saturated atmosphere is practically the same
for all plants. Later Caldwell * demonstrated that this

1 Briggs, L. J., and Shantz, H. L. The Wilting Coefficient
for Different Plants and its Indirect Determination. U. S.
D. A., Bur. Plant Indus., Bul. 230, p. 65. 1912.

2 Briggs, L. J., and Shantz, H. L. The Wilting Coefficient
for Different Plants and its Indirect Determination. U. S.
D. A., Bur. Plant Indus., Bul. 280. 1912.

3 Caldwell, J. S. The Relation of Environmental Condi-
tions to the Phenomenon of Permanent Wilting in Plants.

Physiological Researches, Station N, Baltimore. U.S. D. A.,
Vol. I, No. 1. July, 1913.

WATER OF SOIL IN ITS RELATION TO PLANTS 259

relationship of the physical constants of the soil to the
wilting point depends on the rate at which the plant
loses water, showing that the soil factors are not entirely
dominant in this respect. This work seemed, neverthe-
less, to indicate that the conclusions of Briggs and Shantz
were correct for plants of humid regions, where the wilt-
ing occurred in a saturated atmosphere. If such is the
case, it can be accounted for only by the fact that the
soil forces in their effect on the wilting point are so power-
ful as to override any distinguishing characteristics that
the plant itself may possess, or at least reduce such an
influence within the error of actual experimentation.

180. Determination of the wilting point. — Briggs and
Shantz,’ in their investigations, devised a very accurate
method for making determinations of the wilting point.
Glass tumblers holding about 250 cubic centimeters of
soil in an optimum condition were used. The seeds were
placed in this soil, after which soft paraffin was poured
over the surface in order to stop evaporation, thus re-
moving this disturbing factor in the capillary equilibrium
of the moisture. The seedlings on germination were
able to push through this paraffin. While the plants
were developing, the tumblers were kept standing in a
constant-temperature vat of water in order to prevent
condensation of moisture on the inside of the glass. The
vegetative room was under temperature control. When
definite wilting occurred, as determined in a saturated
atmosphere, a moisture test was made on the soil. The
resulting figure, within experimental error, represents
the wilting point for the soil used.

1 Briggs, L. J., and Shantz, H. L. The Wilting Coefficient
for Different Plants and its Indirect Determination. U. S.
D. A., Bur. Plant Indus., Bul. 280, pp. 10-14. 1912.

%60 SOILS: PROPERTIES AND MANAGEMENT

181. Calculation of the wilting point.— In studying
the correlation of this wilting coefficient to soil conditions,
Briggs and Shantz+ advanced the following relationships.
Expressed as formule they represent methods of at
least approximating the wilting point from other soil
factors. These formule are arranged in the order of
their reliability, based on the data obtained by the
authors : —

_ Moisture equivalent

1. Wilting point
EP 1.84

(error 2.9 per cent)

2. Wilting point .. Hygroscopic coeificient (error 7.1 per cent)

.68

3. Wilting point
— Water-holding capacity (Hilgard method) —21 (5.8 3 ner cent)
2.9

182. Relation of texture to the wilting point. — From
the data already quoted? from Heinrich and from Briggs
and Shantz regarding the hygroscopic coefficient and the
wilting point, It 1s evident that a very close relationship
exists between the texture of the soil and the percentage
of moisture at which plants wilt. The finer the soil
texture, the higher is the wilting point. The following
figures, from Briggs and Shantz,? bring out the point very
clearly : —

1 Briggs, L. J., and Shantz, H. L. The Wilting Coefficient
for Different Plants and its Indirect Determination. U.S. D.
A., Bur. Plant Indus., Bul. 230, pp. 56-77. 1912.

2 This text, paragraph 178.

3 Briggs, L. J., and Shantz, H. L. The Wilting Coefficient
for Different Plants and its Indirect Determination. U.S. D.
A., Bur. Plant Indus., Bul. 230, pp. 26-33. 1912.

WATER OF SOIL IN ITS RELATION TO PLANTS 261

RELATION or TEXTURE To THD WiutTIne Point or KuBANKA

WHEAT

Sor _MoistURE WILTING POINT OF

HQUIVALENT KUBANKA WHEAT
Sand ....... 1.55 .86
Fine sand ..... 4.66 2.60
Fine sand ..... 5.50 3.33
Fine sand ..... 6.74 3.70
Sandy loam. ... . 9.70 4.80
Sandy loam .... . 14.50 9.60
Sandy loam... . . 18.60 8.84
Loam ...... . 23.80 12.40
Loam ........ 25.00 13.90
Clayloam ..... 27.40 14.50
Clay loam ..... 29.30 17.10

Briggs and Shantz have attempted to express this
correlation by a formula which, while very inaccurate,
shows in general the relationships already expressed.
The correlation in this case is made between the wilting
point and the mechanical composition of the soil :—

Wilting point = .01 sand + .12 silt + .57 clay (error 10
per cent)

183. Available and super-available water. — Advanc-
ing from the wilting, or critical, moisture content of a
soil, all the remaining capillary water is found to be avail-
able for normal plant use. However, when free water
begins to appear, a condition adverse to plant growth is
established, and as the saturation point is approached
this condition becomes more adverse. This free water
is designated as the super-available water, since it is
beyond the available and its presence generates condi-
tions unfavorable to plant growth. The upper limit of

262 SOILS: PROPERTIES AND MANAGEMENT

the capillary water is called the maximum water content
for plant growth. The bad effects of free water on the
plant arise largely from the poor aération that results
from its presence. Not only are the roots deprived of
their oxygen, but toxic materials tend to accumulate.
Favorable bacterial activities, such as nitrification and
ammonification, are much retarded also.

The various forms of water in the soil and their avail-
ability to the plant are illustrated diagrammatically in
the following figure.

i
HYGCFOSCOFIC NP LENTOCAPULARITY MAAIMUNM WATER
COLFFIIENT.” | POINT COM

HYGROSCOPIC | OPTIMUM WATER CONTENT _| ies on SUPERAPUABLE

AVAILABLE MOISTURE

Fic. 41.—Diagram showing the forms of water in the soil and their

relationship to the plant.

184. Optimum moisture for plant growth—vAIt is
very evident that there must be some moisture condition
of a soil which is best for plant development. This is
usually designated as the optimum content. It is not
to be assumed, however, that the total range of the
available soil water represents this condition for optimum
plant growth. Nor is this optimum water content in
any particular soil to be designated by a definite per-
centage. In reality the moisture im a soil may undergo
considerable fluctuation and yet allow the plant to develop
normally. This is because the physical condition of the
soil changes with varying water content and the plant is
able to accommodate itself to such a fluctuation without
a disturbance in its normal development occurring.
Wollny ! has shown that the optimum moisture for com-

1 'Wollny, E. Untersuchung iiber den Hinfluss der Wachs-
thumsfaktoren auf des Produktionsvermégen der Kultur-

WATER OF SOIL IN ITS RELATION TO PLANTS 263

mon field crops in general covers a range from 60 to 80
per cent of the water capacity of the soil. Mayer!
placed the optimum moisture content of wheat at 80
per cent of the water capacity of the soil, rve at 75 per
cent, barley at 75 per cent, and oats at from 85 to 90
per cent. Such estimates not only emphasize the range
of optimum moisture conditions, but at the same time
show the relatively high percentage of moisture necessary
for maximum crop growth.

Granulation has considerable influence on the range of
optimum moisture conditions, since the better the granu~
lation, the better is the soil able to accommodate itself
to changes in water content without disturbance of
plant growth. The poorer the tilth of any soil, the
narrower does this fluctuating in optimum moisture be-
come. In moisture conservation and control a granular
soil is one of the first improvements to be aimed at.
Drainage, liming, addition of organic matter, and tillage,
by leading up to such a condition, increase the effective-
ness and economy of utilization of soil moisture.

pflanzen. Forsch. a. d. Gebiete d. Agri.-Physik, Band 20,
Seite 53-109. 1897.
1Mayer, A. Uber den Hinfluss kleinerer oder Grdsserer

Mengen von Wasser auf die Entwickelung einiger Kultur-
pflanzen. Jour. f. Landw., Band 46, Seite 167-184. 1898.

CHAPTER XIII

THE CONTROL OF SOIL MOISTURE

In the discussion of the water requirements of plants,
it was apparent that for a normal yield of any crop the
amount used by the plant alone was very great, varying
from five to ten acre inches according to conditions. Were
this the only loss of water, the question of raising crops
with given amounts of rainfall would be a simple one.
Three further sources of water loss, however, are usually
found functioning in the soil and tending to lower the
water that would go toward transpiration, a loss absolutely
necessary for proper plant growth. The various ways by
which water finds an exit from a soil are (1) transpiration,
(2) run-off over the surface, (3) percolation, and (4) evap-~
oration. The following diagram makes clear their re-
lationships

Transpiration _ Transpiration
SAAN = ~~ fly of
NS — Lvqporation
J, 77TS
/ tr
ff t
1} 7 TT +
tt < ehLll i | Pun off =
OIRETRE
ut gar | ty
Bee , _ — Tt SEE
gi't | | Jy \ { J | rY CL
We n | { | 4 ‘ tly
A tw Sy Ay Percolation </ ve U :

Fig 42 —Diagram ulustrating the ways by which water may be lost
from a soil.

264

THE CONTROL OF SOIL MOISTURE 265

It is immediately obvious that as the losses by run-off,
leaching, and evaporation increase, the amount of water
left for crop utilization decreases. In arid and semiarid
regions this is fatal to plant growth, while in humid regions
it may be such a factor in periods of drought as to se-
riously reduce the harvest. Control of moisture is there-
fore necessary in all regions, and this really consists in
so adjusting run-off, leaching, and evaporation as to
maintain optimum moisture conditions in the soil at all
times. This control should result in a proper and eco-
nomic utilization of the soil water by the plant.

185. Run-off losses —In regions of heavy rainfall
or in areas where the land is sloping or rather impervious
to water, a considerable amount of the moisture received
as rain is likely to be lost by running away over the sur-
face. Under such conditions two considerations are im-
portant: (1) by not entering the soil the water is lost for
plant use; and (2) washing of the soil may occur, which
if allowed to proceed may entirely ruin the land. The
amount of run-off varies with the rainfall, the slope, and
the character of the soil. In some regions it may rise
as high as 50 per cent of the rainfall, while in arid regions
it is of course very nearly zero. As a general thing, this
loss is estimated with the losses by leaching, the two being
expressed as one figure.

186. Percolation losses. — When at any time the
amount of rainfall entering a soil becomes greater than
the water-holding capacity of the soil, losses by percola-
tion will result. The losses will depend largely on the
amount and distribution of the rainfall and the capa-
bility of the soil to hold moisture. The bad effects of
excessive percolation are twofold: (1) the actual loss of
water, and (2) the leaching-out of salts that may function

966 SOILS: PROPERTIES AND MANAGEMENT

as plant-food. The quantity of nutrient elemen. t
annually from the average soil in a humid region ce
than equals that withdrawn by the crops. The results
from the Rothamsted drain gauges! from 1871 to 1904
on a clay loam soil of three different depths are inter-
esting as to the light that they afford regarding actual
drainage losses : —

PROPORTION or
DRaINn Se RaInFALL DRAINED
THROUGH Sor

Rane [oo
PALL Depth in Inches Per Cent
20 40 60 20 40 60

January . . . .| 2.82| 1.82) 2.05} 1.96} 78.5) 88.4) 84.5
February . . . .| 1.97) 1.42} 1.57) 1.48} 72.2) 80.0) 75.2
March . . . . ./] 1.83] 0.87] 1.02} 0.95] 47.6) 55.6] 52.0
April . . . . .| 1.89] 0.50] 0.57} 0.53 | 26.5] 30.0; 28.0
May . . . . «| 211) 0.491 0.55) 0.50 | 23.2) 26.1) 23.6
June . . . . «| 2.86} 0.638] 0.65} 0.62 | 24.0] 27.6) 26.3
July . . . . .| 2.73] 0.69} 0.70) 0.65 | 25.3} 25.6) 23.8
August . . . . .| 2.67] 0.62|) 0.62) 0.58) 23.2) 23.2) 21.7
September . . .| 2.52] 0.88] 0.83) 0.76) 35.0) 32.8) 30.0
October . . . .| 3.20} 1.85) 1.84] 1.68] 57.8] 57.5) 52.5
November. . . .| 2.86) 2.11] 2.18] 2.04} 76.7) 76.3) 72.4
December... 2.52| 2.02} 2.15) 2.04) 80.3] 85.4) 81.0

Mean total per year | 28.98 | 13.90 | 14.73 | 18.79 | 48.2} 51.0) 48.0
Winter, October to

March . . . .{14.70) 10.09 | 10.81 | 10.15 | 68.6] 72.8) 69.0
Summer, April to °

September . . ./14.28] 3.81] 3.92] 3.64] 26.6/ 27.4) 25.4
The rainfall and relative loss through the 40-inch depth
of soil is shown graphically in the following diagram : —

1 Hall, A. D. The Book of the Rothamsted Experiments,
p. 23. London. 1905.

THE CONTROL OF SOIL MOISTURE 267

Fig. 43.—Rainfall and percolation losses through a 40-inch soil column.
Lysimeter records, Rothamsted Experiment Station, England.

It appears from these figures that about 50 per cent
of the rainfall in such a climate as that of England is
lost by percolation alone. It appears also that the loss
is much lower in summer than in winter, the ratio being
about one to three. Also, the longer the soil column,
the less is the percolation, due to the greater water-
holding capacity possessed by the longer column.

187. Methods of checking loss by run-off and leaching.
— Jt must not be inferred that the soil is never in such
a condition that percolation, and even run-off, are not
advantageous. Often in winter the excess water may
be drained over the surface with no damage whatsoever.
Also, when the soil becomes filled with free water, either
in winter or in the growing season, dramage must
take place in order to establish optimum soil conditions.
The control of the free water of the soil may be brought

268 SOILS: PROPERTIES AND MANAGEMENT

about by drainage operations or by methods that will
increase the water-holding capacity of the soil. The
former is really a matter of engineering technique and
will be treated in a separate chapter. The latter is a
function of the soil itself and must be specifically con-
sidered at this point.

The necessity of giving attention to losses due to
run-off and leaching varies with climatic conditions.
In very humid regions these losses are of grave importance,
while in arid regions they are insignificant as compared
with losses by evaporation. For example, in England
the losses by percolation and run-off in many cases are
as high as 60 per cent of the rainfall. In the Mississippi
River basin the loss is 50 per cent, in the Missouri it is
about 20, while in the Great Basin it drops to zero. This
does not indicate that drainage is not practiced in the
last-named region, however, for, owing to over-irrigation,
seepage, and other conditions, drainage operations often
become as important as in humid climates.

The quantity of water. entering a soil is determined
almost entirely by the physical condition of the soil.
If the soil is loose and open, the water enters readily and
little is lost over the surface as run-off. If, on the other
hand, the soil is compact, impervious, and hard, most
of the rainfall runs away, and not only is there a serious
loss of water, but considerable erosion may also result.
The first step in checking run-off losses, therefore, is
strictly physical in nature. As the water that has entered
the soil moves downward it is continually being changed
to capillary water in 1ts passage. If the capillary capacity
of the soil is high, a greater percentage of this rain water
becomes capillary and a less percentage is left to be carried
away as gravitational water. The secret in the control

THE CONTROL OF SOIL MOISTURE 269

of run-off and percolation, then, is first, to have a loose,
open structure of soil in order to facilitate ready entrance
of the water; and secondly, to promote and encourage
a. physical condition of soil which provides high capillary
capacity. Drainage, lime, humus, and good tillage en-
courage granulation, which has so much to do with the
proper entrance of water into the soil and its proper
handling and utilization therem. The benefits of drain-
age are felt only when free water, superavailable to
plants, becomes present. Its quick removal, therefore,
not only betters the physical condition of the soil, but
also aids in the maintenance of the optimum moisture
conditions for the plants.

Fall and early spring plowing is always recommended
as a means of increasing the moisture capacity of the
soil, particularly where organic matter is well supplied.
It provides a deep soil, and should establish the best
conditions for the storage of moisture, as well as food,
for the plant. If organic matter is not supplied, deep
plowing is not advisable on light sandy soil; but on
clay soil it is beneficial because of the loosening and granu-
lating effect. Fall plowing in particular is to be recom-
mended for such soil, as the loose condition produced
facilitates the entrance of surface water while the granu-
lation that the soil undergoes during the winter increases
its water-holding power. A soil in excellent physical
condition may contain considerably more water than
the soil of the same texture but in poor tilth, and yet
present better conditions for crop growth. Where fall
plowing cannot be done, early spring plowing is the next
best. procedure.

188. Evaporation losses. — Evaporation of soil water
takes place almost entirely at the surface, exceptions

270 SOILS: PROPERTIES AND MANAGEMENT

being where deep, large cracks occur, which allow thermal
loss directly from the subsoil. This loss of water by
direct evaporation from the soil may be excessive and
may result in direct reduction of the crop yield — a type
of loss so familiar that examples hardly need be cited.
In the results with the Rothamsted rain gauges about
50 per cent of the annual rainfall was regained in the
drainage water. Since the gauges bore no crop, the
remaining 50 per cent must have been lost by evapora~
tion. It should be noted that in the summer months
under warm temperature this loss was greatest, amount-
ing to 75 per cent of the rainfall. Correspondingly, in
the semiarid and arid sections of the country, where
there is little or no drainage, the rainfall is all lost by
evaporation. Investigations indicate that about 70 per
cent of the precipitation on the land surface is derived
from evaporation from land surface. Even in humid
regions, where the annual rainfall is ample for maximum
crop production, the crops are frequently reduced below
the profit point by prolonged periods of dry weather in
the growing season, during which the loss of water from
the plants, coupled with the loss from the soil, exhausts
the moisture supply.

While run-off and percolation are directly proportional
to the rainfall, loss by evaporation does not vary to such
a degree. The loss by percolation depends almost
directly upon the amount of rainfall above the retentive
power of the soil. In years of heavy precipitation,
losses by percolation must increase. Evaporation from
the soil depends largely upon the time that the soil
surface is moist, and this will not vary markedly from
year to year. The following figures from the Rothamsted
drain gauges may be quoted in this regard :—

THE CONTROL OF SOIL MOISTURE 271

Recorps FROM RotHamstep (1870-1878) !

RAINFALL INcHES EVAPORATION INCHES PERCOLATION INCHES
22.9 17.3 5.6
26.3 18.4 7.9
29.3 18.1 11.2
30.8 18.3 12.5
31.6 16.6 15.0
32.6 18.0 14.6
34.2 18.0 16.2
35.8 18.3 17.5
42.7 17.2 25.5

A rough calculation may be made which will show the
apportionment of the yearly rainfall in a humid region of
the temperate zone between the three forms of losses —
run-off and percolation, evaporation, and transpiration.
The percolation under a rainfall, say, of 28 inches, as
shown by the Rothamsted work, is roughly 14 inches, or
50 per cent. The water requirement of an ordinary
crop is about 7 inches. This leaves a loss of 7 inches
to be credited to evaporation. In other words, one-
half the rainfall goes as run-off and percolation, while
the other half is divided about equally between the plant
and loss by evaporation. While run-off and percolation
may be checked to some extent, not enough conservation
can occur in this direction to tide a crop over a period
of drought. Paramount attention should therefore be
directed toward the checking of losses by evaporation,
since moisture thus saved means just that amount added
to the water available for crop use. It should be remem-
bered that over a large proportion of cultivated lands

1 Warington, R. Physical Properties of the Soil, p. 109.
900.

272 SOILS: PROPERTIES AND MANAGEMENT

the crop yields are controlled more directly by lack than
by excess of water. It is a common observation that
soils which ordinarily give a low yield in seasons of nor-
mal or low rainfall give good yields in a wet season,
indicating how dominant is this influence of moisture on
soil fertility.

189. Methods of checking evaporation losses. — All
methods for the reduction or elimination of evaporation
losses depend on one or both of two functions: (1) the
actual control of evaporation as it occurs at the surface;
and (2) the prevention of the movement of capillary
water upward to take the place of the moisture already
lost. It has been shown that as water is lost at the sur-
face of a soil, movement is induced and capillarity is
set up. Such action, if allowed to continue, must ulti-
mately bring about great losses. The obstruction of
eapillarity would obviously lower these losses to a marked
degree. As it is difficult and often impracticable to en-
tirely eliminate evaporation, the most successful methods
of water control usually include a change in the structural
condition of the soil which tends toward a lower capil-
larity, especially at the surface. Of all the methods of
moisture conservation, the use of a mulch has been found
most satisfactory. The consideration of mulches is
therefore one of the most important phases in the study
of moisture control.

190. Mulches for moisture control.— Any material
applied to the surface of a soil primarily to prevent loss
by evaporation may be designated as a mulch. It may
at the same time fulfill other useful functions, such as
the keeping down of weeds and the maintaining of a
uniform soil temperature. By the conservation of the
moisture, more water remains in the soil for the solution

THE CONTROL OF SOIL MOISTURE 273

of the essential elements, and bacterial activity is en-
couraged. As a general rule, more soluble plant-food is
likely to be found under a mulched soil, other conditions
being equal, than under a soil not so treated.

191. Kinds of mulches. — Mulches are of two general
sorts, artificial and natural. In the former case, foreign
material is merely spread over the soil surface and evapora-
tion is obstructed thereby. Manure, straw, leaves, and
the like, may be used successfully. Such mulches, while
very effective, are not generally applicable to field crops
where intertillage is practiced, since they would make
cultivation absolutely impossible by cumbering the soil
surface with a large amount of inert material. Their
use is therefore limited to intensive crops such as are
found in trucking operations. Leaves, including pine
needles, and sawdust are very effective as a mulch, but
some precautions should be observed in their application.
For example, the oak is rich in tannic acid, which may
be washed out of the mulch into the soil and by its effect
on the growing plant may cause a lowering of productivity.
In some European countries, as well as in a few localities
in America, stones have been drawn on the soil to serve
as a mulch, particularly in orchard and vineyard culture,
with markedly beneficial effects. Particularly is this
true on such lands as are too steep to permit cultivation.
As further evidence of the utility of this practice, it has
been observed in the fruit-growing section of the Ozark
Mountains, and doubtless in other regions, that the
removal of stones from the land not only results in the
soil’s becoming harder, but also reduces crop yield by
increasing loss of moisture. It is therefore necessary
for the farmer to decide whether the inconvenience
to tillage or other operations due to the presence of

974 SOILS: PROPERTIES AND MANAGEMENT

stones may not be more than offset by their beneficial
effects.

The materials for mulching mentioned above are all
strictly artificial, and their application is greatly limited,
due to the lack of material and the expense involved.
They are therefore used only under special conditions.
The second type of mulch is almost universal in its prac-
tical availability.

By proper cultivation almost any soil surface may be
brought into such a condition that evaporation of mois-
ture is more rapid than the upward capillary movement.
This is because surface tillage produces a loose, open
structure, which, while increasing the rate of thermal
movement of the water, at the same time obstructs
capillary action. The surface layer, therefore, quickly
becomes air-dry and is in a condition designated as a
soil mulch. As it differs from the soil below only in
structure, it has numerous advantages over artificial
mulches, at the same time performing successfully all
the functions of the latter. Since not only the water in
the mulch is sacrificed but also a small quantity pumped
upward by capillarity during the operation, speed in
formation is of importance. The tillage implements
that give the maximum looseness and granulation will
prove the most successful. A spike-tooth harrow or a
weeder is the instrument’ ordinarily employed.

192. The functions of a mulch. — A soil mulch depends
for its effectiveness on two functions — (1) the shutting-
off of evaporation, and (2) the checking of capillary move-
ment upward. It has already been shown that thermal
movement of water through dry soil layers is practically
nil;! therefore, as long as the soil is dry, evaporation is

1 This text, paragraph 166.

THE CONTROL OF SOIL MOISTURE 275

very low. Moreover, any layer of air-dry soil resists
wetting, principally because of the resins and oils that
become deposited on the surface of the soil particles.
This material, called “ agricere,” has a low surface tension
and the capillary water film is not easily resumed under
such conditions. Again, if the soil is well granulated
it is able to assume a looser and more open structure.
The interstitial angles, which afford spaces for capillary
surfaces, are cut down, and the capillary pulling power
of the layer is much reduced even if it should assume a
film of water. It is evident that looseness and dryness
are the essentials in the efficiency of a soil mulch. As
long as a mulch is dry, texture is not a very important
factor in efficiency, a dry sand being about as effective
as a dry clay. Texture is important, however, in the
length of time that a mulch will remain effective. Due
to the fact that the capillary power of a clay is so great,
it will become moist from below after a few days; while
a sand mulch, if there is no rain, will remain dry for an
indefinite period. On a heavy clay soil in fine tilth a
mulch may be destroyed by moist, foggy weather, or
by a number of days of very humid atmosphere; such a
condition, by causing condensation of moisture on the
clay, hastens the reéstablishment of capillarity with the
subsoil, thus allowing moisture to be pumped up and
lost.

193. The soil mulch versus the dust mulch. — A few
words will not be amiss at this point regarding the term
“dust mulch,” which is observed so commonly in soil
literature. This term would indicate that the mulch is
in a very fine condition, its granulation having been
broken down. Such a condition would not be conducive
to efficiency, as it would encourage capillarity, while at

276 SOILS: PROPERTIES AND MANAGEMENT

the same time it would become puddled on wetting —
certainly a very undesirable condition. As a matter of
fact, efficient mulches are not in a dust form, but are
granulated and much looser than could be obtained were
they finely divided. It is evident that the term “ dust
mulch ” is incorrect and should be superseded by “ soil
mulch,” a figure of speech which more exactly expresses
the true field conditions.

194. Formation of a mulch.—AIt has already been
stated that a mulch should be formed as quickly as
possible. This would not be such a factor were the
mulch adjusted only once in a season. It is necessary,
however, especially in humid regions, to re-form a mulch
every week or ten days. The cutting-down of formation
losses therefore becomes important. In general the
mulch should be made just as soon after a rain as it is
possible to work the land, since the most rapid evapora-
tion occurs during the few hours immediately after a
rain, when the soil is very moist. Even after light showers
the soil should be quickly cultivated, since the rain may
have established a capillary communication with the
surface and thus provided for a rapid loss of the water
already conserved by previous work. Under arid con-
ditions, where the atmosphere is dry and hot and in free
circulation, the surface soil is quickly dried out after a
rain. This drying takes place so rapidly that the capil-
lary films quickly become so thin that movement is
stopped and no more water is brought to the surface.
The soil may be ever so hard and compact, but as long
as it is kept dry it very effectively conserves the moisture
below. The more rapid the loss, the more quickly will
the mulch condition be created, and therefore the less the
total loss of water is likely to be. This has been demon-

THE CONTROL OF SOIL MOISTURE OTT

strated by Buckingham* in some experiments in which
arid climate conditions were created at the surface of a
capillary column forty-six inches in height. The soil
was a fine sandy loam. At first the loss of water under
the arid conditions was very rapid and exceeded that
under the humid conditions; but the rate of loss soon
dropped considerably below that of the humid column,
and continued to fall behind during the twenty days
of the experiment. The differences in this case were
due to self-mulching, a very common phenomenon of
arid land soils, particularly those of a loamy character.
This self-mulching is often seen in sands in humid
regions. The under layers of a sand pile are always
moist, due to the self-mulching tendencies of the sur-
face. The results of Buckingham are shown in the fol-

lowing curves : —
foe |

Eee
Z2c4nnne
Va

20 GAYS BhLAP SEO

GRAMS OF WATER: EVAPORATED

Fie. 44 —Evaporation curves on a sandy Joam under humid and arid
conditions. Self-mulching has occurred under the arid conditions
and a reduction in evaporation has resulted.

1 Buckingham, E. Studies on the Movement of Soil Mois-
ture. U.S. D. A., Bur. Soils, Bul. 38, pp. 18-24. 1907.

278 SOILS: PROPERTIES AND MANAGEMENT

195. Depth of a mulch. — The depth of a mulch is an
important question in humid regions. Not only must
all the water in the layer be sacrificed in order to make
the mulch effective, but the plant-food of that layer
is temporarily withdrawn from use. In humid areas,
where the surface soil is usually not over eight or ten
inches in depth, the latter consideration is vital, since
the fertility of the soil would be greatly depressed by a
deep soil mulch. Another factor to be considered here
is the possible root pruning that may occur while the
mulch is being formed. While not of importance early
in the season, it is worthy of considerable attention when
the intertilled crop attains some age. It has been shown,
with such crops as corn, that considerable depression in
yield may result from the maintenance of a mulch at too
great a depth, some of the feeding roots being cut off
thereby. For such reasons the average depth of mulch
for humid regions and in dry-farming operations has
become regulated to about three inches, although in the
late cultivation of corn a less depth than this is advocated.
In irrigated regions where little rainfall occurs and where
the soil is very deep and uniformly fertile, mulches as
deep as ten or twelve inches are sometimes found, es-
pecially in orchards. As rainfall occurs but few times
during the season, such a mulch often needs no attention
except for its original formation. With crops having
shallow roots a thinner mulch layer must of course be used.

196. Résumé of mulch control. — To summarize briefly,
the cardinal points in mulch control are: (1) mulches are
more effective and more easily maintained in an arid than
in a humid climate; (2) their efficiency depends directly
on their dryness, looseness, and granulation; (3) sandy
soil is more easily maintained as a mulch than clay soil;

THE CONTROL OF SOIL MOISTURE 279

(4) from two to three inches is ordinarily the most effec-
tive depth; (5) after a heavy rain, the soil mulch must
be renewed by tillage, and this is much more urgent on
clay than on sandy soil; even without rain, a clay mulch
may become inefficient; (6) tillage for mulch purposes
must ordinarily be more frequent in spring or during
periods of heavy rain, than at other times of the year;
(7) the use of foreign materials as mulches may be justi-
fied under special circumstances.

197. Water saved by a mulch. —It is very difficult
to quote data regarding the capacity of a mulch to con-
serve moisture, since conditions vary to such a degree
from one region to another. Again, water may not be the
limiting factor in crop growth, and even if moisture were
saved there might be but little influence on crop yields.
As a general rule, mulches are most easily maintained
and most effective in arid and semiarid regions. Since
there is no doubt that moisture, under such conditions, is
the limiting factor in plant growth, data from such regions
should be especially significant.

Morsture Content or MuucHep ann UNMULCHED EASTERN
Montana Sorts. AVERAGE oF Toren Years.! OcrosBer 6

MoutucHep UNMULCHED
First foot... 0. 0. ke es 16.8 10.8
Second foot . . . . ..... 16.4 9.4
Third foot . . . . ....~. 13.2 9.5
Fourth foot . . . .... . . 10.1 8.9
Fifth foot. . . . . . . we 9.6 8.5
Average. . . . . . ee 13.2 9.4

SL NA

1Buckman, H. O. Moisture and Nitrates in Dry Land
Agriculture. Proc. Amer. Soc. Agron., Vol. 2, p. 131. 1910.

280 SOILS: PROPERTIES AND MANAGEMENT

If the wilting point of this soil is 6 per cent, the mulched
area contains more than twice as much available moisture.
This 3.8 per cent of available moisture by which the
roulched soil excels the unmulched is equivalent in a five-
foot depth to about 250 tons of water, enough to increase
the crop by a ton of drv matter — certainly not an insig-
nificant saving where crop yield and moisture are so very
closely correlated.

A considerable amount of experimentation ‘ is available
which seems to indicate that mulching a soil does not in-
crease its yield over a soil not so treated. One reason for
this, as already suggested, may be in the fact that water
may not have been the limiting factor, the rainfall having
been just right in amount and distribution. Again, the
roots may have so intercepted the capillary water as to
have allowed no more evaporation from the unmulched
soil than from the mulched. In some soils hard layers
often form which act in repelling capillary movement.
Such a condition would function as successfully in check-
ing losses as if a true mulch were present. In the study
of mulches and their value in increasing a crop, decided
opinions should not be advanced until every phase has
been thoroughly investigated regarding the exact factors
dominant in the determination of yield. The extended
use of soil mulches in the Corn-Belt and in dry-farming
operations argues for their benefits.

198. Effect of mulches other than on moisture. — That
mulching a soil has other effects besides the conserving of
moisture is universally evident. In general the physical
condition of the soil is always better after a crop that has

1 Cates, J. S., and Cox, H. R. The Weed Factor in the
Cultivation of Corn. U.S. D. A., Bur. Plant Indus., Bul.
257. 1912.

THE CONTROL OF SOIL MOISTURE 281

been intertilled. Not only has the surface been kept
well granulated, but the presence of optimum moisture
below has allowed the granulating agents to become
more active. The following of potatoes by corn is, at
least partially, an attempt to take advantage of the
better tilth of the soil with a crop that is particularly
benefited thereby. Again, a mulch not only tends to
allow a ready entrance of water into the soil, but at the
same time increases the water-holding capacity — factors
already emphasized in the discussion of control of losses
by percolation and run-off. By keeping down weeds!
another saving is effected, not only in moisture but also
in plant-food. Some results from an experiment? con-
ducted at Cornell University serve to illustrate the re-~
lation of mulches and weeds to soil moisture and crop
production in a humid region in a season of good rainfall.
The crop grown was maize. Every third plot was a
check and was given normal treatment : —

Yietps Caiev-

LATED TO Basts|S0™ Mortsrure

DURING AUGUST

Ofnce Poors Per Cent

Check plot . . . . . . ee 100 21.1
Weeds removed, but not cultivated . 96 18.2
Mulched with straw . . ... . 121 25.0
Check plot Soe ee ee. 100 18.2
No cultivation; weeds allowed to grow 3l 9.8
One cultivation; weeds allowed to

erow . . 2. . «6 2 ew ew ee 98 17.0
Check plot . . . . .. .. . 100 17.7

1 Cates, J.S.,and Cox, H. R. The Weed Factor in the Culti-
vation of Corn. U.S. D. A., Bur. Plant Indus., Bul. 257. 1912.

2 Craig, C. BE. The Cause of Injury to Maize by Weeds.
Presented as a thesis for the degree of M.S. A., Cornell Uni-
versity. Unpublished. June, 1908.

282 SOILS: PROPERTIES AND MANAGEMENT

The application of a soil mulch is not confined to
intertilled crops such as maize, potatoes, vineyards,
fallow, and the like. Under some conditions it may be
applied to grain fields with good results. In those sections
of the country where dry farming is practiced, it is not
uncommon to drag the grainfield with a sharp-tooth
harrow; the teeth pointing backward. This is begun when
the plants are small, and may be continued until they
attain a considerable size or until they sufficiently shade
the ground to greatly reduce surface evaporation.

199. General usefulness of a mulch. — While a soil
mulch is used primarily in order to conserve moisture,
its relationships are different in different regions accord-
ing to climatic and cropping peculiarities. In dry-
farming regions a mulch is maintained as nearly as possible
the year round, since moisture must be carried from the
previous summer and winter to the growing season in
order to supplement the rainfall occurring at that time.
In irrigated regions a mulch is useful in two ways — by
conserving the rainfall and by checking the loss of irriga-
tion water; after the latter is once in the soil less addi-
tional water need be applied and the consequent cost of
irrigation is much less. Again, in arid regions where
there is an excess of soluble salts, rapid evaporation is
detrimental since these salts tend to concentrate near
the surface and become harmful to plants. The pre-
vention of the rise of alkali is therefore a very important
function of the soil mulch in such regions.

In humid regions the utilization of a soil mulch is
much less intense, since the conservation of moisture
over long periods is unnecessary, due to the rainfall.
However, during the growing season periods of drought
occur, when if available water is lacking in the soil, the

THE CUNTROL OF SOIL MOISTURE 283

crop suffers. The amount of moisture conserved by a
mulch will usually keep the plant growing normally
through such periods, while crops on soils not so treated
may suffer greatly. ‘The tiding of crops over short periods
of light rainfall is the chief function of mulches in humid
climates.

200. Other practices affecting evaporation losses. —
Although the control of water by mulches is such an
important consideration, other means of checking losses
are available. These may be grouped under five heads:
(1) fall and early spring plowing, (2) rolling, (3) shelters,
(4) level cultivation, (5) plants.

201. Fall and early spring plowing. — Fall and early
spring plowing owe much of their efficiency to the con-
servation of moisture effected through the creation of a
mulch over the surface. Fall plowing may be practiced
for a number of reasons, but in regions of deficient rain-
fall, particularly in winter, the conservation of the mois-
ture in the soil at the close of the growing season Is an
important consideration. This practice is well adapted
to those soils in semiarid sections that do not blow too
badly when fall-plowed, and where the winter rain is
not sufficient to saturate the soil. If the soil is left in
the bare, hard condition resulting from the removal of
a crop of maize, wheat, or barley, a large quantity of
water may be lost by evaporation during the fall months.

For the average farmer in humid regions where the
winter rainfall is sufficient to saturate the soil, early
spring plowing, coupled with tillage, is very important.
Not only may moisture be conserved, but the soil is
worked at the stage when it yields most readily to pul-
verization. Fallow land, and bare stubble land of fine-
textured soil, are most benefited, since they become

284 SOILS: PROPERTIES AND MANAGEMENT

compact to the very surface as a result of the winter
rain and snow, and are therefore in condition for the
most rapid loss of water. They should be plowed as
early as practicable without injury to their structure.
At the Wisconsin Experiment Station’ two adjacent
pieces of land very uniform in character were plowed
seven days apart. At the time when the second plot
was plowed, it was found to have lost 1.75 inches of
water from the surface four feet in the previous seven
days; while the piece plowed earlier had actually gained,
doubtless by increased capillarity, a slight amount of water
over what it had contained when plowed. There was a
conservation of nearly two inches of water in the root zone
as a result of plowing one week earlier — enough to
produce 1500 pounds of dry matter in maize to the acre,
if properly utilized.

202. Rolling. — Very often in the spring, when the
seed bed is very loose, rolling is resorted to, in order to
bring about a compaction of the soil. At the same
time capillarity is established with the firmer earth
beneath, and as the moisture moves upward a rapid
germination of the seed is induced. Care must be taken
that this capillarity be checked once it has performed
this office, as great losses from evaporation may occur
at the surface and the crop be robbed of much available
water. It is an economic procedure in such cases to
follow the roller after a few days with a harrow, in order
that a mulch may be established and this loss checked.

203. Shelters. — Shelters of any kind, whether natural
or artificial, tend to break the wind velocity and thereby
check losses by evaporation. Strips of timber are com-

1 King, F. H., The Soil, p. 189. New York. 1906.

THE CONTROL OF SOIL MOISTURE 285

monly grown or retained for this purpose. Wooden fences
and walls of one sort or another have a similar effect.
Windbreaks composed of growing plants have the dis-
advantage that for a considerable distance beyond the
spread of their branches their roots penetrate the soil
and use the moisture, which is one reason for the smaller
growth of crops near trees. Bearing on the efficiency of
windbreaks, results by King+ show that when the rate
of evaporation at twenty, forty, and sixty feet to the
leeward of a black oak grove fifteen to twenty feet high
was 11.5, 11.6, and 11.9 cubic centimeters, respectively,
from a wet surface of twenty-seven square inches, the
evaporation was 14.5, 14.2, and 14.7 cubic centimeters,
at two hundred and eighty, three hundred, and three
hundred and twenty feet distant — or 24 per cent greater
at the outer stations than at the inner ones. A scanty
hedgerow reduced evaporation 30 per cent at twenty
feet and 7 per cent at one hundred and fifty feet, below
the evaporation at three hundred feet from the hedge.
Very often tent shelters are used in the growing of
tobacco. The commonest form of the tent is a frame
eight or nine feet high, over which is spread a loosely
woven cloth. Investigations by Stewart ? in Connecticut
showed: (1) That the tent greatly reduced the velocity
of the wind. This reduction amounted to 98 per cent
when the outside velocity was seven miles an hour, and
85 per cent when the outside velocity was twenty miles
an hour, there being a small regular decrease in relative
efficiency with increased velocity of the wind. (2) The
relative humidity under the tent was higher than outside,

1King, F. H. The Soil, p. 205. New York. 1906.
2Stewart, J. B. Effects of Shading on Soil Conditions.
U.S. D. A., Bur. Soils, Bul. 39. 1907.

286 SOILS: PROPERTIES AND MANAGEMENT

and during a good part of the time attained a difference
of 10 per cent. The effect of this was to reduce evapora-
tion by from 53 to 63 per cent on different days in July,
in spite of a higher temperature inside the tent. (8) The
direct effect of this was to increase the moisture content
in the soil in spite of a larger crop growth under the tent.
These differences are shown by the following curves (see
Fig. 45), which represent the percentage of water in the
soil to a depth of nine inches from June 13 to August 1.

MERIOD OF QPSERVATION

SS0S00 SSR e eee
Yee pt | ttt | ttt Ty
ELAS REE
SRR

Lt [Tf yy

Fig. 45 —Curves showing the percentage of moisture in a sandy soil to
the depth of nine inches inside and outside of a loosely woven tent
over a period of about fifty days Heavy line, moisture inside of
tent; broken line, moisture curve of soil outside of tent.

Not only was the tent effective in preventing evapora-
tion and thereby increasing the average moisture content
of the soil, but the soil was able to maintain a more uni-
form content, due to the freer movement and adjustment
of the capillary water under the tent — conditions more
conducive to rapid crop growth.

204. Level cultivation.— The velocity of the wind
next to the ground may be checked by ridging the soil.
It is doubtful whether this practice conserves moisture,

THE CONTROL OF SOIL MOISTURE 287

because a greater amount of surface is exposed over
which evaporation may take place. On the other hand,
wide experience, as well as investigation, indicates that,
for the conservation of water, level culture is better than
ridged culture. This principle has led to the gradual
abandonment of the practice of “laying by” corn and
potatoes with a high ridge. In all regions of deficient
rainfall, the best practice prescribes level tillage and a
fine, dry mulch, both of which are attained by the frequent
use of shallow-running small-tooth cultivators. Many
experiments have demonstrated the larger crop yields
to be obtained, on the average, from this practice.

205. Plants.— Plants growing on the soil tend to
check evaporation from two causes— (1) their shading
effects, and (2) the tendency of the roots to intercept
capillary water as it moves upward and to appropriate
it for plant growth. Plants, however, tend to intercept
a certain amount of rain and prevent its ever reaching
the soil. The amount of water wasted in this way by
forests ranges from 15 to 30 per cent. In general this
tendency just about offsets the saving that occurs from
shading.

206. Summary of moisture control. — It is clearly seen
from the discussion of moisture control that the structural
condition of the soil is the secret of successful operation.
Run-off and leaching are reduced by increased capillary
capacity, a structural relationship. Evaporation is
checked by a soil mulch, which depends for its effective-
ness on its physical condition. Drainage, lime, addition
of organic matter, and tillage in perfecting granulation
function in increasing the ease and effectiveness with
which soil moisture may be controlled. It must be
clearly kept in mind that all such control is directed

288 SOILS: PROPERTIES AND MANAGEMENT

toward the regulation of the soil moisture in such a way
that an optimum water supply may be held constantly
in the soil during the growing season. If this can be
accomplished, the largest crop yields may be expected that
are possible under the existing fertility conditions of any
soil.

CHAPTER XIV

SOIL HEAT?

Norma plant growth is practically suspended below a
temperature of about 40° F., while proper germination of
seeds does not proceed much below that temperature.
As a rule it is not desirable to place either seeds or plants
in a soil in which active growth does not take place almost
immediately, since certain molds and fungi, active at
low temperature, may sap their vitality and ultimately
cause their destruction. The desirable chemical reactions
in the soil are checked to a certain extent by lack of heat,
while the important biological activities are greatly im-
peded, if not brought entirely to a standstill, when the
soil temperature approaches 32°F. Such functions as
the decay and putrefaction of organic matter, the forma-
tion of ammonia from simple humic bodies, the building-up
of this ammonia into the nitrate form, and the fixation
of the free nitrogen either by free-fixing or symbiotic
bacteria, depend on an optimum soil temperature.

A knowledge of the functions of heat, therefore, es-
pecially as to its relationship to plant growth and bac-
terial activities, becomes important; for the farmer can
to a certain extent control soil temperature. He is able

1For bibliography of the literature of soil heat, see Bouyoucos,
G. J. An Investigation of Soil Temperature and Some of the
Most Important Factors Influencing It. Michigan Agr. Exp.
Sta., Technical Bul. 17, pp. 194-196. 1913.
U 289

2990 SOILS: PROPERTIES AND MANAGEMENT

also to govern the time when his sowing and planting are
performed in such a way that the soil will be fitted, at
least as far as heat is concerned, for proper seed germina-
tion and plant growth.

207. Relation of heat to germination and growth. —
In order to show the exact relationship of heat to ger-
mination of seeds and to the growth of plants, the follow-
ing data from Haberlandt! are given. While these
tables are not exact, they show clearly the necessity of
careful control of temperature in the propagation of
plants : —

THe RELATION oF TEMPERATURE TO THE GERMINATION OF
Certain Steps (In Decress FAHRENHEIT)

MINIMUM OPTIMUM Maximum
Corn . 115
Scarlet bean 115
Pumpkins . 115
Wheat 108
Barley 99

Tue RELATION oF TEMPERATURE TO THE GROWTH OF CERTAIN
Prants (IN Decrees FAHRENHEIT)

OprrimMuM MaxIMUM

77-88 88-98

MINIMUM

Wheat ...... . .| 82+40

Barley . . . . . . . .| 82-40 77-88 88-98
Corn .... .. . .| 40-51 88-98 98—-L1L
Peas... . 0. ee 32-40 77-88 88-98
Buckwheat . . ... . 32-40 77-88 98-111

88-98 111-122

Melon .......~. 60-65
. oe 98-111 111-122

Pumpkin 51-60

1 Haberlandt, F. Die Oberen und Unteren Temperatur-
grenze fiir die Keimung der Wichtigeren Landwirthschaftlichen
Samereien. Landw. Versuchs. Stat., Band 17, Seite 104~116.
1874.

SOIL HEAT 291

It is noticeable that there are here three groups of
plants as far as temperature conditions for optimum
growth are concerned. Wheat represents the crops that
germinate and grow at a relatively low temperature.
Corn requires a medium high temperature for proper
growth, while melons and pumpkins represent crops the
temperature requirements of which are verv high. These
needs must be supplied for a proper development of such
plants, and must of course be considered in crop adapta-
tion as well as in soil management in general.

208. Chemical and physical changes due to heat. —
In the soil a certain amount of chemical action is going on,
no matter what the temperature may be; but it is with-
out doubt true that this activity is greatly accelerated by
an increase in soil heat. This arises from two causes:
(1) because heat increases the solubility of the soil con-
stituents; and (2) because the activity of the soil or-
ganisms is stimulated to such an extent as to in
turn influence chemical reaction. The increased pro-
duction of carbon dioxide is a good example of this re-
lationship. The warming of the soil in spring and
summer, therefore, by stimulating the amount of solu-
tion, increases to a marked extent the constituents avail-
able for plant growth.

The effect of temperature is less marked in a direct
way on the structure of the soil than on its chemical or
biological nature unless the freezing point is reached.
At this point, if moisture is present, the soil mass is dis-
rupted and may become rather granulated if the freezing
process is often repeated. The practice of fall-plowing
in order to better the tilth of the soil is really taking advan-
tage of -this natural phenomenon. A change in tem-
perature also causes the expansion or contraction of the

2902 SOILS: PROPERTIES AND MANAGEMENT

soil gases and may greatly facilitate their movement.
This is essentially a physical relationship. It must be
kept in mind, however, that with heat as with other soil
factors, no clear-cut and distinct discussion of its effects
in one direction may be made without considering the
indirect influences that are continually opening up avenues
which lead to phases more or less foreign to the one under
discussion. This serves to emphasize the close correla-
tion of the various factors and conditions that must be
dealt with in a study of soils.

209. Sources of soil heat.— The soil may receive
heat directly or indirectly from three general sources:
(1) from the sun, (2) from the stars, and (3) by
conduction from the heated interior of the earth.
The two last-named sources are so unimportant as
to warrant no further discussion, since the amount of
heat received by the soil therefrom is so small as to be
negligible.

The sun, then, either directly or indirectly supplies
all the heat and energy that make it possible for soils to
support vegetation. This heat is derived in various ways,
as follows : —

(1) By direct radiation of rays, both of light and of
invisible heat. These rays when absorbed tend to raise
the temperature of the absorbing medium. This source
of heat is by far the most important and may be desig-
nated as the direct method of heat induction.

(2) A considerable amount of heat may be derived by
radiation and conduction from the atmosphere surround-
ing the earth. This heat has of course been originally
obtained from the sun and is passed on to the soil, the
length of the waves being somewhat changed in the transi-
tion, Clouds may sometimes serve as a blanket and shut

SOIL HEAT 293

in around the earth heat that would otherwise be entirely
lost so far as the soil is concerned.

(3) A certain amount of heat may be brought to the
soil by precipitation. A warm spring rain, by falling
on the earth and percolating into its subsoil, may be a
determining factor in crop growth. Although the
aggregate amount of heat added in this way is small,
the opportuneness of its application is of no small
importance. A warm rain often imparts an impetus
to plant growth which may be noticeable for many weeks
afterward.

(4) A large amount of heat is annually entrapped by
growing plants. This energy is stored up and may ulti-
mately be liberated by the decay of the tissue. If such
oxidation takes place in the soil, as it very largely should
under good farm management, a certain amount of heat
is liberated in the soil. How important this is it is
difficult to say, for such energy is given off so grad-
ually as to be rendered difficult of measurement. Bac-
terial activity is very closely allied to the utilization
of such heat. Except under exceptional conditions, as
in hotbeds or very heavily manured lands, such heat
has no appreciable effect in altering the temperature of
a normal soil.

210. Factors affecting soil temperature. The tem-
perature that the soil of any given locality may attain
is dependent on a certain group of factors so closely re-
lated as to make their separate consideration sometimes
rather difficult. For convenience these factors may be
listed as follows, the actual temperatures and their
probable fluctuations under field conditions being re-
served until the various intrinsic and external factors of
soil heat have been discussed : —

994 SOILS: PROPERTIES AND MANAGEMENT

. Specific heat

. Absorption

. Radiation

. Conductivity and convection
. Evaporation of moisture

. Organic decay

. Slope

. Heat supply and its effects

211. Specific heat. — The specific heat of any material
may be defined as its thermal capacity as compared with
that of water. It is the ratio of the quantity of heat
required to raise the temperature of a given weight of
the substance one degree Centigrade to the quantity
needed to change an equal weight of water from 19.5°
to 20.5° Centigrade. A knowledge of the specific heat
of soil is important because of the general light it sheds
on the warming-up of a soil in spring and on its rate of
cooling in autumn. The data from a number of investi-
gations, in the order of their priority, is here quoted,
the calculations being based on dry soil : —

CO AT & Or BR OW De

Wrigcat Sprctric Heat or Sorts

Pfaundler! (1866) Liebenberg? (1878)
Fine sand . . . .1923 Coarsesand . . .1920
Alluvial soil . . .2507 Diluvialloam . .2250
Granite soll . . .38489 Fineloam . . . .2770
Humous soil . . .4143 Humousloam . .3290
Peat. . . . . .5069 Granite soil . . 3880

1Pfaundler, L. Ueber die Warme Capacitat Verschiedener
Bodenarten und deren Hinfluss auf die Pflanze. Ann. d.
Physik u. Chemie, Band 205, Seite 102-135. Leipzig, 1866.

2 Liebenberg, R. von. See Lang, C. Ueber Warme Capa-
citat der Bodenconstituenten. Forsch. a. d. Gebiete d. Agri.-
Physik, Band I, Siete 118. 1878.

SOIL HEAT 295

Lang! (1878) Patten? (1909)
Coarse sand . . .1980 Norfolksand . . .1848
Limestone soil . .2490 Podunk fine sandy
Humous soil . . .2570 loam . . . .. .1828
Garden soil . . .2670 Hagerstown loam .1914
Peat. . . . . .4770 Leonardtown loam .1944

Galveston aay . .2097
Bouyoucos? (1913)

Sand .. . . . « L929
Gravel . . 2. . we) 2045
Clay ....... . . .2059
Loam ....... . . 2154
Peat ..... . . . « 2525

212. Variations of specific heat. — These figures show
a considerable amount of variation, part of which is of
course due (1) to inaccuracies in the designation of the
materials used, (2) to differences in methods, and (3)
to differences in technique. Allowing for these probable
errors, there still seem to be other factors involved. One
of these might be texture, since, according to the earlier
investigators, the finer mineral soils seem to possess a
higher specific heat. The data of Bouyoucos and Patten,
however, seem to controvert this assumption. An in-
vestigation more to the point is that of Ulrich.t| In work-

iLang, C. Ueber Warme Capacitat der Bodenconstitu-
enten. Forsch. a. d. Gebiete d. Agri-Physik, Band I, Seite
109-147. 1878.

2Patten, H. E. Heat Transference in Soils. U.S. D. A,
Bur. Soils, Bul. 59, p. 34. 1909.

$’Bouyoucos, G.J. An Investigation of Soil Temperature.
Michigan Agr. Exp. Sta., Tech. Bul. 17, p. 12. 1918.

4Ulrich, R. Untersuchungen uber die Warmekapazitat
der Bodenkonstituenten. Forsch. a. d. Geb. d. Agri.-Physik,
Band 17, Seite 1-31. 1894.

996 SOILS: PROPERTIES AND MANAGEMENT

ing with various grades of quartz sand he obtained
practically identical specific heats with the various sepa-
rates :—

Spociric Huat or Varrous GRADES OF SAND AS Founp py

ULRICH
Diameter of Sands in Millmeters Specific Heat

2-1 1912

1-5 .1908

6-25 1922

25-171 1919

71-114 1919

114-071 1904

.071-.010 1890

It is evident, therefore, not only that texture has no
very great direct effect on specific heat, but also that
the controlling factor in the data already quoted is the
composition of the soil. The predominate minerals
found in soils possess a specific heat of from .180 to .220.!
This rather narrow range would normally be still further
lessened, since an average soil is a complex of the
different minerals. Humus, then, possessing a specific
heat of about .56 must, when added to any soil, in-
crease markedly its thermal capacity and would un-
doubtedly be the determining factor in weight specific
heat of the mixture.

213. Specific heat based on volume of soil. — Under
normal conditions, however, the soil contains a consider-
able amount of pore space, and different soils would

1Ulrich, R. Untersuchungen uber die Warmekapazitat
der Bodenkonstitenten Forsch. a. d. Geb. d. Agri.-Physik,
Band 17, Seite 1-31 1894.

SOIL HEAT 297

therefore show different weights to the cubic foot. A
specific heat comparison based on weight, therefore, does
not yield a fair idea of the heat capacities of two soils.
The multiplication of the weight specific heat by the
apparent specific gravity of the soil in question will
obviously yield a volume specific heat, which is a
much more rational basis for comparison. A quota-
tion from Ulrich! makes clear the value of such a com-
putation : —

Sepncrric Hoat or Sor EXPRESSED BY WEIGHT AND BY VOL-
UME OF SOIL

APPARENT
8 H § H
Sreouric ‘BY Wagar | BY VoLUm
Sand .... . 1.52 .1909 2901
Clay ..... 1 04 2243 2333
Humus oe ee Ol 4431 .1639

It is evident that in the first case the specific heat is
governed by the organic content of the soils in question;
the greater the amount of organic material present, the
higher is the thermal capacity. Such is not the case when
the specific heat of the soil is calculated on a volume basis.
In an expression of the thermal capacity on this rational
basis, namely, that of volume, the apparent specific grav-
ity, or volume weight, is the dominant factor. The ad-
dition of humus when this method of expression is em-
ployed merely serves to lower the volume weight, and

1Ulrich, R. Untersuchungen uber die Warmekapazitat der
Bodenkonstituenten. Forsch. a. d. Geb. d. Agn.-Physik,
Band 17, Seite 1-31. 1894.

2908 SOILS: PROPERTIES AND MANAGEMENT

a reduction of specific heat thereby occurs. Under such
conditions more heat is necessary to raise the temperature
of the sand than is the case with the weight expression.
This is because of its high apparent specific gravity. The
clay shows very little change, as its apparent specific
gravity is about one; but the humus exhibits a marked
falling-off, due to its exceedingly low volume weight.
The factor that tends to vary the specific heat of dry
soil under natural conditions, therefore, is the apparent
specific gravity, or the volume weight. By deep and
efficient plowing the farmer may encourage the warm-
ing of his soil, due to a lowered thermal capacity. By
increasing its humus content he may attain the
same result, since the volume weight is depressed to
a markedly greater extent than the specific heat is in-
creased by the addition of organic matter. In fact, any
operation on or any addition to the soil that will vary
its apparent specific gravity will in turn affect the specific
heat.

214. Effect of water on specific heat.— One other
factor, much more potent than the two already men-
tioned, is yet to be discussed. This factor is water, so
universally present in soils and of the greatest importance
in all natural soil phenomena. As the specific heat of
water is very high compared with the thermal capacity
of the soil constituents, any addition of it must naturally
raise the specific heat of a normal soil. That moisture,
not apparent specific gravity nor organic content, is the
controlling factor 1s demonstrated from the following
data, calculated by Ulrich! on a volume basis : —

1Ulnch, R Untersuchungen uber die Warmekapazitat der
Bodenkonstituenten. Forsch a.d Geb d Agn-Physik, Band
17, Seite 27. 1894.

SOIL HEAT

299

Tas Errect or Sort Morsivry. ov taco Vouume Sprciric
Hat or Sort, tHE Moisture BLING Exprossop AS A PER-
CENTAGE or THE Toran Watinr Capacity

Quartz
Kaolin
Humus

| 2919

3300 | 3682 | 4063 | 4445
2945} 3558} 4170) 4783
2427 | 3207 | 3987 | 4767

2333
1647

It is at once evident, from these data and the accom-
panying curves (see Fig. 46), that moisture, in its effect
on the specific heat of an average soil, is so potent as to

Fig. 46.—Curves showing the effect of moisture on the volume specific

heat of souls of different texture and humus content.

300 SOILS: PROPERTIES AND MANAGEMENT

entirely obscure in most cases the variations due directly to
such factors as apparent specific gravity and humus con-
tent. Organic matter, because of its high water capacity,
usually accentuates the dominance of moisture in this
respect. While a humous soil of low volume weight may
warm up most easily when dry, its high water content may
so increase its thermal capacity as to markedly retard
its temperature changes. This is exemplified by Petit!
and Bouyoucos” in their study of frost penetration in
peat. This soil was the last to freeze in winter and,
conversely, the last to thaw in spring. The advantage
of removing excess water by drainage is of importance
from this standpoint, as a wet soil is necessarily a colder
soil in spring than one that is well drained. This at least
partially accounts for the fact that a sandy soil is usually
an early one, and is therefore of particular value in truck-
ing operations.

215. Absorptive power of soils for heat. — The greater
proportion of the heat received by the soil is obtained
by direct radiation from the sun. This radiant heat is
propelled by free wave action in the ether, the space
intervening between the sun and the earth being but
little affected by the transfer. Were the total amount
of heat received from a vertical sun by any unit surface
wholly absorbed by a layer of soil twelve inches thick,
the temperature of the soil would rise thirty degrees
Fahrenheit an hour. Such is not the case under normal

1 Petit, A. Untersuchungen uber den Einfluss des Frostes
auf die Temperaturverhaltnisse der Boden von Verschiedener
Physikolischer Beschaffenheit. Forsch. a. d. Geb. d. Agri.
Physik, Band 16, Seite 285-310. 1898.

2 Bouyoucos, G. J, An Investigation of Soll Temperature.
Michigan Agr. Exp. Sta., Tech. Bul. 17, p. 214. 1913.

SOIL HEAT 301

conditions, however, as the atmosphere continuously
refracts, reflects, and absorbs a certain amount of this
radiant energy. More important still are certain inher-
ent qualities of the soil itself which function materially
in the modification of the amount of heat absorbed. These
intrinsic factors are color, reflection, texture, and structure.

916. Effect of color on absorption of heat. (See Fig.
47.)—In a natural soil it is very difficult to effect a change
in soil color without changing the texture, structure, and
more particularly the constitution, of the particles. In
order to eliminate these disturbing factors in a study of
heat, a quartz sand colored with various dyes was used
by Bouyoucos.t The following data, taken at Lansing,
Michigan, on a clear, warm day in August, illustrate
the general effects of color on absorption : —

Errect or Dirroronr Corors on Hrat ABSORPTION BY
Quartz Sanp, August 5, 1.380 p.m.

Color Temperature
(Degrees Centigrade)
Black . . . . .. . hl. 87.6
Blue ........ . . 86.7
Red ...... . .. . 85.9
Green. 2. ww we ee ee OAT
Yellow ...... . . . 826
White. . ...... . . 817

It is quite evident that the darker the soil, the greater
is its absorptive power. This is because of differences
in reflection, a light-colored soil reflecting more of the
heat rays than one of a darker color. There might be a
question here as to the difference in radiation arising from

1Bouyoucos, G. J. An Investigation of Soil Temperature.
Michigan Agr. Exp. Sta., Tech. Bul. 17, p. 31. 1913.

302 SOILS: PROPERTIES AND MANAGEMENT

color, the white soils radiating more heat than the black
ones. The following data from Bouyoucos,’ substantiating
those of Lang,? are a conclusive negative answer to such
a query : —

RADIATION oF DIFFERENT-COLORED SANDS, WHITE BERING
TAKEN As 1.00

White . ...... =. . . 1.000
Black . . . ..0..CeS)COQQI
Blue ........ . . 981
Green . . ww. ew ee ee) 981
Red. . 2... ew ee eee GT
Yellow. . . 2. 2. ee eee) 989

The addition of organic matter, provided its decay has
been of the proper sort, will consequently always raise
the soil temperature, other factors of course being equal.
Wollny,® in experimentation with soils covered with thin
layers of different-colored material, found marked dif-
ferences under field conditions. The black soil not only
exhibited the highest temperature, but also showed a
greater amount of fluctuation. The minimum tempera-
tures of the different-colored soils were almost the same.
The temperature differences of course decreased with
depth. Some typical data obtained on a clear day, as
quoted from Wollny’s work, are as follows : —

1Bouyoucos, G. J. An Investigation of Soil Temperature.
Michigan Agr. Exp. Sta., Tech Bul. 17, p. 30. 1918.

*Lang, C. Uber Warme-absorption und Emission des
Boden. Forsch. a. d. Gebiete d. Agri.-Physik, Band I, Seite
379-407. 1878.

3 Wollny, E. Untersuchungen uber den Hinfluss der Farbe
des Bodens auf dessen Erwarmung. Forsch. a. d. Geb. d.
Agri-Physik, Band I, Seite 43-69. 1878. Also, Untersuch-
ungen uber den Einfluss der Farbe des Bodens auf dessen HErwar-

mung. Forsch. a. d. Geb. d. Agri.-Physik, Band IV, Seite
327-305. 1881.

SOIL HEAT 303

TEMPERATURES OF DIFFERENT-COLORED Sorts at A Depre or
4. INCHES, TAKEN JUNE 23, 1876, at Munica (in DuGrezs
CLUNTIGRADD)

TIME

Midnight
2 A.M.

7 2 4- 6 8 fo WN 2 F & & SOTIIIE.

Fig. 47.— Curves showing the temperature variation of different-colored
soils at a four inch depth compared with air temperature. Munich,
June 23, 1876.

804 SOILS: PROPERTIES AND MANAGEMENT

Besides the quite obvious effect of the dark color on
the rate of heat absorption, two other points are worthy
of notice. The first is the tendency of the soil tempera-
ture to lag behind the temperature of the air, and the
second is the almost equal minimum reached by the two
soils. The latter point would seem to indicate also that
color had little differential effect on the heat lost from
the soil by radiation into the air.

217. Effects of texture and structure on heat absorp-
tion. — Ordinarily the texture and the structure of a
soil, other conditions being equal, have little direct
influence on rate of absorption. Wollny! found with
dry and moist soil that the coarser the particles, the higher
is the temperature during warm weather. A loose, open
structure was always more favorable for high tempera-
tures than one more finely pulverized. Wollny’s tem-
perature differences, however, were very small, and it is
probable that the experimental error, particularly due
to lack of moisture control, was greater than the observed
differences. Under normal conditions the practical effects
arising from the influence of texture and structure on
rate of absorption are probably entirely eliminated by
other factors. The importance of texture and structure,
as will be shown later, is in the direction of the control
of soil heat through their influence on soil moisture.
Moisture in turn is a potent factor in the ultimate soil
temperature, as it influences specific heat, radiation, and
evaporation to such an extent.

218. Radiation of heat by soil. — The principal loss

1'Wollny, E. Untersuchungen uber den Hinfluss der Struk-
tur des Bodens auf dessen Feuchtigkeits- und Temperatur-
verhaltnisse. Forsch. a. d. Geb. d. Agri.-Physik, Band V,
Seite 145-209. 1882.

SOIL HEAT 305

of heat by the soil is through radiation, this radiation
being controlled by certain factors of which moisture
content, soil mulches, artificial coverings, shelters, and
clouds are the most important. Color as a factor in
radiation has already been eliminated by the work of
Bouyoucos and Lang. The effects of texture and struc-
ture have also been investigated by these authors, as
well as by other physicists. The general results seem
to indicate that unless a dry soil is dealt with these factors
may be eliminated from consideration as far as their
direct practical effect on radiation is concerned. Of
course, indirectly through their influence on such factors
as moisture, they are of extreme importance.

An increase in the moisture of a soil has the general
effect of heightening the radiation ratio. This, together
with the effects of evaporation and of increased specific
heat, accounts for the fact that an undrained soil in spring
is a cold soil. Bouyoucos! found the following relation-
ships between moist and dry soils: —

Erroct or MoisturgE on RADIATION

Som, PERCENTAGE OF | RADIATION OF RADIATION OF

Morsturs Moisr Soin Dry Sor
Gravel . . . . . 100 92.4.
Sand . .... . 100 93.1
Clay .... . . 100 91.9
Loam ..... . 100 90.9
Peat . .... . L100 86.1

Mulches, either natural or artificial, tend to check the
loss of soil heat through their covering effect and their

1 Bouyoucos, G. J. An Investigation of Soil Temperature.
Michigan Agr. Exp. Sta.,, Tech. Bul. 17, p. 34. 1913.

306 SOILS: PROPERTIES AND MANAGEMENT

influence on radiation. As a mulch is usually dry, its
radiant power is lower than that of the moist soil beneath.
Shelters decrease radiation by checking air movement.
The vegetation growing on soil also lowers radiation
through its covering effect, although the temperature of
soils covered with vegetation is usually low in summer
due to the obstruction of the sun’s rays. Clouds, by
shutting in the heat, tend to check radiation and in many
cases prevent a frost that would otherwise occur. The
protecting effect of snow is well illustrated from the fol-
lowing data, taken from Boussingoult : —

Errect or Snow on Soin ToMPERATURE.! (TEMPERATURE IN
D5rGREES CENTIGRADE)

Sameeennaneanmen

Dare anp Hour AIR gen, QNDER
Feb. 11, 5 p.m. +2.5 | — 1.5 0.0
Feb. 12, 7 a.m. —3.0 | ~12.0) —3.5
Feb. 18, 7 a.m. —38 | — 82), — 2.0
Feb. 18, 5.80 p.m. +45 | — 1.0 0.0

One of the important features of soil heat radiation is
its effect on air temperature. As the radiant energy from
the sun passes through the atmosphere, very little of the
heat is appropriated, due to the wave lengths. But,
as this energy is radiated from the soil, the heat waves
have become shortened and are readily taken up by the
atmosphere, particularly if the latter is moist. How-
ever, as the air is always in motion its heat is not con-
trolled by the soil radiation of any particular locality.

1 Warington, R. Lectures on Some of the Physical Proper-
ties of Soils, p. 159. Oxford. 1900.

SOIL HEAT 307

In fact, the soil may be warmed by conduction of heat
from air to soil. This probably occurs to some extent
in spring, when the air is growing warmer, due to low
specific heat and its movement. The changes in air
temperatures are always more rapid and usually greater
in range, due to the factors cited above.

219. Conductivity and convection of heat in soils. —
While radiation has to do with the transfer of heat by
ether waves, conductivity is a term used in relation to
molecular transmission of energy through the body under
investigation. It may be defined as the amount of heat
in calories that will pass across a cube of unit edge (1
centimeter), in unit time (1 second) under a temperature
gradient of 1 degree Centigrade. Convection refers to
the transmission of heat by actual apparent and visible
movements of matter. It is to these two modes of trans-
fer that we owe the possibility of the soil’s warming below
a surface that receives most of its heat as radiant energy.
It must be remembered that in studying the soil we are
dealing with a material made up of mineral and organic
compounds and always containing, under normal condi-
tions, a certain quantity of water. Air likewise is always
present, which, while a poor conductor of heat, may carry
energy by convection. Besides these varying substances,
often in loose contact and usually containing air capable
of considerable movement, there is bound to occur a
certain amount of transfer conductivity which is the heat
resistance found at the boundary of two substances in
contact. The study of heat movement downward through
a soil is difficult to analyze, since it is almost impossible
to control the factors concerned while varying any one.
In a normal soil this heat movement occurs through both
the agency of conduction and that of convection, depend-

8308 SOILS: PROPERTIES AND MANAGEMENT

ing on the texture and structure of the soil and the amount
of moisture present.

920. Measurement of conductivity. — Ordinarily the
conductivity of a soil is measured by applying a constant
source of heat as quickly as possible and measuring the
change in temperature by means of thermometers set
in the soil at regular intervals. (See Fig. 48.) The soil in
question should be homogeneous in composition and of
uniform compaction, and should contain a definite mois-
ture content. It should of course be at a temperature
equilibrium before the heat is applied. Ordinarily radia-
tion and convection currents are diminished somewhat
by inclosing the soil in an insulated compartment. The
study of heat movement downward instead of laterally
is to be recommended, in order that unnecessary air
circulation may be avoided to some extent.

AN
us

4 ,
LLY Abd ¢

B Ar r@® (22727727722 42

Fia 48 —Longitudinal section of apparatus for the study of heat con-
ductivity of soul (C), water at constant temperature, (¢), ther-
mometer, (P), copper plates, (F), screw clamp for pressing soil
firmly against source of heat, (7), skids for soil box.

221. Effect of texture on conductivity of heat. — The
conductivity of a soil is affected by a number of factors

SOIL HEAT 309

which may or may not lend themselves to modification
in the field. From the fact that type is of primary im-
portance in choosing a soil, texture in its relation to con-
ductivity might be considered first. From the work of
Wagner! and Potts? it is clearly established that the
coarser the texture of a soil, the faster the rate of conduc-
tion of heat will be, other factors remaining constant.
Data quoted from the findings of Bouy oucos ® substantiate
these results : —

Convuctiviry or Various Sorts 4s MpasurED By THE TIME

RroQvIRoD FoR A THORMOMETER 7 INCHES FROM THE SOURCE
or Hnat ro SuHow 4 Rise in TEMPERATURE

si Relate Rate o
Sand... . 6. ew we ee 1.00
Loam .......... L&i
Clay... . 2. eee Od
Peat... . .. ee 46]

Such results as these are only comparative and qualita-
tive. The difficulties of quantitative determinations are
so beset by error that only one investigator has as yet,
made any consistent attempt along this line. Patten,‘
who has prosecuted such an investigation, finds that such
work may be vitiated by thermometer spacing, size of
thermometer, error in readings, moisture control, and

1Wagner, F. Untersuchungen uber das Relative Warme-
leitungsvermogen Verschiedner Bodenarten. Forsch a. d.
Geb d Agr -Physik, Band VI, Sette 1-51. 1885.

2 Potts, E. Untersuchungen Betreffend die Fortpflan-~
zung der Warme in Boden durch Leitung lLandw. Ver. Stat,
Band XX, Seite 273-855. 1877.

3’ Bouyoucos, G. J An Investigation of Soil Temperature.
Michigan Agr. Exp. Sta, Tech Bul 17, p 20 1913.

4Patten, H E. Heat Transfer in Souls. U.S. D. A., Bur.
Soils, Bul. 59. 1909.

310 SOILS: PROPERTIES AND MANAGEMENT

the necessity of taking time-temperature curves in the
unsteady state. His results, expressed as metric K (the
heat conductivity coefficient in C. G. 5. units), show the
same general comparisons as already presented : —

Hear Conpuctiviry oF DirrEReNtT SOILS
K in C.G-.S. units

Soil (See Definition of

Conductivity)
Coarse quartz . . . . . .000917
Leonardtown loam . . « 000882
Podunk fine sandy loam . . = .000792
Hagerstown loam . . . . .000699
Galveston clay . . . . . .000577
Muck. . . . . . .~ . 000849

222. Effects of humus and structure on conductivity. —
A disturbing factor always present when soils are used
in the determination of the effect of texture on conduc-
tivity, is humus. It is evident, in dry soil at least, that
an increase in the organic content of a soil means a lower-,
ing in conductivity. Humus, therefore, must be listed
as a second factor tending to vary the movement of heat
through soils. A third factor is the structural condition
of the soil under examination. Wagner‘! has shown in
this regard that the more compact a soil, the faster is
the conduction of heat. This is probably due to the more
intimate contact of the soil grains, and a consequent
cutting-down of the insulation factors and diminution
of the transfer resistance.

223. Influence of moisture on heat conductivity in soil.
— The greatest single factor to be considered in conduc-

1Wagner, F. Untersuchungen itiber das Relative Warme-

leitungsvermogen Verschiedner Bodenarten. Forsch. a. d.
Geb. d. Agri-Physik, Band VI, Seite 1-51. 1885.

SOIL HEAT 311

tivity study, however, is the moisture content of the soil.
The following curve for quartz powder, taken from Pat-
ten’s ! work, illustrates its effect and shows how its influ-
ence may heavily override the factors already mentioned.

ce)
QMEFUSIVITY SCALE °C

002

® oy
IF, VOL. SCALE -og :

FZ 1? iF ao
Jo WATER BY WEIGHT

Fic. 49.— Effect of moisture upon the apparent specific volume, heat
conductivity, and diffusivity of coarse quartz powder.

1Patten, H. E. Heat Transfer in Soils. U.S. D. A.,
Bur. Soils, Bul. 59, p. 30. 1909.

812 SOILS: PROPERTIES AND MANAGEMENT

At first glance it appears peculiar that the heat move-
ment through a soil, the mineral constituents of which
possess a conductivity coefficient of about .01066, should
be raised by the addition of a liquid possessing a value of
Ix of about .00149, a conductivity about one-seventh of
the soil minerals. The explanation of this as given by
Patten is a lowering of the transfer resistance. He has
calculated that heat will pass from soil to water approxi-
mately one hundred and fifty times more easily than
from soil to air. This being true, it is evident that as
the water is increased in any soil and the air decreased,
the conductivity coefficient increases. It must be kept
in mind, however, that as the moisture mcreases, the
total amount of heat necessary to raise this soil to a given
temperature must also be increased. The necessity for
the maintenance of a medium moisture content in any
soil becomes apparent, although the conductivity may
not thereby be at its maximum. ‘The curves in question
show that not only is there a change of volume weight,
but also there is a decrease in diffusivity with high water
percentages — another reason for avoiding excessive
moisture contents in a field soil.

As has already been noted, the warming-up of a soil
becomes less and less rapid as the subsoil is penetrated.
This is not due to lessened conductivity, but rather to
a lessened heat supply. Bouyoucos! has shown that
under natural conditions the tendency of heat is to travel
downward more rapidly than laterally, due to a higher
moisture in the lower depths of the average field soil.
The time-temperature curves and the temperature gradi-

1 Bouyoucos, G. J. An Investigation of Soil Temperature.
Michigan Agr. Exp. Sta., Tech. Bul. 17, p. 25. 1913.

SOIL HEAT 313

ent for quartz powder as drawn by Patten! (see Figs. 50
and 51) illustrate the effect of distance on temperature
rise, the conductivity coefficient remaining constant.

Degrees C.
80 ne {

eee
=
fT

70 £0 30.4 50 [ime INT.

Fic. 50.—Temperature time curves for quartz powder at various dis~
tances from the source of heat.

From this brief discussion of conductivity it may be
established that such a movement is of importance to
plants in carrying heat downward into the soil. While
it is affected directly by tex-
ture, structure, and humus
to a certain extent, moisture
is the dominant factor. Under
natural conditions it 1s neces-
sary to maintain a medium
moisture content, although
the conductivity of heat is pe ze Pom soctce of Moe,
not then at its maximum. Fig. 51.—Temperature gradi-
However, it must always be ent for air-dry coarse quartz
remembered that convection °°¥¢*™
is active under such conditions and may do much in
facilitating heat distribution. Good tilth and increased
organic content of any soil, by raising the optimum

1Patten, H. E. Heat Transfer in Soils, U. 8S, D. A,
Bur. Soils, Bul. 59, pp. 23-24. 1909.

S14 SOILS: PROPERTIES AND MANAGEMENT

moisture content for plant growth, will place the soil in
the best possible condition, consistent with plant devel-
opment, for good heat movement.

224. Effect of evaporation of water on soil temperature.
— There is perhaps no factor, besides the loss of heat by
direct radiation, which exerts such an effect on soil tem-
perature as does evaporation. The fact that water does
not allow the long rays received by direct radiation to pass
readily through it accounts for its rapid vaporization.
This evaporation, caused by an increased molecular
activity, requires a certain expenditure of heat, result-
ing in a cooling effect on the water and consequently on
any material in close contact with it. To evaporate a
pound of water requires the withdrawal of about 966
heat units.1 This is sufficient to lower the temperature
of a cubic foot of saturated clay soil about 10° Fahrenheit.
The difference in temperature exhibited by wet and dry-
bulb thermometers measures the cooling effect of
evaporation.

Any condition that increases the rate of evaporation
lowers the temperature of the surface concerned. The
amount of water present is undoubtedly the controlling fac-
tor in this regard. King? found, in his study of a drained
and an undrained soil in April, that the former maintained
a temperature ranging from 2.5° to 12.5° Fahrenheit
higher than the latter. Parks * records the same general

1 An English heat unit is the amount of energy necessary to
raise one pound of pure water from 32° to 33° F. It is equal to
about 778 foot-pounds.

*King, F. H. Physics of Agriculture, p. 220. Published
by the author, Madison, Wisconsin. 1910.

’ Parks, J. On the Influence of Water on the Temperature
OA Soils. Jour. Roy. Agri. Soc. Eng., Vol. 5, pp. 119-146.
1845.

SOIL HEAT 315

results in England. Wollny‘ finds a wet soil to be the
cooler in the daytime, the difference being roughly pro-
portional to the amount of water present. The effect
of the amount of water on the rate of evaporation is of
course influenced to a certain extent by texture, struc-
ture, and humus, since these factors exert such a marked
influence on water capacity and capillary movement.
The practical importance of a study of the effect of
evaporation on soil temperature lies in the fact that evap-
oration can be controlled to a certain extent under field
conditions. ‘This is not so true, unfortunately, of radia-
tion and conduction. Thorough underdrainage is the
dominant operation in the prevention of cooling by
evaporation. By this removal of excess water the specific
heat is lowered, radiation is slightly retarded, and con-
vection is facilitated. This means a faster warming of
the soil, tending toward an optimum temperature rela~
tion as far as the plant is concerned. Optimum moisture
encourages optimum heat conditions, as well as other
favorable relations whether chemical, physical, or biologi-
cal. Drainage, lime, humus, and tillage figure in heat
control as well as in other phases of soil improvement.
225. Effect of organic decay on soil temperature. —
Besides the effect of organic matter on color and its conse-
quent influence on the absorption of heat, it may function
in another direction, namely, in producing heat of fer-
mentation. How far this liberation of heat under field

1Wollny, E. Untersuchungen iiber den Hinfluss des
Wassers auf die Boden. Forsch. a. d. Geb. d. Agri.~Physik,
Band IV, Seite 147-190. 1881. Also, Untersuchungen tiber
den. Einfluss der Oberflichlichen Abtrochnung des Boden auf
dessen Temperatur- und Feuchligkeitsverhaltnisse. Forsch. a. d.
Geb. d. Agri.-Physik, Band ITI, Seite 325-348. 1880.

316 SOILS: PROPERTIES AND MANAGEMENT

conditions is effective in bringing about any important
modification of soil temperature it is often difficult to
decide. In greenhouses and hotbeds perceptible increases
are obtained by the use of large quantities of fresh manure,
as high an increase as 75 degrees Centigrade has been
observed under such conditions. In the field, however,
where the absorption and radiation of heat are very large,
where the organic matter makes up only a fraction of the
soil’s components, and where the applications of barnyard
manure are relatively small compared to the bulk of the
soil, it is doubtful whether any important increase of
soil heat actually occurs. Georgeson,! working in Japan
with varying quantities of manure, obtained during the
first twenty days an excess over the check of only 3.4
degrees Fahrenheit from an application of eighty tons an
acre. With twenty tons the increase was 1.7 degrees.
Wagner? obtained similar results, finding an average
excess of 1 degree Fahrenheit from the use of twenty
tons of barnyard manure. Bouyoucos? has obtained the
latest data on this subject. Under controlled laboratory
conditions he found that unless excessive amounts of
manure were applied no appreciable effects were observed.
With an application of ten tons the highest rise was one-
half degree Centigrade; after one hundred and three
days the manured soil was only one-fourth degree higher
than the untreated. Such results show that the heat of
fermentation has little important practical influence

1Georgeson, C. C. Influence of Manure on Soil Tempera-
ture. Agr. Sci., Vol. I, pp. 25-52. 1887.

2 Wagner, F. Uber den Einfluss der Dungung mit Organ-
ischen Substance auf die Bodentemperatur. Forsch. a. d.
Geb. d. Agri.-Physik, Band V, Seite 373-405. 1882.

3 Bouyoucos, G. J. An Investigation of Soil Temperature.
Michigan Agr. Exp. Sta., Tech. Bul. 17, pp. 180-190. 1913.

SOIL HEAT 317

on soil temperature, so far as the total bulk is concerned.
There are without doubt certain localized influences,
both chemical and biological, but how important they
may be it is rather difficult to say. From what is known
at the present time it seems that organic matter exerts
its greatest temperature effects through the darkening of
the color and the increase in moisture capacity of the
soil.

226. Relation of slope to soil temperature. ——- The rela-
tion of exposure to soil heat is the last phase to be con-
sidered, with the exception of meteorological factors,
which are external in their relationships rather than intrin-
sic as have been most of the phases already discussed.
The slope of a surface varies the amount of heat
absorbed from the sun, without affecting, of course, the
absorptive power of the surface involved. The greater
the inclination of a soil from a right-angle interception
of the heat rays, the less rapid will be its rise of tempera-
ture in a given unit of time, the source of heat remaining
constant. This is because the greater the inclination,
the greater is the amount of surface a given amount of
heat must serve. It is evident that a less amount of
heat will reach each unit of soil surface, and a conse-
quent slower rise in temperature of the soil so situated
will result. Under normal conditions, therefore, any
inclination that will cause a surface to approach a right-
angle interception of the sun’s rays will not only increase
its rate of temperature rise but at the same time will
increase its average seasonal temperature. In the North
Temperate Zone this of course is a southerly inclination.
The following diagram, illustrating the conditions on the
42d parallel at noon on June 21, makes clear this rela-
tionship :—

318 SOILS: PROPERTIES AND MANAGEMENT

Fig. 52.—Diagram showing the proportional amount of heat received to
the unit area by different slopes on June 21, at the 42d parallel north.

It is seen that in this case a southerly slope of 20°
receives to a unit area the greatest amount of heat, the
level soils and the soils having northerly inclination of
20° differing in the order named. The following table
shows the proportional amount of heat received by each
one of these soils per unit area at midday with such an
inclination of the sun’s rays :—

ProportTionaL Amount oF Heat Ruecetvep per Unit Arma
BY DirrereNntT Stopes on June 21, av tan 42p ParaLLEen
Norts LatirupEe

20° Southerly slope = 106
Level 100
20° Northerly slope 81

SOIL HEAT 319

These figures show not only that the slope itself is impor-
tant, but also that the direction of the inclination must
play a part in the selection of land with its probable
temperature relationships borne in mind. The investi-
gations of Wollny,' which have since been corroborated
by King? and others, may be cited at this point as typi-
cal: —

AVERAGE TEMPERATURE at 6 IncHES or A Humous Sanpy
LoaM FRoM APRIL TO OcToBER, 1877, Munica, GERMANY

Temperature
in Degrees
Centigrade

South. . . . . .. . . . 14.46
Southeast ....... . 14.42
Southwest ....... . 1442

East . . ... .. 618,99
West . . ... . . «13.98
Northwest . ...... . 13.64
Northeast . ..... . . 138.56

North. . ..... .. . 18.52

1Wollny, E. Untersuchungen tiber den Hinfluss der
Exposition auf die Erwairmung des Bodens. Forsch. a. d.
Geb. d. Agri.-Physik, Band I, Seite 263-294, 1878; Unter-
suchungen iiber die Feuchtigkeits- und Temperaturverhalt-
nisse des Bodens bei Verschiedener Neigung des Terrains gegen
den Horizont. Forsch. a. d. Geb. d. Agri.-Physik, Band IX,
Seite 1-70, 1886; Untersuchungen tiber die Feuchtigkeits-
und Temperaturverhiltnisse des Bodens bei Verschiedener
Neigung des Terrains gegen die Hummelsrichtung und gegen
den Horizont. Forsch. a. d. Geb. d. Agri-Physik, Band X,
Seite 1-54, 1887; Untersuchungen iiber die Temperaturver-
haltnisse des Bodens bei Verschiedener Neigung des Terrains
gegen die Hummelsrichtung und gegenden Horizont. Forsch.
a. d. Geb. d. Agri.-Physik, Band X, Seite 345-364. 1887.
,2King, F. H. Physics of Agriculture, p. 218. Published
by the author, Madison, Wisconsin. 1910.

320 SOILS: PROPERTIES AND MANAGEMENT

Wollny found also that the soil temperature on the
southward slopes varied according to the time of year.
For example, the southeasterly inclination was highest
in the early season, the southerly slope during mid-season,
and the southwesterly slope during the fall. A southeast-
erly slope is usually preferred by gardeners. Orchardists
also pay strict attention to aspect, as it often is a factor
in susceptibility to sun scald and other diseases.

King, in comparing a red clay with a southerly slope
of 18° to that on a level on July 21, obtained the follow-
ing results : —

TEMPERATURE IN Decrens FanRENHEIT or RED CLAY AS
INFLUENCED BY SLOPE

Frrst Foor | Szconp Foor Tarrp Foor

Southerly slop 7
Level . . 2... 6

It is apparent immediately that the influence of slope
is not confined to the surface, but, owing to conduction
and convection, is felt to a considerable depth. Slope,
therefore, together with moisture control, becomes a
dominant factor in the heat relations of a soil. This is
particularly true with specialized crops, with which the
early warming of the soil is important. A normally early
soil may become late because of exposure, or a naturally
late soil may become earlier due to an inclination south-
ward. Slope many times is a dominant factor in the
adaptation of crop to soil.

227. Heat supply and its effects. — The direct heat
supply is without doubt the controlling factor in soil

SOIL HEAT 3821

temperature, influenced, of course, by the conditions
already discussed. The effect of this heat supply is re-
flected in the seasonal, monthly, and daily soil tempera-
tures at the surface and at varying depths below. The
following data illustrate the differences that may ordi-
narily be expected to take place from season to season on
an average soil : —

AVERAGE TEMPERATURE Reapincs Taken at Bresuav, GER-
MANY.! AVERAGE oF TEN Yurars, 1901-1910 (In Ducrees
FAHRENHEIT)

Winter

43.5

Spring.
Summer . 57.5
Autumn . 53.3

AVERAGE TEMPERATURE Reapines Taken at Lincoun, NE-
BRASKA.”2 Averace or TwerLtve YxEarsS, 1890-1902 (Nn
DEGREES FAHRENHEIT)

Incues | Incuns

1Schulze, B., and Burmester, H. Beobochtungen tiber
Temperaturverhiltnisse der Bodenoberflache und verschiedener
Bodentiefen. Internat. Mitt. fiir Bodenkunde, Band II, Heft
2~3, Seite 188-148. 1912.

2Swezey, G. D. Soil Temperatures at Lincoln, Nebraska.
Nebraska Agr. Exp. Sta., 16th Ann. Rept., pp. 95-102, 1903,

322 SOILS: PROPERTIES AND MANAGEMENT

These average readings, taken at different points, are
supported by the data of other observers.’ It is apparent
that seasonal variation of soil temperature is considerable,
even at the lower depths. The surface layers of soil seem
to vary nearly in accord with the air temperature, and
therefore exhibit a greater fluctuation than the subsoil.
In general the surface soil is warmer in spring and sum-
mer than the lower layers, but cooler in fall and winter.
The following data taken at Lincoln, Nebraska, may be
of interest : —

AVERAGE MonrHuy TEMPERATURE READINGS? TAKEN at Lin-
con, NEBRASKA. AVERAGE OF TWELVE YEARS.

January . . | 25.2|27.3| 27.8 | 28.6 | 30.0 | 31.2 | 35.4 | 38.5

February. | 24.2 | 27.7 | 27.3 | 27.8 | 28.3 | 30.2 | 33.5 | 35.5
Mareh . ./|35.8)38.2/ 37.2 | 36.6 | 35.6 | 35.4 | 35.4 | 35.8
April. . . | 52.1) 57.5) 56.0 | 53.3 | 50.6 | 49.3 | 45.6 | 43.8
May . . .|61.9/68.7| 67.5 | 65.1 | 63.3 | 60.7 | 56.2 | 53.3
June . . ./ 71.0} 78.1} 78.0 | 75.7 | 73.8 | 69.9 | 64.6 | 61.3
July . . .| 76.0) 85.1) 838.6 | 81.6 | 79.3 | 75.7 | 70.2 | 67.4
August . .| 74.5) 82.9) 81.3 | 80.1 | 78.5 | 75.7 | 72.2 | 69.8
September . | 67.6|73.8| 73.4 | 72.0 | 70.7 | 69.2 | 68.7 | 67.6
October . .|55.5/ 56.7) 58.4 | 57.8 | 58.3 | 57.8 | 60.0 | 61.3

November . |38.7/|38.7| 40.9 | 41.5 | 43.3 | 44.7 | 49.2 | 52.2
December . | 28.3) 31.6) 31.4 | 32.0 | 33.4 | 35.2 | 40.1 | 48.3

Average . ./50.9/ 55.5) 55.3 | 54.6 | 53.8 | 52.9 | 52.6 | 52.5

tiemettemshieimniiteaeneed Teimmmnetamaeigammmmmenad Senmmenineiansnanianiasteniiniein” Kemeuptiamanemamanmeaaamanl Mbamanemmmnrensnamemee’l Yearemmammmrretaemanman’ Can cocimemumoraanet Ce

Range . .|51.8/ 57.8) 56.3 | 58.8 | 51.0 | 45.5 | 38.7 | 34.3

1Ebermayer, EH. Untersuchungen itiber das Verhalten
Verschiedener Bodenarten gegen Warme. Forsch. a. d. Geb.
d. Agri-Physik, Band 14, Seite 195-253. 1891.

*Swezey, G. D. Soil Temperatures at Lincoln, Nebraska.
Nebraska Agr. Exp. Sta., 16th Ann. Rept., pp. 95~102. 1903.

SOIL HEAT 323

The upper soil layers vary in accordance with the air
temperature, the maximum and the minimum occurring
in the same month. A lagging (see Fig. 53) is apparent
in the subsoil, due to the slow response of this area to the
heat penetrating from above. These figures also show
the surface soil to be warmer in spring and summer, and
cooler in winter and fall, than the lower depths. The
surface soil not only never falls as low in temperature as
the air, but reaches a higher point In summer. ‘This is
shown in the range of the air and soil temperatures. The
range for the air is 51.8°, while that for the soil is 57.8°,
56.3°, 53.8°, 51.0°, 45.5°, 38.7°, and 34.8°, respectively,
for the depths ranging from 1 inch to 36 inches. While
this range of soil temperature is greater in the aggregate
than that of the air, the changes are much slower and
often extend over a number of days, while the air may vary
many degrees in an hour.

oof RE

pect Ne

VAN FEB KAR APE MAY UNE SULY AUG SEPT O6TO HOV GEG

Fig. 53.—Curves showing the average monthly temperature readings at
various soil depths. Average of twelve years, Lincoln, Nebraska.

3894. SOILS: PROPERTIES AND MANAGEMENT

The daily and hourly temperature of the air and the
soil may be fairly constant or rather variable, according
to conditions. On days of sunshine, however, consis-
tent changes may be expected. The air temperature rises
from morning until about two o’clock, when the maxi-
mum is reached. Jt then falls rapidly. The soil, how-
ever, does not reach its maximum temperature until
later in the afternoon, due to the lagging so apparent in
soil temperature changes. This lagging is greater in
the lower layers than at the surface. The following data,
taken on a bright day on May 26 in Germany, illustrate
the ordinary differences that may be expected in soil
and air temperatures : —

Hourity TEMPERATURES TAKEN IN GERMANY ON May 26, 1884,
on A Loam Sor at 4-Ince Depts (In Dogrens FAHRENHDIT)

Hour AIR Barn Sor
Midnight Coe eee 55.4 63.5
2AM. . 2. « 2 ee 54.3 60.4.
AL. wk ke ke 52.7 58.5
6 . 1. 2 ew we ee 67.6 57.0
8B 2. ww wee ee 76.4 58.4.
JO... . 2. eee 82.0 63.3
Noon . . .. ... 83.5 69.8
2PM. . . 2. «© 2 « 85.6 74.8
re 84.2 77.9
6 2... we ee 78.1 V1
BS 2. oe ww ee 68.7 73.9
10... . ee ee 65.1 69.8

1Wollny, E. Untersuchungen uber den Hinfluss der
Pflanzendecke und der Beschattung auf die Physikolischen
Higenschaften des Bodens. Forsch. a. d. Geb. d. Agri.~Physik,
Band 6, Seite 197-256. 1885.

SOIL HEAT 325

Pas A ee Fa) & 40 wy 2 Xn 6 8 10 TYME

Fig 54—Curves showing the hourly temperatures of bare soul at a
depth of four inches and of the air above the soil. May 26, Germany.

The temperature of the soil at the surface may often
exceed that of the air, and the amount of daily fluctua-
tion may be greater; but for the lower depths the tem-
perature curve flattens out. The subsoil shows but
little daily, and even monthly, variation, and is affected
only by seasonal changes.

228. Control of soil temperature.— The means of
practical control and modification of soil temperature
are those commonly in vogue in good soil management.
The most important factor is, of course, soil moisture.
Good drainage, proper tilth developed by deep plowing,
plenty of lime, and sufficient organic matter, favor opti-
mum moisture conditions. Such moisture regulation
means a lowered specific heat and good conductivity.
The use of a soil mulch or an artificial covering not only
will check evaporation but will markedly retard loss of
heat by radiation. Any farmer who so controls his soil

826 SOILS: PROPERTIES AND MANAGEMENT

moisture that optimum conditions as far as the plant is
concerned may be obtained, should have no fear of a
poor utilization of heat.

The increase of soil humus, of course, may act directly
in heat control by darkening the color and increasing
absorption. A soil mulch, being dry, not only checks
evaporation but lowers radiation while increasing absorp-
tion. Any methods of handling the land which tend to
better the physical condition of the soil and increase its
tilth tend also toward a proper heat control at the same
time. The whole question may be summarized by say-
ing that if a farmer adopts a proper system of moisture
control and at the same time employs methods that tend
always toward a better physical condition of the soil,
the problem of control of soil heat will be automatically
solved. He will then have brought about the best condi-
tions for heat absorption and will have facilitated conduc-
tion and convection, while at the same time retarding
losses by evaporation and radiation.

CHAPTER XV

AVAILABILITY OF PLANT NUTRIENTS AS
DETERMINED BY CHEMICAL ANALYSIS

ForRTUNATELY for mankind, only an exceedingly minute
proportion of the soil is at any one time soluble in water
or in the aqueous solutions with which it is in contact.
It is this great degree of insolubility that gives the soil
its permanence, for in humid regions, without this property,
it would be rapidly carried away in the drainage water.
The portion of the soil that is soluble in the various natural
solvents with which it comes in contact furnishes mineral-
food materials for plants. The great mass of soil, which
is relatively insoluble, is constantly subjected to natural
processes which very slowly bring its constituents into
solution. The agents that are concerned in the decom-
position of rock also act on the soil to bring about its
further disintegration, and thereby render it more soluble;
while added to these are the operations of tillage, which
contribute to the same end.

Only the surfaces of the soil particles come into contact
with the decomposing agents, and hence it is the surface
matter of the particles that gradually goes into solution.
The factors that determine how rapidly solution shall
proceed are: (1) the amount of surface exposed, which,
as has been seen, varies with the size of the particles; (2)
the composition of the particles; (8) the strength of the
decomposing and solvent agencies. Were it not for this

327

328 SOILS: PROPERTIES AND MANAGEMENT

process, there would soon be no mineral food available
to plants, as drainage water and the growth of crops take
up relatively large quantities of these substances each
year; but in spite of this loss the soil is able to provide
at least some plant-food material for each crop, when
called upon by the plant.

229. Solubility of the soil in various solvents. — For
purposes of analyses that are intended to show the amounts
of mineral plant-food materials in a soil, any one of sev-
eral different solvents may be used. These solvents differ
in strength, and consequently the percentages of the
various constituents obtained from samples of the same
soil are different for each solvent. A chemical analysis
of a soil is a determination of the quantities of the con-
stituents that have been dissolved in the solvent used.
Therefore it will readily be seen that the interpretation
of a chemical analysis must depend largely on the nature
of the solvent, and, unless the solvent is equivalent in
its action to some process or processes in nature, the results
must be entirely arbitrary.

The methods that have been used for obtaining solu-
tions of the soil for analysis may be grouped as follows : —

1. Complete solution of the soil.

2. Partial solution with strong acids.
3. Partial solution with weak acids.
4, Extraction with water.

230. Complete solution of the soil. — By the use of
hydrofiuoric and sulfuric acids and by fusion with alkalies,
the entire soil mass may be decomposed and all its inor-
ganic constituents determined. Such an analysis shows

“he

1Wiley, Harvey W. Principles and Practices of Agri-
cultural Chemical Analysis, Vol. 1, pp. 398-399. 1906.

AVAILABILITY OF PLANT NUTRIENTS 329

the total quantity of the plant-food materials except
nitrogen, which is never determined in any of the acid
solutions but by a separate process.! A deficiency of
any particular substance may be discovered in this way,
but nothing can be learned as to the ability of the plant
to obtain nutriment from the soil. A rock may show as
much mineral plant-food material as a rich soil. This
method of analysis is used only to ascertain the ultimate
limitations of a soil or its possible deficiency in any essen-
tial constituent. Results of such analyses are to be found
in paragraphs 46, 48, 52, 53 of this text.

231. Partial solution with strong acids. — While sul-
furic, nitric, and hydrochloric acids have all been used as
solvents,” the one most commonly employed is hydrochloric
acid of 1.115 specific gravity. It has been used to such
an extent that it may be considered the standard solvent,
and a statement of a chemical analysis of a soil in this
country may be considered as based on this solvent unless
otherwise stated.

1 Official and Provisional Methods of Analysis. U.S. D. A.,
Bur. Chem., Bul. 107 (revised), p. 19. 1908.

2 Analyses using concentrated mineral acids on the same soil.
From Snyder, Harry. Soils. Minnesota Agr. Exp. Sta., Bul.
41, p. 66. 1895.

erat

Hypro-

CHLORIC Nrrric

83.45 80.45

Total insoluble percentage . 81.20

Potash percentage 0.42 0.30 0.52
Lime percentage 0.55 0.30 0.53
Magnesia percentage . . 0.40 0.32 0.52
Phosphorie acid percentage . 0.23 0.23 0.26
Sulfurie acid percentage . 0.08 0.08 0.10

’ Official and Provisional Methods of Analysis. U.S. D. A.,
Bur. Chem., Bul. 107 (revised), pp. 14~18. 1908.

830 SOILS: PROPERTIES AND MANAGEMENT

An analysis by this method is supposed to show the
proportion of plant-food materials in a soil that are in a
condition to be ultimately used by plants at the time
when the analysis is made, and the plant-food materials
that are not dissolved by treatment with hydrochloric
acid are assumed to be in a condition in which plants
cannot use them. The difficulty with this assumption is
that, while treatment with hydrochloric acid of a given
strength marks a definite point in the solubility of the
compounds in the soil, it does not bear a uniform rela-
tion to the natural processes by which these compounds
become available to the plant.

In the case of most soils a large proportion is not de-
composed by treatment with strong hydrochloric acid,
and the portion that is dissolved may contain a larger or
a smaller quantity of the agriculturally important ele-
ments, depending on the character of the soil. Thus if
calcium is present as a phosphate, a larger proportion
will be dissolved by the acid than if it is in the form of
silicate. The form in which potassium occurs also in-
fluences greatly the amount shown by analysis.

Snyder! has analyzed a number of soils by means of
digestion with strong hydrochloric acid, and has then
decomposed the acid-insoluble residue by fusion and
determined its composition. Veitch? has analyzed soils
by the hydrochloric acid method and by means of com-
plete solution. A few examples are given below to show
how soils may vary in the solubility of their constituents
in strong hydrochloric acid : —

Snyder, Harry. Soils. Minnesota Agr. Exp. Sta., Bul. 41,
p. 35. 1895.

*Veitch, F. P. The Chemical Composition of Maryland
Soils. Maryland Agr. Exp. Sta., Bul. 70, p. 103. 1901.

AVAILABILITY OF PLANT NUTRIENTS 331

PERCENTAGE OF CONSTITUENTS NOT SOLUBLE IN HCtu,
1.115 sp. GR.

Sor. FROM MINNESOTA Sor, From MARYLAND
. Experi- | Hudson
F Colum- | Chesa- :
Haven Holden se bia peake Shale
Potash... 94. Sl 83 95 67 73
Lime .. . 25 61 4} 90 82 3¢
Magnesia . .| 48 76 36 34. 29 28
Phosphorie
anhydride . 40 45 18 66 15 0
Sulfuric anhy-
dride .. 74 90 20 — — —

232. Significance of a strong hydrochloric acid analysis.
— This method of analysis was originally thought to
give some indication of both the permanent fertility and
the immediate manurial needs of a soil; but for each
question the accuracy of the deductions is limited by a
number of conditions that make it impossible invariably
to predict from an analysis how productive a soil may be
or what particular manure may be profitably applied.
It is very apparent that the chemical composition of a
soil is only one of the many factors affecting its produc-
tiveness. Unfortunately, not all the factors are under-
stood, and consequently these unknown ones cannot be
determined either qualitatively or quantitatively. If
it ever becomes possible to determine quantitatively all
the factors entering into soil productiveness in the field
condition, the problem will be solved.

233. Relation of texture to solubility. — The ratio of
sand to clay in a soil, and the distribution of the fer-
tilizing materials in these constituents, will affect the mini-

882 SOILS: PROPERTIES AND MANAGEMENT

mum quantity of any constituent required to produce
a good crop. Hilgard has shown that the addition of
four or five volumes of quartz sand to one volume of a
heavy, but highly productive, black clay soil greatly
increased the productiveness, while diluting the potash
content of the mixture to 0.12 per cent and the phosphoric
acid to 0.03 per cent. It is evident that in this soil the
plant-food materials were in a condition to be easily
taken up by the plant when the physical condition of the
soil was suitable.

If these small quantities of food elements had been
distributed in the sand particles as well as in the original
clay, the result would doubtless have been different.
Suppose, for example, that fifty per cent of the potash
and phosphoric acid had been in the sand particles and
the remainder in the clay; in that case the former, in a
soil exposing much the less surface to dissolving liquids,
would be proportionately less soluble, and as the minimum
quantity is approached, as shown by the more dilute soil’s
yielding less than the other, the effect would doubtless
have been to decrease the production. In some soils,
particularly those of arid regions, the larger particles
may carry much of the mineral nutrients, in which case
it is quite evident that a higher percentage of fertility
is required than in soils carrying the plant-food material
largely in the small particles.

234. Nature of the subsoil.— The nature and com-
position of the subsoil is naturally a factor in determining
soil productiveness, and must be considered as well as
the top soil. An impervious subsoil, or a very loose
sandy one, will confine the productive zone largely to
the topsoil and hence require a greater proportionate
amount of fertility in that part of the soil.

AVAILABILITY OF PLANT NUTRIENTS 333

935. Calcium carbonate.— A determination of the
amount of calcium present as a carbonate is important
as an aid to the interpretation of an analysis of the soil.
Lime not so combined is generally in the form of a sili-
cate, or possibly a phosphate. If there is a large quantity
of calcium carbonate in a soil, the potash, phosphoric
acid, and nitrogen are likely to be more readily soluble,
and smaller quantities are sufficient for crop growth, than
if the calcium is not found in this form. The effect of
the carbonate of lime on the nitrogen! compounds is to
furnish a base for the acids produced in the formation of
nitrates, and its presence promotes this process. It
probably replaces potassium in certain compounds where
otherwise it would be secured with more difficulty. It
insures the presence of some phosphates of lime, in which
form phosphorus is more soluble than when combined
with iron. The form of the manures to be used on the
soil will also depend in large measure on the presence
or the absence of calcium carbonate. For example,
where calcium carbonate is deficient, steamed bone or
Thomas slag are likely to be more profitable than super-
phosphate, and nitrate of soda than sulfate of ammonium.
Finally, the absence of calcium carbonate indicates the
need of liming, and if the analyses show a considerable
quantity of potash and phosphoric acid, but practice
shows these materials to be somewhat deficient, it is
probable that liming will be very beneficial, and that
manures carrying these substances will not be so essential
as the chemical analysis would indicate. It must be
stated, however, that there are cases for which these de-
ductions do not hold, owing to the intervention of other
factors.

1Not determined in the hydrochloric acid extract.

8384 SOILS: PROPERTIES AND MANAGEMENT

236. Deficiency of ingredients and manurial needs. —
Many standards have been set for the minimum quantity
of each of the important soil constituents that must be
present in order to insure a productive soil. Experi-
ence has shown, however, that no definite standards hold
for all soils. By comparing analyses of soils of known
productivity with that of a soil under investigation it is
an easy matter to ascertain whether the soil contains a
large quantity of each agriculturally important ingredi-
ent; but when the quantity of any constituent is low,
it becomes a difficult matter to tell how this will affect
the agricultural value of the soil. Some soils will be
productive with 0.05 per cent of phosphoric anhydride,
while others are unproductive when all the plant nutrients
are present in ample quantity.

The fact that the degree of productiveness of a soil
cannot always be gauged by its analysis gives rise to a
similar uncertainty with regard to its manurial needs.
A soil may contain potassium in very large quantities,
sufficient to produce crops for hundreds of years, as indi-
cated by a strong hydrochloric acid analysis, and yet a
potassium salt may be used with profit. On the other
hand, it is evident that as the content of any constituent
becomes less, the probable need for its application be-
comes greater, and a knowledge of the composition of
the soil thus suggests a practice without assuring its
success. An analysis of the hydrochloric acid extract,
therefore, cannot be taken as an infallible guide to the
fertilizer needs of a soil, and of itself should not be relied
upon; but in connection with other knowledge, particu-
larly that derived from fertilizer tests, it may be useful.

237. Partial solution with weak acids. — The difficulty
in judging of the properties of a soil from the results of

AVAILABILITY OF PLANT NUTRIENTS 335

a strong hydrochloric acid analysis has led to the use of
weak acids for obtaining the solution. These weak acids
dissolve much less of the soil constituents than do the
strong acids, and the portion so dissolved is supposed to
represent more nearly the amount that the plant can make
use of. Both dilute organic acids and dilute mineral
acids have been used. Among the former are citric,
acetic, oxalic, and tartaric acids. The assumption on
which the use of the organic acids is based is that they
correspond to the solvent agents in the soil combined with
the solvent action that the plant is supposed to possess,
and thus dissolve from the soil the quantities of nutrients
that the plant could take up if it came in contact with
all the soil particles to a depth represented by the sample
analyzed.

238. Advantages in the use of dilute acids. — The ac-
tion of each of these dilute acids on the same soil does
not give equal quantities of the various constituents in
solution. The dilute acids naturally dissolve a much
smaller amount of material from the soil than does strong
hydrochloric acid. The dilute acids permit the detection
of smaller quantities of easily soluble phosphoric acid and
potash than does the latter, larger quantities of soil being
used. For example, a chemical analysis of the strong
hydrochloric acid solution is very likely not to show any
increase in the phosphorus or potassium in a soil that may
have been abundantly manured with these fertilizers
and its productiveness greatly increased thereby. This
is because the amount of plant-food material added is so
small in comparison with the weight of the area of soil
nine inches deep over which it is spread that the increase
in percentage may well come within the limits of analytical
error. An acre of soil nine inches deep weighs about

836 SOILS: PROPERTIES AND MANAGEMENT

2,500,000 pounds. If to this there is added a dressing
of 2500 pounds of phosphoric acid fertilizer containing
400 pounds of phosphoric acid, it would increase the per-
centage of that constituent in the soil only 0.016 per cent
— a, difference that could not be detected by the analysis
of the hydrochloric acid solution.

239. The one-per-cent citric acid method. — This
method was proposed by Dyer? and was shown by him
to give results with Rothamsted soils that permitted of
an accurate estimation of their relative productivity.
Dyer adopted the one-per-cent strength as the result of
an investigation in which he determined the acidity of
the juices in the roots of over one hundred species or
varieties of plants representing twenty different natural
orders. The average acidity of the juices of the twenty
orders, calculated to crystallized citric acid, was 0.91
per cent, which led Dyer to adopt a strength of 1 per cent.
It must be said, however, that the different varieties
varied greatly in this respect, some having ten times as
much acidity as others. The implication is that plants pro-
duce a solvent action on a soil in proportion to the acidity
of their juices, but an examination of Dyer’s figures does
not show that the size of the crop ordinarily produced by
the plants tested would in many cases correspond to the
acidity of these juices. Thus, of the Cruciferse the horse-
radish has several times the acidity of the Swedish turnip
or of the field cabbage, although the crop produced by the
former is much less than that of the latter.

240. Usefulness of the citric acid method. — As shown
by Dyer, the use of a one-per-cent solution of citric

1 Dyer, Bernard. On the Analytical Determination of Prob-
ably Available ‘‘Mineral’’ Plant Food in Soils. Jour. Chem.
Soc., Vol. LXV, pp. 115-167. 1894.

AVAILABILITY OF PLANT NUTRIENTS 337

acid is well adapted to show the amount of easily
soluble phosphoric acid and potash in certain soils, but
for other soils it has failed to give satisfaction in
the hands of a number of analysts. It is doubtless
best suited to soils rich in calcium and low in iron and
aluminium.

The reason urged by Dyer for the superiority of the
citric acid method over the hydrochloric acid extraction
is that soils, shown by experience to need phosphoric
manures, yielded a relatively much greater quantity of
phosphorus to citric acid than to hydrochloric acid when
compared with soils not needing this element.

The application of both the hydrochloric and citric acid
methods to a soil, when used to supplement each other,
may add greatly to a knowledge of the potential and
present productiveness of the soil.

According to Dyer, for cereals and for most other
crops there should be present in a soil at least .01 per cent
of phosphoric acid, soluble in one-per-cent citric acid.
A soil containing less than this quantity is deficient in
phosphoric acid, unless this acid exists largely in the form
of ferric or aluminium phosphate, which is not readily
soluble in citric acid but is fairly available to the plant.
Sod land contains organic compounds of phosphorus that
are readily available to the plant; hence such soil, to
indicate sufficiency, should show by analysis more than
0.01 per cent of phosphoric acid. The quantity of potash
soluble in the same solvent should also be not less than
0.01 per cent in arable land.

1Dyer, Bernard. A Chemical Study of the Phosphorie
Acid and Potash Contents of the Wheat Soils of Broadbalk
Field, Rothamsted. Philosoph. Trans. Royal Soc. London,
Series B, Vol. 194, pp. 235-290, 1901.
%

388 SOILS: PROPERTIES AND MANAGEMENT

941. Dilute mineral acids.—Of the mineral acids
in a diluted form used for extracting soils, those that
have received the most attention are one-fifth normal
nitric! or hydrochloric acid and one two-hundredth
normal hydrochloric acid.2 The methods employing
these solvents are admittedly empirical. There is no
natural relation between these solvents and the processes
by which the plant obtains its nutriment from the soil.

The solvent that has received the most attention is
one-fifth normal nitric acid. In ease of manipulation
this is preferable to the one-per-cent citric acid, which is
rather tedious to work with. It has been used nearly
as extensively in this country as the latter has in Great
Britain. Its use has been confined largely to the deter-
mination of the readily available phosphorus and potas-
sium in the soil, as has the citric acid method. It is
obvious that some minerals are more readily soluble than
are others, and for that reason the method will distinguish
between phosphorus and potassium in different forms.
The calcium phosphates are supposed to be entirely soluble
in this solvent. According to Fraps? it dissolves iron
and aluminium phosphates to only a slight extent, thus
distinguishing between these forms of phosphorus. Fraps
finds also that no potassium is removed from orthoclase
and microcline, that less than ten per cent is dissolved

1 Official and Provisional Methods of Analysis. U.S. D. A.,
Bur. Chem., Bul. 107 (revised), p. 18. 1908.

2 Wiley, H. W. Principles and Practice of Agricultural
Analysis, pp. 394-396. Easton, Pennsylvama. 1906.

3Fraps, G. S. Active Phosphoric Acid and Its Relation
to the Needs of the Soil for Phosphoric Acid in Pot Experi-
ments. Texas Agr. Exp. Sta., Bul. 126, pp. 7-72. 1909.
Also, The Active Potash of the Soil and Its Relation to Pot
Experiments. Texas Agr. Exp. Sta., Bul. 145, pp. 5-39. 1912.

AVAILABILITY OF PLANT NUTRIENTS 339

from glauconite and biotite, and that from fifteen to sixty
per cent is dissolved from muscovite, nephelite, leucite,
apophyllite and phillipsite.

There are several factors, however, that make the use
of one-fifth normal nitric acid an uncertain guide to the
available phosphorus and potassium in the soil. When
a soil is treated with the acid some of it is neutralized by
the reactions that result and thus its strength is lessened.
This may have no relation to the quantities of phosphorus
or potassium dissolved. Some analysts correct for the
neutralization and some do not. Again, as with strong
hydrochloric acid, the degree of solubility of the soil con-
stituents in the nitric acid may not correspond with the
ability of the plant to obtain these substances. With
this, as with the other methods discussed, the objection
holds that the result cannot be taken as an infallible guide
to the productiveness of a soil, or to its fertilizer needs;
but each of the methods affords some information in
regard to a soil, and is thus of value.

242. Extraction with an aqueous solution of carbon
dioxide. — As carbon dioxide is a universal constituent
of the water of the soil, and without doubt a potent factor
in the decomposition of the mineral matter, it has been
proposed to use a solution of carbon dioxide as a solvent
in soil analysis. The amounts of soil constituents taken
up by this solvent are much less than are taken up by
any of the others heretofore mentioned, but all mineral
substances used by plants are soluble in it to some extent.
The amount of phosphorus is so small as to make its
detection by the gravimetric method difficult. Like
other methods employing very weak solvents, this method
is open to the objection that the extraction fails to remove
a considerable portion of the dissolved matter that is

340 SOILS: PROPERTIES AND MANAGEMENT

retained by adsorption, and as this varies with soils of
different texture a fair comparison of such soils is impos-
sible.

243. Extraction with pure water.— When soil is di-
gested with distilled water, all the mineral substances
used by plants are dissolved from it, but in very small
quantities. It has been proposed to use this extract for
soil analysis on the ground that it involves no artificial
solvent the presence or amount of which in the soil is
doubtiul, but shows those substances that are undoubtedly
in a condition to be used by plants. By determining the
water content of the soil and using a known quantity of
water for the extraction, the percentage of the various
constituents in the soil water or in the dry soil may be
calculated.

The substances dissolved from the soil by extraction
with distilled water are probably only those contained
in the soil-water solution, including a part of the solutes
held by adsorption. The aqueous extract does not con-
tain the entire quantity of the nutritive salts in solution
in the soil water, and hence is not a measure of the
fertility held in that form. An undetermined quantity
of nutrients is retained in the water, in the very small
spaces and on the surface of the soil particles. It is,
however, a fair comparative measure of the content of
available nutrients.

244. Influence of absorption. —- The quantity of ex-
tracted material depends on the absorptive properties of
the soil and on the amount of water used in the extrac-
tion, or on the number of extractions. Analyses of the
aqueous extract of a clay and of a sandy soil on the Cornell
University farm serve to illustrate the greater retentive
power of the former for nitrates. Sodium nitrate was

AVAILABILITY OF PLANT NUTRIENTS 341

applied to a clay soil and to a sandy loam soil at the rate
of 640 pounds to the acre. Analyses of aqueous extracts
some ninety days later showed the following : —

NITRATES IN Soin

Kinp oF Soin FERTILIZER (Parts per million)
Clay . . . . . . .| Sodium nitrate 7.8
Clay . ... . . .| No fertilizer 1.8
Sandy loam . . . . .{ Sodium nitrate 150.0
Sandy loam . . . . .| No fertilizer 29.7

There was apparently a much greater retention of
nitrate by the clay soil, as shown by a comparison of the
fertilized and the unfertilized plats on both soils.

Schulze? extracted a rich soil by slowly leaching 1000
grams with pure water, so that one liter passed through
in twenty-four hours. The extract for each twenty-four
hours was analyzed every day for a period of six days.
The total amounts dissolved during each period were as
follows : —

Toran Marrar

SuccussivE Exrracrions “Grams. ‘Gan. "Gee.
First . . ... 0.535 0.340 0.195
Second. .... . 0.120 0.057 0.063
Third . .. . . 0.261 0.101 0.160
Fourth... . .). 0.203 0.083 0.120
Fifth . 2... 0.260 0.082 0.178
Sixth . . .. 4. 0.200 0.077 0.123

1Schulze, F. Ueber den Phosphorsaure-Gehalt des Wasser-
Auszugs der Ackererde. Landw. Vers. Stat., Band 6, Seite
409-412. 1864.

842 SOILS: PROPERTIES AND MANAGEMENT

It will be noticed that the dissolved matter, both or-
ganic and inorganic, fell off markedly after the first ex-
traction, which was larger because of the matter in solu-
tion in the soil water. Later extractions were doubtless
supplied largely from the substances held by adsorption,
which gradually diffuse into the water extract as the
tendency to maintain equilibrium of the solution overcomes
the adsorptive action. With the removal of the adsorbed
substances, the equilibrium between the soil particles
and the surrounding solution is disturbed, solvent action
is increased, and more material gradually passes from the
soil into the solution. In this way the uniform and con-
tinuous body of extractives 1s maintained.

245. Other factors influencing extraction. — For pur-
poses of soil analysis, the quantity of water used for extrac-
tion must be placed at some arbitrary figure, and this
is open to the objection that it does not represent accu-
rately the soil-water solution. Analyses of soils of different
types are not comparable, and the water extract cannot
be considered as measuring the concentration, or even
the composition, of the solution existing between the
root hair and the soil particles. However, for studying
some of the changes which go on in the soil and which are
detectable in the soil-water solution, the practice may be
followed to advantage.

246. The soil solution in situ.—It has already been
pointed out that the interstitial spaces of any arable soil
contain more or less water all the time; that there is a
constant tendency for this water to assume the capillary
condition owing to the gravitational movement of free
water; and that the normal evaporation of moisture from
the soil tends to reduce the capillary film to the condition
of hygroscopic water (par. 132). As the movement

AVAILABILITY OF PLANT NUTRIENTS 343

of free water is comparatively rapid and that of capil-
lary water relatively slow, the soil moisture supply is
usually somewhere between the point of lento-capillarity
and free water. In this condition each particle or aggre-
gation of particles is enveloped in a thin moisture film,
and this film water is constantly in motion although the
movement is rather slow.

Soils are more or less soluble in pure water; and in soil
water, charged as it always is with carbon dioxide, they
are still more readily soluble. Consequently the moisture
films constantly tend to approach a state of equilibrium
with respect to the water-soluble matter in the soil parti-
eles. Jf plants are entirely dependent for their mineral
nutrients on the supply in the soil-water solution, the
strength of this solution becomes an important matter.
The supply of mineral nutrients for higher plants will be
discussed later (par. 839). Even if the plant itself
has no influence on the supply of mineral nutrients that go
into solution, the quantity of food that it finds in the
soil solution already prepared for its use must constitute
an important factor in its growth.

Unfortunately there is no adequate method of ascer-
taining the strength of the solution. Attempts have
been made to remove this solution from the soil, but it
is altogether unlikely that the analyses of the liquid
obtained represent the composition of the soil solution,
because of the very small quantity of the liquid available
for analysis and also because of the uncertainty that the
sample obtained was representative of the soil solution.

247. Devices for obtaining a soil solution. —— An at-
tempt by Briggs and McLane! to sample the soil solution

1 Briggs, Lyman J., and McLane, John W. The Moisture
Equivalent of Soils. U.S. D.A., Bur. Soils, Bul. 45, pp. 6~8. 1907.

344 SOILS: PROPERTIES AND MANAGEMENT

involved the use of centrifugal motion, which developed
a force of two or three thousand times that of gravita-
tion. When the soil contained a rather large quantity
of capillary water, a small amount of it could be removed
in this way.

Another device, by Briggs and McCall,’ consists of a
close-grained, unglazed, porcelain tube, closed at one end
and provided at the other with a tubulure, by which it
can be connected with an exhausted receiver. This
tube is moistened and buried in the soil. If the moisture
content of the soil is sufficient to reduce the pressure of
the capillary water surface in the soil to less than the dif-
ference between the pressure inside and outside of the
tube, there will-be a movement of water inward. This
water may be collected and analyzed.

More recently Van Suchtelen has used another method
to obtain the soil solution.? He replaces the soil water
by means of paraffin in a liquid state, at the same time
subjecting the soil to suction on a filter. The displaced
water is considered to represent the soil solution.

248. Composition and concentration of the soil solu-
tion. — It has gencrally been held that because some soils
are more productive than others, and because fertilizers
containing soluble salts frequently increase the yields of
crops, the soil solution in the better-yielding soils is more
concentrated, at least as regards plant nutrients, than is
that in the poorer soils. The argument is, of course,

1 Briggs, L. J., and McCall, A. G. An Artificial Root for
Inducing Capillary Movement of Soil Moisture. Science,
N.S., Vol. 20, pp. 566-569. 1904.

2Van Suchtelen, F. H. H. Methode zur Gewinnung der
Natirlichen Bodenlosung. Jour. f. Landw., Band 60, Seite
369-370. 1912.

AVAILABILITY OF PLANT NUTRIENTS 345

based on the assumption that, other things being equal,
plant growth is a function of the concentration of the
plant nutrients in the soil solution. According to this
conception, increased or decreased soil fertility is reflected
in the composition and concentration of the soil solution,
and this in turn in crop yields. The soil solution is there-
fore a variable quantity, and, to some extent at least, within
the control of man. An elaborate explanation for the
responsiveness of the soil solution has been worked out
by Van Bemmelen and his school.

249. Variability in composition and concentration of
the soil solution. — The process of rock weathering has,
according to Van Bemmelen,' Biltz,? and others, resulted
in deep-seated chemical changes in some of the mineral
constituents of the soil, whereby there are formed com-
plex colloidal silicates which, in the form of gels, cover
the surfaces of the soil particles. These colloidal com-
plexes may contain iron, aluminium, calcium, magnesium,
potassium, phosphorus, and other substances, which are
absorbed from the different clectrolvtes as ions or as
salts and depend in quantity on the concentration of the
solution from which they are absorbed. They therefore
act like solid solutions, whose composition changes
with every change in the concentration of the liquid solu-
tion that comes in contact with them. This relation of
the colloidal complexes to the soil water with which they
come in contact is essentially different from that of the

1Van Bemmelen, J. M. Beitrage zur Kenntniss der
Verwitterungsprodukte der Silikate in Ton, Vulkanischen, und
Laterit-Béden. Zeit. f. Anorganische Chemie, Band 42,
Seite 265-324. 1904.

2Biltz, W. Ueber die Gegenseitige Beeinflussung Col-
loidal Geléster Stoffe. Ber. deutsch. chem. Gesell., Band
37, Seite 1095-1116. 1904.

8416 SOILS: PROPERTIES AND MANAGEMENT

pure minerals, as they are not true chemical combina-
tions. The organic matter in the soil adds another class
of colloidal matter; so that, in the opinion of Van Bem-
melen,! the colloidal silicates and the colloidal humus form,
in various proportions, a mass of colloidal complexes that
control the composition of the soil solution. The col-
loidal condition of this material is readily decomposable
under variations in temperature and concentration of
solutions, and would doubtless be in a state of constant.
transition in the soil.

This conception of the soil surface would account for
changes in the concentration of the soil solution due to
the application of soluble fertilizers, and would also
explain the continued effect of such fertilizers on the
theory that they are absorbed by the colloidal complexes
and redissolved as the soil solution tends to become more
dilute.

A somewhat different view has been taken by Whitney
and Cameron, who hold that the composition and con-
centration of the solution in all soils is practically the
same. Their conception, according to a recent paper by
Cameron,” appears to differ from that of Van Bemmelen
in assuming that the soil water is in contact with the soil
partieles for such a short time that the quantity of matter
that goes into solution is too slight to bear any relation
to the total quantity of soluble matter in the soil. The
soil solution does not come into equilibrium with the
soil mass, nor even approximate such a condition. The

1Van Bemmelen, J. M. Die Zusammensetzung der Acker-
erde. Landw. Vers. Stat., Band 37, Seite 347-373. 1890.

2Cameron, F. K. Concentration of the Soil Solution.
Original Communications, Highth International Congress of
Applied Chem., Vol. 15, pp. 48-48. 1912.

AVAILABILITY OF PLANT NUTRIENTS 347

solution being similar in all soils, it follows that the rela-
tive productiveness of different soils bears no relation to
the supply of soluble nutrients, but must be due to other
factors. Hence soluble fertilizers increase plant growth,
not by supplying a greater quantity of plant nutrients,
but through other effects on the soil —as, for instance,
their favorable influence on tilth, or through the de-
struction of toxic matter.

250. Discussion of the theories regarding soil solu-
tions. — The difficulty in securing a true sample of the
soil solution as it exists in situ complicates any attempt
to ascertain how these theories comport with the actual
condition of the soil solution. A number of attempts
have been made to throw light on this subject, but none
of the data obtained is of a nature to definitely prove the
correctness of either theory. The evidence, so far as it
goes, indicates that the water extract of soils differs in
concentration in different soils, and is increased, under
some conditions, by large and continued applications
of soluble fertilizers. There can be no doubt, more-
over, that plant growth in properly balanced nutrient
solutions increases with the concentration of the solu-
tion up to several thousand parts to the million, as has
been demonstrated by many experiments.

One rather convincing experiment may be quoted.
Hall, Brenchley, and Underwood! analyzed the water
extract from certain plats on the Rothamsted Experi-
ment Station farm, the fertilizer treatment and the
yields of which had been recorded for a long term of years.

1 Hall, A. D., Brenchley, W. E., and Underwood, T. M.
The Soil Solution and the Mineral Constituents of the Soil.
Philosoph. Trans. Royal Soc. London, Series B, Vol. 204, pp.
179-200. 1913.

848 SOILS: PROPERTIES AND MANAGEMENT

Complete analyses of the soil from the several plats were
also made : —

Yisups or Crops, anp Composition oF Sor, AnD WatTrr
Extract or Sor, on RoruamstepD EXPERIMENT STATION
Farm

CompLetr ANALYSIS Water Exrractr

YIELD

"ACRE
’ K20 PeQ K20

(Pounds) (perecntage) (percentage) (p D rn Ydp > m )

Unmanured . . .| 1,276) 0.099 0 1838 0.525 3.40
N+ P30; . . .|8,972!) 0.173 0.248 3.900 3 88
N + K,0 . . .| 2,985; 0.102 0.257 0.808 | 30.33
Complete fertilizer | 5,087 | 0.182 0.326 | 4.025 | 24.03

Farm manure . .|6,184| 0.176 0.167 | 4.463 | 26.45

A similarly treated set of plats, which had been planted
to another crop and analyzed as were these, gave similar
results. It is a very striking example of the effect of
long-continued treatment of the soil with a certain fertilizer
on the composition of the water extract. The subject,
however, must be investigated further, as it is of funda~-
mental importance to a knowledge of the properties of
soils.

CHAPTER XVI

THE ABSORPTIVE PROPERTIES OF SOILS

Ir the brown water extract from manure is filtered
through a clay soil not containing soluble alkalies, the
filtrate will be nearly colorless. Many solutions of dye-
stuffs are affected in the same way. Solutions of alkali
or alkaline earth salts are more or less modified by this
operation, the bases being retained by the soil to a greater
extent than are the acids. Thus, when a solution of
the nitrate, sulfate, or chloride of any one of these bases
is filtered through the soil, a part of the base is absorbed
by the soil, while most of the acid comes through in the
filtrate. If these bases are in the form of phosphates
or silicates, not only the base is absorbed, but the acid
as well.

251. Substitution of bases.— Associated with the
absorption of the base from solution, there is liberation
of some other base from the soil, which combines with
the acid in the solution and appears in the filtrate as a
salt of that acid.

When absorption takes place from solution, the base
is never entirely removed, no matter how dilute the solu-
tion may be. A dilute solution of potassium chloride
filtered through a soil will produce a filtrate containing
some calcium, magnesium, or sodium chloride, or all
these salts, and some potassium chloride. The more

dilute the solution, the larger will be the proportion re-
349

350 SOILS: PROPERTIES AND MANAGEMENT

tained, but the less the total quantity absorbed. Peters !
treated 100 grams of soil with 250 cubic centimeters of a
solution of potassium salts, and found that the potassium
of different salts was retained in different proportions,
and that the stronger solutions lost relatively less than
the weaker, while more potassium was removed from the
stronger solutions.

vy NORMAL go NORMAL
STRENGTH OF SOLUTION i | ar
Grams K20 absorbed | Grams KO absorbed

KCl . . . 0.3124 0.1990

K.SO4 toe ee 0.3362 0.2098
KeCO, . 2. wee 0.5747 0.3134

The same bases are not always absorbed in the same
proportion by different soils; one soil may have a greater
absorptive power for potassium, while another may re-
tain relatively more ammonia. They seem to be inter-
changeable, as any absorbed base may be released by
another in solution. The absorptive power of a soil for
certain bases is reflected in the composition of the drainage
water from the soil. The composition of the drainage
water varies with different soils, and a soluble fertilizer
applied to one soil will have a different effect on the com-
position of the drainage water than if applied to a different
soil. This is well illustrated from lysimeter experiments
by Gerlach? at Bromberg. Several soils were used,

1 Peters, E. Ueber die Absorption von Kali durch Acker-
erde. Landw. Vers. Stat., Band 2, Seite 113-151. 1860

2 Gerlach, Dr. Uber die durch sickerwasser dem Boden
Entzogenen Menge Wasser und Nahrstoffe. Ill. Landw. Zei-
tung, 30 Jahrgange, Heft 95, Seite 871-881. 1910.

THE ABSORPTIVE PROPERTIES OF SOILS 851

one of each being fertilized and one unfertilized. The
lysimeters were 1.2 meters deep and contained 4 cubic
meters of soil. The drainage water was caught and
analyzed for four years. The first year there was no
crop, the second year potatoes were grown, the third
oats, and the fourth rye. The following results were
shown : —~

AVERAGE COMPOSITION OF DRAINAGE WaTER IN PARTS PER
MILLION

TREATMENT Tora Nirric | Oreanie ee)

NitroGcrn | Nrrrocen |Nirrocnun

Cad

nance | oni TTTRmntanmirit | eilimsitivnesssitninttaanetriinimninn | meimainimasmuiiemniirtie | mEmmeMimirssems!

os Fertilized | 32.7 30.0 2.7 | 32.2 | 405
Moor soil . ave 65.0 | 60.3 | 4.7 |26.2|507
Loamy sand Fertilized | 25.5 25.1 0.4 | 25.1) 92
low in humus || Untreated!) 20.9 20.4 0.5 8.5} 90
Sandy loam Fertilized | 67.8 64.6 3.1 | 70.2 | 399
highinhumus|| Untreated; 69.5 66.1 3.4 | 47.4|414

Absorption will not proceed to an unlimited extent.
A soil will cease to absorb any particular substance after
a certain quantity has been taken up. This quantity
will vary with every soil. Clay and loam soils have
greater absorptive power than sandy soils. This differ-
ence, both as to amount and as to rate of absorption, is
well shown by the following curves adapted from Schreiner
and Failyer.

1Schreiner, O., and Failyer, G. H. The Absorption of
Phosphates and Potassium by Soils. U. 8. D. A., Bur. Soils,
Bul. 32. 1906. See also Cameron, F. K., and Bell, J. M.
The Mineral Constituents of the Soil Solution. U. 8S. D. A.,
Bur. Soils, Bul. 30, pp. 42-66. 1905. Patten, H. E., and Wag-
gaman, W. H. Absorption by Soils. U. 8. D. A., Bur. Soils,
Bul. 52. 1908.

CO
to

5
[9 O00 2 Af77
| | be
ee
/

SOILS: PROPERTIES AND MANAGEMENT

Wie. 55.--Curves showing the absorption of PO, in parts to a million
by various soils from a solution of monocalcium phosphate, contain-
ing 200 parts to a million of PO, The volume of the percolate is
used as the abscissas.

Note. — The law which appears to govern absorption of phos-
phates and potash by the soil may be expressed mathematically
as follows:—

in which K is a constant, A the maximum quantity possible
for the soil to absorb, and y the quantity actually fixed when v,
volume of the solution, has percolated through.

A short discussion of the mathematics of this law may be
found in the following publication: Schreiner, O., and Failyer,
G.H. The Absorption of Phosphates and Potassium by Soils.
U.S. D. A., Bur. Soils, Bul. 32, pp. 23-24, 37-39. 1906.

THE ABSORPTIVE PROPERTIES OF SOILS 358

Fig. 56.—Curves showing the absorption of K in parts to a million by
various soils from a solution containing 200 parts to a million of K.
The volume of the percolate is used as the abscissas.

252. Time required for absorption. — The amount of
absorption depends on the time of contact between the
soil and the solution. While a large part of the dissolved
base is taken up in a short time after being placed in
contact with the soil, the maximum absorption is effected
only after a considerable period. Ammonia, according
to Way, reaches its maximum absorption in half an hour;
while Henneberg and Stohmann ! found that phosphorus
required twenty-four hours to reach the same degree of
absorption.

1 Henneberg, W., and Stohmann, F. Ueber das Verhalten der
Ackererde gegen Lisungen von Ammoniak und Ammoniaksalzen.
Jour. f. Landw., Neue Folge, Band 3 (Der ganze Reihe siebenter
Jahrgang), Seite 25-47. 1859.

854 SOILS. PROPERTIES AND MANAGEMENT

This, however, has no significance so far as danger
from loss of a soluble fertilizer constituent is concerned,
since water, even after a heavy rain, would not pass so
quickly through the soil that absorption would not take
place, except possibly in the case of soil of a very coarse
texture. The depth through which the substance js
distributed in the soil may, however, be influenced by
the time required for its absorption. Ordinarily ferti-
lizers do not penetrate very far into the soil. Demolon
and Bronet! have investigated the rate and distance of
penetration of certain soluble salts in soils, and find that
a total rainfall of ten inches is not sufficient to carry down
sodium nitrate in a sandy soil to a depth of eight inches.

253. Insolubility of certain absorbed substances. —
Although bases once absorbed may be easily displaced
by other bases, it is difficult to dissolve them from the
soil with pure water. Peters? treated 100 grams of soil
with 250 cubic centimeters of water containing potassium
chloride, of which 0.2114 gram of K.O was absorbed.
The soil was then leached with distilled water, using 125
cubic centimeters of water daily for ten days. At the
end of that time 0.0875 gram of KO had been removed,
or at the rate of 28,100 parts of water to one part of
K,O dissolved from the soil. Henneberg and Stoh-
mann? found that it required 10,000 parts of water

1Demolon, A., and Bronet, G. Sur la Pénétration des
Hngrais Solubles dans les Sols. Ann. Agron., Tome 28, pp.
401-418. 1911.

* Peters, E. Ueber die Absorption von Kali durch Acker-
erde. Landw. Vers. Stat., Band 2, Seite 1138-151. 1860.

* Henneberg, W., and Stohmann, F. Ueber das Verhalten
der Ackererde gegen Liésungen von Ammoniak und Ammoniak-
salzen. Jour. f. Landw., Neue Folge, Band 3 (Der ganze Reihe
siebenter Jahrgang), Seite 25-47. 1859.

THE ABSORPTIVE PROPERTIES OF SOILS 345

to dissolve one part of absorbed ammonia from the
soil.

254. Influence of size of particles. — The surface area
of the soil particles determines to some extent the amount
of substance absorbed. For this and other reasons, a
fine-grained soil absorbs a greater quantity of material
than a coarse-grained soil. In fact, it was early shown by
Way! that the phenomenon of absorption is largely a
function of the silt, clay, and humus of the soil.

255. Causes of absorption.— A number of causes
have been assigned for the absorption of substances by
soils, and there can be no doubt that the phenomenon is
not due to any one process. Several distinct causes are
now very generally recognized, while others that have
been suggested may have a part in the result.

256. Zeolites. — As the result of his extended researches
on absorption of soils, Way concluded that the property
of absorption, or fixation of bases, rests largely with the
hydrated silicates of aluminium, containing calcium or
magnesium and one of the alkali metals, these compounds
being known as zeolites. He prepared artificially a
hydrated silicate of aluminium and sodium, and found
that by treating this with a solution of a calcium salt
he could replace most of the sodium, obtaining thereby
a silicate of aluminium, calcium, and part of the sodium
that was originally contained in the silicate. The re-
mainder of the sodium could be replaced by potassium
from solution and, likewise, by magnesium and ammonium.

1Way, J. T. On the Power of Soils to Absorb Manure.
Jour. Royal Agr. Soc. England, Vol. 11, pp. 313-379. 1850.
Also, On the Power of Soils to Absorb Manure. Jour. Royal Agr.
Soe. England, Vol. 18, pp. 123-148. 1852. Also, On the
Influence of Lime on the ‘ Absorptive Properties ” of Soils. Jour.
Royal Agr. Soc. England, Vol. 15, pp. 491-515. 1854.

856 SOILS: PROPERTIES AND MANAGEMENT

Way found further that exposure to a strong heat de-
stroyed the absorptive properties of these substances, as
did also treatment with strong hydrochloric acid. In all
these respects the absorptive properties of the soil and
of the zeolites coincide.

257. Chabazite. — Eichhorn! experimented with the
natural zeolite chabazite, and found that he could produce
substitutions by means of the proper salt solutions. In
column I of the table below is given the composition of
chabazite used for the experiment; in column II is stated
its composition after treatment with a solution of sodium
chloride; and in column III the composition after the
zeolite is further treated with a solution of ammonium
chloride : —

Composirion OF CHABAZITE ORIGINALLY AND AFTER TRBAT-

MENT WwiTH SopIuM CHLORIDE AND AFTERWARDS WITH
AMMONIUM CHLORIDE

CouuMN I IT III
Sid, « 47.4. 48.3 51.3
AlsO3 20.7 21.0 22.2
CaO . 10.4 6.7 4,2
KO . 0.7 0.6 0.6
NasOQ se el 0.4 5.4 °
Ha... .... 20.2 18.3 14.9
(NH4)20 0.0 0.0 6.9

The substitutions were evidently made at the expense
of calcium in the compound, both when treated with
sodium and when treated with ammonium salts in chemi-
cally equivalent quantities. These and subsequent ex-

i1Hichhorn, H. Ueber die Einwirkung Verdiinuter Salz-
losungen auf Ackererde. Landw. Cenirlb. f. Deutschland,
6 Jahbrgang, Band 2, Seite 169-175. 1858.

THE ABSORPTIVE PROPERTIES OF SOILS 357

periments by numerous investigators have been rather
widely accepted as indicating that the zeolites are at
least partly responsible for the absorptive properties of
soils. It has been shown further that the absorptive
power of a soil is more or less proportional to the quantities
of acid-soluble silicates it contains. The zeolites being
rather easily soluble in strong mineral acids, it is held
that the bases so combined are more readily available
to plants than in most combinations found in the soil,
and yet are not easily leached out of it.

258. Presence of zeolites questioned. — On the other
hand, zeolites have never been definitely proved to be
present in soils. Merrill+ has attempted to show that
they cannot be of wide occurrence in soils, but neither
their absence nor their presence has been demonstrated.
Since the time when Way first published his researches
in 1850, the zeolite constituents of the soil have generally
been held to be largely responsible for its absorptive
power for bases.

259. Absorption of phosphoric acid. — It has already
been said that although hydrochloric, sulfuric, and nitric
acids are not absorbed by soils, except in small quantities,
phosphoric acid is absorbed and retained in an almost
insoluble condition so far as extraction with water is
concerned. That this absorption cannot be due to
zeolites is generally conceded, and has recently been
demonstrated, for permutite at least, by Rostworowski
and Wiegner,? who in a carefully conducted experiment

1Merrill, G. P. Rocks, Rock Weathering, and Soils, pp.
362-367. New York. 1906.

2 Rostworowski, S., and Wiegner, G. Die Absorption der
Phosphorsaure dureh ‘‘Zeolithe’’ Permutite. Jour. f. Landw.,
Band 60, Seite 223-235. 1912.

858 SOILS: PROPERTIES AND MANAGEMENT

with this zeolite — which is an amorphous gel containing
potassium, calcium, aluminium and silicic acid — found
that there was no absorption of phosphoric acid from a
neutralized solution of monocalcium phosphate or from
a solution of dicalcium phosphate at various degrees of
concentration.

260. Formation of insoluble phosphates. — The reten-
tion of soluble phosphoric acid in soils may be easily ac-
counted for by the fact that there are present in all soils
hydrated ferric oxide and hydrated silicates of alumina,
and frequently calcium carbonate, with which substances
phosphoric acid in solution would naturally form com-
pounds insoluble in water. Iron and aluminium phos-
phates are practically insoluble in water containing carbon
dioxide or weak organic acids such as might be present
in soil water. Calcium carbonate forms with a soluble
phosphate fertilizer some dicalcium phosphate, the
solubility of which in soil water is much greater than
the iron and aluminium phosphates. This is one of the
advantages of keeping a soil well supplied with lime if
a superphosphate fertilizer is to be used. Even the
tricalcic phosphate, although less soluble than the dicalcic,
is more readily soluble than the iron and aluminium
phosphates. As lime has a tendency to move downward
in soil, and as phosphoric acid is retained in the plowed
depth when added as a fertilizer, it is important that the
applications of lime be sufficiently frequent to keep this
part of the soil in a condition to form the lime phosphates.

Cameron! has suggested that the absorption of phos-
phoric acid is probably due to the formation with lime
or ferric oxide of a solid solution, which might account

1Cameron, F. K. The Soil Solution, p. 59. Easton, Penn-
sylvania. 1911.

THE ABSORPTIVE PROPERTIES OF SOILS 359

for the availability of phosphorus in soils to which a
superphosphate fertilizer had been applied many months
previously. It might explain also the availability of
a superphosphate on soils devoid of calcium carbonate.
Although such availability is always less than where
this carbonate exists, it is greater than would be ac-
counted for by the solubility of ordinary iron phosphate.

261. Adsorption. — There is a physical fixation, termed
adsorption, due to the concentration of the soil solution
in immediate contact with the surface of the particles.
The phenomenon is familiarly exemplified in the clarify-
ing effect of the charcoal filter. This process results in
the retention, in fine-grained soils, of considerable soluble
material that would otherwise be washed out. In the
case of nitrates, which are not retained by the zeolites,
adsorption is an important factor (par. 244). If a
solution of a known quantity of nitrate of soda is added
to a clay soil, and an attempt is then made to extract
the nitrate from the soil with distilled water, it will be
found impossible to recover a very appreciable propor-
tion of the amount added. While adsorption probably
does not account for all the nitrates retained, there can
be no doubt that it plays an important part. Nutritive
salts held in this way are readily available to the plant,
whose root hairs come in contact with the soil particles.
It is not impossible that other fertilizer constituents are
held by the soil in this manner.

262. Absorption by colloids. — According to Van Bem-
melen,! who has made a very exhaustive study of this

1Van Bemmelen, J. M. Die Absorptionsverbindungen und
das Absorptionsvermégen der Ackererde. Landw. Vers. Stat.,
Band 35, Seite 69-136. 1888. Also, Die Absorption, Seite
548. Dresden, 1910.

360 SOILS: PROPERTIES AND MANAGEMENT

subject, absorption by soils is, without doubt, largely
due to the presence of colloidal matter which exerts an
absorbent action for water, gases, solutes, and solids in
suspension. The colloidal matters in soils that contrib-
ute to their absorptive properties are the following : —

(1) remains of plant and animal tissues ;

(2) humous substances ;

(3) colloidal iron oxide;

(4) colloidal silicic acid ;

(5) amorphous colloidal silicates that have been formed
through weathering.

Van Bemmelen also credits crystalline silicates with
absorbent properties, although he does not consider that
their action is very important. Absorption is brought
about also by true chemical combination of soil com-
pounds with substances in solution, by which certain of
the cations or anions in solution are chemically combined
and remain inthe soil in a very difficultly soluble condition.

263. Absorptive properties of colloidal matter. —
Among the products of rock weathering there have been
found in soils amorphous substances that are of the nature
of colloidal gels. These, with the other colloidal matter,
are contained in the very small particles that remain for
a long time in suspension when soil is stirred up in water.
These colloids are coagulated by many acids, and by
some bases and salts. This is especially true of the
material that is dialyzable. Some of these again go into
solution on being treated with water, while others remain
insoluble until they undergo molecular change. Many
colloids form hydrogels with soil water. These hydrogels
are not ordinary chemical compounds. Gels dry very
slowly. They adsorb water in varying quantities, not

THE ABSORPTIVE PROPERTIES OF SoI~s 861

in certain definite proportion as do crystalloids in the
process of crystallization. The more water adsorbed by
colloids, the less firmly is it held in combination. There-
fore it is easier to evaporate the water when a large quan-
tity has been taken up, and as the amount decreases it
becomes more difficult to drive it off.

Another property of colloidal matter is that when it
is separated from solution it carries down with it other
substances in the solution from which it is precipitated.
If, on the other hand, the colloidal matter has been pre-
cipitated in a pure state, it absorbs substances from
solutions with which it remains in contact for some time.
The substances taken up in this way are not chemically
combined, but substances that unite chemically may be
absorbed.

The combinations produced by absorption are weak
and it is possible to leach out the combined substances,
which are generally held in the water of the gels. The
following example of one kind of absorption is given
by Van Bemmelen:! ten grams of a hydrogel having the
composition SiO, . 4.2 HO, shaken with 100 cubic cen-
timeter solution of 20 molecular equivalent KCl, will
absorb 0.8 to 1.1 molecular equivalent of the dissolved
substance. The absorption in this case was as if the
solution had been diluted with 4.2 to 5.8 cubic centimeters
of water. As the amount of gel water in 10 grams of
hydrogel of SiO, is about 5 cubic centimeters, the as-
sumption may be made that the dissolved substance is
taken up in equal concentration by the gel water. Ten
grams of hydrogel of SiO, shaken with 100 cubie centi-

1Van Bemmelen, J. M. Die Absorptionsverbindungen und
das Absorptionsvermégen der Ackererde. Landw. Vers. Stat.,
Band 35. Seite 75. 1888.

862 SOILS: PROPERTIES AND MANAGEMENT

meter solution of 50 molecular equivalent KCl — that
is, 24 times the concentration of the former solution —
absorbs 24 times as much, or 2.1 to 2.5 molecular equiva-
lent. This applies also to concentrations five times
stronger than the first mentioned above, but beyond that
the relation is not so simple. It serves, however, to
illustrate the manner in which the absorption takes place
from dilute solutions.

264. Selective absorption. — A selective absorption is
very common, especially from solutions of salts having
weak acids, a greater fixation of the bases taking place
than of the acids. Dissociation of the salts takes place
in the solution, the bases being absorbed, in consequence
of which further dissociation occurs; and this proceeds
until an equilibrium is established between the absorbing
and combining power of the colloidal material and the
reverse action of the water and resulting acids. In this
way the absorptive power decreases as the amount ab-
sorbed becomes greater.

The colloidal silicates possess the property of absorbing
a certain base when presented to it in solution, and con-
tributing in return a chemically equivalent quantity of
some other base. Potassium is most firmly combined
in the soil and most strongly withdrawn from solution,
with an exchange of a chemically equivalent quantity of
calcium, sodium, and magnesium, which passes into the
solution. Ifa soil is treated with a solution of potassium,
magnesium, sodium, or calcium salts of equal concentra-
tion, the concentration of the solution in the end is less
for the potassium than for the magnesium, and less for
the magnesium than for the sodium and the calcium,
because the potassium is most strongly bound in the
colloidal material, while the calcium and sodium are least

THE ABSORPTIVE PROPERTIES OF SOILS 368

so. In other words, the action of a calcium salt in solu-
tion on the absorbed potassium combination is less than
the action of a dissolved potassium salt on the absorbed
calcium combination. Thus it comes about that under
similar conditions of temperature, volume, and concen~
tration of the solution, the quantity of calcium or of
sodium or of magnesium that goes into solution when
colloidal silicates are treated with a solution of a potassium
salt is greater than the quantity of potassium that would
go into solution if the same silicates were treated with a
solution containing the salts of any of these other bases.

265. Absorptive power of colloidal silicates. — The
quantity of a substance that a certain weight of a colloidal
silicate can absorb increases with the strength of the
solution of the substance presented for absorption, be-
cause the final solution can remain stronger and conse-
quently its solvent power for that particular substance
is less. The point of equilibrium between the fixing
power of the colloid and the solvent action of the solvent
therefore varies with the strength of the solution.

The nature of the acid with which a base is combined
likewise has an influence on the quantity of the base
absorbed. A base combined with a weak acid is ab-
sorbed in greater amount than the same base combined
with a strong acid. This is presumably because the
stronger acid remaining in solution has a greater solvent
action.

266. Absorption by colloids versus absorption by
zeolites. — The early conception of the phenomenon of
fixation in soils was naturally a chemical one and was
founded on the chemical knowledge of that day. The
fact that the substitution of bases in the solutions passed
through the soil was in chemically equivalent quantities,

364 SOILS: PROPERTIES AND MANAGEMENT

placed it in line with what was known regarding chemical
reactions. Zeolites were found to possess absorbent
properties of a similar nature toward salts in solution, a
characteristic of which is the substitution of bases and
the appearance in solution of the released base in com-
bination with the acid of the original salt. It was a
natural conclusion that true mineral zeolites exist in
soil and that the absorptive properties of soil are due to
their action.

Many years later, when the principles of physical
chemistry had been applied to the study of colloids, it
was shown that absorptive properties are possessed by
certain colloids similar to those characteristic of soils.
Zeolites have never actually been isolated from any soil.
This fact has always occasioned some doubt as to the
hypothesis to which their properties have given rise.
Colloids, on the other hand, are well known to occur in soils,
but the exact nature of soil colloidal matter is not well
understood ; consequently there is considerable indefinite-
ness about the extent of their absorptive function, and
even Van Bemmelen grants the crystalloids a part in this
phenomenon.

The zeolite hypothesis furnished an explanation for
the form in which the available plant-food materials of
the soil are held. On it is largely based the idea that
the solution of a soil in strong hydrochloric acid repre-
sents the nutrients that are available to plants. The
silicates that go into solution are held to be the zeolitic
silicic acid and the bases with which it is united. ‘The
fact that such treatment largely destroys the absorptive
properties of a soil is taken as a proof of this. It would,
however, answer equally well as an argument in favor
of colloidal absorption, as the colloidal condition of the

THE ABSORPTIVE PROPERTIES OF SOILS 365

silicates would be destroyed by the same treatment.
On the whole, the evidence appears to be in favor of
the dominance of colloidal absorption rather than
erystalloidal absorption by soils, with its important
function in conserving soluble fertilizers and retaining
a supply of plant nutrients in a more or less readily
available condition.

267. Absorption by organic matter.— The partially
decomposed organic matter in soils, especially that part
which has undergone such transformations as to form
humus (par. 90), has an absorptive power. Soils rich
in humus, without doubt, owe much of their fertility
to the retention by that constituent of a large supply of
readily available plant-food material. Many prairie soils
that have been reduced in productiveness under culti-
vation respond to the application of organic matter in a
remarkable manner. Humus in these soils seems to be the
chief conserver of readily available plant-food materials.

Van Bemmelen,! who has studied these compounds,
states that soils hold colloidal humous compounds con-
taining ammonia, potassium, sodium, and other sub-
stances, as well as iron oxide. A part is soluble, or forms
soluble compounds with alkalies, but the principal part
is insoluble. Some of these latter compounds are of a
colloidal nature and of changing composition. The soluble
matter is easily precipitated by a salt solution and carries
down with it bases from the solution. Absorption of bases
also takes place from solution, with substitution of one
base for another. Potassium is more strongly held in
combination than is calcium or magnesium. Bases are
removed, however, only from salts of the weaker acids.

1Van Bemmelen, J. M. Die Absorption, Seite 135-141.
Dresden, 1910.

866 SOILS: PROPERTIES AND MANAGEMENT

268. Absorption of water vapor and of gases by soils. —
Hygroscopic water in soils has already been discussed (pars.
133, 184, 135). It need merely be remarked here that
there is a close relation between the absorptive power of a
soil for water vapor and for bases. Soils having a high
content of humus and composed of very fine material are
likely to have great absorptive properties for both vapors
and solutes.

In a similar way soils absorb gases. The deodorizing
property of soil is well known. Decomposing organic
matter is rendered inoffensive by covering it with soil.
Gases produced in the processes of decomposition are
largely absorbed by the soil. The fertility of the soil
may be increased by the absorption of certain gases.

269. Absorption of ammonia. — Ammonia, which exists
in minute quantities in the air, is absorbed by soils, and
also when given off by decomposing organic matter in the
soil. As all nitrogeneous organic matter may eventually
form ammonia when decomposed, the ability of the soil
to absorb it is very important. Quartz alone will absorb
only a very small quantity of ammonia, while a clay soil
will hold practically all that is likely to be produced by
the decomposition of the organic matter incorporated in it.

270. Absorption of carbon dioxide. — Carbon dioxide
is absorbed by soils to a very considerable extent, and
this also adds to the productiveness of soils, since it aids
in their decomposition. The supply of carbon dioxide
comes from decomposing organic matter and from plant
roots. As will be explained later, the soil air always
contains a considerable supply of this gas, and its con-
densation and absorption is constantly going on. It
forms soluble bicarbonates with the alkalies and bases
of soils, producing a readily available plant-food material.

THE ABSORPTIVE PROPERTIES OF SOILS 3867

271. Absorption of nitrogen and oxygen. — Nitrogen
is absorbed by soils to a greater degree than is oxygen.
The latter probably is of greater importance to soil fer-
tility, as its absorption is accompanied by oxidation of
other absorbed gases. Because of their absorptive prop-
erties and their great surface area, soils have strong
oxidizing power.

The absorption of gases by soils is largely an absorp-
tion phenomenon, the gases being condensed on the
surface of the particles. Von Dobeneck! has shown
that the absorption is greater, the finer the particles
of soil; but this increase is not directly proportional
to the increase in surface, large particles apparently
having a greater adsorptive power than their surface
area would indicate.

272. Relation of temperature to gas absorption. —
The temperature of the soil influences its absorptive
properties for vapors. As the temperature increases the
absorption becomes less. Hilgard? does not find this
to be the case (par. 136). He exposed soils to a moisture-
saturated atmosphere and found that they absorbed
more moisture at high than at low temperatures. In
his conclusions, however, he is doubtless in error. All
the work previous to his gave a directly contrary result,
and a more recent investigation by Patten and Gallagher °
confirmed the work of the earlier investigators.

1Von Dobeneck, A. F. Untersuchungen uber das Adsorp-
tionsvermégen und die Hygroskopizitat der Bodenkonstit-
uenten. Forsch. a. d. Agri.-Physik., Band 15. Seite 163-228.
1892.

2 Hileard, E. W. Soils, pp. 196-198. New York, 1906.

3 Patten, H. E., and Gallagher, F. E. Absorption of Gases
and Vapors by Soils. U.S. D. A., Bur. Soils, Bul. 51, pp. 31-
35. 1908.

868 SOILS: PROPERTIES AND MANAGEMENT

273. Relation of absorptive capacity to productiveness.
— The absorptive capacity of a soil is not so much a
measure of its immediate as of its permanent productive-
ness. It is well known that a very sandy soil responds
quickly to the application of soluble manures, but that
the effect is confined mainly to one season; while a clay
soil, although not so quickly responsive to fertilization,
shows the effect of the application much more markedly
the second or the third year than does the sandy soil.
Adsorption, which is largely shown in sandy soil, holds
the nutritive material in a very readily available con-
dition, while absorption by amorphous compounds
renders these substances somewhat less readily available.
There are also other reasons why the sandy soil is more
responsive. King,! in working with eight types of soil
from different parts of the United States, found that
those soils removing the most potassium from solution
gave the largest yield of crops. It would not be per-
missible, however, to adopt this test as a method for
determining productiveness in soil.

274, Absorption as related to drainage. — The drainage
water from cultivated fields in humid regions, and to a
less extent in semiarid and arid regions, except where
irrigation is practiced, carries off very considerable quan-
tities of plant-food material. The loss of this material
is due to the operation of the various natural disintegrating
agents on the soil mass, and to the application of fertilizing
materials in a soluble form. The various absorptive prop-
erties stand between the natural solubility of the soil and
the tendency to loss in drainage, and hold, in a condition

1 King, F. H. Influence of Farm Yard Manure upon Yield
and upon the Water-Soluble Salts of Soils, p. 25. Madison,
Wisconsin. 1904.

THE ABSORPTIVE PROPERTIES OF SOILS 3869

in which they may readily be used by the plant, these
materials which would otherwise be lost.

275. Substances usually carried in drainage water. —
However, some material is always lost in drainage water,
of which, among the bases of the soil, those most likely to
be found are calcium, sodium, magnesium, and potassium ;
and of the acids, carbonic, nitric, sulfuric, and hydrochloric.
Nitric acid and lime undergo the most serious losses.
The former may be curtailed to a great extent by keeping
crops growing on the soil during all the time that nitri-
fication is going on, and if the crop does not mature, or
if for any other reason it is not desired to harvest the
crop, it should be plowed under, to return the nitrogen in
the form of organic matter. A crop used for this purpose
is called a catch crop. Rye is used rather commonly as
a catch crop, as it continues growth until late in the fall
and resumes growth early in the spring, conserving ni-
trates whenever nitrification is likely to occur, and
it may then be plowed under to prepare the land for
another crop. Rye also has the advantage of small
cost for seed.

The loss of calcium cannot well be prevented, and
the use of commercial fertilizers always greatly increases
such loss. The only remedy is the application of some
form of calcium to the soil.

276. Drainage records at Rothamsted. — Drainage
water from a series of plats at the Rothamsted Experi-
ment Station, which have been manured in various
ways and planted to wheat each year since 1852, have
been analyzed at certain times, and the results of these
analyses, as compiled by Hall,! give some idea of the loss

1Hall, A. D. The Book of the Rothamsted experiments,
pp. 237-239. New York, 1905,

370 SOILS: PROPERTIES AND MANAGEMENT

of salts from cultivated soils. The drainage water was
obtained from the tile drains, a line of which extended
under each plat from one end to the other and opened
into a ditch, so that the water could be collected when
desired. The analyses are shown in the table on page
371.

Ammoniacal nitrogen in the drainage water is very small
in quantity, but nitrate nitrogen is present In quantities
sufficient to make the loss of some concern. The use of
sodium nitrate occasioned the greatest loss of nitrogen,
while ammonium salts and farm manure contributed
nearly as much. From forty to fifty pounds of nitrogen to
the acre may be lost annually in this way; this amount
would have a commercial value of eight or nine dollars.

277. Drainage records at Bromberg.—AIt is not
always the case that a manured soil loses more fertilizing
material than an unfertilized one. Gerlach?! reports
experiments in soil tanks at the Bromberg Institute of
Agriculture, as the result of which five soils, when ration-
ally fertilized, yielded larger crops and lost in the main
less nitrogen and lime in the drainage water than the
same soils unmanured. The loss of potash was slightly
greater from the manured than from the unmanured soils.
Apparently the stimulation that the plants received
from the fertilizer enabled them to make such a good
growth that they absorbed more soluble nitrogen and
lime in excess of the unfertilized plants than was added
in the fertilizer, and nearly as much potash.

1Gerlach, M. Ueber die durch Sickerwasser dem Boden
Entzogenen Menge Wasser und Nahrstoffe. Illus. Landw.
Zeitung, 30 Jahrgang, Heft 95, Seite 871-881. 1910. Also,
Untersuchungen tiber die Menge und Zusammensetzung der

Sickerwasser. Mitt. K. W. Inst. f. Landw. in Bromberg, Band
3, Seite 351-381. 1910.

THE ABSORPTIVE PROPERTIES OF SOILS 371

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872 SOILS: PROPERTIES AND MANAGEMENT

278. Losses of nitrogen and calcium.—'The most
serious losses of plant nutrients in the drainage water of
soils are those of nitrogen and calcium, and both are to
an extent unavoidable. Potassium and phosphorus,
which must also be purchased in manures, are lost only
at the rate of a few pounds to the acre. Nitrogen and
calcium may be conserved by maintaining a crop on the
soil continually. A large removal of nitrogen in the
drainage water is usually accompanied by a large re-
moval of calcium; for nitrogen is leached from the soil
mainly in the form of nitric acid, which of course com-
bines with a base, and calcium being the base finally
liberated it is carried off in drainage water. While most
of the calcium in drainage water is in the form of bicar-
bonate, the quantity is greatly increased by nitric acid.

The relation of nitric acid to caletum in drainage water
is shown by experiments with soil in large tanks from which
drainage water was collected. Plants were grown in the
soil of certain tanks, while others had none, other conditions
being similar. Analyses of the drainage water at Ithaca,
New York, as reported by Lyon and Bizzell! show a greatly
increased loss of calcium from the unplanted tanks, from
which the loss of nitrate nitrogen was also much greater : —
NITROGEN AND Catcium Ruemovuop In Drainace WATER BE-

TwEEN May 238, 1910, anp May 1, 1911. CancunatTEep To
Pounps To THE ACRE

Crop GROWN Nitrate NirRoGEN CaLclum
None ...... . 119.6 406.7
Maize... ... . 10.8 158 0
OatS . . . . . «ws. 125 173.4

1 Lyon, T. L., and Bizzell, J. A. Composition of the Drain-
age Water of a Soil with and without Vegetation. Jour. Indus.
and Eng. Chem., Vol. 3, pp. 742~743. 1911,

THE ABSORPTIVE PROPERTIES OF SOILS 873

Where crops were present to absorb the nitric acid,
calcium was greatly conserved. The quantities of ma-
terial carried off in drainage water was doubtless ab-
normally high in this case, as the soil had recently been
placed in the tanks.

279. Composition of surface water. — Another method
proposed for obtaining these data is to analvze and
measure the water draining from a known area of land.
Norton! has done this in the valley of Richland Creek,
Arkansas, and has calculated the loss of a number of the
soil constituents. A comparison of the figures obtained
by Norton with those obtained by Lyon and Bizzell in
the experiments just quoted will give some idea of the
quantities of mineral matter removed from soils by
drainage water. The Arkansas soil had presumably
received little manure. The soil in the Cornell Uni-
versity tanks had previously received fifteen tons of
stable manure. The Arkansas drainage doubtless in-
cluded some surface water that had never passed through
the soil and was therefore poor in mineral matter; the
large quantity of volatile matter indicates its surface
nature, as water that passes through a soil contains little
organic matter.

There is little similarity in the results of these analyses.
They serve, however, to bring out the differences between
the composition of the run-off and the drainage water of
soils, in so far as that may be judged from widely dif-
ferent soils and climatic conditions, including the
rainfall.

1Norton, J. H. Quantity and Composition of Drainage
Water and a Comparison of Temperature, Evaporation, and
Rainfall. Journal Am. Chem. Soc., Vol. 30, pp. 1186-1190.
1908.

374 SOILS: PROPERTIES AND MANAGEMENT

Supstances Removep IN Drarinaczs WatER FROM ONE ACRE
or LAND IN Ong YEAR

Lyon anp Bizz0uu

NoRrTon

Planted Soil Bare Soil
Total solids . . . . 794.0 800 2584
Organic matter . . . 134.0 0 0
Nitrogen . . . . . 4.0 11 119
Potash... .. . 5.0 6 11
Phosphoric acid . .. 0.1 Trace Trace
Lime ..... . 81.0 158 407

It will be seen that the total solids in the drainage
water from the Arkansas land and from the planted
tank were not greatly different in amount, but that
none of the constituents differed greatly. This was
notably the case with organic matter and with lime.
The former was doubtless carried largely in the run-off
and not in theleachings. Thelatter was probably more
abundant in the glaciated soil used in the tank than
in the residual soil of Arkansas.

CHAPTER XVII
ACID, OR SOUR, SOILS

SomE soils are known as acid, or sour, soils. The
property of acidity is of practical significance because
some plants do not grow so well on sour soils as they do
on soils that are neutral or alkaline; on the other hand,
some crops prefer an acid soil. Sour soils are rarely met
with in arid regions, but in humid sections of the United
States they are commonly found.

280. Nature of soil acidity. — Soils may be acid, or
sour, so far as their relation to plant growth is concerned,
(1) when free acids are present, (2) when no soluble free
acid exists, but when there is a deficiency of basic material
in the soil. Decomposition of organic matter in certain
soils under an inadequate supply of oxygen often results
in the formation of considerable quantities of organic
acids, as has already been explained (par. 93).

281. Positive acidity.— The formation of organic
acids under conditions of insufficient oxygen supply is
frequently seen in muck and other soils high in organic
matter that are saturated with water and that are also
deficient in lime. In such cases an acid condition is very
likely to be found, but when the land is drained the
acidity usually disappears because of the better aération
resulting. When a large quantity of green vegetation
is plowed under, as is done in green-manuring land, a

sour condition sometimes appears after the material has
3875

O16 SOlLs: PROPERTIES AND MANAGEMENT

had time partially to decay. The acidity of soil that
arises from the presence of free acids has been termed
positive acidity.

It is to be presumed that soils in which free acids exist
are rather deficient in basic material, and that the bases
are held so firmly combined that some of the relatively
weak organic acid present is not capable of forming salts
with them. Plummer! has shown that dihydroxvstearic
acid when added to an acid soil had a distinctly toxic
effect on wheat plants, but when added to the same soil
previously treated with lime there was no toxic effect,
indicating that this substance retained its acid properties
in the unlimed soil.

982. Negative acidity.—A soil deficient in basic
material but containing no soluble free acids may be
sour as regards its relation to plant growth. At least
such a soil may be greatly benefited by liming, although
it shows no acidity to most of the ordinary indicators of
acidity when these are used in the customary way. This
condition has been termed negative acidity and is really
not acidity according to a correct use of the word. Such
acidity does not have a direct effect on the plant, but
an indirect one arising from a lack of bases. Soils that
are acid in this sense always have a large capacity for
absorbing lime or other bases, before exhibiting an al-
kaline reaction. Calcium being, as has already been
seen (par. 264), the base most liberally released to solution,
there is a tendency toward the formation of calcium
carbonate in any soil dependent on the equilibrium be-

1Plummer, J. K. The Isolation of Dihydroxystearie Acid
from Volusia Silt Loam. Thesis presented in partial fulfillment
of the requirements for the degree of Master of Science. Cornell
University Library (not published). 1911.

ACID, OR SOUR, SOILS 377

tween the basic material and the absorptive substances
in the soil. Thus, a soil containing large quantities of
clay, and other absorbent substances requires more basic
material for the formation of calcium carbonate than
does a soil having less absorptive material. Further-
more, with the same original content of basic material,
the former soil requires a greater addition of lime to
overcome its sourness than does the latter. For this
reason a heavy soil usually requires a larger dressing of
lime to correct its acidity than does a light one.

Even if a soil does not have its absorptive capacity for
bases satisfied, there is some formation of calcium car-
bonate constantly taking place, as is evidenced by the
removal of the bicarbonate of calcium in the drainage
water of soils that are distinctly acid. The benefits that
soils derive from the presence of calcium carbonate will
be mentioned later (pars. 454-457). It need only be said
here that its presence in insufficient quantity constitutes
a form of so-called acidity, or sourness, in soils. The
formation of calcium carbonate in a given soil increases
with the mass of base. The effect of an application
of lime, therefore, is to increase the quantity of car-
bonate formed, even when the absorptive capacity of
the soil is not satisfied. This is why even relatively
small applications of lime are beneficial to soils having
great absorptive capacity.

283. Production of sour soils. — Soils in a humid
region tend to become acid. This may be due to any one
or more of several causes: (1) removal of calcium and
other bases in drainage water; (2) removal of bases by
plants; (8) formation of salts of the bases with organic
matter incorporated with soil; (4) accumulation of acid
residues of fertilizers.

878 SOILS: PROPERTIES AND MANAGEMENT

284. Removal of bases by drainage as a cause for
acidity. — The most potent cause of acid soils is doubt-
less the removal of bases in drainage water. The quan-
tities of basic material that may be lost from an acre of
soil are shown elsewhere (pars. 278, 279). These bases are
removed largely as bicarbonates, being obtained from
the hydrated aluminium silicates and other colloidal
matter. When the soil is uncropped a considerable loss
of lime occurs in the form of nitrate. As the decom-
position of the organic matter of the soil always results
in the formation of carbon dioxide and nitric acid, and
as decomposition is continually going on except when the
temperature of the soil becomes too low to admit of it,
the drain of bases from the soil is almost continuous.
Formation of carbon dioxide and of nitric acid occurs
largely in the surface soil; consequently the removal
of bases begins there. The result is that soils are
likely to contain less calcium in the surface layers than
at lower depths. Ames and Gaither! have shown from
a large number of analyses of Ohio soils that those con-
taining calcium carbonate in appreciable quantities have
more calcium in the subsoil than in the surface six
inches. In other soils this was not uniformly the case.
Leaching is, of course, greater in amount where con-
siderable quantities of calcium carbonate are present
than where it is lacking.

285. Removal of bases by plants. — Plants always
remove more bases than acids from soils in the process
of their growth. The table in paragraph 339 showing the
composition of the ash of some crops indicates that the
calcium, potassium, and magnesium removed from

1Ames, J. W., and Gaither, E. W. Soil Investigations.
Ohio Agr. Exp. Sta., Bul. 261. 1913.

ACID, OR SOUR, SOILS 319

the soil in this way is very considerable. When the
vegetation on the land is returned to it after life
ceases and its organic material is again incorporated
with the soil, there is no loss in this way, but in ordi-
nary agricultural practices most of the above-ground
portion of the crops is removed from the land. The
manure of growing animals returns to the soil only a
small proportion of the calcium that was originally in
the plants.

Breazeale and LeClerc! found that the selective action
of plants in absorbing more bases than acids from a
nutrient solution caused the solution to become toxic to
wheat seedlings because of its acidity.

286. Effect of green manures on acidity. — Although
the return of vegetation to the land on which it grew
does not result in any actual loss of basic material to
the soil, it generally results in the formation and libera-
tion of organic acids that unite with the basic material
and thus render it neutral. In soils deficient in lime
the incorporation of green-manure crops has been con-
sidered to temporarily produce an acid condition.
Coville? determined the acidity of some green-ma~
nure crops, on the basis of which he has estimated
the acidity, in terms of ground limestone required to
neutralize it, when the lime contained in the crop is de-
ducted from the total lime required. This is given in the
table on the next page.

1 Breazeale, J. F., and LeClere, J. A. The Growth of Wheat
Seedlings as Affected by Acid or Alkaline Conditions. U. S.
D. A., Bur. Chem., Bul. 149. 1912.

2 Coville, J. V. The Agricultural Utilization of Acid Lands
by Means of Acid-Tolerant Crops. U.S. D. A., Bul. No. 6,
p. 5. 1918.

880 SOILS: PROPERTIES AND MANAGEMENT

Wricut, Liman Contrrent, anp Acipiry or Groen Manurzs
Tro THo ACRE

ACIDITY, DX-

WULIGHT Lime PRESSED AS LIME
Crop (tons) Gon REQUIREMENT
Alfalfa . 25 139 267
Red clover 2 131 142
Cowpea 25 92 200
Rye . 2 Il 178
Broom sedgo . 1 4. 89

As decomposition proceeds the acids are oxidized, and
finally basic material is held largely in combination with
so-called humus of the soil. This is doubtless in the
form of a colloidal complex, not a definite chemical com-
pound. Analyses by Snyder! of purified humous ash
from eight productive prairie soils have been averaged
and are presented in tabular form in paragraph 97.

The quantity of basic material ordinarily held by the
organic matter of the soil is small compared with the
total soil content. The bases contained in humus are
principally potassium and sodium— not calcium, as
might be expected in the salt of an organic acid formed
in the soil. Humus in the soil tends to overcome acidity
and functions as an alkali. In respect to its composition
and properties, much of it resembles a colloidal com-
plex rather than a chemical combination of soil bases
with organic acids.

It has often been observed that land from which forest
has been cleared will yield good crops of red clover for

1Snyder, Harry. Soils. Minnesota Agr. Exp. Sta., Bul.
41. 1895.

ACID, OR SOUR, SOILS 381

several decades, after which it becomes more and more
difficult to obtain a crop until the attempt must finally
be abandoned. The change from forest to tillage has
opened the way for an acid condition of soil, through the
loss of bases carried off in the crops and the destruction
of humus by tillage. The dissipation of humus is doubt-
less the more serious source of loss. Instances may be
cited in which a farm has been so managed as to main-
tain the humus supply and the ability of the soil to pro-
duce red clover, although surrounding farms, on which
humus has been depleted, have completely failed to grow
this crop.

Apparently humus holds the basic constituents of the
soll in a form in which they function as rather easily
soluble salts, instead of locking them up as insoluble
silicates. A given quantity of base in a soil is therefore
more effective in preventing acidity by combining with
weak acids, and possibly in forming carbonates, if the soil
is well supplied with humus than if it is lacking in that
constituent.

287. Effect of fertilizers on soil acidity. — That the
continued use of ammonium sulfate on land may result
in producing a sour condition has been shown by a num-
ber of investigators. The absorption and nitrification
of the ammonia of that salt, and its final utilization by
plants, leaves sulfuric acid, which combines with calcium
and escapes in the drainage water. This may occur even
when this fertilizer is used in quantities not excessive,
but continued for many years, as has been shown by
Gardner and Brown?! at the Pennsylvania Experiment

1Gardner, F. D., and Brown, B. E. The Lime Require-
ment of the General Fertilizer Plats as Determined Periodically.
Rept. Pennsylvania Agr. Exp. Sta., 1910-1911, pp. 25-60.

882 SOILS: PROPERTIES AND MANAGEMENT

Station. Other fertilizers leaving an acid radicle in the
soil also act in this way. It is conceivable that potassium
chloride and potassium sulfate might have a tendency
to produce an acid condition, but the bases in these salts
do not disappear from the soil so quickly as would am-
monia, and consequently their action is slower.

The use of free sulfur on the land as a means of com-
bating certain fungous diseases may lead to the formation
of a sour soil through the oxidation of the sulfur with
formation of sulfuric acid. Lint? has found that a
soil in which sulfur was used at the rate of 600 pounds
to the acre for prevention of potato scab, changed in its
lime requirement from 2431 pounds to 4177 pounds as a
result of the one treatment.

288. Acidity in relation to climate and to formation of
soil. — In an arid or a semiarid climate soils are not likely
to become sour. The great source of lime removal,
leaching, operates to only a slight extent, or not at all,
in a dry climate. The removal of bases in crops is ap-
parently offset by the upward movement of bicarbonates
in the capillary water. Experience shows that acidity is
not a problem in soils of dry countries.

Soils that are derived from limestone or that have been
mixed with limestone soils in the process of their forma-
tion are, under similar climatic conditions, less likely
to become acid than are soils that originally contained
less lime. The fact that a soil is derived from limestone,
however, does not insure that it may not be benefited by
an application of lime.

289. Weeds that flourish on sour soils. — The acidity
or the basicity of soils influences very greatly the growth

‘Lint, H. Clay. The Influence of Sulfur on Soil Acidity.
Jour. Indus. and Eng. Chem., Vol. 6, pp. 747-748. 1914.

ACID, OR SOUR, SOILS 383

of vegetation and determines to a large degree its nature.
The flora undergoes a considerable variation as a soil
changes from a basic to a sour condition. This is because
some plants are injured to a greater extent than are others
by the conditions that accompany an acid reaction of the
soil. Some higher plants really grow better on a sour
soil than they do on an alkaline one, but these form only
a minority of the plants of agricultural importance.
Weeds that abound and appear to flourish on acid soils
may do so either because they grow better on sour soil
than on basic, or because other vegetation growing on
the soil does not thrive and therefore the dominant weeds
of the region have less competition than they otherwise
would have. There are certain weeds that may be taken
to indicate a sour soil when present in large numbers.
Some of these are found in one part of the country and
some in another : —

Wereps tuat Fuovuriso on Sour SoIus

Common name Botanical name
Sheep sorrel! . . . Rumer acetosella
Paintbrush . . . . Hvreracium aurantiacum
Daisy . . . . . Bellis perennis
Horsetail rush? . . Equisetum arvense
Corn spurry”? . . . Spergula arvensis
Wood horsetail? . . Hquisetum sylvaticum
Plantain . . . . Plantago major
Goose grass® . . . Polygonum anculare

1Knisely, A. L. Acid Soils. Oregon Agr. Exp. Sta., Bul.
90, p. 23. 1906.

2 Whitson, A. R., and Weir, W. W. Soil Acidity and Liming.
Wisconsin Agr. Exp. Sta., Bul. 230, pp. 7~-11. 1913.

?Voelcker, J. A. The Woburn Field Experiments. Jour.
Royal Agr. Soc. England, Vol. 69, pp. 337-357. 1908.

2884 sorILsS: PROPERTIES AND MANAGEMENT

290. Crops adapted to sour soils.—-There are some
useful agricultural plants that grow better on sour soils
than on alkaline soils, while other plants are apparently
indifferent to the condition of the soil in this respect. As
acid soils arc of very common occurrence, and as the
correction of this difficulty may not always be financially
profitable or otherwise desirable, it is important to know
what plants will thrive and how agricultural practice
may be maintained on such soils. A list of these plants,
based on different authorities, is herewith given : —

Crops ADAPTED TO SouR SOILS

Blueberry ? Hairy vetch !
Cranberry ” Crimson clover 4
Strawberry ! Potato ?
Blackberry ? Sweet potato !
Raspberry ” Rye?
Blackeap ? Millet ?
Watermelon ? Buckwheat 4
Turnip * Carrot ?

Red top ? Lupine ?
Rhode Island bent-grass ” Serradella ”
Cowpea 1 Radish ?
Soybean ! Velvet bean ”

Castor bean ?

The very considerable number of these plants, and
especially the inclusion among them of legumes that
may be grown for soil improvement, suggest the possi-

1 Coville, F. W. The Agricultural Utilization of Acid Lands
by Means of Acid-Tolerant Crops. U. 8. D. A., Bul. No. 6,
pp. 7-12. 1913.

* Wheeler, H. J. The Liming of Soils. U.S. D.A., Farmers’
Bul. 77. 1905.

ACID, OR SOUR, SOILS 885

bilitv of a successful agricultural practice on acid soils
where the important money crop to be grown, or some
other condition, would make it undesirable to correct
the soil acidity. There are certain crops, such as blue-
berries and cranberries, that require an acid soil; there
are others, such as potatoes, that may suffer less from
disease if the soil is sour. These crops are sometimes the
ones that are of greatest financial importance in a region,
and it therefore becomes desirable to maintain an acid
condition of soil.

291. Crops that are injured by acid soils. — There
are many plants that are injured by a sour condition of
the soil, and these include some of the most important
farm crops. It should therefore be borne in mind that
for most farm practice an acid soil is very undesirable.
One notable reason for this is that such crops as red
clover and alfalfa, which are of great value both as a
means of improving soil and for hay, can be grown only
with great uncertainty or not at all on acid soils.

Crops THAT ARE INJURED By Sour Soris!

Alfalfa, salsity Cauliflower
Red clover Squash Cabbage
Saltbush Spinach Cucumber
Timothy Red beet Lettuce
Kentucky blue-grass Sorghum Onion
Maize Barley Okra

Oats Sugar beet Peanut
Pepper Currant Tobacco
Parsnip Mangel-wurzel Kohlrabi
Pumpkin Celery Eggplant

1 Wheeler, H. J. The Liming of Soils. U.S. D. A., Farmers’
Bul. 77 (revised). 1905,

886 SOILS: PROPERTIES AND MANAGEMENT

While soils may be either sour or alkaline, there are
also degrees of sourness. Thus a soil may be so sour as
to completely prevent the growth of one kind of plant
and yet produce excellent crops of another plant which
would have perished if the soil had been more acid. For
example, red clover will grow fairly well on soil that is
too sour to raise alfalfa.

292. Qualitative tests for acidity.— A simple test to
indicate an acid condition of soil is not so easy of execu-
tion nor so infallible in its prediction as might be desired.
The object of such a test is to ascertain whether a soil is
not well adapted to the growth of certain plants and
whether the application of lime would benefit it in this
respect. A number of tests have been proposed which
will be outlined and briefly discussed.

293. Litmus paper test. — Blue litmus paper is brought
into contact with the wet soil. A rapid and decided
change to red is taken to indicate an acid condition of
the soil. Carbonic acid, which is always present in soils,
is supposed to give only a faint pink color to the litmus
paper. Various ways of bringing the paper into contact
with the soil have been recommended, among others the
interposing of filter paper between the soil and the litmus
paper! It is also generally pointed out that the acid
perspiration on the fingers may lead to delusion.

A criticism of the test has been made by Cameron,?
who states that the absorbent action of soils for bases is
greater than is that of paper, while for acids the reverse

1 Kellerman, K. F.,and Robinson, T. R. Legume Inoculation
and the Litmus Reaction of Soils. U.S. D.A., Bur. Plant Indus.,
Cire. 71, pp. 3-11. 1910.

*Cameron, F. K. The Soil Solution, pp. 65-66. Easton,
Pennsylvania. 1911.

ACID, OR SOUR, SOILS 387

is the case. Consequently the base that had produced
the blue color is absorbed from the litmus, leaving the
acid compound, which is red. Cameron concludes that
the test is unreliable, and proposes to extract the soil
with water, boil it in order to expel carbon dioxide, and
then test the reaction of the solution.

Much litmus paper that is sold is of very poor quality ;
but when good paper is used and the test is carefully
made, the general experience has been that it is a fairly
good, although not an infallible, guide to the need of a
soil for lime. Red coloration due to absorptive action is
probably an advantage rather than a source of error in
the test, as a soil strongly absorptive of bases is likely
to need lime. This coloration does not necessarily in-
dicate the presence of free acid, but merely need of lime.

294. Ammonia test.— In this test the soil is stirred
with a dilute solution of ammonia hydroxide. After
settling, if the supernatant liquid on standing takes on
a, dark chocolate or a black color it is said to be acid.
This method, which has been proposed by Miintz,? is
not of general application and would not always be re-
liable in the case of soils of arid regions. The depth of
color is not a guide to the degree of acidity, since many
acid soils are low in organic matter.

295. Zinc sulfide test.— A test recently proposed by
Truog” consists in mixing the soil to be tested with a
small quantity of calcium chloride and a very little zinc
sulfide. Water is added and the mixture is heated to

1 Wheeler, H. J., Hartwell, B. L., and Sargent, C. L. Chemi-
cal Methods for Ascertaining the Lime Requirements of Soils.
Rhode Island Agr. Exp. Sta., Bul. 62, pp. 65-88. 1899.

2Truog, EH. A. New Method for the Determination of Soil
Acidity. Science, N. 8., Vol. 40, pp. 246-248. 1914.

388 SOILS: PROPERTIES AND MANAGEMENT

boiling. A strip of moistened lead acetate paper is held
over the mouth of the flask for two minutes while the
boiling proceeds. If the soil is acid, the paper will be
darkened on the underside; if the soil is not acid, no
darkening will occur.

This method is evidently designed to test the need of
the soil for lime as well as actual acidity, for the absorp-
tion of calcium from the dissociated chloride would leave
free hydrochloric acid. The action of this acid on zine
sulfide would generate hydrogen sulfide, thus blackening
the lead acetate paper.

A somewhat similar principle is involved in the proposal
to use a solution of potassium nitrate in the litmus paper
test.

296. Litmus paper and potassium nitrate.— This is
performed in the same manner as the former litmus
paper test; except for the substitution of a saturated
solution of potassium nitrate instead of distilled water
for moistening the soil.

297. Acid test for carbonates.— In this test a dry
sample of the soil is treated with a few drops of dilute
hydrochloric acid. Effervescence indicates the presence
of carbonates or bicarbonates in sufficient quantities to
insure an alkaline soil, although sometimes lime may
still be beneficial.

Whitson and Weir! have objected to this method on
the ground that the displacement of air in the pore spaces
of the soul by the dilute acid may be mistaken for evolu-
tion of carbon dioxide. In the hands of an experienced
and careful operator this would not necessarily invalidate
the method.

_ ‘Whitson, A. R., and Weir, W. W. Soil Acidity and Lim-
ing. Wisconsin Agr. Exp. Sta., Bul. 230, pp. 7-11. 1918,

ACID, OR SOUR, SOILS 389

298. Plants as indicators of acidity. —In addition
to these chemical tests for acidity there may also be
mentioned what is perhaps the most reliable indication
of the need of lime, namely, the failure of a soil to produce
red clover, and the presence of those weeds that have
previously been shown to thrive on sour soil (par. 289).
When a soil bears this relation to the plant growth it may
safely be assumed that those plants included in the list of
crops that are injured by sour soils will yield better if the
soil is limed than if it is not so treated. The crops adapted
to sour soils may not be injured.

299. Quantitative determinations of acidity. — A num-
ber of quantitative methods for determining the degree
of acidity or the lime requirements of soils have been
devised. Only a few of these need be mentioned.

300. Potassium nitrate method.!— The soil is shaken
with a normal solution of potassium nitrate for three
hours, and then allowed to stand overnight. An aliquot
portion of the supernatant liquid is boiled in order to
expel carbon dioxide, and when cool it is titrated with
a standard solution of sodium hydroxide.

This method does not estimate either the free acid
or the lime requirement of the soil. What it does is
to give the absorptive power of the soil for potassium
when in equilibrium with a solution containing the
acid with which the potassium was originally in com-
bination. There is a substitution of bases during the
contact of the nitrate solution with the soil, and a
partial decomposition of these salts during the titration
with alkali.

1 Official and Provisional Methods of Analysis. Association
of Official Agricultural Chemists. U. 8S. D. A., Bur. Chem.,
Bul. 107 (revised), p. 20. 1908.

800 SOILS: PROPERTIES AND MANAGEMENT

301. Limewater method.— A measured quantity of
a, standard solution of limewater is brought into contact
with the soil and absorption is accomplished by evapora-
tion, after which water is added and the filtrate 1s tested
with phenolphthalein. Failure to produce a pink color
shows that the lime requirement of the soil has not been
reached; an alkaline reaction shows that an excess of
lime has been added. A number of tests must be made
in order to reach a point below which the indicator shows
no color and above which it does. The lime requirement
may thus be indicated. This determination was devised
by Veitch,! and is a useful method since it indicates to
within a few hundred pounds the quantity of lime re-
quired to satisfy the absorptive power of a soil.

302. Résumé. —In conclusion, a few facts regarding
so-called acid soils may be restated: (1) acidity is not
always due to free acids, but often to the lack of an abun-
dance of bases; (2) it is not injurious to all plants, but is
likely to depress the yields of the majority of agricultu-
rally important crops, while some valuable ones are bene-
fited by it; (3) it may be overcome sometimes by aéra-
tion of the soil, and always by the application of lime or
wood ashes. The correction of acidity by means of lime
will be discussed in a later chapter, as will also the rela-
tion of certain bacteria to acidity.

1 Veitch, F. P. The Estimation of Soil Acidity and the Lime
Requirements of Soils. Jour. Am. Chem. Soc., Vol. 24, pp.
1120~1128. 1902.

CHAPTER XVIII

ALKALI SOILS

It has already been shown that soils are acted upon by
a great variety of weathering agents which gradually
render soluble a portion of the most susceptible constitu-
ents. This soluble material becomes a part of the soil
solution and may come in contact with the roots of any
crop growing on the soil. In humid regions, »where a
large quantity of water percolates through the soil, this
soluble matter has little opportunity to collect. In arid
regions, however, where loss by drainage is slight, these
salts may often collect in large amounts. During periods
of drought they are carried upward by the capillary rise
of the soil water, while during periods of rainfall they may
move downward again in proportion to the leaching action.
At one time the lower soil may contain considerably more
soluble salt than the upper; at another time the condition
may be reversed, in which case the solution in contact
with plant roots may contain so much soluble matter
that vegetation is injured or destroyed. This excess of
soluble salts usually has a marked alkaline reaction, but
in any case it produces what is termed an alkali soil.

303. Composition of alkali salts. — The materials dis-
solved in the soil water consist of all the substances found
in the soil, but as the rates of solubility of these substances
vary greatly there is accumulated a much larger quantity
of some substances than of others. Carbonates, sulfates,

391

392 SOILS: PROPERTIES AND MANAGEMENT

and chlorides of sodium, potassium, calcium, and mag-
nesium occur in the largest amounts. Sodium may be
present as carbonate, sulfate, chloride, phosphate, and
nitrate. Potassium may be similarly combined. Mag-
nesium is likely to appear as a sulfate or a chloride, and
calcium as a sulfate, a chloride, or a carbonate. One
salt will predominate in some soils, and other salts in other
soils. A base may be present in combination with several
different acids. The nature of the prevailing salt greatly
influences the effect on vegetation. The table on page
393 gives the composition of the soluble salts from a
number of alkali soils.

A few years ago Headden? called attention to large
accumulations of nitrates in certain localities in Colorado.
These salts dissolve in the soil water and are frequently
present in such large quantities as to be injurious to
vegetation.

304. White and black alkali. — Sulfates and chlorides
of the alkalies, when concentrated on the surface of the
soil, produce a white incrustation, which is very common
in alkali regions during a dry period as a result of evapora-
tion of moisture. Incrustations of this character are
called white alkali.

Carbonates of the alkalies, particularly sodium car-
bonate, dissolve organic matter from the soil, thus giving
a dark color to the solution and to the incrustation. For
this reason alkali containing large quantities of these
salts is called black alkali. Black or brown alkali may
also be produced by calcium chloride or by an excess of
sodium nitrate.

1Headden, W. P. Deterioration in the Quality of Sugar
Beets due to Nitrates Formed in the Soil. Colorado Agr.
Exp. Sta., Bul. 183. 1912.

ALKALI SALTS 393

PERCENTAGE CoMPOSITION OF ALKALI SALTS IN SOILS

7 z 3 BILLINGS, Yuma,

~ < ee Montana 4 ARizona §

Q yee | 2%

Sx 8 3. S ot ant | £8 n A on

2 a, iP i ais 3 Eo 8 27 a

Be cs ai ide & Bae é as
KCl . . .| 164} —— | 5.61); —— 4.00 | 22.10
K280,.0.0.{ —— 3.95 |—— | 1.60, 21.41} —— | ——
K:CO; . .| —— 03 — |——
NaSO, . .| —— | 25.28 | —— | 85.57 | 35.12 | —— | ——
NaNO; . .| 33.07 | 19.78 | —— | —— | —— | —— | ——_
NaexCO; . .| —— | 32.58 | 13.86 7.28 | —— | ——
NaCl . . .| 6.61 | 14.75 | ——j} 0.55) —— | 81.15! 13.77
NasHPO,. .| —— 2.25 |-—— | —— | —— | —— | ——
Megs0, —— | 8.90; 4.06;-——| 6.88
MgCl. . .| 12.71 | —— | —|—|—— | 7.71; 3.98
CaCl, . . «| 17.29 | —— | —— | —— 0.25 | ——
NaHCO; . .| —— | —— |36.72} 0.67) 22.06; 0.28) 21.02
CaSO, . .| 21.48 | —— | 1.87) 2.71) 10.07) 6.61) 32.25
Ca(HCO;):; .{| —— | —— | 16.48 ——— | ——— | ———
Me(HCO;), .| —— | —— | 15.73; —— | —— | —— | ——
(NEH,)2CO3 . | —— 141 |-—— | —— | —— | —— | ——

1Headden, W. P. The Fixation of Nitrogen. Colorado
Agr. Exp. Sta., Bul. 155, p. 10. 1910.

* Hilgard, H. W. Soils, p. 442. New York, 1906.

3’ Dorsey, C. W. Alkali Soils of the United States. U. S.
D. A., Bur. Soils, Bul. 35, p. 79. 1906.

4 Tbid., p. 103. § [bid., p. 109.

894 SOILS: PROPERTIES AND MANAGEMENT

Black alkali is much more destructive to vegetation
than is white. A quantity of white alkali that would
not seriously interfere with the growth of most crops
might completely prevent the development of useful
plants if the alkali were black.

305. Effect of alkali on crops.— The presence of
relatively large amounts of salts dissolved in water and
brought into contact with a plant cell has been shown to
cause a shrinkage of the protoplasmic lining of the cell,
the shrinking increasing with the concentration of the
solution. This causes the plant to wilt, to cease growth,
and finally to die. The nature of the salt, and the species
and even the individuality of the plant, determine the
point of concentration at which the plant succumbs.

The directly injurious effect of the chlorides, sulfates,
nitrates, and other salts of the alkalies and alkali earths
is due to this action on the cell contents of the plants.
The carbonates of the alkalies have, in addition, a cor-
roding effect on the plant tissues, dissolving the parts
of the plant with which they come in contact. Indirectly
alkali salts may injure plants by their influence on the
soil tilth, soil organisms, and fungous and _ bacterial
diseases.

306. Effect on different plants.— The factors that
determine the tolerance of plants toward alkali are:
(1) the physiological constitution of the plant; (2) the
rooting habit. The first is not well understood, but
resistance varies with species, and even with individuals
of the same species. So far as the rooting habit influences
tolerance of alkali, the advantage is with the deep-rooted
plants such as alfalfa and sugar beets, probably because
a part of the root is in a less strongly impregnated part
of the soil.

ALKALI SALTS 395

Of the cereals, barley and oats are the most tolerant,
these being able in some cases to produce good crops on
soil containing twe-tenths per cent of white alkali. Of the
forage crops, a number of valuable grasses are able to
grow on soil containing considerably more than two-tenths
per cent of alkali. Timothy, smooth brome, and alfalfa
are the cultivated forage plants most tolerant of alkali,
although they do not equal the native grasses in this
respect. Cotton also tolerates a considerable amount of
alkali.

Loughridge,' after experiments and observation for a
number of years, has obtained data regarding the resist-
ance of various crops to the several alkali salts. His
results are given in part below, expressed in pounds to
an acre to a depth of four feet : —

Crop NaeSO NazeCOs NaCl Toray ALKALI
Grapes 40,800 7,050 9,640 45,760
Oranges . 18,600 3,840 3,360 21,840
Pears 17,800 1,760 1,360 20,920
Apples 14,240 640 1,240 16,120
Peaches . 9,600 680 1,000 11,280
Rye . 9,800 960 1,720 12,480
Barley 12,020 12,170 5,100 25,520
Sugar beets 52,640 4,000 5,440 59,840
Sorghum .. 61,840 9,840 9,680 81,360
Alfalfa . . .{ 102,480 2,360 5,760 110,320

Saltbush . .| 125,640 18,560 12,520 156,720

1Loughridge, R. H. Tolerance of Alkali by Various Cul-
tures. California Agr. Exp. Sta., Bul. 188. 1901. See also
Kearney, T. H., and Harter, L. L. Comparative Tolerance of
Various Plants for the Salts Commonin Alkali Soils. U.S. D.A.,
Bur. Plant Indus., Bul. 118. 1907.

896 SOILS: PROPERTIES AND MANAGEMENT

Although in general the results as to the resistance to
alkali of the various crops are so conflicting, the Bureau
of Soils,! in its alkali mapping, has been able to make a
rough classification as follows : —

PEROFNTAGE OF ToTaL PERCENTAGE or Crops
Buack ALKALI

0 to 0.20 Less than 0.05 | All crops grow

0.20 to 0.40 0.05 to 0.10 All but most sensitive

0.40 to 0.60 0.10 to 0.20 Old alfalfa, sugar beet,
barley, and sorghum

0.60 to 1.00 0.20 to 0.380 Only most resistant plants

1.00 to 3.00 0.380 and above | No plants

307. Other conditions that influence the action of
alkali.— The higher the water content of the soil, the
less is the injury to plants from alkali; but should
the same soil become dry, the previous large quantity of
water would, by bringing into solution a larger amount
of alkali, render the solution stronger than it would
otherwise have been, and thus cause greater injury (see
Fig. 57).

The distribution of the alkali at different depths may
have an important bearing on its effect on plants.
Young plants and shallow-rooted crops may be entirely
destroyed by the concentration of alkali at the surface,
while the same quantity evenly distributed through the
sou, or carried by moisture to a lower depth, would have
caused no injury. A loam soil, by reason of its greater
water-holding capacity and adsorptive power, will carry
more alkali without injury to plants than will a sandy

1 Dorsey, C. W. Alkali Soils of the United States. U. S.
D. A., Bur. Soils, Bul. 35, pp. 23-25. 1906.

ALKALI SALTS 397

soil. Certain of the alkali salts exert a deflocculating
action on clay soils and effect an indirect injury in that

way.

AMOUNTS OF INGRED EPS IN (00) OF SOIL.
Z a

rae

Fig. 57.—-Diagram showing the amount and composition of alkal salts
at various depths. Tulare, California.

308. Accumulation of alkali.— The alkali salts, being
readily soluble, are carried by the soil water where there
is any lateral movement, as is often the case where land
slopes to some one point. Low-lying lands adjacent to
such, slopes are thus likely to contain considerable alkali,
and the “alkali spots’? of semiarid regions and the
large accumulations of alkali in many of the valley lands
of arid regions are traceable to this cause.

309. Irrigation and alkali. — In irrigated regions, the
injurious effect of alkali is in many cases discovered only

898 SOILS: PROPERTIES AND MANAGEMENT

after irrigation has been practiced for a few years. This
is due to what is known as a “ rise of alkali,” and comes
about through the accumulation, near the surface of the
soil, of salts that were formerly distributed throughout
a depth of perhaps many feet. Before the land was
irrigated, the rainfall penetrated only a slight depth into
the soil, and when evaporation took place, salts were
drawn to the surface from only a small volume of soil.
When, however, irrigation water is turned on the land,
the soil becomes wet to a depth of perhaps fifteen or
twenty feet. During the portion of the year in which
the soil is allowed to dry, large quantities of salts are
carried toward the surface by the upward-moving capil-
lary water. Although these salts are in part carried
down again by the next irrigation, the upward movement
constantly exceeds the downward one. This is because
the descending water passes largely through the non-
capillary interstitial spaces, while the ascending water
passes entirely through the capillary spaces. The smaller
spaces, therefore, contain a considerable quantity of
solubie salts after the downward movement ceases and
the upward movement begins. In other words, the
volume of water carrying the salts downward in the
capillary spaces is less than that carrying them upward
through these spaces. Surface tension causes the salts
to accumulate largely in the capillary spaces, and it is
therefore the direction of the principal movement through
these spaces that determines the point of accumulation
of the alkali.

There are large areas of land in Egypt, in India, and
even in France and Italy, as well as in this country, that
have suffered in this way, and not infrequently they have
reverted to a desert state.

ALKALI SALTS 399

310. The handling of alkali lands.!— Ordinarily there
are two general ways in which alkali lands may be handled
in order to avoid the injurious effect of soluble salts.
The first of these is eradication, the second may be
designated as control. In the former case, an at-
tempt is made to actually eliminate by various means
some of the alkali. In the latter, methods of soil
management are employed which will keep the salts
well “distributed throughout the soil. In many cases
soils would grow excellent crops if the alkali could
only be kept well distributed through the soil layers
so that no toxic action could occur, at least within
the root zone. In general, steps should always be taken
toward the control of alkali, whether eradication is at-
tempted or not. Under irrigation, careful control is
always wise.

311. Eradication of alkali. — Of methods designed to
at least partially free the soil of alkali, the commonest
are: (1) leaching with underdrainage, (2) correction with
gypsum, (3) scraping, and (4) flushing.

312. Leaching with underdrainage.-—— Of the various
methods for removing an excess of soluble salts, the use
of tile drains is the most thorough and satisfactory.
When this method is used in an irrigated region, heavy
and repeated applications of water must be made, to
leach out the alkali from the soil and drain it off through
the tile. When used for the amelioration of alkali spots

1 Dorsey, C. W. Reclamation of Alkali Soils. U.S. D. A.,
Bur. Soils, Bul. 34. 1906. Also, Hilgard, HE. W. Utilization
and Reclamation of Alkali Lands, Soils. New York, 1911.
Also, Brown, C. F., and Hart, R. A. Reclamation of Seeped
and Alkali Lands. Utah Agr. Exp. Sta., Bul. 111. 1910.
Also, Dorsey, C. W. Reclamation of Alkali Soils at Billings,
Montana. U.S. D. A., Bur. Soils, Bul. 44. 1907.

400 SOILS: PROPERTIES AND MANAGEMENT

in a semiarid region, the natural rainfall will in time
effect the removal.

In laying tiles it is necessary to have them at such a
depth that soluble salt in the soil beneath them will not
readily rise to the surface. This will depend on those
properties of the soil governing the capillary move-
ment of water. Three or four feet in depth is usually
sufficient, but the capillary movement should first be
estimated.

After the drains have been placed, the land is flooded
with water to a depth of several inches. The water is
allowed to soak into the soil and to pass off through the
drains, leaching out part of the alkali in the process.
Before the soil has time to become very dry the flooding
is repeated, and the operation is kept up until the land
is brought into a satisfactory condition.

Crops that will stand flooding may be grown during
this treatment, and they will serve to keep the soil
from puddling, as it is likely to do if allowed to become
dry on the surface. If crops are not grown, the soil
should be harrowed between floodings. The operation
should not be carried to a point where the soluble
salts are reduced below the needs of the crop, or so
low that they lose entirely their effect on the retention
of moisture.

313. Correction with gypsum.— The use of gypsum
on black alkali land has sometimes been practiced for
the purpose of converting the alkali carbonates into
sulfates, thus ameliorating the injurious properties of
the alkali without decreasing the amount. The quantity
of gypsum required may be calculated from the amount
and composition of the alkali. The soil must be kept
moist, in order to bring about the reaction, and the

ALKALI SALTS 401

gypsum should be harrowed into the surface, not plowed
under. The reaction is as follows : —

NaeCOsz -+- CaSO, = CaCO; -+- NaasO,

When soil containing black alkali is to be tile-drained,
it is recommended that the land shall first be treated
with gypsum, as the substitution of alkali sulfates for
carbonates causes the soil to assume a much less compact
condition and thus facilitates drainage. It also prevents
the loss of organic matter dissolved by the carbonate of
soda and the soluble phosphates, both of which are pre-
cipitated by the change.

314. Scraping. — Removal of the alkali incrustation
that has accumulated at the surface is sometimes re-
sorted to. Very often the rise of alkali is encouraged
by applications of irrigation water, which is allowed
to evaporate unretarded. The salts are thus carried
upward by the capillary movement of the soil water.
This method of alkali eradication is never very effi-
cient, and is often dangerous, as it encourages the
presence of very large amounts of alkali salts in the sur-
face soil.

315. Flushing. — Often alkali accumulations may be
washed from the soil surface by turning on a rapidly
moving stream of water. The texture of the soil, as well
as the slope of the land, must be just right for such a
procedure. Generally so much water enters the soil
that the land remains heavily impregnated with alkali
salts. Both this method and the previous one, even
if successful, are only temporary. Moreover, lands
carrying so much alkali as to admit of either one of these
procedures may be so heavily charged as never to yield
to any form of either eradication or control.

402 SOILS: PROPERTIES AND MANAGEMENT

316. Control of alkali. —Where excessive amounts of
soluble salts do not exist in a soil, the control of the alkali
with a view of keeping it well distributed in the soil
column is the best practice. The retardation of evapora-
tion is, of course, the main object in this procedure. The
intensive use of the soil mulch is therefore to be advocated,
especially in all irrigation operations where alkali concen-
trations are likely to occur. Such a method of soil
management not only saves moisture, but also prevents
the excessive translocation of soluble salts into the root
zone. This method of control is the most economical,
the cheapest, and the one to be advocated on all occasions,
no matter what may have been the previous means of
dealing with the alkali situation.

317. Cropping with tolerant plants. — Certain soils
that are strongly impregnated with alkali may be grad-
ually improved by cropping with sugar beets and other
crops that are tolerant of alkali and that remove large
quantities of salts. This is more likely to be efficacious
where irrigation is not practiced. Certain crops, more-
over, while somewhat seriously injured while young, are
very resistant once their root systems are developed.
A good example is alfalfa, the young plants being very
tender while the more mature ones are extremely resistant.
Temporary eradication of alkali may allow such a crop to
be established. It will then maintain itself in spite of the
concentrations that may later occur.

318. Alkali spots. — In semiarid regions small areas of
alkali are often found, varying from a few square yards
to several acres in size. The quantities of alkali in these
are usually not sufficient to prevent the growth of plants
in years of good rainfall, but in periods of drought the
concentration of the salts and the compact condition that

ALKALI SALTS 408

they tend to produce combine to injure the crop. The
methods already mentioned for treating alkali land are
of service on these small areas, and, in addition, the
plowing-under of fresh farm manure has been found to
improve their productiveness. This, with surface drain-
age, deep tillage, and good cultivation in order to prevent
the soil from drying out, will usually remedy the difficulty.
In many cases these spots become highly productive under
proper treatment.

CHAPTER XIX

ABSORPTION OF NUTRITIVE SALTS BY
AGRICULTURAL PLANTS

Auu the salts taken up by the roots of agricultural
plants are in solution when absorbed. The movement
into the root thus depends on the presence of moisture,
which is the medium of transfer. The root-hairs are the
great absorbing organs of the plant, and through the
cells of their delicate tissues the solutions of the various
salts are passed.

319. How plants absorb nutrients. — The nature and
quantity of material absorbed by a plant is determined
by the law of osmosis. From the cells of the root-hairs
the dissolved salts are transferred to other parts of the
plant, where they undergo the metabolic processes that
determine which constituents shall be retained in the
tissues of the plant. The unused ions that remain in
the plant juices prevent by their presence the further
absorption of those particular substances from the soil
water. It thus happens that the composition of the
ash of a plant may be very different from that of the
substances presented to it in solution. For example,
aluminium, although always present in the soil in a very
slightly soluble form, is present in mere traces in the ash
of most plants. On the other hand, iodine, although
present in sea water only in the most minute quantities,
is present in large quantities in the ash of certain marine
algee.

404

ABSORPTION OF NUTRITIVE SALTS 405

A plant will, in general, take up more of a nutritive
substance if it is presented in large amount, as compared
with the other soluble substances in the nutrient solution,
than if it is presented in small amount. Thus, the per-
centage of nitrogen in maize, oats, and wheat may be
increased by increasing the ratio of nitrogen to other
nutritive substances in the nutrient media. This is
also true of potassium and phosphorus, respectively.
This fact is accounted for by the maintenance of the
osmotic equilibrium at a higher level for a particular
ion which is relatively abundant in the nutrient solution,
thus preventing the return of the excess from the plant.

320. Relation between root-hairs and soil particles. —
In a rich, moist soil the number of root-hairs is very
great, while in a poor or a very dry soil or in a saturated
soil there are comparatively few root-hairs. The con-
nection between the root-hairs and the soil particles is
extremely intimate. When in contact with a particle
of soil, a root-hair in many cases almost incloses it, and
by means of its mucilaginous wall forms a contact so close
as practically to make the solution between the particle
and the cell wall distinct from that between the soil
particles themselves.

There has been considerable difference of opinion as to
how a plant can obtain its mineral nutrients from a sub-
stance so difficultly soluble as the soil. This has arisen
because of the conflicting nature and the inadequate
character of the data available.

321. Liebig and Sachs on-solvent action of plant
roots. — Liebig‘' called attention to the fact that a plant
may obtain one hundred times as much phosphorus and

1 Liebig, J. Die Chemie in Ihrer Anwendung auf Agrikultur.
862.

406 SOILS: PROPERTIES AND MANAGEMENT

nitrogen and fifty times as much potassium as can be
extracted from the same volume of soil with pure water
or with water containing carbon dioxide. It has, of
course, been recognized that the soil water is aided in its
solvent action by a variety of substances that may be
normally present in solution, beginning with the gases
taken up by rain in its descent through the atmosphere,
and further added to by the carbon dioxide and the or-
ganic and mineral substances obtained from the soil. It
has been held that the plant roots aid solution of mineral
matter by excretion of acids, which act effectively as
solvents. The well-known root tracings on limestone
and marble have been taken as proof of the excretion of
such acids. Sachs,! and later other investigators, grew
plants of various kinds in soil and other media in which
was placed a slab of polished marble or dolomite or cal-
cium phosphate, covered with a layer of washed sand.
After the plants had made sufficient growth the slabs were
removed, and on the surfaces were found corroded trac-
ings, corresponding to the lines of contact between the
rootlets and the minerals.

322. Czapek’s experiments. In order to test this
theory, Czapek? repeated the experiments of Sachs,
using plates of gypsum mixed with the ground mineral
that he wished to test, and this mixture he spread over a
glass plate. Using these plates in the same manner as
previously described, Czapek found that, while plates of
calcium carbonate and of calcium phosphate were cor-
roded by the plant roots, :plates of aluminium phosphate

1Sachs, J. Auflésung des Marmors durch Mais-Wurzeln
Bot. Zeitung, 18 Jahrgang, Seite 117-119. 1860.

2 Czapek, J. Zur Lehre von den Wurzelausscheidung. Jahrb.
f. Wiss. Bot., Band 29, Seite 321-390. 1896.

ABSORPTION OF NUTRITIVE SALTS 407

were not. He concludes that if the tracings are due to
acids excreted by the plant roots, the acids so excreted
must be those that have no solvent action on aluminium
phosphate. This would limit the excreted acids to car-
bonic, acetic, propionic, and butyric. Czapek also re-
plies to the argument that the acids producing the tracings
must be non-volatile ones because of the definite lines
made in the mineral, by stating that the excretion of
carbon dioxide alone would be sufficient to account for
the observations since it dissolves in water to form car-
bonic acid, and that carbonic acid is always present in
the cell walls of the root epidermis. By means of micro-
chemical analyses of the exudations of root-hairs grown
in a water-saturated atmosphere, Czapek found potassium,
magnesium, calcium, phosphorus, and chlorine in the
exudate. He concludes that the solvent action of plant
roots is due to acid salts of mineral acids, particularly
acid potassium phosphate. He has not proved, however,
that the exudations were not from dead root-hairs nor
from the dead cells of the rootcap. In either case they
would have some solvent action, but whether sufficient
to make them of importance is doubtful.

323. Secretion of an oxidizing enzyme by plant roots. —
Molisch * found that root-hairs secrete a substance having
properties corresponding to those of an oxidizing enzyme.
His work has been repeated by others who have failed to
obtain similar results, but lately Schreiner and Reed ? have

1Molisch, H. Ueber Wurzelausscheidungen und deren
Hinwirkung auf Organische Substanzen. Sitzungsber. Akad.
Wiss. Wien-Math. Nat., Band 96, Seite 84-109. 1888. Ab-
stract in Chem. Centrlb., Band 18, Seite 1518, 1888, and in
Centrlb. f. Agr. Chem., Band 17, Seite 428, 1888.

* Schreiner, Oswald, and Reed, H. S. Studies on the Oxidiz-
ing Powers of Roots. Bot. Gazette, Vol. 47, p. 355. 1909.

408 SOILS: PROPERTIES AND MANAGEMENT

demonstrated an oxidizing action of roots that is appar-
ently due to a peroxidase. Oxidation alone, however,
would hardly suffice to account for the solvent action
accompanying the development of plant roots, although
it is doubtless an important function and useful in other
ways.

324. Importance of carbon dioxide as a solvent. —
Stoklasa and Ernst? have contributed much to this sub-
ject during the last decade. Stoklasa’s earlier experiments,
conducted by maintaining the plant roots in a saturated
atmosphere, gave only carbon dioxide in the exudate.
In this he is in agreement with most of the recent inves-
tigators of this subject. Stoklasa emphasizes the im-
portance of carbon dioxide as a solvent by showing the
quantity produced by plants and by microdrganisms.
He estimates that in one acre of soil to a depth of sixteen
inches there are sixty-eight pounds of carbon dioxide
produced by bacterial respiration in two hundred days,
and fifty-four pounds of carbon dioxide excreted by plant
roots in one hundred days; these periods he considers
as representing the year’s activity of bacteria and higher
plants.

In later experiments, Stoklasa and Ernst? found that
when plants do not have a sufficient supply of oxygen in
the air surrounding their roots, they secrete acetic and
formic acids from the root-hairs. These investigators
believe that these acids are toxic rather than beneficial,

1 Stoklasa, J., and Ernst, A. Ueber den Ursprung die Menge
und die Bedeutung des Koblendioxyds im Boden. Centrlb. f.
Bakt., II, Band 14, Seite 723~736. 1905.

2 Stoklasa, J.. and Ernst, A. Beitrage zur Lésung der Frage
der Chemischen Natur des Wurzelsekretes. Jahrb. f. Wiss.
Bot., Band 46, Seite 55-102. 1908-1909.

ABSORPTION OF NUTRITIVE SALTS 409

and that they are responsible, in large measure, for the
injurious effect on plants of a very compact condition of
soil. In the same communication these authors report
an experiment in which it was found that the kinds of
plants that excrete the largest quantity of carbon dioxide
from their roots are the ones that absorb the greatest
quantities of phosphorus from gneiss and from basalt.
This, however, does not necessarily connote any conse-
quential relation between these physiological functions.

Barakov ! drew air through planted soils contained in
large tanks. He found that the maximum production
of carbon dioxide occurred at the time when the plants
were blossoming, whether the plants blossomed early
or late in the season. This he considered to indicate
that the plant assists most vigorously in the solution of
nutrient materials at the time when it is most active in
absorbing them.

325. Insufficiency of carbon dioxide. — Pfeiffer and
Blanck? passed carbon dioxide through soil contained in
vessels in which plants were growing. The soil in some ves-
sels contained a difficultly soluble tricalcic phosphate, that
in other vessels the more easily soluble dicalcic phosphate,
and that in still other vessels was unfertilized. Another
set of vessels having the same fertilizer treatment received
no carbon dioxide. The soil receiving carbon dioxide
produced larger yields of dry matter and phosphorus in

1 Barakov, F. The Carbon Dioxide Content of Soils at
Different Periods of Plant Growth. Jour. Exp. Agr. (Russian),
Vol. 11, pp. 321-342. 1910. The authors are indebted to
Dr. J. Davidson for a translation of this paper.

2 Pfeiffer, Th., and Blanck, E. Die S&ureausscheidung
der Wurzeln und die Léslichkeit der Bodennihrstoffe in Koh-
lensaurehaltigem Wasser. Landw. Vers. Stat., Band 77, Seite
217~268. 1912.

410 SOILS: PROPERTIES AND MANAGEMENT’

the crop on the soil to which dicalcic phosphate had been
applied than did the soil not receiving carbon dioxide;
but the soil to which no phosphate was added yielded
equally well whether it received carbon dioxide or not.
The plants used were oats, peas, and lupines. These
investigators conclude that carbon dioxide is not a sufhi-
cient solvent to account for the mineral nutrients obtained
from soils by plants.

326. The present status of the question. — The avail-
able evidence on excretion of acids other than carbonic
by the roots of plants does not admit of any very satis-
factory conclusion as to their relative importance in the
acquisition of plant-food materials. There can be no
doubt, however, that carbon dioxide resulting from root
exudation and from decomposition of organic matter in
the soil plays a very prominent part in this operation.
The very large quantity of carbon dioxide in the soil,
amounting in some cases to from .5 to nearly 10 per cent
of the soil air, or several hundred times that of the at-
mospheric air, must aid greatly in dissolving the soil
particles.

Whatever may be the concentration of the soil water,
it seems probable that the liquid which is found where
the root-hair comes in contact with the soil particle, and
which is separated, in part at least, from the remainder
of the soil water, must have a density much greater than
that found elsewhere in the soil. That portion of the
soil water immediately in contact with the soil grain is a
much stronger solution than the water farther from the
soil surfaces, because of the adsorptive action of the
particles.

Many plants grown in solutions of nutritive salts have
few or no root-hairs, but absorb through the epidermal

ABSORPTION OF NUTRITIVE SALTS 411

tissue of the roots. Ifthe plant depended wholly on the
prepared solution in the soil water, a similar structure
would doubtless suffice. The special modification by
which the root-hairs come in intimate contact with the
soil particle and almost surround it, indicates a direct
relation between the soil particles and the plant, and
not merely between the soil solution and the plant.

New root-hairs are constantly being formed, and the
old ones become inactive and disappear. The contact
of a root-hair with a soil particle is not long-continued.
Whether the period of contact is determined by the
ability of the root to absorb nutriment from the particle
is not known. Certain it is that only a small portion of
the particle is removed.

327. Possible root action on colloidal complexes. —
It has already been stated that there is some evidence
to lead to the belief that the surfaces of soil particles are
covered to a large extent with colloidal complexes, com-
posed of both organic and inorganic matter having vigor-
ous absorptive properties and holding the bases and phos-
phorus in an absorbed condition. Roots of growing
plants have been found to cause coagulation of at least
some colloids, possibly by leaving an acid residue in the
nutrient solution by reason of the selective absorption of
bases and rejection of the acids of the dissolved salts.
It is conceivable that the root-hair, by removing bases
from the solution existing between the cell wall and the
colloidal covering of the soil particle, may cause coagula-
tion of the colloidal matter and thus liberate the plant-
food materials held by absorption: The liberated ma-
terial, being of a readily soluble nature, would be taken
up by the solution between the rootlet and the soil particle,
from which the root-hair could readily absorb it. Such

412 SOILS: PROPERTIES AND MANAGEMENT

an hypothesis would account for the ability of plants
to obtain a quantity of nutrient materials far in excess of
what can be accounted for by the solvent action of pure
water, and even beyond what many investigators are
willing to attribute to the solvent action of water charged
with carbon dioxide.

328. Why crops vary in their absorptive powers. —
As has already been pointed out (pars. 331-336), crops of
different kinds vary greatly in their ability to draw
nourishment from the soil. The difference between the
nitrogen, phosphorus, and potassium taken up by a corn
crop of average size and a wheat crop of average size is
very striking. In the table on page 419 it is seen that
two tons of red clover contain three times as much potash,
nearly ten times as much lime, and somewhat more phos-
phoric acid than does a crop of thirty bushels of wheat
including the straw.

The difference in absorbing power may be due to either
one or both of two causes: (1) a larger absorbing system ;
(2) a more active absorbing system. ‘The former is deter-
mined by the extent of the root-hair surfaces; the latter
by the intensity of the osmotic action.

329. Extent of absorbing system. — Plants with large
root systems may be expected to absorb the larger amounts
of nutrients from the soil. Such is usually the case,
although the extent of the root system is not necessarily
proportional to the total area of the absorbing surfaces
of the root-hairs.

330. Osmotic. activity.— The osmotic activity of a
plant under any giveh condition of soil and climate de-
pends on: (1) the rapidity and completeness with which
the plant elaborates the substances taken from the soil
into plant substance, or otherwise removes them from

ABSORPTION OF NUTRITIVE SALTS 413

solution; (2) the extent to which the exudations from the
root-hairs — whether these be carbon dioxide, salts of
mineral acids, or organic acids — act on the soil particles.
The first of these is a function of the vital energy of the
plant and its ability to utilize sunshine and carbon dioxide
to produce organic matter. It may be compared to the
property which enables one animal to do more work than
another animal of the same weight on a similar ration.
The removal from the ascending water current in the
plant of substances derived from the soil is accomplished
in the leaves. By the dissociation of these substances,
ions are constantly furnished for metabolism into materials
that may be built into the tissues of the plant. The re-
maining ions are kept in the solution. There is a con-
stant tendency to bring the composition and density of
the solution into equilibrium, by diffusion and diosmosis,
with the solution between the soil particle and the root-
hair. The rapiditv with which the metabolic process
removes a substance from the solution in the plant, there-
fore, determines the rate at which it is removed from a
solution of given composition and density in the soil.
Plants making a rapid growth remove more nutrients in
a given time than those making a slower growth, when
the nutrient solution is of a given composition and density.
Another factor that affects the rate of absorption of
salts from the soil is the solvent influence of exudates from
the root-hairs. Thissubject has already been treated (pars.
321-326), and it only remains to be said that this action
apparently varies with different kinds of plants, and
probably accounts in no small measure for the difference
in the ability of different plants to withdraw salts from
the soil.
These several factors, which, when combined, deter-

4{4 SOILS: PROPERTIES AND MANAGEMENT

mine the so-called “feeding power” of the plant, are
recognized by the popular terms ‘‘ weak feeder” and
“strong feeder,’ — applied, on the one hand, to such
crops as wheat or onions, which require very careful soil
preparation and manuring, and, on the other hand, to
maize, oats, or cabbage, which demand relatively less
care. In the manuring and rotating of crops, this differ-
ence in absorptive power must be considered, in order not
only to secure the maximum effect on the crop manured,
but also to get the greatest residual effect of the manure
on succeeding crops.

331. The absorptive power of cereals. — Cereals have
the power of utilizing the potassium and phosphorus of
the soil to a considerable degree, but they generally re-
quire fertilization with nitrogen salts. Most of the cereals,
such as wheat, rye, oats, and barley, take up the principal
part of their nitrogen early in the season, before the nitri-
fication processes have been sufficiently operative to fur-
nish a large supply of nitrogen; hence nitrogen is the
fertilizer constituent that usually gives the best results,
and should be added in a soluble form. Wheat, in partic-
ular, needs a large amount of soluble nitrogen early in
its spring growth. Since it is a “ delicate feeder,” it does
best after a cultivated crop or a fallow, by which the
nitrogen has been converted into a soluble form. Oats
can make better use of the soil fertility and do not require
so much manuring. Maize is a very coarse “ feeder,”
and, while it removes a large quantity of plant-food from
the soil, it does not require that this shall be added in a
soluble form. Farm manure and other slowly acting
manures may well be applied for the maize crop. The
long growing period required by the maize plant gives it
opportunity to utilize the nitrogen as it becomes avail-

ABSORPTION OF NUTRITIVE SALTS 415

able during the summer, when ammonification and nitri-
fication are active. Phosphorus is the substance usually
most needed by maize.

332. The feeding of grass crops. — Grasses, when in
meadow or in pasture, are greatly benefited by manures.
They are less vigorous ‘‘ feeders”’ than the cereals, have
shorter roots, and, when left down for more than one
year, the lack of aération in the soil causes decomposition
to decrease. There is usually a more active fixation of
nitrogen in grass lands than in cultivated lands, but this
becomes available very slowly.

Different soils and different climatic conditions neces-
sitate different methods of manuring for grass. Farm
manures may well be applied to meadows in all situations,
while the use of nitrogen is generally profitable.

333. Leguminous crops. — Most of the leguminous
crops are deep-rooted and are vigorous “ feeders.” Their
ability to take nitrogen from the air makes the use of that
fertilizer constituent unnecessary except in a few in-
stances, such as young alfalfa on poor soil, where a small
application of nitrate of soda is usually beneficial. Lime
and potassium are the substances most beneficial to leg-
umes on the majority of soils.

334. Root crops. — Many root crops will utilize very
large quantities of plant-food if it is in a form in which
they can use it. Phosphates and nitrogen are the sub-
stances generally required, the latter especially by beets
and carrots.

335. Vegetables. —In growing vegetables, the object
is to produce a rapid growth of leaves and stalks rather
than seeds, and often this growth is made very early in
the season. As a consequence, a soluble form of nitrogen
is very desirable. Farm manure should also have a promi-

416 SOILS: PROPERTIES AND MANAGEMENT

nent part in the treatment, as it keeps the soil in a mechan-
ical condition favorable to retention of moisture, which
vegetables require in large amounts, and it also supplies
needed fertility. The very intensive method of culture
employed in the production of vegetables necessitates the
use of much greater quantities of manures than are used
for field crops, and the great value of the product justifies
the practice.

336. Fruits. — In manuring fruits, with the exception
of some of the small, rapidly-growing ones, it is the aim
to maintain a continuous supply of nutrients available
to the plant, but not sufficient for stimulation except
during the early life of the tree, when rapid growth of
wood is desired. An acre of apple trees in bearing re-
moves as much plant-food material from the soil in a
season as does an acre of wheat. Farm manure and a
complete fertilizer mav be used, of which the constituents
should be in a fairly available form, as a constant supply
is necessary. A young growing orchard requires con-
siderably more nitrogen than does an old orchard. Some
nitrate of soda in early spring is desirable.

337. Mineral substances absorbed by plants. — The
plant, in its process of growth, withdraws from the soil
certain mineral substances that are presented to its roots
in a dissolved condition. As the salts in solution are
rather numerous, and as the osmotic pressure by which
the absorption is accomplished does not admit of the entire
exclusion of any ion capable of diosmosis, there are to be
found in the plant most of the mineral constituents of the
soil. Some of these are concerned in the vital processes
of the plant and are essential to its growth; others seem
to have no specific function, but are generally present.

The substances commonly met with in the ash of plants

ABSORPTION OF NUTRITIVE SALTS ALT

are potassium, sodium, calcium, magnesium, Iron, man-
ganese, aluminium, phosphorus, sulfur, silicon, and chlo-
rine. In addition to these, nitrogen is absorbed from the
soil in the form of soluble salts. Of these the substances
known to be absolutely essential to the normal growth. of
plants to maturity, are potassium, calcium, magnesium,
iron, phosphorus, sulfur, and nitrogen, while the others
are probably beneficial to the plant in some way not yet
discovered.

Of the substances acting as plant nutrients, each must
be present in an amount sufficient to make possible the
maximum growth consistent with other conditions, or
the yield of the crop will be curtailed by its deficiency.
To some extent certain essential substances may be re-~
placed by others, as, for instance, potassium by sodium ;
but such substitution is probably possible only in some
physiological réle other than that of an elemental con-
stituent of an organic compound. The substances that are
likely to be so deficient in an available form in any soil
as to curtail the yield of crops, are potassium, phosphorus,
nitrogen, and possibly sulfur; while the addition of cer-
tain forms of calcium is likely to be beneficial because of
its relation to other constituents and properties of the soil.
It is for the purpose of supplying these substances, and
to some extent to improve the mechanical condition of
the soil, that mineral manures are used.

338. Relation of plant growth to concentration of nu-
trient solution.— It has already been stated that the
addition of soluble salts to a soil has been found by some
experimenters to apparently increase the concentration
of the soil solution (par. 250). It has also been found
that plant growth, as measured by weight of plants, in-
creases with the concentration of the nutrient solution in

418 S80ILS: PROPERTIES AND MANAGEMENT

which the plants are grown.) This is the way in which
it is generally believed that soluble fertilizer salts benefit
plant growth. Insoluble plant-food materials have a
similar, but less active, result because they do not increase
the concentration of the soil solution to as great an extent.

339. Quantities of plant-food material removed by
crops. — The utilization of mineral substances by crops
is a source of loss of fertility to agricultural soils. In a
state of nature, the loss in this way is comparatively small,
as the native vegetation falls on the ground, and in the
process of decomposition the ash is almost entirely returned
to the soil. Under natural conditions, soil usually in-
creases in fertility; for, while there is some loss through
drainage and other sources, this is more than counter-
balanced by the action of the natural agencies of disin-
tegration and decomposition, and the fixation of atmos-
pheric nitrogen affords a constant, though small, supply
of that important soil ingredient.

When land is put under cultivation, a very different
condition is presented. Crops are removed from the
land, and only partially returned to it in manure or straw.
This withdraws annually a certain small proportion of
the total quantity of mineral substances, but, what is of
more immediate importance, it withdraws all of this in a
readily available form.

The following table, computed by Warington, ? shows

1 Hall, A. D., Brenchley, W. E., and Underwood, L. M.
The Soil Solution and the Mineral Constituents of the Soil.
Philosoph. Trans. Royal Soc. London, Series B, Vol. 204, pp.
179-200. 1918. Also, Lyon, T. L., and Bizzell, J. A. The
Plant as an Indicator of the Relative Density of Soil Solutions.
Proc. Am. Soc. Agron., Vol. 4, pp. 35-49. 1912.

? Warington, R. Chemistry of the Farm, pp. 64-65. Lon-
don. 1894.

ABSORPTION OF NUTRITIVE SALTS 419

the quantities of nitrogen, potassium, phosphorus, and
lime removed from an acre of soil by some of the common
crops. The entire harvested crop is included : —

PHos-

Toran NITRO- PorasH| Lim | pHoric

Crop 3 ASH oN K20 CaO Aor
OI5

(Pound) (Pounds)\(Pound-) (Pounds) (Pounds)

Wheat . . . .| 30 bushels | 172 . 9.2 | 21.1

Barley . . . .| 40 bushels | 157 . 9.2 | 20.7
Oats . . . .| 45 bushels | 191 Li 11.6 | 19.4
Maize . . . .| 30 bushels | 121 . — | 18.0
Meadow hay . .| 14 tons 203 9} 32.1 | 12.3
Red clover . .| 2 tons 258 Al 90.1 | 24.9
Potatoes . . .| 6 tons 127 }. 3.4 | 21.5

Turnips . . .| 17 tons 364 8} 74.0 | 33.1

340. Quantities of plant-food materials contained in
soils. — Comparing the figures given above with those
showing the percentages of the fertilizing constituents in
certain soils, it is evident that there is a supply in most
arable soils that will afford nutriment for average crops
for a very long period of time. (See pars. 46, 48, 52, 53.)

341. Possible exhaustion of mineral nutrients. — On
the other hand, when it is considered that the soil must
be depended upon to furnish food for humanity and
domestic animals as long as they shall continue to in-
habit the earth, at least so far as is now known, the very
apparent possibility of exhausting, even in a period of
several hundred vears, the supply of plant nutrients be-
comes a matter of grave concern. The visible sources of
supply, to replace or supplement those in the soils now
cultivated, are, for the mineral substances, the subsoil
and the natural deposits of phosphates, potash salts, and

42() SOILS: PROPERTIES AND MANAGEMENT

limestone; and for nitrogen, deposits of nitrates, the by-
product of coal distillation, and the nitrogen of the
atmosphere. The last of these is inexhaustible, and the
exhaustion of the nitrogen supply, which a few years ago
was thought to be a matter of less than half a century,
has now ceased to cause any apprehension. The conser-
vation or extension of the supply of mineral nutrients is
now of supreme importance. The utilization of city refuse
and the discovery of new mineral deposits are develop-
ments well within the range of possibility, but neither of
these promises to afford more than partial relief. The
utilization of the subsoil through the gradual removal by
natural agencies of the topsoil will, without doubt, tend
to constantly renew the supply. The removal of topsoil
by wind and erosion is, even on level land, a very con-
siderable factor. The large amount of sediment carried
in streams immediately after a rain, especially in summer,
gives some idea of the extent of this shifting. This affects
chiefly the surface soil, and thereby brings the subsoil
into the range of root action.

There is little doubt that a moderate supply of plant-
food materials will always be available in most soils, but
for progressive agriculture manures must be used.

CHAPTER XX
ORGANISMS IN THE SOIL

A vast number of organisms, animal and vegetable, live
in the soil. By far the greater part of these belong to
plant life, and these comprise the forms of greatest influ-
ence in producing the changes in structure and composition
that contribute to soil productiveness. Most of the
organisms are so minute as to be seen only by the aid of
the microscope, while a much smaller proportion range
from these to the size of the larger rodents. Thev may
thus be classed as microérganisms and macroérganisms.
The latter class will be considered first.

MACROORGANISMS OF THE SOIL

Of the macroérganisms in the soil the animal forms
belong chiefly to (1) rodents, (2) worms, and (3) insects;
and the plant forms to (1) the large fungi and (2) plant
roots.

342. Rodents. — The burrowing habits of rodents —
of which the ground squirrel, the mole, the gopher, and the
prairie dog are familiar examples — result in the pulveri-
zation and transfer of very considerable quantities of soil.
While the activities of these animals are often not favor-
able to agriculture, the effect on the character of the soil
is rather beneficial and is analogous to that of good tillage.
Their burrows also serve to aérate and drain the soil, and

421

499 SOILS: PROPERTIES AND MANAGEMENT

in permanent pastures and meadows are of much value
in this way.

343. Worms. — The common earthworm is the most
conspicuous example of the benefit that may accrue from
this form of life. Darwin, as the result of careful measure-
ments, states that the quantity of soil passed through
these creatures may, in a favorable soil in a humid climate,
amount to ten tons of dry earth per acre annually. The
earthworm obtains its nourishment from the organic
matter of the soil, but takes into its alimentary canal the
inorganic matter as well, expelling the latter in the form
of casts after it has passed entirely through the body.
The ejected material is to some extent disintegrated, and
is in a flocculated condition. The holes left in the soil
serve to increase aération and drainage, and the move-
ments of the worms bring about a notable transportation
of lower soil to the surface, which aids still more in effect-
ing aération. Darwin’s studies led him to state that from
one-tenth to two-tenths of an inch of soil is yearly brought
to the surface of land in which earthworms exist in normal
numbers.

Instances are on record of land flooded for a consider-
able period so that the worms were destroyed, and the
productiveness of the soil was seriouslv impaired until it
was restocked with earthworms.

Wollny conducted experiments with soil, the soil in one
case containing earthworms and in another case not con-
taining them. Although there was much variation in his
results, they were in every case in favor of the soil con-
taining the worms, and in a number of the tests the yield
on rich soil was several times as great as where no worms
were present.

Earthworms naturally seek a heavy, compact soil, and

ORGANISMS IN THE SOIL 493

it is in soil of this character that they are most needed
because of the stirring and aération they accomplish.
Sandy soil and the soils of arid regions, in which are
found few or no earthworms, are not usually in need of
their activities.

344. Insects. — There is a less definite, and probably
less effective, action of a similar kind produced by insects.
Ants, beetles, and the myriads of other burrowing insects
and their larvee effect a considerable movement of soil
particles, with a consequent aération of the soil. At the
same time they incorporate into the soil a considerable
quantity of organic matter.

345. Large fungi. — The larger fungi are chiefly con-
cerned in bringing about the first stages in the decom-
position of woody matter, which is disintegrated through
the growth in its tissues of the root mycelia of the fungi.
These break down the structure, and thus greatly facili-
tate the work of the decay bacteria. Action of this kind
is largely confined to the forest and is not of great im-
portance in cultivated soil.

Another function of the large fungi is exercised in the
intimate, and possibly symbiotic, relation of the fungal
hyphe to the roots of many forest trees, in soil where
nitrification proceeds very slowly, if at all, for nitrates are
apparently not abundant in forest soils. This envelop-
ing system of hyphe, which may consist of masses in a
definite zone of the cortex with occasional filaments pass-
ing outward into the soil, or which may surround the root
with a dense mass of interwoven hyphe, is called mycor-
rhiza.

The cereal, cruciferous, leguminous, and solanaceous
plants are not associated with mycorrhiza. Mycotrophic
plants are usually those that live in a humous soil filled

494 SOILS: PROPERTIES AND MANAGEMENT

with the mycelia of fungi. It is thought that the mycor-
rhiza aid the higher plants to obtain nutriment that they
must strive for in competition with the fungi.

Mycotrophic plants are also able to grow with a very
small transpiration of moisture, as is well known to be
the case with many conifers; and this restricted tran-
spiration would doubtless result in lack of nutriment were
it not for the assistance of the mycorrhiza.

346. Plant roots. — The roots of plants assist in pro-
moting productiveness of the soil both by contributing
organic matter and by leaving, on their decay, openings
which render the soil more permeable to water and which
also facilitate drainage and aération. The dense mass of
rootlets, with their minute hairs that are left in the soil
after every harvest, furnish a well-distributed supply of
organic manure, which is not confined to the furrow slice,
as is artificially incorporated manure. The drainage and
aération of the lower soil, due to the openings left by the
decomposed roots, are of the greatest importance in heavy
soil, and the beneficial effects of clover and other deep-
rooted plants are due in no small measure to this function.

MICROORGANISMS OF THE SOIL

Of the microérganisms commonly exist-
ing in soils, the greater part belong to
plant rather than to animal life. Of the
latter, the only organisms of well-known
economical importance are the nematodes
(Fig. 58), whose injurious effect on plant
growth is accomplished through the for-
mation of galls on the roots, in which the
Fie. 58.—Nema- young are hatched and live to sexual

todes entering .
aplantroot. maturity.

ORGANISMS IN THE SOIL 425

347. Plant microdrganisms. — The microscopic plants
of the soil may be classed as slime molds, bacteria, fungi,
and alge.

348. Plant microérganisms injurious to higher plants.
—Jnjurious plant microérganisms are confined mostly
to fungi and bacteria. They may be entirely parasitic in
their habits, or only partially so. They injure plants by
attacking the roots. Those that attack other parts of
plants may live in the soil during their spore stage, but
they are not strictly microdrganisms of the soil. Some
of the more common diseases produced by soil organisms
are: wilt of cotton, cowpeas, watermelon, flax, tobacco,
tomatoes, and other plants; damping-off of a large num-
ber of plants; root-rot; galls.

These fungi or bacteria may live for long periods, prob-
ably indefinitely, in the soil, if the conditions necessary
for their growth are maintained. Some of them will die
within a few years if their host plants are not grown on
the soil, but others are able to maintain existence on
almost any organic substance. Once a soil is infected,
it is likely to remain so for a long time, or indeed indefi-
nitely. Infection is easily carried. Soil from infected
fields may be carried on implements, plants, or rubbish
of any kind, in soil used for inoculation of leguminous
crops, or even in stable manure containing infected plants
or in the feces resulting from the feeding of infected plants.
Flooding of land by which soil is washed from one field
to another may be a means of infection.

Prevention is the best defense from diseases produced
by these soil organisms. Once disease has procured a
foothold, it is practically impossible to eradicate all its
organisms. Rotation of crops is effective for some dis-
eases, but entire absence of the host crop is oftener neces-

496 SOILS: PROPERTIES AND MANAGEMENT

sary. The use of lime is beneficial in the case of certain
diseases. Chemicals of various kinds have been tried
with little success. Steam sterilization is a practical
method of treating greenhouse soils for a number of dis-
eases. The breeding of plants immune to the disease af-
fecting its particular species has been successfully carried
out in the case of the cowpea and cotton plants, and can
doubtless be accomplished with others.

In regions in which farming is confined largely to one
crop or to a limited number of cereals, it is the common
experience that yields decrease greatly in the course of a
score of years after the virgin soil is broken. The cause
for this,is attributed by Bolley' in large measure to a
diseased condition of the plants due to the growth of
various fungi that inhabit the soil and attack the crops
grown on it. He reports that he has experimented with
pure cultures taken from wheat grains, straw, and roots,
and has demonstrated that certain strains or species of
Fusarium, Helminthosporium, Alternaria, Macrosporium,
Colletotrichum, and Cephalothecium are directly capable
of attacking and destroying growing plants of wheat, oats,
barley, brome grass, and quack grass, and that within
limits the disease may be transferred from one type of
crop to another.

349. Plant microdrganisms not injurious to higher
plants. — The vegetable microdrganisms of the soil all
take an active part in removing dead plants and animals
from the surface of the soil, and in bringing about the other
operations that are necessary for the production of plants.
The first step in the preparation for plant growth is to
remove the remains of plants and animals that would

1Bolley, H. L. Wheat. North Dakota Agr. Exp. Sta.,
Bul. 107. 1913.

ORGANISMS IN THE SOIL 427

otherwise accumulate to the exclusion of other plants.
These are decomposed through the action of organisms
of various kinds, the intermediate and final products of
decomposition assisting plant production by contributing
nitrogen and certain mineral compounds that are a
directly available source of plant nutriment, and also by
the effect of certain of the decomposition products on the
mineral substances of the soil, by which they are rendered
soluble and hence available to the plant.

Through these operations the supply of carbon and
nitrogen required for the production of organic matter is
kept in circulation. The complex organic compounds
in the bodies of dead plants or animals, in which condi-
tion plants cannot use them, are, under the action of
microérganisms, converted by a number of stages into
the very simple compounds used by plants. In the course
of this process a part of the nitrogen is sometimes lost
into the air by conversion into free nitrogen, but fortu-
nately this may be recovered and even more nitrogen
taken from the air by certain other organisms of the soil.

The slime molds, bacteria, fungi, and algze all play a
part in these processes, but none of them so actively
during every stage of the processes as do the bacteria.
Molds and fungi are particularly active in the early stages
of decomposition of both nitrogenous and non-nitrogenous
organic matter. Molds are also capable of ammonifying
proteins, and even re-forming the complex protein bodies
from the nitrogen of ammonium salts. Certain of the
molds and of the alge are apparently able to fix atmos-
pheric nitrogen, and contribute a supply of carbohydrates
required for the use of the nitrogen-fixing bacteria. Among
these are Aspergillus niger and Penicillium glaucum.

It also seems probable that the fungi associated with

492 SOILS: PROPERTIES AND MANAGEMENT

the roots of many forest trees and known as mycorrhizal
fungi have the ability to fix atmospheric nitrogen, and that
in some way the trees obtain a part, at least, of the nitro-
gen so fixed. The growth of forests on poor, sandy soil
containing practically no nitrogen has been urged as an
example of this process.

350. Bacteria. — Of the several forms of microérgan-
isms found in the soil, bacteria are the most important.
In fact, the abundant and continued growth of plants on
the soil is absolutely dependent on the presence of bacteria,
for through their action chemical changes are brought
about which result in making soluble both organic and
inorganic material necessary for the life of higher plants,
and which, in part at least, would not otherwise occur.

Bacteria are thus trans-
formers, not producers, of
fertility in the soil, although,
as will be seen later, certain
kinds of bacteria take nitro-
gen from the air and leave it
in the soil. With this excep-
tion, however, they add no
plant-food to the soil. It is
their action in rendering
available to the plant ma-
Pig, 69.-—Some toes of coil mi terial already present in the

crodrganisms hiehly maenifed. SO that constitutes their

(a), nitrate sore iH (2), ni- greatest present value in crop

lens ; (a), B. fusiformis P(e), B. production. It 1s to their

subtilis a (f), Clostridium pas- activity In conveying nitro-

" gen from the air to the soil

that we are indebted for most of our supply of nitrogen
in virgin soils (see Fig. 59).

ORGANISMS IN THE SOIL 429

It is not usually the entire absence of bacteria from the
soil that is to be avoided in practice, for all arable soils con-
tain bacteria, although sometimes not all of the desirable
forms; but, as great bacterial activity is required for the
large production of crops, the practical problem is to main-
tain a condition of soil most favorable to such activity.

351. Distribution of bacteria. — Bacteria are found
almost universally in soils, although they are much more
numerous in some soils than in others. A number of in-
vestigators have stated that in soils from different locali-
ties and of.different types that they have examined, the
numbers of bacteria were proportional to the productive-
ness of the soils. The number of bacteria present has in
some cases been shown to be proportional to the amount
of humus contained in the soil. It is natural to expect
that within certain limits both these findings will hold. The
conditions obtaining in a productive soil are those favorable
to the development of certain forms of bacteria, and these
kinds constitute a very large proportion of those generally
found in soils. However, there is evidence that compara-
tively unproductive soils may contain a large number of
bacteria that are presumably not favorable to plant growth.

Samples of soil taken from certain productive and rela-
tively unproductive parts of a field on the Cornell Uni-
versity farm contained a larger number of bacteria in the
poor soil, although the two soils were equally well drained
and the good soil had slightly more organic matter.
They had also received practically the same treatment
during the preceding few years : —

Character of Number of bacteria
soil per gram of dry soil

Good ....... . + 1,200,000
Poor. . . . . « « « « + 1,600,000

430 SOILS: PROPERTIES AND MANAGEMENT

After wheat had been growing for two months on these
soils in the greenhouse, the soils being maintained at the
same moisture content, the samples showed the following
count : —

Character of Number of bacteria,

soil to a gram of dry soil
Good ....... 2... 760,000
Poor. ....... . « 1,120,000

Another reason why this relation between the number
of bacteria and soil productiveness does not hold is that
the bacteria having the same functions in relation to plant-
food do not always have the same physiological efficiency.
In other words, they do not have the same virulence, a
small number in some cases being able to bring about the
same changes that in other cases require a much greater
number.

Bacteria are found chiefly in the upper layers of soil,
although not in large numbers at the immediate surface
of the ground. In humid regions the layer between the
first inch and the sixth or the seventh inch contains, in
most soils, the great bulk of bacteria present. In arid or
semiarid regions, bacteria are found at greater depths
and the densest population is located at lower levels than
in humid regions. This is largely because of the deeper
penetration of the air and the conditions that accom-
pany it.

352. Numbers of bacteria.—'The number of bacteria in
a, soil will naturally vary with the conditions that favor or
discourage their growth. In very sandy soils, forest soils,
desert soils, water-logged soils, and soils low in humus,
the bacteria are either absent or comparatively few in
numbers. In soils very rich in organic matter, especially

ORGANISMS IN THE SOIL 431

where animal manure has been applied or where a carcass
has been buried, the number becomes very large, as
many as 100,000,000 to a gram of soil having been found ;
while in soil of ordinary fertility and tilth the numbers
range from 1,000,000 to 5,000,000 toa gram. The extreme
rapidity with which reproduction occurs makes it possible
for the number to increase enormously when conditions
are favorable for their growth.

The table on page 482 shows the number of bacteria
to a gram of soil found in different parts of the United
States during some portion of the growing season.

The figures showing the number of bacteria in each
gram of soil that are presented in this table cannot be
used for a comparison of the relative numbers of bacteria
in soils of different regions of this country, because dif-
ferent methods were used by the experimenters in making
the estimations. They are, however, an indication of
what may be considered the ordinary range in arable
soils.

353. Numbers as influenced by season. — It might be
supposed that, like most plants, bacteria would develop
most rapidly in summer months and that they would be
found in largest numbers at that season, at least in regions
of low temperatures during the winter months. That
this is not always the case has been shown by Conn,!
who found as the result of periodical enumeration of bac-
teria throughout a term of two years that the highest
counts were obtained during the winter months, when
the soil was frozen. This does not mean that all classes
of bacteria are present in largest numbers at that season,
but, as explained by Conn, it seems likely that certain

1Conn, H. J. Bacteria in Frozen Soils II. Centrlb. f.
Bakt., II, Band 32, Seite 70-97. 1912.

432

SOILS: PROPERTIES AND MANAGEMENT

NUMBER OF BactTERIA TO A GRAM OF SOIL DURING Some
PERIOD OF THE GROWING SEASON

terrence

STrarE

Delaware .

Kansas
Kansas
Kansas
Kansas
Towa

Towa
Towa

Towa

1Chester, F. D. The
Delaware Agr. Exp. Sta., Bul. 65.

Son

Adjoining soil above
and of same char-
acter

Of same type as

._ =» * © 8 # 8 @ #8 @

Loam, rich in humus

Loam, richer in hu-

mus than soil above

Thin soil, gumbo
subsoil

Loam, low in humus

Marshall loam, no
lime applied

Marshall loam, 1,000
pounds lime per

acre
Marshall loam, 2,000

pounds lime per
acre

Marshall loam, 6,000
pounds lime per

acre

inches

3
inches

30
inches
30
inches
30
inches
30
inches
top
soil

top
soil

INVESTI-~
GATOR

Orchard in high} Chester !

state of culti-
vation. In
cover crops
Meadow for
twelve years

Vegetables and
heavily ma-
nured

Searlet clover
plowed under
and alter-
nated with
maize for ten
years

Alfalfa,
years

Alfalfa

five

Mixed grasses

Chester !

Mayo and
Kinsley ?
Mayo and
Kinsley ?
Mayo and
Kinsley 2

Oats and wheat} Mayo and

Kinsley 2
Brown 3
Brown 3

Brown 3

Brown ®

Bacreria

sie napmiereentetmetnnnen | 1 | LN | TT | NHN IH | etal MrTERMEAn—eretinneninen

Stiff clay

2,200,000

450,000

1,800,000

3,360,000

33,931,808
53,596,060
78,534
8,543,006
1,930,000
2,342,000

2,787,000

3,766,000

Bacteriological Analysis of Soils.

1904.

*Mayo, U. S., and Kinsley, A. F. Bacteria of the Soil.
Kansas Agr. Exp. Sta., Bul. 117.
’ Brown, P. E. Some Bacterial Effects of Liming. Iowa

Agr. Exp. Sta., Research Bul. 2.

1903.
1911.

ORGANISMS IN THE SOIL 433

forms predominate in summer and others in winter (see
Fig. 60).

Velo TIT TTI AT TT TTT ATT
CCCP EEE LAAT
“SSA CURE TNA
pee cry

Fig. 60.—Periodical enumcration of bacteria in soil of two plats during
two years, expressed in millions to a gram of dry soil.

Brown and Smith?! obtained results that in the main
confirmed Conn’s work, and they advanced the theory
that the concentration of the soil solution immediately
surrounding the soil particles, together with the high
surface tension exerted by the soil particles, prevents the
freezing of the surface film and that this water forms a
suitable medium for the development of bacteria.

354. Conditions affecting growth.— Many conditions
of the soil affect the growth of bacteria. Among the most
important of these are the supply of oxygen and moisture,
the temperature, the presence of organic matter, and the
acidity or the basicity of the soil.

355. Oxygen.— All soil bacteria require for their
growth a certain amount of oxygen. Some bacteria, how-
ever, can continue their activities with much less oxygen
than can others. Those requiring an abundant supply
of oxygen have been called aérobic bacteria, while those
preferring little or no air are designated as anaérobic

1Brown, P. E., and Smith, R. E. Bacterial Activities in
Frozen Soil. Iowa Agr. Exp. Sta., Research Bul. 4. 1912.

434 SOILS: PROPERTIES AND MANAGEMENT

bacteria. This is an important distinction, because those
bacteria that are of the greatest benefit to the soil are, in
the main, aérobes, and those that are injurious in their
action are chiefly anaérobes. However, it seems likely
that an aérobic bacterium may gradually accommodate
itself within certain limits to an environment containing
less oxygen, and an anaérobic bacterium may accommo-
date itself to the presence of a larger amount of oxygen.
Thus a bacterium may be most active in the presence of
an abundant supply of oxygen, but, when subjected to
conditions in which the supply is small, growth continues
but with lessened vigor. The term facultative bacteria
has been used to designate those bacteria that are able
to adapt themselves to considerable variation in oxygen
supply. The structure, tilth, and drainage of the soil
consequently determine largely whether aérobic or an-
aérobic bacteria shall be more active.

356. Moisture. — Bacteria require some moisture for
their growth. A notable decrease in the moisture con-
tent of the soil may temporarily decrease the number of
bacteria by limiting their development to the films of
moisture surrounding the particles. With a decrease in
the moisture content of a soil, there occurs an increase
in the oxygen in the interstitial spaces. Those bacteria
that thrive in the presence of oxygen are thereby favored,
and the character of the bacterial flora is correspondingly
changed. When the soil remains saturated, or nearly
so, for any considerable period, the anaérobic forms
assert themselves, and the usually beneficial activities
of the aérobic bacteria are temporarily suspended.
The most favorable moisture condition for the activity
of the most desirable bacteria is that found in a well-
drained soil.

ORGANISMS IN THE SOIL 435

357. Temperature. — Soil bacteria, like other plants,
continue life and growth under a considerable range of
temperature. Freezing, while rendering bacteria dor-
mant, does not kill them, and growth begins slightly
above that point. It has been shown that nitrification
goes on at temperatures as low as from 37° to 39° F. It
is not, however, until the temperature is considerably
higher that their functions are pronounced. From 70°
to 110° F. their activity is greatest, and it diminishes
perceptibly below or above those points. The thermal
death point of most forms of bacteria is found at some
point between 110° and 160° F., but the spore forms even
resist boiling. Only in some desert soils does the natural
temperature reach a point sufficiently high to actually
destroy bacteria, and there only near the surface. In fact,
it is seldom that soil temperatures become sufficiently high
to curtail bacterial activity.

358. Organic matter.— The presence of a certain
amount of organic matter is essential to the growth of
most, but not all, forms of soil bacteria. The organic
matter of the soil, consisting as it does of the remains of
a large variety of substances, furnishes a suitable food
supply for a very great number of forms of organisms.
The action of one set of bacteria on the cellular matter of
plants embodied in the soil produces compounds suited to
other forms, and so from one stage of decomposition to
another this constantly changing material affords sus-
tenance to a bacterial flora the extent and variety of which
it is difficult to conceive. Not only do bacteria affect the
organic matter of the soil, but, in the case of certain
forms, their activities produce changes in the inorganic
matter that cause it to become more soluble and more
easily available to the plant.

436 SOILS: PROPERTIES AND MANAGEMENT

A soil low in organic matter usually has a lower bac-
terial content than one containing a larger amount, and,
under favorable conditions, the beneficial action, to a cer-
tain point at least, increases with the content of organic
substance; but, as the products of bacterial life are
generally injurious to the organisms producing them,
such factors as the rate of aération and the basicity of
the soil must determine the effectiveness of the organic
matter.

359. Soil acidity. — A soil having an acid reaction
makes a poor medium for the growth of certain bacteria.
A neutral or a slightly alkaline soil furnishes the most
favorable condition for the development of the forms of
bacteria most beneficial to arable land. The activities of
many soil bacteria result in the formation of acids which
are injurious to the bacteria themselves, and, unless there
is present some basic substance with which these can
combine, bacterial development is inhibited by their own
products. This is one of the reasons why lime is so often of
great benefit when applied to soils, and especially to those
on which alfalfa and red clover are growing. For the
same reason, the presence of lime hastens decay of or-
ganic matter in certain soils, and the conversion of nitrog-
enous material with a minimum loss into compounds
available to the plants. As showing the value of lime
in the process of nitrate formation, it has been pointed
out that in the presence of an adequate supply of lime
the availability of ammonium salts is almost as high
as that of nitrate salts, but where the supply of lime
is insufficient the value of ammonium salts is relatively
rather low.

360. Functions of soil bacteria. — Bacteria have a part
in many of the processes of the soil which greatly affects

ORGANISMS IN THE SOIL A387

its productiveness. It has become customary to refer to
the changes produced by certain forms of bacteria as their
function in contributing to soil productiveness.

361. Decomposition of mineral matter. — Certain bac-
teria decompose some of the mineral matter of the
soil and render it more easily available to the plant.
While the nature of the processes and their extent
are not known, there is sufficient evidence to justily
the above statement. It is well known that several
forms of bacteria are instrumental in decomposing rock,
and that sulfur and iron compounds are acted upon by
other forms.

To what extent the very difficultly soluble forms of
phosphorus, as tricalcium phosphate for example, are
rendered soluble and available to agricultural planis by
Microérganisms, is a matter of great importance. The
extent to which the subject has been investigated is
rather limited, but, in the main, there is indicated a con-
siderable action of both bacteria and fungi on tricalcium
phosphate.

362. Influence of certain bacteria and molds on the
solubility of phosphates. — Some very significant experi-
ments were performed by Stoklasa, Duchacek, and Pitra,!
who found that bone meal, when brought into contact
with pure cultures of certain bacteria, was apparently
rendered soluble, the extent to which the solubility pro-
gressed varying with the different forms of bacteria
brought into contact with it. The percentage of the total
phosphorus in the meal that was rendered soluble was as
follows : —

1 Stoklasa, J., Duchacek, F., and Pitra, J. Uber den Hinfluss
der Bakterien auf die Knochenzersetzung. Centrlb. f. Bakt.,
II, Band 6, Seite 526-535, 554-558. 1900.

438 SOILS: PROPERTIES AND MANAGEMENT

Per cent
Not inoculated . ..... . 8.83
B.megatherlum ..... . . 21.56
B. fluorescens . . . . . . . .) 9.19
B. proteus vulgaris . . . . . . 14.79
B. butyricus Hueppe. . . . . . 15.55
B.mycoides ...... . . 28.03
B.mesentericus .... . . . 20.60

Léhnis! quotes Grazia e Cerza to have found that
Aspergillus niger, Penicillium glaucum, and P. brencaule,
isolated from garden soil, when placed in nutrient solu-
tion with tricalcium phosphate, assimilated one-fifth to
one-third of the phosphorus in sixty days.

There is some difference of opinion whether the solvent
action arising from bacterial growth is due entirely to the
acids that are produced by the bacteria exerting such
action, or whether there is also some other influence exer-
cised by bacteria. Stoklasa accounts for the solvent
action of the bacteria in his experiments by the bacterial
secretion of proteolytic and diastatic enzymes acting on
the bone meal. In opposition to this idea, Krober?
maintains that the solvent action depends on the kind of
fermentation that the organic matter undergoes, acid fer-
mentation rendering the phosphates more soluble, while
ammoniacal fermentation results in no solvent action on
tricalcium phosphate and, in the presence of sufficient
basic material, may render the monocalcium and dical-

1Lohnis, F. Handbuch d. Landw. Bakteriologie, Seite 700.
Berlin. 1910.

*Krober, E. Uber das Léslichwerden der Phosphorsadure
aus Wasserunloslichen Verbindungen unter der Einwirkung von
Bakterien und Hefen. Jour. f. Landw., Band 57, Seite 5~80.
1909-1910.

ORGANISMS IN THE SOIL 439

cium phosphates insoluble. He would limit the solvent
action of bacteria to the effect of the acids they produce.

Sackett, Patten, and Brown ! have in a measure repeated
Stoklasa’s experiments and obtained somewhat similar
results, which lead them to conclude that there is a
solvent agent other than the acids produced by the
bacteria.

It would appear from these experiments that bacteria,
and possibly fungi, commonly found in soils act on tri-
calcium phosphate in such a manner as to render a part
of it soluble. Nevertheless, experiments that have been
conducted for the purpose of ascertaining whether tri-
calcium phosphate in soils is rendered more readily avail-
able to plants when large quantities of decomposing organic
matter are present than when this is not the case, have
not, in the main, indicated that the decomposing organic
matter increases availability of the phosphorus (par. 439).
An explanation of this may possibly be found in the
occurrence of a reverse biological process which results
in the transformation of soluble phosphates into insoluble
ones, the occurrence of such a process having been found
by Stoklasa ? and others.

The carbon dioxide produced by bacteria is a solvent
for many of the silicates of the soil, and may free calcium
and potassium from hornblende and feldspar.

Various groups of sulfur bacteria, through the produc-
tion of H,S and H.SO,, act on iron in the soil and con-
vert it into sulfide and sulfate. Carbon dioxide also

1 Sackett, W. G., Patten, A. J., and Brown, C. W. The
Solvent Action of Soil Bacteria upon the Insoluble Phosphates
of Raw Bone Meal and Natural Rock Phosphate. Michigan
Agr. Exp. Sta., Special Bul. 48. 1908.

2 Stoklasa, J. Biochemischer Kreislauf des Phosphat-Ions
im Boden. Centrlb. f. Bakt., IT, Band 29, Seite 385-519. 1913.

440 SOILS: PROPERTIES AND MANAGEMENT

plays a part in the solution of iron. The lower fungi and
the algce precipitate iron from solution as Iron oxide.

363. Decomposition of non-nitrogenous organic matter.
— The organic matter commonly decomposed in goils
contains a large proportion of compounds containing no
nitrogen. Many non-nitrogenous substances decompose
rather rapidly, and the organie nitrogen disappears less
rapidly than the carbon, hydrogen, and oxygen of organic
bodies.

Humus always contains a higher percentage of nitrogen
than do the plants from which it is formed.

The non-nitrogenous substances consist of cellulose and
allied compounds forming the cell walls of plants, and the
carbohydrates, organic acids, fats, and the like, contained
in them. The dissolution of cellulose is brought about
by the action of the enzyme cytase secreted by a number
of fungi, and is also probably accomplished by the Bacillus
amylobacter, but whether through the secretion of an
enzyme is not known. Other bacteria have been reported
to secrete a cytase that acts on certain constituents of the
cell wall. It is probable that numerous organisms capa-
ble of fermenting cellulose and allied substances exist in
the soil, accomplishing this decomposition through the
production of cytase.

The effect of cytase on cellulose and other fiber is to
hydrolyze it with the formation of sugar, as glucose,
mannose, zylose, arabinose, and the like.

Starch is converted into glucose by a ferment (diastase)
either present in the plant itself or possibly secreted by
fungi or bacteria. All the sugars are finally converted
into organic acids which may combine with mineral bases.
Distinct organisms have been isolated that can utilize
for their development formates, acetates, propionates,

ORGANISMS IN THE SOIL 4.41

butyrates, and the like, the final product being carbon
dioxide and water. Thus, step by step, the non-nitroge-
nous matter incorporated with the soil is carried by
one and another form of organism from the most com-
plex to the simplest combinations.

The final product of the decomposition of carbonaceous
matter being carbon dioxide, there is a return to the air
of the compound from which the carbon of the decompos-
ing substance was originally derived. In the plant, un-
less it is saprophytic, the earbon of the tissues comes
largely from the carbon dioxide of the air, from which
more complex carbon-bearing compounds are produced and
utilized in its functions or in its tissues. A portion of the
carbon is returned to the air by the plant in the form of
carbon dioxide; the remainder is retained by the plant,
and may be returned by the process of decay or may be
consumed by an animal, and, as the result of its physio-
logical processes, either exhaled as carbon dioxide or
deposited in the tissues to be later decomposed and con-
verted into carbon dioxide. The soil is thus the scene of
at least a part of the varied transformations through
which carbon is continually passing as it is utilized by
higher plants, animals, bacteria, and fungi.

The non-nitrogenous organic substances in their various
stages furnish food for a large number of bacteria, among
which are those concerned in the decomposition of mineral
matter and in the processes of nitrification and nitrogen
fixation. There are, therefore, two ways in which these
substances are of great importance in soil fertility: (1) as
a source of carbon dioxide and of organic acids; (2) as
a food supply for useful soil bacteria.

364. Decomposition of nitrogenous organic matter. —
The decomposition of nitrogenous organic matter is ac-

442 SOILS: PROPERTIES AND MANAGEMENT

complished by a series of changes from one compound to
another, as was seen to be the case with the non-nitroge-
nous materials. The final products are carbon dioxide,
water, usually some hydrocarbon gases resulting from
the carbon and hydrogen of the organic matter, and also
some hydrogen sulfide or other gas containing sulfur
or a final oxidation of the sulfur of the proteids into sul-
fates; while the nitrogen is ultimately converted into
nitrates, or into free nitrogen, although a portion of the
original nitrogen sometimes escapes into the air in the
intermediate stage, ammonia.

The processes will be discussed under the following
heads, which represent certain more or less definite stages
in the decomposition: 1, decay and putrefaction; 2, am-
monification; 3, nitrification; 4, denitrification; 5, fixa-
tion of atmospheric nitrogen. These various processes
form what has been termed the nitrogen cycle.

CHAPTER XXI

THE NITROGEN CYCLE

Or the various elements composing the nutrients used
by plants, nitrogen has the highest commercial value.
It is, moreover, absorbed in large quantities by agricul-
tural plants and the supply is constantly liable to loss in
drainage water and in the gaseous form. Its importance
to agriculture has led to much study of its occurrence,
combinations, reactions, and movements in the soil.

When it is recalled that the nitrogen gas of the atmos-
phere is the one primitive source of the world’s supply of
nitrogen, it becomes apparent that the agencies that have
been instrumental in its transfer from one condition to
another have been extremely active. The movement of
nitrogen from air to soil, from soil to plant, from plant
back to soil or to animal, and from animal back to soil,
with a return to air at various stages, involves many
forces, many factors, many organisms, and many re-
actions.

365. Decay and putrefaction. — Decomposition of the
nitrogenous organic matter of the soil, consisting largely
of the proteins, begins with either one of two processes
— decay or putrefaction. Decay is produced by aérobic
bacteria, and naturally occurs when the conditions are
most favorable for their development. When the condi-
tions are otherwise, the growth of these bacteria is checked,
and then further decomposition would be extremely slow

443

444 SOJLS: PROPERTIES AND MANAGEMENT

were it not for the other process — putrefaction. Putre-
faction is produced by anaérobic bacteria. In the same
body, and consequently in the same soil, decay and putre-
faction may be in progress simultaneously, decay taking
place on the outside and on the surfaces of other parts
exposed to the air, while putrefaction occurs on the in-
terior, where the supply of oxygen is limited. By means
of the two processes, decomposition is greatly facilitated.

Decay (see Fig. 61) produces a very rapid and complete
decomposition of the substance in which it operates, most
of the carbon and hydrogen being quickly converted into
carbon dioxide and water, and the nitrogen into ammonia
and probably some free nitrogen. The latter is possibly
due to the oxidation of ammonia, thus

4.NH; +30, =6H.0O +2 N,

The sulfur of the proteins finally appears in the form of
sulfates.

What the intermediate products are has not been deter-
mined, but in the decay of meat, in which there was an
abundant supply of oxygen, succinic, palmytic, oleic, and
phenyl-propionic acids have been found.

Putrefaction results in a large number of complex inter-
mediate compounds and proceeds much more slowly.
Many of the substances thus produced are highly poison-
ous, and most of them have a very offensive odor. They
may be further broken down by decay when the condi-
tions are suitable, or by a continuation of the process of
putrefaction. In either case, the poisonous properties
and the odor are removed.

In the process of decomposition of organic matter two
classes of substances are produced: (1) those that have
been excreted or secreted by the bacterium, and therefore

TUE NITROGEN CYCLE 445

have passed through the metabolic processes of the organ-
ism; (2) those that have been formed because of the
removal of certain atoms by bacteria or enzymes from
compounds, thus necessitating a readjustment of the
remaining atoms and the consequent formation of a new
compound.

Putrefaction is carried on by a large number of forms
of bacteria, the resulting product depending on the sub-
stance in process of decomposition and on the bacteria
involved. Some of the characteristic, although not con-
stant, products formed in the putrefaction of albumin
and proteins are albumoses, peptones, and amino acids,
followed by the formation of cadaverine, putrescine, ska-
tol, and indol. Where an abundant supply of oxygen is
present, or where a sufficient supply of carbohydrates
exist, these substances are not formed. There are many
other products of putrefaction, including a number of
gases, as carbon dioxide, hydrogen sulfide, marsh gas,
phosphine, hydrogen, nitrogen, and the like.

It will be noticed that these changes, like those occur-
ring in the non-nitrogenous organic matter, involve a
breaking-down of the more complex compounds and the
formation of simpler ones; and that a very large number
of bacteria are concerned in the various steps, while even
the same substances may be decomposed and the same
resulting compounds formed by a number of different
species of bacteria.

Present-day knowledge of the subject does not make
it possible to present a list of the bacteria concerned in
each step, or to name all the intermediate products
formed; but for the student of the soil the principal
consideration is a knowledge of the circumstances under
which the nitrogen is made available to plants, and the

446 SOILS: PROPERTIES AND MANAGEMENT

conditions that are likely to result in its loss from the
soil.

366. Ammonification. — Decay and putrefaction may
be considered as the beginning of the process of ammoni-
fication. Ammonification (see Fig. 61), as its name
implies, is that stage of the process during which am-
monia is formed from the intermediate products.

Like the other processes of decomposition, there are
many species of bacteria capable of forming ammonia
from nitrogenous organic substances. Different forms
display different abilities in converting nitrogen of the
same organic material into ammonia, some acting more
rapidly or more thoroughly than others. In tests by
certain investigators in which the same bacteria are used
on different substances, the order of their efficiency is
changed with the change of substance. It seems likely,
therefore, that certain forms are most efficient when
acting on certain organic compounds; that, in other
words, each species is best adapted to ‘the decom-
position of certain substances, while capable of attack-
ing others although less effectively. This characteristic
preference of a class of bacteria for the decomposition of
certain substances is made evident by the experiments
of Sackett,! who found that in some soils dried blood was
ammonified more rapidly than was cottonseed meal, while
in other soils the reverse was true.

367. Bacteria and substances concerned in ammoni-
fication. — Among the bacteria producing ammonifica-
tion are B. mycoides, B. subtilis, B. mesentericus vul-
gatus, B. janthnus, and B. proteus vulgaris. Of these,
B. mycoides has been very carefully studied, and the

1 Sackett, W. G. The Ammonifying Efficiency of Certain
Colorado Soils. Colorado Agr. Exp. Sta., Bul. 184. 1912.

THE NITROGEN CYCLE 447

findings of Marchal’ may be taken as representative
of the process of ammonification. He found that when
this bacterium was seeded on a neutral solution of albumin,
ammonia and carbon dioxide were produced, together
with small amounts of peptone, leucine, tyrosine, and
formic, butyric, and propionic acids. He concludes that
in the process, atmospheric oxygen is used, and that
the carbon of the albumin Is converted into carbon dioxide,
the sulfur into sulfuric acid, and the hydrogen partly
into water, and partly into ammonia by combining
with the nitrogen of the organic substance. He suggests
that a complete decomposition of the albumin occurs
according to the following reaction : —

CrHirz NigdOx + 77 O»
= 29 H,O + 72 CO, “Ts SO; + 18 NH;

The greatest activity occurred at a temperature of 86°
F., and as low as 68° F. action was rather strong. Access
of an increased amount of air, produced by increasing the
surface of the liquid, increased the rate of ammonification.
A slightly acid reaction in the liquid produced the maxi-
mum activity, but in a neutral or even slightly acid me-
dium the process was continued, although much less
actively.

Marchal found that B. mycoides was also capable of
ammonifying casein, fibrin, legumin, glutin, myosin,
serin, peptones, creatine, leucine, tyrosine, and asparagine,
but not urea.

368. Nitrification. — Some agricultural plants can util-
ize ammonium salts as a source of nitrogen. This has

iMarchal, E. Sur la Production de ’Ammoniaque dans
le Sol par les Microbes. Bulletins de Acad. Royale de Belg.,
3 series, Ff, 25, pp. 727-776. 1893.

448 SOILS: PROPERTIES AND MANAGEMENT

been determined for maize, rice, peas, barley, and po-
tatoes. Other plants, such as beets, show a decided
preference for nitrogen in the form of nitrates. Whether
any of the common crops can thrive as well on ammo-
nium salts as on nitrates has not been finally demon-
strated. In most arable soils the transformation of nitro-
gen does not stop with its conversion into ammonia, but
goes on by an oxidation process to the formation of first
nitrous, and then nitric, acids (see Fig. 61). This may be
considered to proceed according to the following equa-
tions : —
2 HNO, + O, = 2 HNO,

The acid in either case combines ‘with one of the bases
of the soil, usually calcium, so that calcium nitrate
results.

Each of these steps is brought about by a distinct
bacterium, but the bacteria are closely, related. Collec-
tively they are called nitrobacteria. Nitrosomonas and
Nitrosococcus are the bacteria concerned in the conver-
sion of ammonia into nitrous acid or nitrites. The former
are supposed to be characteristic of European, and the
latter of American, soils. They are sometimes referred
to as nitrous ferments.

Nitrobacter are those bacteria that convert nitrites
into nitrates. They are also designated nitric ferments.
There seem to be some differences in bacteria from dif-
ferent soils, but the differences are slight and the condi-
tions favoring the actions of the bacteria are similar. It
is also true that the conditions favoring the action of
Nitrosomonas and Nitrobacter are similar, and they
are generally found in the same soils, although some

THE NITROGEN CYCLE 449

experiments show that in the same soil nitrites may
sometimes accumulate, indicating conditions more favor-
able to the development of the Nitrosomonas bacteria.

1) i ad 70 awiuneal
Vrms =
3 (i)
iS
nos . ae - Green” far a Pete
a ee [Ns aut Ctaaure oe
ts eat .. as |
Jf. PAXTON ee LUHOSIS att a Dai a,
ar ‘ pig ee - 7 7 ray
ie Jae sen cana eral te ein’ a wet ty
FIC, Ti Wo -
RS %, ~ btigpspcariany ; ’
~ . ae ~“: Ts Mirates «Nitta 0" PL?

~ . .
we : - Deon SL KFICAT? 10 a Se
’ mre. . --
a

Sm eae seme! cat my mie one hg
.

Fig. 61.—Diagrammatic representation of the movements of nitrogen
between soil, plant, animal, and atmosphere. This has been termed
the nitrogen cycle.

The formation of nitrates usually follows closely on the
production of nitrites, so that there is rarely more than
a trace of the latter to be found in soils. A soil favorable
to the process of nitrification is usually well adapted to
all the processes of nitrogen transformation.

Marked differences have been found in the nitrifying
power of bacteria from different soils. Highly productive
soils have generally been found to contain bacteria having
greater nitrifying efficiency than those from less produc-
tive soils, but this may not always be the case, as other
factors may limit the productiveness.

369. Effect of organic matter on nitrification. — A
peculiarity in the artificial culture of nitrifying bacteria

450 SOILS: PROPERTIES AND MANAGEMENT

is that they cannot be grown in artificial media containing
organic matter. This property for a long time prevented
the isolation and identification of these organisms, as it
was hardly conceivable that organisms living in the dark,
where energy cannot be obtained from sunlight, could
exist without using the energy stored by organic matter.
It has been suggested, in explanation of this, that the
energy produced by the oxidation involved in the process
of nitrification makes possible the growth of the organisms
under these apparently impossible conditions. Some
experimenters report having grown nitrobacteria in or-
ganic media, but it is generally believed at present that
this is not possible and that there has been some error in
the work of these experimenters.

The presence of peptone in the proportion of 500
parts per million completely prevents the development
of nitrobacteria, and one-half that quantity checks it;
while 150 parts of ammonia to the million has a similar
effect. In anormal soil the quantity of soluble ammo-
nium. salts is well below this amount, as must also be that
of soluble organic matter. In confirmation of the inhibit-
ing effect of organic matter on the nitrobacteria, cases
have been reported of soils very rich in organic matter
in which no bacteria of this type exist.

It has also been stated that very heavy manuring
with organic manures results in decreased nitrification
in the soil. While this may be true where farm manure
is used in the quantities sometimes applied in gardening
operations, it is not likely to be the case in soils on which
ordinary field crops are grown. The principle is well
ilustrated by the dry-earth closet. Manure mixed with
earth in relatively small proportions and kept aérated
by occasional mixing undergoes a very thorough decom-

THE NITROGEN CYCLE 451

position of the manure but without any corresponding
increase in nitrates. On the other hand, under field con-
ditions, manure used in relatively small amounts does
not undergo this serious loss.

The application of twenty tons of farm manure to the
acre to sod on a clay loam soil for three consecutive years,
at Cornell University, resulted in a larger production
of nitrates on the manured soil than on a contiguous plat
of similar soil left unmanured. This was true during the
third year of the applications, when the land was in sod,
and also during the fourth year, when no manure was
applied to either plat and when both plats were planted
to corn, as may be seen from the following table : —

Nitrates Propucep on Heaviny Manurep anp on Un-
MANURED Soin

NOs In Parrs to a Minion,
Dry Sor

Twenty tons

manure to the

acre for three
years

Land in wmnothy
April 23.
May 3 .
May 14
May 30
Junel .
June 13.
June 20
July 24
August 14.

Land in maize

May 19

June 22

July 6

July 28

August 10

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452 SOILS: PROPERTIES AND MANAGEMENT

370. Effect of soil aération on nitrification. — Probably
the most potent factor governing nitrification in the soil
is the supply of air. In clay, and even in loam soils, the
tendency to compactness is such as to prevent the pres-
ence of sufficient air to enable nitrification to proceed
as rapidly as desirable unless the soil is well tilled. Col-
umns of soil eight inches in diameter and eight inches in
depth were removed from a field of clay loam on the Cor-
nell University farm, and carried to the greenhouse with-
out disturbing the structure of the soil as it existed in
the field. At the same time, vessels of similar size were
filled with soil dug from a spot near by. These may be
termed unaérated and aérated soils. Both were kept
at the same temperature and moisture content in the
ereenhouse, but no plants were grown on them. The
production of nitrates was as follows : —

Nitrates In Dry Sort, Parts
To THE MILLION
Time or ANALYSIS

Unaerated soil | Aerated soil

When taken from field . . .. . 3.2

3.2
After standing one month . .. . 4.2 17.6
After standing two months... . 9.0 45.6

371. Effect of sod on _ nitrification. — Nitrification
proceeds slowly on sod land, especially if the soil is heavy.
On the same type of soil as that used in the experiment
last described, the average quantities of nitrates for each
month of the growing season in the surface eight inches
of sod land, as compared with maize land under the same
manuring, were as follows ; —

THE NITROGEN CYCLE 453

Nirrates In Dry Sort, Parrs
TO THE MILLION

Monte
Sod land Manze land
Aprl . 2... 2.) le 8.9 —
May . . . 6 6. «© «© «© 2 « 3.0 17.1
June... 2. 1 ew ew we wk 2.4 40.3
July . 2 ew ee we et 4.0 194.0
August . . . . 0. ee ee 5.4 186.7

The amount of nitrogen removed by the maize crop
was greater than that removed by the timothy; conse-
quently the greater amount in the former soil cannot be
due to the effect of the crop.

So far as the conservation of nitrogen is concerned,
sod is an ideal crop, for nitrates are formed very little
faster than they are used, and are not carried off in large
quantities by the drainage water.

In the corn land as much as 175 pounds of nitrate
nitrogen was present in the first twelve inches of one
acre, or fully three times as much as was used by the
crop.

372. Depths at which nitrification takes place. — War-
ington! concluded from his experiments that nitrification
takes place only in the surface six feet of soil. Hall?
has pointed to the fact that no more nitrates were leached
from the 60-inch lysimeter at Rothamsted than from the
one 40 inches deep; which is very good evidence that in

1Warington, R. On the Distribution of the Nitrifying
Organism in the Soil. Trans. Chem. Soc., Vol. 51, p. 118.
1887.

2Hall, A. D. The Book of the Rothamsted Experiments,
p. 230. New York, 1905.

454 SOILS: PROPERTIES AND MANAGEMENT

that particular soil nitrification does not take place below
40 inches from the surface. In more porous soils, how-
ever, nitrification probably extends deeper, especially
in the rich and porous subsoils of arid and semiarid regions.

In all probability, nitrification is largely confined to
the furrow slice, where the opening-up of the soil by til-
lage has provided the necessary air, and where the tem-
perature rises to a point more favorable to the action
of nitrifying bacteria. The results from the aérated and
unaérated soils as shown above represent the differences
that doubtless exist between the furrow slice and the sub-
soil so far as nitrification is concerned.

373. Loss of nitrates from the soit. — Nitrogen hav-
ing been converted into the form of nitric acid, it im-
mediately combines with available bases in the soil,
forming salts, all of which are very easily soluble and
which are carried in solution by the soil water. In a
region of much rainfall, the removal of nitrates in the
drainage water is very rapid. Hall! states that nitrates
formed during the summer or the autumn of one year are
practically all removed from the soil of the Rothamsted
fields before the crops of the following year have advanced
sufficiently to utilize them. It was formerly customary
to fertilize with ammonium salts in autumn, but the
drainage water showed on analysis such a large quantity
of nitrates during the months intervening between the
time of fertilizing and the opening of the growing season
that the practice was discontinued.

In regions of less rainfall or of greater surface evapora-
tion, the loss in this way is less, reaching a minimum in an
arid region when irrigation is not practiced. Under

1Hall, A.D. The Soil, p. 176. New York, 1903.

THE NITROGEN CYCLE 455

such conditions, there is a return of nitrates to the upper
soil as capillary water moves upward to replace evapo-
rated water. In fact, wherever evaporation takes place
to any considerable extent there is some movement of
this kind. The need for catch crops to take up and pre-
serve nitrogen is therefore greater in a humid region than
in an arid or a semiarid one. A system of cropping that
allows the land to stand idle for some time, or a crop that
requires intertillage, as does maize, fails to utilize all the
nitrates produced, and promotes the loss of nitrogen in
drainage water.

374. Nitrate reduction. — The nitrogen-transforming
bacteria thus far studied have been those that cause
the oxidation of nitrogen as the result of their activi-
ties. A number of forms of bacteria that accomplish a
reverse action may now be considered. The several
processes involved are commonly designated by the
general term denitrification, and comprise the follow-
ing: 1, reduction of nitrates to nitrites and ammonia;
2, reduction of nitrates to nitrites, and of these to ele-
mentary nitrogen.

The number of organisms that possess the ability to
accomplish one or more of these processes is very large —
in fact, greater than the number involved in the oxida-
tion processes; but, in spite of their numbers, permanent
loss of nitrogen in ordinary arable soils is unimportant
in amount, although in heaps of barnyard manure it
may be a very serious cause of loss.

Some of the specific bacteria reported as bringing about
nitrate reduction are: B. ramosus and B. pestifer, which
reduce nitrates; B. mycoides, B. subtilis, B. mesentericus
vulgatus, and many other ammonification bacteria which
are capable of converting nitrates into ammonia.

456 SOILS: PROPERTIES AND MANAGEMENT

B. denitrificans alpha and B. denitrificans beta reduce
nitrates with the evolution of gaseous nitrogen.

375. Nitrate-assimilating organisms. — In addition to
the nitrate-reducing bacteria already mentioned, there are
other bacteria which also utilize nitrates; but, like higher
plants, these convert the nitrogen into organic nitrog-
enous substances. However, as they operate in the
dark and cannot obtain energy from sunlight, they must
have organic acids or carbohydrates as a source of energy.
While these bacteria cannot be considered as nitrate
reducers, they help to deplete the supply of nitrates when
conditions are favorable for their development. What
these conditions are is not well understood, nor can any
estimate be made as to the extent of their operations.

376. Denitrification. — The term denitrification may
be used to include both the process of nitrate reduction
and that of nitrate assimilation (see Fig. 61).

Most of the denitrifying bacteria perform their func-
tions only under a limited amount of oxygen, while others
can operate in the presence of a more liberal supply;
but, m general, thorough aération of the soil practically
prevents denitrification. Straw apparently carries an
abundant supply of denitrifying organisms, and also
furnishes a supply of carbohydrates which favor their
action; so that stable manure is very likely to undergo
denitrification, and straw or coarse stable manure are
conducive to the growth of denitrifying bacteria in the soil.

Under ordinary farm conditions, denitrification is
of no significance in the soil where proper drainage and
good tillage are practiced. Warington! showed that if

1 Warington, R. Investigations at Rothamsted Experi-
mental Station. U.S. D. A., Office of Exp. Sta., Bul. 8, p. 64.
1892.

THE NITROGEN CYCLE 457

an arable soil is kept saturated with water to the exclu-
sion of air, nitrates added to the soil are decomposed,
with the evolution of nitrogen gas. As lack of drainage
is usually most pronounced in early spring, when the soil
is likely to be depleted of nitrates, it is not likely that
much loss arises in this way unless a nitrate fertilizer has
been added. Among the many difficulties arising from
poor drainage, denitrification of an expensive fertilizer
may be a very considerable item.

The addition of a nitrate fertilizer to a well-drained soil
receiving stable manure is not likely to result in a loss of ni-
trates unless the dressings of manure have been extremely
heavy. Hall* states that at Rothamsted, where large quan-
tities of nitrate of soda are used every year in connection
with annual dressings of farm manure, the nitrate produces
nearly as large an increase when added to the manured
as when added to the unmanured plat. In other words,
there appears to be no loss of nitrate by denitrification.

It is possible to reach a point in manuring at which
denitrification may take place. Market-gardeners some-
times reach this point, when fifty tons or more of farm
manure, in addition to a nitrate fertilizer, are added to
the soil. Plowing under heavy crops of green manure
may produce the same result. In either case, the best
way to overcome the difficulty is to allow the organic
matter to partly decompose before adding the fertilizer.
The removal of the easily decomposable carbohydrates
needed by the denitrifying organisms decreases or pre-
cludes their activity.
~ 377. Nitrogen fixation through symbiosis with higher
plants. —It has long been recognized by farmers that

1 Hall, A. D. The Book of the Rothamsted Experiments,
pp. 114-115. New York, 1905.

458 SOILS: PROPERTIES AND MANAGEMENT

certain crops, as clover, alfalfa, peas, beans, and some
others, improve the soil, making it possible to grow larger
crops of cereals after these crops have been on the land.
Within the past century the benefit has been traced to
an increase in the nitrogen content of the soil, and the
specific plants so affecting the soil were found to be, with
a few exceptions, those belonging to the family of legumes.
It has furthermore been demonstrated that under certain
conditions these plants utilize the uncombined nitrogen of
the atmosphere (see Fig. 61), and that they contain,
both in the aérial portions and in the roots, a very high
percentage of nitrogen. In consequence, the decomposi-
tion of even the roots of the plants in the ‘soil leaves a
large amount of nitrogenous matter.

378. Relation of bacteria to nodules on roots. — It has
also been shown that the utilization of atmospheric nitro-
gen is accomplished through the aid of certain bacteria
that live in nodules (tubercles) on the roots of the plants.
These bacteria take free nitrogen from the air in the soil,
and the host plant secures it in some form from the bac-
teria or their products. The presence of a certain species
of bacteria is necessary for the formation of tubercles.
Leguminous plants grown in cultures or in soil not con-
taining the necessary bacteria do not form nodules and do
not utilize atmospheric nitrogen, the result being that
the crop produced is less in amount and the percentage
of nitrogen in the crop is less than if nodules were formed.

The nodules are not normally a part of leguminous
plants, but are evidently caused by some irritation of the
root surface, much as a gall is caused to develop on a leaf
or a branch of a tree by an insect. In a culture contain-
ing the proper bacteria, the prick of a needle on the root
surface will cause a nodule to form in the course of a few

THE NITROGEN CYCLE 459

days. The entrance of the organism is effected through
a, root-hair which it penetrates, and it may be seen as a
filament extending the entire length of the hair and into
the cells of the cortex of the root, where the growth of
the tubercle starts.

Even where the causative bacteria occur in cultures
or in the soil, a leguminous plant may not secure any
atmospheric nitrogen, or perhaps only a small quantity,
if there is an abundant supply of readily available com-
bined nitrogen on which the plant may draw. The bac-
teria have the ability to utilize combined nitrogen as
well as uncombined nitrogen, and prefer to have it in
the former condition. On soils rich in nitrogen, legumes
may therefore add little or no nitrogen to the soil; while
in properly inoculated soils deficient in nitrogen an impor-
tant gain of nitrogen results.

While B. radicicola is considered the organism common
to all leguminous plants, it is now known that the organ-
isms from one species of legume are not equally well adapted
to the production of tubercles on each of the other species
of legumes. They show greater activity on some species
than on others, but do not develop so successfully on all
species as on the one from which the organisms were
taken. It was rather generally believed at one time that
the longer any species of legume is in contact with the
organisms from another species, the more active this
species becomes and the greater is the utilization of
atmospheric nitrogen. Considerable doubt has been cast
on this view in recent years, and it is now generally con-
ceded that the bacteria of certain legumes are not capable
of inoculating certain other species of legumes.

379. Transfer of nitrogen to the plant.—It has been
shown by several investigators that bacteria from the

460 SOILS: PROPERTIES AND MANAGEMENT

nodules of legumes are able to fix atmospheric nitrogen
even when not associated with leguminous plants. There
would seem to be no doubt, therefore, that the fixation of
nitrogen in the tubercles of legumes is accomplished di-
rectly by this organism, not by the plant itself nor through
any combination of the plant and the organism — though
both of these hypotheses have been advanced. The part
played by the plant is doubtless to furnish the carbohydrates
which are required in large quantities by all nitrogen-fixing
organisms and which the legumes are able to supply in
large amounts. The utilization of large quantities of
carbohydrates by the nitrogen-fixing bacteria in the tuber-
cles may also account for the small proportion of non-
nitrogenous organic matter in the plants.

How the plant absorbs this nitrogen after it has been
secured by the bacteria is less well understood. Early
in the growth of the tubercle, a mucilaginous substance
is produced, which permeates the tissues of the plant in
the form of long, slender threads containing the bacteria.
These threads develop by branching or budding, and form
what have been called Y and T forms, known as bac-
teroids, which are peculiar to these bacteria. The threads
finally disappear, and the bacteria diffuse themselves more
or less through the tissues of the root. What part the
bacteroids play in the transfer of nitrogen is not known.
It has been suggested that in this form the nitrogen is
absorbed by the tissues of the plant. It seems quite likely
that the nitrogen compounds produced within the bacteria
cells are diffused through the cell wall and absorbed by
the plant.

380. Soil inoculation for legumes. — Immediately fol-
lowing the discovery of the nitrogen-fixing bacteria, the
possibility was conceived of securing a better growth of

THE NITROGEN CYCLE 461

leguminous crops on soils not having previously grown
such crops successfully. Extensive experiments showed
the practicability of inoculating land for a certain legumi-
nous crop by spreading on its surface soil from a field
on which the same crop is successfully growing. It is
manifestly much better to apply-the organisms from a
certain species of legumes from a field having grown the
same species, than to attempt to use organisms from an-
other species of legumes. The fact that soil inoculation
by means of soil from other fields may possibly transmit
weed seeds and fungous diseases, and also necessitates
the transportation of a great bulk and weight of material,
has led to numerous efforts to inoculate soil by means
of pure cultures. The pure culture may also make it
possible to bring to the soil bacteria of greater physio-
logical efficiency than those already there.

The first attempt at moculation by pure cultures
was made in Germany, the cultures being sold under the
name of “nitragin.” Careful experiments made with
this material previous to the year 1900 did not show
it to be very efficient; but in recent years improvements
in the method of manipulating the cultures have resulted
in much greater success. In “nitragin” the medium
used for growing the organisms is gelatin, and before use
this was formerly dissolved in water; but now a solution
of greater density is used in order to prevent a change of
osmotic pressure, which may cause plasmolysis and result
in the destruction of the bacteria.

Within recent years a number of cultures for soil
inoculation have been offered to the public. The first
of these utilized absorbent cotton to transmit the bac-
teria in a dry state from the pure culture in the laboratory
to the user of the culture, who was to prepare therefrom

462 SOILS: PROPERTIES AND MANAGEMENT

another culture to be used for inoculating the soil. Care-
ful investigation of this method showed that its weakness
lay in drying the cultures on the absorbent cotton, which
frequently resulted in the death of the organisms. More
recently, liquid cultures have been placed on the market
in this country, and these have, in the main, proved to
be more successful, notably those sent out by the United
States Department of Agriculture. Another very suc-
cessful culture medium, now being distributed by the
Department of Plant Physiology at Cornell University, is
steamed soil. The process of steaming under a pressure
of two or three atmospheres increases greatly the solu-
bility of both organic and inorganic matter, and produces
a medium highly favorable to the development of the
organisms isolated from the nodules of legumes.

Liquid cultures for legume inoculation have now been
prepared and distributed by the United States Depart-
ment of Agriculture for seven years, and during this time
a record has been kept of the results so far as it has been
possible to do this. These are summarized by Keller-
man! as follows: average percentage of success, 76;
average percentage of failure, 24. If, however, the doubt-
ful reports are included with the failures, the percentage
of success is reduced to 38, Kellerman states as his
opinion that moculation with pure liquid cultures is as
certain a means of infection as is inoculation with soil
from fields on which legumes have been successfully grown
for extended periods, if the soil to be infected is one well
adapted to the leguminous crop; but on soils not well
suited to legumes, the use of soil from old fields is a much
more satisfactory medium with which to attempt inocula-

1 Kellerman, K. F. The Present Status of Soil Inoculation.
Centrlb. f. Bakt., II, Band 34, Seite 42-50. 1912.

THE NITROGEN CYCLE 463

tion. It is only a question of time until a successful
method of inoculating soil from artificial cultures will be
found. In the meantime, inoculation by means of in-
fested soil is the most practical method.

381. Nitrogen fixation without symbiosis with higher
plants. — If a soil is allowed to stand idle, either without
vegetation or in grass, it will, under favorable moisture
conditions in the northern states, accumulate in one or two
years an appreciable amount of nitrogen not present at the
beginning of the period. At the Rothamsted Experiment
Station, one of the fields in volunteer plants, consisting
mainly of grass without legumes, gained in the course of
twenty years about twenty-five pounds of nitrogen per
acre annually.1. According to Hall, the nitrogen brought
down by rain would account for about five pounds to the
acre per annum, and dust, bird droppings, and the like, for
a little more.

382. Nitrogen-fixing organisms.— Direct experiment
has shown that certain bacteria have the ability to utilize
atmospheric nitrogen and to leave it in the soil in a com-
bined form (see Fig. 61). An anaérobic bacillus — Clos-
iridium pasteurianum — was first found to produce this
result. Later, a commercial culture called “ alinit ” was
placed on the market in Germany, claimed to contain
Bacterium ellenbachensis, with which the soil was to be
inoculated, and it was claimed that a large fixation of
atmospheric nitrogen would result. A number of tests of
this material failed to show that it caused any marked
fixation of atmospheric nitrogen.

A number of other nitrogen-fixing organisms have
since been discovered. There are: (1) several members

1Hall, A. D. On the Accumulation of Fertility by Land
Allowed to Run Wild. Jour. Agr. Sci., Vol. 1, p. 241 1905.

464 SOILS: PROPERTIES AND MANAGEMENT

of the group designated Azotobacter, which are aérobic
bacteria, and which some investigators hold to be capable of
fixing atmospheric nitrogen when grown in pure cultures,
while others believe them to be able to do so, at least in
large amounts, only in the presence of certain other
organisms; (2) members of the Granulobacter group,
which are large spore-bearing bacilli of anaérobic habits;
(3) Bacillus radiobacter, which appear to be closely related
to or identical with the B. radicicola of legume tubercles.
The last-named has been shown to beable to fix atmospheric
nitrogen even when not growing in symbiosis with leg-
umes.

There are doubtless many other nitrogen-fixing or-
ganisms still to be discovered.

A peculiarity of these nitrogen-fixing organisms is
their use of carbohydrates, which they decompose in
the process of nitrogen fixation. They secure more
atmospheric nitrogen when in a nitrogen-free medium.
The presence of soluble lime or magnesium salts, especially
carbonates, is necessary for the best performance of the
nitrogen-fixing function, as is also the presence of a some-
what easily soluble form of phosphorus. The organisms
are exceedingly sensitive to an acid condition of the soil.

383. Mixed cultures of nitrogen-fixing organisms. —
Mixed cultures of the various organisms mentioned fix
larger amnounts of nitrogen than do the pure cultures
of any one of them, while some forms are incapable of
fixing nitrogen in pure cultures. Certain alge, particularly
the blue-green alge, aid greatly in promoting growth and
nitrogen fixation by these organisms. This they probably
do by producing carbohydrates, which are used by the
bacteria as a source of energy for nitrogen fixation, the
bacteria furnishing the algee with nitrogenous compounds,

THE NITROGEN CYCLE 465

To what extent the relation is symbiotic is not known at
present, but it seems probable that a relation may exist
similar to that between leguminous plants and the nitrogen-
gathering bacteria in their nodules.

384. Nitrogen fixation and denitrification antagonistic.
— Nitrogen fixation and denitrification are reverse pro-
cesses. The former is, for most bacteria, favored by
an abundant supply of air and a moderately high tempera-
ture. Thus, at 75° F. fixation was rapid, at 59° F. it was
decreased, and at 44° F. there was no fixation. Denitri-
fication is favored by a somewhat limited supply of
oxygen.

There is no reason to believe that the practical impor-
tance of nitrogen fixation without legumes is equal, under
the most favorable conditions, to that with legumes.
A further knowledge of the organisms effecting fixation
and of their habits will doubtless make possible a greater
utilization of their powers to supplement the use of leg-
umes as a source of combined nitrogen in the soil.

TREATMENT OF SOILS WITH VOLATILE ANTISEPTICS AND
WITH HEAT

Attention was first drawn to the effects of carbon bisul-
fide on the soil in a paper by Girard ! and one by Oberlin?
which appeared in 1894. Girard noticed that soil treated
with carbon bisulfide for the purpose of combating a para-
sitic disease of sugar-beet was more productive than it

1 Girard, A. Recherches sur l’Augmentation des Récoltes
par l’Injection dans le Sol du Sulfure de Carbone 4 Doses Mas-
sives. Bul. Soc. Nationale d’Agric., Tome 54, p. 356. 1894.

2 Oberlin. Bodenmiidigkeit und Schwefelkohlenstoff. Mainz,

894.

466 SOILS: PROPERTIES AND MANAGEMENT

was before such treatment. The beneficial effect of the
treatment extended to the second year.

Oberlin found a somewhat similar condition where
the soil of vineyards treated with carbon bisulfide to kill
phylloxera showed greatly increased productiveness after
the treatment. The effect of carbon bisulfide on the
vineyard soil was to make it possible to raise grapes con-
tinually on the same land, whereas it had previously been
necessary to rest the land by growing a succession of
other crops at intervals of several years. It was noticed,
however, that immediately after treatment the plants did
not grow so well as under normal conditions. Systematic
investigations of the subject then began, and as early as
1895 Pagnoul! reported that when carbon bisulfide is
applied to soils nitrification is temporarily depressed.

Investigation of the effect of heat on soil had begun
somewhat earlier, when Frank? showed in 1888 that it
increases the quantities of soluble matter, both organic
and inorganic, as well as causing the soil to be more pro-
ductive.

The subject has been investigated by a large number of
persons, and in addition to carbon bisulfide a considerable
number of other volatile antiseptics, including ether,
chloroform, and toluene, have been found to influence the
productiveness of soils. The effect of heat, particularly
in steam, at various temperatures from slightly above
normal to more than 200° C., has also been studied, while

1Pagnoul, M. Nouvelles Recherches sur les Transforma~
tions que Subit l’Azote dans le Sol. Annales Agronomique,
Tome 21, pp. 497-501. 1895.

*Frank, B. Ueber den Einfluss welchen das Sterilisiren
des Erdbodens auf die Pflanzen Entwickelung ausiibt. Ber.
d. Deut. Bot. Gesell. (Generalversammlungs Heft) Band 4,
Seite 87-97. 1888.

THE NITROGEN CYCLE 467

it has been found that the mere drying of soils effects
important changes in their solubility and in the bacterial
processes that occur in them. As the result of the in-
vestigations, certain well-established facts have been
worked out in connection with certain treatments when
applied to most souls.

385. Effects of carbon bisulfide and heat on properties
of soils. — Volatile antiseptics usually increase the pro-
ductiveness of soils, although there may be at first a slight
temporary retardation of plant growth. It is of course
customary to permit the antiseptic to volatilize from
the soil before seed is planted. For this purpose the soil
is spread out in a thin layer, in which condition it is al-
lowed to remain until the odor of the antiseptic has dis-
appeared. The soil is then placed in vessels and moistened
and the seeds are planted in it.

Other characteristic effects of treatment with volatile
antiseptics reported by different investigators are: (1)
an initial decrease in the numbers of bacteria, followed by
a long-continued increase; (2) a disturbance of the equi-
librium of the bacteria, by which certain types multiply
more rapidly than others; (8) a slight initial mcrease
in ammonia content, followed by a considerable increase
in the rate of production of ammonia; (4) depression of
the process by which ammonia is converted into nitric
acid, and a very slow recovery in the activity of the bac-
teria concerned, as a result of which ammonia accumulates
in the soil; (5) an increase in the rate at which oxidation
takes place in soils; (6) destruction of protozoa.

386. Hypotheses to account for effects of carbon
bisulfide and of heat. — A number of hypotheses have
been formulated by which to account for the increased
plant growth and for changes induced in soils by treat-

468 SOILS: PROPERTIES AND MANAGEMENT

ment with heat and volatile antiseptics. A number of
these theories will be mentioned, but it should be remem-
bered that much important work on the subject has been
done by investigators who have not advanced any hy-
potheses.

387. Koch’s theory. — Koch! was the first to offer
any explanation. In 1899 he stated it as his opinion that
carbon bisulfide has a directly stimulating action on the
plants themselves. He later? found ether to have a
similar action, and continued his experiments with carbon
bisulfide. He found that soil sterilized with heat pro-
duced better crops when treated with carbon bisulfide
than when not so treated, and concludes that the effect
of the antiseptic, therefore, cannot be due to the effect
of the antiseptic on bacteria. He also experimented with
field soils, and showed that the size of the crop on treated
soils is not proportional to the quantity of nitrogen
contained.

The theory of Koch has been supported by Fred,? who
fertilized soils with an abundant supply of sodium nitrate
and found that in every case in which carbon bisulfide
was added the growth and yield of crop were much su-
perior to those in the corresponding pots not treated with
that substance. He concludes that as there was no lack
of plant-food and other conditions favorable to plant

1Koch, A. Untersuchungen tiber die Ursachen der Riiben-
miidigkeit mit Besonderes Beriicksichtigung der Schwefel-
kohlenstoffbehandlung. Arb. Deut. Landw. Gesell., Heft 40,
Seite 7-38. 1899.

2 Koch, A. Ueber die Wirkung von Aether Schwefelkoh-
lenstoff auf Héhere und Niedere Pflanzen. Cenirlb. f. Bakt.,
II, Band 31, Seite 175-185. 1911-1912.

3Fred, H. B. Effect of Fresh and Well-rotted Manure

on Plant Growth. Virginia Poly. Inst. Agr. Exp. Sta., Ann.
Rept. 1909-1910, pp. 142-159.

THE NITROGEN CYCLE 469

growth, the effect of the antiseptic must have been directly
on the plants.

388. Hiltner and Stérmer’s theory. — According to
Hiltner and Stormer, the effect of treatment with carbon
bisulfide is to cause a disturbance in the equilibrium of
the different forms of soil bacteria. These investigators
compared the numbers in three groups of bacteria that
developed on gelatin plates inoculated from soil infu-
sions. The groups were Streptothrix, liquefiers, and
non-liquefiers. The normal relation of these in the soil
with which they worked was 20 per cent Streptothrix,
5 per cent liquefiers, and 70 per cent non-liquefiers. After
treatment with carbon bisulfide the relative proportions
were 5 per cent, 10 per cent, and 85 per cent, respectively.
From 70 to 75 per cent of the whole number of bacteria
were destroyed by the treatment, but the numbers rapidly
increased after treatment, rising in a few weeks to 50,-
000,000 to a gram in a soil that contained 10,000,000 to a
gram before treatment. This increase is due largely to
the development of the non-liquefiers, the Streptothrix
remaining at about the same actual number.

The fact that the equilibrium of the bacterial flora
was so greatly disturbed by the treatment with carbon
bisulfide led Hiltner and Stérmer to believe that the greater
productiveness of the soil after treatment is due to the
greater effectiveness of the surviving and rapidly develop-
ing forms in rendering available the supply of plant

1 Hiltner, L., and Stérmer, K. Studien iiber die Bakteri-
enflora des Ackerbodens, mit besonderer Beriicksichtigung
ihres Verhaltens nach einer Behandlung mit Schwefelkohlenstoff
und nach Brache. Arb. Biol. Abt. f. Land- u. Forstwirtschaft
am. Kaiserl. Ges. Amt., Band III. Heft 5. Berlin, 1903. Ab-
stract in Centrlb. f. Agrikultur Chemie, 33 Jahrg., Seite 361-
374. 1904.

470 SOILS: PROPERTIES AND MANAGEMENT

nutrients in the soil, and to a decrease in the number of
denitrifying bacteria, which obviates loss of available
nitrogen through their action.

Heinze,! working with soils treated with carbon bisul-
fide, and Pfeiffer, Frank, Friedlander, and Ehrenberg,
working with steamed soils, found that there was a large
fixation of nitrogen following these treatments. They
conclude that this is at least partly responsible for the
greater productiveness of the soils after the treatments
mentioned.

389. Russell and Hutchinson’s theory. — The next
comprehensive theory to be brought forward was one by
Russell and Hutchinson, who account for the increased
productiveness of soils partially sterilized, either by heat
or by volatile antiseptics, as due to the use by plants of
the ammonia, which, as had been shown by previous
investigators, accumulated in soils so treated by reason
of the stimulation given to the process of ammonification
and the depression of nitrification. They hold, further-
more, that the stimulation of ammonification is brought
about by the greatly increased numbers of bacteria in
the soil following the destruction of some larger organisms,
probably protozoa or allied forms, that normally interfere
with the activities of the ammonifying bacteria. Care-
ful experiments by these investigators have shown that
there is a much larger quantity of nitrogen in the combined
forms of ammonia and nitrates in partially sterilized

1Heinze, B. Hine Weitere Mitteilungen tiber den Schwefel-
kohlenstoff und die CS.-Behandlung des Bodens. Centrlb.
f. Bakt., IT, Band 18, Seite 56-74, 246-264, 462-470, 624-634,
790~798. 1907.

2 Pfeiffer, Th., Frank, L., Friedlander, K., and Ehrenberg,
P. Der Stickstoffhaushalt des Ackerbodens. Mitt. d. Landw.
Inst. d. Kénigl. Univ. Breslau, Band 4, Seite 715-851. 1909.

THE NITROGEN CYCLE 471]

soils than in untreated soils. There can be no doubt,
therefore, that, at least for some higher plants, the quan-
tity of available nitrogen is greater in the treated soils.

The relation of protozoa to the ammonifying bacteria
is somewhat more difficult of demonstration. Methods
for the enumeration of protozoa in the soil are not suffi-
ciently well worked out to admit of an entirely satisfactory
study of their relation to the ammonifying bacteria.
However, Russell and Hutchinson do not hold that pro-
tozoa are necessarily the limiting factor in ammonia
production in normal soils, but grant that some other
organism of comparatively large size may be responsible
for this. They intimate also that not only the available
nitrogen, but also the quantities of other plant nutrients,
are limited by organisms destroyed by partial steriliza-
tion; otherwise increased productiveness induced by
partial sterilization would be confined to soils in which
nitrogen is normally the limiting factor. The theory
does imply, however, that plant-food is the limiting factor
in all soils benefited by partial sterilization under the
conditions of the experiment.!

1 Russell, BE. J., and Darbishire, F. V. Oxidation in soils
and its relation to productiveness. Part 2. The influence
of partial sterilization. Jour. Agr. Sci., Vol. 2, pp. 305-326.
1907.

Russell, E. J., and Hutchinson, H. B. The effect of partial
sterilization of soil on the production of plant food. Jour.
Agr. Scei., Vol. 3, pp. 111-144. 1909.

Russell, E. J., and Hutchinson, H. B. The effect of partial
sterilization of soil on the production of plant food. Part 2.

Russell, E. J., and Hutchinson, H. B. Thelimitation of bac-
terial numbers in normal soils and its consequences. Jour. Agr.
Sci., Vol. 5, pp. 152-221. 1903.

Buddin. W. Partial sterilization of soil by volatile and
non-volatile antiseptics. Jour. Agr. Sci., Vol. 6, pp. 417-451.
1914.

472 SOILS: PROPERTIES AND MANAGEMENT

Some typical results of investigations by Russell and
Hutchinson on the effect of partial sterilization on bac-
teria numbers, ammonia production, and presence of
protozoa are given below: —

NITROGEN
BactTERIA AS NH3 anp
APrER Stxry- | NO; aArrer DeErRIi-

BlcHt Days, |Sixry-nigut| MENTAL PROTOZOA
Tro A GRAM or |Days, Parts} Facror OUND
Dry Som [toa Minion
or Dry Sori
Ciliates
Untreated soil . .| 11,100,000 13.0 | Present |, Amoeba
Monads

Ciliates

Soil heated to 40° ° -
7,900,000 14.4 Present |< Amoeba
for three hours Monads

Soil heated to eC 37,500,000 | 36.7 | Killed | All killed

for three hours

390. Greig-Smith’s theory.— An entirely different
explanation of the effect of partial sterilization on soils
has been advanced by Greig-Smith.! He states that
when disinfectants are applied to the soil their action is
a double one. They kill the less resistant bacteria, and
dissolve from the surfaces of the soil particles a waxy
covering, to which he has given the name “ agricere.”’
The surviving bacteria, among which are the beneficial
ones, are able to develop more rapidly because of the
greater accessibility of the food supply which the re-
moval of the “ agricere”’ has exposed.

Greig-Smith holds that heat destroys substances toxic

1Greig-Smith, R. The Bacteriotoxins and the ‘‘Agricere”’
of Soils. Centrlb. f. Bakt., IT, Band 30, Seite 154-156. 1911.

THE NITROGEN CYCLE 473

to bacteria, and also certain of the less resistant bacteria,
thus permitting the more resistant species to multiply
very rapidly owing to the absence of the bacteriotoxins.

In order to ascertain whether chloroform has any effect
other than the destruction of protozoa, Greig-Smith
applied it to soil previously heated to 62° C. (which he
had found was sufficient to kill all protozoa), and then
determined the number of bacteria in untreated soil, in
heated soil, and in soil heated and treated with chloro-
form. The counts to a gram of soil were made at inter-
vals, and are shown below : !—

At
SrTarr

4 Days 12 Days 25 Days 39 Days

csetnmnnmernennanened Uunemimracimemianeninienpenntanemniiomstionntasenemnnn’l Renpmiunsanmnenammemmnranareen tame emrteareee een’ Ranemmmenenanmnenmaremneemeasemanauneamuanl Comes nance amaeaamarneniaeunasammemeed

Untreated soil! 52 680,000; 2,700,000) 4,300,000} 5,400,000
Soil heated
at 62° C. 16 | 15,800,000} 11,800,000; 9,000,000} 8,000,000
Soil heated
at 62° C.
and treated
with chlo-
roform .| 13 | 24,600,000! 45,400,000} 41,600,000) 90,000,000

Greig-Smith concludes that as the bacteria developed
more rapidly in the soil treated with chloroform after
heating than in the soil which was only heated and in
which the protozoa were presumably dead, the chloro-
form must have exerted some beneficial effect other than
the destruction of protozoa, and assumes that this is due
to the removal of “ agricere.”

Partial or complete sterilization of soils has been prac-

1Greig-Smith, R. Contributions to our Knowledge of Soil
Fertility. Proc. Linnean Soc. New South Wales, 1912, Part IT,
pp. 238-248.

474 SOILS: PROPERTIES AND MANAGEMENT

ticed in greenhouses for a long time, principally for the
purpose of combating plant diseases. Its value in in-
creasing productiveness has been a consideration since
this phase of the subject has been emphasized by investi-
gations, and the treatment of “ sewage-sick”’ soils has
been shown by Russell and Golding! to be a practical
matter. It is as a means of studying the principles of
soil fertility, however, that the investigation of the sub-
ject of partial sterilization of the soil is of greatest im-
portance.

1 Russell, EH. J., and Golding, J. Investigations on ‘“‘sick-
ness’? in soil. Part 1. ‘‘Sewage sickness.” Jour. Agr. Sci.,
Vol. 5, pp. 27-47. 1912.

Russell, H. J., and Golding, J. Investigations on ‘‘sickness”’
in soil. Part 2. ‘‘Sickness’’ in glasshouse soils. Jour. Agr.
Sei., Vol. 5, pp. 86-111. 1912.

CHAPTER XXII
THE SOIL AIR

Tue air of the soil is merely a continuation of the
atmospheric air into the interstitial spaces of the soil,
when these are not filled with water. As it is more or
less inclosed by the soil, movement does not take place
so readily as it does above the surface of the ground and
hence the soil air is more greatly influenced by its sur-
roundings than is atmospheric air. This leads to impor-
tant differences in composition between the atmospheric
air and soil air, the composition of the latter depending
on a variety of conditions in which physical, chemical,
and biological properties play a part.

FACTORS THAT DETERMINE VOLUME

The amount of air that soils contain varies with their
properties, and in any one soil the air content varies with
certain changes to which the soil is subject from time to
time. The factors that influence the volume of air in
soils are: (1) texture; (2) structure; (3) organic matter ;
(4) moisture content.

391. Texture. — The size of the soil particles affects
the air capacity of the soil in exactly the same way
as it does the pore space, since in dry soil they are
identical. A fine-textured soil in a dry condition would

therefore contain as large a volume of air as would a
476

476 SOILS: PROPERTIES AND MANAGEMENT

coarse-textured soil, provided the particles were spherical
and all of the same size. Under the conditions actually
existing in the field, the soils composed of small particles
generally possess the larger amount of air space.

392. Structure.— The volume of air in a water-free
soil being identical with the pore space, the formation
of aggregates of particles is favorable to a large air volume.
The volume of air in any soil, therefore, changes from
time to time; and particularly is this true of a fine-
grained soil, in which the changes in structure are greater
than in a soil with large particles. A change in sgoil
structure may greatly alter the volume of air contained
by changing the pore space, thereby influencing the pro-
ductiveness. Clay is affected to the greatest extent in
this way.

393. Organic matter. Since organic matter is more
porous than mineral particles of any size or arrangement,
the effect of that constituent is always to increase the
volume of air. While this is generally beneficial in a
humid region, it 1s often very Injurious in an arid region.
Unless sufficient water falls on the soil to wash the soil
particles around the organic matter and to maintain a
supply sufficient to promote decomposition, the presence
of vegetable matter leaves the soil so open that the capil-
lary rise of moisture is interfered with, and the consider-
able movement of air keeps the soil dry, with the result
that the portion of the soil layer mixed with and lying
above the organic matter is too dry to germinate seeds
or to support plant growth.

394. Moisture content. — It is quite evident that the
larger the proportion of the interstitial space filled with
water, the smaller will be the quantity of air contained.
This does not necessarily mean that the higher the per-

THE SOIL AIR 477

centage of water in the soil, the smaller will be the volume
of air, since the amount of pore space determines both the
water and the air capacity. A soil with 30 per cent
moisture may contain more air than one with a water
content of 20 per cent, because of the tendency of mois-
ture to move the soil particles farther apart.

In soils in the field, the average diameter of the cross
section of the pore space is the most potent factor in
determining the volume of air. Small spaces are likely
to hold water, while larger spaces, not retaining water
against gravity, are filled with air.

In a clay soil the volume of air is increased, other
things being equal, by the formation of granules, and is
decreased by deflocculation or compaction. The volume
of air in any soil may be calculated from the following
formula :—

% air space = % pore space — (% H,O X ap. sp. gr.)

COMPOSITION OF SOIL AIR

The air of the soil differs from that of the outside
atmosphere in that it contains more water vapor, a much
larger proportion of carbon dioxide, a correspondingly
smaller amount of oxygen, and slightly larger quantities
of other gases, including ammonia, methane, hydrogen
sulfide, and the like, formed by the decomposition of
organic matter.

395. Analyses of soil air.— The composition of the
air of several soils, as determined by Boussingault and
Lewy, is quoted by Johnson ! in the table following : —

1 Johnson, 8. W. How Crops Feed, p. 219. New York, 1891.

478 SOILS: PROPERTIES AND MANAGEMENT

VoLuME IN OND
Acre or Sort To | Composirion oF 100 Parrs
Depra or 14 or Sor, Air BY VoLtumE
CHARACTER INCHES
oF Soin

. Carbon
(ou. Fe) (Cotes see Oxygen | Nitrogen

nine peaamatrreeceertnnnnnimenem | ttemaiacrmemeemnintnisiie ] Raee—ritievee$ | Tmmininitimememuanissientteninn | wtinnrmmtersrsTer—TTrertNR

Sandy subsoil of forest .| 4,416 14| 0.24 | —— |; ——
Loamy subsoil of forest .| 3,530 28! 0.79 | 19.66 | 79.55
Surface soil of forest . .| 5,891 57 | 0.87 | 19.61 | 79.52
Clay soil . . . . ..
Soil of asparagus bed not

manured for one year . | 11,182 86 | 0.74 | 19.02 | 80.24
Soil of asparagus bed

freshly manured . .j11,182|) 172) 1.54 | 18.80 | 79.66
Sandy soil, six days after
manuring . 11,783 | 257| 2.21 | —— | ——

Sandy soil, ten days after

manuring (three days

of rain) . . . . .{11,7838 | 1,144} 9.74 | 10.385 | 79.91
Vegetable mold compost | 21,049 | 772) 3.64 | 16.45 | 79.91

There are several factors that influence the composi-
tion of the soil air, those of greatest importance being
the production and escape of carbon dioxide.

396. Sources of carbon dioxide in soil air. — The
presence of carbon dioxide in soils is due in small part
to infiltration from the atmospheric air, there being a
tendency for the carbon dioxide, which is heavier than
oxygen and nitrogen, to settle out. It may also have a
purely chemical origin. But in much greater measure
is the carbon dioxide a product of biological processes
that occur in the soil. At one time it was believed that
the formation of carbon dioxide in soils was a purely
chemical process of oxidation, and possibly a part of the
gas is formed in that way. It has already been seen that
there is a condensation of gases in the manifold pores

THE SOIL AIR 4AT9

of the soil (see par. 268), the organic portion of which is
especially capable of condensing gases. Oxygen con-
densed on the surface of this organic matter would, in
the words of Johnson, “ spend itself in chemical action,”
of which carbon dioxide would be the result.

There is now no doubt, however, that biological pro-
cesses are largely responsible for the occurrence of the
large quantity of carbon dioxide in the soil air. There
are two distinct processes involved: (1) the physiological
action of bacteria by which they absorb oxygen and give
off carbon dioxide, and (2) the excretion of carbon dioxide
by plant roots. The extent to which carbon dioxide is
produced in normal soils in these two ways has been es-
timated by Stoklasa,? who has done much work on the
subject. He concludes that the microdrganisms in
an acre of soil to a depth of four feet may produce between
sixty-five and seventy pounds of carbon dioxide a day
for two hundred days in the year, and that during the
growing period the roots of oats or wheat would give
off nearly as much to an acre.

397. Production of carbon dioxide as affecting com-
position. — Although the formation of carbon dioxide
in the soil depends on the decomposition of organic
matter, it is not always proportional to the quantity
of organic matter present. The rate of decomposition
varies greatly, and where this is depressed, as is sometimes
seen in muck or forest soils, the content of carbon dioxide
is relatively low. A high percentage of organic matter

1 Johnson, 8. W. How Crops Feed, p. 218. New York,
1891.

2 Stoklasa, J. Ueber den Ursprung die Menge und die
Bedeutung des Kohlendioxids im Boden. Centrlb. f. Bakt., II,
Band 14, Seite 723-736. 1905.

480 soInS: PROPERTIES AND MANAGEMENT

is in itself likely to prevent a proportional formation of
carbon dioxide, since the accumulation of the gas may
inhibit further activity of the decomposing organisms.

Ramann ! states that the percentage of carbon dioxide
in the soil air has the following relations : —

1. The carbon dioxide increases with the depth.

2. In general the percentage of carbon dioxide rises
and falls with the temperature, being higher in the warm
months and lower in the cold months.

3. Changes in temperature and air pressure change the
percentage of carbon dioxide.

4. In the same soil the content of carbon dioxide varies
greatly from year to year.

5. An increase of moisture in the soil increases the per-
centage of carbon dioxide.

6. The amount of carbon dioxide varies in different
parts of the soil.

The movement of carbon dioxide from the soil depends
chiefly on diffusion into the outside atmosphere. The
conditions governing diffusion, which will be discussed
elsewhere (par. 400), therefore largely determine the
rate of loss of carbon dioxide from the soil.

FUNCTIONS OF THE SOIL AIR

Both oxygen and carbon dioxide, as they exist in the
air of the soil, have mmportant relations to the processes
by which the soil is maintained in a habitable condition
for the roots of plants. Deprived of these gases, the soil
would soon become sterile.

398. Oxygen. — An all-important process in the soil
is that of oxidation, because by it the organic matter

1Ramann, H. Bodenkunde. Seite 301. Berlin, 1905.

THE SOIL AIR 481

that would soon accumulate to the exclusion of higher
plant life is disposed of, and the plant-food materials
are brought into a condition in which they may be ab-
sorbed by plant roots. The presence of oxygen is essen-
tial to the life of the decomposing organisms and to the
complete decay of organic matter. Through this pro-
cess, roots of past crops, as well as other organic matter
that has been plowed under, are removed from the soil.
The process of decay gives rise to products, chiefly car-
bon dioxide, that are solvents of mineral matter, and leaves
the nitrogen and ash constituents more or less available
for plant use.

Oxygen is also necessary for the germination of seeds
and the growth of plant roots. These phenomena, al-
though not involving the removal of large quantities
of oxygen, are yet entirely dependent on its presence in
considerable amounts.

399. Carbon dioxide. — The solvent action of carbon
dioxide is its most important function in the soil. By
this action it prepares for absorption by plant roots most
of the mineral substances found in the soil. Although
a weak acid when dissolved in water, its universal pres-
ence and continuous formation during the growing season
results in a large total effect.

Carbonic acid dissolves from the soil more or less of
all the nutrients required by plants. The amounts so
dissolved are appreciably greater than those dissolved
in pure water. The constant formation of carbon dioxide
by decomposition of organic matter keeps this solvent
continually in contact with the soil.

Carbon dioxide serves a useful purpose in combining
with certain bases to form compounds beneficial to the
soil. Particularly is this the case with calcium carbonate,

482 SOILS: PROPERTIES AND MANAGEMENT

which is of the greatest benefit to the soil in maintaining
a slight alkalinity very favorable to the development of
many beneficial bacteria and to the maintenance of good
tilth.

Stoklasa ! has correlated the carbon dioxide production
with the quantity of phosphates found in the drainage
water from certain soils. Some of his results are given
below : —

RELATIVE PRropuc-
P2Os rn DRAINAGE TION OF

ATER i 008 0.
(Kilograms to a hectare) on eres 5 ° pon

Loam . 5.2 24
Clay 3.5 15
Lime soil 5.8 36
Humous soil . 8.4 56

Stoklasa considers that the production of carbon dioxide
is a measure of the intensity of bacterial action in the
soil, and that in consequence of this activity the phos-
phorus is rendered soluble.

When carbon dioxide is combined as sodium carbonate
or potassium carbonate in considerable quantity, as in
certain alkali soils, a very injurious action on plant roots
and on soil structure results. On plants the carbonate
acts as a direct poison (see par. 305). The effect on
soil structure is to deflocculate the particles producing

the separate grain or the compact arrangement (see par.
420).

1 Stoklasa, J. Methoden zur Bestimmung der Atmungs-
intensitat der Bakterien im Boden. Zeit. f. d. Landw. Versuchs-
wesen in Oesterreich, Band 14, Seite 1248-79. 1911.

THE SOIL AIR 483

MOVEMENT OF SOIL AIR

There is a constant movement of the air in the inter-
stitial spaces of the soil and an exchange of gases between
the soil atmosphere and the outside atmosphere, as well
as a more general, but probably less effective, movement
of the air out of or into the soil, as the controlling condi-
tions may determine. The movement may be produced
by any one or more of the following phenomena: (1)
diffusion of gases; (2) movement of water; (3) changes
in atmospheric pressure; (4) changes of temperature in
atmosphere or in soil; (5) suction produced by wind.

400. Diffusion of gases. — The wide difference in the
composition of soil and atmospheric air gives rise to a
movement of gases due to a tendency for the external
and the internal gases to come into equilibrium. Accord-
ing to Buckingham,! the interchange of atmospheric and
soil air is due in large measure to diffusion.

The rate of movement of the soil air due to diffusion
is dependent on the aggregate volume of the interstitial
spaces, not on their average size. Thus, it is the porosity
of the soil that influences most largely the diffusion of
the air from it. Consequently the size of the particles
is not a factor, but good tilth permits diffusion to take
place more rapidly than does a compact condition of soil,
as the volume of the pore space is thereby increased.
Compacting the soil in any way, as by rolling or trampling,
has the opposite effect.

401. Movement of water.— As water, when present
in a soil, fills certain of the interstitial spaces, it decreases
the air space when it enters the soil and increases it when

1Buckingham, HE. Contributions to Our Knowledge of
the Aération of Soils. U.S. D. A., Bur. Soils, Bul. 25. 1904.

484. SOILS: PROPERTIES AND MANAGEMENT

it leaves. The downward movement of rain water pro-
duces a movement of soil air by forcing it out through
the drainage channel below, while at the same time a
fresh supply of air is drawn in behind the wave of satura-
tion as the water passes down from the surface. The
movement thus occasioned extends to a depth where
the soil becomes permanently saturated with water.
Twenty-five per cent of the air in a soil may be driven out
by a normal change in the moisture content of the soil.

402. Changes in atmospheric pressure. — Waves of
high or of low atmospheric pressure, frequently involving
a change of 0.5 inch on the mercury gauge, cross the con-
tinent alternately every few days. The presence of a
low pressure allows the soil air to expand and issue from
the soil, while a high pressure following causes the out-
side air to enter in order to equalize the pressure. An
appreciable, but not important, movement of soil air is
produced in this way.

The size of the interstitial spaces is more potent than
their volume in effecting soil ventilation by this and the
following methods.

403. Changes of temperature in atmosphere orin soil. —
A movement of soil air may be induced by a change of
temperature in the atmosphere or in the soil itself. Changes
in atmospheric temperature act in the same way as do
changes in atmospheric pressure; in fact, it is the effect
of temperature on air pressure that causes the movement.
Like the movement due to atmospheric pressure, it is
not great; but where the soil immediately at the surface
of the ground attains a temperature of 120° F. at midday,
as is the case in the Corn Belt, the movement must be
appreciable.

The diurnal change in soil temperature decreases

THE SOIL AIR 485

rapidly from the surface downward, due to the absorp-
tion and slow conduction of heat (see par. 227). At
the Nebraska Experiment Station! the average diurnal
range for the month of August, 1891, was as follows : —

DivurgnaL Rance or AIR AND Sor, TEMPERATURES

Degrees Fahrenheit

Air 5 feet above ground . ....... I44
Soil l inch below surface. . . ... . . I7.9
Soil 3 inches below surface . . . . . . . 148
Soil 6 inches below surface . . . . . . . 92
Soil 9 inches below surface . . . . . . .~ 6.6
Soil 12 inches below surface. . . . . . .) 48
Soil 24 inches below surface . . . . . . . = 0.5
Soil 36 inches below surface. . . . . . . 0.0

This soil contains about fifty per cent of pore space, in
the upper foot of which forty per cent is normally filled
with water during the summer months. This leaves 518
cubic inches of air in the upper cubic foot of soil. With
an increase in temperature, the air expands z4qz in volume
for each degree Fahrenheit. The average increase of
temperature is, in this case, about 11 degrees Fahrenheit
for the first foot. The air exhaled or inhaled by each
cubic foot of soil would then be

518 X 11
491
As this is slightly over two per cent of the air contained

in the upper foot of soil, and as the movement below
that depth is negligible, the change in composition at any

= 11.6 cubic inches

1Swezey, G. D. Soil Temperatures at Lincoln, Nebraska.
Neb. Agr. Exp. Sta., 16th Ann. Rept., pp. 95-102. 1903.

486 SOILS: PROPERTIES AND MANAGEMENT

one time is not great; but this pumping effect is kept up
day after day, although less energetically in the cooler
seasons of the year. In proportion as poor drainage
equalizes the temperature it would prevent this type of
circulation. The total effect, assisted by diffusion, is to
aid materially in ventilating the soil. Owing to diffusion
of air in the interstitial spaces, the air expelled is different
in composition from that inhaled.

404. Suction produced by wind. — The movement of
wind, being almost always in gusts, alternately increases
and decreases the atmospheric pressure at the surface
of the soil. There is a tendency, therefore, for the soil
air to escape and for atmospheric air to penetrate the
soil with each change in pressure. ‘The effect presumably
influences only the superficial air spaces, but it must be
very frequent in its action. No measurements have
been made and no definite estimate of its effect can be
stated.

METHODS FOR MODIFYING THE VOLUME AND THE MOVE-
MENT OF SOIL AIR

The conditions that influence the ‘ventilation of soils
are: (1) volume and size of the interstitial spaces; (2)
moisture content; (3) daily and annual range in tem-
perature.

Although the size of the interstitial spaces does not
appear to greatly influence the diffusion of gases from
a soil, it has a marked effect on certain of the other pro-
cesses by which air enters and leaves the soil. A sandy
soil, a soil in good tilth, and, particularly, a soil composed
of clods, permit of more rapid movement of air than does
a compact soil.

THE SOIL AIR 487

While a certain movement of air through the soil is
desirable, and indeed necessary, for the reasons already
stated a very considerable movement is injurious unless
there is an abundant rainfall. The effect of air move-
ment through the soil is to remove soil moisture. In a
region of light rainfall and low atmospheric humidity, this
may be disastrous if the soil is not kept compact by care-
ful tillage. On the other hand, in a humid region and
in clay soil there is likely to be too small a supply of oxygen
for the use of crops and lower plant life unless the soil
is well stirred.

405. Tillage.— The ordinary operations of tillage
greatly influence the ventilation of the soil. When a soil
is plowed, the soil at the bottom of the furrow is exposed
directly to the air at the surface, and, by the separation
of adhering particles and aggregates of particles, air
is brought into contact with particles that may previously
have been completely shut off from air. It is partly
because of its effect on soil ventilation that plowing is
beneficial, and the necessity for its practice is greater
in a humid region and on a heavy soil than in a region
of light rainfall and on a light soil. The practice of list-
ing corn, by which the soil is sometimes left unplowed
for a number of years, although in semiarid regions pro-
ductive of crops of sufficient yield to make them profitable,
would fail utterly on the heavy soils of a humid region.

Subsoiling, by loosening the subsoil, increases the
ventilation to a greater depth. Rolling and subsurface
packing both diminish the volume and the movement of
air. Their essential difference is in their effect on mois-
ture rather than on air. Harrowing and cultivation have
the opposite effect, and both increase the production of
nitrates in the soil by promoting aération.

488 SOILS: PROPERTIES AND MANAGEMENT

406. Manures.— Farm manures, lime, and _ those
amendments that improve the structure of the soil, have
for that reason a beneficial action on soil aération. By
their effect on the physical condition of the soil they
increase its permeability, and by their action in con-
tributing to the production of carbon dioxide they stimu-
late diffusion.

It is chiefly through its effect in increasing the volume
of air space in soils that farm manure is injurious in light
soils of semiarid regions. It may thus be injurious in-
stead of beneficial, if used under certain conditions.

407. Underdrainage.— By lowering the water table,
underdrainage by means of tiles removes from the soil
the water from all but the small capillary spaces, and
leaves free to the air the remainder of the interstitial
spaces. There is also a very considerable movement
of air through the drains, and a movement of air upward
from the drains to the surface of the soil, which serves
to aérate to some extent this intervening layer. The
aération of the soil brought about by underdrainage
is one of its beneficial features.

408. Irrigation. — ‘The influence of irrigation on the
soil is much like that of rainfall. The alternate filling
and emptying of the interstitial spaces with water and
air causes a very considerable change of air.

409. Cropping. — The roots of plants left in the soil
after a crop has been harvested decay and leave channels
in the soil through which air penetrates. Below the fur-
row slice, where the soil is not stirred and where it is
usually more dense than at the surface, this affords an
important means of aération. The absorption of moisture
from the soil by roots also causes the air to penetrate, in
order to replace the water withdrawn.

CHAPTER XXIII

COMMERCIAL FERTILIZERS

As treated in this volume, manures include all those
substances, with the exception of water (the function and
application of which is discussed in par. 167), that are
added to soils to make them more productive. There are
several ways in which manures applied to soils may in-
crease plant growth: (1) by addition of the nutrient mate-
rials utilized by plants, which is the chief function of
most of the so-called commercial fertilizers; (2) by im-
provement of the physical condition of a soil, which
usually results from the application of lime and the in-
corporation of organic matter; (3) by favoring the action
of useful bacteria, which is one of the beneficial results
of farm manure and also of lime; (4) by counteracting
the effects of toxic substances — as, for instance, the
conversion of sodium carbonate into sulfate by gypsum,
or the neutralization of acidity, or possibly the destruc-
tion of toxic organic substances by certain salts; (5) by
catalytic action, either on chemical processes in the soil
or by its influence on those bacteria that exert a favorable
influence on soil fertility or by direct stimulation of the
plant.

410. Early ideas of the function of manures. —
Manures were at one time supposed to pulverize the soil,
and the French word maneuvrer, from which the word
manure comes, implies to work with the hand. This

489

490 SOILS: PROPERTIES AND MANAGEMENT

idea probably originated through the observation that
farm manure, which was the only manure in use at that
time, made the soil less cloddy.

It has been argued, notably by Jethro Tull,’ that since
tillage pulverizes the soil it may be used as a substitute
for manures. There are, however, conditions aside from
tilth that are influenced by manures, and good tilth alone
will not suffice to maintain a permanently intensive agri-
culture. It is true in the United States, as it is in Europe,
that a large consumption of manures goes hand in hand
with a highly developed and intensive system of farming.

411. Development of the idea of the nutrient function
of manures. — While the use of animal excrement on cul-
tivated soils was practiced as far back as systematic agri-
culture can be definitely traced, the earliest record of
the use of mineral salts for increasing the yield of crops
was published in 1669 by Sir Kenelm Digby. He says:
“By the help of plain salt petre, diluted in water, and
mingled with some other fit earthly substance, that may
familiarize it a little with the corn into which I endeavored
to introduce it, I have made the barrenest ground far
outgo the richest in giving a prodigiously plentiful har-
vest.’ His dissertation does not, however, show any
true conception of the reason for the increase in the crop
through the use of this fertilizer. In fact, the want of
any real knowledge at that time of the composition of
the plant would have made this impossible.

In 1804, Theodore de Saussure * published his chemical

1Tull, Jethro. Horse-Hoing Husbandry. London. 1829.

* Digby, Kenelm. A Discourse Concerning the Vegetation
of Plants. London. 1669.

’ Saussure, Theodore de. Recherches Chimiques sur la
Vegetation. Paris. 1804.

COMMERCIAL FERTILIZERS 491

researches on plants, In which he, for the first time,
called attention to the significance of the ash ingredients
of plants, and pointed out that without them plant life
is impossible and, further, that only the ash of the plant
tissue is derived from the soil.

Justus von Liebig,! in his writings published about
the middle of the nineteenth century, emphasized still
more strongly the importance of mineral matter in the
plant and the extraction of this matter from the soil.
He refuted the theory, at that time popular, that plants
absorb their carbon from humus, but he made the mis-
take of attaching little importance to the presence of
humus in the soil. He showed the importance of potas-
sium and phosphorus in manures, but in his later expres-
sions he failed to appreciate the value of nitrogenous
manures, holding that a sufficient amount is washed
from the atmosphere in the form of ammonia.

A true conception of the necessity for a supply of
combined nitrogen in the soil was even at that time enter-
tained by Boussingault and by Sir John Lawes, although
the elaborate experiments conducted by Lawes, Gilbert,
and Pugh? in 1857 were required to fully demonstrate
the fact. Their care in conducting the experiments
resulted in their sterilizing the soil with which they ex-
perimented, and hence their failure to discover the utiliza-
tion of free atmospheric nitrogen by legumes.

1 Liebig, J. Justus von. Principles of Agricultural Chemistry
with Special Reference to the Late Researches Made in England.
London. 1855. Also, Chemistry in its Applications to Agri-
culture and Physiology. New York. 1556.

2 Lawes, J. B., Gilbert, J. H., and Pugh, HE. On the Sources
of the Nitrogen of Vegetation, with Special Reference to the
Question whether Plants Assimilate Free or Uncombined Nitro-
gen. Rothamsted Memoirs, Vol. 1, No.1. 1862.

492 SOILS: PROPERTIES AND MANAGEMENT

Between 1840 and 1850, Sir John Lawes began the
manufacture of bone superphosphate, and about the
same time Peruvian guano and nitrate of soda were intro-
duced into Europe. The commercial fertilizer industry
thus dates from that time.

412. Classes of manures. — While manures are very
numerous as to kind and while a certain manure may have
a number of distinct functions, they may yet be roughly
divided into classes. They will accordingly be treated
here under the following heads: (1) commercial fertilizers ;
(2) soil amendments; (38) farm manures; (4) green
manures.

413. Commercial fertilizers. — Although the commer-
cial fertilizer industry is little more than half a century
old, the sale of fertilizers in this country amounts to more
than $110,000,000 annually. Animal refuse and phos-
phate fertilizers are exported, while nitrate of soda and
potassium salts are imported.

Of the fertilizers sold in the United States in 1909,
about fifty per cent was consumed in the South Atlantic
States, in an area lying within three hundred miles of
the seaboard. Nearly one-half of the remainder was pur-
chased in the Middle Atlantic and New England States.
Only five per cent was purchased west of the Mississippi
River.t

Primarily the function of commercial fertilizers is to
add plant nutrients to the soil, usually in a form more
readily soluble than those already present in large quan-
tity. While other beneficial effects may be produced by
certain fertilizers, these are usually of secondary impor-
tance as compared with the addition of the plant nutrients.

1 Statistics from Thirteenth Census of the United States.
Abstract of the Census, p. 372. Washington. 1918.

COMMERCIAL FERTILIZERS 493

414. Fertilizer constituents. — Prepared fertilizers, as
found on the market, are usually composed of a number
of ingredients. Since these are the carriers of the fertiliz-
ing material, and since it is on their composition and solu-
bility that the value of a fertilizer depends, a knowledge
of the properties of these constituents is of interest to
every one who uses fertilizers and is a valuable aid in their
purchase.

FERTILIZERS USED FOR THEIR NITROGEN

Nitrogen is the most expensive constituent of manures
and is of great importance, since it is very likely to be
deficient in soils. A commercial fertilizer may have its
nitrogen in the form of soluble inorganic salt, or combined
as organic material. On the form of combination de-
pends toa certain extent the value of the nitrogen, as
the soluble inorganic salts are very readily available to
the plant, while the organic forms must pass through the
various processes leading to nitrification before the
plant can use the nitrogen so contained. The inorganic
nitrogen fertilizers are sodium nitrate, ammonium sulfate,
calcium nitrate, and calcium cyanamide.

415. Forms in which nitrogen exists in soils. — There
are several forms in which nitrogen exists in soils. The
uncombined nitrogen of the soil air constitutes the largest
supply because of its diffusibility with the atmospheric
air. Next in quantity is the nitrogen of organic com-
pounds, ranging from 0.05 to 0.3 per cent in ordinary
arable land and slightly, but appreciably, soluble in soil
water. In upland cultivated soils the nitrogen of nitrate
salts forms the next largest supply, but rarely exceeds
20 per cent of the total combined nitrogen of the soil.

494. SOILS: PROPERTIES AND MANAGEMENT

In swamp and inundated soils the nitrogen of ammonium
salts and nitrites forms a larger proportion of the soil
nitrogen than does the nitrate nitrogen, but in well
aérated soils these compounds exist in very small quan-
tities.

416. Forms in which nitrogen is absorbed by plants. —
The utilization of atmospheric nitrogen by leguminous
plants and by a few others that have nodule-bearing roots
has been established beyond question; but the extent
to which this form of nitrogen may be utilized by other
plants, or the identity of the plants that participate in
its use, are subjects on which opinions differ, and which
are still being investigated.

417. Use of nitrates by plants. — Boussingault first
demonstrated the importance of nitrates for higher
plants. Previous to that time ammonia had been con-
sidered the chief source of nitrogen, and at a still earlier
time humus had been considered the source. Liebig
gave the weight of his influence in favor of ammonia
as the supply. He was unaware, of course, of the trans-
formation of ammonia nitrogen into nitrates in the soil.
Since the publication of the experiments by Boussin-
gault and the later work on nitrification, there has
been a tendency to consider nitrate nitrogen as the
only available supply of nitrogen for agricultural plants.
While this is an extreme view of the matter, the
fact remains that all the higher plants, including the
legumes, appear to be able to absorb nitrates, and this
form of nitrogen has frequently proved of greater benefit
to plants than other forms of nitrogen tested at the
same time.

418. Ammonia as a plant-food. — That rice plants on
swamps use ammonia nitrogen rather than other forms

COMMERCIAL FERTILIZERS 495

has been demonstrated. by Kellner! and later by Kelley.?
On upland soils, however, it is presumable that rice plants
utilize nitrate nitrogen, which would indicate that some
plants, at least, may adapt themselves to the use of the
more abundant form of nitrogen.

Hutchinson and Miller? found that peas obtained
nitrogen from ammonium salts as readily as from sodium
nitrate, but that wheat plants, although able to obtain
nitrogen directly from ammonium salts, grew much better
in a solution containing nitrates. One feature brought
out by the numerous experiments with ammonium salts
is the difference between plants of various kinds in respect
to their ability to absorb nitrogen in this form.

419. Utilization of humus compounds by plants. —
One of the early beliefs in regard to plant nutrition was
that organic matter as such is directly absorbed by higher
plants. This opinion was afterwards entirely replaced
by the mineral theory propounded by Liebig; and still
later the discovery of the nitrifying process almost dis-
posed completely of the belief that organic matter is a
food for higher plants. It is quite certain, however, that
some organic nitrogenous compounds furnish suitable
nutrient material for some higher plants without under-
going bacterial change.

Hutchinson and Miller, in the paper just referred to,
give the following list of the organic substances used in

1 Kellner, O. Agrikulturchemische Studien tiber die Reis-
kultur. Landw. Vers. Stat., Band 30, Seite 18-41. 1884.

2Kelley, W. P. The Assimilation of Nitrogen by Rice.
Hawaii Agr. Exp. Sta., Bul. 24, pp. 5-20. 1911.

Hutchinson, H. B., and Miller, N. H. J. The Direct
Assimilation of Inorganic and Organic Forms of Nitrogen by
Higher Plants. Centrlb. f. Bakt., II, Band 30, Seite 513-547.
1911.

496 SOILS: PROPERTIES AND MANAGEMENT

experiments by various investigators, and their avail-
ability for the nutriment of higher plants : —
REeapDiIty ASSIMILATED

Ammonium salts

Acetamide CH;.CO.NH,

NH;
Urea COC NH,
Barbituric acid (with calcium carbonate)
/NH.CO\
CONE. CO PCEa
NH.CO
Alloxan ONE. Co CO

Humates

ASSIMILATED

Formamide H.CO.NH,
Glycine NH, . CH, . COOH
Aminopropionic acid CH;.CH(NH2) . COOH

Guanidine hydrochloride NH. (NED

NNH2
NH .CO
Cyanuric acid CO NH. CO NH

CO. NH,
Oxamide |
CO .NH,

CH(NH,)COOH
Sodium aspartate |

CH, . COOH
Peptone

COMMERCIAL FERTILIZERS 497

DovuBTFruu

Trimethylamine

para--+ Urazine cocn NCO
Hexamethylenetetramine

Nor ASSIMILATED

Ethyl nitrate Hydroxylamine hydrochloride
Propionitrile Methyl carbonate
Toxic
Tetranitromethane

This list comprises only those substances that have been
used in experiments with peas. Many other substances
remain to be tested, and those already tested may act
differently with other plants.

One of the organic compounds isolated from soils by
Shorey,! called creatinine, has been shown by Skinner?
to be used directly by plants as a source of nitrogen,
and to have produced a better growth of wheat seedlings
than did an equivalent quantity of nitrogen in the form
of sodium nitrate. Histidine, arginine, and creatine
have also been found in soils and shown to be a direct
source of nitrogen for wheat seedlings (par. 92).

These and numerous other investigations of this subject
show that amine as well as amide nitrogen 1s assimilated
by at least some agricultural plants, but to what extent
most of these compounds may successfully replace the

1Shorey, E. C. I. The Isolation of Creatinine from Soils.
U.S. D. A., Bur. Soils, Bul. 838, pp. 11-22. 1911.

2 Skinner, J.J. III. Effects of Creatinine on Plant Growth.

U. 8S. D. A., Bur. Soils, Bul. 83, pp. 38-44. 1911.
2k

498 SOILS: PROPERTIES AND MANAGEMENT

inorganic forms of nitrogen has not been definitely worked
out. Certain organic nitrogenous fertilizers — as, for ex-
ample, dried blood —have a high commercial value, the
nitrogen in this form selling for more a pound than the nitro-
gen in any of the inorganic salts. Many crops, especially
among garden vegetables, are most successfully grown only
when supplied with organic nitrogenous material. Some
nitrate nitrogen is always present under natural soil con-
ditions, so that crops are never limited to organic nitro-
gen alone; and it may be that the latter form of nitrogen
is most useful when it supplements the nitrate nitrogen.

420. Sodium nitrate. — This now constitutes the prin-
cipal source of inorganic nitrogen in commercial fertilizers.
The salt exists in the crude condition in northern Chili.
The crude salt is purified by crystallization, and as put
on the market it contains about 96 per cent sodium
nitrate, or about 16 per cent of nitrogen, 2 per cent of
water, and small amounts of chlorides, sulfates, and in-
soluble matter. The cost of nitrogen in this form is
from fifteen to eighteen cents a pound.

Because of its easy availability, sodium nitrate acts
quickly in inducing growth. For this reason it is used
much by market gardeners, and for other purposes when
a rapid growth is desired. It is the most active form of
nitrogen. A light dressing on meadowland in early
spring assists greatly in hastening growth by furnishing
available nitrogen before the conditions are favorable
for the process of nitrification. On small grain a similarly
useful purpose is served where the soil is not. rich.

Owing to the fact that nitrate is not absorbed by the
soil in large quantities, it is easily lost in the drainage
water; for this reason it should be applied only when crops
are growing on the soil, and then only in moderate quantity.

COMMERCIAL FERTILIZERS 499

The continued and abundant use of sodium nitrate
on the soil may result, through its deflocculating action,
in breaking down aggregates of soil particles, thus com-
pacting and injuring the structure. This effect is attrib-
uted to the accumulation of sodium salts, particularly
the carbonate, as the sodium is not utilized by the plant
to the same extent as is the nitrogen.

421. Ammonium sulfate. — When coal is distilled, a
portion of the nitrogen is liberated as ammonia and is
collected by passing the products of distillation through
water in which the ammonia is soluble, forming the am-
moniacal liquor. The ammonia thus held is distilled into
sulfuric acid, with the formation of ammonium sulfate
and the removal of impure gases.

Commercial ammonium sulfate contains about twenty
per cent of nitrogen. It is the most concentrated form in
which nitrogen can be purchased as a fertilizer, having
from sixty to eighty pounds more of nitrogen to a ton
than sodium nitrate. It is therefore economical to
handle. Its effect on crops is not so rapid as that of sodium
nitrate, but it is not so quickly carried from the soil by
drainage water, as the ammonium salts are readily ab-
sorbed by the soil. A pound of nitrogen in the form of
ammonium sulfate has about the same.agricultural value
as the same amount in the form of nitrate if the soil on
which it is used is abundantly supplied with lime; but
on an acid soil ammonium sulfate has less value.

The long and extensive use of ammonium sulfate on a
soil has a tendency to produce an acid condition, through
the accumulation of sulfates which are not largely taken
up by plants.

Ammonium sulfate, like sodium nitrate, should not be
applied in autumn, as the ammonia is converted into

500 SOILS: PROPERTIES AND MANAGEMENT

nitrates and leached from the soil in sufficient quantities to
entail a very decided loss of nitrogen. There is not likely
to be so large a loss of nitrogen from ammonium salts as
from nitrates, and, as would naturally be expected, there is
greater loss of nitrogen when these salts are used alone than
when they are combined with other fertilizing ingredients.

Hall? has estimated the loss of nitrogen from certain
drained plats at the Rothamsted Experiment Station.
This estimate is based on the concentration of the drain-
age from the different plats, of which there was no record
of total flow, but for which the measurements of flow from
the lysimeter draining 60 inches of soil were taken and the
total loss of nitrates was calculated on this basis. Esti-
mated in this way the effects of several different methods
of manuring are shown in the accompanying table : —

Pounpbs To tHE AcRE or Nirric NITROGEN In Drainage WATER

1879-80 1880-81
TROATMENT Spring |Harvest| Spring | Harvest

sowing to sowing to
to spring to spring
harvest | sowing | harvest | sowing

aiimhanianenionannensiensenen’ Rantimmeapeneenemnesneneene’ Gemmemmmenemmerta ed

Unmanured .. toe kl 1.7 | 10.8 0.6 | 17.1

Mineral fertilizers only . ~ . « «| 1.6 | 18.3 0.7 | 17.7
Minerals + 400 pounds ammonium

salts . 18.3 | 12.6 | 4.3 | 21.4
Minerals -+ 550 pounds nitrate of

soda. 45.0 | 15.6 | 15.0 | 41.0
Minerals + 400 pounds: ammonium

salts applied in autumn. . . .| 9.6 | 59.9 | 3.4 | 74.9

400 pounds ammonium salts alone . | 42.9 | 14.3 | 7.4 | 35.2
400 pounds ammonium salts + sul-
phate of potash . . . . .| 19.0 | 164) 3.7 | 25.3

Estimated drainage in inches .| U1 4,7 1.8 | 18.8

i1Hall, A. D. The Book of the Rothamsted Experiments,
p. 235, New York, 1905,

COMMERCIAL FERTILIZERS 501

This table, in addition to confirming the statements
already made in regard to the joss of nitrogen in drainage
water, also shows how closely the supply of available
nitrogen was used by the crops on those plats, which were
evidently in need of nitrogen fertilization as the plats
lost very little nitrogen during the growing season, while
during the remainder of the year they lost nearly as
much as did some of the nitrogen-manured plats. The
table also indicates that the loss when nitrate is used is
greater than when ammonium salts are applied, as the
amount of nitrogen in the 550 pounds of nitrate is really
eight pounds to the acre more than in the 400 pounds of
ammonium sulfate, which is not sufficient to account for
the difference in the loss. However, half of the nitrate-
treated plat recetved no other manure and produced only
a small crop, which would naturally result in a greater
loss by drainage.

422. Fertilizers containing atmospheric nitrogen. —
The vast store of atmospheric nitrogen, chemically un-
combined but very inert, will furnish an inexhaustible
supply of this highly valuable fertilizing element, when it
can with reasonable economy be combined in some manner
resulting in a product that will be commercially trans-
portable and that will, when placed in the soil, be or be-
come soluble without liberating substances toxic to plants.
The importance of the nitrogen supply for agriculture may
be appreciated when it is considered that nitrates are
being carried off in the drainage water of all cultivated
soils at the rate of twenty-five to fifty pounds, and even
more, to the acre annually, and that nearly as much
more is removed in crops.

The exhaustion of the supply of nitrogen in most soils
may be accomplished within one or two generations of

502 SOILS: PROPERTIES AND MANAGEMENT

men, unless a renewal of the supply is brought about in
some way. Natural processes provide for an annual ac-
cretion through the washing-down of ammonia and
nitrates by rain water from the atmosphere, and through
the fixation of free atmospheric nitrogen by bacteria; but
without the frequent use of leguminous crops, the supply
could not be maintained. Farm practice of the present
day requires the application of nitrogen in some form of
manure, and, as the end of the commercial supply of com-
bined nitrogen is easily in sight, there is urgent need of
discovering a new source. This has been done by com-
bining calcium with atmospheric nitrogen in the forms of
calcium cyanamide and calcium nitrate.

423. Cyanamid.-—— The trade name for calcium cyana-
mide is “cyanamid”’ and that name is therefore used
in this volume. One process for the production of cyana-
mid consists in passing nitrogen into closed retorts con-
taining powdered calcium carbide heated to a high tem-
perature; the product being calctum cyanamide and free
carbon : —

CaC, +2N = CaCN, +C

The free carbon remains distributed in the cyanamide
and gives the fertilizer a black color. The nitrogen re.
quired for the process is obtained either by passing air
over heated copper, or by the fractional distillation of
liquid air.

The fertilizer, as placed on the market, is a heavy,
black powder or granulated material with a somewhat dis-
agreeable odor.

424. Composition of cyanamid.‘— Cyanamid as manu-

1Cyanamid is a trade name; the chemical compound is
spelled cyanamide.

COMMERCIAL FERTILIZERS 508

factured in this country has about the following composi-

tion :*— Per cent
Calcium cyanamide . . . . CaCN, 45.92
Calcium carbonate . . . . CaCQOs 4.04.
Caletum sulfide . . . . . CaS 1.73
Calcium phosphide . . . . CasPe 0.04
Calcium hydroxide . . . . Ca(OH), 26.60
Free carbon ...... C 18.14
Tron and alumina. . . . . ROs 1.98
Silica . 2... 1. wee SOD 1.62
Magnesia . ..... . MgO 0.15
Combined moisture... . 3.12
Free moisture . . . . . . HO 0.35
Undertimed ...... 1.31

100.00

According to this composition the material would con-
tain 16 per cent of nitrogen. Lime in the forms of carbo-
nate and hydroxide would add somewhat to its value,
and the residue of the calcium cyanamide, which upon
decomposition is also calcium hydroxide, is likewise ben-
eficial to the soil.

425. Changes of calcium cyanamide in the soil. —
Calcium cyanamide must be decomposed in the soil be-
fore its nitrogen becomes available to plants. There
are several steps in the decomposition process by which
the nitrogen finally emerges in the form of ammonia.
These, according to Pranke in the work just cited, con-
sist first of hydrolysis, by which acid calcium cyanamide
and calcium hydroxide are formed : —

2CN.NCa + HO = (CN. NH).Ca + Ca(OH)»

calcium water acid calcium calcium
cyanamide cyanamide hydroxide

1 Pranke, E. J. Cyanamid, p.8. Easton, Pennsylvania. 1913.

504. SOILS: PROPERTIES AND MANAGEMENT

The acid calcium cyanamide quickly loses its calcium,
leaving free cyanamide. Investigators differ as to the
process involved in this change, but the ultimate condi-
tion of the calcium is carbonate. The three explanations
of the process may be represented by the following re-
actions : —

1. (CN . NH).Ca + CO. = 2 CN . NH, + CaCOs,

In this reaction the carbon dioxide of the soil water is
supposed to cause precipitation of the calcium.

In this case hydrolysis occasions the reaction. The
hydroxide would, of course, be converted into carbonate
in the soil.

8. (CN .NH).Ca + CO. = CN .NH, + CaCN.CO,

acid calerum carbon ree calcium
cyanamide dioxide cyanamide cyanamide
carbonate
CaCN.CO, + H,0 = CN .NH» + CaCQ,
free calcium
cyanamide carbonate

By this reaction calctum cyanamide carbonate is an in-
termediate product, but is at once hydrolyzed and free
cyanamide produced.

The next step in the process is the formation of urea by
hydrolysis of the free cyanamide : —

CN . NH, a HO = CO(NHs2)e

free cyanamide water urea,

The changes up to the production of urea are independent
of bacterial action. The urea is converted through bac-
terial action into ammonium carbonate : —

COMMERCIAL FERTILIZERS 505

CO(NH2).o +- 2 H.O = (NHy).COs

urea ammonium
carbonate

This may be converted into nitrates in the usual manner.

426. The use of cyanamid.— The changes as here
described are those that proceed under favorable condi-
tions in the soil. When conditions are not favorable —
as, for example, when a soil is saturated with water or
when it is acid some more or less injurious products
may be formed. For this reason cyanamid is not likely
to be so satisfactory on soils of this nature as on better
soils. To very sandy soils it is not well suited. Ordi-
narily its fertilizing value is not greatly below that of
sodium nitrate, and is about equal to that of ammonium
sulfate when not used in heavy applications.

It should be incorporated with the soil at least a week
before planting, as it may injure the young plants if de-
composition has not proceeded far enough to remove its
somewhat toxic properties. As it must undergo this
decomposition before its nitrogen becomes available to
the young plants, there is an added reason for this pre-
caution. It does not give its best results as a top-dressing
because it requires incorporation with the soil for its
proper decomposition.

427. Calcium nitrate. — The other process for com-
bining atmospheric nitrogen is of more recent invention
than that for the manufacture of calcium cyanamid but
is not conducted on a commercial scale in this country ;
however, with the vast opportunities for developing elec-
tric power which are offered in certain localities, factories
for the manufacture of calcium nitrate will some day be
established.

The process employs an electric are to produce nitric

506 SOILS: PROPERTIES AND MANAGEMENT

oxide by the combustion of atmospheric nitrogen, accord-
ing to the simple equation : —

Ne + O2.=2 NO
NO + 0 = NO;

A very high power is required for this synthesis, in-
volving a temperature of 2500° to 3000° C., and the
expense of the operation is determined almost entirely by
the cost of the electricity.

The nitric oxide gas is passed through milk of lime,
giving basic calcium nitrate: —

Ca(OH). + 2 HNO; = Ca(NQ3)2 +- 2 H.O

The calcium nitrate resulting from this process has a
yellowish white color, and is easily soluble in water but
deliquesces very rapidly in the air. This last property
can be overcome by adding an excess of lime in the manu-
facture, thus producing a basic calcium nitrate which
contains only 8.9 per cent of nitrogen. Another way of
avoiding the difficulties involved by the deliquescent
property of the nitrate is practiced by the factory at
Nottoden, Norway. This consists in first melting the
product, then grinding it fine and packing it in air-tight
casks. The fertilizer thus prepared contains from 11 to
13 per cent of nitrogen.

Calcium nitrate contains its nitrogen in a form directly
available to plants. It resembles sodium nitrate in its
solubility, availability, and lack of absorption by the soil.
It may be spread on the surface of the ground, as it exerts
no poisonous action and does not tend to form a crust, as
does sodium nitrate.

The relative values of the different soluble nitrogén
fertilizers vary with a great many conditions and can be

COMMERCIAL FERTILIZERS 507

accurately judged only by a large number of tests. At
present, both calcium nitrate and cyanamid are being
produced at less cost per pound of nitrogen than is sodium
nitrate, when laid down in the neighborhood of the fac-
tories in Europe. It seems fairly certain that, when the
processes have been further improved, the result will be
to greatly reduce the cost of available nitrogen.

428. Organic nitrogen in fertilizers.— The commercial
fertilizers containing organic nitrogen include cottonseed
meal, which contains 7 per cent of nitrogen when free
from hulls; linseed meal, with 5.5 per cent of nitrogen;
castor pomace, with 6 per cent of nitrogen; and a num-
ber of refuse products from packing houses, among which
are red dried blood and black dried blood, the former
having about 18 per cent of nitrogen and the latter from
6 to 12 per cent; dried meat and hoof meal, with 12 to
13 per cent of nitrogen; ground fish, with 8 per cent of
nitrogen ; and tankage, of which the concentrated product
has a nitrogen content of from 10 to 12 per cent and the
crushed tankage from 4 to 9 per cent; also leather meal
and wool-and-hair waste, but these, because of their
mechanical condition, are of very little value.

The meals made from seeds are primarily stock foods
but are sometimes used as manures. They decompose
rather slowly in the soil, owing to their high oil content,
and are much more profitably fed to live stock than ap-
plied as farm manure. They contain some phosphorus
and potash as well as nitrogen.

Guano consists of the excrement and carcasses of sea
fowl. The composition of guano depends on the climate
of the region in which it is found. Guano from an arid
region contains nitrogen, phosphorus, and potassium, while
that from a region where rains occur contains only phos-

508 SOILS: PROPERTIES AND MANAGEMENT

phorus — the nitrogen and potassium having been largely
leached out. In a dry guano the nitrogen exists as uric
acid, urates, and, in small quantities, ammonium salts.
A damp guano contains more ammonia. The phosphorus
is present as calcium phosphate, ammonium phosphate,
and the phosphates of other alkalies. A portion of
the phosphate is readily soluble in water. Thus all
the plant-food either is directly soluble or becomes so
soon after admixture with the soil. The composition
is extremely variable. The best Peruvian guano con-
tains from 10 to 12 per cent of nitrogen, from 12 to 15
per cent of phosphoric acid, and from 3 to 4 per cent of
potash.

Guano was formerly a very important fertilizing ma-
terial, but the supply has become so nearly exhausted
that it is relatively unimportant at the present time.

Of the abattoir products, dried blood is the most readily
decomposed, and therefore has its nitrogen in the most
available form. In fact, it produces results more quickly
than any other form of organic nitrogen. It requires a
condition of soil favorable to decomposition and nitrifica-
tion, which prevents its exerting a strong action in early
spring. It should be applied to the soil before the crop
is planted. The black dried blood contains from 2 to 4
per cent of phosphoric acid.

Dried meat contains a high percentage of nitrogen, but
does not decompose so easily as dried blood, and is not so
desirable a form of nitrogen. It can be fed to hogs or
poultry to advantage, and the resulting manure is very
high in nitrogen.

Hoof meal, while high in nitrogen, decomposes slowly,
being less active than dried blood. It is of use in increas-
ing the store of nitrogen in a depleted soil.

COMMERCIAL FERTILIZERS 509

Ground fish is an excellent form of nitrogen, and is as
readily available as blood but has a lower nitrogen content.

Tankage is highly variable in composition, and the con-
centrated tankage, being more finely ground, undergoes
more readily the decomposition necessary for the utiliza-
tion of the nitrogen. Crushed tankage contains from 3 to
12 per cent of phosphoric acid, in addition to its nitrogen.

Leather meal and wool-and-hair waste when untreated
are in such a tough and undecomposable condition that
they may remain in the soil for years without losing their
structure. They are not to be recommended as manures.

429. Availability of organic nitrogenous fertilizers. —
The forms in which combined nitrogen is available to
most agricultural plants has already been stated to be
nitrates, ammonium salts, and certain organic compounds.
Of the latter the simple compounds, as urea, appear to be
most readily taken up by plants. Decomposition is there-
fore a necessary process for most of these fertilizers, and
their usefulness is, in general, proportional to the readi-
ness with which aérobic decomposition proceeds, or to the
proportion of available compounds that they contain in
their original condition. Guano, for instance apparently,
contains much nitrogen that is available without further
decomposition. Dried blood quickly decomposes and
soon forms available substances, consisting of the simpler
organic nitrogenous compounds, ammonia and nitrates.
The decomposition process is a biological one, arising from
the action of microdrganisms that first break down the
complicated organic compounds, forming simpler ones,
and finally carry the nitrogen into the form of ammonia,
then to nitrous acid, and at last to nitric acid.

Numerous attempts have been made to determine the
relative availability of the nitrogen in various organic

510 SOILS: PROPERTIES AND MANAGEMENT

nitrogenous fertilizers. A few such tests, in which nitrate
of soda and ammonium sulfate are used as a basis for com-
parison, are given in the table below, the statement being
in terms of percentage availability when nitrate of soda
is taken as one hundred. The experiments quoted were
conducted by Wagner and Dorsch,! by Johnson, Jenkins,
and Britton,? and by Voorhees and Lipman.’

PeRcENTAGE AVAILABILITY OF FERTILIZER NITROGEN

WAGNER JOHNSON | VOORHEES

AND AND AND
DoxrscH OTHERS LIPMAN

Nitrate of soda wee ee 100 100 100
Sulfate of ammonia .... . 90 70
Dried blood te ee ke kl 70 73 64
Bonemeal . ......~. 60 17
Stable manure ....... 45 53
Tankage . . .... +... 49
Horn and hoof meal . . .. . 70 68
Linseed meal . . ..... 69
Cottonseed meal . . ... . 65
Castor pomace wee ee 65
Woolwaste ....... =. 30
Leathermeal . ...... 20
Dry ground fish ...... 64

One difficulty in drawing conclusions from these experi-
ments is that the substances grouped under the same
name are not always identical in the method of their

1 Wagner, P., and Dorsch, F. Die Stickstoffdiingung der
Landw. Kulturpflanzen, Erstes Teil. Berlin. 1892.

2 Johnson, 8. W., Jenkins, E. H., and Britton, W. E. Experi-
ments on the Availability of Fertilizer-Nitrogen. Connecticut
Agr. Exp. Sta., 21st Annual Rept., Part 4, pp. 257-277. 1897.

8 Voorhees, EH. B., and Lipman, J. G. Investigations Rela-
tive to the Use of Nitrogenous Materials, 1898-1907. New
Jersey Agr. Exp. Sta., Bul. 221. 1909.

COMMERCIAL FERTILIZERS 511

preparation or in their composition. Another discrep-
ancy arises from the fact that all soils do not respond in
the same relative degree to any one fertilizer. Thus,
Sackett + found that in some soils dried blood was am-
monified more rapidly than was cottonseed meal, while
in other soils the reverse was true; and that a similar
difference obtained in soils with respect to the ammoni-
fication of alfalfa meal and flaxseed meal. It would
therefore appear to be impossible to make any close dis-
tinctions in the relative availability of the nitrogen in
various organic nitrogenous fertilizers. A considerable
number of these experiments are, in the aggregate, useful
in pointing out the probable relative availabilities of the
more widely differing nitrogen-bearing substances.

FERTILIZERS USED FOR THEIR PHOSPHORUS

Phosphorus is generally present in combination with
lime, iron, or alumina. Some of the phosphates contain
also organic matter, in which case they generally carry
some nitrogen. Phosphates associated with organic
matter decompose more quickly in the soil than do un-
treated mineral phosphates.

430. Bone phosphate.— Formerly bones were used
entirely in the raw condition, ground or unground. When
ground they act as a fertilizer more quickly than when
unground. Raw bones contain about 22 per cent of phos-
phoric acid and 4 per cent of nitrogen. The phosphorus
is in the form of tricalcic phosphate (Cag(PO,)2).

Most of the bone now on the market is first boiled or

1 Sackett, W. G. The Ammonifying Efficiency of Certain
Colorado Soils. Colorado Agr. Exp. Sta., Bul. 184, pp. 3-23.
1912.

512 SOILS: PROPERTIES AND MANAGEMENT

steamed. This frees it from fat and nitrogenous matter,
both of which are used in other ways. Steamed bone is
more valuable as a fertilizer than raw bone, because the
fat in the latter retards decomposition and also because
steamed bone is in a better mechanical condition. The
form of the phosphoric acid is the same as in raw bone
and constitutes from 28 to 30 per cent of the product,
while the nitrogen is reduced to 15 per cent.

Bone tankage, which has already been spoken of as a
nitrogenous fertilizer, contains from 7 to 9 per cent of
phosphoric acid, largely in the form of tricalcium phos-
phate. All these bone phosphates are slow-acting ma-
nures, and should be used in a finely ground form and for
the permanent benefit of the soil rather than as an imme-
diate source of nitrogen or phosphorus.

431. Mineral ph sphates. —— There are many natural
deposits of mineral phosphates in different parts of the
world, some of the most important of which are in North
America. The phosphorus in all these is in the form of
tricalcium phosphate, but the materials associated with
it vary greatly.

Apatite is found in large quantities in the provinces of
Ontario and Quebec, Canada. It exists chiefly in crys-
talline form. The tricalcium phosphate of which it is
composed is in one form associated with calcium fluoride
and in the other with calcium chloride. The Canadian
apatite contains about 40 per cent of phosphoric acid,
being richer than that found elsewhere. Phosphorite is
another name for apatite, but is chiefly applied to the
impure amorphous form.

Coprolites are concretionary nodules found in the
chalk or other deposits in the south of England and in
France. They contain from 25 to 30 per cent of phos~

COMMERCIAL FERTILIZERS 513

phoric acid, the other constituents being calcium carbonate
and silica.

South Carolina phosphate contains from 26 to 28 per
cent of phosphoric acid and a very small amount of iron
and alumina. As these substances interfere with the
manufacture of superphosphate from rock, their presence
is very undesirable — rock containing more than from
3 to 6 per cent being unsuitable for that purpose.

Florida phosphates exist in the form of soft phosphate,
pebble phosphate, and bowlder phosphate. Soft phos-
phate contains from 18 to 30 per cent of phosphoric acid,
and because of its being more easily ground than most
of these rocks it is often applied to the land. without being
first converted into a superphosphate. The other two
forms, pebble phosphate and bowlder phosphate, are
highly variable in composition, ranging from 20 to 40 per
cent in phosphoric acid content. Tennessee phosphate
contains from 30 to 35 per cent of phosphoric acid.

Basic slag, or, as it is also called, phosphate slag or
Thomas phosphate, is a by-product in the manufacture
of steel from pig-iron rich in phosphorus. The phos-
phorus present is usually considered to be in the form of
tetracalcium phosphate, (CaO),4P.0;, or possibly a double
silicate and phosphate of lime having the composition
(CaO) sP,0sSi02. It contains also calcium, magnesium,
aluminium, iron, manganese silica, and sulfur. Because
of the presence of iron and aluminium, and because its
phosphorus is more readily soluble than tricalcium phos-
phate, the ground slag is applied directly to the soil with-
out treatment with acid.

The degree of fineness to which the slag is ground is
supposed to be an important factor in determining its
solubility in the soil. It is much more soluble in water

514 SOILS: PROPERTIES AND MANAGEMENT

charged with carbon dioxide than in pure water, a property
that greatly increases its value because of the fact that
soil water always contains more or less of this gas. It is
also readily acted upon by organic acids. For this reason
it is particularly effective in a peat soil, and likewise in
most soils deficient in lime. As it contains a considerable
quantity of free lime it has another beneficial effect on
such. soils.

432. Superphosphate fertilizers. In order to render
more readily available to plants the phosphorus contained
in bone and mineral phosphates, the raw material, purified
by being washed and finely ground, is treated with sulfuric
acid. This results in a replacement of phosphoric acid by
sulfuric acid, with the formation of monocalcium phos-
phate and calcium sulfate, and a smaller amount of dical-
cium phosphate, according to the reactions : —

Cag(PO4)o+ 2 H,S0,= CaH,(POs)e+ 2 CaSO,
Cag(POg)o+ HeSO,= CagHe(POx)2 + CaSO,

The tricalcium phosphate being in excess of the sul-
furic acid used, some of it remains unchanged.

In the treatment of phosphate rock some of the sul-
furic acid is consumed in acting on the impurities present,
which usually consist of calcium and magnesium carbo-
nates, iron and aluminium phosphates, and calcium chlo-
ride or fluoride, converting the bases into sulfates and
freeing carbon dioxide, water, hydrochloric acid, and
hydrofluoric acid. The resulting superphosphate is there-
fore a mixture of monocalcium phosphate, dicalcitum phos-
phate, tricalcium phosphate, calcium sulfate, and iron and
aluminium sulfates.

In the superphosphates made from bone, the iron and
aluminium sulfates do not exist in any considerable

COMMERCIAL FERTILIZERS 515

quantities. However, as long as the phosphorus remains
in the form of monocalcium phosphate, the value of a
pound of available phosphorus in the two kinds of fertilizer
is the same; but the remaining tricalcium phosphate has
a greater value in the bone than in the rock superphosphate.

The superphosphates made from animal bone contain
about 12 per cent of available phosphoric acid and from
3 to 4 per cent of insoluble phosphoric acid. They also
contain some nitrogen. Bone ash and bone black super-
phosphates contain practically all their phosphorus in an
available form, but they contain little or no nitrogen.
South Carolina rock superphosphate contains from 12 to
14 per cent of available phosphoric acid, including from
1 to 3 per cent of reverted phosphoric acid. The best
Florida rock superphosphates contain from 17 per cent
downward of available phosphoric acid, some of which is
reverted. ‘The Tennessee superphosphates contain from
14 to 18 per cent of available phosphoric acid.

Double superphosphates. —In making superphosphates
a material rich in phosphorus must be used, not less than
60 per cent of tricalcium phosphate being necessary for
their profitable production. The poorer materials are
sometimes used in making what is known as double super-
phosphates. For this purpose they are treated with an
excess of dilute sulfuric acid; the dissolved phosphorus
and the excess of sulfuric acid are separated from the mass
by filtering, and are then used for treating phosphates
rich in tricalcium phosphate and thus forming superphos-
phates. The superphosphates so formed contain more
than twice as much phosphorus as those made in the
ordinary way.

433. Reverted phosphoric acid. — A change sometimes
occurs in superphosphates on standing by which some of

516 SOILS: PROPERTIES AND MANAGEMENT

the phosphoric acid becomes less easily soluble, and to
that extent the value of the fertilizer is decreased. This
change, known as reversion, is much more likely to occur
in superphosphates made from rock than in those derived
from bone. It will also vary in different samples, a well-
made article usually undergoing little change even after
long standing. It is supposed to be caused by the presence
of undecomposed tricalcium phosphate and of iron and
aluminium sulfates.

434. Relative availability of phosphate fertilizers. —
Superphosphates and double superphosphates contain
their phosphorus in a form in which it can be taken up
by the plant at once. They are therefore best applied
at the time when the crop is planted, or shortly before,
or they may be applied when the crop is growing. Crude
phosphates, on the other hand, become available only
through the natural processes in the soil. They should
be applied in quantity sufficient to meet the needs of the
crops for a number of years.

Reverted phosphorus, although not soluble in water,
is readily soluble in dilute acids. It is now generally
believed that in this form an available supply of phos-
phorus is furnished to the plant. In a statement of fer-
tilizer analyses reverted phosphorus is termed cttrate-
soluble, and this and the water-soluble are termed available.

The degree of fineness to which the material is ground
makes a great, difference in the availability of the less
soluble phosphate fertilizers, especially in the ground-rock
phosphates and in ground bone. This material should be
ground fine enough to pass through a sieve having meshes
at least one-fiftieth of an inch in diameter.

435. Changes that occur when superphosphate is added
to soils. — When incorporated with soils superphosphate

COMMERCIAL FERTILIZERS 517

undergoes changes, the nature o: which depends more or
less on the properties of the particular soil with which it
is mixed. No matter how readily soluble the phosphorus
may be in the fertilizer, it soon becomes insoluble in the
soil, only a fractional proportion of it being recoverable in
water extracts. Absorption by colloidal complexes is the
fate of a part of the phosphorus, in which condition it is
still available to plants, especially when the colloidal
matter becomes coagulated. The excess phosphorus en-
ters into combination with the calcium of the soil, form-
ing tricalcium phosphate and some dicalcium phosphate,
and with the iron or the aluminium, forming phosphates of
those metals. The latter compounds are less readily soluble
than the former, and probably do not serve as a direct
source of phosphorus for plants; while tricalcium phosphate,
although acted upon by plant roots, is not so readily avail-
able as is the phosphorus held by the colloidal matter.

It is desirable that there should be an abundant supply
of calcium in a soil to which a superphosphate is added, be-
cause the phosphorus not absorbed by the colloidal matter
of the soil will, under such circumstances, form more cal-
cium phosphate than if only a small supply of lime is pres-
ent, according to the law of mass action. The great. loss
of availability through the conversion of phosphorus into
iron and aluminium phosphates may thus be mitigated.

436. Other factors influencing the availability of tri-
calcium phosphate. — As this is the form in which phos-
phorus is probably most extensively held in the ordinary
soil, and as it is also a cheap form of phosphorus in manures,
it is a matter of some importance to know the most favor-
able conditions for its utilization by agricultural plants.
Experimentation by numerous investigators has estab-
lished at least four factors that influence the availability

518 SOILS: PROPERTIES AND MANAGEMENT

of this substance: (1) kind of plant grown; (2) degree of
basicity of soil; (38) fermentation of organic matter;
(4) character of the accompanying salts.

437. Effect of plants on the availability of tricalcium
phosphate. — It is to be expected that the various kinds
of plants should not all exert an equal influence on the
availability of the phosphorus of tricalctum phosphate.
Prianischnikov! found that lupines, mustard, peas,
buckwheat, and vetch responded to fertilization with raw
rock phosphate in the order named, while the cereals did
not respond at all. He did not include maize in his
experiments, but that crop is said to respond well to diffi-
cultly soluble phosphates. It is generally considered
that those plants which have a long growing season are
better able to utilize tricalcium phosphate than are more
rapidly growing plants. An explanation for the ability
of some plants to utilize the phosphorus of difficultly
soluble phosphates more successfully than do other plants
has been sought in the rate of excretion of carbon dioxide
by plant roots. It has already been stated (par. 324) that
Stoklasa and Ernst found that the capacity of a plant to
absorb phosphorus from difficultly soluble phosphates is
proportional to the rate at which carbon dioxide is given
off by the roots, but that the experiments of Kossowitch
and Barakoff failed to confirm these results. This ques-
tion is bound up with the larger one involving the solvent
action of plant roots, regarding which little is now known.

438. Effect of basicity on the availability of tricalcium
phosphate. — It is recognized that raw rock phosphate is
more available to the same plant in some soils than in
others, and a number of persons have stated, as the result

1Prianischnikov, D. Bericht uber Verschiedene Versuche
mit Rohphosphaten unter Reduction. Moscow. 1910.

COMMERCIAL FERTILIZERS 519

of experimentation, that the availability is greater in acid
soils than in those strongly basic. If acidity of the soil
is due to the presence of free acid (positive acidity), it is
conceivable that the availability may be due to the sol-
vent action of the soil acid on the calcium of the trical-
cium phosphate, producing the dicalcium salt which ap-
pears to be fairly readily available to plants. When,
however, soil acidity is due to a lack of basicity (apparent
acidity), the case is different. Gedroiz! explains this
on the basis of the absorptive properties of the apparently
acid soil. He regards rock phosphate, not as a chemical
compound, but as a solid solution of dicalcium phosphate
with lime. It is this excessive basicity of the phosphate
which is responsible for its unavailability. Absorption of
the excess calcium would leave the phosphate in a more
readily available condition by forming the dicalcium salt,
and this is brought about in an apparently acid soil.
Gedroiz experimented with a highly basic soil that did
not respond to fertilization with rock phosphate. He
subjected this soil to repeated washings with distilled
water charged with carbon dioxide. After such treatment
the soil gave a marked increase in crop with rock phos-
phate as compared with the same soil untreated. Accord-
ing to Gedroiz the greater availability of the phosphate
after treatment with carbonic acid was due to the removal
of bases and the greater absorptive power of the soil
brought about thereby. This was further corroborated
by the fact that the treated soil responded to a test for
unsaturation while the untreated soil did not. Without

1Gedroiz, K. K. Soils to which Rock Phosphates may
be Applied with Advantage. Jour. Exp. Agronomy (Russian),
Vol. 12, pp. 529-539, 811-816. 1911. The authors are in-
debted to Dr. J. Davidson for the translation.

5920 SOILS: PROPERTIES AND MANAGEMENT

necessarily accepting all of Gedroiz’s explanation of the
phenomenon, there can be little doubt that lack of basicity
is a factor in the availability of raw rock phosphates in
some soils.

439. Influence of fermenting organic matter. — There
has been great difference of opinion among investigators
as to the effect of fermentation of organic matter on the
availability of the phosphorus of tricalctum phosphate.
The contention that the availability is increased probably
originated with Stoklasa,' the results of whose experi-
ments with bone meal indicated that the availability is
increased by fermentation. A large number of experi-
ments have been conducted with raw rock phosphate
composted with stable manure, among which may be
mentioned those by Hartwell and Pember? and also by
Tottingham and Hofiman® who in carefully conducted
experiments failed to find that the availability of the raw
phosphate was increased by fermentation with stable
manure. Opposing results have also been obtained, how-
ever, and the evidence is somewhat conflicting. Kréber,*
who thinks that the action of bacteria is due to the acids
they produce, explains the contradictions in the various

1 Stoklasa, J., Duchacek, F., and Pitra, J. Ueber den Ein-
fluss der Bakterien auf die Knochenzersetzung. Centrlb. f.
Bakt., IIT, Band 6, Seite 526-535, 554-558. 1900.

2 Hartwell, B. L., and Pember, F. R. The effect of cow dung
on the availability of rock phosphate. Rhode Island Agr.
Exp. Sta., Bul. 151. 1912.

’Tottingham, W. E., and Hoffman, C. The Nature of the
Changes in Solubility and Availability of Phosphorus in Fer-
menting Mixtures. Wisconsin Agr. Exp. Sta., Research Bul.
29. 1918.

4Kréber, EH. Ueber das Léslichwerden der Phosphorsaure
aus Wasserunléslichen Verbindungen unter der Hinwirkung

von Bakterien und Hefen. Jour. f. Landw., Band 57, Seite
5-80. 1909-1910.

COMMERCIAL FERTILIZERS 621

experiments as arising from the different kinds of fer-
mentation that the organic matter undergoes. He thinks
that acid fermentation renders the phosphate more readily
soluble, while fermentation that does not give rise to acids
leaves it in an insoluble condition.

Parallel with the biological process that results in the
transformation of insoluble phosphates into soluble, there
is, according to Stoklasa and others, a reverse biological
process resulting in the transformation of soluble phos-
phates into insoluble.

Whatever may be the conditions under which raw rock
phosphate is rendered more readily soluble or available
by fermentation of organic matter, it does not appear
that composting with stable manure produces this change,
at least from results of numerous experiments including
those mentioned above. These have been mainly opposed
to any such conclusion.

440. Influence of other salts. — The presence of cer-
tain salts has been found to influence the availability of
difficultly soluble phosphates. The subject has been in-
vestigated by a large number of experimenters and it will
be possible to summarize their results only in part and
very briefly. It has been found, for instance, that cal-
cium carbonate decreases the availability of raw rock
phosphate and bone-meal. Sodium nitrate reduces the
availability of the tricalcium phosphates, while the am-
monium salts increase their availability. Iron salts
decrease availability. The influence of other salts has not
been so well worked out. Prianischnikov,' as the result
of his extended experiments on the subject, holds that

1 Prianischnikov, D. Ueber den Hinfluss yon Kohlenséuren
Kalk auf die Wirkung von Verschiedenen Phosphaten. Landw.
Vers. Stat., Band 75, Seite 357-376. 1911.

522 SOILS: PROPERTIES AND MANAGEMENT

salts from which plants absorb acid in larger amounts
than they do bases decrease availability, or at least do not
affect it, while salts from which plants absorb the bases in
greater quantity than the acids have a tendency to render
the phosphate more available, because of the solvent
action of the acid.

FERTILIZERS USED FOR THEIR POTASSIUM

The production of potassium fertilizers is largely con-
fined to Germany, where there are extensive beds varying
from 50 to 150 feet in thickness, lying under a region of
country extending from the Harz Mountains to the Elbe
River and known as the Stassfurt deposits. Deposits
have lately been discovered in other parts of Germany.

441. Stassfurt salts. — The Stassfurt salts contain
their potassium either as a chloride or as a sulfate. The
chloride has the advantage of being more diffusible in the
soil, but in most respects the sulfate is preferable. Potas-
sium chloride in large applications has an injurious effect
on certain crops, among which are tobacco, sugar beets,
and potatoes. On cereals, legumes, and grasses, the
muriate appears to have no injurious effect.

The mineral produced in largest quantities by the
Stassfurt mines is kainit. Chemically it consists of mag-
nesium and potassium sulfate and magnesium chloride,
or of magnesium sulfate and potassium chloride. Kainit
has the same effect on plants as has potassium chloride.
It contains from 12 to 20 per cent of potash and from 25
to 45 per cent of sodium chloride, with some chloride and
sulfate of magnesium.

Kainit should be applied to the soil a considerable
time before the crop for which it is intended is planted.

COMMERCIAL FERTILIZERS 528

It should not be drilled in with the seed, as the action of
the chlorides in direct contact with the seed may injure
its viability. In addition to the potassium added to the
soil by kainit, there are also in this fertilizer magnesium
and sodium. The magnesium may be objectionable if
there is much already present in the soil (see par. 458).
Sodium may to some extent replace potassium in the soil
economy, and in that way may be beneficial.

Silvinit contains its potassium both as chloride and as
sulfate. It also contains sodium and magnesium chlorides.
Potash constitutes about 16 per cent of the material.
Owing to the presence of chlorides, it has the same effect
on plants as has kainit.

The commercial form of potassium chloride generally
contains about 80 per cent of potassium chloride or 50
per cent of potash. The impurities are largely sodium
chloride and insoluble mineral matter. The possible
injury to certain crops from the use of the chloride has
already been mentioned. For crops not so affected, potas-
sium chloride is a quickly acting and effective carrier of
potassium, and one of the cheapest forms.

High-grade ‘sulfate of potassium contains from 48 to
50 per cent of potash. Unlike the muriate it 1s not in-
jurious to crops, but is more expensive.

There are a number of other Stassfurt salts, consisting
of mixtures of potassium, sodium, and magnesium in the
form of chlorides and sulfates. They are not so widely
used for fertilizers as are those mentioned above.

442. Wood ashes. — For some time after the use of
fertilizers became an important farm practice, wood
ashes constituted a large proportion of the source of supply
of potassium. They also contain a considerable quantity
of lime and a small amount of phosphorus. The product

524 SOILS: PROPERTIES AND MANAGEMENT

known as unleached wood ashes contains from 5 to 6 per
cent of potash, 2 per cent of phosphoric acid, and 30 per
cent of lime. Leached wood ashes contain about 1 per cent
of potash, 1} per cent of phosphoric acid, and from 28 to 29
per cent of lime. They contain the potassium in the form
of a carbonate, which is alkaline in its reaction and in large
amount may be injurious to seeds. They are beneficial
to acid soils through the action of both the potassium and
calcium salts. The lime is valuable for the other effects it
has on the properties of the soil. (See pars. 454-457.)

443. Insoluble potassium fertilizers. — Insoluble forms
of potassium, existing in many rocks usually in the form
of a silicate, are not regarded as having any manurial
value. Experiments with finely ground feldspar have been
conducted by a number of investigators, but have, in the
main, given little encouragement for the successful use of
this material. An insoluble form of potassium is not
given any value in the rating of a fertilizer based on the
results of its analysis.

SULFUR AND SULFATES AS FERTILIZERS

The use of these substances as a means of increasing
plant growth when applied to soils has recently received
revived attention. The use of free sulfur has been in-
vestigated to some extent in France and Germany. There
have been suggested three ways in which it may be bene-
ficial to plants (1) as a direct stimulant; (2) by its in-
fluence on the activities of microédrganisms; (3) as a
source of plant-food, which might otherwise be deficient.

444, The use of free sulfur.— Boullanger! added
flowers of sulfur to a soil at the rate of 23 parts to a million

1 Boullanger, HE. Action du soufre en fleur sur la végétation.
Compt. Rend. Acad. Sci. Paris, T. 154, pp. 369-370. 1912.

COMMERCIAL FERTILIZERS 525

of soil. He obtained increased growth in all treated soils
on which carrots, beans, celery, lettuce, sorrel, chicory,
potatoes, onions, and spinach were grown, the weight of
the crops on the treated soil being from 10 per cent to 40
per cent greater than those on the untreated soil. On
soils that had been sterilized before applying sulfur the
effect was much less, from which he concludes that the
beneficial effects were due to the influence of the sulfur
on the microérganisms of the soil. There may be some
question, however, whether this conclusion is justifiable.
Sulfur was found by Boullanger and Dugardin! to favor
ammonification in soils. Beneficial effects from the use
of free sulfur have also been obtained by Demelon,? and
by Bernhard * among others, while von Feilitzen* found
it to be ineffective as a fertilizer.

That free sulfur may, under some conditions, exert a
beneficial influence on plant growth must undoubtedly be
conceded, but how the action is brought about remains to
be conclusively demonstrated. Free sulfur is insoluble and
cannot be absorbed by plant roots. However it is readily
oxidized in soils® eventually producing sulfates with bases in
the soil and in this form may readily be taken up by plants.

1 Boullanger, E., and Dugardin, M. Mecanisme de l’action
fertilisante du soufre. Compt. Rend. Acad. Sci. Paris, T. 155,
pp. 327-329. 1912.

2Demelon, A. Sur l’action fertilisante du soufre. Compt.
Rend. Acad. Sci. Paris, T. 154, pp. 524-526. 1912.

3 Bernhard, A. Versuche uber die Wirkung des Schwefels als
Dung im Jahre 1911. Deutsche Landw. Presse. Band 39, p. 275.
1912.

4von Feilitzen, H. Ueber die Verwendung der Schwefel-
blute zur Bekampfung des Kartoffelschorfes und als indirektes
Dungemittel. Fuhling’s Landw. Zeit. Band 62, Seite 7.

5 Mares, M. N. Des transformations que subit le soufre

en poudre quand il es reponds sur le sol. Compt. Rend. Acad.
Sci. Paris, T. 69, pp. 974-979.

526 SOILS: PROPERTIES AND MANAGEMENT

445. Sulfur as sulfate. — There is less experimental
evidence regarding the effect of sulfur in the form of
sulfate on plant growth than there is for the free sulfur.
The fact that the bases with which the sulfate is com-
bined are likely to have an effect on plant growth, makes
the accumulation of proof by experimentation a somewhat
more difficult matter. That there may be a possible de-
ficiency of sulfur in arable soils has been pointed out by
several investigators, including Hart and Peterson! in
this country. They point out that crops remove more
sulfur from the soil than was shown by the early deter-
minations of sulfur in plant ash, from which a large part
of the sulfur was volatilized during the process. They
then proceed to calculate the sulfur removed by a num-
ber of crops on the basis of their own methods and
compare this with the phosphorus in similar crops.

Pounps Suutrur TrRrioxipE AND PuospHorus PENTOXIDE
REMOVED TO THE AcRE BY AVERAGE CROPS

CoNTENT IN POUNDS TO THE

CROP AND YIELD TO THE ACRE ACRE

SOs P20s
Wheat (380 bu.) . 2. 2. 2. ww, 15.7 21.1
Barley (40 bu.). . . . . . 14.3 20.7
Oats (45 bu.) . . . 2... 19.7 19.7
Corn (80 bu.) . . toe 12.0 18.0
Alfalfa (9000 Ib. dry wt. ) toe ee 64.8 39.9
Turnips (4657 lb. dry wt) . . . 92.2 39.1
Cabbage (4800 lb. dry wt.) . . .. 98.0 61.0
Potatoes (8360 Ib. dry wt.) . . 11.5 21.5
Meadow hay (2822 lb. dry wt. ) wok 11.3 12.3

1 Hart, E. B., and Peterson, W. H. Sulphur requirements
of farm crops in relation to the soil and air supply. Wisc.
Agr. Exp. Sta., Research Bul. No. 14. 1911.

COMMERCIAL FERTILIZERS 527

They then call attention to the quantities of sulfur
trioxide contained in average soils which, as shown by
Hilgard, are less than the quantities of phosphorus pen-
toxide.

Conrentr IN POUNDS TO THE

ACRE
SQs3 P2Os
Sandy soils . . ...... . 1650 2610
Clay soils. . . .....¢%.~. 2250 4230

To ascertain whether the supply of sulfur in the soil
is really depleted by cropping, the same authors made
parallel determinations of sulfur in five virgin soils and
in five soils of the same respective types that had been
cropped for sixty years. In each type the cropped soil
contained less sulfur than the virgin soil, the average for
the cropped soils being .053 per cent SO; and for the
virgin soils .085 per cent SOs.

There is no doubt that the quantity of sulfur carried
down by rain and snow is much less than that removed
in drainage water. There can be no question therefore
that most soils, and especially cultivated soils, are losing
more sulfur than they receive by natural processes.

It has been customary to add to soils manures of one
kind or another that contain more or less sulfur. Among
these are farm manure and other animal or bird excre-
ments, residues of crops, animal offal, gypsum or land
plaster, superphosphate, ammonium sulfate, potassium
sulfate, kainit, and the like, all of which contain conse-
quential quantities of sulfur. It seems probable that

528 SOILS: PROPERTIES AND MANAGEMENT

any system of soil management that does not include
one or more of these substances would probably, on some
soils at least, be improved by making provision for the
application of sulfur in some form.

CATALYTIC FERTILIZERS

The term catalytic fertilizers has been used rather
loosely to designate a class of substances that, when added
to a soil, increase plant growth by apparently accelerating
the processes that normally take place in soils. They
do not function as fertilizers because their value does not
lie in the nutrients that they possess, but they may
properly be classed as soil amendments. However,
substances not classed as catalyzers, such as lime, have
such action, and in all probability most of the fertilizers
do also, so that it is difficult to draw any definite distinc-
tion and the term will doubtless be used only temporarily.

446. Nature of catalytic action. — The term catalysis
is employed in a chemical sense to mean a change brought
about in a compound by an agent that itself remains
stable. As an example of this may be cited the part that
hydrochloric acid plays in the inversion of cane sugar,
the acid not entering into the reaction but by its presence
greatly accelerating it. When an attempt is made to
study these phenomena in soils, it becomes difficult,
owing to the multiplicity of factors and reactions, to
determine whether the agent is acting in a purely cata-
lytic manner.

447. Catalytic action of soils. — Most soils themselves
act as catalyzers in so far as they hasten the decomposition
of hydrogen peroxide. Many substances, both organic
and inorganic, have this property, and it is not necessarily

COMMERCIAL FERTILIZERS 529

entirely lost to the soil after the organic matter has been
destroyed by ignition. It is therefore not due to an
enzyme, as stated by Konig, Hasenbiumer, and Coppen-
rath,' who first investigated the subject, nor entirely to
organic substances in the soil. Doubtless there are several,
or perhaps many, activating substances any of which have
this property. It is altogether likely that other catalyzers
exist in soils, and that they affect various reactions that are
concerned in plant production. Among these substances,
as pointed out by Konig, Hasenbéumer, and Coppenrath,?
are manganese and iron oxides, which are well known to
exert catalytic action on certain reactions. While soils
naturally possess certain catalytic powers, it seems possible
to still further activate some soils by proper applications
of so-called catalytic fertilizers.

Organic matter is doubtless concerned in the catalytic
properties of soils, and the investigators just mentioned
found that in six soils the catalytic action stood in almost
direct relation to the humus content; Sullivan and Reid?
however, did not find this correlation to hold. Both
organic and inorganic substances are involved in this
property of soils, but the forms in which they operate
are not well understood. In the main productive soils
have a strong catalytic effect and very poor soils are weak
in this respect, but this correlation also is not constant.

1 Konig, J.. Hasenbiumer, J., and Coppenrath, E. Hinige
Neue Higenschaften des Ackerbodens. Landw. Vers. Stat.,
Band 63, Seite 471-478. 1905-1906.

2 Konig, J., Hasenbiumer, J., and Coppenrath, E. Bezieh-
ungen zwischen den Higenschaften des Bodens und der N&br-
stoffaufnahme durch die pflanzen. Landw. Vers. Stat., Band
66, Seite 401-461. 1907.

$ Sullivan, M. X., and Reid, F. R. Studies in Soil Catalysis,
U.S. D. A., Bur. Soils, Bul. 86. 1912.

580 SOILS: PROPERTIES AND MANAGEMENT

448. Substances used as catalytic fertilizers. — A
large number of substances have been found to act as
catalytic fertilizers. Among these are various salts of
manganese, iron, aluminium, zinc, lead, copper, nickel,
cobalt, uranium, boron, cerium, lanthanum, and the like.
These substances stimulate plant growth when used in
small quantities, and are toxic in large amounts. In
water cultures a much less quantity of any of them is
required to produce an injurious action on plant growth
than when applied to an equal volume of soil. The
absorptive properties of the soil and the less ready diffusi-
bility serve to mitigate the toxic action.

Different kinds of plants respond differently to the same
concentration of any of these substances. For instance,
Montemartini! found that uranium, copper, zinc, alumin-
ium, and cadmium oxides retard the germination of beans
and accelerate the germination of maize when used in equal
concentrations.

Of the various plant stimulants mentioned, manganese
is the only one that gives promise, at the present time,
of usefulness on a commercial basis, and it is the only one
that will receive separate treatment in this book.

449. Manganese.-- It seems probable that all soils
contain manganese, but the quantity present in some
soils is very small, often being less than 0.01 per cent;
in other soils, however, more than 1 per cent is found,
and Kelly? reports an Hawaiian soil containing 9.74 per

1 Montemartini, L. Quoted with other experiments on this
subject by N. H. J. Miller, in Annual Reports on the Progress
of Chemistry, Vol. 10, pp. 229-230. 1914.

2 Kelly, M. P. The Influence of Manganese on the Growth
of Pineapples. Jour. Indus. and Eng. Chem., Vol. 1, p. 533.
1909.

COMMERCIAL FERTILIZERS 5381

eent of Mn,0,. Sullivan and Robinson! examined
twenty-six American soils and found the content of MnO
to vary from 0.01 to 0.51 per cent, the average being
0.071 per cent.

Manganese is a universal constituent not only of soils,
but likewise of plants grown under natural conditions;
in plants the quantities present vary much more than in
soils, and range from a few tenths of one per cent to nearly
one-half of the total ash. However, plants may be pro-
duced in water cultures or other media in which apparently
no manganese is present and a normal growth and fructi-
fication will follow. It is evident, therefore, that any
benefit to plant growth that may accrue through the
addition of manganese to the soil is not due to its function
as a nutrient material in the sense in which nitrogen,
potassium, and phosphorus act in that capacity.

450. Physiological réle of manganese. — It was the
discovery by Bertrand ? of the existence of manganese in
the oxidizing enzymes of plants and of its function in
stimulating the oxygen-carrying power of these catalytic
agents that suggested its use as a stimulating agent in
crop production. In water cultures a very dilute solution
of manganese salts increases plant growth, but beyond a
very low concentration its effect is toxic. Plants differ
widely in their response to manganese, with respect both
to stimulation and to injury. A certain concentration
may be stimulating to one plant and toxic to another.

Experiments in the application of manganese salts

1 Sullivan, M. X., and Robinson, W. O. Manganese as a
Fertilizer, U.S. D. A., Bur. Soils, Cire. 75. 1912.

2 Bertrand, G. Sur l’Action Oxydante des Sels Manganeux
et sur la Constitution Chemique des Oxydases. Compt. Rend.
Acad. Sci. Paris, Tome 124, pp. 1355-1358. 1897.

582 SOILS: PROPERTIES AND MANAGEMENT

to soils have not afforded as satisfactory results as have
the trials with water cultures. Applications of a certain
salt of manganese, when applied at the same rates to
different soils, have in some cases produced increased
growth, have in other cases had no apparent effect, and
have in still other cases proved injurious to plants. The
reason for this is doubtless to be found in the inherent
properties of the particular soil to which the application
is made.

451. Action of manganese as a fertilizer. — The fact
that manganese stimulates plant growth in water cultures
is very good evidence that it has at least a direct action
on the plant. Whether it has a further influence through
reactions brought about in the soil 1s less evident, although
it seems likely that such is the case. Thus, Skinner and
Sullivan! conclude from some of their experiments that
oxidation in some soils is increased by the application of
manganese salts. It also seems probable that manganese
may have some influence on the activity of the microor-
ganisms of the soil, but this has not been definitely demon-
strated.

452. Forms of manganese and response of soils. —
The manganese salts that have been found to be effective
as fertilizers are the sulfate, the chloride, the nitrate, the
carbonate, and the dioxide. Of these the first has -been
most generally used, and in quantities up to 50 pounds
an acre It has in most cases not been toxic. On acid
soils it is not supposed to exercise any beneficial action,
and on very productive soils Skinner and Sullivan, in
the experiments cited above, found it to be ineffective;

1Skinner, J. J., and Sullivan, M. X. The Action of Man-
ganese in Soils. U.S. D.A., Bul. 42. 1914.

COMMERCIAL FERTILIZERS 538

while they obtained appreciable benefit from its use on
poor soils. They argue that since very productive soils
have great oxidative power the use of manganese is un-
necessary, but since poor soils undergo insufficient oxida~
tion the stimulation that this process receives by the
application of manganese is productive of much good.
Accordingly manganese is most profitably used on poor
soils not deficient in lime.

CHAPTER XXIV

SOIL AMENDMENTS

Certain substances are sometimes added to soils for
the purpose of increasing productiveness through their
influence on the physical structure of the soil, and thereby
on the chemical and bacteriological properties. These
substances are called soil amendments. It is true that
they may add essential plant ingredients to the soil, but
that function is of minor importance.

453. Salts of calcium. — Calcium, although essential
to plant growth, seldom needs to be added to the soil to
supply the plant directly; but because of its effect on the
soil properties, its use is beneficial to a great number of
soils.

454. Effect on tilth and bacterial action. — On clay
soils the effect of lime is to bring the fine particles into
aggregates which are loosely cemented by calcium carbon-
ate. The effect of this structure on tilth has already been
explained (par. 120). On sandy soils the carbonate of
calctum serves to bind some of the particles together,
making the structure somewhat firmer and increasing the
water-holding power. It should be used only in small
quantities on sandy soils.

There is a tendency for most cultivated soils to become
acid, as has already been explained (par. 283). Acidity
may reach a point where it becomes directly injurious to
certain plants, but it becomes indirectly injurious before

534

SOIL AMENDMENTS 5385

that point is reached. One way in which this occurs is
by curtailing the quantity of calcium carbonate in the
soll. An easily available base to combine with the
organic acids affords the most favorable condition for the
decomposition processes due to bacterial action, and
hence the best results cannot be obtained where carbonate
of lime is not present. Its action in improving tilth also
facilitates desirable forms of bacteriological activity by
increasing the permeability of the soil for air.

455. Liberation of plant-food materials. — It has been
stated that the alkalies and the alkaline earths are more
or less interchangeable in certain compounds in the soil.
The addition of lime may in this way liberate potassium,
when otherwise it would be difficult for crops to obtain
a sufficient supply from a particular soil. The substitu-
tion of bases has been discussed (par. 251) and the
liberation of potassium is in accord with these phenomena.
Magnesium, although rarely deficient, may also be made
available in this way. The use of calcium salts may,
under some soil conditions, render phosphorus more use-
ful, probably by supplying a base more soluble than iron
or alumina, with which, in soils deficient in calcium, the
phosphorus might otherwise be combined. Experiments
by Prianischnikov,! in which plants were grown in washed
sand containing Hellriegel’s nutrient solution to which
mono-, di-, and tri-calcium phosphate respectively were
added, both with and without calcium carbonate, showed.
a decreased availability of the tricalcium phosphate due
to the presence of the carbonate, but neither a reduced
nor an increased availability of the other forms of phos-

1 Prianischnikov, D. Ueber den Einfluss von Kohlensauren
Kalk auf die Wirkung von Verschiedenen Phosphaten. Landw.
Vers. Stat., Band 75, Seite 357-376. 1911.

586 SOILS: PROPERTIES AND MANAGEMENT

phorus arising from the presence of carbonate. Neither
did the availability of iron or aluminium phosphate
appear to be influenced by calcium carbonate.

These and recent experiments by Simmermacher? and
others tend to discredit the earlier conclusions as quoted
above and as set forth by Dehérain ? regarding the favor-
able influence of lime on the availability of phosphorus.
However, the preponderating evidence is still with the
earlier experimenters. The principles that underlie the
effect of lime on availability of phosphorus are discussed
in paragraphs 259 and 260.

456. Influence of lime on the formation of nitrates in
soil.— It has already been remarked that nitrification
proceeds very slowly in acid soils. A _ soluble base
must be present with which the nitric acid may com-
bine, otherwise the process will be inhibited by the toxic
effect of the acid on the bacteria concerned in the forma-
tion of the acid. The addition of lime is the most
economical method of providing the base. This is
often a matter of great moment for crops that respond
readily to nitrate nitrogen, and is one of the important
reasons for applying lime to sour soils. The fact that
some plants grow better in some soils than in strongly
basic ones is also an indication that such plants absorb
a considerable part of their nitrogen in forms other than
nitrates.

Many investigators have found that the presence of
calcium carbonate promotes the ammonifying and nitrify-
ing process. The addition of calcium carbonate to a

1Simmermacher, W. Einwirkung der Kohlensauren Kalkes
bei der Dungung von Haferkulturen mit Mono- und Diecaleium
Phosphat. Landw. Vers. Stat., Band 77, Seite 441-471. 1912.
* Dehérain, P. P. Traité de Chemie Agricole, p. 525. 1892.

SOIL AMENDMENTS 5387

sandy loam soil was found by Kellerman and Robinson }
to favor the formation of nitrates up to an application
of 2 per cent, which is much more than would ever be
applied in practice. It must be kept in mind, however,
that this limit does not apply to all soils, as the absorp-
tive properties of the soil for lime will determine the
maximum application that may profitably be made.
Kellerman and Robinson found also that the application
of magnesium carbonate in excess of 0.25 per cent in-
hibited the formation of nitrates. Kelly? also has
recently reported that the addition of magnesium car-
bonate to the soils with which he experimented resulted
in a marked depression of both ammonification and nitri-
fication, and that the addition of calcium carbonate did
not overcome this depressing influence.

457. Effect on toxic substances and plant diseases. —
Free acids are toxic to most agricultural plants. Some
plants are much more sensitive than others. Alfalfa,
for example, should have a slightly alkaline medium for
its best growth, and any acid is very injurious. Calcium
salts, in neutralizing acidity, remove this toxic condition.
A liberal application of lime is therefore a precaution
against injury of this kind.

The presence of soluble calcium, with its effects on the
soil, retards the development of certain plant diseases,
such as the “ finger and toe’”’ disease of the Cruciferz.
On the other hand, it may promote some diseases, as, for
example, potato scab.

1 Kellerman, K. F., and Robinson, F. R. Lime and Legume
Tnoculation. Science, n. s., Vol. 32, pp. 159-160. 1910.

2 Kelly, W. P. The Effect of Caletum and Magnesium Car-
bonates on Some Biological Transformations of Nitrogen in

Soils. Univ. of Calif. Pub., Agr. Sci., Vol. 1, No. 3, pp. 39-49.
1912.

588 SOILS: PROPERTIES AND MANAGEMENT

458. The lime-magnesia ratio. —The physiological
balancing of magnesium by calcium was first worked out
by Loew,! and the ratio in which these two cations should
exist in nutrient solutions in order to secure the best
growth of certain agricultural plants has been very satis-
factorily demonstrated by the experiments of many
investigators. The optimum ratio varies with different
kinds of plants, and in general the calcium must exceed
the magnesium in amount, but there is a limit beyond
which it should not be present. If calcium alone is
present, it acts as a toxic agent on the plant, and mag-
nesium acts in a similar way. It is only when the ratio
between these cations falls within certain limits that
they exert no toxic action. This ratio varies between
one part of calcium oxide to one part of magnesium
oxide, and seven parts of calcium oxide to one part of
magnesium oxide.

In the soil the relations of calcium and magnesium to
plant growth are not so simple. It is impossible to
determine the actual or the relative quantities of these
cations that are available for absorption by the plant.
This is mainly because of the absorptive properties of
soils, by which they remove the bases from solution and
hold them in a somewhat difficultly soluble form. The
ratio of calcium to magnesium is not likely to disturb
crop yields in soils unless the quantity of magnesium
present happens to be very large. Gile and Ageton?
have found ordinarily fertile soils having ratios as high

1Loew, O. The Physiological Réle of the Mineral Nutrients
of Plants. U.S. D. A., Bur. Plant Indus., Bul. 1, p. 53. 1901.

*Gile, P. P., and Ageton, C. U. The Significance of the
Lime-Magnesia Ratio in Soil Analyses. Journ. Indus. and
Eng. Chem., Vol. 5, pp. 33-85. 1913.

SOIL AMENDMENTS 539

as 500 CaO to 1 MgO by weight. On the other hand,
excessive applications of magnesium compounds have
been found to be injurious on some soils. Even on a
very heavy clay soil, at Cornell University, an applica-
tion of 1333 pounds to the acre of magnesite markedly
decreased the yields of sorghum and oats. The soil
originally contained about equal parts of calcium and
magnesium.

459. Forms of calcium.— Calcium is used on the
soil in the form of calcium oxide, or quicklime (CaO),
water-slaked lime (Ca(OH).), air-slaked lime (CaCQ,),
ground limestone, marl (also a carbonate), and calcium
sulfate, or gypsum (CaSO..2H,O). The application of
any of these is usually called liming the soil, although
gypsum does not serve exactly the same purpose as do
the other forms. Owing to differences in the molecular
weights of these compounds of calcium, it requires more
of some forms than of others to furnish the same amount
of calcium. Approximately equivalent quantities of some
of the common forms when fairly pure are : —

Quicklme ........... . . 56 pounds
Water-slaked lime .. . . . . . 74 pounds
Air-slaked lime, marl, and ground limestone 100 pounds

Quicklime, and the hydrate, when added to the soil, even-
tually assume some of the more insoluble forms of com-
bination or remain as the carbonate, never being present
as the oxide. It is always desirable to have present in the
soil at least a small amount of calcium carbonate.

460. Caustic limes. — Quicklime and water-slaked lime
have a markedly alkaline reaction, and hence neutralize
quickly any active acidity that may exist in the soil.
They act quickly also in liberating plant-food, particularly

540 SOILS: PROPERTIES AND MANAGEMENT

nitrogen. Some soils respond more rapidly to quicklime
or water-slaked lime than to carbonate of lime, evpecially
when the carbonate is in the form of marl or ground lime-
stone, these substances never being in such a finely pul-
verized condition as is caustic lime. The use of the
caustic forms of lime has been said to result in the loss
of nitrogen by the too rapid decomposition of organic
compounds.

On clays the granulating effect of caustic lime is more
marked than that of the carbonate, and for this reason
the former has a distinct advantage for use on heavy clay.
For the same reason an occasional moderate dressing is
better than a heavy dressing given less frequently.

461. Carbonate of lime. — Air-slaked lime has the
advantage of being in a finely divided condition, and
does not produce the injurious action on organic matter
that is sometimes attributed to caustic lime. Its effect
on the granulation of clay soils is probably less pro-
nounced than that of caustic lime.

Marl (par. 27) differs from air-slaked lime principally
in its property of being in a less finely pulverized condi-
tion. It acts less quickly than does caustic lime. Owing
to the fact that marl deposits differ greatly in the com-
position of their products, it is well to know the quality
of the material before buying it. The carbonate of lime
in marl may vary from 5 or 10 to 90 or 95 per cent in
different samples.

Ground limestone has been used extensively in recent
years. It is very important that it be finely ground, as
on the comminution of the material much of its efficiency
depends. However, it is doubtful whether there is any
advantage in making it finer than is required to pass
through a sieve with 50 meshes to the inch.

SOIL AMENDMENTS 541

462. Relative effectiveness of caustic lime and car-
bonate. — In order to test the value of ground limestone
and other forms of calcium carbonate, experiments in
which it was compared with caustic lime have been con-
ducted at some of the experiment stations. Reports of
tests at the Pennsylvania Experiment Station, in which
plats treated with slaked lime at the rate of two tons per
acre once in four years were compared with plats treated
with ground limestone at the rate of two tons to the acre
every two years, show that at the end of twenty years,
in every case, the total yields were greater on the plats
receiving ground limestone. After the treatment on
these plats had been continued for sixteen years, a de-
termination of nitrogen showed the upper nine inches of
soil on the limestone-treated plats to contain 2979 pounds
of nitrogen to the acre, and the slaked-lime plats to con-
tain 2604 pounds. It may be inferred from these figures
that the slaked lime caused a slightly greater destruction
of organic matter than did the limestone.

Patterson? also conducted experiments for eleven
years with caustic lime produced by burning both stone
and shells, and the carbonate of lime in ground shells and
shell marl. The average crops of maize, wheat, and hay
were all larger on the plats treated with carbonate of
lime.

While these experiments show, at first glance, results

1Waters, H. J., and Hess, EH. H. General Fertilizer Experi-
ments. Pennsylvania State College, Rept. 1894, Part 2, pp.
258-281. Also, Hunt T. F. Soil Fertility. Pennsylvania
Agr. Exp. Sta., Bul. 90. 1909.

2 Patterson, H. J. Lime, Sources and Relation to Agri-
culture. Maryland Agr. Exp. Sta., Bul. 66, pp. 127-130. 1900.
Also, Investigations on the Liming of Soils. Maryland Agr. Exp.
Sta., Bul. 110, pp. 16-21. 1906.

542 SOILS: PROPERTIES AND MANAGEMENT

rather favorable to the use of carbonate of lime, a careful
analysis of them by Wheeler! raises some doubt as to
the legitimacy of this interpretation. He points out, for
instance, that in the Pennsylvania experiments excessive
quantities of lime were used, and that no farm manure
nor commercial fertilizers were applied to the plats be-
tween which comparisons were made.

There is, unfortunately, a paucity of definite and con-
clusive data that may be applied to the solution of the
question as to the relative values of these different forms
of lime for use as soil amendments, but some information
has accumulated through experience and practice that
may be taken as a fairly safe guide in their use. It is
well known, for instance, that burned lime has a more
pronounced effect on soil granulation than has the car-
bonate, and may therefore be expected to be more bene-
ficial to heavy clay soils. On the other hand, burned
lime is not so desirable a form to apply to very sandy
soils, especially when they are likely to be dry, as there
is danger that organic matter will be destroyed.

463. Sulfate of calcium.— Gypsum, in which form
calcium sulfate is usually applied to soils, has been used
for many years and was a popular soil amendment in
this country before the common commercial fertilizers
were used to any great extent. It frequently went by
the name of land plaster, and, as it was rather widely
distributed in nature and not difficult to obtain, it was
ground and largely used in many localities throughout
the eastern states. Its popularity has waned in recent

1 Wheeler, H. J. Is the Recommendation that Only Ground
Limestone Should be Used for Agricultural Purposes a Sound
and Rational One? National Lime Manufacturers’ Assoc.,
Bul. 4. 1912.

SOIL AMENDMENTS 548

years, and its effectiveness has apparently decreased as
the soils on which it was used have been longer under
cultivation. Possibly this is due to the tendency of these
soils to become more acid, which has caused the gypsum
to be less effective in liberating potassium — a property
with which it has generally been credited. At present
gypsum is not very generally used on soils. It must be re-
membered, however, that superphosphates always contain
a considerable proportion of this material, and it may add
appreciably to the beneficial effects of that fertilizer.

Aside from its action in liberating potassium (the actual
extent of which has never been very clearly demon-
strated), gypsum serves to supply sulfur to the soil. The
sulfur, while it may be needed in some soils, has the dis-
advantage of being present as an acid; and if the acid
is added in larger quantity than is removed by plants,
there is a resulting loss of basic material in the drainage
water and a tendency for the soil to become sour.

The action of gypsum in improving tilth is less marked
than that of caustic lime or of the carbonate. Asa source
of calcium it is of no moment, as, if applied in such quan-
tities as those in which the other forms are used, the
sulfate would be very injurious. Ordinarily it is applied
at the rate of only a few hundred pounds to the acre at the
most. On the whole, gypsum is not an adequate substi-
tute for, nor so desirable a form of, calcium as the oxide,
the hydroxide, or the carbonate.

464. Common salt. — Sodium chloride has a marked
effect on some soils, but wherein its effectiveness lies
is not well understood. The addition of sodium and of
chlorine as plant constituents is clearly not the reason,
as these substances are always present in soils in avail-
able form far in excess of their requirements.

544 SOILS: PROPERTIES AND MANAGEMENT

The effect of sodium chloride on clay-bearing soils
is to liberate certain plant nutrients, among which are
calcium, magnesium, potassium, and phosphorus. This
action, although limited in amount, is probably, in some
cases at least, partly responsible for the beneficial action
of common salt.

The structure of the soil is improved by the applica-
tion of sodium chloride, just as it is by lime, although
usually not to the same extent.

Another effect of salt is to conserve and distribute
soil moisture. Its conserving action is probably due to
an increase in the density of the soil-water solution, thus
retarding transpiration. The film movement of water is
likewise increased by the presence of salt in the solution,
and in this way the upward movement of bottom water
is facilitated and the supply within reach of the roots
maintained in time of drought.

It has been seen that sodium is not one of the substances
essential to the growth of plants. But that sodium may
be substituted, in part, for the potassium absorbed by
agricultural plants in their normal growth, has been
shown in this country by the experiments of Wheeler
and Adams;! and the more ready availability of the
sodium applied as a chloride than of the potassium in
its natural condition in some soils probably accounts in
part for the beneficial effects of this salt.

It is not all soils, however, that are benefited by salt,
its usefulness not being of such wide application as that
of lime. Certain crops, as previously mentioned, are
injured by the presence of chlorine.

1 Wheeler, H. J., and Adams, G. HE. Concerning the Agri-
cultural Value of Sodium Salts. Rhode Island Agr. Exp. Sta.,
Bul. 106. 1905.

SOIL AMENDMENTS 545

465. Muck.— The effect of muck (par. 72) is to
change the structure of soils, making a heavy clay soil
lighter and more porous, and binding together the par-
ticles of a sandy soil. Both classes of soils, but particu-
larly the sandy type, have a greater water-holding
capacity after treatment with muck, owing to its great
absorptive power which amounts to 70 per cent or more
of its own weight. It is to its content of organic matter
that the physical effects of muck are due.

Muck contains 1 to 2 per cent of organic nitrogen,
calculated to dry matter, which does not readily undergo
ammonification. The addition of farm manure (which
ferments readily) and of lime serves to hasten ammoni-
fication. Its use as an absorbent in the stable fits it well
for use on the land.

Very large applications of muck are necessary when
it is used to improve the structure of the soil. From
ten to forty or fifty tons per acre are frequently applied.

Muck has been used successfully as a carrier of Bacillus
radicicola; for this it is eminently adapted by its absorbent
qualities, which prevent it from drying out and thus caus-
ing injury to the bacteria. At the rate of thirty pounds
to the acre it has served as a highly effective medium for
inoculating soil for alfalfa.1

Muck is also used as a filler in certain commercial
fertilizers.

1 Lyon, T. L., and Bizzell, J. A. Some Experiments in Top-
Dressing Timothy and Alfalfa. Cornell Univ. Agr. Exp. Sta.,
Bul. 339. 1918.

CHAPTER XXV

FERTILIZER PRACTICE

THE purchase and use of commercial fertilizers in an
economical way requires not only specific technical
knowledge of the various materials, as already set forth,
but also a certain amount of general knowledge both
practical and theoretical. There are at present so many
fertilizing materials on the market under various trade
names, that the question as to the best one to buy for a
certain crop growing under definite soil and climatic
conditions becomes a difficult one. The greater the
general knowledge, therefore, that a person possesses
as to the effects of the different elements on plant growth,
as to fertilizer inspection and control, as to methods of
buying, as to home mixing, as to methods and time of
application, and as to mixtures for special crops, the
better he is able to utilize fertilizers that will result in
financial gain. That a fertilizer shall be profitable is
the ultimate desideratum. Moreover, as all fertilizers
exert, either directly on indirectly, a residual effect, the
problem necessarily broadens into a study of the systems
of applying fertilizers to a series of crops or to a rotation,
rather than a study of the effects of one particular ferti-
lizer application on one particular crop.

Note. — For discussions of fertilizer practice see Halligan, J. E.,
Soil Fertility and Fertilizers, Chapters 13-17. Easton, Penn-
sylvania. 1912. Also, Van Slyke, L. L. Fertilizers and Crops,
Chapters 21-25, and 27-35. New York, 1912. Also, Fraps,
G. S. Principles of Agricultural Chemistry, Chapter 16. Eas-

ton, Pennsylvania. 1913.
546

FERTILIZER PRACTICE 547

466. Effects of nitrogen on plant growtht— Of the
three primary elements of a fertilizer, nitrogen? seems
to have the quickest and most pronounced effect, not
only when present in excess of the other constituents,
but also when moderately used. It tends primarily to
encourage aboveground vegetative growth and to impart
to the leaves a deep green color, a lack of which is usually
due to insufficient nitrogen. It tends in cereals to in-
crease the plumpness of the grain, and with all plants it
is a regulator in that it governs to a certain extent the
utilization of potash and phosphoric acid. Its application
tends to produce succulence, a quality particularly de-
sirable in certain crops. In its general effects it is very
similar to moisture, especially when supplied in excessive
quantities.

he peculiarity of nitrogen lies not only in its absolute
necessity for plant growth, its stimulation of the vegeta-
tive parts, and its close relationship to the general tone
and vigor of the crop, but also in the fact that it was not
one of the original elements of the earth’s crust. During
the formation of the soil it slowly and gradually became
present, brought down by rains and fixed naturally in the
soil itself mostly through the agency of bacterial action.
Even now it exists largely locked up in complex nitrog-
enous compounds of the humus and the less decayed
organic matter, and becomes slowly available to plants

1 Discussions of the effects of the various elements on plants
may be found as follows: Russell, E. J. Soil Conditions and
Plant Growth, Chapter IT, pp. 19-50. London, 1912. Also,
Hall, A. D. Fertilizersand Manures, Chapters III, V, and VI.
New York, 1910.

2For a discussion of nitrogen in relation to crop yield, see
Hunt, T. F. The Importance of Nitrogen in the Growth of
Plants. Cornell Univ. Agr. Exp. Sta., Bul. 247. 1907.

548 SOILS: PROPERTIES AND MANAGEMENT

largely through bacterial activity. It may be stated with
certainty that one of the possible limiting factors to
crop growth is a lack of water-soluble nitrogen at critical
periods in amounts necessary for normal crop develop-
ment. Since soluble nitrogen may be very readily lost
from the soil by leaching, the problem of proper plant
nutrition becomes a serious one. Not only must the
farmer be able to so regulate its addition in fertilizers
as to obtain the highest efficiency, but he must understand
the control and encouragement of the natural fixation
as well. The emphasis placed on all phases of the nitrogen
problem serves to reveal its great importance in fertility
practices.

Because of the immediately visible effect from the ap-
plication of soluble nitrogen, the average farmer is prone
to ascribe too much importance to its influence in proper
crop development. This attitude is unfortunate, since
nitrogen is the highest-priced constituent of ordinary
fertilizers. Moreover, of the three primary elements
it is the only one which added in excess will result in
harmful after effects on the crop. Its general influences,
besides its functions in the metabolic and synthetic
processes of plant development, may be listed briefly as
follows :

1. Notrogen tends to rncrease the growth of the above-
ground parts.

2. Lt delays maturity by encouraging vegetative growth.
This oftentimes endangers the crop to frost, or
may cause trees to winter badly.

3. Lt mcreases the ratio of straw to grain in cereals, and
the ratio of leaves to underground parts in root
crops,

FERTILIZER PRACTICE 549

4. It weakens the straw and causes lodging in grain. This
is due to an extreme lengthening of the internodes,
and as the head fills the stem is no longer able to
support the increased weight.

5. It lowers quality. This is especially noticeable in
certain grains and fruits, as barley and peaches.
The shipping qualities of fruit and vegetables are
also impaired.

6. It increases the percentage of natrogen in the crop,
particularly in the straw of cereals and in timothy
hay.

7. It decreases resistance to disease. This is probably due
to a change in the physiological resistance to disease
within the plant, and also to a thinning of the cell
wall, allowing a more ready infection from without.

While certain plants, as the grasses, lettuce, radishes,
and the like, depend for their usefulness on plenty of
nitrogen, for the average crop it is generally better to
limit the amount of nitrogen so that growth may be
normal. This results in a better utilization of the nitro-
gen and in a marked reduction of the fertilizer cost for a
unit of crop growth. This is a vital factor in all fertil-
izer practice, and shows immediately whether fertilization
is or is not an economic success.

467. Effects of phosphorus on plant growth. —It is
difficult to determine exactly the functions of phosphoric
acid in the economy of even the simplest plants. Neither
cell division nor the formation of fat and albumen go on
to a sufficient extent without it. Starch may be pro-
duced when it is lacking, but will not change to sugar.
As grain does not form without its presence, it very
probably is concerned in the production of nucleoproteid

550 SOILS: PROPERTIES AND MANAGEMENT

materials. Its close relationship to cell division may
account for its presence in seeds. Its general effects on
plant growth may be listed as follows:

1. Phosphorus hastens maturity by ws effect on rate of
ripening. This makes phosphorus especially valu-
able in wet years, and in cold climates where the
season is short.

2. It increases root development, especially of lateral and
fibrous rootlets. This renders it valuable with
such soils as do not encourage root extension and
to such crops as naturally have a restricted root
development. Phosphorus is therefore valuable in
fall-sown crops, in years of drought, and for farm-
ing on arid land.

3. It decreases the ratio of straw to grain by hastening the
filling of the grain and by promoting maturity.

4, It strengthens the straw, due to its balancing effect on
the nitrogen.

5. It emproves the quality of the crop. This has been
recognized in the handling of pastures in England
and France. The effect on vegetables is also
marked.

6. It increases percentage of phosphorus in the crop.
With cereals this is particularly noticeable in the
straw.

7. It wncreases resistance to disease, due probably to
more normal cell development.

Excessive phosphorus ordinarily has no bad effect,
as it does not stimulate any part excessively as does ni-
trogen, nor does it lead to a development which is detri-
mental. Its lack is not quickly apparent, as in the case

FERTILIZER PRACTICE 551

of nitrogen, and as a consequence phosphorus starvation
may occur without any suspicion thereof being enter-
tained by the farmer.

One of the most important phases to be noted from this
comparison of the effects of nitrogen and phosphorus is
the balancing powers of the latter on the unfavorable in-
fluences generated by the presence of an undue quantity
of the former. This is a vital factor in fertilizer practice,
since normal fertilizer stimulation always results in the
most economic gains. Such a normal increase is obtained
only when the plant functions of the several fertilizer
constituents are in proper accord.

468. Effects of potassium on plant growth. — The
effects of potash are more localized than those of nitrogen
and phosphorus. Potash is essential to starch formation,
either in photosynthesis or in translocation, and is a
necessary component of chlorophyll. It is important
in grain formation, giving plump, heavy kernels. In
general it tends to impart tone and vigor to a plant. In
increasing resistance to disease 1t tends to counteract
the ill effects of too much nitrogen, while in delaying
maturity it works against the ripening influences of
phosphoric acid. In a general way it exerts a balancing
effect on both nitrogen and phosphate fertilizer materials,
and consequently is necessary in a mixed fertilizer, es-
pecially if the potash of the soil is lacking or unavail-
able. As with phosphorus, it may be present in large
quantities in the soil and yet exert no harmful effect on
the crop.

469. Law of the minimum. — In connection with the
obvious importance of utilizing, for any particular soil
and crop, a fertilizer well balanced as to the three primary
elements, two queries naturally arise. These are:

552 ~SOILS: PROPERTIES AND MANAGEMENT

(1) What are the right proportions of nitrogen, phos-
phorus, and potash to apply under given conditions?
(2) What would be the effect if any one of these should
not be present in such a quantity as to make it equal in
function to the others? The first query cannot be dis-
posed of until the question of fertilizer mixtures has been
considered. The second, however, is not affected by so
many factors, and is more clearly a question of the func-
tion of the elements concerned.

Any element that exists in relatively small amounts as
compared with the other important constituents natu-
rally becomes the controlling factor in crop development.
Any reduction or increase in this element will cause a
corresponding reduction or increase in the crop yield.
This element, then, is said to be ‘‘in the minimum.”
In fertilizer practice, ideal conditions would exist if no
constituent functioned as a decided minimum and the
entire influence of each single element were fully utilized.
In other words, the fertilizer would be balanced as to its
relationship to normal plant growth. That such a con-
dition is more or less ideal and theoretical is obvious,
from the fact that the various fertilizer carriers undergo
more or less radical changes after being applied to the
soil. The composition of the soil itself is also a disturb-
ing factor. Nevertheless, the nearer an approach can be
made to such conditions, the greater will be the economy
of fertilizer practice.

Numerous persons have investigated the question as
to what effect an increase of an element in the minimum
may have on crop yield, and various ideas have been
advanced thereon. The idea of a definite law governing
the increase of plant growth according as the element
in the minimum is increased, was first suggested by

FERTILIZER PRACTICE 558

Liebig. Wagner! later stated definitely that up to a
certain point the increase yield was proportional to the
increase in the application. This, however, evidently
cannot apply except over a very limited field, since it is
a matter of common observation that increased crop
vield becomes lower as the lacking element is supplied.
Recently Mitscherlich ? has formulated a law* which is a
logarithmic, rather than a direct, function of the increase
in the element occupying the position of the minimum.
Mitscherlich’s law may be stated concisely as follows:
the increased growth produced by a unit increase of the
element in the minimum is proportional to the decre-
ment from the maximum. The following curve (see
Fig. 62) constructed from data obtained by Mitscherlich,*
shows the trend of the increased growth curve as governed
by increased applications of an element in the minimum,
other factors being, of course, under control. This curve
is maintained by Mitscherlich to approximate a theoretical
curve of a definite mathematical formula.

1Wagner, H. Beitriage zur Dungerlehre. Landw. Jahr.,
Band 12, Seite 691 ff. 1883.

2 Mitscherlich, A. E. Das Gesetz des Minimums und das
Gesetz des Abnehmen den Bodenertrages. Landw. Jahr.,
Band 38, Seite 537-552. 1909.

Also, Ein Beitrige zur Erforschung der Ausnutzung des
im Minimum Vorhandenen Niahrstoffes durch die Pflanze.
Landw. Jahr., Band 39, Seite 133-156. 1910.

3
- =(a—y)k. Integrating, log (a— y)= ¢ —kz.
x

y = total yield from any number of increments.
x = amount of any particular fertilizer constituent utilized.
a= maximum yield and is a constant.
k = a constant depending on y and z, variables.
4Mitscherlich, A. BE. Uber das Gesetz des Minimums und
die sich aus diesem Ergebenden Schlussfolgerungen. Landw.
Ver. Stat., Band 75, Seite 231-263. 1911.

554 SOILS: PROPERTIES AND MANAGEMENT

Ben

Pept
| |
oe

| Pf of

.0
GRAMS LQ, PER POT

Fig. 62.-~Curve showing the increased growth of oats under the in-
fluence of constantly increasing amounts of phosphorus, that ele-
ment being in the minimum.

The formula as proposed by Mitscherlich has been
questioned by several investigators! who have shown
that a number of conditions, such as light, heat, and

1 Pfeiffer, Th., Blanck, E., and Flugel, M. Wasser und Licht
als Vegetationsfaktoren und ihre Beziehungen zum Gesetze vom
Minimum. lLandw. Ver. Stat., Band 76, Seite 211-223. 1912.

Also, Mazé, P. Recherches sur les Relations de la Plante

FERTILIZER PRACTICE 555

moisture, tend to disturb the application of such a law.
The fact that crop yield is the summation of so many
varying factors seems to argue in favor of no hard and
fast rule regarding the increased growth due to the added
increments of an element in the minimum. It is enough,
in the practical utilization of fertilizers, to remember that
this curve in general approximates the one already cited,
and that in order to obtain the best results from a com-
plete fertilizer a mixture should be used that is approxi-
mately balanced so far as the effects of the elements are
concerned, the crop as well as the chemical constitution
of the soil being considered.

470. Fertilizer brands. — In an attempt to meet the
demands for well-balanced fertilizers suited to various
crops and soils, manufacturers have placed on the market
numberless brands of materials containing usually at
least two of the important elements, and nearly always
the three; the former being designated as incomplete
fertilizers, while the latter are spoken of as complete
fertilizers. These various brands usually have some
catchy name, such as “The Ureka Corn Special,” ‘“ Far-
mers’ Potato and Corn Fertilizer,” ‘‘'The Golden Har-
vest,” or “The Empire State Sure Crop Phosphate.”
Such a name frequently implies the usefulness of the
material for some particular crop, but oftener it has no
relation either to crop or to soil. Ordinarily the name
should be ignored in the purchase of fertilizers.

A brand of fertilizer is usually made up of a number
of materials containing the important ingredients. These
materials, already described, are called carriers. The
making-up of a commercial fertilizer consists, then, in

avec les Elements Nutritifs du Sol. Compt. Rend., Vol. 154,
pp. 1711-1714. 1912,

556 SOILS: PROPERTIES AND MANAGEMENT

merely mixing the various carriers together so that the
required percentages of nitrogen, potash, and phosphoric
acid are obtained, care being taken that no detrimental
reaction shall occur and that a physical condition con-
sistent with easy distribution shall be maintained. If
the substances used are difficultly soluble, the fertilizer
is not so valuable as one composed of easily soluble con-
stituents. The general solubility of the various in-
gredients should be known by a prospective purchaser.

The various brands on the market, besides being
complete or incomplete, may be designated as high-grade
or low-grade. These terms may be used in two ways —
high-grade or low-grade as to availability, or high-grade
or low-grade as to amount of plant-food constituents
carried. A low-grade fertilizer in the percentages of
nitrogen, phosphoric acid, and potash is always encum-
bered with a large amount of inert material, which adds
to the cost of mixing, transportation, and handling. It
is thus usually a more expensive fertilizer to a unit of
plant-food obtained than one of higher grade. Except
for special purposes, a low-grade fertilizer as to avail-
ability should be bought sparingly or not at all.

471. Fertilizer inspection and control.— With the
many different materials available for mixing commercial
fertilizers, and from the fact that so many opportunities
are open for fraud either as to availability or as to guaran-
tee, laws have been found necessary for controlling the
sale of fertilizers. Most states have such a law, the
western laws generally being superior to those in force
in eastern states, where the fertilizer sale is heavier.
This is because the western regulations are more recent
and the legislators have had the advantage of the ex-
perience gained where fertilizers have long been used.

FERTILIZER PRACTICE 557

Moreover, the legislators in such states have not been so
strongly confronted with fertilizer lobbying, and have
consequently been free to enact stricter laws than were
possible where fertilizers are such an important com-
mercial commodity.

Usually certain provisions are common to all fertilizer
laws. In general, all fertilizers selling for a certain price
or over (usually, 45 a ton) must pay a state license fee and
print the following data on the bag or an authorized tag :—

1. Number of net pounds of fertilizer to a package.
2. Name, brand, or trade-mark.

3. Name and address of manufacturer.

4, Chemical composition or guarantee.

The composition of a commercial fertilizer is ordinarily
expressed simply; for example, as a 3-06-10, meaning 3
per cent of nitrogen, 6 per cent of phosphoric acid, and
10 per cent of potash. This, however, is too brief for a
guaranteed analysis on goods exposed for sale, as It gives
no idea whatsoever regarding the solubility of the ma-
terials. As might be expected, there is a wide range in
the character of the guarantee required by the various
states. For example, some states insist on the statement
of the percentage of both nitrogen and ammonia, while
others insist only on the percentage of nitrogen. Some
require the soluble, the reverted, and the total phosphoric
acid, while others require only the soluble and the re-
verted. As to potash, in some cases the soluble must be
stated, while in other cases the total must be given. In
general, a guarantee should show not only the amount
of the various constituents, but also their form or avail-
ability. The guarantee required by North Dakota is
excellent in this respect : —

558 SOILS: PROPERTIES AND MANAGEMENT

Guarantee required by the State of North Dakota

Percentage of N in nitrates Percentage of P.O; soluble

Percentage of N as ammonia in water
Percentage of N total Percentage of P.O; re-
verted a
Percentage of P.O; in-
Percentage of K,O soluble soluble

Percentage of K,0 as chloride Percentage of P.O; total

Since a fertilizer law is designed primarily to protect
not only the purchasers but also the manufacturers, a
certain amount of variation is allowed below a guarantee.
This is a matter of extreme variation in the different states.
Ordinarily, also, the offering for sale of any leather matter
or its products, either separately or in mixtures, is pro-
hibited, unless so stated specifically on the package.

For the enforcement of such laws, the states usually
provide adequate machinery. The inspection and analyses
may be in the hands of the state department of agricul-
ture, of the director of the state agricultural experiment
station, of a state chemist, or under the control of any
two of these. In any case, a corps of inspectors is pro-
vided, the members of which take samples of the fertilizers
on the market throughout the state. These samples are
analyzed in laboratories provided for the purpose, in
order to ascertain whether the mixture is up to its guar-
antee. If the fertilizer falls below the guarantee, — allow-
ing, of course, for the variation permitted by law, — the
manufacturer is subject to prosecution.

A more effective check on fraudulent guarantees, how-
ever, is found in publicity. The state law usually pro-
vides for the publication each year of the guaranteed and
found analyses of all brands inspected. Not only has

FERTILIZER PRACTICE 559

this proved effective in preventing fraud, but it is really
a great advantage to the honest manufacturer.

The expenses for the inspection and control of fertilizers
are usually defrayed by the license fees, which average
for the different states from ten to twenty dollars a year
for each brand selling for $5 or more a ton. In the
eastern states this fee produces a net return greatly in
excess of the expenses incurred by the fertilizer inspection
and control, and consequently has become the source of
a handsome income for these states.

472. Trade values of fertilizers. —It has become cus-
tomary for the authorities charged with fertilizer inspec-
tion and control in the various states to adopt each year
a schedule of the trade values of the various elements as
they appear on the market in unmixed lots. These
values are obtained by averaging all the wholesale prices
of a ton for the various unmixed supplies for the six
months preceding March 1, to which is added 20 per cent
of the price to cover cost of handling. The trade values
for 1912 were as follows :+—

TrapE VaLuEs oF Prant-roop ELEMENTS IN Raw Ma-
TERIALS AND CHEMICALS
Cents a pound

Nitrogen in ammonia salts oe we we ee «188
Nitrogen in nitrates . . 183
Organic nitrogen in dry and fine fish, meat, and blood 20
Organic nitrogen in fine bone, tankage, and mixed

fertilizer . . . . . . . IY
Organic nitrogen in coarse - bone ‘and tankage . . 1d
Organic nitrogen in castor pomace and cottonseed

meal . . .... ee eee ee 620

iNew York (Geneva), Agr. Exp. Sta., Bul. 371, p. 434. 1913.

560 SOILS: PROPERTIES AND MANAGEMENT

Cents a pound

Phosphoric acid, water-soluble soe ew we
Phosphoric acid, citrate-soluble (reverted) . . . 4
Phosphoric acid, in fine bone, fish, and tankage . 4
Phosphoric acid, in cottonseed meal and castor
pomace . 4
Phosphoric acid, in coarse fish, bone, tankage, and
ashes oo... 35
Phosphoric acid in mixed fertilizers, insoluble in
water or ammonium citrate _ 2

Potash as high-grade sulfate, in forms free from chlo-
rides, mn ashes, etc. ; . rs

Potash as muriate . . .. 4

Potash as castor pomace and cottonseed meal 5

It must be remembered that these prices are seaboard
evaluations, and represent the cost to the manufacturer
of the elements as they exist in the unmixed carriers.
This is called the commercial evaluation of a fertilizer,
and is the first, of a number of items that enter into the
total cost, or the price the farmer must pay on the retail
market. The items that make up this ultimate price
may be listed as follows: (1) retail cash cost, or com-
mercial evaluation; (2) cost of mixing; (3) profit of
manufacturers; (4) transportation; (5) storage, com-
mission to agents, bad debts, and so forth; and (6) profit
of retailer. These additional charges are often sufficient
to double the original commercial value of the fertilize
constituents.

It is evident that by knowing the composition of a fer-
tilizer, and the carriers of the various constituents, the
commercial evaluation of the mixture may be easily cal-
culated. However, what the farmer must pay depends

FERTILIZER PRACTICE 561

to a large extent on the additional charges already listed.
Thus, a fertilizer evaluated at $22 a ton on the New York
market may cost the farmer $35, or even $45, after having
passed through the hands of the manufacturer and the
retail merchant. This commercial evaluation, however,
must not be confused with the agricultural evaluation,
which is the value of the increased crop produced by the
application of the fertilizer. It is evident that the agri-
cultural value will vary with the soil, the crop, or the
season, and may be above or below the total cost accord~-
ing to circumstances. In good fertilizer practice, the
excess of the agricultural value over the total cost of the
fertilizer, all costs incidental with the growing, harvest-
ing, and marketing of the increase being first deducted,
should be sufficient to give a handsome profit on the
investment.

473. The buying of mixed goods. — The successful
buying of mixed fertilizers on the retail market depends
on two things: (1) the selection of a suitable composi-
tion, with carriers of known value; and (2) the purchase
of high-grade goods. The farmer who observes these
two points will have at least purchased successfully.
Whether he obtains a profit from the use of the fertilizer
depends on the balancing of a number of factors more or
less variable from season to season.

The selection of a suitable fertilizer, as to carriers and
composition for any particular crop or soil, entails first
of all a study of the guarantee. Should the guarantee
be such as that already cited, a large amount of informa-
tion is at hand concerning the forms of the carriers and
the availability of the important constituents. This
knowledge, properly correlated with the probable needs
of the crop and the soil, will determine whether that

562 SOILS: PROPERTIES AND MANAGEMENT

particular brand should be purchased or not. The real
question here is not the actual quantities of the elements
in a ton of the fertilizer, but their balance among them-
selves. The actual pounds of nitrogen, phosphoric acid,
or potash applied per acre can be governed by the rate
at which the mixture is applied.

The purchase of high-grade goods is the second impor-
tant point to be considered. Data collected from practi-
cally every state show that the higher the grade of the
fertilizer, both as to availability and as to the percentage
of the constituents carried, the greater is the amount of
plant-food obtained for every dollar expended. The
following data, taken from Vermont? for 1909, are the
average of one hundred and thirty brands and are typical
data in this regard : —

» aT: rae
19 wae = fe a
Go Op Zee | Cosr (tv Cunts) BA p
O ea Ep, | OF ONE Pounn or| a § 8
FERTILIZER 2% BAY 2 ib PR Oo i eo
oa mag BR | Mew a AF
AS CER ai | &y& PA
so Ao BS a 8 BAS
Ss an ce | 287) ~ |pos| K0 [388
On Os Be | OFF >
(cents)
Low grade [$13.52 | $27.10 | $13.58 | $1.00 | .388 | 7.6 | 8.5 [50.0
Medium
grade . 18.22 | 30.00| 11.78; 0.65) .31 | 6.3 | 7.0 |60.6
67.6

High grade | 26.30} 38.93; 12.63) 0.48] .28 | 5.7 | 6.3

It is noticeable at once that the lower the grade of the
fertilizer, the higher is the proportional cost of placing
the goods on the market. In other words, it costs just

1 Hills, J. L., Jones, C. H., and Miner, H. L. Commercial
Fertilizers. Vermont Agr. Col., Bul. 143, pp. 147-149. 1909.

FERTILIZER PRACTICE 563

as much per ton to market a low-grade material as a
high-grade one. This accounts for the fact that the ele-
ments are cheaper per pound in a high-grade mixture,
and that the value of plant-food received for every dollar
expended is greater.

474. Home-mixing fertilizers. — In comparing the above
commercial evaluations with the prices actually paid
by the farmer on the retail market, it is found that the
latter shows an increase ranging from 48 to 100 per cent.
This is due to the charges for mixing, transportation, han-
dling, storage, commission, interest on capital, profit,
and other items, made during the passage of the material
from the wholesale dealer to the user. In order to escape
these costs. many farmers have begun the practice of
buying the separate carriers, thus avoiding these charges
—except, of course, that of transportation. In many
cases the mixing on the farm costs nothing, as it can be
done in winter when the farm work is not pressing. Even
if the farmer must charge himself with this mixing, it
seldom amounts to more than fifty cents a ton.

As might be expected, this practice has met with much
opposition from manufacturers. In general it is claimed
that the factory goods are more finely ground than those
mixed by the farmer, and consequently the ready-mixed
goods are not only more uniform but also in better physi-
cal condition. Also, the manufacturer is able to treat
certain materials with acids, and thus increase their
availability. While these reasons are more or less valid,
good results may be expected from a fertilizer even though
it may not be quite uniform, as the soil tends to equalize
this deficiency. Moreover, by screening and by using
a proper filler, a farmer can obtain a physical condition
which will in no way interfere with the drilling of the ma-

564 SOILS: PROPERTIES AND MANAGEMENT

terial. While, obviously, one farmer alone cannot afford
to buy direct from the wholesale dealer because of the
high freight charges on small lots, this objection is being
met by clubs and various organizations whereby the
single carriers may be bought in carload lots.

It is evident that when a farmer mixes his own fertilizer
he is able to obtain not only pure goods, but high-grade
goods as well, thus reducing freight. Moreover, as a gen-
eral thing home mixing is cheaper than buying the ready-
mixed goods. A quotation from Connecticut’ for 1906
illustrates about what this saving may be: —

Prant-Foop PurcHasep ror $30

Pouwps| Pounps} Pounps
N | POs | K,0 | TOTAL

Nitrogenous superphosphates

Best quality . . . . . . .| 738 | 188 | 111 | 372

Least valuable woe ew ew we | 2B | BTID 538 | 355
Special manures

Best quality . . . . . . .| 69 | 170 | 148 | 382

Lowest quality . . . . . .| 82 | 174 66 | 272
Home mixtures

Average ofall . . . . . . .| 77 | 200 | 168 | 445

A third point, and by some considered to be more im-
portant than those already discussed, is the educational
value of home mixing. No farmer can mix his own fertil-
izer without becoming familiar with the carriers, their
availability, and their effects. He is forced to study their
influence on the crops more closely, and thus is placed

1 Jenkins, H. H., and Winton, A. Lh. Fertilizer Report.
Conn. (New Haven) Agr. Expt. Sta., Rept. 1906, Part I, pp.
1-106.

FERTILIZER PRACTICE 565

in a position to make changes that will tend to a higher
efficiency of the constituents. The chances are that he
will alter his fertilizer mixture as his rotation progresses
and his soil changes in fertility.

Such arguments do not always mean, however, that
it pays to mix at home. As a matter of fact, In many
cases it does not pay, especially where only a small amount
of fertilizer is needed and it is impossible to codperate
with other farmers. As a general rule, fertilizers should
be bought by the method that will give the greatest value
for every dollar expended. Farmers often can avail
themselves of the advantage of both systems by asking
for bids from various manufacturers on carload lots of
mixed goods having a certain designated composition.
The farmers in this case designate the carriers as well.
All the advantages of machinery mixing may thus be
gained, with the lower cost which has made home mixing
so popular.

475. Fertilizers not to be mixed. — Every farmer who
practices home mixing should keep in mind that there
are certain fertilizers which should not be mixed. ‘This
is due to the fact that a number of materials carry lime
in the oxide, the hydrate, or the carbonate form. This
lime, particularly the caustic forms, may react in three
directions, depending on the fertilizer with which it is in
contact: (1) im setting free ammonia, (2) In causing re-
version of acid phosphate, and (3) in producing a bad
physical condition, especially when in contact with ma-
terials more or less deliquescent. Van Slyke! may be
quoted in this regard as follows : —

1Van Slyke, L. L. Fertilizers and Crops, pp. 485-486.
New York, 1912.

566 SOILS: PROPERTIES AND MANAGEMENT

Calcium oxide
Calcium hydrate

| ammonium sul-
fate

Wood ashes | animal manures,
La > should not be} as _ tankage,
Basic slag ;
Calcium cyanamid mixed with} blood, and the
Basic calcium like
nitrate j nitrogenous
guanos
Calcium oxide
Calcium hydrate
Calcium carbonate | should not be soluble phos-
2. . phates
Wood ashes mixed with of anv kind
Basic calcium y
nitrates
Calcium oxide should not be oe
9 Calcium hydrate mixed with |? ride
" Basic calcium (unless applied |}, . .
, : kainit, and the
nitrate } immediately) like

Neither is it wise to allow moist acid phosphate to lie
in contact with large quantities of sodium nitrate, as
nitric acid may be slowly liberated by free sulfuric or
phosphoric acid. Also, large quantities of calcium cyana-
mid should not be mixed with acid phosphate because
of the lime contained in the former. If, however, the
ratio is not greater than one to ten, the results are bene-
ficial, since the reaction, without causing serious rever-
sion of the phosphate, generates enough heat to quickly
season the mixture. The fine and dry condition of the
eyanamid is also conducive to a good mechanical condi-
tion, and accounts for the fact that this material is in
such favor with manufacturers of mixed goods.

FERTILIZER PRACTICE 567

476. How to mix fertilizers. — As the various carriers
are bought under guarantee, the percentages of nitrogen,
phosphoric acid, and potash in the ingredients to be mixed
are accurately known. The calculation of the amounts
of each carrier and of the filler necessary to make up a
ton of a fertilizer having a certain formula, then becomes
a matter of simple arithmetic. The mixing is an equally
simple operation. The implements needed in home mixing
are as follows: (1) a tight floor, (2) platform scales,
(3) a sand screen with from three to six meshes to an inch,
(4) a tamper or a grinder, (5) shovels, a rake, and like
tools.

First, the various ingredients, after being crushed and
screened if lumpy, are weighed out in amounts sufficient
for the unit of fertilizer to be mixed at any one time.
The bulkiest material is spread on the floor first and leveled
uniformly by raking. The remaining ingredients are
then spread in thin layers above the first, in the order
of their bulk. Beginning at one side, the material is
next shoveled over, care being taken that the shovel
reaches the bottom of the pile each time. The pile is
then again leveled, and the process is repeated a sufficient
number of times to insure thorough mixing. Sometimes
a mixing machine may be used for this operation. For
storage and general convenience, the fertilizer may be
weighed into sacks of from 100 to 150 pounds capacity
and put in a dry place until needed for use.

A word of caution should be inserted here regarding the
concentration of the mixture. Some farmers, in order
to lessen the work of mixing and application in the field,
raise the percentage of the elements exceedingly high —
a, condition very likely to occur when high-grade materials
are used. This is bad practice, in that it may interfere

568 SOILS: PROPERTIES AND MANAGEMENT

with germination and may also injure the young plants.
Also, it is likely to result not only in a poor physical condi-
tion but also in uneven distribution, which will bring about
a lowered efficiency of the fertilizer. The use of sufficient
dry, finely divided filler will obviate such dangers.

477. Factors affecting the efficiency of fertilizers. —
The agricultural value of a fertilizer is necessarily a vari-
able quantity, since, in applying fertilizers, a material
subject to change is placed in contact with two wide
variables, the soil and the crop. The general factors
that govern the effect of fertilizers may be listed as
follows : —

1. Seed, crop, and adaptation of crop to sor. — It is quite
evident that different crops will respond differ-
ently to the same fertilizer elements. Also, the
strength of the seed, the management of the crop,
and the adaptation of crop to soil, will be potent
factors in variation.

2. Temperature, sunshine, and rainfall. —'These factors
are meteorological and, of course, are dominant
in the growth of the plant. Rainfall especially
is important, as an optimum moisture content
is conducive’ to good plant development. In
general, as shown by experiments in Ohio and
Pennsylvania, the higher the rainfall, the greater
is the efficiency of the fertilizer used.

3. Drainage. — This 1s of great importance in ferti-
lizer practice, since it places the soil in a better
condition from all standpoints for plant growth.
In other words, the better the normal soil condi-
tions, the better should be the reaction from ferti-
lizer application.

FERTILIZER PRACTICE 569

4, Physical condition of the soil. — The addition of lime
and organic matter, the utilization of drainage,
tillage, and the like, all are conducive to higher
crop returns through the indirect effect on fertilizer
efficiency.

5. Lime. — Lime, by improving physical conditions,
by setting plant-food free, by correcting acidity,
by stimulating bacterial action, and by tending
to eliminate toxic materials either directly or
indirectly, is of great importance in fertilizer
practice. In fact, certain fertilizers, such as
ammonium sulfate and acid phosphate, do not
reach their full efficiency unless plenty of lime is
present.

6. Organic matter. — Besides the effect of organic matter
on physical conditions and chemical reactions
which indirectly influence fertilizer action, an im-
portant action is set up by organic matter in the
encouragement of bacterial functions. As the
favorable changes of fertilizers, especially those
carrying nitrogen, is due to biological activity,
the presence of organic materials becomes doubly
important.

7. Chemical composition of the soil.— Since the full
return from a fertilizer is derived when the ele-
ments are well balanced, the actual constitution
of the soil becomes a factor, especially when ready
availability 1s obtainable. Therefore, in choosing
a fertilizer and deciding on the amounts to apply,
the chemical condition of the soil is no mean factor.

While the conditions affecting fertilizer efficiency have
thus been so briefly disposed of, it is evident that a more

570 SOILS: PROPERTIES AND MANAGEMENT

detailed consideration of the question would be not only
interesting but also profitable, would space permit. One
point of broader scope, however, than the addition of a
well-balanced food stimulation, stands out clearly in this
consideration. The necessity of putting a soil in any
given climate into the best possible condition for plant
growth is paramount. This means that drainage, lime,
humus, and tillage, in the order named, must be raised
to their highest perfection. Under such improvements
the further use of commercial fertilizers may or may not
be a paying investment.

478. Method and time of applying fertilizers. — The
distribution of the fertilizer by means of machinery is
much more satisfactory than is broadcasting by hand,
as the former method gives a more uniform distribution.
Cereals and other crops are now usually planted with a
drill or a planter provided with an attachment for dropping
the fertilizer at the same time that the seed is sown, the
fertilizer being by this method placed under the surface
of the soil. Broadcasting machines are also used, which
leave the fertilizer uniformly distributed on the surface
of the ground, thus permitting it to be harrowed in suffi-
ciently before the seed is planted, and preventing injury
to the seed by the chemical activity of the fertilizing
material.

Corn planters with fertilizer attachments deposit
the fertilizer beneath the seed, thus avoiding a possible
detrimental contact. Grain drills do not do this, and,
where the amount of fertilizer used exceeds 300 or 400
pounds an acre, it is better to apply it before seeding.
Grass and other small seeds should be planted only after
the fertilizer has been mixed with the soil for several
days. For crops to which large quantities of fertilizers

FERTILIZER PRACTICE 571

are to be added, especially potatoes and garden crops,
it is desirable to drop only a portion of the fertilizer with
the seed, the remainder having been broadcasted by ma-
chinery and harrowed in earlier.

479. Fertilizing crops. — Three primary considerations
must be observed in the actual utilization of fertilizers:
(1) the percentage of nitrogen, phosphorus, and potash
suited to the crop and the soil; (2) the availability of the
carriers; and (3) the amounts to be applied. It is evi-
dent, due to so many factors that are difficult to control,
that fertilizer formulas for different crops on particular
soils are difficult to determine. In fact, such data can
never be more than merely suggestive. Further, the
best quantity of a mixture to apply, even though it is
perfectly balanced, is a figure that can only be approxi-
mated. Probably the largest percentage of the fertilizer
waste that occurs annually can be charged to this factor.
Many farmers make the mistake of applying too much
fertilizer. As a consequence, any information along such
lines can only be merely suggestive, rather than literal,
it being understood that the general formulas suitable
to various crops, and the quantities ordinarily applied,
are subject to wide variations.

The fact that there are so many mixtures on the market
in this country for the same crops would be rather amus-
ing, did it not so strikingly expose the ignorance of the
manufacturer as well as the gullibility of the public.
Recognizing the need of standard formulas subject to
change according to local conditions, Van Slyke? has
offered the following for general use: —

1Van Slyke, L. L. Fertilizers and Crops, p. 528. New
York. 1912.

572 SOILS: PROPERTIES AND MANAGEMENT
FrrRrinizeER FoRMULAS FOR GENERAL APPLICATION

IRCE E| Poromnracno | Pores
Crops PrRcenTAGE | Pore P NTAGE

OF OF £905 OF 9
Leguminous 1 8 10
Cereal 3 8 5
Garden . 4, 8 10
Grass 3 6 9
Orchard 2 5 10
Root 3 8 7

While it is recognized that these formulas are probably
far from correct in their application to such groups as
the garden crops, where so many entirely different plants
are concerned, it is felt that they furnish the basis, as
far as our knowledge now extends, for a more economic
fertilization. The variation of such mixtures to suit
specific needs is a part of fertilizer practice.

The carriers largely used for such readily available
mixtures are sodium nitrate, acid phosphate, and potassium
chloride or sulfate. Tankage or blood is often substituted
for sodium nitrate where humus is desirable, while am-
monium sulfate and calcium cyanamid are growing in
popularity. Raw rock phosphate and basic slag are used
rather largely in separate applications, the amounts
being usually larger than with the ordinary fertilizer
materials.

The other phase of fertilizer practice is in the amount
to be applied. With all the groups considered above
except garden and root crops, the applications are rela-
tively light, ranging from 150 to 300 pounds to an acre.
Where excessive vegetative growth is required, as in silage,
the rate may be increased to 500 pounds. In the top-
dressings of meadows or grains, the rate varies from 75

FERTILIZER PRACTICE 573

to 150 pounds an acre. Very often this dressing is sodium
nitrate alone. With garden and root crops the amount
of fertilizer applied is very large, ranging from 800 to
sometimes as high as 2000 pounds. The cropping here
is intensive, and the expenditure for fertilization may be
large and yet yield handsome profits.

It must always be remembered that in fertilizer prac-
tice the very high yields obtained under fertilizer stimu-
lation are not always the ones that give the best returns
on the money invested. In other words, the law of
diminishing returns is a factor in the influence of ferti-
lization on crop yield. This relationship is clearly shown
by the curve illustrating the law of the minimum (par.
469), in which the return for each increment of fertilizer
becomes less and less as the total quantity added becomes
greater. It is evident, therefore, that with an excessive
application of any mixture, the returns to an increment
will at last become so small that the increased crop fails
entirely to pay for even the fertilizer, not to mention such
charges as cost of application, harvesting of increased
crop, storage, and the like. The application of moderate
amounts of fertilizer is to be urged for all soils until the
maximum paying dose that may be applied to any given
crop is ascertained by careful experimentation. Over-
fertilization probably accounts for the fact that such a
large proportion of the fertilizers sold to the farmers each
year not only is entirety wasted, but probably in some
cases even becomes detrimental to crop yield.

480. Systems of fertilization. — During the evolution
of fertilizer practice, particularly since the early part
of the nineteenth century, a number of systems of apply-
ing fertilizer have been advocated or have been in actual
use. These may be listed as follows : —

574 SOILS: PROPERTIES AND MANAGEMENT

1. Single-element system.— This was one of the first
to be suggested, and was advocated because each
particular crop was supposed at that time to
respond largely to one element. Thus, nitrogen
was supposed to dominate wheat, rye, and oats;
phosphoric acid, to dominate corn, turnips, and
sorghum; and potash to dominate potatoes,
clover, and beans. Present knowledge of the
balancing effects of fertilizers shows this idea to
be fallacious.

2. Abundant supply of minerals.— This system had
its origin from the fact that potash and phosphoric
acid are relatively cheap and are slowly leached
from the soil, while nitrogen is expensive and easily
lost. Such a plan, therefore, provides always plenty
of potash and phosphorus, which is to be balanced
each season with sufficient nitrogen to give paying
yields.

3. A system based on the plant-food taken out by the
crop. — According to this plan, as much plant-
food is added each year as will probably be taken
out by the plant, this being determined by chemi-
cal analyses. This system overlooks the fact
not only that different plants feed differently on
the same soil, but that the same crop exhibits
marked variability with change of season and
change of soil. Moreover, no allowance is made
for losses by leaching, which are known to equal
at times the losses due to plant growth.

4. Irrational system. —'This is the plan followed by
many farmers where fertilizers are an important fac-
tor in soil management. The formula is changed
from year to year, In a vain attempt to strike a

FERTILIZER PRACTICE 575

high point in production. The same continual shift
is found in the quantities applied. T'oo often
the specific brand used is determined by the trade
name that it carries or by the recommendation of
the retail merchant, rather than from a careful
consideration of the guarantee or of the carriers
for each important element. The educational
phase of home mixing should do much to eliminate
this system.

5. Fertilization of the money crop. — In trucking or in
general farming operations one crop is usually a
money crop. Naturally its stimulation by heavy
fertilization will pay better than applications to
crops that bring less on the market. The general
plan in this system is to allow the crops following
the money crop to utilize the residuum. When
this residual influence works out, the system is
likely to be a profitable one; but when the follow-
ing crops fail to respond, the method becomes
wasteful in the extreme.

In the selection of a system that will result in an ef-
fective utilization of fertilizers, only two of the plans de-
scribed above need be considered. In any fertilizer,
phosphoric acid and potash should always be present in
amounts sufficient to more than balance the nitrogen,
since the activity of nitrogen is so pronounced. There-
fore a scheme that calls for an abundance of minerals is
a sound one. This, coupled with the heavy fertilization
of the money crop, does not, however, constitute what
might be considered a rational system, since the crops
that follow may or may not be adequately supplied with
plant-food. Unwise fertilization often leaves the soil,

576 SOILS: PROPERTIES AND MANAGEMENT

as far as its balance is concerned, less able to yield a
paying crop than before. The careful fertilization of the
rotation, then, with special attention to the money crop,
is the only rational system that can ordinarily be employed,
since it not only cares for the crop on the land but also
looks to those that are to succeed. The attention that
must necessarily be paid to the fertility of the soil in such
a system insures the establishment of a soil management
which will ultimately result in a great conservation of
fertility, while at the same time raising the yields and
increasing the prosperity of the farming class.

CHAPTER XXVI

FARM MANURES

Or all the by-products of the farm, barnyard manure
is probably the most important, since it affords a means
whereby the unused portion of the crop, the residue of
the finished farm product, may again be returned to the
soil. This country is now entering on an era in which
the prevention of all waste is becoming more and more
necessary and a nearer approach to a, self-sustaining sys-
tem of agriculture far more essential. A clear under-
standing of the composition of farm manure, the changes
it undergoes, and its avenues of loss, and also of methods
for its practical handling, and a realization of its effects
both on soil and on crop, are of vital importance. This
need appeals not only to the practical man but to the
theoretical and technical man as well, for here is a field
in which theory and practice not only meet but widely
overlap.

481. General character and function of farm manures.
— The term farm manure may be employed in reference to
the refuse from all animals of the farm, although, as a
general rule, the bulk of the ordinary manure which ul-
timately finds its way back to the land is produced by
cattle and horses. This arises not only because these
animals consume the greater part of the grain and rough-
age on the average farm, but also because the methods
of handling them make it easier and more practicable to

2P 677

578 SOILS: PROPERTIES AND MANAGEMENT

conserve their excreta. Yard manure generally refers
to mixed manures. The mixing usually occurs during
storage, either for convenience in handling or for the pur-
pose of checking losses and facilitating fermentation.
Thus, horse and cow manures are commonly mixed, since
the too rapid fermentation and probable loss of ammonia
in the former is checked, while at the same time a more
rapid and much more complete decay is encouraged in
the latter.

The ordinary manure consists of two original compo-
nents, the solid and the liquid portion. As these con-
stituents differ greatly, not only in composition but also
in physical properties, their proportions must appreciably
affect the quality of the excreta and its agricultural value.
Litter added for bedding or for adsorptive purposes is
almost always an important factor, for while it prevents
losses of the soluble constituents it may at the same time
lower the value of the product for a unit amount.

Farm manure ordinarily fulfills two functions which
are usually not so simultaneously yet clearly developed
in any other material — that of a direct and that of an
indirect fertilizer. Consisting of 73 per cent of water
and only 27 per cent of dry matter, the percentages of
plant-food are necessarily low. As mixed farm manure
contains on the average! 0.50 per cent of nitrogen, 0.25
per cent of phosphoric acid, and 0.60 per cent of potash,
considerable quantities of plant-food elements are added
in an ordinary application. ‘Ten tons of average manure,
even if only one-half of the nitrogen, one-sixth of the
phosphorus, and one-half of the potash are readily avail-
able, is equivalent to 300 pounds of sodium nitrate, 60

1See Analyses, Storer F. H. Agriculture, pp. 237-248.
New York. 1910.

FARM MANURES 579

pounds of acid phosphate, and 125 pounds of potassium
chloride. This is equivalent to the addition of 485
pounds of an approximately 10-2-12 ready-mixed ferti-
lizer. Moreover, from the fact that so large an amount
of the plant-food carried is not readily available, it acts
as a residuum, which is slowly given up to the succeeding
crops. It has been shown in England! that paying in-
creased returns may be obtained from manure four years
after its application. At Rothamsted, England,? a
residual impetus was noticeable on crops forty years after
the soil was manured. This, however, is an exceptional
case.

Farm manure may act as an indirect fertilizer in its
tendency toward improved physical relations. The addi-
tion of organic matter is the vital factor here. Better
tilth, better aération, improved drainage, and increased
water capacity are the necessary accessories to a rise in
humus content. The influence of manure on the avail-
ability of the mineral constituents of the soil is not the
least of its indirect effects. Even the increased adsorp-
tive power of the soil should be mentioned, in its tendency
toward the counteraction of toxic principles.

Another general characteristic of average farm manure
is that, while it is a fertilizer, it is an unbalanced one.
Proportional very roughly to a 10-2~12 commercial mix-
ture, any one acquainted with general fertilizer practice
can see that it is too high in nitrogen and too low in avail-
able phosphoric acid. The elimination of such a condi-

1Voeleker, J. A., and Hall, A. D. The Valuation of Unex-
hausted Manure Obtained by the Consumption of Foods by
Stock. London. 1903.

2Hall, A. D. Fertilizers and Manures, p. 218. New York.
1910.

580 SOILS: PROPERTIES AND MANAGEMENT

tion and a balancing thereby of the plant ration is one
of the many problems that present themselves in the
economic handling and utilization of animal residues.

482. Variable composition of manures. —'The manure
produced on an average farm is rather likely to vary
markedly in composition and character from time to
time. It may even change radically from one day to
another. There are five general factors that are usually
listed as being responsible for this variation: (1) litter;
(2) class of animal; (3) individuality, condition, and age of
animal; (4) food of animal; and (5) handling of manure.

483. Litter. — Perhaps under ordinary circumstances
the amount and character of the litter has as much to
do with the variation in manurial composition as has
any other one factor, if not more. By an increase in
the amount of bedding, the product becomes bulky,
light in weight, and difficult to handle. This is likely
to be the case with manure from livery stables, where
the litter is used to keep the horses clean and not for
purposes of plant-food conservation. That bedding must
also exert a marked effect on chemical composition is
evident from the following analyses : —

Composition oF LirrER

N P.Os KO
Sawdust shavings ... . 0.10 0.20 0.40
Oat straw . . . . 0. 0.62 0.20 1.04
Peat... ... ..~. 2.63 0.20 0.17

Leaves . . . . 0.06. 0.65 0.15 0.30

Sawdust and shavings add little of value to the manure
and really act as a diluent. While they are good absorb-

FARM MANURES 581

ents they decompose so slowly as to make them somewhat
objectionable on light soils. Leaves decompose readily,
but add little fertility. Oat straw carries no more nitro-
gen than does average manure, and this nitrogen, like
that of peat or muck, is not readily available as plant-
food. Litter, however, is of such extreme importance as
an adsorbent that the resistant qualities of even such
materials as shavings can be to a degree ignored. Be-
cause of the influence of the bedding on composition,
manure should never be bought unless this phase has
been carefully looked into.

484. Class of animal.— The second factor causing
radical variation in the composition of farm manure is
the class of animal by which it is produced. The following
figures, compiled from Ohio, Connecticut, and New York
(at Cornell University), Ulustrate this point clearly : —

PERCENTAGE OF

oer ryritninansaaeensimmmemenitiareatan | eTerbsilantinetAhaaeneRreeenltniiis { ainnmmrem~tinnyeeetshitinAiMNRmanmemainiihtilitlit | 44MeuttemennnhistihnBSLén emma ser teeHht

Horse manure with straw | 62.80 0.57 0.12 0.54
Cow manure with straw 78.00 0.46 0.13 0.36

A working horse on maintenance ration will return in
the manure almost all the nitrogen and minerals taken
as food. In other words, the building-up and the break-
ing-down, or elimination, processes are about equal.
A young fattening pig, on the other hand, will return only
about 85 per cent of the nitrogen received as food and 96
per cent of the mineral material, and a milking cow 75
per cent and 89 per cent, respectively.

1Thorne, C. E. Farm Manures, p. 89. New York. 1914.

582 SOILS: PROPERTIES AND MANAGEMENT

485. Individuality, condition, and age of animal. —
Various animals differ in capacity, some retaining much
more of the elements contained in the food than do others,
and consequently producing a poorer manure. The
service to which the animal is subjected is also a factor.
A milch cow will certainly utilize more nutriments than
an animal not in that condition. Age is perhaps more
accountable for variation in farm manure than either of
the other two causes. A young animal gaining in muscle
and bone is storing away large quantities of nitrogen,
phosphorus, and potash, and producing a manure corre-
spondingly poorer in these ingredients.

486. Food of animal. — Since the animal will retain
only a certain quantity of the food elements, it is reason-
able to suppose that the richer the food, the richer will
be the corresponding excrement, both liquid and solid.
Such has proved to be the case. Wheeler,’ in studying
the rations of chickens, found the following difference
in the manure produced : —

PERCENTAGE OF

RATION
HO N P K
Fresh hen manure (nitrog-
enous ration) . . .| 659.7 0.80 0.41 0.27
Fresh hen manure (car-
bonaceous ration) . . 55.3 0.66 0.32 0.21

From Ohio,? where the production of manure has been
most thoroughly investigated, the following data may be
quoted : —

1Wheeler, W. P. Poultry Feeding Experiments. Rept.
New York (Geneva) Agr. Exp. Sta., No. 8, p. 62. 1889.

2Thorne, C. E., and others. The Maintenance of Fertility.
Ohio Agr. Exp. Sta., Bul. 183. 1907.

FARM MANURES 583

Errect or Ration on Manvuritau Composition

PURCENTAGE OF

Ration
N P K
Cornand mixed hay .. . 1.49 0.23 1.11
Corn, oil meal, and hay . . 1.55 0.24 1.02
Corn, oil meal, and clover. 1.68 0.26 1.04

487. Handling manure.—In dealing with a product
of which almost one-half is liquid, there is great danger
that a considerable amount of valuable plant-food will be
lost by leaching. ‘The modification and consequent
lowering of the plant-food value of farm manure is a
vital question in the economic handling of this product.
Next to the litter, lack of care is perhaps the most im-
portant single factor concerned in altering the chemical
composition of manures in general. The influence of
handling is so clearly brought out by the following figures
from Schutt,! on mixed horse and cow manure, that further
discussion seems unnecessary. The protected manure in
this case was in a bin under a shed. The exposed sample
was in a similar bin but unprotected from the weather :—

Loss at END oF Loss at END or
Six Monrss TWELVE Montss
(Percentage) (Percentage)

Protected | Exposed | Protected | Exposed

Te eaanh-anmagaieeerinmaananentnenaamenanal Hantaddidastenaamenentmuaamaetesuaee RTT Ceaesccameteamenemtananminimant taumneeedl Lontiesese nia Ener

Loss of organic matter 58 65 60 69

Loss of nitrogen . . . 19 30 23 40
Loss of phosphoric acid 0 12 4, 16
Loss of potash . . 3 29 3 36

1§chutt, M.A. Barnyard Manure. Canadian Dept. Agr.,
Centr. Exp. Farm, Bul. 31. 1898.

584+ SOILS: PROPERTIES AND MANAGEMENT

488. Composition and character of farm manures. —
Although the probable composition of farm manures is so
dificult to state in exact figures, compilations of the
available data have yielded percentages which, while
they demand a most liberal interpretation, afford con-
siderable light regarding the differences that normally
exist between the excrement of various animals. Of
these compilations, Van Slyke’s is perhaps the best.

Tuer Composition oF FresH Manure!

PoRCENTAGE OF

EXCREMENT
B20 N P20s K20
Solid 80 per cent 75 0.55 0.30 0.40
Horse } Liquid 20 per cent 90 1.35 Trace | 1.25
[Whole manure. 78 0.70 0.25 0.55
{Solid 70 per cent 85 0.40 0.20 0.10
Cow Liquid 30 per cent 92 1.00 Trace | 1.35
| Whole manure . 86 0.60 0.15 0.45
Solid 67 per cent 60 0.75 0.50 0.45
Sheep ; Liquid 33 per cent 85 1.35 0.05 2.10
Whole manure . 68 0.95° | 0.385 1.00
Solid 60 per cent 80 0.55 0.50 0.40
Swine { Liquid 40 per cent 97 0.40 0.10' | 0.45
Whole manure. 87 0.50 0.35 0.40

Since the horse does not ruminate its food, the manure
is likely to be of an open character. It is also a fairly
dry manure, as is that from sheep, the liquid in these two
manures making up 20 and 33 per cent, respectively,
of the whole product. The complete manure from these
two animals contains 78 and 68 per cent, respectively,

1Van Slyke, L. L. Fertilizers and Crops, p. 291. New
York. 1912.

FARM MANURES 585

of water — a considerable contrast to the 86 and 87 per
cent presented by the cattle and swine excrements.
Cattle and swine manures, being very wet, are rather
solid and compact. The air, therefore, is likely to be
excluded to a large degree and decomposition is relatively
slow. They are usually spoken of as cold, inert manures
as compared with the dry, open, rapidly heating excre-
ments obtained from the horse and the sheep.

In every case except that of swine the liquid portion
of the various excrements is much the richer in nitrogen,
containing on the average more than twice as much when
compared on the percentage basis. The liquid is also
richer in potash than the solid, averaging for the four
classes of animals 1.36 per cent as compared to 0.34 per
cent contained in the solid manure. Most of the phos-
phoric acid, however, is contained in the solid excrement,
only traces being found in the urine except in the case
of the swine. It is therefore evident that the liquid
manure, pound for pound, is more valuable in so far as
the plant-food elements are concerned. The advantage
leans heavily toward the urine also in that the constit-
uents therein contained are immediately available; this
cannot be said of the solid manure.

489. Actual plant-food in liquid and solid excrement. —
While the liquid manure carries more nutriments to an
equal weight than the solid, it yet remains to be seen
which actually carries more of the primary food elements.
In general, more solid manure is excreted than liquid,
tending to throw the advantage toward the former in so
far as total food elements are concerned. The following
table, adopted from Van Slyke,! bears on this point : —

1Van Slyke, L. L. Fertilizers and Crops, p. 295. New
York. 1912.

586 SOILS: PROPERTIES AND MANAGEMENT

DISTRIBUTION OF PLANT-Foop CONSTITUENTS BETWEEN THE
LiguID AND THE SoLip oF WHOLE Manure

PERCENTAGE

PERCENTAGE PERCENTAGE
or TOTAL Por poral c or ToTaL
EXCROEMENT NirTrRoGEN ‘ACID PotasH

Solid | Liquid] Solid | Liquid] Solid | Liquid

Horse ..... .{| 62 38 100

0 56 44

Cow. ..... .| 49 51 | 100 0 15 &5

Sheep .... . .| 52 48 95 5 30 70

Swine... . . .| 67 33 88 | 12 57 43

Average. . . . .| 57 43 95 5 40 60
Average for horse and

cow .... .| 55 45 | 100 0 35 65

It is seen here that a little more than one-half the
nitrogen, almost all the phosphoric acid, and about
two-fifths of the potash, are found in the solid manure.
Nevertheless this apparent advantage of the solid manure
is balanced by the ready availability of the constituents
carried by the urine, giving it in total about an equal
commercial and agricultural value with the solid excre-
ment. Such figures are suggestive of the care that should
be taken of the liquid manure. Its ready loss of nitrogen
by fermentation, and the ease with which all its valuable
constituents may escape by leaching, should make it
an object of especial regard in handling.

490. Production of manure. — A well-fed, moderately
worked horse will produce daily from 45 to 55 pounds
of manure, of which from 10 to 11 pounds is urine. A
cow, on the other hand, having a greater food capacity,
will excrete from 70 to 90 pounds during the same period,
of which from 20 to 30 pounds is liquid. Swine and

FARM MANURES 587

sheep, varying so greatly in weight, will excrete such
widely different quantities that it is difficult and mis-
leading to express the amount based on the individual.
A clearer method of comparison is that employed below,
in which a thousand pounds in weight of animal is made
the basis of the calculation : —

ManvurE ExcrRetTeD BY Various Farm ANIMALS To THE 1000
Pounps Live WEIGHT

Ania Fopmns | Tos
Horse . . 2... we ee el 50 9.1
Cow? . . 2. 2. 6 ew eee 70 12.7
Steer? . . . . 1. kw ew ee AQ 7.3
Swine . . . .0. 0. 6 2 we ee 85 15.5
6.2

Sheep® . ..... .. . . . .4 84 .

It is quite evident that, for the weight of animal, the
swine and the cow give the heaviest production of manure
on the farm, but it should be remembered also that they
consume the greatest amount of food. Whether these
animals are the most economical in production of manure
must depend largely on age and individuality.

1 Roberts, I. P., and Wing, H. H. On the Deterioration of
Farmyard Manure by Leaching and Fermentation. Cornell
Univ. Agr. Exp. Sta., Bul. 13. 1889. Also, Roberts, I. P.
The Production and Care of Farm Manure. Cornell Univ.
Agr. Exp. Sta., ‘Bul. 27. 1891. Also, Watson, G. C. The
Production of Manure. Cornell Univ. Agr. Exp. Sta., Bul. 56.
1893.

2Thorne, C. EK. Farm Manures, p. 97. New York. 1914.

’'Thorne, C. E., and others. The Maintenance of Fertility.
Ohio Agr. Exp. Sta., Bul. 188. 1907.

4 Watson, G.C. The Production of Manure. Cornell Univ.
Agr. Exp. Sta., Bul. 56. 1898.

5Van Slyke, L. L. Fertilizers and Crops, p. 294. New
York. 1912.

588 SOILS: PROPERTIES AND MANAGEMENT

491. Heiden’s formulas. — Perhaps a better and more
nearly accurate means of calculating the probable pro-
duction of manure is from the food consumed, rather
than from the combined weight of animals kept. Formu-
las have been devised from experimental data in Ger-
many and are designated as Heiden’s formulas! From
the amount of absolute dry matter fed and the excrement
produced, Heiden was able to determine certain definite
relationships of the latter to the former. These, of course,
varied for different animals, being 2.10 for the horse, 3.80
for the cow, and 1.80 for sheep. For example, if a horse
received 20 pounds of dry matter daily, the manurial
production would be 42 pounds. Such formulas are of
particular value on English farms, where the incoming
renter must pay the preceding tenant for the manure
produced on the farm during previous years.

492. Poultry manure. — The excrement from poultry
is extremely variable, due to causes that have already
been discussed. In general, this manure is much richer
than that from other farm animals. Storer? cites the
following analysis : —

Composition or Pouttry MANnuRE

Per cent
Water ........ . 0.56
Nitrogen . ....... 1.60
Phosphoricacid . . . . . . 1.75
Potash . . ...... . 0.90.
Lime. . ...... 2.25

1 Henry, W. A. Feeds and Feeding, p. 265. Madison,
Wisconsin. 1904.

2Storer, F. H. Agriculture, Vol. 1, p. 618. New York.
1910. Also, Vorhees, E. B. Ground Bone and Miscellaneous
Samples. New Jersey Agr. Exp. Sta., Bul. 84. 1891. Also,

FARM MANURES 589

It is evident that poultry excrement is the most valu-
able manure produced on the farm. It dries readily
and the loss of nitrogen by fermentation is not great.
Because of its great strength farmers are very careful
regarding its application, as injurious effects on the crop
may result. Notwithstanding its great value it probably
receives less care than any other manure produced on the
farm.

493. Commercial and agricultural evaluation of
manures. — For purposes of comparison, experimenta-
tion, and sale, farm manures are often evaluated in a way
similar to that used with commercial fertilizers. The
great difficulty here lies in arriving at prices for the im-
portant constituents which are at all comparable with the
value of the manure in the field. The following figures
are calculated from the preceding tables, and show not
only the comparative value of the fresh excrement from
different sources but also what might be considered as
fair prices a ton for the manures. The value of the nitro-
gen is here placed at ten cents a pound, the phosphoric
acid at two and one-half cents, and the potash at four
cents : —

Value of

manure

a ton

Swine manure ........ .. . . $1.50
Cow manure ........ . +... 41.64
Horse manure ............ %J.97
Sheep manure ........... . 2.87
Poultry manure . . . . . « . 4,80
Average of cow manure and horse n manure mixed. 1.80

Goessman, C. A. Massachusetts State Exp. Sta., Bul. 37,
1890, and Bul. 63, 1896.

590 SOILS: PROPERTIES AND MANAGEMENT

This commercial evaluation, of course, must be applied
with care because of the many factors tending to vary
the composition of the excrement. Litter, particularly,
will exert a great influence in this direction. Perhaps a
safe figure as regards the commercial value of manure
as it is likely to be handled on the average farm is about
$1.50aton. This approaches more nearly the price that a
market gardener, for example, may pay for such a product.

This commercial evaluation must never become con-
fused with what is known as the agricultural value of a
manure. The former is based on composition, while
the latter arises from the effects as measured in crop
growth. A manure of high commercial value may, when
placed on the soil, yield only a low to medium agricultural
return. This latter evaluation is, of course, the one of
greatest significance in agricultural practice. A very
good example of this might be cited from the Ohio experi-
ments! with manure. In this case both treated and
untreated manures were evaluated commercially and
were then applied to the land. The value of the increased
crops in a three-years’ rotation was then calculated in
terms of return to a ton of manure applied : —

COMMERCIAL AND AGRICULTURAL EVALUATION oF MANURES

Conarar- AGRICUL-
Manure clAL VaLuE Vatow
Yard manure untreated . . . . . . «| $14i1 $2.15
Yard manure plus floats Lo . oe 2.04. 3.31
Yard manure plus acid phosphate tee 1.65 3.67
Yard manure plus kainit. . . . . .. 1.45 2.79

Yard manure plusgypsum . ..... 1.48 2.76

1'Thorne, C. E., and others. The Maintenance of Fertility.
Ohio Agr. Exp. Sta., Bul. 183, pp. 206-209. 1907.

FARM MANURES 591

In practice, then, it is this agricultural evaluation which
must be especially watched. Its expression should be
not only in net yield to the acre, but also in net return
to a ton of manure applied.

494. The fermentation of manure.1.— During the
processes of digestion the food of animals becomes more
or less decomposed and decayed. This condition comes
about partly because of the digestive processes and
partly from the bacterial action that takes place, largely
in the lower intestines. Of these two influences within
the animal, bacterial activities are probably of the greater
importance as far as the breaking-up of the complicated
foodstuffs is concerned. The fresh excrement, then, as
it comes from the stable, consists of decayed or partially
decayed plant materials, with a certain amount of broken-
down animal tissue and mucus. This is more or less
intimately mixed with litter and the whole mass is wetted,
or moistened, with the liquid excrement, carrying, as it
does, considerable quantities of soluble nitrogen and
potash. This mass of material, ranging from the most
complex compounds to the most simple, is teeming with
bacteria, especially those that function in decay and putre-
faction. The number very often runs into billions to a
gram of excrement. In such an environment it is of
little wonder that biological changes go on so rapidly.

Although so many different groups of organisms live
and function in manure, and although so many products,
both simple and complex, are continually being split
off, for convenience and simplicity the bacteria may be

1Good discussions may be found as follows: Lipman, J. G.
Bacteria in Relation to Country Life, pp. 303-356. New York.
1911. Hall, A. D. Manures and Fertilizers, pp. 184-210.
New York. 1910.

592 SOILS: PROPERTIES AND MANAGEMENT

grouped under two heads, aérobic and anaérobic. The
former work in the presence of oxygen, the latter when
air is either lacking or only very slightly present. This
grouping is not a distinct one by any means, as many
organisms may function not only in air but also when
oxygen is lacking. The products, however, are as dif-
ferent under these two conditions as if they arose from
distinct organisms.

495. Aérobic action. — When manure is first produced
it is likely to be rather loose, and if allowed to dry at
once it becomes well aérated. The first bacterial action
is therefore likely to be rather largely aérobic in nature.
Transformations are very rapid and are accompanied by
considerable heat, ranging from 100° to 150° F. and some-
times higher. This action falls largely on the simple
nitrogenous compounds. Urea is principally affected,
and will very quickly disappear from well-aérated manure.
The reaction is as follows : —

CON.H, + 2 H,O = (N Ha)o CO,

The ammonium carbonate is a volatile compound, and
on the least exposure and evaporation of the manurial
liquids it changes into ammonia and carbon dioxide.
Thus nitrogen may be rapidly lost from manure by the
unwise allowing of excessive aérobic decay and decom-
position to proceed.

This complex group of aérobic putrefactive organisms
also attack to a certain extent the more complicated ni-
trogenous compounds, as well as some of the simpler car-
bohydrates contained in the solid and the liquid portions
of the manure. More carbon dioxide therefore results,
as well as certain simplified products which ultimately
may be reduced to such a form as to be available as plant-

FARM MANURES 593

food. In other words, the whole mass of the manure
tends to simpler forms. The mass becomes decayed,
humus is produced, and available plant-food is evolved.

496. Anaérobic action.— As the manure becomes
compacted, especially if it is left moist, oxygen is grad-
ually excluded within the heap and its place is taken by
carbon dioxide, which is given off during the process of
any form of bacterial activity. The fermentation now
changes from aérobic to anaérobic, it becomes slower, and
the temperature falls to as low as 80° or 90° F. New
organisms may now function, and even some of the same
ones that were active under aérobic conditions may con-
tinue to be effective. The process is now a deep-seated
one and the products become changed to a considerable
degree. Carbon dioxide, of course, continues to beevolved,
but instead of ammonia being formed the nitrogenous
matter is converted into the usual putrefactive products,
such as indol, skatol, and the like. The carbonaceous
matter is resolved into numerous hydrocarbons, of which
methane (CH,) is prominent; and as a by~product of
the breakihg-down of the proteins, hydrogen sulfide
(H.S) and sulfur dioxide (SO,) are evolved. The com-
plex nitrogenous and carbohydrate bodies are attacked
with the splitting-off, not only of simpler materials, but
often of those more complex. Such compounds may be
listed in general as organic acids and humic bodies.
They of course ultimately succumb to simplification.

497. Fermentation in general.—In any process of
fermentation, acids tend to form which if not neutralized
will render the mass acid and impede bacterial activity.
This occurs when the solid excrement decomposes alone.
The liquid manure, however, is alkaline and will tend
to correct any acidity due to fermentation. The advan-

594 SOILS: PROPERTIES AND MANAGEMENT

tage of either handling the liquid and the solid together,
or pumping the liquid over the solid at intervals, is there-
fore apparent.

The general changes in any manure pile can readily
be recapitulated. First is the aérobic action, with escape
of ammonia and carbon dioxide. Next the manure is
wetted, it compacts, and the slow, deep-seated decay
sets in with a simplification of some compounds, with
the production of acids, and with a gradual formation
of humic materials. As the manure becomes alternately
wet and dry, the two general processes may follow each
other in rapid succession, the anaérobic bacteria attack-
ing the complex materials, the aérobic affecting both the
complex and the simpler compounds. Carbon dioxide
is given off continuously during the process.

498. Gases from manure.— The changes in the
composition of the gases drawn from wet and compact
manure, as compared with those from the same pile dry
and open, are well shown from results by Dehérain.'
The pile in this experiment was about eight feet high : —

COMPOSITION oF Gases FROM Dry anp Moist Manure

PERCENTAGE OF

MANURE
CO2 Oz CH, N
Top 7.2 7.0 0.0 85.8
Dry manure { Middle 14.5 4.7 1.3 79.5
Bottom 50.8 0.0 49.2 0.0
Wet and { Top 42.7 Ll 52.4 9.8
compact < Middle 49.8 0.0 48.3 2.2
manure Bottom 47.8 0.0 51.2 1.0

1Hall, A.D. Fertilizers and Manures, p. 188. New York. 1910.

FARM MANURES 595

It is noticeable that nitrogen ceases to be lost under
anaérobic conditions, but the production of’ methane is
mouch increased. Carbon dioxide is present at all times.

499. Change of bulk and composition of rotting manure.
— Because of the great loss of carbon dioxide during the
fermentation processes, there is a considerable change in
bulk of the manure. Fresh excrement loses 20 per cent
in bulk by partial rotting, 40 per cent by more thorough
rotting, and 60 per cent by becoming completely decom-
posed. This means that 1000 pounds of fresh manure
may be reduced to 800, 600, or 400 pounds, according
to the degree of change it has undergone.

Although considerable loss of nitrogen may have oc-
curred through aérobic bacterial action, and although
both nitrogen and the minerals may have been consider-
ably leached away, the loss of carbon dioxide is so much
greater that generally there is an actual percentage in-
crease of the former constituents in the well-rotted prod-
uct. This relationship is well shown by figures from
Wolff,! in which the samples were compared on the basis
of equal amounts of dry matter : —

ComposiITion of FresH AND Drcomposep Manure

ieee ARIA, Hela mAs

FRESH Rorrep
(Per cent) | (Per cent)

Ash . .... ee ee ee ee 8B 4.76

Nitrogen . 2. . 1. ee ee ee 0.39 0.49
Potash . . 2... ee ew ee ee 0.45 0.56
Lime .... .. 2. 2. «© e 2 es 0.49 0.61
Magnesia . ...... . . . .] 0.12 0.15
Phosphoric acid . ...... . .{ 0.18 0.23

Sulfuric acid . . . . . . .. . .}| O10 0.13

1 Aikman, C. M. Manures and Manuring, p. 288. Edin-
burgh and London. 1910.

596 SOILS: PROPERTIES AND MANAGEMENT

It must be remembered, however, that this is only a
general case and holds good only when the manure has
had fairly careful attention. When the manure has been
improperly handled, the soluble constituents may be lost
as soon as formed and a rotted product may result which
is very low in nitrogen, potassium, and phosphorus. It is
therefore evident that the handling of the fresh manure is
a controlling factor in the ultimate value of the product.

A further insight into the condition of rotted manure
is given by Voelcker,! the data being calculated to a dry-
weight basis : —

Froese Rorrnp
MANURE Manvurn
(Per cent) | (Per cent)

Soluble organic matter . . ..... 7.33 15.09

Soluble inorganic matter . ..... 4.55 5.98
Insoluble organic matter . . . . . .| 76.14 51.34

Insoluble inorganic matter . . . . . .| 11.98 27.59

These figures show the increased soluble matter in
well decomposed manure and emphasize the value of
rotting. ‘The great loss of organic matter through the
giving-off of carbon dioxide is also evident.

500. Fire-fanging of manure. — A change of a fermenta-
tive nature which sometimes takes place in loose and well-
dried manure is fire-fanging. Many farmers consider
this to be due to actual combustion, as the manure is very
light in weight and has every appearance of being burned.
This condition, however, is produced by fungi instead
of bacteria, and the dry and dusty appearance of the

1 Halligan, J. E. Soil Fertility and Fertilizers, p. 67. Eas-
ton, Pennsylvania. 1912.

FARM MANURES 597

manure is due to the mycelium, which penetrates in all
directions and uses up the valuable constituents. dIanure
thus affected is of little value either as plant-food or as a
soil amendment.

501. Waste of farm manures. — Any system of agri-
culture, in order to be permanent, must arrange for the
addition of as much plant-food as is removed in the crop
and the drainage water combined. Even if all of the
crop were returned to the soil, a permanent system of
agriculture would fall far short of being established, since
at least as much plant-food is removed by leaching as by
cropping. As a matter of fact, it is not even possible to
return to the land as farm manure all the constituents
taken off in the crop, due to the ease with which loss occurs.
These losses may be grouped under two general heads:
(1) those that occur as the food passes through the animal ;
and (2) those that are due to leaching and fermentation.

502. Losses due to digestion. — A certain quantity of
material is necessarily taken from the original food as it
passes through the animal. This loss falls most heavily
on the organic matter and only slightly on the mineral
constituents. Wolff! presents the following figures aver-
aged from all classes of animals : —

PERCENTAGE or Originat Foop Constituents RECOVERED
In Presa MANURE

tener emg amenanem

sank capt

Sourp Liquip

MANURE MANURE Toran
Organic matter . . . 42.5 3.4 45.9
Nitrogen . . . . . 40.1 47.2 87.3

Minerals . . . . . 59.7 39.0 98.7

rennet see ebtnsedtattttteiequenngsran error ener enamel ARRAS RO itenpnnAewettenr ahi

nnn emateesheemertos vente NSiNmianaae He mnmmeaemammadabsetinhltin ilps ELTA er n-fPRANHaSnR ERR Tie eR NIE ATBRLAA IAN mrs tenis PHN

1 Aikman, C. M. Manures and Manuring, pp. 228 and 232.
Edinburgh and London, 1910.

598 SOILS: PROPERTIES AND MANAGEMENT

It is to be noted that the organic matter of the food
has sustained an average loss of about 55 per cent, while
the loss of nitrogen and of minerals has been 13 per cent
and 2 per cent, respectively. The loss of the organic
matter is especially serious, although it can be replaced by
using green manures and the practicing of a proper rotation.
The loss of nitrogen can be replaced only by the growing
of legumes or by the addition of a nitrogenous fertilizer.

503. Losses due to leaching and fermentation. — As
about one-half of the nitrogen and two-thirds of the potash
in farm manures is in a soluble condition, the possibility
of loss by leaching is very great, especially where the
manure is exposed to heavy rainfall. The loss of phos-
phorus is also of some consequence. In addition, the
fermentation, especially that of an aérobic nature, will
cause the formation of ammonia, which may be lost in
large quantities if steps are not taken to control such
action. It is evident that losses by leaching may be
checked considerably by protecting the manures from
excessive rainfall and by providing tight floors in the
stable or an impervious bottom in the manure pit or
under the manure pile. Packing and moistening the
manure will change the aérobic fermentation to anaérobic,
thus reducing very markedly the production of ammonia
while allowing a simplification of the manurial compounds
to proceed steadily. All wise methods of handling and
storing manures provide against these losses through
leaching and fermentation by protecting the manure from
rain and by controlling fermentation through moisten-
ing and compacting.

It is very difficult, in quoting figures for waste of
manure, to separate the losses due to leaching from those
due to fermentation. The two processes go on simul-

FARM MANURES 599

taneously, and the loss from one source is dependent, to
a certain extent, on the other. It is only the nitrogen,
however, that may be lost by both fermentation and
leaching, the minerals being wasted only through the
latter avenue. A few figures regarding the losses to
manures when exposed to atmospheric conditions may
not be amiss at this point : —

LOSSES FROM MANURE THROUGH LEACHING AND

FERMENTATION
New
N New N J Cpsey
Ew EW Ver
Yorx! Yors} CANADY vont age for Oxt0 4
eight
years)

seamen ermrmeeeitiohen amend Remmemumen =a etainn naan’ Heenmanneemuna eesaeniaatanrand Teaeeeenueanenainae nes acadl Renee eT Recenter

Kind of Manure Horse | Horse | Horse Cow

emcnaamaatetivasemtvieetnstt | Aereteeemiithiyerriarr || peetiniiinetitineteiaiten | nites mE | LapmRReerNTEInetererttes | shone rinrtsheptimthd

|
ee |
Time exposed (days) .| 183 | 188 | 274 | 183 | 77 | 94
Loss of nitrogen (per- |

centage) . 36 60 40 41; 31 30
Loss of phosphoric acid

(percentage) . . 50 47 16 19 | 19 23
Loss of potash (percent-

age) . .. . . .| 60 76 34 8 | 43 58

It seems evident that when manure is exposed to at-
mospheric agencies, even under the best conditions, the
losses of nitrogen, phosphoric acid, and potash will be
on the average 45, 30, and 50 per cent, respectively.

1 Roberts, I. P., and Wing, H. H. On the Deterioration
of Farmyard Manure by Leaching and Fermentation. Cornell
Univ. Agr. Exp. Sta., Bul. 13. 1889.

2 Schutt, M. A. Barnyard Manure. Canadian Dept. Agr.,
Centr. Exp. Farms, Bul. 31. 1898.

’ Thorne, C. E. Farm Manures, p. 146. New York. 1914.

4 Thorne, C. E., and others. The Maintenance of Fertility.
Ohio Agr. Exp. Sta., Bul. 188. 1907.

600 SOILS: PROPERTIES AND MANAGEMENT

Under conditions on the average farm such losses may
easily rise to 50 per cent of all the constituents, and prob-
ably very much higher as regards nitrogen and potash.
From one-half to three-fourths of the important elements
contained in the original food fails to again reach the
land. Hall,} quoting from Woods’ experiments at Cam-
bridge, shows that about 10 per cent of the nitrogen in
the food consumed is retained by the animal. He also
shows that 15 per cent of nitrogen is lost during the making,
and from 10 to 25 per cent during the storage, of the ma-
nure, even under the best conditions. This gives a total
loss of nitrogen amounting to from 35 to 50 per cent. If
this is the loss under the best conditions, it can readily
be seen that the loss on an average farm must approach
65 or 75 per cent.

Some idea as to separate losses from fermentation and
leaching may be gained from data drawn from Canada.?
In this experiment a mixture of horse dung and cow dung
was divided. One-half was placed in a bin under a shed;
the other half was exposed to the weather, outside in a
similar bin. After a year the two portions were analyzed
and the losses computed : —

Losses FrRoM MANURE arrer Tweitve Monras

tana meester sinters tian Ata neti NN Emerita RAH aarti

PROTECTUD UNPROTECTED

(Per cent) (Per cent)
Loss of organic matter . . .. . 60 69
Loss of nitrogen... ... . 23 40
Loss of phosphoric acid . . . . . 4 16
Loss of potash . . woe ee 3 36

1 Hall, A. D. Fertilizers and Manures, p. 198. New York.
1910.

*Schutt, M. A. Barnyard Manure. Canadian Dept. Agr.,
Centr. Exp. Farm, Bul. 31. 1898.

FARM MANURES 601

Evidently the losses by fermentation are verv consider-
ably augmented by exposure, especially if the rainfall
is high. This waste not only is very considerable as
regards the nitrogen, but is especially high as far as the
organic matter 1s concerned. Such figures serve also
to emphasize again the importance of shielding manure
in storage from excessive rainfall. Some water is, of
course, necessary, but too much serves only to carry
away the materials already soluble or rendered soluble
by fermentation.

504. Increased value of protected manure. — From
the previous discussion it is evident that a well-protected
and carefully preserved manure will be higher in plant-
food constituents than one not so handled. Moreover,
the agricultural value of such manure will be higher.
This is shown by actual tests from Ohio! Over a period
of fourteen years, in a three-years’ rotation of corn, wheat,
and hay, a stall manure gave a vield 30 per cent higher
than that with a yard manure, the quantities applied in
each case being equal. In New Jersey, in comparing
fresh manure with leached manure the former showed a
gain in crop yield 53 per cent higher than the latter over
a period of three years immediately following the appli-
cation. Such figures are worthy of careful considera-
tion by the average farmer.

505. The money waste of manure.— To make the
seriousness of the question of waste in manures more
striking, the probable losses may be calculated in money
value for the United States. The entire live stock of all
kinds in this country may be roughly calculated as equiv-

1'Thorne, C. E., and others. Plans and Summary Tables
of the Experiments of the Central Farm. Ohio Agr. Exp. Sta.,
Cire. 120. 1912.

602 SOILS: PROPERTIES AND MANAGEMENT

alent in manure producing capacity to about 100,000,000
cattle, each weighing 1000 pounds. Assuming that
each animal will produce manure to the value of $21
a year and that the cattle are yarded for four months,
the total value of excrement produced during the yarding
period would be, in round numbers, $700,000,000. If
only one-third of the value of the manure is lost by mis-
handling, an annual waste of $233,000,000 would occur.
This is a very conservative estimate regarding the losses
of farm manure throughout the United States. The an-
nual sale of commercial fertilizers in this country, prob-
ably amounting to over $100,000,000, is entirely inade-
quate to replace this loss.

506. Handling of manures. 1— The ultimate considera-
tion in a study of farm manures comprises the best
methods of economic handling, both as to labor and as to
the saving of the constituents carried by the product. The
greater the amount of plant-food that can be saved in
the manure and returned to the land, the less will be the
necessity of commercial sources of these elements. Many
methods present themselves as being more or less effica-
clous, but none are absolutely perfect, as losses by fer-
mentation are bound to occur even though leaching is
entirely prevented. Methods of handling are usually
chosen because of their adaptability to particular cir-
cumstances, rather than because of the exact amount
of valuable constituents that they will conserve.

1Good discussions of handling farm manure are as follows:
Hart, E. B. Getting the Most Profit from Farm Manure.
Wisconsin Agr. Exp. Sta., Bul. 221. 1912. Beal, W.H. Barn-
yard Manure. U.S.D.A., Farmers’ Bul. 192. 1904. Roberts,
I. P. The Fertility of the Land, Chapter [X, pp. 188~213.
New York. 1904.

FARM MANURES 608

507. Care of manure in the stalls. — Considerable loss
to manure occurs in the stable, due to fermentation and
leaching. Before the litter can absorb the liquid, it
is likely to ferment and to leach away in exceptional
amounts. ‘Therefore the first care is as to bedding, which
should be chosen for its absorptive properties, its cost,
and its cleanliness. The following table! expresses the
absorptive capacity of some common litters : —

ABSORPTIVE PowrER or BEDDING FoR WATER

Per cent
Wheat straw ...... . . 220
Oak leaves . ....... . £162
Peat ....... . =... 600
Sawdust . .... . .. . . 485
Spenttan ........ . 450
Air-dry humous soll . . . . . 50
Dry peatmoss . . .. .. . . 1800
Muck . ........ . . 200

The amount of litter to be used is determined by the
character of the food. If the food is watery, the bedding
should be increased. In general, the litter may amount
to about one-third of the dry matter of the food consumed.
Sheep require about a pound of bedding a head, cattle
from eight to ten pounds, and horses from six to seven
pounds. No more litter than is necessary to keep the
animal clean and to absorb the liquid manure should be
used, as the excrement is thus diluted unnecessarily with
material which often does not carry large quantities of
fertilizing ingredients.

1Beal, W. H. Barnyard Manure. U.S. D. A., Farmers’
Bul. 192. 1904.

604 SOILS: PROPERTIES AND MANAGEMENT

The next care is that floors shall be tight, so that free
liquids cannot drain away but will be held in contact
with the absorbing materials. The preserving of manures
in stalls with tight floors has been for years a common
method of handling dung in England. The trampling
of the animals, and the continued addition of litter with
the liquid and solid excrement, explain the reason for
the success of the method. The following data, from
Ohio,! show the relative recovery of food elements in
manure produced on a cement floor and on an earth floor,
respectively. The experiment was conducted with steers
over a period of six months.

Recovery oF Foop E.ements In Manure Propucrep
on CrementT Fioor; on HartH FLoor

Prr Cent PER Cunt
Nitrogen . 2. . . 1. 0. ee ee 74.7 62.4
Phosphorus . . . . .... . 77.5 78.9

Potash. . 2. . 0.0.0 we es 87.8 78.4

508. Hauling directly to the field. — Where it is pos-
sible to haul directly to the field, this practice is to be
advised, since opportunities for excessive losses by leach-
ing and fermentation are thereby prevented. Manure
may even be spread on frozen ground or on the top of
snow, provided the land is fairly level and the snow is
not too deep. This system saves time and labor, and
when leaching does occur the soluble portions of the ma-
nure are carried directly into the soil.

509. Cement pit.— Very often it is not convenient

iThorne, C. E. The Maintenance of Fertility. Ohio
Agr. Exp. Sta., Bul. 183, p. 199. 1907.

FARM MANURES 605

nor possible, especially in certain parts of the year, to
haul manure directly to the field. Means of storage
must therefore be provided. Some farmers, if the amount
of manure produced on their lands is large, find it prof-
itable to construct manure pits of concrete. These
storage pits are usually rectangular in shape, with a shed
covering, and with open ends so that a team may drive
in at one end and out at the other. In such a pit leaching
is prevented by the covering and by the solid bottom.
By keeping the manure carefully spread and well mois-
tened, fermentation may proceed with a minimum loss
of nitrogen. Some dairymen even go so far as to utilize
a cistern, into which is shoveled both the liquid and the
solid manure. Later, when fermentation has proceeded
sufficiently, the material is pumped out and applied to
the land. This method is not to be advocated in this
country except under particular conditions.

510. Covered barnyard. Another method of storage
is by means of a covered barnyard. Such a yard must
have an impervious bottom. The manure is spread out
in the yard, and if animals are allowed to exercise here
the manure is kept thoroughly packed as well as damp.
The storage of manure in deep stalls, a favorite method
in England, is similar to this system and has been shown
to be very economical. It also affords an opportunity
for the mixing of the manure from different classes of
animals. The desirability of this has already been shown
regarding horse and cow excrements. The advantages
of trampling, as far as the keeping qualities of manure
are concerned, are clearly shown by the following figures
taken from the work of Frear : + —

1Frear, W. Losses of Manure. Pennsylvania Agr. Exp.
Sta., Bul. 68. 1903.

606 SOILS: PROPERTIES AND MANAGEMENT

Loss or MANURE IN COVERED SHEDS

PERCENTAGE OF

N K20 P205
Covered and trampled . 5.7 5.5 8.5
Covered and untrampled . . 34.1 19.8 14.2

Throwing manure in heaps under a shed and allowing
hogs to work the mass over, 1s an economical practice so
far as food utilization is concerned. It interferes, how-
ever, with proper and economical packing of the manure.
The question to be decided is whether the added food
value of the manure overbalances the extra losses by
fermentation incurred by the rooting of the swine.

511. Piles outside.— Very often it is necessary to
store manure outside, fully exposed to the weather.
When this is the case, certain precautions must be ob-
served. In the first place, the pile should be located on
level ground far enough from any building so that it
receives no extra water therefrom in times of storm. The
earth under the pile should be slightly dished in order
to prevent loss of excess water. If possible, the soil
of the depression should be puddled, or, better, lined with
cement.

The sides of the heap should be perpendicular, so as
to shed water readily. The manure must be kept moist
in dry weather in order to decrease aérobic action. Each
addition of manure should be packed in place, the fresh
on and above the older. This allows the carbon dioxide
from the well-rotted dung to pervade the fresher and
looser portions, thus quickly establishing the aérobic

FARM MANURES 607

conditions so essential to economic and favorable fer-
mentation.

Placing fresh manure in small heaps in the field to be
spread later, is, in the first place, poor economy of labor.
Moreover, it encourages loss by fermentation, while at
the same time the soluble portions of the pile escape into
the soil immediately underneath. There is thus a poor
distribution of the essential elements of the dung, and
when the manure is finally spread, an overfeeding of
plants at one point and an underfeeding at another results.
A low efficiency of the manure is thus realized. This
method of handling manure is not to be recommended.

512. Distribution of manure in the field.— In the
actual application of manure to the land, certain general
principles should always be kept in mind. In the first
place, evenness of distribution is to be desired, since it
tends to raise the efficiency of the manure bv encouraging
a more uniform plant growth. This evenness of spread-
ing is much aided by fineness of division. Moreover, it
is generally better, especially in diversified farming on
medium to heavy soils, to decrease the amounts at each
spreading and apply oftener. Thus, instead of adding
20 tons to the acre, 10 tons would be applied and twice
as much area covered. The applications would then
be made oftener. A larger and quicker return in net
crop yield per ton of manure applied would be realized.
This has been strikingly shown by the Ohio experiments !
over a test for eighteen years in a three-years rotation of
wheat, clover, and potatoes, the manure being placed on
the wheat and affecting the clover and the potatoes as a

1Thorne, C. li., and others. Plans and Summary Tables
of the Experiments at the Central Farm. Ohio Agr. Exp.
Sta., Cire. 120, p. 108. 1912.

608 SOILS: PROPERTIES AND MANAGEMENT

residuum. The results are expressed in yield per ton of
manure applied : —

Yreto to tar Ton or MANURE WHEN APPLIED IN
DiFFERENT AMOUNTS

WHEAT CLOVER Porators

(Bushels) (Pounds) (Bushels)
4.tons to the acre . . .. 8.0 177 37.3
8 tons to the aere . to 4.1 150 19.4.
16 tons to the aere . . . . 2.4 99 11.6

etree neni tmnt em atte

Not only is the mecreased efficiency from lower appli-
cations apparent, but a great recovery of the manurial
fertility in the crops also results. The Ohio experiments
have shown that in the first rotation after the manure
is applied, a recovery may be expected from a treatment
of 8 tons 25 to 30 per cent higher than from one of
16 tons.

Evenness of application and fineness of division are
greatly facilitated by the use of a manure spreader. This
also makes possible the uniform application of small
amounts of manure, even as low as five or six tons to the
acre. It is impossible to spread so small an amount by
hand and obtain an even distribution. Moreover, a
spreader lessens the labor and more than doubles the
amount of manure one man can apply a day. When
any quantity of manure is to be handled, a manure spreader
will pay for itself in a season or two at the most.

Whether manure should be plowed under or not depends
largely on the crop on which it is used. On timothy it
is spread as a top-dressing. Ordinarily, however, it is
plowed under. This is particularly necessary if the

FARM MANURES 609

manure is long, coarse, and not well rotted. It should
not be turned under so deep, however, as to prevent ready
decay. If manure is fine and well decomposed, it may
be harrowed into the surface soil. The method employed
depends on the crop, the soil, and the condition of the
manure. The amount to be applied varies consider-
ably. Eight tons to the acre would be a light dressing,
15 tons a medium dressing, and 25 tons heavy for an
ordinary soil. On trucking lands, however, as high as
50 or 100 tons is often used.

513. Reinforcement of manure. — The reinforcement
of farm manures is designed to accomplish two things in
the handling of this product: (1) checking loss by leaching
and fermentation, and (2) balancing the manure and
rendering its agricultural value higher. Four chemicals
may be used in this reinforcement: gypsum (CaSOQ,),
kainit CXCl, mostly), acid phosphate (CaH,(PO)»2 +
CaSO,), and floats (raw rock phosphate, Ca3(PO,)2).

Gypsum is supposed to act on the ammonia, changing
it to ammonium sulfate, a stable compound. It is rather
insoluble, however, so that its action is slow. It may be
applied in the stable or on the manure pile. The rate
is about 100 pounds to the ton of manure. It has no
balancing effect.

Kxainit is added to react with any ammonia that may
be produced and also to increase the potash in the manure.
It is soluble, and because of its caustic tendencies it must
not come into contact with the feet of the animals. It
must not be spread on the manure, therefore, until the
stock has been removed. Since manure is unbalanced
as to phosphorus, the agricultural value of this reinforce-
ment is likely to be slight. Kainit is usually added at
the rate of 50 pounds to the ton of manure,

610 SOILS: PROPERTIES AND MANAGEMENT

Acid phosphate, when used as a reinforcing agent, is
applied at the rate of 50 pounds to the ton of manure.
It is soluble, and therefore becomes intimately mixed
with the excrement. It adds phosphorus, in which
manure is especially lacking. Its gypsum may react
with the ammonia. Theoretically it should prevent loss
by fermentation, as well as function as a balancing agent.
It must not come into contact with the feet of farm ani-
mals,

Raw rock phosphate, or floats, is a very insoluble com-
pound, and consequently reacts but slowly with the
soluble constituents of manure. Carrying such a large
percentage of phosphorus, it tends to balance the product
and to raise its agricultural value. It is supposed that
the intimate relationship between the phosphate and the
decaying manure increases the availability of the former
to plants when the mixture is added to the soil. No
increased solubility, however, as determined by chemical
means, has ever been as definitely shown to occur (see
par. 439). The reinforcement is usually at the rate of
100 pounds to the ton of manure.

514. Benefits from reinforcing. — Experimental data
have shown that these various reinforcements have no
effect on the nature, function, and number of the bacterial
flora. Their conserving influence, if any, when the ma-
nure is exposed, must be in checking leaching and in
preventing loss of ammonia. The following figures
from Ohio experiments! show how slight this conserving
effect is. The reinforcement was at the rate of 40 pounds
to the ton : —

1Thorne, C. E. Maintenance of Fertility. Ohio Agr.
Exp. Sta., Bul. 183, p. 206. 1907.

FARM MANURES 611

ConsERVING Errect of Reinrorcing AGENTS ON MANURE
EXPOSED FoR THREE MonTaHS

VaLUE or a Ton oF

TREATMENTS LANURE PERCENTAGE
In January In April
No treatment. . .... $2.19 $1.41 36
Gypsum ..... 4. 2.05 1.48 38
Kainit . . ..... 2.24 1.45 35
Floats . . . . 3.0. 6 2.81 2.04 24.
Acid phosphate . . . . . 2.34 1.65 29

It is immediately evident that kainit and gypsum do not
conserve the manure, and, although acid phosphate and
floats show some influence, it is slight. The principal
benefit from reinforcing manure, if any, must therefore
be as a balancing agent. The figures from Ohio! over a
period of fourteen years in a rotation of corn, wheat, and
hay may be taken as evidence regarding this point.
The manure was added to the corn at the rate of 8 tons
to the acre. The reinforcing was 40 pounds to the ton
of manure in every case : —

THe Rernrorcine or Fresa Manure

Tora, Nev In-

CREASED VALUE Ner INcrEasEep

T ¥ T
REATMENT OF Cnop to mH a Manone ON
Manure plus floats . .. . $35.94 $4.49
Manure plus acid phosphate . 38.55 4.82
Manure plus kainit . .. . 29.67 3.71
Manure plusgypsum. .. . 28.48 ) 3.56

Manure alone ..... . 26.48 3.31

1Thorne, C. E., and others. Plans and Summary Tables
of the Experiments at the Central Farm. Ohio Agr. Exp. Sta.,
Cir. 120, p. 112. 1912.

612 SOILS: PROPERTIES AND MANAGEMENT

This balancing effect may be shown in another way.
Let it be supposed that to 10 pounds of poultry manure
having a composition of 1.6 per cent nitrogen, 1.5 per
cent phosphoric acid, and 0.9 per cent potash, there are
added 4 pounds of sawdust, 4 pounds of acid phosphate,
and 2 pounds of kainit. The manure is rendered drier,
and its composition becomes 0.8 per cent nitrogen, 3.7
per cent phosphoric acid, and 1.5 per cent potash. It is
evident, from this and the data previously given, that
the principal benefit of reinforcing manure lies in the
balancing influence, and that acid phosphate and floats
are the most desirable to use.

515. Lime and manure.— Very often it would be a
saving of labor to apply lime and manure to the soil at
the same time. This can readily be done with the car-
bonated forms. Such lime may be mixed with the
manure, elther in the stable or in the pile, without any
danger of detrimental results. The close union of the
lime and the organic matter may even increase the solu-
bility of the former. Caustic compounds of lime, how-
ever (CaO and Ca(OH).), must be kept from manure.
These active forms react with the ammonium carbonate
coming from the urea, and cause the liberation of the
ammonia, which may be readily lost in the air: —

CONeH, + 2 H.O = (NH,)2CO,
(NH4),CO; + Ca(OH), = CaCO; + 2 NH,OH

A stable or a shed containing manure may be at once
deodorized by the use of quicklime, but only by the loss
of much nitrogen, which costs on the market eighteen or
twenty cents a pound. Caustic lime and manure may be
applied to the same soil by applying the lime ten days
or two weeks before the manure. The lime will then

FARM MANURES 613

have had time to leach into the soil or to largely change
to a carbonate form.

516. Composting. — A compost is usually made up of
alternate layers of manure and some vegetable matter
that is to be decayed. Layers of sod or of humous soil
are often introduced. The manure is used to supply
the decay organisms and to start the action. The foun-
dation of such a humus manufactory is usually soil, and
the pile is preferably capped with earth. The compost
should be kept moist in order to prevent loss of ammonia
and to encourage vigorous bacterial action. Acid phos-
phate or raw rock phosphate and a potassium fertilizer
are often added, to balance up the mixture and make it a
more effective fertilizer. Lime is also introduced, to react
with such organic acids as may tend to form and to inter-
fere with proper decay. Undecayed plant tissue, such as
sod, leaves, weeds, grass, sticks, or organic refuse of any
kind, may thus be changed slowly to a humus which will be
valuable in building up the soil and in nourishing plants.
Even garbage may be disposed of in such a manner.

517. Manure and muck.— Muck soil recently re-
claimed from a swamp condition is usually treated, if
possible, with a dressing of manure. This is not so much
for the purpose of adding plant-food as to supply decay
and decomposition organisms that will break down the
complicated humic compounds into such forms as may
be utilized by the crop. Plenty of lime is therefore essen-
tial in muck, in order to render the effects of this inocu-
lation effective and lasting.

518. Effects of manure on the soil. — The direct fer-
tilizing effect of manure is by no means its greatest
influence. In the first place, manure as it rots down
produces humus. This humus increases the absorptive

614 SOILS: PROPERTIES AND MANAGEMENT

capacity of the soil. In clays it promotes granulation,
while in sands it acts as a binding agent. Under all con-
ditions it promotes granulation and tilth. The capacity
of a soil to resist drought is raised; its aération is in-
creased and drainage is promoted. All these changes
tend to benefit plant growth and to produce those indirect
fertilizing effects that are characteristic of farm manure.

From the chemical standpoint, the presence of manure
in the soil tends to increase organic acids, notably car-
bonic acid. The soil minerals are thus rendered more
easily soluble. The case of the influence of manure on
the action of raw rock in the soil has already been cited.
The humus, also, may combine with certain of the mineral
elements and hold them in a form more easily available
to crops. Nor is the chemical influence of farm manure
the final effect. The modification of the soil flora can
by no means be passed by. Not only are millions of
organisms added by an application of manure, but those
already present in the soil are vastly stimulated by this
fresh acquisition of humic materials. Nitrification, am-
monification, and nitrogen fixation are all increased to a
remarkable degree.

519. Residual effect of manure. — No other fertilizing
material exerts such a marked residual effect as does
manure. This is partly because of its indirect physical
and biological influences, and partly because of the stimu-
lated root development of the crops grown. The greatest
residual influence, however, is brought about by the slowly
decomposable nature of the manure, only a small per-
centage being recovered in the first crop grown after the
manure is applied. Hall+ presents the following data

1 Hall, A. D. Fertilizers and Manure, p. 210. New York,
1910.

FARM MANURES 615
from Rothamsted. The crop was mangolds, and the re-
covery of the constituents carried by the manure was

very low: —

REcovEeRY or NITROGEN IN A Crore ofr MANGOLDS

TREATMENT | Per ACRE ype .. EDRCENTAGE
Nitrate of soda . . | 550 pounds 17.95 78.1
Ammonium salts 400 pounds 15.12 57.3
Rape cake . 2000 pounds 20.95 70.9
Manure . 14 tons 17.44 31.6

et ener eer net y nant
(rhe rreeetNint rt imnuntn ALN Ret ainrnereAUent ten} eprrmrtiren lameness

The length of time through which the effects of an
application of farm manure may be detected in crop
growth is very great. Hall! cites data from the Roth-
amsted experiments in which the effects of eight yearly
applications of 14 tons each were apparent forty years
after the last treatment. This is an extreme case; ordi-
narily, profitable increases may be obtained from manure
only from two to five years after the treatment. The fact
remains, nevertheless, that of all fertilizers farm manure
is the most lasting, lends the most stability to the soil,
and is really a soil builder par excellence.

520. Place of manure in the rotation. — With a num-
ber of trucking crops, the application of manure directly
to the crop year after year has proved to be advisable.
In an ordinary rotation, however, where less intensive
methods are employed, it is evident that manure may
vary in its effect according to the place in the rotation at

1Hail, A. D. Fertilizers and Manure, p. 213. New York.
1910.

616 SOILS: PROPERTIES AND MANAGEMENT

which it is applied. This has proved to be the case with
commercial fertilizers, and the fact is also becoming
recognized in the economic use of farm manures.

In general, hay has derived more benefit from the re-
sidual food than almost any other crop in the rotation.
At the Pennsylvania Experiment Station,’ in a rotation of
corn, wheat, and hay over a test for twenty-five years, in
which manure was applied in equal amounts to the corn
and wheat, the results were as follows : —

Percentacs IncREASE FROM Usr or MANURE, AND VALUE OF
THAT INCREASE

TREATMDONT CorRN Oats Waurar Hay

Ce eT Tn ee nee eee crcl Mnren ste znan aameatemmebsaeeaaiainenen neaneanmdanenll Tenieememmmmmenemeeenetentreemmnanamaaaet

6 tons manure | 37 per cent | 28 per cent |73 per cent ;39 per cent
Cost $9 . .| $10.85 $3.66 $9.70 $6.55

The same fact has been clearly shown in the Ohio
experiments” covering a term of eighteen years. The
query immediately arising here’ is: If hay responds so
well to residual feeding, why not apply the manure
directly to it? On this point the following figures from
the Illinois Experiment Station * may be presented, com-
paring the response of corn and oats when manured to
the yield of clover with the same treatment : —

1Hunt, T. F. General Fertilizer Experiments. Ann. Rept.
Pennsylvania Agr. Exp. Sta., 1907-1908, pp. 68-93.

Thorne, C. E., and others. Plans and Summary Tables
of the Experiments at the Central Farm. Ohio Agr. Exp. Sta.,
Cir. 120, pp. 101-105. 1912.

® Hopkins, C. G. Thirty Years of Crop Rotation in Illinois.
Til. Agr. Exp. Sta., Bul. 125, p. 387. 1908.

FARM MANURES 617

AVERAGE PERCLNTAGE Toran VALUn oF

Hearne ntetipe ne oar oe A see remerttnaeneveneen tit hime mene ettittmreettneintmnuaetimntttgrmerit ih Semen ntntimmtanernmnsibretinn

When hay is included in any rotation it is evident that
the best results from manure may be obtained by placing
it on this crop. This, however, is often not advisable,
especially where the amount of manure is limited. A
commercial fertilizer may take its place on the hay, al-
lowing the farm manure to be utilized on special crops.
When applied to hay it should be spread as a light top-
dressing. When manure is used for such a crop as corn,
however, it is best plowed under, as the amounts added
per acre are often large. Farm manure in judicious
amounts may be harrowed in or plowed under in orchards.

521. Résumé. — From the general discussion already
presented, it is evident that barnyard manure, from the
standpoint of soil fertility, is the most valuable by-product
of the farm. A careful farmer will therefore attempt to
utilize it in the most economical way. The handling of
manure in such a manner that only a small waste will
occur from the time when the manure is voided until it
has reached the land again, is not an easy problem.
Manure is so susceptible to the loss of valuable ingredients,
both by leaching and by fermentation, that careful methods
must be employed. The utilization of tight floors in the
stable and of covered sheds or manure pits is to be ad-

618 SOILS: PROPERTIES AND MANAGEMENT

vised. Hauling immediately to the field is a wise pro-
cedure. Yet even with the best of care a loss of from 30
to 50 per cent is often incurred. A permanent system of
agriculture evidently cannot be established by simply
returning all the manure possible to the land. Neverthe-
less, it is certainly worth the while of any farmer to use
at least some care in the handling of this product. Even
reasonable attention would save for the soils of this coun-
try thousands of dollars’ worth of manurial fertility
which is now carried away in the streams and rivers.

CHAPTER XXVII
GREEN MANURES!

From time immemorial the turning-under of a green
crop to supply organic matter to the soil has been a com-
mon agricultural practice. Records show that the use of
beans, vetches, and lupines for such a purpose was well
understood by the Romans, who probably borrowed the
practice from nations of still greater antiquity. The art
was lost to a great extent during the Dark Ages, but was
revived again as the modern era was approached. At
the present time green-manuring is considered a part of
a well-established system of soil management, and is
given a place, where possible, in every rational plan for
permanent soil improvement.

522. Effects of green-manuring. — The effects of turn-
ing under green plants are both direct and indirect —
direct as to the influence on the succeeding crop, and in-
direct as to the action on the physical condition of the
soil so treated. In the first place, certain ingredients are
actually added to the soil by such a procedure. The car-
bon, oxygen, and hydrogen of a plant come largely from

1Penny, C. L. Cover Crops as Green Manures. Delaware
Agr. Exp. Sta., Bul. 60. 1903.

Storer, F. H. Agriculture, pp. 187-175. New York. 1910.

Lipman, J.G. Bacteria in Relation to Country Life, Chapter
XXIV, pp. 237-263. New York. 1911.

Piper, C. V. Leguminous Crops for Green Manuring.
U.S. D. A., Farmers’ Bul. No. 278. 1907.

Spillman, W. J. Renovation of Worn-out Soils. U.S. D.A.,
Farmers’ Bul. No. 245. 1906.

619

620 SOILS: PROPERTIES AND MANAGEMENT

the air, and the plowing-under of a crop therefore in-
creases the store of such constituents in the soil. If the
plant is a legume and the nodule organisms are active,
the nitrogen content of the soil is also augmented. The
mineral parts of the turned-under crop, of course, come
from the soil originally and they are merely turned back
toitagain. As they return, however, they are in intimate
union with organic materials, and are thus readily avail-
able as plant-food as the decay process goes on. Indeed
they are much more readily available than they previously
were, when the green-manuring crop acquired them.
Actual additions are thus made to the soil, together with
a promotion of an increased availability of the constit-
uents dealt with.

Green manures may function also as cover crops, in
so far as they take up the extremely soluble plant-food
and prevent it from being lost in the drainage water. The
nitrates of the soil are of particular importance in this
regard, as they are very soluble and are adsorbed only
slightly by the soil particles. Besides this, green manures,
especially those with long roots, tend to carry food up
from the subsoil, and when the crop is turned under
this material is deposited within the root zone. Again,
the added organic material acts as a food for bacteria,
and tends to stimulate biological changes to a marked
degree. This bacterial action is especially prone to in-
crease the production of carbon dioxide, ammonia, ni-
trates, and organic acids of various kinds, which are very
important in plant nutrition. The humus that results
from this decay increases the adsorptive power of the soil,
and promotes aération, drainage, and granulation — con-
ditions that are extremely important in successful crop
growth.

GREEN MANURES 621

523. Quantities of plant constituents added by green-
manuring. —In an average crop of green manure, from
five to ten tons of material is turned under. Of this,
from one to two tons is dry matter, and from four to eight
tons water. Of this dry matter a great proportion is car-
bon, hydrogen, and oxygen — a clear gain to the soil in
so far as these constituents are concerned. The amount
of nitrogen added to a soil if the green manure is a legume !
is a difficult question to decide. Much depends on the
virulence of the organisms occupying the nodules. These
bacteria are in turn much influenced by plant and _ soil
conditions. Hopkins? estimates that about one-third of
the nitrogen in a normal inoculated legume comes from
the soil and two-thirds from the air. He also considers
that one-third of the nitrogen exists in the roots. It is
evident, therefore, that in gencral the nitrogen found in
the tops will be a rough measure of the nitrogen fixed by
the soil organisms. If this is returned to the soil, there
is a clear gain of just that amount.

If the preceding assumption is correct, clover® would
actually add to every acre about 40 pounds of nitrogen

1Smith, C. D., and Robinson, F. W. Influence of Nodules
on the Roots upon the Composition of Soybean and Cowpea.
Mich. Agri. Exp. Sta., Bul. 224. 1905.

Hopkins, C. G. Alfalfa on [linois Soil. Tllinois Agr. Exp.
Sta., Bul. 76. 1902.

Hopkins, C. G. Nitrogen Bacteria and Legumes. Illinois
Agr. Exp. Sta., Bul. 94. 1904.

Shutt, F. T. The Nitrogen Enrichment of Soils through the
Growth of Legumes. Canadian Dept. Agr., Rept. Centr. Exp.
Farms, 1905, pp. 127-132.

2 Hopkins, C. G. Soil Fertility and Permanent Agriculture,
p. 223. Boston, 1910.

3 Penny, C. L. The Growth of Crimson Clover. Delaware
Agr. Exp. Sta., Bul. 67. 1905.

622 SOILS: PROPERTINS AND MANAGEMENT

per ton, alfalfa about 50, cowpeas 43, and soy beans
53 pounds. ‘These figures, even though they may
be far from correct, at least give some idea as to the
possible addition of nitrogen by green-manuring prac-
tices, and show how the soil may be enriched by such
management. As in the case of farm manures, the in-
direct effects of such a procedure may override the
direct influences, making the use of legumes as green-
manuring crop less necessary than at first thought might
be supposed.

524. Decay of green manure. — As a green crop enters
the soil, the process of its decay is the same as that of
any plant tissue that becomes a part of the soil body.
The organisms that are active are those common to the
soil, together with such bacteria as are carried into the
soil on the turned-under crop. The decay should be
accomplished under aérobic conditions so that only
beneficial products may result. Plenty of water is a
necessity, as otherwise the soil would be robbed of a
part of its available moisture in facilitating the process of
decay. When proper decay has occurred, end products
should result which can be utilized as plant-food. The
intermediate compounds that are formed should yield a
black humus, should readily split up into simple com-
pounds, and should be in general beneficial, both directly
and indirectly, to crop growth. The decay of green
manure under conditions of poor drainage and improper
aération is likely to cause the generation of materials
detrimental to the proper development of plants.

525. Crops suitable for green manures. — The crops
that may be utilized as green manures are usually grouped
under two heads, legumes and non-legumes. Some of the
common green manures are as follows: —

GREEN MANURES 623

Legumes Non-legumes
Annual Biennial

Cowpea Red clover Rye
Soy bean White clover Oats
Peanut Alsike clover Mustard

fetch Alfalfa Mangels
Canada field pea Sweet clover Rape
Velvet bean Buckwheat

Crimson clover
Hairy vetch

When other conditions are equal, it is of course always
better to choose a leguminous green manure in preference
to a non-leguminous one, because of the nitrogen that may
be added to the soil. However, it is so often difficult to
obtain a catch of some of the legumes that it is poor
management to turn the stand under until after a number
of years. Again, the seed of many legumes Is very expen-
sive, almost prohibiting their use as green manures.
Among the legumes most commonly grown as green ma-
nures, cowpeas, sov beans, and peanuts may be named.
Many of the other legumes do not so fit into the common
rotations as to be handily turned under as a green manure.

For the reasons already cited, the non-legumes have in
many cases proved the more popular and economic as
green manures. Rye and oats are much used because
of their rapid, abundant, and succulent growth and _ be-
cause they may be accommodated to almost any rotation.
They are hardy and will start on almost any kind of a
seed bed. They are thus extremely valuable on poor soils.
Often the value of such & green manure as oats is greatly
increased by sowing peas with it. The advantages of a
legume and a non-legume are thus combined.

624 SOILS: PROPERTIES AND MANAGEMENT

526. When to use green manures. — The indiscrimi-
nate use of green manures is of course never to be ad-
vised, as the soil may be injured thereby and the normal
rotation much interfered with. When soils are poor in
nitrogen and humus, they are very often in poor tilth.
This is true whether the texture of the soil be fine or
coarse. The turning-under of green crops must be judi-
cious, however, in order that the soil may not be clogged
with undecayed matter. Once or twice in a rotation is
usually often enough for such treatments. Proper drain-
age must always be provided. In regions where the rain-
fall is scanty, very great caution must be observed in the
handling of green manures. The available moisture that
should go to the succeeding crop may be used in the
process of decay, and the soil left light and open, due to an
excess of undecomposed plant tissue.

527. When to turn under green crops. — It is generally
best to turn under green crops when their succulence is
near the maximum. In this case a large quantity of water
is carried into the soil, and the draft on the original soil
moisture is less. Again, the succulence encourages a
rapid and more or less complete decay, with the maximum
production of humus and end products. The plowing
should be done, if possible, at a season when a plentiful
supply of rain occurs. The effectiveness of the manuring
is thereby much enhanced.

528. How to turn under green material. — In general,
in turning under green manures the furrow slice should
not be thrown over flat, since the green crop is then de-
posited as a continuous layer between the surface soil
and the subsoil. Capillary movement is thus impeded
until a more or less complete decay has occurred, and the
succeeding crop may suffer from lack of moisture.

GREEN MANURES 625

The furrow ordinarily should be turned only partly
over, and thrown against and on its neighbor. The green
manure is then distributed evenly from the surface down-
ward to the bottom of the furrow. When decomposition
occurs the humic materials are evenly mixed with the
whole furrow slice. Moreover, this method of plowing
does not interfere with the capillary movements of water,
and in actual practice is a great aid in drainage and
aération.

§29. Green manures and lime. — The decay of organic
matter in the soil is always accompanied by the produc-
tion of organic acids. Such acids tend to form in large
amount, especially if the fermenting matter is of a suc-
culent nature. The need of plenty of lime under such
conditions is clearly apparent, as a soil of a neutral or an
acid character may assume a bad condition during the
process of humic decay. Lime may be added to the green-
manure seeding and be turned under with that crop.
The amendment would thus be in very close contact with
the decaying vegetable tissue. Ordinarily, however, the
application of lime at some point in the rotation is suffi-
cient.

530. Green manure and the rotation. — Verv often it
is somewhat of a problem as to when, in an ordinary rota-
tion, a green manure may be introduced so that it may
fit in well with the crops grown. In a rotation of corn,
oats, wheat, and two years of hay, a green manure might
be introduced after the corn. This would nét be a very
good practice, however, as a cultivated crop should
usually follow a green manure so as to facilitate decom-
position and decay. In such a rotation the plowing-
under of the hay stubble is really a form of green-manur-
ing, there being a considerable accumulation of roots,

626 SOILS: PROPERTIES AND MANAGEMENT

stubble, and aftermath on the soil. When a rotation of
this kind is used it is better either to supply organic
matter in other ways, or to alter or break the rotation in
such a manner as to admit of a more advantageous use
of green crops.

Where trucking crops are grown and no very definite
rotation is adhered to, green-manuring is easier. It is
especially facilitated when cover crops are grown, as in
orchards. Soiling operations also favor the easy and
profitable use of green manures. In general it may be
said that the organic matter obtained from such a source
should be supplemented by farmyard manures where
possible. A better balanced and richer soil humus is
more likely to result.

CHAPTER XXVIII
LAND DRAINAGE

LAND drainage! is the process of withdrawing from the
soil the superfluous or gravitational water occurring in
the larger spaces within the normal root zone. Excess
moisture in the soil interferes with ventilation, keeps
down the temperature, and seriously disturbs the physical
nature of the soil. Any means that permits the free flow
from the soil of the gravitational water affords drainage.
Many methods are used, according to circumstances.
Indications of the need of drainage are the presence of
free water in the surface soil and in excavations into the

1 Elliott, C. G. Engineering for Land Drainage. New
York. 1912.

Faure, L. Drainage et Assainissement Agricole des Terres.
Paris. 1908.

King, F. H. Irrigation and Drainage, Part IT. New York.
(Revised edition. 1909.)

Klippart, J. H. Principles and Practice of Land Drainage.
Cincinnati. 1894.

Woodward, S. M. Land Drainage by Means of Pumps.
U.S. D. A., Office Exp. Sta., Bul. No. 248. I911.

Warren, G. M. Tidal Marshes and their Reclamation.
U.S. D. A., Office Exp. Sta., Bul. No. 240. 1911.

Elliott, C. G. Drainage of Farm Lands. U. S. D. A.,
Farmers’ Bul. No. 187. 1904.

Miles, M. Land Drainage. New York. 1897.

See also the following bulletins of state experiment stations:
Michigan, Sp. 56; Maryland, 186; New York (Cornell), 254;
Utah, 123; Wisconsin, 138, 199, 229; Ontario, Canada, 174,
175.

627

628 SOILS: PROPERTIES AND MANAGEMENT

subsoil; and the tendency of the soil to puddle and bake
when dry. When the wetness is prolonged, the accu-
mulation of organic matter in the surface soil imparts a
dark color. Poor drainage causes a mottled color in the
subsoil, and in extreme cases a pale gray color resulting
from excessive leaching. When the land is in crops the
wet places are recognized by their miry condition in early
spring and after rains, and by the slow starting of the
crop. In meadows the grass is often winterkilled, leaving
only those weeds that can withstand the conditions.
Heaving of soil is another indication of wetness. In tilled
crops the wet spots are often marked by the small growth
of the plants and by curled, wilted leaves in dry periods.
In orchards weakened and missing trees are in many
cases an indication of defective drainage, especially in the
subsoil, where the roots of older trees seek to develop.

Steeply sloping hill land may need drainage quite as
much as flat land if it has a compact subsoil overlaid by a
porous topsoil. Water is then trapped in the soil, and is
removed very slowly by percolation on top of the hard
subsoil and by evaporation. It is wet land in need of
drainage.

531. Extent of drainage needed in humid regions. —
The amount of farm land in need of some drainage is very
large. Besides the land commonly designated as swamp
and marsh, there are very large areas of land devoted to
crop production, the yields from which are reduced by the
excess of water that they contain at certain seasons of the
year. The extent of swamp land varies in different coun-
tries, but is likely to aggregate about five per cent of the
total area. The cropped land in need of some drainage is
very much larger, and roughly aggregates three-fourths of
the total improved land surface. The temporary wetness

LAND DRAINAGE §29

that much land experiences is often more injurious than
the prolonged wetness of swamp land. On the latter
there is no loss except on the investment value of the land,
which is likely to be low. On the tilled land, however, a
considerable sum of money is expended for labor, seed,
and perhaps fertilizers and manures, without corresponding
returns. The loss under these conditions may be heavy.
For the ordinary farm and garden crops, the fluctuation
of the soil moisture from a condition of somewhat pro-
longed saturation to the dry and often bard condition
that usually results is exceedingly difficult to withstand.
Drainage is concerned not only with the surface and the
topsoil water, but also with the subsoil water to the depth
to which the roots of crops normally penetrate.

532. History of drainage. — The need for soil drainage
in the production of the ordinary farm and garden crops
on many soils has been recognized from the beginning of
historic times. The old Roman husbandman Cato,? and
his successors of the next ten centuries, in their writings
on agriculture pointed out the importance of draining wet
soil, and Cato explains how bundles of faggots should be
buried in trenches in the land. In western Europe?
artificial drainage has been practiced for some hundreds
of years. In England within the last two hundred years
drainage by means of pipes has become a general practice.

The practice of underdrainage by means of clay tile
was begun in America in the early part of the nineteenth

1Cato, M. P. Roman Farm Management by a Virginia
Gentleman. New York. 1913.

2 Elliott, C. G. Engineering for Land Drainage. New
York. 1912.

Miles, M. Land Drainage, Chapter VI. New York. 1892.

French, H. F. Farm Drainage, Chapter IT. New York.
1859.

630 SOILS: PROPERTIES AND MANAGEMENT

eentury. John Johnston, a Scotchman living near
Geneva, New York, carried out the most extensive of
these pioneer enterprises, beginning about 1835. A very
thorough system of tile drains, aggregating about sixty
miles in length, was installed on his farm of three hundred
acres, and these drains are still in operation and are pro-
ducing excellent results.

533. Effects of land drainage on the soil. — The need
and value of thorough drainage of the soil can often be
better appreciated after a careful summary of its effects
on the properties that determine crop growth. From a
study of these it may be seen that for the production of
the ordinary upland crops a reasonable amount of soil
drainage is the first requisite. It may well be termed
the foundation of good soil management. The more
noticeable effects are as follows : —

1. Drainage permits the development of the granular
structure in soils, especially in those containing much
clay, and thereby permits the creation of a much better
tith. This tilth is brought about by the frequent changes
in moisture content of the soil made possible by drainage,
coupled with other natural and artificial agencies, as has
already been explained. As a result the soil maintains
the open and friable condition favorable for the absorp-
tion of rain water, and the circulation of the water in
the spaces in the soil without interference with the crop
roots. The tendency of the soil to puddle and form
large, hard lumps is reduced.

2. The withdrawal of the excess water from the larger
spaces in the soil permits the admission of air into those

1 Mellen, C. R. History and Results of Drainage on the
John Johnston Farm. Proc. New York State Drainage Assoc.,
pp. 27-32. 1912-1913.

LAND DRAINAGE 631

spaces. This results in better ventilation. The free
movement downward through the soil of the waves of
saturation accelerates the process of deep soil ventilation
by driving the contaminated air out through the under-
drains while fresh air is drawn in behind the wave of soil
moisture.

3. The removal of the excess moisture by drainage
permits the soil to maintain a higher average tempera-
ture. The high specific heat of water as compared with
the soil causes the presence of water to be the chief deter-
mining factor in soil temperature. Further, the process
of evaporation of the excess water from the soil requires
a tremendous amount of heat. The use of solar heat to
warm useless water and to remove it by evaporation is
avoided by draining away this excess. Drained soil not
only maintains a higher average temperature in summer,
but warms up earlier in spring to a temperature for
planting seeds. This gives a longer growing season.

4. The improved ventilation resulting from drainage
permits the roots of plants to penetrate deeper into the
soil, where they come in contact with a larger supply of
moisture and food. One of the indications of the need of
drainage is the shallow root development of crops. Stag-
nant water in a saturated soil is as resistant to the pene-
tration of upland crops as is the hardest rock (see Fig.
63).

5. The improved physical condition of the soil that
results from drainage permits the retention of a larger
amount of film water, and this, in time of drought, re-
sults in a much larger available supply of moisture to
the crops.

6. The improved physical condition of the soil permits
better internal circulation of water, by which the films are

632 SOILS: PROPERTIES AND MANAGEMENT

renewed and the excess water is permitted to pass away
quickly im the drainage channels.

tom,

PY Nine?
oom lige _
. arts eee
* w* _
% wid, Of “ ae Ser rat
« aos a ay x
fel wet « bd
aa) * Grass wr “ya ~” af ‘ hy ‘
we Ow w TS he de eit" recs Wi
o" we at nate Se OR i anf
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A _ ate Hy .
* <V f wif gs ee yee
wy ~ Wie rant %
oe By) is Cpe
ae

be he
Ase
eda fps tesa

taeda:
ig

pe
eS
aad

Re RES Le N <
Ay SSS ep roots Ur s
SS SERRE \\

Fig. 63 — Area of land nearly level, but having compact subsoil with
undulating subsurface, thereby causing wet pockets that force
plants to form short roots. Weeds are abundant in such areas.
Drainage removes the water and permits deeper penetration of the
plant roots, thus enlarging their feeding zone.

Z if

7. The improved ventilation and higher temperature
due to drainage promote the activity of decay organisms,
by which fresh organic matter is changed into forms that
may be used as food by crops. This aids in the formation
of humus, with its beneficial physical effects on the soil.

8. The higher temperature, better ventilation, better
distribution of moisture and of decayed organic matter,
together with the deeper penetration of roots, make avail-
able a larger amount of mineral elements from the soil
particles.

9. It may now be recognized that there is a distinct
sanitary aspect to soil management. The accumulation
of materials of a toxic nature is promoted by poor drain-
age, and their destruction is hastened, and perhaps in
part their formation is prevented, by the conditions
that accompany good soil drainage.

10. Drainage reduces heaving. Heaving, or the lifting
of crops by frost action in the soil, indicates the presence

LAND DRAINAGE 633

of too much moisture in the soil in proportion to tits
pore space. When water freezes it expands one-eleventh
of its volume. If the soil is too nearly saturated, this ex-
pansion is expressed at the surface of the soil by a lifting,
or heaving, which is exceedingly injurious to most crops
that pass the winter in the soil. It breaks their roots
and gradually lifts the smaller plants out of the ground
if the process is many times repeated. When the soil is
drained so that free air spaces are distributed through
the mass, the expansion of the water as it freezes is taken
up in these spaces without heaving at the surface.

11. Drainage reduces erosion of soils by withdrawing
the water through the soil instead of permitting it to
accumulate to the point where it must move over the
surface, often with serious erosive action. In order that
the drains may be efficient, the soil above the drains must
be sufficiently porous to permit the removal of the water
as fast as it accumulates.

12. Thorough soil drainage greatly increases the effi-
ciency of all equipment and practices used in crop produc-
tion on the farm. ‘There is a longer time in which to do
the work, a longer season in which the crop may grow,
and usually less labor is required in order to fit the land
and keep it properly tilled. Further, the crop matures
more evenly and is likely to be of better quality. The
need for a commercial fertilizer is reduced because of the
higher efficiency of the soil.

13. Prompt and thorough drainage of a wet soil results
in a large increase in yield and quality of crops. All the
common farm, garden, and orchard crops are injured by
a saturated condition of the soil, and the changes that
accompany the correction of that condition permits a
large growth of the plants. The fundamental nature of

634 SOILS: PROPERTIES AND MANAGEMENT

those changes, and therefore the basic importance of good
drainage of the soil, is indicated by this summary of
effects. Even where ordinary yields of crops can be
grown, improved drainage will usually increase the yield
10 per cent or more; and increases of several hundred
per cent are in many cases realized where the conditions
before drainage were particularly bad. Land in need of
drainage is in many eases fertile in all other respects, and
when the soil moisture is properly adjusted it responds
with large yields. Proper drainage should be the starting
point in any permanent improvement of the soil.

534. Methods of drainage. — T'wo general methods of
drainage are employed: (1) open ditches, and (2) closed
drains, or underdrains.

Open ditches are most satisfactory where the volume
of water to be moved is very large. The general drainage
of a region is usually carried in open ditches. They are
used where the land is exceedingly flat, and especially if
the land level is very near the level of the water in the
outlet channel so that only a small head can be developed.
They are used also where a temporary result is desired.

There are many objections to open ditches, either large
or small, especially as applied to tilled land. They waste
a considerable area of land in the channel and on the
banks, and they interfere with free tillage operations. In
the case of small field ditches this interference is serious.
The ditch bank promotes the growth of weeds. The
shallow surface trenches commonly used to remove stand-
ing water from the land are of very low efficiency, since
they do not remove the water from the subsoil and often
are so shallow that the surface soil remains almost satu-
rated. Water flows slowly in such rough, irregular
channels.

LAND DRAINAGE 635

The cost of maintenance of a system of open ditches is
heavy, because of erosion, the accumulation of silt, and
the growth of weeds, all of which make frequent repairs
necessary.

Underdrains when properly constructed are more
permanent than open ditches and cost less for mainte-
nance. They do not interfere with surface operations.
The better grade gives them a relatively larger carrying
capacity than open ditches have, and their greater depth
below the surface permits much higher efficiency in the
removal of excess moisture from the root zone.

535. Construction of small open ditches. — Small
field ditches may be used in the field to remove small
accumulations of surface water. They usually consist of
a furrow run in the lowest parts and made with a large
single shovel plow, with a turning plow, or with a two-
way plow having moldboards to turn the soil on either
side. Another modification in the construction of open
ditches, which is frequently combined with the foregoing,
is the use of “dead furrows.” The land is plowed in
narrow beds two or three rods in width, with a deep
“dead” furrow between each which drains off some of
the surplus water from the higher parts of the intervening
area. A further modification is sometimes used in plant~
ing cultivated spring crops on wet land. Ridges are
thrown up along each row and the seed is planted on these
ridges. The intervening trench affords some drainage.

536. Construction of large open ditches. — Where
larger volumes of water must be removed, a larger channel
is necessary, its size being determined by the area to be
drained, the grade of the ditch, its length, its straightness,
and the smoothness of the sides and bottom. The ideal
shape for the ditch for the largest carrying capacity is a

686 SOILS: PROPERTIES AND MANAGEMENT

semicircle. In this form the ditch is one-half as deep as
it is wide at the surface. This brings the minimum sur-
face in contact with the moving water. The tendency
of the banks to cave near the top, as well as the diff-
culty of constructing such a form, has led to the modifi-
cation of the walls to an inclined slope that is normally
one to one, or an angle of forty-five degrees. This angle
is further modified by the nature of the soil through which
the ditch passes, and is steeper in clay soil and _ less
steep in loose sandy soil. Where the land is very flat
and near the level of the water in the outlet channel, it
may be desirable to deepen the ditch considerably below
the minimum level of water in order to increase the flow
during freshets.

The shape may be further modified where the volume
of water to be carried varies excessively. A wide channel
may be provided to accommodate the flood water, and
in the bottom of this channel a smaller channel may be
provided for the normal flow, of such a size that it is more
likely to be kept clean and free than would a ditch of
larger cross section in which the water would be shallow.

An open ditch should be kept as straight as possible so
as to avoid erosion of the banks where turnsoccur. Change
of direction should begin gradually and should have the
maximum curvature at the middle of the turn. It should
then pass gradually on into the straight line of the new
direction.

The grade will naturally conform in a large measure to
the surface of the ground, but it may need to be modified
from the natural grade where the slope is so steep as to
cause serious erosion. This difficulty receives special
attention in constructing canals to carry irrigation water.
Sandy soils having low cohesion are most subject to

LAND DRAINAGE OT

erosion on high grades. Fine-textured clays are least
affected by erosion. The grades and rates of flow that
are permissible depend largely on the size of the ditch.
A velocity of three feet a second is usually the maximum
that is permissible. It may be a little higher in clay,
and should be a third lower in silt and fine sandy loam.
This rate of flow may be attained in ditches where the
water is several feet deep by a fall of only six inches to a
foot a mile. In small ditches where the water is a foot
or less in depth the grade may be from fifty to sixty feet
a mile, and in heavy clay, especially if it is compact and
stony, a still higher grade will not cause serious washing.

These limits depend to a large extent on the amounts
of sediment that the water carries. Material in suspen-
sion greatly increases erosive action on the ditch walls.

In constructing open ditches care should be taken to
deposit the earth several feet back from the edge of the
channel. This is desirable for two reasons: first, it re-
moves the weight from the unsupported bank, where
caving is very likely to occur when the soil is saturated ;
second, it provides a larger throat for the stream should
it be inclined to overflow.

Another method of constructing an open ditch, es-
pecially in wet grass land, is to form a broad, shallow
channel by the use of a road scraper. The earth is
gradually worked back a rod or more, and the walls are
so flat, even with a ditch three feet deep, that crops grow
and may be collected in the bottom of the ditch. This
system reduces the loss of land and the interference with
farm operations.

537. Construction of early types of underdrains. —
Any material or condition that affords an underground
passage for the flow of water measurably fulfills the func-

688 SOILS: PROPERTIES AND MANAGEMENT

tion of an underdrain. Many methods and materials
have been employed. One used in England in clay soil
is termed mole drainage. A plow having a long, thin
shank, with a molelike or cigar-shaped point at the
bottom, is slowly drawn through the soil by teams or a
capstan. The passage formed persists for several years
in the finer and more coherent classes of soil, and may
do good service. Soil free from stones and having a con-
siderable degree of plasticity is necessary for this method
to have much value.

In ancient times, and in pioneer days in America,
bunches of faggots, brush, poles, rails, straw, and wooden
boxes of triangular or square shape, have been extensively
employed for underdrainage and have been very useful.
They may still have some use, but they have generally
been superseded by more permanent, if not more efficient,
materials.

538. Stone drains. — Wherever stones are abundant
they have been placed in trenches in some manner and
often have served for many years to facilitate the removal
of excess water from the soil. Where there are flat stones
they may be arranged to form a continuous throat.
Several systems of arrangement have been used. All
throated drains are more likely to be closed by sediment
than a drain with no single, distinct throat. Perhaps
the safest, arrangement is to place flat stones on edge in
the trench, with their faces parallel to one another and
to the walls of the ditch, depending on the irregularities
between their faces for the flow of the water. Flat stones
are placed over the top of the vertical stones. Where
round stones are available the safest method is to place
them in the trench without any arrangement except to
put the small stones on the surface. The water will find

LAND DRAINAGE 6389

its way through the openings. All stone drains are
likely to be of short duration because of obstructions that
develop in the channel by the accumulation of sediment,
often promoted by the burrowing of animals. The
throat of a ditch, to receive stone or brush, should be
relatively large (see Fig. 64).

Fig. 64 —The most common types of drainage tile and other materials
used for land drainage. (1), cobblestones with smaller pieces of
stone on top; (2), flat stones placed face to face and parallel to line
of ditch; (8) and (4), throated drains constructed of flat stones
used in different ways; (5), pole drain: (6), triangular box drain;
(7), square box drain. Note construction for admission of water
along lower edge; (8), horseshoe tile laid on a board; (9), horse-
shoe tile, bottom attached; (10), single sole tile with round open-
ing; (11), double sole tile; (12), hexagonal tile; (13), round tile;
(14), Y-shaped junction piece; (15), elbow piece.

539. Tile drains. — Modern underdrainage is usually
accomplished by means of short sections of pipe of burned
clay or concrete, placed in the ground sufficiently deep to
lower the water table in the subsoil to the desired depth
within two or three days. They are given an accurate
grade, and this, coupled with the smooth, hard channel
which is not subject to erosion, makes them a very efli-

640 SOILS: PROPERTIES AND MANAGEMENT

cient as well as a very permanent means of land drainage
at relatively small cost. If they are well installed and of
good material, they should continue to operate for cen-
turies with very little attention. As noted above, tile
drains have been in continuous operation in America for
seventy-five years and are still firm and efficient.

540. Quality of tile. — There may be a considerable
range in the quality of tile made of either clay or concrete.
Clay tile is made of several grades of clay and sand mixed
and burned at a high temperature. Material that is
fused slightly is thereby vitrified, and forms a tile having
a very dense, impervious wall. This is vitrified tile.
Burned at a lower temperature the walls are more porous
and less resistant. Some material does not fuse at any
temperature to which it may be raised, and produces a
tile having soft, porous walls. This makes soft, or brick,
tile. Still another grade of tile is made of clay — usually
fire clay — dipped into a salt solution before firing. This
gives a smooth glaze, commonly seen in sewer tile. This
is glazed tile.

Of the three grades mentioned, the vitrified tile is
normally the best because of its strength and resistance
to the destructive agencies in the soil. The most notice-
able of these agencies is frost. Even burned clay cannot
resist the destructive action of freezing water. Any tile
that has walls porous enough to absorb an appreciable
amount of water — and the larger the amount, the greater
is the danger — will, if frozen and thawed a few times, be
shattered into flakes. The walls of soft tile will absorb
capillarily from 8 to 20 per cent of moisture, and under
the action of frost will go to pieces rapidly. Glazed tile
is less injured, especially when the glaze is intact; but
once a crack has formed the tile is rapidly destroyed.

LAND DRAINAGE H41

The vitrified tiles have walls so dewe that they ahsorh
less than 3 or 4 per cent of moisture, and often less than
2 per cent, so that they are much less vulnerable to frost
action. Good tile should be well formed and should
give a clear ring when struck with a hammer.

Concrete tile of good quality may be made, but the
quality is normally inferior to that of the best vitrified
tile. The porosity is likely to be 5 to 10 per cent. To
make good cement tile requires a rich proportion of cement,
good sand, and as wet a mixing and molding as is prac-
ticable. Several machines of both farm and factory size
are in the market for molding concrete tile.

Water enters tile through the joints, not through the
walls. Even the most porous tiles having a high absorp-
tion do not permit an appreciable amount of water to
pass through the walls. Therefore, soft tiles have no
higher efficiency than vitrified tiles, and, owing to the
risk of freezing, the effectiveness of a line of porous tiles
is much jeopardized. Since water enters at the joints of
the tile, short lengths are more efficient than long lengths.
The usual length of sections of tile under 12 inches in
diameter is 12 to 13 ches. In larger sizes, where the
carrying function predominates over the collecting func-
tion, lengths of 2 feet are employed.

541. Shapes of tile. — Tile should have a round open-
ing and a round or a hexagonal exterior. A flat-bottomed
opening is objectionable because it reduces the flow and
promotes the accumulation of sediment. U-shaped tiles
with flat sides are called horseshoe, or single-sole tile.
This shape is unsatisfactory. Tiles are often warped
in the process of drying and burning, and the last-named
shape does not allow a close joint to be formed by turn-
ing the tile. Round and hexagonal shapes permit turn-

642 SOILS: PROPERTIES AND MANAGEMENT

ing until a good joint is formed. An earlier type was
the U-shaped tile laid on a board. These tiles are easily
broken by the pressure of the earth. They are no more
efficient than the ordinary round tile.

542. Protection of joints. — Soil water should enter
the tile at the lower side of the joint. Any unusual
opening in the joint should be on the lower side. If the
soil has low coherence, such as may be the case with fine
sand and silt, the upper half of the joint should be pro-
tected against the entrance of sediment. A cap of paper
or of burlap cloth, two or three inches wide and long enough
to cover the upper half of the joint, may be used.

Other methods of protecting joints are to cover them
with clay, thick cement mortar, or the sod and granular
soil from the surface. The last named is most commonly
employed. Filters may be constructed by placing around
the tile a layer of coarse sand or gravel, cinders, straw,
or leaves. Where the soil is of a serious quicksand nature
(clean, fine sand or silt filled with water), 1t may be desir-
able to place a bed of gravel or cinders under the tiles
as well as around them. The entrance of water from the
lower side of the joint in small trickles will generally
prevent any difficulty from sediment. Water should
flow from a drain approximately clear, and any other
condition usually indicates a too rapid entrance of water.
Where the soil is a fine clay with high cohesion, the ends
of tiles should not be so close together as in loose soil.
The tops may sometimes be separated an eighth of an
inch with entire safety. In such cases it is especially im-
portant to return the soil to the trench in a dry condition
and to place the topsoil next to the tile.

543. Entrance of roots into tile.— The entrance of
roots into the joints of tile drain sometimes causes an

LAND DRAINAGE 643

obstruction by breaking up into such a mass of fine root-
lets that the tile is finally closed. Any kind of tree or
plant may cause this difficulty if permitted to develop
under certain conditions. Trouble from roots occurs only
where the tile carries water from a spring or some other
continuous source, so that in dry periods the water may
leak out at the joints into the adjacent dry soil. This
leads the roots in the direction of the tile. In the ab-
sence of such a spring, plant roots do not appear to inter-
fere with drains. Where a drain carrying water con~
tinuously comes near a tree, especially if the adjacent
soil is likely to become dry, the joints of tile should be
closed by cement.

544. Protections of joints on curves. — Special care
may be needed in order to protect the jomts on turns
where the outer side may be too open. The larger the
size of the tile, the longer will be the opening on a given
curve. Short turns should not be made. Stones are
usually unsafe material to place around the joints of a
tile under such conditions, especially in soil that is likely
to erode easily. If so used, special care should be em-
ployed to protect the joints with caps.

545. Foundation for tile.— Tiles should have a firm
foundation, and if the bottom of the ditch is soft it may
be advisable to bed them in sand or cinders or lay them
on a board. Soft muck and quicksand make this most
necessary. Ordinarily the bottom of the trench is finished
on the undisturbed earth, which affords a firm setting.

546. Arrangement of drainage systems.— The ar-
rangement of a system of underdrains should be deter-
mined by the slope of the land and the structure of the
soil. No fixed rule can be laid down. The aim must be
to place the drains in the line of movement of water in

644 SOILS: PROPERTIES AND MANAGEMENT

the soil, and thereby intercept its flow. The need of
drainage may arise from several conditions. It is always
indicated by the occurrence of a stratum of rather com-
pact soil which intercepts the natural flow of water and
brings it within the root zone. Sometimes this obstruc-
tion is near the surface, sometimes it 1s several feet below
the surface. The water may be brought to the surface
in a single spring or in a series of springs, in the latter
case forming a seepage line. The retaining layer may
have an uneven surface and form basins and hollows
disguised by a covering of porous soil. For all these
reasons, the drainage conditions of the soil and the lines
of movement of water through it should be studied as
fully as possible before the drainage system 1s planned.
The main lines should first be located. Where the land
is in need of drainage in parts, a few lines of tile will
accomplish this. Springy holes should generally be tapped
by the most direct route. Often, short wing drains may
be necessary at the upper end, to collect the underground
flow. (See Fig. 65.)

Where there is a line of seepage at nearly a uniform
level, a drain placed across the slope at the upper edge
of the wet area, and if possible cutting to the underlying
hard stratum, will intercept the flow and meet the needs of
the lower land. This is an intercepting system of drains.

Where the land is more nearly uniform in its need of
drainage, a regular system is required and will usually
result in a saving of tile. This arrangement should
approximate a rectangular system, in order to avoid
double drainage where lateral tile join the main line.
This may of course be modified according to conditions.
The line of tile should be as long as is practicable for
convenience in construction, To this end, if the field

LAND DRAINAGE 645

is wide in proportion to the length of the main drains,
the subdrains may branch out laterally at a right angle
or less. If the laterals on either side of the main drain
join at the same acute angle, the “ herring-bone ”’ system.

i iis

14 Pal DN eABlE se
ee

as sca

ca ab Be, 7.
Ue.

oe ai z

sy fi Sp ry
Ee Dil alls
be od oe oT .

- ine

i
« f “ if ae Win
/ pa eo ma =
dliilta.” = 4%

Fie. 65.—Sectional view of soil and rock formation, showing the under-~
ground movement of water and the position of resulting wet areas
on the surface In addition to the springy places, the soil is kept
wet by the seepage of water along the top of the compact subsoil.
This figure also illustrates the reason for locating a cross drain
above the springy area in order to effect drainage. This method
cuts off the water supply.

is formed. If the main drain is situated in the wettest
part of the field, this system has some advantage. If the
field is long and very narrow, the main drain may be along
the short side of the field, with long laterals leading up the
slope. If the land is of about equal wetness on a slope,
the drains should extend wp and down rather than across
the slope.

547. Grade of tile drains.— Where the land is rela-
tively flat or uneven, a survey should be made in order
to determine the distribution and extent of the grades.
This is necessary in arranging the system. Where the
grades are simple, the arrangement may be determined
by the eye, if the man in charge is experienced.

646 SOILS: PROPERTIES AND MANAGEMENT

Tile drains operate best on a grade of one or two feet
in a hundred. Larger grades are permissible, but in
such cases the earth should be carefully packed around the
tile in filling. Tile will operate even on the very slight
grade of one or two inches in a hundred. In this case
the minimum size of tile should be larger than on high
grades, and the distribution of the fall should be very
uniform. Every part of the operation of planning and
construction should be guided by readings of an accurate
level.

548. Depth of drains. — The depth of tile drains should
ordinarily be from two feet to three and one half feet.
The former depth should be the one for clay loam
or other moderately impervious soil, and is adequate
for most crops having a shallow root penetration. The
greater depth should be used on sandy and gravelly soil
and where deep-rooted perennials are to be grown. Under
special conditions the drains may be laid deeper or less
deep than these figures. On very dense clay or where a
very impervious hardpan exists, the drains may be placed
a little nearer the surface, since their function is primarily
to remove the water trapped near the surface. To
intercept deep underground flow or to secure an outlet
for it, or where especially deep rooting of crops is desired,
drains may be laid deeper than the normal.

Where the soil is sufficiently porous to permit reasonably
free percolation of water, as in gravelly and sandy sub-
soils, the deeper drains operate earlier after a rain and are
the more efficient. The number of drains necessary is
also reduced by laying them deeper. Where the subsoil
is relatively impervious, shallow drains should be in-
stalled and placed as near the top of the impervious laver
as is practicable. A shallow trench should be formed in

LAND DRAINAGE 647

the compact layer to receive the tile, and if its depth
exceeds half the diameter of the tile special care should
be taken to place the topsoil or some other porous material
on the tile and around the joints in order to insure the
entrance of water.

549. Distance between drains. — The interval be-
tween drains must be determined by the nature and the
wetness of the soil and the value of the crops produced.
In soil where drains must be installed at a depth of two
and a half feet or less, for general farming the interval
between drains must ordinarily be not more than fifty
feet. Where they may be placed deeper, the interval
may be correspondingly greater.

The number of feet and rods of tile required when the
lines are laid regularly at a specified distance apart is
given in the following table : —

TILE TO THE ACRE
Distance APART IN Feur

Feet Rods
20 2,178 131.50
25 1,740 105.42
30 1,452 88.00
40 1,089 65.75
50 870 52.71
80 545 32.88
100 435 26.36
150 290 17.57
200 218 13.18

Under the influence of the drains the physical nature
of the surface soil and of the subsoil gradually changes
and undergoes improvement. Lines of seepage develop,

648 SOILS: PROPERTIES AND MANAGEMENT

and the drain gradually increases in efficiency. In heavy
soil and in soils having hardpan properties, several seasons
may be required for this change in the soil to spread
three or four rods from the drains. The problem is to
remove the excess water from the soil at the maximum
distance from the drains in time to avoid serious injury
to the crop.

550. Construction of drainage trenches for tile. —
Trenches should be as small as possible and yet permit
the ready introduction of the tile. Unless the tiles to be
used are of the larger sizes, the ditch should be made
from twelve to fourteen inches wide, with vertical sides.
Where leveling instruments are employed, the course
of the ditch is staked out and the grade cord is stretched
a definite distance above the proposed grade line of the
ditch, to guide the workmen. In hand digging, the earth
is thrown out with a narrow-pointed spade, the loose earth

Fra. 66 —Tools for ditehing (1) and (2), ditching spades for remov-
ing the major part of the earth from the ditch, (3), grading scoop
used to finish the bottom of the ditch and the grade, (4), skeleton
spade adapted for use in very plastic soil, (5), shovel for removing
loose earth, (6), hook used to place tile in deep, narrow trenches,
(7), pick for loosening stone and hard earth

LAND DRAINAGE 649

is cleaned out with a round-pointed shovel, and the bottom
is finished to a smooth, perfect grade by means of the
grading scoop, which also rounds the bottom of the trench
into shape to receive the tile. (See Fig. 66.) Care
should be taken not to excavate the trench below the
grade line, so that the tile may have a firm bed.

Horse and engine power are now verv generally applied
to trench digging. Several types of plows drawn by
horses are available to loosen the soil, and some types
are arranged to follow the grade and to elevate the loose
earth out of the trench. Several types of engine-driven
machines are in use where the land is not excessively
stony. They cut the trench to the full depth at one
operation, and are constructed so as to follow a perfect
grade, so that tile may be laid as fast as the machine
progresses.

551. Laying tile.— Where two lines of tile join they
should come together at an acute angle, forming a Y
so that the two streams of water will have the minimum
interference and the collection of sediment will be pre-
vented. If the lines are arranged at right angles, one of
the strings may be turned down grade in the form of a
curve in the last rod of its course, to make the proper
union. Junction pieces or Y’s may be bought in the
smaller size of tile. They are rated by the diameter of
the lateral and main branches; for example, a 3 X 6
junction indicates a three-inch lateral and a six-inch
main. A lateral tile should enter the main drain with a
slight drop. A small tile should enter a larger main
drain at the horizontal center of the latter.

The tiles are placed in the trench by hand, or, if the
trench is deep or the tiles are very large, by means of
some mechanical arrangement such as a hook. Their

650 SOILS: PROPERTIES AND MANAGEMENT

ends are put in line and as close together as conditions
seem to indicate is necessary. Any covering or filling
material is then put in place. The tile should be placed in
the trench as soon as the latter is finished, and the trench
should then be at least partially filled with earth in order
to avoid danger from freezing or from the caving-in of
the walls. The first lot of earth — usually from the sur-
face —is carefully placed about the tiles and packed
in so as to hold them in position. This is called the
blinding, or back-filling. The later filling may be accom-
plished in any convenient way.

552. Size of tile. — The size of tile must be deter-
mined by the amount and rate at which the water must be
removed, the grade of the drain, and the nature of the
soil. The small lateral drains whose function is to collect
the water from the soil will usually be of three or four
inches internal diameter. Drains smaller than this
should not be used because of their inclination to become
clogged. Small tiles are relatively more affected than
larger tiles by the inevitable slight imperfections in the
grade. The high friction of the walls in small tiles to
the moving water reduces the rapidity of flow and en-
courages the accumulation of sediment. In soil some-
what of the nature of quicksand, and where the grade is
less than one foot in a hundred, no tile smaller than four
inches in diameter should be used. As the drainage
water is collected by the different lines, the size of the
tiles must increase correspondingly.

553. Amount of water to be removed from land. —
Many things affect the amount of water to be removed
from a given area of land. The more important of these
are the rainfall, the occurrence of springs, surface accu-
mulation, the storage capacity of the soil, and rate of

LAND DRAINAGE 651

evaporation. Underdrains are designed with a capacity
to remove only part of the normally largest rainfall
in a period of twenty-four hours. The absorptive
power of the soil and its hindrance to the flow of
water through its pores permits the use of a tile-drain
system capable of removing from one-quarter to one-
half inch of water over the drainage basin in twenty-
four hours. This is termed the drainage coefficient of the
area. The drainage coefficient of the system, especially
if it is a large system, should be determined after careful
study of the amount and distribution of the rainfall
and the extent to which surface and subterranean water
is accumulated.

554. Carrying capacity of a tile-drain system. — The
carrying capacity of a system of tile drains depends on
their respective sizes, their grade, or fall, their total length,
their depth in the ground, the straightness of their course,
and the smoothness of the interior of the tile. Some of
these factors affect the flow directly as they increase,
others inversely. The two most important elements
in determining the capacity of a drain are the diameter
and the grade. The capacity of a drain varies as the
square of the diameter. Doubling the grade increases
the capacity by approximately one-third. With cer-
tain additional corrections and modifications, all the
factors that affect the flow have been put together in a
formula to determine the necessary size of the outlet
tile for a given area. This formula, known as Ponce-
let’s formula, as modified by Elliott! for large systems,
is as follows : —

1Elhott, C. G. Engineering for Land Drainage, Chapters
VII, VIII, IX. New York. 1912.

652 SOILS: PROPERTIES AND MANAGEMENT

4
(1) A 0
(2) Q=aV
, d(h+5) +3K
OF ss 1+ 54d
A = acres to be drained
C = coefficient of drainages selected for the area in
cubic feet per second. It is determined by
the depth of water to be removed in twenty-
four hours
Q = quantity of water the tile will discharge, in
cubic feet per second
area of tile in square feet
velocity in feet per second
= diameter of tile in feet
= length of tile in feet
head, or difference in elevation between outlet
and upper end, in feet
b = sum of amounts of head in laterals, in feet
m = number of laterals
depth of tile below soil surface at upper end, in
feet
48 and 54 are factors that take account of gravity,
the size of the tile, and the roughness of the
walls. The former figure is larger for tile
more than twelve inches in diameter.

=~ ATA
|

my
I

The first formula determines the number of acres that
a given size of tile will drain, by dividing the quantity
of water to be removed by the coefficient of drainage
selected for the region.

LAND DRAINAGE 653

The second formula determines the quantity of water
possible to remove, by multiplying the area of the cross
section of the tile by the velocity of flow.

The third formula is used to determine the velocity of
flow of water in the outlet tile.

In a small system, where the laterals are relatively
unimportant and where the soil is fairly close, the velocity
formula may be much simplified as follows :—

Vy =48 =
1+ 54d

The term 3 K is used only where the soil is so very
porous that the ready movement of the water through
the soil has an influence on the flow in the tile.

Coefficients of drainage and their equivalents in cubic
feet per second of discharge are as follows : —

eewemvinoommiaean Leagan amit teat ett ete RLM} amet yer Ree

DrerH or Water in IncHes Removep | Cunic Freer ro a Sgeconp or Dis-

In Twenty-Four Hours CHARGD
Fraction Decimal ~ PoanAcre | Toa Square Mile
1 1.00 0.0420 26.9
re 0.75 0.0315 20.2
i 0.50 0.0210 13.4
i 0.25 0.0105 6.7

amenities tetera lero pete isan SN needs arent to

From the above formula Elliott has calculated the
number of acres of land drained by outlet tiles of different
sizes and grades where the coefficient is one-fourth of an
inch in twenty-four hours and where the main is 1000
feet in length : —

654 SOILS: PROPERTIES AND MANAGEMENT

ACRES FROM wHicH A Main True Larp on Grapes INDICATED
May ApEQquATELY Recerve DraInaAGE WatTER

Graprts to A HunpreD Frnt in DecimaLs or 4 Foor with
APPROXIMATE EQUIVALENTS IN INCHES

DIAMDTER
or TILE ; ; ] ; ; ;
(in INCHES) 1 inch I inch 2 inches 8 inches | 6 inches | 9 inches
0.04 0 08 0.16 0.25 0.50 0.75
Acres Acres” Acres Acres Acres Acres
5 17.3 19.1 22.1 25.1 32.0 37.7
6 27.3 29.9 34.8 39.6 50.5 59.4
7 39.9 44.1 51.1 58.0 74.5 87.1
8 55.7 61.4 71.2 80.9 103.3 | 121.4
9 74.7 82.2 95.3 108.4: 138.1 | 162.6

10 96.9 106.7 123.9 140.6 | 179.2 | 211.1
12 152.2 167.7 194.6 221.1 | 281.8 | 331.8

Heenan iret et mater rt ee ne

555. Cost of drainage.— The cost of tile drainage
depends on many things, including especially the size of
the tile, the frequency of the drains, the depth, the nature
of the soil, the method of digging, and the price of labor.
The cost of tile varies in different regions and increases
rapidly with the size.

The following schedule will serve merely as a general
guide to the range in price a thousand feet and a rod when
purchased in car lots :—

Sizm (DraMEeTER IN [NcHES)

2 3 4 5 6 8
Cost a thousand
feet . . . . | $10—$14) $ 13-8 18] $ 18~-$ 25) $ 25~$ 32 | $ 35-8 45 | $ 65-8380

Costarod . . | $16-$.21) $.20-$.27| $.27-$.38| $.38-$.48 | $.53-3.68 | $.98-$1.12

The cost for digging the trench of course varies widely.
In medium soil free from stone, for a ditch two and one-

LAND DRAINAGE 655

half feet deep to receive tile up to ten inches in diameter,
the cost may be from fifteen cents to fifty cents a rod,
with an average of about thirty-five cents. The cost can
sometimes be reduced by the use of a power machine.
In stony and hardpan soil the cost may be very much
higher than these estimates. The deeper trench is rela-
tively the more expensive to construct.

Laying the tile, filling the trench, and other miscel-
laneous operations for the smaller sizes of tile will cost
at least ten cents a rod. This makes a total cost for four-
inch tile of about 80 cents a rod, $5 a hundred feet, and
$260 a mile.

Records are available of the cost of drainage on an
extensive area of cultivated farm land in northern Ohio,
where the soil is chiefly a medium clay loam, somewhat
stony, and where the depth was two to three and one-half
feet. Some of the work was done by hand and some with
the aid of a traction ditching machine. A fairly low price
prevailed for tile, the size ranging from three to thirteen
inches.

The results are as follows : —

water mere rt pte ere etiam eaersnthsaremlb print

Cost or Insrauuine TILE
RAINS

Hand work | Machine work

Area (in acres) . . . . . . 40 188

Number of rods of tile . . .. . 2,060 8,835
Cost of installation perrod. . . .| $0.4489 $0.3746
Average cost of tile perrod. . . .| $0.2445 $0.2445
Average number ofrodstotheacre . 48 48

Average cost totheacre. . .. . $33.28 $29.72

etter Ti fornirnenkehgindLAretennrengstremitetertelmememiAlterrrnAttrreulanimatal “Bratt arene

1Goddard, L. H., and Tiffany, H. O. The Cost of Tile
Drainage. Ohio Agr. Exp. Sta., Cire. 147. 1914.

656 SOILS: PROPERTIES AND MANAGEMENT

556. Storm channels. ~ Where large volumes of water
must be carried for a short time in addition to the normal
flow, a medium-sized tile drain may be combined with an
open surface channel for carrying away the flood water.
The open channel is located a little to one side of the
tile drain so that the latter may not be displaced by pos-
sible erosion. The open surface channel is made broad
and shallow in order to avoid interference with tillage
operations, and if erosion is likely to occur, it may be
kept in grass.

557. Silt basins.— Silt basins are wells in the line
of tile drains, for collecting sediment that might other-
wise be deposited in the tile. The course of the drain
is intercepted and a small well is sunk two or more feet
below the bottom of the drain. The well extends to the
surface of the ground and has a cover. The inlet drains
come in at a slightly higher level than the outlet. The
heavy sediment drops to the bottom, whence it may be
removed from time to time. The end of the outlet tile
is finished with an elbow, turned down so as to prevent
the entrance of sticks or other floating material. The
walls of the well may be made of wood, concrete, or
brick.

558. Surface intakes. — The admission of surface water
into a tile drain should always be managed with great
eare to remove the heavier sediment or other material
that might obstruct the tile. Sereen boxes should be
used. The screen should incline to the intake at an angle
of fifty or sixty degrees, so that floating material, instead
of obstructing the flow, will be pushed upward out of the
course.

559. Outlets. — As few outlets as is practicable should
be constructed for tile drains, and these should have a

LAND DRAINAGE 657

~.
Aa ay
we
obey
alt
_
ant”
ly
‘
hades
.

yah

Fie. 67.—A drainage plan of an area of land exhibiting many differences
as to soil, slope, and degree of wetness. Herein are shown the kinds,
sizes, and arrangements of drains necessary to provide efficient
drainage under the various conditions.

658 SOILS: PROPERTIES AND MANAGEMENT

drop and be well protected by wing walls. Lines of
drains should be connected in systems for this purpose.
Unless the drain has a high grade the outlet should not be
covered by water. The end of the tile should be pro-
tected by a gate or a series of rods to prevent the entrance
of small animals.

560. Muck and peat soil. — Muck and peat soil should
usually be drained by open ditches at first. After learn-
ing the nature of the material and the structure of the
subformation, it may be found permissible to install tile
in the smaller ditches. When the organic material is
more than four feet deep, so that tile could not be laid
on a hard bottom, much risk is involved in its use due
to the excessive shrinkage of such soil when the surplus
water is removed and when even moderate drying occurs.
If the area is fed by springs so that the water level will
be kept permanently at the base of the tile, the shrinkage
will be very small and the tile may usually be laid with
safety, especially if placed on boards to aid in keeping
the alignment. In so-called dry peat, where the subsoil
may dry out seriously in summer, the use of tile is inad-
visable. In muck soil, which has a finer texture resulting
from a more advanced stage of decay, tile drains may be
used with greater safety.

The distance between drains in muck should be from
one hundred to five hundred feet, depending much on
the nature of the subsoil. Since the surface is likely to
be relatively flat, nothing smaller than four- or five-inch
tile should be employed and the joints should be carefully
protected as described above.

Since the capillary power of muck soil is low, the water
table should not be lowered more than from two to three
feet, depending on the quality of the soil. While the

LAND DRAINAGE 659

bottom of the open ditch may go below this level, it is
often advisable to insert check gates to hold the water
level when it has been lowered to the desired depth.

561. Drainage of irrigated and alkali lands. — Exces-
sive irrigation and the occurrence of underground seep-
age has resulted in the water-logging of extensive tracts
of arid and semiarid land, and in the serious accumulation
of alkali salts in the surface soil. An effective remedy
for this condition is the installation of a thorough system
of drains,! preferably underdrains, coupled with heavy
irrigation by means of which the excess salt is leached out
in the drainage water. The most seriously alkaline land
is now being effectively reclaimed by drainage, for the
production of alkali-sensitive crops.

For this purpose drains are installed deeper than is the
custom in humid regions, in order to reduce the capillary
rise of moisture to the surface of the soil, where the alkali
salts are deposited in injurious amounts. The drains
are often placed at depths of from four to six feet. Special
care is also taken to intercept the underground seepage.
Sometimes the seepage water from leaky canals and reser-
voirs and from over-irrigation may pass long distances
in porous gravel strata and rise to the surface of the land
on encountering some impervious obstruction. In such
cases wells may be sunk many feet to the water-bearing
stratum, and the water thus conducted away in drains
far enough below the surface to avoid injury to the soil.

Many special problems are encountered, such as the
occurrence of hardpan — usually a stratum cemented by
alkaline carbonates — and the development of a serious

1 Elliott, C. G. Development of Methods of Draining Tm-
gated Lands U. 8S. D. A., Office Exp. Sta., Ann. Rept.,
pp. 489-501. 1910.

660 SOILS: PROPERTIES AND MANAGEMENT

quicksand condition of soil. The hardpan may need to
be partially broken up by dynamite. The latter condi-
tion may require the placing of the tile on boards or the
use of wooden box drains to keep the alignment.

Coupled with deep drainage, sufficient irrigation water
is employed to produce heavy percolation, by means of
which the excess salt is removed. The most alkaline
land can usually be reclaimed in two or three years of
leaching.

562. Vertical drainage. — A gravity outlet for drainage
is sometimes difficult to provide. In such a case it may
be possible to remove the drainage water through some
porous stratum below the surface. There must be such
a porous stratum within reach below the surface, in order
to render the method of vertical drainage practicable.
Basin-shaped areas without an outlet may be wet because
of the accumulation of a thin layer of clay or other im-
pervious sediment in its lowest part, beneath which at
a short distance is a porous gravel or sand formation.
Anything that perforates this impervious layer and keeps
open the passage will afford drainage. Wells several
feet in diameter may be constructed and filled with stone.
Tile drains and open drains have been emptied into such
structures. An opening of temporary efficiency may be
formed by a charge of dynamite. The tendency of such
an opening, however, is to become clogged.

A second condition under which vertical drainage may
be advisable exists in a soil that is underlaid within a few
hundred feet by a limestone or other porous rock forma-
tion into which the surface water may be emptied. A
casing may be installed to protect the walls of the well
and to reach from the surface to the porous stratum.
In addition a trapped intake, coupled with a silt basin,

LAND DRAINAGE 661

may be placed at the top of the well to insure its continu-
ous operation. Extensive systems of underdrains are
reported to have been discharged by this arrangement,
where it might otherwise have been necessary to go a
long distance in order to obtain an outlet. It should be
noted that in many cases a sufficiently porous stratum
is lacking in the structure of the surface portion of the
earth, so that the method could not often be employed.

563. Drainage by means of explosives. — The use of
explosives for promoting drainage has been proposed
for three conditions : —

1. To break up a hard subsoil and possibly make a
connection with a more porous stratum below, so that the
soil could better handle the normal rainfall. This is
closely related to the operations of subsoiling.

2. To break through a thin impervious layer in the
bottom of a wet basin-shaped area. This is identified
with vertical drainage described above.

3. To open up channels for drainage purposes. This
use is the most extensive. By proper distribution of the
charges of explosives, coupled with favorable soil and
weather conditions, a very good channel can be opened
by this method. It is suited only to the excavation of
open ditches of medium size, three feet or more in width,
and it has the greatest advantages where the land is
much obstructed by stone or stumps. The force of the
explosive largely clears the ditch of earth and obstructions.
No very accurate grading of the bottom of the ditch can
be accomplished by this method.

564. Résumé.— The removal of the excess water
from the soil by any means constitutes drainage and is
one of the most fundamental operations in soil manage-
ment. The effects of adequate drainage are numerous

662 SOILS: PROPERTIES AND MANAGEMENT

and far-reaching. In its accomplishment the physical
properties of the soil and its moisture relations must be
taken into account. Whether open ditches or under.
drains are employed depends on the local conditions, but
where practicable underdrains are always to be chosen.
While the cost of drainage is a considerable sum, the
improvement when well made is of long duration and the
cost may therefore be distributed over a long period.
The benefits accrue not only in increased crops, which
are generally large, but also in the saving of expense in
operation. Good drainage is the basis of good soil
management.

CHAPTER XXIX

TILLAGE

WuitE the farmer depends somewhat largely on the
weathering agencies for granulation of his soil, maximum
tilth can be obtained only by certain external operations.
The advantages to be derived from drainage have been
pointed out. The importance of the addition of lime
and organic matter as a means of soil improvement has
been emphasized. Yet, after all these have been pro-
vided, a further fundamental practice remains to be
followed. This practice is tillage, or the manipulation
of the soil by means of implements so that its struc-
tural relationships may be made better for crop growth.
Tillage is so general in its application, so pronounced in
its effects, and so complex in its modes of operation, and
has to do with so many machines employing different
mechanical principles, that it requires discussion by itself.

565. Objects of tillage. — Tillage aims to accomplish
three primary purposes: (1) modification of the struc-
ture of the soil; (2) disposal of rubbish or other coarse
material on the surface, and the incorporation of manures
and fertilizers into the soil; (8) deposition of seeds and
plants in the soil in position for growth.

The most prominent of these purposes is the modifi-
cation of the soil structure. This affects the retention
and movement of moisture, aération, and the absorption
and retention of heat, and either promotes or retards the

663

664 SOILS: PROPERTIES AND MANAGEMENT

growth of organisms. Through all these factors the com-
position of the soil solution, and finally the penetration
of plant roots, is influenced. The creation of a soil
mulch is merely a change in the structure of the soil at
such times and in such a manner as will prevent evapora-
tion of moisture. For this reason it is essential to under-
stand the relation of soil structure to the movement of
moisture in managing the mulch. In fine-textured soils,
in which the granular or crumb structure 1s most desired,
tillage may have an important influence on the formation
or destruction of granules. As has been pointed out,
any treatment that increases the number of lines of weak-
ness in the soil structure facilitates the action of the mois-
ture films and the colloidal matcrial in solidifying the
soil granules. ‘Tillage shatters the soil and breaks it into
many small aggregates which may be further drawn
together and loosely cemented as a result of the evapo-
ration of moisture. The more numerous the lines of
weakness produced, the more pronounced is the granu-
lation; and, conversely, the fewer the lines of weakness
produced, the more coarse and cloddy is the structure.

566. Implements of tillage. — The implements adapted
to the manipulation of the soil are very numerous, and
embrace many types. Many operations are compre-
hended by the term tillage, which includes the use of all
those implements that are used to move the soil in any
way in the practice of crop production. It includes the
smallest hand implements as well as the heaviest trac-
tion machinery.

567. Effects on the soil. — All these operations may
be divided into two groups, according to their effect on
the soil, — those that loosen the soil structure, and those
that compact the soil structure. In the subsequent

TILLAGE 665

paragraphs of this chapter the effect of the commoner
types of tillage implements on the soil are pointed out
as a guide to their selection for the accomplishment of
a desired modification. Good soil management consists,
first, in analyzing the soil conditions, in order to deter-
mine the change that should be effected; and second, in
the selection of the implement or other treatment that
will most readily and economically accomplish the object.

568. Classes of tillage implements. — According to
their mode of action, tillage implements may be divided
into three groups, — plows, cultivators, packers and
crushers.

569. Plows. — The primary function of a plow is to
take up a ribbon of soil, twist it upon itself, and lay
it down again bottom side up, or partially so. In the
process two things result: (1) if the soil is in proper condi-
tion for plowing, it will be shattered and broken up;
(2) the soil is partially or wholly inverted, and any rubbish
is put beneath the surface.

570. Pulverizing action of the plow. — In twisting, the
soil tends to shear into thin layers, as already pointed
out (par. 128). These layers are moved unequally upon
each other, as the leaves of a book when they are bent.
The result should be a very complete breaking-up of the
soll. How thorough the breaking-up will be will depend
on (1) the condition of the soil, and (2) the type of plow.
As to the condition of the soil, there is a certain optimum
moisture content at which the best results will be obtained.
That condition of moisture is the one that is best for
plant growth. Any departure from this optimum moisture
content will result in less efficient work. It has been said
that, in proportion to the energy required, the plow is
the most efficient pulverizing implement used by the

666 SOILS: PROPERTIES AND MANAGEMENT

farmer. The optimum moisture content for plowing is
indicated by that moist state in which a mass of the soil,
when pressed in the hand, will adhere without puddling
but may be readily broken up without injury to the
intimate soil structure. This is a much more critical
stage for fine-textured soils than for coarse-textured ones.
Sandy soils are not greatly altered by plowing when out
of optimum moisture condition. On the other hand, if
a clay is plowed when it is saturated with water, it will
be thoroughly puddled and will dry out into a hard, lumpy
condition. Such a structure requires a considerable time
to remedy.

571. Types of plows (Fig. 68).— There are two gen-
eral types of turning plows, the common moldboard plow
and the disk plow. Their mode of action is quite dif-
ferent, although, so far as the soil is concerned, the result
is much the same. The moldboard plow seems to have
a wider application than the disk plow, but both have
a particular sphere of usefulness.

The disk plow is essentially a large revolving disk
set at such an angle that it cuts off and inverts the soil,
at the same time pulverizing it fairly effectively after
the manner of the moldboard plow. One advantage
claimed for the disk plow is its lighter draft for the same
amount of work done, due to its having rolling friction in
the soil instead of sliding friction. In practice it appears
to be especially effective on very dry, hard soil and in
turning and covering rubbish.

For any given texture of soil and any given soil condi-
tion, there is a type of plow, a shape of moldboard, and
a depth of furrow slice, that will give the best results.
This fact is to be kept constantly in mind in plowing soil.
Sod land requires a different shape of plow from fallow

TILLAGE 667

land, sandy land from clay land. Rubbish on the surface
may be handled by one plow and not by another. On
wet clay one should use a different shape of plow from
that which is preferable for dry soil.

Fic. 68.—The plow. (1), modern walking plow with parts named;
(2), types of moldboard for (a) fallow ground, light soil, (b) fallow
ground, clay soil, (c) sod ground, (d) general purpose, fairly well
suited to a wide range of soil conditions; (3), deep-tilling disk plow ;
(4), subsoiler; (5), plow attachments: (a) jointer, (0) knife or
beam colter, (c) fin colter, (d) rolling colter.

572. Shapes of moldboard plows. — Of the moldboard
type there are two general shapes: (1) The long, sloping
moldboard, which rises very gradually and has little or

668 SOILS: PROPERTIES AND MANAGEMENT

no overhang, found on what is called the sod plow. This
neatly cuts off the roots at the bottom of the slice, slowly
and gradually twists the soil over without breaking the
sod, and lays it smoothly up to the previous furrow slice.
(2) The short, steep moldboard with a marked overhang
This is not adapted to sod land, because it breaks up
the sod and shoots it over in a rough, jagged manner
with uneven turning. But on fallow land, to which it
is adapted, it very completely breaks up the soil and
throws it over in a nearly level, mellow mass. The pul-
verizing effect is obviously much greater than with the
sod plow. Since the steep moldboard, or fallow-ground,
plow exerts the most force on the soil in a given time at
a given speed of movement, it follows that if a particular
soil is over-wet it should be plowed with the sod plow,
while, if it must be plowed when too dry, the fallow-ground
plow will be more effective — disregarding the draft,
which will probably be larger in the latter case.

573. Position of the furrow slice (Fig. 69). — Con-
siderable care should be taken concerning the angle at
which the furrow slice is placed. It is seldom desirable
to completely invert the soil. If it is too flat, the stubble
and rubbish are matted at the bottom of the furrow and
tend to interfere with capillary movement for a consid-
erable period. This may cause serious difficulty on
spring-plowed soil, where the capillary connection does
not have time to be renewed before a crop occupies the
land. If, on the other hand, the furrow is too steep, the
proper pulverization does not take place and the turning-
under of stubble and rubbish is not satisfactorily accom-
plished. The stubble and rubbish are likely to interfere
with subsequent operations.

The best angle at which to turn the furrow slice is

TILLAGE 669

about from 30° to 40° with the horizontal. A furrow thus
set furnishes ready entrance for rain water and facilitates
the best of aeration for the soil. Such an angle is espe-
cially to be recommended for turning under green manures.
The capillary connections with the subsoil are not broken
and the green material is well distributed from the top
to the bottom of the furrow. Where a sod is to be plowed,
a flatter turning of the furrow is advocated in order to
increase the packing and avoid the danger of the sod’s
interfering with subsequent cultivation.

Fra 69 —Section of plowed land showing the correct proportions and
position of the furrow slice as left by a moldboard plow The effect
of the jomter in turning under the edge of the furrow slice as well
as the position of turned under vegetation is apparent

574. Depth and width of furrow. — There is a general
relation between the width of the furrow slice and its
depth. In general, it may be said that this ratio is about

670 SOILS: PROPERTIES AND MANAGEMENT

two in width to one in depth. The greater the depth, the
less in proportion may be the width of the furrow slice.

On clay soil in particular, there is also a relation be-
tween depth and condition. A wet soil should be plowed
more shallow, other things being equal, than a dry soil,
because the puddling action is less. On a dry soil the
depth should be increased, in order to increase the pul-
verization. Combining these principles, then, it may be
said that if a clay soil must be plowed when too wet, it
should be plowed with a sod plow and to as shallow a
depth as is permissible. But on an over-dry soil the
opposite conditions should be fulfilled — that is, the use
of a steep moldboard and to an increased depth. Like-
wise, on sandy soil, where the aim is generally to compact
the structure, this may be furthered by deep plowing
with a steep moldboard when the land is over-wet.

575. Plow sole. — In connection with this phase of
the subject it is Important to consider what is often called
the “ plow sole,’’ — that is, the soil at the bottom of the
furrow, which bears the weight of the plow and the tram-
pling of the team, and which under a uniform depth of
plowing does not become loosened. In clay soil, espe-
cially, it gradually becomes more compact, developing
in time something of a hardpan character, which is detri-
mental to the circulation of air and moisture and inter-
feres with the penetration of plant roots. Consequently,
occasional deep plowing, or even subsoiling, is recom-
mended to break up this unfavorable soil structure.
There is less tendency for the disk plow than for the mold-
board plow to form the “ sole.”

576. Hillside plow. — The hillside plow is a modified
form of the moldboard plow. It has a double curvature
to the moldboard, so that it is essentially two plows in

TILLAGE 671

one. The plow swings on a swivel in such a way that
it may be locked on either the right or the left side. It
removes the necessity of plowing in beds, and, by per-
mitting all the work to be done from one side, enables
the plowman to lay the furrow slices in one direction.
On the hillside this direction is down the slope, because
of the greater ease in turning the soil in that direction.
This plow also removes the difficulty of pulling up and
down the hill. There is another type of moldboard plow,
designed to eliminate “dead furrows” and “ back fur-
rows.” Dead furrows are developed by the last furrow
slices of two lands being turned in opposite directions,
thereby leaving a gulley between, which is often unpro-
ductive in character; the back furrow consists of two
furrow slices thrown together, usually forming a ridge
more productive than the average of the land. This
plow is of the sulky type, the plow being carried on wheels
and regulated by means of levers and the traction power.
Two plows are carried, one having a right-hand turn to
the moldboard, and the other a left-hand turn. By
using one plow in one direction and the other in the oppo-
site direction, it is possible to begin on one side of the field
and throw the furrow slice in one direction until the
entire area is covered, thereby leaving the soil in a uni-
form condition. Such plows, being heavier than the
single, walking plow, are not adapted to very uneven
ground.

577. Covering rubbish.— The secondary function of
the plow is to cover weeds, manure, and rubbish that
may be on the surface. This also the turning plow
does very effectively. The cutting and turning of the
sod, rubbish, and weeds is facilitated by several attach-
ments, such as colters, jointers, and drag chains. There

672 SOILS: PROPERTIES AND MANAGEMENT

are several types of colters. Blade colters are attached
to the beam or to the share in such a manner as to cut
the furrow slice free from the land side. They should
be adjusted in such a position as to cut the soil after it
has been raised and put in a stretched condition, at which
time the roots are most easily severed. This position is a
little back of the point of the share. A knife edge attached
to the share is commonly called a fin colter. A jointer
ig a miniature moldboard attached to the beam for cutting
and turning under the upper edge of the furrow slice,
so that a neat, clean turn is effected without the exposure
of a ragged edge of grass which may continue growth.
This is used chiefly on sod land. A drag chain is an ordi-
nary heavy log chain, one end of which is attached to
the central part of the beam and the other to the end of
the double tree on the furrow side, and with enough slack
so that it drags down the vegetation on the furrow slice
just ahead of the turning point. It is used primarily in
turning under heavy growths of weeds or green-manure
crops.

578. Subsoil plow. — There is a third type of plow,
the so-called subsoil plow. The purpose of this imple-
ment is to break up and loosen the subsoil without mix-
ing the material with the soil. It consists essentially of a
small, molelike point on a long shin. This implement is
drawn through the bottom of the furrow, and shatters
and loosens the subsoil to a depth of 18 inches or 2 feet.
It is often useful on soils having a dense, hard subsoil.
Its use requires the exercise of judgment, as the process
may prove very injurious if done out of season. As a
general rule, it is best to use the subsoil plow in the fall,
when the subsoil is fairly dry and may in a measure be
recompacted by the winter rain. Spring subsoiling is

TILLAGE 673

seldom advisable in humid regions, owing to the danger
of puddling the subsoil, or to the possibility of its remain-
ing too loose for best root development if the work is done
when the subsoil is dry enough not to puddle.

579. Cultivators (Fig. 70).—- There are more types
of cultivators than of any other form of soil-working im-
plements. These may be grouped into (1) cultivators
proper; (2) leveler and harrow types of cultivators; (3)
seeder cultivators. These implements agree in their mode
of action on the soil, in that they lift up and move it side-
wise with a stirring action which loosens the structure and
cuts off weeds, and to a slight degree covers rubbish. How-
ever, the action is primarily a stirring one, and, in general,
it is much shallower than that of the plow. One impor-
tant fact should be kept in mind in cultural operations,
especially those just following the plowing; that is, the
work should be done when the soil is in the right moisture
condition. Particularly is this true in the pulverization
following the plowing. Plowing, if it is properly done,
leaves the soil in the best possible condition to be further
pulverized. It is properly moistened, and if the clods
are not shattered they are reasonably frail and may be
much more readily broken down than when they are
permitted to dry out. In drying they are somewhat
cemented together and thereby hardened. Not only is
it desirable in almost all cases to take advantage of this
condition of the soil, but the leveling and pulverizing
of the soil reduces drying and improves the character of
the seed bed.

580. Cultivators proper.— There is a great variety
in types and patterns of cultivators. They may be
divided into large shovel forms and small shovel forms,
and the duck-foot form. The first type has a few com-

674 SOILS: PROPERTIES AND MANAGEMENT

paratively large shovels set rather far apart, which vigor-
ously tear up the earth to a considerable depth and leave
it in large ridges. There is a lack of uniform action, and
the bottom of the cultivated part is left in hard ridges.
Such implements are now much less used than they were
formerly, and may be considered to supplant in a measure
the use of the plow, where deep working without turning

Foe

Nas eR ; </
(Sa

“ny

u
Wilt

— an
er

Fig. 70.—Types of cultivators: (1), wheel hoe, or hand garden culti-
vator, with attachments; (2), adjustable small-tooth, one-horse
cultivator, with duck-foot shovel behind; (3), two-horse spring-
toothed cultivator; (4), two-horse sweep or knife cultivator;
(5), two-horse disk cultivator.

TILLAGE 675

is desired. Some of the wheel hoes used in orchard
tillage belong to this type. The single and double shovel
plows are earlier types of the same implement.

The small shovel cultivators have very generally sup-
planted the large shovel type in most cultural work.
The decrease in size of shovels is made up by the great
increase In number. Ordinarily they operate to shallow
depths, but very thoroughly and uniformly. They are
now much preferred in all intertillage work for eradication
of small weeds and the formation of a loose surface mulch.

The duck-foot cultivator — or sweep as it is called in
the southern states, where it is extensively used in the
cultivation of cotton—is a broad blade that operates
in a nearly horizontal position an inch or two beneath the
surface. The surface layer of soil is severed and raised
slightly from the under soil, and is somewhat crumbled
in the operation. This tool is very efficient in establishing
and maintaining a mulch and in destroying weeds. It
covers every part of the soil. The implement is increasing
in popularity in the northern and eastern states. It is
not adapted for use in very stony or hard soil.

Another classification, which has less relation to utility
than to the convenience and comfort of the operation,
is based on the presence or the absence of wheels. ‘There
is a strong movement toward the use of wheel cultivators
carrying a seat for the operator. These have a wider
range of operation as to depth and facility of movement
than have the cultivators without wheels.

Still further, there is the distinction of shovels from
disks. Disks are used on the larger cultivators but seldom
on the small ones.

Cultivators may be constructed to till one or more rows
at a time.

676 SOILS: PROPERTIES AND MANAGEMENT

581. Leveler and harrow types of cultivator (Fig. 71),
— In this group are the spike-tooth harrow, the smoothing
harrow, the spring-tooth harrow, the disk harrow, the
spading harrow, weeders, and the Acme and Meeker
harrows.

The spike-tooth harrow is essentially a leveling imple-
ment, adapted to very shallow cultivation of loose soils.
It is also something of a cleaner, in that it picks up surface
rubbish. The spring-tooth harrow works more deeply
than does the spike-tooth harrow, and can therefore be
used in many soils for which the latter is not adapted.
In working down cloddy soil it brings the lumps to the
surface, where they may be crushed. The disk harrow
depends for its primary advantage on the conversion of
sliding friction into rolling friction. Its draft is therefore
less for the same amount of work done. It has a vigorous
pulverizing action similar to that of the plow, surpassing
shovel cultivators in this respect. The disk harrow is
not adapted to stony soil, but the toothed forms are as
effective on such soil as on soil free from stones, as long
as the stones are not large enough to collect in the imple-
ment. On the other hand, on land full of coarse manure,
sod, and the like, the disk harrow isthe more efficient.
The spading harrow (cutaway disk) is very little different
from the disk harrow, except that it takes hold of the soil
more readily. A recent attempt to bring about a high
degree of pulverization, and with greater uniformity, is
represented by the double-disk implements. In these
implements there are two sets of disks, one set in front
of and zigzagged with the other, and the two adjusted
so as to throw the soil in opposite directions.

Weeders are a modified form of the spring-tooth har-
row, adapted to shallow tillage of friable, easily worked

TILLAGE 677

soil, where the aim is to kill weeds and create a thin sur-
face mulch. They are wide and are fitted with handles,
and therefore have an intermediate place between culti-
vators proper and harrows. They are much used for
intertillage of young crops.

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: ¥ . Ee 2/4 “at . .,
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ine f care > th het Sinner 04:
a 14 ef year Sen er
ere it ae Lt eR pT

Fic. 71.—Types of harrows: (1), spike-tooth; (2), spring-tooth;
(3), weeder; (4), double disk (note that the forward disks are
solid while the rear disks are of the cut-out type); (5), spading
disk; (6), Acme. All these belong to the cultivator group of im-
plements.

The Acme harrow consists of a series of twisted blades
which cut the soil and work it over. They are most
useful in the later stages of pulverization on soil relatively
free from stones. The Meeker harrow is a modified form
of disk, used primarily for pulverization. It consists of
a series of lines of small disks arranged on straight axles,
and is especially adapted to breaking up hard, lumpy soil.

678 SOILS: PROPERTIES AND MANAGEMENT

In this particular it may be considered as belonging to the
third set of implements, the clod crushers. But as com-
pared with the roller on hard soil it is more efficient.

582. Seeder cultivators. — Many implements used
primarily for seeding purposes are also cultivators, and
their use is equivalent to cultivation. The grain drill
is a good example of this group. It 1s essentially a culti-
vator — either shoe or disk — adapted to depositing the
grain in the soil at the proper depth. All types of planters
that deposit the grain in the soil have a similar action
on the structure of the soil. The ordinary two-row maize
planter, the potato planter, and the like, while of low
efficiency as cultivators, still have an effect which is
measurable. This action is well seen in the lister, used
for planting maize, by which the grain is deposited beneath
the furrow, which is filled by cultivation after the grain
isup. The lister is generally used without previously plow-
ing the ground, and its use is limited to regions of low rain-
fall where the soil is aérated by natural processes. Plowed
ground listers have lately been introduced, which com-
bine the advantages of deep planting with proper prep-
aration of the soil.

There is also a very considerable tillage action in many
harvesting implements. The potato digger, for example,
very thoroughly breaks up and cultivates the soil, and
this process is one important reason for the general
high yield of crops following the potato crop. Bean
harvesters and beet looseners also have a similar action
on the soil:

§83. Packers and crushers. — These may be divided
into two groups — those implements that aim to compact
the soil, and those the primary purpose of which is to
pulverize the soil by crushing the lumps. Both kinds

TILLAGE 679

of implements have something of the same action on the
soil. That is to say, any implement that compacts the
soil does a certain amount of crushing; and, conversely,
any implement that crushes the soil does some com-
pacting.

584. Rollers (Fig. 72). — The type of the first group
is the solid, or barrel, roller, which by its weight tends to
force the particles of soil nearer together and to smooth
the surface. The smaller the diameter in proportion to its
weight, the greater is the effectiveness of the roller. Its
draft is correspondingly greater. As a crusher, the roller
is relatively inefficient on hard, lumpy soil, because of its
large bearing surface. Lumps are pushed into the soft
earth rather than crushed.

It should be mentioned that there is one condition
under which the roller is effective in loosening up the soil
structure. This is on fine soil on which a crust has
developed as a result of light rainfall. Here the roller
may break up the crust and restore a fairly effective soil
mulch.

Another form of roller is the subsurface packer. One
type of this implement consists of a series of wheels with
narrow, V-shaped rims, which press into the soil and com-
pact it while leaving the surface loose. The wheels
are designed primarily to smooth the land after plowing,
and to bring the furrow slices close together and in good
contact with the subsoil, in order to conserve moisture
and promote decay of organic material that may be plowed
under. This packer has been developed chiefly in semi-
arid and arid sections of country where the conservation
of moisture is especially important, but it might well
have a much larger use for the same purpose in sections
of the country that are subject to late summer and fall

680 SOILS: PROPERTIES AND MANAGEMENT

droughts. While compacting the soil, this implement
leaves a mulch.

arr

Fre. 72 —Types of packers and pulverizers: (1), solid or barrel roller;
(2), corrugated roller; (8), crusher and subsurface packer; (4),
bar roller.

585. Clod crushers. — The aim of these clod crushers
is to break up lumps. As to mode of action, there are
several forms. The corrugated and the bar roller and
the clod crusher concentrate their weight at a few points,
and are open enough so that the fine earth is forced up
between the bearing surfaces. They are very effective
in reducing lumpy soil to comparatively fine tilth. They
have very little leveling effect further than the breaking-
down of lumps.

The planker, drag, or float, variously so-called, con-
sists essentially of a broad, heavy weight without teeth,
which is dragged over the soil. The lumps are rolled
under its edge and ground together in a manner which
very effectively reduces their size. At the same time
the soil is leveled, smoothed, and, to a degree, compacted.
This implement may well be used in the place of the roller

TILLAGE 681

as a pulverizer, on many occasions. It is constructed in
many forms.

586. Efficient tillage. — Efficient tillage requires an
understanding of the properties of the soil, good practi-
cal judgment as to its condition, facility in the selection
of the proper implements for its modification, and me-
chanical skill in their operation. The same result may
often be attained in different ways, and the practical
necessity that frequently arises for the farmer to get on
with a relatively few tillage implements where a variety
of soil conditions must be dealt with draws heavily on his
resourcefulness.

CHAPTER XXX

IRRIGATION AND DRY-FARMING

IRRIGATION ! is the application of water to the soil for
the purpose of growing crops. It is supplementary to the
natural precipitation. The quantity of water applied
and the time of application must therefore be determined
by the character of the rainfall.

587. Relation of irrigation to rainfall. — The limit of
rainfall where irrigation becomes necessary is not a fixed

1°Widtsoe, J. A. Principles of Irrigation Practice. New
York. 1914.

Olin, W. H. American Irrigation Farming. Chicago. 1913.

Bowie, A. Practical Irrigation. New York. 1908.

King, F. H. Irrigation and Drainage. New York. 1899.

Paddock, W., and Whipple, O. B. Fruit Growing in Arid
Regions. New York. 1910.

Newell, F. H. Irrigation. New York. 1902.

Mead, E. Irrigation Institutions. New York. 1903.

Mead, E. Preparing Land for Irrigation and Methods of
Applying Water. U.S. D. A, Office Exp. Sta., Bul. No. 145.
1904.

Wickson, J. A. Irrigation among Fruit Growers on the
Faciic Coast. U.S. D. A., Office Exp. Sta., Bul. No. 108.
1902.

Widtsoe, J. A., and Merrill, L. A. Methods for Increasing
the Crop Producing Power of Irrigation Water. Utah Agr.
Exp. Sta., Bul. No. 116. 1912.

Fortier, 8. The Use of Small Water Supplies for Irrigation.
U. 8. D. A., Yearbook, p. 409. 1907.

Fortier, S. Irrigation of Orchards. U.S. D. A., Farmers’
Bul. 404. 1910.

682

IRRIGATION AND DRY-~FARMING 683

amount. Irrigation is practiced in all parts of the world
— in those regions where the rainfall is 50 and 60 inches
a year, as well as in those regions where it is only 20 inches
or less. (See Fig. 73.) The need of irrigation is de-
termined by (1) the time when the rainfall occurs,
(2) the way in which it occurs, whether in small or

Se UNA te EEA

naniiiite Coa
RRR RRRR Ee
SRR
tal

Fic. 73.—Diagram showing the extent and distribution of rainfall in an
arid region (Yuma, Arizona), and a humid region (Buffalo, New
York). ;

large quantities, (3) the nature of the soil, (4) the
air temperature and wind movement, and (5) the nature
and value of the crops grown. Other factors, such
as the cost of applying water, methods of tillage,
and market facilities, have some influence in deter-
mining the practicability of irrigation. Irrigation is
usually associated with a low rainfall of 20 or 25 inches
a year. Using these figures as a measure of the need
of irrigation throughout the world, it appears that about
60 per cent of the earth’s surface has so low a rainfall that
irrigation is necessary in order to secure paying yields of
crops. About 25 per cent of the earth’s surface receives
10 inches or less of rainfall annually. About 30 per cent
receives between 10 and 20 inches, and about 10 per cent

684 SOILS: PROPERTIES AND MANAGEMENT

receives between 20 and 30 inches. Every continental
area has its arid portion where the rainfall drops below
10 inches. (See Fig. 75.) These sections are usually in
the interior, but their position depends on the topography
of the land and the direction of the moisture-laden winds.
Sometimes, as in the western United States, the coastal
mountains cause an arid climate in the adjacent interior
valleys, some of which extend quite out to the ocean as
in southern California.

eI CO en ae ee
SAN DIEGO

Fic. 74.—Four types of rainfall. The diagrams show the distribution
y months.

It has been estimated that the total available water
supply is sufficient to irrigate only one-tenth to one-fifth
of the proportion of the earth’s surface in need of such
treatment.

IRRIGATION AND DRY-~FARMING 685

588. Extent of irrigated land.—In 1905, Mead?
estimated the total area of land irrigated at 100,000,000
acres. Since that date the practice of irrigation has
been extended rapidly in all parts of the world, and it is
probable that at the present time the total area of land
irrigated is at least 200,000,000 acres. In Egypt, in
Australia, and in India, as well as in the United States,
large projects for irrigation developments have recently
been undertaken. In the United States, according to
the Thirteenth Census, the area of land irrigated increased
7,500,000 acres between 1899 and 1909. At the latter
date enterprises for the provision of water were under
way to cover a total of 31,000,000 acres.

589. History of irrigation. The practice of irriga-
tion is very ancient. The very earliest records of the
peoples in the valleys of the Nile and Euphrates rivers,
in Africa and Asia, mention large irrigation works.
In China and India also the practice is very old. The
remains of ancient works for irrigation often amaze
the modern engineer by their size and excellence of con-
struction, considering the facilities that were available.
As early as 2084 3.c. an artificial lake fifty miles in cir-
cumference was constructed in Egypt, communicating
with the Nile through a canal. The Great Imperial
Canal in China, connecting the Hoangho River with the
Yangtze, was 650 miles long and had several lakes in its
course. In Peru, Mexico, and the southwestern United
States, there exist remains of very extensive irrigation
works of great antiquity. In Argentina large irrigation
canals may still be traced for from four to five hundred

1Mead, E. Irrigation Engineering and Practice. American
Cyclopedia of Agriculture, p. 420. New York. 1907.

686 SOILS: PROPERTIES AND MANAGEMENT

miles. In the Verde River valley in Arizona, remains
of the cliff dwellings, which were scattered long before the
advent of the Spanish explorers, are associated with ex-
tensive irrigation canals showing much skill. The ditches
and the reservoirs were finished with hard linings of tamped
or burned clay, and in one instance a main canal was cut
for a considerable distance in solid rock. Sometimes a
smaller ditch was sunk in the bottom of a large canal, to
facilitate the movement of small runs of water. The
ancient canals in the Salt River valley’ had a length
of at least 150 miles and were sufficient to irrigate 250,000
acres of land.

In modern times the great Assouan dam has been built
on the Nile River, and with the associated reservoirs it
is designed to control the flow of the river and provide
water for irrigation. It stands as an example of present-
day irrigation development and control.

590. Development of irrigation practice in the United
States. — In the United States the earliest modern people
to practice irrigation were the Catholic missionaries in
southern California. The immediate predecessors of
the present irrigation systems in the United States were
built by a colony of one hundred and forty-seven Mor-
mons who went into the Salt Lake valley in Utah in July,
1847. The crops of these people were grown with water
diverted from City Creek, and their community life, to-
gether with their peculiar situation, led them to work out
in the succeeding decades the fundamental principles
of economic and social life as adapted to irrigation farm-
ing. In the last thirty years the practice of irrigation has

1Forbes, R. H. Irrigation in Arizona. U.S. D. A., Office
Exp. Sta., Bul. No. 235, p. 9. 1911.

687

IRRIGATION AND DRY—-FARMING

‘youl UL SMOTII
pruny ‘ayIGM Ul SUOTHaI plelues puv PITY “PPOA oY} UL [feyuTeL Jo UOTNQUySIP oy} Burmoys duy—'G, "OLT

688 SOILS: PROPERTIES AND MANAGEMENT

extended rapidly in the western United States. It has
approximately doubled each ten years since 1879.

Irrigation is employed somewhat generally throughout
the region west of the 100th meridian, which runs through
central Nebraska. With the exception of limited areas
the annual rainfall is less than 25 inches, and over large
areas it is less than 15 inches.

The methods of securing water and applying it to the
land have grown up gradually out of the experience of
the people in many communities and under many condi-
tions. Codperative effort of some sort is essential to
provide water for irrigation, and this has led to the use
of several types of organizations for the purpose. Nat-
urally, the states concerned have taken a part in the
matter by passing laws and providing funds to promote
irrigation practices. Finally, the aid of the Federal
Government was enlisted. The enterprises for the pro-
vision of water for irrigation may be divided into seven
groups,' chiefly according to their legal status: (1) com-
mercial enterprises selling water for profit; (2) partner-
ships among individual farmers without formal organiza-
tion; (8) codperative enterprises, made up of water
users; (4) irrigation districts which are public corpora-
tions; (5) Carey Act? enterprises, by Federal enact-
ment authorized August 18, 1894, and made up of
grants to the arid and semiarid states, these states
being held responsible for the irrigation of these grants ;
(6) United States Indian Service enterprises, to provide
for the construction of irrigation works in Indian reser-
vations; and (7) the United States Reclamation Serv-

1 Thirteenth U. S. Census, Chapter 14, p. 421. 1910.
* Stover, A. P. Irrigation under the Carey Act. U.S. D. A.,
Office Exp. Sta., Ann. Rept. pp. 451-488. 1910.

IRRIGATION AND DRY-FARMING 689

ice, established by Federal law June 17, 1902, providing
for the construction of irrigation works with the re-
ceipts from the sale of public lands in the arid and semi-
arid states.

These several provisions and their successive growth
in size suggest the necessity of large enterprises and care-
ful coérdination in providing water for irrigation. The
many attractive features of farming in arid regions under
irrigation, together with the publicity that the enterprises
have had, have hastened the growth of irrigation farming
so that it now plays a very substantial part in the agri-
cultural business of the country.

591. Irrigation in humid regions.—In the humid
states — that is, those in which there is a large normal
rainfall and in which crops can usually be produced with-
out artificial addition of water — irrigation has been
practiced to some extent. Irrigation is useful (1) where
the crop has a high value, as for vegetables and small
fruits near large cities; (2) where the quality of the crop
is much affected by unfavorable conditions, as the pro-
duction of wrapper tobacco in northern Florida and of
rice in Louisiana; (3) where the soil is especially sandy ;
and (4) where the supply of water may be very cheaply
applied to the land, as in the diversion of streams to adja~
cent fields, usually meadows. In Great Britain and in
central and southern Europe, the diversions of streams
to near-by grass meadows is relatively common. Under
all these conditions, small irrigation enterprises have
been developed in different parts of the eastern United
States. The rainfall under which irrigation is practiced
in these regions ranges from 30 to more than 60 inches
annually. The practice of irrigation in humid regions
is in the nature of an insurance against dry years. The

690 SOILS: PROPERTIES AND MANAGEMENT

probability of the occurrence of these in the eastern
United States is shown in the following table‘ of rainfall
records for the ten years from 1900 to 1909, inclusive ; —

NUMBER OF
FirrTeen-par| NumBrr or
AVERAGD Preriops or | Days WHIN
Sravtion ANNUAL OVER wirH | IRRIGATION
RAINDALL LESS THAN was Re-
1 INCH or QUIRED (a)

Rain
Ames, lowa ...... 30.39 23 190
Oshkosh, Wisconsin . . . 29.78 27 292
Vineland, New Jersey . . . 47.47 46 352
Columbia, South Carolina . 47.55 62 568

Selma, Alabama... . . 50.75 60 724

(a) No days counted until after a fifteen-day period with less
than 1 inch of rain.

The aggregate area of the projects is small and amounts
to only a few thousand acres.

592. The Reclamation Service.— The financing of
irrigation enterprises by the Federal Government through
the Reclamation Service has been a wonderful stimulus.
The total number of acres on which ditches have been
constructed or are in process of construction in this way
ageregates 3,101,456, in thirty projects distributed through
seventeen states and involving a total expenditure of
hundreds of thousands of dollars. These projects contem-
plate the impounding of 13,272,490 acre-feet of water.

1 Williams, M. B. Possibilities and Need of Supplemental
Irrigation in the Humid Regions. U.§8. D. A., Yearbook 1911,
pp. 309-320.

Also, Teele, R. P. Irrigation in Humid Regions. American
Cyclopedia of Agriculture, p. 487. New York, 1905.

IRRIGATION AND DRY-FARMING 691

About one-third of this area was irrigated in1915. Many
of the dams and canals involved are of stupendous size
and necessitate feats of bold engineering. Often hydro-
electric power is developed in large amount in the passage
of the water from the reservoirs to the fields where it is
to be used to grow crops.

593. Legal, economic, and social effects of irrigation. —
The practice of irrigation on an extensive scale has caused
important changes in the construction of law! relative to
water and property rights and in commercial and social
organization.

Riparian rights in streams and lakes under humid
conditions, for purposes of domestic use, power, and trans-
portation, must be modified in an arid country. Here
values of all real property depend largely on the supply
of water for purposes of irrigation. The control and use
of water becomes of the utmost public concern. Conse-
quently the use of water for the purpose of growing crops
takes precedence over use for all other purposes except
domestic use. In nearly every country in the world
where irrigation is extensively practiced, the state or
the government has assumed ownership or a large measure
of control over the water in all lakes and streams. The
necessity of the use of water for irrigation has conferred

1Mead, E. Irrigation Institutions. New York, 1903.

Mead, E. [Irrigation Institutions in Different Countries.
American Cyclopedia of Agriculture, Vol. IV, p. 154. New
York, 1909.

Hess, R. H. Further Discussion of American Irrigation
Policies. American Cyclopedia of Agriculture, Vol. IV, p.
160. New York, 1909.

Hess, R. H. Socio-Economic Aspects of Irrigation. Ameri-
can Cyclopedia of Agriculture, Vol. IV, p. 167. New York,
1909.

692 SOILS: PROPERTIES AND MANAGEMENT

certain privileges, such as the principle of eminent domain,
in conserving and utilizing water. The provisions differ
somewhat in detail, but in general agree in conferring the
right to use water upon those persons who can first make
the best use of it for the purpose of growing crops. Other
rights in the use of water are largely subject to its use for
irrigation. Further, the tendency is to attach the right
to the use of water to the title to land, since each has
value only as it is associated with the other. However,
in the attachment of water from a particular source to
any given area of land, many difficult questions may be
raised which must be decided by the larger principle of
beneficial use.

A close economic dependence among the people and a
high degree of social codrdination grows out of the practice
of irrigation farming on a large scale. The fertile nature
of the soil, the favorable climate, and the codperation
necessary to supply water for irrigation, leads to intensive
methods of farming, to specialization in production, and
to many codperative enterprises, not only in agriculture,
but also in associated industries in the same region. These
intensive practices and the close personal association
involved promote a high intellectual and social standard
in the community. Irrigation has been an efficient school-
master in the practice and value of codperation in all sorts
of enterprises.

§94. Divisions of irrigation. ——- Two main parts make
up the practice of irrigation: the first is the provision
of water, which is essentially an engineering problem ;!
the second is the use of water on the land, which is es-

1 Wilson, H. M. Irrigation Engineering, p. 625. New York,
1909.

IRRIGATION AND DRY~FARMING 693

sentially an agricultural problem. It is important to
maintain this clear distinction in dealing with the prac-
tice of irrigation, especially in its larger aspects. The
two functions are largely exercised by different groups
of men, and they involve widely different types of knowl-
edge and skill. The supreme test of an irrigation system
is efficient use of the water on the land in the production
of crops.

595. Sources of water for irrigation. — The practice
of irrigation is dependent on some adjacent supply of
water that may be diverted on to the land. It may be
derived by (1) the diversion of streams flowing from
well-watered regions; (2) the melting of snow on moun-~
taim areas; (8) the regulation of the flow of streams by
storage reservoirs; and (4) the utilization of underground
water by means of wells. All these sources may require
the construction of large and costly works, which are well
exemplified in the structures built by the United States
Reclamation Service and by the Egyptian government
in the Nile valley. Dams hundreds of feet high and
thousands of feet long, containing millions of cubic yards
of masonry and concrete, have been constructed for these
purposes.

596. Canals. — The conveyance of the water from the
point of supply to the place where it is to be used necessi-
tates further difficult engineering problems, which in some
cases have entailed the construction of large tunnels
under mountains and the development of large pumping
and. power plants as well as the construction of thousands
of miles of main and lateral canals. In 1909 the length
of main irrigation ditches in the United States was 875,911
miles, and of laterals 38,062 miles. As a rule the water
is conveyed by gravity flow without pressure. Important

694 SOILS: PROPERTIES AND MANAGEMENT

problems presented relate to the prevention of seepage,
erosion, and evaporation. The loss? of water in transit
from its source to the field has been found to average 60
per cent, and to range from 0.25 per cent to as much as
64 per cent a mile with an average of about 6 per cent.
The seepage water from canals may result in further loss
by accumulating in low lands, where the evaporation,
coupled with the solution of the soluble salts in the soil,
causes injurious accumulation of alkali in the surface soil,
and in extreme cases a swampy condition which destroys
the value of the soil for agricultural purposes. In order
to prevent seepage many kinds of lining and treatment
of the walls of canals have been employed. Cement
lining in different forms, wooden flumes, clay puddling,
oiling, applications of tar, and silting have been used.
The need of a lining depends much on the nature of the
formation through which the ditch passes. Silt is an
excellent means of checking seepage. Where clear water
is carried, the ditch must usually be lined, and the prac-
tice of lining canals in order to reduce seepage is increas-
ing rapidly. Sand and gravel permit much seepage and
are easily eroded. Clay permits little seepage and is not
easily eroded. The velocity of flow of water in canals
should not exceed three feet a second. In large canals
this will not permit a grade of more than six inches in a
mile; in very small ditches a grade of from forty to fifty
feet in a mile may be necessary to cause the same velocity
of flow. A lining that is not subject to erosion, together

1Teel, R. P. Irrigation and Drainage Investigations.
U.S. D, A., Office of Exp. Sta., Ann. Rept. 1904, p. 36. Also,
Mead, H., and Etcheverry, B. A. Lining of Ditches and Reser-
voirs to Prevent Seepage Losses. Calif. Agr. Exp. Sta., Bul.
No. 188. 1907.

IRRIGATION AND DRY~FARMING 695

with a channel that is deep in relation to its width, not
only reduces seepage, but also, by permitting the rapid
flow of water, reduces loss by evaporation.

At the farm on which the water is to be used, it is dis-
tributed in small field laterals which are carried on the
higher ground. Precautions against seepage and evapo-
ration should here be taken. The tendency now is toward
the distribution of the water to the fields by means
of underground pipes, with standpipes and valves at
the points of discharge. The arrangement of the farm
laterals must of course be determined by the topography
of the land, since the water flows by gravity.

597. Preparation of land for irrigation. — The prep-
aration of the land for irrigation depends on the method
used to apply the water. Usually marked irregularities
should be removed by smoothing the surface. Where
any sort of basin method of irrigation is used, it may also
be necessary to level the surface. Various types of scrap-
ers and levelers have been found useful for this operation.
Much of the arid and semiarid land carries a growth of
sage brush or other bushy vegetation, and of course
this must be removed before smoothing operations can
become effective.

598. Methods of applying water.— There are four
general methods! of applying water to the soil. These
are (1) overhead sprays, (2) sub-irrigation, (3) flooding,
and (4) furrows.

599. Overhead sprays. — By the overhead spray system
(Fig. 76) the water is distributed in pipes under a pres-
sure of forty to sixty pounds and discharged from a series

1 Fortier, 8. Methods of Applying Water to Crops. U. 8S.
D. A., Yearbook 1909, pp. 293-308.

696 SOILS: PROPERTIES AND MANAGEMENT

of nozzles. Several types of nozzles are employed. The
amount of water that can be applied is relatively small,
and consequently the method is used chiefly in humid
regions to supplement a rather high rainfall, in the growth
of crops of large value. It is used in the growth of truck
and small fruit crops near the large eastern cities.

The advantages of the system are : —

1. The water is conveniently applied at the desired
point. 2. The system may be used on uneven land and
without preparation of the surface. 3. There is no
waste of land bv ditches. 4. The application of the
water is easily controlled by valves and by the movement
of the pipes.

The disadvantages of the system are: —

1. The capacity is limited. 2. The cost is high for
equipping and maintaining the plant, and for developing
the pressure requisite to suitably distribute the water from
the nozzles. 3. There is possibility of injury to crops
where water is applied on warm, bright days, since the
water comes into contact with the foliage.

600. Sub-irrigation. — Sub-irrigation is the distribution
of water from underground pipes. These are buried in
the soil and perforated in such a way that the water finds
an outlet and is distributed by the capillarity of the soil
and by natural gravity flow. In greenhouses and where
shallow-rooted annuals are grown, lines of drain tile are
employed, the water flowing out at the joints. Con-
tinuous pipes having an open seam or perforations have
been used. Another method employs a porous cement
plug which rises a little above the supply pipe. The
object of the last-named method is to avoid the common
difficulty from the entrance of roots into the pipes. The
pipes must have a very slight grade in order to insure a

IRRIGATION AND DRY-FARMING 697

Outdoor Nozzle Lawn Sprinkler Nozzle Greenhouse Noazle

Fre. 76.—Essential features of construction in one method of overhead
spray irrigation. Water is supplied under pressure from under-
ground pipes and is distributed from small nozzles (NV) along the
axis of the pipe. Different forms of nozzles are used for different
purposes (see detail). Gauge (@) shows pressure, (S) is pipe sup-
port, and (Z) is lever for turning the discharge pipe, which is fitted
with a freely moving sleeve joint.

698 SOILS: PROPERTIES AND MANAGEMENT

uniform distribution of water. They operate under
little or no pressure. The system has a number of ad-
vantages, but in practice these are usually more than
offset by its disadvantages. The advantages are: —

1. The system is permanent. 2. It is economical of
water. 3. There is no injury to the physical properties
of the soil. +4. There are no obstructions at the surface.
5. The deep rooting of crops is encouraged. 6. There is
very little expense for supervision of the distribution of
water. 7. The accumulation of soluble salts on the surface
of the soil by evaporation is reduced. 8. The system may
sometimes be used as a means of drainage also.

The disadvantages are : —

1. There is a strong tendency for the pipes to be clogged
by the entrance of roots, especially where perennial crops
are grown. The porous-plug method of discharging water
is designed to reduce this difficulty. 2. The slow lateral
capillary diffusion of water in dry soil makes it necessary
to install the lines of pipe near together, which entails
heavy expense.

The method is best adapted to shallow-rooted annual
crops, and least adapted to orchards. The seepage of
water from the pipes attracts the growing roots, which
are likely to enter the pipes, break up into many small
fibers, and clog the system.

There are soil conditions under which this method is
especially useful. Where the soil is a porous sand or
gravel underlaid at a depth of four feet or less by a rather
impervious stratum, the water may be distributed rapidly
from the pipes so that it accumulates on the hard sub-
stratum and saturates the soil, the pipes being quickly
emptied. There is then no tendency for the roots to
enter the pipes, and the porous nature of the soil permits

IRRIGATION AND DRY-FARMING 699

the pipes to be placed several rods apart, thus reducing
the expense of installation.

Sub-irrigation sometimes occurs naturally under condi-
tions similar to those just described, where water is sup-
plied from springs or by seepage. Where it can be em-
ployed, sub-irrigation is the ideal method of applying
water to the soil.

601. Methods most used in arid regions. — The two
methods preéminently used to apply water to the soil
under arid conditions are by furrows and by flooding.
The land must generally be prepared to some extent for
either of these methods, by smoothing or leveling the
surface, throwing up levees, or constructing distribution
furrows. It is a fortunate fact that the subsoil in arid
regions is about as fertile as the soil, and therefore grad-
ing can be practiced with impunity. Both methods have
a large number of variations in detail to adapt them to
particular soils, topography, or crops.

The chief factors determining the choice between flood-
ing and furrowing are (1) the nature of the crop, (2) the
character of the soil, (8) the contour of the land, and
(4) the quantity of water available.

602. Flooding. — Flooding is especially employed
(1) where the crop occupies the entire area, such as in
grainfields and meadows; (2) where the soil is of medium
porosity and does not bake seriously on drying; (8) where
the surface is relatively flat; and (4) where the supply of
water is relatively large.

The advantages of this method are: —

1. The handling of water is easy.

2. There is economy in ditches.

3. The necessity of tearing up the crop is avoided.

4, The method is especially suited to certain crops

700 SOILS: PROPERTIES AND MANAGEMENT

that grow in standing water, such as rice and cran-
berries.

Its disadvantages are: —

1. A large quantity of water is required.

2. Over irrigation, with consequent seepage and diffi-
culties from alkali, is likely to occur.

3. On heavy soil, puddling and checking of the surface
soil result from lack of tillage.

4, Some crops are injured by direct contact with water.

5. The cost of leveling and of construction of levees is
large.

There are two main types of flooding. In the first
the water is turned into level checks or blocks, where
it stands until it is absorbed by the soil — called commonly
closed-field flooding. In the second type the water is
distributed in a moving sheet or a series of small rills,
from field supply ditches— called open-field flooding.
This method is used only where there is a moderate slope
to carry the water.

In closed-field, or check, flooding, the land is divided
into blocks, each having a level surface and surrounded
by a levee. The size of the checks, their shape, and the
height of the levees is determined by the contour of the
land. On a slope they may be very irregular. Small
checks of one to three acres are most successfully irri-
gated, but areas of twenty or more acres have been flooded
in one block. A flow of five to seven second-feet of
water is necessary in order to make the method thoroughly
successful. One man can irrigate from five to twenty
acres a day, depending on the size and form of the checks.
The levees may be permanent, as is usually the case
especially in meadows, or they may be thrown up for
each application of water. The permanent levees may

IRRIGATION AND DRY-FARMING 701

be broad and low so that they will not interfere with
harvesting. ‘This method of flooding is falling into disuse.

A phase of check flooding is the basin method of irri-
gating orchards, in which small, shallow basins are formed
around each tree and separated from the trunk by a block

Fig. 77.—Implements used in irrigation practice. (A), seraper for
making small levees in irrigation furrows; (B), (C), and (D), wood
and metal topoons used to close irrigation furrows and by means
of the small openings divide and regulate the flow; (2), canvas
dam used in flooding from field ditches. The edge of the ganvas is
held down by a shovelful of earth.

702 SOILS: PROPERTIES AND MANAGEMENT

of earth to prevent injury to the growing wood. This
method is used rather extensively throughout the arid
regions.

In the open-field, or blind, flooding, the water is sup-
plied in ditches which are carried across the contours at
a moderate grade, and at intervals the flow is intercepted
by a canvas dam or other obstruction and forced to flow
over the lower bank, from which point it is distributed
down the slope and over the field in numerous small
trenches. Any surplus water is collected in a ditch at the
lower side of the field. In this method of applying water,
constant attention is required to guide the flow and prevent
erosion. One man can irrigate from five to ten acres in a
day. This method is used in irrigating grainfields and
sloping meadowland and in saturating the soil in prepa-
ration for a crop.

603. Furrows.— In the furrow system of irrigation
the water is led out from the supply ditch on the upper
side of the field into small, parallel furrows extending
down or across the slope at a considerable grade. This
system is used for cultivated field and garden crops, and
to a large extent in orchards. The rate of flow of water
in the furrows should not exceed one to two feet per
second, depending on the nature of the soil. This permits
a wide range of grade, from 2 to 10 per cent, where the
head of water is only a fraction of a second-foot in each
furrow. The flow on a given slope may be regulated by
the head of water and is determined by the porosity of the
soll. On heavy soil a small head and a steep grade may be
employed; on sandy soil, which washes easily, a low grade
and a large head of water is used. The length of furrows
that may be employed depends on the nature’of the soil
and the head of water available. The water is distrib-

IRRIGATION AND DRY~FARMING 703

x
RECTANGULAR CHECK re) cnn
\

LATERAL >
fmf

FOAD

B9G96G S09 rat teil bit a
ao 9egegs3 279 Ne MH itt ft ath i
i

id a H
te a '
a itl a
i \3 ua
a i i

| ny

ne i can
Y

eee Ee an |

9999900
gat ove
$xooan
9arGoo
GIIVess

Fre. 78.—Plan of irrigated farm showing the methods of irrigating dif-
ferent crops and the arrangement of the irrigation works for apply-
ing the water under the different conditions.

704 SOILS: PROPERTIES AND MANAGEMENT

uted from the furrows by percolation and by capillary
movement. Percolation causes the accumulation of
water under the upper end of the furrows; capillary move-
ment distributes the water laterally as well as downward,

Fig 79 —Diagrams showing the relative rate of movement of water
from iurngation furrows into clay loam (left), and sandy loam
(right), after different pe1iods of time

and its rate determines the distance between the furrows.
The downward! movement is much more rapid than the
lateral movement, and both are very irregular, depending
on the nature and structure of the soil. Ordinarily the
furrows are relatively close together, to give greater
uniformity in distribution. In corn, potatoes, berries,
garden vegetables, and crops of similar character, a furrow
is placed in each row, or at least in every other row as 1s

1 Widtsoe, J. A, and MeLaughhn, W W. The Movement
of Water in Irrigated Sols. Utah Agr. Exp Sta, Bul. No.
115. 1912. Also, Loughridge, R. Hl. Distribution of Water
in the Soil in Furrow Irmgation. U.S. D A., Office Exp. Sta.,
Bul. No. 203. 1908.

IRRIGATION AND DRY-FARMING 705

sometimes the case in strawberries, in order to permit
harvesting.

In orchard culture two or more furrows are placed
between each two rows. Often for young trees a furrow
is placed on either side at a distance of about two feet,
this distance being increased as the trees increase in size.
The furrows are temporary and are usually renewed
after each application of water, as the establishment of a
soil mulch is necessary in order to prevent excessive loss
of water by evaporation.

604. Size and form of furrows. —In shape the fur-
rows should be relatively narrow and deep. Water is
conserved by this form in three ways: (1) it flows more
freely, both in the furrow and into the soil; (2) less surface
is exposed to evaporation; and (3) the surface mulch is
more easily maintained. (See Fig. 80.) Under,arid con-
ditions a deep mulch! of six to eight inches is most

Fig 80 — Diagram showing the relative advance of water into the soil
from a deep (left) and a shallow (right) irmgation furrow Note
the relative extent of surface soil wet in the two cases A deep
mulch and deep irngation furrows aid in the conservation of
moisture,

1Fortier, S Evaporation Losses in Irrigation and Water
Requirements of Crops. U.S. D. A., Office Exp. Sta., Bul. No.
177. 1907.
22

706 SOILS: PROPERTIES AND MANAGEMENT

efficient, and the bottom of the furrow should extend
well below its base. This will allow the water to diffuse
laterally rapidly, and the deep dry mulch reduces the
extent to which the surface becomes moist, thereby con-
serving moisture and reducing the accumulation of alkali
at the surface.

The application of water to the soil in irrigation must
be guided by the principles elucidated in the discussion of
the physical properties of the soil, and its relation to
moisture and its control.

605. Units of measurement.— The measurement of
water in irrigation practice involves the use of units of
volume and pressure. By the head is understood the
volume of water supplied in the unit of time. The flow
of water in canals is usually stated in units of flow per
unit of time, that is, the number of cubic feet per second,
called the second-foot. Frequently the term second-foot
is applied to the volume of water that would result from
a flow of that rate throughout the season. A smaller
unit is the miner’s inch, a term derived from mining
practice, which refers to the quantity of water that will
flow out of an orifice one inch square under a constant
pressure which varies in different states from a four to
an. eight inch head above the top of the orifice. Like the
second-foot, the flow is frequently rated by the season.
The pressure is proportional to the depth, or head. It is
commonly stated in pounds per square inch. A column
of water ten feet in height exerts a pressure of approxi-
mately 4.34 pounds to a square inch.

In the field, water is commonly measured in terms of
depth over an acre. An acre-foot is the quantity of water
that will cover an acre one foot in depth. An acre-inch is
one-twelfth of an acre-foot. These are very convenient

IRRIGATION AND DRY-FARMING 107

terms because of their definiteness and relation to the
common method of stating rainfall. Usually an inch or a
foot of water refers to that depth over an acre.

Various mechanisms are employed for measuring !
water in irrigation practice. The commonest of these
are the weir and the flume. (See Fig. 81.) The weir is

an" Net ll
Wh JE: PANG LP
r HN YF Vie
— ee Zap fy a
A
£ \ Vay r} 1 \
c \
ria , wn cr

Fie. 81.—Plank measuring box and a Cippoletti weir used in determin-
ing the flow of irrigation water.

a simple device to give the stream a definite cross section
and to aid in the measurement of the depth, and there-
fore the volume of flow. It is usually a knife-edged notch,
of a standard shape calibrated to a grade stake a short
distance up stream from which the depth of water and
its velocity are rated. The measuring box, frequently
termed a module, is a box for measuring the flow of water
from an orifice under fixed conditions. The Staldate
module, developed in Italy, is most generally adopted for
the purpose. Small streams are divided by a knife-edge

1 Carpenter, L.C. The Measurement and Division of Water.
Colorado Agr. Exp. Sta., Bul. No. 150, 4th ed. 1911.

708 SOILS: PROPERTIES AND MANAGEMENT

diverter inserted into the current, which diverts a definite
portion of the stream. This is called a divider.

606. Amount of water to apply. — The amount of
water to apply to the soil at any one time depends on
(1) the nature and condition of the soil, (2) the supply of
water, (3) the crop, and (4) the season. In the main,
enough water should be applied to capillarily saturate
the soil to a depth of one foot and to increase the soil
moisture to a depth of three feet. A fairly dry, fine-
textured soil will effectively take the largest irrigation.
Some crops are more sensitive to water at one period of
growth than at another. Potatoes should mature in a
rather dry soil. The application of water at a single
irrigation should ordinarily be from four to eight inches.
In very hot weather it may be reduced to two or three
inches. In late fall or early spring, when the soil is
unoccupied, the application may be relatively larger
provided the soil is dry.

Excessive irrigation is to be avoided. While the total
yield increases with increase in the application of water
up to the maximum point, the unit production decreases.!
The following brief table, calculated by Widtsoe from
actual yields of wheat, illustrates this point : —

Tairtry ACRE-INCHES OF WATER SPREAD OVER

1 acre 2 acres 3 acres 4 acres 6 acres

Grain (bushels) | 47.51 91.42 130.59 | 166.16 | 226.16
Straw (pounds) | 4532 2908 10256 13204 | 17916

Pe OAT ERT A RAR rere mbt Asha rH PLAN al

1Widtsoe, J. A. The Production of Dry Matter with Ditf-
ferent Quantities of Irrigation Water. Utah Agr. Exp. Sta.,
Bul. No. 116. 1912,

IRRIGATION AND DRY-FARMING 709

Small applications of water are relatively most efficient.
Up to the limit where injury results, the more concentrated
the soil solution, the larger is the yield of crop.

607. Time to apply water. The best time to apply
water depends to a large extent on the nature and habits
of the crop. Ordinarily the soil should be thoroughly
moistened at the time of planting, in which case the
application will have been made before fitting the ground.
For sugar beets and other crops planted in rows, it is
permissible to irrigate immediately after seeding. The
formation of a crust is to be avoided. After planting,
water may be applied at intervals of two or four weeks,
or when the soil has reached the stage of dryness at which
sluggish capillary movement occurs. The experienced
irrigator becomes very proficient in recognizing this con-
dition. For grain and forage crops, the soil should be well
moistened when the crop approaches maturity. For al-
falfa, irrigation may be either shortly before or just after
harvest with good results. For root crops a relatively
dry condition of the soil at maturity is preferred. The
same is true for trees, and the large application of water
late in the growing season is especially to be avoided
because the new wood growth is likely to be winter-
killed. Irrigation in spring, especially at blossoming time,
is to be avoided because it interferes with the setting of
fruit. One or two thorough irrigations in a season are
usually sufficient for the growth of trees. Small fruits
should have plenty of water at the maturity of the crop.

Where water is available in late fall and in winter, it
may be applied to the soil and stored there for use during
the following season. Investigations at the Utah * station

1Widtsoe, J. A. The Storage of Winter Precipitation in
Soils. Utah Agr. Exp. Sta., Bul. No. 104. 1908.

710 SOILS: PROPERTIES AND MANAGEMENT

have shown that moisture may be effectively stored in the
soil to a depth of more than eight feet and be readily used
by crops the next season. The total amount of water to
be applied depends on many things. ‘The following factors
affect the duty of water: (1) character of the crop;
(2) climate; (3) texture and structure of the soil; (4) depth
of the soil; (5) fertility of the soil, including the total
amount of soluble material; (6) kind of tillage practiced ;
(7) thickness of planting; (8) season when the crop grows;
(9) frequency and method of applying water; (10) amount
and time of applying water. A fertile soil and a large
and rapid growth of the crop go with economy of water.
Many of the above factors, such as thickness of planting,
tillage practice, and manner of using water, determine the
loss from the soil that has no direct relation to the crop.

The total amount of water to be applied? in irrigation
should range from five to twenty inches, with the tendency
toward the lower figure. This means a duty of 280 to
75 acres a second-foot for a season of sixty days. From
one to four applications of water are usually made. The
larger the plant and the deeper the root system, the larger
the individual application of water may be, and the fewer
the number of applications.

608. Conservation of moisture after irrigation. — The
conservation of moisture applied by irrigation should be
provided for whenever practicable. Crops planted in
rows should be cultivated as soon as the soil is dry enough
not to puddle. As suggested above, when the furrow
method is employed the furrows should be deep, so that
only a small part of the surface soil will be wet. Coupled

1Widtsoe, J. A. Principles of Irrigation Practice, Chapter
AVIT. New York. 1914.

IRRIGATION AND DRY—FARMING T11

with this, a mulch of dry soil from four to eight inches
deep should be maintained. This is a protection against
too high a temperature in moist soil unprotected by shade,
as well as against loss of moisture. The surface of the
soil should be kept as nearly level as possible.

Crops that are not planted in rows, such as grain, may
be cultivated with a fine-tooth harrow until they reach a
height of from several inches to a foot, at which stage
evaporation from the soil is largely prevented by the
shading of vegetation. If it is to be successful this culti-
vation must begin as soon as the seedlings appear above
the surface, in order that the roots may be forced deep
into the soil. Then the top may be much twisted with
but little injury to the plant, and that injury appears to
be more than counterbalanced by the tillering of the plant.
By prompt and thorough tillage following irrigation, very
much may be done not only to conserve soil moisture but
also to prevent the accumulation of alkali at the surface
by evaporation.

609. Sewage irrigation. — A phase of the general prac-
tice of irrigation is the application of sewage! to the land
for purposes of crop production. This supplies plant-food
as well as water. The food content, however, is relatively
small, being about two parts in one thousand, of which
one-half is organic and one-half is inorganic material.
In European countries sewage irrigation is extensively
employed near cities, but in the United States the practice
has not been largely followed. The city of Boston has
carried out extensive experiments, and the city of Los

1 Rafter, G. W., and Baker, M.N. Sewage Disposal in the
United States. New York. 1904. Also, Rafter,G. W. Sew-
age Irrigation. U.S. Geol. Survey, Water-Supply and Irrigation
Papers, Nos. 3 and 22. 1897 and 1899.

712 SOILS: PROPERTIES AND MANAGEMENT

Angeles has a large farm irrigated with sewage water.
The same general principles prevail in the use of water
as in normal irrigation practice, except that the soil may
become clogged and foul from the accumulation of solid
material, especially where the idea of disposal over-
shadows that of efficient use. This practice is used
chiefly for the production of hay and forage.

DRY-FARMING

The water supply for irrigation is sufficient for only a
small part of the earth’s surface which needs such treat-
ment. The remainder of this vast area of land having a
deficient rainfall must be utilized, if at all, by the most
scrupulous and careful conservation and use of the natural
rainfall. The growth of crops without irrigation under
such conditions is termed dry-farming.t It is merely an
intensified form of the methods which are recognized
as good practice to conserve moisture in more humid
regions.

Dry-farming is based on the principle that the production
of dry matter in crops requires only a small part of the
water which may be used in one way or another in its
growth, and that a large part of that water is lost by sur-

1 Widtsoe, J.A. Dry Farming. New York. 1910. (Appendix
includes a large list of references on dry land farming.)

MacDonald, Wm. Dry Farming. New York. 1910.

Campbell, H. W. Soil Culture Manual. Lincoln, Nebraska.
1907.

Chilcott, E. C. Dry Farming in the Great Plains Area.
U.S. D. A., Yearbook, pp. 451-468. 1907.

Briggs, L. J., and Shantz, H. L. The Water Requirement
of Plants. Investigations in the Great Plains in 1910 and 1911.
U.S. D.A., Bur. Plant Ind., Bul. 284. 1918. Also, the Water
Requirements of Plants. A review of literature. U.S. D. A.,
Bur. Plant Ind., Bul. 285. 1918.

IRRIGATION AND DRY—FARMING 7138

face flow, by seepage, and especially by evaporation,
without performing any useful service to the plant.

610. Practices in dry-farming. — The practice of dry-
farming may be divided into three groups: (1) the main-
tenance of such a condition of the soil at all seasons of
the year as will insure the complete absorption of the
rain- and snow-fall; (2) the conservation of the stored
moisture by appropriate methods of tillage; (3) the selec-
tion of drought-resistant crops and of rotations adapted
to the small use of water.

611. Storage of water in the soil. — In different regions
the rainfall occurs at different seasons. A loose, open
condition of the surface soil should be maintained during
that period. This may require deep plowing, and if the
subsoil is compact it may include subsoiling. Where
the precipitation comes as snow, the surface should be
rough so as to prevent drifting, in order that the resulting
water may be uniformly absorbed by the soil. Fall
plowing is an important factor where much of the pre-
cipitation comes in winter and the soil is compact.
Another reason for the maintenance of a ridged surface
is to reduce erosion by the high winds which frequently
occur in winter in dry-farming regions and which cause
the serious removal of the soil. The roughened surface
impedes the wind movement, and the moist soil at the
crest of the ridges resists erosion.

612. Conservation of moisture. — The conservation of
the moisture in the soil involves two things — an increase
in the capillary capacity of the soil, and the prevention of
evaporation. Where the rainfall is low, the deep subsoil
is usually very dry. The rainfall penetrates to a limited
distance from the surface. Having loosened the subsoil
so that the rainfall is absorbed, the next step is to compact

714 SOILS: PROPERTIES AND MANAGEMENT

the substratum as much as possible by tillage in order to
increase its capillary capacity. The need of this treat-
ment, of course, depends on the nature of the soil, and
is not always the most favorable. It is undesirable that
this packing should extend to the surface. Following the
plow, the land is frequently worked down with a subsur-
face packer, an implement of considerable weight, made
up of openwork rims that press the soil together and at
the same time leave a mulch on the surface. By acting
on the lower part of the furrow instead of on the surface,
the packer brings it into closer contact with the subsoil
and thereby establishes better capillary connection.

After thorough packing of the main part of the furrow,
a dust mulch is maintained on the surface. This should
be of medium depth in the season when rains are likely
to occur, and of somewhat greater depth during the
dry period. Two or three inches is usually a sufficient
depth.

Various applications of the principle of mulching may be
employed. Land may be disked before plowing in fall or
spring, to hold moisture until the plowing can be done.
As soon as a crop is removed, the land should be plowed
or fitted and worked down to a good mulched surface.
Land should not be allowed to stand unworked for any
considerable time after harvest. All rowed crops should
be kept thoroughly mulched. Much may be done to
conserve water in grain and hayfields by tillage. The
same principles apply to the practices that are used on
irrigated land. Special revolving toothed implements
have been devised to loosen up the surface soil under
such conditions.

613. Alternate cropping. — Where the rainfall is too
light in a single season to permit the production of a profit-

IRRIGATION AND DRY~FARMING 715

able crop, it is sometimes the practice to collect and store
the rainfall of two seasons in the soil. This is the system
of alternate-year cropping. In the intervening year the
soil is carefully fallowed and mulched, to hold the stored
moisture. That such long-time storage of available
moisture is possible has been clearly demonstrated ! under
dry-farming conditions, and also in the study of irrigation
problems. An arid or a semiarid climate is especially
favorable for the formation and maintenance of an effi-
cient dust mulch, and the occurrence of dry earth in the
lower subsoil permits moisture to be stored and retained in
large quantities within reach of the roots of crops. It is
believed by some persons that the practice of fallowing
in alternate years is very destructive of organic matter
in the soil, and that it may be better to grow a green-
manure crop in that period to be turned under. It is
questionable whether the loss of water may not be a
serious objection to this. |

614. Drought-resistant crops. — For growth under dry-
farming conditions, crops are preferred which have a low
moisture requirement, which are not seriously affected
by severe drying, and which have a fairly deep root system.
The sorghums come in the first class and also fulfill the
second requirement. Corn is fairly satisfactory. Wheat,
barley, and alfalfa are favorite dry-farm crops. Drought-
resistant varieties of these crops are being sought. A
rotation is desirable which exposes the soil as little as
possible to evaporation, and permits continuous mulch-
ing with the minimum of plowing.

1 Atkinson, A., Buckman, H. O., and Gieseker, L. F. Dry
Farm Moisture Studies. Montana Agr. Exp. Sta., Bul. 87.
1911. Also Burr, W. W. Storing Moisture in the Soil. Ne-
braska Agr. Exp. Sta., Bul. No. 114. 1910.

716 SOILS: PROPERTIES AND MANAGEMENT

615. Soils associated with dry-farming. — Dry-farming
is often closely associated with irrigation, being practiced
on the heavier soils where the water-storage capacity is
large and where the practice of irrigation 1s most difficult.
Successful dry-farming requires an annual rainfall of at
least fifteen inches, and twenty inches is much, safer as a
basis for the practice. A general principle to be observed
in dry-farming is that the shorter the soil moisture supply,
the lighter should be the rate of seeding. Wheat, for
example, may be seeded at the rate of only twenty pounds

Fig. 82.—Areas of western Umted States where dry-land farming is or
may be practiced.

IRRIGATION AND DRY~FARMING 717

to the acre. The crop will stool out strongly and adjust
itself to the moisture supply. Under dry-land and irri-
gation farming, crops as a rule root much deeper than in
humid soils.

616. Extent of dry-farming.—In the United States
many thousands of acres in the Great Plains region, in
the semiarid northwestern valleys, and in the Pacific
Coast States, are now being cropped under systems of
dry-farming (see Fig. 82). Further, the practice is be-
ginning to be followed somewhat more definitely in all
parts of the world where similar conditions prevail. The
large open areas of land and the dry climate in such
regions have encouraged the employment of larger power
equipment in planting and harvesting the crops, especially
wheat. In parts of California machines are used which
cut, thresh, and sack the grain in one operation.

The study of the principles on which dry-farming is
based, together with the extension of their practice,
may be expected to bring large areas of land, now sub-
stantially worthless, to a measurable degree of productive-
ness. The tendency in the practice of both dry-farming
and irrigation is toward the more efficient use of water
for purposes of crop production, and to approach the
actual requirements of the plant in the utilization of water.
In both cases the fundamental principles in the storage,
conservation, and use of water by plants must be observed,
as well as care regarding the application of these prin-
ciples according to the soil, the crop, and the nature of the
water supply.

CHAPTER XXXI

THE SOIL SURVEY

Tur function of the soil survey is to investigate the
nature and occurrence of soils in the field. The soils are
classified into areas having approximately the same crop
relations and tillage properties. The location of the areas
of each kind of soil is represented on charts or maps, and
their character and chief economic and agricultural rela-
tions are described in printed reports.

617. The classification! of soils by survey. — The
occurrence of differences in the tillage and manurial re-

1 Klassification, Nomenclature, und Kartierung der Boden-
arten.

Verhandlungen der zweiten internationalen Agrogeologenkon-
ferenz. (Proceedings of the Second International Agro-geological
Conference, Stockholm, Chapter V, pp. 223-298. (Seven papers.)
1911.

Report on Soil Classification. Proc. Amer. Soc. Agron., Vol.
6, No. 6, pp. 284-288. 1914.

Fippin, E. O. The Practical Classification of Soils. Proce.
Amer. Soc. Agron., Vol. 3, pp. 76-88. 1911.

Marbut, C. F. Soils of the United States. U. S. D. A.,
Bur. Soils, Bul. 96, pp. 7-16. 1913.

Coffey, G. N. A Study of the Soils of the United States.
U.S. D. A., Bur. Soils, Bul. 85, p. 114. 1912.

Hall, A. D., and Russell, E. J. Soil Surveys and Soil Analy-
sis. Jour. Agr. Sei., Vol. 4, Part 2. 1911.

Tularkov, N. The Genetic Classification of Soils. Jour.
Agr. Sci., Vol. 3, pp. 80-85. 1909.

Stevenson, W. H., Christie, G. I., and Willeox, 0. W. The

718

THE SOIL SURVEY 719

quirements of soils, their crop relations, and their agri-
cultural value make necessary the determination of the
properties of the soil that are chiefly responsible for those
differences, and their arrangement into an orderly scheme
of classification. The aim is to divide the land into
areas of approximately the same general character. This
volume is largely an exposition of those properties of soils
that make differences in their crop relations and manage-
ment. It is evident that differences are numerous and
varied, and that some have greater significance than
others.

Soils may be classified from many different points of
view. The basis may be purely geological, purely physical,
or almost entirely chemical. Any one of these alone is
likely to be inadequate for the purposes of the agriculturist.
The viewpoint of the agricultural soil survey should be
such as to secure unity in the crop relations of each distinct
area of soil recognized.

The system of classification in use must employ as a
basis some combination of the groups of properties enu-
merated above. The combination selected has differed
in different parts of the world, depending on the training

Principal Soil Areas of Iowa. Iowa Agr., Exp. Sta., Bul. 82.
1905.

Mooers, G. A. The Soils of Tennessee. Tennessee Agr.
Exp. Sta., Bul. 78. 1906. :

Sherman, C. W. The Indiana Soil Survey. Dept. Geol.
and Natural Resources, 32d Ann. Rept., pp. 17-47. 1907.

Hopkins, C. G., and Pettit, J. H. The Fertility of Illinois
Soils. Ilthmois Agr. Exp. Sta, Bul. 123. 1908.

Hall, A. D., and Russell, E. J. Report on the Agriculture
and Soils of Kent, Surrey, and Essex. Dept. Bd. Agr. and Fish-
eries. London. 1911.

Kummel, A.B. Soil Surveys as Related to Geology. N. J.
Bd. Agr., 36th Ann. Rept., pp. 162-169. 1908.

720 SOILS: PROPERTIES AND MANAGEMENT

of the person by whom the survey was proposed, and the
kinds of soils and crops with which he dealt. Some
persons have used the vegetation,! especially the native
vegetation, as a means of classifying soils. Where this
is present it is an excellent means of identifying differences,
and pioneers as well as others have always made use of
the vegetation growing on a soil to detect variation in
its cropping capacities. Unfortunately the vegetation,
whether native or introduced, being a result of natural
causes, affords information regarding the properties of a
soil only when the correlation has been worked out.
Further, the native vegetation is now seldom present in
well-settled areas, so that it is inadequate as a general
means of classification, though very useful for some
purposes of comparison.

618. Factors employed in classification. — In classify-
ing soils, four primary and two secondary factors are
employed. The former group deals entirely with the
soil itself; the latter group deals with the climate or the
situation in which the soil is placed. The situation exerts
an influence on the crop value and on the properties of the
soil. The factors, beginning with those of the smallest
range of occurrence, are as follows: (1) texture, (2) special
properties, chiefly chemical, (8) kind of material from
which the soil was formed, (4) agency of formation,
(5) humidity and precipitation, and (6) normal and
mean temperature.

The soil type is the unit of classification, and may be
defined as an area of soil that is essentially alike in all the
above characters.

1 Hilgard, E. W. Soils, Chapters XXIV, XXV, and XXVI.
New York. 1906.

T21

THE SOIL SURVEY

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722 SOILS: PROPERTIES AND MANAGEMENT

619. Texture — the soil class. — Of all the properties
of the soil, the one which is most apparent and which
exerts the most direct influence on the plant is the tex-
ture, or fineness of division, of the soil particles. Is it a
clay, a silt, a sand, a gravel, or some combination of these?
Is it stony, or is it free from stone? ‘The texture is the
first property made use of in classifying soil. This divi-
sion based on texture is called the soil class. It is a purely
physical division, and does not recognize any chemical
or other differences in the soil except as such differences
may occur between coarse and fine materials.

620. Special properties—the soil series. — Soils of
different texture may be alike in other properties. They
may be all red, all black, or all yellow. They may be
well drained or poorly drained. Such a group of soils of
different texture but alike in all other properties consti-
tutes a soil series. The properties by which the soil
series is recognized are (1) color, which is predominant
in the separation, (2) content of organic matter, (3) natural
drainage, (4) content of lime carbonate, (5) ultimate
chemical composition, and (6) arrangement of the soil in
the section. Any one or a combination of these properties
may identify an area of soils. Such an area would con-
stitute a soil series. These properties permit the recog-
nition of chemical differences quite as much as physical
differences of the soil in mass.

If it were possible clearly to identity all the properties
that may be recognized in the series and class divisions,
there would be no need of employing other factors in the
classification. Such a clear identification, however, is
only partially possible, and is further limited by the
conditions under which the soil survey must be carried
out in the field. Many of these properties are of such

THE SOIL SURVEY 723

an intimate nature that they cannot be recognized by
inspection. However, they are correlated with the origin
and mode of formation of the soil, and therefore the use
of those factors in the classification is justified as an aid
to rapid and accurate field identification.

621. Source of material — the soil group. — The soils
of a region may be similar in many properties because
they have been derived from the same kind of rock. They
may be similar also because they have been derived from
the same mixture of different rock materials. As a result
of the many kinds of rock and the different proportions in
which they may be mingled, many groups of soil series
may be recognized. Some of the commoner groups of
rocks identified with these differences are acid and basic
crystalline rocks, shales, sandstone, and limestone.

622. Agency of formation — the soil province. — The
way in which a rock formation has been broken down and
the residue brought to its new resting place affects both
the chemical and the physical nature of the resultant soil.
The six groups of forces that have been predominant
in the formation of soils are: (1) weathering, or the
decay and disintegration of rocks in place, forming a
residual soil; (2) biological processes, which form organic
matter and give rise to cumulose soils; (8) water in
streams, lakes, and oceans, which reduces, transports,
and sorts soil-forming materials, and which imparts to its
deposits a distinctly stratified arrangement; (4) atmos-
phere, especially as regards wind, which exerts an abra-
sive and sorting action similar to that of water but with
a very much smaller range in the texture of the strata
formed, and with a type of stratification also distinct
from that formed by water; (5) glaciation, or the action
of continental masses of ice, the deposits from which are

794. SOILS: PROPERTIES AND MANAGEMENT

exceedingly heterogeneous in nature and are without
sorting or stratification except as the action of wind and
water may have combined with the action of the ice;
(6) gravity, or the slow creep of material on slopes, which
is a minor agency of soil formation (see Chapter II).

623. Climate. — Soils owe their origin to the operation
of one or more of the forces named above. Usually some
one of these agencies is predominant and gives specific
character to the soil. The elements of climate have been
used in the practical classification of soils to only a small
degree, since the inherent properties of the material in
these divisions are usually distinct enough to make sepa-
ration easy. The excessive accumulation of the soluble
salts known as alkali is associated with a low rainfall,
and other chemical and physical properties are correlated
with aridity. Three main divisions in humidity and pre-
cipitation may readily be made, namely, (1) humid,
(2) semiarid, (8) arid. The exact precipitation limits of
these divisions depend on the temperature relations and
the time and manner of occurrence of the precipitation.

In a world system of soil classification the temperature
relations of the soil would be recognized, but this division
is seldom important in any single country.

624. The practical classification of soils in the United
States. — As practiced in the United States, the classi-
fication of soils? has disregarded the climatic factor and
has usually combined the kind of rock and the agencies
of formation as a single basis of separation of soils, desig-
nating the division resulting therefrom as a soil province.
In some areas one element of formation is dominant and

1 Marbut, C. F., Bennett, H. H., Lapham, J. H., and Lap-

ham, M. H. Soils of the United States. U. §, D. A., Bur.
Soils, Bul. 96, p. 891. 1913,

THE SOIL SURVEY 725

in other areas another element is dominant. To this
extent the classification deviates from the ideal system
outlined above.

625. The soil type and series. How characterized and
named. —- The two predominant divisions of soil are the
soil type and the soil series. The soil type is the unit
of field study and classification, and corresponds to a
species of plant or animal in biological classification. It
includes all those areas of soil that are essentially alike
in all properties — texture, color, chemical nature, struc-
tural properties, source of material, and mode of forma-
tion. In other words, soils of the same type are as nearly
alike as field identification will admit. The soil series is
a group of types differing only in the texture of the differ-
ent members. This may be said to correspond to the
genera in biological classification.

A name is given to each series of soil for purposes of
easy identification, and to this name the class designation
is added, thereby fixing the identity of the type. For
example, the Miami series includes certain light-colored,
timbered, glacial soils of the East Central States. The
Hagarstown series includes certain light brown to reddish
residual limestone soils, found in the blue-grass region of
Kentucky and adjacent states. The Norfolk series in-
cludes lemon yellow, marine-deposited soils of the coastal
plain of the Atlantic and Gulf regions. Clay loam would
refer to a particular texture of any of these series, as the
Miami clay loam, for example, thus completing the type
name of a soil, which is made up of the series name and
the class designation.

The common practice is to select for the series desig-
nation some geographical name in the region where the
soil is first identified or is best developed. The word

726 SOILS: PROPERTIES AND MANAGEMENT

Miami is taken from the Miami River in southwestern
Ohio, where the Miami series was first recognized.

This system of a proper generic name and a descriptive
class name is most widely used in the United States to
identify the;soil type. It gives a specific identity of the
soil in its situation and in all its properties.

Hopkins* has proposed and used the Dewey Library
System of numerical naming of soils, by which each prop-
erty is given a fixed series of numbers and the identifica-
tion number is obtained by combining the numbers that
represent its properties. Whole numbers are assigned to
important and definite soil types, and decimals are used
for related types possessing some distinct variations.
For example, 451.2 represents a glacial soil made up of
brown loam on silt. While the numbering system of
designation is admirable in many ways, it does not lend
itself to the same practical use that is possible with a
proper descriptive name.

626. The equipment for survey work.— The most
important part of the equipment for soil survey work is
the field man. He should be a keen and careful observer,
and he should have had broad training for his work. He
should be acquainted with the technic of soils in the labora-
tory and in the field. He should be familiar with the
chief physical and chemical processes and material in-
volved in soil formation. He should have an under-
standing of that phase of geology known as physiography.
On the agricultural side, he should be acquainted with
plants and the methods of growing the more important
crops. He should know tillage practice, and should be

1 Hopkins, C. G., and Pettit, J. H. The Fertility of Illinois
Soils. Tllinois Agr. Exp. Sta., Bul. 128, p. 252. 1908.

THE SOIL SURVEY 727

able to distinguish between the properties of the soil that
are native and permanent and those that may be induced
by the method of handling. There is very little knowl-
edge of natural phenomena that will not be found useful
to the field man in classifying soils, because he uses all
sorts of observations in making and checking his divisions
in soils. In brief, he should have a good training in the
fundamental technic of geology, chemistry, and agricul-
ture.

In the way of physical equipment the field man should
have a good map of the region, on a scale of one inch to
a moile or larger. The field work should be done on at
least as large a scale as the finished map, as this increases
the degree of accuracy. The map should show the roads,
streams, and towns of the region, and in addition the
topography, location of houses, and other natural and
cultural features which are useful in placing boundaries
of soil. Where a satisfactory map is not available the
field man must make such a map‘ during the progress of
the soil survey. For this purpose a Gannett plane table,
a sight alidade, and some method of measuring distance —
preferably an odometer,:such as is used for counting the
revolutions of a buggy wheel—are necessary. Cloth-
back drawing paper is generally used.

Where a suitable base map is already available, a set
of pencils of different colors for representing each type of
soil on the map as it is recognized is essential. A horse
and buggy is the usual method of conveyance. For ex-
amining the soil a soil auger is used (see Fig. 83). This
consists of a one-and-one-half-inch wood auger attached to
a half-inch pipe rod with a T handle, making a total length

1 Instruction to Field Parties. U.S. D.A., Bur. Soils. 1914.

793 SOILS: PROPERTIES AND MANAGEMENT

of about thirty-eight inches. By the use of additional
sections the length may be increased. The end of the

Fie. 83 —-Auger used
in the examination
of soils. (A),
handle; (B), joint;
(C), worm with
modified cutting
edge.

auger may be modified by cutting off
the screw and the cutting jaws, to
better adapt it to the work in soil.
Generally a bottle of muriatic acid
for detecting carbonates, and strips
of sensitive litmus paper of red and
blue for testing for soil acidity, are
useful adjuncts to the equipment. In
arid regions where important quanti-
ties of alkali are met with, the field
man should be supplied with a modi-
fied Wheatstone bridge and chemical
equipment necessary for the detection
and measurement of the important
salt constituents. A geologist’s ham-
mer for examining soil and rock should
be added, together with such other
minor equipment as may increase the
convenience and efficiency of the work.
A substantial field book should be
provided, for notes on the character
of soil types and other observations
and data, and for records of borings
and samples. The notes should be
carefully classified. Muslin bags of

about one quart capacity should be used for collecting
and shipping the samples to the laboratory for mechani-
eal analysis. Where the natural field structure and

1 Davis, R. O. E., and Bryan, H. The Electrical Bridge
for the Determination of Soluble Salts in Soils. U.S. D. A.,

Bur. Soils, Bul. 61.

1910.

THE SOIL SURVEY 729

moisture conditions of the sample are to be preserved,
wide-mouth, sealed-top, metal or glass containers should
be used. Aluminum cans are usually most suitable, as
they are not corroded by the sample.

627. Procedure in the field. — The area for survey
having been selected, the field party — which usually
consists of two men, a chief and an assistant — proceeds
to examine the soils of the district. Headquarters are
temporarily established in a convenient village or coun-
try residence, and excursions are made into the adjacent
territory. The routes are laid out carefully and system-
atically with the purpose of examining the soils of the
entire area. The party proceeds along the highway,
with frequent stops and side excursions into the field,
examining the soil to a depth of three or more feet with
the auger. In humid regions the basis of the soil classi-
fication is a section of soil three feet deep. In arid
regions, where alkali is prevalent, a six-foot section is usu-
ally the basis of classification, and occasionally much
deeper examinations are made for studying the position of
the water table. The soil is examined especially with refer-
ence to its texture, structure, color, drainage, content of
organic matter, depth of different strata, and special chemi-
eal properties such as lime and alkali. The natural vege-
tation is observed, and note is taken of the type and
growth of crops as well as the extent and species of forest
trees.

Borings and other observations are made from point
to point as the appearance of the soil, the topography,
the conformation of the country, and the character of the
vegetation may suggest. The frequency and position of
observations are determined entirely by the judgment of
the field man. They may be made every few rods or at

730 SOILS: PROPERTIES AND MANAGEMENT

much wider intervals. In getting acquainted with new
types, more borings and detailed observations are neces-
sary than after the soil properties have become familiar
and can be more readily identified. Where the soil is
highly variable, much more frequent observations are
necessary than where it is more uniform. As the survey
proceeds the field man progresses from point to point,
along the highway and in the field, on foot or by convey-
ance as may be more convenient, extending his observa-
tions about half the distance to the next highway in order
that all the territory may be covered most conveniently.
Usually the trip is arranged in a circuit. All areas of soil
essentially alike in their properties and plant relations are
recognized as of the same soil type, and their position on
the map is represented by one of the colors. As the
observations proceed, a change in the character of the soil
may occur. When this change becomes of such char-
acter and importance as to cause difference in agricultural
relations and to be recognizable under the plan of classi-
fication outlined above, a new type is recognized. The
boundary line between the two types must be carefully
traced out by observation and by borings. As the work
proceeds other types of soil may be recognized and the
boundaries are determined and represented on the map,
each type being indicated by a particular color or symbol.
A large number of types of soil may be recognized in each
area surveyed. ‘The character and relationships of these
must be studied carefully in order to decide how they
may be grouped in series and larger units.

In practice it is usually better for the field party to
first make general observations over the area, in order
to recognize the main divisions of the soil that may later
require subdivision into types. To this end all available

THE SOIL SURVEY 731

facts, particularly concerning the geology of the region,
should be familiar to the survey man before active field
work is begun. It is easier and results in a greater degree
of accuracy to first recognize the larger divisions of an
area of soil, and later work out the types, than to’ be con-
cerned from the very beginning entirely with these ele~
mental subdivisions.

During the progress of the field observation the rela~
tionship of each type of soil to natural and cultivated
plants should be studied, and the tillage properties of the
soil noted. The farmers also may be interviewed con-~
cerning their soils, as to tillage properties, crop relations,
and response to methods of improvement. In short, all
available data concerning the character of the soils of the
region should be sought.

Records are made in the field notebook descriptive of
the average character of each type of soil. The descrip-
tion of typical borings may be recorded and their location
noted on the map. Preliminary samples may be taken
and sent to the central laboratory for physical or chemical
examination, to check the judgment of the field man.

628. Collection of soil samples. — Samples of soil for
laboratory examination should be taken only after the
field man is thoroughly familiar with each type of soil
and can select a location that accurately represents the
average material of the type. Attention should be given
to the slope, drainage, abnormal modifications, and
manurial treatment of the soil at that point. Therefore,
in survey work samples are collected only in the latter
part of the season. One or more samples of each im-
portant type of soil are taken. The material, to the
amount of a quart, is preserved in cloth bags. Usually
each sample is divided into two parts, one representing

1382 SOILS: PROPERTIES AND MANAGEMENT

the soil and the other the subsoil. If there is a marked
change in appearance or texture in the subsoil, other divi-
sions of the sample may be made. Usually a composite
of a number of borings over an area of several square
rods, or even of several acres, may be necessary in order
to secure an accurate sample and to obtain enough ma-
terial. A composite of several representative borings
made over a considerable area gives a more nearly accu-
rate sample than is possible in a single boring. The
possibility of local variations is very great, and their
effect is reduced when composite sampling is done.

Each bag should bear a tag which is given a number
and on which is placed the name of the type, the location
of the sample in the section, and a brief description of the
material. ‘The same data are recorded in the field note-
book, which is finally preserved as a part of the permanent
office record of the survey. The description in the note-
book may be amplified more than is possible on the tag.
The location where each sample was taken should be
accurately marked on the field map by a number corre-
sponding to the number of the sample. Usually each
sample is given a number, and the parts are indicated by
a letter, proceeding from the surface downward. Where
the material is very wet and likely to become lumpy
when dry, it may be dried in a thin layer before being
finally bagged for shipping or preservation. Care should
be bestowed on every part of the operation of collection,
describing, numbering, tagging, tying, and shipping, in
order to insure accuracy and permanency of the record.

The soil auger is generally used in taking the sample
and in examining the soil section. The worm of the
auger is bored into the soil until it is filled. It is then
withdrawn and the soil is removed. The soil may be

THE SOIL SURVEY 733

collected on one or more squares of oilcloth, or it may be
placed directly in the appropriate bags. The worm of the
auger having been cleaned, it is inserted into the same
hole and advanced until it is again full, when it is with-
drawn and cleaned as before. This operation is repeated
until the desired depth is reached. Where the soil is a
very heavy clay, it may be advisable to only partially
fill the worm with soil. Where the soil is very dry and
pulverizes to a dust, it may slip off the worm, in which
case water may be added to make it adhere. The upper
part of the hole should be cleaned, and it may be slightly
enlarged so as to prevent contamination with the material
from the lower part of the section. Where there is rubbish
on the surface, this should be removed previous to begin-
ning the collection of the sample.

In very stony soil the auger is not suited to taking a
sample, either for examination or for record. In such
soil a shovel may be used, or the sample may be taken in
a road or some other cut by means of a geologist’s hammer.

The face of the section should be removed to a depth
of several inches, in order to eliminate weathered or con-
taminated material which may not be typical of the soil
section. Usually a difference in color and _ physical
properties of the soil indicates a modification of the typi-
cal material.

629. The accuracy and detail of the soil survey. — The
accuracy and detail of the soil survey depend on many
things. Assuming an adequate preparation on the part
of the field man, there are limitations in accuracy imposed
by the scale on which the map is made and the nature of
the soil. The smaller the scale of the map used in the
field, the less is the detail that may be represented. The
commonest scale employed is one inch to a mile. Some

734 SOILS: PROPERTIES AND MANAGEMENT

states use a larger scale, and in reconnolssance surveys
a smaller scale is used. While a large scale increases
the detail that may be represented, it also multiplies
the difficulties of making an accurate classification
because it increases the number of properties to be
observed.

The nature and occurrence of soils in the field involves
more variations than can be shown on the map. The
boundaries of soil types grade into one another, and it
may not be possible to mark the division within several
rods. Sometimes even a wider range occurs. The accu-
racy with which the boundary may be determined and
drawn depends very much on the way in which the two
adjacent soils have been formed. If they are very dif-
ferent, the boundary may be very distinct. Some types
of soil are characterized by local variations in sections,
or from point to point, which are on too small a scale to
be recognized as a type. Variations may be induced ina
type due to differences in topography, drainage, or culti-
vation. Where the properties do not bring about an
important change in the crop relations of the soil, they
may be ignored. Differences due to cultivation are
generally disregarded. The soil survey is made to cover
a period of years, and only permanent differences should
be considered.

Variations in the soil must be considered in relation to
the scale of the map. On a scale of one inch to a mile
the minimum area that can be shown is about ten acres.
Occasionally, where the difference in type constitutes a
striking contrast, the small area may be somewhat ex-
agegerated in size. An area of muck soil having high
value for the production of truck crops might be such an
exception.

THE SOIL SURVEY 735

630. The soil survey report. — The soil survey report
consists of two parts, the printed report and the map
showing the distribution of the soil types. The printed
report accompanying the soil map should be a brief but
comprehensive summary of the observations of the field
party in the areas surveyed. It should cover six types of
information: (1) location and boundaries of the area;
(2) general physical features; (3) climate; (4) agricul-
tural history and development; (5) description of the
soils; (6) suggestions for improvement in the manage-
ment of the soil that may have been determined by the
survey.

The description should point out the salient topographic
forms, the range in elevation, the nature and development
of the drainage, the transportation facilities, and the dis-
tribution of population and of farm areas. The discus-
sion of climate should note the monthly mean tempera-
ture and amount of precipitation; the character of the
extreme ranges in these; the direction of prevailing winds ;
and the océurrence of any special features, such as untimely
frosts, sleet and hail and windstorms, and the nature of
local variations in climate that may be due to the prox-
imity of bodies of water or topographic features. The
agricultural history should note the source and character
of the agricultural population, the chief products and any
changes that have occurred in their production, and the
present status of the area.

The description of the soils should be in two parts.
First, the grouping of the types into series and larger
divisions, with the geological and topographic relations
of these groups and a clear statement of the characteristic
properties of each group. Any important characteris-
tics that are common to two or more types or series, such

736 SOILS: PROPERTIES AND MANAGEMENT

as a deficiency in humus, lime, or drainage, should be
pointed out. Secondly, a detailed description of each
type following a uniform outline of properties, including
color, texture, depth, structural peculiarities, and minera-
logical and chemical features. Following this, attention
should be drawn to the location and extent of the type
in the area, and to its mode of origin, drainage conditions,
and economic relations, including the crop rotation and
extent of development.

In making suggestions for the treatment of the soils a
clear distinction should be drawn between methods of
soil management and improvement, and questions of farm
organization and management. The data collected by
the soil survey man will usually lead him to confine his
suggestions to the former group.

631. The soil map (Fig. 84).— The soil map is de-
signed primarily to show the geographic position and ex-
tent of each type of soil. Therefore an accurate base map,
showing important natural and cultural features as noted
above, is essential. The scale of the map must, be adapted
to the amount of detail to be shown. The commonest
scale in use in the United States is one inch to a mile. In
reconnoissance surveys a scale of one inch to six miles is
usually employed. The map is printed in colors or in
symbols representing the different types of soil. Symbols
may be added to the color to indicate further variation,
such as the presence of much stone, occurrence of ledge
rock, or a swampy condition. On the right-hand border
of the map a legend to the colors or symbols is given, and
they may be arranged in accordance with the scheme of
classifying the soils to show their relationship. On the
left-hand border, the character of the profile of each type
of soil is indicated by a series of legends.

oils, U. S. Dept. of Agriculture

.
74

AN Rae Cy = A SS q i j i | | E / . Vy =<
iq oe ~ N : = 0 7 ie ff 4 4 A é
: * eS 4 4

Volusia Volusia Dunkirk Huntington Dunkirk Muck.
silt loam goam gravelly foam loam clay

Fic. 84.— Part of the Madison County, N. Y., soil map showing the topography
and the relation of the various soil types to one another.

THE SOIL SURVEY 737

632. The extent of soil surveys in the United States. —
The detailed survey and mapping of soils by the Bureau
of Soils of the United States Department of Agricul-
ture, according to the scheme outlined above, has been in
progress since 1899. On January 1, 1915, about 330,000
square miles had been covered by detailed surveys and
435,000 square miles had been covered by reconnoissance
surveys. In addition, several miscellaneous surveys have
been made in outlying provinces such as Porto Rico,
Panama, Philippime Islands, and Alaska. The total num-
ber of soul types and series recognized is approximately
2000 and 600 respectively.

633. Surveys by state institutions. — Several states
are engaged in soil survey work, either independently or
In cooperation with the United States Bureau of Soils.
The states that have undertaken this work independently
have carried it out In the same general manner as in the
Federal survey. Some of the states that are working
independently have confined their investigations to recon-
noissance surveys on a large scale. Tennessee has pub-
lished a general report, with a map, on the soil areas of
the state, with special reference to their geological rela-
tions. Account is also taken of the texture, chemical
composition, and other properties. Iowa, Missouri, and
Illinois and Ohio! have published similar general reports
showing soil areas based chiefly on origin. Illinois, In-
diana, and New Jersey have also published detailed reports
on particular areas. In their work the principles of clas-
sification laid down above have been followed in a general
way, but with emphasis on certain selected properties.

1 Coffey, C. N., and Rice, T. D. Reconnoissance Soil Survey
of Ohio. U.S. D. A., Bur. Soils, Field Op., p. 184, 1912,
OB

738 SOILS: PROPERTIES AND MANAGEMENT

Tilinois has given special prominence to color, and, in ad-
dition to the general description of the soil types, includes
data derived from chemical analyses to show the store of
plant-food in the surface layers. The Indiana and Mis-
souri surveys have combined a purely geological scheme of
classification on the basis of origin, with certain properties
of practical importance, such as texture, color, and content
of humus, but without observing a systematic order.
The New Jersey survey includes rather full data on the
chemical composition of the soil types, in addition to the
usual discussion of their properties and relationships.

634. Surveys in other countries. —- Several countries
have undertaken some type of soil or agrogeological sur-
vey. These surveys, which have been undertaken in
Germany, France, Italy, Russia, Great Britain, and Japan,
have aimed at a broad practical classification of soils
based on their agricultural values and tillage properties.
Several thousand square miles have been covered by the
surveys in each of these countries. Colored charts are
published to accompany the descriptive reports. In these
surveys the classification is largely genetic, in combina~
tion with a consideration of the more evident physical
and chemical properties, which are recognized and grouped
in the field in much the same manner as in the American
surveys. The details, of course, are considerably differ-
ent in the reports of the different countries. In Germany
the maps are geological-agronomic in character; that is,
prominence is given to both the geological and the crop
relations of the soils. Their physical and chemical proper-
ties are pointed out and are used in the classification.
Similar methods are followed in France and Japan.

In England the areas of soil are determined, first, by
means of their texture; secondly, by means of their con-

THE SOIL SURVEY 739

tent of humus and lime carbonate, with which color and
drainage are associated; and thirdly, by means of the
geological formation and mode of origin. Fairly com-
plete mechanical and chemical analyses of representative
samples of the important types are included, and the rela-
tion of the soils to crops and farm practice is discussed at
some length. The grouping of the types into series,
groups, provinces, and the like, is not so distinct as in the
American surveys. That the fundamental importance
of the larger factors in classification are recognized is
shown in the discussion of the relation of precipitation
and temperature to the properties and agricultural uses
of the soil, in which the controlling influence of these
over large areas is pointed out.

635. Uses of the soil survey.— The soil survey is
useful in many ways, but it is not a final investigation.
It is to be regarded rather as a means of determining the
status of the soil and related conditions in the field.
These may throw light on many farm practices and lead
to their improvement. More frequently the soil survey
points to lines of further investigation that should be
carried out.

The uses of the soil survey may be conveniently divided
into two groups —its use to the individual, and its use
to the state. For the individual, the soil survey (1) points
out the character and location of the several types of soil
on his farm which may be correlated with particular
crops and farm practices; (2) shows him the relationship
of soils over wide areas, which may form a basis for the
adoption of new crops or new methods of soil manage-
ment; (3) provides a reliable central source of informa-
tion concerning soil conditions; (4) standardizes methods
of description and representation of soils; (5) reveals in

740 SOILS: PROPERTIES AND MANAGEMENT

many cases important problems of soil improvement that
need attention; (6) affords a guide in the exchange of
real estate and in the selection of land for particular pur-
poses. For the state the soil survey (1) shows its soil
resources; (2) by the collection of this data at a central
point, affords the basis for the correlation of all other
types of information, the character of which is affected
by the soil relations; (8) shows in many cases the occur-
rence and importance of large questions of soil improve-
ment, and may point out the need for further investiga-
tions; (4) gives a basis on which much of the results of
experiments, investigations, and observations on soil im-
provements, crop growth, and in many cases farm man-
agement, should be applied; (5) is a means of commu-
nication and mutual understanding between the state
institutions concerned with agricultural mformation and
the individual farmer; (6) by affording a basis of facts,
promotes sound commercial, social, and governmental
development.

The soil survey is essentially an inventory of the re-
sources in land and closely allied interests. It helps the
farmer to understand the situation of his farm and its
relations to other farms. It helps the state to get ac-
quainted with its domain, and promotes a better sense of
mutual understanding and helpfulness. The soil survey
in some form is an essential step in sound community
building, for the success of most interests — commercial,
social, and institutional —rests ultimately, to a large
extent, on the character and value of the soil.

AUTHORS’ INDEX

Adams, G. E., Salt as fertilizer, 544.
Ageton, C. U., Lime and magnesium,
538.
Aikman, C. M., Composition of manure,
595.
Production of manure, 597.
Alway, F. G., Composition of humus,
148.
Ames, J. W., Lime in soil, 378.
Soil investigation, 69, 70.

Ammon, G., Hygroscopicity, 203.

Appiani, G., Silt cylinder, 91.

Ashley, H. E, Colloidal clay, 161.
Estimation of colloids, 167.
Plasticity, 172.

Atkinson, A., Storage of moisture in

soil, 715
Atterberg, A., Classification of soil par-
ticles, 96.
Cohesion test, 176.
Measurement of cohesion, 181.
Mechanische Bodenanalyse, 84.
Plasticity, 171.
Silt cylinder, 91.

Baker, M. N., Sewage irrigation, 711.

Bancroft, W. D., Colloidal chemistry,
153.

Barakov, F., Carbon dioxide in soil, 409.

Baumann, A., Composition of humus,
133.

Beal, W. I., Absorptive capacity of
litter, 603.

Handling manure, 602.

Bennett, H. H., Classification of soils
in U.§., 724.

Bertrand, G., Manganese, 531.

Biltz, W., Soil solution, 345.

Bizzell, J. A., Composition of drainage
water, 372.

Legume cultures, 545.

Blanck, E., Law of mmimum, 554.

Bolly, H. L., Disease-producing organ-
ism, 426.

Boullanger, E., Sulfur, 524.

Boussingault, J. B., Snow and tempera-
ture, 306.

Bouyoucos, G. J., Bibliography of soil
heat, 289.

Manure and soil temperature, 316.

Radiation, 302, 304.

Soil temperature, 301.

Specific heat of soil, 295.

Texture and conductivity, 309, 312.
Bowie, A., Practical irrigation, 682.
Breazeale, J. F., Acid toxicity, 379.

Estimation of organic matter, 143.
Brenchley, W. E., Soil solution and

plant growth, 347.

Briggs, L. J., Analysis of soil, 143.
Capillary movement, 225.
Classification of particles, 96.
Hygroscopic and capillary water,

208.

Hygroscopic moisture, 206.

Mechanical soil analysis, 84.

Moisture equivalent, 220.

Soil solution in situ, 343.

Water requirements of plants, 245,

712.
Wilting point, 258.
Britton, W. E., Availability of ferti-
lizers, 510.

Bronet, G., Penetration of fertilizers,
354.

Brown, B. E., Carbonized materials, 141,
144.

Fertilizers and acidity, 381.

Brown, C. F., Alkali land reclamation,

399.

Brown, C. W., Bacteria in soil, 439.

Brown, P. E., Bacteria in soil, 432.

Bryan, H., Soil analysis, 93.

Buckingham, E., Capillary movement,

232.

Capillary water, 217.

Diffusion of gases in soil, 483.

Movement of water vapor in soil,

241.
Natural mulching, 277.

741

742

Buckman, H. O., Formation of residual
clay, 25.
Moisture control, 279.
Storage of soil moisture, 715.
Buddin, W., Partial sterilization of soil,
471,
Burmester, H , Temperature of soil, 321.
Burr, W. W., Storage of soil moisture,
715.

Caldwell, J. 8., Wilting point, 258.
Cameron, F. K., Estimation of organic
matter, 143.
Litmus paper test, 386.
Physical condition of soil, 181.
Soil solution, 346.
Solubility of phosphates, 358.
Test for cohesion, 176.
Campbell, H. W., Dry-farming, 712.
Carpenter, L. C., Measurement of
water, 707.
Cates, J. 8., Mulch and moisture, 280.
Cato, M. P., Land drainage, 629.
Chamberlin, T. C., Driftless area, 67.
Chamberlain, C. W., Molecular attrac-
tion, 206.
Chester, F. D., Bacteria in soil, 432.
Chilcott, E. C., Dry-farming, 712.
Christie, G. I., Soil survey of Iowa, 718.
Clark, F. W., Data of geochemistry, 5,
24, 72.
Composition of loess, 59.
Coffey, C. N., Reconnoissance survey of
Ohio, 737.
Classification of soils, 718.
Conn, H. J., Bacteria in soil, 431.
Coppenrath, E., Catalytic agents, 529.
Coville, F. W., Acid-tolerating plants,
384,
Coville, J. V., Acids in plants, 379.
Cox, H. R., Mulch and moisture, 280.
Craig, C. E., Weeds and crop growth,
281.
Crosby, W. O., Colors of soils, 76.
Cushman, A. 8., Air elutriator, 86.
Colloids, 161.
Plasticity, 172.
Czapek, J., Solvent action of roots, 406.
Czermak, W., Hygroscopic coefficient,
190.

Darwin, C., Earthworms, 19, 422.

Daubree, A., Solubility of orthoclase, 24.

Davis, N. B., Plasticity, 172.

Davis, R. O. E., Electrical bridge, 728.
Salts and capillarity, 229.

AUTHORS’ INDEX

Dehérain, P. P., Lime and phosphorus,
536.
Demelon, A., Sulphur, 525.
Penetration of fertilizers, 354.
Digby, K., Mineral manure, 490.
Diller, G. S., Composition of limestone
soil, 66.
Residual clay, 27.
Dobeneck, A. F. von, Absorption, 367.
Hygroscopicity, 203, 207.
Dorsch, F., Availability of fertilizers, 510.
Dorsey, C. W., Alkali land reclamation,
399.
Composition of alkali, 393.
Duchacek, F., Bacteria in soil, 437.
Fermentation and phosphates, 520.
Dugardin, M., Sulfur, 525.
Dupré, H. A., Capillary movement, 231.
Dyer, B., Citric acid method soil an-
alysis, 336.
Plant food in Broadbalk field, 337.

Ebermayer, HE , Temperature of soil, 322.
Ehrenberg, P., Effect of soil antiseptics,
470,
Estimation of colloids, 168.
HKichhorn, H., Absorption by chabazite,
356.
Elliott, C. G., Land drainage, 627, 629.
659.
Size of tile, 651.
Ernest, A., Carbon dioxide production,

139, 408.
Etcheverry, B. A., Linings for canals,
694.

Failyer, G. H., Absorption by soils, 351.

Composition of soil, 70.

Minerals in soil separates, 101.
Faure, L., Land drainage, 627.
Feilitzen, H. von, Sulfur, 525.

Fippin, E. O., Causes for granulation, 188.

Classification of soils, 718.

Fletcher, C. C., Soil analysis, 93.

Flugel, M., Law of minimum, 554.

Forbes, R. H., Irrigation, 686.

Fortier, §., Application of
water, 695.

Mulches under irrigation, 705.

Orchard irrigation, 682.

Small water supply, 682.

Frank, B., Effect of heat on soluble
matter, 466.
Fraps, M . §., Availability of phosphates,

irrigation

Fertilizers, 546,

AUTHORS’ INDEX

Frear, W., Losses of manure, 605.

Fred, E. B., Effect of soil antiseptics,
468.

French, H. F., Drainage, 629.

Freundlich, H., Kapillar chemie, 153.

Friedlander, K., Soil antiseptics, 470.

Gaither, E. W., Lime in soil, 378.
Soil investigation, 69, 70.
Gallagher, F. E., Absorption of gases,
367.
Cohesion tests, 176.
Physical condition of soil, 181.

Temperature and hygroscopicity,
208.

Gardner, F. D., Fertilizers and acidity,
381.

Gedroiz, K. K., Phosphate fertilizer, 519.
Geikie, A., Geology, text of, 40.
Georgeson, C. C., Manure and soil tem-
perature, 316.
Gerlach, U., Composition of drainage
water, 350.
Drainage water, 370.
Gieseker, L. F., Storage of soil moisture,

715.
Gilbert, J. H., Composition of drainage
water, 240.

Gile, P. P., Lime and magnesium, 538.
Nitrogen in plant nutrition, 491.
Girard, A., Soil antiseptics, 465.
Goddard, L. H., Cost of drainage, 655.
Goessman, C. A., Poultry manure, 589.
Golding, J., Partial sterilization, 474.
Grandeau, L., Estimation of humus, 144.
Greig-Smith, R., Effect of partial ster-
ilization, 472.

Haberlandt, H., Cohesion test, 175.
Heat and germination, 290.

Hall, A. D., Accumulation of soil nitro-

gen, 463.

Classification of soil particles, 96.
Classification of soils, 718.
Composition of crops, 418.
Composition of drainage water, 369.
Composition of manure gases, 594.
Crop adaptation and texture, 105.
Denitrification, 457.
Fermentation of manure, 591.
Losses of manures, 600.
Losses of nitrates, 454.
Losses of nitrogen, 500.
Lysimeter records, 266.
Manures, 579.
Mechanical analysis, 103.

148

Hall, A. D., Nitrification, 453.
Nitrogen fertilizers, 547.
Residual effect of manures, 614.
Soil separates, 102.
Soil solution and plant growth, 347.
The Soil, 11.
Halligan, J. E., Composition of rotted
manure, 596.
Fertilizers, 546.
Hart, R. A., Alkali land reclamation,
399.
Handling manure, 602.
Sulfur as a fertilizer, 526.
Hartwell, B. L., Acidity test, 387.
Fermentation and phosphates, 520.
Hasenbaumer, J., Catalytic agents, 529.
Colloidal chemistry, 153.
Hassler, C., Colloid chemistry, 153.
Headden, W. P., Nitrates in alkali soil,
292.
Heinrich, R., Hygroscopie coefficient,
257.
Heinze, B., Soil antiseptics, 470.
Hellriegel, H., Water requirement of
plants, 246, 249, 250.
Henneberg, W., Absorbed bases, 354.
Absorption, 353.
Henry, W. A., Production of manure, 588.
Hess, E. H., Lime, 541.
Hess, R. H., Social aspect of irrigation,
g

691.
Hilgard, EH. W., 79, 82.
Absorption and temperature, 367.
Alkali land reclamation, 399.
Churn elutriator, $8.
Composition of alkali, 393.
Dilution of plant food in soil, 332.
Estimation of humus, 144, 147.
Retentive power of soil for water, 221.
Roots and humus, 127.
Soil analysis, 96.
Soil and climate, 62, 72.
Soils of arid and humid regions, 71.

Temperature and hygroscopicity,
208.

Vegetation and soil classification,
720.

Hills, J. L., Commercial fertilizers, 562.
Hiltner, L., Effect of soil antiseptics, 469.
Hoffman, C., Fermentation and phos-
phates, 520.
Hopkins, C. G., Library system of soil
naming, 726.
Manure and the rotation, 616.
Nitrogen storage by legumes, 621.
Soil survey of Illinois, 719.

144.

Houston, H. A., Estimation of humus,
142.
Hunt, T. F., Manure and the rotation,
616.
Nitrogen fertilizers, 547.
Hutchinson, H. B., Nitrogen assimila-
tion, 495.
Organic matter in soil, 136.
Partial sterilization of soil, 470.

Jenkins, EK. H., Availability of fertilizers,
510.
Commercial fertilizers, 564.
Jodidi, 8. L., Nitrogen compounds, 133.
Johuson, 8. W., Availability of fertilizers,
510.
Composition of soil air, 477.
Johnston, J., Early drainage in America,
630.
Jones, C. H., Commercial fertilizer, 562.

Kellerman, K. F., Lime, 537.

Nitro-cultures, 462.

Litmus test, 386.

Kelley, W. P., Ammonia as plant food,
495,

Magnesium and nitrates, 536.
Kellner, O., Ammonia as plant-food, 495.
Kelly, M. P., Manganese, 530.

Kerr, W. C., Composition of marl, 38.

Kiesselbach, T. A., Water requirement
of corn, 248.

King, F. H., Absorption and produc-
tivity, 368.

Aspirator, 124.

Capillary and ground water, 214.

Capillary movement, 225.

Drainage and soil temperature, 314.

Drainage and free water, 237.

Effect of barometric pressure, 234.

Effective diameter of soil particles,

123.
Effective surface of soil particles,
125.

Irrigation, 682.

Land drainage, 627.

Movement of ground water, 235.

Pore space in soil, 116, 117.

Slope and soil temperature, 319.

Spring plowing, 284.

Surface tension and temperature, 227.

Temperature and hygroscopicity,

208.

Water requirement of plants, 247.

Wind breaks and moisture, 285.
Kinnison, C. 8., Plasticity, 171.

AUTHORS’ INDEX

Kinsley, A. F., Bacteria in soil, 432.
Klippart, J. H., Land drainage, 627,
Knisely, A. L., Acid soil, 383.
Koch, A., Theory as to effect of anti-
septics, 468.
Konig, J., Catalytic agents, 529.
Colloid chemistry, 153.
Kostytscheff, M. P., Roots and humus,
127.
Kroéber, E., Bacteria in soil, 438.
Fermentation and phosphates, 520.
Kummel, A. B., Soil and geological
surveys, 719.

Lang, C., Radiation, 302.
Lapham, J. E., Classification of soils of
United States, 724.
Lapham, M. H., Classification of soils
of United States, 724.
Capillary movement, 225.
Lawes, J. B., Composition of drainage
water, 240.
Nitrogen in plant nutrition, 491.
Leather, J. W., Water requirements of
plants, 247.
LeClere, J. A., Acid toxicity, 379.
Liebenberg, R. von, Specific heat of
soils, 294.
Liebig, J. J. von, Composition of plants,
491.
Law of minimum, 553.
Solvent action of roots, 405.
Lint, H. C., Sulfur and soil acidity, 382.
Lipman, ©. B., Bacteria in arid soils, 73.
Lipman, J. G., Availability of fertilizers,
510.
Fermentation of manure, 591.
Green manures, 619.
Loew, O., Lime and magnesia, 538.
Lébnis, F., Bacteria in soil, 438.
Loughridge, R. H., Crop tolerance to
alkali, 395.
Distribution of irrigation water in
soil, 704.
Hygroscopic water, 204.
Soil separates, 102.
Lynde, C. J., Capillary movement, 231.
Lyon, T. L., Composition of drainage
water, 372.
Legume cultures, 545,
Lysimeter tanks, 241.

McBride, F. W., Estimation of humus,
142, 144.

McCall, A. G., Solution of soil in situ,
344,

AUTHORS INDEX

McCaughey, W. J., Color of soil, 77.

Soil-forming minerals, 100.
MacDonald, W., Dry-farming, 712.
McLane, J. W., Moisture equivalent,

220.

Soil solution in situ, 343.

McLaughlin, W. W., Capillary move-
ment, 224.

Movement of irrigation water, 704.

Marbut, C. F., Classification of soils of
United States, 718, 724,

Soils of United States, 34.

Marchal, E., Ammonification, 447.
Mares, M. N., Sulfur, 525.

Mayer, A., Optimum moisture, 263.
Mayo, U.§8., Bacteria in soil, 432.
Mazé, P., Law of minimum, 554.
Mead, E., Extent of irrigation, 685.

Irrigation institutions, 682.

Legal status of irrigation, 691.

Lining for canals, 694.

Preparation for irrigation, 682.
Mellen, C. R., Drainage of Johnston

farm, 630.
Merrill, G. P., Color of soil, 77.

Residual clay, granite, 27.

Rock weathering, 13, 26, 62.

Weathering of gneiss, 66.

Zeolitis, 357.

Merrill, L. A., Irrigation of crops, 682.

Merzbacher, G., Origin of loess, 60.

Miles, M., Drainage in Europe, 629.

Miller, N. H. J., Nitrogen assimilation,
495.

Organic matter in soil, 136.

Miner, H. L., Commercial fertilizers, 562.
Mitscherlich, A. E., Estimation of
colloids, 168.

Hygroscopicity, 208.

Law of Minimum, 5538.

Water and plant growth, 253.
Molisch, H., Enzymes of roots, 407.
Montemartini, L., Catalysis, 530.
Montgomery, E. G., Water require-

ments, 245, 248, 249.

Water requirement of corn, 251.

Mooers, G. A., Soil survey of Tennessee,
719.

Mulder, T. J., Organic matter of soil, 131.

Miller, R., Solubility of minerals, 24.°

Newell, F. H., Irrigation, 682.

Niklas, H., Colloid chemistry, 153.

Norton, J. H., Composition of surface
water, 378.

Noyes, A. A., Properties of colloids, 153.

745

Oberlin, C., Soil antisepties, 465.

Olin, W. H., American irrigation, 682.
Osborne, T. B., Beaker method of
mechanical analysis, 96.
Classification of soil particles, 90,

Paddock, W., Irrigation of fruit, 682.

Pagnoul, M., Effects of carbon bisul-
fide, 466.

Parks, J., Drainage and soil tempera-
ture, 314.

Patten, A. J., Bacteria in soil, 439.

Patten, H. E., Absorption of gases, 367.
Absorption by soils, 351.

Heat of condensation, 209.

Heat transfer, 309, 313.

Specific heat of soil, 295.

Temperature and hygroscopicity,

208.

Patterson, H. J., Lime, 541.

Peake, W. A., Estimation of organic
matter, 143.

Pember, F. R., Fermentation and phos-
phates, 520.

Penny, C. L., Clover as green manure,
621.

Green manures, 619.

Penrose, R. A. F., Composition of resid-

ual soil, 33.

Peters, E., Absorbed bases, 354.,
Absorption of potassium, 350.

Peterson, W. H., Sulphur as fertilizer,

526.
Petit, A., Temperature of soil, 300.
Pettit, J. H., Soil survey of Illinois,
719.

Pfaundler, L., Specific heat of soil, 204.

Pfeiffer, T., Effect of soil antisepties, 470.
Law of minimum, 554.

Carbon dioxide as soil solvent, 409.
Pick, H., Estimation of colloids, 168.
Pickel, G. M., Composition of muck,

37.

Piper, C. V., Green manures, 619.

Pitra, J., Bacteria in soil, 437.
Fermentation and phosphates, 520.

Plummer, J. K., Acid materials, 376.

Potts, E., Texture and conductivity, 309.

Pranke, Ei. J., Cyanamid, 503.

Prianischnikov, D., Availability of phos-

phorus, 518, 521, 535,

Puchner, H., Cohesion test, 176.
Composition of soil separates, 102.
Measurement of cohesion, 178.

Pugh, E., Nitrogen in plant nutrition,

491.

746

Rafter, G. W., Sewage irrigation, 711.
Ramann, E., Carbon dioxide in soil air,
480.

Colloid chemistry, 153.

Reed, H. 8., Oxidation by roots, 407.
Toxic material in soils, 136.

Reid, F. R., Catalysis, 529.

Rice, T. D., Reconnoissance, 737.

Richthofen, F., Character of loess, 59.

Roberts, I. P., Losses of manure, 599.
Production of manure, 587.

Robinson, F. R., Lime, 537.

Robinson, F. W., Root nodules and
nitrogen storage, 621.

Robinson, T. R., Litmus test, 386.

Robinson, W. O., Color of soils, 77.
Manganese, 531.

Rodewald, H., Estimation of colloids,

168.
Rostworowski, §., Absorption by per-
mutite, 357.

Russell, E. J., Plant food elements, 3.
Classification of particles, 96.
Classification of soils, 718.
Crop adaptation and texture, 105.
Mechanical soil analysis, 103.
Nitrogen fertilizers, 547.
Partial sterilization of soils, 470.
Sewage sick soils, 474.

Russell, J. C., Subaérial deposits, 62.

Sachs, J., Solvent action of roots, 406.

Sackett, W. G., Ammonification, 446.
Availability of fertilizers, 511.

Salisbury, R. D., Driftless area, 67.
Glacial geology, 47.

Sanborn, J. W., Roots of crops, 81.

Sargent, C. L., Acidity tests, 387.

Saussure, T. de, Composition of plants,

490.
Schantz, H. L., Water requirements,
245, 712,
Wilting point, 258.
Schlicter, C. 8., Effective diameter of
particles, 123.

Schine, E., Elutriator, 87.

Schreiner, O., Absorption by soil, 351.
Carbonized material in soil, 141, 144.
Composition of humus, 134, 186.
Organic substances in soil, 132.
Oxidation by roots, 407.

Schiibler, G., Cohesion test, 175.

Schucht, F., Mechanische Bodenunter-

suchung, 84.
Schulze, B., Temperature of soil, 321.
Schulze, F., Water extract of soil, 341.

AUTHORS INDEX

Schutt, M <A, Losses of manure, 583
599, 600.
Seelhorst, C. von, Water requirements,
251, 255.
Sheppard, J. H., Roots of crops, 82.
Sherman, C. W., Soil survey of Indiana,
719.
Shorey, E. C., Creatinine, 497.
Organic substances in soil, 132,
Shutt, F. T., Nitrogen storage by leg~
umes, 621.
Simmermacher, W., Lime and phos-
phates, 536.
Skinner, J. J., Creatinine, 497.
Organic matter in soil, 136.
Smith, C. D., Root nodules and nitrogen,
storage, 621.
Smith, R. HE , Bacteria in frozen soil, 433,
Snyder, H., Ash of humus, 145.
Complete solution of soil, 330.
Composition of humus, 149.
Production of humus, 140.
Spillman, W. J., green manures, 619.
Stevenson, W. H., Soil survey of Iowa,
718.
Stewart, J. B., Moisture control, 285,
Capillary movement, 225,
Stohman, F., Absorption, 353, 354.
Stoklasa, J., Bacteria in soil, 437, 439.
Carbon dioxide production, 139.
Carbon dioxide production in soil,
408.
Carbon dioxide in goil air, 479, 482.
Fermentation and phosphates, 520.
Storer, F. H., Farm manure, 578.
Green manure, 619.
Humus and capillarity, 219.
Poultry manure, 588.
Stérmer, K., Effect of soil antiseptics,
469.
Stover, A. P., Carey Act, 688,
Stremme, H., Estimation of colloids,
167.
Sullivan, M. X., Catalysis, 529.
Manganese, 531.
Swezey, G. D., Temperature of soil, 321,
485.

Teel, R. P., Losses of irrigation water,
694.
Ten Eyck, A. M., Roots of plants, 81.
Thaer, W., Properties of colloids, 153.
Thorne, C. E., Application of manure,
607.
Cement versus dirt floors, 604.
Effect of food on manure, 582,

AUTHORS INDEX

Thorne, C. E., Farm manure, 581
Losses of manure, 599.
Manure and the rotation, 616.
Production of manure, 587.
Reinforcing manure, value, 610.
Value of manure, 590, 601.
Trowbridge, A. C., Classification of sedi-
ments, 31.
Truog, E. A., Sulfide test for soil acidity,
387.
Tularkov, N., Classification of soils, 718.
Tull, Jethro, Effects of tillage, 490.

Ulrich, R., Specific heat of soil, 295.
Underwood, T. M., Soil solution and
plant growth, 347.

Vail, C. E., Composition of humus, 148.
Van Bemmelen, J. M , Adsorption, 359.
Colloids, 161.
Colloidal humus, 365.
Colloidal material, 346.
Color of soil, 77
Composition of humus, 133.
Estimation of colloids, 167.
Soil solution, 345.
Van Slyke, L. L., A general fertilizer,
571.
Composition of manure, 584.
Fertilizers, 546.
Fertilizer mixtures, 565.
Production of manure, 587.
Van Suchtelen, F. H. H., Soil solution in
stiu, 344.
Veitch, F. P., Complete solution of soil,
330.

Composition of soil, 66.
Test for acidity, 390.
Voelcker, J. A., Composition of rotted
manure, 596,
Manure, 579.
Soil acidity, 383.
Von Engeln, O. D., Glaciation and agri-
culture, 70, 71.
Voorhees, E. B., Availability of fer-
tilizers, 510.
Poultry manure, 588.
Waggaman, W. H., Absorption by soil,
351.

Wagner, F., Conductivity in soil, 310.
Manure and soil temperature, 316.
Texture and conductivity, 309.

Wagner, H., Law of minimum, 553.

T47

Wahnschaffe, F., Silt cylinder, 92.
Warington, R., Causes of granulation,
186.
Colloids, 161.
Composition of crops, 418.
Composition of drainage water, 240.
Denitrification, 456.
Estimation of organic matter, 143.
Evaporation losses, 271.
Lime and granulation, 194.
Nitrification, 453.
Snow and soil temperature, 306.
Warren, G. M., Marsh land drainage,
627
Waters, H. J., Lime, 541.
Watson, G. C., Production of manure,
587.
Way, J. T., Absorption by soil, 355.
Colloids, 161.
Weir, W. W., Soil acidity, 383.
Test for carbonates, 388.
Welitschkowsky, D. von, Temperature
and movement of water, 234.
Wheeler, H. J., Acid-tolerating plants,
38.
Acidity tests, 387.
Forms of lime, 542.
Plants injured by acidity, 385.
Salt as a fertilizer, 544.
Wheeler, W. P., Poultry manure, 582.
Whipper, O. B., Irrigation of fruit, 682.
Whitbeck, R. H., Glaciated and residual
soils, 70.
Whitney, M., Apparent specific gravity,
114,

Soil classes, 104.
Soil solution, 346.
Specific gravity of soil, 118.
Whitson, A. R., Soil acidity, 383.
Test for carbonates, 388.
Wickson, J. A., Irrigation of fruit, 682.
Widtsoe, J. A., Amount of water to
apply, 710.
Capillary movement, 224.
Dry-farming, 712.
Dry matter and water, 254.
Irrigation water and yield, 708.
Movements of irrigation water, 704.
Principles of irrigation, 682.
Storage of water in soil, 709.
Water requirement of plants, 248,
251.
Wiegner, G., Absorption by permutite,
357.

Wagner, P., Availability of fertilizers, | Wiley, H. W., Complete solution of soil,
328.

510.

T48 AUTHORS INDEX

Wiley, H. W., Estimation of organic | Wollny, E., Capillarity and temperature,
matter, 143, 144. 214

Mechanical soil analysis, $4, 92. Color and temperature, 302.
Soil analysis, 338. Composition of soil air, 139.
Willcox, O. W., Soil survey of Iowa, 718. Effect of earthworms, 422.
Williams, H. F., Soil-forming minerals, Gravitational movement of water,
100. 234.
Williams, M. B., Irrigation in humid Optimum moisture, 262.
regions, 690. Roots and humus, 127.
Wilson, H. M., Irrigation engineering, Slope and temperature, 319.
692. Water requirements of plants, 246.
Wing, H. H., Losses of manure, 599. Water and soil temperature, 315.
Production of manure, 587. Woodward, 8S. M, Land drainage by
Winton, A. L., Commercial fertilizers, pumping, 627.
564.

Wolff, E., Composition of manure, 595. | Yoder, P. A., Centrifugal elutriator, 89.
Wollny, E., Capillary movement, 226,
228, 230. Zsigmondy, R., Colloid chemistry, 153.

INDEX

Absolute pireniic gravity of minerals, | Acidity, effect on phosphate fertilizer,
. 519.

of soil, 118.
of soil particles, 113.
Absorption by the soil, 349.
causes, 355.
formation of insoluble substances,
358.
influence of chabazite, 356.
influence of colloids, 165, 359, 360.
influence of organic matter, 150, 365.
influence of silicates, 363.
influence of zeolites, 355.
influence on soil analysis, 340.
insolubility of absorbed substances,
354, 358.
of ammonia, 366.
of carbon dioxide, 366.
of gases, 366.
of heat, 300.
of nitrogen and oxygen, 367.
of phosphoric acid, 357.
relation to temperature, 367.
relation to drainage, 368.
relation to productiveness, 368.
selective, 362.
time necessary, 353.
Absorptive power of different plants,
414,
Absorbed bases, solubility of, 354.
Abundance of common minerais, 11.
of plant-food elements, 5.
Acetic acid secreted by roots, 408.
Acid, a flocculating agent, 159.
in plant juices, 336.
rocks, 7.
soils, 375.
soils caused by ammonium sulfate,
499,
test for carbonates, 388.
Acidity and climate, 382.
and colloids, 165.
and forests, 380.
and sulfur, 382.
and plants indicating, 382.

relation to bacteria, 436.
relation to fertilizers, 381.
quantitative determinations, 389.
tests for, 386.

Acid phosphate, 514.
for reinforcing manure, 610.

Acids formed from fermenting manure,

593.
in plant juices, 379.
secreted by plant roots, 408.

Acme harrow, 677.

Adobe, solian soil, 47, 59,
described, 61.
wind origin, 16.

Afolian soils, deposition of, 58.
adobe, 61.
composition of, 60, 62.
distribution, 61.
loess, 59.
sand dunes, 63.

Aération and denitrification, 456,
and toxic materials, 133.
effect of drainage on, 631.
effect on nitrification, 452.
influence on decay, 129.
promoted by soil organisms, 422.

Aérobic bacteria, 433.
bacteria and decay, 444.
fermentation of manure, 592.

Agencies of rock decay, 14.

Agricere in soil, 275, 472.

Air of the soil, 475.
analyses, 478, 139.
carbon dioxide, 139, 478.
composition of, 477,
control of, 486.
effect of organic matter on, 139, 476.
effect of soil moisture on, 476.
effect of texture, 475.
effect of tillage, 487.
function of, 480.
movement of, 483.
volume, 475,

749

750

Air-slaked lime, 539.
Alge, aid to nitrogen fixation, 464.
Alinit, nitro-culture, 463.
Alkali in soils, 392.
accumulation of, 397.
and irrigation, 397.
and the mulch, 282.
block alkali, 392.
composition, 393.
correction, 399.
control, 402.
effect on plants, 394.
effect of method of irrigation, '706.
formation of, 724.
outfit for testing, 728.
salts in soil, 391.
Alkali land, drainage of, 659.
Alkali lands, management of, 399.
Alkali lands of foreign countries, 398.
Alkali spots, 402.
Alluvial soils, described, 39.
distribution of, 41.
humus and nitrogen in, 148.
Alternaria, disease organism, 426.
Alternate cropping, 714.
Aluminum, 6.
Aluminum phosphate, 337.
Aluminum in soil separates, 102.
Amendments of the soil, 534.
calcium sulfate, 542.
calcium carbonate, 540.
caustic lime, 539.
common salt, 543.
effect on nitrification, 536.
effect on tilth and bacteria, 534.
effect on toxic materials, 537.
liberation of plant-food, 535.
lime and granulation, 1938.
muck, 545.
Amid nitrogen, plant-food, 497.
Ammonia, absorption of, 353, 366.
as plant-food, 494.
from plant decay, 139.
salts and acidity, 381.
test for acidity, 387.
Ammonification in soil, 446.
Ammonification, effect of partial ster-
ilization, 470.
Ammonium sulfate, as fertilizer, 499.
Amount of water to use in irrigation, 710.
Anaérobie bacteria, 433.
Anaérobic bacteria and putrefaction,
44.4, .
Anaérobic fermentation of manure, 593.
Analysis, mechanical, of soil, 97, 104,
107.

INDEX

Analysis, mineralogical, 100.
of adobe, 62.
of air, 139, 478.
of alkali, 3938.
of arid and humid soils, 72, 147.
of coastal plain soils, 70, 66.
of crops, 419.
of cumulose soil, 37.
of cyanamid, 503.
of drainage water, 351, 371, 374, 500.
of gases from manure, 594.
of glacial soils, 68, 70.
of granite and residual soil, 27.
of humus, 149.
of humus ash, 145.
of limestone and residual clay, 27, 33,
68.
of litter, 580.
of loess, 60.
of manure, 581, 582, 588, 584, 588,
595.
of marl, 38.
of residual soils, 66, 68, 70.
of soils, humus, 147, 148.
of soil, organic matter, 146.
of soil separates, 101, 102..
of water extract, 348.
Animals, capacity to produce manure,
587.
effect on granulation, 192.
effect on composition of manure,
581, 582, 584.
soil-forming agent, 18.
Antiseptics, treatment of soil with, 465.
Apatite, mineral, 9.
as a fertilizer, 512.
Apophyllite, solubility, 339.
Apparent specific gravity, 113.
Application of water, time, 709.
Arginine, plant-food, 497.
Arid and humid soils, 71.
composition of, 72.
properties of, 72, 82.
soil particles, composition of, 100,
101.
Arrangement of soil particles, 108.
Artificial mulch, 273.
Ash composition of humus, 145.
Ash constituents of plants, 416.
Aspergillus niger in soil, 427.
Atmospheric pressure affects soil air,
484,
Attraction of soil particles, 206.
Auger, for soil examination, 727, 732.
Augite, 9.
Availability of organic fertilizer, 510.

INDEX

Availability of plant-food and bacteria,
4.28

Availability of soil water, diagram, 262.
Azotobacter bacteria, 464.

Bacillus, denitrificans, alpha and beta,
456.
mesentericus, reducing organism, 455.
mycoides, reducing organism, 455.
pestifer, reducing organism, 455.
radicicola, 459, 545.
radvobacter, 464.
ramosus, reducing organism, 455.
subtilis, reducing organism, 455.
vulgaius, reducing organism, 455.
Back furrow, 671.
Bacteria and ammonification, 446.
and plant decay, 129.
and root nodules, 458.
carbon dioxide production, 408.
conditions for growth, 433.
distribution, 429.
functions, 436.
in frozen soil, 431.
influence of sulfur on, 525.
influence on organic matter, 435.
inoculation with, 460.
nitrate reduction, 455.
number in soil, 4380.
nitrogen supply, 428.
non-symbiotic, 460.
solvent action of, 439.
Bacteria in soil, 427, 428.
Bacterial action, effect on phosphates,
520.
Bacteroids, 460.
Bactervum ellenbachensis, 463.
Balanced fertilizer, 551.
Barnyards, covered for manure, 605.
Barometric pressure and drainage, 234.
Basalt, 8.
Bases absorbed, solubility of, 354.
Bases, absorbed by colloids, 165.
Bases and toxicity, 379.
Bases in plant ash, 378.
Bases, removed in drainage, 378.
Basic rocks, 7.
Basic slag phosphate, 513.
Basic soil, effect on phosphates, 519.
Bacillus amylobacter, 440.
Bedding, absorptive capacity, 603.
Biotite, 9.
Biotite, solubility, 330.
Black alkali, 392.
Blood, dried, as fertilizer, 507.
Bones as fertilizer, 511.

Tol

Bone phosphate, 511.

Bone tankage, 512.

Brands of fertilizer, 555.
Broadeasting fertilizer, 570.

Bromberg, composition of drainage
water, 370.

Bureau of soils, classification of alkali,
396.

Calcium, 4, 6.

Calcium carbonate, 7, 10.

Calcium carbonate in soil, 333.

Calcium combinations, 539.

Calcium compounds, root action on, 406.
Calcium cyanamid, 502.

Calcium hydrate in fertilizer, 566.
Calcium in soil separates, 101.

Calcium loss in drainage, 372.

Calcium nitrate, 505.

Calcium phosphate, effect of bacteria on,

439,

Calcium salts, as amendments, effects,
534.

Calcium sulfate to reinforce manure,
609.

Calculation of air space of soils, 238, 477.
of apparent specific gravity, 113.
of free water, 238.
of number of soil particles, 118.
of pore space, 116.
of surface of soil particles, 120.
of wilting point, 260.
Canals for drainage, construction, 635.
Canals for irrigation, 693.
Capillarity and texture, 214.
Capillarity carries nitrates to surface,
454.
Capillary movement, 221,
and alkali formation, 298.
in wet and dry soil, 225.
influenced by thickness of film, 2238.
influenced by surface tension, 227.
influenced by texture, 229.
influenced by structure, 232,
intercepted by green manure, 624.
Capillary water, 201, 210.
Capillary water, amount, 213.
and organic matter, 218.
and structure, 217.
and surface tension, 213.
and texture, 214.
estimation of, 219.
factors affecting amount, 213.
form of surface, 212.
relation to plant, 261.
Capillarity and ground water, 214,

752

Carbohydrates and nitrogen fixation,
464.
Carbohydrates as source of energy, 456.
Carbohydrates in soil, 127.
Carbon, 4, 6.
Carbon dioxide, absorption of, 366.
as an influence on climate, 49.
and root action, 406, 408.
end product of decay, 188.
functions in soil, 481.
in soil air, 21, 139, 410, 478.
in atmosphere, 139.
product of decay, 130.
production by bacteria, 408.
use in soil analysis, 339.
Carbon disulfide as soil antiseptic, 465.
Carbon disulfide from plant decay, 140.
Carbonate of lime, 540.
Carbonates of lime, effect on nitrates,
536.
Carbonates, acid test for, 388.
Carbonates in earth’s crust, 11.
Carbonates, effect on soil, 482.
Carbonation as weathering agent, 19.
Carbonized material in soil, 140, 144.
Carriers, in fertilizers, 555.
Catalytic action of soil, 528.
Catalytic fertilizer, 528.
Catch crops, and nitrate conservation,
455,
Caustic lime, 539.
Cement pit storage of manure, 604.
Centrifugal soil analysis, 93.
Cephalothecium, disease organism in
soil, 426.
Cereals, absorptive power, 414.
Chabazite, 356.
Checking of losses by evaporation, 272.
of losses by leaching, 267.
Chemical agents of rock decay, 14.
Chemical analysis of soil, 327.
complete, 328.
extraction with acids, 329.
extraction with water, 340.
Chemical changes due to heat, 291.
Chemical composition of soils.
Analysis.
Chili saltpeter, £98.
Chloride of potash, 523.
Chlorine, 6.
Chlorine as fertilizer, 544.
Chlorite, 9.
Chloroform as soil antiseptic, 473.
Cistern storage of manure, 605.
Citric acid method, 336.
Class, the soil, defined, 103.

See

INDEX

Class, the soil, in classification, 722.
Classification of rocks, 6.
Classification of soil material, geological,
31.
Classification of soil particles, 95.
Classification of soil, factors used, 720.
Classification of soil, outline of, 721.
Clostridium pastortanum, 463.
Clay, character of separate, 98.
Clay, colloidal, 161.
Climate and acidity, 382.
Climate and efficiency of fertilizer, 568.
Climate, influence on soil, 65.
Climate as factor in soil classification,
724.
Clouds, effect on radiation, 306.
Clod crushers, 678.
Coefficient of cohesion, 175.
Coefficients of drainage, 651, 652.
Coefficients of expansion of rocks, 17.
Coefficient of friction, 229.
Coefficient of hygroscopicity, 208.
Coefficient of plasticity, 171.
Coefficient of wilting, 257, 258.
Cohesion defined, 173.
Cohesion, determination, 174.
Cohesion, control, 183, 197.
Cohesion, factors affecting, 178.
Cold and heat as weathering agents, 16.
Collectotrichum, disease organism in
soil, 426.
Colloids in the soil, 153.
Colloids, absorption by, 359.
and acids, 165.
chemistry, 153.
effect of roots on, 411.
estimation of, 166.
factors affecting, 165.
organic, 140.
preparation of, 163.
Colloidal humus, 133.
materials, 346.
matter, relation to phosphates, 517.
phases, 158.
state, 154.
Colluvial soils described, 38.
Color of soil, 73.
Color of soils, due to weathering, 20.
due to humus, 75.
due to iron, 75.
agricultural significance, 78.
and temperature, 301.
Color of arid and humid soils, 72.
of glacial soil, 53.
of marine soil, 44.
of residual soil, 33.

INDEX

Colters, types, 672.
Commercial value of fertilizer, 560.
Complete solution of soil, 328.
Composition, of arid and humid soils,
72.
of animal manures, 584.
of alkali, 391.
of cumulose soil, 37.
of crops, 419.
of drainage water, 369.
of gases from manure, 594.
of glacial soil, 52.
of glacial and residual clay, 68, 69.
of humus, 131, 140.
of horse and cow manure, 581.
of loess, 60.
of marl, 38.
of manure litter, 580.
of plants, 127, 418.
of residual and marine soil, 66.
of rotted manure, 596.
of residual soil, 33.
of soil in general, 2.
of soil-forming minerals, 9.
of soil due to weathering, 29,
of soil separates, 101.
of subsoil, 332.
of soil air, 139, 477.
of surface water, 373.
of yard manure, 578.
Composting manure, 613.
Concentration and growth, 417.
Concrete tile, 641.
Condensation, heat of, 209.
Conduction of heat in soil, 307.
Conservation of moisture in irrigation,
710.
Convection in soil, 307.
Coprolites as fertilizer, 512.
Cornell tanks, composition of drainage
water, 372.
Cornell University, bacteria in soil, 429.
effect of magnesium, 539.
nitrates in soil, 451.
production of manure, 587.
soil inoculation, 462.
Cottonseed meal, as fertilizer, 507.
Cover crops and green manure, 620.
Covered barnyards for manure, 605.
Cow manure, composition, 584.
Creatinine, plant-food, 497.
Cropping, alternate in dry-farming, 714.
Cropping, effect in soil ventilation, 488.
Crops, composition of, 419.
drought-resistant, 715.
effect of alkali on, 394.

758

Crops, efficiency of fertilizer, 568.
feeding power, 415.
for green manure, 622.
suited to basic soils, 385.
suited to acid soil, 384.
Crumb structure, 109.
Crushers and packers as soil pulverizer,
678.
Cultivators, types, 673.
Cultures, mixed nitrogen-fixing, 464.
Cultures of nitrogen-fixing bacteria, 458,
461.
Cumulose soils, 35.
Cyanamid, nitrogen fertilizer, 502.
Cyanamid in fertilizer mixtures, 566.
Cytase, enzyme, 440.

Dam, canvas, 701.
Damping-off fungi in soil, 425.
Dead furrow, objectionable, 671.
‘*Dead”’ furrows, for drainage, 635.
Decay of green manure in soil, 622.
of organic matter in soil, 128.
organic, and soil temperature, 315.
and putrefaction, 443.
of rocks, law of, 24.
Decomposition of organic matter, 440.
Decomposition of rock, 14.
Deep-tilling plow, 667.
Deflocculation of sodium nitrate, 499.
Delta defined, 41.
Denitrification, 456.
Denudation, rate of, in U. S., 14.
Denudation by Mississippi River, 15.
Deoxidation as weathering agent, 20,
Department of Agriculture, U. 8. Nitro-
culture, 462,
Depth of moisture storage in soil, 710.
for plowing, 669.
of soil in relation to humus, 148,
of soil mulch, 278.
of tile drains, 646.
Detention of plant-food in soil, 332.
Dewey system of classification, 726.
Diabase, 6.
Diffusion of gases in soil, 483.
Dihydroxystearic acid, 376.
Diorite, 6,
Disease of plants and moisture, 253.
Diseases of plants, effect of lime, 536.
Disease organisms in soil 426.
Disease resistance, effect of phosphorus,
550.
effect of nitrogen, 549.
Disintegration of rock, 14.
Disk harrow, single and double, 676.

(i:

Disk plow, 666.
Disking to hold moisture, 714.
Ditching machines, 649.
Dolomite, 6, 9.
Drag as soil pulverizer, 680.
Drain till, quality, 640.
Drainage and absorption, 368.
Drainage and denitrification, 456.
coefficient, 651.
effects on soil, 630.
effect on soil ventilation, 477, 488.
effect on soil bacteria, 434.
extent of need, 628.
efficiency of fertilizer, 568.
formation of humus, 152.
history of development, 629.
of irrigated and alkali land, 659.
of land, indications of need, 627.
methods, 634,
muck and peat soil, 658.
promoted by soil organisms, 422.
reclamation of alkali land, 400.
relation to green manure practice,
624.
relation to colloids, 166.
run-off checked, 269.
systems, arrangement, 643.
toxic materials eliminated, 137.
use of explosives, 661.
tile drains, 639.
vertical, 660,
Drainage water at Bromberg, 370.
Drainage water, composition, 369, 351.
Dramage water, relation of phosphates
and carbon dioxide, 482.
Drains, protection of joints, 642.
Dried blood, 507.
Drift defined, 52.
Drought-resistant crops, 715.
Dry-farming practices, 713.
principles, 712.
drought-resistant crops, 715.
soils best suited for, 716.
extent, 717.
Drying and wetting, effect on granula-
tion, 187.
Dust mulch, 272.
Dust mulch under irrigation, 705, 710.
Duty of water in irrigation, 708.
Dynamite, drainage by means of, 661.

Karthworms, action on soil, 19.
Karthworms and productiveness, 422.
Effective diameter of soil particles, 122.
Effective surface of soil, 125.

Effects of organic matter on soil, 150.

INDEX

Electrical production of nitrogen fer
tilizer, 502.
Elements of plant-food, 3.
Enzymotic action of bacteria, 129.
Enzymes, effect on plant-food, 438.
Enzymes in roots, 407,
Epidote, 9.
Erosion, agencies causing, 14.
effect of drainage, 633.
in ditches, limits of grade, 636,
ice as agency, 16.
in irrigation canals, 694.
rate of, in U.S, 14.
wind action, 15.
Eiskers, 50.
Evaporation and alkali, 282.
and temperature, 314.
and wind movement, 285.
at Rothamsted, 271.
from plants, 270.
prevented by, 272.
rainfall lost by, 271.
Excreta from animals, 577.
Exhaustion of soil, 419.
Expansion of minerals by heat, 16.
Explosives, drainage by means of, 661.

Factors for plant growth, 3.

Factory-mixed fertilizer, 563.

Fall plowing, relation to dry-farming,

713.

Fall and spring plowing, 283.

Farm manures, 577.

Farm manure, waste, 597.

Fats in soil, 127.

Fats, effect on capillarity, 211.

Feeding power of plants, 414.

Feldspar, as potash fertilizer, 524.

Feldspar in soil separates, 101.

Fermentation, effect on phosphates, 520.

Fermentation of manure, 591.

Ferric phosphate availability, 337.

Fertilizers, 489.

Fertilizers and acidity, 381.
amounts to use, 572.
application of, 570.
brands, 555.
catalytic, 5380.
commercial value, 560
commercial, extent of use, 492.
effect on toxic material, 137.
factors in efficiency, 568.
for special crops, 571.
grades of, 562.
home mixing, 563.
incompatible material, 565.

INDEX

Fertilizers, inspection, 556.
mixed, 561.
nitrogen, 493.
penetration into soil, 354.
practice, 546.
potash, 522.
systems of, 573.
sulfur, 524.
trade value, 559.
Fertilizing crops, 571.
Filler in fertilizer, 556.
Filler in fertilizer, muck, 545.
Film water, 206, 210.
Fineness in phosphates, 513.
Finger lakes, 50.
Fire-fanging, manure, 596.
First bottom land, 42.
Fish as fertilizer, 508.
Floats to reinforce manure, 610.
Flocculation, 159.
Flooding, as means of soil infection, 425,
Flooding, irrigation by, 699.
Flume, for measurement of water, 707.
Flushing, correction for alkali, 401.
Food of animal, effect on manure, 582.
Food elements, sources, 4.
Food material in crops, 418.
Food of plants, absorption of, 404,
Forces of weathering, 14.
Formie acid secreted by roots, 408.
Forests and acidity, 380.
Forest trees, mycorrhize of, 428.
Free water in soul, 236.
Free water, bad effects, 262.
Freezing, effect on granulation, 189.
relation to soil colloids, 166.
Fresh versus leached manure, 601.
Friction and available water, 256.
Friction coefficient, 229.
Frost as soil pulverizer, 680.
Frost as weathering agent, 17.
Frozen soil, bacteria in, 431.
Fruiting effect of nitrogen, 548.
Fruits, feeding power, 416.
Functions of fertilizers, elements, 547,
549, 551.
of soil to plant, 1.
of water to plant, 243.
Fungi and fire-fanging of manure, 596.
Fungi in soil, 423.
Furrow, back, productive, 671.
correct position, 668.
dead, objectionable, 671.
depth and width, 669.
use in irrigation, 702.
Fusarium as a disease organism, 426.

T55

Gabbro, 6.

Gases, from manure, 594.

Gel colloids, 159.

Geological classification of soil material,

31.

Germination, effect of heat on, 290.

Glacial drift, 47.

Glacial ice, as erosive agent, 16.

Glacial lakes, 55.

Glacial soil, composition, 52,

Glacial soil, humus in, 54.

Glacial soils, 47.

Glauconite, solubility, 339.

Gneiss, 6.

Grade of drains, 645.

Grain, effect of phosphorus, 550
effect of potassium, 551.
effect of nitrogen, 548.

Granite, 6, &
weathering of, 27.

Granular soil, 111.

Granulation, 185.

Granulation, cause of, 187.
defined, 170.
effect of plow, 195.
effect on cohesion, 179.

Granulation of soil and optimum mois-

ture, 263.
effect of drainage, 630.
modified by tillage, 663.

Granulabacter, group of bacteria, 464.

Granules in soul, 109,

Grass crops, feeding power, 415.

Gravel, 99.

Gravitational water, 201, 233.

Gravitational water, injurious to crops,

261.
calculation of, 237.
control of, drainage, 627.
movement, factors affecting,
235.
movement of, 233.
study of, 238.

Green manure, 151.

Green manure, and acidity, 379.
conditions for plowing under, 624.
constituents added, 621.
crops, 622.
decay in soil, 622.
denitrification, 547.
effects, 619.
lime relations, 625.
relation to the rotation, 625.

Ground limestone, 540. -

Ground water and capillarity, 214.

Group, the, in soil classification, 723.

233,

756

Growing season, effect of drainage, 631.

Growth, effects of nitrogen, 547.

Guano, as fertilizer, 507.

Guarantee, fertilizer, 558.

Gypsum, 9, 542.

Gypsum, correction for alkali, 400.

Gypsum, lime fertilizer, 539.

Gypsum, solvent action of roots on,
406.

Gypsum to reinforce manure, 609.

Handling manure, 602.
Hardpan, alkali, effect on drainage, 659
Harrow as cultivator, 676.
Heat, absorption of, 300.
and cold, mechanical action, 16.
chemical and physical changes due
to, 291.
condensation, 209.
convection in soil, 307.
functions of, in soil, 289.
effect on soil, 466.
unit defined, 314.
sources in soil, 292.
specific heat of soil, 294.
Head of water, defined, 706.
Head of water for irrigation, 702.
Heaving of soil indicates wetness, 628,

632.

Heiden’s formula for manure production,
588.

Helminthosporium, disease organism,

Hematite, 9.
Hematite, hydration of, 21.
Herring-bone system of drainage, 645.
High-grade fertilizer, 562.
Hillside plow, 670.
Histidine, plant-food, 497.
Home-mixing fertilizer, 563.
Home-rmixing fertilizer, method, 567.
Hoof meal as fertilizer, 507.
Hornblende, 9.
Hornblende in soil separates, 101.
Horse manure, composition, 584.
Humid and arid soils, 71.
Humid climates, irrigation in, 689.
soils, composition of, 72.
soils, organic matter of, 146, 147.
Humidity, effect on hygroscopicity, 207.
Humus, absorption by, 365.
Humus ash composition, 145.
and conductivity, 310.
and capillarity, 219.
and efficiency of fertilizer, 569.
and roots of plants, 127.

INDEX

Humus and run-off, 269.
and specific heat, 297.
as plant-food, 495.
composition of, 131.
content of soils, 147.
effect of drainage on formation, 632,
effect on hygroscopicity, 204.
effect on granulation, 190.
effect on cohesion, 170.
effects on soil, 150.
estimation of, 142, 144.
in glacial soil, 54.
nature of, in soil, 180.
specific gravity of, 113.
Hummus, defined, 130.
Hydration as weathering agent, 20.
Hydrochloric acid used in soil survey,
728.
Hydrochloric acid solution of soil, 329.
Hydrochloric acid test for carbonates,
388.
Hydrogen, 4, 6.
Hydrogen, from plant decay, 140.
Hygroscopic coefficient, 257.
Hygroscopic moisture, 201, 202.
Hygroscopic moisture and plasticity,
171.
relation to colloids, 168.
relation to plants, 256.
Hygroscopicity, determination of, 208.

Ice, as erosive agent, 16.
Ice-formed soils, 52.
Ice sheet, 47.
Igneous soil-forming rocks, 6.
Implements, tillage, 664.
Infection by soil fungi, 425.
Inoculation of soil for legumes, 460.
Inorganic colloids, 158, 162.
Insects in soil, 428.
Inspection of fertilizers, 556.
Interception losses in forests, 287.
Todine in ash of sea weed, 404.
Iron, 4, 6.
Iron a catalytic fertilizer, 529.
Tron as a soil color, 75.
Tron phosphate available, 337.
Tron in soil separates, 102.
Irrigation, amount of water applied, 708.
amount of water to apply, 710.
and alkali, 397.
application of water and yield, 208,
canals, 693.
canals, linings, 694.
conditions that warrant, 683.
development in the United States, 686.

INDEX.

Irrigation, erosion in canals, 694.
flooding, 699.
furrow, 702.
history, 685.
in humid regions, 689.
legal, economic and social effects,

land, drainage of, 659.

land, extent of, 685.

methods of water supply, 688.
methods of applying water, 695.
movement of water, 704.
preparation of land, 695.
relation to rainfall, 682.

setting of fruit, 709.

sewage, 711.

sources of water, 693.

sub, 696.

theory and practice, 682.

units of water measurement, 706.

Jointer, 672.
Joints, protection in tile drains, 642.

Kainit, potassium salt, 522.
Kainit to reinforce manure, 609.
Kames, 50.

Kaolin, specific heat, 299.
Kaolinite, 9.

Lacustrine soils, 56.
Lagoons, 40.
Land drainage, indications of need, 627.
Land plaster, 542.
Land plaster to reinforce manure, 609.
Leaching of manure, 599.
Leather meal as fertilizer, 507.
Legumes and symbiosis, 458.
Legumes, feeding power, 415.
Legume manure, nitrogen added by,
621.
Leguminous green manures, 623.
Lento-capillarity, 257.
Lento-capillarity, defined, 224.
Leucite, solubility, 339.
Level tillage, 286.
Lime as amendment, effects, 534.
Lime carbonate, 333.
Lime, a catalytic fertilizer, 528.
effect on bacteria, 432, 436.
effect on nitrates, 536.
effect on toxic substances, 536.
effect on efficiency of fertilizer, 569.
effect on sanitation of soil, 138.
effect on granulation, 198.
fertilizer mixtures of, 566.

157

Lime, flocculating agent, 160.
forms of, 539.
formation of humus, 152.
green manure and, 625.
loss in drainage, 372.
manure and, 612.
nitrogen, fixations, 464.
relation to available phosphorus,
517.
relation to soil colloids, 166.
relation to soil diseases, 426.
run-off relationships, 269.
soil separate content, 101.
soil and subsoil content, 378.
Lime-magnesia ratio, 538.
Lime phosphate, effect of bacteria on,
439.
Limestone, 6, 8.
Limestone for soil, 539.
Limestone, residual soil from, 38.
Limestone soil, not rich in lime, 28.
Limestone, weathering of, 27.
Limewater test for acidity, 390.
Limonite, 9.
Linseed meal as fertilizer, 507.
Liquid manure compared with solid, 585.
Lister, seeder cultivator, 678.
Listing, effect on soil ventilation, 487.
Lysimeter described, 239.
Litmus test for acidity, 386.
Litter, absorptive capacity, 603.
Litter in manure, 578, 580.
Loam, defined, 104.
Loess, Atolian soil, 58.
description and composition, 59,
wind origin, 15.
soil distribution of, 51.
Loss of manure in handling, 583, 600.
Low-grade fertilizer, 562.

Machinery, tillage, 664.
Macroérganisms in soil, 421.
Macrosporium, disease organism in soil,
426
Magnesium, 4, 6
Magnesium carbonate, and nitrates, 536.
catalytic fertilizer, 530.
in soil separates, 102.
Manure, 489.
Manure, amount produced by animals,
587.
commercial value, 589.
composition, causes of variation, 580.
composition of gases from, 594.
composition of rotted, 596.
composting, 613,

158

Manure, covered yards and pits, 605
denitrification of, 457.
destruction of organic matter in
feed, 597.
effect. of food of animal, 582.
effect of handling on composition,
588, 600.
effects on the soil, 618.
effect on soul ventilation, 488.
farm, 597.
farm corrects alkali, 403.
fermentation, 591.
frequent small applications, 607.
fresh versus leached, 601.
fire-fanging, 596.
functions, 489.
green, 619.
green and lime, 625.
Heidens formula for production, 588.
lime and, 612.
muck and, 6138.
needs and plant food deficiency, 334.
organic and nitrification, 450.
plowing under, 608.
reinforcement, 609.
residual effects, 614.
rotation relation, 615.
small versus large applications, 608.
spreader, 608,
storage in open piles, 606.
yard composition, 578.
Marble, 6, 48.
Marine soil compositions, 66.
Marl, 539.
Marl, composition, 38.
found under muck, 37.
Marsh mud composition, 37.
Maturity, effect of nitrogen, 548.
Maturity, effect of phosphorus, 550.
Maximum water content, 262.
Measurement of water in irrigation, 706.
Meat, as fertilizer, 507.
Mechanical analysis, 84.
Mechanical analysis of samples, 728.
Meeker harrow, 677.
Metamorphic soil-forming rocks, 6.
Methane in soil air, 140.
Mica in soil separates, 101.
Microcline, solubility, 338.
Microdrganisms, 424.
Microérganisms, effect of sulfur, 525.
Mineral acid, method of analysis, 338.
colloids, 162,
definition of, 7.
matter, decomposition by bacteria,

INDEX

Mineral acid, nutrients of feed in ma.
nure, 597.
phosphates as fertilizer, 512.
Minerals, absorbed by plants, 416.
law of decay, 24.
relative abundance, 11.
rock-forming, 8.
soil-forming, 8.
Mineralogical character of soil separates,
99.
Miner’s inch of water, defined, 706.
Minimum, law of, 551.
Mississippi River, denudation by, 15.
Mixed fertilizers, 561.
Modification of structure, 187,
Module, for measuring water, 709.
Moisture of the soil, 198.
conductivity relations, 310.
capacity of soul, effect of drainage,
631,
capillary form, 210.
conservation in irrigation, 710.
content, effect on soil air, 476.
control of, 264.
effect on bacteria, 434.
effect on cohesion, 179.
effect of movement on soil air, 484.
equivalents of soil, 220.
forms of, 200.
gravitational, 233.
hygroscopic, 202.
maximum content, 221.
methods of stating, 198.
relation to colloids, 165.
relation to decay, 129.
relation to plowing, 196.
used by plant, 261.
uses to plant, 243.
Moldboard plows, 667.
Moldboard, shapes for best
196.
Molds in soil, ammonify proteins, 427.
Mole drainage, 638.
Moraine, terminal, 50.
Movement, of soil air, 483.
heat, 307.
heat factors affecting, 308, 310.
moisture, capillary, 221.
moisture, factors affecting capillarity,
223.
moisture, gravitational, 233.
moisture, thermal, 241.
water, affected by friction, 223.
water, affected by texture, 229.
water, affected by structure, 232.
Muck, defined, 36.

result,

INDEX

Muck, as fertilizer, 545.
and manure, 613.
and moisture control, 272.
nitrogen compounds in, 133.
specific growth of, 113.
Mulch and the control of alkali, 402.
Mulch, depth of, 278.
depth in irrigation farming, 705, 715.
dry-farming, use in, 714.
effectiveness in arid regions, 277.
effect other than on moisture, 280.
factors of effectiveness, 275.
formation of, 276.
functions of, 274.
kinds of, 278.
management of, 278.
of soul, 233.
résumé of control, 278.
usefulness of, 282.
water saved by, 279.
Mulching grain crops, 282.
Muriatic acid used in soil survey, 728.
Muscovite, 9.
Muscovite, solubility, 339.
Mycorrhiza, relation to fertility, 423.
Mycotrophic plants, 423.

Natural mulch, 273.
Negative acidity, 376.
Nematodes in soil, 424.
Nephelite, solubility, 339.
Nitrate assimilation by bacteria, 456.
Nitrate of calcium, fertilizer, 505.
Nitrate of soda, as plant food, 498.
Nitrate, reduction of, 455.
Nitrates, conserved by green manure,
620.
constituent of alkali, 392.
effect of lime on, 536.
in soil, effect of absorption on, 341.
loss from soil, 454.
product of decay processes, 130.
returned to surface, 454,
Nitric acid method of analysis, 338.
Nitric acid solution of soil, 329.
Nitrification in soil, 447.
effect of aeration, 452.
effect of antiseptics, 465.
effect of carbon bisulfide, 466.
effect of depth, 453.
effect of organic matter, 449.
effect of sod, 452.
temperature for, 435.
Nitrobacter in soil, 448.
Nitrogen, 4, 12.
absorption of, 367.

T59

Nitrogen, added to soil by legumes, 621.
available from atmosphere, 501.
chemical estimation, 329.
cycle, 443.
effects on plant growth, 547.
effect on toxic material, 137.
fertilizers, 493.
fertilizer from the air, 501.
fertilizers, organic, 507.
fixation, 457.
fixation and mycorrhiza, 428.
fixation by molds, 427.
fixation, non-symbiotic, 463.
fixing organisms, 463.
forms in soil, 493.
forms used by plants, 448, 494.
found in animal manures, 597.
in humus, 147,
loss in drainage, 372.
loss from Rothamsted soil, 500.
necessary to plants, early studies,

491,
supply and bacteria, 428.
utilized by bacteria, 459.

“Nitrogen ”’ culture, 461.

Nitrosococcus in. soil, 448.

Nitrosomonas in. soil, 448.

Nodules on plant roots, 458.

Number of soil particles, 118.

Nutrient salts, absorption of, by plants,

404,
absorption by soils, 349.
selective absorption, 362.

Odometer used in soil survey, 727.
Oils, effect on capillarity, 214.
Oils in soil, 128.
Oily material, and capillary movement,
226, 228.
Oily materials in soil, 275.
Olivine, 9.
Open ditches, construction, 635.
Open-ditch drainage, objections, 634.
Optimum water content, 262.
Orchards, manure in, 617.
Organic colloids, 157, 161.
Organic fertilizer availability, 510.
Organic constituents of soils, 2, 12, 128,
131.
Organic decay and soil temperature, 315.
Organic matier, 12.
absorption by, 365.
and capillary water, 218.
catalytic action, 529.
composition in soil, 135.
effect on granulation, 190.

760

Organic matter, effect on nitrification,

449,

effect on phosphates, 520.

effects on soil, 150.

effect on soil bacteria, 435.

efficiency of fertilizer, 569.

estimation of, 141.

losses in digesting food, 597.

maintenance in soil, 151.

relation to air in soil, 476.

soil content, 126.

soils of U. 8. content, 146.

source of carbon dioxide, 479.

specific heat relations, 297.
Organic nitrogen, plant food, 497.
Organisms in soil, 421.

effect of heat on, 289.

effect of drainage on, 632.

macro- in soil, 421.

micro- in soil, 424.
Orthoclase mineral, 9.

solubility of, 338.

weathering of, 22.
Osmotic activity of plant roots, 412.
Outlets to the drains, 656.
Oxbows, 40.
Oxidation and soil fertility, 137.
Oxidation as weathering agent, 19.
Oxidation of sulfur in soil, 525.
Oxygen, 4, 6.
Oxygen, absorption of, 367.
Oxygen, effect on soil bacteria, 433.
Oxygen in soil, air functions, 480.
Oxygen in soil, relation to carbon dioxide,

479,

Packers and crushers, 678.
Packer, sub-surface, 679.
Partial solution of soil, 329, 331.
Particles, in soil, chemical composition,
101.
in soil, mineral composition, 99.
in soil, physical character, 98.
of soil, classification, 95.
of soil, number, 118.
surface exposed in soil by, 120.
Peas, materials used as food, 496.
Peat, defined, 36.
Peat, nitrogen compounds in, 133.
Peat, specific gravity of, 113.
Penicillium glaucum in soil, 427.
Percolation of water, 233.
effect of pressure on, 233.

effect of texture and structure on,

235.
effect on air movement, 483.

INDEX

Percolation of water, losses from, 265.
losses from, control, 267.
objection to, in irrigation, 704.
Rothamsted figures on, 266.

Peridotite, 8.

Permutite, absorption by, 357.

Peruvian guano, 508.

Phillipsite, solubility, 339.

Phosphate, acid, to reinforce manure, 610,
bone, early manufacture, 492.
calcium, root action on, 406.
effect of bacteria on, 4389, 437.
fertilizers, 511.
fertilizers, relative availability, 516.
insoluble, 358.
of iron and aluminum, 337.
row rock, to reinforce manure, 610.
relation to carbon dioxide, 482,
reverted, 515.

Phosporic acid, absorption of, 352, 357,

Phosphorite as fertilizer, 512.

Phosphorus in sol, 4, 6.
effect on toxic material, 137.
effects on plant growth, 549.
in soil separates, 101.

Physical agencies of weathering, 14.
absorption, 359.
changes due to heat, 291.
character of soil separates, 98.
effect of organic matter, 150.

Piedmont soils, 34.

Plagioclase, 9.

Plane table for soil survey, 727.

Planker, as soil pulverizer, 680.

Plant food, elements of, in soil, 3.

Plant food, deficiencies and manurial

needs, 334.

distribution in liquid and solid ma-~
nure, 586.

elements, abundance of, 5.

elements, essential, 417,

elements, sources of, 4.

appearing in manure, 597.

in soil minerals, 101.

in plants, 418.

limiting elements, 4.

proportion of feed in manure, 581.

relation to bacteria, 428.

relation to dilution, 332.

shown by analysis, 330.

supplied in sewage, 711.

Plant growth, effects of nitrogen, 547,
factors for, 3.
functions of water, 243.
and the soil solution, 347.
and strength of soil solution, 417.

INDEX

Plant nutrients, absorption of, 404.
Plant roots in soil, 424.
Plant roots, solvent action, 405.
Plants, absorptive power, 412.
acid in juices, 379.
available water for, 261.
composition of, 128.
effect of alkali on, 394.
effect on availability of phosphorus,
518.
effect on granulation, 192.
indicating an acid soil, 382.
requirements for growth, 3.
soil-forming agents, 18.
soil shelters, 287.
suceession on soil, 1.
utilize simple and complex material,
131.
water requirements of, 244.
Plasticity, causes of, 172.
Plasticity, defined, 170.
Plow attachments, 671.
effect on granulation, 195.
hillside, 670.
as tillage implement, 665.
subsoil, 672.
sale of, 670.
Plowing, correct position of furrow, 668.
depth, 669.
fall, relation to dry-farming, 7138.
under manure, 608.
Poncelet’s formula, 652.
Pore space in spherical particles, 109.
in soil, 115.
in soil, calculation, 116.
Porosity and diffusion of gases, 483.
Positive acidity, 375.
Potassium in soils, 4, 6.
absorption of, 358.
chloride, 523.
effects on plant growth, 551.
effect on toxic material, 137.
fertilizers, 522.
nitrate test for acidity, 388, 389.
soil separates content, 101.
solubility, 339.
sulfate, 523.
Poultry manure, composition, 582, 588.
Pressure, atmospheric, affects soil air,
484,

Properties of soil separates, 98, 99, 101.

Protein decay, 447. .

Proteins in soil, 127.

Protozoa, relation to soil productive-
ness, 471.

Province, the, in soil classification, 723.

761

Puddled soil, 110.

Pulverizing action of plow, 195, 665.
Putrefaction and decay, 443.
Putrefaction, products of, 445.

Quartz, mineral, 9.

Quartz, specific heat, 299.

Quartz, in soil separates, 99.

Quartzite, 6.

Quicklime, 539.

Quicksand, management in drainage,
660.

Radiation, effect of moisture, 305.

Radiation from soil, 302.

Rainfall, distribution in world, 683, 686.
effect on soil ventilation, 483.
relation to irrigation, 682.

Raw rock phosphate, 512.

Reclamation service of the United

States, 688, 690.

Reconnoissance soil surveys, 737.

Reduction of nitrates, 455.

Reinforcement of manure, 609.

Residual effects of manure, 614.

Residual soils, colors, 33.
characters of, 32.
composition of, 66.
defined, 31.
distribution of, 34.
origin of, 31.

Resinous material in soil, 275.

Reverted phosphate, 515.

Ridge tillage versus level, 287.

Riparian rights, modified under irriga~

tion, 691.

Ripening and moisture, 253.

Rodents in soil, 421.

Rock flour, 68.

Rock rot, 68.

Rock-forming minerals, 8.

Rock, definition of, 7.

Rocks, acid, 7.
basic, 7.
classification of, 6.
coefficients of expansion, 17.
decay agencies of, 14.
law of decay, 24.
soil-forming, 6.
solubility in sodium carbonate, 26.
weathering of, 13.

Rolling and moisture control, 284.

Roller as soil pulverizer, 679.

Root crops, feeding power, 415.

Root-hairs and food absorption, 404.

Root-hairs, relation to soil particles, 405,

762

Root development, effect of drainage,
631.
Root excretions, 136.
Roots, effect on colloids, 411.
effect of phosphorus, 550
effect on soil ventilation, 488.
entrance Into tile, 642.
extent of surface, 412.
nodules on, 408.
of plants, distribution, 81.
of plants and humus, 127.
of plants under dry-farming, 717.
of plants in soil, 424.
oxidizing enzymes in, 407.
solvent action, 405.
Rotation and green manure, 625.
of crops and maintenance of humus,
152.
of crops and manure, 615.
of crops, remedy for soil diseases,

425,
Rothamsted, composition of drainage
water, 370.

drain gauges, 266.
losses of nitrogen, 500.
Run-off, losses from, 265.

Salt, as amendment, 543.

Sampling soil in the field, 731.

Sand, 99.

Sand dunes, 63.

Sandstone, 6, 8.

Sanitation of soil, effect of drainage, 633.

Sanitation of soil and toxic material, 137.

Saturated soil, 201.

Sawdust as litter, 603.

Schist, 6.

Scraping, correction for alkali, 401.

Second-food of water, defined, 706.

Sediment in water, effect on erosion, 637.

Sedimentary, soil-forming rocks, 6.

Seeding machines as cultivators, 678.

Seepage, extent and prevention in irri-
gation, 694.

Selective absorption, 362.

Selective absorption by colloids, 165.

Separates, mineralogical character, 99.

Separates, physical character of, 98.

Separates of soil, 84.

Series, the, in soil classification, 722.

Series of soil, named, 725.

Serpentine, 9.

Sewage irrigation, 711.

Sewage-sick soil, 474.

Shading and moisture loss, 287.

Shale, 6.

INDEX

Sheep manure, composition, 584.
Shelters and moisture control, 285,
Siderite, 9
Silica in soil separates, 102.
Silicates, absorption by, 360.
Silicates, influence on absorption, 357.
Silicon, 6.
Silt, character of separate, 98.
Silt-basins, in drains, 656.
Silvinit, potassium salt, 523.
Single-grain structure, 110.
Size of colloidal particles, 154.
Size of soil particles, 95.
Size of the drains, 650, 654.
Slate, 6.
Slag phosphate, 513.
Slope and temperature, 317.
Slime molds 1n soil, 425.
Snow, effect on soil temperature, 306.
Sod, effect on nitrification, 452.
Sodium, 6.
Sodium compounds, as fertilizer, 544.
Sodium nitrate, as plant food, 498.
Sol, colloidal condition, 159.
Soldate, module, 707.
Solid manure compared with liquid, 585.
Solubility of rocks in sodium carbonate,
26.
of soil and texture, 331.
of the soil, 327.
Solution and soil formation, 21.
Solution in soil and plant growth, 417.
Solvent action of roots, 405,
Solvents of the soil, 328.
Soil amendments, 534.
best suited for dry-farming, 716.
classification, factors used, 720.
composition, general, 2.
defined, 1.
organic matter, 126.
organisms, 421.
sampling in the field, 731.
solution in situ, 342.
solution and plant growth, 347.
survey, accuracy and detail, 733.
survey, equipment for, 726.
surveys, extent, 737.
survey map, 736.
survey report, 735.
survey, its uses, 739.
survey, principles of classification,

type, name, 725.
Soil and subsoil, arid and humid regions,
82.
Soil and subsoil, defined, 79.

INDEX

Soil-forming minerals, 8.
Soil-forming rocks, 6.
Soil mulch versus dust mulch, 275.
Sour soils, 375.
Sources of plant food, 419.
Specific gravity, absolute, 112.
apparent, 113.
of minerals, 112.
of soil separates, 113.
Specific heat of soil, 294.
Spray system of irrigation, 695.
Spring, early plowing, 283.
Stall manure versus yard manure, 601.
Starch, effect of potassium, 551.
Stassfurt salts, 522.
Storage of water in soil, 279.
Straw, effect of nitrogen, 548,
effect of phosphorus, 550.
relation to denitrification, 456.
Stone drains, 638.
Stone mulch, 273.
Structure and capillary mévement, 232.
and capillary water, 217.
and conductivity, 310.
defined, 108, 170.
effect on diffusion of gases, 483.

effect on gravitational movement, 235.

modified by tillage, 663.
relation to air in soil, 476.
temperature relations, 304.
Subirrigation, 696.
Subsoil and soil defined, 79.
Subsoil, composition of, 332.
Subsoil plow, 672.

Subsoiling, relation to dry-farming, 713.

Substitution of bases, 355.
Substitution of elements by plant, 417.
Subsurface packer, 679.
Subsurface packing, 714.
Sulfates as fertilizer, 526.
Sulfate of ammonia as fertilizer, 499.
Sulfate of potash, 523.
Sulfur, 4, 6.
Sulfur and acidity, 382.
Sulfur as fertilizer, 524.
Sulfur bacteria in soil, 439.
Sulfur dioxide, from plant decay, 140.
Sulfur, free, as fertilizer, 524.
Sulfuric acid solution of soil, 329.
Superphosphate fertilizer, 514.
Surface of roots, 412.
Surface of soil particles, 120.
Surface tension, 211.
and capillary movement, 227.
and capillary water, 213.
Surface water, composition of, 373.

168

Swine manure, composition, 584.

Symbiosis, nitrogen fixation through,
457.

Syenite, 6, 8.

Systems of fertilization, 573.

Tale, 9.
Tankage as fertilizer, 507.
Temperature changes, affect soil air, 484.
Temperature in fermenting manure, 593.
Temperature of soil and air, 485.
annual, 321.
annual range, 322.
control, 325.
daily range, 324.
effect of drainage, 631.
effect of slope, 317.
effect of snow, 306.
evaporation influence, 314.
factors affecting, 293.
influence on absorption, 367.
influence on bacterial activity, 435.
influence on efficiency of fertilizer,
568.
influence decay, 129.
influence on hygroscopicity, 207.
influence on movement of water, 234.
influence on organic decay, 315.
Tenacity of soil, 174.
Terrace, defined, 41.
Texture, adaptation of crops to, 105.
defined, 83.
effect on capillary movement, 214,
229.
effect on cohesion, 179.
effect on conductivity, 308.
effect on hygroscopicity, 204.
relation to air mn soil, 475,
relation to gravitational movement,
235.
relation to soil classification, 722.
relation to solubility of soil, 331.
relation to wilting point, 260.
rock, and weathering, 28.
influence on absorption, 355.
influence on. diffusion of gases, 483.
temperature relations, 304,

Thermal movement of water, 241.

Tile, quality, 640.

Tile drains, 639.

carrying capacity, 651.
cost, 654.

dangers from roots, 642.
depth, 646,

formula for size of tile, 652.
grade, 645.

T64

Tile drains, interval, 647.
laying, 649.
outlets, 656.
silt basins, 656.
size, 650, 654,
surface intakes, 656.
trenches, construction, 648.
Tile drainage in alkali land, 659.
Tile drainage in muck and peat soil, 658.
Till, glacial soil, 53.
Tillage, objects, 663.
relation to colloids, 166.
relation on granulation, 194.
relation to means of soil infection,
425.
relation to run-off, 269.
relation to soil ventilation, 487.
implements, 664.
practices, 663.
Tillering and moisture, 253.
Tilth, effect of lime, 534,
Tilth of soil, 184.
Toxic material and drainage, 262, 632.
Toxic material in soil, 136.
Toxic substances, effect of lime, 536.
Toxicity and loss of bases, 378.
Trade values of fertilizer, 559.
Transpiration ratio, 244.
Transpiration and fertility, 250.
Transported soils, 31, 46.
Type of soil, named, 725.
Type of soil, the unit, 720.

Unavailable soil water, 256.
Underdrains, advantages, 635.
Underdrains, tile, 639.

Units in water measurement, 706.
Urea, derived from cyanamide, 504.
Urea, product of decay, 130.

Urine in manures, 584, 586.

Value of fertilizer, trade, 559, 562.

Value of manure, commercial, 602.

Vegetables, feeding power, 415.

Vegetation as means of soil classifica-
tion, 720.

Vegetative growth, favored by nitrogen,
547

Ventilation of soil, effect of drainage,
487, 630.

Vertical drainage, 660.

Volcanic dust, 63.

Water, amount to apply in irrigation, 710.
available to plants, 261.
application, time, 709.

INDEX

Water, as solvent in soil analysis, 340,
as weathering agent, 14.
carrying power, 40.
content, maximum, 262.
control of, 264.
capillary form, 210.
effect of movement on soil air, 483,
equivalents of soil, 220.
expansive power in freezing, 17.
forms in soil, 200.
functions of, in plant growth, 243.
gravitational form, 233.
hygroscopic form, 202.
interception losses, 287.
losses from evaporation, 270.
losses from run-off, 265.
relation of application to yield, 708.
requirements of plants, 244.
saved by mulch, 279.
sources for irrigation, 693.
specific heat, relation to, 298,
storage in soil, 713.
surfaces in soul, 212.
unavailable in soil, 256.
Water-logged land, 659.
Water-slaked lime, 539,
Weathering, conditions affecting, 22.
forces of, 14.
in arid and humid regions, 23.
of rocks, 13.
special cases, 27,
Weeder, cultivator, 676.
Weeds and crop growth, 280.
Weight of soil, 115.
Weir, for measurement of water, 707.
Wetting and drying, effect on granula-
tion, 187.
White alkali, 392.
Wilt of crops, a soil organism, 425.
Wilting coefficient, 257, 258.
Wilting point, calculation of, 260.
Wilting point, relation to texture, 261.
Wilting, when it occurs, 257.
Wind, effect of suction on soil air, 486.
Wind, erosion by, 15.
Wind, soils formed by, 58.
Wind-breaks and moisture control, 285.
Wood ashes, as fertilizer, 523.
Wool waste, as fertilizer, 507.
Worms in soil, 422.

Yard manure, 578.
Zeolites, 9, 355.

Zine sulfide test for acidity, 387.
Zircon, 9.

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